of 12 Material Safety Data Sheet (Resin C) RubberLoc Corporation

of 12 Material Safety Data Sheet (Resin C) RubberLoc Corporation
Page 1 of 12
Material Safety Data Sheet (Resin C)
RubberLoc Corporation
1128 S. West St
Indianapolis , IN 46225
Chemtrec emergency phone 1-800-424-9300
Date:10/15
Product Identification
Chemical family: Polyurethane
Product name: Rubber-Loc 100 Resin (C)
Formula: The specific chemical formula for this material is a trade secret of RubberLoc
Chemical name: Reaction product of a Polyether with toluene diisocyanate (TDI).
Composition Information / Ingredients
Ingredient Name / CAS Number
Synthetic Polyurethane Prepolymer
CAS # 59675-67-1
TDI
CAS number 584-84-9
Exposure Limits
TWA Not determined
STEL not determined
.005 ppm, TWA 0.02 ppm, STEL
(OSHA, ACGIH)
Concentration
99%
Less than
1%
Hazard assessment based on available data.
Transportation: n/a
OSHA (1910.1200 – irritant, sensitizer, Carcinogen (NTP, IARC, 2b
EEC* - irritant, sensitizer, irreversible effects
Physical data
Appearance and odor: viscous transparent liquid; slight aromatic odor
Solubility: reacts slowly in water, soluble in THF, DMF, or methylene chloride
Melting point: not determined
Boiling point: Greater than 350 F
Specific gravity (H2O=1): 1.1095
Vapor Pressure @ 20 C: not determined
Vapor density (air=1): not determined
Volatility @ 70 F: nil
Fire and explosion hazard data
Flash point: >400 F (204 C) CC
Extinguishing media: water spray, dry chemical
Autoignition temperature: not determined
Flammable limits: not determined
Special fire fighting procedures: protect against inhalation of cyanate vapors and other decomposition/combustion products.
Unusual hazards: none identified.
Reactivity data
Stability: stable at ambient temperatures and pressures.
Incompatibility: avoid contamination with water, solvents and any foreign matter.
Decomposition products: high temperatures will release cyanates and hydrocarbons. Oxides of carbon, nitrogen and small amount of HCN under burning conditions.
Special protection information
Engineering controls: None required
Personal protection equipment: chemical resistant gloves and goggles should be worn.
Storage, spills and disposal information
Storage: store away from sources of direct heat and moisture. Seal containers with a dry nitrogen blanket and keep closed when not in use. Moisture contamination will evolve CO2 and
create pressure in closed systems.
Spills: absorb on inert carrier. Transfer to open containers outside or in well-ventilated area. Soak with dilute ammonia hydroxide of water alcohol mixture. Allow time for reaction to be
complete before disposal.
Reportable quantity: 100 lbs. (TDI pure)
Disposal: in accordance with any applicable local, state or federal regulation regarding polymeric waste.
Environmental information: environmental effects have not been determined.
Health related data
Specific hazard(s): contact with eyes and skin may cause irritation. Repeated, minimal contact with skin may cause sensitization. At room temperatures inhalation is not normally consider
a hazard unless the product is heated about 300 F in liquid form
Primary route(s) of entry: skin absorption
First aid procedures:
Eye contact: flush with water for 15 minutes. Get medical attention.
Skin contact: wipe excess. Wash with rubbing alcohol, if available, followed by soap and water. Discard shoes if contaminated.
Toxicology information: there are no acute toxicology data on this material; however, residual TDI (0.02 – 4.0%) does possess irritancy and sensitization potential.
RubberLoc Resin (C)
Page 2 of 12
Chronic: oral gavage administration of TDI in corn oil to rats and mice for 2 years resulted in an increased incidence of tumors. Six hour daily inhalation exposures to rats and mice of 0.05
and 0.15 ppm TDI for 2 years did not produce tumors. Since inhalation is the usual route of human exposure, the carcinogenic potential of TDI to humans has not been established.
