Manual 21605548

Manual 21605548
Safety Data Sheet
Dow Chemical Company Ltd
Product Name: GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
Revision Date: 2006/10/07
Print Date: 28 Sep 2007
Dow Chemical Company Ltd encourages and expects you to read and understand the entire (M)SDS,
as there is important information throughout the document. We expect you to follow the precautions
identified in this document unless your use conditions would necessitate other appropriate methods or
actions.
1.
Identification of the substance/preparation and of the company/undertaking
Product Name
GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
Use of the substance/preparation
Cavity sealing foam.
COMPANY IDENTIFICATION
Dow Chemical Company Ltd
Diamond House, Lotus Park
Kingsbury Crescent
TW18 3AG Staines, Middlesex
United Kingdom
020 3139 4000
Customer Information Number:
EMERGENCY TELEPHONE NUMBER
+44 (0) 1553 761 251
00 44 155 37 61 251
24-Hour Emergency Contact:
Local Emergency Contact:
2.
Composition/information on ingredients
Component
Amount
Prepolymer of MDI and
> 50.0 %
polyol
4,4'-Methylenediphenyl
10.0 - 20.0 %
diisocyanate;
diphenylmethane-4,4'diisocyanate (MDI)
Methylenediphenyl
10.0 - 20.0 %
diisocyanate,
homopolymer
Dimethyl ether
2.0 - 6.0 %
Isobutane
2.0 - 6.0 %
Propane
3.0 - 6.0 %
See Section 16 for full text of R-phrases.
Classification:
CAS #
EC #
Not classified.
Confidential
Polymer
Xn: R20; Xi: R36/37/38; 101-68-8
R42/43
202-966-0
Not classified.
39310-05-9
Polymer
F+: R12
F+: R12
F+: R12
115-10-6
75-28-5
74-98-6
204-065-8
200-857-2
200-827-9
* Indicates a Trademark
Page 1 of 10
Product Name: GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
3.
Revision Date: 2006/10/07
Hazards Identification
Irritating to eyes, respiratory system and skin.
May cause sensitization by inhalation and skin contact.
Extremely flammable.
May cause slight temporary corneal injury. May stain skin. Material may stick to skin causing irritation
upon removal. Excessive exposure may cause irritation to upper respiratory tract (nose and throat)
and lungs. May cause pulmonary edema (fluid in the lungs.) Asthma-like symptoms may include
coughing, difficult breathing and a feeling of tightness in the chest. Occasionally, breathing difficulties
may be life threatening.
4.
First-aid measures
Eye Contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the
initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a
physician, preferably an ophthalmologist.
Skin Contact: Remove material from skin immediately by washing with soap and plenty of water.
Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists.
Wash clothing before reuse. An MDI skin decontamination study demonstrated that cleaning very
soon after exposure is important, and that a polyglycol-based skin cleanser or corn oil may be more
effective than soap and water. Discard items which cannot be decontaminated, including leather
articles such as shoes, belts and watchbands.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth
use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by
qualified personnel. Call a physician or transport to a medical facility.
Ingestion: Do not induce vomiting. Call a physician and/or transport to emergency facility immediately.
Notes to Physician: If lavage is performed, suggest endotracheal and/or esophageal control. Danger
from lung aspiration must be weighed against toxicity when considering emptying the stomach. The
decision of whether to induce vomiting or not should be made by a physician. May cause respiratory
sensitization or asthma-like symptoms. Bronchodilators, expectorants and antitussives may be of
help. Treat bronchospasm with inhaled beta2 agonist and oral or parenteral corticosteroids.
Respiratory symptoms, including pulmonary edema, may be delayed. Persons receiving significant
exposure should be observed 24-48 hours for signs of respiratory distress. Maintain adequate
ventilation and oxygenation of the patient. If you are sensitized to diisocyanates, consult your
physician regarding working with other respiratory irritants or sensitizers. No specific antidote.
Treatment of exposure should be directed at the control of symptoms and the clinical condition of the
patient.
Medical Conditions Aggravated by Exposure: Excessive exposure may aggravate preexisting
asthma and other respiratory disorders (e.g. emphysema, bronchitis, reactive airways dysfunction
syndrome).
5.
Fire Fighting Measures
Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire
extinguishers. Foam. Do not use direct water stream. May spread fire. Alcohol resistant foams (ATC
type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function,
but will be less effective.
Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay
upwind. Keep out of low areas where gases (fumes) can accumulate. Water is not recommended, but
may be applied in large quantities as a fine spray when other extinguishing agents are not available.
Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or
monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound from
venting safety device or discoloration of the container. Do not use direct water stream. May spread
Page 2 of 10
Product Name: GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
Revision Date: 2006/10/07
fire. Move container from fire area if this is possible without hazard. Use water spray to cool fireexposed containers and fire-affected zone until fire is out.
Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely,
change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is
not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire
from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer to
the relevant sections.
Unusual Fire and Explosion Hazards: Product reacts with water. Reaction may produce heat and/or
gases. This reaction may be violent. Container may rupture from gas generation in a fire situation.
Violent steam generation or eruption may occur upon application of direct water stream to hot liquids.
Dense smoke is produced when product burns.
Hazardous Combustion Products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Nitrogen oxides. Isocyanates. Hydrogen cyanide.
Carbon monoxide. Carbon dioxide.
6.
Accidental Release Measures
Steps to be Taken if Material is Released or Spilled: Spills should be contained by, and covered
with large quantities of sand, earth or any other readily available absorbent material which is then
brushed in vigorously to assist absorption. The mixture can then be collected into drums and removed
for disposal. Wash area from residues with soap and water and rinse down.
