Safety Data Sheets - Dynamic RIC Electric

Safety Data Sheets - Dynamic RIC Electric
Safety Data Sheets
Table of content
1100 Welding Electrode
1530 Big Blast
1718 Zinc Proof
1755 Hi-Speed
2207 Foam It Away
2404 Ram Rod
'44' Rosin Flux Cored Solder
Abrasive Grinding Wheel
Acetone
Acetylene
Acid Flux Cored Solder
Air Tool Lubricant
Battery Acid
Battery Fluid (Alkali)
Battery Terminal Cleaner
Big Brute
C5-A High Temperature
Chain Lube
Contact Cement
Contact Cleaner
Copper Based Welding & Braze Wire & Rod
Copper
Cutting Oil
Dry Chemical (Fire Extinguisher)
Duct Tape
Electrical Insulating Varnish
Epoxy Resin
Filled Vinyl & Acryllic Emulsion
Gasoline
Glass Cleaner
Hydraulic Fluid
Knock-Out Weed Killer
Krylon Engine Paint
Liquid Bleach
LPS 3 Heavy Duty Rust Inhibitor
Medaphene Plus Disinfecting Deoderant
Mineral Spirits
Misty Powder Puff Residual Insecticide
1
Oxygen
PB B'Laster
Pressure Treated Wood
Propane
PVC Plastic Pipe
PVC Solvent
Rapid Wrench
Rough Touch Scrubs-In-A-Bucket
Silicone Sealant
Spitfire RTU
Super Carb & Choke Cleaner
Super Electra-Saf
Tin Alloy Solder
TMS Polymeric
Triple 'D'
Wasp & Hornet Spray
Wheel Bearing Grease
Windshield Washer Fluid
Xylene
Yellow 77
Zep 45
Zep Clean 'Ems
Zep Drill Chill
Zep Gold Touch
Zep Measure Up Degreaser
Zep Powerhouse
ATC-4
Krylon- Seal Coat
Hilti- FS One Fire Sealant
Ideal- AquaGel Wire Lube
Masterflow 928 Grout
Cable Clean
Cold Galvanized Spray
Penetrating Oil
Motor Oil
WD-40
Black Flag Wasp & Hornet Killer
Kopr-Shield
Rigid Dark Cutting Oil
Spectracide Wasp & Hornet Killer
2
1100 Welding Electrode
SAFETY DATA SHEET
This Safety Data Sheet complies with European Commission Directive 91/155/EEC, ISO 11014-1 and ANSI Z400.1
1.
PRODUCT AND COMPANY IDENTIFICATION
Product Name:
Application:
Classification:
Supplier:
Telephone No.:
Emergency No.:
Web site:
2.
DUAL SHIELD MILD STEEL AWS A5.20 T-1, T-2, T-9 & T-12 FLUX CORED WELDING ELECTRODES
Arc Welding
AWS A5.20
THE ESAB GROUP, INC., 801 Wilson Avenue, Hanover, PA 17331
1-717-637-8911, 1-800-933-7070
1-717-637-8911 and 1-800-424-9300 (CHEMTREC)
www.esabna.com
HAZARDS IDENTIFICATION
Emergency Overview: Metal wires in varying colors. These products are normally not considered hazardous as
shipped. Gloves should be worn when handling to prevent cuts and abrasions.
Some of these products contain nickel and cryolite. Nickel is classified as a skin sensitizer and a suspect carcinogen.
Cryolite is classified as toxic and dangerous for the environment. Some of these products contain potassium
fluorosilicate which is classified as toxic by inhalation, skin contact, and ingestion. In the form that these
substances are present in these products, they do not contribute to a hazard classification of the products. These
products contain titanium dioxide which is possibly carcinogenic. These products contain quartz, but normally not
in an inhalable fraction. Quartz can cause silicosis and may cause cancer.
Skin contact is normally no hazard but should be avoided to prevent possible allergic reactions.
Persons with a pacemaker should not go near welding or cutting operations until they have consulted their doctor
and obtained information from the manufacturer of the device.
When these products are used in a welding process, the most important hazards are heat, radiation, electric shock
and welding
Spatter and melting metal can cause burn injuries and start fires. Arc rays can severely damage eyes or skin.
Electric shock can kill.
Overexposure to welding fumes may result in symptoms like metal fume fever, dizziness, nausea, dryness or
irritation of the nose, throat or eyes. Chronic overexposure to welding fumes may affect pulmonary function.
Prolonged inhalation of nickel compounds above safe exposure limits can cause cancer. Overexposure to
manganese and manganese compounds above safe exposure limits can cause irreversible damage to the central
nervous system, including the brain, symptoms of which may include slurred speech, lethargy, tremor, muscular
weakness, psychological disturbances and spastic gait.
fumes.
Heat:
Radiation:
Electricity:
Fumes:
3.
COMPOSITION/INFORMATION ON INGREDIENTS
These products are preparations of flux-cored wire.
3
Ingredients
Aluminum
CAS#
7429-90-5
EINECS#
231-072-3
Aluminum Oxide
Carbon
Cryolite
1344-22-4
7440-44-0
15096-52-3
215-691-6
231-153-3
239-148-8
Iron
Iron Oxide
Lithium Fluoride
Magnesium
Manganese
7439-89-6
1309-37-1
7789-24-2
7439-95-4
7439-96-5
231-096-4
215-168-2
232-152-0
231-104-6
231-105-1
Hazard
(1)
classification
F; R15 R10
stablized
F; R15-17
pyrophoric
No
No
T; R48/23/25
Xn; R20/22
N; R51-53
No
No
No
No
No
(2)
IARC
--
(3) OSHA
(4)
NTP
List
---
----
----
----
------
------
------
Product Identity: DUAL SHIELD MILD STEEL AWS A5.20 T-1, T-2, T-9 & T-12 FLUX CORED WELDING ELECTRODES
Hazard
Ingredients
CAS#
EINECS#
classification
Nickel
7440-02-0
231-111-4
Potassium Fused Flux
Titanium Oxide
Manganous Oxide
Potassium Oxide
Silicon Dioxide (amorphous)
Potassium Silico Fluoride
Silicon
Silicon Dioxide
Sodium Fluoride
13463-67-7
1344-43-0
12136-45-7
60676-86-0
16871-90-2
7440-21-3
14808-60-7
7681-49-4
Sodium Fused Flux
Titanium Oxide
Manganous Oxide
Sodium Oxide
Silicon Dioxide (amorphous)
Titanium Oxide
Zirconium
Zirconium Dioxide
13463-67-7
1344-43-0
12401-86-4
60676-86-0
13463-67-7
7440-67-7
1314-23-4
(1)
(2)
(1)
(3) (4)
IARC
NTP
OSHA List
Carc. Cat. 3;
R40-R43
2B
S
--
236-675-5
215-695-8
235-227-6
262-373-8
240-896-2
231-130-8
238-878-4
231-667-8
No
No
No
No
T; R23/24/25
No
T; R45
T; R25
Xi; R36/38, R32
2B
-----1
--
------K
--
---------
236-675-5
215-695-8
215-208-9
262-373-8
236-675-7
231-176-9
215-227-2
No
No
No
No
No
F; R15-17
No
2B
---##
---
--------
--------
Hazard Classification according to European Council Directive 67/548/EEC, for R-phrases, see Section 16.
(2)
Evaluation according to the International Agency for Research on Cancer. 1 – Human Carcinogen 2B –
Possibly carcinogenic to humans
4
(3)
Classification according to the 11th Report on Carcinogens, published by the US National Toxicology
Program.
K – Known Carcinogen
S – Suspect Carcinogen
(4) Carcinogen listing according to OSHA, Occupational Safety & Health Administration (USA). ## Presently
designated to become 2B with publication of monograph.
APPROXIMATE COMPOSITION (Wt. %)
“All Position” T-1, T-9 & T 12 Electrodes
Dual Shield
Dual Shield
Dual Shield
Dual Shield
Dual Shield
Dual Shield
Dual Shield
7200
<0.5
<0.5
<0.2
<0.5
<0.5
0.2-1
1.5-3.5
-0.1-0.5
<0.5
0.5-1.5
0.5-1.5
<0.5
8-11
<0.5
Bal (>80)
E71T-1C/T-9C
ARC-71
<0.5
<0.5
<0.2
<0.5
<0.5
<0.5
1.5-3.5
0.1-0.5
-<0.5
0.5-1.5
0.5-1.5
<0.5
6-9
<0.5
Bal (>80)
E71T-1C
FC-717
<0.5
<0.5
<0.2
<0.5
<0.5
0.2-1
1.5-3.5
---0.5-1.5
0.5-1.5
<0.5
5.5-8.5
<0.5
Bal (>80)
E71T-1CH8/
T-1MH8/
T-9CH8/T9MH8
Product Trade Name:
Aluminum
Aluminum Oxide
Carbon
Fluoride Compounds
Iron Oxide
Magnesium
Manganese
Manganese Oxide
Nickel
Potassium Oxide
Silicon
Silicon Dioxide
Sodium Oxide
Titanium Oxide
Zirconium Dioxide
Iron
AWS Classification
70 Ultra Plus 7000
7100 LC
7100 Ultra
--<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.2
<0.2
<0.2
<0.2
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
0.2-1
-0.2-1
0.2-1
1.5-3.5
1.5-3.5
1.5-3.5
1.5-3.5
-0.1-0.5
--------<0.5
<0.5
0.5-1.5
0.5-1.5
0.5-1.5
0.5-1.5
0.2-1
0.2-1
0.5-1.5
0.5-1.5
<0.5
<0.5
<0.5
<0.5
8-11
6-9.5
8-11
6-9
<0.5
<0.5
<0.5
<0.5
Bal (>80)
Bal (>80)
Bal (>80)
Bal (>80)
E71T-1M/T-9M E71T-1C/T-1M E71T-1CH8/ E71T-1CH8/
T-1M/T-9CH8/T-1M/T-9CH8/
T-9M
T-9M
Product Identity: DUAL SHIELD MILD STEEL AWS A5.20 T-1, T-2, T-9 & T-12 FLUX CORED WELDING ELECTRODES
APPROXIMATE COMPOSITION (Wt. %)
Dual Shield II
Dual Shield II Dual Shield II Dual Shield II Dual Shield II
Dual Shield II Dual Shield II
70 Ultra
70 HYN
70LC
70LF
70T-12
70T-12H4
71 ULTRA
Aluminum
--
--
<0.5
--
--
--
<0.5
Aluminum Oxide
0.2-1
0.2-1
0.2-1
0.2-1
0.2-1
0.2-1
<0.5
Carbon
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
Fluoride Compounds
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
Iron Oxide
<0.5
<0.5
<0.5
<0.5
<0.5
0.5-2
<0.5
Product Trade Name:
5
Magnesium
0.2-1
0.2-1
0.2-1
0.2-1
0.2-1
0.2-1
0.2-1
Manganese
1.5-3.5
1.5-3.5
1.5-3.5
1.5-3.5
1.5-3.5
1.5-3.5
1.5-3.5
Manganese Oxide
--
--
--
--
--
--
--
Nickel
--
<0.5
--
<0.5
--
--
0.1-0.5
Potassium Oxide
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
<0.3
Silicon
0.5-1.5
0.5-1.5
0.5-1.5
0.5-1.5
0.5-1.5
0.5-1.5
0.5-1.5
Silicon Dioxide
0.5-1.5
0.5-1.5
0.5-1.5
0.5-1.5
0.5-2
0.5-1.5
0.5-1.5
Sodium Oxide
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
Titanium Oxide
6-9
6-9
6-9
6-9
6-9
6-9
6-9
Zirconium Dioxide
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
Iron
Bal (>80)
Bal (>80)
Bal (>80)
Bal (>80)
Bal (>80)
Bal (>80)
AWS Classification
E71T-1M/T12M
E71T-1M/T12M
E71T-1M/TE70T-1C/T-9C 12M
Bal (>80)
E71T1MJH4/T-
E71T-1MJ/T12MJ
E71T-1C/T-12C
12MJH4
Dual Shield
Dual Shield
Dual Shield
Dual Shield II Dual Shield II
Dual Shield II Dual Shield
Aluminum
700X
--
710X
<0.5
710X-M
<0.5
711X
<0.5
712X
--
71 HYD
<0.5
7210
<0.5
Aluminum Oxide
<0.5
<0.5
<0.5
<0.5
0.2-1
<0.5
<0.5
Carbon
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
Fluoride Compounds
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
Iron Oxide
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
Magnesium
--
0.2-1
0.2-1
0.2-1
0.2-1
0.2-1
0.2-1
Manganese
2.5-4
1.5-3.5
1.5-3.5
1.5-3.5
1.5-3.5
1.5-3.5
1.5-3.5
Manganese Oxide
0.2-1.0
--
--
--
--
--
--
Nickel
0.1-0.5
0.1-0.5
--
0.1-0.5
--
0.1-0.5
0.1-0.5
Potassium Oxide
<0.3
<0.5
<0.5
<0.3
<0.3
<0.3
<0.5
Silicon
1-2.5
0.5-1.5
0.5-1.5
0.5-1.5
0.5-1.5
0.5-1.5
0.5-1.5
Silicon Dioxide
0.5-2
0.5-1.5
0.5-1.5
0.5-1.5
0.5-2
0.5-1.5
0.5-1.5
Sodium Oxide
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
Titanium Oxide
4.5-6.5
8-11
8-11
6-9
6-9
6-9
8-11
Zirconium Dioxide
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
Iron
Bal (>80)
Bal (>80)
AWS Classification
E70T-1C
Bal (>80)
E71T-1C/T12C
Bal (>80)
E71T-1MJ/
12MJ
Product Trade Name:
Bal (>80)
E71T-1M/TE71T-1C/T-9C 9M
Bal (>80)
T-E71T-1C/T12C
Bal (>80)
E71T-1C/T-9C
Product Identity: DUAL SHIELD MILD STEEL AWS A5.20 T-1, T-2, T-9 & T-12 FLUX CORED WELDING ELECTRODES
6
APPROXIMATE COMPOSITION (Wt. %)
“Downhand” T-1 & T-9 Electrodes
Product
Name:
Trade
Dual Shield
111-A
Dual Shield
111-AC
Dual Shield
111-HD
Dual Shield
111-RB
Dual Shield
70-GB
Dual Shield
78
Aluminum
Aluminum Oxide
Carbon
Fluoride Compounds
Iron Oxide
Magnesium
Manganese
Manganese Oxide
Nickel
Potassium Oxide
Silicon
Silicon Dioxide
Sodium Oxide
Titanium Oxide
Zirconium
Zirconium Dioxide
Iron
-<0.5
<0.2
<0.5
1.5-3
-3-4.5
--<0.3
1-2.5
0.5-1.5
<0.5
5.5-7.5
-<0.5
Bal (>80)
-<0.5
<0.2
<0.5
0.2-2
-3-4.5
0.2-1.0
-<0.3
1-2.5
0.5-1.5
<0.5
4.5-6.5
-<0.5
Bal (>80)
-<0.5
<0.2
<0.5
1-2
-3-4.5
0.2-1.0
-<0.3
1-2.5
0.5-1.5
<0.5
4.5-6.5
-<0.5
Bal (>80)
0.1-0.5
<0.5
<0.2
<0.5
<0.5
0.1-0.5
1.5-3.0
0.2-1.0
-<0.3
0.5-2.0
0.5-1.5
<0.5
2.5-4.5
0.1-0.5
<0.5
Bal (>80)
-<0.5
<0.2
<0.5
<0.5
0.1-0.5
1.5-3.0
--<0.3
<0.5
0.5-1.5
<0.5
5.5-7.5
-<0.5
Bal (>80)
-<0.5
<0.2
<0.5
<0.5
-3-4.5
0.2-1.0
-<0.3
-1-3
<0.5
4.5-6.5
0.1-0.5
<0.5
Bal (>80)
AWS Classification
E70T-1C
E70T-1C
E70T-1C
E70T-1C
E70T-GM
E70T-1C
Dual Shield
Dual Shield
Dual Shield
Dual Shield
Dual Shield
ARC 70
ARC 87
ARC 90
R-70H
R-70 ULTRA
T-62
-<0.5
<0.2
<0.5
0.5-2
-3-4.5
0.2-1.0
-<0.3
1-2.5
0.5-1.5
-<0.5
<0.2
<0.5
<0.5
-2.5-4
<0.5
-<0.3
1-2.5
0.5-1.5
-<0.5
<0.2
<0.5
<0.5
-2.5-4
0.2-1.0
0.1-0.5
<0.3
1-2.5
0.5-2
-<0.5
<0.2
<0.5
0.5-2
0.1-1
3-4.5
<0.5
0.1-0.5
<0.3
0.5-2.0
0.5-1.5
-<0.5
<0.2
<0.5
0.5-2
-3-4.5
0.2-1.0
0.1-0.5
<0.3
<0.5
0.5-1.5
-<0.5
<0.2
<0.5
0.5-2
-3-4.5
0.2-1.0
-<0.3
-1-3
Dual Shield
Product Trade Name:
Aluminum
Aluminum Oxide
Carbon
Fluoride Compounds
Iron Oxide
Magnesium
Manganese
Manganese Oxide
Nickel
Potassium Oxide
Silicon
Silicon Dioxide
7
Sodium Oxide
Titanium Oxide
Zirconium
Zirconium Dioxide
Iron
AWS Classification
<0.5
5.0-7.0
-<0.5
Bal (>80)
E70T-1C/T-1M/
<0.5
4.5-6.5
-<0.5
Bal (>80)
<0.5
4.5-6.5
-<0.5
Bal (>80)
E70T-1C
E70T-1C
T-9C/T-9M
<0.5
5.0-7.0
-<0.5
Bal (>80)
<0.5
<0.5
5.0-7.0
5.0-7.0
-0.1-0.5
<0.5
<0.5
Bal (>80)
Bal (>80)
E70T-1CH8/
E70T-1C/T-1M/
E70T-1C/T-9C T-1M/T-9CH8/TT-9C/T-9M
9M
Product Identity: DUAL SHIELD MILD STEEL AWS A5.20 T-1, T-2, T-9 & T-12 FLUX CORED WELDING ELECTRODES
APPROXIMATE COMPOSITION (Wt. %)
“Downhand” T-2 Electrodes
Product Trade Name:
Aluminum Oxide
Carbon
Iron Oxide
Manganese
Manganese Oxide
Silicon
Silicon Dioxide
Sodium Oxide
Titanium Oxide
Zirconium Dioxide
Iron
AWS Classification
4.
Dual Shield
Dual Shield
Dual Shield
110
T-63
SP
<0.5
<0.2
<0.5
2.5-4
0.2-1
0.5-3
0.5-1.5
<1
4.5-6.5
<0.5
Bal. (>80)
E70T-2C
<0.5
<0.2
1-3
2.5-5
0.2-1
0.5-3
0.5-1.5
<1
4.5-6.5
<0.5
Bal. (>80)
E70T-2C
<0.5
<0.2
<0.5
2.5-4
0.2-1
0.5-3
2-3
<1
3.5-5.5
<0.5
Bal. (>80)
E70T-2C
FIRST AID MEASURES
Inhalation:
If breathing has stopped, perform artificial respiration and obtain medical assistance
immediately! If breathing is difficult, provide fresh air and call physician.
Eye contact:
For radiation burns due to arc flash, see physician. To remove dusts or fumes flush with water for
at least fifteen minutes. If irritation persists, obtain medical assistance.
Skin contact:
For skin burns from arc radiation, promptly flush with cold water. Get medical attention for burns
or irritations that persist. To remove dust or particles wash with mild soap and water.
Electric shock: Disconnect and turn off the power. Use a nonconductive material to pull victim away from contact
with live parts or wires. If not breathing, begin artificial respiration, preferably mouth-to-mouth. If no detectable
pulse, begin Cardio Pulmonary Resuscitation (CPR). Immediately call a physician.
General: Move to fresh air and call for medical aid.
8
5.
FIRE FIGHTING MEASURES
No specific recommendations for welding consumables. Welding arcs and sparks can ignite combustible and
flammable materials. Use the extinguishing media recommended for the burning materials and fire situation. Wear
self-contained breathing apparatus as fumes or vapors may be harmful.
6.
ACCIDENTAL RELEASE MEASURES
Solid objects may be picked up and placed into a container. Liquids or pastes should be scooped up and placed into
a container. Wear proper protective equipment while handling these materials. Do not discard as refuse.
Personal precautions:
refer to Section 8
Environmental precautions:
7.
refer to Section 13
HANDLING AND STORAGE
Handling:
Handle with care to avoid stings and cuts. Wear gloves when handling welding consumables. Avoid exposure to
dust. Do not ingest. Some individuals can develop an allergic reaction to certain materials. Retain all warning and
identity labels.
Storage:
Keep separate from chemical substances like acids and strong bases, which could cause chemical reactions.
8.
EXPOSURE CONTROL/PERSONAL PROTECTION
Avoid exposure to welding fumes, radiation, spatter, electric shock, heated materials and dust. Engineering
measures:
Ensure sufficient ventilation, local exhaust, or both, to keep welding fumes and gases from breathing zone and
general area. Keep working place and protective clothing clean and dry. Train welders to avoid contact with live
electrical parts and insulate conductive parts. Check condition of protective clothing and equipment on a regular
basis.
Personal protective equipment:
Use respirator or air supplied respirator when welding or brazing in a confined space, or where local exhaust or
ventilation is not sufficient to keep exposure values within safe limits. Use special care when welding painted or
coated steels since hazardous substances from the coating may be emitted. Wear hand, head, eyes, ear and body
protection like welders gloves, helmet or face shield with filter lens, safety boots, apron, arm and shoulder
protection. Keep protective clothing clean and dry.
Use industrial hygiene monitoring equipment to ensure that exposure does not exceed applicable national
exposure limits. The following limits can be used as guidance. For information about welding fume analysis refer to
Section 10
Substance
Aluminum (metal dust)
Aluminum Oxide
Carbon
CAS#
7429-90-5
1344-28-1
7440-44-0
ACGIH TLV
10
10
None
(1)
mg/m
3
OSHA PEL
15*, 5**
15*, 5**
None
(2)
9
mg/m
3
Cryolite
Iron and Iron Oxides
Iron Oxide
Lithium Fluoride (as F)
Manganese &
Manganese Compounds (as Mn)
Nickel (inhalable fraction)
Potassium Fused Flux
Titanium Oxide
Manganous Oxide
Potassium Oxide
Silicon Dioxide (amorphous)
15096-52-3
7439-89-6
1309-37-1
7789-24-2
7439-65-5
2.5
5**
5**
2.5
0.2
2.5
10 (fume)
10 (fume)
2.5
5 Ceiling
7440-02-0
1.5
1
13463-67-7
1344-43-0
12136-45-7
60676-86-0
10
0.2
None
None
Potassium Silico Fluoride (as F)
Silicon (nuisance dust)
Silicon Dioxide (quartz)
16871-90-2
7440-21-3
14808-60-7
2.5
10*, 3***
0.025**
Sodium Fluoride (as F)
Sodium Fused Flux
Titanium Oxide
Manganous Oxide
Sodium Oxide
Silicon Dioxide (amorphous)
7681-49-4
2.5
15*
5 Ceiling
None
3
10 mg/m **
%SiO2+2
2.5
15*, 5**
10 mg/m³**
%SiO2+2
2.5
13463-67-7
1344-43-0
12401-86-4
60676-86-0
10
0.2
None
None
13463-67-7
10
15*
5 Ceiling
None
3
10 mg/m **
%SiO2+2
15*
7440-67-7
1314-23-4
5, 10 (STEL)
5, 10 (STEL)
5
5
Titanium Oxide
Zirconium
&
Compounds
Zirconium Dioxide
(1)
withdrawn
withdrawn
Zirconium
Threshold Limit Values according to American Conference of Governmental Hygienists, 2007
(2)
Permissible Exposure Limits according to the Occupational Safety & Health Administration (USA) Unless
noted, all values are for 8 hour time weighted averages (TWA).
* Total dust, ** Respirable fraction, *** Inhalable fraction.
NOTE: Some of these products may not contain all of the materials listed. For details of composition, refer to the
COMPOSITION TABLE in Section 3.
9.
PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Solid, non-volatile with varying color
Melting point: >1000°C / >1800ºF
10.
STABILITY AND REACTIVITY
General: These products are only intended for normal welding purposes.
Stability: These products are stable under normal conditions.
Reactivity:
Contact with chemical substances like acids or strong bases could cause generation of gas.
10
When these products are used in a welding process, hazardous decomposition products would include those from
the volatilization, reaction or oxidation of the materials listed in Section 3 and those from the base metal and
coating.
The amount of fumes generated from these products varies with welding parameters and dimensions but is
generally no more than 5 to 15 g/kg consumable. Fumes from these products may contain compounds of the
following chemical elements: Fe, O, Mn, Zr, Ni, F, Na, Si, K, Al, Li and Ti. The rest is not analyzed, according to
available standards.
Refer to applicable national exposure limits for fume compounds, including those exposure limits for fume
compounds found in Section 8. Manganese and nickel have low exposure limits, in some countries, that may be
easily exceeded.
Reasonably expected gaseous products would include carbon oxides, nitrogen oxides and ozone. Air contaminants
around the welding area can be affected by the welding process and influence the composition and quantity of
fumes and gases produced.
11.
TOXICOLOGICAL INFORMATION
Inhalation of welding fumes and gases can be dangerous to your health. Classification of welding fumes is difficult
because of varying base materials, coatings, air contamination and processes. The International Agency for
Research on Cancer has classified welding fumes as possibly carcinogenic to humans (Group 2B).
Acute toxicity: Overexposure to welding fumes may result in symptoms like metal fume fever, dizziness, nausea,
dryness or irritation of the nose, throat or eyes.
Chronic toxicity: Overexposure to welding fumes may affect pulmonary function. Prolonged inhalation of nickel
compounds above safe exposure limits can cause cancer. Overexposure to manganese and manganese compounds
above safe exposure limits can cause irreversible damage to the central nervous system, including the brain,
symptoms of which may include slurred speech, lethargy, tremor, muscular weakness, psychological disturbances
and spastic gait. Inhalable quartz is a respiratory carcinogen; however, the process of welding converts crystalline
quartz to the amorphous form which is not considered to be a carcinogen.
12.
ECOLOGICAL INFORMATION
Welding consumables and materials could degrade/weather into components originating from the consumables or
from the materials used in the welding process. Avoid exposure to conditions that could lead to accumulation in
soils or groundwater.
Some of these products contain cryolite, which is classified by European Council Directive 67/548/EEC, as toxic to
aquatic organisms and may cause long-term adverse effects in the aquatic environment.
13.
DISPOSAL CONSIDERATIONS
Discard any product, residue, disposable container or liner in an environmentally acceptable manner, in full
compliance with federal and local regulations. Use recycling procedures if available.
USA RCRA: These products are not considered hazardous waste if discarded.
Residues from welding consumables and processes could degrade and accumulate in soils and groundwater.
Welding slag from these products typically contain mainly the following components originating from the powder
filling of the flux-cored wire: Fe, O, Mn, Zr, Ni, F, Na, Si, K, Al, Li and Ti.
11
14.
TRANSPORT INFORMATION
No international regulations or restrictions are applicable.
15.
REGULATORY INFORMATION
Read and understand the manufacturer's instructions, your employer's safety practices and the health and safety
instructions on the label. Observe any federal and local regulations. Take precautions when welding and protect
yourself and others.
WARNING: Welding fumes and gases are hazardous to your health and may damage lungs and other organs. Use
adequate ventilation.
ELECTRIC SHOCK can kill.
ARC RAYS and SPARKS can injure eyes and burn skin. Wear correct hand, head, eye and body protection.
Canada: WHMIS classification: Class D; Division 2, Subdivision A
Canadian Environmental Protection Act (CEPA): All constituents of these products are on the Domestic Substance
List (DSL).
USA:
Under the OSHA Hazard Communication Standard, these products are considered hazardous.
These products contain or produce a chemical known to the state of California to cause cancer and birth defects
(or other reproductive harm). (California Health & Safety Code § 25249.5 et seq.)
United States EPA Toxic Substance Control Act: All constituents of these products are on the TSCA inventory list or
are excluded from listing.
CERCLA/SARA Title III
Reportable Quantities (RQs) and/or Threshold Planning Quantities (TPQs):
Ingredient name
RQ (lb)
TPQ (lb)
Product is a solid solution in the form of a solid article.
-
-
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the
National Response Center and to your Local Emergency Planning Committee.
Section 311 Hazard Class
As shipped:
Immediate
In use: Immediate delayed
EPCRA/SARA Title III 313 Toxic Chemicals
The following metallic components are listed as SARA 313 “Toxic Chemicals” and potential subject to annual SARA
313 reporting. See Section 3 for weight percent.
Ingredient name
Manganese
1.0%
Disclosure threshold
de minimis concentration
12
Nickel
0.1%
de minimis concentration
16.
OTHER INFORMATION
This
Safety Data Sheet has been revised due to modifications to several paragraphs and/or new
format.
This SDS supersedes 7971-1-W.
Refer to ESAB "Welding and Cutting - Risks and Measures", F52-529 “Precautions and Safe Practices for Electric
Welding and Cutting” and F2035 “Precautions and Safe Practices for Gas Welding, Cutting and Heating” available
from ESAB, and to:
USA:
Contact ESAB at www.esabna.com or 1-800-ESAB-123 if you have questions about this SDS.
American National Standard Z49.1 "Safety in Welding and Cutting", ANSI/AWS F1.5 “ Methods for Sampling and
Analyzing Gases from Welding and Allied Processes”, ANSI/AWS F1.1 “Method for Sampling Airborne Particles
Generated by Welding and Allied Processes”, AWSF3.2M/F3.2 “Ventilation Guide for Weld Fume”, American
Welding Society, 550 North Le Jeune Road, Miami, Florida, 33135. Safety and Health Fact Sheets available from
AWS at www.aws.org.
OSHA Publication 2206 (29 C.F.R. 1910), U.S. Government Printing Office, Superintendent of Documents, P.O. Box
371954, Pittsburgh, PA 15250-7954.
American Conference of Governmental Hygienists (ACGIH), Threshold Limit Values and Biological Exposure Indices,
6500 Glenway Ave., Cincinnati, Ohio 45211, USA.
NFPA 51B “Standard for Fire Prevention During Welding, Cutting and Other Hot Work” published by the National
Fire Protection Association, 1 Batterymarch Park, Quincy, MA 02169.
UK:
WMA Publication 236 and 237, "Hazards from Welding Fume”, “The arc welder at work, some general
aspects of health and safety".
Germany:
Unfallverhütungsvorschrift BGV D1, "Schweißen, Schneiden und verwandte Verfahren".
Canada: CSA Standard CAN/CSA-W117.2-01 “Safety in Welding, Cutting and Allied Processes”
These products have been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
R-phrases:
R10 – Flammable.
R15 – Contact with water liberates extremely flammable gases.
R17 – Spontaneously flammable in air.
R25 – Toxic if swallowed.
R32 – Contact with acids liberates very toxic gas.
R40 – Limited evidence of a carcinogenic effect.
R43 – May cause sensitization by skin contact.
R45 – May cause cancer.
13
R51 – Toxic to aquatic organisms.
R53 – May cause long-term adverse effects in the aquatic environment. R20/22 – Harmful by inhalation and if
swallowed.
R23/24/25 – Toxic by inhalation, in contact with skin and if swallowed. R36/38 – Irritating to eyes and skin.
R48/23/25 –
swallowed.
Toxic: danger of serious damage to health by prolonged exposure through inhalation and if
ESAB requests the users of these products to study this Safety Data Sheet (SDS) and become aware of product
hazards and safety information. To promote safe use of these products a user should:
notify its employees, agents and contractors of the information on this SDS and any product
hazards/safety information.
-
furnish this same information to each of its customers for these products.
request such customers to notify employees and customers for the same product hazards and safety
information.
The information herein is given in good faith and based on technical data that ESAB believes to be reliable. Since
the conditions of use are outside our control, we assume no liability in connection with any use of this information
and no warranty, expressed or implied is given. Contact ESAB for more information.
1530 Big Blast
PRO-CHEM, INC.
1475 BLUEGRASS LAKES PKWY.
ALPHARETTA, GA 30004
EMERGENCY/INFO # (800) 241-8180
ADDITIONAL EMERGENCY # INFO TRAC 1-800-535-5053
MATERIAL SAFETY DATA SHEET
BIG BLAST / 1515
MARCH 2006
HEALTH 1
FIRE 2
REACTIVITY 1
P.P.E. A
Complies With USDL Safety and Health Regulations, (29 CFR 1910.200)
SECTION 1 – Chemical and Company Identification
CHEMICAL FAMILY:
Wasp and Hornet Killer
14
SECTION 2 – Composition on Ingredients
COMPONENTS
CAS No.
OSHA PEL
(Chemical Identity,
Common Name(s))
Aliphatic
64742-47-8 Not estab.
hydrocarbon
Carbon dioxide
124-38-9
5000 ppm
ACGIH-TLV
OTHER LIMITS
% (Opt.)
RECOMMENDED
Not estab.
5000 ppm
100 ppm Manu. 60-100%
STEL 30000 ppm 3.0 - 7.0%
Any substance listed as hazardous by the States of California, Florida, Illinois, Michigan, New Jersey, Ohio,
Pennsylvania or Texas is described above if known present in regulated concentrations.
SECTION 3 – Hazards Information
ROUTE (S) OF ENTRY:
EYES? YES
INHALATION? YES
SKIN? YES
INGESTION? YES
ACUTE HEALTH HAZARDS - Caution. Causes moderate eye irritation. May cause skin irritation. Unlikely to be
swallowed, but contains petroleum distillates which may present an aspiration hazard if swallowed. May be
harmful if inhaled.
CHRONIC HEALTH HAZARDS - Prolonged or frequently repeated skin contact may cause allergic reactions in some
individuals. Follow label instructions and good chemical hygiene practices to avoid these hazards.
CARCINOGENITY:
OSHA: NO
ACGIH: NO
NTP: NO IARC: NO
SIGNS AND SYMPTOMS OF EXPOSURE: Redness, dryness, scaling or itching skin. Excessive inhalation of vapors may
cause headaches, stupor, or irritation of throat and eyes. Swallowing may cause irritation of stomach and
intestines resulting in nausea and vomiting.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Pre-existing skin and kidney conditions may be
adversely affected. Follow good chemical hygiene practices to avoid this hazard.
SECTION 4 – First Aid Measures
Flush with plenty of water (for at least 15 minutes lifting eyelids to insure
complete
removal.) Call a physician if irritation persists.
Wash thoroughly with soap and water. Remove contaminated clothing and
SKIN:
shoes.
Launder contaminated clothing before reuse. Call a physician if irritation
arises and
persists. Note to physician: Contains petroleum distillates (>80%).
Get to fresh air. If breathing has stopped, qualified personnel should
INHALATION: administer artificial
respiration.
Unlikely from aerosol can. If large quantities are swallowed, call a physician
INGESTION:
or poison
control center immediately. Get immediate medical attention.
EYES:
SECTION 5 – Fire Fighting Measures
15
0”, no flashback
USA FLAME PROJECTION TEST (ASTM D-3065):
FLAMMABLE LIMITS:
No Data LEL:
No Data UEL:
No Data
EXTINGUISHING MEDIA:
Treat as an oil fire. Water may cause fire to float and spread. Use carbon
dioxide, dry chemical or foam.
SPECIAL FIRE FIGHTING PROCEDURES:
Use water spray to keep containers cool and vapors down.
Do not allow runoff to enter sewers or public watercourses.
Wear self-contained breathing apparatus in chemical fires.
HAZARDOUS PRODUCTS OF COMBUSTION: Carbon dioxide, carbon monoxide, oxygen, smoke, soot
and various organic oxidation by-products.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Aerosol container (pressurized) may burst if heated over
130qF. Combustible contents.
SECTION 6 – Accidental Release Measures
SMALL SPILL:
Caution, slip hazard. Wipe up small spills promptly. Thoroughly clean any residues with an
effective cleaning compound.
LARGE SPILL:
Isolate traffic and ventilate area. Eliminate all ignition sources. Wear protective gear as
necessary. Dike to prevent spread. Prevent from entering drains, sewers or any watercourse or waterway. Pick up
with an absorbent material. Put in a suitable container for proper disposal. This product is toxic to fish and aquatic
invertebrates.
SECTION 7 – Handling and Storage
HANDLING:
Avoid contact with eyes or clothing. Wash thoroughly with soap and water after handling. Do not
swallow. Avoid inhaling mist or vapors. Do not deliberately concentrate and inhale vapors. Use with adequate
ventilation. Keep away from heat, sparks and open flame. Do not use around ignition sources such as heat, sparks,
open flame, static electricity, electric motors, welding arcs, etc. Do not smoke while using. Exposure to
temperatures above 130qF may cause bursting. Direct spray away from face. Replace cap when not in use. Do not
puncture or incinerate container. Do not apply directly to water.
STORAGE:
Store in a cool (under 130qF) dry location away from heat, sparks, open flame, and direct
sunlight. Keep out of reach of children. Follow label directions carefully.
SECTION 8 – Exposure Controls/Personal Protection
EYE PROTECTION:
Yes, goggles or approved safety glasses (ANSI Z87)
SKIN PROTECTION:
Not usually needed. If direct contact is possible, wear chemical resistant gloves or PPE.
RESPIRATORY PROTECTIONS:
Not usually necessary. Use with adequate ventilation. If PELs or TLVs are
exceeded (see Section II), follow NIOSH\MSHA recommendations.
ENGINEERING CONTROLS:
overexposure.
Ventilation not usually necessary but should be provided in the event of
SECTION 9 – Physical and Chemical Properties
Clear colorless liquid with a slight petroleum
APPEARANCE/ODOR: odor.
PHYSICAL STATE:
Liqud
pH:
N/A
SPECIFIC GRAVITY (70qF): 0.806
BOILING POINT (Concentrate):430qF
MELTING POINT:
No Data
16
EVAPORATION RATE (Butyl Acetate = 1): No Data
PRESSURE (psig. @
90+ 5
VAPOR DENSITY (AIR=1): Greater than one (1)
70qF):
SOLUBILITY IN WATER:
Negligible
VOLATILE
ORGANIC
COMPOUNDS
0 grams per liter or 0% by weight VOC’s.
(VOCs):
SECTION 10 – Stability and Reactivity
HAZARDOUS POLYMERIZATION: This product will not undergo hazardous polymerization. HAZARDOUS
DECOMPOSITION/BY-PRODUCTS: Carbon dioxide, carbon monoxide, oxygen, smoke, soot and various organic
oxidation by-products.
CHEMICAL STABILITY:
Stable
INCOMPATIBILITY (Materials to Avoid):
metal acetylhalides and chromium.
Strong oxidizing agents, alkali metals, alkaline earth metals,
SECTION 11 – Toxicological Information
No Data
SECTION 12 – Ecological Information
No Data
SECTION 13 – Disposal Consideration
DISPOSAL METHOD:
Dispose of in accordance with all applicable local, state, and federal regulations.
RCRA WASTE INFORMATION:
If this product becomes a waste, it would not be a hazardous waste as defined
by RCRA (40 CFR 261). However the waste should be properly characterized to evaluate whether its composition
has been modified prior to disposal.
SECTION 14 – Transport Information
DOT INFORMATION:
PROPER SHIPPING DESCRIPTION:
HAZARD CLASS:
IDENTIFICATION NUMBER
PACKING GROUP:
AIR TRANSPORTATION:
PROPER SHIPPING DESCRIPTION:
HAZARD CLASS:
IDENTIFICATION NUMBER:
PACKING GROUP:
REPORTABLE QUANTITY (RQ):
MARINE POLLUTANTS:
49 CFR 172.101
Consumer Commodity
ORM-D
None
None
Aerosols, non-flammable
2.2
UN 1950
None
49 CFR 172.101: Not applicable
None
SECTION 15 – Regulatory Information
US Federal Regulations:
17
TSCA (Toxic Substances Control Act) Status: All ingredients are on the TSCA inventory or are not required to be
listed on the TSCA inventory.
CERCLA RQ – 40 CFR 302.4 (a) : None Listed
SARA 313 Components – 40 CFR
372.65
Name
CAS
Percentage
Tetramethrin
7696-12-0
0.1%
Permethrin
52645-53-1
0.26%
Piperonyl butoxide
51-03-6
0.52%
State and Local Regulations:
California Proposition 65
None
SECTION 16 – Other Information
WARNING! The use of this product is beyond the control of the manufacturer; therefore, no guarantee, expressed
or implied, is made as to the effects of such or the results to be obtained if not used in accordance with directions
or established safe practice. The user must assume all responsibility, including injury or damage, resulting from its
misuse as such, or in combination with other materials. The manufacturer warrants only that this product meets
the manufacturer's specifications for such product. THIS WARRANTY IS IN LIEU OF ALL OTHER WARRANTIES,
EXPRESS OR IMPLIED, AS TO DESCRIPTION , QUALITY, MERCHANTABILITY. FITNESS FOR
ANY PARTICULAR PURPOSE, PRODUCTIVENESS, OR ANY OTHER MATTER, OF THIS
PRODUCT. THE MANUFACTURER SHALL BE IN NO WAY RESPONSIBLE FOR THE IMPROPER USE OF THIS PRODUCT.
The sole and exclusive remedy against the manufacturer for breach of warranty shall be reimbursement of the
purchase price of the product in the event that a defective condition of the product shall be found to exist. NO
OTHER REMEDY (INCLUDING BUT NOT
LIMITED TO INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR INJURY TO PERSON OR
PROPERTY OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE.
1718 Zinc Proof
PRO CHEM, INC.
1475 BLUEGRASS LAKES PKWY.
ALPHARETTA, GA 30004
EMERGENCY/INFO # (800) 241-8180
ADDITIONAL EMERGENCY # INFO TRAC 1-800-535-5053
MATERIAL SAFETY DATA SHEET
ZINK PROOF / 1718
DECEMBER 2009
HEALTH 2
FIRE 3
REACTIVITY 1
P.P.E. I
Complies With USDL Safety and Health Regulations, (29 CFR 1910.200)
18
SECTION 1 – Chemical and Company Identification
PRODUCT TYPE: Aerosol
FORMULA:
Proprietary
SECTION 2 – Composition on Ingredients
CHEMICAL NAME
CAS #
Toluene
108-88-3
% WT 313/CHEM SKIN CARCINOGEN
PEL
TLV-TWA
30-40
YES
YES
NO
200 ppm 50 ppm
Hydrotreated, Light 64742-47-8 1-10
NO
NO
NO
500 ppm 100 ppm
7440-66-6 10-20
YES
NO
NO
Liquefied Petroleum
68476-86-8 35-45
Gas
NO
NO
NO
10 mg/m
(Dust)
1000
ppm
Petroleum Distillates,
Zinc
3
N/E
1000
ppm
SECTION 3 – Hazards Information
PRIMARY ROUTES OF ENTRY & EFFECTS OF OVEREXPOSURE:
EYES: May cause irritation accompanied by stinging, tearing, redness, and swelling of eyes. SKIN: May cause mild
irritation. Frequent or prolonged contact may cause redness, burning, and drying and cracking of skin. Passage of
this material into the body through the skin is possible. May aggravate existing skin conditions.
INHALATION: Inhalation of small amounts of vapor or mist is not likely to cause harmful effects. Inhalation of large
amounts may irritate the upper respiratory tract, cause flu-like symptoms, and have a slight anesthetic effect.
Prolonged overexposure can cause central nervous system excitation followed by central nervous system
depression and other central nervous system effects, temporary changes in mood and behavior, muscle weakness,
loss of coordination, confusion, irregular heartbeat, coma, and death. Intentional, prolonged abuse may lead to
damage to the central and peripheral nervous systems, vision, hearing, liver, kidneys, heart, blood, and brain.
INGESTION: Can cause gastrointestinal irritation, nausea, fever, vomiting and diarrhea. Aspiration of material into
the lungs can cause lung inflammation and other lung injury.
SECTION 4 – First Aid Measures
EYES: Flush with large amounts of cool running water for at least 15 minutes while holding upper and lower lids
open. If irritation persists get medical attention immediately.
SKIN: Wash with soap and water. If irritation persists seek medical attention.
INHALATION: Remove to fresh air. Seek medical attention immediately. If breathing stops give artificial respiration.
INGESTION: Do not induce vomiting. Seek medical attention immediately
SECTION 4 – First Aid Measures
EYES: Flush with large amounts of cool running water for at least 15 minutes while holding upper and lower lids
open. If irritation persists get medical attention immediately.
19
SKIN: Wash with soap and water. If irritation persists seek medical attention.
INHALATION: Remove to fresh air. Seek medical attention immediately. If breathing stops give artificial respiration.
INGESTION: Do not induce vomiting. Seek medical attention immediately
SECTION 6 – Accidental Release Measures
STEPS TO BE TAKEN IN CASE OF SPILL OR LEAK: Allow propellant to evaporate. Maintain local exhaust and
adequate ventilation. No smoking. Keep sparks, heat sources and open flame far away from spill or leak. Cover
with absorbent material and sweep up. Wash area to prevent slipping.
Dispose of soaked absorbent material in accordance with Federal, State, and local laws.
SECTION 7 – Handling and Storage
KEEP OUT OF REACH OF CHILDREN. For Industrial and Institutional use only. Store in a cool, dry area away from
heat or open flame. Do not store at temperatures above 120 F.
NFPA CODE 30B RATING: Level 3 Aerosol
SECTION 8 – Exposure Controls/Personal Protection
RESPIRATORY PROTECTION: If air concentrations exceed exposure limits listed in Section 2, wear NIOSH/MSHA
approved respirator with dust filter and organic vapor cartridge.
VENTILATION: Provide local exhaust to keep air concentrations of ingredients listed in Section 2 below acceptable
limits.
PROTECTIVE GLOVES: Use chemical resistant gloves to prevent hand contact.
EYE PROTECTION: Always wear safety glasses or chemical proof goggles when working with chemicals.
SECTION 9 – Physical and Chemical Properties
DATA BELOW BASED ON AEROSOL CONCENTRATE ONLY:
BOILING POINT:
>200 F
VAPOR DENSITY (AIR=1):
>1
pH:
N/A
1.105
SPECIFIC GRAVITY (H20=1) @ 70 F:
SOLUBILITY IN WATER:
Negligible
APPEARANCE/ODOR: Gray Viscous Liquid, Solvent Odor
DATA BELOW BASED ON TOTAL CONTENTS:
VAPOR PRESSURE OF CAN ([email protected] 72 F): 60
TOTAL VOC %: 77.62
SECTION 10 – Stability and Reactivity
STABILITY: Material Stable
HAZARDOUS POLYMERIZATION: Will not occur
INCOMPATIBILITY: Avoid contact with strong oxidizing agents, acids, halogen gases and alkaline hydroxides.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Dioxide, Carbon Monoxide, and Zinc Oxide fume.
SECTION 11 – Toxicological Information
20
No data available.
SECTION 12 – Ecological Information
No data available.
SECTION 13 – Disposal Consideration
WASTE DISPOSAL METHOD: Aerosol cans, when emptied and depressurized through normal use, pose no disposal
hazard and should be recycled. Consult Federal, State and local authorities for approved procedures.
SECTION 14 – Transport Information
D.O.T. HAZARD CLASS: Consumer Commodity, ORM-D
SECTION 15 – Regulatory Information
HMIS RATING (Based on Aerosol Concentrate):
0 – Minimal
1 – Slight
2 – Moderate
3 – Serious
4 – Extreme
N/A = Not Applicable
N/E = Not Established N/D = Not Determined
<=Less than >=More Than
SECTION 16 – Other Information
NOTICE: The information contained on this Material Safety Data Sheet is considered accurate as of the date of
publication. It is not necessarily all inclusive nor fully adequate in every circumstance. The suggestions should not be
confused with, nor followed in violation of applicable laws, regulations, rules or insurance requirements. No
warranty, express or implied, of merchantability, fitness, accuracy of data, or the results to be obtained from the
use thereof is made. The vendor assumes no responsibility for injury or damages resulting from the inappropriate
use of this product.
THIS INFORMATION MUST BE ON ALL MSDS’S COPIED AND DISTRIBUTED FOR THIS MATERIAL.
NO WARRANTY IS EXPRESSED/IMPLIED REGARDING THE ACCURACY OF THIS DATA OR
RESULTS OBTAINED FROM USE. PROCHEM ASSUMES NO RESPONSIBILITY FOR PERSONAL
INJURY OR PROPERTY DAMAGE TO USER. VENDEE/USER ASSUMES ALL RISKS ASSOCIATED
WITH USE.
1755 Hi-Speed
MATERIALSAFETYDATASHEET
HEALTH-2
FLAMMABILITY-2 REACTIVITY-0
PERSONAL PROTECTION-B
=====================================================================================
SECTION I - MANUFACTURED FOR:
PRO CHEM, INC. - 1475 BLUEGRASS LAKES PARKWAY - ALPHARETTA, GA. 30004 - EMERGENCY AND
INFORMATION#: (800) 241-8180
=====================================================================================
SECTION II - HAZARDOUS INGREDIENTS
CHEMICAL NAME: ISOBUTANE PROPANE BLEND.
OSHA PEL: 800 PPM.
ACGIH TLV: 800 PPM.
% RAW MTL:
OTHER LIMITS:
CAS#: 75-28-5 ,74-98-6.
21
CHEMICAL NAME: PETROLEUM OIL.
OSHA PEL: 5MG/ M3.
ACGIH TLV: 5MG /M3.
% RAW MTL: .
OTHER LIMITS: CAS#: 64742-53-6.
=====================================================================================
SECTION III - PHYSICAL DATA
BOILING POINT: N A.
APPEARANCE: DARK OIL, ODOR OF SULFURIZED OILS.
SOLUBILITY: INSOLUBLE.
SPECIFIC GRAVITY (H20=1): 1.0.
VAPOR PRESSURE (mm Hg.): MAX 60.
MELTING POINT:
VAPOR DENSITY (AIR=1): N E.
EVAPORATION RATE(): N E.
=====================================================================================
SECTION IV - FIRE AND EXPLOSION DATA
FLASH POINT: N A. METHOD USED:
FLAMMABILITY LIMIT: NON-FLAMMABLE.
LEL: N E.
UEL: N E.
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL, AND CARBON DIOXIDE.
SPECIAL FIRE FIGHTING PROCEDURES: SELF CONTAINED BREATHING APPARATUS.
UNUSUAL FIRE AND EXPLOSION HAZARDS: DO NOT EXPOSE AEROSOLS TO TEMPERATURES ABOVE 130 DEG. F OR
THE CONTAINER MAY RUPTURE.
=====================================================================================
SECTION V - REACTIVITY DATA
STABILITY: STABLE. CONDITIONS TO AVOID: OPEN FLAME, WELDING ARCS, HEAT.
INCOMPATIBILITY (MATERIALS TO AVOID): STRONG OXIDIZERS.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS: CO, CARBON DIOXIDE, SULFUR OXIDES.
HAZARDOUS POLYMERIZATION: NO. CONDITIONS TO AVOID: NONE KNOWN.
=====================================================================================
SECTION VI - HEALTH HAZARD DATA
ROUTE(S) OF ENTRY:
INHALATION? Y. SKIN? N
INGESTION?N
EYES? N
HEALTH HAZARDS (ACUTE AND CHRONIC): INHALATION - EXCESSIVE INHALATION OF VAPORS CAN BE HARMFUL
AND MAY CAUSE HEADACHE, DIZZINESS, ASPHYXIA, ANESTHETIC EFFECTS AND POSSIBLE UNCONSCIOUSNESS.
EYES - IRRITATION.
SKIN - IRRITATION.
INGESTION - POSSIBLE CHEMICAL PNEUMONITIS IF ASPIRATED INTO LUNGS. NAUSEA.
CARCINOGENICITY:
U K. NTP?
IARC MONOGRAPHS?
OSHA REGULATED?
SIGNS AND SYMPTOMS OF EXPOSURE: EYES - FLUSH WITH WATER FOR 15 MINUTES. IF IRRITATED, SEE PHYSICIAN.
SKIN – WASH WITH SOAP AND WATER. IF IRRITATED, SEE PHYSICIAN.
INHALATION - REMOVE TO FRESH AIR. RESUSCITATE IF NECESSARY. GET MEDICAL AID.
INGESTION - CALL PHYSICIAN IMMEDIATELY. DO NOT INDUCE VOMITING.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: MAY AGGRAVATE EXISTING EYE, SKIN, OR UPPER
RESPIRATORY CONDITIONS.
EMERGENCY AND FIRST AID PROCEDURES:
=====================================================================================SECTION
VII - PRECAUTIONS FOR SAFE HANDLING AND USE
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: ABSORB WITH SUITABLE MEDIUM. INCINERATE
OR LANDFILL ACCORDING TO LOCAL, STATE OR FEDERAL REGULATIONS. KEEP OUT OF SEWERS AND STREAMS.
WASTE DISPOSAL METHOD: AEROSOL CANS WHEN VENTED TO ATMOSPHERIC PRESSURE THROUGH NORMAL USE,
POSE NO DISPOSAL HAZARD.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: DO NOT PUNCTURE OR INCINERATE CONTAINERS. DO
NOT STORE AT TEMPERATURES ABOVE 130 DEG. F.
OTHER PRECAUTIONS: AVOID FOOD CONTAMINATION. KEEP OUT OF REACH OF CHILDREN. AVOID BREATHING
VAPORS.
22
=====================================================================================
SECTION VIII - CONTROL MEASURES
RESPIRATORY PROTECTION (SPECIFY TYPE): IF VAPOR CONCENTRATION EXCEEDS TLV, USE RESPIRATOR APPROVED
BY U.S. BUREAU OF MINES FOR ORGANIC VAPOR.
VENTILATION: LOCAL EXHAUST: MECHANICAL (GENERAL):
ADEQUATE VENTILATION TO KEEP VAPOR CONCENTRATION BELOW TLV.
SPECIAL:
OTHER LIMITS:
PROTECTIVE GLOVES: NONE UNLESS SKIN IRRITATION A PROBLEM.
EYE PROTECTION: SAFETY GLASSES RECOMMENDED.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: NONE.
WORK & HYGIENIC PRACTICES: WASH WITH SOAP AND WATER BEFORE HANDLING FOOD. REMOVE
CONTAMINATED CLOTHING.
=====================================================================================
SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
OTHER PRECAUTIONS:
=====================================================================================
SECTION 313 SUPPLIER NOTIFICATIONS
2207 Foam It Away
PRO CHEM, INC.
1475 BLUEGRASS LAKES PKWY.
ALPHARETTA, GA 30004
EMERGENCY/INFO # (800) 241-8180
ADDITIONAL EMERGENCY # INFO TRAC 1-800-535-5053
MATERIAL SAFETY DATA SHEET
FOAM-IT-AWAY / 2207
FEBRUARY 2009
HEALTH 2
FIRE 0
REACTIVITY 0
P.P.E. B
Complies With USDL Safety and Health Regulations, (29 CFR 1910.200)
SECTION 1 – Chemical and Company Identification
CHEMICAL FAMILY: Degreaser
SECTION 2 – Composition on Ingredients
CAS #
111-76-2
CHEMICAL NAMES
2-butoxyethanol
WT %
< 5 25
TLV (UNITS)
(PPM) skin
N/E = not established
SECTION 3 – Hazards Information
23
PRIMARY ROUTE(S) OF ENTRY: Skin contact/absorption and inhalation
SIGNS AND SYMPTOMS OF OVEREXPOSURE: Gastrointestinal irritation (nausea, vomiting, diarrhea), irritation to
nose, throat, and respiratory tract.
TARGET ORGAN EFFECTS: Overexposure to this material (or its components) has been suggested as a cause of the
following effects in laboratory animals and may aggravate pre-existing disorders or these organs in humans:
chronic ingestion may cause kidney and liver lesions at high doses.
IMMEDIATE HEALTH EFFECTS:
EYES: Corrosive. Exposure may cause noticeable pain, and severe irritation and transient corneal injury.
SKIN: Corrosive. Causes chemical burns. Harmful contact may not cause immediate pain.
Ethylene glycol monobutyl ether and 2-aminoethanol may be absorbed through the skin.
INHALATION: Exposure to vapor or mist is possible. Short term inhalation is not likely to cause harmful effects:
breathing large amounts may be harmful. Symptoms are more typically seen at air concentrations exceeding the
recommended exposure limits.
INGESTION: Harmful or fatal if swallowed. Causes chemical burns to mouth, throat and stomach.
REPRODUCTIVE/DEVELOPMENTAL INFORMATION: No data.
CARCINOGENIC INFORMATION: This material is not listed as a carcinogen by IARC, NTP, or OSHA.
LONG TERM EFFECTS: No data
SECTION 4 – First Aid Measures
EYES: Immediately flush with water. Remove contact lenses, if applicable, and continue flushing with water for 15
minutes. Call a physician immediately.
SKIN: Immediately flush with water for 15 minutes. Call physician if irritation persists. Completely decontaminate
clothing, shoes, and leather goods before reuse or discard.
INHALATION: If symptoms develop move victim to fresh air. If symptoms persist, call a physician.
INGESTION: Do not induce vomiting. Rinse mouth with water, then drink one or two glasses of water or milk. Call a
physician immediately. Never give anything by mouth if victim is unconscious, is rapidly losing consciousness
or is convulsing
.
SECTION 5 – Fire Fighting Measures
FLASH POINT:
No Flash at Boil
METHOD USED: C.C. Method
EXPLOSIVE LIMITS:
Not Applicable
AUTOIGNITION TEMPERATURE:
Not Applicable
HAZARDOUS PRODUCTS OF COMBUSTION: Oxides of carbon, oxides of nitrogen, and ammonia
EXTINGUISHING MEDIA:
Not Applicable
FIRE FIGHTING INSTRUCTIONS:
Avoid contact with this material. Avoid walking in spilled
material. Wear protective clothing for skin and eyes.
SECTION 6 – Accidental Release Measures
SMALL SPILL: Absorb with an inert solid and scoop up for disposal, then rinse soiled area with water down the
drain.
LARGE SPILL: Stop leak at the source and collect into a suitable container, then treat as a small spill.
SECTION 7 – Handling and Storage
24
HANDLING: Containers of this material may be hazardous when emptied. Since emptied containers retain product
residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be
observed.
STORAGE: Store in a cool, dry place. Keep container closed when not in use.
SECTION 8 – Exposure Controls/Personal Protection
EYE PROTECTION: Chemical Splash goggle in compliance with OSHA regulations is advised: however, OSHA
regulations also permit other type safety glasses. Consult your safety representative.
SKIN PROTECTION: Wear rubber gloves (consult your safety equipment supplier). To prevent repeated or
prolonged skin contact, wear impervious clothing and boots.
RESPIRATORY PROTECTION: If workplace exposure limits of product or any component are exceeded (see exposure
guidelines), NIOSH/OSHA approved air-supplied respirator is advised in the absence of proper
environmental control. OSHA relations also permit other NIOSH/OSHA respirators (negative
pressure type) under specific conditions (see your industrial hygienist). Engineering or
administrative controls should be implemented to reduce exposure.
ENGINEERING CONTROLS: Provide sufficient mechanical (general and local exhaust) ventilation to maintain
exposure below level of overexposure (from known, suspected or apparent adverse effects).
SECTION 9 – Physical and Chemical Properties
APPEARANCE/ODOR:
pH CONCENTRATE:
VAPOR PRESSURE:
BOILING POINT: 212qF
PERCENT VOLATILE:
Thin, green liquid with a floral odor
11.5 – 12.5
Unknown
VAPOR DENSITY:
Unknown
SOLUBILITY IN WATER:
Complete
90%
SPECIFIC GRAVITY (H20=1):
1.05 +/- 0.02
SECTION 10 – Stability and Reactivity
CHEMICAL STABILITY:
CONDITIONS TO AVOID:
INCOMPATIBILITY:
HAZARDOUS DECOMPOSITION:
HAZARDOUS POLYMERIZATION:
Stable
Temperature extremes.
Chlorine bleach, oxidizers, acids.
Will not occur.
Will not occur.
SECTION 11 – Toxicological Information
No data available.
SECTION 12 – Ecological Information
No data available.
SECTION 13 – Disposal Consideration
WASTE DISPOSAL INFORMATION: Dispose of in accordance with all applicable Federal, State, and Local regulations.
RCRA INFORMATION: If this material becomes a waste, it would be considered hazardous under 40 CFR 261.22,
and would be classified as EPA Waste Number D002.
SECTION 14 – Transport Information
DOT INFORMATION:
49 CFR 172.10
25
DOT DESCRIPTION:
DOT HAZARD CLASS:
HAZARDOUS COMPONENT:
REPORTABLE QUANTITY (RQ):
NOT APPLICABLE
33440 Class 55
8, NA 1760, II
Potassium Hydroxide
49 CFR 172.101
SECTION 15 – Regulatory Information
US Federal Regulations:
TSCA (Toxic Substances Control Act) Status
TSCA (United States) The intentional ingredients of this product are listed.
CERCLA RQ – 40 CFR 355 Appendix A: None
SARA 302 Components 40 CFR Appendix A: None
Section 311/312 Hazard Class 40 CFR 370.2: Immediate (X) Delayed (X) Fire ( ) Reactivity ( )
Sudden Release of Pressure ( )
SARA 313 Components – 40 CFR 372.65
CAS # Chemical Names %
N/A *Glycol Ethers <5.0
*Listed in Section 2 as Ethylene Glycol Monobutyl Ether
State and Local Regulation:
California Proposition 65: None
California SCAQMD Rule 443.1 VOC’s: > 250 g/L
North Carolina Administrative Code 2D.1104 and 2B.0610: None
South Carolina Regulation 62.5 Standard Number 8: Ethylene Glycol Monobutyl Ether < 5.0
SECTION 16 – Other Information
The information accumulated herein is believed to be accurate but is not warranted to be whether originating with
the company or not. Recipients are advised to confirm in advance of need that the information is current,
applicable and suitable to their circumstances. This information was compiled from current manufacturer’s MSDS’s
of the component parts of the product, as well as other sources, such as:
Code of Federal Regulations 29, Revised as of July 1, 1994.
Code of Federal Regulations 40, Revised as of July 1, 1994
ACGIH, Guide to Occupational Exposure Values, 1996.
ANSI Z129.1-1994, Precautionary Labeling for Hazardous Industrial Chemicals.
Hazard Communication Handbook, A Right To Know Compliance Guide. Craig A. Moyer & Michael Francis.
Clark Broadman Company. Ltd. New York, NY 1992
RCRA Regulations and Keyword Index, Compiled and Published by McCoy and Associates, Inc Lakewood,
Colorado. 1992.
THIS INFORMATION MUST BE ON ALL MSDS’S COPIED AND DISTRIBUTED FOR THIS MATERIAL.
NO WARRANTY IS EXPRESSED/IMPLIED REGARDING THE ACCURACY OF THIS DATA OR
RESULTS OBTAINED FROM USE. PROCHEM ASSUMES NO RESPONSIBILITY FOR PERSONAL
INJURY OR PROPERTY DAMAGE TO USER. VENDEE/USER ASSUMES ALL RISKS ASSOCIATED
WITH USE.
2404 Ram Rod
PRO CHEM, INC.
26
1475 BLUEGRASS LAKES PKWY.
ALPHARETTA, GA 30004
EMERGENCY/INFO # (800) 241-8180
ADDITIONAL EMERGENCY # INFO TRAC 1-800-535-5053
MATERIAL SAFETY DATA SHEET
RAM ROD / 2404
MAY 2012
HEALTH 3
FIRE 0
REACTIVITY 2
P.P.E. C
Complies With USDL Safety and Health Regulations, (29 CFR 1910.1200)
SECTION 1 – Chemical and Company Identification
CHEMICAL FAMILY:
Drain Opener
SECTION 2 – Composition on Ingredients
NAME
CAS #
OSHA PEL
ACGIH TLV
Sulfuric Acid
7664-93-9
1 mg/m3
0.2 ppm *
Water, dye
N/A
N/A
* - Threshold limit value is mist only
Note – No materials listed are subject to SARA Title III reporting
SECTION 3 – Hazards Information
EFFECTS OF OVEREXPOSURE:
EYE CONTACT: Corrosive to eyes on contact, including corneal damage or blindness
SKIN CONTACT: Corrosive to skin on contact, including inflammation and blistering
INGESTION: Will cause abdominal pain, nausea, vomiting, destruction of tissue in the gastrointestinal tract.
INHALATION: Spray mist may cause irritation, burning, destruction of tissue. Symptoms may include coughing,
choking, pain, or shortness of breath. Severe overexposure may lead to fatal lung damage.
HEALTH HAZARDS:
1) ACUTE: Causes burns/irritation to eye, skin and respiratory tract.
2) CHRONIC: Prolonged exposure to spray mist may produce respiratory irritation leading to frequent attacks of
bronchial infection.
National Toxicological Program: NO I.A.R.C. Monographs: NO OSHA: NO
SECTION 4 – First Aid Measures
EMERGENCY FIRST AID PROCEDURES:
EYE CONTACT: Immediately flush with cool running water for at least 15 minutes. Remove contact lenses while
continuing to flush. Get medical attention.
INGESTION: Call Physician or Poison Control immediately. Give lots of water to drink. DO NOT INDUCE VOMITING.
Never give anything by mouth to an unconscious person.
SKIN CONTACT: Immediately flush with water for 15 minutes. Remove clothing and wash before reuse.
27
INHALATION: Remove to fresh air. If breathing is difficult get medical help.
SECTION 5 – Fire Fighting Measures
FLAMMABILITY LIMITS (% IN AIR):
FLAMMABILITY CLASSIFICATION:
RECOMMENDED EXTINGUISHING MEDIA:
SPECIAL FIRE FIGHTING PROCEDURES:
N.A.
N.A.
FLASH POINT (CC):
N.A.
Dry Chemical or CO2
Firefighters should be equipped with protective gear
including self-contained breathing apparatus.
UNUSUAL FIRE/EXPLOSION HAZARDS: Product will react violently with water.
SECTION 6 – Accidental Release Measures
PROCEDURES IF MATERIAL IS SPILLED OR RELEASED: Use proper protective equipment. Dike or dam large spills.
Absorb spill on inert absorbent material. Pick-up and place in clean DOT specified container for disposal. Rinse area
with water.
SECTION 7 – Handling and Storage
PRECAUTIONS IN HANDLING AND STORAGE AND OTHER PRECAUTIONS: Practice good industrial hygiene in the
handling of these products. Avoid spills and splashing of opened products. Store product in tightly closed original
container. Store in a cool dry place. Provide adequate ventilation. KEEP OUT OF REACH OF CHILDREN.
SECTION 8 – Exposure Controls/Personal Protection
RESPIRATORY PROTECTION: NIOSH/MSHA approved respirator to prevent breathing spray mists.
VENTILATION: Local exhaust recommended.
PROTECTIVE GLOVES: Latex, rubber or neoprene.
EYE PROTECTION: Safety glasses or splash goggles
OTHER PROTECTIVE EQUIPMENT: Rubber apron, boots, as well as an eye wash station are strongly recommended.
SECTION 9 – Physical and Chemical Properties
BOILING RANGE:
550°F
VAPOR PRESSURE (mmHg):
VAPOR DENSITY (AIR=1): None
REACTIVITY IN WATER:
APPEARANCE & ODOR:
SPECIFIC GRAVITY (H20=1):
1.84
1.0 @ 300°F
SOLUBILITY IN H20:
EVAPORATION RATE (WATER=1): >1.0
Mixes violently with water with generation of heat.
Red to amber liquid with no odor.
pH:
<1
Complete
SECTION 10 – Stability and Reactivity
STABILITY: Stable under normal conditions
INCOMPATIBILITY WITH OTHER MATERIALS: Contact with metals, strong oxidizers, strong alkalies may cause high
energy release.
HAZARDOUS DECOMPOSITION PRODUCTS: Hydrogen gas on contact with some metals.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: See incompatibility statement.
SECTION 11 – Toxicological Information
No data available.
SECTION 12 – Ecological Information
28
No data available.
SECTION 13 – Disposal Consideration
WASTE DISPOSAL PROCEDURES: Dispose of in accordance with local, state and federal pollution regulations.
SECTION 14 – Transport Information
DOT HAZARD CLASS: Sulfuric Acid, 8 UN 1830, PGII
SECTION 15 – Regulatory Information
No data available.
SECTION 16 – Other Information
This information is believed to be accurate and represents the best information currently available to Pro Chem,
Inc. However, we make of merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should make their own investigations to
determine the suitability of the information.
THIS INFORMATION MUST BE ON ALL MSDS’S COPIED AND DISTRIBUTED FOR THIS MATERIAL.
NO WARRANTY IS EXPRESSED/IMPLIED REGARDING THE ACCURACY OF THIS DATA OR
RESULTS OBTAINED FROM USE. PROCHEM ASSUMES NO RESPONSIBILITY FOR PERSONAL
INJURY OR PROPERTY DAMAGE TO USER. VENDEE/USER ASSUMES ALL RISKS ASSOCIATED
WITH USE.
'44' Rosin Flux Cored Solder
Material Safety Data Sheet
KESTER SOLDER
MSDS Number: 44 Core
Date Prepared: 31-Aug-01
SECTION 1 - CHEMICAL PRODUCT AND COMPANY INFORMATION
Product Identifier As Used On Label:
Product Use:
"44" ROSIN FLUX CORED SOLDER
Soldering flux in cored solder for electrical or electronic applications.
Manufacturer's Name and Address Supplier's Name and Address (if different from manufacturer)
KESTER SOLDER
DIVISION OF LITTON SYSTEMS, INC
515 E. TOUHY AVENUE
DES PLAINES, IL 60018
USA
Telephone Number for Information: (847) 297-1600
CHEMTREC 24-Hour Emergency Telephone Number: (800) 424-9300
29
NA = Not Applicable
NE = Not Established
UN = Unknown
SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS
HAZARDOUS INGREDIENTS 1 % or greater
CARCINOGENS 0.1 % or greater
C.A.S.
Number
Weight
Percent
OSHA
PEL
ACGIH TLV
mg/m³
mg/m³
TWA
LD 50
ingested
g / Kg
LC 50
inhaled
g / m³
Lead
7439-92-1 *
**
0.05
0.15
NE
NE
Tin
7440-31-5
**
2
2
NE
NE
Silver
7440-22-4 *
**
0.01
0.1
NE
NE
Bismuth
7440-69-9
**
NE
NE
NE
NE
Antimony
7440-36-0 *
**
0.5
0.5
7.0 Rat
NE
Rosin
8050-09-7
<3
NE
NE
NE
NE
NON-HAZARDOUS INGREDIENTS
NON-HAZARDOUS INGREDIENTS
PEL:
Permissible Exposure Limit
ACGIH: American Conference of Government
Industrial Hygienists
TLV:
Threshold Limit Values
STEL:
Short-Term Exposure Limit
TWA: Time Weighted Average
C.A.S. Chemical Abstract Service
NOTES: *
See Section 15 for U.S.A. Regulatory Information.
** Composition and weight % of solder alloys varies widely and can be determined by product label. Flux in core is
typically 1-3% by weight.
SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Hot solder can burn eyes and skin. Fumes during soldering are irritating to eyes and may cause headache and
respiratory system irritation or damage. Prolonged or repeated exposure to rosin flux fumes during soldering may
result in allergic reaction in a sensitive person, resulting in asthma symptoms
ECC (Europe) DANGEROUS SUBSTANCES
HAZARD DESIGNATION:
G
PRIMARY EXPOSURE:
Xn Harmful
R-PHRASES (Risks to Humans or the Environment):
R 61 - May cause harm to the unborn child.
R 62 - Possible risk of impaired fertility.
R 33 - Danger of cumulative effects.
R 36/37/38 - Irritating to eyes, respiratory system
and skin.
30
Fumes during soldering may contain droplets of rosin and/or other organic decomposition products. Skin contact
from handling and decomposition products when heating with soldering iron.
PRIMARY ROUTES OF ENTRY:
Skin
Eyes
Inhalation
Ingestion
TARGET ORGANS:
Flux fumes: eyes, mucous membranes and respiratory system. Ingestion of lead metal can affect kidneys,
gastrointestinal, reproductive and neurological systems.
POTENTIAL HEALTH EFFECTS OF ACUTE (severe short-term) EXPOSURE:
INHALATION:
Flux fumes during soldering may cause irritation and damage of mucous membranes
and respiratory system.
Irritation from contact with smoke from soldering.
Possible local irritation by contact with flux or fumes
May be harmful if swallowed.
None.
EYE CONTACT:
SKIN CONTACT:
INGESTION:
SKIN ABSORPTION:
POTENTIAL HEALTH EFFECTS OF CHRONIC (prolonged) EXPOSURE:
Smoke during soldering will contain rosin which is an allergen that can cause eye irritation and respiratory system
irritation and damage. Repeated inhalation or ingestion of lead can result in systemic poisoning.
Medical Conditions Generally Aggravated by Exposure:
Chemical hypersensitivity, asthma and other respiratory conditions, existing eye and skin disorders. Lead: Diseases
of the blood and blood-forming organs, kidneys, nerves and possibly reproductive systems.
CARCINOGENICITY/
NTP
TERATOGENICITY / MUTAGENICITY:
OSHA
IARC
Not Listed
See Sections 11 and 15 for additional information.
SECTION 4 - FIRST AID MEASURES
Seek medical assistance for further treatment, observation and support if needed
EYE CONTACT:
For burns flush immediately with cool water and get medical attention. For fume
irritation use eye drops and remove from exposure.
SKIN CONTACT:
For burns flush immediately with cool water. If a rash develops from flux fumes,
remove person from exposure and wash skin with soap and water.
INHALATION:
Remove person from exposure to fumes.
INGESTION:
Not likely to occur.
SECTION 5 - FIRE FIGHTING MEASURES
Flammability:
No
Yes
Conditions
avoid:
to
NE
31
Flash Point (T.O.C):
NA °F
Auto-Ignition Temperature:
NA °C
Flammability Limits percent by volume in air:
Extinguishing Means:
Water
Hazardous Combustion Products:
Explosion Sensitivity:
LEL:
Alcohol Foam
Dry Chemical
Carbon monoxide, carbon dioxide. Melted solder above 1000 °F will liberate toxic lead
and/or antimony fumes.
Impact - None Identified
Special Firefighting Procedures:
NA °C
UEL: NA
NA
Carbon Dioxide
NA °F
Static Discharge Sensitivity:
No
Yes
Avoid breathing smoke. Wear self-contained breathing apparatus if this material is in the
Vicinity of a fire.
Unusual Fire and Explosion Hazards: Flux in cored solder may ignite when the solder melts in a fire.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Steps to be Taken if Material is Spilled or Released:
Melted solder will solidify on cooling and can be scraped up. Use caution to avoid breathing fumes if a gas torch is
used to cut up large pieces.
SECTION 7 - HANDLING AND STORAGE
Storage Precautions:
Exposure to sulfur or to high humidity will tarnish the solder surface.
Handling Precautions:
Do not place flux-cored solder into a hot solder pot because the flux may ignite.
Personal Precautions: Avoid breathing smoke / fumes generated during soldering. Wash hands after handling
solder before eating or smoking
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
VENTILATION
TO BE USED:
Provide adequate exhaust ventilation (general and / or local) if necessary to meet exposure
requirements.
Local exhaust ventilation is preferred to minimize dispersion of smoke and fumes into the work
area.
Respiratory Protection: When ventilation is not sufficient to remove fumes from the breathing zone, a safety
approved respirator or self-contained breathing apparatus should be worn.
Protective Gloves: Wear rubber or cloth gloves to avoid skin
contact.
Other Protective Clothing and Equipment:
Eye Protection:
Safety glasses or goggles should be used.
None.
Hygienic Work Practices: Wash hands thoroughly after handling chemicals or solder containing lead before eating or
smoking.
32
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State at 20 °C: Solid
Specific Gravity (water = 1 at 25 °C):
Boiling Point (760 mm Hg):
NA °F
NA °C
Melting Point:
Vapor Pressure (mm Hg at 20 °C):
>7
>212 °F
>100 °C
ND
Evaporation Rate (butyl acetate = 1):
NA
Percent Volatile (by volume):
0 %
Vapor Density (air = 1): NA
Solubility
weight):
in
Water
(%
by
0
Volatile Organic Compound (VOC):
NA g / Liter
pH: NA
Odor Threshold:
Freezing Point (760 mm Hg):
Appearance and Odor:
NA °F
NA °C
NE
Coefficient of
Distribution:
Water
/
Oil
NE
Silver-gray metal in wire, ribbon or preformed shapes with a core of flux, no odor.
SECTION 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable
Unstable
Conditions to avoid: NE
Incompatibility (materials to avoid): Strong acid, strong oxidizers
Hazardous Decomposition Products:
When heated to soldering temperatures, the rosin may be thermally degraded to liberate aliphatic aldehydes,
acids and terpenes. No lead or antimony are detected in fumes from soldering below 1000 °F (537 °C).
HAZARDOUS POLYMERIZATION:
Conditions to avoid:
Not
applicable.
May Occur
Will Not Occur
SECTION 11 - TOXICOLOGICAL INFORMATION
EXPOSURE LIMITS:
Not determined for the product. See Section 2 for ingredients
Lead can accumulate in bone and body organs, and elimination from the body is slow. Medical examinations are
advised for persons repeatedly exposed to levels above the exposure limit for lead. Lead is classified as a Group 2B
carcinogen by the International Agency for Research on Cancer (IARC) and the U.S. Environmental Protection
Agency (EPA). Women of child bearing age should avoid chronic exposure to lead because of possible effects on
reproduction and potential injury to a developing fetus.
SECTION 12 - ECOLOGICAL INFORMATION
33
Keep out of waterways.
SECTION 13 - DISPOSAL CONSIDERATIONS
Waste Disposal Methods:
Solder can be reclaimed.
CAUTION:
Empty containers may contain product residue. Observe all label precautions.
SECTION 14 - TRANSPORT INFORMATION
DOT (U.S.A.):
Not Regulated
TDG (Canada): Not Regulated
SECTION 15 - REGULATORY INFORMATION
U.S.A.: Canada
Europe:
All Chemical substances in this product are listed in the EPA (Environmental Protection Agency) TSCA
(Toxic Substances Control Act) Inventory.
USEPA - Lead and its compounds are placed in Class B2, probably carcinogenic to humans.
IARC - Lead and its compounds are placed in Class 2B, possibly carcinogenic to humans.
*This chemical is subject to the reporting requirements of Section 313 of Title III of the USA Superfund
Amendment and Reauthorization Act (SARA) of 1986 and 40 CFR, Part 372.
California Proposition 65: This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm.
WHMIS (Workplace Hazardous Materials Information System) CLASSIFICATION:
This product has been classified in accordance with the hazard criteria of the Canadian Controlled
Product Regulations (CPR) and the MSDS contains all the information required by the CPR.
D2A
European Council Directive 67/548/EEC
• DANGEROUS SUBSTANCES HAZARD CLASSIFICATION:
T- Toxic Xn - Harmful
• R-PHRASES (Risks to Humans or the Environment)
R 61 - May cause harm to the unborn child.
34
R 62 - Possible risk of impaired fertility.
R 33 - Danger of cumulative effects.
R 36/37/38 - Irritating to eyes, respiratory system and skin.
• S-PHRASES (Safety Precautions for Storing, Handling and Using the Product)
S 2 - Keep out of reach of children.
S 20/21 - When using do not eat, drink or smoke.
S 23 - Do not breathe the fumes.
SECTION 16 - OTHER INFORMATION
NFPA Rating:
Health:
1
Flammability:
1
Reactivity:
0
Special:
HMIS Rating:
Health:
1
Flammability:
1
Reactivity:
0
Personal Protection: X
PREPARATION INFORMATION
Revision Summary:
Change of format and new data in most sections.
Prepared By: D. Bernier
Date Prepared:
31-Aug-01
Telephone Number: (847) 297-1600
Supersedes:
20-Jun-01
The information contained herein is based on data considered accurate and is offered solely for information,
consideration and investigation. Kester Solder extends no warranties, makes no representations and assumes no
responsibility as to the accuracy, completeness or suitability of this data for any purchaser's use. The Data on this
Material Safety Data Sheet relates only to this product and does not relate to use with any other material or in any
process. All chemical products should be used only by or under the direction of technically qualified personnel who
are aware of the hazards involved and the necessity for reasonable care in handling. Hazard communication
regulations require that employees must be trained how to use a Material Safety Data Sheet as a source for Hazard
information.