Carcinogenic per
Toxic Chemical
SARA Title III (40CFR 372) – Section 313 Toxic Chemicals Notification
CAS Number
2,4-toluene diisocyanate
2,6-toluene diisocyanate
584-84-9
91-08-7
NTP__X__
IARC__2b__
OSHA______
None______
% (by weight)
0.75
0.25
(TDI)
RubberLoc Catalyst (C)
Page 3 of 12
Material Safety Data Sheet (RubberLoc Catalyst C)
RubberLoc Corporation
1128 S. West St
Indianapolis , IN 46225
Chemtrec emergency phone 1-800-424-9300
Date:10/15
Product Identification
Chemical family: Hydroxy Terminated Poly (Oxyalkylene) Polyol mixture.
Product name: Rubber-Loc Catalyst C.
Formula: The specific chemical formula for this material is a trade secret of Rubber-Loc
Chemical name: Blend of amine & polyols.
Synonyms: Polyether Triol.
C.A.S. number: 9082-00-2.
Composition Information / Ingredients
Ingredient Name / CAS Number
Exposure Limits
Concentration
Polyol
CAS number 9082-00-2
OSHA: not established
ACGIH: not established
80-90%
Aromatic Diamine
OSHA: not established
ACGIH: not established
5-10%
Hazardous Material Identification
Warning! Do not take internally
Routes of absorption: Skin
Inhalation: At room temperatures inhalation is not normally consider a hazard unless the product is heated about 300 F in liquid form
Odor threshold: there is no data for odor threshold.
Irritation threshold: there is no data for irritation threshold.
Immediate danger to life or health: the IDLH concentration has not been established for this product.
Medical conditions aggravated by exposure: there are no medical conditions known to be aggravated by exposure.
Interactions with other chemicals, which enhance toxicity: there is no chemical known to enhance the toxicity of the product.
Emergency and first aid procedure
Inhalation: Not a route of entry at room temperature unless the product is heated above 300 F in liquid form
Skin: May be a slight a skin irritant with repeated exposure. Washing any substance off the skin with water is a good safety practice.
Eyes: Slight eye irritant , flush with water.
Ingestion: immediately drink water to dilute. Seek medical attention if symptoms develop.
Fire and explosion hazard data
Flammable: no.
Combustible: no.
Pyrophoric: no.
Flash point: 300-500 F (150-260 C) test method: Cleveland Open Cup.
Auto ignition temperature: no data.
Flammable limits at normal atmospheric temperature and pressure (percent volume in air) LEL: no data, UEL: no data.
Extinguishing media: carbon dioxide, dry chemical and water spray.
Fire fighting procedures: use water to cool containers exposed to fire, use normal fire fighting equipment. Additional respiratory protection is necessary when a spill or fire involving this
product occurs. You are recommended to use a cartridge type NIOSH/OSHA approved respirator with dust/mist cartridges. Additional protective clothing must be worn to prevent
personal contact with this material. Those items include but are not limited to boots, impervious gloves, hardhat, splash-proof goggles, impervious clothing (chemically impermeable suit).
Accidental release measures
For all transportation accidents, call Chemtrec.1-800-424-9300
Reportable quantity: N/A (per 40 CFR 300.4).
Spill mitigation procedures: stop source of spill as soon as possible and notify appropriate personnel.
Air release: N/A.
Water release: this material is slightly soluble in water and may be subject to emulsification. Divert flow of water and contain that which is contaminated. Remove as a liquid utilizing a
vacuum or pumping system as possible.
Land spill: dike spill area and begin to remove as a liquid. If unable to do so, then absorb in clay, sand or a commercial absorbent and containerize for disposal. Compatible absorbents
sand, clay soil.
Spill residues: (see Disposal considerations)
Special precautions and storage data
Do not take internally: avoid contact with skin, eyes and clothing. Upon contact with skin or eyes, wash off with water.
Storage conditions: do not store at temperatures above 100 F .
Other: product is hygroscopic; protect with padding of dry nitrogen.
Shelf life: 12 months (closed container).
Incompatible materials for packaging: use glass or vinyl lined containers. Recommend lined steel (Amercoat number 23 vinyl coating 5-coat system); 304SS.
Incompatible materials for storage or transport: strong oxidizers.
RubberLoc Catalyst (C)
Page 4 of 12
Personal protection
Eye protection: safety glasses with side shields.