Personal Precautions: Use appropriate safety equipment. For additional information, refer to Section
8, Exposure Controls and Personal Protection. Only trained and properly protected personnel must be
involved in clean-up operations. Keep unnecessary and unprotected personnel from entering the
area. If available, use foam to suppress vapors. See Section 10 for more specific information.
Environmental Precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information. Should the product enter sewers or drains, it
should be pumped into a covered, vented container; the cover should be placed loosely on the
container but not made pressure tight. Emergency services may need to be called to assist in the
cleanup operation.
7.
Handling and Storage
Handling
General Handling: Keep away from heat, sparks and flame. Use only with adequate ventilation.
Storage
Keep in a cool, well-ventilated place. Keep away from sources of ignition. See Section 10 for more
specific information.
Storage Period:
Storage temperature:
12 Months
15 - 25 °C
8.
Exposure Controls / Personal Protection
Exposure Limits
Component
List
Type
Value
Ireland OELV
TWA as
NCO
0.02 mg/m3 SEN
|
4,4'-Methylenediphenyl
diisocyanate;
diphenylmethane-4,4'diisocyanate (MDI)
Page 3 of 10
Product Name: GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
Ireland OELV
ACGIH
UK WEL
UK WEL
Revision Date: 2006/10/07
STEL as
NCO
TWA
TWA as
NCO
STEL as
NCO
0.07 mg/m3 SEN
0.005 ppm
0.02 mg/m3 SEN
0.07 mg/m3 SEN
|
Dimethyl ether
Ireland OELV
WEEL
EU IOELV
UK WEL
UK WEL
TWA
TWA
TWA
TWA
STEL
1,920 mg/m3 1,000 ppm
1,880 mg/m3 1,000 ppm
1,920 mg/m3 1,000 ppm
766 mg/m3 400 ppm
958 mg/m3 500 ppm
Isobutane
ACGIH
TWA
1,000 ppm
Propane
ACGIH
UK WEL
TWA
1,000 ppm
HAZ_DES
HAZ_DES
Included in the regulation but with no
data values. See regulation for
further details
Simple asphyxiant.
Asphyxiant.
|
|
Propane
Ireland OELV
UK WEL
A "SEN" notation following the exposure guideline refers to the potential to produce sensitization, as
confirmed by human or animal data.
Personal Protection
Eye/Face Protection: Use chemical goggles. Chemical goggles should be consistent with EN 166 or
equivalent. Eye wash fountain should be located in immediate work area.
Skin Protection: Use protective clothing chemically resistant to this material. Selection of specific
items such as face shield, boots, apron, or full body suit will depend on the task. Remove
contaminated clothing immediately, wash skin area with soap and water, and launder clothing before
reuse or dispose of properly. Items which cannot be decontaminated, such as shoes, belts and
watchbands, should be removed and disposed of properly.
Hand protection: Use chemical resistant gloves classified under Standard EN374: Protective
gloves against chemicals and micro-organisms. Examples of preferred glove barrier materials
include: Butyl rubber. Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate
("EVAL"). Examples of acceptable glove barrier materials include: Natural rubber ("latex").
Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Viton. Avoid gloves made of:
Polyvinyl chloride ("PVC" or "vinyl"). When prolonged or frequently repeated contact may
occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240
minutes according to EN 374) is recommended. When only brief contact is expected, a glove
with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to
EN 374) is recommended. NOTICE: The selection of a specific glove for a particular
application and duration of use in a workplace should also take into account all relevant
workplace factors such as, but not limited to: Other chemicals which may be handled, physical
requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions
to glove materials, as well as the instructions/specifications provided by the glove supplier.
Respiratory Protection: Atmospheric levels should be maintained below the exposure guideline.
When atmospheric levels may exceed the exposure guideline, use an approved air-purifying respirator
equipped with an organic vapor sorbent and a particle filter. For situations where the atmospheric
levels may exceed the level for which an air-purifying respirator is effective, use a positive-pressure
air-supplying respirator (air line or self-contained breathing apparatus). For emergency response or
for situations where the atmospheric level is unknown, use an approved positive-pressure selfcontained breathing apparatus or positive-pressure air line with auxiliary self-contained air supply.
Use the following CE approved air-purifying respirator: Organic vapor cartridge with a particulate prefilter, type AP2.
Ingestion: Avoid ingestion of even very small amounts; do not consume or store food or tobacco in
the work area; wash hands and face before smoking or eating.
Page 4 of 10
Product Name: GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
Revision Date: 2006/10/07
Engineering Controls
Ventilation: Use only with adequate ventilation. Local exhaust ventilation may be necessary for some
operations. Provide general and/or local exhaust ventilation to control airborne levels below the
exposure guidelines. Exhaust systems should be designed to move the air away from the source of
vapor/aerosol generation and people working at this point. The odor and irritancy of this material are
inadequate to warn of excessive exposure.
9.
Physical and Chemical Properties
Physical State
Color
Odor
Flash Point - Closed Cup
Flammable Limits In Air
Autoignition Temperature
Vapor Pressure
Boiling Point (760 mmHg)
Vapor Density (air = 1)
Specific Gravity (H2O = 1)
Freezing Point
Melting Point
Solubility in Water (by
weight)
pH
Kinematic Viscosity
10.
Foam
Brown
Musty
No test data available
Lower: No test data available
Upper: No test data available
No test data available
No test data available
No test data available.
No test data available
No test data available
No test data available
No test data available
reacts with water
Not applicable
No test data available
Stability and Reactivity
Stability/Instability
Stable under recommended storage conditions. See Storage, Section 7.
