Dy-Mark Rock Coding Ink Std All Colours

Dy-Mark Rock Coding Ink Std All Colours
Dy-Mark Rock Coding Ink Std All Colours
Dy-Mark
Chemwatch Hazard Alert Code: 1
Chemwatch: 4502-48
Version No: 11.1.1.1
Safety Data Sheet according to WHS and ADG requirements
Issue Date: 16/05/2017
Print Date: 17/05/2017
S.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name
Synonyms
Other means of
identification
Dy-Mark Rock Coding Ink Std All Colours
32402001 Black 20Ltr, 32402002 Red, 32402003 Blue, 32402004 Green, 32402005 Yellow, 32402006 Orange, 32402008 Violet, 32402011 White, 32402503 Blue
25 Litre, 32410002 Red, 32410003 Blue, 32410004 Green, 32410005 Yellow, 32410008 Violet, 32410011 White
Not Available
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses
Rock coding ink.
Details of the supplier of the safety data sheet
Registered company name
Address
Telephone
Fax
Website
Email
Dy-Mark
89 Formation Street Wacol QLD 4076 Australia
+61 7 3271 2222
+61 7 3271 2751
https://www.dymark.com.au
[email protected]
Emergency telephone number
Association / Organisation
Emergency telephone
numbers
Other emergency telephone
numbers
Not Available
+61 403 186 708
Not Available
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.
COMBUSTIBLE LIQUID, regulated for storage purposes only
CHEMWATCH HAZARD RATINGS
Min
Flammability
Toxicity
Body Contact
Reactivity
Chronic
Max
1
1
1
0
0
0 = Minimum
1 = Low
2 = Moderate
3 = High
4 = Extreme
Poisons Schedule
Classification [1]
Legend:
Not Applicable
Flammable Liquid Category 4
1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI
Label elements
Hazard pictogram(s)
SIGNAL WORD
Not Applicable
WARNING
Hazard statement(s)
H227
Combustible liquid
Supplementary statement(s)
Continued...
Chemwatch: 4502-48
Page 2 of 8
Version No: 11.1.1.1
Dy-Mark Rock Coding Ink Std All Colours
Issue Date: 16/05/2017
Print Date: 17/05/2017
Not Applicable
Precautionary statement(s) Prevention
P210
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement(s) Response
P370+P378
In case of fire: Use water spray/fog for extinction.
Precautionary statement(s) Storage
P403+P235
Store in a well-ventilated place. Keep cool.
Precautionary statement(s) Disposal
P501
Dispose of contents/container in accordance with local regulations.
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Substances
See section below for composition of Mixtures
Mixtures
CAS No
%[weight]
Name
64-17-5
10-15
ethanol
Not Available
<10
dye
7732-18-5
>80
water
NOTE: Manufacturer has supplied full ingredient information to allow CHEMWATCH assessment.
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
Skin Contact
If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
Inhalation
If fumes or combustion products are inhaled remove from contaminated area.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.
Transport to hospital, or doctor.
Ingestion
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.
Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
For acute or short term repeated exposures to ethanol:
Acute ingestion in non-tolerant patients usually responds to supportive care with special attention to prevention of aspiration, replacement of fluid and correction of nutritional deficiencies
(magnesium, thiamine pyridoxine, Vitamins C and K).
Give 50% dextrose (50-100 ml) IV to obtunded patients following blood draw for glucose determination.
Comatose patients should be treated with initial attention to airway, breathing, circulation and drugs of immediate importance (glucose, thiamine).
Decontamination is probably unnecessary more than 1 hour after a single observed ingestion. Cathartics and charcoal may be given but are probably not effective in single ingestions.
Fructose administration is contra-indicated due to side effects.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing media
The product contains a substantial proportion of water, therefore there are no restrictions on the type of extinguishing media which may be used. Choice of extinguishing media should take into
account surrounding areas.
Though the material is non-combustible, evaporation of water from the mixture, caused by the heat of nearby fire, may produce floating layers of combustible substances.
In such an event consider:
foam.
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Chemwatch: 4502-48
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Version No: 11.1.1.1
Dy-Mark Rock Coding Ink Std All Colours
Issue Date: 16/05/2017
Print Date: 17/05/2017
Special hazards arising from the substrate or mixture
Fire Incompatibility
None known.
Advice for firefighters
Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Prevent, by any means available, spillage from entering drains or water course.
Use water delivered as a fine spray to control fire and cool adjacent area.
Fire Fighting
Combustible.
