MATERIAL SAFETY DATA SHEET
1. PRODUCT AND COMPANY IDENTIFICATION
Page : 1/5
Date Issued : Sep.14, 2010
MSDS No. F-01981
Product Name: MX-B20NT1/ MX-B20BT1/ MX-B20GT1/ MX-B20FT1/ MX-B20AT1/ MX-B20CT1
( Black Toner )
Supplier Identification
: Sharp Corporation
22-22 Nagaike-cho, Abeno-ku, Osaka, Japan
Local suppliers are listed below. Please contact the nearest supplier for additional information.
Area
North
America
Oceania
(Country)
U.S.A.
Canada
Australia
Germany
United
Kingdom
France
Austria
Europe
Italy
Spain
Netherlands
Sweden
Switzerland
Middle
East
U.A.E.
(Local suppliers)
Sharp Electronics Corporation
Sharp Plaza, Mahwah, New Jersey 07495-1163
Telephone number
: 800-237-4277
Emergency telephone number : 800-255-3924
Sharp Electronics of Canada Ltd.
335 Britannia Road East, Mississauga, Ontario L4Z 1W9
Telephone number
: 905-890-2100
Emergency telephone number : 1-800-255-3924
Sharp Corporation of Australia PTY. Ltd.
No1 Huntingwood Drive Huntingwood Blacktown N.S.W.
Telephone number
: 1300-13-50-22
Sharp Electronics (Europe) GMBH
Sonninstrasse 3, 20097 Hamburg
Telephone number
: 040-2376-2185
Sharp Electronics (U. K.) Ltd.
4 Furzeground Way, Stockley Park, Uxbridge Middlesex,
UB11 1EZ
Telephone number
: 08705-274-277
Sharp Electronics France S.A.
22, Avenue des Nations, Paris Nord 2, BP 52094 / 95948
Roissy-Charles de Gaulle, Cedex
Telephone number
: 01-49-90-34-00
Sharp Electronics (Europe) GmbH
Handelskai 342 1020 Wien
Telephone number
: 01-727-19-0
Sharp Electronics (Italy) S.P.A.
Via Lampedusa, 13 20141 Milano
Telephone number
: 02895951
Sharp Electronics (Espana) S.A.
Calle Sena, 2-10 Poligono Industrial Can Sant Joan. Parcela 8,
08174 Sant Cugat Del Valles
Telephone number
: 93-581-97-00
Sharp Electronics Benelux B.V.
P.B. 900 Meidoornkade 10, 3992 AE Houten
Telephone number
: 30-6359500
Sharp Electronics Nordic AB
Box 14098, Gustavslundsvagen 12, SE-167 14, Bromma
Telephone number
: 08-634-36-00
Sharp Electronics(Schweiz)AG
Moosstrasse 2, Postfach 321 8803 Ruschlikon
Telephone number
: 01-846-6111
Sharp Middle East FZE
P.O.Box 17115 Jebel Ali, Dubai
Telephone number
: 04-8815311
MATERIAL SAFETY DATA SHEET
Date Issued : Sep.14, 2010
MSDS No. F-01981
2. COMPOSITION / INFORMATION ON INGREDIENTS
Substance[ ]
Preparation[X]
CAS No.
Ingredient
Styrene-Acrylate
Confidential
copolymer
Carbon black
1333-86-4
Charge control agent Confidential
Iron Oxide
1309-38-2
Amorphous silica
68611-44-9
Proportion
80-90%
5-10%
1-5%
1-5%
0.1-1%
Page : 2/5
OSHA PEL
Not listed
ACGIH TLV
Not listed
MAK-TWA
Not listed
NOHSC-TWA
Not listed
3.5mg/m
Not listed
Not listed
3
80 mg/m
3.5mg/m
Not listed
Not listed
3
2mg/m
Not listed
Not listed
Not listed
Not listed
3mg/m
Not listed
Not listed
Not listed
3
3
3
3. HAZARDS IDENTIFICATION
Most Important Hazards and Effects of the Products
Human Health Effects : There are no anticipated carcinogenic effects from exposure based on animal tests
performed using toner. When used as intended according to instructions, studies do not
indicate any symptoms of fibrosis will occur.
Environmental Effects : Not toxic to aquatic organisms
Specific Hazards
: Dust explosion (like most finely divided organic powders)
Directive 1999/45/EC(Europe) : Not classified as dangerous
Australian Information
: Not classified as hazardous according to criteria of NOHSC.
4. FIRST-AID MEASURES
Route(s) of Entry : Inhalation?
Yes
Skin?
No
Ingestion?
Possible but very unusual.
Inhalation
: Remove to fresh air. If symptoms occur, consult medical personnel.
Skin Contact : Wash with soap and water for 15 minutes or until particle is removed.
If irritation does occur, consult medical personnel.
Eye Contact : Flush eyes immediately with water for 15 minutes. If irritation does occur, consult medical personnel.
Ingestion
: Rinse with water and drink several glasses of water. If irritation or discomfort does occur, consult
medical personnel.
5. FIRE-FIGHTING MEASURES
Extinguishing Media
: Water, CO2, foam and dry chemicals
Special Fire Fighting Procedures : None
Fire and Explosion Hazards
: Toner material, like most finely divided organic powders, may form an explosive
mixture.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
Environmental Precautions
Methods for Cleaning Up
: None
: None
: Wipe off with paper or cloth. Do not use vacuum cleaner when a large amount is
released. It, like most finely divided organic powders, is capable of creating a
dust explosion.