Abrasive Grinding Wheel
MATERIAL SAFETY DATA SHEET 02458
1. Chemical Product and Contact Information
Product Name:
Abrasive Grinding Wheel
(Aluminum Oxide)
LECO Corporation
Part Numbers:
810-339, 812-231
35
3000 Lakeview
St. Joseph, Michigan 49085
Information: 269-983-5531
Chemtrec: 800-424-9300
(Chemtrec Int'l: 703-527-3887)
2. Composition/Information on Ingredients
Component
Aluminum Oxide
CAS No.
1344-28-1
OSHA
PEL (mg/m3)
10 (total)
ACGIH
TLV (mg/m3)
10 (total)
Typical %
by Weight
96
3. Hazard Identification
EMERGENCY OVERVIEW
No unusual fire or spill hazard; irritant health hazard.
Potential Health Effects
EYES: Dust may irritate.
SKIN: Some may experience irritation.
INHALATION: Coughing, shortness of breath.
INGESTION: No known adverse effects, but not recommended.
MEDICAL CONDITIONS AGGRAVATED: Persons with chronic respiratory or dermatological disorders may be at
increased risk from exposure.
CHRONIC OVEREXPOSURE: Prolonged exposure may affect lung function.
ACUTE OVEREXPOSURE: Not available.
CARCINOGENICITY: None.
4. First Aid Measures
EYES: Flush with water for at least 15 minutes.
SKIN: Wash exposed area with soap and water.
INHALATION: Remove to fresh air.
INGESTION: Contact a physician.
5. Fire Fighting Measures
FLAMMABLE PROPERTIES: Non-flammable.
Flash Point: None.
Method Used: Not applicable.
Flammable Limits (% by Volume in Air):
Lower: None.
Upper: None.
AUTO-IGNITION TEMPERATURE: Not applicable.
HAZARDOUS COMBUSTION PRODUCTS: None.
EXTINGUISHING MEDIA: Use agent appropriate for surrounding fire.
FIREFIGHTING INSTRUCTIONS: No special instructions.
6. Accidental Release Measures
SMALL/LARGE SPILL: Sweep up and collect for disposal.
7. Handling and Storage
HANDLING: No special precautions needed.
STORAGE: Keep container closed.
8. Exposure Controls/Personal Protection
ENGINEERING CONTROLS: Mechanical or local exhaust ventilation recommended.
36
RESPIRATORY PROTECTION: NIOSH/MSHA respirator if exposure limits exceeded.
SKIN AND HAND PROTECTION: Protective gloves recommended.
EYE AND FACE PROTECTION: Safety glasses with side shields.
OTHER PROTECTIVE EQUIPMENT: Not available.
9. Physical and Chemical Properties
APPEARANCE: Brown to black solid.
BOILING POINT: Not available.
FREEZE-MELT POINT: Not available.
VAPOR PRESSURE (mm): Not available.
VAPOR DENSITY (air = 1): Not available.
SOLUBILITY IN WATER: Insoluble.
SPECIFIC GRAVITY: 2.50
pH: Not available.
ODOR: None.
PERCENT VOLATILES: 0
EVAPORATION RATE (Butyl Acetate = 1): Not available.
10. Stability and Reactivity
CHEMICAL STABILITY: Stable.
INCOMPATIBILITY: Not available.
HAZARDOUS DECOMPOSITION PRODUCTS: None.
HAZARDOUS POLYMERIZATION: None.
11. Toxicological Information
None reported.
12. Ecological Information
Not available.
13. Disposal Consideration
Recycle or dispose of in accordance with federal, state & local regulations.
14. Transportation Information
U.S.A. DOT: Not regulated.
15. Regulatory Information
U.S. FEDERAL REGULATIONS:
TSCA STATUS:
On Toxic Substance Control Inventory.
CERCLA REPORTABLE QUANTITY: None.
SARA TITLE III:
Section 302 Extremely Hazardous Substances:
None.
Section 311/312 Hazardous Categories:
Acute, Chronic.
Section 313 Toxic Chemicals:
Aluminum Oxide
(Fibrous Forms only)
RCRA STATUS:
Not regulated.
CANADIAN REGULATIONS:
WHMIS: Not regulated.
37
16. Other Information
Hazard Index: (0 - 4, 4 = Extreme)
Health: 1
Fire: 0
Reactivity: 0
Prepared By:
Jason Whitt
Information herein is given in good faith as authoritative and valid; however, no warranty, expressed
or implied can be made.
Acetone
Acetone, NF
AX0126
Material Safety Data Sheet
Acetone, NF
1. Product and company identification
Product name
:
Acetone, NF
Product code
:
AX0126
Supplier
:
EMD Chemicals Inc.
480 S. Democrat Rd.
Gibbstown, NJ 08027
856-423-6300 Technical Service
Monday - Friday: 8:00 - 5:00 PM
Synonym
: Dimethyl Ketone; 2-Propanone
Material uses
: Other non-specified industry: Analytical reagent.
Validation date
:
02/24/2009
In case of emergency
:
800-424-9300 CHEMTREC (USA)
613-996-6666 CANUTEC (Canada)
24 Hours/Day: 7 Days/Week
2. Hazards identification
Emergency overview
: DANGER!
38
EXTREMELY FLAMMABLE LIQUID AND VAPOR.
HARMFUL IF INHALED OR SWALLOWED.
CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION.
VAPOR MAY CAUSE FLASH FIRE.
MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS: RESPIRATORY TRACT, SKIN, EYES,
CENTRAL NERVOUS SYSTEM.
Keep away from heat, sparks and flame. Do not breathe vapor or mist. Do not ingest. Avoid
contact with eyes,
skin and clothing. Use only with adequate ventilation. Keep container tightly closed and
sealed until ready for
use. Wash thoroughly after handling.
Physical state
OSHA/HCS status
: Liquid.
: This material is considered hazardous by the OSHA Hazard Communication Standard (29
CFR 1910.1200).
Routes of entry
: Dermal contact. Eye contact. Inhalation. Ingestion.
Potential acute health effects
Inhalation
: Toxic by inhalation. Irritating to respiratory system.
Ingestion
: Toxic if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage.
Skin
: Irritating to skin.
Eyes
: Irritating to eyes.
Potential chronic health effects
Carcinogenicity
: No known significant effects or critical hazards.
Mutagenicity
: No known significant effects or critical hazards.
Teratogenicity
: No known significant effects or critical hazards.
Developmental effects
: No known significant effects or critical hazards.
Fertility effects
: No known significant effects or critical hazards.
: May cause damage to the following organs: upper respiratory tract, skin, eyes, central
nervous system (CNS).
Target organs
Medical conditions aggravated : Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk
by
may be
over-exposure
aggravated by over-exposure to this product.
See toxicological information (section 11)
3.
Composition/information on ingredients
Name
CAS number
Acetone
67-64-1
% by weight
100
39
4.
First aid measures
Eye contact
:
Skin contact
:
Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical
attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing
contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly
before reuse. Get
medical attention immediately.
Inhalation: Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest
occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing
such as a collar, tie, belt or waistband. Get medical attention immediately.
Ingestion: Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. Get medical attention immediately.
5.
Fire-fighting measures
: Extremely flammable liquid. In a fire or if heated, a pressure increase will occur and the
Flammability of the product container may burst,
with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread
along the ground.
Vapors may accumulate in low or confined areas or travel a considerable distance to a
source of ignition and
flash back. Runoff to sewer may create fire or explosion hazard.
:
Use dry chemical,
Extinguishing media
, water spray (fog) or foam.
CO
: Do not use water2
Not suitable
jet.
: Promptly isolate the scene by removing all persons from the vicinity of the incident if
Special exposure hazards
there is a fire. No action
shall be taken involving any personal risk or without suitable training. Move containers
from fire area if this
can be done without risk. Use water spray to keep fire-exposed containers cool.
Hazardous
decomposition
produc
ts
thermal
: Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
Special protective equipment: Fire-fighters should wear appropriate protective equipment and self-contained breathing
for
apparatus (SCBA)
fire-fighters
with a full face-piece operated in positive pressure mode.
Special remarks on fire: Dangerous fire and explosion risk. Vapor may travel a considerable distance to source of
hazards
ignition and flash
back.
6.
Accidental release measures
: No action shall be taken involving any personal risk or without suitable training. Evacuate
Personal precautions
surrounding areas.
40
Environmental
precautions
Methods for cleaning up
Spill
7.
Keep unnecessary and unprotected personnel from entering. Do not touch or walk through
spilled material.
Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe
vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate.
Put on appropriate
personal protective equipment (see section 8).
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers. Inform
the relevant authorities if the product has caused environmental pollution (sewers,
waterways, soil or air).
: Stop leak if without risk. Move containers from spill area. Approach release from upwind.
Prevent entry into
sewers, water courses, basements or confined areas. Contain and collect spillage with noncombustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal
according to local regulations (see section 13). Use spark-proof tools and explosion-proof
equipment. Dispose
of via a licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the
spilled product. Note: see section 1 for emergency contact information and section 13 for
waste disposal.
Dilute with water and mop up if water-soluble or absorb with an inert dry material and place
in an appropriate
waste disposal container.
Handling and storage
Handling: Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not
enter storage areas and confined spaces unless adequately ventilated. Keep in the original
container or an approved alternative made from a compatible material, kept tightly closed
when not in use. Store and use away from heat, sparks, open flame or any other ignition
source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment.
Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid
fire or explosion, dissipate static electricity during transfer by grounding and bonding
containers and equipment before transferring material. Empty containers retain product
residue and can be hazardous. Do not reuse container.
Storage: Store in accordance with local regulations. Store in a segregated and approved area. Store in original
container, protected from direct sunlight. Eliminate all ignition sources. Separate from
oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers
that have been opened must be carefully resealed and kept upright to prevent leakage.
8.
Exposure controls/personal protection
Ingredient
Exposure limits
Acetone
ACGIH (United States, 1996).
STEL: 1782 mg/m³ 15 minute(s).
TWA: 1188 mg/m³ 8 hour(s).
41
OSHA (United States, 1989).
STEL: 2400 mg/m³ 15 minute(s).
TWA: 1800 mg/m³ 8 hour(s).
ACGIH TLV (United States, 1/2008).
TWA: 500 ppm 8 hour(s).
TWA: 1188 mg/m³ 8 hour(s).
STEL: 750 ppm 15 minute(s).
STEL: 1782 mg/m³ 15 minute(s).
OSHA PEL 1989 (United States, 3/1989).
TWA: 750 ppm 8 hour(s).
TWA: 1800 mg/m³ 8 hour(s).
STEL: 1000 ppm 15 minute(s).
STEL: 2400 mg/m³ 15 minute(s).
NIOSH REL (United States, 6/2008).
TWA: 250 ppm 10 hour(s).
TWA: 590 mg/m³ 10 hour(s).
OSHA PEL (United States, 11/2006).
TWA: 1000 ppm 8 hour(s).
TWA: 2400 mg/m³ 8 hour(s).
Consult local authorities for acceptable exposure limits.
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
Engineering measures
other engineering
controls to keep worker exposure to airborne contaminants below any recommended or
statutory limits. The
engineering controls also need to keep gas, vapor or dust concentrations below any lower
explosive limits.
Use explosion-proof ventilation equipment.
: Wash hands, forearms and face thoroughly after handling chemical products, before
Hygiene measures
eating, smoking and
using the lavatory and at the end of the working period. Appropriate techniques should be
used to remove
potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure
that eyewash stations
and safety showers are close to the workstation location.
Personal protection
: Use a properly fitted, air-purifying or air-fed respirator complying with an approved
Respiratory
standard if a risk
assessment indicates this is necessary. Respirator selection must be based on known or
anticipated exposure
levels, the hazards of the product and the safe working limits of the selected respirator.
: Chemical-resistant, impervious gloves complying with an approved standard should be
Hands
worn at all times when
handling chemical products if a risk assessment indicates this is necessary. Recommended:
butyl rubber
: Safety eyewear complying with an approved standard should be used when a risk
Eyes
assessment indicates this is
necessary to avoid exposure to liquid splashes, mists or dusts. Recommended: splash
goggles
: Personal protective equipment for the body should be selected based on the task being
Skin
performed and the risks
involved and should be approved by a specialist before handling this product.
42
Environmental
controls
Recommended: lab coat
exposure: Emissions from ventilation or work process equipment should be checked to ensure they
comply with the
requirements of environmental protection legislation. In some cases, fume scrubbers,
filters or engineering
modifications to the process equipment will be necessary to reduce emissions to
acceptable levels.
9.
Physical and chemical properties
Physical state
:
Liquid.
Flash point
:
Closed cup: -18.15°C (-0.67°F)
Auto-ignition
: 464.85°C (868.7°F)
temperature
Flammable limits
:
Lower: 2.6%
Upper: 12.8%
Color
:
Colorless.
Odor
:
Pungent.
Molecular weight
:
58.09 g/mole
Molecular formula
: C3-H6-O
pH
: Not available.
Boiling/condensation
:
56.1°C (133°F)
point
Melting/freezing point
: -94.2°C (-137.6°F)
Critical temperature
:
234.9°C (454.8°F)
Relative density
:
0.791
Vapor pressure
:
Not available.
Vapor density
: 2 [Air = 1]
Odor threshold
:
100 ppm
Evaporation rate
: 6.06 compared with(n-BUTYL ACETATE=1)
Soluble in the following materials:
Solubility
:
water
10 . Stability and reactivity
Chemical stability
: The product is stable.
Possibility
of
hazardous
: Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Hazardous polymerization
: Under normal conditions of storage and use, hazardous polymerization will not occur.
: Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
Conditions to avoid
braze, solder, drill, grind
or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in
low or confined areas.
Do not swallow.
: Extremely reactive or incompatible with the following materials: oxidizing materials and
Materials to avoid
acids.
Hazardous
decomposition: Under normal conditions of storage and use, hazardous decomposition products should
products
not be produced.
: Extremely flammable in the presence of the following materials or conditions: open
Conditions of reactivity
flames, sparks and static
discharge, heat, shocks and mechanical impacts and oxidizing materials.
Dangerous fire and explosion risk. Vapor may travel a considerable distance to source of
ignition and flash back.
43
Extremely explosive in the presence of the following materials or conditions: open flames,
sparks and static discharge, heat, shocks and mechanical impacts and oxidizing materials.
11 . Toxicological information
Acute toxicity
Product/ingredient name
Acetone
Test Route
LD50 Intravenous
LD50 Oral
LD50 Oral
LDLo Oral
LDLo Dermal
LDLo Intraperitoneal
LDLo Oral
TDLo Oral
LC50 Inhalation Vapor
Species
Rat
Rabbit
Rat
Human
Rabbit
Rat
Dog
Rat
Rat
Result
5500 mg/kg
5340 mg/kg
5800 mg/kg
714 mg/kg
20 mL/kg
500 mg/kg
8000 mg/kg
5 mL/kg
50100 mg/m3
Carcinogenicity
Classification
Product/ingredient name ACGIH IARC
EPA
Acetone A4
No known significant effects or critical hazards.
Mutagenicity
No known significant effects or critical hazards.
Teratogenicity
No known significant effects or critical hazards.
12 . Ecological information
Aquatic ecotoxicity
Product/ingredient name
Acetone
NIOSH NTP
OSHA
-
Result
Acute EC50 13500 mg/L
Acute EC50 8990 mg/L
Acute EC50 23.5 mg/L
Acute LC50 5540 mg/L
Acute LC50 >100 mg/L
Acute LC50 >100 mg/L
Acute LC50 6900 mg/L Fresh
water
Acute LC50 5.54 to 6.33 ml/L
Fresh water
Acute LC50 8300000 ug/L Fresh
water
Species
Exposure
Daphnia
48 hours
Fish
48 hours
Daphnia
48 hours
Fish
96 hours
Daphnia
96 hours
Fish
96 hours
Daphnia - Water flea - Daphnia
48 hours
magna
Fish - Rainbow trout,donaldson trout 96 hours
- Oncorhynchus mykiss - 1 g
Fish - Bluegill - Lepomis
96 hours
macrochirus - 5.3 to 7.2 cm - 3.5 to
3.9 g
Acute LC50 8120000 to
Fish - Fathead minnow - Pimephales 96 hours
8760000 ug/L Fresh water
promelas - 33 days - 22.6 mm 0.159 g
Acute LC50 8098000 to
Daphnia - Water flea - Ceriodaphnia 48 hours
8640000 ug/L Fresh water
dubia - Neonate - <12 hours
Acute LC50 7810000 ug/L Fresh Daphnia - Water flea - Daphnia
48 hours
water
cucullata - 11 days
44
Acute LC50 7550000 ug/L Fresh
water
Acute LC50 7460000 ug/L Fresh
water
Acute LC50 7280000 to
7880000 ug/L Fresh water
Crustaceans - Aquatic sowbug Asellus aquaticus
Daphnia - Water flea - Daphnia
cucullata - 11 days
Fish - Fathead minnow - Pimephales
promelas - 28 days - 19.2 mm 0.076 g
Acute LC50 6210000 to
Fish - Fathead minnow - Pimephales
7030000 ug/L Fresh water
promelas - 32 days - 18 mm - 0.087
g
Acute LC50 >100000 ug/L Fresh Fish - Fathead minnow - Pimephales
water
promelas - Juvenile (Fledgling,
Hatchling, Weanling) - 0.2 to 0.5 g
Acute LC50 13300000 ug/L
Daphnia - Water flea - Daphnia
Fresh water
magna - <24 hours
Acute LC50 10000 ug/L Fresh
Daphnia - Water flea - Daphnia
water
magna
Acute LC50 12600000 ug/L
Daphnia - Water flea - Daphnia
Fresh water
magna - <24 hours
Acute LC50 12100000 ug/L
Daphnia - Water flea - Daphnia
Fresh water
magna - <24 hours
Acute LC50 11000000 to
Fish - Bleak - Alburnus alburnus - 8
11300000 ug/L Marine water
Acute LC50 10700000 ug/L
Fresh water
Acute LC50 9218000 to
14400000 ug/L Fresh water
Acute LC50 9100000 to
9482000 ug/L Fresh water
Environmental effects
Other adverse effects
cm
Fish - Fathead minnow - Pimephales
promelas - 25 mm
Daphnia - Water flea - Daphnia
magna - Neonate - <12 hours
Fish - Fathead minnow - Pimephales
promelas - 2 to 3 months - 19 mm 0.06 g
Acute LC50 8800000 ug/L Fresh
Daphnia - Water flea - Daphnia
water
pulex - <24 hours
: No known significant effects or
critical hazards.
: No known significant effects or
critical hazards.
48 hours
48 hours
96 hours
96 hours
96 hours
48 hours
48 hours
48 hours
48 hours
96 hours
96 hours
48 hours
96 hours
48 hours
13. Disposal considerations
The information presented only applies to the material as supplied. The identification based on characteristic(s) or
listing may not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste
generator to determine the toxicity and physical properties of the material generated to determine the proper
waste identification and disposal methods in compliance with applicable regulations. Disposal should be in
accordance with applicable regional, national and local laws and regulations.
14. Transport information
Regulatory
UN number Proper shipping name Classes
information
DOT Classification
UN1090
ACETONE
3
PG* Label
II
Additional information
Reportable quantity
5000 lbs. (2270 kg)
45
PG* : Packing group
15. Regulatory information
United States
HCS Classification
: Flammable liquid
Toxic material
Irritating material
Target organ effects
U.S. Federal regulations : TSCA 4(a) final test rules: Acetone
United States inventory (TSCA 8b):
This material is listed or exempted.
TSCA 12(b) one-time export: Acetone
TSCA (Toxic Substance Control Act): This product is listed on the TSCA Inventory.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: Acetone
SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
Acetone : Fire hazard,
Immediate (acute) health hazard, Delayed (chronic) health hazard
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean Air Act (CAA) 112 accidental release prevention: No products were found.
Clean Air Act (CAA) 112 regulated flammable substances: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
DEA
List
I
Chemicals
:
(Precursor
Chemicals)
DEA
List
II
Chemicals
:
(Essential
Chemicals)
Massachusetts Substances
:
New
Jersey
Hazardous
:
Substances
New York Acutely Hazardous :
Substances
Pennsylvania RTK Hazardous :
Substances
Canada
WHMIS (Canada)
:
Not listed
Listed
This material is listed.
This material is listed.
This material is listed.
This material is listed.
Class B-2: Flammable liquid
Class D-2B: Material causing other toxic effects (Toxic).
Canadian lists
: CEPA Toxic substances: This material is listed.
Canadian ARET: This material is not listed.
Canadian NPRI: This material is listed.
Alberta Designated Substances: This material is not listed.
Ontario Designated Substances: This material is not listed.
Quebec Designated Substances: This material is not listed.
CEPA DSL / CEPA NDSL
: This material is listed or exempted.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and
the MSDS contains all the information required by the Controlled Products Regulations.
46
EU regulations
Hazard symbol or : symbols
Risk phrases
Safety phrases
: R11- Highly flammable.
R36- Irritating to eyes.
: S2- Keep out of the reach of children.
S9- Keep container in a well-ventilated place.
S16- Keep away from sources of ignition - No smoking.
S26- In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
International regulations
International lists
: Australia inventory (AICS): This material is listed or exempted.
China inventory (IECSC): This material is listed or exempted.
Japan inventory (ENCS): This material is listed or exempted.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): This material is listed or exempted.
New Zealand Inventory of Chemicals (NZIoC): This material is listed or exempted.
Philippines inventory (PICCS): This material is listed or exempted.
16. Other information
National Fire Protection Association : (U.S.A.)
Health 1 3 0 Flammability
Special Instability
Notice to reader
The statements contained herein are based upon technical data that EMD Chemicals Inc. believes to be reliable,
are offered for information purposes only and as a guide to the appropriate precautionary and emergency
handling of the material by a properly trained person having the necessary technical skills. Users should consider
these data only as a supplement to other information gathered by them and must make independent
determinations of suitability and completeness of information from all sources to assure proper use, storage
and disposal of these materials and the safety and health of employees and customers and the protection of the
environment. EMD CHEMICALS INC. MAKES NO
REPRESENTATION OR WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING MERCHANTABILITY OR
FITNESS FOR A PARTICULAR USE, WITH RESPECT TO THE INFORMATION HEREIN OR THE PRODUCT TO WHICH
THE INFORMATION
REFERS
Acetylene
Material Safety Data Sheet
47
Acetylene
Section 1. Chemical product and company identification
Product name
Supplier
: Acetylene
: AIRGAS INC., on behalf of its subsidiaries
259 North Radnor-Chester Road
Suite 100
Radnor, PA 19087-5283
1-610-687-5253
Product use
Synonym
MSDS #
Date of
Preparation/Revision
In case of emergency
: Synthetic/Analytical chemistry.
: acetylen; acetylene ; ethine; ethyne; narcylen
: 001001
: 5/11/2011.
: 1-866-734-3438
Section 2. Hazards identification
Physical state
: Gas.
Emergency overview
: WARNING!
FLAMMABLE GAS.
MAY CAUSE FLASH FIRE.
MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.
CONTENTS UNDER PRESSURE.
Keep away from heat, sparks and flame. Do not puncture or incinerate container. May
cause target organ damage, based on animal data. Use only with adequate ventilation.
Keep container closed.
Target organs
Routes of entry
Potential acute health effects
Contact with rapidly expanding gases can cause frostbite.
: May cause damage to the following organs: lungs, upper respiratory tract, central
nervous system (CNS).
: Inhalation
Eyes
Skin
: Contact with rapidly expanding gas may cause burns or frostbite.
: Contact with rapidly expanding gas may cause burns or frostbite.
Inhalation
: Acts as a simple asphyxiant.
Ingestion
Potential chronic health effects
Chronic effects
Target organs
: Ingestion is not a normal route of exposure for gases
Medical conditions
aggravated by overexposure
: Pre-existing disorders involving any target organs mentioned in this MSDS as being at
risk may be aggravated by over-exposure to this product.
: May cause target organ damage, based on animal data.
: May cause damage to the following organs: lungs, upper respiratory tract, central
nervous system (CNS).
See toxicological information (Section 11)
48
Section 3. Composition, Information on Ingredients
Name
Acetylene
CAS number
74-86-2
% Volume
100
Exposure limits
NIOSH REL (United States, 6/2009).
CEIL: 2662 mg/m³
CEIL: 2500 ppm
Section 4. First aid measures
No action shall be taken involving any personal risk or without suitable training.If it is suspected that fumes are still
present, the rescuer should wear an appropriate mask or self-contained breathing apparatus.It may be dangerous
to the person providing aid to give mouth-to-mouth resuscitation.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
attention immediately.
Skin contact
: In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. To avoid the risk of static discharges
and gas ignition, soak contaminated clothing thoroughly with water before removing it.
Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical
attention immediately.
Frostbite
: Try to warm up the frozen tissues and seek medical attention.
Inhalation
: Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.
Ingestion
: As this product is a gas, refer to the inhalation section.
Section 5. Fire-fighting measures.
Flammability of the product
: Flammable.
Auto-ignition temperature
: 305°C (581°F)
Flash point
: Closed cup: -18.15°C (-0.7°F).
Flammable limits : Lower: 2.5% Upper: 100%
Products of combustion : Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
Fire hazards in the presence : of various substances
Extremely flammable in the presence of the following materials or conditions: open flames, sparks and static
discharge, heat and oxidizing materials.
Fire-fighting media and instructions: In case of fire, use water spray (fog), foam or dry chemical.
In case of fire, allow gas to burn if flow cannot be shut off immediately. Apply water from a safe distance to cool
container and protect surrounding area. If involved in fire, shut off flow immediately if it can be done without risk.
Contains gas under pressure Flammable gas. In a fire or if heated, a pressure increase will occur and the container
may burst, with the risk of a subsequent explosion
Special protective
: Fire-fighters should wear appropriate protective equipment and self-contained
breathing
49
equipment for fire-fighters
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Section 6. Accidental release measures
Personal precautions
: Immediately contact emergency personnel. Keep unnecessary personnel away. Use
suitable protective equipment (section 8). Shut off gas supply if this can be done safely. Isolate area until gas has
dispersed.
Environmental precautions
waterways, drains and sewers.
: Avoid dispersal of spilled material and runoff and contact with soil,
Methods for cleaning up : Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof
tools and explosion-proof equipment. Note: see section 1 for emergency contact information and section 13 for
waste disposal.
Section 7. Handling and storage
Handling
: Use only with adequate ventilation. Use explosion-proof electrical (ventilating, lighting
and material handling) equipment. High pressure gas. Do not puncture or incinerate
container. Use equipment rated for cylinder pressure. Close valve after each use and
when empty. Keep container closed. Keep away from heat, sparks and flame. To avoid
fire, eliminate ignition sources. Protect cylinders from physical damage; do not drag, roll,
slide, or drop. Use a suitable hand truck for cylinder movement.
Storage : Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed
until ready for use. Avoid all possible sources of ignition (spark or flame). Segregate
from oxidizing materials. Cylinders should be stored upright, with valve protection cap in
place, and firmly secured to prevent falling or being knocked over. Cylinder temperatures
should not exceed 52 °C (125 °F).
Section 8. Exposure controls/personal protection
Engineering controls
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation
or other engineering controls to keep worker exposure to airborne contaminants below any recommended or
statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower
explosive limits. Use explosion-proof ventilation equipment.
Personal protection
Eyes
: Safety eyewear complying with an approved standard should be used when a risk assessment indicates
this is necessary to avoid exposure to liquid splashes, mists or dusts.
Skin
: Personal protective equipment for the body should be selected based on the task being performed and
the risks involved and should be approved by a specialist before handling this product.
Respiratory
: Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if
a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure
levels, the hazards of the product and the safe working limits of the selected respirator.
The applicable standards are (US) 29 CFR 1910.134 and (Canada) Z94.4-93
Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times
when handling chemical products if a risk assessment indicates this is necessary.
50
Personal protection in case of a large spill : Self-contained breathing apparatus (SCBA) should be used to avoid
inhalation of the product.
Product name
Ethyne NIOSH REL (United States, 6/2009).
CEIL: 2662 mg/m³
CEIL: 2500 ppm
Consult local authorities for acceptable exposure limits.
Section 9. Physical and chemical properties
Molecular weight
:
Molecular formula
Melting/freezing point
:
C2-H2
: Sublimation temperature: -81.8°C (-115.2 to °F)
Critical temperature
Vapor pressure
Vapor density
: 35.3°C (95.5°F)
:
635 (psig)
:
0.907 (Air = 1)
3
Specific Volume (ft /lb)
3
Gas Density (lb/ft )
:
:
26.04 g/mole
14.7058
0.0691 (-80°C / -112 to °F)
Section 10. Stability and reactivity
Stability and reactivity
: The product is stable.
Incompatibility with various : Extremely reactive or incompatible with the following materials: oxidizing materials.
substances
Hazardous decomposition
products
: Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
Hazardous polymerization
: Under normal conditions of storage and use, hazardous polymerization will not occur.
Section 11. Toxicological information
Toxicity data
Chronic effects on humans
: May cause damage to the following organs: lungs, upper respiratory tract, central
nervous system (CNS).
Other toxic effects on
humans
: No specific information is available in our database regarding the other toxic effects of
this material to humans.
Specific effects
Carcinogenic effects
: No known significant effects or critical hazards.
Mutagenic effects
: No known significant effects or critical hazards.
Reproduction toxicity
: No known significant effects or critical hazards.
Section 12. Ecological information
Aquatic ecotoxicity
Not available.
Products of degradation : Products of degradation: carbon oxides (CO, CO2) and water.
51
Environmental fate
Environmental hazards
Toxicity to the environment
: Not available.
: This product shows a low bioaccumulation potential.
: Not available.
Section 13. Disposal considerations
Product removed from the cylinder must be disposed of in accordance with appropriate Federal, State, local
regulation. Return cylinders with residual product to Airgas, Inc.Do not dispose of locally.
Section 14. Transport information
Regulatory
information
UN number
Proper shipping
name
Class
Packing group
DOT Classification
UN1001
ACETYLENE,
DISSOLVED
2.1
Not applicable (gas).
Label
Additional
information
Limited
quantity
Yes.
Packaging
instruction
Passenger
aircraft
Quantity
limitation:
Forbidden.
Cargo aircraft
Quantity
limitation:
15 kg
TDG Classification
UN1001
ACETYLENE,
DISSOLVED
2.1
Not applicable (gas).
Explosive
Limit and
Limited
Quantity
Index
0
Passenger
Carrying Ship
Index
75
Passenger
Carrying
Road or Rail
Index
Forbidden
Special
52
provisions
38, 42
Mexico
Classification
UN1001
ACETYLENE,
DISSOLVED
2.1
Not applicable (gas).
-
“Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the
product.”
Section 15. Regulatory information
United
States
U.S. Federal regulation :
TSCA 8(a) IUR: Partial exemption
United States inventory (TSCA 8b): This material is listed or exempted.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: Ethyne
SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
Ethyne: Fire hazard, reactive, Sudden release of pressure, Immediate (acute)
health hazard
Clean Air Act (CAA) 112 accidental release prevention - Flammable Substances:
Acetylene
Clean Air Act (CAA) 112 regulated flammable substances: Ethyne
State regulations :
Connecticut Carcinogen Reporting: This material is not listed.
Connecticut Hazardous Material Survey: This material is not listed.
Florida substances: This material is not listed.
53
Illinois Chemical Safety Act: Massachusetts Spill: This material is not listed.
This material is not listed.
Massachusetts Substances: This material is listed.
Illinois
Toxic
Substances Michigan Critical Material: This material is not listed.
Disclosure to Employee Act: Minnesota Hazardous Substances: This material is not listed.
This material is not listed.
New Jersey Hazardous Substances: This material is listed.
Louisiana
Reporting:
This New Jersey Spill: This material is not listed.
material is not listed.
New Jersey Toxic Catastrophe Prevention Act: This material is not listed.
Louisiana Spill: This material is New York Acutely Hazardous Substances: This material is not listed.
not listed.
New York Toxic Chemical Release Reporting: This material is not listed.
Pennsylvania RTK Hazardous Substances: This material is
listed.
Rhode Island Hazardous Substances: This material is not listed.
Canada
WHMIS (Canada)
: Class A: Compressed gas.
Class B-1: Flammable gas.
Class F: Dangerously reactive material.
CEPA Toxic substances: This material is not listed.
Canadian ARET: This material is not listed.
Canadian NPRI: This material is listed.
Alberta Designated Substances: This material is not listed.
Ontario Designated Substances: This material is not listed.
Quebec Designated Substances: This material is not listed.
Section 16. Other information
United States
Label requirements
: FLAMMABLE GAS.
MAY CAUSE FLASH FIRE.
MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.
CONTENTS UNDER PRESSURE.
Canada
Label requirements
: Class A: Compressed gas.
Class B-1: Flammable gas.
Class F: Dangerously reactive material.
Hazardous Material
Information System (U.S.A.)
:
National Fire Protection
Association (U.S.A.)
Health
*
1
Flammability
4
Physical hazards
2
:
4
Flammability
54
0 3
Health
Instability
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
55
Acid Flux Cored Solder
Material Safety Data Sheet
acc. to ISO/DIS 11014
1 Identification of substance
Product details
Trade name: ACID CORE
Application of the substance / the preparation: Flux cored solder
Manufacturer/Supplier:
Kester
800 W. Thorndale Ave.
Tel.(847)
297-1600
Fax.(847)
390-9338
Itasca, IL 60143
Information
department:
Emergency
information:
CHEMTREC
24-Hour
Emergency
Response
Telephone
Number
:
(800)
424-9300
CHEMTREC 24-Hour Emergency Response (Outside US & Canada)Telephone Number : (703) 527-3887
2 Hazards identification
WHMIS Hazard Symbols
<
Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of international guidelines. Harmful by inhalation,
in contact with skin and if swallowed.
Danger of cumulative effects.
Limited evidence of a carcinogenic effect. May cause sensitisation by skin contact.
Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and
if swallowed.
56
Possible risk of impaired fertility. Possible risk of irreversible effects.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Contains lead.
Should not be used on surfaces liable to be chewed or sucked by children.
NFPA ratings (scale 0 - 4)
Health = 3
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 - 4)
Health = 3
Fire = 1
Reactivity = 0
GHS label elements
Trade name: ACID CORE
~Warning
3.5/2 - Suspected of causing genetic defects. 3.6/2 - Suspected of causing cancer.
3.7/2 - Suspected of damaging fertility or the unborn child.
3.9/2 - May cause damage to organs through prolonged or repeated exposure.
~Warning
3.1/4 - Harmful if swallowed.
3.1/4 - Harmful in contact with skin. 3.1/4 - Harmful if inhaled.
3.4/1 - May cause an allergic skin reaction.
4.1/3 - Harmful to aquatic life with long lasting effects.
Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood. Do not breathe
dust/fume/gas/mist/vapours/spray.
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash thoroughly after handling.
Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area.
Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as
required.
Response:
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of
soap and water.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF exposed or concerned:
Get medical advice/attention.
Call a POISON CENTER or doctor/physician if you feel unwell. Get medical advice/attention if you feel unwell.
Specific treatment (see label). Specific measures (see label). Rinse mouth.
If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse.
57
Storage:
Store locked up.
Disposal:
Dispose of contents/container in accordance with local/regional/national/international regulations.
Trade name: ACID CORE
3 Composition/Data on components
Chemical characterization
Description: Mixture of the substances listed below with nonhazardous additions.
Dangerous
components:
7440-31-5
7439-92-1
tin
lead
Danger:
0-100%
0-100%
~[1] 3.1.O/3, 3.1.I/4
Warning: ~
7440-50-8
7440-36-0
7440-69-9
7440-22-4
7440-66-6
7646-85-7
3.7/2
copper
antimony
bismuth
silver
zinc
zinc chloride
Danger:
3.2/1B
142-04-1
0-100%
0-100%
0-100%
0-100%
≤ 2.5%
≤ 2.5%
~[1]
3.1.O/3;
~
Warning: ~ 4.1.C/1
anilinium chloride
≤ 2.5%
~[1] 3.1.O/3, 3.1.D/3, 3.1.I/3, 3.4.S/1; ~ 3.9/1,
3.5/2, 3.6/2; ~ 3.3/1
Warning: ~ 4.1.A/1
Danger:
Additional informatio:
Composition and weight percent of solder all ys varies widely
and can be determined by product label. Flux in core is typically
1-3% by weight.
4 First aid measures
General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact: Rinse opened eye for several minutes under running water. After swallowing: Seek immediate 58
medical advice.
5 Firefighting measures
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards caused by the material, its products of combustion or resulting gases:
Melted solder above 1000°F will liberate toxic lead and/or antimony fumes. In case of fire, the following can be
released:
Carbon monoxide (CO) Carbon dioxide (CO2)
Nitrogen oxides (NOx)
Protective equipment: Wear self-contained respiratory protective device.
6 Accidental release measures
Person-related safety precautions:
Ensure adequate ventilation Wear protective clothing.
Measures for environmental protection: Do not allow product to reach sewage system or any water course.
Measures for cleaning/collecting:
Melted solder will solidify on cooling and can be scraped up. Use caution to avoid breathing fumes if a gas torch is
used to cut up large pieces.
7 Handling and storage
Handling:
Information for safe handling: Ensure good ventilation/exhaustion at the workplace.
Information about protection against explosions and fires: Keep respiratory protective device available.
Storage:
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: Store in dry conditions.
8 Exposure controls and personal protection
Additional information about design of technical systems: No further data; see item 7.
Components with limit values that require monitoring at the workplace:
7440-31-5 tin
PEL
2 mg/m³
Metal
REL
2 mg/m³
Tin, Metal
TLV
2 mg/m³
PEL
0.1*;1** mg/m³
7440-50-8 copper
*fume **dusts & mists
REL
0.1*;1** mg/m³
*Copper fume, as Cu **Copper dusts & mists, as Cu
59
0.2*, 1** mg/m³
TLV
*fume; ** dusts&mists, as Cu
PEL
1 mg/m³
REL
Short-term value: 2 mg/m³
7646-85-7 zinc chloride
Long-term value: 1 mg/m³
TLV
Short-term value: 2 mg/m³
Long-term value: 1 mg/m³
fume
7439-92-1 lead
PEL
0.05* mg/m³
as Pb
REL
<0.1* mg/m³
as Pb; *Blood Pb <0.06 mg/100 g whole blood
0.05 mg/m³
TLV
as Pb; BEI
PEL
0.5 mg/m³
REL
0.5 mg/m³
7440-36-0 antimony
as Sb
TLV
0.5 mg/m³
as Sb
7440-22-4 silver
PEL
0.01 mg/m³
REL
0.01 mg/m³
TLV
0.1 mg/m³
Additional information:
PEL = Permissible Exposure Limit (OSHA)
REL= Recommended Exposure Limit (NIOSH)
TLV= Threshold Limit Value (ACGIH)
OSHA= Occupational Safety and Health Administration
ACGIH= American Conference of Governmental Industrial Hygienists
NIOSH= National Institute for Occupational Safety and Health
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Breathing equipment:
When ventilation is not sufficient to remove fumes from the breathing zone, a safety approved respirator or
selfcontained
breathing apparatus should be worn.
Protection of hands:
Protective gloves
60
Trade name: ACID CORE
Material of gloves:
Nitrile rubber, NBR
Natural rubber, NR
Penetration time of glove material:
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
Safety glasses
9 Physical and chemical properties
General Information
Form:
Color:
Odor:
Solid
Silver grey
Mild
Change in condition
Melting point/Melting range: > 100°C (> 212°F)
Boiling point/Boiling range: Undetermined.
Flash point:
Danger of explosion:
Density at 20°C (68°F):
Solubility in / Miscibility with
Water:
Not applicable.
Product does not present an explosion hazard.
> 7 g/cm³
Not miscible or difficult to mix.
10 Stability and reactivity
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Materials to be avoided: Strong acids, strong oxidizers.
Dangerous reactions No dangerous reactions known.
Dangerous products of decomposition:
Carbon monoxide and carbon dioxide
Nitrogen oxides
11 Toxicological information
Acute toxicity:
LD/LC50 values that are relevant for classification:
7646-85-7 zinc chloride
Oral
LD50
350 mg/kg (rat)
142-04-1 anilinium chloride
Oral
LD50
840 mg/kg (rat)
7440-36-0 antimony
Oral
LD50
7000 mg/kg (rat)
7440-69-9 bismuth
Oral
LD50
5000 mg/kg (rat)
Primary irritant effect:
on the skin: Caustic effect on skin and mucous membranes.
on the eye: Strong irritant with the danger of severe eye injury.
61
through inhalation: Flux fumes during soldering may cause irritation and damage of mucous membranes and
respiratory system.
through ingestion: May be harmful if swallowed.
Sensitization: No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Aniline is a blood toxin, causing hemoglobin to convert to meet hemoglobin, resulting in cyanosis. Prolonged or
repeated contact may result in decreased appetite, anemia, weight loss, nervous system affects, and kidney,
liver, and bone marrow damage.
12 Ecological information
General notes:
Do not allow product to reach ground water, water course or sewage system.
Harmful to aquatic organisms
13 Disposal considerations
Product:
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
Trade name: ACID CORE
14 Transport information
DOT regulations:
Hazard class: Not regulated.
Land transport ADR/RID (cross-border):
ADR/RID class: Not regulated.
Maritime transport IMDG:
IMDG Class: Not regulated.
Marine pollutant: No
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: Not regulated.
UN "Model Regulation": Environmental hazards: Marine pollutant
Transport/Additional information: Not dangerous according to the above specifications.
15 Regulations
USA The following information relates to product regulation specific to the USA.
SARA (Superfund Amendments and Reauthorization Act)
Section 355 (extremely hazardous substances):
None of the ingredient is listed.
Section 313 (Specific toxic chemical listings):
7439-92-1
lead
7440-36-0
antimony
7440-50-8
copper
7440-22-4
silver
7646-85-7
zinc chloride
62
TSCA (Toxic Substances Control Act):
All ingredients are listed or exempt from listing.
California Proposition 65
Chemicals known to cause cancer:
WARNING: This product contains a chemical(s) known to the State of California to cause cancer.
Chemicals known to cause reproductive toxicity:
WARNING: This product contains a chemical(s) known to the State of California to cause birth defects and/or
other reproductive harm.
Carcinogenicity categories
EPA (Environmental Protection Agency)
7439-92-1
lead
IARC (International Agency for Research on Cancer)
7439-92-1
lead
B2
2B
NTP (National Toxicology Program)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
CANADA: The following information relates to product regulation specific to Canada.
Workplace Hazardous Materials Identification (WHMIS):
This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products
Regulation (CPR) and the MSDS contains all of the information required by the CPR.
EUROPEAN UNION
The following information relates to product regulation specific to the directives of the European Union.
Risk phrases:
Harmful by inhalation, in contact with skin and if swallowed.
Danger of cumulative effects.
Limited evidence of a carcinogenic effect.
May cause sensitization by skin contact.
Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and
if swallowed.
Possible risk of impaired fertility.
Possible risk of irreversible effects.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety phrases:
Keep out of the reach of children.
Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point.
Wear suitable protective clothing and gloves.
If swallowed, seek medical advice immediately and show this container or label.
Special labeling of certain preparations:
Contains lead. Should not be used on surfaces liable to be chewed or sucked by children.
63
16 Other information
The information contained herein is based on data considered accurate and is offered solely for information,
consideration and investigation. Kester extends no warranties, makes no representations and assumes no
responsibility as to the accuracy, completeness or suitability of this data for any purchaser's use. The data on this
Material Safety Data Sheet relates only to this product and does not relate to use with any other material or in
any process. All chemical products should be used only by, or under the direction of, technically qualified
personnel who are aware of the hazards involved and the necessity for reasonable care in handling. Hazard
communication
regulations require that employees must be trained on how to use a Material Safety Data Sheet as a source for
hazard information.
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises Dangereuses par Route (European Agreement
concerning the International Carriage of
Dangerous Goods by Road)
RID: Reglement internationale concernent le transport des merchandises dangereuses par chemin de fer
(Regulations Concerning the International
Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
Air Tool Lubricant
MSDS No.: 139
Revision No.: 008
Revision Date: 01/17/07
Page: 1 of 2
MATERIAL SAFETY DATA SHEET
Product name:
Air Tool Lubricant
Description:
Petroleum based hydraulic oil
Supplier:
Hilti, Inc. P.O. Box 21148, Tulsa, OK 74121; phone 1800 879 8000
Emergency # (Chem-Trec.):
1 800 424 9300 (USA, PR, Virgin Islands, Canada); 001 703 527 3887 (other countries)
Hazardous
Ingredients: Petroleum oils,
hydrotreated, spent
COMPOSITION / EXPOSURE LIMITS
CAS Number:
TLV:
3
5.0 mg/m
64742-58-1
*
PEL:
3
5.0 mg/m
*
STEL:
64
NE
Petroleum oils, clay treated
5.0 mg/m
64742-62-7
3
*
5.0 mg/m
3
*
NE
Abbreviations: PEL = OSHA Permissible Exposure Limit. TLV = ACGIH Threshold Limit Value. These are 8
hour time-weighted averages unless otherwise indicated by "C" (Ceiling) or "STEL" (Short Term Exposure Limit).
NE = None Established. * indicates “as oil mist”.
PHYSICAL DATA
Appearance:
Pale amber liquid
Odor:
Petroleum odor
Vapor Density:
> 8 (Air = 1)
Vapor Pressure:
< 0.1 @ 100º F
Boiling Point:
Wide range
VOC Content:
Negligible
Evaporation Rate:
< 1 (n-butyl acetate = 1)
Solubility in Water:
Negligible
Specific Gravity:
0.9
pH:
Not determined
FIRE AND EXPLOSION HAZARD DATA
Flash Point:
415°F, COC
Flammable Limits:
Not applicable
Extinguishing Media:
CO2, Dry Chemical, Foam
Special Fire Fighting
Procedures:
A self-contained breathing apparatus should be worn when fighting fires involving chemicals.
Unusual Fire and Explosion
Hazards:
None known. Thermal decomposition products can be formed. See below.
REACTIVITY DATA
Stability:
Stable.
Hazardous Polymerization:
Will not occur.
Incompatibility:
Strong oxidizers such as chlorine, sodium hypochlorite and calcium hypochlorite.
Decomposition Products:
Thermal decomposition can yield dense smoke, carbon monoxide and oxides of sulfur.
Conditions to Avoid:
Contact with strong oxidizers.
Known Hazards:
HEALTH HAZARD DATA
Can cause eye irritation. Prolonged and repeated overexposure to oils can lead to skin
irritation
and dermatitis.
Signs and Symptoms of
Exposure:
None expected. Exposure to oil mists can cause respiratory irritation. Chronic exposure to the
skin can cause dermatitis.
Routes of Exposure:
Dermal. Inhalation.
Carcinogenicity:
No ingredients are classified as a carcinogen by IARC, NTP or OSHA.
Medical Conditions
Aggravated by Exposure:
Eye, skin, and respiratory conditions.
EMERGENCY AND FIRST AID PROCEDURES
Eyes:
Flush with plenty of water. Call a physician if symptoms occur.
Skin:
Wash with soap and water. Launder contaminated clothing before reuse.
Inhalation:
Not considered a route of exposure. Product has a low vapor pressure.
Medical
Do not induce a vomiting unless directed
physician. Seek attention.
physician: If aspirated into the lungs, can cause chemical pneumonitis).
Ingestion:
65
(Note to
Other:
Referral to a physician is recommended if there is any question about the seriousness of the
injury/exposure.
CONTROL MEASURES AND PERSONAL PROTECTIVE EQUIPMENT
Ventilation:
General (natural or mechanically induced fresh air movements).
Eye Protection:
Safety glasses are required in most industrial settings.
Skin Protection:
Not required. Gloves recommended.
Respiratory Protection:
Not normally required. If exposure to mist is likely, use a NIOSH-approved dust/mist respirator.
PRECAUTIONS FOR SAFE HANDLING AND USE
Handling and Storing
Precautions:
Spill Procedures:
Avoid prolonged or repeated contact with skin. Avoid breathing mists or vapor.
Avoid high
temperatures. Water contamination should be avoided.
For small spills, wipe away with an absorbent cloth. For larger spills, absorb with inert
material.
Sweep or scoop up and discard. Prevent spread of spill into sewers and watercourses.
REGULATORY INFORMATION
Hazard Communication:
This MSDS has been prepared in accordance with the federal OSHA Hazard Communication
Standard 29 CFR 1910.1200.
HMIS Codes:
Health 1, Flammability 1, Reactivity 0, PPE A
DOT Shipping Name:
Not regulated.
TSCA Inventory Status:
Chemical components listed on TSCA inventory.
This product does not contain any ingredients which are subject to reporting under Section 313
of
SARA Title III (40 CFR Part 372).
SARA Title III, Section 313:
EPA Waste Code(s):
Waste Disposal Methods:
Not regulated by EPA as a hazardous waste
Consult with regulatory agencies or your corporate personnel for disposal methods that
comply
with local, state, and federal safety, health and environmental regulations.
CONTACTS
Customer Service:
1 800 879 8000
Technical Service:
1 800 879 8000
Health / Safety:
1 800 879 6000 Jerry Metcalf
Emergency # (Chem-Trec):
1 800 424 9300 (USA, PR, Virgin Islands, Canada); 001 703 527 3887 (other countries)
(x6704)
The information and recommendations contained herein are based upon data believed to be correct; however,
no guarantee or warranty of any kind expressed or implied is made with respect to the information provided.
66
Battery Acid
Colonial Chemical Company
A Unit of The ESS Group, Inc.
Manufacturers of Quality Electrolyte and Blended Products.
78 Carranza Road, Tabernacle, NJ 08088 Œ(609) 268-1200 Œ (609) 268-2117 Fax
MATERIAL SAFETY DATA SHEET
PRODUCT:
BATTERY FLUID, ACID
10% - 51%
MANUFACTURER/DISTRIBUTOR
Colonial Chemical Company
78 Carranza Road
Product Information: (609) 268-1200
Emergency:
CMB(800) 457-4280
Tabernacle, NJ 08088
IDENTITY
Chemical Name: Battery fluid, acid; Electrolyte battery acid, Sulfuric
acid Chemical Family: Mineral Acid, Inorganic acid
Molecular Formula: H2SO4
CAS Number: 7664-93-9
Hazard Class: Corrosive Material, 8
UN/NA Number: UN 2796
WHMIS Classification: Class E - Corrosive, Class D1A
Packaging Group II
NFPA Ratings:
NPCA-HMIS Ratings
Health:
3
Health:
3
Flammability:
0
Flammability:
0
Reactivity:
2
Reactivity
2
Water Reactive
EXPOSURE LIMITS
3
1mg/m - 8 Hr TWA
STEL: 3 mg/m
TLV (ACGIH)
3
PEL (OSHA) 1 mg/m - 8 Hr TWA
Aquatic Toxicity: The 48 hour Tlm in flounder is 100-300 ppm.
PHYSICAL DATA
Physical State: Liquid
Appearance: Clear and odorless
Boiling Point: 10% - 210qF
51% - 270qF
Freezing Point: 10% - 25qF
51% - -30qF
Vapor Pressure: 0.3 mm Hg at 77qF
Vapor Density: 3.4
Evaporation Rate: Less than 1
Water
Solubility:
100%
soluble pH: Less than 1
Battery Fluid, Acid Material Safety Data Sheet
67
2
COMPONENTS
Sulfuric Acid
Water
Specific Gravity
CAS# 7664-93-9
CAS# 7732-18-5
@ 60qF
10.77%
89.23%
1.074
20%
80%
1.145
24.85%
75.15%
l.180
28.53%
71.47%
l.210
30%
70%
1.222
33.33%
66.67%
1.250
35.15%
64.85%
1.265
36.99%
63.01%
1.280
38.05%
61.95%
1.290
39.25%
60.75%
1.300
41%
59%
1.315
47%
53%
1.370
50.17%
49.83%
1.401
FIRE AND EXPLOSION DATA
UEL: Not applicable
LEL: Not applicable
Hazards: Reacts with most metals, especially when dilute, to give flammable, potentially
explosive hydrogen gas. Follow appropriate National Fire Protection Assoc. (NFPA) codes.
Extinguishing Media: Use media appropriate for surrounding material. Use water spray to
cool containers exposed to fire; do not get water inside containers.
Special Instructions: Evacuate personnel to a safe area. Keep personnel removed and upwind
of fire. Generates heat upon addition of water, with possible spattering. Wear full protective
clothing. Runoff from fire control may cause pollution. Neutralize runoff with lime, soda ash,
etc. Wear self-contained breathing apparatus if fumes or mists are present.
HAZARDOUS REACTIVITY
Instability:
Stable, but reacts violently with water and organic materials with evolution of
heat.
Decomposition:
Releases sulfur dioxide at extremely high temperatures.
Polymerization:
Polymerization will not occur.
Materials to Avoid: Vigorous reactions with water; alkaline solutions; metals, metal
powder; carbides; chlorates; fuminates; nitrates; picrates; strong
oxidizing, reducing, or combustible organic materials. Hazardous
gases are evolved on contact with chemicals such as cyanides,
sulfides, and carbides.
68
Battery Fluid (Alkali)
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: ALKALINE BATTERY ELECTROLYTE
POTASSIUM HYDROXIDE SOLUTION
Battery Fluid, Alkali, 8, UN2797, PGII
Saft America Inc.
d/b/a Alcad Standby Batteries
3 Powdered Metals Drive
North Haven, CT 06473
Information:
Phone 203-985-2500
Fax 203-985-2539
HMIS RATINGS
NFPA RATINGS
For Chemical Emergency
Spill, Leak, Fire, Exposure or Accident
Call CHEMTREC - Day or Night
800-424-9300
Date: 06/11/08
3 Health
3 Health
0 Flammability
0 Flammability
1 Reactivity
1 Reactivity
1. HEALTH HAZARD INFORMATION
Effects
of
Overexposure
Contact with electrolyte solution inside battery causes very rapid, sever damage.
Eye Effects:
Extremely corrosive to
eye tissues. May result in permanent blindness.
Contact with electrolyte solution inside battery may cause serious burns to skin
Skin Effects:
tissues.
Ingestion of electrolyte solution causes tissue damage to throat area and
Ingestion:
gastro/respiratory tract.
Electrolyte mist may cause varying degrees of irritation of the nasal mucous
Inhalation:
membranes and respiratory
tract tissues. May vary from mild irritation of nasal mucous membranes to damage of
lung tissues.
Carcinogenicity:
Not listed as carcinogenic by IARC, NTP, OSHA, ACGIH.
2. EMERGENCY FIRST AID
Battery Electrolyte
Eye Contact:
Flush with plenty of water for at least 15 minutes. Get immediate medical attention.
Remove contaminated clothing and flush affected areas with plenty of water for at
Skin Contact:
least 15 minutes.
Seek medical attention if necessary.
Do not induce vomiting. Dilute by giving water. If available give 2 to 4 cups of milk. Get
Ingestion:
immediate
medical attention. Do not give anything by mouth to an unconscious person.
Remove to fresh air. Give oxygen or artificial respiration if needed. Get immediate
Inhalation:
medical attention.
3. SPECIAL PROTECTION INFORMATION
Respiratory Protection: Use NIOSH-approved dust/mist type respirator for protection against mists.
Eye Protection: Use chemical safety goggles plus full face shield whenever handling Potassium Hydroxide
solution.
Hand Protection: If exposure to electrolyte solution, or dried salts is likely, use any water-insoluble
69
non-permeable glove, i.e., synthetic rubber. DO NOT user leather or wool.
Other protective Equipment: Face shield, rubber boots, rubber apron or rainwear or equivalent if exposure
to electrolyte solution is likely.
Ventilation: Local exhaust as necessary to eliminate mist.
4. REACTIVITY DATA
CAUTION: DO NOT ADD SULFURIC ACID.
Instability: Under normal conditions, material is stable.
Incompatibilities: Electrolyte will react with aluminum, zinc, tin and other active metals, acid, chlorinated
and aromatic hydrocarbons, nitrocarbons, and halocarbons. Tricholoroethylene will react with electrolyte
solution to form dicloroacetylene which is spontaneously combustible.
Hazardous Polymerization: Material is not known to polymerize.
5. FIRE AND EXPLOSION HAZARDS
Extinguishing Media: Use water spray, foam, CO2, sand or dry chemicals in the
storage area. Special Fire Fighting Procedures: Not Flammable. Avoid direct contact.
Fire and Explosion Hazards Electrolyte solution is corrosive to all human tissues. It will react violently
with many organic chemicals, especially nitrocarbons and chlorocarbons. Electrolyte solution reacts
with zinc, aluminum, tin and other active materials releasing flammable hydrogen gas.
6. INGREDIENTS
CAS #
Potasium Hydroxide
1310-58-3
Lithium Hydroxide
1310-66-3
EXPOSURE LIMITS
2
3
mg/m ACGIH CEILING-Air
2
3
mg/m – OSHA Ceiling
QUANTITY
= 20-25%
<3%
7. PHYSICAL PROPERTIES
Boiling Point -
| 250qF
Specific Gravity
-
Vapor Pressure -
At 20qC - 14 mm
Formula:
Off white color, no odor
Solubility
Water -
Appearance and Odor
1.180 - 1.250
20-25% KOH + 3% LiOH
+
Water
in
Complete.
8. SPILL MANAGEMENT PROCEDURES
Electrolyte Solution Spills
Small (up to 5 gallons): Flush with water and neutralize with dilute citric acid.
Large: Contain material in suitable containers or holding area. DO NOT allow material to enter sewers, streams, or
storm conduits. Recover material with vacuum truck and dispose of properly. Reportable Quantity: 1,000 pounds.
40 CFR 117.13.
9. DISPOSAL INFORMATION
The material resulting from clean-up operation may be hazardous wastes and, therefore, subject
to specific regulations. Package, store, transport, and dispose of all clean-up material in accordance
with all applicable federal, state, and local health environmental regulations. To dispose of
Electrolyte liquid ship as Hazardous Waste with the following description:
Waste. Environmentally Hazardous Substance, Liquid, N.O.S., 9, UN3082, PG III (Potassium
Hydroxide Solution)
70
10. PRECAUTIONS AND COMMENTS
Precautions in Handling:
Avoid adding water to caustic. In diluting, carefully add caustic to water while stirring as heat is
evolved. Never mix with acids.
Other Precautions:
Do not get into eyes, on skin, or on
clothing. Avoid breathing dust or mist.
Use with adequate ventilation and employ appropriate respiratory protection when exposed
to dust or mist. When handling, wear chemical splash goggles, face shield, rubber gloves, and
protective clothing.
Wash thoroughly after handling or contact – exposure can cause burns which are not immediately
painful or visible.
Last Date Revised 06/11/08
Disclaimer: This information has been complied for sources considered to be dependable and is to the best of our
knowledge and belief, accurate and reliable as of the dated compiled. However, no representation, warranty (either
expressed or implied) or guarantee is made to the accuracy reliability or completeness of the information contained herein.
This information relates to the specific material designated and may not be valid for such material used in combination with
any other materials or in any process. It is the user’s responsibility to satisfy himself as to the suitability and completeness
of this information for his own particular use. We do not accept liability for any loss or damage that may occur, whether
direct, indirect, incidental or consequential, for the use of this information nor do we offer warranty against patent
infringement. Additional information is available by calling the telephone number above designated for this purpose.
71
MATERIAL SAFETY DATA SHEET
Battery Terminal Cleaner
KEM CANADA MFG.
4 BLAIR DRIVE
BRAMPTON, ONTARIO
EMERGENCY
# (905)
456-9444
CANUTEC
# (613) 996-6666
W.H.M.I.S. CLASSIFICATION
L6T 2H5
MATERIAL REFERENCE
NO: 105700
SECTION I - MATERIAL IDENTIFICATION AND USE
---------------------------------------------------------------------|MATERIAL NAME/I.D.: BATTERY TERMINAL CLEANER
|
---------------------------------------------------------------------|CHEMICAL NAME: NOT APPLICABLE
|CHEMICAL FAMILY: ALKALINE BLEND |
---------------------------------------------------------------------|CHEMICAL FORMULA: MIXTURE
|MOLECULAR WEIGHT: NOT APPLICABLE|
---------------------------------------------------------------------|SYNONYMS: NONE
|
---------------------------------------------------------------------|MATERIAL USE: ALKALINE BATTERY POST CLEANER
|
---------------------------------------------------------------------SECTION II - HAZARDOUS INGREDIENTS OF MATERIAL
|
|
HAZARDOUS
INGREDIENTS
|
|
APPROX. %|
CONCENT. |
|SODIUM METASILICATE | 5.0-10.0
|TRISODIUM PHOSPHATE
| 1.0-5.0
|DIPROPYLENE GLYCOL
| 1.0-5.0
| METHYL ETHER
|
|
|
|
|
|
|
|
|
TLV
PPM
|
|
|
|
|
|
|
|
|
|
C.A.S. NO.
NO DATA |
NO DATA |
150
|
|
|
|
|
|
6834-92-0
7601-54-9
34590-94-8
|
|
LD
RAT,
50 |
ORAL |
| 1153 MG/KG|
| 2000 MG/KG|
| 5400 ȝL/KG|
|
|
|
|
|
|
|
|
|
|
---------------------------------------------------------------------SECTION III - PHYSICAL DATA FOR MATERIAL
---------------------------------------------------------------------|PHYSICAL STATE: LIQUID |
---------------------------------------------------------------------|ODOUR AND APPEARANCE: CLEAR, ORANGE LIQUID; SLIGHT AMMONIA ODOUR.
|
---------------------------------------------------------------------|ODOUR THRESHOLD (PPM) |
SPECIFIC GRAVITY
|
VAPOUR PRESSURE (MM)|
| NOT AVAILABLE
|
1.04
|
NOT
AVAILABLE
|
---------------------------------------------------------------------|VAPOUR DENSITY (AIR=1)|
|
>1
|
EVAPORATION
(WATER = 1)
RATE
<1
---------------------------------------------------------------------| BOILING POINT (C)
| FREEZING POINT (C) |%
| 93.3
| 0 (EST.)
|
--------------------------------------------------------------------|pH (10% SOLUTION)
|
DENSITY (G/ML)
|
11.5-12.5
|
NOT APPLICABLE
----------------------------------------------------------------------
|SOLUBILITY IN WATER
|COMPLETE
(20 ø
VOLATILE
93
|
C) |
(BY WEIGHT)|
|
|COEF.OF WATER/OIL DISTR|
|
NOT AVAILABLE
|
72
SECTION IV - FIRE AND EXPLOSION HAZARD OF MATERIAL
---------------------------------------------------------------------|FLAMMABILITY:
NON-FLAMMABLE
|IF YES, UNDER
WHICH CONDITIONS:
|
SELF-CONTAINED
---------------------------------------------------------------------WATER.
|MEANS OF EXTINCTION: WATER FOG, CHEMICAL FOAM, CO2
---------------------------------------------------------------------|SPECIAL PROCEDURES: WEAR FULL PROTECTIVE GEAR AND |BREATHING APPARATUS. COOL FIRE
EXPOSED DRUMS WITH |
---------------------------------------------------------------------|FLASH POINT (C) AND METHOD: NONE (TAG CLOSED CUP)
---------------------------------------------------------------------|HAZARDOUS COMBUSTION PRODUCTS:
|AMMONIA, OXIDES OF PHOSPHOROUS
|
|
CARBON DIOXIDE, CARBON MONOXIDE,
AND SODIUM.
|UPPER EXPLOSION LIMIT | LOWER EXPLOSION LIMIT | AUTOIGNITION
TEMP(C)|
|
NOT AVAILABLE |
NOT AVAILABLE |
NOT AVAILABLE |
---------------------------------------------------------------------|EXPLOSION DATA SENSITIVITY| RATE OF BURNING
|
EXPLOSIVE POWER
|TO CHEMICAL IMPACT
|
|
NOT
AVAILABLE
NOT AVAILABLE
|
NOT AVAILABLE
---------------------------------------------------------------------|SENSITIVITY TO STATIC DISCHARGE: NOT AVAILABLE|
---------------------------------------------------------------------SECTION V - REACTIVITY DATA
|CHEMICAL STABILITY: YES
|IF NO, UNDER WHICH CONDITIONS:
|INCOMPATIBILITY TO
|IF SO, WHICH ONES:
OTHER SUBSTANCES: YES
STRONG ACIDS, STRONG OXIDIZERS.
---------------------------------------------------------------------|REACTIVITY AND UNDER WHAT CONDITIONS: NOT ESTABLISHED
|
|HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
---------------------------------------------------------------------|HAZARDOUS DECOMPOSITION PRODUCTS: CARBON DIOXIDE, CARBON MONOXIDE, | |AMMONIA. |
---------------------------------------------------------------------SECTION VI - HEALTH HAZARD DATA
---------------------------------------------------------------------|ROUTE OF ENTRY:
|
--------------------------------------------------------------------|SKIN CONTACT:
YES
SKIN ABSORPTION:
YES
EYE CONTACT: YES |
| INHALATION:
YES
INGESTION:
YES
|
---------------------------------------------------------------------SECTION VIII - FIRST AID MEASURES
---------------------------------------------------------------------|PROCEDURES:
|EYES-FLUSH WITH WATER FOR AT LEAST 15 MINUTES WHILE HOLDING EYELIDS |
73
|OPEN. GET MEDICAL ATTENTION IF PAIN OR IRRITATION PERSISTS.
|SKIN-FLUSH AFFECTED AREA WITH
WATER FOR AT LEAST 15 MINUTES. WHILE
|REMOVING CONTAMINATED COTHING. GET MEDICAL ATTENTION IF IRRITATION
|PERSISTS. LAUNDER CLOTHING BEFORE REUSE.
|INHALATION-MOVE VICTIM TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE|
|OXYGEN. IF NOT BREATHING, ADMINISTER ARTIFICIAL RESPIRATION AND
|THEN GIVE OXYGEN. GET MEDICAL
ATTENTION.
|INGESTION-IF SWALLOWED DO NOT
INDUCE VOMITING. RINSE MOUTH WITH
|WATER. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS OR CONVULSING |
|PERSON. GET IMMEDIATE MEDICAL
ATTENTION.
---------------------------------------------------------------------|SOURCES USED: RAW MATERIAL SUPPLIER'S MATERIAL SAFETY DATA SHEETS |
---------------------------------------------------------------------|ADDITIONAL INFORMATION: NONE
|
---------------------------------------------------------------------SECTION IX - TDG SHIPPING INFORMATION
---------------------------------------------------------------------| SHIPPING NAME
|
CLASS |
UN NO.
|
PACKING GROUP |
| NOT REGULATED
|
|
|
|
---------------------------------------------------------------------|HANDLING PROCEDURES AND EQUIPMENT: AVOID CONTACT WITH EYES AND SKIN.|
|WEAR RECOMMENDED PROTECTIVE EQUIPMENT WHEN HANDLING CONCENTRATE.
|WASH THOROUGHLY AFTER USE.
---------------------------------------------------------------------|STORAGE REQUIREMENTS: KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP
|FROM FREEZING.
---------------------------------------------------------------------|SPECIAL SHIPPING INFORMATION: HEATED |
---------------------------------------------------------------------SECTION X - HMIS HAZARD RATING INFORMATION
---------------------------------------------------------------------| FLAMMABILITY
|
REACTIVITY
| 1
|
0
|
|
HEALTH
2
---------------------------------------------------------------------SECTION XI - PREPARATION DATE OF MSDS
---------------------------------------------------------------------|PREPARED BY: TECHNICAL
DEPARTMENT
TELEPHONE
# (905)
456-9444
|REVISED:
JUNE 21, 2009
REPLACES:
OCTOBER 25, 2004
---------------------------------------------------------------------DISCLAIMER:
THE INFORMATION CONTAINED HEREIN IS COMPILED FROM SOURCES BELIEVED TO
BE RELIABLE. THE MANNER AND CONDITIONS OF USE AND HANDLING MAY INVOLVE
OTHER AND ADDITIONAL CONSIDERATIONS. WE ACCEPT NO RESPONSIBILTY FOR THE
ACCURACY, SUFFICIENCY, RELIABILITY OR FOR ANY LOSS OR INJURY RESULTING
FROM THE USE OF THE INFORMATION.
74
Big Brute
BIG BRUTE
Material Safety Data Sheet
Identity (Trade Name As Used On Label)
GATEWAY CHEMICALS, INC.
MSDS:
Manufacture : 724 Golfair Blvd.
CAS Number:
Address:
Jacksonville, FL 32206
9/26/1991
Date Prepared:
904-353-4791
Daniel L. Cobb
Phone Number (For Information: 80424-9300
Emergency Phone Number
Prepared by:
Telex
Note: Black spaces are not permitted. If any item
is not applicable, or no information is available,
the space must be marked to indicate that
Section 1 - Material Identification And Information
Components - Chemical Name and Common names
(Hazardous Components 1% or greater; Carcinogens 0.1%
greater)
%
OSHA
PEL
ACGIH
TLV
OTHER
LIMITS
RECOMMENDED
Non hazarous Ingredients
Total
100
Section 2 - physical / chemical charactiristics
Boiling point
400
Vapor Pressure (mm Hg and Temperature)
Vapor Density (Air-1)
Solubility in Water
N/A
COMPLETE
Specific Gravity (H2O =1) 1.02
19.5
Melting Point N/A
Evaporation Rate
(Water _______=1) 5
Water Reactive NO
Appearance and odor: BROWN VISION LIQUID WITH ORANGE FRAGRANCE
75
Section 3 - Fire and Explosion Hazard Data
Flash Point and Method Used:
NONE
Extinguisher Media:
Auto-Ignition
Temperature: N/A
Flammability Limits in
Air % by Volume:
N/A
LEL: N/A
UEL:
N/A
N/A
Special
Fire
Fighting
Procedures:
N/A
Unsual fire and explosion
hazard
NONE
Secret 4 - Reactivity hazard data
Stability
Stable
Unstable
Incompatibility
NONE
Conditions
to
Avoid
NONE
(Materials
Hazardouz
to
Avoid)
Decomposition
Production
NONE
Hazardouz
Mary
Will Not Occur
Polymerization
Occur
Conditions
to
Avoid
None
76
C5-A High Temperature
MATERIAL SAFETY DATA SHEET
SECTION 1 – PRODUCT NAME AND COMPANY IDENTIFICATION
PRODUCT USE: Use as anti seize compound on engine spark
Plugs, fasteners, and fittings, but not limited to such use.
PRODUCT NAME: Graphite Petrolatum
Anti Seize Thread Compound
Meets Spec. SAE-AMS-2518
Armite Laboratories Inc.
Manufacture/Supplier:
Cage Code
1560 Superior Ave
84180
Costa Mesa, CA 92627
EMERGENCY:
Chem-Tel Inc. (800) 255-3924
Phone: (949) 646-9035
Fax:(949) 646-8319
Prepared By: Armite Laboratories
Last Revision Date: December 20, 2012
SECTION 2 – COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components (Specific)
Non-Hazardous Blend
Petrolatum
Graphite (Synthetic)
CAS Number
8009-03-8
7782-42-5
OSHA PEL
(As Oil Mist,
Generated)
3
5 mg/m TWA
3
10mg/m STEL
3
15mg/m (Total Dust)
3
5mg/m
(Respirable Fraction)
ACGIH TVL
% (opt.)
if
+
50 /- 2
3
2mg/m (for all forms of
graphite except graphite
fibers)
48-52%
SECTION 3 – HAZARDS IDENTIFICATION
Route of Entry:
Eyes, Ingestion, Skin
Eyes:
May cause irritation.
Ingestion:
May cause diarrhea.
May cause possible rash for persons with hypersensitivity.
Skin:
SECTION 4 – FIRST AID MEASURES
Eyes: Flush with water until all residual material is gone. If irritation persists, seek medical help.
Ingestion: Do not induce vomiting. Wash out mouth. Contact a physician immediately.
Skin:
Remove by wiping or with a waterless hand cleaner, followed by washing with soap and water.
SECTION 5 – FIRE FIGHTING MEASURES
Flammability: Not Available
Extinguishing Media: Foam CO2 Dry Chemical
Flash Point: (COC): > 400° F (203°C )
Explosive Properties: Not Available
Hazardous Combustion Products: Not Available
Special Fire Fighting Procedures: None as Grease Product.
SECTION 6 – ACCIDENTAL RELEASE MEASURES
Spillage: Scoop up excess, wipe down affected area and pick up residue with clay, pumice, etc., to avoid
walking hazard.
Environmental Precautions: Unavailable
SECTION 7 – HANDLING AND STORAGE
Handling Procedures: No special handling precautions necessary.
0
Storage Requirements: Normal. Prefer under 125 F.
Engineering Controls: None available
77
SECTION 8 – EXPOSURE CONTROLS/PERSONAL PROTECTION
Respiratory Protection: None required.
Hand Protection:
Protective gloves for hypersensitive persons.
Eye Protection:
Protective glasses if applied to moving parts.
SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Dark Grey Paste
Specific Gravity: Not Available
VOC: 0.0 lbs/gal (as 100% solid material)
Boiling Point: 350° F
Melting Point: 500° F
Freezing Point: Not Available
Odor: Slight Petroleum
Odor Threshold: Not Determined
pH: Not Available
Density: Not Available
Evaporation Rate
(Butyl Acetate + 1.0): N/A
Vapor Pressure: Not Available
Vapor Density: Not Determined
Solubility in Water: Insoluble
SECTION 10 – STABILITY AND REACTIVITY
Stability: Stable
Chemically stable under normal conditions.
Conditions/Materials to Avoid: Product contains graphite, which may promote corrosion of aluminum,
magnesium, ferrous, zinc, and cadmium alloys or plated coating and should not be used with such metals.
Hazardous Decomposition Products: Unknown
Hazardous Polymerization: Will not occur
SECTION 11 – TOXICOLOGY INFORMATION
Exposure Limit of Material:
See Section 2
Teratogenicity, Embryotoxicity and/or Fetotoxicity:
Not Available
Mutagenicity: Not Available
Effects of Long-Term (Chronic) Exposure:
Carcinogenicity: None
NTP: No
IARC: No
OSHA: No
SECTION 12 – ECOLOGICAL INFORMATION
Possible Effects: May generate oil fractions that could act as a marine pollutant in extreme cases, but is highly
unlikely. Behavior: Relatively well behaved. Bio accumulation potential nil.
Environmental Fate: Highly unlikely to cause widespread contamination.
SECTION 13 – DISPOSAL CONSIDERATION
Consult federal, state and local regulations for disposal of petroleum products.
SECTION 14 – TRANSPORTATION INFORMATION
IMDG Classification: This product
is not regulated by IMDG.
ICAO Classification: This product is not regulated by the ICAO.
Land and Rail:
Not Regulated
PLACARDS: None
CLASS
UN
PG
SECTION 15 – REGULATORY INFORMATION
Not regulated
WHMIS – Not regulated
SECTION 16 – OTHER INFORMATION
Do not reuse containers. Keep out of each of children.
This M.S.D.S and the information it contains is offered to you in good faith as accurate. We believe that information to be
correct but cannot guarantee its accuracy or completeness. Health and safety precautions in this data sheet may not be
adequate for all individuals and/or situations. It is the user’s obligation to evaluate and use this product safely and to
comply with all applicable laws and regulations. No statement made in this data sheet shall be construed as a permission or
recommendation for the use of any product in a manner that might infringe existing patents.
HMIS
SYMBOL
NFPA SYMBOL
FIR
E
78
HEALTH
1
FLAMMABILITY
1
REACTIVITY
PPI
1
NR
1
TOXICITY
REACTIVITY
1
1
NR
PERSONAL PROTECTION INDEX
79
Chain Lube
Material Safety Data Sheet acc. to ISO/DIS 11014
1. Identification of substance
Trade name:
Product codes:
Manufacturer:
CHAIN & WIRE LUBE
HY00200302
SEYMOUR OF SYCAMORE
917 Crosby Avenue
Sycamore, IL 60178
(815)-895-9101, www.seymourpaint.com
Emergency information: CHEMTEL 1-800-255-3924, 813-248-0585 *if located outside the U.S.*
2 Composition/Data on components
Chemical Description: This product is a mixture of the substances listed below with nonhazardous additions.
Dangerous components:
8012-95-1
Petroleum hydrocarbon
110-54-3
n-hexane
74-98-6
propane
64742-89-8
VM&P Naphtha
67-64-1
Acetone
106-97-8
n-butane
3 Hazards identification
Hazard description:
Effects of chronic overexposure:
NFPA ratings (0 - 4):
HMIS-ratings (0 - 4):
45.97%
12.82%
12.61%
11.33%
8.96%
7.41%
Harmful
Extremely flammable
Physical dangers: Extremely flammable liquid and vapor in a pressurized container. Keep
away from heat, sparks, and flame.
Has narcotizing effect.
Extremely flammable.
Harmful: danger of serious damage to health by prolonged exposure through inhalation.
Possible risk of impaired fertility
Keep out of the reach of children.
May cause permanent brain and nervous system damage. Repeated
overexposure can also damage kidneys, lungs, liver, heart, and blood.
Intentional misuse by deliberately inhaling the contents may be harmful or
fatal.
Health = 1
Fire = 4
Reactivity = 3
Health= 1
Fire= 4
Physical Hazard= 3
4 First aid measures
After inhalation: Supply fresh air; consult doctor in case of complaints.
After skin contact:
Remove contaminated clothing. Wash exposed area with soap and water.
After eye contact:
Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:
Contact physician or poison control center.
5 Firefighting measures
Extinguishing agents:
Protective equipment:
CO2, sand, extinguishing powder, or water spray. Fight larger fires with water spray or
alcohol resistant foam.
No special measures required.
6 Accidental release measures
Personal safety:
Wear protective equipment. Keep unprotected persons away.
80
Environmental safety:
Clean-up/collection:
7 Handling and storage
Fire/explosion protection:
Storage requirements:
Do not allow product to reach sewage systems or ground water.
Ensure adequate ventilation.
Do not spray on a naked flame or any incandescent material. Do not smoke. Protect
from electrostatic discharges.
Observe pressurized container storage regulations. Consult with your local authorities.
8 Exposure controls and personal protection:
Components with limit values that require monitoring at the workplace:
8012-95-1 Petroleum hydrocarbon
PEL 5
mg/m³
110-54-3 n-hexane
PEL
1800 mg/m³, 500 ppm
REL
180 mg/m³, 50 ppm
TLV
176 mg/m³, 50 ppm
Skin; BEI
74-98-6 propane
PEL
1800 mg/m³, 1000 ppm
REL
1800 mg/m³, 1000 ppm
TLV
Varies mg/m³, 1000 ppm
67-64-1 Acetone
PEL
2400 mg/m³, 1000 ppm
REL
590 mg/m³, 250 ppm
TLV
Short-term value: 1782 mg/m³, 750 ppm
Long-term value: 1188 mg/m³, 500 ppm
BEI
106-97-8 n-butane
REL
1900 mg/m³, 800 ppm
TLV
Varies mg/m³, 1000 ppm
Hygienic protection:
Breathing equipment:
Hand protection:
Eye protection:
Keep away from foodstuffs and animal feed. Wash hands after use.
A respirator is generally not necessary when using this product outdoors or in large
open areas. In cases where short and/or long term overexposure exists, a charcoal filter
respirator should be worn. If you suspect overexposure conditions exist, please consult
an authority on chemical hygiene.
Protective gloves. The glove material has to be impermeable and resistant to the
substance. No glove recommendation can be given.
Tightly sealed goggles
9 Physical and chemical properties:
General Information:
Odor:
Aromatic
Boiling point:
-44°C (-47°F)
Flash point:
-19°C (-2°F)
Auto igniting:
Product is not self-igniting.
Danger of explosion:
Stable at normal temperatures. Can may burst when exposed to temperatures
exceeding 120 degrees Fahrenheit. In use, may form flammable/explosive vapour-air
mixture.
Lower Explosion Limit:
1.2 Vol %
Upper Explosion Limit:
10.9 Vol %
Vapor Pressure:
40 PSI, 2750 hPa
Density at 20°C (68°F):
0.73 g/cm³
Specific Gravity:
Between 0.77 and 0.85 (Water equals 1.00)
VOC content:
353.9 g/l / 2.95 lb/gl
VOC content (less exempt solvents):
44.2 %
MIR Value:
0.65
81
Solids content:
46.9 %
10 Stability and reactivity:
Do not allow the can to exceed 120 degrees Fahrenheit. Stable at normal temperatures.