Skin protection: Latex gloves
Ventilation: no special ventilation is required unless the product is heated above 300 f in Liquid form
Respirator: not required at room temperatures.
Physical properties
Appearance: Thin black liquid
Freezing point: no data.
Boiling point: no data.
Decomposition temperature: no data.
Specific gravity: 0.99.
Bulk density: N/A.
pH @ 25 C: neutral 10/6 isopropanol/water.
Vapor pressure @ 25 C: 0.01-3.5 mm Hg.
Solubility in water: soluble to slightly soluble.
Volatiles, percent by volume: 0.
Evaporation rate: N/A.
Vapor density: no data.
Molecular weight: N/A – mixture.
Odor: slightly musty to odorless.
Coefficient of oil/water distribution: no data.
Stability and reactivity
Conditions under which this product may be unstable:
Temperatures above: no data.
Mechanical shock or impact: no.
Electrical (static) discharge: no.
Other: no.
Hazardous polymerization: will not occur.
Incompatible materials: strong oxidizers.
Hazardous decomposition products: carbon monoxide, carbon dioxide and other fragments, which have not been identified.
Summary of reactivity:
Oxidizer: no.
Pyrophoric: no.
Organic peroxide: no.
Water reactive: no.
Toxicological information
Acute toxicity:
Inhalation LC50: greater than a nominal concentration of 200 mg/1 for 1-hour (rat).
Dermal LD50: >g/kg (rabbit).
Oral LD50: > 5g/kg (rat).
Irritation: not a skin and eye irritant.
Chronic target organ toxicity: there are no known or reported effects from repeated exposure.
Reproductive and developmental toxicity: there are no known or reported effects on reproductive function pre-fetal development.
Carcinogenicity: this product is not known or reported to be carcinogenic by any reference source including LARC, OSHA, NTP, or EPA.
Mutagenicity: this product is not known or reported to be mutagenic.
Ecological information
Aquatic toxicity: none known or reported.
Disposal considerations
Waste disposal method: waste must be disposed of in accordance with local, state and federal environmental control regulations. Incineration is the preferred method.
If this product becomes a waste, it does not meet the criteria of a hazardous waste as defined under 40 CFR 261, in that it does not exhibit the characteristics of hazardous waste of
Subpart C, nor is it listed as a hazardous waste under Subpart D.
Care must be taken to prevent environmental contamination from the use of this material. The user of this material has the responsibility to dispose of unused material, residues and
containers in compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and disposal for hazardous and non-hazardous wastes.
Shipping information
This material is not regulated as a DOT hazardous material.
Technical shipping name: Propylene Glycol – DOT (domestic surface).
Proper shipping name: Liquid Resin (non-regulated).
DOT hazard classification: none.
UN/NA number: none.
Packaging group: none.
DOT labels required: none.
DOT placards required: none.
Freight class: 55.
RubberLoc Catalyst (C)
Page 5 of 12
Regulatory information
Toxic substances control act: this substance is listed on the Toxic Substance Control Act inventory.
Superfund Amendments and Reauthorization Act Title III:
Hazard categories: per 40 CFR 370.2: health – none physical – none.
Emergency planning and community right to know, per 40 CFR App. A:
Extremely hazardous substance – threshold-planning quantity: none established.
Supplier notification requirements per 40 CFR 372.45: none established.
California Proposition 65:
Component B for this product does not contain any chemicals that are listed under California Proposition 65.
Other information
NFPA ratings: not established.
HMIS ratings:
Health
1
Flammability
1
Reactivity
0
This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Rubber-Loc Inc. The data on this sheet relates only to the specific
material designated herein.Rubber-Loc, Inc. assumes no legal responsibility for use or reliance upon this data.
