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MATERIAL SAFETY DATA SHEET 3M™ Lightweight Body Filler - PN 05800, 05801, 05803, 05804, 05805, 35801 10/02/12
Material Safety Data Sheet
Copyright, 2012, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
PRODUCT NAME: 3M™ Lightweight Body Filler - PN 05800, 05801, 05803, 05804, 05805, 35801
MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center, St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 10/02/12
Supercedes Date: 05/11/09
Document Group: 18-1856-6
ID Number(s):
LB-K100-0692-2, 41-0003-6599-3, 41-0003-6644-7, 41-0003-6664-5, 41-0003-6730-4, 41-0003-6769-2, 604550-6996-7, 60-9801-0558-3, 60-9801-0559-1, 60-9801-0561-7, 60-9801-0579-9
This product is a kit or a multipart product which consists of multiple, independently packaged components. An MSDS for
each of these components is included. Please do not separate the component MSDSs from this cover page. The document
numbers of the MSDSs for components of this product are:
24-7586-1, 29-5993-0
Revision Changes:
Kit: Component document group number(s) was modified.
Page Heading: Product name was modified.
Kit: Product name was modified.
Kit: ID Number(s) was modified.
Section 1: Manufacturer name was added.
Section 16: Disclaimer (first paragraph) was added.
Section 16: Disclaimer (second paragraph) was added.
Section 16: Web address was added.
Section 1: Address was added.
Copyright was added.
_________________________________________________________________________________________________________
Page 1 of 2
MATERIAL SAFETY DATA SHEET 3M™ Lightweight Body Filler - PN 05800, 05801, 05803, 05804, 05805, 35801 10/02/12
Company logo was added.
Telephone header was added.
Company Telephone was added.
Section 1: Emergency phone information was added.
Company Logo was deleted.
Copyright was deleted.
Kit: Manufacturer's name was deleted.
Kit: Emergency phone information was deleted.
Kit: Disclaimer (first paragraph) was deleted.
Kit: Disclaimer (second paragraph) was deleted.
Kit: Address line 1 was deleted.
Kit: Address line 2 was deleted.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M
3M USA MSDSs are available at www.3M.com
_________________________________________________________________________________________________________
Page 2 of 2
MATERIAL SAFETY DATA SHEET 3M™ 3M Lightweight Body Filler 5800, 5801, 5804, 5805 03/22/12
Material Safety Data Sheet
Copyright, 2012, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M™ 3M Lightweight Body Filler 5800, 5801, 5804, 5805
MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center, St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 03/22/12
Supercedes Date: 06/21/10
Document Group: 24-7586-1
Product Use:
Intended Use:
Automotive
SECTION 2: INGREDIENTS
Ingredient
C.A.S. No.
% by Wt
1,3-ISOBENZOFURANDIONE, POLYMER WITH 2,5-FURANDIONE AND
2,2'-OXYBIS(ETHANOL)
LIMESTONE
TALC
STYRENE MONOMER
MAGNESIUM CARBONATE
OXIDE GLASS CHEMICALS
SYNTHETIC CRYSTALLINE-FREE SILICA GEL
CHLORITE (MINERAL)
TITANIUM DIOXIDE
QUARTZ SILICA
26123-45-5
15 - 40
1317-65-3
14807-96-6
100-42-5
546-93-0
65997-17-3
112926-00-8
1318-59-8
13463-67-7
14808-60-7
10 - 30
10 - 30
10 - 30
5 - 10
3- 7
1- 5
0.5 - 1.5
< 0.5
< 0.5
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Paste
Odor, Color, Grade: Pungent Styrene odor Gray Paste
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Page 1 of 10
MATERIAL SAFETY DATA SHEET 3M™ 3M Lightweight Body Filler 5800, 5801, 5804, 5805 03/22/12
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: Flammable liquid and vapor. Closed containers exposed to heat from
fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back.
Contains a chemical or chemicals which can cause cancer. May cause target organ effects.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:
Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Inhalation:
Intentional concentration and inhalation may be harmful or fatal.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Prolonged or repeated exposure may cause:
Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes
in lung function tests.
May be absorbed following inhalation and cause target organ effects.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice.