Conditions to avoid:
No dangerous reactions known.
Hazardous Reactions:
11 Toxicological information:
Skin effects:
No irritant effect.
Eye effects:
No irritating effect.
Sensitization:
No sensitizing effects known.
12 Ecological information
Other information:
Ecotoxical effects:
Aquatic toxicity:
Remark:
This product does not contain any chlorofluorocarbons (CFC's), hydro
chlorofluorocarbons (HCFC's), chlorinated solvents, or ozone depleting substances.
Harmful to aquatic organisms.
Hazardous for water, do not empty into drains.
Harmful to fish
13 Disposal considerations
DISPOSAL METHOD: Dispose of in accordance with local, state, and federal regulations. Do not puncture, incinerate, or
compact. Partially empty cans must be disposed of responsibly. Do not heat or cut empty containers with electric or gas
torches. (
Recommendation:
Completely empty cans should be recycled.
14 Transport information:
Hazard class:
Identification number:
Label
ADR/RID/TDG class:
UN-Number:
IMDG Class:
Packaging group:
II
EMS Number:
Marine pollutant:
ICAO/IATA Class:
2.1
Proper shipping name:
2.1
N/A
2.1
2 5F Gases
1950
2.1
F-D,S-U
No
Aerosols, Flammable
Consumer Commodity ORM-D
15 Regulations
SARA Section 355 (extremely hazardous substances):
None of the ingredients in this product are listed.
SARA Section 313 (Specific toxic chemical listings):
110-54-3
TSCA:
n-hexane
CPSC:
All ingredients are listed.
This product complies with 16 CFR 1303 and does not contain more than 90 ppm of lead.
California Proposition 65 chemicals known to cause cancer:
None of the ingredients in this product are listed.
CANADIAN
ENVIRONMENTAL
PROTECTION ACT:
WHMIS Symbols for
Canada:
All hazardous ingredients for this product appear on the Canadian Domestice Substance List.
EPA:
A= Known human carcinogen
A - Compressed gas
D2A - Very toxic material causing other toxic effects
B= Probable human carcinogen
82
C= Possible human carcinogen
D= Not classifiable as to human carcinogenicity: Inadequate human and animal evidence
of carcinogenicity (or no data is available).
I: 'Data are inadequate for an assessment of human carcinogeni potential.'
II: 'Inadequate information to assess carcinogenic potential.'
110-54-3
67-64-1
IARC:
n-hexane
Acetone
II
I
Group 2A: The ingredient is probably carcinogenic to humans.
Group 2B: The ingredient is possibly carcinogenic to humans. There is limited evidence of
carcinogenicity.
Group 3: The ingredient is unclassifiable as to its carcinogenicity to humans.
Group 2A: The ingredient is probably carcinogenic to humans.
Group 2B: The ingredient is possibly carcinogenic to humans. There is limited evidence of carcinogenicity.
Group 3: The ingredient is unclassifiable as to its carcinogenicity to humans.
ACGIH:
67-64-1
A1-designates a confirmed human carcinogen.
A2-designates a suspected human carcinogen.
A3-designates an animal carcinogen.
A4-designates "not classifiable as a human carcinogen".
Acetone
A4
The following substances are regulated in the United States with reference to occupational
NIOSH:
exposure
limits:
The following substances are regulated in the United States with reference to occupational exposure limits:
Risk phrases:
Extremely flammable.
Harmful: danger of serious damage to health by prolonged exposure through inhalation.
Possible risk of impaired fertility
Safety phrases:
Keep out of the reach of children.
Do not breathe gas/fumes/vapour/spray.
Do not empty into drains, dispose of this material and its container at hazardous or special waste
collection point
Wear suitable protective clothing and gloves.
If swallowed, seek medical advice immediately and show this container or label.
Use only in well-ventilated areas.
USA
(Contd. on page 4)
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific
product features and shall not establish a legally valid contractual relationship.
Contact: Regulatory Affairs
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
PP: Severe Marine Pollutant
P: Marine Pollutant
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
ISO: International Organization for Standardization
EPA: Environmental Protection Agency
IARC: International Agency for the Research of Cancer
NIOSH: National Institute for Occupational Safety and Health
TSCA: Toxic Substances Control Act
CPSC: Consumer Product Safety Commission
83
Contact Cement Material Safety Data Sheet
ITW Consumer - Devcon/Versachem
CONTACT CEMENT
This product appears in the following stock number(s): 18045
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Tradename: CONTACT CEMENT
General use: Flexible, waterproof repairs. After solvent evaporates, product is not hazardous Chemical family:
Neoprene Adhesive Solution
MANUFACTURER
ITW Consumer - Devcon/Versachem
2107 West Blue Heron Blvd.
EMERGENCY INFORMATION
Emergency telephone number
(CHEMTEL): (800) 255-3924
(CHEMTEL International): (+01) 813248-0585
Other Calls: (561) 845-2425
Riviera Beach, Florida 33404
2. COMPOSITION/INFORMATION ON INGREDIENTS
Component
Abbr.
Weight%
METHYL ETHYL KETONE
78-93-3
MEK
30-60
N-HEXANE
110-54-3
n/e
10-30
HEPTANE
142-82-5
TRADE
SECRET
hazardous)
MIXTURE
n/e
5-15
n/e
Balance
ACGIH; TLV-TWA OSHA PEL:
Other Limits
200 ppm TWA 200 ppm TWA;
200 ppm Canada
ACGIH
590
3
mg/m
500 ppm TWA;
50 ppm
50 ppm Canada
1800
3
mg/m TWA
500 ppm TWA;
400 ppm
n/e
2000
3
mg/m TWA
(Nonn/e
n/e
"TLV" means the Threshold Limit Value exposure (eight-hour, time-weighted average, unless otherwise noted) established
by the American Conference of Governmental Industrial Hygienists. "STEL" indicates a short-term exposure limit. "PEL"
indicates the OSHA Permissible Exposure Limit. "n/e" indicates that no exposure limit has been established. An asterisk (*)
indicates a substance whose identify is a trade secret of our supplier and unknown to us.
3. HAZARDOUS IDENTIFICATION
Emergency Overview
Appearance, form, odor: Amber liquid with hydrocarbon odor
DANGER!. Extremely Flammable. Eye, skin and respiratory irritant. May cause central nervous system effects. Based on
animal studies, potential reproductive effects
Potential health effects
Primary Routes of Exposure:
Symptoms of acute overexposure
Eye. Skin. Inhalation (breathing), skin absorption
85
Skin: May be absorbed through skin in harmful amounts. Has a drying effect; may irritate. Eyes: Irritant
Inhalation: Causes irritation of the mouth, nose,and throat. Central Nervous System Depression: signs/symptoms can
include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and
unconsciousness.
Ingestion: May cause gastric distress (nausea, vomiting, diarrhea). Aspiration (breathing) of vomitus into lungs may result in
pneumonitis.
Effects of Chronic Exposure: May cause dermatitis. Overexposure to methyl ethyl ketone and n-hexane may cause
peripheral nerve damage (that of arms and legs) and result in muscular weakness and loss of sensation. Long term
overexposure to solvents have been associated with lung, liver and kidney damage.
Medical Conditions Recognized as Being Aggravated by Exposure:
Preexisting pulmonary and dermatological disorders.
Other: Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal
4. FIRST AID MEASURES
Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical
attention if irritation persists.
Skin Contact: Remove contaminated clothing. Wash area with soap and water. If irritation persists, seek medical
attention.
Inhalation: If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing
becomes difficult
Ingestion: Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never
give anything by mouth to an unconscious person
5. FIRE FIGHTING MEASURES
General fire and explosion characteristics: Flammable liquid Class 1B.
Recommended Extinguishing Media: Carbon dioxide, Dry chemical, foam
Flash point: -20°F
Lower Explosive
Limit: 1%
Method: TCC
Upper Explosive
Limit: 11.6%
Special Fire-Fighting Procedures: Evacuated unprotected personnel. Firefighters should wear self-contained breathing
apparatus. Use water spray to cool exposed containers.
Unusual Fire/Explosion Hazards:
Vapors may travel from container toward sources of ignition and flashback.
Hazardous Products of Combustion:
Thermal decomposition will produce CO, CO2 and various unidentified organic compounds
6. ACCIDENTAL RELEASE MEASURES
Spill Control: Avoid personal contact. Eliminate ignition sources. Ventilate area.
Containment: Dike, contain and absorb with clay, sand or other suitable material
Cleanup: For large spills, pump to storage/salvage vessels. Soak up residue with an absorbent such as clay, sand or
other suitable material and dispose of properly.
86
Special procedures: Prevent spill from entering drainage/sewer systems, waterways and surface water. Use nonsparking tools.
7. HANDLING AND STORAGE
Handling precautions: Extremely flammable. Avoid breathing vapors or mists. Avoid contact with the skin and the eyes.
Wash thoroughly after handling. Ground container when pouring. Do not use near heat, sparks and open flame. Wear
appropriate personal protective equipment.
Storage: Keep in cool and dark place. Avoid direct sunlight. Store away from heat, sparks or open flame. Do not store at
temperatures above 120 degrees F. Keep containers closed when not in use. Maintain air space in storage containers.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering controls:
Ventilation:
General; local exhaust ventilation as necessary to control any air contaminants to within their exposure limits (or to
the lowest feasible levels when limits have not been established) during the use of this product.
Other engineering controls: Keep container tightly closed. Observe label precautions. Have emergency shower and eye
wash available.
Personal protective equipment
Eye and face protection: Safety glasses with side shields or splash-proof goggles are recommended
Skin protection: Chemical-resistant gloves (i.e. butyl) and other gear as required to prevent skin contact.
Respiratory protection: With good ventilation, none required. An approved respirator (i.e.NIOSH, etc.) should be worn
when exposures are expected to exceed the applicable limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Specific Gravity: 0.82
Boiling Point: 156°F
Melting point: n/d
Vapor Density (Air=1): >1
Vapor Pressure: n/d
Evaporation Rate: Faster than butyl acetate
VOC: 76% by weight
Solubility in water: Insoluble
pH (5% solution or slurry in water): n/a
10. STABILITY AND REACTIVITY
This material is chemically stable. Hazardous polymerization will not occur.
Conditions to Avoid: Keep away from heat,sparks and flame.
Incompatabilities: Oxidizing agents, acids, bases, halogenated organic compounds.
Hazardous Products of Combustion: Thermal decomposition will produce CO, CO2 and various
unidentified organic compounds
Conditions under which hazardous polymerization may occur: None.
11. TOXICOLOGICAL INFORMATION
Eye Contact: No data available.
Subchronic effects: No data available.
87
Carcinogenicity, tertogenicity and mutagenicity: No data available.
Other chronic effects: Laboratory studies involving rats indicate some evidence that MEK may be embryotoxic,
fetotoxic and teratorgenic.
Toxicological information on hazardous chemical constituents of this product:
Component
Oral LD50 (rat)
Dermal LD50 (rabbit)
Inhalation LC50 4hr (rat)
METHYL ETHYL KETONE
2737 mg/kg
6840 mg/kg
23500 mg/m /8h
Oral LD50 (rat)
28710 mg/kg
Dermal LD50 (rabbit)
n/d
Inhalation LC50
(rat)
48000 ppm/4h
n/d
n/d
n/d
n/d
n/d
n/d
3
78-93-3
Component
N-HEXANE
110-54-3
HEPTANE
142-82-5
TRADE SECRET (Non-hazardous)
MIXTURE
4hr
'n/d' = not determined
12. ECOLOGICAL INFORMATION
Ecotoxicity: No data available.
Mobility and persistence: No data available.
Environmental fate: No data available.
13. DISPOSAL CONSIDERATIONS
Please see also Section 15, Regulatory Information.
Recommended Method of Disposal: Do not dispose of in a landfill. Incineration is the preferred method of
disposal.
US EPA Waste Number: D001/D035 as per 40CFR 261.21 and a TCLP waste per 261.24 (methyl ethyl
ketone and benzene).
14. TRANSPORT INFORMATION
Proper shipping name: *Adhesives
Technical name: N/A
Hazard class: 3
UN/ID Number: 1133
Packing group: II
Emergency Response Guide no: 128
Other: *Depending upon the size and type of container, this material may be reclassified as "Consumer
Commodity, ORM-D" for shipments within the United States, or "Limited Quantity" elsewhere. Refer to the
appropriate regulation.
15. REGULATORY INFORMATION
U.S. Federal Regulations
TSCA:
All ingredients of this product are listed, or are exempt from listing on the TSCA Inventory. Export notification88is
required under TSCA Sec.12B - see below..
The following RCRA code(s) applies to this material if it becomes waste:
D001/D035
Regulatory status of hazardous chemical constituents of this product:
Component
METHYL ETHYL KETONE
Toxic
Extremely Chemical**
Hazardous
*
No
No
CERCLA RQ
(lbs)
12B EXPORT
NOTIFICATION:
5000 lbs. (2270
kg)
Not required
78-93-3
Component
N-HEXANE
110-54-3
HEPTANE
142-82-5
TRADE SECRET (Non-hazardous)
MIXTURE
Toxic
Extremely Chemical**
Hazardous
*
CERCLA RQ (lbs) 12B EXPORT
No
Yes
NOTIFICATION:
5000 lbs (2270
kg)
Required
No
No
0.0
Not required
No
No
0.0
Not required
*Consult the appropriate regulations for emergency planning and release reporting requirements for substances on the
SARA Section 301 Extremely Hazardous Substance List.
**Substances for which the "Toxic Chemical" column is marked "Yes" are on the SARA Section 313 list of Toxic Chemicals,
for which release reporting may be required. For specific requirements, consult the appropriate regulations.
For purposes of SARA Section 312 hazardous materials inventory reporting, the following hazard classes apply to this
material: Immediate health hazard, Delayed health hazard, Fire hazard
California regulations: For purposes of the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Prop 65),
this product does not contain any chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
Canadian Regulations
WHMIS Hazard Class: B2 FLAMMABLE LIQUIDS, D2B TOXIC MATERIALS
All components of this product are on the Canadian Domestic Substances List .
16. OTHER INFORMATION
Hazardous Material Information System (HMIS) rating:
Health 2*
Flammability 3 Physical Hazard 0
HMIS is a registered trademark of the National Paint and Coatings Assn.
Revision Date: August/25/2008
Revision Number: 6
The information and recommendations in this document are based on the best information available to us at the time of
preparation, but we make no other warranty, express or implied, as to its correctness or completeness, or as to the results
of reliance on this document.
89
Contact Cleaner
Product Name:
QD™ Contact Cleaner (aerosol)
Product Number (s):
72130
Product Use:
Electronic cleaner
Manufacturer / Supplier Contact Information:
In United States:
CRC Industries, Inc.
885 Louis Drive
Warminster, PA 18974
www.crcindustries.com
1-215-674-4300 (General)
(800) 521-3168 (Technical)
(800) 272-4620 (Customer Service)
In Canada:
CRC Canada Co.
2-1246 Lorimar Drive
Mississauga, Ontario L5S 1R2
www.crc-canada.ca
1-905-670-2291
24-Hr Emergency – CHEMTREC: (800) 424-9300
In Mexico:
CRC Industries Mexico
Av. Benito Juárez 4055 G
Colonia Orquídea
San Luís Potosí, SLP CP 78394
www.crc-mexico.com
52-444-824-1666
or (703) 527-3887
Emergency Overview
DANGER:
Extremely Flammable. Harmful or Fatal if Swallowed. Contents Under Pressure.
As defined by OSHA’s Hazard Communication Standard, this product is hazardous.
Appearance & Odor:
Clear, colorless liquid with alcohol odor
Potential Health Effects:
ACUTE EFFECTS:
EYE:
SKIN:
INHALATION:
INGESTION:
May cause mild irritation including stinging and redness, but does not injure eye.
Single, brief exposures may cause mild irritation. Frequent or prolonged contact may cause more
severe irritation, defatting of the skin, and dermatitis.
High vapor concentrations are irritating to the respiratory tract and may cause headaches,
dizziness, anesthesia, drowsiness, unconsciousness and other central nervous system effects,
including death. May cause peripheral nervous system disorder and/or damage.
Low order of toxicity by ingestion. Main hazard is aspiration into the lungs during swallowing or
vomiting. Small amounts aspirated into the respiratory system may cause bronchopneumonia or
pulmonary adema, possibly progressing to death.
CHRONIC EFFECTS: Overexposure to n-hexane may cause progressive and potentially irreversible damage to the
peripheral nervous system, particularly in the arms and legs.
TARGET ORGANS:
central nervous system, peripheral nervous system, respiratory system
Medical Conditions Aggravated by Exposure:
skin and respiratory conditions
See Section 11 for toxicology and carcinogenicity information on product ingredients.
Flammable Properties:
COMPONENT
Hexane isomers
CAS NUMBER
64742-49-0
% by Wt.
75 - 85
90
n-Hexane
110-54-3
6.1
Synthetic isoparaffinic hydrocarbon
64741-66-8
5 - 10
Methanol
67-56-1
<1
Carbon dioxide
124-38-9
3-8
Eye Contact:
Immediately flush with plenty of water for 15 minutes. Call a physician if irritation persists.
Skin Contact:
Remove contaminated clothing and wash affected area with soap and water. Call a physician if
irritation persists. Wash contaminated clothing prior to re-use.
Inhalation:
Remove person to fresh air. Keep person calm. If not breathing, give artificial respiration. If
breathing is difficult give oxygen. Call a physician.
Ingestion:
Do NOT induce vomiting. Contact a physician immediately.
Note to Physicians:
discretion.
Treat symptomatically. Gastric lavage using a cuffed endotracheal tube may be performed at your
This product is extremely flammable in accordance with aerosol flammability definitions.
(See 16 CFR 1500.3(c)(6) ).
Flash Point: < 0°F (TCC)
Upper Explosive Limit:
9.0
Autoignition Temperature: 489°F
Lower Explosive Limit:
1.7
Fire and Explosion Data:
Suitable Extinguishing Media:
Products of Combustion:
Class B fire extinguishers, dry chemical, foam or CO2
Fumes, smoke and carbon monoxide
Explosion Hazards:
Aerosol containers, when exposed to heat from fire, may build pressure and explode. Vapors
may accumulate in a confined space and create a flammable atmosphere.
Protection of Fire-Fighters:
Firefighters should wear self-contained, NIOSH-approved breathing apparatus for
protection against suffocation and possible toxic decomposition products. Proper eye and skin protection should be
provided. Use water spray to keep fire-exposed containers cool and to knock down vapors which may result from product
decomposition. Do not spray water directly on fire; product will float and could be reignited on surface of water.
Personal Precautions:
Use personal protection recommended in Section 8.
Environmental Precautions: Take precautions to prevent contamination of ground and surface waters. Do not flush into
sewers or storm drains.
Methods for Containment & Clean-up: Dike area to contain spill. Remove all sources of ignition. Ventilate the area with
fresh air. If in confined space or limited air circulation area, clean-up workers
should wear appropriate respiratory protection. Recover or absorb spilled
material using an absorbent designed for chemical spills. Place used absorbents
into proper waste containers.
Use proper grounding and bonding procedures for transferring materials. Do not use
Handling Procedures: product
near any source of ignition. Avoid contact with eyes and skin. Avoid breathing vapors.
Use
caution around energized equipment. The metal container will conduct electricity if it
91
contacts a
live source. This may result in injury to the user from electrical shock and/or flash fire. For
product use instructions, please see the product label.
Storage Store in a cool dry area out of direct sunlight. Aerosol cans must be maintained below 120 F to
prevent cans from rupturing.
Storage Procedures:
Aerosol
Level:
Exposure Guidelines: III
OSHA
COMPONENT
TWA
Hexane isomers
500(v)
ACGIH
STEL
1000(v)
TWA
500
OTHER
STEL
1000
TWA
NE
p
p
m
500
NE
50(s)
NE
NE
Synthetic isoparaffinic hydrocarbon
NE
NE
NE
NE
NE
200
Carbon dioxide
5000
N.E. – Not Established
250 (v)
30000(v)
(c) – ceiling
200
5000
250
30000
(s) – skin
SOURCE
p
p
m
n-Hexane
Methanol
U
N
I
T
NE
p
p
m
NE
p
p
m
(v) – vacated
Controls and Protection:
Engineering Controls:
Area should have ventilation to provide fresh air. Local exhaust ventilation is generally
preferred because it can control the emissions of the contaminant at the source,
preventing
dispersion into the general work area. Use mechanical means if necessary to maintain vapor
levels below the exposure guidelines. If working in a confined space, follow applicable OSHA
regulations.
Respiratory Protection:
None required for normal work where adequate ventilation is provided. If engineering controls
are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved
cartridge respirator with organic vapor cartridge. Air monitoring is needed to determine actual
employee exposure levels. Use a self-contained breathing apparatus in confined spaces and
for emergencies.
Eye/face Protection:
For normal conditions, wear safety glasses. Where there is reasonable probability of liquid
contact, wear splash-proof goggles.
Skin Protection: Use protective gloves such as nitrile, PVC, Viton. Also, use full protective clothing if there is
prolonged or repeated contact of liquid with skin.
92
Physical State: liquid
Color:
clear, colorless
Odor:
alcohol
Odor Threshold:
ND
Specific Gravity:
0.6699
Initial Boiling Point: 140°F
Freezing Point:
< -76°F
Vapor Pressure:
160 mmHg @ 68°F
Vapor Density:
>1
(air = 1)
Evaporation Rate:
very fast
Solubility:
negligible in water
Coefficient of water/oil distribution:
ND
pH: NA
Volatile Organic Compounds:
wt %: 95
Stability:
g/L: 636.4
lbs./gal: 5.3
Stable
Conditions to Avoid:
Sources of ignition, temperature extremes
Incompatible Materials: Strong oxidizers
Hazardous Decomposition Products:
Oxides of carbon
Possibility of Hazardous Reactions:
No
Long-term toxicological studies have not been conducted for this product. The following information is available
for components of this product.
Acute Toxicity:
Component
Hexane isomers
n-Hexane
Synthetic isoparaffinic hydrocarbon
Methanol
Carbon dioxide
Oral LD50 (rat)
> 15,000 mg/kg
28,710 mg/kg
No data
5600 mg/kg
No data
Dermal LD50 (rabbit)
> 2000 mg/kg
3000 mg/kg
No data
15,800 mg/kg
No data
Inhalation LC50 (rat)
No data
48,000 ppm/4H
No data
3
81,000 mg/m /14H
470,000 ppm/30M
Chronic Toxicity:
Component
Hexane isomers
n-Hexane
Synthetic isoparaffinic
hydrocarbon
Methanol
Carbon dioxide
OSHA
Carcinogen
No
No
IARC
Carcinogen
No
No
NTP
Carcinogen
No
No
No
No
No
No
Sensitizer
Unknown
Unknown
No
Irritant
No
E (moderate) /
S (moderate) /
R (moderate)
E (mild)
No
No
E (moderate) / S
Unknown
No
No
(moderate)
No
No
Unknown
93
E – Eye
Reproductive Toxicity:
Teratogenicity:
Mutagenicity:
Synergistic Effects:
No
available
No
available
No
available
No
available
S – Skin
R - Respiratory
information
information
information
information
Ecological studies have not been conducted for this product. The following information is available for components of this
product.
Ecotoxicity:
n-hexane - 48 Hr EC50 water flea: 3.87 mg/L
96 Hr LC50 Lepomis macrochirus: 4.12 mg/L
Persistence / Degradability:
No information available
Bioaccumulation / Accumulation:
No information available
Mobility in Environment:
No information available
Waste Classification: The dispensed liquid product is a RCRA hazardous waste for the characteristic of ignitability with
a waste code of D001. Pressurized containers are a D003 reactive waste. (See 40 CFR Part
261.20 – 261.33)
Any liquid product should be managed as a hazardous waste. Empty aerosol containers
may be recycled.
All disposal activities must comply with federal, state, provincial and local regulations. Local regulations may be more
stringent than state, provincial or national requirements.
US DOT (ground):
Consumer Commodity, ORM-D
ICAO/IATA (air):
Consumer Commodity, ID8000, 9
IMO/IMDG (water):
Aerosols, UN1950, 2.1, Limited Quantity
Special Provisions:
None
U.S. Federal Regulations:
Toxic Substances Control Act (TSCA):
All ingredients are either listed on the TSCA inventory or are exempt.
Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) :
Reportable Quantities (RQ’s) exist for the following ingredients: n-hexane (5000 lbs)
methanol (5000 lbs)
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the
National Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Superfund Amendments Reauthorization Act (SARA) Title III:
Section 302 Extremely Hazardous Substances (EHS):
Section 311/312 Hazard Categories:
Fire Hazard
None
Yes
94
Reactive Hazard
Release of Pressure
Acute Health Hazard
Chronic Health Hazard
No
Yes
Yes
Yes
This product contains the following substances subject to the reporting
requirements
of Section 313 of Title III of the Superfund Amendments and Reauthorization
Act of
1986 and 40 CFR Part 372:
n-hexane (6.1%), methanol (0.9%)
Section 313 Toxic Chemicals:
Clean Air Act:
Section 112 Hazardous Air Pollutants (HAPs): n-hexane, methanol
U.S. State Regulations:
California Safe Drinking Water and Toxic Enforcement Act (Prop 65):
This product may contain the following chemicals known to the state of
California to cause cancer, birth defects or other reproductive harm:
None
Consumer Products VOC Regulations: This product does not comply with Consumer product VOC regulations and
cannot be sold for use in California, Connecticut, Maine, Maryland,
Massachusetts, New Jersey, Ohio and Pennsylvania.
State Right to Know:
New Jersey:
Pennsylvania:
Massachusetts:
Rhode Island :
75-83-2, 109-66-0, 78-78-4, 96-37-7,
107-83-5, 75-83-2, 110-54-3,
79-29-8,
107-83-5, 75-83-2,
110-54-3,
79-29-8,
75-83-2, 110-54-3,
79-29-8, 67-56-1,
110-54-3, 79-29-8, 67-56-1, 124-38-9
67-56-1, 124-38-9
67-56-1, 124-38-9
124-38-9
Canadian Regulations:
Controlled Products Regulations:
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the
MSDS contains all the information required by the Controlled Products Regulations.
WHMIS Hazard Class:
Canadian DSL Inventory:
A, B5, D2B
All ingredients are either listed on the DSL Inventory or are exempt.
European Union Regulations:
RoHS Compliance: This product is compliant with Directive 2002/95/EC of the European Parliament and of the Council
of 27 January 2003. This product does not contain any of the restricted substances as listed in
Article 4(1) of the RoHS Directive.
Additional Regulatory Information:
NFPA
HMIS® (II)
Health:
2
95
Flammability:
3
Reactivity:
0
PPE:
B
3
2
0
Ratings range from 0 (no hazard) to 4 (severe hazard)
Prepared By:
CRC #:
Revision Date:
Michelle Rudnick
599C
04/162009
Changes since last revision: MSDS reformatted to meet the requirements of the Canadian Controlled Products
Regulations.
The information contained in this document applies to this specific material as supplied. It may not be valid for this
material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries'
knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and
directions on the label. For further clarification of any information contained on this MSDS consult your supervisor, a
health & safety professional, or CRC Industries.
American Conference of Governmental Industrial
ACGIH: Hygienists
CAS: Chemical Abstract Service
CFR:
DOT:
DSL:
Code of Federal Regulations
Department of Transportation
Domestic Substance List
NA:
ND:
NIOSH
:
NFPA:
NTP:
Not Applicable
Not Determined
National Institute of Occupational Safety &
Health
National Fire Protection Association
National Toxicology Program
Occupational
Safety
and
Health
Administration
Pensky-Martens Closed Cup
Personal Protection Equipment
Parts per Million
Restriction of Hazardous Substances
Short Term Exposure Limit
Tag Closed Cup
g/L:
HMIS:
IARC:
IATA:
ICAO:
IMDG:
IMO:
lbs./ga
l:
grams per Liter
Hazardous Materials Identification System
International Agency for Research on Cancer
International Air Transport Association
International Civil Aviation Organization
International Maritime Dangerous Goods
International Maritime Organization
OSHA:
PMCC:
PPE:
ppm:
RoHS:
STEL:
TCC:
pounds per gallon
LC:
LD:
Lethal Concentration
Lethal Dose
TWA: Time Weighted Average
WHMIS:
Workplace
Hazardous
Information
System
Materials
96
Copper Based Welding & Braze Wire & Rod
SDS NO. 08-G
SAFETY DATA SHEET
This Safety Data Sheet complies with European Commission Directive 91/155/EEC, ISO 11014-1 and ANSI
Z400.1
1.
PRODUCT AND COMPANY IDENTIFICATION
Product Name:
ALL-STATE COPPER BASED BRAZING ALLOYS
Bare P/Ns:
69063000, 69060001,069063001, 69160511, 69060002, 69063002, 69160510, 69160512,
69060003, 69060004, 69060005
Coated P/Ns: 69063006, 69063020, 69060020, 69063007, 69063021, 69060021, 69060022, 69060023,
69060025
41FC P/Ns:
69051101, 69050101, 69053101, 090931, 69050102, 090981, 69001008, 69051100,
69050100, 69053100, 090906
Application:
Classification:
Supplier:
Telephone No.:
Emergency No.:
Web site:
Copper Based Brazing Alloys
None
THE ESAB GROUP, INC., 801 Wilson Avenue, P. O. Box 517, Hanover, PA 17331
1-717-637-8911, 1-800-933-7070
1-717-637-8911 and 1-800-424-9300 (CHEMTREC)
www.esabna.com
2.
HAZARDS IDENTIFICATION
Emergency Overview: Metal rods and coated metal rods in varying colors. These products are normally not considered
hazardous as shipped. Gloves should be worn when handling to prevent cuts and abrasions.
Avoid eye contact or inhalation of dust from these products. Skin contact is normally no hazard but should be avoided to
prevent possible allergic reactions.
Persons with a pacemaker should not go near brazing operations until they have consulted their doctor and obtained
information from the manufacturer of the device.
When these products are used in a brazing process, the most important hazards are heat, radiation, electric shock and
brazing fumes.
Heat:
Spatter and melting metal can cause burn injuries and start fires.
Radiation:
Arc rays can severely damage eyes or skin.
Electricity:
Electric shock can kill.
Fumes:
Overexposure to brazing fumes may result in symptoms like metal fume fever, dizziness, nausea, dryness
or irritation of the nose, throat or eyes. Chronic overexposure to brazing fumes may affect pulmonary function.
Overexposure to manganese and manganese compounds above safe exposure limits can cause irreversible damage to the
central nervous system, including the brain, symptoms of which may include slurred speech, lethargy, tremor, muscular
weakness, psychological disturbances and spastic gait.
Flame When used with combustible gas equipment (e.g., oxy-acetylene torch), read the use and safety information for
Processing: that equipment.
3.
COMPOSITION/INFORMATION ON INGREDIENTS
These products are solid metal rods and coated metal rods.
Ingredients
CAS#
EINECS#
Hazard
classification
Borax Glass
Boric Acid
IARC
(2)
NTP
(3)
OSHA List
(4)
(1)
1330-43-4
10043-35-3
215-540-4
233-139-2
No
Repr. Cat. 2
R60-61
---
---
---
Copper
7440-50-8
231-159-6
No
--
--
--
Iron
7439-89-6
231-096-4
No
--
--
--
Manganese
7439-96-5
231-105-1
No
--
--
--
97
Silicon
7440-21-3
231-130-8
No
--
Product Identity: ALL-STATE COPPER BASED BRAZING ALLOYS
Ingredients
Tin
Zinc
CAS#
EINECS#
7440-31-5
7440-66-6
231-141-8
231-175-3
Proprietary
Trade Secret
Methacryalate/Apliphatic
and
Naphthenic Hydrocarbon
Compound
(1)
(2)
(3)
(4)
Not known
Hazard
(1)
classification
No
F; R15-17N;
R50-53
No
--
--
SDS NO.
08-G
DATE REVISED:
02/23/2011
IARC
(2)
NTP
(3)
OSHA List
---
---
---
--
--
--
(4)
Hazard Classification according to European Council Directive 67/548/EEC, for R-phrases, sees Section 16.
Evaluation according to the International Agency for Research
on Cancer. 1 – Human Carcinogen 2B – Possibly carcinogenic to
humans
Classification according to the 11th Report on Carcinogens, published by the US National Toxicology Program.
K – Known Carcinogen S – Suspect Carcinogen
Carcinogen listing according to OSHA, Occupational Safety & Health Administration (USA).
All-State
APPROXIMATE COMPOSITION (Wt. %)
All-State Low Fuming
All-State Low Fuming
All-State 41FC
Product Trade Name:
Bronze Bare
Bronze Flux Coated
Borax
--
0.5-2.5
0.5-2.5
Boric Acid
--
3-6
3-6
56-62
55-58
55-58
<1
<1
<1
<0.5
<0.4
<0.4
--
<1
<1
<0.5
<0.5
<0.5
Tin
0.3-1.5
0.3-1.5
0.3-1.5
Zinc
38-42
32-39
32-39
Copper
Iron
Manganese
Methacryalate/Apliphatic and
Naphthenic Hydrocarbon
Silicon
4.
FIRST AID MEASURES
Inhalation:
If breathing has stopped, perform artificial respiration and obtain medical assistance immediately! If
breathing is difficult, provide fresh air and call physician.
Eye contact:
For radiation burns due to arc flash, see physician. To remove dusts or fumes flush with water for at least
fifteen minutes. If irritation persists, obtain medical assistance.
Skin contact: For skin burns from arc radiation, promptly flush with cold water. Get medical attention for burns or
irritations that persist. To remove dust or particles wash with mild soap and water.
Ingestion:
Not a likely route of exposure. If product dusts are swallowed, call a physician or poison control center
immediately. Do not induce vomiting unless directed to do so by a physician.
98
Electric shock: Disconnect and turn off the power. Use a nonconductive material to pull victim away from contact with live
parts or wires. If not breathing, begin artificial respiration, preferably mouth-to-mouth. If no detectable
pulse, begin Cardio Pulmonary Resuscitation (CPR). Immediately call a physician.
GeneFral:
5.
Move to fresh air and call for medical aid.
FIRE FIGHTING MEASURES
No specific recommendations for brazing consumables. Brazing sparks can ignite combustible and flammable materials. Use
the extinguishing media recommended for the burning materials and fire situation. Wear self-contained breathing
apparatus as fumes or vapors may be harmful.
6.
ACCIDENTAL RELEASE MEASURES
Solid objects may be picked up and placed into a container. Liquids or pastes should be scooped up and placed into a
container. Wear proper protective equipment while handling these materials. Do not discard as refuse.
Personal precautions:
refer to Section 8.
Environmental precautions:
refer to Section 13.
7.
HANDLING AND STORAGE
Handling:
Handle with care to avoid stings and cuts. Wear gloves when handling welding consumables. Avoid exposure to dust.
Do not ingest. Some individuals can develop an allergic reaction to certain materials. Retain all warning and identity
labels.
Storage: Keep separate from chemical substances like acids and strong bases, which could cause chemical reactions.
8.
EXPOSURE CONTROL/PERSONAL PROTECTION
Avoid exposure to brazing fumes, radiation, spatter, electric shock, heated
materials and dust. Engineering measures: (Brazing operations)
Ensure sufficient ventilation, local exhaust, or both, to keep brazing fumes and gases from breathing zone and general
area. Keep working place and protective clothing clean and dry. Train welders to avoid contact with live electrical parts
and insulate conductive parts. Check condition of protective clothing and equipment on a regular basis.
Personal protective equipment: (Brazing operations)
Use respirator or air supplied respirator when brazing in a confined space, or where local exhaust or ventilation is not
sufficient to keep exposure values within safe limits. Use special care when brazing painted or coated steels since
hazardous substances from the coating may be emitted. Wear hand, head, eyes, ear and body protection like welders
gloves, helmet or face shield with filter lens, safety boots, apron, arm and shoulder protection. Keep protective clothing
clean and dry.
Use industrial hygiene monitoring equipment to ensure that exposure does not exceed applicable national exposure
limits. The following limits can be used as guidance. For information about brazing fume analysis refer to Section 10.
Substance
CAS#
Borax
(as borates)
1330-43-4
Boric Acid
Copper
(as borates)
(as fume)
(as
dust/mist)
(as iron
oxide)
10043-35-3
7440-50-8
Iron
Manganese &
Manganese compounds
Silicon
(as Mn)
(1)
3
ACGIH TLV mg/m
OSHA PEL
2 ***, 6 (STEL)
No
***
ne
2 ***, 6 (STEL)
No
***
ne
0.2
0.1
7439-89-6
1
5**
1
10
7439-96-5
0.2
5
7440-21-3
10*, 3***
(2)
mg/m
3
Ceilin
g
15*, 5**
99
Tin (metal)
7440-31-5
2
Zinc (metal)
7440-66-6
None
2
No
ne
(1)
Threshold Limit Values according to American Conference of Governmental Hygienists, 2010
Permissible Exposure Limits according to the Occupational Safety & Health
Administration (USA) Unless noted, all values are for 8 hour time weighted averages
(TWA).
(2)
* Total dust, ** Respirable fraction, *** Inhalable fraction.
NOTE: Some of these products may not contain all of the materials listed. For details of composition, refer to the
COMPOSITION TABLES in Section 2.
9.
PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Metal rods and coated metal rods in varying colors.
Specific Gravity:
8.3 – 8.5 (H2O = 1)
Boiling Point:
2595°C/4703°F (copper)
907°C/1665°F (zinc)
Melting Point:
1600-1900°C/871-1038°F (copper)
419°C/786°F (zinc)
Vapor Pressure:
Not determined (solid).
Vapor Density:
Not determined (solid).
Evaporation Rate:
Not applicable.
Solubility in Water:
None.
Flash Point:
Not flammable.
Upper/Lower Flame Limit:
None.
Auto-ignition Temperature:
None.
10.
STABILITY AND REACTIVITY
General:
These products are intended for normal brazing purposes.
Stability:
These products are stable under normal conditions.
Reactivity: Contact with chemical substances like acids or strong bases could cause generation of gas.
When these products are used in a brazing process, hazardous decomposition products would include those from the
volatilization, reaction or oxidation of the materials listed in Section 3 and those from the base metal and coating.
Fumes from these products may contain compounds of the following chemical elements: B, Cu, Fe, O, Mn, Si, Sn and Zn.
The rest is not analyzed, according to available standards.
Refer to applicable national exposure limits for fume compounds, including those exposure limits for fume compounds
found in Section 8. Manganese has a low exposure limit, in some countries that may be easily exceeded.
Reasonably expected gaseous products would include carbon oxides, nitrogen oxides and ozone. Air contaminants around
the brazing area can be affected by the brazing process and influence the composition and quantity of fumes and gases
produced.
11.
TOXICOLOGICAL INFORMATION
Inhalation of brazing fumes and gases can be dangerous to your health. Classification of brazing fumes is difficult because
of varying base materials, coatings, air contamination and processes. The International Agency for Research on Cancer has
classified welding fumes as possibly carcinogenic to humans (Group 2B).
Acute toxicity:
Overexposure to brazing fumes may result in symptoms like metal fume fever, dizziness, nausea, dryness
or irritation of the nose, throat or eyes.
Chronic toxicity: Overexposure to brazing fumes may affect pulmonary function. Overexposure to manganese and
manganese compounds above safe exposure limits can cause irreversible damage to the central nervous
100
system, including the brain, symptoms of which may include slurred speech, lethargy, tremor, muscular
weakness, psychological disturbances and spastic gait.
12.
ECOLOGICAL INFORMATION
Contains zinc which may be toxic to aquatic species and is regulated as an environmental hazard in the European Union.
This hazard is not anticipated from the handling of brazing consumables but is relevant if consumables enter natural
waterways.
Brazing consumables and materials could degrade/weather into components originating from the consumables or from the
materials used in the brazing process. Avoid exposure to conditions that could lead to accumulation in soils or
groundwater.
13.
DISPOSAL CONSIDERATIONS
Discard any product, residue, disposable container or liner in an environmentally acceptable manner, in full compliance
with federal and local regulations. Use recycling procedures if available.
USA RCRA: These products are not considered hazardous waste if discarded.
Residues from brazing consumables and processes could degrade and accumulate in soils and groundwater. Brazing
residues from these products typically contain mainly the following components: B, Cu, Fe, O, Mn, Si, Sn, and Zn.
14.
TRANSPORT INFORMATION
No international regulations or restrictions are applicable.
15.
REGULATORY INFORMATION
Read and understand the manufacturer's instructions, your employer's safety practices and the health and safety
instructions on the label. Observe any federal and local regulations. Take precautions when brazing and protect yourself
and others.
WARNING: Brazing fumes and gases are hazardous to your health and may damage lungs and other organs. Use adequate
ventilation.
ELECTRIC SHOCK can kill.
ARC RAYS and SPARKS can injure eyes and
burn skin. Wear correct hand, head, eye and
body protection.
Canada: WHMIS classification: Class D; Division 2, Subdivision A
Canadian Environmental Protection Act (CEPA): All constituents of these products are on the Domestic
Substance List (DSL).
USA:
Under the OSHA Hazard Communication Standard, these products are considered hazardous.
These products contain or produce a chemical known to the state of California to cause cancer and birth
defects (or other reproductive harm). (California Health & Safety Code § 25249.5 et seq.)
United States EPA Toxic Substance Control Act: All constituents of these products are on the TSCA inventory list
or are excluded from listing.
CERCLA/SARA Title III
Reportable Quantities (RQs) and/or Threshold Planning Quantities (TPQs):
Ingredient name
RQ (lb)
Product is a solid solution in the form of a
-solid article.
TPQ (lb)
--
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the
National Response Center and to your Local Emergency Planning Committee.
Section 311 Hazard Class
As shipped:
Immediate, delayed
In use: Immediate, delayed
101
EPCRA/SARA Title III 313 Toxic Chemicals
The following components are listed as SARA 313 “Toxic Chemicals” and potential subject to annual SARA 313
reporting. See Section 3 for weight percent.
Ingredient name
16.
Disclosure threshold
Copper
1.0% de minimis concentration
Manganese
1.0% de minimis concentration
THER INFORMATION
This Safety Data Sheet has been revised due to modifications to several paragraphs and/or new format. This SDS
supersedes 8-F.
Refer to ESAB “Welding and Cutting - Risks and Measures”, F52-529 “Precautions and Safe Practices for Electric Welding
and Cutting” and F2035 “Precautions and Safe Practices for Gas Welding, Cutting and Heating” available from ESAB, and
to:
USA:
Contact ESAB at www.esabna.com or 1-800-ESAB-123 if you have questions about this SDS.
American National Standard Z49.1 "Safety in Welding and Cutting", ANSI/AWS F1.5 “Methods for Sampling and
Analyzing Gases from Welding and Allied Processes”, ANSI/AWS F1.1 “Method for Sampling Airborne Particles
Generated by Welding and Allied Processes”, AWSF3.2M/F3.2 “Ventilation Guide for Weld Fume”, American
Welding Society, 550 North
Le Jeune Road, Miami, Florida, 33135. Safety and Health Fact Sheets available from AWS at www.aws.org.
OSHA Publication 2206 (29 C.F.R. 1910), U.S. Government Printing Office, Superintendent of Documents, P.O.
Box 371954, Pittsburgh, PA 15250-7954.
American Conference of Governmental Hygienists (ACGIH), Threshold Limit Values and Biological Exposure
Indices, 6500 Glenway Ave., Cincinnati, Ohio 45211, USA.
NFPA 51B “Standard for Fire Prevention during Welding, Cutting and Other Hot Work” published by the National
Fire Protection Association, 1 Battery march Park, Quincy, MA 02169.
UK:
WMA Publication 236 and 237, “Hazards from Welding Fume”, “The arc welder at work, some general aspects of
health and safety”.
Germany: Unfallverhütungsvorschrift BGV D1, “Schweißen, Schneiden und verwandte Verfahren”.
Canada:
CSA Standard CAN/CSA-W117.2-01 “Safety in Welding, Cutting and Allied Processes”.
These products have been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
R-phrases: R15 – Contact with water liberates extremely flammable
gases. R17 – Spontaneously flammable in air.
R50 – Very toxic to aquatic organisms.
R53 – May cause long-term adverse effects in the aquatic environment.
R60 – May impair fertility.
R61 – May cause harm to the unborn child.
ESAB requests the users of these products to study this Safety Data Sheet (SDS) and become aware of product hazards and
safety information. To promote safe use of these products a user should:
- notify its employees, agents and contractors of the information on this S.D.S and any product hazards/safety information.
- furnish this same information to each of its customers for these products.
- request such customers to notify employees and customers for the same product hazards and safety information.
The information herein is given in good faith and based on technical data that ESAB believes to be reliable. Since the
conditions of use are outside our control, we assume no liability in connection with any use of this information and no
warranty, expressed or implied is given. Contact ESAB for more information.
102
Copper
Material Safety Data Sheet
Copper(II) acetylacetonate
MSDS# 50570
Section 1 - Chemical Product and Company Identification
MSDS Name:
Copper(II) acetylacetonate
Catalog Numbers:
AC110650000, AC110650250, AC110651000
2,4-Pentanedione, metal derivative; Cupric acetylacetonate.
Synonyms:
Company Identification:
Acros Organics BVBA
Janssen Pharmaceuticalaan 3a
2440 Geel, Belgium
Company Identification: (USA)
Acros Organics
One Reagent Lane
Fair Lawn, NJ 07410
For information in the US, call:
800-ACROS-01
For information in Europe, call:
+32 14 57 52 11
Emergency Number, Europe:
+32 14 57 52 99
Emergency Number US:
201-796-7100
CHEMTREC Phone Number, US:
800-424-9300
CHEMTREC Phone Number, Europe:
703-527-3887
Section 2 - Composition, Information on Ingredients
---------------------------------------CAS#:
13395-16-9
Chemical Name:
Copper(II) acetylacetonate
%:
99
EINECS#:
236-477-9
---------------------------------------Hazard Symbols:
XN
Risk Phrases:
20/21/22 36/37/38
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Warning! Harmful if swallowed, inhaled, or absorbed through the skin. Causes eye, skin, and respiratory tract
irritation. Target Organs: Respiratory system, eyes, skin.
Potential Health Effects
Eye:
Causes eye irritation.
104
Skin:
Ingestion:
Causes skin irritation. Harmful if absorbed through the skin. Harmful if swallowed. May cause
Inhalation:
irritation of the digestive tract. Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
No information found.
Section 4 - First Aid Measures
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately. Call a poison control center.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is
difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance;
induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper
respiratory medical device.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH
(approved or equivalent), and full protective gear. Dangerous fire hazard in the form of dust when
exposed to heat or flame.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Auto ignition Temperature: 250 deg. C (482.00 deg. F)
Flash Point: Not applicable.
Explosion Limits: Not available
Lower:
Upper:Not available
Explosion Limits:
NFPA Rating:
health: 2;
flammability: 1; instability: 0;
General
Information:
Section 6 - Accidental Release Measures
Use proper personal protective equipment as indicated in Section 8.
Vacuum or sweep up material and place into a suitable disposal container. Wear a self-contained
breathing Spills/Leaks: apparatus and appropriate personal protection. (See Exposure Controls, Personal Protection
section).
Avoid generating dusty conditions. Provide ventilation. Do not let this chemical enter the environment.
Section 7 - Handling and Storage
Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Use only in a chemical fume hood.
Storage: Store in a cool, dry place. Store in a tightly closed container.
Handling:
Section 8 - Exposure Controls, Personal Protection
+-----------------+
-------------------- +------------------+----------------|
Chemical Name
|
ACGIH
|
NIOSH
|OSHA - Final
|-----------------|
-------------------- |------------------|----------------| Copper(II) acetylac|none listed
|1 mg/m3 TWA (dust
|none listed
| etonate
|
|and mist, as Cu,
|
|
|
| except copper
|
+
PELs|
|
|
|
|
105
| fume)
(listed
|under Copper
| compounds,
|n.o.s.).100 mg/m3
|IDLH (dust and
| mist, as Cu)
| (listed under
| Copper
|compounds,
| n.o.s.).
+-----------------+
-------------------- +------------------OSHA Vacated PELs: Copper(II) acetylacetonate: None listed
Engineering Controls:
|
|
|
|
|
|
|
|
|
|
|
|
|
|
+-----------------
+
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use
only under a chemical fume hood.
Exposure Limits
Personal Protective Equipment
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and
face
Eyes:
protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a
Respirators: NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
Physical State: Crystalline powder
Color: blue-gray - blue
Odor: weak odor
pH: Not available
Vapor Pressure:
0.13 hPa @ 163 deg C
Vapor Density:
Not available
Evaporation Rate:
Not available
Viscosity:
Not available
Boiling Point:
160 deg C @ 9.8 mmHg ( 320.00°F)
Freezing/Melting Point: 245 deg C (decom)
Decomposition Temperature:
Solubility in water: 0.2 g/L (20°C)
Specific Gravity/Density:
Molecular Formula: C10H14O4Cu
Molecular Weight: 261.76
Section 10 - Stability and Reactivity
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials
Strong oxidizing agents.
106
Hazardous Decomposition Products
Carbon monoxide, carbon dioxide, 2,4-pentanedione, oxides of copper.
Hazardous Polymerization
Will not occur.
Section 11 - Toxicological Information
RTECS#:
CAS# 13395-16-9: GL6520000
LD50/LC50:
RTECS: Not available.
Carcinogenicity: Copper(II) acetylacetonate - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
The toxicological properties have not been fully investigated.
Other:
Section 12 - Ecological Information
Other:
Do not empty into drains.
Section 13 - Disposal Considerations
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - Transport Information
US DOT
Shipping Name: Not regulated as a hazardous material
Hazard Class:
UN Number:
Packing Group:
Canada TDG
Shipping Name: Not available
Hazard Class:
UN Number:
Packing Group:
Section 15 - Regulatory Information
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
WGK (Water Danger/Protection)
CAS# 13395-16-9: Not available
Canada
CAS# 13395-16-9 is listed on Canada's DSL List
Canadian WHMIS Classifications: D1B, D2B
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all of the information required by those regulations.
CAS# 13395-16-9 is not listed on Canada's Ingredient Disclosure List.
US Federal
TSCA
CAS# 13395-16-9 is listed on the TSCA
107
Inventory.
Section 16 - Other Information
MSDS Creation Date: 9/02/1997
Revision #7 Date 7/20/2009
The information above is believed to be accurate and represents the best information currently
available to us. However, we make no warranty of merchantibility or any other warranty, express or
implied, with respect to such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the information for their particular
purposes. In no event shall the company be liable for any claims, losses, or damages of any third party
or for lost profits or any special, indirect, incidental, consequential, or exemplary damages howsoever
arising, even if the company has been advised of the possibility of such damages.
108
Cutting Oil
AGS COMPANY PAGE 12 Cutting Grinding Oil
MATERIAL SAFETY DATA SHEET
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product: CG-13BK, CG-18, CG-18BK, CG-20BK, CG-55
Manufacturer:
AGS Company
Street Address:
2651 Hoyt St
City/ State/ Zip
Muskegon Ht s., MI 49444
Phone:
800 -253 -0403
Phone:
231 -733 -2101
FAX:
231 -733 -1784
Transportation Emergency: CHEM-TEL
Phone:
800 -255 -3924
Trade Name:
Common
Name:
Cut t ing and Grinding
Oil
Cut t ing and Grinding
Oil
Original Issue Date:
Revision No
11
10/2/1986
Date 12/10/2012
SECTION 2 - COMPOSITION/ INFORMATION ON INGREDIENTS
ITEM
1
2
3
4
5
Hydrotreated Heavy Napthenic Oil
Petroleum Sulfonic Acids, Sodium Salts
2-Butoxyethanol
4-(2-Nitrobutyl), Morpholine
4,4'-(2-Ethyl-2-Nitrotrimethylene) Dimorpholine
CAS NUMBER
64742-52-5
68608-26-4
111-76-2
2224-44-4
1854-23-5
WT/WT %
60-100
15-40
0.1-1
0.1-1
0.1-1
EXPOSURE LIMITS
ACGIH
ITEM
1
2
3
4
5
OSHA
TLV-TWA
TLV-STEL
PEL-TWA
PEL-CEILING
3
3
3
N.E.
5 mg/m skin
10 mg/m
5 mg/m
N.E.
N.E.
N.E.
N.E.
60 ppm (30
20 ppm
50 ppm
N.E.
min)
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
(See Section 16 for abbreviation legend)
SECTION 3 - HAZARDS IDENTIFICATION
Liquid may be irritating and can cause pain, tearing, reddening and
swelling.
Prolonged or repeated contact may result in irritation and/or
dermatitis.
EYE CONTACT:
SKIN CONTACT:
INHALATION:
INGESTION:
CHRONIC HAZARDS:
Primary Route(s)
Entry
of
Prolonged inhalation may cause headaches, dizziness and nausea.
This material may be harmful or fatal if
swallowed.
Overexposure
may
lead
to
dermatitis.
Skin and eye contact or ingestion.
SECTION 4 - FIRST AID MEASURES
EYE CONTACT: Immediately flush eyes with plenty of water. Get medical attention, if irritation persists.
SKIN CONTACT: Immediately flush with plenty of water. Remove clothing. Get
medical attention immediately. Wash clothing separately before reuse.
INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get immediate medical attention.
109
INGESTION: Get medical attention immediately. If swallowed, DO NOT induce vomiting. Give victim a glass of water or milk.
Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person.
MATERIAL SAFETY DATA SHEET
SECTION 5 - FIRE FIGHTING MEASURES
o
FLASH POINT:
C.O.C.
>350 F
LOWER EXPLOSIVE LIMIT:
UPPER EXPLOSIVE LIMIT:
AUTOGNITION TEMPERATURE:
N.D.
EXTINGUISHING MEDIA:
FOAM, CO2, DRY CHEMICAL, WATER FOG
N.D.
N.D.
%
%
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Avoid excessive mist and /or aerosol formation.
Mist or spray could ignite at temperature below the indicated flash point. Keep away from
flames.
Wear NIOSH/MSHA approved self-contained breathing apparatus
SPECIAL FIREFIGHTING PROCEDURES:
and
protective gear. Water spray may be utilized to cool containers.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
RECOVERY PROCEDURES:
Dike area to contain spill and clean up by absorbing on an inert material.
Do not flush into sewers or waterways. Non-essential personnel should not enter area due to slipping hazards
SECTION 7 - HANDLING AND STORAGE
HANDLING: Wash thoroughly after handling
STORAGE: Store in a cool, dry ventilated area away from heat, sparks and flame.
Keep containers closed when not in use.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Use in well ventilated area. Local exhaust sould be utilized to remove
fumes.
ENGINEERING CONTROLS:
RESPIRATORY PROTECTION:
For most conditions, no respiratory protection should be needed,
however, if high vapor concentration should develop, use a NIOSH approved organic vapor respirator.
SKIN PROTECTION:
Where contact is likely, wear chemical resistant gloves.
EYE PROTECTION:
Wear safety glasses with side shields or goggles.
OTHER PROTECTIVE EQUIPMENT: Eye wash in work area.
HYGIENIC PRACTICES: Wash hands before eating. Remove contaminated clothing and wash before reuse. Use
only in a well ventilated area. Follow all MSDS/label precautions even after container is emptied because they
may retain product residues. Avoid prolonged or repeated contact with eyes, skin, and clothing.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
BOILING RANGE
ODOR
o
>500 F
petroleum odor
VAPOR DENSITY:
>1
ODOR THRESHOLD
N.D.
EVAPORATION
APPEARANCE
Clear dark amber
N.D.
RATE
emulsifiable
VOC
NA
SOLUBILITY IN H2O
FREEZE POINT
N.D.
SPECIFIC GRAVITY 0.93 at 60oF
o
VAPOR PRESSURE
pH @ 5.0%
8 to 9
<[email protected] C
>
100SUS
o
PHYSICAL STATE
liquid
VISCOSITY:
@100 F
COEFFICIENT OF WATER / OIL DISTRIBUTION:
NEGLIGIBLE
(See Section 16 for abbreviation legend)
110
SECTION 10 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Sources of
ignition.
INCOMPATIBILITY:
HAZARDOUS
PRODUCTS
HAZARDOUS
POLYMERIZATION:
Strong acid or alkali, oxidizers and amines.
DECOMPOSITION Oxides of carbon, sulfur, nitrogen and sodium are
products of
combustion.
Will not occur under normal conditions
STABILITY: This product is stable under normal storage conditions.
AGS COMPANY
PRODUCT LD 50
Cutting Grinding
Oil
PAGE 12
MATERIAL SAFETY DATA SHEET
SECTION 11 - TOXICOLOGICAL PROPERTIES
mg/k
>5000
PRODUCT LC 50
g
Based on component data
SECTION 12 - ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION:
No Information
SECTION 13 - DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Dispose of in accordance with federal, state and local regulations.
SECTION 14 - TRANSPORTATION INFORMATION
DOT
PROPER
SHIPPING
NAME
DOT
TECHNICAL
NAME
DOT HAZARD CLASS
DOT UN / NA
NUMBER:
Not Regulated
HAZARD SUBCLASS: NA
PACKING GROUP: NA
RESP. GUIDE PAGE
SECTION 15 - REGULATORY INFORMATION
U.S FEDERAL REGULATIONS:
AS FOLLOWS -
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200)
CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed according to the EPA 'Hazard Categories'
promulgated under Sections 311 and 312 of the Superfund Amendment and
Reauthorization Act of 1986 (SARA Title III ) and is considered, under applicable
definitions, to meet the following categories:
Acute Health Hazard
SARA SECTION 313
This product contains the following substance subject to the reporting requirements
of Section 313 of Title of the Superfund Amendments and Reauthorization Act of
1986 and 40 CFR Part 372:
CHEMICAL NAME
CAS NUMBER
No SARA Section 313 components exist in this product
WT /WT % IS LESS THAN
111
TOXIC SUBSTANCE CONTROL ACT:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12 (B) if
exported from the United States:
CHEMICAL NAME
No information is available
CAS NUMBER
AGS COMPANY
Cutting
Grinding Oil
PAGE 12
MATERIAL SAFETY DATA SHEET
AS FOLLOWS U.S. STATE REGULATIONS:
NEW JERSEY RIGHT-TOKNOW:
The following materials are non-hazardous, but are among the top five components in this product:
CHEMICAL NAME
CAS NUMBER
No non-hazardous materials are among the top
five ingredients.
PENNSYLVANIA RIGHT-TO-Know
The following non-hazardous ingredients are present in the product
at greater than 3%:
CHEMICAL NAME
CAS NUMBER
No non-hazardous ingredients are present at
greater than 3%.
CALIFORNIA PROPOSITION
65:
WARNING: The chemical(s) noted below and contained in this product, are know to the state of California
to causes cancer, birth defects or other reproductive harm.
CHEMICAL NAME
CAS NUMBER
No Proposition 65 chemicals exist in this
product.
INTERNATIONAL
AS FOLLOWS REGULATIONS:
CANADIAN
This MSDS has been prepared in compliance with Controlled
WHMIS:
Product Regulations
except for use of the 16
headings.
No
information
CANADIAN WHMIS CLASS:
available.
SECTION 16 - OTHER
INFORMATION
Flammab
HMIS RATINGS:
Health
2
1 Phys. Haz.
0 PPE
ility
Flammab
NFPA
Health
2
1 Reactivity
0
ility
VOLATILE ORGANIC COMPOUNDS
NA
(VOCS):
LEGEND: N.A.
N.D.
Not Applicable
Not
Determined
N.E.
B
Not Established
112
Disclaimer: The information contained herein is base on data available. However, no warranty is expressed or
implied regarding the accuracy of the data or the results obtained from the use thereof. Because the
information contained herein may be applied under conditions beyond our control, we assume no responsibility for
its use.
113
Dry Chemical (Fire Extinguisher)
MATERIAL SAFETY DATA SHEET
SECTION: 1
PAGE 1 OF 4
DATE PREPARED:
REVISED:
MANUFACTURER:
PRODUCT IDENTIFICATION
Strike First Corporation
c/o Steel Fire Equipment
150 Superior Blvd.
Mississuaga, ON
L5T 2L2
Phone: 1-905-564-1500
ABC SUPER 90 DRY CHEMICAL
Multi-Purpose Dry Chemical
Fire Extinguisher
JUNE 01/06
April 2/2012
EMERGENCY PHONE:
Canutec: 1-613-996-6666
SECTION: 2
HAZARDOUS INGREDIENTS
%
CHEMICAL NAME
CAS #
*ACGIH
mg/m3
W/W TLV
Mono Ammonium Phosphate
Mica
Attaclay
Silicone Oil
Calcium Carbonate
Silica
Yellow Pigment
7722-76-1
12001-26-2
8031-18-3
63148-57-2
471-34-1
112926-00-8
5468-75-7
95*
<3
<3
<1
<1
<1
<1
3
NE
NE
NE
2
NE
STEL
*OSHA
mg/m3
PEL STEL
IDLH
NE
NE
NE
NE
NE
NE
3
NE
NE
NE
6
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
OTHER
NE
NE
NE
NE
NE
NE
*ACGIH TLV for particulars, not otherwise classified = 10; OSHA PEL for particulars not
otherwise regulated, Total dust =15 Respirable fraction 5.
NE = Not established
SECTION :3
PHYSICAL DATA
BOILING POINT
VAPOR PRESSURE
VAPOR DENSITY
SOLUBILITY IN WATER
SPECIFIC GRAVITY
PERCENT VOLATILE BY
VOLUME
EVAPORATION RATE
pH: (10% solution)
APPEARANCE &
COLOR
Not applicable
Not applicable
Not applicable
Not soluble. Water repellent coating.
Approximately 0.88
Not applicable
Not applicable
Approximately 9-10
This material is a finely divided yellow
powder.
114
MANUFACTURER: Strike First Corporation
PRODUCT IDENTIFICATION: ABC DRY CHEMICAL FIRE EXTINGUISHER
SECTION: 4
FIRE AND EXPLOSION DATA
FLASH POINT
FLAMMABLE LIMITS
EXTINGUISHING MEDIA
SPECIAL FIREFIGHTING
PROCEDURES
SECTION: 5
Not applicable
Lower (LEL) Not applicable
Upper (LEL) Not applicable
None This product is a fire extinguishing
agent.
Incipient fire responders should wear eye
protection. Structural fire fighters must
wear Self-Contained Breathing Apparatus
and full protective equipment.
HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE
OSHA PEL
EFFECTS OF OVEREXPOSURE
Acute
Chronic
*ACGIH TLV for particulars, Not otherwise
classified = 10
For particulars not otherwise regulated;
Total Dust =15, Respirable Fraction 5.
This extinguishing material presents only
a slight risk of causing acute health
effects. If such effects occur, they will be in
the form of mild irritation of the skin, nose, or
throat and moderate irritation of the eyes.
If ingested, this product may cause an
upset stomach.
This product is not known to cause
chronic illnesses or diseases.
EMERGENCY FIRST-AID PROCEDURES
SKIN EXPOSURE
If spilled on skin, immediately begin
decontamination with running water.
Remove exposed or contaminated clothing,
taking care not to contaminate eyes. If
reddening or irritation occurs, victim and
rescuers must seek immediate medical
attention.
EYE EXPOSURE
If chemical is splashed in eyes, open
victim's eyes while under gentle running
water. Use sufficient force to open eyelids.
Have victim "roll" eyes. Minimum flushing
is for 15 minutes.
115
MANUFACTURER: Strike First Corporation
PRODUCT IDENTIFICATION: ABC DRY CHEMICAL FIRE EXTINGUISHER
SECTION: 5
EMERGENCY FIRST-AID PROCEDURES
INHALATION
SECTION: 6
SECTION: 7
If chemical is inhaled, remove victim to
fresh air. If necessary, use artificial
respiration to support vital functions. If
reddening or irritation occurs, victim and
rescuers must seek immediate medical
attention.
REACTIVITY DATA
STABILITY
INCOMPATIBILITY
Stable
Strong acids. Reacts violently with lithium.
HAZARDOUS
DECOMPOSITION PRODUCT
Carbon monoxide and carbon dioxide
HAZARDOUS
POLYMERIZATION
Will not occur
SPILL OR LEAK PROCEDURES
SMALL SPILLS
Sweep up the spilled solid and place all
spill residue in a double plastic bag and
seal.
LARGE SPILLS
If it is determined that exposure guidelines
for nuisance particulates - 10 mg/m3
(total particulates) or 5 mg/m3 (respirable
particulates) is exceeded use Level C:
triple gloves (rubber gloves with nitrile gloves,
over latex gloves), chemically resistant
suit and boots, hard hat, and air purifying
respirator with a HEPA filter. Sweep or vacuum.
Dispose of in accordance with Federal, Provincial
and local hazardous waste disposal regulations
MANUFACTURER: Strike First Corporation
PRODUCT IDENTIFICATION: ABC DRY CHEMICAL FIRE EXTINGUISHER
116
SECTION: 8
SPECIAL PROTECTION INFORMATION
RESPIRATORY
PROTECTION
VENTILATION
PROTECTIVE GLOVES
EYE PROTECTION
OTHER PROTECTIVE
EQUIPMENT:
SECTION: 9
Respiratory protection is not expected to
be needed. Maintain airborne contaminant
concentrations below guidelines for
nuisance particulates: (see Section 5)
Use with adequate ventilation. Use a
mechanical fan or vent area to outside.
Wear rubber gloves for routine industrial
use.
Safety glasses.
Use body protection appropriate for task.
SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
All employees who handle this material should be trained to handle it
safety. Avoid breathing dusts generated by this product.
Avoid getting chemicals ON YOU or IN YOU.
OTHER PRECAUTIONS:
None
SECTION: 10
TRANSPORTATION
Hazard Class or Division:
Fire Extinguisher,
Class 2.2
UN 1044
For additional information contact Strike First Corporation
No harm to the environment is expected from this preparation
Fire extinguishers are designed and produced for the specific purpose of providing a safe and efficient
safety tool to be used only in the fighting of fires. Improper or careless use may cause severe bodily injury
and/or property damage.
Contents are under pressure which is necessary to deliver the contained extinguishing agent to the fire
source.
Contents under pressure. Do not puncture, incinerate or discharge into another person's face.
Do not store at high temperatures above 120 degrees Farenheit or 49 degrees Celcius.
Keep away from children.
Avoid inhaling the extinguishing agent. Avoid inhaling smoke and fumes - all fires release toxic
substances that are hamful. DO NOT remain in a closed area after use: evacuate the area
immediately and ventilate thoroughly before re-entering.
Although extinguishing agents are non toxic when used properly, contact with them may cause
irritation to eyes, nose, throat and other allergic symptoms.
117
Duct Tape
MATERIAL SAFETY DATA SHEET 3M™ Duct Tape 3900, 3939, 6969 & 3M™ General Use Duct Tape 2929 &
3M™ Outdoor Masking and Stucco Tape 5959 & 3M™ Performance Plus Duct Tape 8979 & 8979N & 3M™
Value Duct Tape 1900 & Scotch(r) Polyethylene Coated Cloth Tape 390 02/02/10
Material Safety Data Sheet
Copyright, 2010, 3M Company. All rights reserved. Copying and/or downloading of this information for the
purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no
changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or
otherwise distributed with the intention of earning a profit thereon.
This material safety data sheet (MSDS) is provided as a courtesy in response to a customer request. This
product is not regulated under, and a MSDS is not required for this product by the OSHA Hazard
Communication Standard (29 CFR 1910.1200) because, when used as recommended or under ordinary
conditions, it should not present a health and safety hazard. However, use or processing of the product not in
accordance with the product's recommendations or not under ordinary conditions may affect the performance
of the product and may present potential health and safety hazards.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M™ Duct Tape 3900, 3939, 6969 & 3M™ General Use Duct Tape 2929 &
3M™ Outdoor Masking and Stucco Tape 5959 & 3M™ Performance
Plus Duct Tape 8979 & 8979N & 3M™ Value Duct Tape 1900 &
Scotch(r) Polyethylene Coated Cloth Tape 390
MANUFACTURER:
3M
DIVISION:
Industrial Adhesives and Tapes Division
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 02/02/10
Supercedes Date: 02/02/10
Document Group: 26-2650-5
Product Use:
Specific Use:
Intended Use:
Bundling, Reinforcing, & Sealing
Industrial use
SECTION 2: INGREDIENTS
Ingredient
Polyethylene Film over Cloth Scrim Backing
Rubber Adhesive
C.A.S. No.
None
Trade Secret
% by Wt
51 - 99
1 - 49
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Odor, Color, Grade: various colored duct tape
119
General Physical Form: Solid
Immediate health, physical, and environmental hazards: The environmental properties of this product present a
low environmental hazard. This product, when used under reasonable conditions and in accordance with the 3M
directions for use, should not present a health hazard. However, use or processing of the product in a manner not in
accordance with the product's directions for use may affect the performance of the product and may present
potential health and safety hazards.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
No health effects are expected.
Skin Contact:
No health effects are expected.
Inhalation:
No health effects are expected.
Ingestion:
No health effects are expected.
2.
POTENTIAL ENVIRONMENTAL EFFECTS
This substance does not leach metals or other RCRA (Resource Conservation and Recovery Act) listed TCLP (Toxic
Characteristic Leaching Procedure) hazardous substances at concentrations that would make the product a
hazardous waste.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial
hygiene practices are followed.
Eye Contact:
Skin Contact:
Inhalation:
If Swallowed:
No need for first aid is anticipated.
No need for first aid is anticipated.
No need for first aid is anticipated.
No need for first aid is anticipated.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature
Flash Point
Flammable Limits - LEL
Flammable Limits - UEL
Not Applicable
Not Applicable
Not Applicable
Not Applicable
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
120
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained
breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards:
No unusual fire or explosion hazards are anticipated.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures:
Not applicable.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
This product is considered to be an article which does not release or otherwise result in exposure to a
hazardous chemical under normal use conditions.
7.2 STORAGE
Not applicable.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Not applicable.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact.
8.2.2 Skin Protection
Avoid prolonged or repeated skin contact.
8.2.3 Respiratory Protection
Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory
protection.
8.2.4 Prevention of Swallowing
Not applicable.
8.3 EXPOSURE GUIDELINES
None Established
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
121
Odor, Color, Grade:
General Physical Form:
Autoignition temperature
Flash Point
Flammable Limits - LEL
Flammable Limits - UEL
Boiling point
Density
Vapor Density
various colored duct tape
Solid
Not Applicable
Not Applicable
Not Applicable
Not Applicable
Not Applicable
Not Applicable
Not Applicable
Vapor Pressure
Not Applicable
Specific Gravity
pH
Melting point
Not Applicable
Not Applicable
Not Applicable
Solubility in Water
Evaporation rate
Volatile Organic Compounds
Kow - Oct/Water partition coef
Percent volatile
VOC Less H2O & Exempt Solvents
Viscosity
Nil
Not Applicable
Not Applicable
Not Applicable
Not Applicable
Not Applicable
Not Applicable
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid
10.1
Conditions to avoid
None known
10.2
Materials to avoid
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition: Under recommended usage conditions, hazardous decomposition products are not
expected. Hazardous decomposition products may occur as a result of oxidation, heating, or reaction with another
material.
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this
material and/or its components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
122
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Reclaim if feasible. If product can't be reclaimed, dispose of waste product in a
sanitary landfill. Alternatively, incinerate the waste product in an industrial, commercial, or municipal
incinerator.
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
These transportation classifications are provided as a customer service. As the shipper YOU remain responsible
for complying with all applicable laws and regulations, including proper transportation classification and
packaging. 3M’s transportation classifications are based on product formulation, packaging, 3M policies and 3M’s
understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification
information. This information applies only to transportation classification and not the packaging, labeling, or
marking requirements. The original 3M package is certified for U.S. ground shipment only. If you are shipping by air
or ocean, the package may not meet applicable regulatory requirements.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No
Reactivity Hazard - No
Immediate Hazard - No
Delayed Hazard - No
STATE REGULATIONS
Contact 3M for more information.
CHEMICAL INVENTORIES
This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 0 Flammability: 1
Reactivity: 0 Special Hazards: None
123
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel
to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill,
or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the
material but also include the toxic properties of combustion or decomposition products that are known to be
generated in significant quantities.
Revision Changes:
Section 2: Product identification comment was deleted.
Section 1: Product name was modified.
Page Heading: Product name was modified.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date
issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.
User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's
method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M
product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that
electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no
representations as to its completeness or accuracy. In addition, information obtained from a database may not be
as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
124
Electrical Insulating Varnish
DOW CORNING CORPORATION
Material Safety Data Sheet
DOW CORNING(R) 997 VARNISH
1. PRODUCT AND COMPANY IDENTIFICATION
24 Hour Emergency Telephone: (989) 496-5900
Customer Service: (989) 496-6000
Product Disposal Information: (989) 496-6315
CHEMTREC: (800) 424-9300
Dow Corning Corporation
South Saginaw Road
Midland, Michigan 48686
Revision
2011/11/01
MSDS No.: 01002015
Generic Description:
Physical Form:
Color:
Odor:
Silicone resin.
Liquid
Brown
Solvent odor.
NFPA Profile: Health 2 Flammability 3 Instability/Reactivity
0
Note: NFPA = National Fire Protection Association
2. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
Acute Effects
Eye:
Direct contact may cause mild irritation. Vapor may cause eye irritation.
Skin:
May cause severe irritation.
Inhalation:
drowsiness,
Vapor may irritate nose and throat. Overexposure by inhalation may cause
dizziness, confusion or loss of coordination.
Oral:
Low ingestion hazard in normal use.
Prolonged/Repeated Exposure Effects
Skin:
may result in
Repeated or prolonged contact may cause defatting and drying of skin which
skin irritation and dermatitis.
125
Date:
Inhalation:
Kidneys. Nervous
Overexposure by inhalation may injure the following organ(s): Liver.
system.
Oral:
Repeated ingestion or swallowing large amounts may injure internally.
Other Health Effects
This product contains a chemical(s) that has the following effect(s):
Developmental Toxicity
Carcinogenicity
See Section 11 for specific details.
Signs and Symptoms of Overexposure
No known applicable information.
Medical Conditions Aggravated by Exposure
No known applicable information.
The above listed potential effects of overexposure are based on actual data, results of studies performed upon
similar compositions, component data and/or expert review of the product. Please refer to Section 11 for the
detailed toxicology information.
3. COMPOSITION/INFORMATION ON INGREDIENTS
CAS Number
Wt %
Component Name
1330-20-7
30.0 - 50.0
Xylene
100-41-4
10.0 - 30.0
Ethylbenzene
8001-26-1
3.0 - 7.0
Linseed Oil
64742-94-5
3.0 - 7.0
Heavy aromatic petroleum solvent naphtha
91-20-3
<1.0
Naphthalene
The above components are hazardous as defined in 29 CFR 1910.1200.
4. FIRST AID MEASURES
Eye:
Remove from the source of contamination or move to fresh air Immediately
flush the
contaminated eye(s) with lukewarm, gently flowing water for 5 minutes while
holding the
eyelid(s) open. Obtain medical attention.
126
As quickly as possible remove contaminated clothing, shoes and leather
goods (e.g.
Skin:
watchbands, belts). Quickly and gently blot or brush away excess chemical.
Immediately
flush with lukewarm gently flowing water for 15 minutes. Completely
decontaminate clothing,
shoes and leather goods before reuse or discard. Immediately obtain medical
attention.
Inhalation:
Remove from the source of contamination or move to fresh air. Obtain medical
attention.
Oral:
If irritation or discomfort occur, obtain medical advice.
Notes to Physician:
Treat according to person's condition and specifics of exposure.
5. FIRE FIGHTING MEASURES
Flash Point:
77 °F / 25 °C (Pensky-Martens Closed Cup)
Autoignition
Temperature:
Flammability
Air:
Not determined.
Limits
Extinguishing Media:
in
Not determined.
On large fires use dry chemical, foam or water spray. On small fires use
carbon dioxide
(CO2), dry chemical or water spray. Water can be used to cool fire exposed
containers.
Self-contained breathing apparatus and protective clothing should be worn in
Fire Fighting Measures: fighting large
fires involving chemicals. Determine the need to evacuate or isolate the area
according to
your local emergency plan. Use water spray to keep fire exposed containers
cool.
Unusual Fire Hazards:
Vapors are heavier than air and may travel to a source of ignition and flash
back. Static
electricity will accumulate and may ignite vapors. Prevent a possible fire
hazard by bonding
and grounding or inert gas purge.
127
6. ACCIDENTAL RELEASE MEASURES
Containment/Clean up:
Remove possible ignition sources. Determine whether to evacuate or isolate the area
according to your local emergency plan. Observe all personal protection equipment
recommendations described in Sections 5 and 8. For large spills, provide diking or
other
appropriate containment to keep material from spreading. If diked material can
be pumped, store recovered material in appropriate container. Clean up
remaining materials from spill with suitable absorbant. Clean area as appropriate
since spilled materials, even in small quantities, may present a slip hazard. Final
cleaning may require use of steam, solvents or detergents. Dispose of saturated
absorbant or cleaning materials appropriately, since spontaneous heating may
occur. Local, state and federal laws and regulations may apply to releases and
disposal of this material, as well as those materials and items employed in the
cleanup of releases. You will need to determine which federal, state and local laws
and regulations are applicable. Sections 13 and 15 of this MSDS provide
information regarding certain federal and state requirements.
Note: See Section 8 for Personal Protective Equipment for Spills. Call (989) 496-5900, if additional information is
required.
7. HANDLING AND STORAGE
Use with adequate ventilation. Traces of benzene (carcinogen) may form if heated in air above 300°F (149°C).
Provide ventilation to control vapor exposure within inhalation guidelines when handling at elevated
temperatures. Review the OSHA benzene regulation for detailed information on safe handling requirements.
Avoid eye exposure. Do not get on skin. Avoid breathing vapor, mist, dust, or fumes. Keep container closed. Do
not take internally.
Static electricity will accumulate and may ignite vapors. Prevent a possible fire hazard by bonding and grounding
or inert gas purge. Keep container closed and away from heat, sparks, and flame.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Component Exposure Limits
CAS Number
Component Name
1330-20-7
Xylene
100-41-4
Ethylbenzene
64742-94-5
91-20-3
Heavy aromatic petroleum solvent
naphtha
Naphthalene
Exposure Limits
Observe xylene limits. OSHA PEL (final rule) and
ACGIH
TLV: TWA 100 ppm, STEL 150 ppm.
OSHA PEL (final rule): TWA 100 ppm, 435 mg/m3.
ACGIH
TLV: TWA 20 ppm, STEL 125 ppm.
Observe petroleum distillates limits. OSHA PEL (final
rule):
TWA 400 ppm.
OSHA PEL (final rule): TWA 10 ppm and ACGIH TLVskin:
TWA 10 ppm, STEL 15 ppm.
Engineering Controls
128
Local Ventilation:
General Ventilation:
Recommended.
Recommended.
Personal Protective Equipment for Routine Handling
Eyes:
Use chemical worker's goggles.
Skin:
Wash at mealtime and end of shift. Skin contact must be avoided by using impervious
protective clothing (gloves, aprons, boots, etc.). Use chemical protective gloves as a
minimum and wash skin promptly upon any skin contact.
Avoid skin contact by implementing good industrial hygiene practices and procedures.
Select
and use gloves and/or protective clothing to further minimize the potential for skin
contact.
Consult with your glove and/or personnel protective equipment manufacturer for
selection of
appropriate
compatible
materials.
Use respiratory protection unless adequate local exhaust ventilation is provided or
exposure
assessment demonstrates that exposures are within recommended exposure
guidelines. IH
personnel can assist in judging the adequacy of existing engineering controls.
Suitable Gloves:
Inhalation:
Suitable Respirator:
General and local exhaust ventilation is recommended to maintain vapor
exposures below
recommended limits. Where concentrations are above recommended limits or are
unknown,
appropriate respiratory protection should be worn. Follow OSHA respirator
regulations (29
CFR 1910.134) and use NIOSH/MSHA approved respirators.
Personal Protective Equipment for Spills
Eyes:
Skin:
Inhalation/Suitable
Respirator:
Precautionary Measures:
Use full face respirator.