Prepared by :
Approval date: 10/15
Supersedes none
RubberLoc Primer (B)
Page 6 of 12
Material Safety Data Sheet (RubberLoc Primer)
RubberLoc Corporation
1128 S. West St
Indianapolis,IN 46225
Chemtrec emergency phone 1-800-424-9300
Product Identification
Chemical family: resin solvent mixture
Product name: RubberLoc Primer B
Composition Information / Ingredients
Ingredient Name / CAS Number
Hydrocarbon Resin
Ethyl Acetate
CAS number 141-78-6
Exposure Limits
ACGIH TLV Not Established
OSHA PEL not Established
NIOSH PEL/TWA Not Established
NIOSH PEL Not established
OSHA-Final PEL’s 400 p.p.m TWA ; 1400 mg/m3 TWA
NIOSH 400 ppm TWA;1400 mg/m3 TWA 2000 p.p.m IDLH
ACGIH 400 p.p.m – TWA
Concentration
10%-20%
80%-90%
Hazardous Material Identification
Primary route(s) of exposure: skin, inhalation and ingestion.
Eyes: eye irritant, effects are reversible
Skin: skin irritant. Direct skin contact is not a likely route or entry into the body. .
Inhalation: at room inhalation of vapors is not normally a problem with brush or dip applications however if the material is sprayed or heated ,mist may cause irritation of act (dry throat,
cough, shortness of breath or chest tightness). In addition, sinusitis, bronchitis or respiratory sensitization (asthma-like symptoms) may occur.
Emergency and first aid procedure
Eyes: flush with large amounts of water for at least 15 minutes. Seek medical attention immediately.
Skin: wash exposed area thoroughly with soap and water. Be sure to wash contaminated clothing before reusing. Seek medical attention.
Inhalation: move person into fresh air. Oxygen may be administered if available and needed. Seek medical attention immediately.
Ingestion: do not induce vomiting. Give glass of water or milk to drink. Do not give anything by mouth to unconscious person. Seek medical attention immediately.
Fire and explosion hazard data
Flash point: 40 F .
Flammable limits (% by volume in air): upper – 6.88 Vol %, lower – 1.26 Vol %
Extinguishing media: water spray (fog), foam, dry chemical or carbon dioxide.
Full protective equipment with self-contained breathing apparatus should be worn.
Material contains flammable solvent. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Closed containers may explode when exposed to
extreme heat. Water spray may be used to cool closed containers and prevent pressure build-up. Empty containers may contain liquid or vapor, which is flammable or explosive. Do not
weld, burn or cut empty containers.
Accidental release measures
Shut off and eliminate all ignition sources. Ventilate confined spaces. Workers should avoid direct skin or eye contact, or inhalation of vapors. Absorb on dry inert material. Package for
disposal.
Special precautions and storage data
Storage temperature: 100 F (38 C) maximum
Shelf life: minimum 1 year at 75 F (23 C)
Keep containers closed when not in use. Keep away from heat, sparks and open flame. Store in tightly sealed containers and away from moisture and direct sunlight. Wear personal
protective equipment when working on equipment that may be contaminated with material.
RubberLoc Primer (B)
Page 7 of 12
Personal protection
Respiratory protection: not normally a problem with good ventilation however if working in conditions where TLV is exceeded, use a chemical cartridge mask or air supply hood as required
and/or approved by ANSI and OSHA.
Eye protection: splash goggles or face shield required.
Skin protection: chemical resistant gloves are recommended.
Ventilation requirements: use with adequate forced air mechanical ventilation in accordance with OSHA regulations. Ventilation must be sufficient to prevent vapors from exceeding
exposure limit(s) or build-up of explosive concentrations of vapor in air.
Physical properties
Appearance: Thin liquid
Odor: Camphor-like odor
Color: clear
Boiling point: 209 F
Specific gravity: 0.862
Percent volatile by volume: 80-90
Evaporation rate (ether = 1): slower
Vapor density (air = 1): greater
Solubility in water (%): negligible/reacts slowly with water
Stability and reactivity
Stability: stable under normal conditions.
Hazardous decomposition products: by high heat and fire, carbon monoxide, carbon dioxide, oxides of nitrogen, traces of HEN, isocyanate and solvent vapors.
Hazardous polymerization will not occur under normal conditions.
