Safety Data Sheets
Safety Data Sheets
Field
Gradex Inc.
01/21/2015
Safety Data Sheet Index
Binder: Gradex Inc. - Field
Product Name
Manufacturer
Version Date
Page
“GROUP A”: E6010, E6011; “GROUP B”:
E7018, E7018-1
Hobart Brothers Company
11/30/2008
5
16BR BLACK SILICONE ADHESIVE SEALANT
3 OZ
ITW Permatex
06/11/2012
8
272 Threadlocker High Strength
Loctite Corporation
02/02/2004
11
30756 OATEY PURPLE PRIMER NSF
OATEY CO.
02/29/2000
16
66BR CLEAR RTV SILICONE ADHESIVE
SEALANT 3 OZ
Permatex, Inc.
06/01/2011
21
765-1221 NAPA HIGH TACK GASKET
SEALANT(PTX80062) 4 FL.OZ
ITW Permatex
01/26/2012
24
ABC Dry Chemical
BUCKEYE FIRE EQUIPMENT
COMPANY
06/01/2013
27
Praxair, Inc.
11/01/2008
31
Air Brake Anti Freeze
E-Zoil Products, Inc.
07/01/2005
41
Air Tool Oil
CRC Industries, Inc.
03/29/1999
43
All Purpose Cleaner for ABS , PVC and CPVC
Oatey Company
03/10/2000
46
Battery Cleaner (Spray)
Sprayon Products
05/01/2000
50
BernzOmatic BF55 Butane Fuel
BERNZ-O-MATIC
08/01/2010
52
BG 109 - Compression Performance
Restoration (CPR)
BG PRODUCTS, INC.
12/30/2010
57
BG 244
BG PRODUCTS, INC.
08/12/2014
66
Brake & Parts Clean, Non-Chlorinated, 55
Gallon Drum
CYCLO INDUSTRIES INC
06/18/2013
80
CAT ANTI-SEIZE COMPOUND GRAPHITE
BASE
Chemtool, Inc.
09/22/2009
87
CAT ASSEMBLY LUBRICANT
Chemtool, Inc.
09/23/2009
94
CAT BEARING MOUNT COMPOUND
Chemtool, Inc.
11/06/2008
101
CAT CEMENT
Chemtool, Inc.
06/11/2004
107
CAT LIQUID GASKET-A
Chemtool, Inc.
11/06/2008
114
Chemtool Incorporated
02/06/2014
121
Chemtool, Inc.
04/25/2008
134
Acatylene, dissolved
CAT MINERAL SPIRITS
CAT RETAINING COMPOUND
CAS Number
74-86-2
64742-88-7
Page 2 of 320
Product Name
CAS Number
CIGWELD Arcair DC Gouging Carbons
Manufacturer
Version Date
Page
CIGWELD Pty Ltd
12/05/2011
140
COMPRESSOR OIL ISO 100
64742-54-7
NAPA Air Compressors
12/15/2009
149
Dielectric Tune-Up Grease
63148-62-9
Permatex, Inc.
01/19/2004
154
DriGraph Graphite Lubricant
Lawson Products, Inc.
09/19/2014
157
DURA BOND (TUBES)
PRO CHEM, INC.
09/01/2008
170
DuraMAX Windshield Washer Solvent (NF) (-20
Degree)
RelaDyne LLC
10/22/2013
172
Fleetguard DCA 4 Liquid Cooling Conditioner
Fleetguard, Inc.
01/05/1996
173
GUNK INDUSTRIAL GLASS CLEANER
Radiator Specialty Company
04/19/2011
176
Hardsurfacing Electrodes
Hobart Brothers Company
07/14/2005
180
Hot Shot Wasp & Hornet Killer 3
CHEMSICO DIV OF UNITED
INDUSTRIES CORP
10/18/2010
182
Inter-Lube Delayed Viscosity Penetrating
Grease
KIMBALL-MIDWEST
04/01/2012
183
KRYLON CONTRACTOR Marking Paint,
Fluorescent Orange
Krylon Products Group
05/28/2014
184
LOCTITE 620 RETAINING COMPOUND
Henkel Canada Corporation
02/07/2014
190
Low Fuming Bronze Bare and Low Fuming
Bronze Flux Coated
J.W. Harris Company, Inc.