Slight fire hazard when exposed to heat or flame.
Heating may cause expansion or decomposition leading to violent rupture of containers.
On combustion, may emit toxic fumes of carbon monoxide (CO).
Combustion products include:
carbon dioxide (CO2)
,
other pyrolysis products typical of burning organic material.
May emit poisonous fumes.
May emit corrosive fumes.
Fire/Explosion Hazard
HAZCHEM
Not Applicable
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
See section 8
Environmental precautions
See section 12
Methods and material for containment and cleaning up
Remove all ignition sources.
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Minor Spills
Moderate hazard.
Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves.
Major Spills
Personal Protective Equipment advice is contained in Section 8 of the SDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
DO NOT allow clothing wet with material to stay in contact with skin
Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Prevent concentration in hollows and sumps.
Safe handling
Store in original containers.
Keep containers securely sealed.
No smoking, naked lights or ignition sources.
Store in a cool, dry, well-ventilated area.
Other information
Conditions for safe storage, including any incompatibilities
Metal can or drum
Packaging as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Suitable container
Avoid reaction with oxidising agents
Avoid strong bases.
Storage incompatibility
+
+
X
0
+
+
O
X
+
+
— Must not be stored together
— May be stored together with specific preventions
— May be stored together
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Continued...
Chemwatch: 4502-48
Page 4 of 8
Version No: 11.1.1.1
Issue Date: 16/05/2017
Print Date: 17/05/2017
Dy-Mark Rock Coding Ink Std All Colours
Source
Ingredient
Material name
TWA
STEL
Peak
Notes
Australia Exposure Standards
ethanol
Ethyl alcohol
1880 mg/m3 / 1000 ppm
Not Available
Not Available
Not Available
EMERGENCY LIMITS
Ingredient
Material name
TEEL-1
TEEL-2
TEEL-3
ethanol
Ethyl alcohol; (Ethanol)
Not Available
Not Available
15000 ppm
Ingredient
Original IDLH
Revised IDLH
ethanol
15,000 ppm
3,300 [LEL] ppm
dye
Not Available
Not Available
water
Not Available
Not Available
Exposure controls
Appropriate engineering
controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly
effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and
"removes" air in the work environment.
Personal protection
Eye and face protection
Skin protection
Hands/feet protection
Body protection
Other protection
Thermal hazards
Safety glasses with side shields.
Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of
lenses or restrictions on use, should be created for each workplace or task.
See Hand protection below
Wear chemical protective gloves, e.g. PVC.
Wear safety footwear or safety gumboots, e.g. Rubber
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer. Where
the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior
to the application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be observed when making a final
choice.
Personal hygiene is a key element of effective hand care.
See Other protection below
Overalls.
P.V.C. apron.
Barrier cream.
Not Available
Recommended material(s)
Respiratory protection
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the computergenerated selection:
Dy-Mark Rock Coding Ink Std All Colours
Type A Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88
or national equivalent)
Selection of the Class and Type of respirator will depend upon the level of breathing zone
contaminant and the chemical nature of the contaminant. Protection Factors (defined as the
ratio of contaminant outside and inside the mask) may also be important.
Maximum gas/vapour
concentration present in air
p.p.m. (by volume)
Half-face
Respirator
Full-Face
Respirator
A
Required
minimum
protection factor
NEOPRENE
A
up to 10
1000
-
NATURAL RUBBER
C
A-AUS /
Class1
NATURAL+NEOPRENE
C
up to 50
1000
-
A-AUS /
Class 1
NITRILE
C
up to 50
5000
Airline *
-
NITRILE+PVC
C
up to 100
5000
-
A-2
PE/EVAL/PE
C
up to 100
10000
-
A-3
PVA
C
100+
PVC
C
VITON
C
Material
CPI
BUTYL
* CPI - Chemwatch Performance Index
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the glove, a final
selection must be based on detailed observation. * Where the glove is to be used on a short term, casual or infrequent basis, factors such as
"feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwise
be unsuitable following long-term or frequent use. A qualified practitioner should be consulted.
Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demand
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen
cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G =
Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
Methyl bromide, AX = Low boiling point organic compounds(below 65 degC)
Cartridge respirators should never be used for emergency ingress or in areas of unknown
vapour concentrations or oxygen content. The wearer must be warned to leave the contaminated
area immediately on detecting any odours through the respirator. The odour may indicate that
the mask is not functioning properly, that the vapour concentration is too high, or that the mask
is not properly fitted. Because of these limitations, only restricted use of cartridge respirators is
considered appropriate.