Prolonged or repeated exposure may cause:
Immunological Effects: Signs/symptoms may include alterations in the number of circulating immune cells, allergic skin and /or
respiratory reaction, and changes in immune function.
Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of
the extremities, weakness, tremors, and/or changes in blood pressure and heart rate.
Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision.
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
Ingredient
QUARTZ SILICA
C.A.S. No.
14808-60-7
SILICA, CRYSTALLINE (AIRBORNE
PARTICLES OF RESPIRABLE SIZE)
SILICA, CRYSTALLINE (AIRBORNE
SEQ677
SEQ677
Class Description
Grp. 1: Carcinogenic to
humans
Grp. 1: Carcinogenic to
humans
Known human carcinogen
Regulation
International Agency for Research on Cancer
International Agency for Research on Cancer
National Toxicology Program Carcinogens
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MATERIAL SAFETY DATA SHEET 3M™ 3M Lightweight Body Filler 5800, 5801, 5804, 5805 03/22/12
PARTICLES OF RESPIRABLE SIZE)
STYRENE MONOMER
STYRENE MONOMER
TITANIUM DIOXIDE
100-42-5
100-42-5
13463-67-7
Grp. 2B: Possible human carc.
Anticipated human carcinogen
Grp. 2B: Possible human carc.
International Agency for Research on Cancer
National Toxicology Program Carcinogens
International Agency for Research on Cancer
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed:
Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature
Flash Point
Flammable Limits(LEL)
Flammable Limits(UEL)
OSHA Flammability Classification:
No Data Available
88 ºF [Test Method: Closed Cup]
0.9 % [Details: based on styrene]
6.8 % [Details: based on styrene]
Class IC Flammable Liquid
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed
containers and surfaces cool and prevent explosive rupture. Water may be used to blanket the fire. Wear full protective equipment
(Bunker Gear) and a self-contained breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Flammable liquid and vapor. Closed containers exposed to heat from fire may build
pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all
ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with
fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with
good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill
area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard.
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Page 3 of 10
MATERIAL SAFETY DATA SHEET 3M™ 3M Lightweight Body Filler 5800, 5801, 5804, 5805 03/22/12
6.2. Environmental precautions
Collect the resulting residue containing solution. Place in a metal container approved for transportation by appropriate authorities.
Dispose of collected material as soon as possible.
Clean-up methods
Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill.
Contain spill. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that can
dissolve in water. An AR - AFFF type foam is recommended. Working from around the edges of the spill inward, cover with
bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry.
Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by
a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and
MSDS. Seal the container.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat,
sparks, open flame, pilot lights and other sources of ignition. Ground containers securely when transferring contents. Wear low static
or properly grounded shoes. Avoid breathing of vapors, mists or spray. Avoid skin contact. Do not ingest. Avoid static discharge.
Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Keep container closed when not in use. Avoid
breathing of dust created by cutting, sanding, grinding or machining. Avoid contact with oxidizing agents. Use general dilution
ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not
adequate, use respiratory protection equipment.
7.2 STORAGE
Store in a cool place. Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated
area. Keep container tightly closed. Do not store containers on their sides. Store away from areas where product may come into
contact with food or pharmaceuticals. Store away from oxidizing agents.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use in an enclosed process area is recommended. Provide appropriate local exhaust for cutting, grinding, sanding or machining. Use
in a well-ventilated area. Do not use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or
local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If
ventilation is not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray. To minimize the risk of injury to face and eyes, always wear eye and face protection
when working at sanding or grinding operations or when near such operations.
The following eye protection(s) are recommended: Full Face Shield
Indirect Vented Goggles
.
8.2.2 Skin Protection
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MATERIAL SAFETY DATA SHEET 3M™ 3M Lightweight Body Filler 5800, 5801, 5804, 5805 03/22/12
Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure
assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Nitrile Rubber
Polyvinyl Alcohol (PVA)
.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges and P95 particulate prefilters
. Select and use respiratory protection to prevent an inhalation exposure based on the results of an exposure assessment. Consult with
your respirator manufacturer for selection of appropriate types of respirators.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Do not ingest.
