Safety Data Sheets
SAFETY DATA SHEET
1. IDENTIFICATION OF THE SUBSTANCE PREPARATION AND COMPANY UNDERTAKING
1.1 PRODUCT IDENTIFIER
Product name:
N/A
Part number:
WERCS1176798
1.2 IDENTIFIED USES AND USES ADVISED AGAINST
For use in:
This mixture is a toner used in copiers/printers.
1.3 SUPPLIER DETAILS
Supplier:
Contact Hours:
Clover Technologies Group
4200 Columbus Street.
Ottawa, IL 61350
United States
Phone number: 815-431-8100
Fax: 815-461-8583
08:00AM-05:00PM CST
1.4 EMERGENCY TELEPHONE NUMBERS
Supplier:
N/A
* This document provides safety-related information about toner contained in print cartridge for use in laser printer
2. HAZARDS IDENTIFICATION
2.1 INFORMATION and CLASSIFICATION
Overview:
Primary Entry Routes: Inhalation. Target Organs: N/A. Acute Effects: N/A. Inhalation: Slight irritation of
respiratory tract. Eye: Dust may cause irritation by mechanical abrasion. Skin: Slight irritation.
Ingestion: None known. Carcinogenicity: N/A. Medical Conditions Aggravated By Long-Term Exposure:
Accumulation of dust in the respiratory system may cause congestion. Chronic Effects: If these
materials are used in a manner that could generate airborne particles (dust), it is recommended that
the dust be treated as a NUISANCE PARTICULATE according to the American Conference of Government
Industrial Hygienists (ACGIH)(TLV=10mg/m3).
2.2 LABEL ELEMENTS
Applicable Pictograms:
Danger Indications:
N/A
Risk Phrases:
N/A
Safety Phrases:
N/A
2.3 OTHER HAZARDS
PBT or vPvB:
Product: N/A
N/A
Revision date: 05/19/2015
Page: 1/9
SAFETY DATA SHEET
3. COMPOSITION / INFORMATION ON INGREDIENTS
Ingredients
CAS number
Weight %
OSHA
PEL
Styrene-Acrylate
Copolymer
25036-16-2
70
15mg/m3;
5mg/m3 for
respirable
fraction
Iron Oxide (Black Pigment)
Polypropylene
1317-61-9
9003-07-0
21
5
Dye
Silica
84179-66-8
7631-86-9
2
2
ACGIH
TLV
Other
ACGIH TWA:
10mg/m3
for nuisance
particulate
Toner is regulated under OSHA as
particulate not otherwise
regulated.
The Full Text for all R-Phrases are Displayed in Section 16
COMPOSITION COMMENTS
The Data Shown is in accordance with the latest Directives.
This section provides composition information for the toner powder contained in specially designed container inside of the print
cartridge.
4. FIRST-AID MEASURES
4.1 FIRST AID MEASURES
4.1.1
4.1.2
FIRST AID INSTRUCTIONS BY RELEVANT ROUTES OF EXPOSURE
Inhalation:
Remove to fresh air. Treat any irritation symptomatically. Call a physician if condition persists.
Eye contact:
Skin contact:
In case of contact immediately flush with plenty of low pressure water for at least 15 minutes.
Remove any contact lenses to ensure thorough flushing.
Wash well with soap and running water.
Ingestion:
N/A
ADDITIONAL FIRST AID INFORMATION
Additional first aid information:
Immediate Medical Attention Required:
After first aid, get appropriate in-plant paramedic or community medical support
if serious sign and symptoms persist.
N/A
4.2 SYMPTOMS AND EFFECTS
Acute Symptoms from Exposure:
N/A
Delayed Symptoms from Exposure:
N/A
4.3 IMMEDIATE SPECIAL TREATMENT OR EQUIPMENT REQUIRED
Note to Physicians: N/A
Product: N/A
Revision date: 05/19/2015
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SAFETY DATA SHEET
5. FIRE-FIGHTING MEASURES
5.1 EXTINGUISHING MEDIA
Recommended Extinguishing Media:
Water spray, dry chemical, foam, carbon dioxide, or halon type extinguishers. Do not
release runoff from fire control methods to sewers or waterways.
N/A
Extinguishing Media Not to be Used:
5.2 SPECIAL HAZARD
Unusual Fire/Explosion Hazards:
May form flammable dust-air mixture. Hazardous combustion products: Carbon
monoxide, carbon dioxide, nitrogen oxide and smoke. Under certain conditions some
aliphatic aldehydes and carboxylic acids may form.
N/A
Extinguishing Media Not to be Used:
5.3 ADVICE FOR FIRE FIGHTERS
Avoid inhalation of smoke. Wear protective cloting an wear self-contained breathing apparatus
6. ACCIDENTAL RELEASE MEASURES
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
6.1.1
PRECAUTIONS FOR NON-EMERGENCY PERSONNEL
N/A
6.1.2
ADDITIONAL FIRST AID INFORMATION
N/A
6.1.3
PERSONAL PROTECTION
Wear personal protective equipment as described in Section 8.
