safety data sheet

safety data sheet
SAFETY DATA SHEET
KEYSTONE FRYER CLEANER
Section 1. Chemical product and company identification
Product name
Recommended use and
restrictions
: KEYSTONE FRYER CLEANER
: Degreaser
Use only for the purpose on the product label.
Product dilution information : Not applicable
Supplier's information
Code
Date of issue
: Ecolab Inc. Institutional Division
370 N. Wabasha Street
St. Paul, MN 55102
1-800-352-5326
: 924785-04
: 15 Nov 2013
EMERGENCY HEALTH INFORMATION: 1-800-328-0026
Outside United States and Canada CALL 1-651-222-5352 (in USA)
Section 2. Hazards identification
GHS Classification
Product AS SOLD
Product AT USE DILUTION
: ACUTE TOXICITY: ORAL - Category 4
Product is sold ready to use.
SKIN CORROSION/IRRITATION - Category 1B
SERIOUS EYE DAMAGE/ EYE IRRITATION Category 1
SPECIFIC TARGET ORGAN TOXICITY
(SINGLE EXPOSURE) [Respiratory tract
irritation] - Category 3
GHS label elements
Signal word
Symbol
: Danger
:
Hazard statements
: Harmful if swallowed.
Causes severe skin burns and eye damage.
May cause respiratory irritation.
Precautionary statements
Prevention
Response
: Wear protective gloves. Wear eye or face
protection. Wear protective clothing. Use only
outdoors or in a well-ventilated area. Avoid
breathing dust. Do not breathe dust or mist.
Wash hands thoroughly after handling.
: IF INHALED: Remove victim to fresh air and
keep at rest in a position comfortable for
breathing. Immediately call a POISON
CENTER or physician. IF SWALLOWED:
Immediately call a POISON CENTER or
physician. Rinse mouth. Do NOT induce
vomiting. IF ON SKIN (or hair): Take off
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KEYSTONE FRYER CLEANER
15 Nov 2013
Section 2. Hazards identification
immediately all contaminated clothing. Rinse
skin with water or shower. Wash contaminated
clothing before reuse. Immediately call a
POISON CENTER or physician. IF IN EYES:
Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to
do. Continue rinsing. Immediately call a
POISON CENTER or physician.
: No other specific measures identified.
: See section 13 for waste disposal information.
: Handling and/or processing of this material
may generate a dust which can cause
mechanical irritation of the eyes, skin, nose and
throat.
Storage
Disposal
Other hazards
Section 3. Composition/information on ingredients
Substance/mixture
Product AS SOLD
: Mixture
Hazardous ingredients
SODIUM METASILICATE
SODIUM CARBONATE
TETRASODIUM EDTA
alcohols, c12-16, ethoxylated
Concentration Range (%)
>50
5 - 20
1-5
1-5
CAS number
6834-92-0
497-19-8
64-02-8
68551-12-2
Product AT USE DILUTION
Hazardous ingredients
Concentration Range (%)
CAS number
Product is sold ready to use.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
Product AS SOLD
Product AT USE DILUTION
: Rinse cautiously with water for several minutes.
Product is sold ready to use.
Remove contact lenses, if present and easy to do.
Continue rinsing. Get medical attention
immediately.
: Take off immediately all contaminated clothing.
Rinse skin with water or shower. Get medical
attention immediately. Wash clothing before
reuse. Clean shoes thoroughly before reuse.
: Remove victim to fresh air and keep at rest in a
position comfortable for breathing. Get medical
attention immediately.
: Get medical attention immediately. Rinse mouth.
Do not induce vomiting.
Protection of firstaiders
: No action shall be taken involving any personal risk or without suitable training. It may be
dangerous to the person providing aid to give mouth-to-mouth resuscitation. If ventilation is
inadequate, use respirator that will protect against dust/mist. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The
exposed person may need to be kept under medical surveillance for 48 hours.
See toxicological information (section 11)
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15 Nov 2013
Section 5. Fire-fighting measures
Product AS SOLD
Suitable fire extinguishing
media
Specific hazards arising
from the chemical
Hazardous thermal
decomposition products
Specific fire-fighting
methods
Special protective
equipment for fire-fighters
: Use dry chemical powder.