Wash at mealtime and end of shift. Skin contact must be avoided by using
impervious
protective clothing (gloves, aprons, boots, etc.). Use chemical protective gloves as
a
minimum and wash skin promptly upon any skin contact.
Respiratory protection recommended. Follow OSHA Respirator Regulations (29 CFR
1910.134) and use NIOSH/MHSA approved respirators. Protection provided by air
purifying
respirators against exposure to any hazardous chemical is limited. Use a positive
pressure air
supplied respirator if there is any potential for uncontrolled release, exposure
levels are
unknown, or any other circumstance where air purifying respirators may not
provide adequate
protection.
Avoid eye exposure. Do not get on skin. Avoid breathing vapor, mist, dust, or
fumes. Keep
container closed. Do not take internally. Use reasonable care.
129
Comments:
Traces of benzene (carcinogen) may form if heated in air above 300°F (149°C).
Provide
ventilation to control vapor exposure within inhalation guidelines when handling at
elevated
temperatures. Review the OSHA benzene regulation for detailed information on
safe
handling requirements.
When heated to temperatures above 150°C (300°F) in the presence of air, product can
form formaldehyde vapors. Formaldehyde is a potential cancer hazard and a known skin
and respiratory sensitizer. Vapors irritate eyes, nose, and throat. Safe handling
conditions may be maintained by keeping vapor conditions within the OSHA permissible
exposure limit for formaldehyde.
Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications
may require added precautions. For further information regarding aerosol inhalation toxicity, please refer to the
guidance document regarding the use of silicone-based materials in aerosol applications that has been developed by the
silicone industry (www.SEHSC.com) or contact the Dow Corning customer service group.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical Form: Liquid
Color: Brown
Odor: Solvent odor.
Specific Gravity @ 25°C: 1.002
Viscosity: 105 cSt
Freezing/Melting Point: Not determined.
Boiling Point: > 130 °C
Vapor Pressure @ 25°C: Not determined.
Vapor Density: Not determined.
Solubility in Water: Not determined.
pH: Not determined.
Volatile Content: Not determined.
Flash Point: 77 °F / 25 °C (Pensky-Martens Closed Cup)
Autoignition Temperature: Not determined.
Flammability Limits in Air: Not determined.
Note: The above information is not intended for use in preparing product specifications. Contact Dow
Corning before writing specifications.
10. STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Hazardous
Polymerization:
Conditions to Avoid:
Hazardous polymerization will not occur.
Materials to Avoid:
Oxidizing material can cause a reaction.
None.
Hazardous Decomposition Products
130
Thermal breakdown of this product during fire or very high heat conditions may evolve the following
decomposition products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon
dioxide. Metal oxides. Formaldehyde.
11. TOXICOLOGICAL INFORMATION
Special Hazard Information on Components
Carcinogens
CAS Number
100-41-4
Wt %
Component Name
10.0 - 30.0 Ethylbenzene
91-20-3
<1.0
Naphthalene
IARC Group 2B - Possibly
Carcinogenic
to Humans.
IARC Group 2B - Possibly
Carcinogenic
to Humans.
NTP - Reasonably Anticipated to be
a
Human Carcinogen.
Developmental Toxicity
CAS Number
1330-20-7
Wt %
30.0 - 50.0
Component Name
Xylene
12. ECOLOGICAL INFORMATION
Environmental Fate and Distribution
Complete information is not yet available.
Environmental Effects
Complete information is not yet available.
Fate and Effects in Waste Water Treatment Plants
Complete information is not yet available.
Ecotoxicity Classification Criteria
Hazard Parameters (LC50 or EC50)
High
Medium
Low
Acute Aquatic Toxicity (mg/L)
<=1
>1 and <=100
>100
Acute Terrestrial Toxicity
<=100
>100 and <= 2000
>2000
This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993.
This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please
read the other information presented in the section concerning the overall ecological safety of this material.
13. DISPOSAL CONSIDERATIONS
131
RCRA Hazard Class (40 CFR 261)
When a decision is made to discard this material, as received, is it classified as a hazardous waste? Yes
Characteristic Waste:
Ignitable:
TCLP:
D001
D018
State or local laws may impose additional regulatory requirements regarding disposal. Call (989) 496-6315, if
additional information is required.
14. TRANSPORT INFORMATION
DOT Road Shipment Information (49 CFR 172.101)
Proper Shipping Name:
Flammable liquids, n.o.s.
Hazard Technical Name:
Xylene / Ethylbenzene
Hazard Class:
3
UN/NA Number:
UN 1993
Packing Group:
III
Hazard Label(s):
Flammable Liquid
Ocean Shipment (IMDG)
Proper Shipping Name:
FLAMMABLE LIQUID, N.O.S.
Hazard Technical Name:
Xylene / Ethylbenzene
Hazard Class:
3
UN/NA Number:
UN 1993
Packing Group:
III
Hazard Label(s):
flammable liquid
Air Shipment (IATA)
Proper Shipping Name:
Flammable liquid, n.o.s.
Hazard Technical Name:
Xylene / Ethylbenzene
Hazard Class:
3
UN/NA Number:
UN 1993
Packing Group:
III
132
Hazard Label(s):
Flammable Liquid
Call Dow Corning Transportation, (989) 496-8577, if additional information is required.
15. REGULATORY INFORMATION
Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
TSCA Status: All chemical substances in this material are included on or exempted from listing on the TSCA
Inventory of Chemical Substances.
EPA SARA Title III Chemical Listings
Section 302 Extremely Hazardous Substances (40 CFR 355):
None.
Section 304 CERCLA Hazardous Substances (40 CFR 302):
CAS Number
Wt %
Component Name
1330-20-7
35.0
Xylene
100-41-4
11.0
Ethylbenzene
91-20-3
0.46
Naphthalene
Section 311/312 Hazard Class (40 CFR 370):
Acute: Yes
Chronic: Yes
Fire: Yes
Pressure: No
Reactive: No
Section 313 Toxic Chemicals (40 CFR 372):
CAS Number
Wt %
Component Name
1330-20-7
35.0
Xylene
100-41-4
11.0
Ethylbenzene
91-20-3
0.46
Naphthalene
Note: Chemicals are listed under the 313 Toxic Chemicals section only if they meet or exceed a reporting
threshold.
Supplemental State Compliance Information
California
Warning: This product contains the following chemical(s) listed by the State of California under the Safe
Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth
defects or other reproductive harm.
133
CAS Number
100-41-4
Wt %
Component Name
Ethylbenzene
Carcinogenic.
91-20-3
10.0000 30.0000
<1.0000
Naphthalene
Carcinogenic.
108-88-3
<0.1000
Toluene
Developmental toxin.
136-52-7
<0.1000
Cobalt bis(ethylhexanoate)
Carcinogenic.
62-53-3
<0.0100
Aniline
Carcinogenic.
Massachusetts
CAS Number
Wt %
Component Name
1330-20-7
30.0 - 50.0
Xylene
100-41-4
10.0 - 30.0
Ethylbenzene
62-53-3
<0.1
Aniline
CAS Number
Wt %
Component Name
68037-66-1
40.0 - 60.0
Dimethyl, methyl, phenyl, phenylmethyl silicone resin
1330-20-7
30.0 - 50.0
Xylene
100-41-4
10.0 - 30.0
Ethylbenzene
8001-26-1
3.0 - 7.0
Linseed Oil
64742-94-5
3.0 - 7.0
Heavy aromatic petroleum solvent naphtha
New Jersey
91-20-3
<1.0
Naphthalene
Wt %
Component Name
Pennsylvania
CAS Number
68037-66-1
40.0 - 60.0
Dimethyl, methyl, phenyl, phenylmethyl silicone resin
1330-20-7
30.0 - 50.0
Xylene
100-41-4
10.0 - 30.0
Ethylbenzene
8001-26-1
3.0 - 7.0
Linseed Oil
134
64742-94-5
3.0 - 7.0
Heavy aromatic petroleum solvent naphtha
16. OTHER INFORMATION
Prepared by: Dow Corning Corporation
These data are offered in good faith as typical values and not as product specifications. No warranty, either
expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are
believed to be generally applicable. However, each user should review these recommendations in the specific
context of the intended use and determine whether they are appropriate.
(R) indicates Registered Trademark
135
Epoxy Resin
Material Safety Data Sheet
1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION
24-Hour Emergency Phone Number: 989-636-4400
Product: D.E.R.* 332 EPOXY RESIN
Product Code: 19251
Effective Date: 04/16/04
002199
Date Printed: 04/17/04
MSD:
The Dow Chemical Company, Midland, MI 48674
Customer Information Center: 800-258-2436
2. COMPOSITION/INFORMATION ON INGREDIENTS
Diglycidyl Ether of Bisphenol A
CAS# 001675-54-3
100%
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
************************************************************************
*
Yellow liquid.
Mild odor.
May cause allergic skin reaction. *
************************************************************************
POTENTIAL HEALTH EFFECTS (See Section 11 for toxicological data.)
EYE: May cause slight temporary eye irritation. Corneal injury is unlikely.
SKIN: Has caused allergic skin reactions in humans. Prolonged exposure not likely to cause significant skin
irritation. Repeated contact may cause skin irritation with local redness. Prolonged skin contact is
unlikely to result in absorption of harmful amounts.
INGESTION: Very low toxicity if swallowed. Harmful effects not anticipated from swallowing small
amounts.
INHALATION:
Vapors are unlikely due to physical properties.
SYSTEMIC (OTHER TARGET ORGAN) EFFECTS: Except for skin sensitization, repeated exposures to low
molecular weight epoxy resins of this type are not anticipated to cause any significant adverse effects.
CANCER INFORMATION: Many studies have been conducted to assess the potential carcinogenicity of
diglycidyl ether of bisphenol A (DGEBPA). Although some weak evidence of carcinogenicity has been
reported in animals, when all of the data are considered, the weight of evidence does not show that
DGEBPA is carcinogenic. Indeed, the most recent review of the available data by the International
Agency for Research on Cancer (IARC) has concluded that DBEBPA is not classified as a carcinogen.
136
TERATOLOGY (BIRTH DEFECTS): DGEBPA did not cause birth defects or other adverse effects on the fetus
when pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when
pregnant rats or rabbits were exposed orally.
REPRODUCTIVE EFFECTS: In animal studies, did not interfere with reproduction.
4. FIRST AID
EYES: Flush eyes thoroughly with water for several minutes. Remove contact lenses after initial 1-2
minutes and continue flushing for several additional minutes. If effects occur, consult a physician,
preferably an ophthalmologist.
SKIN: Wash skin with plenty of water. Items which cannot be decontaminated, including leather articles
such as shoes, belts, and watchbands should be disposed of properly.
INGESTION:
No emergency medical treatment necessary.
INHALATION: Move person to fresh air; if effects occur, consult a physician.
NOTE TO PHYSICIAN: Consider additional thorough skin wash with mild non-abrasive soap and plenty of
warm water for at least 15 minutes. No specific antidote. Treatment of exposure should be directed
at the control of symptoms and the clinical condition of the patient.
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
FLASH POINT:
485, 252C
METHOD USED:
PMCC
AUTOIGNITION TEMPERATURE:
Not applicable
FLAMMABILITY LIMITS
LFL:
Not applicable
UFL:
Not applicable
HAZARDOUS COMBUSTION PRODUCTS: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: phenolic compounds, carbon monoxide, carbon dioxide.
OTHER FLAMMABILITY INFORMATION: Container may rupture from gas generation in a fire situation.
Violent steam generation or eruption may occur upon application of direct water stream to hot
liquids. Dense smoke is emitted when burned without sufficient oxygen.
EXTINGUISHING MEDIA: Water fog or fine spray, dry chemical fire extinguishers, carbon dioxide fire
extinguishers and foam. Do not use direct water stream. May spread fire. Alcohol resistant foams
(ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may
function, but will be less effective. Water fog, applied gently may be used as a blanket for fire
extinguishment.
FIRE FIGHTING INSTRUCTIONS: Keep people away. Isolate fire area and deny unnecessary entry. Use
water spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has passed. Fight fire from protected location or safe distance. Consider use of unmanned
hose holder or monitor nozzles. Immediately withdraw all personnel from area in case of rising sound
from venting safety device or discoloration of the container. Do not use direct water stream. May
spread fire. Move container from fire area if this is possible without hazard. Burning liquids may be
moved by flushing with water to protect personnel and minimize property damage. Water fog,
applied gently may be used as a blanket
137
for fire extinguishment.
PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS: Wear positive pressure self-contained breathing apparatus
(SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, pants, boots, and
gloves). If protective equipment is not available or not used, fight fire from a protected location or
safe distance.
6. ACCIDENTAL RELEASE MEASURES (See Section 15 for Regulatory Information)
PROTECT PEOPLE: Isolate area. Keep unnecessary and unprotected personnel from entering the area. Use
appropriate safety equipment. For additional information, refer to Section 8, Exposure
Controls/Personal Protection. Refer to Section 7, Handling, for additional precautionary measures.
PROTECT THE ENVIRONMENT: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information.
CLEANUP: Absorb with material such as sand or polypropylene or polyethylene fiber products. Collect in
suitable and properly labeled containers. Remove residual with soap and hot water.
Solvents are not recommended for clean up unless the recommended exposure guidelines and safe
handling practices for the specific solvent are followed. Consult appropriate solvent SDS for handling
information and exposure guidelines.
7. HANDLING AND STORAGE
HANDLING: Avoid contact with skin and clothing. Wash thoroughly after handling. See Section 8,
Exposure Controls/Personal Protection.
STORAGE: Recommended pumping and storage temperature range is 125F to 140F (51C to 60C).
Additional storage information on this product may be obtained by calling your Dow sales or
customer service contact. Ask for a product brochure.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: Good general ventilation should be sufficient for most conditions.
PERSONAL PROTECTIVE EQUIPMENT
EYE/FACE PROTECTION:
Use safety glasses.
SKIN PROTECTION: Use protective clothing chemically resistant to this material. Selection of specific
items such as face-shield, gloves, boots, apron or full body suit will depend on operation. Remove
contaminated clothing immediately, wash skin area with soap and water, and launder clothing
before reuse or dispose of properly. Items which cannot be decontaminated, such as shoes, belts
and watchbands, should be removed and disposed of properly.
RESPIRATORY PROTECTION: No respiratory protection should be needed.
EXPOSURE GUIDELINE(S):
None established.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE/PHYSICAL STATE:
ODOR:
Mild
VAPOR PRESSURE:
Not applicable
VAPOR DENSITY:
Not applicable
BOILING POINT:
Not applicable
SOLUBILITY IN WATER:
None
SPECIFIC GRAVITY:
1.16
Yellow liquid
138
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY: Stable under recommended storage conditions. See Storage, Section 7.
CONDITIONS TO AVOID: Avoid temperatures above 350C, 662F. Potentially violent decomposition can
occur above 350C, 662F. Generation of gas during decomposition can cause pressure in closed
systems. Pressure build-up can be rapid.
INCOMPATIBILITY WITH OTHER MATERIALS: Avoid contact with: oxidizing materials, acids, bases. Avoid
unintended contact with amines.
HAZARDOUS DECOMPOSITION PRODUCTS: Decomposition products depend upon temperature, air
supply and the presence of other materials. Gases are released during decomposition. Uncontrolled
exothermic reaction of epoxy resins release phenolics, carbon monoxide and water.
HAZARDOUS POLYMERIZATION: Will not occur by itself. Masses of more than one pound (0.5kg) of
product plus an aliphatic amine will cause irreversible polymerization with considerable heat buildup.
11. TOXICOLOGICAL INFORMATION (See Section 3 for Potential Health Effects. For detailed toxicological data, write
or call the ad
SKIN:
The LD50 for skin absorption in rabbits is 20,000 mg/kg.
INGESTION:
The oral LD50 for rats is >5000 mg/kg.
MUTAGENICITY (EFFECTS ON GENETIC MATERIAL): Animal genetic toxicity studies were negative. In vitro
genetic toxicity studies were negative in some cases and positive in other cases.
12. ECOLOGICAL INFORMATION (For detailed Ecological data, write or call the address or non-emergency number
shown in Section 1)
ENVIRONMENTAL FATE
MOVEMENT & PARTITIONING: Bioconcentration potential is moderate (BCF between 100 and 3000 or
Log Pow between 3 and 5). Measured log octanol/water partition coefficient (log Pow)
is 3.7-3.9. Potential for mobility in soil is low (Koc between 500 and 2000). Soil organic
carbon/water partition coefficient (Koc) is estimated to be 1800-4400. Henry's Law Constant (H) is
estimated to be <6.94E-09 atm-m3/mole. Log octanol/water partition coefficient (log Pow) is
estimated, using a structural fragment method, to be 3.84.
DEGRADATION & PERSISTENCE: Theoretical oxygen demand (ThOD) is calculated to be 2.35 p/p. In the
atmospheric environment, material is estimated to have a tropospheric half-life of 1.92 hr.
Biodegradation reached in Modified Zahn-Wellens/EMPA Test (OECD Test No. 302B) after 28 days:
12%. The 20-Day Biochemical Oxygen Demand (BOD20) is <2.5%.
ECOTOXICOLOGY: Material is moderately toxic to aquatic organisms on an acute basis (LC50 or EC50
between 1 and 10 mg/L in the most sensitive species tested). Acute LC50 in water flea Daphnia
magna is 1.3 mg/L. Acute LC50 in fathead minnow (Pimephales promelas) is 3.1 mg/L. Toxicity to
aquatic species occurs at concentrations greater than water solubility. Maximum acceptable
toxicant concentration (MATC) in water flea Daphnia magna is 0.55 mg/L. Growth inhibition
threshold in bacteria is >42.6 mg C/L. Inhibitory concentration (IC50) in OECD Activated Sludge
Respiration Inhibition Test (OECD Test No. 209) is >100 mg/L.
13. DISPOSAL CONSIDERATIONS (See Section 15 for Regulatory Information)
DISPOSAL: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All
disposal methods must be in compliance with all Federal, State/Provincial and local laws and
139
regulations. Regulations may vary in different locations. Waste characterizations and compliance with
applicable laws are the responsibility solely of the waste generator.
THE DOW CHEMICAL COMPANY HAS NO CONTROL OVER THE MANAGEMENT
PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR
USING THIS MATERIAL.
THE INFORMATION PRESENTED HERE PERTAINS
ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION 2
(Composition/Information On Ingredients).
FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed,
permitted: recycler, reclaimer, incinerator or other thermal destruction device.
As a service to its customers, Dow can provide names of information resources to help identify waste
management companies and other facilities which recycle, reprocess or manage chemicals or plastics,
and that manage used drums. Telephone Dow's Customer Information Center at 800-258-2436 or
989-832-1556 for further details.
14. TRANSPORT INFORMATION
DEPARTMENT OF TRANSPORTATION (D.O.T.): For D.O.T. regulatory information, if required, consult
transportation regulations, product shipping papers or contact your Dow representative.
CANADIAN TDG INFORMATION: For TDG regulatory information, if required, consult transportation
regulations, product shipping papers, or contact your Dow representative.
15. REGULATORY INFORMATION (Not meant to be all-inclusive--selected regulations represented)
NOTICE: The information herein is presented in good faith and believed to be accurate as of the effective date
shown above. However, no warranty, express or implied is given. Regulatory requirements
are subject to change and may differ from one location to another; it is the buyer's responsibility to ensure that its
activities comply with federal, state or provincial, and local laws. The following specific information is made for the
purpose of complying with numerous federal, state or provincial, and local laws and regulations. See other sections
for health and safety information.
U.S. REGULATIONS
SARA 313 INFORMATION: To the best of our knowledge, this product contains no chemical subject to SARA Title III
Section 313 supplier notification requirements.
--------------------SARA HAZARD CATEGORY: This product has been reviewed according to the EPA "Hazard Categories" promulgated
under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is
considered, under applicable definitions, to meet the following categories:
An immediate health hazard
--------------------TOXIC SUBSTANCES CONTROL ACT (TSCA):
All ingredients are on the TSCA inventory or are not required to be listed on the TSCA inventory.
---------------------
140
STATE RIGHT-TO-KNOW: This product is not known to contain any substances subject to the disclosure
requirements of
Pennsylvania
--------------------OSHA HAZARD COMMUNICATION STANDARD:
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR
1910.1200.
CANADIAN REGULATIONS
====================
WHMIS INFORMATION: The Canadian Workplace Hazardous Materials Information System (WHMIS) Classification
for this product is:
D2B - skin sensitizer
Refer elsewhere in the MSDS for specific warnings and
REGULATORY INFORMATION (CONTINUED)
safe handling information. Refer to the employer's workplace education program.
CPR STATEMENT: This product has been classified in accordance with the hazard criteria of the Canadian Controlled
Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
1.
- - - HAZARDOUS PRODUCTS ACT INFORMATION: This product contains the following ingredients which are Controlled
Products and/or on the Ingredient
Disclosure List (Canadian HPA section 13 and 14)
COMPONENTS:
CAS
#AMOUNT(%w/w)
Diglycidyl ether of
001675-54-3
100%
bisphenol A
--------------------CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):
All substances in this product are listed on the Canadian Domestic Substances List (DSL) or are not required to be
listed.
16. OTHER INFORMATION
MSDS STATUS:
Revised Sections 3,4,5,6,7,8,9,10,11,15.
* OR (R) INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY
The Information Herein Is Given In Good Faith, But No Warranty, Express Or Implied, Is Made. Consult The Dow Chemical
Company For Further Information.
141
Filled Vinyl & Acryllic Emulsion
MATERIAL SAFETY DATA SHEET
Prepared to U.S. OSHA, CMA, ANSI and Canadian WHMIS Standards
PART I
What is the material and what do I need to know in an emergency?
1. PRODUCT IDENTIFICATION
TRADE NAME (AS LABELED):
FSC3, Joint Fire Protective Coating
CHEMICAL NAME/CLASS:
SYNONYMS:
PRODUCT USE:
SUPPLIER/MANUFACTURER'S NAME:
ADDRESS:
Filled Vinyl & Acrylic Emulsion
None
Elastomeric Firestop, Intumescent
EGS Nelson Firestop
th
4135 S. 100 East Avenue, Suite 100
Tulsa, Oklahoma 74146
CHEMTREC EMERGENCY NO.:
BUSINESS PHONE:
DATE OF PREPARATION:
1-800-424-9300 (United States)
(918) 627-5530/(800) 331-7325
January, 2002
2. COMPOSITION and INFORMATION ON INGREDIENTS
Ingredient
CAS #
Percent (max)
2-Propenoic acid, polymer
052640-81-0
10 – 20
Aluminum oxide
001344-28-1
5 – 10
Calcium carbonate
001317-65-3
10 – 20
Ethylene Glycol
000107-21-1
<1
Methenamine
000100-97-0
<1
Phenol,isopropylated, phosphate (3:1)
068937-41-7
1–5
Phenol-formaldehyde polymer
009003-35-4
5 – 10
Polyvinyl Acetate Emulsion
NJ801415075P
10 – 20
Quartz
014808-60-7
<1
Triphenyl phosphate
000115-86-6
1-5
142
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: The chief health hazard associated with overexposure would be the potential to
slightly irritate the eyes, skin, nose, and other tissues that come in contact with this product or in the event that
particulates are generated from the product. This product is not flammable or reactive. Emergency responders
must wear proper personal protective equipment for the releases to which they are responding.
SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: Under normal circumstances of use, this product should
not present significant health hazards. The most significant routes of occupational overexposure would be via
inhalation and contact with skin. The symptoms of overexposure to this product, via route of entry, are as follows:
INHALATION: Breathing airborne particulates, if generated during use of this product, may irritate the nose, throat,
or upper respiratory system. Symptoms of such exposure could include nausea, coughing and sneezing, tightness
of chest. Hypersensitive individuals may experience allergic respiratory reaction and wheezing. Symptoms are
generally alleviated when exposure ends.
CONTACT WITH SKIN or EYES: Spray applications of this material may create aerosols which may be irritating to the
eyes. Prolonged eye contact can result in permanent damage. Minor skin contact may cause irritation. Prolonged
skin contact can result in burns. Hypersensitive individuals may develop an allergic reaction resulting in dermatitis,
rash or hives.
SKIN ABSORPTION: Harmful if absorbed through the skin.
INGESTION: Ingestion of this product is unlikely. May be irritating if ingested, Reproductive and developmental
effects have been reported for certain ingredients. Long-term repeated ingestion of small amounts of product may
cause a decrease in red blood cells or liver and kidney damage. Ethylene glycol has been shown to produce
teratogenic and developmental toxic effects in laboratory animals. Phenol-formaldehyde polymer has tested
positive as a mutagen.
INJECTION: Injection of this product is unlikely.
143
PART II What should I do if a hazardous situation occurs?
4. FIRST-AID MEASURES
Contaminated individuals must seek medical attention if any adverse effect occurs.
Rescuers should be taken for medical attention, if necessary. Take a copy of label
and MSDS to physician or health professional with the contaminated individual.
SKIN EXPOSURE: Wash with soap and water. Remove contaminated clothing and
wash before reuse. Seek medical attention if adverse reaction occurs.
EYE EXPOSURE: If fumes or particulates generated from the product contaminate
the eyes, open victim's eyes while under gently running water. Use sufficient force
to open eyelids. Have the contaminated individual "roll" eyes. The recommended
minimum flushing time is 15 minutes. Seek medical attention if any adverse effect
occurs.
INHALATION: If fumes or particulates generated from the product are inhaled,
remove victim to fresh air. If adverse effect occurs after removal to fresh air, seek
medical attention.
INGESTION: Do not induce vomiting. If discomfort or irritation persists, consult a
physician.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing dermatitis, and
other skin disorders can be aggravated by exposure to this product.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms.
5. FIRE-FIGHTING MEASURES
FLASH POINT: > 212º F / 100º C
Flash Point Method: Estimated
AUTOIGNITION TEMPERATURE: Not applicable.
FLAMMABLE LIMITS (in air by volume, %):
Lower (LEL): Not applicable.
Upper (UEL): Not applicable.
FIRE EXTINGUISHING MATERIALS: Select fire extinguishing media appropriate for the surrounding area.
Water Spray: YES
Carbon Dioxide: YES
Alcohol Foam: YES
Dry Chemical: YES
Other: Any "ABC" Class.
144
NFPA RATING
FLAMMABILITY
0
HEALTH
1
0
REACTIVITY
OTHER
See Section 16 for
Definition of Ratings
UNUSUAL FIRE AND EXPLOSION HAZARDS: This product is not combustible and does not contribute to the intensity of a fire.
When involved in a fire, this material may decompose and produce irritating vapors, acrid smoke, and toxic gases
nitrogen may be evolved).
(e.g., oxides of
Explosion Sensitivity to Mechanical Impact: Not sensitive.
Explosion Sensitivity to Static Discharge: Not sensitive.
145
SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection.
Structural firefighters must wear Self-Contained Breathing Apparatus and full protective
equipment. Move fire-exposed containers if it can be done without risk to firefighters. If
possible, firefighters should control runoff water to prevent environmental contamination.
Rinse contaminated equipment with soapy water before returning such equipment to service.
No special procedures specific to this product.
6. ACCIDENTAL RELEASE MEASURES
RELEASE RESPONSE: Prevent spills from entering drinking water supplies, streams, or sewers.
Collect material with an inert, noncombustible material and remove for disposal.
PART III How can I prevent hazardous situations from occurring?
7. HANDLING and STORAGE
WORK AND HYGIENE PRACTICES: Avoid contact with eyes, skin and clothing. Do not take
internally. Practice good personal hygiene to avoid ingestion. Wash clothing before reuse. Use
only with adequate ventilation.
STORAGE AND HANDLING PRACTICES: Store this product in a cool, dry location, away from
sources of intense heat. Store away from incompatible materials (see Section 10, Stability and
Reactivity).
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: No special ventilation and engineering controls
are required for use of this product.
RESPIRATORY PROTECTION: None normally required for routine use of this product. Airborne
contaminant concentrations must be maintained below guidelines listed in Section 2
(Composition and Information on Ingredients). If respiratory protection is needed, use only
protection authorized in the U.S. Federal OSHA Standard (29 CFR 1910.134), applicable U.S.
State regulations, or the Canadian CSA Standard Z94.4-93. Oxygen levels below 19.5% are
considered IDLH by OSHA. In such atmospheres, use of a full-facepiece pressure/demand
SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air supply is
required under OSHA’s Respiratory Protection Standard (1910.134-1998).
EYE PROTECTION: Wear goggles to prevent exposure to high vapor or mist concentrations.
Wear goggles or safety glasses with side shields and a full-face shield to prevent contact due
to splashing.
HAND PROTECTION: Wear Impervious(PVC, latex or nitrile) gloves for routine industrial use.
BODY PROTECTION: Work clothing with long sleeves, long pants and work boots must be
worn. Clothing must be laundered before reuse. Disposable tyvek suits may be used during
spray applications.
9. PHYSICAL and CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
RELATIVE VAPOR DENSITY (air = 1): >1 SPECIFIC GRAVITY (water = 1): Not Available SOLUBILITY IN WATER:
Appreciable.
VAPOR PRESSURE, mm Hg @ 20 C: Unknown BULK DENSITY (lbs/Cubic Foot) : Not Applicable
APPERANCE/ODOR: Red / Mild latex odor. EVAPORATION RATE (n-BuAc = 1): 1 VISCOSITY: Unknown
146
BOILING POINT: >100ºC (212ºF). pH: Not applicable.
%
Volatiles
L): (70ºF/21ºC): < 250 g/l
(gr/
10. STABILITY and REACTIVITY
STABILITY: Stable.
DECOMPOSITION PRODUCTS: Carbon dioxide, Carbon monoxide, Low molecular weight hydrocarbons, Aldehydes,
magnesium carbonate and lime.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Strong oxidizers, strong acids, ammonium salts, flourine, maganese trioxide, oxygen diflouride
and chlorine trifluoride.
PART IV Is there any other useful information about this material?
11. TOXICOLOGICAL INFORMATION
Ingredient
CAS Number
Triphenyl phosphate
000115-86-6
LD20 and LC50
Oral LD50 Rat : 3500 mg/kg;
Oral LD50 Mouse : 1320 mg/kg
Carcinogenicity:
Ingredient
IARC
IARC
IARC
NTP
NTP
OSHA
Group1
Group 2A
Group 2B
Known
Suspect
2-Propenoic acid, polymer…
No
No
No
No
No
No
Aluminum oxide
No
No
No
No
No
No
Calcium Carbonate
No
No
No
No
No
No
Magnesium Aluminum Silicate
No
No
Yes
No
No
No
Phenol, isopropylated, phosphate (3:1) No
No
No
No
No
No
Phenol-formaldehyde polymer
No
No
No
No
No
No
Polyvinyl Acetate Emulsion
No
No
No
No
No
No
Quartz
Yes
No
No
Yes
Yes
Yes
Triphenyl Phosphate
No
No
No
No
No
No
Contains formaldehyde below 0.1% threshold. Product is capable of releasing formaldehyde under certain
conditions. Exposures during typical applications are expected to be insignificant. Exposure to formaldehyde
vapor is a potential concern if product is applied under confined space conditions. NTP: Suspect Carcinogen. IARC:
Group 2A. OSHA: Potential.
Mutagenicity:
Teratogenicity:
Phenol-formaldehyde polymer in this product has tested positive as a
mutagen.
Ethylene glycol contained in this product has been shown to produce
teratogenic
effects in laboratory animals.
Reproductive Toxicity:
No information available.
147
12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
Environmental Fate:
No data available for product.
Ecotoxicity:
No data available for product.
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate U.S. Federal, State, and
local regulations or with regulations of Canada and its Provinces. According to EPA (40 CFR § 261), waste of this product
is not defined as hazardous.
14. TRANSPORTATION INFORMATION
PROPER SHIPPING NAME:
Not applicable.
Nonhazardous.
HAZARD CLASS NUMBER and DESCRIPTION:
UN IDENTIFICATION NUMBER:
Not applicable.
PACKING GROUP:
Not applicable.
DOT LABEL(S) REQUIRED:
Not applicable.
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (2000): Not applicable.
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This material is not considered
as dangerous goods by Transport Canada.
IATA DESIGNATION: This material is not considered as dangerous goods by the International Air Transport
Association. UPS SHIPPING: This material is not considered as Hazardous Materials by the United Parcel Service.
15. REGULATORY INFORMATION
Regulatory Chemical Lists:
CERCLA (Comprehensive Response Compensation and Liability Act):
(None present unless listed below)
SARA Title III (Superfund Amendments and Reauthorization Act)
SARA Section 312/Tier I & II Hazard Categories:
Health Immediate (acute)
Yes
Health Delayed (chronic)
Yes
Flammable
No
Reative
No
Pressure
No
302 Reportable Ingredients (Identification Threshold 1%): None
313 Reportable Ingredients (Chemicals present below reporting threshold are exempt):
Chemical Name
CAS
WT %
148
Acetaldehyde
000075-07-0
.0014
Acrylamide
00079-06-01
.0008
Acrylonitrile
000107-13-1
.0002
Aluminum Oxide
001344-28-1
6.7
Ammonia
07664-41-7
.12
Chlorothalonil
001897-45-6
.0404
Ethyl Acrylate
000140-88-5
.0022
Ethylene Glycol
000107-21-1
.27
Formaldehyde
000050-00-0
.0321
Glycol Ethers
RR-00067-9
.011
Methyl Alcohol
000067-56-1
.0018
Vinyl Acetate
000108-05-4
.0742
National Volatile Organic Compound Emission Standards For Architectural Coatings:
Volatile Organic Content: (gr/L)
WHMIS Classification(s):
< 250 g/l
D2 B
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR). This MSDS contains all the information required by the CPR.
State Requlatory Information:
California Proposition 65:
Warning! This product contains substances known to the state of
California to cause cancer, birth defects or other reproductive harm.
Massachusetts Hazardous Substance List (Identification threshold 0.001% (1ppm)):
Chemical Name
CAS #
Wt %
Acetaldehyde
000075-07-0
.0014
Acrylamide
000079-06-1
.0008
Acrylonitrile
00107-13-1
.0002
Ammonia
007664-41-7
.12
Chlorothalonil
001897-45-6
.0404
Ethyl Acrylate
000140-88-5
.0022
Formaldehyde
000050-00-0
.0321
Quartz
014808-60-7
.2675
Vinyl Acetate
000108-05-4
.0742
New Jersey Hazardous Substance List (Identification threshold (0.1%)):
Chemical Name
CAS #
Wt %
Aluminum Oxide
001344-28-1
6.7
Ammonia
007664-41-7
.12
Ethylene Glycol
000107-21-1
.27
149
Pennsylvania Hazardous Substance List (Identification threshold (0.1%):
Chemical Name
CAS #
Wt %
Formaldehyde
000050-00-0
.032
Chemical Inventory Status:
All Chemicals in this product are listed or exempt from listing in the following countries:
US
CANADA
TSCA
DSL
Yes
Yes
EUROPE
AUSTRALIA
JAPAN
KOREA
PHILIPPINES
NDSL
EINECS/ELINCS
AICS
ENCS
ECL
PICCS
No
Not
Determined
Not
Determined
Not
Determined
Not
Determined
Not
Determined
16. OTHER INFORMATION
The information contained herein is based on data considered accurate. However, no warranty is expressed or
implied regarding the accuracy of these data or the results to be obtained from the use thereof. Nelson EGS
assumes no responsibility for injury to the vendee or third persons proximately caused by the material if
reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, Nelson EGS
assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the
material even if reasonable safety procedures are followed. Furthermore, vendee assumes the risk in his use of
the material.
DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these which are commonly used include the
following: CAS #: This is the Chemical Abstract Service Number which uniquely identifies each constituent.
EXPOSURE LIMITS IN AIR:
ACGIH - American Conference of Governmental Industrial Hygienists, a professional association which establishes
exposure limits. TLV - Threshold Limit Value - an airborne concentration of a substance which represents
conditions under which it is generally believed that nearly all workers may be repeatedly exposed without adverse
effect. The duration must be considered, including the 8-hour Time Weighted Average (TWA), the 15-minute Short
Term Exposure Limit, and the instantaneous Ceiling Level (C). Skin absorption effects must also be considered.
OSHA - U.S. Occupational Safety and Health Administration.
PEL - Permissible Exposure Limit - This exposure value means exactly the same as a TLV, except that it is
enforceable by OSHA. The OSHA Permissible Exposure Limits are based in the 1989 PELs and the June, 1993 Air
Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191). Both the current PELs and the vacated PELs
are indicated. The phrase, “Vacated 1989 PEL,” is placed next to the PEL which was vacated by Court Order. IDLH Immediately Dangerous to Life and Health - This level represents a concentration from which one can escape
150
within 30-minutes without suffering escape-preventing or permanent injury. The DFG - MAK is the Republic of
Germany’s Maximum Exposure Level, similar to the U.S. PEL. NIOSH is the National Institute of Occupational Safety
and Health, which is the research arm of the U.S. Occupational Safety and Health Administration (OSHA).
NIOSH issues exposure guidelines called Recommended Exposure Levels (RELs). When no exposure guidelines are
established, an entry of NE is made for reference.
HAZARD RATINGS:
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM : Health Hazard:
0 (minimal acute or chronic exposure hazard); 1 (slight acute or chronic exposure hazard); 2 (moderate acute or
significant chronic exposure hazard); 3 (severe acute exposure hazard; onetime overexposure can result in
permanent injury and may be fatal); 4 (extreme acute exposure hazard; onetime overexposure can be fatal).
Flammability Hazard: 0 (minimal hazard); 1 (materials that require substantial pre-heating before burning); 2
(combustible liquid or solids; liquids with a flash point of 38-93 C [100-200 F]); 3 (Class IB and IC flammable liquids
with flash points below 38 C [100 F]); 4 (Class IA flammable liquids with flash points below 23 C [73 F] and boiling
points below 38 C [100 F]. Reactivity Hazard: 0 (normally stable); 1 (material that can become unstable at elevated
temperatures or which can react slightly with water); 2 (materials that are unstable but do not detonate or which
can react violently with water); 3 (materials that can detonate when initiated or which can react explosively with
water); 4 (materials that can detonate at normal temperatures or pressures).
NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0
(material that on exposure under fire conditions would offer no hazard beyond that of ordinary combustible
materials); 1 (materials that on exposure under fire conditions could cause irritation or minor residual injury); 2
(materials that on intense or continued exposure under fire conditions could cause temporary incapacitation or
possible residual injury); 3 (materials that can on short exposure could cause serious temporary or residual injury);
4 (materials that under very short exposure causes death or major residual injury). Flammability Hazard and
Reactivity Hazard: Refer to definitions for “Hazardous Materials Identification System”.
FLAMMABILITY LIMITS IN AIR:
Much of the information related to fire and explosion is derived from the National Fire Protection Association
(NFPA). Flash Point - Minimum temperature at which a liquid gives off sufficient vapors to form an ignitable
mixture with air. Autoignition Temperature: The minimum temperature required to initiate combustion in air with
no other source of ignition. LEL - the lowest percent of vapor in air, by volume, that will explode or ignite in the
presence of an ignition source. UEL - the highest percent of vapor in air, by volume, that will explode or ignite in
the presence of an ignition source.
TOXICOLOGICAL INFORMATION:
Human and Animal Toxicology: Possible health hazards as derived from human data, animal studies, or from the
results of studies with similar compounds are presented. Definitions of some terms used in this section are: LD50 Lethal Dose (solids & liquids) which kills 50% of the exposed animals; LC50 - Lethal Concentration (gases) which kills
50% of the exposed animals; ppm concentration expressed in parts of material per million parts of air or water;
3
mg/m concentration expressed in weight of substance per volume of air; mg/kg quantity of material, by weight,
administered to a test subject, based on their body weight in kg. Other measures of toxicity include TDLo, the
lowest dose to cause a symptom and TCLo the lowest concentration to cause a symptom; TDo, LDLo, and LDo, or
TC, TCo, LCLo, and LCo, the lowest dose (or concentration) to cause lethal or toxic effects.
Cancer Information: The sources are: IARC - the International Agency for Research on Cancer; NTP - the National
Toxicology Program, RTECS - the Registry of Toxic Effects of Chemical Substances, OSHA and CAL/OSHA. IARC and
NTP rate chemicals on a scale of decreasing potential to cause human cancer with rankings from 1 to 4. Sub
rankings (2A, 2B, etc.) are also used. Other Information: BEI - ACGIH Biological Exposure Indices, represent the
levels of determinants which are most likely to be observed in specimens collected from a healthy worker who has
151
been exposed to chemicals to the same extent as a worker with inhalation exposure to the TLV. Ecological
Information: EC is the effect concentration in water. BCF = Bioconcentration Factor, which is used to determine if a
substance will concentrate in life forms which consume contaminated plant or animal matter. Coefficient of
Oil/Water Distribution is represented by log Kow or log Koc and is used to assess a substance’s behavior in the
environment.
REGULATORY INFORMATION:
This section explains the impact of various laws and regulations on the material. U.S.: EPA is the U.S.
Environmental Protection Agency. DOT is the U.S. Department of Transportation. SARA is the Superfund
Amendments and Reauthorization Act. TSCA is the U.S. Toxic Substance Control Act. CERCLA (or Superfund) refers
to the Comprehensive Environmental Response, Compensation, and Liability Act. Labeling is per the American
National Standards Institute (ANSI Z129.1). CANADA: CEPA is the Canadian Environmental Protection Act. WHMIS
is the Canadian Workplace Hazardous Materials Information System. TC is Transport Canada. DSL/NDSL are the
Canadian Domestic/Non-Domestic Substances Lists.
152
Gasoline
Product Name:
GASOLINE, UNLEADED AUTOMOTIVE
_____________________________________________________________________________________
MATERIAL SAFETY DATA SHEET
SECTION 1
PRODUCT AND COMPANY IDENTIFICATION
PRODUCT
Product Name:
GASOLINE, UNLEADED AUTOMOTIVE
Product
Description:
Hydrocarbons and Additives
Product Code:
123455-20, 9700, 977032, 977217, 977306, 977360,
977371, 977381,
977445, 977562, 977767, 977920, 979533, 97A039, 97A065, 97A078, 97A087, 97A102,
97A290
97A108, 97A146, 97A147, 97A152, 97A193,
97A200, 97A240, 97A266, 97A273, ,
97A441
97A305, 97A316, 97A317, 97A328, 97A347,
97A380, 97A404, 97A424, 97A431, ,
97A696
97A514, 97A556, 97A557, 97A613, 97A634,
97A653, 97A655, 97A659, 97A686, ,
97A848
97A703, 97A712, 97A726, 97A736, 97A746,
97A767, 97A794, 97A798, 97A827, ,
97A989
97A851, 97A876, 97A883, 97A907, 97A934,
97A948, 97A949, 97A960, 97A983, ,
97AW01
97AW38
97AV99, 97AW00, ,
97AZ87, 97AZ88, 97AZ89, 97AZ90, 97AZ91,
,
97AZ92, 97AZ93, 97AZ94, 97AZ95, 97AZ96, 97AZ97, 97AZ98, 97AZ99, 97BA11,
97BA12, 97BA13, 97BA14, 97BA15, 97BA16,
97BA67, 97BA68, 97BA69, 97BA70,
97BE24, 97BE25, 97BE26, 97BE27, 97BE28,
97BE29, 97BE30, 97BE31, 97BE32,
97BE33, 97BE34, 97BE35, 97BE36, 97BE37,
97BE38, 97BE39, 97BN13, 97BN50,
97BP69, 97BP70, 97BP71, 97BR15, 97BR16,
97BR22, 97BR23, 97BR24, 97BR30,
97C127
97BR43, 97C070, 97C072, 97C075, 97C110, 97C112, 97C113, 97C118,
,
97C140, 97C148, 97C166, 97C417, 97C558, 97C576, 97C632, 97C702, 97C731,
97C759, 97C770, 97C782, 97C794, 97C870, 97C917, 97D130, 97D228, 97E002,
97E010, 97E041, 97E065, 97E087, 97E103,
97E104, 97E11, 97E112, 97E113, 97E170,
97E171, 97E196, 97E197, 97E259, 97E260,
97E304, 97E305, 97E347, 97E42, 97E532,
97E564, 97E581, 97E595, 97E606, 97E611,
97E619, 97E649, 97E655, 97E66, 97E682,
97E749, 97E860, 97E88, 97E999,
97F005, 97F020, 97F030, 97F054, 97F312, 97F344,
97M192 97M193
97M195 97M229
97F952, 97M190, 97M191, ,
97M194, ,
97M230,
,
,
97N89
97M232, 97N832, 97N844, 97N848, 97N861, 97N873, 97N877, 97N879,
1,
97Q76
97N895, 97N913, 97N917, 97N921, 97N941, 97N942, 97N954, 97Q303,
3,
97Q781, 97Q782, 97R368, 97S760, 97U927, 97V321, 97V323, 97V325, 97V326,
97X113, 97X114, 97X131, 97X861, EMGF20
Intended Use:
Fuel, Gasoline
COMPANY IDENTIFICATION
Supplier:
EXXON
MOBIL
153
CORPORATION
3225
GALLOWS
RD.
FAIRFAX, VA. 22037
24 Hour Health Emergency
Transportation
Emergency
Phone
ExxonMobil Transportation
No.
Product
Technical
Information
MSDS Internet Address
SECTION 2
USA
609-737 4411
800-424 9300
281-834 3296
800-662-4525,
800-947-9147
http://www.exxon.com,
http://www.mobil.com
COMPOSITION / INFORMATION ON INGREDIENTS
Reportable Hazardous Substance(s) or Complex Substance(s)
Name
CAS#
ETHYL ALCOHOL
64-17-5
Gasoline
86290-81-5
Concentration*
< 11%
89 100%
Hazardous Constituent(s) Contained in Complex Substance(s)
Name
CAS#
BENZENE
71-43-2
ETHYL BENZENE
100-41-4
N-HEXANE
110-54-3
NAPHTHALENE
91-20-3
PSEUDOCUMENE (1,2,4-TRIMETHYLBENZENE)
95-63-6
Toluene
108-88-3
TRIMETHYL BENZENE
25551-13-7
XYLENES
1330-20-7
* All concentrations are percent by weight unless material is a gas.
Concentration*
0.1 - 5%
1 - 5%
1 - 5%
<1%
1 - 5%
5 - 10%
1 - 5%
5 - 10%
Gas concentrations are in percent by volume.
NOTE: The concentration of the components shown above may vary substantially. In certain countries, benzene content
may be limited to lower levels. Oxygenates such as tertiary-amyl-methyl ether, ethanol, di-isopropyl ether, and ethyltertiary-butyl ether may be present. Because of volatility considerations, gasoline vapor may have concentrations of
components very different from those of liquid gasoline. The major components of gasoline vapor are: butane,
isobutane, pentane, and isopentane. The reportable component percentages, shown in the composition/information on
ingredients section, are based on API's evaluation of a typical gasoline mixture.
SECTION 3
HAZARDS IDENTIFICATION
This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15).
POTENTIAL PHYSICAL / CHEMICAL EFFECTS
Extremely flammable. Material can release vapors that readily form flammable mixtures. Vapor
accumulation could flash and/or explode if ignited. Material can accumulate static charges which may cause
an incendiary electrical discharge.
154
POTENTIAL HEALTH EFFECTS
Irritating to skin. If swallowed, may be aspirated and cause lung damage. May be irritating to the eyes, nose,
throat, and lungs. May cause central nervous system depression. High-pressure injection under skin may cause
serious damage. Prolonged and repeated exposure to benzene may cause serious injury to blood forming organs
and is associated with anemia and to the later development of acute myelogenous leukemia (AML).
Target Organs:
Lung
|
Skin
|
ENVIRONMENTAL HAZARDS
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
NFPA Hazard ID:
Health:
1
Flammability:
3
Reactivity:
0
HMIS Hazard ID:
Health:
1*
Flammability:
3
Reactivity:
0
NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert
advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary
from person to person.
SECTION 4
FIRST AID MEASURES
Inhalation
Remove from further exposure.
For those providing assistance, avoid exposure to yourself or others. Use adequate
respiratory protection immediate medical assistance Mouth-to-mouth resuscitation.
155
If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek If breathing has stopped, assist ventilation
with a mechanical device or use
SKIN CONTACT
Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. If
product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its
size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial
symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may
significantly reduce the ultimate extent of injury.
EYE CONTACT
Flush thoroughly with water.
If irritation occurs, get medical assistance.
Ingestion
Seek immediate medical attention. Do not induce vomiting.
NOTE TO PHYSICIAN
If ingested, material may be aspirated into the lungs and cause chemical pneumonitis.
Treat appropriately.
PRE-EXISTING MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSURE
Benzene- Individuals with liver disease may be more susceptible to toxic effects.
SECTION 5
FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.
Inappropriate Extinguishing Media:
Straight Streams of Water
FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. If a leak or spill has not ignited, use water spray to disperse the vapors and to
protect personnel attempting to stop a leak. Prevent runoff from fire control or dilution from entering streams, sewers,
or drinking water supply. Firefighters should use standard protective equipment and in enclosed spaces, self-contained
breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel.
Unusual Fire Hazards: Extremely Flammable. Vapors are flammable and heavier than air. Vapors may travel across the
ground and reach remote ignition sources causing a flashback fire danger. Hazardous material. Firefighters should
consider protective equipment indicated in Section 8.
Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulfur Oxides, Incomplete combustion
products, Oxides of carbon
FLAMMABILITY PROPERTIES
156
Flash Point [Method]: <-40C
(-40F) [ ASTM D-56]
Flammable Limits (Approximate volume % in air): LEL: 1.4
Autoignition Temperature:
SECTION 6
UEL: 7.6
>250°C (482°F)
ACCIDENTAL RELEASE MEASURES
NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations. US regulations require reporting releases of this material to the environment which exceed the
applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The
National Response Center can be reached at (800)424-8802.
PROTECTIVE MEASURES
Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if
required due to toxicity or flammability of the material. See Section 5 for firefighting information. See the
Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for
Personal Protective Equipment.
SPILL MANAGEMENT
Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you
can do it without risk. All equipment used when handling the product must be grounded. Do not touch or walk
through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapor
suppressing foam may be used to reduce vapors. Use clean non-sparking tools to collect absorbed material.
Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large Spills:
Water spray may reduce vapor; but may not prevent ignition in closed spaces. Recover by pumping or with
suitable absorbent.
Water Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if
you can do it without risk. Do not confine in area of spill. Advise occupants and shipping in downwind areas of
fire and explosion hazard and warn them to stay clear. Allow liquid to evaporate from the surface. Seek the
advice of a specialist before using dispersants.
Water spill and land spill recommendations are based on the most likely spill scenario for this material; however,
geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and
speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways,
sewers, basements or confined areas.
SECTION 7
HANDLING AND STORAGE
HANDLING
Avoid breathing mists or vapors. Avoid contact with skin. Use non-sparking tools and explosion-proof equipment.
Potentially toxic/irritating fumes/vapors may be evolved from heated or agitated material. Do not siphon by mouth. Use
only with adequate ventilation. Use proper bonding and/or grounding procedures. Do not use as a cleaning solvent or
other non-motor fuel uses. For use as a motor fuel only. It is dangerous and/or unlawful to put fuel into unapproved
containers. Do not fill container while it is in or on a vehicle. Static electricity may ignite vapors and cause fire. Place
container on ground when filling and keep nozzle in contact with container. Do not use electronic devices (including but
157
not limited to cellular phones, computers, calculators, pagers or other electronic devices, etc.) in or around any fueling
operation or storage area unless the devices are certified intrinsically safe by an approved national testing agency and to
the safety standards required by national and/or local laws and regulations. Prevent small spills and leakage to avoid slip
hazard. Material can accumulate static charges which may cause an electrical spark (ignition source)
Static Accumulator:
This material is a static accumulator.
STORAGE
Ample fire water supply should be available. A fixed sprinkler/deluge system is recommended. Keep container closed.
Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well-ventilated
area. Outside or detached storage preferred. Storage containers should be grounded and bonded. Drums must be
grounded and bonded and equipped with self-closing valves, pressure vacuum bungs and flame arresters.
SECTION 8
EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMIT VALUES
Exposure limits/standards (Note: Exposure limits are not additive)
Source
BENZENE
Form
NOTE
N/A
Source
OSHA
Sp.Reg.
BENZENE
Limit / Standard
OSHA
0.5 ppm
Action
level
STEL
5 ppm
N/A
BENZENE
TWA
1 ppm
N/A
BENZENE
BENZENE
ETHYL ALCOHOL
STEL
TWA
TWA
Skin
Skin
N/A
ETHYL ALCOHOL
ETHYL BENZENE
ETHYL BENZENE
ETHYL BENZENE
Gasoline
Gasoline
Gasoline
Gasoline
N-HEXANE
STEL
TWA
STEL
TWA
STEL
TWA
STEL
TWA
TWA
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
ACGIH
OSHA Z1
ACGIH
ACGIH
ExxonMobil
ExxonMobil
ACGIH
ACGIH
OSHA Z1
N-HEXANE
NAPHTHALENE
NAPHTHALENE
NAPHTHALENE
PSEUDOCUMENE
(1,2,4-TRIMETHYLBENZENE)
Toluene
TWA
TWA
STEL
TWA
TWA
2.5 ppm
0.5 ppm
1900
mg/m3
1000 ppm
435 mg/m3
125 ppm
100 ppm
200 ppm
100 ppm
500 ppm
300 ppm
1800
mg/m3
50 ppm
50 mg/m3
15 ppm
10 ppm
25 ppm
OSHA
Sp.Reg.
OSHA
Sp.Reg.
ACGIH
ACGIH
OSHA Z1
Skin
N/A
Skin
Skin
N/A
ACGIH
OSHA Z1
ACGIH
ACGIH
ACGIH
Ceiling
300 ppm
N/A
OSHA Z2
1000 ppm
100 ppm
500 ppm
10 ppm
158
Toluene
Maximum
concentra
tion
TWA
TWA
TWA
TWA
STEL
TWA
Toluene
Toluene
TRIMETHYL BENZENE
XYLENES
XYLENES
XYLENES
NOTE: Limits/standards shown for guidance only.
500 ppm
N/A
OSHA Z2
200 ppm
20 ppm
25 ppm
435 mg/m3 100 ppm
150 ppm
100 ppm
N/A
N/A
N/A
N/A
N/A
N/A
OSHA Z2
ACGIH
ACGIH
OSHA Z1
ACGIH
ACGIH
Follow applicable regulations.
ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
Use explosion-proof ventilation equipment to stay below exposure limits.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a
level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
No special requirements under ordinary conditions of use and with adequate ventilation.
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.
Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use
conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material
include:
If prolonged or repeated contact is likely, chemical resistant gloves are recommended. If contact with
forearms is likely, wear gauntlet style gloves.
Eye Protection:
If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
If prolonged or repeated contact is likely, chemical, and oil resistant clothing is recommended.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling
the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
159
ENVIRONMENTAL CONTROLS
See Sections
6, 7, 12, 13.
SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional data.
GENERAL INFORMATION
Physical State:
Liquid
Color:
Clear (May Be Dyed)
Odor:
Petroleum/Solvent
Odor Threshold:
N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15 C):
0.74
Density (at 15 ºC): 720 kg/m³ (6.01 lbs/gal, 0.72 kg/dm³) - 758 kg/m³ (6.33 lbs/gal, 0.76 kg/dm³)
Flash Point [Method]:
<-40C (-40F) [ ASTM D-56]
Flammable Limits (Approximate volume % in air):
LEL: 1.4
UEL: 7.6
Autoignition Temperature:
>250°C (482°F)
Boiling Point / Range:
> 20C (68F)
Vapor Density (Air = 1):
3 at 101 kPa
Vapor Pressure:
> 26.6 kPa (200 mm Hg) at 20 C
Evaporation Rate (N-Butyl Acetate = 1): > 10
pH:
N/A
Log Pow (n-Octanol/Water Partition Coefficient):
>3
Solubility in Water:
Negligible
Viscosity: <1 cSt
(1 mm²/sec) at 40 C
Oxidizing Properties:
See Hazards Identification Section.
OTHER INFORMATION
Freezing Point:
Melting Point:
N/D
N/A
SECTION 10
STABILITY:
STABILITY AND REACTIVITY
Material is stable under normal conditions.
CONDITIONS TO AVOID:
Avoid heat, sparks, open flames and other ignition sources.
MATERIALS TO AVOID:
Halogens,
Strong Acids,
HAZARDOUS DECOMPOSITION PRODUCTS:
HAZARDOUS POLYMERIZATION:
SECTION 11
ACUTE TOXICITY
Route of Exposure
Inhalation
Toxicity (Rat): LC50 > 5000 mg/m³
Alkalies,
Strong oxidizers
Material does not decompose at ambient temperatures.
Will not occur.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar
160
Irritation: No end point data.
Ingestion
Toxicity (Rat): LD50 > 2000 mg/kg
Skin
Toxicity (Rabbit): LD50 > 2000 mg/kg
Irritation: No end point data.
Eye
Irritation: Data available.
materials.
Elevated temperatures or mechanical action may form vapors,
mist, or fumes which may be irritating to the eyes, nose, throat, or
lungs. Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar
materials.
Minimally Toxic. Based on test data for structurally similar
materials.
Moderately irritating to skin with prolonged exposure. Based on
test data for structurally similar materials.
May cause mild, short-lasting discomfort to eyes. Based on test
data for structurally similar materials.
CHRONIC/OTHER EFFECTS
For the product itself:
Laboratory animal studies have shown that prolonged and repeated inhalation exposure to light hydrocarbon
vapors in the same boiling range as this product can produce adverse kidney effects in male rats. However,
these effects were not observed in similar studies with female rats, male and female mice, or in limited studies
with other animal species. Additionally, in a number of human studies, there was no clinical evidence of such
effects at normal occupational levels. In 1991, The U.S. EPA determined that the male rat kidney is not useful
for assessing human risk.
Vapor concentrations above recommended exposure levels are irritating to the eyes and the respiratory
tract, may cause headaches and dizziness, are anesthetic and may have other central nervous system effects.
Small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical
pneumonitis or pulmonary edema.
Gasoline unleaded: Caused cancer in animal tests. Chronic inhalation studies resulted in liver tumors in female
mice and kidney tumors in male rats. Neither result considered significant for human health risk assessment by
the United States EPA and others. Did not cause mutations In Vitro or In Vivo. Negative in inhalation
developmental studies and reproductive tox studies.Inhalation of high concentrations in animals resulted in
reversible central nervous system depression, but no persistent toxic effect on the nervous system. Nonsensitizing in test animals. Caused nerve damage in humans from abusive use (sniffing).
Contains:
BENZENE: Caused cancer (leukemia), damage to the blood- producing system, and serious blood disorders from
prolonged, high exposure based on human epidemiology studies. Caused genetic effects and effects on the
immune system in laboratory animal and some human studies. Caused toxicity to the fetus in laboratory animal
studies.
ETHANOL: Prolonged or repeated exposure to high concentrations of ethanol vapor or overexposure by
ingestion may produce adverse effects to brain, kidney, liver, and reproductive organs, birth defects in offspring,
and developmental toxicity in offspring.
NAPHTHALENE: Exposure to high concentrations of naphthalene may cause destruction of red blood cells,
anemia, and cataracts. Naphthalene caused cancer in laboratory animal studies, but the relevance of these
findings to humans is uncertain.
N-HEXANE: Prolonged and/or repeated exposures to n-Hexane can cause progressive and potentially
irreversible damage to the peripheral nervous system (e.g. fingers, feet, arms, legs, etc.). Simultaneous
exposure to Methyl Ethyl Ketone (MEK) or Methyl Isobutyl Ketone (MIBK) and n-Hexane can potentiate the risk
161
of adverse effects from n-Hexane on the peripheral nervous system. n-Hexane has been shown to cause
testicular damage at high doses in male rats. The relevance of this effect for humans is unknown.
TOLUENE : Concentrated, prolonged or deliberate inhalation may cause brain and nervous system damage.
Prolonged and repeated exposure of pregnant animals (> 1500 ppm) have been reported to cause adverse fetal
developmental effects.
TRIMETHYLBENZENE: Long-term inhalation exposure of trimethylbenzene caused effects to the blood in
laboratory animals.
ETHYLBENZENE: Caused cancer in laboratory animal studies. The relevance of these findings to humans is
uncertain.
Additional information is available by request.
The following ingredients are cited on the lists below:
Chemical Name
BENZENE
ETHYL BENZENE
Gasoline
NAPHTHALENE
1 = NTP CARC
2 = NTP SUS
SECTION 12
CAS Number
71-43-2
100-41-4
86290-81-5
91-20-3
--REGULATORY LISTS SEARCHED-3 = IARC 1
4 = IARC 2A
List Citations
1, 3, 6
5
5
2, 5
5 = IARC 2B
6 = OSHA CARC
ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials.
ECOTOXICITY
Material -- Expected to be toxic to aquatic organisms. May cause long-term adverse effects in the aquatic
environment.
MOBILITY
More volatile component -- Highly volatile, will partition rapidly to air. Not expected to partition to
sediment and wastewater solids.
Less volatile component -- Low solubility and floats and is expected to migrate from water to the
land. Expected to partition to sediment and wastewater solids.
PERSISTENCE AND DEGRADABILITY
Biodegradation:
Majority of components -- Expected to be inherently biodegradable
Atmospheric Oxidation:
More volatile component -- Expected to degrade rapidly in air
BIOACCUMULATION POTENTIAL
Majority of components -- Has the potential to bio accumulate, however metabolism or physical
properties may reduce the bio concentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
162
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.
DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of undesirable combustion products.
REGULATORY DISPOSAL INFORMATION
RCRA Information: Disposal of unused product may be subject to RCRA regulations (40 CFR 261). Disposal of
the used product may also be regulated due to ignitability, corrosivity, reactivity or toxicity as determined by
the Toxicity Characteristic Leaching Procedure (TCLP). Potential RCRA characteristics: IGNITABILITY. TCLP
(BENZENE)
Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can
be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be
completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for
recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental
regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT,
FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14
TRANSPORT INFORMATION
LAND (DOT)
Proper Shipping Name:
Gasoline
Hazard Class & Division:
3
ID
Number:
1203
Packing Group:
II
Marine Pollutant: Yes
ERG Number:
128
Label(s):
3
Transport Document Name:
UN1203, GASOLINE, 3, PG II, MARINE POLLUTANT
LAND (TDG)
Proper Shipping Name:
Hazard Class & Division:
UN Number: 1203
Packing Group:
II
Special Provisions: 17
Gasoline
3
SEA (IMDG)
Proper Shipping Name:
MOTOR SPIRIT or GASOLINE or PETROL
Hazard Class & Division:
3
EMS Number:
F-E, S-E
UN Number:
1203
Packing Group:
Marine Pollutant:
Label(s):
II
Yes
3
163
Transport Document Name:
UN1203, MOTOR SPIRIT or GASOLINE or PETROL, 3, PG II, (-40°C c.c.),
MARINE POLLUTANT
AIR (IATA)
Proper Shipping Name:
Hazard Class & Division:
MOTOR SPIRIT or GASOLINE or PETROL
3
UN Number:
1203
I
Packing Group:
I
Label(s) / Mark(s): 3
Transport Document Name: UN1203, GASOLINE, 3, PG II
SECTION 15
REGULATORY INFORMATION
OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purpose, this material is classified as
hazardous in accordance with OSHA 29CFR 1910.1200.
NATIONAL CHEMICAL INVENTORY LISTING:
EPCRA:
AICS, DSL, EINECS, ENCS, KECI, PICCS, TSCA
This material contains no extremely hazardous substances.
CERCLA: This material is not subject to any special reporting under the requirements of the Comprehensive
Environmental Response, Compensation and Liability Act (CERCLA). Contact local authorities to determine if other
reporting requirements apply.
SARA (311/312) REPORTABLE HAZARD CATEGORIES:
Fire. Immediate Health. Delayed Health.
SARA (313) TOXIC RELEASE INVENTORY:
Chemical Name
CAS Number
PSEUDOCUMENE
(1,2,4-TRIMETHYLBENZENE)
BENZENE
ETHYL BENZENE
N-HEXANE
NAPHTHALENE
Toluene
XYLENES
95-63-6
Typical Value
5
1- %
71-43-2
100-41-4
110-54-3
91-20-3
108-88-3
1330-20-7
0.1 - 5%
1 - 5%
1 - 5%
<1%
5 - 10%
5 - 10%
The following ingredients are cited on the lists below:
Chemical Name
BENZENE
CAS Number
71-43-2
List Citations
1, 2, 4, 10, 11, 13, 15, 16, 17, 18, 19
164
ETHYL ALCOHOL
ETHYL BENZENE
Gasoline
N-HEXANE
NAPHTHALENE
PSEUDOCUMENE
(1,2,4-TRIMETHYLBENZENE)
Toluene
TRIMETHYL BENZENE
XYLENES
64-17-5
100-41-4
86290-81-5
110-54-3
91-20-3
95-63-6
1, 4, 13, 17, 18, 19
1, 4, 10, 13, 16, 17, 18, 19
1, 17, 18
1, 4, 13, 16, 17, 18, 19
1, 4, 5, 9, 10
1, 13, 16, 17, 18, 19
108-88-3
25551-13-7
1330-20-7
1, 4, 11, 13, 15, 16, 17, 18, 19
1, 13, 16, 17, 18, 19
1, 4, 5, 9, 13, 15, 17, 18, 19
165
1 = ACGIH ALL
2 = ACGIH A1
3 = ACGIH A2
4 = OSHA Z
5 = TSCA 4
--REGULATORY LISTS SEARCHED-6 = TSCA 5a2
11 = CA P65 REPRO
7 = TSCA 5e
12 = CA RTK
8 = TSCA 6
13 = IL RTK
9 = TSCA 12b
14 = LA RTK
10 = CA P65 CARC
15 = MI 293
16 = MN RTK
17 = NJ RTK
18 = PA RTK
19 = RI RTK
Code key: CARC=Carcinogen; REPRO=Reproductive
SECTION 16
OTHER INFORMATION
N/D = Not determined, N/A = Not applicable
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:
Revision Changes:
Section 01: Product Code was modified.
Section 14: Proper Shipping Name was modified.
Section 15: SARA (313) TOXIC RELEASE INVENTORY - Table was modified.
Section 09: Oxidizing Properties was modified.
Section 09: Density - Header was added.
Section 09: Density kg/m3(lbs/gal) was added.
THIS MSDS COVERS THE FOLLOWING MATERIALS: ESSO EXTRA MIDGRADE UNLEADED
| ESSO
MIDGRADE UNLEADED
| ESSO PREMIUM UNLEADED
| ESSO REGULAR UNLEADED |
ESSO SUPER
PREMIUM UNLEADED
| EXXON MIDGRADE UNLEADED
| EXXON PREMIUM UNLEADED
| EXXON
REGULAR UNLEADED
| Gasoline | INDOLENE GASOLINE | MIDGRADE UNLEADED |
MOBIL EXTRA
UNLEADED | MOBIL REGULAR UNLEADED |
MOBIL SPECIAL UNLEADED
| MOBIL SUPER UNLEADED |
PREMIUM UNLEADED
| REGULAR UNLEADED
| UNLEADED GASOLINE
PRECAUTIONARY LABEL TEXT:
Contains:
BENZENE, Gasoline DANGER!
HEALTH HAZARDS
Irritating to skin. If swallowed, may be aspirated and cause lung damage. Prolonged and repeated exposure to benzene
may cause serious injury to blood forming organs and is associated with anemia and to the later development of acute
myelogenous leukemia (AML).
Target Organs:
Lung |
Skin |
PHYSICAL HAZARDS
Extremely flammable. Material can accumulate static charges which may cause an incendiary electrical discharge.
Material can release vapors that readily form flammable mixtures. Vapor accumulation could flash and/or explode if
ignited.
PRECAUTIONS
Avoid breathing mists or vapors. Avoid contact with skin. Use non-sparking tools and explosion-proof equipment.
Potentially toxic/irritating fumes/vapors may be evolved from heated or agitated material. Do not siphon by mouth.
Use only with adequate ventilation. Use proper bonding and/or grounding procedures.
FIRST AID
Inhalation: Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use
adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-tomouth resuscitation.
166
Eye:
Oral:
Flush thoroughly with water.
If irritation occurs, get medical assistance.
Seek immediate medical attention.
Do not induce vomiting.
Skin: Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing
before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the appearance
of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even
though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the
first few hours may significantly reduce the ultimate extent of injury.
FIRE FIGHTING MEDIA
Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.
SPILL/LEAK
Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can
do it without risk. Prevent entry into waterways, sewer, basements or confined areas. A vapor suppressing foam may
be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to
containers. Recover by pumping or with suitable absorbent.
Water Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can
do it without risk. Do not confine in area of spill. Advise occupants and shipping in downwind areas of fire and
explosion hazard and warn them to stay clear. Allow liquid to evaporate from the surface. Seek the advice of a
specialist before using dispersants.
This warning is given to comply with California Health and Safety Code 25249.6 and does not constitute an admission
or a waiver of rights. This product contains a chemical known to the State of California to cause cancer, birth defects,
or other reproductive harm. Chemicals known to the State of California to cause cancer, birth defects, or other
reproductive harm are created by the combustion of this product.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief,
accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most
current available from ExxonMobil. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used
for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any
affiliates in which they directly or indirectly hold any interest.
Internal Use Only
MHC: 1A, 0, 0, 0, 3, 1
PPEC: CF
DGN: 2000316XUS
(1011203)
----------------------------------------------------------------------------------------------------------------------------------------------------Copyright 2002 Exxon Mobil Corporation, All rights reserved
167
Glass Cleaner
168
169
Hydraulic Fluid
Material Safety Data Sheet
SECTION I - Material Identity
Item Name...............................
TERESSTIC 68 / HYDRAULIC FLUID
Part Number/Trade Name
TERESSTIC 68 / HYDRAULIC FLUID
National Stock Number...................
CAGE Code...............................
Part Number Indicator...................
9150P46711-55
1ZAY6
A
MSDS
Number
................................ 194646
HAZ Code
B
SECTION II - Manufacturer's Information
Manufacturer Name....................... EXXON MOBILE CORPORATION
Street.................................. 3225 GALLOWS RD
City.................................... FAIRFAX
State................................... VA
Country................................. US
Zip Code................................ 22037
Emergency Phone......................... 609-737-4411
Information Phone....................... 800-662-4525
MSDS Preparer's Information
Date
MSDS
Prepared/Revised
........................ 12MAY04
Active Indicator
Y
Alternate Vendors
SECTION III - Physical/Chemical Characteristics
Appearance/Odor......................... STRAW COLORED LIQUID/MILD ODOR
Boiling Point........................... NE
Melting Point........................... NA
Vapor Pressure.......................... 0.1
Vapor Density........................... >2.0
Specific Gravity........................ 1
170
Evaporation Rate........................ NE
Solubility in Water..................... NEG
Chemical pH............................. NA
Corrosion Rate.......................... NA
Container Type.......................... R
Container Pressure Code................. 1
Temperature Code........................ 4
Product State Code...................... L
SECTION IV - Fire and Explosion Hazard Data
Flash Point............................. 396
Flash Point Method...................... UNK
Lower Explosion Limit................... NA
Upper Explosion Limit................... NA
Extinguishing Media..................... CARBON DIOXIDE, FOAM, DRY
CHEMICAL, WATER FOG
Special Fire Fighting Procedures........ WATER OR FOAM MAY CAUSE
FROTHING, USE WATER TO KEEP
FIRE EXPOSED CONTAINERS COOL.
WATER SPRAY MAY BE USED TO
FLUSH SPILLS AWAY FROM
EXPOSURE. PREVENT RUNOFF FROM
FIRE CONTROL OR DILUTION FROM
ENTERING STREAMS, SEWERS, OR
DRING WATER SUPPLY. WEAR SCBA
Unusual Fire/Explosion Hazards.......... NONE LISTED
SECTION V - Reactivity Data
Stability............................... YES
Stability Conditions to Avoid........... EXTREME HEAT AND HIGH ENERGY
SOURCES OF IGNITION.
Materials to Avoid...................... STRONG OXIDIZERS
Hazardous Decomposition Products........ NONE LISTED
Hazardous Polymerization................ NO
Polymerization Conditions to Avoid...... WILL NOT OCCUR
SECTION VI - Health Hazard Data
Route of Entry: Skin.................... U
Route of Entry: Ingestion............... U
Route of Entry: Inhalation.............. U
Health Hazards - Acute and Chronic...... [CHRONIC] REPEATED AND/OR
PORLONGED EXPOSURE MAY CAUSE
IRRITATION TO THE SKIN, EYES,
171
OR RESPIRATORY TRACT.
Explanation of Carcinogenity............ NO DATA
Symptoms of Overexposure................ UNDER NORMAL CONDITIONS OF
INTENDED USE, THIS PRODUCT DOESNOT POSE A RISH TO
HEALTH.
Medical Cond. Aggrevated by Exposure.... NONE LISTED
Emergency/First Aid Procedures.......... [EYE] FLUSH W/WATER IF
IRRITAITON OCCURS, GET MED.
ATTN. [SKIN] WASH CONTACT AREAS
W/SOAP AND WATER, REMOVE
CONTAMINATED CLOTHING. [INHALE]
NOT EXPECTED TO BE A PROBLEM,
HOWEVER IS RESPIRATORY
IRRITATION, DIZZINESS, NAUSEA,
OR UNCONSCIOUSNESS OCCUR SEEK
MED. ATTN. [INGEST] SEEK MED.
ATTN. IF DISCOMFORT OCCURS. DO
NOT INDUCE VOMITING.
SECTION VII - Precautions for Safe Handling and Use
Steps if Material Released/Spilled......
Neutralizing Agent......................
Waste Disposal Method...................
Handling and Storage Precautions........
Other Precautions.......................
SHUT OFF AT SOURCE, TAKING
NORMAL SAFETY PRECAUTIONS.
RECOVER BY PUMPING OR CONTAIN
SPILLED MATERIAL
W/SAND/ABSORBENT AND REMOVE
MECHANICALLY INTO CONTAINERS.
IF NECESSARY, DISPOSE OF
ABSORBED RESIDUES.
NONE LISTED
IN ACCORDANCE W/STATE, LOCAL,
AND FEDERAL REGULATIONS.
NO SPECIAL PRECAUTIONS ARE
NECESSARY BEYOND NORMAL GOOD
HYGIENE PRACTICES. KEEP
CONTAINERS TIGHTLY CLOSED WHEN
NOT IN USE. DO NOT STORE IN
OPEN OR UNLABELED CONTAINERS.
STORE AWAY FROM STRONG
OXIDIZING AGENTS AND
COMUBSTIBLE MATERIALS. DO NOT
STORE NEAR HEAT, SPARKS, FLAME
OR STRONG OXIDANTS.
READ AND UNDERSTAND ALL
CAUTIONS, LABELS AND
MSDS
BEFORE USING ANY CHEMICAL
PRODUCT.
SECTION VIII - Control Measures
172
Respiratory Protection.................. IF MISTS ARE GENERATED, WEAR
APPROVED RESPIRATOR
Ventilation............................. LOCAL EXHAUST
Protective Gloves....................... OIL RESISTANT
Eye Protection.......................... SAFETY GLASSES W/SIDE SHIELDS OR CHEMICAL GOGGLES
Other Protective Equipment.............. PROTECTIVE CLOTHING
Work Hygenic Practices.................. WASH HANDS THOROUGHLY AFTER
HANDLING
Supplemental Health/Safety Data......... NONE LISTED
SECTION IX - Label Data
Protect Eye.............................
Protect Skin............................
Protect Respiratory.....................
Chronic Indicator.......................
Contact Code............................
Fire Code...............................
Health Code.............................
React Code..............................
YES
YES
NO
YES
UNKNOWN
UNKNOWN
UNKNOWN
UNKNOWN
Specific Hazard and Precaution..........
NONE LISTED
SECTION X - Transportation Data
SECTION XI - Site Specific/Reporting Information
Volatile Organic Compounds (P/G) ....................................... 0
Volatile Organic Compounds (G/L) ........................................ 0
SECTION XII - Ingredients/Identity Information
Ingredient # ........................................................................... 01
Ingredient Name ................................................................... NO HAZARDOUS INGREDIENTS LISTED
ON MSDS
CAS Number .......................................................................... 1005
Percent .................................................................................. 0
NOTICE: For additional information, contact BIOENVIRONMENTAL
173
Knock-Out Weed Killer
HEALTH
FLAMMABILIT
REACTIVITY:
HIMIS
RATING:
2
1 0
:
Y:
RATING 4=extreme,3=serious,2=moderate,1=slight,0=mini
LEGEND:
mal
NOTE: Blank spaces are not permitted. If any item is
not applicable, or
no information is available, the space must be
marked to indicate that.
MATERIAL SAFETY
DATA SHEET
IDENTITY:
KNOCK OUT WEED KILLER
G88
Section I
Manufacturer's Name
Distributed by:
Emergency Telephone Number
Handi-Clean
Products,
(336) 292-3083 After 5:00 p.m. (336) 454-3662
Inc.
Date
301 Swing Rd.
Telephone Number for Information Prepared
Greensboro, NC 27409
(336) 292-3083
6/1/2004
Address:
Section II - Hazardous Ingredients/Identity Information
CAS NO.
68476-3465
91-20-3
1928-43-9
314-40-9
111-90-0
Fuel Oil
Panasol AN3N
Isooctyl 2-ethylhexyl ester 2, 4-D
Bromacil
Diethylene Glycol Monoethyl Ether
OSHA PEL
3
5mg/m
100ppm
10mg/kg
N/E
N/E
ACGIH TLV
3
5mg/m
100ppm
N/E
N/E
N/E
% (optional)
81.00
13.00
1.09
0.98
5.00
Section III - Physical/Chemical Characteristics
0
Boiling Point
Vapor Pressure (mm Hg)
430 F
N/E
Vapor Density (AIR = 1)
N/E
Specific Gravity (H20 = 1)
Evaporation Rate
0.88
Appearance
Odor
Dark Amber Liquid
Hydrocarbon
N/E
(Butyl Acetate =1)
Solubility in Water
Insoluble
Section IV - Fire and Explosion Hazard Data
0
Flash Point (Method Used): 155 F
Flammable Limits
LEL UEL Extinguishing Media: Dry Chemical, CO2 or Foam is recommended
Special Fire Fighting Procedures: Wear a self contained breathing apparatus with a full face-piece operated in
the
positive pressure demand mode with appropriate turn-out gear and chemical resistant personal protective
equipment.
Refer to the personal protective equipment section of this
MSDS.
Unusual Fire and Explosion Hazards: Combustible. Vapors could ignore if exposed to sparks or open flame.
Section V - Reactivity Data
Stability:
Stable
X
Unstable
174
Hazardous
May Occur
Polymerization:
Incompatibility (Materials to Avoid): Acids and strong
oxidizers
Hazardous Decomposition or Byproducts: CO,
CO2
Conditions to Avoid: High Temperatures
Will Not Occur
X
Section VI - Health Hazard Data
Inhalation
Route(s) of Entry:
X
Skin? X
Eyes? X
Ingestion? X
?
Health Hazards (Acute/Potential Health Effects): EYES: May cause mild irritation. Symptoms include stinging,
tearing and redness. SKIN: May cause mild skin irritation. Prolonged or repeated contact may dry the skin.
Absorption
from prolonged or massive skin contact may cause poisoning. INHALATION: Avoid breathing vapors or mists.
May
cause dizziness, nausea, headache or loss of consciousness. INGESTION: Harmful of fatal if swallowed.
Aspiration
hazard - this material can enter lungs during swallowing or vomiting and cause lung inflammation and damage.
Health Hazards (Chronic/Long Term Effects): Reports have associated repeated and prolonged occupational
overexposure to solvents with permanent brain and nervous system
damage.
Signs and Symptoms of Overexposure: Stomach or intestinal upset (nausea, vomiting, diarrhea) irritation (nose,
throat,
airways), central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache,
Emergency and First Aid Procedures: EYES/SKIN: Immediately flush eyes with plenty of water for at least 15
minutes. Get medical attention immediately. Remove contaminated clothing and shoes. Wash clothing before
reuse.
If not breathing, give artificial respiration. If breathing is difficult, give
INHALATION: Remove to fresh air. oxygen.
INGESTION: Seek medical attention immediately. Aspiration hazard: DO NOT induce vomiting or give anything
by
mouth because this material can enter the lungs and cause severe damage. Do not leave individual unattended.