Continued...
Chemwatch: 4502-48
Page 5 of 8
Version No: 11.1.1.1
Issue Date: 16/05/2017
Print Date: 17/05/2017
Dy-Mark Rock Coding Ink Std All Colours
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance
Physical state
Coloured liquid with a sweet, fragrant odour; miscible with water.
Liquid
Relative density (Water = 1)
0.912
Odour
Not Available
Partition coefficient
n-octanol / water
Odour threshold
Not Available
Auto-ignition temperature
(°C)
Not Available
pH (as supplied)
Not Available
Decomposition
temperature
Not Available
Melting point / freezing
point (°C)
Not Available
Viscosity (cSt)
Not Available
Initial boiling point and
boiling range (°C)
78 initial
Flash point (°C)
>60
Molecular weight (g/mol)
Not Available
Not Applicable
Taste
Not Available
Evaporation rate
Not Available
Explosive properties
Not Available
Flammability
Combustible.
Oxidising properties
Not Available
Upper Explosive Limit (%)
Not Available
Surface Tension (dyn/cm or
mN/m)
Not Available
Lower Explosive Limit (%)
Not Available
Volatile Component (%vol)
Not Available
Vapour pressure (kPa)
Not Available
Gas group
Not Available
pH as a solution (1%)
Not Available
VOC g/L
Not Available
Solubility in water (g/L)
Miscible
Vapour density (Air = 1)
>1
SECTION 10 STABILITY AND REACTIVITY
Reactivity
Chemical stability
See section 7
Unstable in the presence of incompatible materials.
Product is considered stable.
Hazardous polymerisation will not occur.
Possibility of hazardous
reactions
See section 7
Conditions to avoid
See section 7
Incompatible materials
See section 7
Hazardous decomposition
products
See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Inhaled
Ingestion
Skin Contact
Eye
Chronic
Dy-Mark Rock Coding Ink
Std All Colours
ethanol
Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by sleepiness, reduced alertness, loss of reflexes, lack of co-ordination,
and vertigo.
Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal handling, may be damaging to the health of the
individual.
There is some evidence to suggest that the material can cause respiratory irritation in some persons. The body's response to such irritation can cause further
lung damage.
Animal testing shows that the most common signs of inhalation overdose is inco-ordination and drowsiness.
Considered an unlikely route of entry in commercial/industrial environments Ingestion may result in nausea, abdominal irritation, pain and vomiting
There is some evidence to suggest that the material may cause moderate inflammation of the skin either following direct contact or after a delay of some time.
Repeated exposure can cause contact dermatitis which is characterised by redness, swelling and blistering.
Open cuts, abraded or irritated skin should not be exposed to this material
There is evidence that material may produce eye irritation in some persons and produce eye damage 24 hours or more after instillation. Severe inflammation
may be expected with pain.
Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure.
Prolonged exposure to ethanol may cause damage to the liver and cause scarring. It may also worsen damage caused by other agents.
TOXICITY
IRRITATION
Not Available
Not Available
TOXICITY
IRRITATION
Dermal (rabbit) LD50: 17100 mg/kg [1]
Eye (rabbit): 500 mg SEVERE
Inhalation (rat) LC50: 64000 ppm/4hr[2]
Eye (rabbit):100mg/24hr-moderate
Oral (rat) LD50: 7060 mg/kge[2]
Skin (rabbit):20 mg/24hr-moderate
Skin (rabbit):400 mg (open)-mild
Continued...
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Version No: 11.1.1.1
Issue Date: 16/05/2017
Print Date: 17/05/2017
Dy-Mark Rock Coding Ink Std All Colours
water
Legend:
ETHANOL
Dy-Mark Rock Coding Ink
Std All Colours & WATER
TOXICITY
IRRITATION
Not Available
Not Available
1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data
extracted from RTECS - Register of Toxic Effect of chemical Substances
The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles,
scaling and thickening of the skin.
No significant acute toxicological data identified in literature search.