: No specific fire or explosion hazard.
: Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
metal oxide/oxides
: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without
suitable training.
: Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Section 6. Accidental release measures
Personal
precautions
Environmental
precautions
Methods for
cleaning up
Product AS SOLD
: Initiate company's spill response procedures
immediately. Keep people out of area. Put on
appropriate personal protective equipment (see
section 8). Do not touch or walk through spilled
material.
: Avoid contact of spilled material and runoff with
soil and surface waterways.
: If emergency personnel are not present, contain
and collect small spillages with non-combustible
absorbent material, e.g. sand, earth or other
suitable material and place in a suitable container
for disposal. Use a water rinse for final clean-up.
Product AT USE DILUTION
Product is sold ready to use.
Section 7. Handling and storage
Handling
Storage
Product AS SOLD
: Do not ingest. Do not get in eyes or on skin or
clothing. Do not breathe dust. Use only with
adequate ventilation. Wash thoroughly after
handling.
: Keep out of reach of children. Keep container
tightly closed.
Product AT USE DILUTION
Product is sold ready to use.
Store between the following temperatures: 0 and
50°C
Section 8. Exposure controls/personal protection
Control parameters
Ingredient name
Exposure limits
None.
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KEYSTONE FRYER CLEANER
15 Nov 2013
Section 8. Exposure controls/personal protection
Product AS SOLD
Appropriate
: Use only with adequate ventilation. If user
operations generate dust, fumes, gas, vapor or
engineering controls
mist, use process enclosures, local exhaust
ventilation or other engineering controls to keep
worker exposure to airborne contaminants below
any recommended or statutory limits. Provide
suitable facilities for quick drenching or flushing
of the eyes and body in case of contact or splash
hazard.
Personal protection
Eye protection
: Use chemical splash goggles. For continued or
severe exposure wear a face shield over the
goggles.
Hand protection
: Use chemical-resistant, impervious gloves.
Skin protection
: Use synthetic apron, other protective equipment
as necessary to prevent skin contact.
Respiratory
: A respirator is not needed under normal and
intended conditions of product use.
protection
Hygiene measures
Product AT USE DILUTION
Product is sold ready to use.
: Wash hands, forearms and face thoroughly after handling chemical products, before eating,
smoking and using the lavatory and at the end of the working period. Appropriate techniques
should be used to remove potentially contaminated clothing. Wash contaminated clothing
before reusing.
Section 9. Physical and chemical properties
Physical state
Product AS SOLD
: Powder
Color
: White [Light]
Odor
pH
Flash point
: Faint odor
: 12 to 13.2 (1%)
: > 100°C
Product does not support combustion.
Explosion limits
Flammability (solid,
gas)
Melting point
Boiling point
Evaporation rate
(butyl acetate = 1)
Vapor pressure
: Not available.
: Not available.
Vapor density
: Not available.
: Not applicable.
Relative density
Product AT USE DILUTION
Product is sold ready to use.
: Not available.
: Not available.
: Not available.
: Not available.
Solubility
: Easily soluble in the following materials: hot water.
Soluble in the following materials: cold water.
Partition coefficient: : Not available.
n-octanol/water
Auto-ignition
temperature
Decomposition
temperature
Odor threshold
: Not available.
: Not available.
: Not available.
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KEYSTONE FRYER CLEANER
15 Nov 2013
Section 9. Physical and chemical properties
Viscosity
: Kinematic (room temperature): 0 cm 2/s (0 cSt)
Section 10. Stability and reactivity
Product AS SOLD
Stability
Possibility of hazardous
reactions
: The product is stable.
: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid
Materials to avoid
: No specific data.
: Slightly reactive or incompatible with the following materials: metals and acids.
Hazardous decomposition
products
: Under normal conditions of storage and use, hazardous decomposition products
should not be produced.