6.2 ENVIRONMENTAL PRECAUTIONS
Regulatory Information:
Keep product out of sewers and watercourses.
6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANUP
Spill or Leak Cleanup Procedures:
Product: N/A
Small Spills: Scoop into a container for disposal, suction up remaining material with high
efficiency vacuum cleaner. Large Spills: Scoop into a container for disposal, suction up
remaining material with high efficiency vacuum cleaner. Containment: For large spills, avoid
suspending particles, collect for later disposal. Do not release into sewers or waterways.
Cleanup: No special requirements. Regulatory Requirement: N/A
Revision date: 05/19/2015
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SAFETY DATA SHEET
7. HANDLING AND STORAGE
7.1 PRECAUTIONS FOR SAFE HANDLING
Recommendations for Handling:
Advice on General Hygiene:
No special precautions when used as intended. Keep containers closed, avoid creating dust.
Keep away from ignition sources.
Never eat, drink or smoke in work areas. Practice good personal hygiene after using this
material, especially before eating, drinking, smoking, using the restroom, or applying
cosmetics.
7.2 CONDITIONS FOR SAFE STORAGE
Avoid high temperatures, >100°F/32°C
7.3 SPECIFIC END USES
Printing devices
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 CONTROL PARAMETERS
The best protection is to enclose operations and/or provide local exhaust ventilation at the site of chemical release in order to
maintain airborne concentrations of the product below OSHA PELs (See Section 2).
Local exhaust ventilation is preferred because it prevents contaminant dispersion into the work area by controlling it at its
source.
8.2 EXPOSURE CONTROLS
Respiratory protection:
IMPROPER USE OF RESPIRATORS IS DANGEROUS. Seek professional advice prior to respirator selection and use. Follow OSHA
respirator regulations (29 CFR 1910.134 and 1910.137) and, if necessary, wear a NIOSH approved respirator. Select respirator
based on its suitability to provide adequate worker protection for given work conditions, levels of airborne contamination, and
sufficient levels of oxygen.
Eye/Face Protection:
Contact lenses are not eye protective devices. Appropriate eye protection must be worn instead of, or in conjunction with contact
lenses.
Hand/Skin Protection:
For emergency or non-routine operations (cleaning spills, reactor vessels, or storage tanks), wear an SCBA. WARNING! Air
purifying respirators do not protect worker in oxygen deficient atmospheres.
Additional Protection:
N/A
Protective Clothing and Equipment:
Wear chemically protective gloves, boots, aprons, and gauntlets to prevent prolonged or repeated skin contact. Wear splashproof chemical goggles and face shield when working with liquid, unless full face piece respiratory protection is worn.
Safety Stations:
Make emergency eyewash stations, safety/quick-drench showers, and washing facilities available in work area.
Contaminated Equipment:
Separate contaminated work clothes from street clothes. Launder before reuse. Remove material from your shoes and clean
personal protective equipment. Never take home contaminated clothing.
Comments:
Never eat, drink or smoke in work areas. Practice good personal hygiene after using this material, especially before eating,
drinking, smoking, using the restroom, or applying cosmetics.
Product: N/A
Revision date: 05/19/2015
Page: 4/9
SAFETY DATA SHEET
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 DETAIL INFORMATION
Physical state:
APPEARANCE: Black, free flowing powder
Color:
N/A
Odor:
Odorless.
Odor threshold:
N/A
Boiling point:
N/A
Melting point:
N/A
Flash point:
N/A
Explosion limits:
N/A
Relative density:
N/A
Auto-ignition temperature:
Not Determined.
9.2 OTHER INFORMATION
VAPOR DENSITY (Air=1): Heavier than air. SPECIFIC GRAVITY: (H2O=1, at 4oC): 1.8. WATER SOLUBILITY: Negligible.
10. CHEMICAL STABILITY AND REACTIVITY
10.1 Reactivity:
Reactivity Hazards:
None
Data on Mixture Substances:
None
10.2 Chemical Stability:
The product is stable. Under normal conditions of storage and use, hazardous
polymerisation will not occur.
10.3 Hazardous Polymerization:
Stable under conditions of normal use.
10.4 Conditions to Avoid:
Keep away from heat, flame, sparks and other ignition sources.
10.5 Incompatible Materials:
Strong oxidising materials
10.6 Hazardous Decomposition:
Will not occur.