Toxicological information
LC50(vapor) rat
4211 ppm 6 hours
oral
4500 MG/KG BWT
skin rabbit > 2000 MG/KG BWT
Acute Toxicity rat 3046 MG/KG BTW
Rabbit > 2000 MG/KG BTW
Ecological information
LC50/96 hours 240 mg/l acute toxicity to fish is low
48 hours Daphnia magna 350 mg/l Low acute toxicity to aquatic invertebrates
EC3 / 72 hours Puseudomonas puticda 78 mg/l low toxicity to bacteria
Disposal considerations
Dispose of in accordance with local, state and federal regulations.
Shipping information
DOT shipping name: Paint Related Material
DOT hazard classification: 3
UN/NA number: UN1263
Packaging group: II
DOT labels required: red label, Flammable Liquid
DOT placards required: Flammable Liquid
Freight class: 55
Packaging, airfreight:
Passenger aircraft only: Packaging Inst. (see IATA): Y305
Passenger/Cargo aircraft only:
Packaging Inst. (see IATA): 305
Cargo aircraft only:
Packaging Inst. (see IATA): 307
Volatile organic content
VOC / liter
755 grams VOC
0 grams Non Exempt VOC/liter
Limited Qty: 1 liter
Limited Qty: 5 liters
Limited Qty: 60 liters
RubberLoc Primer (B)
Page 8 of 12
Regulatory information
California Proposition 65:
Component A for this product contains the following chemicals that are known to cause reproductive toxicity, and are listed under California Proposition 65.
Concentration
Ingredient / CAS Number
None
0%
Hazard Ratings
H.M.I.S
Health
2
Flammability
3
Reactivity/Physical hazards
0
P.P.E.
(Personal Protection Equipment)
Splash aprons, neoprene gloves, Cartridge Respirators (when spray applying)
1
Prepared by:
Approval date: 10/15
Supersedes none
RubberLoc Cleaner (A)
Page 9 of 12
RubberLoc Cleaner (A) Methyl Ethyl Ketone (M.E.K.)
CAS # 78-93-3
MSDS
10/15
**************************MATERIAL SAFETY DATA SHEET*************************
Manufacturer’s Name: RubberLoc.
Street Address: 1128 South West Street
City, State, Zip: Indianapolis, Indiana 46225
Phone: (317)631-9109 Fax (317)631-9101
Emergency Response Phone: 1-800-424-9300
7
*********************SECTION I – PRODUCT IDENTIFICATION*********************
GENERAL OR GENERIC ID: Ketone
DOT HAZARD CLASSIFICATION: 3 (Flammable Liquid)
**************************SECTION II – COMPONENTS*******************************
If present IARC, OSHA carcinogens and chemicals subject to the reporting requirements of SATA Title III
Section 313 are identified in this section. See definition page for clarification.
INGREDIENT
PERCENT
Methyl Ethyl Ketone
CAS # 78-93-3
100
PEL
200 PPM
TLV
200 PPM SKIN
NOTE
(1)
NOTES:
(1) OSHA/ACGIH Short Term Exposure Limit (STEL) for Methyl Ethyl Ketone is 300 PPM. NIOSH
recommends a limit of 200 PPM, 8-hour TWA. This chemical is subject to the reporting requirements of
Section 313 of SATA Title III.
**************************SECTION III – PHYSICAL DATA****************************
BOILING POINT: 175.00 F (79.44 C) @ 760.00 mm Hg
VAPOR PRESSURE: 70.00 mm Hg @ 68.00 F (20.00 C)
SPECIFIC VAPOR DENSITY (air = 1): 2.50
SPECIFIC GRAVITY: .805-.807 @ 68.00 F (20.00 C)
PERCENT VOLATILES: 100%
EVAPORATION RATE (N – Butyl Acetate = 1): 5.70
APPEARANCE: Clear, Apha color 10 max
STATE: Liquid
FORM: Neat
RubberLoc Cleaner(A)
Page 10 of 12
***************SECTION IV – FIRE AND EXPLOSION INFORMATION*************
FLASH POINT (TCC): 23.0 F (-5.0 C)
EXPLOSIVE LIMIT: Lower 2.0% Upper 11.5%
EXTINGUISHING MEDIA: Regular foam or carbon dioxide or dry chemical
HAZARDOUS DECOMPOSITION PRODUCTS: May foam, carbon dioxide and carbon monoxide, etc.