Conditions to Avoid: Avoid temperatures above 40°C (104°F) Can react with itself at temperatures
above 130°C (266°F) Exposure to elevated temperatures can cause product to decompose.
Generation of gas during decomposition can cause pressure in closed systems. Pressure build-up
can be rapid. Avoid moisture. Material reacts slowly with water, releasing carbon dioxide which can
cause pressure buildup and rupture of closed containers. Elevated temperatures accelerate this
reaction.
Incompatible Materials: Avoid contact with: Acids. Alcohols. Amines. Water. Ammonia. Bases.
Metal compounds. Moist air. Strong oxidizers. Products based on diisocyanates like TDI and MDI
react with many materials to release heat. The reaction rate increases with temperature as well as
with increased contact; these reactions can become violent. Contact is increased by stirring or if the
other material acts as a solvent. Products based on diisocyanates such as TDI and MDI are not
soluble in water and will sink to the bottom, but react slowly at the interface. The reaction forms
carbon dioxide gas and a layer of solid polyurea. Reaction with water will generate carbon dioxide and
heat. Avoid contact with metals such as: Aluminum. Zinc. Brass. Tin. Copper. Avoid contact with
absorbent materials such as: Moist organic absorbents. Avoid unintended contact with polyols. The
reaction of polyols and isocyanates generate heat.
Hazardous Polymerization
Can occur. Can react with itself at temperatures above 130°C (266°F) Polymerization can be
catalyzed by: Strong bases. Water.
Thermal Decomposition
Decomposition products depend upon temperature, air supply and the presence of other materials.
Gases are released during decomposition.
Page 5 of 10
Product Name: GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
11.
Revision Date: 2006/10/07
Toxicological Information
Acute Toxicity
Ingestion
Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling
operations are not likely to cause injury; however, swallowing larger amounts may cause injury.
Aspiration into the lungs may occur during ingestion or vomiting, causing lung damage or even death
due to chemical pneumonia. Observations in animals include: Gastrointestinal irritation.
Single dose oral LD50 has not been determined.
Eye Contact
May cause eye irritation. May cause slight temporary corneal injury.
Skin Contact
Prolonged contact may cause moderate skin irritation with local redness. Material may stick to skin
causing irritation upon removal. May stain skin.
Skin Absorption
Prolonged skin contact is unlikely to result in absorption of harmful amounts.
The LD50 has not been determined.
Inhalation
In confined or poorly ventilated areas, vapor can easily accumulate and can cause unconsciousness
and death due to displacement of oxygen. Excessive exposure may cause irritation to upper
respiratory tract (nose and throat) and lungs. May cause pulmonary edema (fluid in the lungs.)
Effects may be delayed. May cause central nervous system depression. Symptoms of excessive
exposure may be anesthetic or narcotic effects; dizziness and drowsiness may be observed.
Excessive exposure may increase sensitivity to epinephrine and increase myocardial irritability
(irregular heartbeats). Decreased lung function has been associated with overexposure to
isocyanates.
Sensitization
Skin
Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with
isocyanates may play a role in respiratory sensitization.
Respiratory
May cause allergic respiratory response. MDI concentrations below the exposure guidelines may
cause allergic respiratory reactions in individuals already sensitized. Asthma-like symptoms may
include coughing, difficult breathing and a feeling of tightness in the chest. Occasionally, breathing
difficulties may be life threatening.
Repeated Dose Toxicity
Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after
repeated excessive exposures to MDI/polymeric MDI aerosols. For the minor component(s): In
animals, effects have been reported on the following organs: Kidney.
Chronic Toxicity and Carcinogenicity
Lung tumors have been observed in laboratory animals exposed to aerosol droplets of MDI/Polymeric
MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory irritation and lung
injury. Current exposure guidelines are expected to protect against these effects reported for MDI.
Developmental Toxicity
In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only
at high doses which were toxic to the mother.
Genetic Toxicology
For the minor component(s): In vitro genetic toxicity studies were negative. Genetic toxicity data on
MDI are inconclusive. MDI was weakly positive in some in vitro studies; other in vitro studies were
negative. Animal mutagenicity studies were predominantly negative.
12.
Ecological Information
Page 6 of 10
Product Name: GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
Revision Date: 2006/10/07
CHEMICAL FATE
Data for Component: Prepolymer of MDI and polyol
Movement & Partitioning
In the aquatic and terrestrial environment, movement is expected to be limited by its reaction
with water forming predominantly insoluble polyureas.
Persistence and Degradability
In the aquatic and terrestrial environment, material reacts with water forming predominantly
insoluble polyureas which appear to be stable. In the atmospheric environment, material is
expected to have a short tropospheric half-life, based on calculations and by analogy with
related diisocyanates.
Data for Component: 4,4'-Methylenediphenyl diisocyanate; diphenylmethane-4,4'-diisocyanate
(MDI)
Movement & Partitioning
In the aquatic and terrestrial environment, movement is expected to be limited by its reaction
with water forming predominantly insoluble polyureas.
Persistence and Degradability
In the aquatic and terrestrial environment, material reacts with water forming predominantly
insoluble polyureas which appear to be stable. In the atmospheric environment, material is
expected to have a short tropospheric half-life, based on calculations and by analogy with
related diisocyanates.
Data for Component: Methylenediphenyl diisocyanate, homopolymer
Movement & Partitioning
In the aquatic and terrestrial environment, movement is expected to be limited by its reaction
with water forming predominantly insoluble polyureas.