MATERIAL SAFETY DATA SHEET
Page : 3/5
Date Issued : Sep.14, 2010
MSDS No. F-01981
7. HANDLING AND STORAGE
Handling
Technical Measures
: None
Precautions
: None
Safe Handling Advice : Use of a dust mask is recommended when handling a large quantity of toner or during long
term exposure, as with any non-toxic dust. Try not to disperse the particles.
Storage
Technical Measures
: None
Storage Conditions
: Keep container closed and Store in a cool and dry place.
Keep out of the reach of children.
Incompatible Products : None
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Measures
Ventilation
Exposure Limit Values
OSHA-PEL(USA)
ACGIH-TLV(USA)
Personal Protective Equipment
Respiratory Protection
Hand Protection
Eye Protection
Skin Protection
Other Protective Equipment
: Not required under intended use.
: 15mg/m (Total Dust),
3
: 10mg/m (Total Dust),
3
5mg/m (Respirable Dust)
3
3mg/m (Respirable Dust)
3
: Not required under intended use.
: Not required under intended use.
: Not required under intended use.
: Not required under intended use.
: Use of a dust mask and goggles are recommended when handling a large
quantity of toner or during long term exposure, as with any non-toxic dust.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical State : Solid
Ph
Boiling / Melting Point
Softening Point(°C)
Flash Point(°C)
Ignition Point(°C )
Explosion Properties
Density(g/cm³)
Solubility in Water
10. STABILITY AND REACTIVITY
Form : Powder
Color : Black
: Not applicable
: Not applicable
: 100 - 130
: Not applicable
: > 350
: No data
: 1.1 (bulk density : approx. 0.35)
: Negligible
Stability
Hazardous Reactions
Conditions to Avoid
Materials to Avoid
Hazardous Decomposition Products
Further Information
Odor : odorless
: Stable
: Dust explosion, like most finely divided organic powders.
: Electric discharge, throwing into fire.
: Oxidizing Materials
: CO, CO2 and NOX
: None Dermal
MATERIAL SAFETY DATA SHEET
11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Ingestion(oral)
Inhalation
Eye irritation
Skin irritation
Skin sensitizer
Mutagenicity
Carcinogenicity
Chronic Effect
Page : 4/5
Date Issued : Sep.14, 2010
MSDS No. F-01981
: LD50 > 2000mg/kg (Rats)
: LC50 > 5.0mg/L (Rats)
: Not an irritant (Rabbits)
: Not an irritant (Rabbits)
: No sensitized
: Negative (Ames Test)
: In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen (possible human
carcinogen). This classification is given to chemicals for which there is inadequate human
evidence, but sufficient animal evidence on which to base an opinion of carcinogenicity. The
classification is based upon the development of lung tumors in rats receiving chronic inhalation
exposures to free carbon black at levels that induce particle overload of the lung. Studies
performed in animal models other than rats did not show any association between carbon black
and lung tumors. Moreover, a two-year cancer bioassay using a typical toner preparation, where
carbon black is bound in a resin matrix, demonstrated no association between toner exposure
and tumor development in rats.
: In a study in rats of chronic inhalation exposure to a typical toner, a mild to moderate degree of
3
lung fibrosis was observed in 92% of the rats in the high concentration (16mg/m ) exposure
group, and a minimal to mild degree of fibrosis was noted in 22% of the animals in the middle
3
3
(4mg/m ) exposure group, but no pulmonary change was reported in the lowest (1mg/m )
exposure group, the most relevant level to potential human exposures.
12. ECOLOGICAL INFORMATION
Ecotoxicity
On available data, toner is not harmful to aquatic organisms
13.DISPOSAL CONSIDERATIONS
Waste from Residues
: Waste material may be dumped or incinerated under conditions which meet all federal,
state and local environmental regulations.
Contaminated Packaging : Waste may be disposed or incinerated under conditions which meet all federal, state
and local environmental regulations.
14. TRANSPORT INFORMATION
UN Classification
: None
Not classified as hazardous for transport.
15. REGULATORY INFORMATION
US Information
TSCA(Toxic Substances Control Act) :
All chemical substances in this product comply with all applicable rules or order under TSCA.
SARA(Superfund Amendments and Reauthorization Act) Title III
302 Extreme Hazardous Substance : None
311/312 Hazard Classification
: None
EU Information
1999/45/EC and 67/548/EEC
Symbol & Indication
: Not required
R-Phrase
: Not required
76/769/EEC
: All chemical substances in this product comply with all applicable rules or
order under 76/769/EEC.
MATERIAL SAFETY DATA SHEET
16. OTHER INFORMATION
Page : 5/5
Date Issued : Sep.14, 2010
MSDS No. F-01981
NFPA Rating (USA)
: Health=1
Flammability=1
Reactivity=0
WHMIS Legislation (Canada) : This product is not a controlled product.
References
IARC(1996) : IARC monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans, Vol. 65,
Printing Process And Printing Inks, Carbon Black and Some Nitro Compounds, Lyon, pp.149-261
H.Muhle, B.Bellmann, O.Creutzenberg, C.Dasenbrock, H.Ernst, R.Kilpper, J.C.MacKenzie, P.Morrow, U.Mohr,
S.Takenaka, and R.Mermelstein(1991) Pulmonary Response to Toner upon Chronic Inhalation Exposure in Rats.
Fundamental and Applied Toxicology 17, pp.280-299.
The information on this data sheet represents our current data and best opinion as to the proper use in handling of this
product under normal conditions. However, all materials may present unknown hazards and should be used with
caution. Although certain hazards are described herein, we do not guarantee that these are the only hazards which
exist.
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