Section VII - Precautions for Safe Handling and Use
Steps to Be Taken in Case Material is Released or Spilled: Stop all leaks. Isolate hazard area. Keep unnecessary
and unprotected personnel from entering. Absorb spill with inert material (e.g. dry sand, earth). Eliminate all
ignition sources. Prevent runoff from entering drains, sewers, streams or other bodies of water. Absorb
unrecoverable product. Transfer contaminated absorbent, soil and other materials to containers for disposal.
Waste Disposal Method:
Dispose in accordance with local, state, & federal regulations.
See label for
further
Precautions to Be Taken in Handling and Storing: Follow all MSDS/label precautions even after container is
emptied because they may contain product residues. Use with adequate ventilation. Do not get in eyes, on skin
175
or on clothing. Store in a cool dry place. Keep container closed when not in use.
Other Precautions:
KEEP OUT OF REACH OF CHILDREN
Section VIII - Control Measures
Respiratory Protection (Specify Type): When Required use Organic Vapor Cartridge
Ventilation: Good/General
Protective Gloves: Nitrile or Neoprene Gloves
Eye Protection: Safety Glasses or Goggles
Other Protective Clothing or Equipment: Prolonged/repeated contact wear impervious clothing and boots.
Work/Hygienic Practices: Wash hands with soap and water after using product
176
Krylon Engine Paint
00— Section 1 —
Material Safety Data Sheet
ProductIdentification
The
Sherwin-Williams Emergency
Company
numbers
Krylon
Products
Group
101 Prospect Avenue
Information
N.W.
number
Cleveland, OH
20,
July
44115
2000
ACGI OSH
H
A
Engine Paints - 1
CAS
No.
7498-6
— Section 2 —
Hazardous
Ingredients
(percent
weight)
Propane
6474289-8
V. M.
Naphtha.
10041-4 § Ethylbenzene
Acetone.
Ethyl
108- Methyl
10-1 § Ketone
Isobutyl
7727-
1923 1927
Ford
Dark Ford
Black
Gold
Blue
Blue
Blu
e
1928ENG1/KRI
Chrysler
Blue
Blue
760.
0
20
18
18
20
20
20
14
20
50 50
PPM
127.
0
11
12
11
10
11
10
6
11
8
8
8
7
8
7
8
16
20
18
17
17
17
17
50
0
500
<750 10
> 00
78- Mrthyl
93-3 § Ketone
10865-6
1705
P
PPM
180.
0
2
Barium Sulfate
10 10[
N
T
21
25
26
23
21
23
40
21
B
4
50 50 P P M 16.0
<75> <75>
Not
Established
R
E
9
20
200 0 P P M 70.7
<300> <30
0>
1-Methoxy-2Propanol Acetate
E
C
10
100 0 P P M 7.1
<125> <12
5>
10
100 0 P P M 5.9
<150> <15
0>
133020-7 § Xylene
6764-1
(800) 2512486
©2000, The SherwinWilliams Co.
PPM
250.
0
<1000> P P M
<1000>
30
0
P.
300 <40 P P M 12.0
0>
&
telephone
250 10
0 00
500
Isohexane
Isomers.
1612
(216) 566- United
2917 States
1908 1909
Chevrole
Universal Universal Engine
Ford
t
Press
TLV PEL Units ure
by <STE <STE
(mm
L>
L>
Hg) Gray
11054-3 § Hexane
10783-5
Vapo
1611
r
telephone
Y
7
W
1.8
Mg/
as
8
5
2
8
8
8
7
1
8
E
I
177
43-7
1346367-7
133386-4
5]
Titanium Dioxide.
Carbon Black.
10
10[
5]
3.5
3.
5
M3 Dust
[Resp Fractio
.
n]
Mg/ as
M3 Dust
[Resp Fractio
.
n]
Mg/
M3
3
2
1
3
G
H
T
0.5
[% Barium]
[0.6]
Weight per Gallon
(lbs.)
6.06
5.96
6.03
6.02
6.05
VOC Less Federally Exempt Solvents (percent by weight)
64.2
63.6
59.9
63.2
<0
<0
<0
<0
Flash Point (°F)
HMIS (NFPA) Rating
flammability - reactivity)
(health
6.02
6.49
6.08
64.9 63.4
45.9
64.3
<0
<0
<0
<0
2* - 4 - 0 2* - 4 - 0 2* - 4 - 0 2* - 4 - 0 2* - 4 - 0 2* - 4 - 0 2 - 4 - 0
2* - 4 - 0
Ingredient subject to the reporting requirements of the Superfund Amendments and Reauthorization
§ Act (SARA) Section 313, 40 CFR 372.65 C
Section 3 — Physical Data
PRODUCT WEIGHT See TABLE
SPECIFIC GRAVITY 0.72-0.78
BOILING RANGE
<0 - 325 °F
VOLATILE VOLUME 89-93 %
EVAPORATION
RATE
VAPOR
DENSITY
Faster than Ether
Heavier than Air
MELTING
POINT
SOLUBILITY
WATER
N.A.
IN
N.A.
Section 4 — Fire And Explosion Hazard Data
FLASH POINT
See TABLE
LEL 0.9
UEL 13.1
EXTINGUISHING
MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Isolate from heat, electrical equipment, sparks, and open flame. Closed containers may explode when exposed to
extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to
178
decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical
attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus should be used. Water spray may be
ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to extreme heat.
Section 5 — Health Hazard Data
ROUTES OF EXPOSURE
Exposure may be by INHALATION and/or SKIN or EYE contact, depending on conditions of use. To minimize
exposure, follow recommendations for proper use, ventilation, and personal protective equipment.
ACUTE Health Hazards
EFFECTS OF OVEREXPOSURE
Irritation of eyes, skin and respiratory system. May cause nervous system depression. Extreme overexposure
may result in unconsciousness and possibly death.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray
mists.
Redness and itching or burning sensation may indicate eye or excessive skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
EMERGENCY AND FIRST AID PROCEDURES
If INHALED: If affected, remove from exposure. Restore breathing. Keep warm and quiet. If on SKIN: Wash affected
area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
If in EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. If SWALLOWED: Never give
anything by mouth to an unconscious person. DO NOT INDUCE VOMITING.
Give conscious patient several glasses of water. Seek medical attention. CHRONIC Health Hazards
Carbon Black is classified by IARC as possibly carcinogenic to humans (Group 2B) based on experimental animals
data, however, there is inadequate evidence in humans for its carcinogenicity.
Prolonged and repeated exposure to Hexane may cause damage to nerve tissue of the arms and legs (peripheral
neuropathy), resulting in muscular weakness and loss of sensation. This effect may be increased by the presence of
Methyl Ethyl Ketone.
Methyl Ethyl Ketone may increase the nervous system effects of other solvents. Prolonged overexposure to
solvent ingredients may cause adverse effects to the liver,
urinary, blood forming and reproductive systems. Prolonged overexposure to solvent ingredients in 1611, 1612, 1705,
1908, 1909, 1923, and 1928 may cause adverse effects to the cardiovascular system.
Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung cancer, however, such exposure levels are
not attainable in the workplace.
Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous
system damage.
Section 6 — Reactivity Data
STABILITY — Stable
CONDITIONS TO AVOID — None known. INCOMPATIBILITY
— None known.
HAZARDOUS DECOMPOSITION PRODUCTS — By fire: Carbon Dioxide, Carbon Monoxide, Oxides of Metals in Section
2
HAZARDOUS POLYMERIZATION — Will Not Occur
Section 7 — Spill Or Leak Procedures
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate and remove with inert absorbent.
179
WASTE DISPOSAL METHOD
Waste from these products may be hazardous as defined under the Resource Conservation and Recovery Act
(RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the appli-cable EPA hazardous waste numbers.
Waste from products containing Methyl Ethyl Ketone may also require extractability testing.
Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State, and Local regulations
regarding pollution.
Section 8 — Protection Information
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation. Avoid breathing vapor and spray mist. Avoid contact with skin and eyes.
Wash hands after using.
These products may contain materials classified as nuisance particulates (listed “as Dust” in Section 2) which may be
present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2,
the applicable limits for nuisance dusts are ACGIH TLV 10 mg./m3 (total dust), 3 mg./m3 (respirable fraction), OSHA PEL
15 mg./m3 (total dust), 5 mg./m3 (respirable fraction).
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained
below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by ventilation, wear
a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in
Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which
may be generated from this product, underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal skin contact is expected. For long or
repeated contact, wear chemical resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
Section 9 — Precautions
DOL STORAGE CATEGORY — 1A
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights,
and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition.
Consult NFPA Code.
Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight,
radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out
of the reach of children.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal.
Section 10 — Other Regulatory Information
CALIFORNIA PROPOSITION 65
WARNING: These products contain chemicals known to the State of California to cause cancer and birth defects or
other reproductive harm.
TSCA CERTIFICATION
All chemicals in these products are listed, or are exempt from listing, on the TSCA Inventory.
180
The above information pertains to these products as currently formulated, and is based on the information
available at this time. Addition of reducers or other additives to these products may substantially alter the
composition and hazards of the product. Since conditions of use are outside our control, we make no warranties,
express or implied,
and assume no liability in connection with any use of this information.
181
Liquid Bleach
182
183
184
185
LPS 3 Heavy Duty Rust Inhibitor
186
187
188
Medaphene Plus Disinfecting Deoderant
Grainger MSDS Lookup
Common Name: 34720 MEDAPHENE DISINFECTANT SPRAY
Manufacturer: ITW DYMON
MSDS Revision Date: 8/18/2005
Grainger Item Number(s): 3U037
Manufacturer Model Number(s):
MSDS Table of Contents
Click the desired link below to jump directly to that section in the MSDS.
SECTION I
SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION
SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
SECTION V - REACTIVITY DATA
SECTION VI - HEALTH HAZARD DATA
SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE
SECTION VIII - CONTROL MEASURES
MATERIAL SAFETY DATA SHEET
MAY BE USED TO COMPLY WITH OSHA'S HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200. STANDARD
MUST BE CONSULTED FOR SPECIFIC REQUIREMENTS.
HMIS(R*):
HEALTH
2
FLAMMABILITY
3
REACTIVITY
0
PERSONAL PROTECTION B
IDENTITY (AS USED ON LABEL AND LIST):
34720 MEDAPHENE DISINFECTANT SPRAY EPA REG. NO.: 211-3211694
NOTE:
BLANK SPACES ARE NOT PERMITTED. IF ANY ITEM IS NOT APPLICABLE, OR NO
INFORMATION IS AVAILABLE, THE SPACE MUST BE MARKED TO INDICATE THAT.
189
SECTION I
MANUFACTURER'S NAME: ITW DYMON
ADDRESS (NUMBER, STREET, CITY, STATE, AND ZIP CODE): 805 EAST OLD 56 HIGHWAY
OLATHE, KANSAS 66061
EMERGENCY TELEPHONE NUMBER: 1-800-535-5053
TELEPHONE NUMBER FOR INFORMATION: 1-913-397-9889
DATE PREPARED: AUGUST 18, 2005
SIGNATURE OF PREPARER (OPTIONAL): REGULATORY DEPT.
SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION
HAZARDOUS COMPONENTS
(SPECIFIC CHEMICAL IDENTITY,
COMMON NAME(S))
CAS NO.
OSHA PEL
ACGIH-TLV
ETHANOL
64-17-5
1000 PPM
1000 PPM
ISOBUTANE
75-28-5
800 PPM
800 PPM
PROPANE
74-98-6
1000 PPM
2500 PPM
ORTHOPHENYLPHENOL*
HAZARDOUS COMPONENTS
(SPECIFIC CHEMICAL IDENTITY,
COMMON NAME(S))
90-43-7
NONE ESTAB.
OTHER LIMITS
RECOMMENDED % (OPT.)
ETHANOL
60-100%
ISOBUTANE
10-30%
PROPANE
1-5%
ORTHOPHENYLPHENOL*
<1%
NONE ESTAB.
*SARA TITLE III SECTION 313 REPORTABLE
TSCA:
ALL INGREDIENTS ARE ON THE TSCA INVENTORY OR ARE NOT REQUIRED TO BE LISTED
ON THE TSCA INVENTORY.
ANY SUBSTANCE LISTED AS HAZARDOUS BY THE STATES OF CALIFORNIA, FLORIDA,
ILLINOIS, MICHIGAN, NEW JERSEY, OHIO, PENNSYLVANIA OR TEXAS IS DESCRIBED
ABOVE IF KNOWN PRESENT IN REGULATED CONCENTRATIONS.
SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS
BOILING POINT CONCENTRATE: 212 DEG. F
SPECIFIC GRAVITY (H2O=1) 70 DEG. F CONCENTRATE: 0.824
190
PRESSURE (PSIG. @ 70 DEG. F): NO DATA
MELTING POINT: NO DATA
VAPOR DENSITY (AIR=1): NO DATA
EVAPORATION RATE (ETHYL ETHER=1): NO DATA
SOLUBILITY IN WATER: COMPLETE
pH: NO DATA
APPEARANCE AND ODOR - CLEAR LIQUID WITH AN ALCOHOL AND FLORAL SCENT IN AN
AEROSOL CAN.
VOC'S - THIS PRODUCT CONTAINS 669 GRAMS PER LITER OR 89.5% BY WEIGHT VOC'S.
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
USA FLAME PROJECTION TEST: >18", NO FLASHBACK (FLAMMABLE)
FLAMMABLE LIMITS: NO DATA
LEL: NO DATA
UEL: NO DATA
EXTINGUISHING MEDIA: USE CARBON DIOXIDE, DRY CHEMICAL, FOAM.
SPECIAL FIRE FIGHTING PROCEDURES - USE WATER SPRAY TO KEEP CONTAINERS COOL
AND VAPORS DOWN. DO NOT ALLOW RUNOFF TO ENTER SEWERS OR PUBLIC
WATERCOURSES. WEAR SELF-CONTAINED BREATHING APPARATUS IN CHEMICAL FIRES.
UNUSUAL FIRE AND EXPLOSION HAZARDS - AEROSOL CONTAINER (PRESSURIZED) MAY BURST IF HEATED OVER
130 DEG. F.
SECTION V - REACTIVITY DATA
STABILITY:
UNSTABLE ( )
STABLE
(X)
CONDITIONS TO AVOID - EXTREME HEAT, DIRECT SUNLIGHT
INCOMPATIBILITY (MATERIALS TO AVOID) - STRONG ACIDS AND OXIDIZERS.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS - CARBON DIOXIDE AND CARBON MONOXIDE
HAZARDOUS POLYMERIZATION:
MAY OCCUR
()
WILL NOT OCCUR (X)
CONDITIONS TO AVOID - NONE KNOWN
SECTION VI - HEALTH HAZARD DATA
191
ROUTE(S) OF ENTRY:
EYES?
YES
INHALATION?
YES
SKIN?
YES
INGESTION?
NO
HEALTH HAZARDS (ACUTE AND CHRONIC) - WILL CAUSE EYE IRRITATION UPON
EXPOSURE AND SKIN IRRITATION WITH PROLONGED EXPOSURE. CAN BE HARMFUL IF
SWALLOWED OR IF SPRAY MIST IS INHALED.
CARCINOGENICITY: NONE KNOWN
NTP?
NO
IARC MONOGRAPHS?
NO
OSHA REGULATED?
NO
SIGNS AND SYMPTOMS OF EXPOSURE IF IN EYES: BURNING SENSATION, WATERING, OR REDNESS.
192
IF ON SKIN:
REDNESS, IRRITATION, OR BURNING SENSATION WITH PROLONGED EXPOSURE.
IF SPRAY MIST IS INHALED:
COUGHING, STUPOR, DROWSINESS OR LOSS OF CONSCIOUSNESS WITH PROLONGED
BREATHING OF VAPORS.
IF SWALLOWED: POSSIBLE GASTROINTESTINAL IRRITATION OR DISTURBANCE.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE - NONE KNOWN.
EMERGENCY AND FIRST AID PROCEDURES:
EYES - FLUSH WITH WATER FOR 15 MINUTES.
SKIN - WASH LIBERALLY WITH SOAP AND WATER.
IF ON CLOTHES - WASH BEFORE REUSE.
INHALATION - REMOVE TO FRESH AIR.
INGESTION - IF PATIENT IS CONSCIOUS AND ALERT, DILUTE BY DRINKING LARGE
QUANTITIES OF WATER. DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. ALWAYS
GET MEDICAL ATTENTION WHEN PRODUCT IS SWALLOWED OR WHEN SYMPTOMS ARE
SIGNIFICANT OR PERSIST.
SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE
STEPS TO BE TAKEN IN CASE
MATERIAL IS RELEASED OR SPILLED THA
MA
SMALL SPILLS (LESS N
1 GALLON) Y
BE CONTAINED AND LEFT TO EVAPORATE.
NOTE: DILUTION WITH WATER WILL REDUCE FLASH POINT.
(MOR THA
LARGE SPILLS E
1 GALLON) SHOULD BE CONTAINED AND COLLECTED (BY
N
ABSORPTION OR VACUUMING) THEN EVAPORATED OR DISPOSED OF PROPERLY.
WASTE DISPOSAL METHOD - THIS PRODUCT IS CONSIDERED A RCRA HAZARDOUS WASTE
FOR FLAMMABILITY (D001) AS IDENTIFIED IN FEDERAL REGULATIONS 40 CFR 261.
DISPOSE OF PRODUCT BY USING IN ACCORDANCE WITH LABEL DIRECTIONS OR IN
COMPLIANCE WITH LOCAL, STATE, AND FEDERAL LAWS AND REGULATIONS (CONTACT
LOCAL OR STATE ENVIRONMENTAL AGENCY FOR SPECIFIC RULES).
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING - DO NOT CONTAMINATE WATER,
FOOD OR FEED. DO NOT REUSE EMPTY CONTAINERS. KEEP CONTAINERS CLEAN AND
CLOSED. KEEP OUT OF REACH OF CHILDREN. DO NOT STORE NEAR IGNITION SOURCES
OR AT TEMPERATURES ABOVE 120 DEG. F.
SECTION VIII - CONTROL MEASURES
RESPIRATORY PROTECTION (SPECIFY TYPE) - GENERAL VENTILATION IS NORMALLY
ADEQUATE. DON NOT CREATE OR INHALE MISTS OR VAPORS. US AND APPROVED VAPOR
193
RESPIRATOR IN TIGHT OR CLOSE AREAS.
VENTILATION:
LOCAL EXHAUST - NOT USUALLY NECESSARY
MECHANICAL (GENERAL) - NORMALLY SUFFICIENT
SPECIAL - NONE
OTHER - NONE
PROTECTIVE GLOVES - YES (RUBBER)
EYE PROTECTION - YES (GOGGLES OR APPROVED SAFETY GLASSES)
OTHER PROTECTIVE CLOTHING OR EQUIPMENT - NOT USUALLY NECESSARY.
WORK/HYGIENIC PRACTICES - WASH HANDS AFTER USING. DON NOT GET INTO EYES, ON
SKIN, OR CLOTHING. MAY BE HARMFUL IF SWALLOWED, PROTECT FOOD AND DRINK FROM
CONTAMINATION BY PRODUCT.
WARNING!
THE USE OF THIS PRODUCT IS BEYOND THE CONTROL OF THE MANUFACTURER;
THEREFORE, NO GUARANTEE, EXPRESSED OR IMPLIED, IS MADE AS TO THE EFFECTS OF
SUCH OR THE RESULTS TO BE OBTAINED IF NOT USED IN ACCORDANCE WITH DIRECTIONS
OR ESTABLISHED SAFE PRACTICE. THE USER MUST ASSUME ALL RESPONSIBILITY,
INCLUDING INJURY OR DAMAGE, RESULTING FROM ITS MISUSE AS SUCH, OR IN
COMBINATION WITH OTHER MATERIALS. THE MANUFACTURER WARRANTS ONLY THAT THIS
PRODUCT MEETS THE MANUFACTURER'S SPECIFICATIONS FOR SUCH PRODUCT. THIS
WARRANTY IS IN LIEU OF ALL OTHER WARRANTIES, EXPRESS OR IMPLIED, AS TO
DESCRIPTION, QUALITY, MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE,
PRODUCTIVENESS, OR ANY OTHER MATTER, OF THIS PRODUCT. THE MANUFACTURER SHALL
BE IN NO WAY RESPONSIBLE FOR THE IMPROPER USE OF THIS PRODUCT. THE SOLE AND
EXCLUSIVE REMEDY AGAINST THE MANUFACTURER FOR BREACH OF WARRANTY SHALL BE
REIMBURSEMENT OF THE PURCHASE PRICE OF THE PRODUCT IN THE EVENT THAT A
DEFECTIVE CONDITION OF THE PRODUCT SHALL BE FOUND TO EXIST. NO OTHER REMEDY
(INCLUDING BUT NOT LIMITED TO INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR INJURY
TO PERSON OR PROPERTY OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL
BE AVAILABLE.
34720
http://complyplus.grainger.com/grainger/msds.asp?sheetid=2820412
6/20/2008
194
Mineral Spirits
MATERIAL SAFETY DATA SHEET
SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
153-8180
PRODUCT NAME
Mineral Spirits
MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
101 Prospect Avenue N.W.
Cleveland, OH 44115
Telephone Numbers and Websites
Regulatory Information (216) 566-2902
www.paintdocs.com
Medical Emergency (216) 566-2917
*
Transportation Emergency (800) 424-9300
*
for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident)
SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS
% by Weight
100
CAS Number Ingredient
Units
Vapor Pressure
64742-88-7 Mineral Spirits
ACGIH TLV
100 PPM
OSHA PEL
100 PPM
2 mm
SECTION 3 — HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper
respiratory system.
HMIS Codes
Health 2
Flammability 2
Reactivity 0
May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly
death.
195
Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the
following organs or systems:
the liver
the urinary system
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to
vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin
exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
SECTION 4 — FIRST AID MEASURES
EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet.
INGESTION: Do not induce vomiting. Get medical attention immediately.
SECTION 5 — FIRE FIGHTING MEASURES
FLASH POINT
LEL
UEL
FLAMMABILITY CLASSIFICATION
Combustible, Flash above 99 and below
200 °F
105 °F PMCC
1.0
6.0
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers may explode when
exposed to extreme heat. Application to
hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may cause a health hazard.
Symptoms may not be immediately apparent. Obtain medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus should be used.
Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed
containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme
heat.
SECTION 6 — ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
SECTION 7 — HANDLING AND STORAGE
196
STORAGE CATEGORY
DOL Storage Class II
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Contents are COMBUSTIBLE. Keep away from heat
and open flame. Consult NFPA Code. Use
approved Bonding and Grounding procedures.
Keep container closed when not in use. Transfer only to approved containers with complete and
appropriate labeling. Do not take internally. Keep out of the reach of children.
SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained
below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted
organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in
Section 2.
PROTECTIVE GLOVES
Wear gloves which are recommended by glove supplier for protection against materials in Section 2.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal.
SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT
SPECIFIC GRAVITY
BOILING POINT
MELTING POINT
VOLATILE VOLUME
6.42 lb/gal
769 g/l
0.77
300 - 395 °F
148 - 201 °C
Not Available
100%
Slower
than
EVAPORATION RATE ether
VAPOR DENSITY Heavier than air
SOLUBILITY IN WATER N.A.
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
6.42
Less Water and Federally Exempt
769 g/l Solvents
lb/gal
6.42
769 g/l Emitted VOC
lb/gal
SECTION 10 — STABILITY AND REACTIVITY
STABILITY — Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
197
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
SECTION 11 — TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous
system damage.
TOXICOLOGY DATA
CAS No.
64742-88-7
Ingredient Name
Mineral Spirits
LC50 RAT
LD50
RAT
4HR
Not Available
Not Available
SECTION 12 — ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.
SECTION 13 — DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource Conservation and
Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable
EPA hazardous waste numbers.
Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with
Federal, State/Provincial, and Local regulations regarding pollution.
SECTION 14 — TRANSPORT INFORMATION
Multi-modal shipping descriptions are provided for informational purposes and do not consider container
sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does
not indicate that the product is packaged suitably for that mode of transport. All packaging must be
reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport.
US Ground (DOT)
May be Classed as a Combustible Liquid for U.S. Ground.
UN1263, PAINT RELATED MATERIAL, 3, PG III, (ERG#128)
Bulk Containers may be Shipped as:
UN1263,
PAINT
RELATED
MATERIAL,
COMBUSTIBLE LIQUID, PG III, (ERG#128)
Canada (TDG)
May be Classed as a Combustible Liquid for Canadian Ground.
UN1263, PAINT RELATED MATERIAL, CLASS 3, PG III, (ERG#128)
IMO
5 Liters (1.3 Gallons) and Less may be Shipped as
Limited Quantity. UN1263, PAINT RELATED
198
MATERIAL, CLASS 3, PG III, (41 C c.c.), EmS F-E, S-E,
ADR (D/E)
IATA/ICAO
UN1263, PAINT RELATED MATERIAL, 3, PG III
SECTION 15 — REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory.
SECTION 16 — OTHER INFORMATION
This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products
Regulations (CPR) and the MSDS contains all of the information required by the CPR.
The above information pertains to this product as currently formulated, and is based on the information
available at this time. Addition of reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are outside our control, we make no
warranties, express or implied, and assume no liability in connection with any use of this information.
199
Misty Powder Puff Residual Insecticide
MATERIAL SAFETY DATA SHEET
This MSDS complies with OSHA'S Hazard Communication Standard 29 CFR 1910.1200 and OSHA
Form 174
IDENTITY AND MANUFACTURER'S INFORMATION
NFPA Rating: Health-2;
Flammability-2;
Reactivity-0; HMIS
Rating: Flammability-2; Reactivity-0; Personal
Special-0
Health-2;
Protection-D
Manufacturer's
Name:
AMREP, INC.
DOT Hazard Classification: ORM-D
Address:
990 Industrial Park Drive
Identity (trade name as used on label):
Marietta, GA 30062
MISTY POWDER PUFF RESIDUAL INSECTICIDE
Date
Prepared:
MSDS
Number:
RevisionPrepared By: LF
03/26/96
427
12
NOTICE: JUDGEMENT BASED ON INDIRECT TEST DATA
Information Calls: (770)422-2071
EMERGENCY RESPONSE NUMBER: 1(800)255-3924
SECTION 1 INFORMATION
MATERIAL
COMPONENTS-CHEMICAL NAMES AND COMMON NAMES
(Hazardous Components 1% or greater; Carcinogens 0.1% or
greater)
CYCLOHEXANE
PIPERONYL
BUTOXIDE
SILICA GEL
ISOPROPANOL
ISOBUTANE / PROPANE BLEND
IDENTIFICATION
AND
CAS
Number
SARA OSHA PEL
110-82-7
III LIST
Yes
(ppm)
300
ACGIH Carcinogen
TLV Ref. Source
(ppm)
**
300
d
51-03-6
Yes
N/E
N/E
d
1343-98-2
No
N/E
N/E
d
67-63-0
No
500
400
d
75-28-5
No
800
800
d
74-98-6
No
1000
1000
d
SECTION 2 - PHYSICAL/CHEMICAL CHARACTERISTICS
Specific
Gravity
Boiling Point: N/A
Concentrate Only = 0.818
(H2O=1):
Vapor Pressure (Non-Aerosols)(mm Hg and Temperature):
Vapor Pressure: PSIG @ 70°F (Aerosols): Max. 60
N/A
Vapor Density (Air = 1): N/E
Evaporation Rate ( = 1): N/E
Solubility in Water: Insoluble
Water Reactive: No
Appearance and Odor: White powder with cyclohexane
solvent odor.
SECTION 3 - FIRE AND EXPLOSION HAZARD DATA
FLAMMABILITY as per USA FLAME PROJECTION
Flammability Limits in Air by % in
TEST
Auto Ignition Temperature Volume:
(aerosols
EXTREMELY FLAMMABLE
N/E
% LEL: N/E
% UEL: N/E
)
FLASH POINT AND METHOD USED (non-aerosols):
EXTINGUISHER MEDIA: Foam, dry chemical,
N/A
carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: Self-contained
breathing apparatus.
Unusual Fire & Explosion Hazards: Do not expose aerosols toabove 130°F or the container may
temperatures
rupture.
SECTION 4 - REACTIVITY HAZARD DATA
STABILIT
HAZARDOUS POLYMERIZATION [
[ X ] STABLE [ ] UNSTABLE
[ X ] WILL NOT OCCUR
Y
] WILL
Incompatibility (Mat. to avoid): Water, aluminum, Conditions to Avoid: Open flame, welding arcs,
200
magnesium, alkalis, oxidizing
heat, sparks.
agents, sodium, amines.
Hazardous Decomposition Products: CO, CO2
SECTION 5 - HEALTH HAZARD DATA
PRIMARY ROUTES OF ENTRY: [ X ] [ ] INGESTION [ ] SKIN ABSORPTION [ ]
] NOT
INHALATION
EYE [
HAZARDOUS
ACUTE EFFECTS:
Inhalation: Excessive inhalation of vapors can be harmful and may cause headache, dizziness, anesthetic effects,
asphyxia, and possible unconsciousness.
Eye Contact: Irritation. Can cause possible eye damage.
Skin Contact: Irritation due to defatting of skin.
Ingestion: Possible chemical pneumonitis if aspirated into
lungs. Nausea.
CHRONIC EFFECTS: (Effects due to excessive exposure to the raw materials of this mixture) May cause liver,
kidney, lung damage, central nervous system depression.
Medical Conditions Generally Aggravated by Exposure: May aggravate existing eye, skin, or upper respiratory
conditions.
EMERGENCY FIRST AID PROCEDURES
Eye Contact: Flush with water for 15 minutes. If irritated, seek medical attention.
Skin Contact: Wash with soap and water. If irritated, seek medical attention.
Inhalation: Remove to fresh air. Resuscitate if necessary. Get medical attention.
Ingestion: DO NOT INDUCE VOMITING. Drink two large glasses of water. Get immediate medical attention.
SECTION 6 - CONTROL AND PROTECTIVE MEASURES
Respiratory Protection (specify type): If vapor concentration exceeds TLV, use respirator approved by U.S. Bureau of
Mines for organic vapor.
Protective Gloves: Neoprene gloves recommended.
Eye Protection: Goggles or face shield required.
Ventilation Requirements: Adequate ventilation to keep vapor concentration below TLV.
Other Protective Clothing & Equipment: Rubber apron.
Hygienic Work Practices: Wash with soap and water before handling food. Remove contaminated clothing.
SECTION 7 - PRECAUTIONS FOR SAFE HANDLING AND USE
Steps To Be Taken If Material Is Spilled Or Released: Absorb with suitable medium. Incinerate or landfill according
to local, state or Federal regulations. DO NOT ALLOW INTO SEWER SYSTEMS. Avoid breathing vapors.
Waste Disposal Methods: Aerosol cans when vented to atmospheric pressure through normal use, pose no disposal
hazard.
Precautions To Be Taken In Handling & Storage: Do not puncture or incinerate containers. Do not store at
temperatures above 130°F.
Other Precautions &/or Special Hazards: KEEP OUT OF REACH OF CHILDREN. Avoid food contamination. Avoid
breathing vapors. Remove ignition sources.
We believe the statements, technical information and recommendations contained herein are reliable, but they are
given without warranty or guarantee of any kind.
** Chemical Listed as Carcinogen or Potential Carcinogen. [a] NTP [b] IARC Monograph [c] OSHA [d]
Not Listed [e] Animal Data Only
201
Oxygen
202
203
204
205
206
207
208
209
210
211
212
PB B'Laster
PB BLASTER
Product: PB−B
Section 1: PRODUCT INFORMATION
Chemical family: Mixture.
Manufacturer: Truflex/Pang Rubber Products Company, Inc.
200 East Coshocton Street
P.O. Box 486
Johnstown, Ohio 43031.
Manufacturer
emergency
phone
800−424−9300.
number: International: 703−527−3887.
Chemtrec
Information phone number: 740−967−9015.
800−433−8324.
Supplier: Same as manufacturer.
Product name: PB BLASTER (MSDS #113)
Product uses: Penetrating lubricant.
Catalog number(s): PB−B
TDG classification:
AEROSOLS
UN1950
Class 2.1.
May be shipped as Consumer Commodity ORM−D.
Labels required: None
Emergency response guidebooknumber:
126
EmS number: 2−13
Reportable Quantity (DOT): Not applicable.
Effective date: 2010/9/20
Revision No.: 3
Last review: 2010/9/20
NFPA:
Section 2: HAZARDOUS INGREDIENTS
C.A.S.
Concentration%
wgt/wgt
Ingredient Name
ACGIH−TLV
TWA
LD/50
LC/50
213
124−38−9 < 2
34590−94−
8
>3
CARBON DIOXIDE
DIPROPYLENE
MONOMETHYL ETHER
64742−57−0 20 − 30
PETROLEUM OIL
64742−94−
> 50
5
NAPHTHA, PETROLEUM
> 2 ML/KG
84133−50−
>2
0
ALKYLOXYPOLYETHYLENEOXYETHAN
OL
NOT AVAILABLE NOT AVAILABLE
GLYCOL
5000 PPM
NOT AVAILABLE NOT AVAILABLE
100 PPM (SKIN) 5400 UL/KG
NOT AVAILABLE
RAT ORAL
5.5 ML/KG
RAT ORAL
10 ML/KG
RABBIT DERMAL
5 MG/M3
NOT AVAILABLE
NOT AVAILABLE
>
590
MG/M3/4H
RAT
RABBIT DERMAL INHALATION
Section 3: PHYSICAL DATA
Physical state: Liquid.
Appearance & odor: Amber
Dark brown.
Strong aromatic odour.
Viscous liquid.
Odor threshold (ppm): Not available.
Vapour pressure (mmHg): Not applicable.
Vapour density (air=1): >1
Volatiles (%)
By volume: 69.1
Evaporation rate >1
(butyl acetate = 1):
Boiling point (°C): 178 − 215 (352−418°F)
Freezing point (°C): Not available.
pH: Not available.
Specific gravity @ 20 °C: 0.9020 (7.515 lbs/gal)
Solubility in water (%):
Not available.
Coefficient of water\oil dist.:
Not available.
VOC: 5.194 LBS/GAL (615.8 G/L)
Section 4: FIRE & EXPLOSION DATA
Flammability:
Flammable aerosol.
Conditions of flammability: Vapours are heavier than air and may travel along the ground and be ignited by
flames, sparks or other ignition sources at locations distant from the material
handling point.
Heat, sparks and open flames.
214
Extinguishing media:
Carbon dioxide, dry chemical, foam.
Special procedures: Self−contained breathing apparatus required.
Firefighters should wear the usual protective gear.
Auto−ignition temperature:
Not available.
Flash point (°C), method: Tag Closed Cup. 66.7 (152°F)
Lower flammability limit (% vol):
Not available.
Upper flammability limit (% vol):
Not available.
Explosion Data
Sensitivity to static discharge: Take precautionary measures against static discharge.
Sensitivity to mechanical impact: Contents under pressure.
Hazardous combustion products: Oxides of carbon (CO, CO2). Various
hydrocarbons.
Explosive power: Product (even just residue) can ignite explosively.
Section 5: REACTIVITY DATA
Chemical stability:
Conditions of instability:
Product is stable.
None known.
Hazardous polymerization:
Will not occur.
Incompatible substances:
Strong acids.
Strong oxidizing agents.
Hazardous decompositionproducts: See hazardous combustion products.
Section 6: TOXICOLOGICAL PROPERTIES
Route of entry: Skin contact, eye contact, inhalation and ingestion.
Effects of acute exposure
Eye contact:
May cause irritation.
May cause redness and tearing. May
cause stinging.
May cause swelling.
Skin contact:
May cause skin burns.
May cause mild irritation.
May cause drying and cracking.
May cause redness or burning sensation.
Inhalation:
May cause drowsiness.
May cause kidney and liver damage.
May cause irritation of the respiratory tract.
May cause light headedness.
Ingestion: Can cause irritation to mouth, throat, esophagus and stomach.
215
Aspiration hazard if swallowed.
Effects of chronic exposure: May affect the central nervous system.
LD50 of product, species & route: Not available for mixture, see the ingredients section.
LC50 of product, species & route: Not available for mixture, see the ingredients section.
Exposure limit of material: Not available for mixture, see the ingredients section.
Sensitization to product: Not available.
Carcinogenic effects: Not listed as a carcinogen.
Reproductive effects: Not available.
Teratogenicity: Not available.
Mutagenicity: Not available.
Synergistic materials: Not available.
Section 7: PREVENTATIVE MEASURES
Precautionary Measures
Gloves/Type:
Chemical resistant gloves.
Polyvinyl alcohol gloves.
Nitrile gloves.
Respiratory/Type:
NIOSH approved respirator, if necessary. (negative
pressure type).
Footwear/Type:
Impervious boots.
Clothing/Type:
Impervious clothing.
Other/Type:
Eye wash facility should be in close proximity.
Emergency shower should be in close proximity.
Ventilation requirements: Explosion proof ventilation equipment.
Local exhaust and/or general ventilation.
Leak/Spill:
Recover using a pump. Eliminate all
sources of ignition. Dike area to prevent
spreading.
Evacuate all non−essential personnel.
Prevent entry into drains, sewers, and other waterways. Absorb residual
material with sand or other absorbent material. Stop leak if without risk.
Wear appropriate protective equipment. Ground
handling equipment.
Transfer to an approved container for disposal. Notify
the appropriate authorities as required.
Waste disposal: In accordance with municipal, provincial and federal regulations.
216
Handling procedures and Maintain a good personal hygiene. equipment: Keep away
from heat, sparks, and open flame.
Use adequate ventilation.
Wash thoroughly after using, particularly before eating or smoking. Wear
personal protective equipment appropriate to task.
Empty containers containing residue may cause a hazard. Do not
cut, grind, weld or drill empty container.
Use proper grounding procedures.
Avoid contact with skin, eyes and clothing. Avoid
breathing vapor, fumes or mist. Launder contaminated
clothing prior to reuse. Do not ingest.
Storage requirements: Store away from all sources of ignition.
Store away from strong acids or oxidizers.
Special shipping information: See transportation information.
Section 8: FIRST AID MEASURES
Skin contact:
Eye contact:
Remove contaminated clothing.
Wash with mild soap and water.
Consult a physician if irritation persists.
Flush eyes with clear, running water for 20 minutes while holding
eyelids open. If irritation persists, consult a physician.
Inhalation:
Keep person warm and at rest.
Remove victim to fresh air. If breathing is difficult administer
oxygen. If not breathing, have qualified person give artificial
respiration. Obtain medical attention.
Ingestion:
If victim is drowsy or unconscious, place on left side with head
down. Do not leave individual unattended.
Never give anything by mouth to an
unconscious person. Do not induce
vomiting,
seek
immediate
medical
attention.
Additional information:
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. This
company shall not be held liable for any inaccuracies.
Section 9: ADDITIONAL INFORMATION
General note:
This material safety data sheet was prepared from information
obtained from various sources, including product suppliers
and the Canadian Center for Occupational Health and Safety.
217
Pressure Treated Wood
218
219
220
221
222
223
224
Propane
225
226
227
228
229
230
231
PVC Plastic Pipe
232
233
PVC Solvent
MATERIAL SAFETY DATA SHEET
Regular Clear PVC Solvent Cement
MSDS# 5-14, 5-12, 5-10, 5-32
March 2009
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Manufactured by: Oatey Company
Address: 4700 West 160th Stree
P.O. Box 35906
Cleveland, OH 44135
EMERGENCY Phone No.: 1+800.255.3924 Chem-Tel (Chemical Emergencies Only)
Phone Number for Information: 850-875-1716 Fax: 850-627-2699
Date Revised: March 2009
SECTION 2. COMPOSITION
INGREDIENT
% OR
CAS NO
RANGE
Acetone
ACIGH
OSHA
TLV TWA
PEL TWA
500 ppm
1000 ppm
0 - 5%
67-64-1
Cyclohexanone
5 - 10%
108-94-1
Tetrahydrofuran
25 - 40%
109-99-9
200 ppm
200 ppm
Methyl Ethyl Ketone
45 - 60%
78-93-3
200 ppm
200 ppm
PVC Resin
10 - 16%
9002-86-2
10 mg/m3
15 mg/m3
OTHER
750 ppm STEL
25 ppm(skin)
50 ppm
25
ppm
(Mfg)
750 ppm STEL
(Non-hazardous)
SECTION 3. EMERGENCY OVERVIEW
Clear liquid with an ether-like odor. Extremely flammable liquid and vapor. Vapors may cause flash fire. May cause eye
and skin irritation. Inhalation of vapors or mist may cause respiratory irritation and central nervous system effects.
Swallowing may cause irritation, nausea, vomiting, diarrhea and kidney or liver disorders. Aspiration hazard. May be
fatal if swallowed. Symptoms may be delayed.
NFPA Hazard Signal: Health: 2 Stability: 1 Flammability: 3 Special: None
HMIS Hazard Signal: Health: 3 Stability: 1 Flammability: 3
Special: None OSHA Hazard Classification: Flammable,
irritant, organ effects
Canadian WHIMS Classification: Class B, Division 1; Class D, Division 2, Subdivision B
SECTION 4. EMERGENCY AND FIRST AID PROCEDURES
234
Skin: Remove contaminated clothing immediately. Wash all exposed areas with soap and water. Get medical
attention if irritation develops. Remove dried cement with Oatey Plumber's Hand Cleaner or baby oil.
Eyes: If material gets into eyes or if fumes cause irritation, immediately flush eyes with water for 15
minutes. If irritation persists, seek medical attention.
Inhalation: If symptoms of exposure develop, remove to fresh air. If breathing becomes difficult,
administer oxygen. Administer artificial respiration if breathing has stopped. Seek immediate medical
attention.
Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water. Never give anything by mouth to a person who is
unconscious or drowsy. Get immediate medical attention by calling a Poison Control Center, or hospital emergency
room. If medical advice cannot be obtained, then take the person and product to the nearest medical emergency
treatment center or hospital.
SECTION 5. FIREFIGHTING MEASURES
Flashpoint / Method: 0 - 5 Degrees F. / PMCC
Flammability: LEL = 1.8 % Volume, UEL = 11.8 % Volume
Extinguishing Media: Use dry chemical, CO2, or foam to extinguish fire. Cool fire exposed container with water. Water
may be innefective as an extinguish-ing agent.
Special Fire Fighting Procedure: Fire Firefighters should wear positive pressure self-contained breathing apparatus
and full protective clothing for fires in areas where chemicals are used or stored.
Unusual Fire or Explosion Hazards: Extremely flammable liquid. Keep away from heat and all sources of ignition
including sparks, flames, lighted cigarettes and pilot lights. Containers may rupture or explode in the heat of a fire.
Vapors are heavier than air and may travel to a remote ignition source and flash back. This product contains
tetrahydrofuran that may form explosive organic peroxide when exposed to air or light or with age.
Hazardous Decomposition Products: Combustion will produce toxic and irritating vapors including carbon monoxide,
carbon dioxide and hydrogen chloride.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Spill or Leak Procedures: Remove all sources of ignition and ventilate area. Stop leak if it can be done without risk.
Personnel cleaning up the spill should wear appropriate personal protective equipment, including respirators if vapor
concentrations are high. Soak up spill with an inert absorbent such as sand, earth or other non-combusting material.
Put absorbent material in covered, labeled metal containers. Prevent liquid from entering watercourses, sewers and
natural waterways. Report releases to authorities as required. See Section 12 for disposal information.
SECTION 7. HANDLING AND STORAGE
Handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists. Use with adequate
ventilation (equivalent to outdoors). Wash thoroughly after handling. Do not eat, drink or smoke in the work area.
Keep product away from heat, sparks, flames and all other sources of ignition. No smoking in storage or use areas.
Keep containers closed when not in use.
Storage: Store in a cool, dry, well-ventilated area away from incompatible materials. Keep containers closed when not
in use.
Other: "Empty" containers retain product residue and can be hazardous. Follow all MSDS precautions in handling
empty containers. Do not cut or weld on or near empty or full containers.
SECTION 8. ECOLOGICAL INFORMATION
This product is not expected to be toxic to aquatic
organisms. Cyclohexanone: 96 hour LC50 values for fish
is over 100 mg/l. Tetrahydrofuran: 96 hour LC50
235
fathead minnow: 2160 mg/L. Methyl Ethyl Ketone: 96
hour LC50 for fish is greater than 100 mg/L. Acetone: 96
hour LC50 for fish is greater than 100 mg/L.
VOC Information: This product emits VOC's (volatile organic compounds) in its use. Make sure that use of this
product complies with local VOC emission regulations, where they exist.
VOC Level: 550 g/l per SCAQMD Test Method 316A.
SECTION 9. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation: Open doors & windows. Provide ventilation capable of maintaining emissions at the point of use below
recommended exposure limits. If used in enclosed area, use exhaust fans. Exhaust fans should be explosion-proof or
set up in a way that flammable concentrations of solvent vapors are not exposed to electrical fixtures or hot surfaces.
Respiratory Protection: For operations where the exposure limit may be exceeded, a NIOSH approved organic vapor
respirator or supplied air respirator is recommended. Equipment selection depends on contaminant type and
concentration, select in accordance with 29 CFR 1910.134 and good industrial hygiene practice. For firefighting, use
self-contained breathing apparatus.
Skin Protection: Rubber gloves are suitable for normal use of the product. For long exposures product chemical
resistant gloves may be required such as 4H(tm) or Silver Shield(tm) to avoid prolonged skin contact.
Eye Protection: Safety glasses with sideshields or
safety goggles. Other: Eye wash and safety shower
should be available.
SECTION 10. PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point: 151 Degrees F / 66 C
Melting Point: N/A
Vapor Pressure: 145 mmHg @ 20 Degrees C
Vapor Density: (Air = 1) 2.5
Volatile Components: 8690% Solubility In Water:
Negligible pH: N/A
Specific Gravity: 0.89 +/- 0.015
Evaporation Rate: (BUAC = 1) = 5.5 8.0 Appearance: Clear Liquid
Odor: Ether-Like
Will Dissolve In: Tetrahydrofuran
Material Is: Liquid
SECTION 11. STABILITY AND REACTIVITY
Stability: Stable.
Conditions To Avoid: Avoid heat, sparks, flames and other sources of ignition.
Hazardous Decomposition Products: Combustion will produce toxic and irritating vapors including carbon monoxide,
carbon dioxide and hydrogen chloride. Incompatibility/Materials To Avoid: Oxidizing agents, alkalies, amines,
ammonia, acids, chlorine compounds, chlorinated inorganics (potassium, calcium and sodium hypochlorite) and
hydrogen peroxides. May attack plastic, resins and rubber.
Hazardous Polymerization: Will not occur.
SECTION 12. DISPOSAL INFORMATION
Waste Disposal: Dispose in accordance with current local, state and federal regulations.
SECTION 13. TOXICOLOGICAL INFORMATION
236
Inhalation: Vapors or mists may cause mucous membrane and respiratory irritation, coughing, headache, dizziness,
dullness, nausea, shortness of breath and vomiting. High concentrations may cause central nervous system
depression, narcosis and unconsciousness. May cause kidney, liver and lung damage.
Skin: May cause irritation with redness, itching and pain. Methyl ethyl ketone and cyclohexanone may be absorbed
through the skin causing effects similar to those listed under inhalation.
Eye: Vapors may cause irritation. Direct contact may cause irritation with redness, stinging and tearing of the eyes.
May cause eye damage.
Ingestion: Swallowing may cause abdominal pain, nausea, vomiting and diarrhea. Aspiration during swallowing or
vomiting can cause chemical pneumonia and lung damage. May cause kidney and liver damage.
Toxicity: Chronic prolonged or repeated overexposure cause dermatitis and damage to the kidney, liver, lungs and
central nervous system.
Toxicity Data:
Acetone: Oral rat LD50: 5,800 mg/kg Inhalation rat LC50: 50,100 mg/m3/8 hours
Cyclohexanone: Oral rat LD50: 1,620 mg/kg Inhalation rat LC50: 8,000 ppm/4 hours.
Skin rabbit LD50: 1 mL/kg
Tetrahydrofuran: Oral rat LD50: 1,650 mg/kg Inhalation rat LC50: 21,000 ppm/3 hours
Methyl Ethyl Ketone: Oral rat LD50: 2,737 mg/kg Inhalation rat LC50: 23,500 mg/m3/8 hours.
Skin rabbit LD50: 6,480 mg/kg
Sensitization: None of the components are known to cause sensitization.
Carcinogenicity: None of the components are listed as a carcinogen or suspect carcinogen by NTP, IARC or OSHA.
The National Toxicology Program has reported that exposure of mice and rats to Tetrahydrofuran (THF) vapor
levels up to 1800 ppm 6 hr/day, 5 days/week for their lifetime caused an
increased incidence of kidney tumors in male rats and liver tumors in female mice. The significance of these findings
for human health are unclear at this time, and may be related to "species specific" effects. Elevated incidences of
tumors in humans have not been reported for THF.
Mutagenicity: Acetone has been positive in a mammal cell cytogenic analysis but negative in many other assays. At
most, acetone is weakly genotoxic. Cyclohexanone has been positive in bacterial and mammalian assays.
Tetrahydrofuran was positive in a bacterial assay. Methyl ethyl ketone is not considered genotoxic based on laboratory
studies.
Reproductive Toxicity: Methyl ethyl ketone and cyclohexanone have been shown to cause embryofetal toxicity and
birth defects in laboratory animals. Acetone and tetrahydrofuran have been found to cause adverse developmental
effects only when exposure levels cause other toxic effects to the mother.
Medical Conditions Aggravated By Exposure: Persons with pre-existing skin, lung, kidney or liver disorders may be at
increased risk from exposure to this product.
SECTION 14. TRANSPORTATION INFORMATION
DOT
Proper Shipping Name:
Hazard
Class/Packing
Group:
UN/NA Number:
Hazard Labels:
IMDG
Proper Shipping Name:
Hazard
Class/Packing
Group:
UN/NA Number:
Hazard Labels:
Less than 1 Liter (0.3
gal)
Greater than 1 Liter
(0.3 gal)
Consumer Commodity
Adhesives
ORM-D 3
None
None
Less than 1 Liter (0.3
gal)
PGII
UN1133
Flammable Liquid
Greater than 1 Liter
(0.3 gal)
Adhesives
3, II
UN1133
None
(Limited
Quantities
are excepted from
Adhesives
3, II
UN1133
Class 3 (Flammable
Liquid)
237
labeling)
RCRA Hazardous Waste Number: U002, U057, U159, U213
EPA Hazardous Waste ID Number: D001, D035, F005
EPA Hazard Waste Class: Ignitable Waste. Toxic Waste (Methyl Ethyl Ketone content)
SECTION 15. REGULATIONS
Hazard Category for Section 311/312: Acute Health, Chronic Health, Flammable
Section 302 Extremely Hazardous Substances (TPQ): This product does not contain chemicals regulated
under SARA Section 302.
Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III
Section 313 Reporting requirements:
Chemical
CAS
Methyl Ethyl Ketone 78-93-3
#%
45-60%
CERCLA 103 Reportable Quantity: Spills of this product over the RQ (reportable quantity) must be reported to the
National Response Center. The RQ for the product, based on the RQ for Tetrahydrofuran (40% maximum) of 1,000 lbs,
is 2,500 lbs. Many states have more stringent release reporting requirements. Report spills required under federal,
state and local regulations.
California Proposition 65: This product contains trace amounts of chemicals known to the State of California to cause
cancer. Under normal use conditions, exposures to these chemicals at levels above the State of California "No
Significant Risk Level" (NSRL) are unlikely. Oatey strongly encourages the use of proper personal protective equipment
(PPE) and ventilation guidelines noted in Section 9 to minimize exposure to these chemicals.
TSCA Inventory: All of the components of this product are listed on the TSCA inventory.
SECTION 16. MANUFACTURED BY
Diversitech
6650 Sugarloaf Parkway, Suite 100
Duluth, GA 30097
Phone 1+678.542.3600
EMERGENCY Phone No. 1 800-255-3924 Chem-Tel (Chemical Emergencies Only)
SECTION 17. REFERENCE NUMBER AND DATE OF ISSUE
MSDS Safety Data Sheet: 5-14, 5-12, 5-10, 5-32
Issued 03/30/2009
This information is, to the best of our knowledge and belief, accurate and reliable as of the date completed. However
no representation, warranty or guarantee is made as to its accuracy, reliability or completeness. It is the user’s
responsibility to satisfy himself as to the completeness and suitability of such information for his own particular use.
We do not accept liability for any loss or damage that may occur from the use of this information, nor do we offer
any warranty against patent infringement.
238
Rapid Wrench
MATERIAL SAFETY DATA SHEET
State Chemical Division – State Industrial Products
3100 Hamilton Avenue, Cleveland, OH 44114 (216)
861-7114
State Chemical Ltd.
1745 Meyerside Dr., Unit #1, Mississauga, Ontario L5T 1C6
(905) 670-4669
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name:
Product
Description:
RAPID WRENCH
24 Hour Emergency CHEMTREC Number: 800-424-9300
A formulated aerosol lubricant sealer and
MSDS Number:
M00919
anti-seize compound.
2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous
Ingredients
CAS Number
Propane
74-98-6
Butane
106-97-8
Heptane
142-82-5
Paraffinic
8042-47-5
Mineral Oil
Paraffin Oil
64742-62-7
Petroleum
64742-65-0
Distillates
Graphite
7782-42-5
Copper
7440-50-8
Weight
< 20%
< 10%
< 45%
ACGIH
2500 ppm
800 ppm
400 ppm
OSHA
1000 ppm
800 ppm
400 ppm
< 5.0%
< 10%
5 mg/m3 as mist
5 mg/m3 as mist
5 mg/m3 as mist
5 mg/m3 as mist
< 10%
< 5.0%
< 10%
5 mg/m3 as mist
2 mg/m3
1 mg/m3
5 mg/m3 as mist
2.5 mg/m3
1 mg/m3
3. HAZARDS IDENTIFICATION
***EMERGENCY OVERVIEW***
Extremely flammable. Contents under pressure. Do not puncture, incinerate or expose to temperature above
120°F(49°C). Vapor harmful. Eye, skin and respiratory irritant.
POTENTIAL HEALTH EFFECTS
Routes
ofExposure may be by inhalation and/or skin or eye contact, depending on conditions of use. To minimize
Exposure:
exposure, follow recommendations for proper use,
ventilation and personal protective equipment.
Eye Contact: May cause eye irritation. Redness and itching or burning sensation may indicate excessive exposure.
Skin Contact: May cause skin irritation. Redness and itching or burning sensation may indicate excessive exposure.
May cause irritation of the respiratory system. May cause nervous system depression. Headache,
Inhalation:
nausea, dizziness and loss of coordination are indications of
excessive exposure to vapors or spray mists. Extreme overexposure may result in unconsciousness and
possibly death.
Reports have associated repeated and prolonged overexposure to solvents with permanent brain and
General:
nervous system damage. Prolonged overexposure to solvent
ingredients may cause adverse effects to the liver, urinary and reproductive systems.
4. FIRST AID MEASURES
Eye Contact:
Promptly flush with a large amount of water for at least 15 minutes. If irritation persists, consult a
physician.
Skin Contact:
Promptly wash affected area thoroughly with soap and water. Remove contaminated clothing and
launder before reuse. If irritation persists, consult a physician.
Inhalation:
Remove to fresh air. Restore breathing if necessary. If irritation persists, consult a physician
Ingestion:
Do not induce vomiting. Never give anything by mouth to an unconscious person. Seek immediate
medical attention.
5. FIRE FIGHTING MEASURES
239
Flashpoint:
Propellant < 0°F.
Lower Explosive Limit(LEL):
1.0
Fire and Explosion Hazards:
Vapors will accumulate readily and may ignite explosively. Isolate from heat, electrical
equipment, sparks and open flame. Closed ontainers may
Upper
Limit(UEL):
Explosive
Autoignition
9.5 Temperature:
NA
explode (due to build-up of pressure) when exposed to extreme heat. Application to hot
surfaces requires special precautions. During emergency
conditions, overexposure to decomposition products may cause a health hazard.
Symptoms may not be immediately apparent. Obtain medical attention.
Extinguishing Media:
Carbon dioxide,
chemical, foam.
dry
Fire Fighting Instructions:
Full protective equipment including self-contained breathing apparatus should be used.
Water spray maybe ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent pressure build-up
and possible autoignition or explosion when exposed to extreme
heat.
6. ACCIDENTAL RELEASE MEASURES
Remove all sources of ignition. Ventilate area and remove with inert absorbent. Waste from this product may be
hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for
ignitability to determine the applicable EPA hazardous waste numbers. Dispose of in accordance with all Federal, State
and Local Regulations regarding waste disposal.
7. HANDLING AND STORAGE
Keep away from heat, flames, sparks or other sources of ignition. Consult NFPA Code. Use approved bonding
and grounding procedures. Contents under pressure. Do not puncture, incinerate or expose to temperature
above 120°F(49°C). Heat from sunlight, radiators, stoves, hot water and other heat sources could cause
container to burst. Do not take internally. Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal. Keep out of reach of children. Use only with adequate ventilation. Avoid
breathing vapor and spray mist. Avoid contact with skin and eyes. Wash hands after using.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Controls:
Local exhaust preferable. General exhaust acceptable if the exposure to materials is
maintained below applicable exposure limits.
Personal Protective Equipment:
Respiratory:
If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly
fitted NIOSH-approved organic vapor/particulate respirator.
Eye:
Wear approved safety glasses with unperforated sideshields.
240
Skin:
None required for normal application of aerosol products where minimal skin contact is expected. For
long or repeated contact, wear chemically resistant gloves.
Other:
An emergency eyewash station or source of clean potable water should be available in case of
accidental eye contact.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Copper.
Physical State:
Liquid aerosol.
Product Weight:
6.05 lb/gal; 724 g/l.
Boiling Point:
< 0 - 238°F; < -18 - 114°C
Melting Point:
NA
Evaporation Rate:
Faster than Ether.
Vapor [email protected]°F: NA
Odor:
pH:
Specific Gravity:
Volatile Volume:
Vapor Density:
Solubility in Water:
VOC Content:
Solvent.
NA
0.73
81%
Heavier than air.
NA
70.00% (less Federally Exempt Solvents).
10. STABILITY AND REACTIVITY
Stability:
Stable.
Hazardous Polymerization:
Will not occur.
Conditions to Avoid:
Heat, sparks, flames or other sources of ignition.
Incompatibility:
None expected.
Hazardous Decomposition Products: By Fire: Carbon Dioxide, Carbon Monoxide.
11. TOXICOLOGICAL INFORMATION
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Hazardous Ingredients
Propane
Butane
Heptane
Paraffinic Mineral Oil
Paraffin Oil
Petroleum Distillates
Graphite
Copper
CAS Number
74-98-6
106-97-8
142-82-5
8042-47-5
64742-62-7
64742-65-0
7782-42-5
7440-50-8
LD50
NE
NE
4 mg/l/24 hr (goldfish)
NE
NE
NE
NE
NE
LC50
NE
658 mg/l/4 hr (rat)
4924 mg/l/24-96 hr (mosquito fish)
NE
NE
NE
NE
NE
12. ECOLOGICAL INFORMATION
NA
13. DISPOSAL CONSIDERATIONS
Do not incinerate. Depressurize container. Dispose of in accordance with all Federal, State and Local Regulations
regarding pollution and waste disposal. Product as supplied is a DOO1 unspecified ignitable waste.
14. TRANSPORT INFORMATION
DOT Shipping
Consumer Commodity, ORM-D.
Data:
Canadian
TDG:
Shipped in accordance with 49 CFR as part of a transborder shipment authorized under Section 5.2
(1) of the Canadian Transportation of Dangerous Goods.
241
For International Shipments
Aerosols, Flammable, 2.1, UN1950.
by Air:
For International Shipments
Aerosols, Flammable, 2.1, UN1950, Limited Quantity
by Vessel:
15. REGULATORY INFORMATION
TSCA:
All ingredients in this product are listed or exempt from listing on the TSCA Chemical Inventory.
CEPA:
All ingredients in this product are listed or exempt from listing on the Canadian DSL/NDSL.
Proposition
65:
This product may contain trace amounts of the following chemicals that are known to the state of
California to cause cancer, birth defects or other reproductive harm:
SARA 313:
Benzene
71-43-2
0.009%
Toluene
108-88-3
0.435%
This product contains the following toxic chemicals that are subject to the reporting requirements of
Section 313 of the Emergency Planning and Community RightTo-Know Act of 1986 (40 CFR
372.65C):
Copper
Compound
7440-50-8
8%
Flammability =
Reactivity = 0 Personal Protection = B
4
HMIS
Classification: Health = 2
WHMIS Classification:
Class A; Class B, Division 5; Class D, Division 2B
16. OTHER INFORMATION
NA = Not Available or Not Applicable.
NE = Not Established
Read and follow all label directions and precautions before using the product. These products are intended for
industrial and institutional use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF THE REACH OF CHILDREN.
While we believe that the data contained herein is factual and the opinions expressed are those of qualified experts,
the data are not to be taken as a warranty or representation for which the company assumes legal responsibility.
They are offered solely for your consideration, investigation, and verification. Any use of these data and information
must be determined by the user to be in accordance with applicable Federal, State, and Local Laws and regulations.
HEALTH AND SAFETY INFORMATION:
(216) 861-7114
Prepared On: October 2008
Replaces: October 2005
Completed By: Regulatory Affairs Specialist.
242
Rough Touch Scrubs-In-A-Bucket
Material Safety Data Sheet
May be used to comply with
OSHA's
HEALTH
Hazard
Communication
Standard,
29 CFR 1910.1200. Standard
FLAMMABILITY
must be
consulted
for
specific
requirements.
Identity (As Used on Label and
List)
42201,42210,42230,42
236,42272
Rough Touch® Scrubs in - a - Bucket®
SECTION I
Manufacturer's Name
ITW Dymon
Address (Number, Street, City, State, and ZIP Code)
805 East Old 56 Highway
Olathe, Kansas 66061
SECTION II - Hazardous Ingredients/Identity
Information
Hazardous
Components
(Specific
Chemical Identity, Common
CAS No.
Name(s))
HMIS
1
REACTIVITY
0
1
PERSONAL PROTECTION
None
Note: Blank spaces are not permitted. If any item is
not applicable, or no
information is available, the space must be marked to
indicate that.
Emergency Telephone Number
1-800-535-5053
Telephone Number for Information
1-913-397-9889
Date Prepared
August 16, 2007
Signature of Preparer (Optional)
Regulatory Dept.
Other Limits
OSHA PEL
ACGIHTLV
Recommended
% (Opt.)
This product is not known to contain any compound in concentrations requiring reporting under SARA Title III Section
313.
TSCA: All ingredients are on the TSCA inventory or are not required to be listed on the TSCA inventory.
Any substance listed as hazardous by the States of California, Florida, Illinois, Michigan, New Jersey, Ohio, Pennsylvania
or
Texas is described above if known present in regulated concentrations.
SECTION III Physical/Chemical Characteristics
Boiling Point
Specific Gravity (H2O = 1)
o
>200 F
o
0.982
Initial
F
@70
o
Vapor Pressure (mm-Hg @ 70 F)
Vapor Density (AIR = 1)
Melting Point
No Data
Greater than
No Data
Evaporation Rate (Butyl Acetate = 1)
243
one (1)
Solubility in Water
No Data
pH
Dispersible
7.4 + 0.5
Appearance and Odor Opaque white liquid with a fresh citrus scent saturated
onto towels.
SECTION IV - Fire and Explosion Hazard Data
Flash Point (Method Used)
Flammable Limits
LEL
UEL
None to boiling (TCC) Solution on
No Data
No Data
No Data
Towel
Extinguishing Media Use carbon dioxide, dry chemical, foam, fog or water spray.
Special Fire Fighting Procedures Keep containers cool and vapors down with water spray. Prevent runoff from entering sewers and public
waterways. Wear SCBA in chemical fires.
Unusual Fire and Explosion Hazards None known.
42230,42236,
42201,42210,
SECTION V - Reactivity Data
Stability
42272
August 16, 2007
Conditions to
Avoid - None
known
Unstable
Stable
X
Incompatibility
(Materials to Avoid) Strong oxidizers and acids.
Hazardous Decomposition or Byproducts Carbon dioxide, carbon monoxide, hydrogen sulfide, sulfur dioxide, smoke and
soot.
Conditions to
Avoid - None
Hazardous
May Occur
known
Will Not
Polymerization
X
Occur
SECTION VI - Health Hazard Data
Route(s) of Entry
Eyes?
Inhalation?
Skin?
Ingestion?
Yes
No
No
Yes
Health Hazards (Acute and Chronic) Caution. Towel may cause eye irritation.
Carcinogenicity:
NTP?
IARC Monographs?
OSHA Regulated?
None known
No
No
No
Signs and Symptoms of Exposure Redness, tearing or burning in eyes. Irritation of the throat or stomach, nausea, vomiting, and diarrhea if swallowed.
Medical Conditions Generally Aggravated by Exposure Pre-existing skin conditions such as dermatitis may be
adversely affected by this and other oil and grease effective cleaners.
Emergency and First Aid Procedures:
Eyes - Flush with plenty of water for at least 15 minutes lifting eyelids to insure complete removal. See a physician
immediately.
244
Ingestion - Not a likely exposure route. If a large quantity of liquid is swallowed, do not induce vomiting, call a
physician or poison control center immediately.
Inhalation - Unlikely route as liquid is impregnated on a towel, minimizing exposure via this route.
Skin - None usually required. Material is designed for skin cleansing.
SECTION VII - Precautions for Safe Handling and Use
Steps to be Taken in Case Material is Released or Spilled - Caution, slip hazard. Wipe up small releases with a dry
absorbent cloth. For large releases, prevent material from entering sewers or drains. Ventilate area and block traffic.
Pick up and put in suitable container for proper disposal.
Waste Disposal Method - Consult local, state, and federal regulations. Discard empty container or offer for recycling or
reuse.
Precautions to be Taken in Handling and Storing - Do not allow towel contact with eyes. For external use only.
Not for use around the mouth or eyes for an extended period of time. Do not smoke while using. Do not
contaminate water, food or feed by use or storage.
Other Precautions - Follow label directions carefully. Keep away from heat sources. Keep out of reach of
children. Keep container tightly sealed when not in use.
SECTION VIII - Control Measures
Respiratory Protection (Specify Type)
Not usually necessary. Use with adequate ventilation. Use NIOSH/MSHA approved respirator if PELs or TLVs are
exceeded.
Ventilation
Local Exhaust
Not usually needed Special
None
Mechanical (General)
Acceptable
None
Other
Protective Gloves -
Eye Protection -
Not necessary
Not necessary
Other Protective Clothing or Equipment Not usually necessary.
Work/Hygienic Practices Normal. Use to wash hands before eating, drinking, smoking, using restrooms, etc.
WARNING! The use of this product is beyond the control of the manufacturer;
therefore, no guarantee, expressed or implied, is made as to the effects of such or the
results to be obtained if not used in accordance with directions or established safe
practice. The user must assume all responsibility, including injury or damage, resulting
from its misuse as such, or in combination with other materials.
The manufacturer warrants only that this product meets the manufacturer's specifications for such
product. THIS WARRANTY IS IN LIEU OF ALL OTHER WARRANTIES, EXPRESS OR IMPLIED, AS TO
DESCRIPTION
,
QUALITY,
MERCHANTABILITY.
FITNESS
FOR
ANY
PARTICULAR
PURPOSE,
PRODUCTIVENESS, OR ANY OTHER MATTER, OF THIS PRODUCT. THE MANUFACTURER SHALL BE IN NO
WAY RESPONSIBLE FOR THE IMPROPER USE OF THIS PRODUCT. The sole and exclusive remedy against
the manufacturer for breach of warranty shall be reimbursement of the purchase price of the product in
the event that a defective condition of the product shall be found to exist. NO OTHER REMEDY
(INCLUDING BUT NOT LIMITED TO INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR INJURY TO PERSON
OR PROPERTY OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE.
245
Silicone Sealant
DOW CORNING CORPORATION
Material Safety Data Sheet
DOW CORNING(R) GENERAL PURPOSE SILICONE SEALANT CLEAR
1. PRODUCT AND COMPANY IDENTIFICATION
Dow Corning Corporation
South Saginaw Road
Midland, Michigan 48686
24 Hour Emergency Telephone: (989) 496-5900
Customer Service: (989) 496-6000
Product Disposal Information: (989) 496-6315
CHEMTREC: (800) 424-9300
Revision
2011/01/24
MSDS No.: 04036588
Generic Description:
Physical Form:
Color:
Odor:
Date:
Silicone elastomer
Paste
Colorless
Acetic acid odor
NFPA Profile: Health 1 Flammability 1 Instability/Reactivity
0
Note: NFPA = National Fire Protection Association
2. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
Acute Effects
Eye:
Direct contact may cause mild irritation.
Skin:
May cause mild irritation.
Inhalation:
Irritates respiratory passages very slightly.
cause drowsiness, dizziness, confusion or loss of coordination.
Oral:
Overexposure by inhalation may
Low ingestion hazard in normal use.
Prolonged/Repeated Exposure Effects
Repeated or prolonged contact may cause defatting and drying of skin which may result in skin irritation and
dermatitis.
Inhalation:
No known applicable information.
Oral:
No known applicable information.
246
Signs and Symptoms of Overexposure
No known applicable information.
Medical Conditions Aggravated by Exposure
No known applicable information.
The above listed potential effects of overexposure are based on actual data, results of studies performed upon
similar compositions, component data and/or expert review of the product. Please refer to Section 11 for the
detailed toxicology information.
3. COMPOSITION/INFORMATION ON INGREDIENTS
CAS Number
Wt %
Component Name
64742-47-8
10.0 - 30.0
Hydrotreated light petroleum distillate
17689-77-9
1.0 - 5.0
Ethyltriacetoxysilane
4253-34-3
1.0 - 5.0
Methyltriacetoxysilane
The above components are hazardous as defined in 29 CFR 1910.1200.
4. FIRST AID MEASURES
Eye:
Skin:
Inhalation:
Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 5
minutes
while holding the eyelid(s) open. Obtain medical attention.
Remove contaminated clothing, shoes and leather goods (e.g. watchbands, belts).
Quickly
and gently blot or brush away excess chemical. Flush with lukewarm gently flowing
water for
15 minutes. If irritation persists, repeat flushing. If irritation persists, obtain medical
advice.
Remove from the source of contamination or move to fresh air. If irritation persists,
obtain
medical advice.
Oral:
If irritation or discomfort occur, obtain medical advice.
Notes to Physician:
Treat according to person's condition and specifics of exposure.
5. FIRE FIGHTING MEASURES
Flash Point:
Not applicable.
Autoignition Temperature:
Not determined.
Flammability Limits in Air: Not determined.
Extinguishing Media:
On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide
247
(CO2), dry chemical or water spray. Water can be used to cool fire exposed containers.
DOW CORNING(R) GENERAL PURPOSE SILICONE SEALANT CLEAR
Fire Fighting Measures:
Unusual Fire Hazards:
Self-contained breathing apparatus and protective clothing should be worn in fighting
large
fires involving chemicals. Determine the need to evacuate or isolate the area according
to
your local emergency plan. Use water spray to keep fire exposed containers cool.
None.
6. ACCIDENTAL RELEASE MEASURES
Observe all personal protection equipment recommendations described in Sections 5
Containment/Clean up:
and 8.
Wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate
since
spilled materials, even in small quantities, may present a slip hazard. Final cleaning
may require use of steam, solvents or detergents. Dispose of saturated absorbant or
cleaning materials appropriately, since spontaneous heating may occur. Local, state
and federal laws and regulations may apply to releases and disposal of this material,
as well as those materials and items employed in the cleanup of releases. You will
need to determine which federal, state and local laws and regulations are applicable.
Sections 13 and 15 of this MSDS provide information regarding certain federal and
state requirements.
Note: See Section 8 for Personal Protective Equipment for Spills. Call (989) 496-5900, if additional information
is required.
7. HANDLING AND STORAGE
Use with adequate ventilation. Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide
ventilation during use to control HOAc within exposure guidelines or use respiratory protection. Avoid eye contact.
Avoid skin contact. Avoid breathing vapor, mist, dust, or fumes. Keep container closed.
Use reasonable care and store away from oxidizing materials. Keep container closed and store away from water or
moisture. This material in its finely divided form presents an explosion hazard. Follow NFPA 654 (for chemical dusts)
or 484 (for metal dusts) as appropriate for managing dust hazards to minimize secondary explosion potential.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Component Exposure Limits
CAS Number
Component Name
Exposure Limits
248
64742-47-8
Hydrotreated light petroleum distillate
Observe petroleum distillates limits. OSHA PEL
(final rule):
TWA 400 ppm.
17689-77-9
Ethyltriacetoxysilane
See acetic acid comments.
4253-34-3
Methyltriacetoxysilane
See acetic acid comments.
Acetic acid is formed upon contact with water or humid air. Provide adequate ventilation to control exposures
within guidelines of OSHA PEL: TWA 10 ppm and ACGIH TLV: TWA 10 ppm, STEL 15 ppm.
Engineering Controls
Local Ventilation:
General Ventilation:
Recommended.
Recommended.
Personal Protective Equipment for Routine Handling
Eyes:
Skin:
Suitable Gloves:
Inhalation:
Suitable Respirator:
Use proper protection - safety glasses as a minimum.
Wash at mealtime and end of shift. Contaminated clothing and shoes should be
removed as
soon as practical and thoroughly cleaned before reuse. Chemical protective gloves
are
recommended.
Avoid skin contact by implementing good industrial hygiene practices and
procedures. Select
and use gloves and/or protective clothing to further minimize the potential for skin
contact.
Consult with your glove and/or personnel protective equipment manufacturer for
selection of
appropriate compatible materials.
Use respiratory protection unless adequate local exhaust ventilation is provided or
exposure
assessment demonstrates that exposures are within recommended exposure
guidelines. IH
personnel can assist in judging the adequacy of existing engineering controls.
General and local exhaust ventilation is recommended to maintain vapor
exposures below
recommended limits. Where concentrations are above recommended limits or are
unknown,
appropriate respiratory protection should be worn. Follow OSHA respirator
regulations (29
CFR 1910.134) and use NIOSH/MSHA approved respirators.
Personal Protective Equipment for Spills
Eyes:
Skin:
Use full face respirator.
Wash at mealtime and end of shift. Contaminated clothing and shoes should be
removed as
soon as practical and thoroughly cleaned before reuse. Chemical protective gloves
249
are
recommended.
Respiratory protection recommended. Follow OSHA Respirator Regulations (29
CFR
1910.134) and use NIOSH/MHSA approved respirators. Protection provided by air
purifying
respirators against exposure to any hazardous chemical is limited. Use a positive
pressure air
supplied respirator if there is any potential for uncontrolled release, exposure
levels are
unknown, or any other circumstance where air purifying respirators may not
provide adequate
protection.
Avoid eye contact. Avoid skin contact. Avoid breathing vapor, mist, dust, or fumes.
Keep
container closed. Use reasonable care.
Inhalation/Suitable
Respirator:
Precautionary Measures:
Comments:
ventilation
Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide
during use to control HOAc within exposure guidelines or use respiratory protection.
Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray
applications may require added precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical Form: Paste Color: Colorless
Odor: Acetic acid odor Specific Gravity @ 25°C: 0.99
Viscosity: Not determined. Freezing/Melting Point: Not determined.
Boiling Point: Not determined. Vapor Pressure @ 25°C: Not determined.
Vapor Density: Not determined. Solubility in Water: Not determined. pH: Not
determined.
Volatile Content: Not determined. Flash Point: Not applicable.
Autoignition Temperature: Not determined. Flammability Limits in Air: Not
determined.
Note: The above information is not intended for use in preparing product specifications. Contact Dow Corning
before writing specifications.
10. STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Hazardous
Polymerization:
Conditions to Avoid:
Hazardous polymerization will not occur.
None.
250
Materials to Avoid:
hazardous
Oxidizing material can cause a reaction. Water, moisture, or humid air can cause
vapors to form as described in Section 8.
Hazardous Decomposition Products
Thermal breakdown of this product during fire or very high heat conditions may evolve the following
decomposition products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide.
Formaldehyde.
11. TOXICOLOGICAL INFORMATION
Special Hazard Information on Components
No known applicable information.
12. ECOLOGICAL INFORMATION
Environmental Fate and Distribution
Complete information is not yet available.
Environmental Effects
Complete information is not yet available.
Fate and Effects in Waste Water Treatment Plants
Complete information is not yet available.
Ecotoxicity Classification Criteria
Hazard Parameters (LC50 or EC50)
High
Medium
Low
Acute Aquatic Toxicity (mg/L)
<=1
>1 and <=100
>100
Acute Terrestrial Toxicity
<=100
>100 and <= 2000
>2000
This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993.
This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the
other information presented in the section concerning the overall ecological safety of this material.
13. DISPOSAL CONSIDERATIONS
RCRA Hazard Class (40 CFR 261)
When a decision is made to discard this material, as received, is it classified as a hazardous waste? NOT ASSESSED
State or local laws may impose additional regulatory requirements regarding disposal. Call (989) 496-6315, if
additional information is required.
251
14. TRANSPORT INFORMATION
DOT Road Shipment Information (49 CFR 172.101)
Not subject to DOT.
Ocean Shipment (IMDG)
Not subject to IMDG code.
Air Shipment (IATA)
Not subject to IATA regulations.
Call Dow Corning Transportation, (989) 496-8577, if additional information is required.
15. REGULATORY INFORMATION
Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
TSCA Status:
All chemical substances in this material are included on or exempted from listing on the TSCA
Inventory of Chemical Substances.
EPA SARA Title III Chemical Listings
Section 302 Extremely Hazardous Substances (40 CFR 355):
None.
Section 304 CERCLA Hazardous Substances (40 CFR 302):
None.
Section 311/312 Hazard Class (40 CFR 370):
Acute: Yes
Chronic: No
Fire: No
Pressure: No
Reactive: No
Section 313 Toxic Chemicals (40 CFR 372):
None present or none present in regulated quantities.
Note: Chemicals are listed under the 313 Toxic Chemicals section only if they meet or exceed a reporting threshold.
Supplemental State Compliance Information
California
Warning: This product contains the following chemical(s) listed by the State of California under the Safe Drinking
Water and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other
reproductive harm.
None known.
252
Massachusetts
No ingredient regulated by MA Right-to-Know Law present.
New Jersey
CAS Number
Wt %
Component Name
70131-67-8
70.0 - 90.0
Dimethyl siloxane, hydroxy-terminated
64742-47-8
10.0 - 30.0
Hydrotreated light petroleum distillate
112945-52-5
5.0 - 10.0
Amorphous fumed silica
17689-77-9
1.0 - 5.0
Ethyltriacetoxysilane
4253-34-3
1.0 - 5.0
Methyltriacetoxysilane
Pennsylvania
CAS Number
Wt %
Component Name
70131-67-8
70.0 - 90.0
Dimethyl siloxane, hydroxy-terminated
64742-47-8
10.0 - 30.0
Hydrotreated light petroleum distillate
112945-52-5
5.0 - 10.0
Amorphous fumed silica
16. OTHER INFORMATION
Prepared by: Dow Corning Corporation
These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed
or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be
generally applicable. However, each user should review these recommendations in the specific context of the
intended use and determine whether they are appropriate.
(R) indicates Registered Trademark
253
Spitfire RTU
MATERIAL SAFETY DATA SHEET
HMIS
NFPA
Health
1
1
Fire Hazard
0
0
Reactivity
Version
Number:
0
0
Spitfire RTU Power Cleaner
Personal protective equipment
None / Aucune / Ninguno
Preparation
2011-03-16
2
date:
1. PRODUCT AND COMPANY IDENTIFICATION
Product
name:
Spitfire RTU Power Cleaner
MSDS #:
MS0300470
Product
03702, 03724
Code:
Recommended use:
Heavy-Duty Alkaline Cleaner. This product is intended to be used neat .
Manufacturer,
importer,
supplier:
US
Canadian Headquarters
Headquarters
Diversey, Inc.
Diversey, Inc. - Canada, Inc.
8310 16th St.