Persistence and Degradability
In the aquatic and terrestrial environment, material reacts with water forming predominantly
insoluble polyureas which appear to be stable. In the atmospheric environment, material is
expected to have a short tropospheric half-life, based on calculations and by analogy with
related diisocyanates.
Data for Component: Dimethyl ether
Movement & Partitioning
Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential for
mobility in soil is very high (Koc between 0 and 50).
Henry's Law Constant (H): 1.31e-03 atm*m3/mole; 25 °C Measured
Partition coefficient, n-octanol/water (log Pow): 0.10 Measured
Partition coefficient, soil organic carbon/water (Koc): 14 Estimated
Persistence and Degradability
Material is not readily biodegradable according to OECD/EC guidelines.
OECD Biodegradation Tests:
Biodegradation
Exposure Time
Method
5%
OECD 301A Test
Data for Component: Isobutane
Movement & Partitioning
Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential for
mobility in soil is very high (Koc between 0 and 50).
Henry's Law Constant (H): 1.19E+00 atm*m3/mole; 25 °C Measured
Partition coefficient, n-octanol/water (log Pow): 2.76 Measured
Partition coefficient, soil organic carbon/water (Koc): 35 Estimated
Distribution in Environment: Mackay Level 1 Fugacity Model:
Soil
Air
Water.
Biota
Sediment
100 %
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Product Name: GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
Revision Date: 2006/10/07
Persistence and Degradability
Biodegradation may occur under aerobic conditions (in the presence of oxygen).
Data for Component: Propane
Movement & Partitioning
Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential for
mobility in soil is very high (Koc between 0 and 50).
Henry's Law Constant (H): 7.07e-01 atm*m3/mole; 25 °C Estimated
Partition coefficient, n-octanol/water (log Pow): 2.36 Measured
Partition coefficient, soil organic carbon/water (Koc): 24 - 460 Estimated
Distribution in Environment: Mackay Level 1 Fugacity Model:
Soil
Air
Water.
Biota
Sediment
100 %
Persistence and Degradability
Degradation is expected in the atmospheric environment within days to weeks.
ECOTOXICITY
Data for Component: Prepolymer of MDI and polyol
The measured ecotoxicity is that of the hydrolyzed product, generally under conditions
maximizing production of soluble species. Material is not classified as dangerous to aquatic
organisms (LC50/EC50/IC50 greater than 100 mg/L in most sensitive species).
Toxicity to Soil Dwelling Organisms
LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg
Data for Component: 4,4'-Methylenediphenyl diisocyanate; diphenylmethane-4,4'-diisocyanate
(MDI)
The measured ecotoxicity is that of the hydrolyzed product, generally under conditions
maximizing production of soluble species. Material is not classified as dangerous to aquatic
organisms (LC50/EC50/IC50 greater than 100 mg/L in most sensitive species).
Toxicity to Soil Dwelling Organisms
LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg
Data for Component: Methylenediphenyl diisocyanate, homopolymer
The measured ecotoxicity is that of the hydrolyzed product, generally under conditions
maximizing production of soluble species. Material is not classified as dangerous to aquatic
organisms (LC50/EC50/IC50 greater than 100 mg/L in most sensitive species).
Toxicity to Soil Dwelling Organisms
LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg
Data for Component: Dimethyl ether
Material is not classified as dangerous to aquatic organisms (LC50/EC50/IC50 greater than
100 mg/L in most sensitive species).
Fish Acute & Prolonged Toxicity
LC50, guppy (Poecilia reticulata), 96 h: > 4,000 mg/l
Aquatic Invertebrate Acute Toxicity
LC50, water flea Daphnia magna, 48 h: > 4,000 mg/l
13.
Disposal Considerations
Contents under pressure. Do not puncture or incinerate container. Relieve all pressure prior to
disposal. Do not dump into any sewers, on the ground, or into any body of water. The generation of
waste should be avoided or minimized wherever possible. Any disposal practice must be in
compliance with all local and national laws and regulations. Refer to manufacturer/supplier for
information on recovery/recycling.
Page 8 of 10
Product Name: GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
14.
Revision Date: 2006/10/07
Transport Information
ROAD & RAIL
Proper Shipping Name: AEROSOLS, FLAMMABLE
Hazard Class: 2.1 ID Number: UN1950
Classification: 5F
Tremcard Number: 20G5A
OCEAN
Proper Shipping Name: AEROSOLS, FLAMMABLE
Hazard Class: 2.1 ID Number: UN1950
EMS Number: F-D,S-U
Marine pollutant.: No
AIR
Proper Shipping Name: AEROSOLS, FLAMMABLE
Hazard Class: 2.1 ID Number: UN1950Cargo Packing Instruction: 203
Passenger Packing Instruction: 203
INLAND WATERWAYS
Proper Shipping Name: AEROSOLS, FLAMMABLE
Hazard Class: 2.1 ID Number: UN1950
Classification: 5F
Tremcard Number: 20G5A
15.
Regulatory Information
European Inventory of Existing Commercial Chemical Substances (EINECS)
The components of this product are on the EINECS inventory or are exempt from inventory
requirements.
EC Classification and User Label Information
Hazard Symbol :
Xn
- Harmful.
F+
- Extremely flammable.
Risk Phrases :
R36/37/38 - Irritating to eyes, respiratory system and skin.
R42/43 - May cause sensitization by inhalation and skin contact.
R12 - Extremely flammable.
Safety Phrases :
S23 - Do not breathe vapour/gas/fumes/spray.
S16 - Keep away from sources of ignition - no smoking.
S24/25 - Avoid contact with skin and eyes.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
S51 - Use only in well-ventilated areas.