8.3 EXPOSURE GUIDELINES
Ingredient
Authority
LIMESTONE
OSHA
LIMESTONE
MAGNESIUM CARBONATE
OSHA
OSHA
MAGNESIUM CARBONATE
OXIDE GLASS CHEMICALS
QUARTZ SILICA
OSHA
Manufacturer
determined
ACGIH
QUARTZ SILICA
OSHA
QUARTZ SILICA
OSHA
SILICA, AMORPHOUS
SILICA, AMORPHOUS
OSHA
OSHA
STYRENE MONOMER
STYRENE MONOMER
STYRENE MONOMER
STYRENE MONOMER
TALC
ACGIH
ACGIH
OSHA
OSHA
ACGIH
TALC
CMRG
TALC
OSHA
TALC
OSHA
TALC
OSHA
TITANIUM DIOXIDE
TITANIUM DIOXIDE
ACGIH
CMRG
TITANIUM DIOXIDE
OSHA
Type
Limit
TWA, respirable
fraction
TWA, as total dust
TWA, respirable
fraction
TWA, as total dust
TWA, as dust
5 mg/m3
TWA, respirable
fraction
TWA concentration,
respirable
TWA concentration,
as total dust
TWA concentration
TWA
0.025 mg/m3
TWA
STEL
TWA
CEIL
TWA, respirable
fraction
TWA, as respirable
dust
TWA concentration,
respirable
TWA concentration,
as total dust
TWA
TWA
TWA, as respirable
dust
TWA, as total dust
Additional Information
15 mg/m3
5 mg/m3
15 mg/m3
10 mg/m3
0.1 mg/m3
0.3 mg/m3
0.8 mg/m3
20 millions of
particles/cu. ft.
20 ppm
40 ppm
100 ppm
200 ppm
2 mg/m3
0.5 mg/m3
0.1 mg/m3
0.3 mg/m3
20 millions of
particles/cu. ft.
10 mg/m3
5 mg/m3
15 mg/m3
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MATERIAL SAFETY DATA SHEET 3M™ 3M Lightweight Body Filler 5800, 5801, 5804, 5805 03/22/12
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Specific Physical Form:
Odor, Color, Grade:
General Physical Form:
Autoignition temperature
Flash Point
Flammable Limits(LEL)
Flammable Limits(UEL)
Boiling Point
Density
Vapor Density
Paste
Pungent Styrene odor Gray Paste
Liquid
No Data Available
88 ºF [Test Method: Closed Cup]
0.9 % [Details: based on styrene]
6.8 % [Details: based on styrene]
293 ºF
1.134 g/ml
3.6
Vapor Pressure
No Data Available
Specific Gravity
pH
Melting point
1.134 [Ref Std: WATER=1]
No Data Available
No Data Available
Solubility in Water
Evaporation rate
Hazardous Air Pollutants
Volatile Organic Compounds
Volatile Organic Compounds
Kow - Oct/Water partition coef
Percent volatile
VOC Less H2O & Exempt Solvents
Viscosity
Negligible
No Data Available
15.9 % weight [Test Method: Calculated]
16.5 % weight [Test Method: calculated SCAQMD rule 443.1]
187 g/l [Test Method: calculated per CARB title 2]
No Data Available
17.0 %
188 g/l [Test Method: calculated SCAQMD rule 443.1]
192000 - 208000 centipoise
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid:
10.1 Conditions to avoid
Sparks and/or flames
Heat
10.2 Materials to avoid
Strong acids
Strong oxidizing agents
Alkali and alkaline earth metals
Strong bases
Additional Information: Storage at elevated temperatures will shorten shelf-life.
Hazardous Polymerization: Hazardous polymerization will not occur.
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Page 6 of 10
MATERIAL SAFETY DATA SHEET 3M™ 3M Lightweight Body Filler 5800, 5801, 5804, 5805 03/22/12
Hazardous Decomposition or By-Products
Substance
Condition
Hydrocarbons
Carbon monoxide
Carbon dioxide
Not Specified
Not Specified
Not Specified
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in
a permitted hazardous waste facility.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
LB-K100-0519-5, LB-K100-0519-6, LB-K100-0519-7, LB-K100-0519-8, LB-K100-0585-9, 41-0003-6596-9, 41-0003-6780-9
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - No
Reactivity Hazard - No
Immediate Hazard - Yes
Delayed Hazard - Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
_________________________________________________________________________________________________
Page 7 of 10
MATERIAL SAFETY DATA SHEET 3M™ 3M Lightweight Body Filler 5800, 5801, 5804, 5805 03/22/12
Ingredient
C.A.S. No
STYRENE MONOMER
100-42-5
% by Wt
10 - 30
STATE REGULATIONS
Contact 3M for more information.
