MSDS 2
Material Safety Data Sheet
MSDS Number: TN389
Issue Date:
9/20/2006
Revision: [01]01/12/2007
Product Name: MN.C38K23 Toner
Section 1 - Chemical Product and Company Identification
Product Name: MN.C38K23 Toner
CAS Number: NA (mixture)
Chemical Formula NA
General Use: Toner
Future Graphics LLC Part Numbers: HP3800CHEMK170
Company Name:
Mitsubishi Kagaku Imaging Corporation
Distributor:
Same as Manufacturer
Street Address:
401 Volvo Parkway
Street Address:
Same as Manufacturer
Town:
Chesapeake
Town:
State:
Virginia
Zip Code:
23320
Emergency Contacts:
Chemtrec 1-800-424-9300
Health
1
Same as Manufacturer
Fire
1
State:
Same as Manufacturer
Reactivity
0
Zip Code:
Same as Manufacturer
PPE
(See Sec. 8)
Other Contacts:
757-382-5750
<<<>>> EMERGENCY OVERVIEW <<<>>>
This product may cause irritation of the respiratory system, eyes, and skin. This product
is stable under normal conditions of use.
Section 2 - Composition and Information on Ingredients
Ingredient
TWA
STEL
IDLH
Ingredient
Carbon Black
CAS No. Proprietary
Ingredient
TWA
STEL
IDLH
1-20
OSHA
ACGIH
NIOSH
UNIT OF MEASURE
3.5
3.5
3.5
mg/cu.meter
NE
NE
NE
mg/cu.meter
NA
NA
1750
mg/cu.meter
Silica, amorphous
OSHA
TWA
STEL
IDLH
% in Mixture
CAS No. Proprietary
ACGIH
% in Mixture
UNIT OF MEASURE
80 / % SiO2
10
6
mg/cu.meter
NE
NE
NE
mg/cu.meter
NA
NA
NE
mg/cu.meter
Styrene Acrylate Copolymer
<5
NIOSH
CAS No. Proprietary
% in Mixture
70-95
OSHA
ACGIH
NIOSH
UNIT OF MEASURE
NE
NE
NE
mg/cu.meter
NE
NE
NE
mg/cu.meter
NA
NA
NE
mg/cu.meter
* TOTAL DUST / INHALABLE DUST
** RESPIRABLE DUST
*** Refer to Section 11 - Toxicological Information
OVERALL MIXTURE:
This product is a mixture of dry chemical components. OSHA regulatory limits set for PARTICULATES NOT
MSDS Printed On:
Monday, January 15, 2007
MSDS Number: TN389
Page 1 of 7
OTHERWISE CLASSIFIED are: 15 mg/cu.meter for TOTAL DUST / INHALABLE DUST and 5 mg/cu.meter for
RESPIRABLE DUST.
Section 3 - Hazards Identification
Primary Entry Routes:
Absorption, Ingestion, Inhalation
Target Organs:
NA
Inhalation Effects:
Slight irritation of respiratory tract.
Eye Effects:
Dust may cause irritation by mechanical abrasion.
Skin Effects:
May cause skin irritation.
Ingestion Effects:
NA
Carcinogenicity:
Carbon Black is listed by IARC as a group 2B (possibly carcinogenic to human), but this classification is based on
rat “lung particulate overload” studies. Toner is not listed by IARC, NTP, or OSHA.
Medical Conditions Aggravated by Long-term Exposure:
Accumulation of dust in the respiratory system may cause moderate congestion.
Chronic Effects and/or Recommendations:
If use generates airborne particles, treat as a NUISANCE PARTICULATE (ACGIH TLV = 10 mg/cu. meter).
Section 4 - First Aid Measures
Inhalation:
Protect yourself with appropriate PPE, remove the person to fresh air. Decontaminate and begin rescue breathing
if breathing has stopped and CPR if heart action has stopped. Seek prompt medical attention.
Eye:
DO NOT allow victim to rub or keep eyes tightly shut. Gently lift eyelids and immediately flush eyes with large
amounts of water. Remove any contact lenses. Continue to flush for at least 30 minutes, occasionally lifting the
upper and lower lids. Seek prompt medical attention.
Skin:
Quickly remove contaminated clothing. Immediately wash area with large amounts of water. Seek prompt
medical attention for any reddened skin other than from washing.
Ingestion:
Never give anything by mouth to an unconscious or convulsing person. Contact a Poison Control Center (PCC).
Unless the PCC advises otherwise, have the conscious and alert person drink 1 to 2 glasses of water to dilute.
Induce vomiting only after recent ingestions due to the possibility of seizures. Seek prompt medical attention.