S2 - Keep out of the reach of children.
S28 - After contact with skin, wash immediately with plenty of water and soap.
4,4'-Methylenediphenyl diisocyanate; diphenylmethane-4,4'-diisocyanate (MDI)
Contains:
Page 9 of 10
Product Name: GREAT STUFF(TM) Pro Gun Fixer Foam 750ml
Revision Date: 2006/10/07
Contains isocyanates. See information supplied by the manufacturer.
Container is under pressure.
Keep out of reach of children.
Protect from sun and temperatures above 50°C.
Do not spray against an open flame or glowing hot objects.
No smoking, open flames or sources of ignition in handling and storage area.
To avoid risk for man and the environment, follow the use instructions.
Do not open with force or incinerate even after use.
16.
Other Information
Other Information
Protective gloves should be worn when handling freshly-made polyurethane products to avoid skin
contact with trace amounts of residual materials, some of which may be hazardous in contact with
skin.
Risk-phrases in Section 2
R12
R20
R36/37/38
R42/43
Extremely flammable.
Harmful by inhalation.
Irritating to eyes, respiratory system and skin.
May cause sensitization by inhalation and skin contact.
Revision
Identification Number: 1001245 / 3005 / Issue Date 2006/10/07 / Version: 3.4
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Dow Chemical Company Ltd urges each customer or recipient of this (M)SDS to study it carefully and
consult appropriate expertise, as necessary or appropriate, to become aware of and understand the
data contained in this (M)SDS and any hazards associated with the product. The information herein is
provided in good faith and believed to be accurate as of the effective date shown above. However, no
warranty, express or implied, is given. Regulatory requirements are subject to change and may differ
between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with
all federal, state, provincial or local laws. The information presented here pertains only to the product
as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is
the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to
the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and
cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have
obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current,
please contact us for the most current version.
Page 10 of 10
Safety Data Sheet
Dow Chemical Company Ltd
Product Name: GREAT STUFF(TM) Pro Gun Cleaner EU 500ml
Revision Date: 2007/08/30
Print Date: 04 Oct 2007
Dow Chemical Company Ltd encourages and expects you to read and understand the entire (M)SDS,
as there is important information throughout the document. We expect you to follow the precautions
identified in this document unless your use conditions would necessitate other appropriate methods or
actions.
1.
Identification of the substance/preparation and of the company/undertaking
Product Name
GREAT STUFF(TM) Pro Gun Cleaner EU 500ml
Use of the substance/preparation
Cleaner.
COMPANY IDENTIFICATION
Dow Chemical Company Ltd
Diamond House, Lotus Park
Kingsbury Crescent
TW18 3AG Staines, Middlesex
United Kingdom
Customer Information Number:
020 3139 4000
For questions about this SDS, contact: [email protected]
EMERGENCY TELEPHONE NUMBER
+44 (0) 1553 761 251
00 44 155 37 61 251
24-Hour Emergency Contact:
Local Emergency Contact:
2.
Hazards Identification
Extremely flammable.
Irritating to eyes.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
Symptoms of excessive exposure may be anesthetic or narcotic effects; dizziness and drowsiness
may be observed. In use, may form flammable/explosive vapour-air mixture.
3.
Composition/information on ingredients
Component
Acetone; propanone
Amount
40.0 - 50.0 %
Classification:
CAS #
EC #
F: R11; Xi: R36; R66;
R67
67-64-1
200-662-2
* Indicates a Trademark
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Product Name: GREAT STUFF(TM) Pro Gun Cleaner EU 500ml
Propan-2-ol; isopropyl
20.0 - 30.0 %
alcohol; isopropanol
Isobutane
20.0 - 30.0 %
Propane
1.0 - 5.0 %
See Section 16 for full text of R-phrases.
4.
Revision Date: 2007/08/30
F: R11; Xi: R36; R67
67-63-0
200-661-7
F+: R12
F+: R12
75-28-5
74-98-6
200-857-2
200-827-9
First-aid measures
Eye Contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5
minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay,
preferably from an ophthalmologist.
Skin Contact: Wash skin with plenty of water.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth
use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by
qualified personnel. Call a physician or transport to a medical facility.
Ingestion: Do not induce vomiting. Call a physician and/or transport to emergency facility immediately.
Notes to Physician: The decision of whether to induce vomiting or not should be made by a
physician. If lavage is performed, suggest endotracheal and/or esophageal control. Danger from lung
aspiration must be weighed against toxicity when considering emptying the stomach. Maintain
adequate ventilation and oxygenation of the patient. Exposure may increase "myocardial irritability".
Do not administer sympathomimetic drugs such as epinephrine unless absolutely necessary.
Consider hemodialysis for patients with persistent hypotension or coma unresponsive to standard
therapy (isopropanol levels >400 - 500 mg/dl). (Goldfrank 1998, King et al, 1970). No specific
antidote. Treatment of exposure should be directed at the control of symptoms and the clinical
condition of the patient.
Medical Conditions Aggravated by Exposure: Skin contact may aggravate preexisting dermatitis.
5.
Fire Fighting Measures
Extinguishing Media: In case of fire, use water fog, foam, dry powder, carbon dioxide.
Fire Fighting Procedures: Down-wind personnel must be evacuated. Fire debris must be disposed
of in accordance with local regulations. Do not discharge extinguishing waters into streams, rivers and
lakes.
Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves).
Unusual Fire and Explosion Hazards: During a fire, smoke may contain the original material in
addition to combustion products of varying composition which may be toxic and/or irritating. Will
support combustion. Violent eruption of containers may occur under fire conditions.