CALIFORNIA PROPOSITION 65
Ingredient
C.A.S. No.
Classification
SILICA, CRYSTALLINE (AIRBORNE
PARTICLES OF RESPIRABLE SIZE)
SEQ677
**Carcinogen
** WARNING: contains a chemical which can cause cancer.
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2
Flammability: 3
Reactivity: 1
Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
Revision Changes:
Section 1: Product use information was modified.
Section 16: NFPA hazard classification for health was modified.
Section 16: NFPA hazard classification for reactivity was modified.
Section 16: Disclaimer (second paragraph) was modified.
Section 5: Fire fighting procedures information was modified.
Section 7: Handling information was modified.
Section 7: Storage information was modified.
Section 8: Engineering controls information was modified.
Section 8: Eye/face protection phrase was modified.
Section 8: Skin protection phrase was modified.
Section 10: Hazardous decomposition or by-products table was modified.
Section 8: Eye/face protection information was modified.
Section 8: Skin protection - recommended gloves information was modified.
Section 8: Respiratory protection - recommended respirators information was modified.
Section 3: Immediate other hazard(s) was modified.
Section 14: Transportation legal text was modified.
_________________________________________________________________________________________________
Page 8 of 10
MATERIAL SAFETY DATA SHEET 3M™ 3M Lightweight Body Filler 5800, 5801, 5804, 5805 03/22/12
Section 3: Other health effects information was modified.
Section 15: Inventories information was modified.
Section 9: Density information was modified.
Section 9: Vapor density value was modified.
Section 9: Vapor pressure value was modified.
Section 9: Boiling point information was modified.
Section 5: Flammable limits (UE) information was modified.
Section 5: Flammable limits (LEL) information was modified.
Section 5: Autoignition temperature information was modified.
Section 5: Flash point information was modified.
Sections 3 and 9: Odor, color, grade information was modified.
Section 9: Property description for optional properties was modified.
Section 9: Specific gravity information was modified.
Section 9: pH information was modified.
Section 9: Melting point information was modified.
Section 9: Solubility in water text was modified.
Section 8: Respiratory protection - recommended respirators guide was modified.
Section 9: Flash point information was modified.
Section 9: Flammable limits (LEL) information was modified.
Section 9: Flammable limits (UEL) information was modified.
Section 9: Autoignition temperature information was modified.
Section 14: ID Number(s) Template 1 was modified.
Section 2: Ingredient table was modified.
Section 15: EPCRA 313 information was modified.
Section 8: Exposure guidelines ingredient information was modified.
Section 3: Carcinogenicity table was modified.
Section 15: California proposition 65 ingredient information was modified.
Section 6: 6.2. Environmental precautions heading was modified.
Section 6: 6.1. Personal precautions, protective equipment and emergency procedures heading was modified.
Section 6: Personal precautions information was modified.
Section 6: Environmental procedures information was modified.
Section 6: Methods for cleaning up information was modified.
Section 10: Materials to avoid physical property was modified.
Section 10: Materials and conditions to avoid comment was added.
Section 10: Materials and conditions to avoid comment heading was added.
Sections 3 and 9: Specific physical form information was added.
Sections 3 and 9: Specific physical form heading was added.
Section 14: ID Number Heading Template 1 was added.
Section 16: Web address was added.
Section 8: Hand protection information was added.
Section 1: Address was added.
Copyright was added.
Company logo was added.
Telephone header was added.
Company Telephone was added.
Section 1: Emergency phone information was added.
Section 1: Emergency phone information was deleted.
Company Logo was deleted.
Copyright was deleted.
Section 16: Web address heading was deleted.
Section 9: Vapor density text was deleted.
Section 9: Vapor pressure text was deleted.
Section 9: Property description for required properties was deleted.
Section 9: Solubility in water value was deleted.
Section 1: Address line 1 was deleted.
Section 1: Address line 2 was deleted.
