MATERIAL SAFETY DATA SHEET Page:1/6 MSDS No.:MFP-2652 Product Name: TONER TN216K Prepared Date:25-May-2009 Revised Date: 19-Aug-2015 1. PRODUCT AND COMPANY Product Name: TONER TN216K used for: C280/C220 IDENTIFICATION Supplier Identification: Konica Minolta Business Solutions (Canada), Ltd. 369 Britannia Road East Mississauga, Ontario L4Z 2H5 Telephone: (905)890-6600 Facsimile: (905)283-2511 Emergency Telephone No. CHEMTREC Telephone: 1-800-424-9300 WHMIS: This product is NOT subject to the controlled products regulations. 2. COMPOSITION / INFORMATION ON INGREDIENTS Substance [ ] Preparation [ X ] Major Ingredients: [Generic Name] Styrene acrylic resin Ferrite Iron oxide . Manganese oxide Wax Carbon black Wax-2 Amorphous silica Titanium dioxide [CAS No.] +++ 1309-37-1 1344-43-0 +++ 1333-86-4 +++ 7631-86-9 13463-67-7 [%] 65-75 1-10 1-10 1-10 1-10 1-10 1-10 <1 +++: Supplier’s confidential information Hazardous Ingredients: Chemical Name: Carbon black (<1%) CAS No.: 1333-86-4 OSHA Z-Tables(USA): 3.5mg/m3 NTP(USA): Not listed California Proposition 65(USA): Listed Symbol(EC): Not listed DFG-MAK(GER): III 3B Chemical Name: Titanium dioxide (<1%) CAS No.: 13463-67-7 OSHA Z-Tables(USA): 15mg/m3 NTP(USA): Not listed Symbol(EC): Not listed Chemical Name: Manganese oxide OSHA Z-Tables(USA): ceiling 5mg/m3 EEC-No.: 215-609-9 ACGIH-TLV(USA): 3.5mg/m3 IARC Monographs: Group 2B R-Phrase(EC): Not listed Worksafe-TWA(Austl): 3mg/m3 EEC-No.: 236-675-5 ACGIH-TLV(USA): 10mg/m3 IARC Monographs: Group 2B R-Phrase(EC): Not listed Worksafe-TWA(Austl): 10mg/m3 ACGIH-TLV(USA): 0.2mg/m3 Worksafe-TWA(Austl): 1mg/m3 MATERIAL SAFETY DATA SHEET Page:2/6 MSDS No.:MFP-2652 Product Name: TONER TN216K Prepared Date:25-May-2009 Revised Date: 19-Aug-2015 3. HAZARDS IDENTIFICATION Emergency Overview: Black powder (mean dia. is 5-10um by volume ). Almost oderless. Classification: Not classified as dangerous. (1999/45/EC) Most Important Hazards and Effects of the Products Ingestion Effect: None currently known. Inhalation Effect: None currently known. Minimal respiratory tract irritation may occur as with exposure to large amount of any non-toxic dust. Eye Effect: None currently known. Skin Effect: None currently known. Chronic Effects: Prolonged inhalation of excessive dusts may cause lung damage. Use of this product, as intended, does not result in inhalation of excessive dust. Environment Hazards: No data are available on the adverse effects of this product on the environment. Specific Hazards: Dust explosion(like most finely divided organic powders) 4. FIRST-AID MEASURES Ingestion: Wash out mouth with water. Drink one or two glasses of water. If symptoms occur, get medical attention. Inhalation: Move victim to fresh air immediately. If symptoms occur, get medical attention. Eye Contact: Immediately flush eyes with plenty of water for 15 minutes. If symptoms occur, get medical attention. Skin Contact: Wash with water and mild soap. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: CO2, water spray, foam and dry chemical Extinguishing Media to Avoid: Full water jet Fire and Explosion Hazards: If dispersed in air, like most finely divided organic powders, may form an explosive mixture. Protection of Firefighters: Use self-contained breathing apparatus(SCBA). 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: None Environmental Precautions: None Methods for Cleaning Up: Wear personal protective equipment(See Section 8). Vacuum or sweep material and place in a bag and hold for waste disposal. Use vacuum equipped with High Efficiency Particulate Air(HEPA) filter. Vacuum should be electrically bonded and grounded to dispel static electricity. To avoid dust generation, do not sweep dry. MATERIAL SAFETY DATA SHEET Page:3/6 MSDS No.:MFP-2652 Product Name: TONER TN216K Prepared Date:25-May-2009 Revised Date: 19-Aug-2015 7. HANDLING AND STORAGE Handling Technical Measures: None Precautions: Do not breathe dust. Avoid contact with eyes. Safe Handling Advice: Try not to disperse the particulates. Storage Technical Measures: None Storage Conditions: Keep container closed. Store in a cool and dry place. Keep out of reach of children. Incompatible Products: None Packaging Materials: Bottles or Cartridge designated by Konica Minolta. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Ventilation: None required with intended use. Control Parameters(As total dust) ACGIH-TLV(USA) : 10mg/m3 (Inhalable particles), 3.0 mg/m3 (Respirable particles) OSHA-PEL(USA): 15mg/m3 (Total dusts), 5.0 mg/m3 (Respirable fraction) DFG-MAK(GER): 4mg/m3 (Inhalable fraction), 1.5mg/m3 (Respirable fraction) Worksafe-TWA(Austl.): 10mg/m3 Personal Protective Equipment Not required under normal conditions. For use other than in normal operating procedures (such as in the event of large spill), goggles and respirators may be required. Hygiene Measures: Wash hands after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State: Solid Color: Black Form: Powder (mean dia. is 5-10um by volume) Odor: Almost oderless PH Not applicable Boiling Point(°C): Not applicable Melting Point(°C)/[F]: Around No data available / (Softening Point) Flash Point(°C): Not applicable Ignition Temperature(°C): No data available Explosion Properties: No data available Vapor Pressure: Not applicable Specific Gravity: 1.2 Solubility: Insoluble in water. Partition Coefficient, n-Octanol/Water: Not applicable MATERIAL SAFETY DATA SHEET Page:4/6 MSDS No.:MFP-2652 Product Name: TONER TN216K Prepared Date:25-May-2009 Revised Date: 19-Aug-2015 10. STABILITY AND REACTIVITY Stability: Stable except above 200C(392F). Hazardous Reactions: Dust explosion, like most finely divided organic powders. Conditions to avoid: Electric discharge, throwing into fire. Materials to Avoid: Oxidizing materials. Hazardous Decomposition Products: CO, CO2, NOx and smoke. Hazardous Polymerization: Will not occur. 11. TOXICOLOGICAL INFORMATION Acute Toxicity: Ingestion(oral), LD50(mg/kg): >2500(Rat) * Dermal, LD50(mg/kg): No data available Inhalation, LC50(mg/l): >5.17(Rat,4hour) * (This was the highest attainable concentration.) Eye irritation: Minimal irritant(Rabbit) * Skin irritation: Mild irritant(Rabbit) * Skin sensitizer: Non sensitizer (Guinea pig) * Local Effects: see Chronic Toxicity or Long term Toxicity Chronic Toxicity or Long Term Toxicity: In a two-year inhalation study of chronic toxicity and carcinogenicity using a typical toner in rats, there were no lung changes at all in the lowest exposure level (1mg/m3), the most relevant level to potential human exposures. A minimal to mild degree of fibrosis was noted in 22% of the animals at the middle exposure level (4mg/m3), and a mild to moderate degree of fibrosis was observed in 92% of the rats at the highest exposure level(16mg/m3). The lung changes observed in the higher exposure groups are interpreted in terms of "lung overloading", a series of generic responses to the presence of large quantities of respirable, insoluble and relatively benign dusts retained for extended time periods in the lungs. Lung tumor frequency was unchanged among rats exposed to toner at the three exposure levels, and for air-only control rats. Carcinogenicity The IARC reevaluated carbon black as a Group 2B carcinogen (possible human carcinogen). This evaluation is given to Carbon Black for which there is inadequate human evidence, but sufficient animal evidence. The latter is based upon the development of lung tumors in rats receiving chronic inhalation exposures to free carbon black at levels that induce particle overload of the lung. Studies performed in animal models other than rats have not demonstrated an association