Hazardous Combustion Products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Carbon dioxide. Carbon monoxide.
6.
Accidental Release Measures
Steps to be Taken if Material is Released or Spilled: Spills should be contained by, and covered
with large quantities of sand, earth or any other readily available absorbent material which is then
brushed in vigorously to assist absorption. The mixture can then be collected into drums and removed
for disposal. Wash area from residues with soap and water and rinse down.
Personal Precautions: Use appropriate safety equipment. For additional information, refer to Section
8, Exposure Controls and Personal Protection. Spilled material may cause a slipping hazard.
Environmental Precautions: Dike to prevent contamination of ground and surface water, then
transfer into closed containers. Recover if possible, or dispose of according to applicable regulations.
Page 2 of 9
Product Name: GREAT STUFF(TM) Pro Gun Cleaner EU 500ml
7.
Revision Date: 2007/08/30
Handling and Storage
Handling
General Handling: Keep equipment clean.
Storage
Keep in a cool place, heat causes an increase in pressure and risk of bursting.
Storage Period:
Storage temperature:
12 Months
15 - 25 °C
8.
Exposure Controls / Personal Protection
Exposure Limits
Component
List
Type
Value
Ireland OELV
ACGIH
ACGIH
EU IOELV
UK WEL
UK WEL
TWA
TWA
STEL
TWA
TWA
STEL
1,210 mg/m3
500 ppm
750 ppm
1,210 mg/m3
1,210 mg/m3
3,620 mg/m3
Ireland OELV
TWA
980 mg/m3 400 ppm SKIN
Ireland OELV
ACGIH
ACGIH
UK WEL
UK WEL
STEL
TWA
STEL
TWA
STEL
1,225 mg/m3 500 ppm SKIN
200 ppm
400 ppm
999 mg/m3 400 ppm
1,250 mg/m3 500 ppm
Isobutane
ACGIH
TWA
1,000 ppm
Propane
ACGIH
UK WEL
TWA
Asphyxiant
1,000 ppm
|
Acetone; propanone
500 ppm
500 ppm
500 ppm
1,500 ppm
|
Propan-2-ol; isopropyl
alcohol; isopropanol
|
|
Propane
Ireland OELV
UK WEL
HAZ_DES
HAZ_DES
Included in the regulation but with no
data values. See regulation for
further details
Simple asphyxiant.
Asphyxiant.
A "skin" notation following the exposure guideline refers to the potential for dermal absorption of the
material including mucous membranes and the eyes either by contact with vapors or by direct skin
contact.
It is intended to alert the reader that inhalation may not be the only route of exposure and that
measures to minimize dermal exposures should be considered.
Personal Protection
Eye/Face Protection: Use chemical goggles. Chemical goggles should be consistent with EN 166 or
equivalent. If exposure causes eye discomfort, use a full-face respirator.
Skin Protection: Wear clean, body-covering clothing.
Hand protection: Use gloves chemically resistant to this material when prolonged or
frequently repeated contact could occur. Use chemical resistant gloves classified under
Standard EN374: Protective gloves against chemicals and micro-organisms. Examples of
preferred glove barrier materials include: Butyl rubber. Natural rubber ("latex"). Neoprene.
Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Examples of acceptable glove barrier
materials include: Chlorinated polyethylene. Nitrile/butadiene rubber ("nitrile" or "NBR").
Polyvinyl alcohol ("PVA"). Polyvinyl chloride ("PVC" or "vinyl"). When prolonged or frequently
Page 3 of 9
Product Name: GREAT STUFF(TM) Pro Gun Cleaner EU 500ml
Revision Date: 2007/08/30
repeated contact may occur, a glove with a protection class of 3 or higher (breakthrough time
greater than 60 minutes according to EN 374) is recommended. NOTICE: The selection of a
specific glove for a particular application and duration of use in a workplace should also take
into account all relevant workplace factors such as, but not limited to: Other chemicals which
may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection),
potential body reactions to glove materials, as well as the instructions/specifications provided
by the glove supplier.
Respiratory Protection: Atmospheric levels should be maintained below the exposure guideline.
When respiratory protection is required, use an approved air-purifying or positive-pressure supplied-air
respirator depending on the potential airborne concentration. For emergency and other conditions
where the exposure guideline may be exceeded, use an approved positive-pressure self-contained
breathing apparatus or positive-pressure air line with auxiliary self-contained air supply. In confined or
poorly ventilated areas, use an approved self-contained breathing apparatus or positive pressure air
line with auxiliary self-contained air supply. Use the following CE approved air-purifying respirator:
Organic vapor cartridge, type A (boiling point >65 ºC)
Ingestion: Avoid ingestion of even very small amounts; do not consume or store food or tobacco in
the work area; wash hands and face before smoking or eating.
Engineering Controls
Ventilation: Use engineering controls to maintain airborne level below exposure limit requirements or
guidelines. If there are no applicable exposure limit requirements or guidelines, use only with
adequate ventilation. Local exhaust ventilation may be necessary for some operations. Lethal
concentrations may exist in areas with poor ventilation.
9.
Physical and Chemical Properties
Physical State
Color
Odor
Flash Point - Closed Cup
Flammable Limits In Air
Autoignition Temperature
Vapor Pressure
Boiling Point (760 mmHg)
Vapor Density (air = 1)
Specific Gravity (H2O = 1)
Freezing Point
Melting Point
Solubility in Water (by
weight)
pH
Kinematic Viscosity
10.
Liquid
Colorless
Characteristic
Not applicable
Lower: 1.4 %(V)
Upper: 13 %(V)
> 230 °C
2,500 - 2,900 hPa
No test data available.