Section 11. Toxicological information
Route of exposure
: Skin contact, Eye contact, Ingestion
Product AS SOLD
Symptoms
Eye contact
Skin contact
Inhalation
Ingestion
Acute toxicity
Eye contact
Skin contact
Inhalation
Ingestion
Product AT USE DILUTION
: Adverse symptoms may include the following:
pain
watering
redness
: Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
: Adverse symptoms may include the following:
respiratory tract irritation
coughing
Respiratory tract irritation
: Adverse symptoms may include the following:
stomach pains
:
:
:
:
Product is sold ready to use.
Causes serious eye damage.
Causes severe burns.
May cause respiratory irritation.
Harmful if swallowed. May cause burns to mouth,
throat and stomach.
Toxicity data
Product/ingredient name
disodium metasilicate
sodium carbonate
acetic acid, (ethylenedinitrilo)tetra-,
tetrasodium salt
alcohols, c12-16, ethoxylated
LD50 Oral
LC50 Inhalation
Dusts and mists
LD50 Dermal
LD50 Oral
LD50 Oral
Rat
Rat
500 mg/kg
1.15 mg/l
LD50 Dermal
LD50 Oral
Rabbit >2000 mg/kg
Rat
1100 mg/kg
Rabbit >2000 mg/kg
Rat
2800 mg/kg
Rat
1700 mg/kg
Chronic toxicity
Carcinogenicity
Mutagenicity
: No known significant effects or critical hazards.
: No known significant effects or critical hazards.
Teratogenicity
: No known significant effects or critical hazards.
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KEYSTONE FRYER CLEANER
15 Nov 2013
Section 11. Toxicological information
Developmental effects
Fertility effects
: No known significant effects or critical hazards.
: No known significant effects or critical hazards.
Section 12. Ecological information
Product AS SOLD
Ecotoxicity
: This material is harmful to aquatic life.
Aquatic and terrestrial toxicity
Product/ingredient name
Result
disodium metasilicate
Acute LC50 210 mg/l
sodium carbonate
Acute EC50 200 mg/l
acetic acid, (ethylenedinitrilo)tetra-, tetrasodium Acute LC50 121 mg/l
salt
alcohols, c12-16, ethoxylated
Acute LC50 1.5 mg/l
Other adverse effects
: No known significant effects or critical hazards.
Species
Fish
Daphnia
Fish
Exposure
96 hours
48 hours
96 hours
Fish
96 hours
Section 13. Disposal considerations
Disposal methods
Product AS SOLD
: Avoid disposal. Attempt to use product
completely in accordance with intended use.
Disposal should be in accordance with applicable
regional, national and local laws and regulations.
Product AT USE DILUTION
Product is sold ready to use.
Section 14. Transport information
Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification
provided may not reflect those exceptions and may not apply to all shipping modes or package sizes.
DOT
DOT Classification
UN3262
DOT Proper shipping name
Corrosive solid, basic, inorganic, n.o.s. (disodium metasilicate)
Class
8
Packing group
II
IMO/IMDG
IMO/IMDG Classification
UN3262
IMO/IMDG Proper shipping name
CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. (disodium metasilicate)
Class
8
Packing group
II
For transport in bulk, see shipping documents for specific transportation information.
Product AT USE DILUTION
Not intended for transport.
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KEYSTONE FRYER CLEANER
15 Nov 2013
Section 15. Regulatory information
Product AS SOLD
U.S. Federal regulations
TSCA 8(b) inventory
: All components are listed or exempted.
SARA 302/304/311/312 extremely hazardous substances: No listed substance
SARA 302/304 emergency planning and notification: No listed substance
Product name
SARA 313
Form R - Reporting
requirements
CAS number
Concentration
: No listed substance
California Prop. 65
: No listed substance
Section 16. Other information
Product AS SOLD
Hazardous Material
Information System (U.S.A.)
:
Health
3
Flammability
0
Physical hazards
0
:
National Fire Protection
Association (U.S.A.)
Flammability
0
Health
3
0
Instability/Reactivity
Special
Date of issue
Prepared by
: 15 Nov 2013
: Regulatory Affairs
1-800-352-5326
Notice to reader
The above information is believed to be correct with respect to the formula used to manufacture the product in
the country of origin. As data, standards, and regulations change, and conditions of use and handling are
beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR
CONTINUING ACCURACY OF THIS INFORMATION.
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