Additional First Aid Information:
NA
Section 5 - Fire Fighting Measures
Flash Point:
Flash Point Method:
NA
NA
Flammability Classification:
1 Slight (HMIS, NFPA)
LEL:
NA
MSDS Printed On:
Auto Ignition Temperature:
ND
Burning Rate:
UEL:
NA
Monday, January 15, 2007
NA
MSDS Number: TN389
Page 2 of 7
Extinguishing Media:
Water spray, dry chemical, foam, carbon dioxide, or halon-type extinguishers.
Unusual Fire / Explosion Hazards:
May form flammable dust-air mixture.
Hazardous Combustion Products:
Carbon monoxide, carbon dioxide, nitrogen oxide, and smoke. Under certain conditions some aliphatic aldehydes
and carboxylic acids may form.
Fire-Fighting Instructions:
Do not release runoff from fire control methods to sewers or waterways.
Fire-Fighting Equipment:
Because fire may produce toxic thermal decomposition products, wear a self-contained breathing apparatus
(SCBA) with a full facepiece operated in pressure-demand or positive-pressure mode.
Section 6 - Accidental Release Measures
Containment Method:
When cleaning up spilled material, keep unnecessary people away, isolate area, and deny entry until the spilled
material has been removed. Scoop up material and place in a chemical waste container. Suction up remaining
material using a high efficiency vacuum cleaner. Avoid suspending particles in the air. Extreme caution should be
used as material presents a slip hazard.
Reporting Requirements:
Follow applicable OSHA regulations (29 CFR 1910.120).
Section 7 - Handling and Storage
Handling Precautions:
Keep containers closed at all times. Avoid creating dust. Keep away from ignition sources.
Storage Requirements:
Product is prone to gradual oxidation which may reduce quality over time.
Regulatory Requirements:
Follow all applicable local, state, and Federal regulations.
Section 8 - Exposure Controls and Personal Protection
Ventilation
The best protection is to enclose operations and/or provide local exhaust ventilation at the site of chemical release
in order to maintain airborne concentrations of the product below OSHA PELs (See Section 2). Local exhaust
ventilation is preferred because it prevents contaminant dispersion into the work area by controlling it at its source.
Respiratory Protection
IMPROPER USE OF RESPIRATORS IS DANGEROUS. Seek professional advice prior to respirator selection
and use. Follow OSHA respirator regulations (29 CFR 1910.134 and 1910.137) and, if necessary, wear a NIOSH
approved respirator. Select respirator based on its suitability to provide adequate worker protection for given work
conditions, level of airborne contamination, and presence of sufficient oxygen. For emergency or non-routine
operations (cleaning spills, reactor vessels, or storage tanks), wear an SCBA. WARNING! Air purifying
respirators do not protect worker in oxygen-deficient atmospheres. If respirators are used, OSHA requires a
written respiratory protection program that includes at least: medical certification, training, fit testing, peroidic
environmental monitoring, maintenance, inspection, cleaning and convenient, sanitary storage areas.
Protective Clothing and Equipment
Wear chemically protective gloves, boots, aprons, and gauntlets to prevent prolonged or repeated skin contact.
Wear splash-proof chemical goggles and face shield when working with liquid, unless full facepiece respiratory
protection is worn. Contact lenses are not eye protective devices. Appropriate eye protection must be worn instead
of, or in conjunction with contact lenses.
Safety Stations
MSDS Printed On:
Monday, January 15, 2007
MSDS Number: TN389
Page 3 of 7
Make emergency eyewash stations, safety/quick-drench showers, and washing facilities avalable in work area.
Contaminated Equipment
Separate contaminated work clothes from street clothes. Launder before reuse. Remove material from your shoes
and clean personal protective equipment. Never take home contaminated clothing.
Comments
Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially
before eating, drinking, smoking, using the restroom, or apply cosmetics.
Additional Information
NA
Section 9 - Physical and Chemical Properties
Freezing or
Melting Point:
Odor
Threshold:
Physical
State:
ND
Solid
Viscosity:
100 - 150 degree
centigrade.
Refractive
Index:
Vapor Density
(Air = 1)
Appearance
and Odor:
NA
NA
Heavier than air.
Black fine powder, faint odor.
% Volatiles:
Surface
Tension:
Vapor
Pressures:
Water
Solubility:
NA
NA
NA
Negligible
Density:
Evaporation
Rate:
Formula
Weight:
Other
Solubilities:
1.0 - 2.0
NA
NA
Partially soluble in toluene and xylene.
pH:
Specifice Gravity where
Water = 1 at 4 deg C
Additional
Comments:
NA
NA
NA
Boiling Point:
NA
Section 10 - Stability and Reactivity
Stability:
Polymerization:
Stable under conditions Hazardous
of normal use.
polymerization cannot
occur.