No test data available
0.74 - 0.76
No test data available
No test data available
Partially soluble
Not applicable
Not applicable
Stability and Reactivity
Stability/Instability
Conditions to Avoid: Exposure to elevated temperatures can cause product to decompose. Because
of high vapour pressure, containers are liable to burst if temperature rises.
Incompatible Materials: Avoid contact with: Strong oxidizers. Alkali metal alkoxides.
Hazardous Decomposition Products: Unlikely to be formed under normal industrial use.
Hazardous Polymerization
Will not occur by itself.
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Product Name: GREAT STUFF(TM) Pro Gun Cleaner EU 500ml
Revision Date: 2007/08/30
Thermal Decomposition
Decomposition products depend upon temperature, air supply and the presence of other materials.
Decomposition products can include and are not limited to: Ketones. Organic acids. Alcohols.
11.
Toxicological Information
Acute Toxicity
Ingestion
Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling
operations are not likely to cause injury; however, swallowing larger amounts may cause injury.
Aspiration into the lungs may occur during ingestion or vomiting, causing lung damage or even death
due to chemical pneumonia. May cause central nervous system depression. May cause nausea and
vomiting. Signs and symptoms of excessive exposure may include: Facial flushing. Low blood
pressure. Irregular heartbeats.
Single dose oral LD50 has not been determined.
Eye Contact
May cause moderate eye irritation which may be slow to heal. May cause moderate corneal injury.
May cause pain disproportionate to the level of irritation to eye tissues. Vapor may cause eye irritation
experienced as mild discomfort and redness. Vapor may cause lacrimation (tears).
Skin Contact
Essentially nonirritating to skin. May cause drying and flaking of the skin.
Skin Absorption
Prolonged skin contact is unlikely to result in absorption of harmful amounts.
The dermal LD50 has not been determined.
Inhalation
Vapor concentrations are attainable which could be hazardous on single exposure. In confined or
poorly ventilated areas, vapor can readily accumulate and can cause unconsciousness and death.
May cause respiratory irritation and central nervous system depression. Symptoms may include
headache, dizziness and drowsiness, progressing to incoordination and unconsciousness. Excessive
exposure may increase sensitivity to epinephrine and increase myocardial irritability (irregular
heartbeats). Excessive exposure (400 ppm) to isopropanol may cause eye, nose and throat irritation.
Incoordination, confusion, hypotension, hypothermia, circulatory collapse, respiratory arrest and death
may follow a longer duration or higher levels. Observations in animals include middle ear lining
damage upon exposure to vapors of isopropanol. However, the relevance of this to humans is
unknown
Repeated Dose Toxicity
Symptoms of excessive exposure may be anesthetic or narcotic effects; dizziness and drowsiness
may be observed. Contains component(s) which have been reported to cause effects on the following
organs in animals: Blood. Kidney. Liver. Development of cataracts has been reported in laboratory
animals after prolonged repeated skin exposure to acetone. Based on information for component(s):
Isopropyl alcohol. Observations in animals include: Lethargy. Kidney effects and/or tumors have
been observed in male rats. These effects are believed to be species specific and unlikely to occur in
humans.
Chronic Toxicity and Carcinogenicity
Based on information for component(s): Isopropyl alcohol. Did not cause cancer in laboratory
animals.
Developmental Toxicity
Isopropanol has been toxic to the fetus in laboratory animals at doses toxic to the mother. Based on
information for component(s): Acetone. Has been toxic to the fetus in lab animals at doses toxic to
the mother.
Reproductive Toxicity
For the component(s) tested: In animal studies, did not interfere with reproduction.
Genetic Toxicology
For the component(s) tested: In vitro genetic toxicity studies were predominantly negative. Genetic
toxicity studies in animals were negative for component(s) tested.
Page 5 of 9
Product Name: GREAT STUFF(TM) Pro Gun Cleaner EU 500ml
12.
Revision Date: 2007/08/30
Ecological Information
CHEMICAL FATE
Data for Component: Acetone; propanone
Movement & Partitioning
Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential for
mobility in soil is very high (Koc between 0 and 50).
Henry's Law Constant (H): 1.38E-5 atm*m3/mole; 25 °C Estimated
Partition coefficient, n-octanol/water (log Pow): -0.24 Measured
Partition coefficient, soil organic carbon/water (Koc): 0.37 - 2.0 Estimated
Persistence and Degradability
Material is readily biodegradable. Passes OECD test(s) for ready biodegradability.
OECD Biodegradation Tests:
Biodegradation
Exposure Time
Method
91 %
28 d
OECD 301B Test
Data for Component: Propan-2-ol; isopropyl alcohol; isopropanol
Movement & Partitioning
Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential for
mobility in soil is very high (Koc between 0 and 50).
Henry's Law Constant (H): 3.38E-6 - 8.07E-6 atm*m3/mole; 25 °C Estimated
Partition coefficient, n-octanol/water (log Pow): 0.05 Measured
Partition coefficient, soil organic carbon/water (Koc): 1.1 Estimated
Persistence and Degradability
Material is readily biodegradable. Passes OECD test(s) for ready biodegradability.
OECD Biodegradation Tests:
Biodegradation
Exposure Time
Method
95 %
21 d
OECD 301E Test
Data for Component: Isobutane
Movement & Partitioning
Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential for
mobility in soil is very high (Koc between 0 and 50).
Henry's Law Constant (H): 1.19E+00 atm*m3/mole; 25 °C Measured
Partition coefficient, n-octanol/water (log Pow): 2.76 Measured
Partition coefficient, soil organic carbon/water (Koc): 35 Estimated
Persistence and Degradability
Biodegradation may occur under aerobic conditions (in the presence of oxygen).