_________________________________________________________________________________________________
Page 9 of 10
MATERIAL SAFETY DATA SHEET 3M™ 3M Lightweight Body Filler 5800, 5801, 5804, 5805 03/22/12
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M
3M USA MSDSs are available at www.3M.com
_________________________________________________________________________________________________
Page 10 of 10
MATERIAL SAFETY DATA SHEET Cream Hardener (Red, White & Blue)
10/02/12
Material Safety Data Sheet
Copyright, 2012, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Cream Hardener (Red, White & Blue)
MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center, St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 10/02/12
Supercedes Date: 10/01/12
Document Group: 29-5993-0
Product Use:
Intended Use:
Automotive
SECTION 2: INGREDIENTS
Ingredient
C.A.S. No.
BENZOYL PEROXIDE
WATER
BENZOIC ACID, C9-11-BRANCHED ALKYL ESTERS
ZINC STEARATE
OXIRANE, POLYMER WITH METHYLOXIRANE, MONOBUTYL ETHER
CALCIUM SULFATE
IRON OXIDE (FE2O3)
FERRIC FERROCYANIDE
FERRIC AMMONIUM FERROCYANIDE
94-36-0
7732-18-5
131298-44-7
557-05-1
9038-95-3
7778-18-9
1309-37-1
14038-43-8
25869-00-5
% by Wt
30 - 60
10 - 30
10 - 30
3- 7
1- 5
1- 5
1- 5
0- 1
0- 1
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Viscous
Odor, Color, Grade: Red paste with slight ester odor
General Physical Form: Solid
Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and
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MATERIAL SAFETY DATA SHEET Cream Hardener (Red, White & Blue)
10/02/12
explode. Dust clouds of this material in combination with an ignition source may be explosive.
May cause allergic skin reaction.
May cause severe eye irritation.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and
impaired vision.
Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Prolonged or repeated exposure may cause:
Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes
in lung function tests.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:
Prolonged or repeated exposure may cause:
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice.
Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased protein
in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed:
Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature
Flash Point
No Data Available
111 ºC [Test Method: Estimated]
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MATERIAL SAFETY DATA SHEET Cream Hardener (Red, White & Blue)
10/02/12
Not Applicable
Not Applicable
Flammable Limits(LEL)
Flammable Limits(UEL)
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures:
(SCBA).
Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Dust clouds
of this material in combination with an ignition source may be explosive.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the
area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in
accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or
vapors in the spill area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or
flammability hazard.
6.2. Environmental precautions
For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Place in a metal container
approved for use in transportation by appropriate authorities. The container must be lined with polyethylene plastic or contain a
plastic drum liner made of polyethylene. Dispose of collected material as soon as possible.
Clean-up methods
Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Contain spill. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam
(AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as
possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person.
Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Seal the container.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat,
sparks, open flame, pilot lights and other sources of ignition. Avoid static discharge. Avoid eye contact with vapors, mists, or spray.
Keep out of the reach of children. Avoid breathing of dust created by cutting, sanding, grinding or machining. Avoid eye contact
with dust or airborne particles.
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MATERIAL SAFETY DATA SHEET Cream Hardener (Red, White & Blue)
10/02/12
7.2 STORAGE
Store away from heat. Store out of direct sunlight. Keep container tightly closed. Do not heat under confinement to avoid risk of
explosion
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Provide appropriate local exhaust for cutting, grinding, sanding or machining. Do not use in a confined area or areas with little or no
air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational
Exposure Limits and/or control dust, fume, or airborne particles. If ventilation is not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Safety Glasses with side shields
Indirect Vented Goggles
.
8.2.2 Skin Protection
Avoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Polymer laminate
.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining.