FIREFIGHTING PROCEDURES: Wear a self-contained breathing apparatus with a full-face piece operated
in the positive pressure demand mode with appropriate turn-out gear and chemical resistant personal
protective equipment. Refer to the personal protective equipment section of this MSDS.
SPECIAL FIRE & EXPLOSION HAZARDS: Never use welding or cutting torch on or near drum (even empty)
because product (even just residue) can ignite explosively. All five-gallon pails and larger metal
containers including tank cars and tank trucks should be grounded and/or bonded when material is
transferred. Vapors are heavier than air and may travel along the ground or may be moved by ventilation
and ignited by pilot lights, other flames, sparks, heaters, smoking, electric motors, static discharge, or other
ignition sources at locations distant from material handling point.
INFA CODES: Health – 1
Flammability – 3
Reactivity – 0
**********************SECTION V – HEALTH HAZARD DATA***********************
PERMISSIBLE EXPOSURE LEVEL: 200 PPM
THRESHOLD LIMIT VALUE: 200 PPM (see Section II)
EFFECTS OF ACUTE OVEREXPOSURE:
EYES: Exposure may cause mild eye irritation. Symptoms may include stinging, tearing and redness.
SKIN: Exposure causes skin irritation. Prolonged or repeated exposure may dry the skin. Symptoms
may include redness, burning, drying and cracking, skin burns and skin damage. Pre-existing skin
disorders may be aggravated by exposure to this material. SKIN ABSORPTION IS POSSIBLE, but
harmful effects are not expected from this route of exposure under normal conditions of handling and use.
BREATHING: Exposure to vapor or mist is possible. SHORT TERM INHALATION TOXICITY IS LOW.
Breathing small amounts during normal handling is not likely to cause harmful effects, breathing large
amounts may be harmful. SYMPTOMS ARE MORE TYPICALLY SEEN AT AIR CONCENTRATIONS
EXCEEDING THE RECOMMENDED EXPOSURE LIMITS. SYMPTOMS OF EXPOSURE MAY
INCLUDE: irritation (nose, throat, respiratory tract), pre-existing lung disorders, e.g., asthma like
conditions, may be aggravated by exposure to this material, central nervous system depression
(dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness).
SWALLOWING: Single oral toxicity is low. Swallowing small amounts during normal handling is not likely
to cause harmful effects, swallowing large amounts may be harmful. SYMPTOMS MAY INCLUDE:
central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, and
unconsciousness). THIS MATERIAL CAN ENTER THE LUNGS DURING SWALLOWING OR
VOMITING AND CAUSE LUNG INFLAMMATION AND/OR DAMAGE.
FIRST AID:
IF ON THE SKIN: Remove contaminated clothing. Flush exposed area with large amounts of water. If
skin is damaged, seek immediate medical attention. If skin is not damaged and symptoms persist, seek
medical attention.
RubberLoc Cleaner(A)
Page 11 of 12
IF IN EYES: If symptoms develop, move individual away from exposure and into fresh air. Flush eyes
gently with water while holding eyelids apart. If symptoms persist or there is any visual difficulty, seek
medical attention.
IF SWALLOWED: DO NOT induce vomiting. This material is an aspiration hazard. If individual is drowsy
or unconscious, place on left side with the head down. Seek medical attention. If possible, do not leave
individual unattended.
IF BREATHED: If symptoms develop move individual away from exposure and into fresh air. If symptoms
persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and
quiet, seek immediate medical attention.
PRIMARY ROUTES OF ENTRY: Inhalation, skin contact, eye contact and skin absorption.
EFFECTS OF CHRONIC OVEREXPOSURE: Based on animal studies, exposure to Methyl Ethyl Ketone
(MEK) increases the onset of peripheral neuropathy caused by exposure to Methyl Butyl Ketone (MBK)
and/or N-Haxine, and/or Ethyl Butyl Ketone. MEK alone has not been shown to cause peripheral
neuropathy. This material (or a component) has been shown to cause harm to the fetus in laboratory
animal studies. The relevance of these findings to humans is uncertain. Based on the available
information, this material cannot be classified with regard to carcinogenicity. This material is not listed as
a carcinogen by IARC, NTP or OSHA. OVEREXPOSURE TO THIS MATERIAL (or its components) has
been suggested as a cause of the following effects in laboratory animals, and may aggravate pre-existing
disorders of these organs in humans: mild reversible liver effects, mild reversible kidney effects.