Hazardous Decomposition Products:
Combustion will produce carbon dioxide and possibly toxic
chemicals such as carbon monoxide.
Chemical Incompatibilities:
NA
Conditions to Avoid:
NA
Other Comments:
NA
Section 11 - Toxicological Information
Checked box indicates that related health effects criteria applies to the overall mixture.
Eye Effects
Acute Oral Effects
Acute Inhalation Effects
Mutagenicity
Skin Effects
Chronic Effects
Carcinogenicity
Teratogenicity
EXPLANATION of HEALTH EFFECTS:
MSDS Printed On:
Monday, January 15, 2007
MSDS Number: TN389
Page 4 of 7
Ames Test Negative. LD50 > 5000 mg/kg.
Chemical Component:
EXPLANATION of TOXICOLOGICAL CRITERIA:
Carbon Black
Carbon Black is listed by IARC as a group 2B (possibly carcinogenic), but IARC monographs vol. 65 and 93 state
that there is inadequate evidence in humans for carcinogenicity of carbon black. Inhalation test of a toner for two
years* showed no significant carcinogenicity.
*"Negative Effect of Long-Term Inhalation of Toner on Formation of 8-Hydroxydeoxyguanosine in DNA in the
Lungs of Rats in Vivo", Yasuo Morimoto, et al, Inhalation Toxicology, vol. 17 (13) 749-753 (2005).
Carbon Black: LD50 4.0 g/kg; add-mus-ihl 6200 ug/m3/16H/12W-I; LD50: oral - rat, > 10 g/kg; LD50:
intravenous - rat, 120 mg/kg; LD50: oral - rat, >15400 mg/kg; LD50: skin - rabbit >3g/kg; TCL0: intermittent
inhalation - rat, 50mg/M3/6 hours
Chemical Component:
Silica, amorphous
SILICON DIOXIDE:
CARCINOGEN STATUS: IARC: Human Inadequate Evidence, Animal Inadequate Evidence, Group 3,
(Amorphous silica)
MEDICAL CONDITIONS AGRRAVATED BY EXPOSURE: respiratory disorders
HEALTH EFFECTS:
INHALATION:
ACUTE EXPOSURE: SILICON DIOXIDE: Dusts may cause irritation of the respiratory tract and coughing.
CHRONIC EXPOSURE: SILICON DIOXIDE: Exposure to dusts of amorphous silica for 6 months to 30 years
may result in silicosis with symptoms of cough, chest pain, dyspnea, tachypnea, marked weakness, and weight
loss. This pulmonary insufficiency may be characterized by diffuse nodular fibrosis, distortion of bronchi, bullous
emphysema. Although pulmonary fibrosis has been reported from the workers exposed to amorphous silica, the
crystalline form is the established cause of fibrotic response in the lung. However, the amorphous form has been
reported as fibrogenic to a lesser extent. As the disease progresses, cor pulmonale, cardiorespiratoy failure, and
death may occur.
SKIN CONTACT:
ACUTE EXPOSURE: SILICON DIOXIDE: Prolonged skin contact with dry particulate may cause drying of the
skin.
CHRONIC EXPOSURE: SILICON DIOXIDE: No data available.
EYE CONTACT:
ACUTE EXPOSURE: SILICON DIOXIDE: Dusts may cause irritation with redness and pain.
CHRONIC EXPOSURE: SILICON DIOXIDE: No data available.
INGESTION:
ACUTE EXPOSURE: SILICON DIOXIDE: The effects of ingestion are purely mechanical as the substance is
inert chemically and biologically.
CHRONIC EXPOSURE: SILICON DIOXIDE: No data available.
Chemical Component:
Styrene Acrylate Copolymer
Data Not Available
Section 12 - Ecological Information
Checked box indicates that information regarding the criteria applies to the overall mixture.
Ecotoxicity
Environmental Fate
Environmental Degradation
Soil Absorption and Mobility
EXPLANATION of APPLICABLE ECOLOGICAL CRITERIA:
NA
Section 13 - Disposal Considerations
MSDS Printed On:
Monday, January 15, 2007
MSDS Number: TN389
Page 5 of 7
Disposal:
Waste material may be disposed of, incinerated, or recycled for its iron oxide under conditions that meet all
Federal, State and Local regulations. Contact your supplier or a licensed contractor for detailed recommendations.