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full
respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce
inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient
Authority
BENZOYL PEROXIDE
BENZOYL PEROXIDE
CALCIUM SULFATE
ACGIH
OSHA
ACGIH
CALCIUM SULFATE
OSHA
CALCIUM SULFATE
CYANIDES
IRON OXIDE (FE2O3)
OSHA
OSHA
ACGIH
IRON OXIDE (FE2O3)
ZINC STEARATE
OSHA
OSHA
Type
TWA
TWA
TWA, inhalable
fraction
TWA, respirable
fraction
TWA, as total dust
TWA, as CN
TWA, respirable
fraction
TWA, as fume
TWA, respirable
fraction
Limit
Additional Information
5 mg/m3
5 mg/m3
10 mg/m3
5 mg/m3
15 mg/m3
5 mg/m3
5 mg/m3
Skin Notation*
10 mg/m3
5 mg/m3
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MATERIAL SAFETY DATA SHEET Cream Hardener (Red, White & Blue)
ZINC STEARATE
OSHA
10/02/12
TWA, as total dust
15 mg/m3
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Specific Physical Form:
Odor, Color, Grade:
General Physical Form:
Autoignition temperature
Flash Point
Flammable Limits(LEL)
Flammable Limits(UEL)
Boiling Point
Density
Vapor Density
Viscous
Red paste with slight ester odor
Solid
No Data Available
111 ºC [Test Method: Estimated]
Not Applicable
Not Applicable
No Data Available
1.2 g/cm3
Not Applicable
Vapor Pressure
Not Applicable
Specific Gravity
pH
Melting point
1.2 [@ 25 ºC] [Ref Std: WATER=1]
No Data Available
No Data Available
Solubility in Water
Evaporation rate
Hazardous Air Pollutants
Volatile Organic Compounds
Volatile Organic Compounds
Volatile Organic Compounds
Kow - Oct/Water partition coef
Percent volatile
VOC Less H2O & Exempt Solvents
Viscosity
Negligible
No Data Available
0 % weight [Test Method: Calculated]
0 lb/gal [Test Method: calculated SCAQMD rule 443.1]
0 g/l [Test Method: calculated SCAQMD rule 443.1]
0 % weight [Test Method: calculated per CARB title 2]
No Data Available
20 % [Details: Water is the volatile component]
0 g/l [Test Method: calculated SCAQMD rule 443.1]
No Data Available
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable. Stable unless exposed to heat, flames and drying conditions.
Materials and Conditions to Avoid:
10.1 Conditions to avoid
Heat
10.2 Materials to avoid
Accelerators
Hazardous Polymerization: Hazardous polymerization will not occur.
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MATERIAL SAFETY DATA SHEET Cream Hardener (Red, White & Blue)
10/02/12
Hazardous Decomposition or By-Products
Substance
Condition
Carbon monoxide
Carbon dioxide
Toxic Vapor, Gas, Particulate
Not Specified
Not Specified
Not Specified
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in
a permitted hazardous waste facility.
This product has been classified on the basis that it is stable as sold. Material may become unstable if allowed to dry out. Classify
appropriately before disposal.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
LB-K100-0965-7, LB-K100-0965-8, LB-K100-0965-9, LB-K100-0966-0, LB-K100-0966-1, LB-K100-0966-2, LB-K100-0966-3,
LB-K100-1035-6, LB-K100-1045-4, LB-K100-1286-7, 41-0003-7987-9, 60-4550-6614-6, 60-4550-6617-9, 60-4550-6830-8, 604550-6981-9, 60-4550-6982-7
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No
Reactivity Hazard - Yes
Immediate Hazard - Yes
Delayed Hazard - Yes
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MATERIAL SAFETY DATA SHEET Cream Hardener (Red, White & Blue)
10/02/12
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient
C.A.S. No
% by Wt
ZINC STEARATE (ZINC COMPOUNDS)
BENZOYL PEROXIDE
FERRIC FERROCYANIDE (CYANIDES)
557-05-1
94-36-0
14038-43-8
3- 7
30 - 60
0- 1
STATE REGULATIONS
Contact 3M for more information.
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
WHMIS: Hazardous
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2
Flammability: 1
Reactivity: 1
Special Hazards: Oxidizer
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
HMIS Hazard Classification
Health: 2
Flammability: 1
Reactivity: 1
Protection: X - See PPE section.
Hazardous Material Identification System (HMIS®) hazard ratings are designed to inform employees of chemical hazards in the workplace. These
ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency
situations. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint and Coatings
Association (NPCA).
Revision Changes:
Section 14: ID Number(s) Template 1 was modified.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
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MATERIAL SAFETY DATA SHEET Cream Hardener (Red, White & Blue)
10/02/12
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M
3M USA MSDSs are available at www.3M.com
_________________________________________________________________________________________________
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