2401 Bristol Circle
Sturtevant, Wisconsin 53177Oakville, Ontario L6H 6P1
1964
Phone: 1-888-352-2249
Phone: 1-800-668-3131
MSDS
Internet
Address:
www.diversey.com
Emergency
telephone
1-800-851-7145 (U.S.); 1-651-917-6133 (Int'l)
number:
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
CAUTION. MAY BE MILDLY IRRITATING TO EYES. MAY BE MILDLY IRRITATING TO SKIN.
Principal routes of exposure:
Eye contact:
Skin contact:
Eye contact. Skin contact.
Inhalation.
May be mildly irritating to
eyes.
May be mildly irritating to
skin.
254
Inhalation:
Ingestion:
None
None known.
3. COMPOSITION/INFORMATION ON INGREDIENTS
0.1 - 1.5%
LD50 Oral Rat
(mg/kg)
1230
LD50 Dermal Rabbit
=2000 mg/kg
111-76-2
0.1 - 1.5%
470
=220 mg/kg
141-43-5
0.1 - 1.5%
1720
=1 mL/kg =1025
mg/kg
Ingredient(s)
CAS #
Weight %
Benzyl alcohol
100-51-6
2-butoxyethanol
Monoethanolamine
Eye contact:
Skin contact:
Inhalation:
Ingestion:
Aggravated
Conditions:
Medical
Suitable
extinguishing
media:
Specific hazards:
Unusual hazards:
Specific methods:
LC50
Inhalation Rat
=8.8 mg/L (4 h)
=2.21 mg/L (4
h)
=450 ppm (4 h)
Not available
4. FIRST AID MEASURES
Flush immediately with plenty of water. If irritation develops, get
medical attention.
Flush immediately with plenty of water. If irritation develops, get
medical attention.
No specific first aid measures are required.
No specific first aid measures are required.
None
known
5. FIRE-FIGHTING MEASURES
The product is not flammable. Extinguish fire using agent suitable for
surrounding fire.
Not applicable
None known
No special methods required
Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus
pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear
Extinguishing media which must not be used for safety reasons: No information available
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Environmental precautions and clean-up methods:
255
Not relevant for the product itself.
Clean-up methods - large spillage. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste
container. Use a water rinse for final clean-up.
7. HANDLING AND STORAGE
Handling:
Avoid contact with skin and eyes. FOR COMMERCIAL AND INDUSTRIAL USE ONLY.
Storage:
Protect from freezing. Keep tightly closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures to reduce exposure:
No special ventilation requirements General room ventilation is adequate
Personal Protective Equipment
Eye protection:
Hand protection:
Skin and body protection:
Respiratory protection:
Hygiene measures:
No special requirements under normal use conditions.
No special requirements under normal use conditions
No special requirements under normal use conditions.
No special requirements under normal use conditions.
Handle in accordance with good industrial hygiene and
safety practice.
Ingredient(s)
CAS #
2-butoxyethanol
111-76-2
ACGIH
20 ppm
(TWA)
OSHA
Skin 50 ppm (TWA)
240
3
mg/m (TWA)
Monoethanolamine
Physical State: Liquid
Appearance: Aqueous solution
141-43-5
6 ppm (STEL) 3 ppm
(TWA)
3 ppm (TWA)
6
3
mg/m
(TWA)
Mexico
75 ppm (STEL)
360
3
mg/m
(STEL) 26 ppm (TWA)
120
3
mg/m (TWA)
6 ppm (STEL)
15
3
mg/m
(STEL) 3 ppm (TWA) 8
3
mg/m (TWA)
9. PHYSICAL AND CHEMICAL PROPERTIES
Bulk density: No information
available
Evaporation Rate No information
available
Color: Clear
Red
Specific gravity: 1.01
Vapor density: No information
available
Boiling
point/range:
Not
determined
Decomposition temperature: Not determined
Solubility: Completely Soluble
Solubility in other solvents: No information
available
Partition coefficient (n-octanol/water):
information available
Odor: Fresh Pine
Melting
point/range:
Not
determined
Autoignition temperature: No information available
Density: 8.42 lbs/gal 1.01 Kg/L
No
Flash point: > 200 °F > 93.4 °C
Viscosity:No
information
available
256
Elemental Phosphorus: 0.00 % by
wt.
pH: 11.3
VOC: 2 % *
Dilution pH: 11.3 @ RTU
Explosion limits: - upper: Not determined - lower: Not determined
3.
- Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products,
Sections 94508
STABILITY AND REACTIVITY
Stability:
Polymerization:
Hazardous
decomposition
products:
Materials to avoid:
The product is stable
Hazardous polymerization does not occur
None reasonably foreseeable.
Acids. Strong oxidising agents.
Acute toxicity:
Component Information:
11. TOXICOLOGICAL INFORMATION
Oral LD50 estimated to be greater than 5000 mg/kg. Dermal LD50 estimated to
be > 2000 mg/kg.
See Section 3
Chronic toxicity:
None known
Specific effects
Carcinogenic effects:
Mutagenic effects:
Reproductive toxicity:
Target organ effects:
None known
None known
None known
None known
12. ECOLOGICAL INFORMATION
Environmental Information:
No data available
13. DISPOSAL CONSIDERATIONS
Waste from residues / unused products:
Dispose of according to all federal, state and local applicable regulations
14. TRANSPORT INFORMATION
DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information
15. REGULATORY INFORMATION
International Inventories at CAS# Level
All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL).
U.S. Regulations
California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65
RIGHT TO KNOW (RTK)
257
Ingredien
t(s)
Benzyl alcohol
2-butoxyethanol
Sodium xylene sulfonate
Monoethanolamine
Water
CAS #
100-51-6
111-76-2
1300-72-7
141-43-5
7732-18-5
MARTK:
X
X
X
-
CERCLA/ SARA
Ingredient(s)
111-76-2
Ingredient(s)
2butoxyethanol
SARA 311/312
Categories
Immediate:
Delayed:
Fire:
Reactivity:
Weight CERCLA/SARA
%
(lbs)
0.1
1.5%
CAS #
2-butoxyethanol
NJRTK:
X
X
-
CAA HAP
PARTK:
X
X
X
-
RIRTK:
X
X
-
RQ Section 302 TPQ
(lbs)
Section 313
CAA
ODS
X
CWA
Pollutants
Priority
X
Hazard
-
Sudden Release of Pressure:
Canada
WHMIS hazard class: Non-controlled
16. OTHER INFORMATION
Reason for revision:
Prepared by:
Additional advice:
Not applicable
NAPRAC
Contains an added fragrance, see "Odor" heading in section 9 for specific
description.
Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not
constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use
and handling are beyond seller's control. User is responsible to evaluate all available information when using product for
any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.
258
Super Carb & Choke Cleaner
1301 E. 9th Street, #700 Cleveland OH 44114 (800) 726-9626
Barnes Distribution
Material Safety Data Sheet
MSDS Form No. : KP1099
Item No. : KP1099, KP1099S, 1099
**** MATERIAL SAFETY DATA SHEET ****
CARB & CHOKE CLEANER
Part # KP1099
**** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ****
MSDS Name: CARB & CHOKE CLEANER Product CAS:
(none)
Product Code:
Synonyms: 1099; 1099-55; CARB & CHOKE CLEANER; KP1099; KP1099-55; KP1099S Company Identification:
Name: KAR PRODUCTS Address: 461 N.
THIRD AVE. Address:
City: DES PLAINES State: IL Zip: 60016 For information, call:
847-296-6111 Emergency Number: 800-752-7869 Emergency
Agency:
Number:
MSDS Creation Date: 7/1/2003 Supersedes
Date: Miscellaneous:
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
Chemical Name
CAS
MIN
METHANOL
67-56-1
10
ACETONE
67-64-1
20
METHYL ETHYL KETONE
78-93-3
5
XYLENE
1330-20-7
25
ETHYLENE GLYCOL MONO BUTYL ETHER
111-76-2
1
MAX
20
40
15
40
5
Miscellaneous:
ITEM
OSHA PEL
ACGHI TLV
1
2
3
4
NA
1000 PPM
200 PPM
100 PPM
200
750
200
100
5
50 PPM
25 PPM
PPM
PPM
PPM
PPM
OTHER LIMITS
NA
NA
NA
NA
NA
259
Lbs of VOC per Gallon Coating (minus water): 0
Coating Density (lbs/gal): 0
Solvent Density (lbs/gal): 0
Percent Solvent (volume): 0
Percent Solids (volume): 0
Percent Water (volume): 0
**** SECTION 3 - HAZARDS IDENTIFICATION ****
NFPA: Health: 2 Fire: 4 Reactivity: 0 Other:
HMIS: Health: 1 Fire: 2 Reactivity: 0 Special Protection:
POTENTIAL HEALTH EFFECTS
Target Organs:
Eye:
MAY CAUSE REDNESS AND BURNING.
Skin:
WILL CAUSE DEFATTING OF THE SKIN.
Ingestion:
A PRIMARY ROUTE OF ENTRY. HEALTH HAZARDS (ACUTE AND CHRONIC): GENERATED MISTS MAY
BE SEVERELY IRRITATING AND CAUSE DAMANGE TO RESPOIRATORY TRACT IF SWALLOWED.HARMFUL OR FATAL IF
SWALLOWED.
Inhalation:
Miscellaneous:
LONG TER EXPOSURE YEARS TO VAPOR MAY CAUSE LUNG, LIVER, OR KIDNEY DAMAGE. THE
SOLVENTS LISTED HAVE BEEN REPORTED TO AFFECT THE CENTRAL NERVOUSE SYSTEM: XYLENE, METHANOL, METHYL
ETHYL KETONE, ACETONE.
**** SECTION 4 - FIRST AID MEASURES ****
Eye:
WASH EYES WITH WATER FOR LEAST 15 MIN AND CALL A PHYSICIAN IMMEDIATELY.
Skin:
WASH SKIN WITH LARGE AMOUNTS OF SOAP AND WATER. IF IRRITATION PERSISTS CALL
PHYSICIAN.
Ingestion:
DO NOT INDUCE VOMITING. CALL PHYSICIAN IMMEDIATELY.
Inhalation:
REMOVE TO FRESH AIR. START ARTIFICAL RESPIRATION IF NECESSARY. OXYGEN MAY BE
ADMINISTERED. CALL A PHYSICIAN.
Notes to Physician:
260
Miscellaneous:
IF YOU HAVE A MEDICAL CONDITION CONSULT WITH A PHYSICIAN PRIOR TO USING THIS
PRODUCT.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
Unusual Fire and Explosion Hazards:
HEATED CANS MAY BURST.
Special Fire Fighting Procedures:
FIREFIGHTERS SHOULD WEAR NIOSH APPROVED POSITIVE PRESSURE SELF-CONTAINED BREATING
APPARATUS. CANS MAY RUPTURE WHEN HEATED.
Extinguishing Media:
USE WATER FOG, DRY CHEMICAL OR CARBON DIOXIDE.
Flash Point:
NA
Flammable Limits:
Lower Limit:
NA
Upper Limit:
NA
AutoIgnition Temperature:
NA
General Information:
FLAMMABLE LIMITS:
NOT DETERMINED
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
Disposal:
DISPOSE AS HAZARDOUS WASTE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REQUIREMENTS.
Spills/Leaks:
SAFELY STOP SPILL AT SOURCE.
CONTAIN SPILL BY DIKING WITH SOIL OR OTHER INERT
MATERIAL AND
CAREFULLY NEUTRALIZE WITH DILUTE ACID. MOP, PUMP OR ABSORB WITH INERT MATERIAL AND
RECLAIM INTO SOUND CONTAINERS FOR PROPER DISPOSAL.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME.
Storage:
STORE AT TEMPERATURES BELOW 120 F.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
261
Engineering Controls:
LOCAL EXHAUST:
YES
MECHANICAL (GENERAL):
NONE
SPECIAL VENTILATION:
NONE
OTHER VENTILATION:
NONE
Eyes:
WEAR EYE PROTECTION. WEAR GLASSES OR GOGGLES.
Skin:
PROTECTIVE GLOVES:
NONE REQUIRED IF SPRAYING.
Clothing:
LONG SLEEVE AND LONG PANTS.
Respirators:
SELF CONTAINED BREATHING APPARATUS IF ABOVE TLV LIMIT EXCEEDING.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Appearance/Odor:
CLEAR LIQUID WITH CHARACTERISTIC SOLVENT ODOR.
pH: NA
Vapor Pressure: MM HG: 140MM HG AT 70 DEG F Vapor
Density: HEAVIER
Evaporation
Rate:
FASTER
Viscosity:
Boiling Point: 133.0 DEG F
Freezing/Melting Point: NA
Decomposition Temperature: Solubility: IN
WATER: NEGLIGIBLE Specific Gravity: .85
Molecular
Formula:
N/A
Molecular
Weight:
Miscellaneous:
% VOLATILE/VOLUME:
NO DATA
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
STABLE:
YES
Conditions to Avoid:
HEAT, SPARKS AND OPEN FLAMES.
Incompatibilities with Other Materials:
STRONG ACIDS OR BASES, OXIDIZING AGENTS.
Hazardous Decomposition Products:
IN FIRE, WATER, CARBON DIOXIDE, CARBON MONOXIDE, PRODUCTS OF INCOMPLETE COMBUSTION.
Hazardous Polymerization:
MAY OCCUR:
NO
262
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
Toxicological Information:
NEW JERSEY RIGHT-TO-KNOW: METHANOL, METHYL ETHYL KETONE, 2-BUTOXYETHANOL, ACETONE,
XYLENE.
WARNING: THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPPRODUCTIVE HARM.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecological Information:
**** SECTION 13 - OTHER PRECAUTIONS ****
Other Precautions:
WHEN SPRAYING MORE THAN ONE HALF CAN CONTINUOUSLY OR MORE THAN ONE CAN
CONSECUTIVELY, USE NIOSH APPROVED RESPIRATOR.
Work/Hygienic Practices:
DO NOT SMOKE WHILE USING.
WASH HANDS AFTER USE.
**** SECTION 14 - TRANSPORT INFORMATION ****
Transportation Information:
Label Information:
**** SECTION 15 - REGULATORY INFORMATION ****
Regulatory Information:
**** SECTION 16 - ADDITIONAL INFORMATION ****
Additional Information:
263
Super Electra-Saf
MATERIAL SAFETY DATA SHEET: SUPER ELECTRA SAF AEROS
Section I - General Information
(000000-000000- - 5491)
Date of Issue:
10/19/2004 12:00:00 AM
Supercedes:
4/16/2001 12:00:00 AM
Trade
Name
&
Synonyms:
SUPER ELECTRA SAF
AERO
Chemical Name & Synonyms:
N/A
Chemical Family:
Formula is a mixture: [√]
PETROLEUM/LIMONENE BLEND
Manufacturer Name:
MANTEK, DIVISION OF NCH CORP.
Manufacturer Address:
BOX 152170
IRVING, TEXAS 75015
Prepared By:
M McDowell/Chemist
Product Code Number:
5491
Emergency
Number:
800-424-9300
Phone
Section II - Hazardous Ingredients
THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS
Chemical Name (Ingredients)
Hazard
TLV
LIGHT ALKYLATE PETROLEUM NAPHTHA
FLAM/IRR
100 PPM $1
D-LIMONENE
IRR/COMB
FLAM/ASPH
Y
FLAM/ASPH
Y
N/E 1
1000
PPM#1
1000
PPM#1
PROPANE
N-BUTANE
$ STODDARD SOLVENT
# ALIPHATIC HYDROCARBON GASES
PEL
500
$2
PPM
N/E 2
1000PPM
2
N/E 2
STE
L
N/
E
N/
E
N/
E
N/
E
Section III - Physical Data
Boiling Point (°F):
340°
Vapor Pressure (mm
1964
Hg):
Specific Gravity (H20=1):
Color:
0.77
COLOR
L
Vapor Density (Air=1):
Odor:
ORANG
1.7
264
E
TRANS
P
pH @ 100% :
N/E
Clarity:
% Volatile by Volume:
100
Evaporation Rate (BuAc=1):
H20 Solubility:
NEGLIGIBLE
Viscosity:
37.8
NONVIS
Section IV - Fire and Explosion Hazard
Flash Point: 39°F
Flammable Limits: PRODUCT MIXTURE
LEL: 0.7
Method
Used:
SETAFLASH
UEL: 9.5
Aerosol Level (NFPA 30B):
3
NFPA 704 Hazard
Rating:
Extinguishing Media:
[ ] Alcohol
[√] Foam
Foam
[√] CO2
[√]
Dry
Chemical
4Extreme
[ ] Other
3-High Flammability: 4
2Modera
Instability:
te
0
Spe
cial:
[√]
Water
Spray
1-Slight
0-Insignificant
Health: 2
HIPS TO PREVENT PULMONARY ASPIRATION. IF COMATOSE, A CUFFED ENDOTRACHAEL TUBE WILL PREVE
ASPIRATION.
Section VI - Toxicity Information
Product Contains Chemicals Listed as Carcinogen or Potential Carcinogen By:
[ ] IARC
[ ] NTP
[ ] OSHA
[ ] ACGIH
[
]
Other
VOC CONTENT: 100% BY WEIGHT, 100% BY VOLUME, 719.0 G/L
LIGHT ALKYLATE PETROLEUM NAPHTHA
ORL-RAT TDLo: 10 GM/KG/4W-I 4.
IHL-RAT TCLo: 7500 PPM/13W-I 4.
HYDROCARBON MISTS DERIVED FROM HIGHLY REFINED PETROLEUM DISTILLATES ARE REPORTED TO HAV
ACUTE AND SUB-ACUTE TOXICITIES IN ANIMALS. EFFECTS FROM SINGLE AND SHORT-TERM REPEATED EXP
HIGH CONCENTRATIONS WELL ABOVE APPLICABLE WORKPLACE EXPOSURE LEVELS INCLUDE LUNG INFLA
REACTION, LIPOID GRANULOMA FORMATION, AND LIPOID PNEUMONIA. IN ACUTE AND SUB-ACUTE STUDIES
EXPOSURES TO LOWER CONCENTRATIONS AT OR NEAR CURRENT WORK PLACE EXPOSURE LEVELS PROD
SIGNIFICANT TOXICOLOGICAL EFFECTS. IN LONG TERM STUDIES (UP TO TWO YEARS) NO CARCINOGENIC E
HAVE BEEN REPORTED IN ANY ANIMAL SPECIES TESTED. THESE PETROLEUM DISTILLATES ARE SEVERELY
HYDROTREATED, SEVERELY SOLVENT EXTRACTED, AND/OR PROCESSED BY MILD HYDROTREATMENT AND
EXTRACTION. FOR THIS REASON, THEY ARE NOT CLASSIFIED AS CANCER HAZARDS. 3.
265
D-LIMONENE
ORL-RAT LD50: >5 G/KG 3.
SKN-RBT LD50: >5 G/KG 3.
SKN-RBT: SEVERELY IRRITATING 3.
EYE-RBT: SEVERELY IRRITATING 3.
PROPANE
NO TOXICITY DATA AVAILABLE
N-BUTANE
IHL-RAT LC50: 658 G/M3/4H 4.
IHL-MUS LC50: 680 G/M3/4H 4.
Section VII - Reactivity Data
Stability
[√] Stable
[ ] Unstable
Conditions to Avoid:
AVOID HEAT, HOT SURFACES, SPARKS, AND OPEN
FLAMES.
Hazardous Polymerization
[ ] May
[√] Will not occur
occur
Conditions to Avoid:
N/A
Incompatibility (Materials to Avoid):
STRONG OXIDIZING AGENTS SUCH AS CHLORINE BLEACH AND CONCENTRATED HYDROGEN PEROXIDE; ACI
ALUMINUM CHLORIDE, HALOGENS, IODINE PENTAFLUORIDE, VINYL CHLORIDE, PLASTICS, AND RUBBER.
Hazardous Decomposition Products:
OXIDES OF CARBON.
Section VIII - Spill Or Leak Procedures
Steps to be Taken if Material is Released or Spilled:
DUE TO THE NATURE OF THE AEROSOL PACKAGING, A LARGE SPILL IS UNLIKELY. FOR A SMALL SPILL, WEA
APPROPRIATE PROTECTIVE CLOTHING, VENTILATE THE AREA, ABSORB WITH AN INERT MATERIAL AND TRA
MATERIAL INTO A PROPERLY LABELED CONTAINER FOR DISPOSAL. USE CARE AS SPILLS MAY BE SLIPPERY
Waste Disposal Method(s):
DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE, AND LOCAL REGULATIONS. TYPICAL DISPOSAL IS
THE EMPTY AEROSOL CONTAINER IN SEVERAL LAYERS OF NEWSPAPER AND DISPOSE OF IN THE TRASH. A
RECYCLING PROGRAMS ARE AVAILABLE IN MANY AREAS. DO NOT PUNCTURE OR INCINERATE THIS CONTAI
Neutralizing Agent
OF GOVERNMENTAL INDUSTRIAL HYGIENISTS, TLV:THRESHOLD LIMIT VALUE, PEL:PERMISSIBLE EXPOSURE
STEL:SHORT-TERM EXPOSURE LIMIT, MLD:MILD, MOD:MODERATE, SEV:SEVERE, MUT:MUTAGENIC, ASPHYX:
PNOS:PARTICLES (INSOLUBLE) NOT OTHERWISE SPECIFIED, SDT:STANDARD DRAIZE TEST, ORL:ORAL, IHL:I
HMN:HUMAN
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE IN LIGHT OF CURRENT
FORMULATION. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THE
THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
MANTEK, DIVISION OF NCH CORP. assumes no responsibility for personal injury or property damage caused by the u
266
disposal of the product in a manner not recommended on the product label. Users assume all risks associated with such
unrecommended use, storage, or disposal of the product.
©2006 NCH Corporation All rights reserved.
267
Tin Alloy Solder
Code: EI-35294
Date: 21 MAR 2000
Revised: 1 NOV 2010
Printed: 1 NOV 2010
WOLVERINE JOINING TECHNOLOGIES, LLC.
MATERIAL SAFETY DATA SHEET
Product: TIN SOLDER ALLOY, 35294
SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Common Name
:
Chemical Name
:
Formula
:
Product CAS No.:
TIN SOLDER ALLOY
TIN ALLOY
Sn
7440-31-5
Product Use
Supplier
Address
City, St, Zip
:
:
:
:
Welding/Brazing/Soldering
WOLVERINE JOINING TECHNOLOGIES, LLC.
235 KILVERT STREET
WARWICK, RI 02886
Phone
: 1-401-739-9550
FOR CHEMICAL EMERGENCY CALL CHEMTREC (24 HOURS): 1-800-424-9300 (US, Canada, Puerto
Rico, Virgin Islands) 1-703-527-3887 (Outside Above Area)
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENT
TIN
CAS NO.
% Wt.
7440-31-5
99.85
INGREDIENT NOTES
NOTE: The percentage by weight values reported for the ingredients in this product represent approximate
formulation values.
NOTE: See Section 8 for Exposure Limits and Section 11 for Toxicological Information.
SECTION 3: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Grey to silver wire
Odorless
268
Flash Point: Not Determined
May cause eye, skin and respiratory tract irritation.
Harmful if large amounts are swallowed. May cause gastrointestinal irritation, abdominal pain, nausea,
vomiting and diarrhea.
Not a fire or explosion hazard in solid form. Finely divided dust may ignite and burn rapidly when mixed with air
in the proper proportions. Toxic metal fumes may be released in a fire situation.
ROUTES OF ENTRY
Eyes? YES
Skin? YES
Inhalation? YES
Ingestion? YES
POTENTIAL HEALTH EFFECTS
EYE CONTACT may cause irritation.
SKIN CONTACT may cause irritation.
INHALATION may cause irritation of the respiratory tract. Short-term overexposure may cause a flu-like illness called
metal fume fever. Typically metal fume fever begins four to twelve hours after sufficient exposure to freshly formed
fumes. The first symptoms are a metallic taste, dryness and irritation of the throat. Cough and shortness of breath may
occur along with headache, fatigue, nausea, vomiting, muscle and joint pain, fever and chills. The syndrome runs its
course in 24-48hrs.
INGESTION of large amounts is harmful. May cause gastrointestinal irritation, abdominal pain, nausea,
vomiting and diarrhea.
NOTE: The potential health effects described above only apply if dust or fume is formed.
CARCINOGENICITY
NTP? NO
IARC? NO
OSHA? NO
CHRONIC HEALTH HAZARDS
Prolonged or repeated inhalation may cause a benign pneumoconiosis.
Refer to Potential Health Effects.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
None known.
NOTE: See Section 8 for Exposure Limits, Section 11 for Toxicological Information and Section 12 for Ecological
Information.
SECTION 4: FIRST AID MEASURES
EYE CONTACT: Flush eyes with plenty of water. If irritation develops, call a physician.
SKIN CONTACT: Immediately wash skin with soap and plenty of water. If irritation persists, call a physician.
INHALATION: If exposed to excessive levels of metal fumes, remove to fresh air and seek medical attention.
INGESTION: Procedures normally not needed. If large quantities are ingested, seek medical advice.
269
SECTION 5: FIRE-FIGHTING MEASURES
Flash Point: Not Determined
Auto-Ignition: Not Determined
LEL: Not Determined
UEL: Not Determined
NFPA HAZARD CLASSIFICATION
Health:
1
Flammable: 0
Reactivity: 0
HMIS HAZARD CLASSIFICATION
Health:
1
Flammable: 0
Reactivity: 0
Special: B
EXTINGUISHING MEDIA
Use dry sand, soda ash, dolomite or other suitable dry powder. Do not apply water directly to burning material. Use
water to keep fire-exposed containers cool.
SPECIAL FIRE FIGHTING PROCEDURES
Wear NIOSH/MSHA approved positive-pressure self-contained breathing apparatus and protective clothing as
specified in 29 CFR 1910.156.
UNUSUAL FIRE AND EXPLOSION HAZARDS
Not a fire or explosion hazard in solid form. Finely divided dust may ignite and burn rapidly when mixed with air in the
proper proportions. Toxic metal fumes may be released in a fire situation.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Contain spillage and scoop up or vacuum. Notification of the National Response Center (800/424-8802) may be required.
Refer to EPA, DOT and applicable state and local regulations for current response information.
It is recommended that each user establish a spill prevention, control and countermeasure plan (SPCC). Such plan
should include procedures applicable to proper storage, control and clean-up of spills, including reuse or disposal as
appropriate (see Section 13: Disposal Considerations).
**NOTE** In the event of an accidental release of this material, the above procedures should be followed.
Additionally, proper exposure controls and personal protection equipment should be used (see Section 8: Exposure
Control/Personal Protection), and disposal of the material should be in accordance with Section 13: Disposal
Considerations.
SECTION 7: HANDLING AND STORAGE
Wash thoroughly after handling.
Store in a cool, dry location away from incompatible materials.
Avoid breathing any dust, mist or fumes resulting from the use of this product.
Avoid contact with any dusts, mists or fumes resulting from the use of this product.
Use only with adequate ventilation.
270
Do not eat, drink, or smoke in work area.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
EXPOSURE LIMITS
INGREDIENT
TIN
PEL-OSHA
TLV-ACGIH
CAS NO.: 7440-31-5
2 mg/m3
2 mg/m3
NOTE: Both OSHA and the ACGIH list welding fumes as having an exposure limit of 5 mg/m3 (total particulate not
otherwise classified). However, the ACGIH states that welding fumes must be tested frequently for individual
components which are likely to be present to determine whether specific exposure limits are exceeded.
NOTE: The permissible exposure limits (PELs), threshold limit values (TLVs), potential health effects statements and
SARA hazard categories may not be applicable as the hazardous ingredients listed are in the solid form. If dust,
powder or fume is generated then these statements will be applicable.
Unless otherwise noted, all values are reported as 8-hour Time-Weighted Averages (TWAs) and total dust (particulates
only). All ACGIH TLVs refer to the 1999 Standards. All OSHA PELs refer to 29 CFR Part 1910 Air Contaminants: Final Rule,
January 19, 1989.
RESPIRATORY PROTECTION
If dust or fume is generated, a NIOSH/MSHA approved respirator may be necessary. Follow all requirements for
respiratory programs and selection set forth in the OSHA regulations (29 CFR 1910.139).
VENTILATION
General; local exhaust ventilation as necessary to control any air contaminants to within their PELs or TLVs
during the use of this product.
PROTECTIVE EQUIPMENT
Safety glasses (with side shields).
Body protection as necessary to prevent skin contact.
Refer to ANSI/ASC Z49.1-94 (Safety in Welding, Cutting and Allied Processes), published by the American
Welding Society, for further information on the selection of personal protective equipment.
PERSONNEL SAMPLING PROCEDURE
For TIN: Refer to NIOSH Manual of Analytical Methods (NMAM), 4th Edition, Method 7300.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Grey to silver wire Odor: Odorless
Boiling Point: 2260 °C Specific Gravity (H2O=1): 7.28 Melting
Point: 232 °C
Vapor Pressure (mm Hg): 1 mm Hg at 1610øC Vapor Density (Air=1): Not
Applicable Evaporation Rate: Not Applicable
% Solubility In Water: Insoluble pH: Not Applicable
SECTION 10: STABILITY AND REACTIVITY
271
Stability: Generally considered stable.
Avoid: None expected.
INCOMPATIBILITY (Materials to Avoid)
Acids, bases, oxidizers and halogens.
Metal salts.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS
Toxic metal oxides are emitted when heated above the melting point. The amount of fume evolved increases as the
temperature rises.
Polymerization: Polymerization is not expected to occur. Avoid: Not applicable.
SECTION
11: TOXICOLOGICAL INFORMATION
CHEMICAL NAME
% Wt. LD50
LC50
TIN
CAS NO.: 7440-31-5
NOTE: See Sections 3, 8
99.85 Not Available
Not Available
and 12 for additional information.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICITY
No data available.
ENVIRONMENTAL FATE
No data available.
SECTION 13: DISPOSAL CONSIDERATIONS
US EPA Waste Number: Not Regulated
Federal, state and local disposal laws and regulations will determine the proper waste disposal/recycling/reclamation
procedure. All waste materials should be reviewed to determine the applicable hazards (testing may be necessary).
Disposal requirements are dependent on the hazard classification and will vary by location and the type of disposal
selected.
**NOTE** Chemical additions, processing or otherwise altering this material may make the waste management
information presented above incomplete, inaccurate or otherwise inappropriate.
As local regulations may vary; all waste must be disposed/recycled/re-claimed in accordance with federal, state, and
local environmental control regulations.
272
SECTION 14: TRANSPORT INFORMATION
INTERNATIONAL
UN Number: Not Regulated
UNITED STATES
EPA Waste Number: Not Regulated
DOT Classification: Not Regulated
CANADA
PIN Number: Not Regulated
TDG Class: Not Regulated
EC
DGL: Not Determined
SECTION 15:
REGULATORY INFORMATION
US FEDERAL REGULATIONS
TSCA: IN TSCA
SARA 311 AND 312 HAZARD CATEGORIES
IMMEDIATE (Acute) Health Hazard: YES
DELAYED (Chronic) Health Hazard: NO
FIRE Hazard: NO
REACTIVITY Hazard: NO
Sudden Release of PRESSURE: NO
SARA SECTION 313 NOTIFICATION
This product does not contain toxic chemicals subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
OZONE DEPLETING SUBSTANCES (ODS)
This product neither contains nor is manufactured with an ozone depleting substance subject to the labeling
requirements of the Clean Air Act Amendments 1990 and 40 CFR Part 82.
VOLATILE ORGANIC COMPOUNDS (VOC)
Not Determined
US STATE REGULATIONS
CALIFORNIA: The State of California has a regulation (Proposition 65) which identifies specific chemicals known to the
State of California to cause cancer or birth defects. Proposition 65 requires a disclosure for products sold within the
State of California containing an identified chemical. The following information is required by the State of California for
this product:
*WARNING: This product contains chemicals known to the State of California to cause cancer.
273
*WARNING: This product contains chemicals known to the State of California to cause birth defects or
other reproductive harm.
VOLATILE ORGANIC COMPOUND (CARB): Not Determined
CANADIAN REGULATIONS
"This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the
MSDS contains all the information required by the Controlled Products Regulations."
DSL/NDSL: DSL
WHMIS Classification: Uncontrolled Product
EUROPEAN REGULATIONS
EINECS: Yes
OTHER REGULATIONS
MITI (Japan): Yes
AICS (Australia): Yes
SECTION 16: OTHER INFORMATION
REVISIONS
Revision Number: 5
PREPARATION INFORMATION
Prepared By: Wolverine Joining Technologies, and Wolverine Tube Inc. Corporate Environmental, Health and
Safety Group.
Phone Number/Address: See Section 1
______________________________________________________________________
This Material Data Sheet is offered pursuant to OSHA';s Hazard Communication Standard (29 CRF 1910.1200). Other
government regulations must be reviewed for applicability to these products. The information in this Material Safety
Data Sheet should be provided to all who will use, handle, store, transport, or otherwise be exposed to this product.
This information has been prepared for the guidance of plant engineering, operations, and management and for
persons working with or handling these products. The information presented in the MSDS is premised upon proper
handling and anticipated uses and is for the material without chemical additions/alterations. We believe this
information to be reliable and up-to-date as of the date of publication, but make no warranty that it is. Additionally, if
this Material Safety Data Sheet is more than three years old, please contact the supplier at the phone number listed in
Section 1 to make certain that this sheet is the most current. Copyright Wolverine Joining Technologies, LLC. License
granted to make unlimited copies for internal use only.
274
TMS Polymeric
MATERIAL SAFETY DATA SHEET
RAY3126
(US, CN Version for International Trade)
SECTION
1:
IDENTIFICATION
PRODUCT
AND
COMPANY
PRODUCT NAME:
TMS™ Polymeric Products
MANUFACTURER:
Tyco Electronics Corporation
DIVISION:
Ident Label Products
ADDRESS:
300 Constitution Drive
Menlo Park, CA 94025-1164
USA
SUPPLIERS
EMERGENCY TELEPHONE NUMBERS:
NON-EMERGENCY HEALTH/SAFETY INFORMATION:
US: CHEMTREC 1-800-424-9300
CN: CHEMTREC 1-800-424-9300
Outside North America: 1-703-527-3887
(Collect calls accepted)
North America: 1- 650-361-4907
CHEMICAL FAMILY:
Not applicable – This product is a manufactured article.
PRODUCT USE:
TMS™ Polymeric Products are typically used for wire and cable identification
This product is not hazardous when used as recommended or intended. If this product is overheated, charred, or burned
the health and safety information presented in this MSDS may apply.
Thermal decomposition and combustion byproducts may be regulated under US-OSHA; CAN-WHMIS; IOSH; ISO; UKCHIP; or EU Directives (67/548/EEC-Dangerous Substance Labelling, 98/24/EC-Chemical Agents at Work, 99/45/ECPreparation Labeling, 2001/58/EC-MSDS Content, and 1907/2006/EC-REACH).
SECTION 2: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: TMS™ Polymeric Products are not hazardous during proper installation, as directed by product
installation guides. If overheated to degradation, most significantly if the product
burns, thermal degradation and combustion byproducts may be toxic and should not
be inhaled.
The thermal degradation and combustion byproducts will depend on the base
polymer used, and may include, but are not limited to carbon monoxide, carbon
dioxide, organic acids (including acetic acid), aldehydes, low molecular weight
hydrocarbons, silicon dioxide, hydrogen chloride, hydrogen fluoride, hydrogen
bromide, fluoro-olefins, and oxides of nitrogen, phosphorus and sulfur.
POTENTIAL HEALTH EFFECTS:
Thermal degradation and combustion byproducts may be toxic and should not be inhaled.
275
ACUTE HEALTH HAZARDS:
EYES:
SKIN:
INGESTION:
Contact with molten material may cause thermal burns.
This product is not expected to be a skin irritant. Contact with the molten material my cause
thermal burns. No harmful effects are expected from skin absorption of this product.
Ingestion of this product is highly unlikely. There is insufficient information available on this
material to predict the effects from ingestion.
INHALATION:
In common with most organic materials, thermal degradation and combustion byproducts may be
toxic and should not be inhaled. (See comments below and the Thermal Degradation and
Combustion Byproducts Section for more specific information).
CHRONIC HEALTH HAZARDS:
None of the ingredients to which users may be exposed and which are present at equal to or greater than 0.1% of the
product, are listed by OSHA, NTP, or IARC as suspect carcinogens.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
Overheating the product to charring or burning may produce vapors that may cause eye, skin, nose and throat irritation.
Persons with pre-existing eye, skin, or respiratory disorders (e.g., asthma conditions) may be more susceptible to the
effects of these vapors.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Not applicable – This product is a manufactured article.
Base polymer materials may include polyethylene, olefin copolymers, and fluoropolymers.
SECTION 4: FIRST AID MEASURES
EYE CONTACT: If eye irritation occurs, hold eyelids apart and flush affected area(s) with clean water for at least 15
minutes. Seek medical attention.
SKIN CONTACT: First aid is normally not required. After handling product, it is good work practice to wash your hands.
If molten material contacts skin, cool area immediately in water. DO NOT attempt to remove
material from the skin. Treat as a burn, and seek medical attention.
INGESTION:
INHALATION:
Not a normal route of exposure. However, if swallowed and symptoms develop, seek
medical attention.
In case of inhalation where symptoms of exposure develop, move victim to fresh air. If
symptoms persist, seek medical attention If breathing difficulties develop, oxygen should be
administered by qualified personnel. If victim is not breathing, move to fresh air and
immediately begin artificial respiration. Keep victim warm and quiet. Seek immediate medical
attention.
SECTION 5: FIRE-FIGHTING MEASURES
FLAMMABLE PROPERTIES
FLASHPOINT:
METHOD USED:
Not determined
Not applicable
FLAMMABLE LIMITS
UPPER FLAMMABILITY LIMIT (% BY VOLUME):
LOWER FLAMMABILITY LIMIT (% BY VOLUME):
AUTOIGNITION TEMPERATURE:
Not determined
SUITABLE EXTINGUISHING MEDIA:
Not available
Not available
276
carbon dioxide X
water X
dry chemical X foam X other
Selection of extinguishing media should be based upon the size of the fire, the firefighting training/experience of the
individual attempting to extinguish or control the fire, and the packaging materials exposed to the fire.
SPECIAL FIRE FIGHTING PROCEDURES & PROTECTIVE EQUIPMENT:
Firefighters should wear self-contained breathing apparatus with a full-face piece operated in the positive pressure
demand mode when fighting fires. Use water spray to cool nearby containers and structures exposed to fire
UNUSUAL FIRE AND EXPLOSION HAZARDS:
SENSITIVITY TO STATIC DISCHARGE: None known
SENSITIVITY TO MECHANICAL IMPACT: None known
SPECIFIC HAZARDS IN CASE OF FIRE:
Degradation and combustion byproducts may be toxic and should not be inhaled.
HAZARDOUS COMBUSTION PRODUCTS:
Thermal degradation is not significant at temperatures achieved during proper installation, as directed by product
installation guides. At temperatures higher than those recommended, most significantly if the product burns, the thermal
degradation and combustion byproducts will depend on the base polymer used and may include, but are not limited to
carbon monoxide, carbon dioxide, organic acids (including acetic acid), aldehydes, low molecular weight hydrocarbons,
silicon dioxide, hydrogen chloride, hydrogen bromide, fluoro-olefins, and oxides of nitrogen, phosphorus, and sulfur.
SECTION 6: ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS:
Wear appropriate personal protection when responding, as specified under Section 8: EXPOSURE CONTROLS / PERSONAL
PROTECTION
ENVIRONMENTAL PRECATIONS:
Prevent spilled material from entering sewers and waterways.
SPILL CONTAINMENT & CLEANUP METHODS/MATERIALS:
Sweep up and collect in a suitable container for disposal or reuse.
SECTION 7: HANDLING AND STORAGE
PRECAUTIONS FOR SAFE HANDLING AND STORAGE:
Handling: Heat resistant gloves are required if hot products are handled after installation.
Storage: This product is stable under normal conditions.
OTHER PRECAUTIONS (e.g.; Incompatibilities):
Avoid heating products beyond temperatures required for normal installation. See installation instructions for proper
installation procedures. If product chars or burns, immediately stop heating. Avoid inhaling any fumes, which may be given
off under such circumstances. Allow any vapors to disperse and ventilate before continuing work in the area.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS/SYSTEM DESIGN INFORMATION:
Ensure adequate ventilation during application, particularly in enclosed areas.
VENTILATION:
Provide general or local exhaust ventilation systems
RESPIRATORY PROTECTION:
277
If installation occurs in a confined, unventilated area, NIOSH/MSHA-approved respirators are recommended.
EYE PROTECTION:
If there is a danger of molten material contacting the eyes, use eye/faceshield.
SKIN PROTECTION:
If there is a danger of molten material contacting the skin, use heat resistant gloves. If it is necessary to handle products
that have beed grossly overheated or fire-damaged, wear natural rubber gloves to prevent possible contact with
potentially corrosive inorganic acid residues.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT:
OSHA, ANSI, or NIOSH guidelines should be followed based on the operation performed.
EXPOSURE GUIDELINES & LIMITS:
Not applicable – This product is a manufactured article.
OSHA
Permissible Exposure Limit (PEL/TWA)
ACGIH
Threshold Limit Value (TLV)
Ontario
Occupational Exposure Level (OEL)
Germany
Maximale Arbeitsplatzkonzentrationen (MAK)
United Kingdom
Occupational Exposure Standard (OES)
TWA – 8-Hour Time Weighted Average/ NE – Not
Established
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE:
ODOR:
ODOR THRESHOLD:
PHYSICAL STATE:
pH:
BOILING POINT:
MELTING POINT:
FREEZING POINT:
VAPOR PRESSURE (mmHg @
º
20 C):
VAPOR DENSITY (AIR = 1):
VOLATILITY (% by Volume)
SPECIFIC GRAVITY (H2O = 1):
EVAPORATION RATE (Butyl
acetate=1):
SOLUBILITY IN WATER:
FLASH POINT:
AUTO-IGNITION TEMPERATURE:
LOWER EXPLOSIVE LIMIT (LEL):
UPPER EXPLOSIVE LIMIT (UEL):
PARTITION COEFFICIENT:
VISCOSITY (centipoise @ 25° C):
DECOMPOSITION TEMPERATURE:
Plastic tubing and molded parts in a variety of shapes, sizes and colors.
No odor.
Not applicable
Solid
Not applicable
Not applicable
85º – 160º C (185º - 320º F)
Not available
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Insoluble
Not available
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Not available
278
FLAMMABILITY/HMIS HAZARD CLASSIFICATIONS (US/CN/EU):
Not applicable – This product is a manufactured article.
HEALTH:
FLAMMABILITY:
REACTIVITY:
SECTION 10: STABILITY AND REACTIVITY
STABILITY:
This product is stable under normal conditions, at ambient
temperature.
INCOMPATIBILITY (MATERIAL TO AVOID):
Avoid overheating of product.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS:
See Section 5: FIRE FIGHTING MEASURES (Hazardous Combustion
Products).
HAZARDOUS POLYMERIZATION:
Will not occur. No known polymerization conditions to avoid.
CONDITIONS TO AVOID:
Avoid overheating of product.
SECTION 11: TOXICOLOGICAL INFORMATION
ACUTE TOXICITY (Test Results Basis and Comments):
LD50 (Oral, Rat): Not determined
LC50 (Inhalation, Rat): Not determined
ROUTES OF ENTRY/EFFECTS OF ACUTE OVEREXPOSURE:
Overheating the product to charring or burning may produce vapors that may cause eye, skin, nose and throat irritation.
SUBCHRONIC/CHRONIC TOXICITY (Test Results and Comments):
Not determined.
IRRITANCY OF PRODUCT: Vapours from the heated product may cause irritation of the eyes, skin, nose, and throat.
SENSITIZATION TO MATERIAL: Persons with pre-existing eye, skin, or respiratory disorders (e.g., asthma conditions) may
be more susceptible to the effects of vapors produced by burning or charing product.
CARCINOGENICITY: None of the ingredients to which users may be exposed and which are present at equal to or greater
than 0.1% of the product, are listed by OSHA, NTP, or IARC as carcinogens.
REPRODUCTIVE TOXICITY: Not determined.
TERATOGENICITY: Not determined.
MUTAGENICITY: Not determined.
TOXICOLOGICALLY SYNERGISTIC PRODUCTS: Not determined.
SECTION 12: ECOLOGICAL INFORMATION
PERSISTENCE & DEGRADABILITY:
No data available on biodegradation.
BIO-ACCUMULATIVE POTENTIAL (Including Mobility):
No data available on bioaccumulation.
AQUATIC TOXICITY (Test Results & Comments):
No data available on aquatic toxicity.
Additional Information
4.
No known effects on stratospheric ozone depletion.
279
5.
Water Endangering Class (WGK): NA
SECTION 13: DISPOSAL CONSIDERATIONS
WASTE DISPOSAL
METHOD:
HAZARDOUS WASTE
Treatment, storage, and disposal must be in accordance with applicable, federal, state,
provincial, and local regulations.
If there are local regulations covering the controlled incineration of halogenated materials.
Then all halogen-containing products will be subject to such regulations. Refer to the product
literature for identification of halogen-containing products.
CLASS/CODE:
US - Not applicable to material as manufactured for distribution into commerce.
CN – Not applicable to material as manufactured for distribution into commerce.
EWC – Not applicable to material as manufactured for distribution into commerce.
Additional Information
Not Included – Dispose/Recycle as allowed by local jurisdiction for the end-of-life characteristics as-disposed.
SECTION 14: TRANSPORT INFORMATION
These products are non-hazardous under Department of Transportation Regulations 49, CFR Section 171.8, IATA, IMO,
and AFR 71-4.
GROUND – US-DOT/CAN-TDG/EU-ADR/APEC-ADR:
Proper Shipping Name
Not Subject to HMR
Hazard Class
Packing Group
NA
NA
AIRCRAFT – ICAO-IATA:
Proper Shipping Name
Not Subject to DGR
Hazard Class
Packing Group
NA
NA
ID
Number
Labels
NA
NA
ID
Number
Labels
NA
NA
RAY3126
(US, CN Version for International Trade)
VESSEL – IMO-IMDG:
Proper Shipping Name
Hazard Class
Packing Group
Additional Information
3.
4.
5.
6.
Not Subject to IMDG
NA
NA
ID Number
Labels
NA
NA
Transportation must be in accordance with applicable, federal, state, provincial, and local regulations.
Transport requires proper packaging and paperwork, including the Nature and Quantity of goods, per applicable
origin/destination/customs points as-shipped. Statement of Jurisdictional/Modal Special Provision(s) required.
Not restricted for any mode of international transport as finished goods.
Not a Marine Pollutant as-shipped per IMO/IMDG.
SECTION 15: REGULATORY INFORMATION
INVENTORY STATUS:
All components are listed on the TSCA; EINECS/ELINCS; and DSL, unless noted otherwise below.
280
U.S. FEDERAL REGULATIONS:
TSCA Section 8b – Inventory Status: All chemicals comprising this product are either exempt or listed on the TSCA
Inventory.
TSCA Section 12b – Export Notification: If the product contains chemicals subject to TSCA Section 12b export notification
they are listed below:
Chemical
CAS #
None
NA
CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT)
Chemicals present in the product which could require reporting under the statute:
Chemical
CAS #
None
NA
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
If the product contains chemicals subject to the reporting requirements of Section 313 of SARA Title III, they are listed
below.
Chemical
CAS #
% wt
None
NA
NA
CERCLA SECTION 311/312 HAZARD CATEGORIES: Note that this product is exempt from these regulations.
Fire Hazard
No
Pressure Hazard
No
Reactivity Hazard
No
Immediate Hazard
No
Delayed Hazard
No
STATE REGULATIONS (US):
California Proposition 65
The following chemicals identified to exist in the product as distributed into commerce are known to the State of
California to cause cancer, birth defects, or other reproductive harm:
Chemical
CAS #
% Wt
None
NA
NA
INTERNATIONAL REGULATIONS (Non-US):
Canadian Domestic Substance List (DSL)
Not applicable.
WHMIS Classifications
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and
the MSDS contains all of the information required by the Controlled Products Regulations."
NPRI and Ontario Regulation 127/01
This product contains the following chemicals subject to the reporting requirements of Canada NPRI and/or Ont. Reg.
Chemical
None
CAS #
N/A
% Wt
N/A
European Inventory of Existing Commercial Chemical Substances (EINECS)
All ingredients remaining in the product as distributed into commerce are exempt from, or included on, the
European Inventory of Existing Commercial Chemical Substances.
European Communities (EC) Hazard Classification according to directives 67/548/EEC and 1999/45/EC.
R-Phrases
S-Phrases
None
None
281
Additional Information
This product may be regulated under additional regulations and laws not identified above, such as for uses other
than described or as-designed/as-intended by the manufacturer, or for distribution into specific domestic
destinations.
SECTION 16: OTHER INFORMATION
OTHER INFORMATION:
Distribution into Quebec to follow Canadian Controlled Product Regulations (CPR) 24(1) and 24(2).
Distribution into the EU to follow applicable Directives to the Use, Import/Export of the product assold.
MSDS/SDS PREPARATION INFORMATION:
Department Issuing MSDS: Tyco Electronics, Menlo Park
DATE OF ISSUE:
April 3, 2009
SUPERCEDES: March 10, 2009
DISCLAIMER:
Tyco Electronics makes no warranties as to the accuracy or completeness of this information and disclaims any liability
in connection with its use. Tyco Electronics’ obligation shall be only as set forth in Tyco Electronics’ standard terms and
conditions of sale for this product. In no case will Tyco Electronics be liable for any incidental, indirect or consequential
damages arising out of the sale, resale, use or misuse of the product.
The information presented herein was prepared at Tyco Electronics by qualified technical personnel, and to our knowledge it
is true and accurate. The information and recommendations are furnished for this product with the understanding that the
purchaser/user will independently determine the suitability of the product for this purpose. The data do not constitute a
warranty, expressed or implied, statutory or otherwise, nor are they a representation for which Tyco Electronics assumes
legal responsibility. The data are submitted for the user’s information and consideration only. Any use of this product must
be determined by the user to be in accordance with the applicable federal, State/Provincial, and local laws and regulations.
Users are advised that they may have additional disclosure obligations under other national and local laws. Users are
advised to ensure that this information is brought to the attention of all employees, agents, and contractors handling this
product. Users of Tyco Electronics products should make their own evaluation to determine the suitability of each such
product for the specific application and to establish safe handling and installation procedures. Distributors of this product
are advised to forward this document, or the information contained herein, to every purchaser of this product.
282
Triple 'D'
283
284
285
286
Wasp & Hornet Spray
Material Safety Data Sheet
Section 1: Product & Company Identification
Product Name:
Bee Blast
Product Number (s):
14009
TM
Wasp & Hornet Killer
Manufactured By:
CRC Industries, Inc.
885 Louis Drive
Warminster, PA 18974
General Information
Technical Assistance
Customer Service
(215) 674-4300
(800) 521-3168
(800) 272-4620
www.crcindustries.com
24-Hr Emergency (CHEMTREC)
(800) 424-9300
Section 2: Hazards Identification
Emergency Overview
Appearance & Odor: Amber liquid, petroleum odor
CAUTION
Flammable. Harmful or fatal if swallowed. Eye irritant. Contents under pressure.
As defined by OSHA’s Hazard Communication Standard, this product is hazardous.
Potential Health Effects:
EYE:
May cause moderate eye irritation.
SKIN:
May cause skin irritation. Prolonged contact may allow material to be absorbed
through the skin
INHALATION:
May cause respiratory irritation. Overexposure to vapors may lead to central
nervous system effects such as headache and drowsiness, followed by dizziness
and nausea.
INGESTION:
May cause gastrointestinal discomfort or irritation of the throat. Aspiration of this
material into the lungs, either while swallowing or vomiting, may lead to chemical
pneumonitis, which could be fatal. Signs of lung involvement include increased
respiratory rate, increased heart rate, and a bluish discoloration of the skin.
CHRONIC EFFECTS:
Repeated skin contact may cause contact dermatitis.
287
TARGET ORGANS:
Central nervous system.
Medical Conditions Aggravated by Exposure:
pre-existing skin conditions
See Section 11 for toxicology and carcinogenicity information on product ingredients.
Section 3: Composition/Information on Ingredients
COMPONENT
CAS NUMBER
% by Wt.
Hydrotreated light distillate
64742-47-8
90 - 100
Tetramethrin
7696-12-0
0.200
Phenothrin
26002-80-2
0.125
Carbon dioxide
124-38-9
1-5
Section 4: First Aid Measures
Eye Contact:
Immediately flush with plenty of water for 15 minutes. Call a physician if irritation persists.
Skin Contact:
Remove contaminated clothing and wash affected area with soap and water. Call a physician
if irritation persists. Wash contaminated clothing prior to re-use.
Inhalation:
Remove person to fresh air. Keep person calm. If not breathing, give artificial respiration. If
breathing is difficult give oxygen. Call a physician.
Ingestion:
Do NOT induce vomiting due to aspiration hazard. If vomiting occurs, lower head below
knees to avoid aspiration. Seek immediate medical attention.
Note to Physicians:
None
Section 5: Fire-Fighting Measures
Flammable Properties: This product is flammable in accordance with aerosol flammability definitions (16 CFR
1500.3(c) (6) ).
288
Flash Point:
Autoignition Temperature:
177 F (PMCC)
ND
Upper Explosive Limit:
Lower Explosive Limit:
Suitable Extinguishing Media:
Use extinguishers appropriate for a class B fire.
Products of Combustion:
Oxides of carbon
ND
ND
Protection of Fire-Fighters: Firefighters should wear self-contained, NIOSH-approved breathing apparatus for protection
against suffocation and possible toxic decomposition products. Proper eye
and skin protection should be provided. Use water spray to keep fireexposed containers cool and to knock down vapors which may result from
product decomposition.
Section 6: Accidental Release Measures
Personal Precautions:
Use personal protection recommended in Section 8.
Environmental Precautions: Take precautions to prevent contamination of ground and surface waters. Do not flush into
sewers or storm drains.
Methods for Containment & Clean-up: Dike area to contain spill. Ventilate the area with fresh air. If in confined space
or limited air circulation area, clean-up workers should wear
appropriate respiratory protection. Recover or absorb spilled material
using an absorbent designed for chemical spills. Place used absorbents
into proper waste containers.
Section 7: Handling and Storage
Handling Procedures: Avoid breathing vapors. Use outside or with adequate ventilation. Avoid contact with eyes, skin and
clothing. Do not use near sparks, open flames or other sources of ignition.
Storage Procedures: Store in a cool dry area out of direct sunlight. Aerosol cans must be maintained below 120 F to
prevent cans from rupturing.
Aerosol Storage Level:
III
Section 8: Exposure Controls/Personal Protection
Exposure Guidelines:
COMPONENT
Hydrotreated light distillate
TWA
OSHA
STEL
NE
NE
ACGIH
TWA
STEL
NE
NE
TWA
OTHER
SOURC
E
UNIT
NE
289
Tetramethrin
NE
NE
NE
NE
NE
Phenothrin
NE
NE
NE
NE
NE
5000
NE
Carbon dioxide
N.E.
–
Established
Not
(c)
ceiling
5000 30000
NE
ppm
–
(s) – skin
(v) – vacated
Engineering Controls: Area should have ventilation to provide fresh air. Use local exhaust to prevent accumulation of
vapors. Use mechanical means if necessary to maintain vapor levels below the exposure
guidelines. If working in a confined space, follow applicable OSHA regulations
Respiratory Protection: None required for normal work where adequate ventilation is provided. Use NIOSHapproved self-contained positive pressure respirators in low circulation areas and
for
emergencies.
Eye/face Protection: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact,
wear splash-proof goggles.
Skin Protection: Use protective gloves such as neoprene or nitrile. Also , use full protective clothing if there is prolonged or
repeated contact of liquid with skin.
Section 9: Physical and Chemical Properties
Physical State:
liquid
Color:
light amber
Odor:
petroleum
Specific Gravity:
0.79
Initial Boiling Point:
420 F
Freezing Point:
ND
Vapor Pressure: < 0.1 mm Hg
Vapor Density:
>1
(air = 1)
Evaporation Rate:
<1
(ether = 1)
Solubility:
negligible in water
pH: NA
Volatile Organic Compounds:
wt %: 33.0
g/L: 260
lbs./gal: 2.17
Section 10: Stability and Reactivity
Stability:
Stable
290
Temperature
extremes;
Conditions to Avoid:
Incompatible Materials:
sources of ignition
Strong acids, bases and oxidizers
Hazardous Decomposition Products:
Carbon monoxide
Possibility of Hazardous Reactions:
No
Section 11: Toxicological Information
Toxicological studies have been conducted on the active ingredient mixture for this product. The following
information was supplied by the manufacturer of the active ingredient mixture.
ACUTE EFFECTS
Component
Test
Result
Route
Species
Active ingredient mixture
Active ingredient mixture
Active ingredient mixture
LD50
LD50
LC50
> 6.31 g/kg
> 2 g/kg
> 5.34 mg/L
Oral
Dermal
Inhalation
Rat
Rat
Rat
CHRONIC EFFECTS
Carcinogenicity:
OSHA:
IARC:
NTP:
Component
None listed
None listed
None listed
Result
Mutagenicity:
No information
Other:
None
Section 12: Ecological Information
Ecological studies have not been conducted for this product. The following information is available for
components of this product.
Persistence / Degradability:
Bioaccumulation / Accumulation:
No information available
No information available
No information available
Mobility in Environment:
No information available
Ecotoxicity:
Section 13: Disposal Considerations
Disposal:
The liquid product is not a RCRA hazardous waste. Full or partial full containers should be punctured
and drained. Empty containers may be recycled or discarded. Contact your state or local regulatory
291
agency for more details.
All disposal activities must comply with federal, state and local regulations. Local regulations may be more stringent
than state or national requirements.
Section 14: Transport Information
Proper shipping description:
US DOT (ground):
Consumer Commodity, ORM-D
Special Provisions:
None
Section 15: Regulatory Information
U.S. Federal
Toxic Substances Control Act (TSCA):
All ingredients are either listed on the TSCA inventory or are exempt.
Comprehensive Environmental Response, Compensation and Liability Act (CERCLA):
Reportable Quantities (RQ’s) exist for the following ingredients:
None
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the
National Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Superfund Amendments Reauthorization Act (SARA) Title III:
Section 302 Extremely Hazardous Substances (EHS):
Section 311/312 Hazard Categories:
None
Fire Hazard
Reactive Hazard
Release of Pressure
Acute Health Hazard
Chronic Health Hazard
Yes
No
Yes
Yes
No
Section 313 Toxic Chemicals: This product contains the following substances subject to the reporting requirements of
Section 313 of Title III of the Superfund Amendments and Reauthorization Act
of 1986 and 40 CFR Part 372:
Tetramethrin, Phenothrin
Clean Air Act:
Section 112 Hazardous Air Pollutants (HAPs):
None
State Regulations
California Safe Drinking Water and Toxic Enforcement Act (Prop 65):
292
NONE
State Right to Know:
Tetramethrin, Phenothrin, 1,2,4-Trimethylbenzene (< 0.5%)
1,2,4-Trimethylbenzene (< 0.5%)
1,2,4-Trimethylbenzene (< 0.5%)
None
New Jersey:
Pennsylvania:
Massachusetts:
Rhode Island :
Additional Regulatory Information:
EPA Registration #55809-3
Section 16: Other Information
NFPA:
HMIS:
Prepared By:
CRC #:
Revision Date:
Health:
Health:
2
2
Flammability:
Flammability:
2
2
Reactivity:
Reactivity:
0
0
PPE: B
Michelle Rudnick
00431A
6/15/2005
Changes since last revision:
Corrected CAS# in Section 3.
The information contained in this document applies to this specific material as supplied. It may not be valid for this material
if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or
obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the
label.
CAS:
ppm:
TCC:
PMCC:
PPE:
TWA:
OSHA:
ACGIH
NIOSH
Chemical Abstract Service
NA:
Parts per Million
ND:
Tag Closed Cup
NE:
Pensky-Martens Closed Cup
g/L:
Personal Protection Equipment
lbs./gal:
Time Weighted Average
STEL:
Occupational Safety and Health Administration
American Association of Governmental Industrial Hygienists
National Institute of Occupational Safety & Health
Not Applicable
Not Determined
Not Established
grams per Liter
pounds per gallon
Short Term Exposure Limit
293
Wheel Bearing Grease
MATERIAL SAFETY DATA SHEET
Section 1: Product & Company Identification
Product Name:
Lithium Complex Wheel Bearing Grease
Product Number (s): SL3110-SL3119
Manufactured By:
CRC Industries, Inc.
885 Louis Drive, Warminster, PA 18974
(215) 674-4300
24-Hour Emergency Information: CHEMTREC
(800) 424-9300
--------------------------------------------------------------------------------------------------------------------------------------Section 2: Composition/Information on Ingredients
Component
CAS
ACGIH
OSHA
OTHER
%
NUMBER
TLV
PEL
LIMITS
Lube Oil 500 SUS
64742-52-5
5 mg/m3
5 mg/m3
(mist)
Lithium 12 Hydroxyoctadecanoate
7620-77-1
NE
NE
NE
Residual Oils
64742-57-0
5 mg/m3
NE
NE
< 10
1030
Nonanedioic acid dilithium salt
38900-29-7
NE
NE
NE
5-10
5070
--------------------------------------------------------------------------------------------------------------------------------------Section 3: Hazards Identification
Emergency Overview
Appearance & Odor: Amber, mild bland petroleum odor.
Potential Health Effects:
Inhalation:
Exposure to oil mists or fumes, which may be generated when heated or burned, may
irritate the nose, throat and upper respiratory tract.
Eyes:
Irritation
Skin:
Irritation
Ingestion:
NA
Carcinogenicity:
Chronic Overexposure:
OSHA:
No
IARC:
No
NTP:
No
NA
Medical Conditions Aggravated by Exposure:
Pre-existing skin and pre-respiratory conditions.
--------------------------------------------------------------------------------------------------------------------------------------Section 4: First Aid Measures
294
Inhalation:
Remove to fresh air. Give artificial respiration if necessary.
Eyes:
Flush with large amounts of water for 15 minutes.
Skin:
Remove contaminated clothing and wash area with soap and water.
Ingestion:
Call a physician. Do not induce vomiting.
--------------------------------------------------------------------------------------------------------------------------------------Section 5: Fire-Fighting Measures
o
Flashpoint:
>300 F
Extinguishing Media:
Hazardous Combustion Products:
Fire-fighting Instructions:
TC
Method:
LEL: ND
UEL:
C
Carbon dioxide, dry chemical and foam
CO2 and carbon monoxide
Remove containers from fire area if possible. Use self-contained
breathing apparatus for fire
fighting.
Health
1
Flammability:
1
Reactivity:
0
:
Health
HMIS:
1
Flammability:
1
Reactivity:
0
PPE:
:
--------------------------------------------------------------------------------------------------------------------------------------Section 6: Accidental Release Measures
ND
NFPA:
B
Spill/Leak Procedures: Area should be ventilated. Absorbent should be used to pick up excess material. All used and
unused product should be disposed of in accordance with federal, state and local regulations.
--------------------------------------------------------------------------------------------------------------------------------------Section 7: Handling and Storage
Handling Procedures: Store in a cool, dry area.
--------------------------------------------------------------------------------------------------------------------------------------Section 8: Exposure Controls/Personal Protection
Engineering Controls: Adequate to prevent accumulation of vapors. Use mechanical means if necessary to maintain
levels below the exposure limits. If working in a confined space, follow applicable OSHA regulations.
Respiratory: Use NIOSH/MSHA compliant respirators or self-contained breathing apparatus above exposure limits.
Follow OSHA regulations 29 CFR 1910.134.
Protective Clothing/Equipment: Wear chemically protective gloves and safety glasses. Use a splash apron and boots
if splashing occurs.
--------------------------------------------------------------------------------------------------------------------------------------Section 9: Physical & Chemical Properties
Physical State:
Semi-solid
Appearance & Odor:
Amber, mild bland petroleum
odor
o
Specific Gravity:
0.9 @ 60 F
Boiling Point:
ND
Freezing Point:
ND
Vapor Pressure:
Neg.
Evaporation Rate:
Neg.
Vapor Density (air = 1)
> than air
295
pH:
NA
Solubility:
Neg.
Volatile Organic Compounds %:
1.5
g/L: 14
lbs./gal:
0.12
--------------------------------------------------------------------------------------------------------------------------------------Section 10: Stability and Reactivity
Stability:
Stable
Hazardous Polymerization: No
Chemical Incompatibilities:
Strong oxidizers.
Materials to Avoid:
Strong oxidizing agents.
Hazardous Decomposition Products:
None
-------------------------------------------------------------------------------------------------------------------------------------Section 11: Toxicological Information
Long-term toxicological studies have not been conducted for this product. See Section 3 of this MSDS for
acute symptoms of overexposure and carcinogenicity information.
--------------------------------------------------------------------------------------------------------------------------------------Section 12: Ecological Information
Ecotoxicity:
No data available.
Environmental Fate:
No data available for biodegradation.
--------------------------------------------------------------------------------------------------------------------------------------Section 13: Disposal Considerations
Disposal: This material if discarded may be hazardous waste under U.S. EPA RCRA regulations. All disposal
activities must comply with federal, state and local regulations. Contact your local or state environmental
agency for specific rules. Do not dump into sewers, on the ground or into any body of water.
--------------------------------------------------------------------------------------------------------------------------------------Section 14: Transportation Information
Shipping Name:
Not Regulated
Hazard Class:
NA
UN Number: NA
Label:
NA
Placard:
NA
Packing Group:
NA
Special Provisions:
NA
--------------------------------------------------------------------------------------------------------------------------------------Section 15: Regulatory Information
TSCA:
All components are either listed under TSCA or are exempt.
SARA Title III:
Section 311/312:
NA
CERCLA/Superfund (RQ):
NA
Extremely Hazardous Substances:
No
California Prop 65:
No
Section 313*:
None
* See section 2 for percentage
--------------------------------------------------------------------------------------------------------------------------------------Section 16: Additional Information
Prepared By:
Technical
Information:
Adam M. Selisker
Date:
March
2002
(800) 521-3168
CRC #:
SL3110
27,
296
This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by
CRC to be accurate. Before using any product, read all warnings and directions on the label.
CAS:
Chemical Abstract Service
NA:
Not Applicable
ppm:
Parts per Million
ND:
Not Determined
TCC:
Tag Closed Cup
NE:
Not Established
LEL:
Lower Explosive Limit
g/L:
grams per Liter
UEL:
Upper Explosive Limit
lbs./gal:
pounds per gallon
PPE:
Personal Protection Equipment
RQ:
Reportable Quantity
COC:
Cleveland Closed Cup
TOC:
Tag Open Cup
297
Windshield Washer Fluid
MATERIAL SAFETY DATA SHEET
MSDS Number: 16968ET - 0
24 Hour Emergency Assistance: CHEMTEL
(877) 276-7283
General Assistance Number:
(877) 276-7285
-------------------------------------------------------------------------------SECTION 1.
PRODUCT IDENTIFICATION
-------------------------------------------------------------------------------MATERIAL IDENTITY:
Windshield Washer Fluid Concentrate
PRODUCT CODES:
16968
COMPANY ADDRESS: Equilon Enterprises LLC, P. O. Box 4453, Houston, TX. 77210-4453
-------------------------------------------------------------------------------SECTION 2
PRODUCT/INGREDIENTS
-------------------------------------------------------------------------------CAS#
CONCENTRATION
INGREDIENTS
Mixture
100 %weight
Windshield Washer Fluid
67-56-1
95 - 99.99 %weight
Methanol
26038-90-4
<1
%weight
Corrosion Inhibitor
-------------------------------------------------------------------------------SECTION 3
HAZARDS IDENTIFICATION
-------------------------------------------------------------------------------EMERGENCY OVERVIEW
Appearance & Odor: Blue, clear liquid Alcohol odor
Health Hazards: Causes severe eye irritation. Highly toxic and may be fatal if swallowed. May cause skin
irritation. Toxic and harmful if absorbed
through the skin. Toxic and harmful
if
NFPA Rating (Health, Fire, Reactivity):
Hazard Rating:Least - 0
inhaled.
2, 3, 0
Slight -
1
Moderate - 2
High - 3
Extreme - 4
Inhalation:
Toxic and harmful if inhaled.
Eye Irritation:
Severely irritating to the eyes causing pain, redness, swelling and blurred vision.
Skin Contact:
May be irritating to the skin causing a burning sensation, redness and/or swelling. Toxic and is
harmful if absorbed through the skin.
Ingestion:
Highly toxic and may be fatal if swallowed.
This material and/or components may cause the following effects: Developmental
Toxicity
298
Eye, Blood/Blood Forming Organs, Nervous System
For additional health information, refer to section 11.
-------------------------------------------------------------------------------SECTION 4
FIRST AID MEASURES
-------------------------------------------------------------------------------Inhalation:
Move victim to fresh air and provide oxygen if breathing is difficult. Get medical attention. If the victim has
difficulty breathing or tightness of the chest, is dizzy, vomiting or unresponsive, give 100% oxygen with
rescue breathing or CPR as required and transport to the nearest medical facility.
Skin:
Remove contaminated clothing, flush with large amounts of water for at least 15 minutes, by the clock, or
longer depending on the concentration amount and duration of exposure. If redness, swelling, pain and/or
blisters occur, transport to the nearest medical facility for additional treatment.
Eye:
Immediately flush eyes with large amounts of water for at least 30 minutes, by the clock, while holding
eyelids open. Transport to nearest medical facility for additional treatment.
Ingestion:
DO NOT take internally. DO NOT GIVE LIQUIDS TO A DROWSY, CONVULSING OR UNCONSCIOUS
PERSON. Transport to nearest medical facility for additional treatment.
-------------------------------------------------------------------------------SECTION 5
FIRE FIGHTING MEASURES
-------------------------------------------------------------------------------Flash Point [Method]:
Extinguishing
54 ºF/12.22 ºC [ Tagliabue Closed Cup]
Media:
Use water fog, foam, dry
flames. Do not use a
chemical or carbon dioxide (CO2) to
direct
stream of water. Material will
extinguish
float and can be
re-ignited on
surface
of water.
Fire Fighting Instructions:
WARNING! DANGER! EXTREMELY FLAMMABLE. Clear fire area of all non-emergency personnel. Only enter
confined fire space with full bunker gear, including a positive pressure, NIOSH-approved, self-contained
breathing apparatus. Cool surrounding equipment, fire-exposed containers and structures with water.
Container areas exposed to direct flame contact should be cooled with large quantities of water (500
gallons water per minute flame impingement exposure) to prevent weakening of container structure.
-------------------------------------------------------------------------------SECTION 6
ACCIDENTAL RELEASE MEASURES
-------------------------------------------------------------------------------Protective Measures:
DANGER! EXTREMELY FLAMMABLE! HIGHLY TOXIC. Eliminate potential sources of ignition. Handling
equipment must be bonded and grounded to prevent sparking.
299
Wear appropriate personal protective equipment when cleaning up spills. Refer to Section 8. Full protective
clothing and self-contained breathing apparatus.
Spill Management:
Shut off source of leak if safe to do so.
Dike and contain spill.
FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels.
FOR SMALL SPILLS: Soak up residue with an absorbent such as clay, sand or other suitable material. Place
in non-leaking container and seal tightly for proper disposal.
Reporting:
U.S. regulations require reporting releases of this material to the environment which exceed the
reportable quantity to the National Response Center at (800)424-8802.
-------------------------------------------------------------------------------SECTION 7
HANDLING AND STORAGE
-------------------------------------------------------------------------------Precautionary Measures:
Wash with soap and water before eating, drinking, smoking, applying cosmetics, or using toilet. Launder
contaminated clothing before reuse. Properly dispose of contaminated leather articles such as shoes or
belts that cannot be decontaminated. EXTREMELY FLAMMABLE. DANGER! Do not take internally. Do not
taste or swallow. Avoid heat, open flames, including pilot lights, and strong oxidizing agents. Use explosionproof ventilation to prevent vapor accumulation. Ground all handling equipment to prevent sparking. Avoid
contact with eyes, skin and clothing. Wash thoroughly after handling.
Handling:
Surfaces that are sufficiently hot may ignite liquid material.
Air-dry contaminated clothing in a well-ventilated area before laundering.
Storage:
Keep liquid and vapor away from heat, sparks and flame. Extinguish pilot lights, cigarettes and turn off
other sources of ignition prior to use and until all vapors have dissipated. Use explosion-proof ventilation
to prevent vapor accumulation while in use.
Container Warnings:
Keep containers closed when not in use. Containers, even those that have been emptied, can contain
explosive vapors. Do not cut, drill, grind, weld or perform similar operations on or near containers.
-------------------------------------------------------------------------------SECTION 8.
EXPOSURE CONTROLS/PERSONAL PROTECTION
-------------------------------------------------------------------------------Methanol
ACGIH TLV TWA: 200 ppmv
STEL: 250 ppmv
Methanol
OSHA PEL - 1989(revoked)
TWA: 200 ppmv
Notation: Skin
STEL: 250 ppmv
Notation: Skin
EXPOSURE CONTROLS
Adequate ventilation to control airborne concentrations below the exposure guidelines/limits. Eye
washes and showers for emergency use.
300
PERSONAL PROTECTION
Personal protective equipment (PPE) selections vary based on potential exposure conditions such as
handling practices, concentration and ventilation.
Information on the selection of eye, skin and respiratory protection for use with this material is provided
below.
Eye Protection:
Chemical Goggles and Face Shield, or Safety glasses with side shields
Skin Protection:
Use protective clothing which is chemically resistant to this material. Selection of protective clothing
depends on potential exposure conditions and may include gloves, boots, suits and other items. The
selection(s) should take into account such factors as job task, type of exposure and durability
requirements.
Published literature, test data and/or glove and clothing manufacturers indicate the best
protection is provided by:
Neoprene, or Nitrile Rubber
Respiratory Protection:
If engineering controls do not maintain airborne concentrations to a level which is adequate to protect
worker health, an approved respirator must be worn. Respirator selection, use and maintenance should be
in accordance with the requirements of the OSHA Respiratory Protection Standard, 29 CFR 1910.134.
Types of respirator(s) to be considered in the selection process include: For Vapors: Air Purifying, R
or P style prefilter & organic cartridge, NIOSH approved respirator. Self-contained breathing
apparatus.
-------------------------------------------------------------------------------SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
-------------------------------------------------------------------------------Appearance & Odor:
Blue, clear liquid Alcohol odor
Substance Chemical Family:
Alcohol
Appearance:
Blue, clear liquid
Flash Point:
Freezing Point:
pH:
54 ºF [Tagliabue Closed Cup]
-51 ºF
9 - 9.5
Specific Gravity:
Vapor Pressure:
0.896
97 mmHg @ 68 ºF
VOC Content:
99 %weight
-------------------------------------------------------------------------------SECTION 10.
REACTIVITY AND STABILITY
-------------------------------------------------------------------------------Conditions to Avoid:
301
Avoid heat, sparks, open flames and other ignition sources.
Materials to Avoid:
Avoid contact with strong oxidizing agents.
Hazardous Decomposition Products:
Thermal decomposition products are highly dependent on combustion conditions. A complex mixture of
airborne solids, liquids and gases will evolve when this material undergoes pyrolysis or combustion.
Aldehydes, Carbon Monoxide, Carbon Dioxide, Ketones and other unidentified organic compounds may be
formed upon combustion
-------------------------------------------------------------------------------SECTION 11.
TOXICOLOGICAL INFORMATION
------------------------------------------------------------------------------Acute Toxicity
Dermal LDLo
<1 g/kg(Monkey)
Inhalation LCLo
OSHA: Toxic
1000 ppmv(Monkey)
Based
on similar material(s)
OSHA: Toxic
Based on similar
material(s)
Oral LITREF
<1 g/kg(Human)
OSHA: Toxic
Based on similar material(s)
Carcinogenicity Classification
Windshield Washer Fluid
NTP: No IARC: Not Reviewed by IARC
ACGIH: No
OSHA: No
Effects
Toxic
Windshield
Fluid
Developmental Toxicity
Methanol was teratogenic in rats by inhalation at 10,000 and 20,000 ppm, 7 hours/day during gestation.
Only slight maternal toxicity was observed indicating that methyl alcohol was probably a primary teratogen
in the rat under the conditions of exposure. At 5000 ppm exposure, methyl alcohol was not teratogenic.
Eye
May produce damage to the optic nerve, causing visual impairment or blindness.
Blood/Blood Forming Organs
May produce systemic acidosis following ingestion.
Nervous System
May produce CNS depression and coma when ingested at high doses or inhaled at high vapor
concentrations.
-------------------------------------------------------------------------------SECTION 12
ECOLOGICAL INFORMATION
-------------------------------------------------------------------------------Environmental Impact Summary:
There is no ecological data available for this product.
-------------------------------------------------------------------------------SECTION 13
DISPOSAL CONSIDERATIONS
--------------------------------------------------------------------------------
302
RCRA Information:
If this material, as it is originally purchased, were subsequently DISCARDED as a waste, the waste would
be a RCRA hazardous waste.
D001 (Ignitable Hazardous Waste)
Under RCRA, it is the responsibility of the user of the material to determine, at the time of the disposal,
whether the material meets RCRA criteria for hazardous waste. This is because material uses,
transformations, mixtures, processes, etc. may affect the classification. Refer to the latest EPA, state and
local regulations regarding proper disposal.
-------------------------------------------------------------------------------SECTION 14.
TRANSPORT INFORMATION
-------------------------------------------------------------------------------US Department of Transportation Classification
Proper Shipping Name:
Technical Names (s):
Identification Number:
Hazard Class/Division:
Packing Group:
Flammable Liquid, N.O.S.
Methanol
UN1993
3 (Flammable Liquid)
II
Hazardous
Substance/Material
RQ:
Emergency
Response Guide #
128
Methanol / 5005.005 lbs
International Air Transport Association
Hazard Class/Division:
3 (Flammable Liquid)
Indentification Number: UN1992
Packing Group:
II
Proper Shipping Name:
Flammable Liquid, Toxic, N.O.S.
Subsidiary Class:
6.1 (Poisonous Material)
Technical Name(s):
Methanol
International Maritime Organization Classification
Hazard Class/Division:
3.2 (Flammable Liquid)
Indentification Number: UN1992
Packing Group:
II
Proper Shipping Name:
Flammable Liquid, Toxic, N.O.S.
Subsidiary Class:
6.1 (Poisonous Material)
Technical Name(s):
Methanol
-------------------------------------------------------------------------------SECTION 15
REGULATORY INFORMATION
------------------------------------------------------------------------------FEDERAL REGULATORY STATUS
OSHA
Classification:
Product is hazardous according to the OSHA Hazard Communication Standard, 29
303
CFR 1910.1200.
Comprehensive Environmental Release, Compensation & Liability Act (CERCLA):
Methanol
RQ 5000
lbs Reportable Spill =>
5005
lbs
or
with
any
Class
670 gal
Ozone Depleting Substances (40
CFR
This
nor
material does not contain
I or
82 Clean Air Act):
was it directly manufactured
Class II ozone depleting substances.
Superfund Amendment & Reauthorization Act (SARA) Title III:
There are no components in this product on the SARA 302 list.
SARA Hazard Categories (311/312):
Immediate Health:YES
Delayed Health:YES
Pressure:NO
Fire:YES
Reactivity:NO
SARA Toxic Release Inventory (TRI) (313):
Methanol
Toxic Substances Control Act (TSCA) Status:
This material is listed on the EPA/TSCA Inventory of Chemical Substances.
Other Chemical Inventories:
Australian AICS,
EINECS,
Inventory
Canadian DSL,
Korean
Chinese Inventory,
European
State Regulation
The following
chemicals
are specifically listed by
product specific health
and safety data in
other sections
be applicable
requirements. For
details
for state
requirements you should
New Jersey Right-To-Know
Methanol (1222)
Methanol
(1222)
contact the appropriate agency in
95 95 -
Chemical List:
99.99
%weight
99.99
%weight
Pennsylvania Right-To-Know Chemical List:
Methanol
(67-56-1)
95 99.99
%weight
-------------------------------------------------------------------------------SECTION 16
OTHER INFORMATION
individual states; other
of the
MSDS may also
on your regulatory
your state.
