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MATERIAL SAFETY DATA SHEET
CLOVER TECHNOLOGIES
4200 COLUMBUS STREET
OTTAWA, ILLINOIS 61350
MAY BE USED TO COMPLY WITH OSHA'S
HAZARD COMMUNICATION STANDARD
29CRF 1910.1200
EMERGENCY TELEPHONE NUMBER 1-815-431-8100
DATE PREPARED: 5/13/14
SECTION 1 CHEMICAL PRODUCT / NAME
Product/Chemical Name:
Toner for use in Samsung SCX 5635/5835/5935/MLTD208L Cartridges
CTG Product No:
13878
CAS Number:
Other Designations:
General Use:
Mixture
N/A
Laser Printer
SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS
Ingredient Name:
Polyester Resin
Carbon Black
Polypropylene Wax
Iron Oxide/Ferrite
Amorphous Silica
CAS
NUMBER
EU
NUMBER
Registered
1333-86-4
TRADE SECRET
1317-61-9
67762-90-7
%
>82
<8
<4
<4
<2
OSHA
PEL
ACGIH
TLV
OTHER
LIMITS
Toner is regulated under OSHA as particulate not
otherwise regulated:
not listed
not listed
3.5mg/m3
3.5mg/m3
not listed
not listed
not listed
not listed
not listed
not listed
NDA = NO DATA AVAILABLE
N/A = NOT APPLICABLE
SECTION 3 HAZARDOUS IDENTIFICATION
Primary Entry Routes:
Inhalation
Target Organs:
N/A
Acute Effects:
N/A
Inhalation:
minimal irritation to respiratory tract may occur.
Eye:
Solid or dust may cause irritation or corneal injury.
NFPA/HMIS
HEALTH
1
FLAMMABILITY. 1
REACTIVITY
1
PPE (Sec.8)
-
Skin:
Essentially nonirritating to skin.
Ingestion:
Oral toxicity is believed to be low.
Carbon Black is reclassified as a group 2B by IARC, but inhalation test using a typical toner showed no
Carcinogenicity:
association between toner and animal tumors.
Medical Conditions Aggravated By Long-Term Exposure:
Accumulation of dust in the respiratory system
may cause congestion.
If these materials are used in a manner that could generate airborne particles (dust), it is recommended that
Chronic Effects:
the dust may be treated as a NUISANCE PARTICULATE according to the American Conference of Government
Industrial Hygienists (ACGIH)(TLV=10mg/m3).
SECTION 4 FIRST AID MEASURES
Inhalation:
Remove to fresh air. Treat any irritation symptomatically. Call a physician if condition persists.
Eye Contact: In case of contact immediately flush with plenty of low pressure water for at least
15 minutes. Remove any contact lenses to ensure thorough flushing.
Skin Contact: Wash well with soap and running water.
Ingestion:
No adverse effects anticipated by this route of exposure incidental to proper handling.
After first aid, get appropriate in-plant paramedic or community medical support
if serious signs and symptoms persist.
Note to Physicians:
N/A
Special Precautions / Procedures:
N/A
SECTION 5 FIRE FIGHTING MEASURES
Flash Point:
N/A
Flash Point Method: N/A
Burning Rate:
N/A
Auto Ignition Temperature: Not Determined
LEL:
N/A
UEL:
N/A
Flammability Classification:
1 Slight (HMIS, NFPA)
Extinguishing Media:
Water spray, fog, foam, carbon dioxide, or dry chemicals.
Unusual Fire of Explosion Hazards:
May form flammable dust-air mixture.
Hazardous Combustion Products:
Carbon monoxide, carbon dioxide, nitrogen oxide and smoke.
Under certain conditions some aliphatic aldehydes and carboxylic acids
may form.
Fire-Fighting Instructions: Do not release runoff from fire controls methods to sewers or waterways.
Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products, wear a
self-contained breathing apparatus (SCBA) with full facepiece operated
in pressure-demand or positive-pressure mode.
SECTION 6 ACCIDENTAL RELEASE MEASURES
Spill / Leak Procedures:
N/A
Small Spills: Scoop into a container for disposal, suction up remaining material with a high efficiency
vacuum cleaner.
Large Spills: Scoop into a container for disposal, suction up remaining material with a high efficiency
vacuum cleaner.
Containment: For large spills, avoid suspending particles, collect for later disposal. Do not release
into sewers or waterways.
Cleanup:
No special requirements.
Regulatory Requirement: N/A
SECTION 7 HANDLING AND STORAGE
Handling Precautions:
Storage Requirements:
Regulatory Requirement:
Keep containers closed at all times. Avoid creating dust. Clean up spills promptly.
Store in a cool, well ventilated dry location away from flames and spark producing equipment.
N/A
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Controls:
Ventilation:
Provide general or local exhaust ventilation systems to maintain airborne concentrations
below OSHA PELs (sec.2). Local exhaust ventilation is preferred because it prevents contaminant
dispersion into the work area by controlling it at its source.
Administrative Controls:
Respiratory Protection:
Seek professional advise prior to respirator selection and use.
Follow OSHA respirator regulations (29 CFR 1910.134) and, if necessary, wear
a MSHA/NIOSH-approved respirator. Select respirator based on its suitability
to provide adequate worker protection for given working conditions, level of
airborne contamination, and presence of sufficient oxygen. For emergency or
nonroutine operation (cleaning spills, reactor vessels, or storage tanks), wear
an SCBA. Warning! Air-purified respirators do not protect workers in oxygen-deficient
atmospheres.