Data for Component: Propane
Movement & Partitioning
Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential for
mobility in soil is very high (Koc between 0 and 50).
Henry's Law Constant (H): 7.07E-01 atm*m3/mole; 25 °C Measured
Partition coefficient, n-octanol/water (log Pow): 2.36 Measured
Partition coefficient, soil organic carbon/water (Koc): 24 - 460 Estimated
ECOTOXICITY
Data for Component: Acetone; propanone
Material is not classified as dangerous to aquatic organisms (LC50/EC50/IC50 greater than
100 mg/L in most sensitive species).
Fish Acute & Prolonged Toxicity
Page 6 of 9
Product Name: GREAT STUFF(TM) Pro Gun Cleaner EU 500ml
Revision Date: 2007/08/30
LC50, rainbow trout (Oncorhynchus mykiss), 96 h: 5,500 - 6,100 mg/l
Aquatic Invertebrate Acute Toxicity
EC50, water flea Daphnia magna, 48 h, immobilization: 6,084 mg/l
Aquatic Plant Toxicity
EC50, diatom Skeletonema costatum, biomass growth inhibition, 5 d: 11,800 - 14,400 mg/l
Data for Component: Propan-2-ol; isopropyl alcohol; isopropanol
Material is not classified as dangerous to aquatic organisms (LC50/EC50/IC50 greater than
100 mg/L in most sensitive species).
Fish Acute & Prolonged Toxicity
LC50, fathead minnow (Pimephales promelas), flow-through, 96 h: 8,680 mg/l
Aquatic Invertebrate Acute Toxicity
EC50, crustacean Corophium volutator, 48 h, immobilization: 7,550 - 13,299 mg/l
Aquatic Plant Toxicity
EC50, alga Scenedesmus sp., Growth rate inhibition, 72 h: > 1,000 mg/l
Toxicity to Micro-organisms
EC50; activated sludge, respiration inhibition: > 1,000 mg/l
Data for Component: Propane
No relevant information found.
13.
Disposal Considerations
Contents under pressure. Do not puncture or incinerate container. Relieve all pressure prior to
disposal. Do not dump into any sewers, on the ground, or into any body of water. The generation of
waste should be avoided or minimized wherever possible. Refer to manufacturer/supplier for
information on recovery/recycling. Any disposal practice must be in compliance with all local and
national laws and regulations.
14.
Transport Information
ROAD & RAIL
Proper Shipping Name: AEROSOLS, FLAMMABLE
Hazard Class: 2.1 ID Number: UN1950
Classification: 5F
Tremcard Number: 20G5A
OCEAN
Proper Shipping Name: AEROSOLS, FLAMMABLE
Hazard Class: 2.1 ID Number: UN1950
EMS Number: F-D,S-U
Marine pollutant.: No
AIR
Proper Shipping Name: AEROSOLS, FLAMMABLE
Hazard Class: 2.1 ID Number: UN1950Cargo Packing Instruction: 203
Passenger Packing Instruction: 203
INLAND WATERWAYS
Proper Shipping Name: AEROSOLS, FLAMMABLE
Hazard Class: 2.1 ID Number: UN1950
Classification: 5F
Tremcard Number: 20G5A
Page 7 of 9
Product Name: GREAT STUFF(TM) Pro Gun Cleaner EU 500ml
15.
Revision Date: 2007/08/30
Regulatory Information
European Inventory of Existing Commercial Chemical Substances (EINECS)
The components of this product are on the EINECS inventory or are exempt from inventory
requirements.
EC Classification and User Label Information
Hazard Symbol :
F+
- Extremely flammable.
Xi
- Irritant.
Risk Phrases :
R12 - Extremely flammable.
R36 - Irritating to eyes.
R66 - Repeated exposure may cause skin dryness or cracking.
R67 - Vapours may cause drowsiness and dizziness.
Safety Phrases :
S16 - Keep away from sources of ignition - no smoking.
S23 - Do not breathe vapour/gas/fumes/spray.
S24/25 - Avoid contact with skin and eyes.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
S51 - Use only in well-ventilated areas.
S2 - Keep out of the reach of children.
Acetone; propanone
Contains:
Propan-2-ol; isopropyl alcohol; isopropanol
Keep out of reach of children.
Container is under pressure.
Protect from sun and temperatures above 50°C.
Do not open with force or incinerate even after use.
No smoking, open flames or sources of ignition in handling and storage area.
Do not spray against an open flame or glowing hot objects.
16.
Other Information
Risk-phrases in the Composition section
R11
R12
R36
R66
R67
Highly flammable.
Extremely flammable.
Irritating to eyes.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
Revision
Identification Number: 1008609 / 3005 / Issue Date 2007/08/30 / Version: 1.2
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Dow Chemical Company Ltd urges each customer or recipient of this (M)SDS to study it carefully and
consult appropriate expertise, as necessary or appropriate, to become aware of and understand the
data contained in this (M)SDS and any hazards associated with the product. The information herein is
provided in good faith and believed to be accurate as of the effective date shown above. However, no
warranty, express or implied, is given. Regulatory requirements are subject to change and may differ
between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with
Page 8 of 9
Product Name: GREAT STUFF(TM) Pro Gun Cleaner EU 500ml
Revision Date: 2007/08/30
all federal, state, provincial or local laws. The information presented here pertains only to the product
as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is
the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to
the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and
cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have
obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current,
please contact us for the most current version.
Page 9 of 9
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