Environmental Hazard
Special Hazard
Environmental Hazard
304
------------------------------------------------------------------------------HMIS Rating (Health, Fire, Reactivity): 2, 3, 0
Revision#: 0
Revision Date: 12/14/2000
Revisions since last change (discussion): The Transportation Information - Section 14 of this Material Safety
Data Sheet has been revised as of 12/14/00.
Changes have not been made to the health, safety or precautionary messages. We encourage you to take
the opportunity to reread the sheet and review the information contained.
-------------------------------------------------------------------------------SECTION 17
LABEL INFORMATION
-------------------------------------------------------------------------------READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF
PRODUCT. THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200) FOR USE IN THE WORKPLACE. THIS LABEL
IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED FOR SALE TO CONSUMERS AND
MAY NOT CONFORM WITH THE REQUIREMENTS OF THE CONSUMER PRODUCT SAFETY ACT OR
OTHER RELATED REGULATORY REQUIREMENTS.
PRODUCT CODES:
16968
Windshield Washer Fluid Concentrate
DANGER!
EXTREMELY FLAMMABLE.
MAY BE FATAL IF INHALED.
BE FATAL
IF SWALLOWED.
CAUSES SEVERE EYE IRRITATION.
ABSORBED
THROUGH THE SKIN.
MAY CAUSE SKIN
IRRITATION.
Eye, Blood/Blood Forming Organs, Nervous System
HIGHLY TOXIC AND MAY
TOXIC AND HARMFUL IF
This material and/or components may cause the following effects: Developmental
Toxicity
Precautionary Measures:
Avoid heat, sparks, open flames and other ignition sources. Avoid breathing of vapors, fumes, or mist. Do
not take internally. Use only with adequate ventilation. Avoid contact with eyes, skin and clothing. Keep
container closed when not in use. Wash thoroughly after handling.
FIRST AID
Inhalation: Move victim to fresh air and provide oxygen if breathing is difficult. Get medical attention. DO
NOT attempt to rescue victim unless proper respiratory protection is worn. If the victim has difficulty
breathing or tightness of the chest, is dizzy, vomiting or unresponsive, give 100% oxygen with rescue
breathing or CPR as required and transport to the nearest medical facility.
Skin Contact: Remove contaminated clothing, flush with large amounts of water for at least 15 minutes, by
the clock, or longer depending on the concentration amount and duration of exposure. If redness, swelling,
pain and/or blisters occur, transport to the nearest medical facility for additional treatment.
305
Eye Contact: Immediately flush eyes with large amounts of water for at least 30 minutes, by the clock,
while holding eyelids open. Transport to nearest medical facility for additional treatment.
Ingestion: DO NOT take internally. DO NOT GIVE LIQUIDS TO A DROWSY, CONVULSING OR UNCONSCIOUS
PERSON. Transport to nearest medical facility for additional treatment.
FIRE
In case of fire, Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Do not use a
direct stream of water. Material will float and can be re-ignited on surface of water.
SPILL OR LEAK
Dike and contain spill.
FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels.
FOR SMALL SPILLS: Soak up residue with an absorbent such as clay, sand or other suitable material. Place in
non-leaking container and seal tightly for proper disposal.
CONTAINS: Methanol, 67-56-1; Corrosion Inhibitor, 26038-90-4
NFPA Rating (Health, Fire, Reactivity): 2, 3, 0
HMIS Rating (Health, Fire, Reactivity): 2, 3, 0
TRANSPORTATION
US Department of Transportation Classification
Proper Shipping Name:
Technical Names (s):
Identification Number:
Hazard Class/Division:
Packing Group:
Hazardous Substance/Material
Flammable Liquid, N.O.S.
Methanol
UN1993
3 (Flammable Liquid)
II
RQ:
Methanol / 5005.005 lbs
Emergency Response Guide #
128
Name and Address
Equilon Enterprises LLC
P. O. Box 4453
Houston, TX 77210-4453
TRANSPORTATION EMERGENCY
CHEMTEL
(877) 2767283
HEALTH EMERGENCY
CHEMTEL
(877) 2767283
ADMINISTRATIVE INFORMATION
COMPANY ADDRESS:
Equilon Enterprises LLC, P. O. Box 4453, Houston, TX.
77210-4453
Company Product
Stewardship & Regulatory Compliance Contact: Timothy W Childs
306
Phone Number:
(281) 874-7708
MSDS FAX-BACK Phone Number: (877) 276-7285
THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE TO
US AT THIS TIME, AND IS BELIEVED TO BE ACCURATE BASED UPON THAT DATA. IT IS
PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT, FOR PURPOSE OF HAZARD
COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE PRODUCT PERFORMANCE
INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE WITH
RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED HEREIN.
YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY, PROCESS, USE OR
DISTRIBUTE, AND ARE ENCOURAGED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH
SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN.
TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT
TO THE PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE APPROPRIATE
GOVERNMENT AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH MATTERS, OR BE
RESPONSIBLE FOR ANY INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. THE
UNDERLYING DATA, AND THE INFORMATION PROVIDED HEREIN AS A RESULT OF THAT DATA,
IS THE PROPERTY OF EQUIVA SERVICES LLC AND IS NOT TO BE THE SUBJECT OF SALE OR
EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF EQUIVA SERVICES LLC.
35720-24876-100R-11/26/2001
307
Xylene
308
309
310
311
312
313
314
315
316
317
318
319
Yellow 77
Document # 6810-009
Flammability
0
Reactiv
ity
Health
1
0
HMIS Rating
WHMIS Hazard
Class: Non-Hazardous
MATERIAL SAFETY DATA SHEET
GENERAL INFORMATION
CATALOG
PRODUCT NAME OR NUMBER (as it appears on label)
NUMBER
®
YELLOW 77 Wire Pulling Lubricant
All “31” Series
MANUFACTURER’S
EMERGENCY
NAME
TELEPHONE NO.
IDEAL INDUSTRIES, INC.
(815) 895-5181
ADDRESS (Number, Street, City, State, Zip Code)
Becker Place, Sycamore, IL 60178
HAZARDOUS MATERIAL DESCRIPTION, PROPER SHIPPING NAME, HAZARD CLASS, HAZARD CLASS,
HAZARD ID NO. (49 CFR 172.101)
None
CHEMICAL
DESCRIPTION
FORMULA
Water-Wax
Proprietary
Emulsion
SECTION I - INGREDIENTS
Listed as a
carcinogen
CAS
REGISTRY
in NTP, I ARC or
%W
CHEMICAL NAME(S)*
NO.
OSHA
1910(z)
(specify)
7732-18-5
<90
Water
No
64742-43-4
<5
Paraffin Wax
No
8009-03-8
<3
Petrolatum
No
64742-53-6
<3
Napthenic Mineral Oil (See *A)
No
9005-08-7
<4
Polyethylene Glycol Ester
No
61791-44-4
<1
Ethoxylated Tallow Amine
No
25265-71-8
<0.1 Perfume
No
8042-47-5
<1
Acrylamide Sodium Acrylate Copolymer
No
24838-91-8
52-51-7
6358-31-2
BOILING
POINT
SOLUBILITY
WATER
<0.1
<0.1
212°F
IN
100°C
with Trideceth-6
Antimicrobial Agent
Yellow Pigment
SECTION II - PHYSICAL DATA
SPECIFIC GRAVITY
(H2O=1)
0.98
pH =
No
No
PERCENT VOLATILE
VOLUME (%)
PERCENT
BY
SOLID
BY
<90
~20
320
APPEARANCE
ODOR
FLASH
POINT
WEIGHT (%)
IS
MATERIAL:
SOLID GEL
LIQUID
GA
POWDE
Yellow paste, slight perfume odor
PASTE R
S
SECTION III - FIRE AND EXPLOSION HAZARD DATA
FLAMMABLE
LIMITS
method used C.O.C
LEL
UEL
None
None
Moderate
AND
None
EXTINGUISHING
MEDIA
7.0 - 8.5
Use extinguishing media suitable for surrounding materials.
SPECIAL FIRE FIGHTING PROCEDURES
Self-contained respiratory protection should be provided for fire fighters. Keep fire
exposed
containers cool with water.
UNUSUAL FIRE AND EXPLOSION HAZARDS
None
* None of the chemical raw materials contained in this formulation are considered hazardous under the Federal
Hazards Communication Standard 29 C. F. R 1910.1200
*A Oil is Severely hydrotreated with a polymorphonuclear content at less than 0.1% and meets OSHA
29 C.F.R. 1910.1200.
SECTION IV - HEALTH HAZARD INFORMATION
EFFECTS OF OVEREXPOSURE - Conditions to Avoid
None normally expected. Upon prolonged contact, may cause temporary
eye
discomfort.
THRESHOLD LIMIT VALUE
N.E.
PRIMARY ROUTES OF ENTRY Skin
Other
Inhalation
Contact
(specify)
EMERGENCY FIRST AID PROCEDURES
SKIN CONTACT:
Wash with soap and water for 15 minutes.
EYE CONTACT:
Flush with water for 15 minutes. Inhalation - Move to fresh air.
INGESTION:
Induce vomiting. Consult physician or local poison control center.
SECTION V - REACTIVITY DATA
UNSTABLE
CONDITIONS TO AVOID
STABILITY
None
STABLE
X
INCOMPATI (materials to
BILITY
avoid)
Avoid strong oxidizers.
HAZARDOUS DECOMPOSTION PRODUCTS:
Excessive heat and burning may release oxides of carbon and nitrogen
MAY OCCUR
CONDITIONS TO AVOID
HAZARDOUS
None
POLYMERIZA
WILL NOT
TION
X
OCCUR
321
SECTION VI - SPILL AND LEAK PROCEDURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Wipe up, shovel or vacuum spilled material. Clean up spills immediately as they can be dangerously
slippery.
WASTE DISPOSAL METHOD
Comply with Federal, state and local regulations for solid landfill.
CERCLA (Superfund) REPORTABLE QUANTITY (in lbs)
None Required
RCRA HAZARDOUS WASTE NO. (40CFR
261.33)
None Required
VOLATILE ORGANIC COMPOUND (VOC) (as
packaged, minus water)
2.7 gms. / ltr
³
³
Theoret
Analyti
lb/gal
ical
cal
N/A
lb/gal
N/A
SECTION VII - PERSONAL PROTECTION INFORMATION
RESPIRATORY PROTECTION (specify type)
None normally required.
LOCAL
EXHAUST
None
SPECIAL None
(Specify Rate)
VENTILATI
ON
MECHANICAL (General) (Specify Rate)
OTHER None
Recommended in closed
areas.
PROTECTIVE GLOVES (specify EYE
PROTECTION
type)
(specify type)
None normally needed Safety glasses or splash goggles.
Neoprene if necessary
OTHER PROTECTIVE EQUIPMENT
Eye fountain in work area is recommended.
SECTION VIII - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Store at temperatures between 40 - 120° F. Avoid freezing.
OTHER PRECAUTIONS
Keep away from children, infants and pets.
SECTION IX - ADDITIONAL INFORMATION
If material is used in extreme heat (>120° F), prolonged and repeated exposure could pose a risk
of pulmonary disease. Exposure below mist TLV (5mg/m) appears to be without risk.
All components used in this product are exempt from the T.O.S.C.A chapter 15 reporting requirements.
N/A = Not Applicable, N.E. = None Established
THIS MATERIAL SAFETY DATA SHEET PREPARED BY:
NAME
TITLE
DATE
James R. MacMurdo
Director, Corporate Quality Assurance
02/11/09
SIGNATURE
322
Zep 45
Zep, Inc.
1310 Seaboard Industrial Blvd. Atlanta, GA 30318 1-877-I-BUY-ZEP (428-9937) www.zep.co
Section 1. Chemical Product and Company Identification
Product name
ZEP 45
Product use
Aerosol Lubricant
Product code
Date of issue
0174
09/16/11
Supersedes 03/19/09
Emergency Telephone Numbers
For MSDS Information:
Compliance Services 1-877-I-BUY-ZEP (428-9937)
For Medical Emergency
(877) 541-2016 Toll Free - All Calls Recorded
For Transportation Emergency
CHEMTREC: (800) 424-9300 - All Calls Recorded
In the District of Columbia (202) 483-7616
Prepared By
Compliance Services
1420 Seaboard Industrial Blvd.
Atlanta, GA 30318
Section 2. Hazards Identification
Emergency overview
Hazard Determination System (HDS): Health, Flammability, Reactivity
WARNING!
2
1
0
VAPOR HARMFUL. CAUSES EYE, SKIN AND RESPIRATORY
TRACT IRRITATION. HARMFUL IF INHALED OR ABSORBED
THROUGH SKIN. CONTENTS UNDER PRESSURE.
NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse effects
are lessened by following all prescribed safety precautions, including the use of proper personal protective
equipment.
Acute Effects
Eyes
Skin
Inhalation
Ingestion
Routes of Entry
Dermal contact. Eye contact. Inhalation.
Causes eye irritation. Inflammation of the eye is characterized by redness, watering and
itching.
Causes skin irritation. Skin inflammation is characterized by itching, scaling, reddening or,
occasionally, blistering.
Avoid inhalation of vapor, spray or mist. Over-exposure by inhalation may cause respiratory
irritation. Can cause central nervous system (CNS) depression. Symptoms and signs include
headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of
consciousness.
Aspiration hazard if swallowed. Can enter lungs and cause damage.
Chronic effects Repeated or prolonged exposure to the substance can produce damage to central
nervous system, peripheral nervous system, kidneys, liver and heart. May cause
hearing impairment or change. Prolonged skin contact may cause dermatitis
with drying and cracking of skin.
Carcinogenicity
Trichloroethylene: Classified + (Proven) by OSHA. Classified Group 2A
(Probable for Human) by IARC. Group 2 (Reasonably Anticipated To Be Human
Carcinogen) by NTP.
323
Product/ingredient name
Trichloroethylene
Tetrachloroethylene
ACGIH
IARC
EPA
NIOSH
2A
2A
Additional Information: See Toxicological Information
(Section 11)
Section 3. Composition/Information on Ingredients
Name
of
Hazardous
Ingredients
TRICHLOROETHYLENE; acetylene trichloride; 1-chloro-2,2-dichloroethylene
PARAFFIN OIL; blend of heavy and light naphthenic petroleum
distillate
MINERAL SEAL OIL; mineral oil; petrolatum
TETRACHLOROETHYLENE; perchloroethylene; perc; carbon bichloride
Calcium alkylnaphthalenesulfonate
DIETHYLENE GLYCOL MONOBUTYL ETHER; 2-(2-butoxyethoxy)-ethanol; butyl carbitol
PRIMARY AMYL ACETATE, MIXED ISOMERS: 3-METHYL BUTYL ACETATE; 2METHYL BUTYL ACETATE
CARBON DIOXIDE
NTP
OSHA
Possible
+
Possible
-
CAS number
79-01-6
% by Weight
40 - 50
64742-52-5
64741-44-2
127-18-4
Proprietary
112-34-5
123-92-2: 628-637
& 624-41-9
124-38-9
15 - 25
5 - 15
1 - 10
1 - 10
1 - 10
<5
<5
Section 4. First Aid Measures
Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the
upper and lower eyelids. Check for and remove any contact lenses. Get medical attention
immediately.
Skin Contact Wash affected area with soap or mild detergent and water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Wash clothing before reuse. Get medical
attention if irritation develops.
Inhalation
Ingestion
Move exposed person to fresh air. If not breathing, give artificial respiration. If breathing
is difficult, give oxygen. Get medical attention immediately.
Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low
so that vomit does not enter the lungs. Never give anything by mouth to an unconscious
person. Get medical attention immediately.
National Fire Protection
Association (U.S.A.)
Section 5. Fire Fighting Measures
1
Flash Point
Flammable Limits
Not applicable.
Not applicable.
2 0
Flammability
Fire hazard
Non-flammable. (CSMA)
CONTENTS UNDER PRESSURE. Container explosion may occur under fire conditions or
when heated. Vapors may accumulate in low or confined areas or travel a considerable
distance
to a source of ignition and flash back.
Fire-Fighting Use dry chemical or CO2. Cool closed containers exposed to fire with water. Wear
special Procedures protective clothing and positive pressure, self-contained breathing
apparatus.
Section 6. Accidental Release Measures
324
Spill Clean up
Large spills are unlikely due to packaging.
Section 7. Handling and Storage
Handling
Storage
Put on appropriate personal protective equipment (see section 8). Avoid contact with eyes, skin
and clothing. Do not breathe vapor or mist. Use only with adequate ventilation. Watch for
accumulation in low confined areas.
Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible
materials (see section 10) and food and drink. Keep away from heat, sparks and flame. Do not
puncture or incinerate container. Do not store above the following temperature: 49°C (120.2°F).
Keep out of the reach of children.
Section 8. Exposure Controls/Personal Protection
Product name
Exposure limits
TRICHLOROETHYLENE; acetylene trichloride; 1-chloro-2,2ACGIH TLV (United States).
dichloroethylene
TWA: 10 ppm 8 hour(s).
STEL: 25 ppm 15 minute(s).
OSHA PEL (United States).
TWA: 50 ppm 8 hour(s).
STEL: 200 ppm 15 minute(s).
PARAFFIN OIL; blend of heavy and light naphthenic petroleum
OSHA PEL (United States).
distillate
TWA: 5 mg/m³ 8 hour(s). Form: Mist
ACGIH TLV (United States).
TWA: 5 mg/m³ 8 hour(s). Form: Mist
NIOSH REL (United States, 6/2009).
TWA: 5 mg/m³ 10 hour(s). Form: Mist
STEL: 10 mg/m³ 15 minute(s). Form: Mist
MINERAL SEAL OIL; mineral oil; petrolatum
OSHA PEL (United States).
: 5 mg/m³ 8 hour(s). Form: Mist
ACGIH TLV (United States).
: 5 ppm 8 hour(s). Form: Mist
TETRACHLOROETHYLENE; perchloroethylene; perc; carbon ACGIH TLV (United States).
bichloride
TWA: 25 ppm 8 hour(s).
STEL: 100 ppm 15 minute(s).
PRIMARY AMYL ACETATE, MIXED ISOMERS: 3-METHYL
OSHA PEL (United States).
BUTYL ACETATE; 2-METHYL BUTYL ACETATE
TWA: 100 ppm 8 hour(s).
ACGIH TLV (United States).
TWA: 50 ppm 8 hour(s).
STEL: 100 ppm 15 minute(s).
CARBON DIOXIDE
ACGIH TLV (United States).
TWA: 5000 ppm 8 hour(s).
STEL: 30000 ppm 15 minute(s).
Personal Protective Equipment (PPE)
Eyes
Recommended: Safety glasses.
Body
Recommended: Chemical-resistant gloves. Viton
Respiratory Use with adequate ventilation. Provide exhaust ventilation or
other engineering controls to keep the airborne concentrations
of vapors below their respective occupational exposure limits.
Use a properly fitted, air-purifying or air-fed respirator complying
325
with an approved standard if a risk assessment indicates this is
necessary.
Section 9. Physical and Chemical Properties
Physical State
pH
Boiling Point
Specific Gravity
Solubility
Liquid. [Aerosol.]
Not available.
87.22°C (189°F)
1.137
Insoluble in the following materials: cold water
and
hot water.
Color Brown. Oily liquid.
Odor Sweet. [Strong]
Vapor Pressure Not available.
Vapor Density Not available.
Evaporation Rate <1 (Carbon tetrachloride = 1)
VOC (Consumer) 50.0% or 568.5 g/l [ISO 11890-1]
Section 10. Stability and Reactivity
Stability and Reactivity
The product is stable.
Reactive or incompatible with the following materials: oxidizing materials, metals and
Incompatibility
alkalis.
Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Hazardous Decomposition Products
Carbon dioxide, carbon monoxide, Hydrogen chloride (HCl), Chlorine and
Phosgene gas.
Section 11. Toxicological Information
Acute Toxicity
Product/ingredient name
Trichloroethylene
Result
LD50 Dermal
LD50 Oral
LD50 Oral
Distillates
(petroleum),
LC50 Inhalation Vapor
straightrun middle
Tetrachloroethylene
LD50 Dermal
LD50 Oral
Diethylene glycol monobutyl LD50 Dermal
ether
LD50 Dermal
LD50 Oral
LD50 Oral
LD50 Oral
Species
Rabbit
Mouse
Rat
Dose
10000 mg/kg
2402 mg/kg
4920 mg/kg
Exposure
-
Rat
1700 mg/m3
4 hours
Rabbit
Rat
Rabbit
10000 mg/kg
2629 mg/kg
2700 mg/kg
-
Rabbit
Mouse
Rat
Rat
2700 mg/kg
2400 mg/kg
4500 mg/kg
5660 mg/kg
-
Section 12. Ecological Information
Environmental Effects
Not available.
Aquatic Ecotoxicity
Product/ingredient name
Test
Diethylene glycol monobutyl
ether
Result
Species
Exposure
Acute
LC50
Fish
Inland
96 hours
2000000
silverside ug/L
Marine
Menidia beryllina water
40 to
100 mm
96 hours
326
Acute
LC50
1300000
ug/L
Fresh
water
-
Fish - Bluegill Lepomis
macrochirus - 33 to
75
mm
Section 13. Disposal Considerations
Waste Information
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Consult your local or regional authorities for additional information.
Waste Stream Code: D040
Classification: - [Hazardous waste.]
Origin: - [RCRA waste.]
Section 14. Transport Information
Regulatory
information
UN number
Proper shipping name
Classes
DOT Classification
None.
Consumer commodity
ORM-D
ORM-D
IMDG Class
Not
determined.
Not available.
PG*
Label
-
Not available.
NOTE: DOT classification applies to most package sizes. For specific container size classifications or for
size exceptions, refer to the Bill of Lading with your shipment.
PG* : Packing group
Section 15. Regulatory Information
U.S. Federal Regulations
SARA 313 toxic chemical notification and release reporting:
Product name
Trichloroethylene
Tetrachloroethylene
Diethylene glycol monobutyl ether
Clean Water Act (CWA) 307: Trichloroethylene (RQ
100
lbs.)
Clean
Water
Act
(CWA)
311:
Trichloroethylene (RQ 100 lbs.)
Clean Air Act (CAA) 112 regulated toxic substances: Trichloroethylene;
Tetrachloroethylene; Diethylene glycol monobutyl ether
All Components of this product are listed or exempt from listing on TSCA Inventory.
TSCA 8(a) IUR: Distillates (petroleum), hydrotreated heavy naphthenic; Distillates
(petroleum), straight-run middle
United States inventory (TSCA 8b): Not determined.
State Regulations
327
California Prop 65 WARNING: This product contains a chemical or chemicals known to the
state of California to cause cancer, birth defects or other
reproductive harm.: Trichloroethylene; Tetrachloroethylene
Section 16. Other Information
To the best of our knowledge, the information contained herein is accurate. However, neither the above named
supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
*NOTE: Hazard Determination System (HDS) ratings are based on a 0-4 rating scale, with 0
representing minimal hazards or risks, and 4 representing significant hazards or risks Although
these ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to
provide them. HDS ratings are to be used with a fully implemented program to relay the
meanings of this scale.
328
Zep Clean 'Ems
ZEP MANUFACTURING COMPANY
Acuity Specialty Products Group, Inc. P.O. BOX 2015
ATLANTA, GA 30301
1- 877- I - BUY- ZEP
Material Safety Data Sheet
and Safe Handling and Disposal Information
Issue Date
Supersedes
Product Name
11/01/95
05/03/95
ZEP CLEAN 'EMS
Product No.
1000
Hand
Cleaning
Towel
SECTION I - EMERGENCY CONTACTS
For MSDS Information:
Acuity Specialy Products Group, Inc.
Compliance Services 1-877-I-BUY-ZEP
For Medical Emergency:
INFOTRAC
(877) 541-2016 Toll Free - All Calls Recorded
For a Transportation Emergency:
CHEMTREC
(800) 424-9300 - All Calls Recorded
In the District of Columbia (202) 483-7616
SECTION II - HAZARDOUS INGREDIENTS
** D-LIMONENE ** orange distillate; citrus terpene; cyclohexene, 1-methyl-4-(1-methylethenyl)-, (R)-;
CAS# 5989-27-5; RTECS# GW6360000; OSHA PEL N/D; TLV - N/D; EFFECTS - CBL SEN; % IN PROD - < 5
@ -Reportable under the SARA 313 Toxic Release Inventory
SECTION III - HEALTH HAZARD DATA
SPECIAL NOTE: MSDS data pertains to the product as dispensed from the container. Adverse health effects
would not be expected under recommended conditions of use (diluted) so long as prescribed safety precautions
are practiced.
ACUTE EFFECTS OF OVEREXPOSURE:
This product can be an eye irritant. Inflammation of eye tissue is characterized by redness, watering, and/or
itching. One of the ingredients in this product has caused sensitization reactions in a small percentage of the
general population.
CHRONIC EFFECTS OF OVEREXPOSURE:
There are no known effects from chronic exposure to this product. None of the ingredients are listed as
carcinogens by IARC, NTP, or OSHA.
EST'D PEL/TLV: Not established
PRIMARY ROUTES OF ENTRY: N/A
HMIS CODES: HEALTH 0; FLAM 0; REACT 0; PERS. PROTECT N/A; CHRONIC HAZ NO
FIRST AID PROCEDURES:
329
SKIN: This product is formulated for use on skin. If irritation occurs, wash skin with soap and water. Get medical
attention if irritation persists. EYES: Immediately flush eyes with plenty of water for at least 15 minutes. If irritation
develops, consult a physician.
INHALE: This route of exposure is not likely due to
product nature. INGEST: This route of exposure is
not likely due to product nature.
SECTION III - HEALTH HAZARD DATA
SPECIAL NOTE: MSDS data pertains to the product as dispensed from the container. Adverse health effects
would not be expected under recommended conditions of use (diluted) so long as prescribed safety precautions
are practiced.
ACUTE EFFECTS OF OVEREXPOSURE:
This product can be an eye irritant. Inflammation of eye tissue is characterized by redness, watering, and/or
itching. One of the ingredients in this product has caused sensitization reactions in a small percentage of the
general population.
CHRONIC EFFECTS OF OVEREXPOSURE:
There are no known effects from chronic exposure to this product. None of the ingredients are listed as
carcinogens by IARC, NTP, or OSHA.
EST'D PEL/TLV: Not established
PRIMARY ROUTES OF ENTRY: N/A
HMIS CODES: HEALTH 0; FLAM 0; REACT 0; PERS. PROTECT N/A; CHRONIC HAZ NO
FIRST AID PROCEDURES:
SKIN: This product is formulated for use on skin. If irritation occurs, wash skin with soap and water. Get medical
attention if irritation persists. EYES: Immediately flush eyes with plenty of water for at least 15 minutes. If irritation
develops, consult a physician.
INHALE: This route of exposure is not likely due to
product nature. INGEST: This route of exposure is
not likely due to product nature.
SECTION V - PHYSICAL DATA
SPECIFIC GRAVITY EVAPORATION RATE (
pH(CONCENTRATE) - N/A
BOILING POINT (F) - N/A
VAPOR PRESSURE(mmHg) - N/A
=1) - N/A
VAPOR DENSITY(AIR-1) - N/A
SOLUBILITY IN WATER - N/A
pH(USE DILUTION OF) - N/A
VOC CONTENT (CONCENTRATE) - 3.3%
APPERANCE AND ODOR - AN ORANGE TOWEL WITH AN ORANGE FRAGRANCE.
SECTION VI - FIRE AND EXPLOSION DATA
FLASH POINT(F) (METHOD USED): N/A
FLAMMABLE LIMITS:LEL: N/A UEL: N/A
EXTINGUISHING MEDIA: Carbon dioxide, dry chemical and foam.
SPECIAL FIRE FIGHTING: None
UNUSUAL FIRE HAZARDS: Potential fire hazard if exposed to an ignition source.
SECTION VII - REACTIVITY DATA
STABILITY: Stable
INCOMPATIBILITY(AVOID): Heat, flame, spark, strong acids
and/or oxidizers. POLYMERIZATION: Will not occur.
HAZARDOUS DECOMPOSITION: Carbon dioxide, carbon monoxide, and other unidentified organic compounds.
SECTION VIII - SPILL AND DISPOSAL PROCEDURES
330
STEPS TO BE TAKEN IN CASE MATERIALS IS RELEASED OR SPILLED:
Observe safety precautions in sections 4 & 9 during clean-up. Spills are not expected due to the nature of the
product. If material is dropped or contaminated, pick up and place in a suitable waste container. Wash area with a
detergent solution and rinse well with water.
WASTE DISPOSAL METHOD:
This product is not considered a hazardous waste under RCRA. Place used product in an appropriate waste
container. Care should be taken to prevent contact with all ignition sources.
RCRA HAZ WASTE NOS: N/A
SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN WHEN HANDLING AND STORING
Store tightly closed container in a dry area at temps. between 40-120 degrees F. Keep product out of eyes. Keep
out of the reach of children.
SECTION X - REGULATORY INFORMATION
DOT PROPER SHIPPING NAME: INDUSTRIAL CLEANERS N.O.I.,LIQUID KEEP FROM
FREEZING
NOTE: DOT information applies to larger package sizes of affected products. For some products, DOT may
require alternate names and labeling in accordance with packaging group requirements.
DOT HAZARD CLASS: NA
DOT PACKING GROUP:
DOT I.D. NUMBER:
DOT LABEL/PLACARD:
EPA TSCA CHEMICAL INVENTORY - ALL INGREDIENTS ARE LISTED
EPA CWA 40CFR PART 117 SUBSTANCE(RQ IN A SINGLE CONTAINER): NONE
EPA CAA: N/A
MATERIAL SAFETY DATA SHEET
NOTICE
Thank you for your interest in, and use of, this product. Acuity Specialty Prod-ucts Group is pleased to be of
service to you by supplying this Material Safety Data Sheet for your files. Acuity Specialty Products Group is
concerned for your health and safety. This product and all others supplied by Acuity Specialty Products Group
companies can be used safely with proper protective equipment and proper handling practices consistent with
label instructions and the MSDS. Before using any this product, be sure to read the complete label and the
Material Safety Data Sheet.
As a further word of caution, Acuity Specialty Products Group wishes to advise that serious accidents have resulted
from the misuse of “emptied” containers. “Empty” containers retain residue (liquid and/or vapor) and can be
dangerous. DO NOT pressurize, cut, weld, braze, solder, drill, grind or expose such con - tainers to heat, flame,
sparks, or other sources of ignition; they may explode or develop harmful vapors and possibly cause injury or
death. Clean empty con-tainers by triple rinsing with water or an appropriate solvent. Empty containers must be
sent to a drum reconditioner before reuse.
TERMS AND ABBREVIATIONS
Listed Alphabetically by Section
SECTION II: HAZARDOUS INGREDIENTS
CAR: Carcinogen - A chemical listed by the National Toxicology Program (NTP), the International Agency for
Research on Cancer (IARC) or OSHA as a definite or possible human cancer causing agent.
CAS#: Chemical Abstract Services Registry Number - A universally accepted numbering system for chemical
substances.
CBL: Combustible - At temperatures between 100°F and 200°F chemical gives off enough vapor to ignite if a source
of ignition is present as tested with a closed cup tester.
CNS: Central Nervous System depressant that reduces the activity of the brain and spinal cord.
COR: Corrosive - Causes irreversible injury to living tissue (e.g. burns). DESIGNATIONS: Chemical and common
names of hazardous ingredients. EIR: Eye Irritant Only - Causes reversible reddening and/or inflammation of eye
tis-sues.
331
EXPOSURE LIMITS: The time weighted average (TWA) airborne concentra-tion at which most workers can be
exposed without any expected adverse ef-fects. Primary sources include ACGIH TLVs, and OSHA PELs.
ACGIH: American Conference of Governmental Industrial Hygienists CEILING: "The concentration that should not
be exceeded in the workplace during any part of the working exposure." Source, ACGIH
OSHA: Occupational Safety and Health Administration.
PEL: Permissible Exposure Limit - A set of time weighted average exposure values, established by OSHA, for a
normal 8-hour day and a 40-hour work-week.
PPM: Parts per million - unit of measure for exposure limits.
(S) SKIN: Skin contact with substance can contribute to overall exposure. STEL: Short Term Exposure Limit Maximum concentration for a continu-ous 15-minute exposure period.
TLV: Threshold Limit Value - A set of time weighted average exposure lim-its, established by the ACGIH, for a
normal 8-hour day and a 40-hour work-week.
FBL: Flammable - At temperatures under 100°F, chemical gives off enough va-pors to ignite if a source of ignition is
present as tested with a closed cup tester. HAZARDOUS INGREDIENTS: Chemical substances that are determined
to be potential health or physical hazards based on the criteria established in the OSHA Hazard Communication
Standard - 29 CFR 1910.1200
HTX: Highly toxic - the probable lethal dose for a 70 kg (150 lb.) man, which may be approximated as less than 6
teaspoons (2 tablespoons)
IRR: Irritant - Causes reversible effects in living tissues (e.g. inflammation) - primarily skin and eyes.
N/A: Not Applicable - Category is not appropriate for this product.
N/D: Not Determined - Insufficient information to make a determination for this item.
RTECS#: Registry of Toxic Effects of Chemical Substances - an unreviewed listing of published toxicology data on
chemical substances.
SARA: Superfund Amendment and Reauthorization Act - Section 313 designates certain chemicals for possible
reporting for the Toxic Chemical Release Inventory. SEN: Sensitizer - Causes allergic reaction after repeated
exposure.
TOX: Toxic - The probable lethal dose for a 70 kg (150 kg) man is one ounce (2 tablespoons) or more.
SECTION III: HEALTH HAZARD DATA
ACUTE EFFECT: An adverse effect on the human body from a single expo-sure with symptoms developing almost
immediately after exposure or within a relatively short time.
CHRONIC EFFECT: Adverse effects that are most likely to occur from re-peated exposure over a long period of
time.
EST'D PEL/TLV: This estimated, time -weighted-average, exposure limit, de-veloped by using a formula provided
by the ACGIH, pertains to airborne con - centrations from the product as a whole. This value should serve as guide
for providing safe workplace conditions to nearly all workers.
HMIS CODES: Hazardous Material Identification System - a rating system developed, by the National Paint and
Coating Association for estimating the hazard potential of a chemical under normal workplace conditions. These
risk estimates are indicated by a numerical rating given in each of three hazard areas (Health/
Flammability/Reactivity) ranging from a low of zero to a high of 4. The presence of a chronic hazard is indicated by
a "YES". Consult HMIS train-ing guides for Personal Protection letter codes, which indicate necessary protec-tive
equipment.
PRIMARY ROUTE OF ENTRY: The way one or more hazardous ingredients may enter the body and cause a
generalized systemic or specific-organ toxic effect. ING: Ingestion - A primary route of exposure through
swallowing of material.
INH: Inhalation - A primary route of exposure through breathing of vapors. SKIN: A primary route of exposure
through contact with the skin.
SECTION IV: SPECIAL PROTECTION INFORMATION
Where respiratory protection is recommended, use only MSHA and NIOSH ap-proved respirators and dust masks.
MSHA: Mine Safety and Health Administration
NIOSH: National Institute for Occupational Safety and Health.
SECTION V: PHYSICAL DATA
332
EVAPORATION RATE: Refers to the rate of change from the liquid state to the vapor state at ambient
temperature and pressure in comparison to a given substance (e.g. water).
pH: A value representing the acidity or alkalinity of an aqueous solution (Highly Acidic pH = 1; Neutral pH = 7;
Highly Alkaline pH = 14)
VOC CONTENT: The percentage or amount in pounds per gallon of the prod-uct that is regulated as a Volatile
Organic Compound under the Clean Air Act of 1990 and various state jurisdictions.
SOLUBILITY IN WATER: A description of the ability of the product to dis-solve in water.
SECTION VII: REACTIVITY DATA
HAZARDOUS DECOMPOSITION: Breakdown products expected to be produced upon product decomposition by
extreme heat or fire. INCOMPATIBILITY: Keep product away from listed substances or condi-tions to prevent
hazardous reactions.
POLYMERIZATION: Indicates the tendency of the product's molecules to com-bine with themselves in a chemical
reaction releasing excess pressure and heat. STABILITY: Indicates the susceptibility of the product to decompose
sponta-neously and dangerously.
SECTION VIII: SPILL AND DISPOSAL PROCEDURES
RCRA WASTE NOs: RCRA (Resource Conservation and Recovery Act) waste codes (40 CFR 261) applicable to
the disposal of spilled or unusable product from the original container.
SECTION X: TRANSPORTATION DATA
CWA: Clean Water Act - Federal law that regulates chemical releases to bodies of water.
RQ: Reportable Quantity - The amount of the specific ingredient that, when spilled to the ground and, can enter a
storm sewer or natural watershed, must be reported to the National Response Center, and other regulatory
agencies. TSCA: Toxic Substances Control Act - A federal law requiring all commercial chemical substances to
appear on an inventory maintained by the EPA.
DISCLAIMER
All statements, technical information, and recommendations contained herein are based on available scientific
tests or data that we believe to be reliable. The accuracy and completeness of such data are not warranted or
guaranteed. We cannot anticipate all conditions under which this information and our products, or the products
of other manufacturers in combination with our products, may be used. Acuity Specialty Products Group assumes
no liability or responsibility for loss or damage resulting from the improper use or handling of our products, from
incompatible product combinations, or from the failure to follow instruc-tions, warnings, and advisories in the
product label and Material Safety Data Sheet
(rev 06/02)
333
Zep Drill Chill
Safety Data Sheet
Zep, Inc.
1310 Seaboard Industrial Blvd.
Atlanta, GA 30318
1-877-I-BUY-ZEP (428-9937)
www.zep.com
Section 1. Chemical Product and Company Identification
Product name
LUBEZE DRILL CHILL
Product use
Aerosol Cutting Oil
Product code
0045
Date of issue
10/03/13
Supersedes
09/29/10
Emergency Telephone Numbers
For MSDS Information:
Compliance Services 1-877-I-BUY-ZEP (428-9937)
For Medical Emergency
(877) 541-2016 Toll Free - All Calls Recorded
For Transportation Emergency
CHEMTREC: (800) 424-9300 - All Calls Recorded
In the District of Columbia (202) 483-7616
Prepared By
Compliance Services
1420 Seaboard Industrial
Blvd.
Atlanta, GA 30318
Section 2. Hazards Identification
Emergency overview
*Hazard Determination System (HDS): Health, Flammability, Reactivity
WARNING!
1
1
0
CAUSES EYE IRRITATION. CONTENTS UNDER PRESSURE.
NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse
effects are lessened by following all prescribed safety precautions, including the use of proper personal
protective equipment.
Acute Effects
Routes of Entry
Dermal contact. Eye contact. Inhalation.
Causes eye irritation. Inflammation of the eye is characterized by redness, watering and
Eyes
itching.
May cause skin irritation. Skin inflammation is characterized by itching, scaling, or
Skin
reddening.
Inhalation Inhalation of oil mist or vapors at elevated temperatures may cause respiratory irritation.
Unlikely in this form. May be harmful if swallowed. Ingestion may cause severe gastric
Ingestion disturbances.
Chronic effects Contains material which may cause damage to the following organs: lungs,
cardiovascular system, upper respiratory tract, skin, eyes, central nervous
system (CNS). Prolonged or repeated contact may dry skin and cause
334
irritation. Repeated or prolonged exposure to spray mist may produce
respiratory tract irritation leading to frequent attacks of bronchial infection.
Carcinogenicity
No known significant effects or critical hazards.
Product/ingredient name
Not available.
Additional Information: See Toxicological Information (Section 11)
Section 3. Composition/Information on Ingredients
Name of Hazardous Ingredients
Distillates (petroleum), hydrotreated heavy naphthenic
Carbon dioxide
CAS number
64742-52-5
124-38-9
% by Weight
85 - 95
5 - 15
Section 4. First Aid Measures
Eye Contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention immediately.
Skin Contact Flush affected skin with plenty of water. Remove contaminated clothing and shoes. Wash
clothing before reuse. Get medical attention if irritation develops.
Inhalation
Move exposed person to fresh air. If irritation persists, get medical attention.
Ingestion
Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be kept
low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. Get medical attention immediately.
National Fire Protection
Association (U.S.A.)
Section 5. Fire Fighting Measures
1
Flash Point
Flammable Limits
Not available.
Not available.
Flammability
Non-flammable. (CSMA)
CONTENTS UNDER PRESSURE. In a fire or if heated, a pressure increase will occur and the container
may
burst. Bursting aerosol containers may be propelled from a fire at high speed.
Use an extinguishing agent suitable for the surrounding fire.
Fire hazard
Fire-Fighting
Procedures
1 0
Section 6. Accidental Release Measures
Spill Clean up
Spills are unlikely due to packaging.
Section 7. Handling and Storage
Handling
Put on appropriate personal protective equipment (see Section 8). Avoid contact with eyes, skin and
clothing. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Empty
containers retain product residue and can be hazardous. Wash thoroughly after handling.
Storage
CONTENTS UNDER PRESSURE. Store away from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Do not puncture,
335
incinerate or store the container at temperatures above 49°C (120°F) or in direct sunlight. Keep
out of the reach of children.
Section 8. Exposure Controls/Personal Protection
Product name
Distillates (petroleum), hydrotreated heavy
naphthenic
Carbon dioxide
Exposure limits
ACGIH TLV (United States, 3/2012).
TWA: 5 mg/m³ 8 hours. Form: Inhalable fraction
NIOSH REL (United States, 1/2013).
TWA: 5 mg/m³ 10 hours. Form: Mist
STEL: 10 mg/m³ 15 minutes. Form: Mist
OSHA PEL (United States, 6/2010).
TWA: 5 mg/m³ 8 hours.
ACGIH TLV (United States, 3/2012). Oxygen Depletion
[Asphyxiant].
TWA: 5000 ppm 8 hours.
TWA: 9000 mg/m³ 8 hours.
STEL: 30000 ppm 15 minutes.
STEL: 54000 mg/m³ 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 10000 ppm 8 hours.
TWA: 18000 mg/m³ 8 hours.
STEL: 30000 ppm 15 minutes.
STEL: 54000 mg/m³ 15 minutes.
NIOSH REL (United States, 1/2013).
TWA: 5000 ppm 10 hours.
TWA: 9000 mg/m³ 10 hours.
STEL: 30000 ppm 15 minutes.
STEL: 54000 mg/m³ 15 minutes.
OSHA PEL (United States, 6/2010).
TWA: 5000 ppm 8 hours.
TWA: 9000 mg/m³ 8 hours.
Personal Protective Equipment (PPE)
Eyes
Safety glasses.
Body
Recommended: Neoprene gloves. Nitrile gloves. Rubber gloves.
Respiratory
Use with adequate ventilation. Provide exhaust ventilation or other engineering controls
to keep the airborne concentrations of vapors below their respective occupational
exposure limits.
Section 9. Physical and Chemical Properties
Physical State
pH
Boiling Point
Specific Gravity
Solubility
Liquid. [Aerosol. ]
Not applicable
Not available.
0.91
Insoluble in the following materials: cold water
and
hot water.
Color Dark Brown.
Odor Solvent-like.
Vapor Pressure Not available.
Vapor Density Not available.
Evaporation Rate Not available.
VOC (Consumer) 0 % (w/w) 0 lbs/gal (0 g/l)
Section 10. Stability and Reactivity
336
Stability and Reactivity
Incompatibility
The product is stable.
Reactive or incompatible with the following materials: oxidizing materials.
Under normal conditions of storage and use, hazardous polymerization will
Hazardous Polymerization
not occur.
Hazardous Decomposition Products carbon oxides (CO, CO₂), sulfur oxides (SO₂, SO₃ etc.)
Section 11. Toxicological Information
Acute Toxicity
Distillates (petroleum), hydrotreated heavy
naphthenic
LD50 Dermal
LD50 Oral
Rabbit
Rat
>5 g/kg
>5000 mg/kg
-
Section 12. Ecological Information
Environmental Effects Not available.
Aquatic Ecotoxicity
Not available.
Section 13. Disposal Considerations
Waste Information
Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult
your local or regional authorities for additional information.
Waste Stream Classification: Non-hazardous waste by
Characteristic. Origin: RCRA waste.
Section 14. Transport Information
Regulatory
information
DOT Classification
IMDG Class
UN
number
-
UN1950
Proper shipping name
Consumer commodity
or Limited quantity
AEROSOLS,
nonflammable
or Limited quantity
Classes
PG*
ORM-D
-
2.2
-
Label
NOTE: DOT classification applies to most package sizes. For specific container size classifications or
for size exceptions, refer to the Bill of Lading with your shipment.
PG* : Packing group
Section 15. Regulatory Information
U.S. Federal Regulations
SARA 313 toxic chemical notification and release reporting:
No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
All Components of this product are listed or exempt from listing on TSCA Inventory.
337
State Regulations
California Prop 65
No products were found.
Section 16. Other Information
To the best of our knowledge, the information contained herein is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
*NOTE: Hazard Determination System (HDS) ratings are based on a 0-4 rating scale, with 0 representing minimal
hazards or risks, and 4 representing significant hazards or risks Although these ratings are not required on
MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HDS ratings are to be used with a
fully implemented program to relay the meanings of this scale.
klm
338
Zep Gold Touch
Section 1. Chemical Product and Company Identification
Product name
Product use
GOLD TOUCH
Hand Cleaner.
Product code
0972
Date of issue
12/05/12
Supersedes 05/28/10
Emergency Telephone Numbers
For MSDS Information:
Technical Services Group
Telephone (780) 453-8100
(Business Hours 8:00am - 5:00pm)
For Medical or Transportation Emergency
CANUTEC (24 Hours)
(613) 996-6666 - Call Collect
Prepared By
Technical Services Group
11627 178th Street
Edmonton, Alberta T5S 1N6
Section 2. Hazards Identification
Emergency overview
CAUTION
MAY CAUSE EYE IRRITATION.
NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse
effects are lessened by following all prescribed safety precautions, including the use of proper personal
protective equipment.
Acute Effects
Eyes
Routes of Entry
Dermal contact. Eye contact.
May cause eye irritation. Inflammation of the eye is characterized by redness,
watering and
itching.
Skin
No known acute effects of this product resulting from skin contact.
No known acute effects of this product resulting from inhalation. Inhalation not likely
Inhalation under
normal use conditions.
Ingestion
No data on acute toxicity of the product when ingested.
Chronic effects
No known chronic effects from exposure.
Additional Information: See Toxicological Information (Section 11)
Section 3. Composition/Information on Ingredients
Name
of
Hazardous
Ingredients
PROPYLENE GLYCOL; 1,2-dihydroxypropane,1,2-propanediol
CAS
number
57-55-6
% by
Weight
1-5
Section 4. First Aid Measures
Eye Contact
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check
339
for and
remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical
attention.
This product is formulated for use on the Discontinue use if irritation and redness
skin.
develop.
Skin Contact
Inhalation
Inhalation not likely under normal use conditions.
Do not induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an
unconscious person. If affected person is conscious, give plenty of water to drink. Get medical
attention.
Ingestion
Section 5. Fire Fighting Measures
Flash Point
Flammable Limits
None.
Not applicable
Flammability
Non-combustible.
Auto-ignition Temperature
Fire-Fighting Procedures
Use an extinguishing agent suitable for the surrounding fire.
Fire hazard
No known significant effects or critical hazards.
Products of Combustion
carbon oxides (CO, CO2) and sulfur oxides (SO2, SO3 etc.)
Explosion hazard
Section 6. Accidental Release Measures
Spill Clean up Move containers from spill area. Dilute with water and mop up if water-soluble or
absorb with an inert dry material and place in an appropriate waste disposal
container.
Section 7. Handling and Storage
Handling
container.
Avoid contact with eyes. Do not ingest. Wash contaminated clothing before reusing. Do not reuse
Storage
Protect from freezing. Store between the following temperatures: 40°F - 120°F (4.4°C - 49°C).
Keep out of the reach of children.
Section 8. Exposure Controls/Personal Protection
Product name
propane-1,2diol
Exposure limits
CA Ontario Provincial (Canada, 7/2010).
TWA: 10 mg/m³ 8 hour(s). Form: Aerosol
only.
TWA: 155 mg/m³ 8 hour(s). Form: Vapour
and aerosol.
TWA: 50 ppm 8 hour(s). Form: Vapour
and aerosol.
Personal Protective Equipment (PPE)
Eyes
No special protection is required.
Hands and
Body
No special protection is required.
340
Respiratory No special ventilation requirements.
Section 9. Physical and Chemical Properties
Physical State
pH
Boiling Point
Specific Gravity
Solubility
Slightly Viscous liquid.
8.5 - 9.5
100°C (212°F)
1.03
Easily soluble in the following materials: cold
water
and hot water.
Freezing Point
Color Amber.
Odor Lemon-lime.
Vapor Pressure Not determined.
Vapor Density Not determined.
Evaporation Rate 1 (Water = 1)
VOC (Consumer) 0 (g/l).
Section 10. Stability and Reactivity
Stability and Reactivity
The product is stable.
Incompatibility
None identified.
Hazardous Polymerization
Will not occur.
Hazardous Decomposition Products Under normal conditions of storage and use, hazardous decomposition
products should not be produced.
Section 11. Toxicological Information
Carcinogenicity Ingredients: Not listed as carcinogen by OSHA, NTP or IARC.
Acute Toxicity
propane-1,2-diol
LD50 Dermal
Rabbit
LD50 Oral
Dog
LD50 Oral
Mouse
LD50 Oral
Rat
208
mg/kg
260
mg/kg
240
mg/kg
200
mg/kg
Section 12. Ecological Information
Environmental Effects
No known significant effects or critical hazards.
Aquatic Ecotoxicity
propane-1,2-diol
-
-
-
Acute EC50 >1000 Daphnia - Water
48 hours
mg/
flea Daphnia magna L Fresh water
<24
hours
Acute
LC50 Crustaceans
48 hours
1020000
Water flea
Ceriodaphnia
ug/L Fresh water dubia <=24 hours
Acute
LC50 Fish - Fathead
96 hours
710000 ug/
minnow Pimephales
L Fresh water
promelas -
341
<=7 days
Section 13. Disposal Considerations
Waste Information
Waste must be disposed of in accordance with applicable regulations. Consult your local or regional authorities for
additional information.
Waste Stream Non-hazardous waste
Section 14. Transport Information
Regulatory
information
TDG Classification
UN number
Proper shipping name Classes
PG* Label
Additional
information
Not regulated.
Not
determined.
IMDG Class
NOTE: DOT classification applies to most package sizes. For specific container size classifications or
for size exceptions, refer to the Bill of Lading with your shipment. Limited Quantity: Small quantities
of controlled goods are not regulated as Dangerous Goods according to TDG regulations.
PG* : Packing group
Section 15. Regulatory Information
Canada
WHMIS (Canada)
Not controlled under WHMIS (Canada).
This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations and the MSDS contains all the information required by the Controlled Products
Regulations.
Section 16. Other Information
To the best of our knowledge, the information contained herein is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described herein, we
cannot guarantee that these are the only hazards that exist.
342
Zep Measure Up Degreaser
Material Safety Data Sheet
Zep Sales & Service, A Unit of Zep
Inc.
Section 1. Chemical Product and Company Identification
1310 Seaboard Industrial Blvd.
Atlanta, GA 30318
1-877-I-BUY-ZEP (428-9937)
www.zep.com
Product name
MEASURE UP #8 - MULTI-PURPOSE
Product use
DEGREASER CONCENTRATE
General Purpose Degreaser
Product code
Date of issue
0607
04/28/08
Supersedes 08/22/03
Emergency Telephone Numbers
For MSDS Information:
Compliance Services 1-877-I-BUY-ZEP (428-9937)
For Medical Emergency
INFOTRAC: (877) 541-2016 Toll Free - All Calls
Recorded
For Transportation Emergency
CHEMTREC: (800) 424-9300 - All Calls Recorded In the District of Columbia (202) 483-7616
Prepared By
Compliance Services
1420 Seaboard Industrial Blvd.
Atlanta, GA 30318
343
Section 2. Hazards Identification
WARNING !
1
0
0
CAUSES EYE AND SKIN IRRITATION.
NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse
effects are lessened by following all prescribed safety precautions, including the use of proper personal
protective equipment.
Acute Effects
Routes of Entry
Dermal contact. Eye contact.
Eyes
itching.
Causes eye irritation. Inflammation of the eye is characterized by redness, watering and
Skin
No known acute effects of this product resulting from skin contact. Prolonged or
repeated contact may dry skin and cause irritation.
Over-exposure by inhalation may cause respiratory irritation.
May be harmful if swallowed. May irritate digestive tract.
Prolonged or repeated contact may dry skin and cause irritation.
Inhalation
Ingestion
Chronic effects
Additional Information: See Toxicological Information (Section 11)
Section 3. Composition/Information on Ingredients
Name of Hazardous Ingredients
SODIUM SILICATE; water glass
DIPROPYLENE GLYCOL METHYL ETHER; dipropylene glycol monomethyl ether
SODIUM DODECYLBENZENE SULFONATE; linear alkyl aryl sodium sulfonate; Sodium
DDBSA
CAS number
1344-09-8
34590-94-8
25155-30-0
% by Weight
1-5
1-5
1-5
Section 4. First Aid Measures
Eye Contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Check for
and remove any contact lenses. Get medical attention.
Skin Contact
Rinse with plenty of running water. If irritation persists, get medical attention.
Inhalation
If inhaled, remove to fresh air. If irritation persists, get medical attention.
Ingestion
Do not induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. If affected person is conscious, give plenty
of water to drink. Get medical attention immediately.
National Fire Protection
Association (U.S.A.)
Section 5. Fire Fighting Measures
Flash Point
Flammable Limits
Not applicable
Not applicable
Flammability
Non-combustible.
0
1 0
344
Fire hazard
Fire-Fighting
Procedures
Not applicable.
Not applicable.
Section 6. Accidental Release Measures
Spill Clean up Put on appropriate personal protective equipment (see section 8). Dilute with water and mop
up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Finish cleaning by spreading water on the contaminated surface and dispose of according to
local and regional authority requirements.
Section 7. Handling and Storage
Handling
Avoid contact with eyes, skin and clothing. Do not ingest. Wash thoroughly after handling.
Storage
Keep container tightly closed. Store between the following temperatures: 40°F - 120°F (4.4°C 49°C). Keep out of the reach of children.
Section 8. Exposure Controls/Personal Protection
Product name
Exposure limits
Supplier Suggested (United
SODIUM SILICATE; water glass
States).
CEIL:
2
mg/m³
DIPROPYLENE GLYCOL METHYL ETHER; dipropylene glycol ACGIH TLV (United States, 2003). Skin
monomethyl
TWA: 100 ppm 8 hour(s).
ether
STEL: 150 ppm 15 minute(s).
OSHA PEL (United States,
2003). Skin
TWA: 100 ppm 8 hour(s).
Personal Protective Equipment (PPE)
Eyes
Body
Safety glasses.
For prolonged or repeated handling, use gloves. Nitrile gloves.
Rubber gloves. Neoprene gloves.
Respiratory Use with adequate ventilation. A respirator is not needed under normal and
intended conditions of product use.
Section 9. Physical and Chemical Properties
Physical State
Liquid.
Color Clear. Green.
pH
11.5 - 12.5
Odor Mild.
Boiling Point
104.44°C (220°F)
Vapor Pressure Not determined.
Specific Gravity 1.04
Vapor Density Not determined.
Solubility
Easily soluble in the following materials: cold water Evaporation Rate 1 compared with Water
and hot water.
VOC (Consumer) 4.87%
0.42 (lb/gal) 51 (g/l).
Section 10. Stability and Reactivity
Stability and Reactivity
The product is stable.
345
Incompatibility
Slightly reactive or incompatible with the following materials: oxidizing materials and acids.
Hazardous Polymerization
Will not occur.
Hazardous Decomposition Products None identified.
Section 11. Toxicological Information
Acute Toxicity
Product/ingredient name
Sodium
Silicate
Dipropylene Glycol Methyl
Ether
Sodium
Sulfonate
Result
Species
LD50 Oral
Rat
LD50 Dermal
LD50 Oral
LD50 Oral
LD50 Oral
Dose
Exposure
-
Rabbit
Rat
3300 mg/kg
13000
mg/kg
5220 mg/kg
Mouse
Rat
2000 mg/kg
1260 mg/kg
-
-
Dodecylbenzene
Material Safety Data Sheet
Product Name M E A S U R E U P # 8 - M U L T I PURPOSE DEGREASER
CONCENTRATE
Section 12. Ecological Information
Environmental Effects
Aquatic Ecotoxicity
No known significant effects or critical hazards.
Not available.
Section 13. Disposal Considerations
Waste Information
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Consult your local or regional authorities for additional information.
Waste Stream Non-hazardous waste
Section 14. Transport Information
Regulatory
information
UN number
DOT Classification
Not regulated. None.
-
Not available. Not available.
Not available.
Proper shipping name Classes
PG*
Label
-
-
IMDG Class
346
NOTE: DOT classification applies to most package sizes. For specific container size classifications or for
size exceptions, refer to the Bill of Lading with your shipment.
PG* : Packing group
Section 15. Regulatory Information
U.S. Federal Regulations
SARA 313 toxic chemical notification and release reporting:
No products were found.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: Sodium Dodecylbenzene Sulfonate
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
All Components of this product are listed or exempt from listing on TSCA Inventory.
State Regulations
California Prop 65
No products were found.
Section 16. Other Information
To the best of our knowledge, the information contained herein is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
*NOTE: Hazard Determination System (HDS) ratings are based on a 0-4 rating scale, with 0 representing minimal
hazards or risks, and 4 representing significant hazards or risks Although these ratings are not required on MSDSs
under 29 CFR 1910.1200, the preparer may choose to provide them. HDS ratings are to be used with a fully
implemented program to relay the meanings of this scale.
347
Zep Powerhouse
Safety Data Sheet
Section 1. Chemical Product and Company Identification
Product name
Product use
ZEP POWERHOUSE
Aerosol Cleaner and Wax Stripper
Product code
0282
Date of issue
09/27/13
Emergency Telephone Numbers
Supersedes
07/22/08
For MSDS Information:
Compliance Services 1-877-I-BUY-ZEP (428-9937)
For Medical Emergency
(877) 541-2016 Toll Free - All Calls Recorded
For Transportation Emergency
CHEMTREC: (800) 424-9300 - All Calls Recorded
In the District of Columbia (202) 483-7616
Prepared By
Compliance Services
1420 Seaboard Industrial
Blvd.
Atlanta, GA 30318
Section 2. Hazards Identification
Emergency overview
*Hazard Determination System (HDS): Health, Flammability, Reactivity
DANGER !
2
1
0
CAUSES EYE BURNS. CAUSES SKIN IRRITATION. HARMFUL IF
INHALED OR ABSORBED THROUGH SKIN.
CONTENTS UNDER PRESSURE.
NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse effects
are lessened by following all prescribed safety precautions, including the use of proper personal protective
equipment.
Acute Effects
Routes of Entry
Dermal contact. Eye contact. Inhalation.
Eyes
Causes eye burns. Direct contact with the eyes can cause irreversible damage,
including blindness. Inflammation of the eye is characterized by redness, watering
and itching.
Skin
itching,
Causes skin irritation. Harmful if absorbed through the skin. Skin inflammation is characterized by
scaling, reddening or, occasionally, blistering.
348
Inhalation Harmful if inhaled. Inhalation of spray mists or vapors may cause central nervous
system depression characterized by headache, dizziness, nausea, and/or stupor.
Avoid breathing vapors, spray or mists.
Ingestion
May be harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and
cause damage. Ingestion may cause nausea, weakness and central nervous
system effects.
Chronic effects Contains material which may cause damage to the following organs: blood, kidneys, the
nervous system, the reproductive system, liver, heart, spleen, lymphatic system,
gastrointestinal tract, upper respiratory tract, skin, bone marrow, central
nervous system (CNS), eye, lens or cornea, testes. Repeated or prolonged contact
with spray or mist may produce chronic eye irritation and severe skin irritation.
Repeated or prolonged exposure to spray mist may produce respiratory tract
irritation leading to frequent attacks of bronchial infection.
Carcinogenicity
No known significant effects or critical hazards.
Product/ingredient name
Not available.
Additional Information: See Toxicological Information (Section 11)
Section 3. Composition/Information on Ingredients
CAS
number
64-17-5
106-97-8
111-76-2
141-43-5
67-63-0
74-98-6
Name of Hazardous Ingredients
Ethanol; Ethyl Alcohol
Butane
2-butoxyethanol
2-aminoethanol
Isopropyl alcohol
propane
% by Weight
10 - 20
1-5
1-5
1-5
1-5
1-5
Section 4. First Aid Measures
Eye Contact Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least
15 minutes, occasionally lifting the upper and lower eyelids. If irritation persists, get medical
attention.
Skin Contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical attention if irritation
develops.
Inhalation
Move exposed person to fresh air. If irritation persists, get medical attention.
Ingestion
Wash out mouth with water. Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical attention
immediately.
National Fire Protection
Association (U.S.A.)
Section 5. Fire Fighting Measures
Flash Point
Closed cup: <60°C (<140°F)
[Tagliabue.]
Flammable Limits
Flammability
Not available.
Non-flammable
Aerosol.
1
2 0
(16
CFR
349
1500.45)
CONTENTS UNDER PRESSURE. In a fire or if heated, a pressure increase will occur and the container
may
burst. Bursting aerosol containers may be propelled from a fire at high speed.
Use an extinguishing agent suitable for the surrounding fire. Cool closed containers exposed to fire
with water.
Fire-fighters should wear appropriate protective equipment.
Fire hazard
Fire-Fighting
Procedures
Section 6. Accidental Release Measures
Spill Clean up
Large spills are unlikely due to packaging.
Section 7. Handling and Storage
Handling
Put on appropriate personal protective equipment (see Section 8). Store and use away from heat,
sparks, open flame or any other ignition source. Avoid contact with eyes. Avoid prolonged or repeated
contact with skin. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation.
Observe label precautions. Wash contaminated clothing before reusing. Wash thoroughly after
handling.
Storage
CONTENTS UNDER PRESSURE. Do not puncture, incinerate or store the container at temperatures
above 49°C (120°F) or in direct sunlight. Keep away from food, drink and animal feeding stuffs. Keep
out of the reach of children.
Section 8. Exposure Controls/Personal Protection
Product name
Ethanol; Ethyl Alcohol
Butane
2-butoxyethanol
Exposure limits
ACGIH TLV (United States, 3/2012).
STEL: 1000 ppm 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 1000 ppm 8 hours.
TWA: 1900 mg/m³ 8 hours.
NIOSH REL (United States, 1/2013).
TWA: 1000 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
OSHA PEL (United States, 6/2010).
TWA: 1000 ppm 8 hours.
TWA: 1900 mg/m³ 8 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 800 ppm 8 hours.
TWA: 1900 mg/m³ 8 hours.
NIOSH REL (United States, 1/2013).
TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 3/2012).
TWA: 1000 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989). Absorbed
through skin.
TWA: 25 ppm 8 hours.
TWA: 120 mg/m³ 8 hours.
NIOSH REL (United States, 1/2013). Absorbed
through skin.
TWA: 5 ppm 10 hours.
TWA: 24 mg/m³ 10 hours.
350
2-aminoethanol
Isopropyl alcohol
propane
ACGIH TLV (United States, 3/2012).
TWA: 20 ppm 8 hours.
OSHA PEL (United States, 6/2010). Absorbed through skin.
TWA: 50 ppm
8
hours.
TWA:
240
mg/m³
8
hours.
ACGIH TLV (United States, 3/2012).
TWA: 3 ppm 8
hours.
TWA:
7.5 mg/m³ 8
hours. STEL: 6
ppm
15
minutes. STEL:
15 mg/m³ 15
minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 3 ppm 8 hours.
TWA: 8 mg/m³ 8 hours.
STEL: 6 ppm 15 minutes.
STEL: 15 mg/m³ 15 minutes.
NIOSH REL (United States, 1/2013).
TWA: 3 ppm 10 hours.
TWA: 8 mg/m³ 10 hours.
STEL: 6 ppm 15 minutes.
STEL: 15 mg/m³ 15 minutes.
OSHA PEL (United States, 6/2010).
TWA: 3 ppm 8 hours.
TWA: 6 mg/m³ 8 hours.
ACGIH TLV (United States, 3/2012).
TWA: 200 ppm 8 hours.
STEL: 400 ppm 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 400 ppm 8 hours.
TWA: 980 mg/m³ 8 hours.
STEL: 500 ppm 15 minutes.
STEL: 1225 mg/m³ 15 minutes.
NIOSH REL (United States, 1/2013).
TWA: 400 ppm 10 hours.
TWA: 980 mg/m³ 10 hours.
STEL: 500 ppm 15 minutes.
STEL: 1225 mg/m³ 15 minutes.
OSHA PEL (United States, 6/2010).
TWA: 400 ppm 8 hours.
TWA: 980 mg/m³ 8 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
351
NIOSH REL (United States, 1/2013).
TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 6/2010).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
ACGIH TLV (United States, 3/2012).
TWA: 1000 ppm 8 hours.
Personal Protective Equipment (PPE)
Eyes
Safety glasses.
Body
Recommended: Neoprene gloves. Nitrile gloves. Rubber gloves.
Respiratory
Use with adequate ventilation. Provide exhaust ventilation or other engineering controls to
keep the airborne concentrations of vapors below their respective occupational exposure
limits. Wear appropriate respirator when ventilation is inadequate.
Section 9. Physical and Chemical Properties
Physical State
pH
Boiling Point
Specific Gravity
Solubility
Liquid. [Aerosol.]
Color Clear. Colorless.
10.5 to 11.5
Odor Pine.
98.3°C (208.9°F)
Vapor Pressure Not available.
0.97
Vapor Density Not available.
Easily soluble in the following materials: cold
Evaporation Rate <1 (Water = 1)
water
and hot water.
VOC (Consumer) 28.2 % (w/w) 2.29 lbs/gal (273.9 g/l)
Section 10. Stability and Reactivity
Stability and Reactivity
Incompatibility
The product is stable.
Reactive or incompatible with the following materials: acids.
Avoid contact with strong oxidizers, excessive heat, sparks or open flame.
Hazardous
Under normal conditions of storage and use, hazardous polymerization will not occur.
Polymerization
Hazardous Decomposition Products
carbon oxides (CO, CO₂), nitrogen oxides (NO, NO₂ etc.)
Section 11. Toxicological Information
Acute Toxicity
Product/ingredient name
Butane
2-butoxyethanol
Isopropyl alcohol
ethanol
2-aminoethanol
Result
LC50 Inhalation Vapor
LC50 Inhalation Gas.
LD50 Dermal
LD50 Oral
LD50 Dermal
LD50 Oral
LC50 Inhalation Vapor
LD50 Oral
LD50 Oral
Species
Rat
Rat
Rabbit
Rat
Rabbit
Rat
Rat
Rat
Rat
Dose
658000 mg/m³
450 ppm
220 mg/kg
250 mg/kg
12800 mg/kg
5000 mg/kg
124700 mg/m³
7 g/kg
1720 mg/kg
Exposure
4 hours
4 hours
4 hours
-
Section 12. Ecological Information
352
Environmental Effects Not available.
Aquatic Ecotoxicity
2-butoxyethanol
-
Acute EC50 >1000 mg/l Fresh
water
Acute LC50 800000 µg/l
Marine water
-
Acute LC50 1250000 µg/l
Marine water
-
Acute LC50 1400000 µg/l
Marine water
-
Acute LC50 1400000 µg/l
-
Acute LC50
Marine water
-
Isopropyl alcohol
ethanol
-
2-aminoethanol
25500
µg/l
Chronic NOEC 4.995 mg/l
Marine water
Chronic NOEC 0.375 ul/L
Fresh water
-
Acute EC50 80000 µg/l Fresh
water
Acute LC50 >100000 µg/l
Marine water
-
Acute LC50
Fresh water
-
170000
µg/l
Daphnia - Water flea 48 hours
Daphnia magna
Crustaceans - Common
48 hours
shrimp, sand
shrimp - Crangon crangon
Fish - Inland silverside 96 hours
Menidia
berylli
na
Crustaceans - Common
48 hours
shrimp, sand
shrimp - Crangon crangon
Fish - Western mosquitofish 96 hours
Gambusia
affinis
Crustaceans - San Francisco
48 hours
Brine
Shrimp - Artemia franciscana
- Larvae
Algae - Green algae - Ulva
96 hours
pertusa
Fish - Eastern mosquitofish - 12
Gambusia
weeks
holbrooki - Larvae
Algae
Haptophyte
96 hours
Isochrysis galbana
Crustaceans - Common
48 hours
shrimp, sand
shrimp - Crangon crangon Adult
Fish - Goldfish - Carassius
96
auratus
hours
Section 13. Disposal Considerations
Waste Information
Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult
your local or regional authorities for additional information.
Waste Stream Code: D001
Classification: Ignitable hazardous waste.
Origin: RCRA waste.
Section 14. Transport Information
Regulatory
information
DOT Classification
IMDG Class
UN
number
-
UN1950
Proper shipping name
Consumer commodity
or Limited quantity
AEROSOLS,
flammable
Classes
PG*
ORM-D
-
2.2
-
Label
non-
353
or Limited quantity
NOTE: DOT classification applies to most package sizes. For specific container size classifications or for
size exceptions, refer to the Bill of Lading with your shipment.
PG* : Packing group
Section 15. Regulatory Information
U.S. Federal Regulations
SARA 313 toxic chemical notification and release reporting:
Product name
2 butoxyethanol Isopropyl
alcohol
Clean Water Act (CWA) 311: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
All Components of this product are listed or exempt from listing on TSCA Inventory.
State Regulations
California Prop 65
WARNING: This product contains less than 0.01% of a chemical known to the State of California to cause cancer.
Section 16. Other Information
To the best of our knowledge, the information contained herein is accurate. However, neither the above named
supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
*NOTE: Hazard Determination System (HDS) ratings are based on a 0-4 rating scale, with 0 representing minimal
hazards or risks, and 4 representing significant hazards or risks Although these ratings are not required on MSDSs
under 29 CFR 1910.1200, the preparer may choose to provide them. HDS ratings are to be used with a fully
implemented program to relay the meanings of this scale.
klm
354
ATC-4
355
356
357
Krylon- Seal Coat
MATERIAL SAFETY DATA SHEET
41303
05 00
DATE OF PREPARATION
Nov 28, 2010
SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
41303
PRODUCT NAME
KRYLON® Crystal Clear Spray Coating
MANUFACTURER'S NAME
SHERWIN-WILLIAMS CANADA INC.
KRYLON Products Group
Vaughan, ON L4K 4T8
Telephone Numbers and
Websites
Product Information (800) 832-2541
Regulatory Information (216) 566-2902
www.paintdocs.com
Medical Emergency (216) 566-2917
*
Transportation Emergency (800) 424-9300
*
for Chemical Emergency ONLY (spill, leak, fire, exposure, or
accident)
SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS
% by Weight
14
13
17
3
1.
41
CAS Number Ingredient
Units
74-98-6 Propane
ACGIH TLV
2500PPM
OSHA PEL
1000PPM
106-97-8 Butane
ACGIH TLV
800PPM
OSHA PEL
800PPM
108-88-3 Toluene
ACGIH TLV
20PPM
OSHA PEL
100 ppm (Skin)
OSHA PEL
150 ppm (Skin) STEL
Medium
Aromatic
64742-94-5 Hydrocarbons
ACGIH TLV
Not Available
OSHA PEL
Not Available
91-20-3 Naphthalene
ACGIH TLV
10 PPM
ACGIH TLV
15 PPM STEL
OSHA PEL
10 PPM
OSHA PEL
15 PPM STEL
67-64-1 Acetone
ACGIH TLV
500 PPM
ACGIH TLV
750 PPM STEL
Vapor Pressure
760 mm
760 mm
22 mm
0.12 mm
1 mm
180 mm
358
4
OSHA PEL
1000 PPM
763-69-9 Ethyl 3-Ethoxypropionate
ACGIH TLV
Not Available
OSHA PEL
Not Available
1.11 mm
SECTION 3 — HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death.
HMIS Codes
Health 2*
Flammability 4
Reactivity 0
Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs
or systems:
the liver
the urinary system
the
cardiovasc
ular
system
the
reproducti
ve system
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to
vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
SECTION 4 — FIRST AID MEASURES
EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet.
INGESTION: Do not induce vomiting. Get medical attention immediately.
SECTION 5 — FIRE FIGHTING MEASURES
FLASH POINT
LEL
Propellant < 0 °F
0.8
UNUSUAL FIRE AND EXPLOSION HAZARDS
UEL
12.8
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
Containers may explode when exposed
to extreme heat. Application to hot
surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may
not be immediately apparent. Obtain medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus should be used.
Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers
to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat.
359
SECTION 6 — ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
SECTION 7 — HANDLING AND STORAGE
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights,
and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight,
radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of
the reach of children.
SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing
vapor and spray mist. Wash hands after using.
This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present
at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the
applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15
mg/m3 (total dust), 5 mg/m3 (respirable fraction).
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below
applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic
vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be
generated from this product, underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated
contact, wear chemical resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal.
SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT 6.07 lb/gal
727 g/l
SPECIFIC GRAVITY 0.73
BOILING POINT <0 - 415 °F
<-18 - 212 °C
MELTING POINT Not Available
VOLATILE VOLUME 94%
EVAPORATION RATE Faster than ether
VAPOR DENSITY Heavier than air
SOLUBILITY IN WATER N.A.
pH 7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
Volatile Weight 50.84%
Less Water and Federally Exempt Solvents
SECTION 10 — STABILITY AND REACTIVITY
STABILITY — Stable
CONDITIONS TO AVOID
360
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
SECTION 11 — TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system
damage.
TOXICOLOGY DATA
CAS No.
Ingredient Name
74-98-6
Propane
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
106-97-8
Butane
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
108-88-3
Toluene
LC50 RAT
4HR
4000 ppm
LD50 RAT
5000 mg/kg
64742-94-5
Medium Aromatic Hydrocarbons
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
91-20-3
Naphthalene
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
67-64-1
Acetone
LC50 RAT
4HR
Not Available
LD50 RAT
5800 mg/kg
763-69-9
Ethyl 3-Ethoxypropionate
LC50 RAT
4HR
Not Available
LD50 RAT
5000 mg/kg
SECTION 12 — ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.
SECTION 13 — DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act
(RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste
numbers.
Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations
regarding pollution.
SECTION 14 — TRANSPORT INFORMATION
US Ground (DOT)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)
Canada (TDG)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)
IMO
May be shipped as Limited Quantity
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U, ADR (D)
SECTION 15 — REGULATORY INFORMATION
361
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
108-88-3
Toluene
17
91-20-3
Naphthalene
0.3
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory.
% Element
SECTION 16 — OTHER INFORMATION
This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products
Regulations (CPR) and the MSDS contains all of the information required by the CPR.
The above information pertains to this product as currently formulated, and is based on the information available at this time.
Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since
conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any
use of this information.
362
Hilti- FS One Fire Sealant
®
MSDS No.:
Revision
No.:
Revision
Date:
259
Page:
1 of 2
012
03/29/12
MATERIAL SAFETY DATA SHEET
Product name:
FS-ONE High Performance Intumescent Firestop Sealant
Description:
One-part acrylic-based sealant
Supplier:
Hilti, Inc. P.O. Box 21148, Tulsa, OK 74121
Emergency # (Chem-Trec.):
1 800 424 9300 (USA, PR, Virgin Islands, Canada); 001 703 527 3887 (other countries)
INGREDIENTS AND EXPOSURE LIMITS
Ingredients:
Polyacrylate dispersion
Calcium carbonate
Zinc borate
Talc
Ethylene glycol
CAS Number:
Mixture
001317-65-3
1332-07-6
014807-96-6
000107-21-1
PEL:
NE
3
5 mg/m (R)
NE
20 mppcf
NE
TLV:
NE
NE
NE
3
2 mg/m (R)
NE
3
STEL:
NE
NE
NE
NE
3
C:100 mg/m (A)
3
Iron oxide
001309-37-1
10 mg/m (F)
5 mg/m (R)
NE
Abbreviations: PEL = OSHA Permissible Exposure Limit. TLV = ACGIH Threshold Limit Value. C = Ceiling. STEL =
Short Term Exposure Limit. NE = None Established. NA = Not Applicable. (T) indicates “as total dust”. (R)
indicates “as respirable fraction”. (A) indicates “as an aerosol”. mppcf = million particles per cubic foot. F =
Fume
PHYSICAL DATA
Appearance:
Vapor Density: (air = 1)
Boiling Point:
Evaporation Rate:
Specific Gravity:
Red paste.
Not
determined.
Not applicable.
Not applicable.
1.5
Odor:
Odorless.
Vapor Pressure:
VOC Content:
Solubility in Water:
pH:
23mbar @ 20C / 68F
75.0 g/L.
Soluble.
Not determined.
FIRE AND EXPLOSION HAZARD DATA
Flash Point:
Extinguishing Media:
Special Fire Fighting
Procedures:
Unusual Fire and Explosion
Hazards:
NonFlammable Limits:
Not applicable.
flammable.
Not applicable. Use extinguishing media as appropriate for surrounding fire.
None known. Use a self-contained breathing apparatus when fighting fires involving
chemicals.
None known. Thermal decomposition products can be formed such as oxides of carbon,
sulfur
and phosphorous.
REACTIVITY DATA
363
Stability:
Incompatibility:
Decomposition Products:
Conditions to Avoid:
Stable.
Hazardous Polymerization:
Strong acids, peroxides, and oxidizing agents.
Thermal decomposition can yield CO and CO2.
None known.
Will not occur.
HEALTH HAZARD DATA
Known Hazards:
Signs and Symptoms of
Exposure:
Medical Conditions
Aggravated by Exposure:
Routes of Exposure:
Carcinogenicity:
None known.
Possibly irritating upon contact with the eyes or upon repeated contact with the skin.
Eye and skin conditions.
Dermal.
No ingredients are classified as carcinogens.
EMERGENCY AND FIRST AID PROCEDURES
Eyes:
Skin:
Inhalation:
Ingestion:
Other:
Immediately flush with plenty of water. Contact a physician if symptoms occur.
Immediately wipe off material and wash with soap and water. Contact a physician if
symptoms
occur.
Move victim to fresh air if discomfort develops. Contact a physician if symptoms occur.
persist.
Seek medical attention. Do not induce vomiting unless directed by a physician.
Referral to a physician is recommended if there is any question about the seriousness of
the
injury/exposure
.
CONTROL MEASURES AND PERSONAL PROTECTIVE EQUIPMENT
Ventilation:
General (natural or mechanically induced fresh air movements).
Eye Protection:
Safety glasses with side shields.
Skin Protection:
Impermeable gloves. Other protective clothing as required to prevent skin contact.
Wher
ventilation is inadequate to control vapors, use a
None normally required. e
NIOSHapproved respirator with organic vapor cartridges. Never enter a confined space
without an
appropriate
air-supplied
respirator.
Respiratory Protection:
Handling and Storing
Precautions:
Spill Procedures:
Hazard Communication:
HMIS Codes:
PRECAUTIONS FOR SAFE HANDLING AND USE
Store in a cool, dry area preferably between 40º and 77º F. Keep from freezing. Do not
store in
Practice good hygiene; i.e. always
direct sunlight. Avoid contact with the eyes or skin.
wash
thoroughly after handling and before eating or smoking. For industrial use only. Keep
out of
reach of children. Follow label/use instructions.
Immediately wipe away spilled material before it hardens. Place in a container for proper
disposal
in accordance with all applicable local, state, or federal requirements.
REGULATORY INFORMATION
This MSDS has been prepared in accordance with the federal OSHA Hazard
Communication
Standard 29 CFR 1910.1200.
Health 1, Flammability Reactivity 0, PPE B
364
0,
DOT Shipping Name:
Not regulated.
IATA / ICAO Shipping Name:
Not regulated.
TSCA Inventory Status:
Chemical components listed on TSCA inventory.
This product contains < 3% ethylene glycol (CAS 107-21-1) and < 15% zinc borate (re:
zinc
compounds) which are subject to reporting under Section 313 of SARA Title III (40 CFR
Part
372).
SARA Title III, Section 313:
EPA Waste Code(s):
Waste Disposal Methods:
Not regulated by EPA as a hazardous waste.