Protective Clothing/Equipment: Wear chemically protective gloves, boots, aprons, and gauntlets to prevent
prolonged or repeated skin contact. Wear protective eyeglasses or
chemical safety goggles, per OSHA eye and face protection regulations
(29CFR 1910.133). Contact lenses are not eye protective devices. Appropriate
protection must be worn instead of, or in conjunction with contact lenses.
Safety Stations:
Make emergency eyewash stations and washing facilities available in work area.
Contaminated Equipment: Separate contaminated work clothing from street clothes. Launder before
re-use. Remove this material from your shoes and clean personal protective
equipment.
Comments: Never eat, drink, or smoke in works areas. Practice good personal hygiene after using this
material, especially before eating, drinking, using the toilet, or applying cosmetics.
5.0mg/m3
Control Parameters:
OSHA PELS (TWA)
(Inert of Nuisance Dust: Respirable fraction)
15.0mg/m4
ACGIH TLV (TWA)
(Inert of Nuisance Dust: Total dust)
ACGIH TLV: TWA (2003)
3.0mg/m3
10.0mg/m4
(particulates not otherwise Classified: Respirable particle Mass)
(particulates not otherwise Classified: Inhalable particle Mass)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Physical State:
Appearance and Odor:
Odor Threshold:
Vapor Pressure:
Vapor Density (Air=1):
Formula Weight:
Density:
Specific Gravity:
pH:
Black, free flowing powder, odorless
N/A
N/A
Heavier than air.
N/A
N/A
(H2O)=1, at 4°C): 1.0-1.5
N/A
Water Solubility:
Other Solubilities:
Boiling Point:
Freezing/Melting Point:
Viscosity:
Refractive Index:
Surface Tension:
% Volatile:
Evaporation Rate:
Negligible
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
SECTION 10 STABILITY AND REACTIVITY
Stability:
Stable
Polymerization:
Will not occur
Chemical Incompatibilities:
N/A
Conditions to Avoid: No Data
(SPECIAL MATERIALS TO AVOID) Oxidizing materials.
Hazardous Decomposition Products:
Only after combustion
SECTION 11 TOXICOLOGICAL INFORMATION
Eye Effects: N/A
Chronic Effects:
N/A
Toxicity Data:*
Skin Effects:
N/A
Acute Inhalation Effects:
Acute Oral Effects:
N/A
N/A
Carcinogenicity:
In 1996, The IARC revaluated carbon black as a Group 2B carcinogen (possible human carcinogen). This evaluation was given to
carbon black for which there is inadequate human evidence, but sufficient animal evidence.The latter based upon the developer
of lung tumors in rat receiving chronic inhalation to free carbon black at level that induce particle overload of the luings.
Studies performed in animal models other than rats have not demonstrated an association between carbon black and lung tumors.
Moreover, a two year cancer bioassay using a typical toner preparation containing carbon black demostrated no association between
toner exposure and tumor development in rats.
Mutagenicity: Ames Test
(Estimated from the results of
testing the constituent components)
Negative
*See NIOSH, RTECS for additional toxicity data.
Teratogenicity:
N/A
SECTION 12 ECOLOGICAL INFORMATION
Ecotoxicity:
N/A
Environmental Fate:
N/A
Environmental Degradation:
Soil Absorption / Mobility:
N/A
N/A
SECTION 13 DISPOSAL CONSIDERATIONS
Disposal:
Waste material may be incinerated / or recycled for its Iron Oxide under conditions which meet
all federal, state, and local environmental regulations.
Disposal Regulatory Requirements:
N/A
Container Cleaning and Disposal:
N/A
SECTION 14 TRANSPORT INFORMATION
DOT Transportation Data (49 CFR 172.101):
Shipping Name:
Shipping Symbol:
Hazard Class:
ID No:
Packing Group:
Label:
Special Provisions:
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Not specifically listed.
Packaging Authorizations
a) Exceptions:
N/A
b) Non-bulk Packaging: N/A
c) Bulk Packaging:
N/A
Quantity Limitations
a) Passenger, Aircraft, or
Railcar:
N/A
Vessel Stowage Requirements
a) Vessel Stowage: N/A
b) Other: N/A
SECTION 15 REGULATORY INFORMATION
EPA Regulations:
RCRA Hazardous Waste Number: Not listed (40 CFR 261.33)
RCRA Hazardous Waste Classification: (40 CFR 261): Not classified
CERCLA Hazardous Substance (40 CFR 302.4) listed unlisted specific per RCRA, sec. 3001;
CWA sec.311 (b)(4);
CWA, Sec. 307(a),CAA,Sec.112
CERCLA Reportable Quantity(RQ), Not listed
SARA 311/312 Codes:
N/A
SARA Toxic Chemical (40 CFR 372.65): Not listed
SARA EHS (Extremely Hazardous Substance) (40CFR 355): Not listed, Threshold Planning Quantity (TPQ)
OSHA Regulations:
Air Containment (29 CFR 1910.1000< Table Z-1-A): Particulates not otherwise regulated.
State Regulations: Check your states regulations that may specifically list copy machine toner.
SECTION 16 OTHER INFORMATION
Prepared By:
N/A
Revision Notes:
N/A
Additional Hazard Rating System:
N/A
THIS INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH WE BELIEVE
ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY
EXPRESS OR IMPLIED, REGARDLESS IT'S CORRECTNESS.
THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE AND DISPOSAL OF THE
PRODUCT ARE BEYOND OUR CONTROL, AND MAY BE BEYOND OUR KNOWLEDGE.
FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY
DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY
CONNECTED WITH THE HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT.
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