Disposal Regulatory Requirements:
NA
Container Cleaning and Disposal:
NA
Section 14 - Transport Information
DOT Transportation Data (49CFR 172.101)
Shipping Name:
Label:
NA
Passenger Air and Railcar:
NA
Shipping Symbols:
NA
Special Provisions:
NA
Cargo Aircraft:
NA
NA
Hazard Class:
Exceptions:
NA
Oceangoing Vessel Stowage:
NA
ID Number:
NA
Non-bulk Packaging:
NA
Other:
NA
Packing Group:
NA
Bulk Packaging:
NA
NA
EXPLANATION of APPLICATION TRANSPORTATION CRITERIA:
NA
Section 15 - Regulatory Information
Checked box(es) indicate that the chemical is subject to the associated regulatory requirements and/or appears
on the associated chemical inventory list
Chemical Component: Carbon Black
40 CFR 261.33
40 CFR 261 classified
CAS #
CAA 40 CFR 112
TSCA inventory (US)
RCRA Section 3001
SARA 40 CFR 311 and 312
SARA 40 CFR 372.65
CERCLA RQ established
SARA 40 CFR 355
40 CFR 302.4
CWA 40 CFR 311( b)(4)
AICS inventory (Australia)
EINECS inventory (Europe)
DSL inventory (Canada)
ECL inventory (Korea)
OSHA 1910 1000 Z-1 tables
ENCS inventory (Japan)
OSHA 1910 subpart Z
PICCS inventory (Phillipines)
CWA 40 CFR 307(a)
CHINA inventory
Chemical Component: Silica, amorphous
40 CFR 261.33
40 CFR 261 classified
CAS #
CAA 40 CFR 112
SARA 40 CFR 311 and 312
SARA 40 CFR 372.65
CERCLA RQ established
SARA 40 CFR 355
CWA 40 CFR 311( b)(4)
AICS inventory (Australia)
EINECS inventory (Europe)
DSL inventory (Canada)
ECL inventory (Korea)
OSHA 1910 1000 Z-1 tables
ENCS inventory (Japan)
OSHA 1910 subpart Z
PICCS inventory (Phillipines)
CWA 40 CFR 307(a)
MSDS Printed On:
Proprietary
TSCA inventory (US)
RCRA Section 3001
40 CFR 302.4
Proprietary
Monday, January 15, 2007
CHINA inventory
MSDS Number: TN389
Page 6 of 7
Chemical Component: Styrene Acrylate Copolymer
40 CFR 261.33
40 CFR 261 classified
CAA 40 CFR 112
SARA 40 CFR 311 and 312
SARA 40 CFR 372.65
CERCLA RQ established
SARA 40 CFR 355
CWA 40 CFR 311( b)(4)
Proprietary
TSCA inventory (US)
RCRA Section 3001
40 CFR 302.4
CAS #
AICS inventory (Australia)
EINECS inventory (Europe)
DSL inventory (Canada)
ECL inventory (Korea)
OSHA 1910 1000 Z-1 tables
ENCS inventory (Japan)
OSHA 1910 subpart Z
PICCS inventory (Phillipines)
CWA 40 CFR 307(a)
CHINA inventory
Section 16 - Other Information
Abbreviations: ACGIH - American Conference of Governmental Industrial Hygienists
IDLH - Immediatly Dangerous to Life and Health
NA - Not Applicable to the criteria OR Not Available
ND- Not Determined OR Not Known
NE - None established
OSHA - Occupational Safety and Health Administration
PEL - Permissible Exposure Limit
RCRA - Resource Conservation Recovery Act
STEL - Short Term Exposure Limit
TLV - Threshold Limit Value
TSCA - Toxic Substances Control Act
TWA - Time Weighted Average
Disclaimer: The information presented in this Material Safety Data Sheet is based on data believed to be
accurate as of the date this Material Safety Data Sheet was prepared. The information above is
provided on the condition that parties receiving the product make their own determination as to the
suitability of the product for their particular purpose and assume the risk of use of the product. NO
WARRANTY OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, OR
ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE
ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED ABOVE, THE
RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE
PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE.
Mitsubishi has no responsibility or liability for any damage or injury resulting from abnormal use or
from any failure to adhere to recommended procedures. Mitsubishi neither grants, nor shall the
party receiving the product imply any authorization to practice any patented invention without a
license.
Additional Comments: NA
Revision Notes: ACB
<<<<< END OF MSDS>>>>>
MSDS Printed On:
Monday, January 15, 2007
MSDS Number: TN389
Page 7 of 7
Was this manual useful for you? yes no
Thank you for your participation!

* Your assessment is very important for improving the work of artificial intelligence, which forms the content of this project

Download PDF

advertisement