Consult with regulatory agencies or your corporate personnel for disposal methods that
comply
with local, state, and federal safety, health and environmental regulations.
CONTACTS
Technical Service:
1 800 879
8000
Customer Service:
1 800 879 8000
Health / Safety:
Emergency # (Chem-Trec):
Jerry
1 800 879 6000
(x71003704)
Metcalf
1 800 424 9300 (USA, PR, Virgin Islands, Canada); 001 703 527 3887 (other countries)
The information and recommendations contained herein are based upon data believed to be correct;
however, no guarantee or warranty of any kind expressed or implied is made with respect to the information
provided.
365
Ideal- AquaGel Wire Lube
Document # 6810-004
Flammability
0
Reactiv
ity
Health
1
0
HMIS Rating
MATERIAL SAFETY DATA SHEET
GENERAL INFORMATION
CATALOG
NUMBER
PRODUCT NAME OR NUMBER (as it appears on label)
TM
ClearGlide Wire Pulling Lubricant
All “31” Series
MANUFACTURER’S
EMERGENCY
NAME
TELEPHONE NO.
IDEAL INDUSTRIES, INC.
(815) 895-5181
ADDRESS (Number, Street, City, State, Zip Code)
Becker Place, Sycamore, IL 60178
HAZARDOUS MATERIAL DESCRIPTION, PROPER SHIPPING NAME, HAZARD CLASS, HAZARD
CLASS, HAZARD ID NO. (49 CFR 172.101)
None
CHEMICAL
DESCRIPTION
FORMULA
Polymer-based
Proprietary
Mixture
SECTION I - INGREDIENTS
Listed as a
carcinogen
CAS
REGISTRY
in NTP, I ARC
%W
CHEMICAL NAME(S)*
NO.
or OSHA
1910(z)
(specify)
7732-18-5
<98 Water
No
6440-58-0
<1
DMDM Hydantoin
No
9038-95-3
<5
Oxirane, Methyl-, Polymer With Oxirane,
No
Monobutyl Ether
9003-11-6
<1
Amino-Methyl-Propanol
No
25322-68-3
9003-01-4
<1
<1
Polyethylene Glycol
Carbomer Thickener
No
No
68037-64-9
<1
Silicone Glycol Blend
No
BOILING
POINT
212°F°C
SOLUBILITY IN WATER
Infini
te
SECTION II - PHYSICAL DATA
SPECIFIC GRAVITY
(H2O=1)
1.09
pH =
7.0 - 8.0
PERCENT VOLATILE BY
VOLUME (%)
<98
PERCENT SOLID BY
WEIGHT
~5
366
(%)
IS
MATERIA
APPEARANCE
AND
SOLI
L:
LIQUID
ODOR
D GEL
POWDE
Clear, colorless gel, slight odor
GAS PASTE R
SECTION III - FIRE AND EXPLOSION HAZARD DATA
FLASH
FLAMMABLE
None
method used C.O.C
LEL
UEL
POINT
LIMITS
Non
e
None
EXTINGUISHING MEDIA
Use extinguishing media suitable for surrounding materials.
SPECIAL FIRE FIGHTING PROCEDURES
None
UNUSUAL FIRE AND EXPLOSION HAZARDS
None
SECTION IV - HEALTH HAZARD INFORMATION
EFFECTS OF OVEREXPOSURE - Conditions to Avoid
None normally expected. Upon prolonged contact, may cause
temporary eye
discomfort.
THRESHOLD LIMIT VALUE
N.E.
PRIMARY
ROUTES
OF Skin
Other (specify)
ENTRY Inhalation
Contact
EMERGENCY FIRST
PROCEDURES
SKIN CONTACT:
EYE CONTACT:
INGESTION:
STABILITY
UNSTAB
LE
AID
Wash with soap and water for 15 minutes.
Flush with water for 15 minutes. Inhalation - Move to fresh air.
Administer water or milk. Consult physician or local poison control center.
SECTION V - REACTIVITY DATA
STABLE
CONDITIONS TO AVOID
Avoid prolonged storage at temperatures exceeding 190 F.
X
INCOMPATI (materials to
BILITY
avoid)
Avoid strong oxidizers and nitrites.
HAZARDOUS DECOMPOSTION PRODUCTS:
Oxides of carbon, nitrogen and silicone
MAY
OCCUR
HAZARDOUS
POLYMERIZAT
WILL NOT
ION
OCCUR
CONDITIONS TO AVOID
None
X
SECTION VI - SPILL AND LEAK PROCEDURES
367
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Wipe up, shovel or vacuum spilled material. Clean up spills immediately
as they can be dangerously slippery.
WASTE DISPOSAL METHOD
Comply with Federal, state or local regulations for solid landfill.
CERCLA (Superfund) REPORTABLE QUANTITY (in lbs)
RCRA HAZARDOUS
261.33)
WASTE
NO.
(40CFR
N/A
N/A
VOLATILE ORGANIC COMPOUND (VOC) (as
packaged, minus water)
³
Theoret
ical
lb/gal
17.4 gms / ltr
³
Analyti
cal
N/A
lb/ga
l
N/A
SECTION VII - PERSONAL PROTECTION INFORMATION
RESPIRATORY PROTECTION (specify type)
None
normally
required.
LOCAL
EXHAUST
SPECIA
None
None
(Specify Rate)
L
VENTILAT
MECHANICAL (General) (Specify Rate)
OTHER None
ION
Recommended in closed
areas.
PROTECTIVE GLOVES (specify EYE
PROTECTION
type)
(specify type)
None
normally
Safety glasses or splash goggles.
required.
OTHER PROTECTIVE EQUIPMENT
Eye fountain in work area is recommended.
SECTION VIII - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Store at temperatures between 40 - 180 F. Avoid freezing.
OTHER PRECAUTIONS
Keep away from children, infants and pets.
SECTION IX - ADDITIONAL INFORMATION
N/A = Not Applicable, N.E. = None Established
THIS MATERIAL SAFETY DATA SHEET PREPARED BY:
NAME
TITLE
DATE
James R. MacMurdo
Manager, Construction Market Dev.
03/06/2012
SIGNATURE
368
ClearGlide
TM
Wire Pulling Lubricant
369
Masterflow 928 Grout
Safety data sheet
MASTERFLOW 928 GRT
1. Substance/preparation and company identification
Company
BASF Agricultural Products de Puerto Rico State Road No. 2, km. 47.3
Manati PR 00674
24 Hour Emergency Response Information
CHEMTREC: 1-800-424-9300
Outside of the United States, call: (001)703-527-3887
BASF HOTLINE: 1-800-832-HELP
2. Composition/information on ingredients
CAS Number
14808-60-7
Content (W/W)
30.0 - 60.0 %
65997-15-1
1309-37-1
1305-78-8
7778-18-9
112945-52-5
1309-48-4
1317-65-3
15.0 - 40.0 %
3.0 - 7.0 %
3.0 - 7.0 %
1.0 - 5.0 %
1.0 - 5.0 %
0.5 - 1.5 %
0.5 - 1.5 %
Chemical name
crystalline silica
Cement,
portland,
chemicals
Iron oxide
calcium oxide
Calcium sulphate
Silica
magnesium oxide
Limestone
3. Hazard identification
Emergency overview
WARNING: MAY BE HARMFUL IF INHALED.
CONTAINS MATERIAL WHICH CAN CAUSE CANCER. Can cause
moderate irritation due to abrasive action.
In combination with water, repeated or prolonged dermal exposure can cause moderate to severe alkali burns. Keep
container tightly closed.
Avoid inhalation of dusts. Avoid ingestion.
Avoid contact with the skin, eyes and clothing. Wash
thoroughly after handling.
Potential health effects
Primary routes of exposure
Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry for gases
include inhalation and eye contact. Skin contact may be a route of entry for liquified gases.
Acute toxicity:
No data available.
Irritation:
370
The product has not been tested. The statement has been derived from the properties of the individual
components.
Information on: calcium oxide
Corrosive! Damages skin and eyes.
Repeated dose toxicity:
Information on: crystalline silica
This product may contain greater than 0.1% crystalline silica.
Repeated exposure to high concentrations results in silicosis, a lung disease characterized by coughing,
difficult breathing, wheezing, scarring of the lungs, and repeated, non-specific chest illnesses.
Information on: Iron oxide
Chronic exposures have been known to produce pneumoconiosis (chronic inflammatory and fibrotic lung
disease).
The substance may cause increase in lung mass and lung tissue changes after repeated inhalation. The product
has not been tested. The statement has been derived from products of a similar structure and composition.
Potential environmental effects
Aquatic toxicity:
At the present state of knowledge, no negative ecological effects are expected.
There is a high probability that the product is not acutely harmful to aquatic organisms.
The product has not been tested. The statement has been derived from products of a similar structure and
composition.
4. First-aid measures
If inhaled:
After inhalation of dust. Keep patient calm, remove to fresh air. If difficulties occur: Obtain medical attention.
If on skin:
After contact with skin, wash immediately with plenty of water and soap. Under no circumstances should organic
solvent be used. If irritation develops, seek medical attention.
If in eyes:
Flush with copious amounts of water for at least 15 minutes.
If swallowed:
Rinse mouth immediately and then drink plenty of water, seek medical attention. Do not induce vomiting unless
told to by a poison control center or doctor.
5. Fire-fighting measures
Flash point:
The substance/product is non-combustible.
Suitable extinguishing media:
foam, water spray, dry extinguishing media, carbon dioxide
Unsuitable extinguishing media for safety reasons: water jet
Hazards during fire-fighting:
carbon dioxide, carbon monoxide, harmful vapours, nitrogen oxides, fumes/smoke, carbon black
371
Protective equipment for fire-fighting:
Wear a self-contained breathing apparatus.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water
must be disposed of in accordance with official regulations.
6. Accidental release measures
Personal precautions:
Avoid dust formation. Avoid contact with skin and eyes. Use personal protective clothing. Handle in
accordance with good building materials hygiene and safety practice.
Environmental precautions:
Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.
Cleanup:
Avoid raising dust.
For small amounts: Pick up with suitable appliance and dispose of. Dispose of absorbed material in
accordance with regulations.
For large amounts: Pick up with suitable appliance and dispose of. Dispose of absorbed material in
accordance with regulations.
7. Handling and storage
Handling
General advice:
Avoid dust formation. Avoid inhalation of dusts. Avoid skin contact. Pour downwind and allow as little free fall as
possible while emptying bags into equipment. Breathing must be protected when large quantities are decanted
without local exhaust ventilation.
Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.
Keep away from sources of ignition - No smoking. Dust can form an explosive mixture with air.
Storage
Storage incompatibility:
General: Segregate from metals. Segregate from acids. Segregate from lyes. Segregate from oxidants. Segregate
from foods and animal feeds.
8. Exposure controls and personal protection
Components with workplace control parameters
TWA
2.4 millions of particles per cubic foot of
crystalline silica
OSHA
value
air
Respirable ; TWA value 0.1 mg/m3 Respirable ; TWA
value
0.3
mg/m3 Total dust ;
Cement,
portland, ACGIH
TWA
0.025 mg/m3 Respirable fraction ;
372
chemicals
OSHA
ACGIH
value
PEL 5 mg/m3 Respirable fraction ; PEL 15 mg/m3
Total dust ;
TWA value 10 mg/m3 ;
Iron oxide
calcium oxide
ACGIH
OSHA
ACGIH
Calcium sulphate
OSHA
magnesium oxide
ACGIH
OSHA
ACGIH
Limestone
OSHA
TWA value 5 mg/m3 Respirable fraction ;
PEL 5 mg/m3 ;
TWA value 2 mg/m3 ;
PEL 5 mg/m3 Respirable fraction ; PEL 15 mg/m3
Total dust ;
TWA
10
mg/m3
Inhalable
;
value
fraction
PEL 15 mg/m3 Total particulate ;
TWA
10
mg/m3
Inhalable
;
value
fraction
PEL 5 mg/m3 Respirable fraction ; PEL 15 mg/m3
Total dust ;
Personal protective equipment
Respiratory protection:
Wear respiratory protection if ventilation is inadequate.
Hand protection:
Chemical resistant protective gloves, Manufacturer's directions for use should be observed because of great diversity
of types.
Eye protection:
Tightly fitting safety goggles (chemical goggles).
Body protection:
Body protection must be chosen based on level of activity and exposure.
General safety and hygiene measures:
Avoid contact with the skin, eyes and clothing. Avoid inhalation of dusts. In order to prevent contamination while
handling, closed working clothes and working gloves should be used. Handle in accordance with good building
materials hygiene and safety practice. When using, do not eat, drink or smoke. Hands and/or face should be washed
before breaks and at the end of the shift. At the end of the shift the skin should be cleaned and skin-care agents
applied. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks).
9. Physical and chemical properties
Form:
Odour:
Colour:
Melting point:
Relative density:
Viscosity, dynamic:
powder
odourless
grey
Unspecified
No data available.
No data available.
10. Stability and reactivity
Conditions to avoid:
Avoid dust formation.
373
Substances to avoid:
strong acids, strong bases, strong oxidizing agents
Hazardous reactions:
The product is stable if stored and handled as prescribed/indicated.
11. Toxicological information
Chronic toxicity
Carcinogenicity:
Information on: crystalline silica
The International Agency for Research on Cancer (IARC) has classified this substance as a Group 1 (known) human
carcinogen.
---------------------------------Other information:
Based on our experience and the information available, no adverse health effects are expected if handled as
recommended with suitable precautions for designated uses.
The product has not been tested. The statements on toxicology have been derived from products of a similar
structure and composition.
12. Ecological information
Environmental toxicity
Other ecotoxicological advice:
Ecological data are not available.
13. Disposal considerations
Waste disposal of substance:
Dispose of in accordance with national, state and local regulations.
Recommendations: Use excess product in an alternate beneficial application.
Container disposal:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being
thoroughly cleaned.
14. Transport information
Land transport
USDOT
Not classified as a dangerous good under transport regulations
Sea transport
IMDG
Not classified as a dangerous good under transport regulations
Air transport
IATA/ICAO
374
Not classified as a dangerous good under transport regulations
15. Regulatory information
Federal Regulations
Registration status:
TSCA, US
released / listed
OSHA hazard category: IARC 1, 2A or 2B carcinogen, NTP listed carcinogen, Chronic target organ effects reported,
OSHA PEL established, ACGIH TLV established
SARA hazard categories (EPCRA 311/312): Acute, Chronic
State regulations
State RTK
CAS Number
14808-60-7
65997-15-1
1305-78-8
7778-18-9
1309-48-4
1317-65-3
Chemical name
crystalline silica
Cement, portland, chemicals
calcium oxide
Calcium sulphate
magnesium oxide
Limestone
State RTK
MA, NJ, PA
MA, NJ, PA
MA, NJ, PA
MA, PA
MA, NJ, PA
MA, PA
CA Prop. 65:
THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
16. Other information
HMIS III rating
Health: 2¤
Flammability: 0
Physical hazard: 1
HMIS uses a numbering scale ranging from 0 to 4 to indicate the degree of hazard. A value of zero means that the
substance possesses essentially no hazard; a rating of four indicates high hazard.
Local contact information
NTU/R NA
END OF DATA SHEET
375
Cable Clean
376
377
378
379
380
381
382
383
Cold Galvanized Spray
24 Hour Assistance:
Material Safety Data Sheet
1-847-367-7700
Rust-Oleum Corp.
www.rustoleum.com
1. Identification
ROHPER LSPR 6PK FLAT COLD GALV
Product Name:
Revision Date:
3/20/2014
COMPOUND
Product Number:
V2185838
Product Use/Class:
Galvanizing Compound/Aerosol
Supplier:
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
Prepared by:
Regulatory Department
Manufacturer:
Rust-Oleum
Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
2. Hazard Identification
EMERGENCY OVERVIEW: Extremely flammable liquid and vapor. Vapors may cause flash fire or explosion. Harmful if
inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. Contents Under Pressure. May
cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if inhaled. Harmful if
swallowed. Causes eye irritation. Use ventilation necessary to keep exposures below recommended exposure limits, if
any. Vapor Harmful. Causes Eye, Skin, Nose, and Throat Irritation.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May be absorbed through the skin in harmful amounts. May cause
skin irritation. Allergic reactions are possible.
EFFECTS OF OVEREXPOSURE - INHALATION: High gas, vapor, mist or dust concentrations may be harmful if inhaled.
High vapor concentrations are irritating to the eyes, nose, throat and lungs. Harmful if inhaled. Avoid breathing fumes,
spray, vapors, or mist. Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated repeated and prolonged occupational
overexposure to solvents with permanent brain and nervous system damage. IARC lists Ethylbenzene as a possible
human carcinogen (group 2B). May cause central nervous system disorder (e.g., narcosis involving a loss of
coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. High concentrations may
lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision)
and/or damage.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
3. Composition/Information On Ingredients
384
Chemical Name
CAS-No.
Weight %
Less Than
ACGIH TLVTWA
ACGIH TLVSTEL
OSHA
TWA
PEL- OSHA PELCEILING
Zinc
Toluene
Liquefied Petroleum Gas
Mineral Spirits
Stoddard Solvents
Ethylbenzene
Amorphous Silica
7440-66-6
108-88-3
68476-86-8
64742-88-7
8052-41-3
100-41-4
7631-86-9
50.0
25.0
20.0
10.0
5.0
1.0
1.0
10
mg/m3
(Dust)
20 ppm
N.E.
100 ppm
100 ppm
20 ppm
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
125 ppm
N.E.
15
mg/m3
(Dust)
200 ppm
N.E.
100 ppm
500 ppm
100 ppm
0.8 mg/m3
N.E.
300 ppm
N.E.
N.E.
N.E.
N.E.
N.E.
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get
medical attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if
irritation develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in
breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: If swallowed, get medical attention.
5. Fire-fighting Measures
Flash Point, °F
-156 (Setaflash)
Extinguishing Media:
Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20 °. F. - EXTREMELY FLAMMABLE LIQUID AND
VAPOR!Water spray may be ineffective. Closed containers may explode when exposed to extreme heat due to buildup of
steam. Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air.
Vapors can travel to a source of ignition and flash back. Isolate from heat, electrical equipment, sparks and open flame.
Perforation of the pressurized container may cause bursting of the can. No unusual fire or explosion hazards noted. Keep
containers tightly closed.
SPECIAL FIREFIGHTING PROCEDURES: Full protective equipment including self-contained breathing apparatus should be
used. Evacuate area and fight fire from a safe distance. Water may be used to cool closed containers to prevent pressure
buildup and possible autoignition or explosion. Use water spray to keep fire-exposed containers cool. Containers may
explode when heated.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use
combustible materials such as sawdust. Isolate the hazard area and deny entry to unnecessary and unprotected personnel.
Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of
according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Ventilate area, isolate
spilled material, and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in
accordance with local, state, and federal regulations.
7. Handling and Storage
385
HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder
before reuse. Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied
because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Contents under
pressure. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of NFPA Class I
flammable liquids. Product should be stored in tightly sealed containers and protected from heat, moisture, and foreign
materials. Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep away from heat,
sparks, flame and sources of ignition. Avoid excess heat.
8. Exposure Controls/Personal Protection
ENGINEERING CONTROLS: Use explosion-proof ventilation equipment. Provide general dilution of local exhaust
ventilation in volume and pattern to keep TLV of hazardous ingredients below acceptable limits. Prevent build-up of
vapors by opening all doors and windows to achieve cross-ventilation. Use process enclosures, local exhaust ventilation,
or other engineering controls to control airborne levels below recommended exposure limits.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements
must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying
respirator with organic vapor cartridge or canister may be permissible under certain circumstances where airborne
concentrations are expected to exceed exposure limits.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin
protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding
types of personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated
clothing immediately and launder before reuse.
9. Physical and Chemical Properties
Vapor Density
Heavier than Air
Odor:
Solvent Like
Appearance:
Liquid
Evaporation Rate:
Faster than Ether
Solubility in Water:
Slight
Freeze Point:
N.D.
Specific Gravity:
1.318
pH:
N.A.
Physical State:
Liquid
(See section 16 for abbreviation legend)
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid temperatures above 120 ° F. Avoid contact with strong acid and strong bases. Avoid all
possible sources of ignition.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition,
it emits acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and
formaldehyde.
386
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological Information
Chemical Name
LD50
LC50
Zinc
N.E.
N.E.
>26,700 ppm (Rat,
Inhalation, 1Hr)
N.E.
>1400 ppm (Rat, Inhalation,
4Hr)
N.E.
N.E.
>250 mg/m3 (Rat, 6Hr)
Toluene
Liquefied Petroleum Gas
636 mg/kg (Rat, Oral)
N.E.
Mineral Spirits
Stoddard Solvents
Ethylbenzene
Amorphous Silica
>5000 mg/kg (Rat, Oral)
>5000 mg/kg (Rat, Oral)
3500 mg/kg (Rat, Oral)
>7500 mg/kg (Rat)
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state and federal regulations and ordinances. Do not
allow to enter waterways, wastewater. soil, storm drains or sewer systems.
14. Transport Information
Domestic (USDOT)
UN Number:
N.A.
International (IMDG)
1950
Air (IATA)
TDG (Canada)
1950
N.A.
Paint Products in
Proper Shipping Name:
Paint Products in
Aerosols
Aerosols
Limited Quantities
Limited Quantities
Hazard Class:
N.A.
2.1
2.1
N.A.
Packing Group:
Limited Quantity:
N.A.
Yes
N.A.
Yes
N.A.
Yes
N.A.
Yes
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312
of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable
definitions, to meet the following categories:
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
387
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name
CAS-No.
Zinc
Toluene
Zinc Oxide
Xylene
Ethylbenzene
Aluminum Oxide
7440-66-6
108-88-3
1314-13-2
1330-20-7
100-41-4
1344-28-1
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if
exported from the United States:
No TSCA 12(b) components exist in this product.
International Regulations:
CANADIAN WHMIS:
This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
Canadian WHMIS Class:
AB5 D2A
16. Other Information
HMIS Ratings:
Health:
2*
Flammabili
4
ty:
Physical
Hazard:
0
Flammabili
4
ty:
Instability
0
Personal
Protection:
X
NFPA Ratings:
Health:
2
VOLATILE ORGANIC COMPOUNDS, g/L:
610
Regulatory
REASON FOR REVISION:
Update
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein
to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and
storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property
damage incurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied,
regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown
hazards and should be used with caution. The information and recommendations in this material safety data sheet are
offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of
this information and to comply with all applicable international, federal, state, and local laws and regulations.
388
Penetrating Oil
Material Safety Data Sheet
MSDS The Blaster Corporation
PB Penetrating Catalyst
MSDS Number: PB - bulk
1
Revision Date: 11/15/10
Page 1 of 6
PRODUCT AND COMPANY IDENTIFICATION
Product Name:
Revision Date:
MSDS Number:
Common Name:
Product Code:
PB Penetrating Catalyst
11/15/10
PB - bulk
PB Blaster
128-PB, 5-PB & 55-PB
Manufacturer:
The Blaster Corporation
8500 Sweet Valley Drive
Valley View, Ohio 44125
(216) 901-5800
(216)
901-5801
fax
www.blasterproducts.com
24 Hour emergency contact:
3
Route of Entry:
Target Organs:
Inhalation:
Skin Contact:
Eye Contact:
Ingestion:
Chemtrec (800) 424-9300
HAZARDS IDENTIFICATION
Eyes, skin, inhalation, ingestion
Inhalation of spray mist may cause irritation to the respiratory tract.
Repeated or prolonged contact with skin may cause mild irritation and possibly dermatitis.
Likely to cause immediate or delayed irritaion. Irritationwill show as redness and/or swelling of
the eyes.
Ingestion may cause irritation to the mouth, esophagus and stomach.
May aggravate pre-existing skin and respiratory disorders.
Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and
nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or
fatal.
Inhalation:
Skin Contact:
Eye Contact:
389
FIRST AID MEASURES
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Continue to monitor. Get medical attention.
Remove contaminated clothing immediately! Wash skin with soap and water. If irritation
develops, seek medical attention.
Flush eye(s) with water for 15 minutes. Get medical attention. If eye irritation persists,
obtain medical treatment.
Do not induce vomiting! Get medical attention immediately!
Ingestion:
5
FIRE FIGHTING MEASURES
o
Flash point: 150 F (TCC) minimum
Extinguishing Media: Dry chemical, carbon dioxide or foam is recommended. Water may be ineffective for extinguishment,
but can be useful in minimizing or dispersing vapors, protecting personnel and cooling containers. If containers are not
properly cooled they can rupture in the heat of a fire. Avoid spreading burning liquid with water used for cooling purposes.
6
ACCIDENTAL RELEASE MEASURES
In case of spill or release, avoid vapors and ignition sources. Use appropriate protective devices and absorbents. Stop and
contain the discharge if it can be done safely. Keep out of drains and waterways. Handle with trained personnel only.
Notify authorities as required by law.
7
HANDLING AND STORAGE
Handling Precautions: Use in accordance with good industrial workplace practices. Avoid unnecessary contact. Wash
thoroughly after handling. Use with good ventilation.
Storage Requirements: Store in a dry place away from excessive heat. Store containers with lids on and properly labeled.
8
Do not store at temperatures above 120 degrees F.
EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls:
Eye wash stations and emegency showers should be immediately available.
Protective Equipment:
Eyes and Face: Standard safety glasses with splash shields typically offer
adequate protection. Where excessive splashing or spraying is possible, a face shield
should be used.
Skin and clothing: Excessive contact should be avoided. Neoprene gloves, boots and
aprons will provide adequate protection when contact cannot be avoided. Remove and
wash any contaminated clothing immediately. Wash thoroughly after handling.
Respiratory: Good general ventilation should be sufficient to control airborne levels.
Maintain airborne concentrations below OSHA established exposure limits of
ingredients in Section 2. Use a NIOSH approved respirator if ventilation is not
adequate to maintain exposures below TLV levels.
390
Exposure Guidelines/Other:
9
The Blaster Corporation takes no responsibility for determining what measures are
required for personal protection in any specific application. This information should be
used with discretion.
PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Physical State:
Orange viscous oily
Liquid
Odor:
pH:
Heavy aromatic
Not determined
Vapor Pressure:
Not determined
Vapor Density:
>1 (air = 1)
Heat Value:
VOC:
Evap. Rate:
Bulk Density:
Octanol:
Molecular Weight:
Particle Size:
Softening Point:
Viscosity:
Percent Volatile:
Sat.
Vap.
Concentrat.:
Not determined
<50%
>1 (NBA = 1)
Not determined
Not applicable
Not determined
Not applicable
Not applicable
Not determined
Not determined
Molecular Formula:
Not determined
10
Boiling Point:
Freezing/Meltin
g Pt.:
Solubility:
Spec
Grav./Density:
352 F
Not determined
nil
0.91 (water = 1)
Not determined
STABILITY AND REACTIVITY
Stability:
This product is stable.
Conditions to avoid:
Materials to avoid (incompatability):
Avoid excessive heat, sources of ingition and excessive water.
Avoid contact with strong oxidizing agents and strong reducing agents (strong
acids or bases.) Avoid mixture with water.
Hazardous Decomposition products:
Carbon monoxide, carbon dioxide, and various hydrocarbons.
Hazardous Polymerization:
Will not occur.
11
TOXICOLOGICAL INFORMATION
Hydrotreated Light Distillates
64742-47-8
ACUTE STUDIES
EYE EFFECTS Slight irritation on contact.
SKIN EFFECTS May cause irritation or dermatitis with prolonged and repeated contact.
ACUTE ORAL EFFECTS Tests on similar materials indicate an order of acute oral toxicity.
ACUTE INHALATION EFFECTS Acute toxicity expected on inhalation.
This product is not listed as carcinogenic or a potential carcinogen by the National Toxicology Program, by the I.A.R.C.
monographs or by OSHA. Therefore, if the precautions outlined in this bulletin are followed to minimize repeated or
prolonged skin contact which could cause irritation, these oils should pose no carcinogenic hazard to humans. Prolonged
391
repeated skin contact with low viscosity materials may defat the skin resulting in possible irritation and dermatitis.
Nevertheless, good industrial hygienic practices are recommended.
Heavy Petroleum Distillate
64742-65-0
Contains: Naphthenic Oil
64742-53-6
INHALATION: Will not produce vapors unless heated to temperatures of ~300 F.º
EYE CONTACT: Irritating, but will not permanently injure eye tissue.
SKIN CONTACT: Prolonged or repeated contact may cause skin irritation.
INGESTION: Small amounts (tablespoonful) swallowed are not likely to cause injury. Larger
amounts may cause nausea and vomiting. Consult a physician promptly.
CHRONIC (CANCER) INFORMATION: IARC Monographs state that when laboratory animals are exposed to severely
hydrotreated oils, such as these product(s), there is insufficient evidence for cancer. Thus, these oils are Unlabeled in
accordance with 29 CFR 1910.1200.
Median Lethal Dose (LD50 LC50) (Species)
Oral: Believed to be >5g/kg (rat); practically non-toxic
Inhalation: Not Determined
Dermal: Believed to be >3 g/kg (rat); practically non-toxic.
Irritation Index Estimation of Irritation (Species).
Skin: Believed to be <0.5/8.0 (rabbit); no appreciable effect
Eyes: Believed to be <15/110 (rabbit); no appreciable effect
Sensitization: Not Available
Other: None
Aromatic Petroleum Distillates
64742-94-5
Over exposure to naphthalene, a minor component in heavy aromatic naphtha may cause skin, eye and respiratory tract
irritation, anemia, loss of vision, nervous system effects and kidney and thymus damage. Also exposure to naphthalene has
produced "respiratory tract" tumors in laboratory animals. IARC list Naphthalene as Group 2B (possibly carcinogenic to
humans).
Heavy Aromatic Solvent Naphtha
Naphthalene
64742-94-5
91-20-3
Pseudocumene
95-63-6
1-7OSHA (TWA): 10 ppm
ACGIH (TWA): 10 ppm
0-1
Dinonylphenol, ethoxylated, phosphated
39464-64-7
INHALATION: : Irritating
EYE CONTACT: Irritating, but will not permanently injure eye tissue.
SKIN CONTACT: Prolonged or repeated contact may cause skin irritation.
INGESTION: May cause irritation.
CHRONIC (CANCER) INFORMATION: Not listed
No known long term effects.
12
ECOLOGICAL INFORMATION
Ecological information on this product as a mixture has not been determined.
13
DISPOSAL CONSIDERATIONS
If this product becomes a waste, it would be expected to meet the criteria of a RCRA hazardous waste for the characteristic
of ignitability with a waste code of D001. (See 40 CFR Part 261.20 - 261.33) It is the responsibility of the generator to
determine at the time of disposal the proper classification and method of disposal
392
All disposal activities must comply with federal, state and local regulations. Local regulations may be more stringent than
state or national requirements.
14
TRANSPORT INFORMATION
Not regulated as a hazardous material.
Please contact The Blaster Corporation for clarification or questions regarding proper shipping information.
15
REGULATORY INFORMATION
Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) 103 Reportable Quantity: This product
is not subject to CERCLA reporting requirements, however, oil spills are reportable to the National Response Center under
the Clean Water Act and many states have more stringent release reporting requirements. Report spills required under
federal, state and local regulations.
Superfund Amendments Reauthorization Act (SARA TITLE) III:
Hazard Category For Section 311/312: Acute Health, Fire Hazard, Sudden Release of Pressure
Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313 Reporting
requirements: None
Section 302 Extremely Hazardous Substances (TPQ): None
EPA Toxic Substances Control Act (TSCA) Status: All of the components of this product are listed on the TSCA inventory.
California Safe Drinking Water and Toxic Enforcement Act (Proposition 65): This product contains a chemical known to the
State of California to cause cancer.
VOC Regulations: This product complies with the consumer product VOC limits of CARB, the US EPA and states adopting
the OTC VOC rules.
Consumer Product Safety Act General Conformity Certification: This product was evaluated by The Blaster Corporation,
and is certified to be in compliance with the provisions of the Consumer Product Safety Act, the Federal Hazardous
Substances Act and the Poison Prevention Packaging Act, as applicable. This product was manufactured at the location listed
in Section 1 of this MSDS. The date of manufacture is stamped on the product container. No testing is required to certify
compliance with the above.
16
OTHER INFORMATION
Manufacturer's Disclaimer:
To the best of our knowledge, the information contained herein is accurate. However, neither The Blaster Chemical
Companies nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the
information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All
materials may present unknown hazards and should be used with caution. Although certain hazards are described herein,
we cannot guarantee that these are the only hazard which exist.
HMIS Ratings:
Health:
Fire:
Reacitivity:
2
2
0
NFPA Ratings:
Health:
Fire:
Reacitivity:
2
2
0
393
394
395
WD-40
Safety Data Sheet
All 50 State Compliant
1 - Identification
Product Name: WD-40 EZ-REACH™ Multi-Use
Product Aerosol
Product Use: Lubricant, Penetrant, Drives Out
Moisture, Removes and Protects Surfaces From
Corrosion
Restrictions on Use: None identified
SDS Date Of Preparation: 07/20/2014
Manufacturer: WD-40 Company
Address:
1061 Cudahy Place (92110)
P.O. Box 80607
San Diego, California, USA
92138 –0607
Telephone:
Emergency only: 1-888-324-7596 (PROSAR)
Information:
1-888-324-7596
Chemical Spills: 1-800-424-9300 (Chemtrec)
1-703-527-3887 (International Calls)
2 – Hazards Identification
Hazcom 2012/GHS Classification:
Flammable Aerosol Category 1
Gas Under Pressure: Compressed Gas
Aspiration Toxicity Category 1
Note: This product is a consumer product and is labeled in accordance with the US Consumer Product Safety
Commission regulations which take precedence over OSHA Hazard Communication labeling. The actual container
label will not include the label elements below. The labeling below applies to industrial/professional products.
Label Elements:
DANGER!
Extremely Flammable Aerosol.
Contains gas under pressure; may explode if heated.
May be fatal if swallowed and enters airways.
Prevention
Keep away from heat, sparks, open flames, hot surfaces – No smoking.
Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.
Response
IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting.
Storage
Store locked up.
Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Store in a well-ventilated place.
Disposal
Dispose of contents and container in accordance with local and national regulations.
3 - Composition/Information on Ingredients
Ingredient
CAS #
Weight Percent
LVP Aliphatic Hydrocarbon
64742-47-8
45-50
Aliphatic Hydrocarbon
Petroleum Base Oil
64742-47-8
64742-56-9
64742-65-0
64742-53-6
64742-54-7
64742-71-8
Mixture
<25
<25
Non-Hazardous Ingredients
US Hazcom 2012/ GHS
Classification
Flammable Liquid Category 3
Aspiration Toxicity Category 1
Aspiration Toxicity Category 1
Not Hazardous
396
<10
Not Hazardous
Carbon Dioxide
124-38-9
2-3
Note: The specific chemical identity and exact percentages are a trade secret.
Simple Asphyxiant
4 – First Aid Measures
Ingestion (Swallowed): Aspiration Hazard. DO NOT induce vomiting. Call physician, poison control center or the
WD-40 Safety Hotline at 1-888-324-7596 immediately.
Eye Contact: Flush thoroughly with water. Remove contact lenses if present after the first 5 minutes and
continue flushing for several more minutes. Get medical attention if irritation persists.
Skin Contact: Wash with soap and water. If irritation develops and persists, get medical attention. Inhalation
(Breathing): If irritation is experienced, move to fresh air. Get medical attention if irritation or other symptoms
develop and persist.
Signs and Symptoms of Exposure: May cause eye and respiratory irritation. Inhalation may cause
coughing, headache and dizziness. Skin contact may cause drying of the skin.
Indication of Immediate Medical Attention/Special Treatment Needed: Immediate medical attention is needed for
ingestion.
5 – Fire Fighting Measures
Suitable (and unsuitable) Extinguishing Media: Use water fog, dry chemical, carbon dioxide or foam. Do not use
water jet or flooding amounts of water. Burning product will float on the surface and spread fire. Specific Hazards
Arising from the Chemical: Contents under pressure. Keep away from ignition sources and open flames. Exposure
of containers to extreme heat and flames can cause them to rupture often with violent force. Vapors are heavier
than air and may travel along surfaces to remote ignition sources and flash back. Combustion will produce oxides
of carbon and hydrocarbons.
Special Protective Equipment and Precautions for Fire-Fighters: Firefighters should always wear positive pressure
self-contained breathing apparatus and full protective clothing. Cool fire-exposed containers with water. Use
shielding to protect against bursting containers.
6 – Accidental Release Measures
Personal Precautions, Protective Equipment and Emergency Procedures: Wear appropriate protective clothing
(see Section 8). Eliminate all sources of ignition and ventilate area.
Methods and Materials for Containment/Cleanup: Leaking cans should be placed in a plastic bag or open pail until
the pressure has dissipated. Contain and collect liquid with an inert absorbent and place in a container for disposal.
Clean spill area thoroughly. Report spills to authorities as required.
7 – Handling and Storage
Precautions for Safe Handling: Avoid contact with eyes. Avoid prolonged contact with skin. Avoid breathing vapors
or aerosols. Use only with adequate ventilation. Keep away from heat, sparks, pilot lights, hot surfaces and open
flames. Unplug electrical tools, motors and appliances before spraying or bringing the can near any source of
electricity. Electricity can burn a hole in the can and cause contents to burst into flames. To avoid serious burn
injury, do not let the can touch battery terminals, electrical connections on motors or appliances or any other
source of electricity. Wash thoroughly with soap and water after handling. Keep containers closed when not in use.
Keep out of the reach of children. Do not puncture, crush or incinerate containers, even when empty.
Conditions for Safe Storage: Store in a cool, well-ventilated area, away from incompatible materials Do not store
above 120°F or in direct sunlight. U.F.C (NFPA 30B) Level 3 Aerosol. Store away from oxidizers.
8 – Exposure Controls/Personal Protection
Chemical
Occupational Exposure Limits
LVP Aliphatic Hydrocarbon
1200 mg/m3 TWA (manufacturer recommended)
Aliphatic Hydrocarbon
1200 mg/m3 TWA (manufacturer recommended)
Petroleum Base Oil
Carbon Dioxide
5 mg/m3 TWA, 10 mg/m3 STEL ACGIH TLV
5 mg/m3 TWA OSHA PEL
5000 ppm TWA (OSHA/ACGIH), 30,000 ppm STEL (ACGIH)
Non-Hazardous Ingredients
None Established
397
The Following Controls are Recommended for Normal Consumer Use of this Product
Appropriate Engineering Controls: Use in a well-ventilated area.
Personal Protection:
Eye Protection: Avoid eye contact. Always spray away from your face.
Skin Protection: Avoid prolonged skin contact. Chemical resistant gloves recommended for operations where
skin contact is likely.
Respiratory Protection: None needed for normal use with adequate ventilation.
For Bulk Processing or Workplace Use the Following Controls are Recommended
Appropriate Engineering Controls: Use adequate general and local exhaust ventilation to maintain exposure
levels below that occupational exposure limits.
Personal Protection:
Eye Protection: Safety goggles recommended where eye contact is possible. Skin
Protection: Wear chemical resistant gloves.
Respiratory Protection: None required if ventilation is adequate. If the occupational exposure limits are exceeded,
wear a NIOSH approved respirator. Respirator selection and use should be based on contaminant type, form and
concentration. Follow OSHA 1910.134, ANSI Z88.2 and good Industrial Hygiene practice. Work/Hygiene Practices:
Wash with soap and water after handling.
9 – Physical and Chemical Properties
Appearance:
Light amber liquid
Odor:
Odor Threshold:
pH:
Melting/Freezing Point
Boiling Point/Range:
Evaporation Rate:
Mild petroleum odor
Not established
Not Applicable
Not established
361 - 369°F (183 187°C)
138°F (59°C) Tag Closed
Cup (liquid)
Not established
Flammability (solid, gas)
VOC:
Flammable Aerosol
206 grams/liter (25%)
Flash Point:
Flammable Limits:
(Solvent Portion)
Vapor Pressure:
Vapor Density:
Relative Density:
Solubilities:
Partition Coefficient; noctanol/water:
Autoignition
Temperature:
Decomposition
Temperature:
Viscosity:
Pour Point:
LEL: 0.6% UEL: 8%
95-115 PSI @ 70°F
Greater than 1 (air=1)
0.8 – 0.82 @ 60°F
Insoluble in water
Not established
Not established
Not established
2.79-2.96 cSt @ 100°F
-63°C (-81.4°F ) ASTM
D-97
10 – Stability and Reactivity
Reactivity: Not reactive under normal conditions
Chemical Stability: Stable
Possibility of Hazardous Reactions: May react with strong oxidizers generating heat.
Conditions to Avoid: Avoid heat, sparks, flames and other sources of ignition. Do not puncture or incinerate
containers.
Incompatible Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide and carbon dioxide.
11 – Toxicological Information
Symptoms of Overexposure:
Inhalation: High concentrations may cause nasal and respiratory irritation and central nervous system effects such as
headache, dizziness and nausea. Intentional abuse may be harmful or fatal.
Skin Contact: Prolonged and/or repeated contact may produce mild irritation and defatting with possible
dermatitis.
Eye Contact: Contact may be irritating to eyes. May cause redness and tearing.
Ingestion: This product has low oral toxicity. Swallowing may cause gastrointestinal irritation, nausea, vomiting and
diarrhea. This product is an aspiration hazard. If swallowed, can enter the lungs and may cause chemical
pneumonitis, severe lung damage and death.
Chronic Effects: None expected.
398
Carcinogen Status: None of the components are listed as a carcinogen or suspect carcinogen by IARC, NTP,
ACGIH or OSHA.
Reproductive Toxicity: None of the components is considered a reproductive hazard.
Numerical Measures of Toxicity:
Acute Toxicity Estimates: Oral > 5,000 mg/kg; Dermal >2,000 mg/kg based on an assessment of the
ingredients. This product is not classified as toxic by established criteria. It is an aspiration hazard.
12 – Ecological Information
Ecotoxicity: No specific aquatic toxicity data is currently available, however components of this product are not
expected to be harmful to aquatic organisms
Persistence and Degradability: Component are readily biodegradable.
Bioaccumulative Potential: Bioaccumulation is not expected based on an assessment of the ingredients.
Mobility in Soil: No data available
Other Adverse Effects: None known
13 - Disposal Considerations
If this product becomes a waste, it would be expected to meet the criteria of a RCRA ignitable hazardous waste (D001).
However, it is the responsibility of the generator to determine at the time of disposal the proper classification
and method of disposal. Do not puncture or incinerate containers, even empty. Dispose in accordance with federal,
state, and local regulations.
14 – Transportation Information_
DOT Surface Shipping Description: UN1950, Aerosols, 2.1 Ltd. Qty (Note: Shipping Papers are not required for Limited
Quantities unless transported by air or vessel – each package must be marked with the Limited Quantity Mark)
IMDG Shipping Description: Un1950, Aerosols, 2.1, LTD QTY
ICAO Shipping Description: UN1950, Aerosols, flammable, 2.1 NOTE: WD-40 does not test aerosol cans to assure
that they meet the pressure and other requirements for transport by air. We do not recommend that our aerosol
products be transported by air.
15 – Regulatory Information
U.S. Federal Regulations:
CERCLA 103 Reportable Quantity: This product is not subject to CERCLA reporting requirements, however, oil
spills are reportable to the National Response Center under the Clean Water Act and many states have more
stringent release reporting requirements. Report spills required under federal, state and local regulations.
SARA TITLE III:
Hazard Category For Section 311/312: Acute Health, Fire Hazard, Sudden Release of Pressure Section 313
Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313
Reporting requirements: None
Section 302 Extremely Hazardous Substances (TPQ): None
EPA Toxic Substances Control Act (TSCA) Status: All of the components of this product are listed on the TSCA
inventory.
California Safe Drinking Water and Toxic Enforcement Act (Proposition 65): This product does not
contain chemicals regulated under California Proposition 65.
VOC Regulations: This product complies with the consumer product VOC limits of CARB, the US EPA and states
adopting the OTC VOC rules.
Canadian Environmental Protection Act: One of the components is listed on the NDSL. All of the other
ingredients are listed on the Canadian Domestic Substances List or exempt from notification.
Canadian WHMIS Classification: Class A (Compressed Gas), Class B-5 (Flammable Aerosol)
This MSDS has been prepared according to the criteria of the Controlled Products Regulation (CPR) and the MSDS
contains all of the information required by the CPR.
16 – Other Information:
HMIS Hazard Rating:
Health – 1 (slight hazard), Fire Hazard – 4 (severe hazard), Reactivity – 0 (minimal hazard)
399
Revision Date: July 20, 2014
Supersedes: May 23, 2014
Revision Summary: Convert to Hazcom 2012. Changes in all sections.
Prepared by: Industrial Health & Safety Consultants, Inc. Shelton, CT, USA
Reviewed By: I. Kowalski
Manager Regulatory Affairs
400
Black Flag Wasp & Hornet Killer
SAFETY DATA SHEET
Chemsico
Division of United Industries Corp
P.O. Box 142642
St. Louis, MO 63114-0642
SDS Date:
Product Name:
Product Name:
Phone:
Items:
Formula Code:
Black Flag Wasp Hornet & Yellowjacket
Killer
1-800-887-3524
HG-11036
21-1058, 21-0666, 01-1006
2/25/15
Black Flag Wasp, Hornet & Yellow Jacket Killer
EPA Reg. No. 9688-190
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
CAS #:
Product Use:
Aerosol
Wasp & Hornet Killer Aerosol
Manufacturer:
Chemsico
Div. of United Industries Corp.
P.O. Box 142642
St. Louis, MO 63114
SECTION 2 - HAZARDS IDENTIFICATION
This product is classified according the Globally Harmonized System (GHS).
ROUTES OF EXPOSURE
Potential short term health effects:
Skin contact, Ingestion
Eyes:
No reaction expected.
Skin:
May cause irritation.
Inhalation:
No expected reaction.
Ingestion:
May be harmful if swallowed.
Target organs:
Skin, Digestive system
Chronic effects:
Prolonged or repeated exposure can cause drying,
defatting and dermatitis.
Signs and symptoms:
Symptoms may include redness, edema, drying, defatting
and cracking of the skin.
SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS
Composition comments:
This product is considered not hazardous under 29 CFR
1910.1200 (Hazard Communication).
NOTE: No reportable quantities of hazardous ingredients are present per OSHA 29 CFR 1910.1200. No
toxic chemical(s) subject to reporting requirements of Section 313 of Title III and 40 CFR 372 are
present.
ACTIVE COMPONENT
Lambda-cyhalothrin
CAS#
91465-08-6
PERCENTAGE
0.010%
401
Prallethrin
Petroleum Distillates
Butyl Propasol
Propane
23031-36-9
64742-47-8
5131-66-8
74-98-6
OTHER COMPONENT
Other
CAS#
N/A
0.025%
3.500%
3.000%
3.500%
PERCENTAGE
89.965
Note: Ingredients not identified are not hazardous.
Chemsico
Division of United Industries
Corp P.O. Box 142642
St. Louis, MO 63114-0642
Product Name:
Phone:
Items:
Formula Code:
Black Flag Wasp Hornet & Yellowjacket
Killer
1-800-887-3524
HG-11036
21-1058, 21-0666, 01-1006
SECTION 4 - FIRST AID MEASURES
FIRST AID PROCEDURES
None required
Skin contact:
Flush with large amounts of cool water. Wash with soap
and water. Remove contaminated clothing and wash
before reuse. Obtain medical attention if irritation
persists.
Inhalation:
None required
Ingestion:
Immediately call a Poison Control Center or doctor. Do not
induce vomiting unless told to do so. Do not give any
liquid to the person. Do not give anything by mouth to an
unconscious person.
Note to Physician:
Symptoms may be delayed.
General advice:
If you feel unwell, seek medical advice (show the label
where possible). Ensure that medical personnel are aware
of the material(s) involved, and take precautions to protect
themselves. Keep out of reach of children.
Eye contact:
SECTION 5 - FIRE FIGHTING MEASURES
Flammable properties:
Pressurized Aerosol Container
SUITABLE EXTINGUISHING MEDIA
Extinguishing media:
Water Fog, Foam, CO2, Dry Chemical
Unsuitable extinguishing media:
Not Available
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL
Protection of firefighters:
Protective equipment for firefighters:
Hazardous combustion products:
Not Available
Firefighters should wear full protective clothing
including self-contained breathing apparatus.
None known
SENSITIVITY TO MECHANICAL IMPACT
Explosion data:
Not Available
Sensitivity to static discharge:
Not Available
Personal precautions:
Keep unnecessary personnel away. Do not touch or walk
402
through spilled material.
HMIS Ratings
Health Hazard 1
Fire Hazard 2 Reactivity 0
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Methods for containment: Prevent entry into waterways, sewers, basements or confined areas.
Chemsico
Division of United Industries Corp
P.O. Box 142642
St. Louis, MO 63114-0642
Methods for cleaning up:
Product Name:
Phone:
Items:
Formula Code:
Black Flag Wasp Hornet & Yellowjacket
Killer
1-800-887-3524
HG-11036
21-1058, 21-0666, 01-1006
Before attempting clean up, refer to hazard data given
above. Small spills may be absorbed with earth, sand or
absorbent material swept up and placed in suitable,
covered, and labeled containers. Prevent large spills from
entering sewers or waterways. Contact emergency
services and supplier for advice. Never return spills in
original containers for re-use.
SECTION 7 - HANDLING AND STORAGE
Handling:
Use good industrial hygiene practices in handling this
material.
Storage:
Keep out of reach of children. Store in a closed container
away from incompatible materials.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls:
General ventilation normally adequate.
EYE / FACE PROTECTION
Personal protective equipment:
None required
Hand protection:
None required
Skin and body protection:
None required
Respiratory protection:
None required
General hygiene considerations:
Handle in accordance with good industrial hygiene and
safety practice. When using, do not eat or drink. Wash
hands before breaks and immediately after handling the
product.
SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES
Appearance:
Clear
Color:
Light yellow to water-white
Form:
Aerosol
Odor:
Aromatic solvent (slight)
Odor threshold:
Not Available
Physical state:
Pressurized liquid
pH:
5-6
Freezing point:
32°F
403
Boiling point:
212°F
Flash point:
Flame Extension
119 F (liquid portion)
0” (level 1 aerosol)
Flammability limits in air,
lower, % by volume:
Not Available
Chemsico
Division of United Industries Corp
P.O. Box 142642
St. Louis, MO 63114-0642
0
Product Name:
Phone:
Items:
Formula Code:
Flammability limits in air,
upper, % by volume:
Not Available
Vapor pressure:
Not Available
Vapor density:
Not Available
Specific gravity:
0.973
Octanol/water coefficient:
Not Available
Auto-ignition temperature:
Not Available
Black Flag Wasp Hornet & Yellowjacket
Killer
1-800-887-3524
HG-11036
21-1058, 21-0666, 01-1006
SECTION 10 - CHEMICAL STABILITY & REACTIVITY INFORMATION
Chemical stability:
Stable under recommended storage conditions.
Conditions to avoid:
Do not mix with other chemicals.
Incompatible materials:
Avoid strong oxidizers.
Hazardous decomposition products:
None known.
Possibility of hazardous reactions:
Hazardous polymerization does not occur.
SECTION 11 - TOXICOLOGICAL INFORMATION
EFFECTS OF ACUTE EXPOSURE
Eye:
May cause irritation.
Skin:
May cause irritation. LD50 >5000 mg/kg
Inhalation:
LC50 > 2mg/L (EPA Tox category IV)
Ingestion:
LD50 > 3000 mg/kg
Sensitization:
Not a skin sensitizer.
Chronic effects/ Carcinogenicity:
Not Available
Mutagenicity:
Not Available
Reproductive effects:
Not Available
Teratogenicity:
Not Available
Ecotoxicity:
Not Available
SECTION 12 - ECOLOGICAL INFORMATION
Environmental effects:
Not Available
Aquatic toxicity:
Toxic to aquatic organisms
Persistence / degradability:
Not Available
Bioaccumulation / accumulation:
Not Available
404
Partition coefficient:
Not Available
Mobility in environmental media:
Not Available
Chemical fate information:
Not Available
Chemsico
Division of United Industries Corp
P.O. Box 142642
St. Louis, MO 63114-0642
Product Name:
Phone:
Items:
Formula Code:
Black Flag Wasp Hornet & Yellowjacket
Killer
1-800-887-3524
HG-11036
21-1058, 21-0666, 01-1006
SECTION 13 - DISPOSAL CONSIDERATIONS
Waste codes:
Disposal instructions:
Waste from residues / unused products:
Contaminated packaging:
Not Available
Dispose in accordance with all applicable regulations.
Not Available
Not Available
SECTION 14 - TRANSPORTATION INFORMATION
U.S. Department of Transportation
(DOT):
Aerosols, Flammable, 2.1, UN-1950, Limited Quantity
U.S. Federal regulations:
This product is not known to be a "Hazardous Chemical" as
defined by the OSHA Hazard Communication Standard, 29
CFR 1910.1200. All components are on the U.S. EPA TSCA
Inventory List.
IATA:
1950, Aerosols, Flammable, 2.1
IMDG:
1950, Aerosols, 2.1 (lambda-cyhalothrin), Marine
Pollutant, Limited Quantity
SECTION 15 - REGULATORY INFORMATION
29 CFR 1910.1200 hazardous chemical
Occupational Safety and Health
Administration (OSHA):
CERCLA (Superfund) reportable
No
405
quantity:
Not Available
HAZARD CATEGORIES
Superfund Amendments and Reauthorization Act of 1986 (SARA):
Immediate Hazard
Delayed Hazard
Fire Hazard
Pressure Hazard
Reactivity Hazard
No
No
No
No
No
Section 302 extremely hazardous
Substance:
No
Section 311 hazardous chemical:
No
Clean Air Act (CAA):
Not Available
Clean Water Act (CWA):
Not Available
State regulations:
INVENTORY STATUS
Inventory Country(s) or region name
on inventory (yes/no)*:
Chemsico
Division of United Industries Corp
P.O. Box 142642
St. Louis, MO 63114-0642
Disclaimer:
N/A, Regulated by EPA
Product Name:
Phone:
Items:
Formula Code:
Black Flag Wasp Hornet & Yellowjacket
Killer
1-800-887-3524
HG-11036
21-1058, 21-0666, 01-1006
Information contained herein was obtained from sources
considered technically accurate and reliable. While every
effort has been made to ensure full disclosure of product
hazards, in some cases data is not available and is so
stated. Since conditions of actual product use are beyond
control of the supplier, it is assumed that users of this
material have been fully trained according to the
requirements of all applicable legislation and regulatory
instruments. No warranty, expressed or implied, is made
and supplier will not be liable for any losses, injuries or
consequential damages which may result from the use of
or reliance on any information contained in this document.
SECTION 16 - OTHER INFORMATION
Issue date:
2/25/15
406
Kopr-Shield
SAFETY DATA SHEET
1. Identification
Product identifier
Kopr-Shield
Other means of identification
SDS number
Product code
Recommended use
Recommended restrictions
SDS-00003
201-31879, 201-31879-1, CP128, CP16, CP8-TB, 54865CK
Lubricants, Greases and Release Products
None known.
Manufacturer/Importer/Supplier/Distributor information
Company name
Thomas & Betts Corporation
Address
8155 T & B Boulevard
Memphis, TN 38125
US
Telephone
901-252-5000 ext.8324
E-mail
Not available.
Emergency phone number
For Hazardous Materials [or Dangerous Goods] Incident
Spill, Leak, Fire, Exposure, or Accident
Call CHEMTREC Day or Night
+1 703-741-5970
2. Hazard(s) identification
Physical hazards
Health hazards
OSHA defined hazards
Label elements
Not classified.
Not classified.
Not classified.
Hazard symbol
None.
Signal word
Hazard statement
None.
The mixture does not meet the criteria for classification.
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
Observe good industrial hygiene practices.
Wash hands after handling.
Store away from incompatible materials.
Dispose of waste and residues in accordance with local authority
requirements.
None known.
Very toxic to aquatic life. Harmful to aquatic life with long lasting effects.
3. Composition/information on ingredients
Mixtures
Chemical name
Lubricating greases; a complex
CAS number
74869-21-9
%
65 - 70
408
combination of hydrocarbons
having carbon numbers
predominantly in the range of
C12 through C50. May contain
organic salts of alkali metals,
alkaline earth metals, etc.
Copper
7440-50-8
25-30
Zinc
bis(dipentyldithiocarbamate)
15337-18-5
<1
SDS
US
Kopr-Shield
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
4. First-aid measures
Inhalation
Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact
Wash off with soap and water. Get medical attention if irritation develops and persists.
Eye contact
Rinse with water. Get medical attention if irritation develops and persists.
Ingestion
Rinse mouth. Get medical attention if symptoms occur.
Most important
symptoms/effects, acute and
delayed
Direct contact with eyes may cause temporary irritation.
Indication of immediate
medical attention and special
treatment needed
Treat symptomatically.
General information
Ensure that medical personnel are aware of the material(s) involved, and take
precautions to protect themselves.
5. Fire-fighting measures
Suitable
media
extinguishing Specific hazards arising from the chemical
Special protective equipment and precautions for firefighters
Fire fighting equipment/instructions
Unsuitable
extinguishing media
409
Use
extinguishing
measures that are
appropriate to local
circumstances and the
surrounding
environment.
Do not use water jet as an
extinguisher, as this will
spread the fire.
None known.
Firefighters should wear full protective clothing including self contained breathing
apparatus. Wear suitable protective equipment.
Use standard firefighting procedures and consider the hazards of other involved
materials.
Specific methods
materials.
Use standard firefighting procedures and consider the hazards of other involved
General fire hazards
No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal
precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Keep unnecessary personnel away. For personal protection, see section 8
of the SDS. Wear suitable protective clothing, gloves and eye/face
protection.
Stop leak if you can do so without risk. Prevent entry into waterways, sewers,
basements or confined areas. The product is immiscible with water and will
spread on the water surface. Should not be released into the environment. Be
aware of potential for surfaces to become slippery.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled
material, where this is possible. Cover with plastic sheet to prevent spreading.
Absorb in vermiculite, dry sand or earth and place into containers. Following
product recovery, flush area with water.
Environmental precautions
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean
surface thoroughly to remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see
section 13 of the SDS. Prevent further leakage or spillage if safe
to do so. Do not contaminate water.
7. Handling and storage
Conditions for safe storage, including any incompatibilities
Precautions for safe handling
410
Wear
personal
protective
equipment. Avoid contact with
skin, eyes and clothing. Remove
contaminated clothing and
wash before reuse. Do not
breathe vapors or spray mist. In
8. Exposure controls/personal protection
case of insufficient ventilation, wear suitable respiratory equipment. Use
only in area provided with appropriate exhaust ventilation. Be aware of
potential for surfaces to become slippery. Do not eat, drink or smoke
when using the product.
Keep container tightly closed in a dry and well-ventilated place. Keep
out of the reach of children. Store away from incompatible materials
(see Section 10 of the SDS).
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
Copper (CAS 7440-50-8)
Type
PEL
Value
1 mg/m3
0.1 mg/m3
Form
Dust and mist.
Fume.
Type
TWA
Value
1 mg/m3
0.2 mg/m3
Form
Dust and mist.
Fume.
US. ACGIH Threshold Limit Values
Components
Copper (CAS 7440-50-8)
US. NIOSH: Pocket Guide to Chemical Hazards
Components
Copper (CAS 7440-50-8)
Biological limit values
Type
Value
TWA
1 mg/m3
No biological exposure limits noted for the ingredient(s).
Form
Dust and mist.
Exposure guidelines
current
No exposure standards allocated. Occupational Exposure Limits are not relevant to the
physical form of the product.
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation
rates should be matched to conditions. If applicable, use process enclosures, local
exhaust ventilation, or other engineering controls to maintain airborne levels below
recommended exposure limits. If exposure limits have not been established, maintain
airborne levels to an acceptable level.
Appropriate
engineering
controls
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin
protection
Hand
Wear appropriate chemical resistant gloves. Suitable gloves can be recommended
by the glove supplier.
protection
Skin protection
Other
Respiratory
protection
Wear apron or protective clothing in case of contact. Use of protective coveralls
and long sleeves is recommended.
In case of insufficient ventilation, wear suitable
Thermal hazards
respiratory equipment. Wear appropriate thermal
General hygiene
protective clothing, when necessary.
considerations
When using, do not eat, drink or smoke. Always observe good personal hygiene
measures, such as washing after handling the material and before eating, drinking,
and/or smoking. Routinely wash work clothing and protective equipment to remove
411
contaminants.
Wash
hands before breaks and
immediately
after
handling the product.
412
9. Physical and chemical properties
Appearance
Physical state
Semi-fluid (gel).
Form
Gel.
Color
Copper.
Odor
Petroleum.
Odor threshold
Not available.
pH
Neutral
Melting point/freezing point NONE.
Initial boiling point and
> 599 °F (> 315 °C)
boiling
range
Flash point
> 590.0 °F (> 310.0 °C)
Evaporation rate
Not available.
Flammability (solid, gas)
Not applicable.
Upper/lower flammability or explosive limits
Flammability limit Not applicable.
lower
(%)
Information on likely routes of exposure
No adverse effects due to inhalation are
Inhalation
expected.
No adverse effects due to skin contact are
Skin contact
expected.
Eye contact
Ingestion
Symptoms related to the
physical, chemical and
toxicological characteristics
Direct contact with eyes may cause temporary irritation.
Expected to be a low ingestion hazard.
Direct contact with eyes may cause temporary irritation.
Information on toxicological effects
Acute toxicity
Product
Kopr-Shield (CAS Mixture)
Acute
Oral
LD50
Not expected to be acutely toxic.
Species
Test Results
3266 mg/kg, Acute toxicity estimate
* Estimates for product may be based on additional component data not shown.
No adverse effects due to skin contact are
expected. Direct contact with eyes may cause
temporary irritation.
413
Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.
Germ cell mutagenicity
are
No data available to indicate product or any components present at greater than 0.1%
Carcinogenicity
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
mutagenic or genotoxic.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
NTP Report on Carcinogens
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
Reproductive toxicity
This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity single exposure
Not classified.
Specific target organ toxicity repeated exposure
Not classified.
Aspiration hazard
Not an aspiration hazard.
Further information
This product has no known adverse effect on human health.
12. Ecological information
Ecotoxicity
Components
Copper (CAS 7440-50-8)
Aquatic
Algae
Very toxic to aquatic life. Harmful to aquatic life with long lasting effects.
Species
Test Results
EC50
Pseudokirchnerella subcapitata
0.031 - 0.054 mg/l, 96 hours
Crustacea
EC50
Water flea (Daphnia magna)
0.03 mg/l, 48 hours
Fish
LC50
Fathead minnow (Pimephales promelas) 0.0068 - 0.0156 mg/l, 96 hours
* Estimates for product may be based on additional component data not shown.
Persistence and degradability
No data is available on the degradability of this product.
Bioaccumulative potential
The product is not expected to bioaccumulate.
Mobility in soil
No data available.
Other adverse effects
creation
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions
Local disposal regulations Hazardous waste code
Waste from residues / unused products
Contaminated packaging
414
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to
drain
into
sewers/water
supplies.
Dispose
of
contents/container
in
accordance
with
local/regional/national/international regulations.
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste disposal
company.
Dispose of in accordance with local regulations. Empty containers or liners may retain some product
residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).
Since emptied containers may retain product residue, follow label warnings even after container is emptied.
Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied
containers retain product residue, follow label warnings even after container is emptied.
14. Transport information
DOT
UN number
UN proper shipping name
LBS)
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
UN3082
Environmentally hazardous substances, liquid, n.o.s. (Copper RQ = 18182
9
9
III
Environmental hazards
Marine pollutant
Yes.
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Special provisions
8, 146, 335, IB3, T4, TP1, TP29
Packaging exceptions
155
Packaging non bulk
203
Packaging bulk
241
IATA
UN number
UN3082
UN proper shipping name
Environmentally hazardous substance, liquid, n.o.s. (Copper)
Transport hazard class(es)
Class
9
Subsidiary risk
Packing group
III
Environmental hazards
Yes.
ERG Code
9L
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
IMDG
UN number
UN3082
UN proper shipping name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (COPPER)
Transport hazard class(es)
Class
9
Subsidiary risk
-
415
Packing group
III
Environmental hazards
Marine pollutant
YES.
EmS
F-A, S-F
Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety
instructions, SDS and emergency procedures before handling.
Transport in bulk according to
Not applicable.
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
US federal regulations
This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Copper (CAS 7440-50-8)
Zinc bis(dipentyldithiocarbamate) (CAS 15337-18-5)
LISTED
LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
No
SARA 313 (TRI reporting)
Chemical name
Copper
Zinc bis(dipentyldithiocarbamate)
CAS number
7440-50-8
15337-18-5
% by wt.
25-30
<1
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
(SDWA)
Not regulated.
US state regulations
US. Massachusetts RTK - Substance List
Copper (CAS 7440-50-8)
US. New Jersey Worker and Community Right-to-Know Act
416
Copper (CAS 7440-50-8)
Zinc bis(dipentyldithiocarbamate) (CAS 15337-18-5)
US. Pennsylvania Worker and Community Right-to-Know Law
Copper (CAS 7440-50-8)
US. Rhode Island RTK
Copper (CAS 7440-50-8)
Zinc bis(dipentyldithiocarbamate) (CAS 15337-18-5)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known
to contain any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region
Australia
Canada
Canada
China
Europe
Europe
Japan
Korea
New Zealand
Philippines
Inventory name
Australian Inventory of Chemical Substances (AICS)
Domestic Substances List (DSL)
Non-Domestic Substances List (NDSL)
Inventory of Existing Chemical Substances in China (IECSC)
European Inventory of Existing Commercial Chemical
Substances (EINECS)
European List of Notified Chemical Substances (ELINCS)
Inventory of Existing and New Chemical Substances (ENCS)
Existing Chemicals List (ECL)
New Zealand Inventory
Philippine Inventory of Chemicals and Chemical
Substances
(PICCS)
On inventory (yes/no)*
No
No
No
Yes
Yes
No
No
No
Yes
Yes
United States & Puerto
Toxic Substances Control Act (TSCA) Inventory
Yes
Rico
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory
administered by the governing country(s).
16. Other information, including date of preparation or last revision
Issue date Revision date Revision #
Further information
HMIS® ratings
NFPA ratings
15-January-2016
04-May-2016
2
HMIS Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard
NFPA Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Health: 0 Flammability: 1 Physical
hazard: 0
417
1
0
0
List of abbreviations
DOT: Department of Transportation.
IATA: International Air Transport Association.
IMDG: International Maritime Dangerous Goods.
HMIS: Hazardous Materials Identification System.
NFPA: National Fire Protection Association.
CAS Number: Chemical Abstracts Service Registry Number.
LC50: Lethal concentration 50% (concentration that kills 50% of test animals).
EC50: (Effective Concentration – 50%) The concentration that will produce a
50% in vivo inhibition
of a biological or biochemical effect, in the test organisms or animals.
MARPOL: International Convention for the Prevention of Pollution from Ships.
Disclaimer
The information presented herein has been compiled from resources
considered to be dependable and accurate to the best of Thomas & Betts
Corporation knowledge. The information relates to the
special material. It may not be valid for this material if used in combination
with any other
materials or in any other process. It is user's responsibility to satisfy himself as
to the suitability
and completeness of this information for his own particular use. Thomas
&
Betts Corporation
cannot anticipate all conditions under which this information and its product,
or the products of
other manufacturers in combination with its product, may be used. It is the
user’s responsibility to
ensure safe conditions for handling, storage and disposal of the product, and to
assume liability for
loss, injury, damage or expense due to improper use. The information in the
sheet was written
based on the best knowledge and experience currently available.
418
Rigid Dark Cutting Oil
MATERIAL SAFETY DATA SHEET
Section 1 – Product & Company Identification
Product Name ........................
Product Catalog No. ...............
: RIDGID Dark Thread Cutting Oil
: 41590, 70830, 41610, 41600
Company Name .....................
Address ..................................
:
:
:
:
:
Telephone ..............................
Emergency Telephone ...........
Website ………………………..:
Issue Date ..............................
Ridge Tool Company
400 Clark Street
Elyria, Ohio 44035-6001
1-800-519-3456 (USA) (8:00 am – 5:00 pm EST, M-F)
call 9-1-1 or local emergency number
www.RIDGID.com
: June 13, 2013
Section 2 – Hazards Identification
EMERGENCY OVERVIEW:
This product is a liquid that is insoluble in water. Direct eye contact may cause minor, short term irritation. Short
term skin exposure is not expected to be irritating. Inhalation and ingestion are not anticipated routes of exposure
during normal conditions of use.
POTENTIAL HEALTH EFFECTS AND SYMPTOMS FROM SHORT TERM / ACUTE
EXPOSURE:
6.
Eye
This product is not expected to cause eye irritation under normal conditions of use. Symptoms of slight
eye irritation may result when direct contact occurs, or when exposed to high mist levels in poorly
ventilated areas.
7.
Skin
Short term skin contact is not expected to cause skin irritation. Prolonged or repeated direct exposure to
the skin may result in symptoms of irritation and redness. In severe cases, prolonged or repeated contact
may result in dermatitis accompanied by symptoms of irritation, itching, dryness, cracking and/or
inflammation.
8.
Inhalation:
This product has low volatility and so is not expected to cause respiratory tract irritation during normal
conditions of use. Exposure to high mist levels in poorly ventilated areas may cause upper respiratory
tract irritation and difficulty breathing.
419
Product Name ........................ :
RIDGID Dark Thread Cutting Oil
7.
Ingestion:
Ingestion may cause slight stomach irritation and discomfort.
8.
Potential Chronic Health Effects No
further data known.
9.
Medical Conditions Aggravated By Exposure: No further
data known.
10.
Carcinogenicity:
This product is not listed as a known or suspected carcinogen by IARC, OSHA or the NTP.
HMIS RATING:
Health
1
Flammability
1
Reactivity
0
PPE
X
Section 3 – Composition / Information On Ingredients
Components listed in this section may contribute to the potential hazards associated with exposure to the
concentrate. The product may contain additional non-hazardous or trade secret components.
Component:
Mineral Oil
Sulfur Additive Package
CAS #
64742-54-7
Mixture
% By Weight
> 90
< 10
This product does not contain silicone.
Section 4 – First Aid Measures
EYE CONTACT:
Upon direct eye contact, hold eyelids open and flush with a steady, gentle stream of water for at least 15
minutes. If irritation is due to exposure to mist or vapors, remove the individual to fresh air. If irritation
persists, flush the eyes with clean water until the irritation subsides. If symptoms persist, contact a
physician.
SKIN CONTACT:
Remove product from the skin by washing with a mild soap and water. Contaminated clothing should be
removed to prevent prolonged exposure. If symptoms of exposure persist, contact a physician.
INHALATION:
420
Inhalation is not an expected route of exposure. If respiratory irritation or distress occurs, remove the
employee to fresh air. Contact a physician or other medical professional if irritation or distress persists.
INGESTION:
If small amounts are ingested, first aid measures are not likely to be necessary. If larger amounts are
ingested or if symptoms of ingestion occur, dilute stomach contents with two glasses of water or milk.
(NOTE: Do NOT give anything by mouth to an unconscious person.) Do not induce vomiting without
medical supervision. If vomiting occurs spontaneously, keep airway clear. If symptoms of ingestion persist,
seek medical attention.
Section 5 – Fire Fighting Measures
FIRE AND EXPLOSIVE PROPERTIES:
Flashpoint ..........................
Flammability Limits ............
:
:
385°F Cleveland Open Cup
LEL
- N/A
UEL
- N/A
EXTINGUISH MEDIA:
In accordance with NFPA guidance, dry chemical, foam or CO2 fire extinguishers are all acceptable. Note
that while water fog extinguishers are also acceptable, do NOT apply a direct stream of water onto
burning product because it may cause spreading and increase fire intensity.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
No further data known.
FIRE-FIGHTING PROCEDURES AND EQUIPMENT:
Emergency responders in the danger area should wear bunker gear and self-contained breathing
apparatus for fires beyond the incipient stage. See Section 8 of the MSDS for other PPE to be worn as
conditions warrant.
Section 6 – Accidental Release Measures
PERSONAL PRECAUTIONS:
Use personal protection recommended in Section 8.
ENVIRONMENTAL:
This material is a water pollutant. Do not let spilled or leaking material enter waterways.
CLEAN-UP MEASURES:
Important: As with any spill or leak, before responding, ensure that you are familiar with the potential
hazards and recommendations of the MSDS. Appropriate personal protective equipment must be worn.
If possible, safely contain the spill with dikes or other spill response equipment appropriate for petroleum
or organic material releases. Take measures to prevent spreading of product. Note that while product will
ignite, it will not readily burn. However, as a precaution, eliminate ignition sources. Prevent from entering
421
sewers or waterways. Large volumes may be transferred to an appropriate container for proper disposal.
Small volumes or residues may be soaked up with absorbents. Spill response materials should be collected
for proper disposal.
Section 7 – Handling And Storage
HANDLING:
As with any industrial chemical, handle the product in a manner that minimizes exposure to practicable
levels. Prior to handling, consult Section 8 of this MSDS to evaluate personal protective equipment needs.
Open containers slowly to relieve any pressure. Follow all other standard industrial hygiene practices.
Empty containers may contain product residue. All safety precautions taken when handling this product
should also be taken when handling empty drums and containers. Keep containers closed when not in
use.
Product residue in empty containers is combustible but will not readily burn. Note, however, that
excessive heating or cutting of empty containers may create an ignition source sufficient to start a fire
and, in extreme cases, cause an explosion.
STORAGE:
Protect product quality by storing indoors and away from extreme temperatures. Close all containers
when not in use.
Section 8 – Exposure Controls / Personal Protection
EXPOSURE GUIDELINES:
Component
Mineral Oil
ACGIH TLV:
ACGIH STEL:
OSHA PEL:
Sulfur Additive Package
No information
5 mg / m3
(as mist)
10 mg / m3 (as mist)
5 mg / m3
(as mist
ENGINEERING CONTROLS:
Normal general ventilation is expected to be adequate. It is recommended that ventilation be designed in
all instances to maintain airborne concentrations at lowest practicable levels. Ventilation should, at a
minimum, prevent airborne concentrations from exceeding any exposure limits.
The user may wish to refer to 29 CFR 1910.1000(d) (2) and the ACGIH "Threshold Limit Values for
Chemical Substances and Physical Agents Biological Exposure Indices" (Appendix C) for the determination
of exposure limits of mixtures. An industrial hygienist or similar professional may be consulted to confirm
that the calculated exposure limits apply.
PERSONAL PROTECTIVE EQUIPMENT:
422
Selection of personal protective equipment should be based upon the anticipated exposure and made in
accordance with OSHA's Personal Protective Equipment Standard found in 29 CFR 1910 Subpart I. The
following information may be used to assist in PPE selection.
(4)
Eye Protection
Wear eye protection appropriate to prevent eye exposure. Where splashing is not likely,
chemical safety glasses with side shields are recommended. Where splashing may occur,
chemical goggles or full face shield is recommended.
(5)
Skin Protection
Gloves are not normally needed during normal conditions of use. If health effects are
experienced, oil or chemical resistant gloves such as butyl or nitrile are recommended. Where
splashing or soaking is likely, wear oil or chemical resistant clothing to prevent exposure.
(6)
Respiratory Protection
A respirator may be worn to reduce exposure to vapors, dust or mist. Select a NIOSH/MSHA
approved respirator appropriate for the type and physical character of the airborne material. A
self-contained breathing apparatus is recommended in all situations where airborne contaminant
concentration has not been confirmed to be below safe levels. Respirator use should comply
with the OSHA Respirator Protection Standard found in 29 CFR 1910.134.
(7)
General Hygiene Considerations Wash
thoroughly after handling.
Section 9 – Physical And Chemical Properties
Physical Appearance: .............
Odor. ......................................
Physical State ........................
Water Solubility ......................
Specific Gravity ......................
VOC ……………………………:
:
:
:
:
:
Black
Mild Petroleum
Liquid
Insoluble
.878
2.5%
Section 10 – Stability And Reactivity
STABILITY:
This product is stable.
CONDITIONS TO AVOID:
Avoid contact with incompatible materials and exposure to extreme temperatures.
INCOMPATIBLE MATERIALS:
This product is incompatible with strong oxidizing agents.
DECOMPOSITION PRODUCTS MAY INCLUDE:
423
Thermal decomposition products are dependent on combustion conditions. A complex mixture of
airborne solid, liquid, particulates and gasses may evolve when the material burns. Combustion byproducts may include:
oxides
of
carbon
oxides of sulfur
incompletely burned hydrocarbons as fumes and smoke
POSSIBILITY OF HAZARDOUS REACTIONS:
This product is not expected to polymerize
Section 11 – Toxicological Information
ACUTE:
Oral LD50: Not determined
Inhalation LC50: Not determined
CHRONIC: No further toxicological data known.
SENSITIZATION: No further toxicological data known.
REPRODUCTIVE EFFECTS: No further toxicological data known.
TERATOGENIC EFFECTS: No further toxicological data known.
MUTAGENICITY: No further toxicological data known.
SYNERGISTIC MATERIALS: No further toxicological data known.
CARCINOGENICITY: This product is not listed as a known or suspected carcinogen by IARC, OSHA or the NTP.
Section 12 – Ecological Information
ECOTOXICOLOGICAL INFORMATION:
This product has not been evaluated for ecotoxicity. As with any industrial chemical, exposure to the
environment should be prevented and minimized wherever possible.
ENVIRONMENTAL FATE:
The degree of biodegradability and persistence of this product has not been determined.
VOC CONTENT: 2.5%
Section 13 – Disposal Consideration
WASTE DISPOSAL:
424
Ensure that collection, transport, treatment and disposal of waste product and containers complies with
all applicable laws and regulations. Note that use, mixture, processing or contamination of the product
may cause the material to be classified as a hazardous waste. It is the responsibility of the product user or
owner to determine at the time of disposal whether the product is regulated as a hazardous waste.
Section 14 – Transportation Information
U.S. DOT HAZARDOUS MATERIAL INFORMATION:
Not DOT regulated.
CANADA TRANSPORT OF DANGEROUS GOODS:
This material is not TDG regulated.
Section 15 – Regulatory Information
FEDERAL REGULATIONS:
SARA 313:
This product contains NONE of the substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part
372.
CLEAN WATER ACT:
This product contains mineral oil and is subject to regulation by Section 311 of the Clean Water
Act and the Oil Pollution Act. Releases of the product into or leading to surface waters must be
reported to the National Response Center at 1-800-424-8802.
CERCLA REPORTABLE QUANTITY:
Any components listed below have been assigned a reportable quantity (RQ) by the Federal
EPA. Releases of the product into the environment that exceed the RQ for a particular
component must be reported to the National Response Center at 1-800-424-8802.
None to report
TOXIC SUBSTANCE CONTROL ACT:
The components of this product are listed on the TSCA Inventory.
OZONE DEPLETING SUBSTANCES:
This product contains no ozone depleting substances as defined by the Clean Air Act.
HAZARDOUS AIR POLLUTANTS:
Any components listed below are defined by the Federal EPA as hazardous air
pollutants:
None to report
425
STATE REGULATIONS
This product contains mineral oil, and as used, may be regulated by state used oil regulations. Check with
the appropriate state agency to determine whether such a regulation exists.
CANADA
WHMIS Classification:
Not controlled under WHMIS
DSL:
The components of this product are listed on DSL Inventory.
Section 16 – Other Information
Prepared by:. . . . . . . . . . . . Ridge Tool Company
Issue Date: . . . . . . . . . . . . . June 13, 2013
Last Revision Date: . . . . . . . October 12, 2009
RIDGE
TOOL
BELIEVES
THE STATEMENTS,
TECHNICAL
INFORMATION
AND
MENDATIONS CONTAINED HEREIN ARE RELIABLE BUT THEY ARE GIVEN WITHOUT WARRANTY
OR GUARANTEE OF ANY KIND, EXPRESSED OR IMPLIED, AND WE ASSUME NO RESPONSIBILITY
FOR ANY LOSS, DAMAGE OR EXPENSE, DIRECT OR CONSEQUENTIAL, ARISING OUT OF THEIR USE.
RECOM-
426
Spectracide Wasp & Hornet Killer
427
428
429
430
431
432
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