between carbon black and lung tumors. Moreover, a two-year cancer bioassay using a typical toner preparation containing carbon black demonstrated no association between toner exposure and tumor development in rats. The IARC reevaluated titanium dioxide as a Group 2B carcinogen (possible human carcinogen). In animal chronic inhalation studies, the tumor formulation observed in only rats with animal chronic inhalation study are attributed to “lung overloading”, a generic response to excessive amounts of any dust retained in the lungs for a prolonged interval. Use of this product, as intended, dose not result in inhalation of excessive dust. Epidemiological study to date have not revealed any evidence of the relation between exposure to titanium dioxide and diseases of the respiratory tract beyond general effects of dust. Mutagenicity: Negative(AMES test) Teratogenicity: No data available (*= Based on data for other Konica Minolta Products with similar ingredients) MATERIAL SAFETY DATA SHEET Page:5/6 MSDS No.:MFP-2652 Product Name: TONER TN216K Prepared Date:25-May-2009 Revised Date: 19-Aug-2015 12. ECOLOGICAL INFORMATION No data are available on the adverse effects of this material on the environment. Ecotoxicity: No data available Mobility: No data available Persistence and degradability: No data available Bioaccumulative potential: No data available 13. DISPOSAL CONSIDERATION When disposing of the waste or recovered material, consult federal, state and/or local regulations for the proper disposal method. 14. TRANSPORT INFORMATION Information on Code and Classifications According to International Regulations UN Classification: None Further information: Not a dangerous good under IATA or IMDG. 15. REGULATORY INFORMATION US Information Information on the label: Not required TSCA(Toxic Substances Control Act): All chemical substances in this product comply with all applicable rules or order under TSCA. California Proposition 65: Ingredient carbon black subject to California Proposition 65 is bound in polymer-matrices so that warnings are not required. EU Information Information on the label (1999/45/EC and 67/548/EEC): Not required Article14 (2.1) of Directive 1999/45/EC is not applicable to this product. WHMIS(Canada): This product is NOT subject to the controlled products regulations. 16. OTHER INFORMATION HMIS Rating: The National Paint and Coating Association(USA): Health: 1 Flammability: 1 Reactivity: 0 Recommended Uses: Toner for Electrophotographic Equipment Explanation of term: IARC 2B means "possible human carcinogen". Revision Information: Regular revision on revised date. Literature References: ANSI Z400.1-1993 ISO 11014-1 Commission Directive 91/155/EEC IARC(2010): IARC monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans, Vol. 93, Carbon Black, Titanium Dioxide, and Talc, Lyon, pp. 43-276 H.Muhle, B.Bellmann, O.Creutzenberg, C.Dasenbrock, H.Ernst, R.Kilpper, J.C.MacKenzie, P.Morrow, U.Mohr, S.Takenaka, and R.Mermelstein(1991) Pulmonary Response to Toner upon Chronic Inhalation Exposure in Rats. Fundamental and Applied Toxicology 17, pp.280-299. NIOSH CURRENT INTELLIGENCE BULLETIN :Evaluation of Health Hazard and Recommendation for Occupational Exposure to Titanium Dioxide :DRAFT MATERIAL SAFETY DATA SHEET Page:6/6 MSDS No.:MFP-2652 Product Name: TONER TN216K Prepared Date:25-May-2009 Revised Date: 19-Aug-2015 Restrictions: The above information is believed to be accurate and represents the best information currently available to Our Corporation. However, Our Corporation makes no warranty with respect to such information, and Our Corporation assumes no liability resulting from its use. Users should make their own investigation to determine the suitability of the information for their particular purposes.
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