Product: N/A
Revision date: 05/19/2015
Page: 5/9
SAFETY DATA SHEET
11. INFORMATION ON TOXICOLOGICAL EFFECT
Mixtures:
Acute Toxicity:
Skin Corrosion/Irritation:
Serious Eye Damage:
Inhalation:
Sensitization:
Mutagenicity:
Carcinogenicity:
Reproductive Toxicity:
STOT - Single Exposure:
STOT - Multiple Exposure:
Ingestion:
Hazard Class Information:
Mixture on Market Data:
Symptoms:
Delayed/Immediate Effects:
Test Data on Mixture:
Not Meeting Classification:
Routes of Exposure:
Interactive Effects:
Absence of Specific Data:
Mixture vs Substance Data:
N/A
N/A
N/A
N/A
N/A
N/A
Ames Test Negative (Estimated from the results of testing the constituent components).
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
See NIOSH,RTECS for additional toxicity data.
N/A
N/A
N/A
N/A
N/A
12. ECOLOGICAL INFORMATION
12.1 Eco toxicity:
N/A
12.2 Degradability:
N/A
12.3 Bioaccumulation Potential:
N/A
12.4 Mobility in Soil:
N/A
12.5 PBT & vPvB Assessment:
N/A
12.6 Other Adverse Effects:
N/A
13. DISPOSAL CONSIDERATIONS
Disposal Information:
Dispose as a solid waste in accordance with local authority regulations.
Empty container retains product residue.
Physical/Chemical Properties that affect Treatment:
Symbol: This product is not classified as dangerous
Risk Phrases: This product is not classified according to the federal, state and local environmental regulations.
Waste Treatment Information:
Do not shred toner cartridge, unless dust-explosion prevention measures are taken. Finely dispersed particles may form explosive
mixtures in air. Dispose of in compliance with federal, state, and local regulations.
Personal Protection Required:
N/A
Product: N/A
Revision date: 05/19/2015
Page: 6/9
SAFETY DATA SHEET
14. TRANSPORT INFORMATION
14.1 ID Number:
DOT Transportation Data (49 CFR 172.101): Not specifically listed.
14.2 Shipping Name:
N/A
14.3 Hazard Class:
HMIS Rating: Health = 1 Fire = 1 Reactivity = 0
14.4 Packing Group:
N/A
14.5 Environmental Hazards:
N/A
14.6 User Precautions:
N/A
14.7 Bulk Transport:
N/A
15. REGULATORY INFORMATION
15.1 Regulatory Information:
N/A
EPA Regulatory Information: RCRA Hazardous Waste Number: Not listed (40 CFR 261.33). RCRA Hazardous Waste
Classification: (40 CFR 261): Not classified.
CERCLA Reportable Quantity: CERCLA Hazardous Substance (40 CFR 302.4) listed/unlisted specific per RCRA, sec. 3001;
CWA sec.311 (b)(4); CWA, Sec. 307(a),CAA,Sec.112. CERCLA Reportable Quantity(RQ), Not
listed.
15.2 Superfund Information:
Hazard Categories:
Immediate: N/A
Delayed: N/A
Fire: Flammability Classification: 1 Slight (HMIS, NFPA
)
Pressure: N/A
Reactivity: N/A
Section 302 - Extremely Hazardous: N/A
Section 311 - Hazardous: N/A
15.3 State Regulations:
Check your states regulations that may specifically list copy machine toner.
15.4 Other Regulatory Information:
SARA Toxic Chemical (40 CFR 372.65): Not listed. SARA EHS (Extremely Hazardous
Substance) (40 CFR 355): Not listed, Threshold Planning Quantity (TPQ). OSHA
Regulations, Air Contaminant (29 CFR 1910.1000< Table Z-1-A): Particulates not
otherwise regulated.
Product: N/A
Revision date: 05/19/2015
Page: 7/9
SAFETY DATA SHEET
16. OTHER INFORMATION
General Comments:
This information is based on our current knowledge. It should not therefore be construed as
guaranteeing specific properties of the products as described or their suitability for a particular
application
Creation Date of this SDS:
05/27/2015
Product: N/A
Revision date: 05/19/2015
Page: 8/9
SAFETY DATA SHEET
Key to Abbreviations and Acronyms used in this sheet:
ACGIH = American Conference of Governmental Industrial
NIOSH = National Institute for Occupational Safety and Health
Hygienists
CERCLA = Comprehensive Environmental Response Compensation OSHA = Occupational Health and Safety Administration
and Liability Act
CLP = Classification, Labeling, and Packaging
PEL = Permissible Exposure Limit
DSD = Dangerous Substances Directive
SCBA = Self Contained Breathing Apparatus
EPA = Environmental Protection Agency
STOT = Specific Target Organ Toxicity
GHS = Globally Harmonized System
TLV = Threshold Limit Value
N/A = Not Applicable
UK = United Kingdom
NFPA = National Fire Protection Association
UN = United Nations
Ref:
DISCLAIMER
All trademarks and models referenced are property of their respective holders and are used for identification purposes only.
These products are not sponsored by, affiliated with, manufactured by or distributed by the named manufacturers.
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or
in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no
warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the
suitability of such information for his own particular use.
Product: N/A
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