Acute Toxicity
Carcinogenicity
Skin Irritation/Corrosion
Reproductivity
Serious Eye
Damage/Irritation
STOT - Single Exposure
Respiratory or Skin
sensitisation
STOT - Repeated Exposure
Mutagenicity
Aspiration Hazard
Legend:
– Data available but does not fill the criteria for classification
– Data available to make classification
– Data Not Available to make classification
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
ENDPOINT
Dy-Mark Rock Coding Ink
Std All Colours
ethanol
water
Legend:
Not
Applicable
TEST DURATION (HR)
Not Applicable
SPECIES
VALUE
SOURCE
Not Applicable
Not
Applicable
Not
Applicable
ENDPOINT
TEST DURATION (HR)
SPECIES
VALUE
SOURCE
LC50
96
Fish
42mg/L
4
EC50
48
Crustacea
2mg/L
4
EC50
96
Algae or other aquatic plants
17.921mg/L
4
NOEC
2016
Fish
0.000375mg/L
4
ENDPOINT
TEST DURATION (HR)
Not
Applicable
Not Applicable
SPECIES
VALUE
SOURCE
Not Applicable
Not
Applicable
Not
Applicable
Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12
(QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE
(Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data
DO NOT discharge into sewer or waterways.
Persistence and degradability
Ingredient
Persistence: Water/Soil
Persistence: Air
ethanol
LOW (Half-life = 2.17 days)
LOW (Half-life = 5.08 days)
water
LOW
LOW
Bioaccumulative potential
Ingredient
Bioaccumulation
ethanol
LOW (LogKOW = -0.31)
water
LOW (LogKOW = -1.38)
Mobility in soil
Ingredient
Mobility
ethanol
HIGH (KOC = 1)
water
LOW (KOC = 14.3)
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packaging
Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in their area. In some
Continued...
Chemwatch: 4502-48
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Version No: 11.1.1.1
Dy-Mark Rock Coding Ink Std All Colours
disposal
Issue Date: 16/05/2017
Print Date: 17/05/2017
areas, certain wastes must be tracked.
A Hierarchy of Controls seems to be common - the user should investigate:
Reduction
Reuse
Recycling
Disposal (if all else fails)
This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use.
DO NOT allow wash water from cleaning or process equipment to enter drains.
It may be necessary to collect all wash water for treatment before disposal.
In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
Where in doubt contact the responsible authority.
Recycle wherever possible or consult manufacturer for recycling options.
Consult State Land Waste Authority for disposal.
Bury or incinerate residue at an approved site.
Recycle containers if possible, or dispose of in an authorised landfill.
SECTION 14 TRANSPORT INFORMATION
Labels Required
COMBUSTIBLE LIQUID, regulated for storage purposes only
Marine Pollutant
HAZCHEM
NO
Not Applicable
Land transport (ADG): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Transport in bulk according to Annex II of MARPOL and the IBC code
Not Applicable
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
ETHANOL(64-17-5) IS FOUND ON THE FOLLOWING REGULATORY LISTS
Australia Exposure Standards
Australia Hazardous Substances Information System - Consolidated Lists
Australia Inventory of Chemical Substances (AICS)
WATER(7732-18-5) IS FOUND ON THE FOLLOWING REGULATORY LISTS
Australia Inventory of Chemical Substances (AICS)
National Inventory
Status
Australia - AICS
Y
Canada - DSL
Y
Canada - NDSL
N (ethanol; water)
China - IECSC
Y
Europe - EINEC / ELINCS /
NLP
Y
Japan - ENCS
N (ethanol; water)
Korea - KECI
Y
New Zealand - NZIoC
Y
Philippines - PICCS
Y
USA - TSCA
Y
Legend:
Y = All ingredients are on the inventory
N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)
SECTION 16 OTHER INFORMATION
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using
available literature references.
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other
settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
Definitions and abbreviations
PC-TWA: Permissible Concentration-Time Weighted Average
PC-STEL: Permissible Concentration-Short Term Exposure Limit
IARC: International Agency for Research on Cancer
ACGIH: American Conference of Governmental Industrial Hygienists
STEL: Short Term Exposure Limit
TEEL: Temporary Emergency Exposure Limit。
Continued...
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Version No: 11.1.1.1
Page 8 of 8
Dy-Mark Rock Coding Ink Std All Colours
Issue Date: 16/05/2017
Print Date: 17/05/2017
IDLH: Immediately Dangerous to Life or Health Concentrations
OSF: Odour Safety Factor
NOAEL :No Observed Adverse Effect Level
LOAEL: Lowest Observed Adverse Effect Level
TLV: Threshold Limit Value
LOD: Limit Of Detection
OTV: Odour Threshold Value
BCF: BioConcentration Factors
BEI: Biological Exposure Index
This document is copyright.
Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written
permission from CHEMWATCH.
TEL (+61 3) 9572 4700.
end of SDS
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