*************************SECTION VI – REACTIVITY DATA**************************
HAZARDOUS POLYMERIZATION: Cannot occur
STABILITY: Stable
INCOMPATIBILITY: Avoid contact with strong oxidizing agents
******************SECTION VII – SPILL OR LEAK PROCEDURES*****************
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
SMALL SPILL: Absorb liquid on vermiculite, floor absorbent material.
LARGE SPILL: Eliminate all ignition sources (flares, flames, including pilot lights, electrical sparks).
Persons not wearing protective equipment should be excluded from area of spill until clean up has been
completed. Stop spill at source. Prevent from entering drains, sewers, streams or other bodies of
water. Prevent from spreading. If runoff occurs, notify authorities as required. Pump or vacuum
transfer spilled product to clean containers for recovery. Absorb unrecoverable product. Transfer to
contaminated absorbent, soil and other materials to containers for disposal. Prevent run-off to sewers,
streams or other bodies of water. If run-off occurs, notify proper authorities as required that a spill has
occurred.
WASTE DISPOSAL METHOD:
SMALL SPILL: Dispose of in accordance with all local, state and federal regulations.
LARGE SPILL: Dispose of in accordance with all applicable local, state and federal regulations.
************SECTION VIII – PROTECTIVE EQUIPMENT TO BE USED************
RESPIRATORY PROTECTION: If workplace exposure limit(s) of product or any component is exceeded
(see Section II), a NIOSH/MSHA approved air supplied respirator is advised in absence of proper
environmental control. OSHA regulations also permit other NIOSH/MSHA respirators (negative pressure
RubberLoc Cleaner(A)
Page 12 of 12
type) under specified conditions (see your industrial hygienist). Engineering or administrative controls
should be implemented to reduce exposure.
VENTILATION: Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure
below TLV(s).
PROTECTIVE GLOVES: Wear resistant gloves (consult your safety equipment supplier).
EYE PROTECTION: Chemical splash goggles in compliance with OSHA regulations are abused, however,
OSHA regulations also permit other type safety glasses. Consult your safety representative.
OTHER PROTECTIVE EQUIPMENT: To prevent repeated or prolonged skin contact, wear impervious
clothing and boots.
***************************SECTION IX – SHIPPING DATA***************************
DOT SHIPPING NAME: Methyl Ethyl Ketone
TECHNICAL SHIPPING NAME: Methyl Ethyl Ketone
DOT HAZARD CLASSIFICATION: 3
UN/NA: UN-1193
DOT LABELS REQUIRED: Red label, Flammable Liquid
DOT PLACARDS REQUIRED: Flammable Liquid (3)
FREIGHT CLASS: 65
PACKAGING, AIRFREIGHT: 307II
LIMIT, AIRFREIGHT: 60 Liters/Package – Air Cargo Only
5 Liters/Package – Passenger Aircraft/Rail
PACKAGING GROUP: II
*******SECTION X – SPECIAL PRECAUTIONS OR OTHER COMMENTS*******
Containers of this material may be hazardous when emptied containers retain product residues (vapor,
liquid, and/or solid), all hazard precautions given in the data sheet must be observed.
WARNING: Sudden release of hot organic vapors or mists from process equipment operating at elevated
temperature and pressure, or sudden ingress of air into vacuum equipment may result in ignition without
the presence of obvious ignition sources. Published “auto ignition” or “ignition” temperature values cannot
be treated as safe operating temperatures in chemical processes without analysis of the actual process
conditions. Any use of this product in elevated temperature processes should be thoroughly evaluated to
establish and maintain safe operating conditions.
THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT
WARRANTED TO BE WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE
ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE IFORMATION IS CURRENT,
APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. THIS MSDS COMPLIES WITH 29 CPR
1910.1200 (THE HAZARD COMMUNICATION STANDARD).
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