02/15/1985
195
Marathon Dexron-III/Mercon Automatic
Transmission Fluid
Marathon Petroleum Company LLC 06/02/2006
197
Marathon Marafluid 4 Transmission & Drive
Train Fluid
Marathon Petroleum Company LLC 06/02/2006
204
Marathon Multi-Purpose Hydraulic Oil
Marathon Petroleum Company LLC 06/02/2006
212
Marathon Multipower-3 15W-40 Motor Oil
Marathon Petroleum Company LP
12/07/2010
220
Marathon Multipower-3 Motor Oil
Marathon Petroleum Company LLC 06/02/2006
229
MULTI-PURPOSE GEAR COMPOUND
MARATHON OIL COMPANY
12/27/1991
238
NAPA 765-1188 THREAD SEALANT W/PTFE 4
FL.OZ
Permatex, Inc.
08/11/2010
243
NAPA 765-1482 HI-TEMP RED RTV GASKET
MAKER 7.25 OZ.
Permatex, Inc.
10/27/2009
246
NAPA BRAKE FLUID-DOT 3
Balkamp, Inc.
11/15/1999
249
NAPA Lith-Ease Grease (Plastic Tub 1 Pound)
765-1393
AGS COMPANY
09/06/1994
254
NAPA/MAC'S STARTING FLUID No. 7216
ASHLAND PETROLEUM
COMPANY
12/01/1984
258
Oatey PVC Heavy Duty Clear Cement
OATEY CO.
11/11/2008
260
Page 3 of 320
Product Name
CAS Number
Manufacturer
Version Date
Page
PB PENETRATING CATALYST (AEROSOL)
The Blaster Corporation
05/26/2014
265
Permatex Medium Strength Threadlocker Blue
Henkel Corporation
01/11/2012
280
Persist
Drummond American, A Lawson
Products Company
04/16/2009
286
PK Force Industrial Hand Cleaner
Woodbine Products Company
12/01/2005
292
Propane
74-98-6
WORTHINGTON CYLINDER
CORPORATION
09/11/2014
293
R-134a
811-97-2
Refrigerant Management Services
of Georgia
08/01/1995
301
Rinker 711 Pipe Joint Lubricant
JTM PRODUCTS, INC.
07/01/2006
306
STIHL 2-Cycle Engine Oil
WESTLAND OIL COMPANY
10/31/1990
308
WD - 40 Aerosol
WD-40 Company
03/01/2001
313
Winter Power 4033
PRIMROSE OIL CO
11/12/2010
315
Page 4 of 320
Page 5 of 320
Page 6 of 320
Page 7 of 320
ITW Permatex
10 Columbus Blvd.
Hartford, CT 06106 USA
Telephone: 1-87-Permatex
(877) 376-2839
Emergency: 800-255-3924 (ChemTel)
International Emergency: +01-813-248-0585
Material Safety Data Sheet
1. PRODUCT IDENTIFICATION
Product Name:
Item No:
Product Type:
16BR BLACK SILICONE ADHESIVE SEALANT 3 OZ
81158
Elastomeric rubber
2. COMPOSITION/INFORMATION ON INGREDIENTS
Component
POLY (DIMETHYLSILOXANE),
HYDROXY TERMINATED
70131-67-8
LIMESTONE
1317-65-3
CALCIUM CARBONATE
471-34-1
DISTILLATES (PETROLEUM),
HYDROTREATED LIGHT
64742-47-8
VINYL OXIMINOSILANE
2224-33-1
CARBON BLACK
1333-86-4
STEARIC ACID
57-11-4
2-BUTANONE OXIME
96-29-7
Weight%
30-50
ACGIH; TLV-TWA
Not listed
OSHA PEL
Not listed
20-40
Not listed
15 mg/m3
15-40
10 mg/m3
Not listed
<5
Not listed
Not listed
<5
Not listed
Not listed
<3
3.5 mg/m3
3.5 mg/m3
<2
Not listed
Not listed
0.5-2.0
Not listed
Not listed
3. HAZARDS IDENTIFICATION
Toxicity:
Primary Routes of Entry:
Signs and Symptoms of Exposure:
May cause eye and skin irritation. When this product if exposed to moisture, butanone oxime may be
formed. May be harmful if swallowed. May irritate lips, gums, tongue, mouth, nose and throat.
Eye and skin contact, ingestion, inhalation
Butanone oxime produced during curing is toxic and irritates eyes, nose and throat. Overexposure to the
silane may cause coma and respiratory failure.
Component
Weight%
<3
CARBON BLACK
1333-86-4
Aggravated Medical Condition:
4. FIRST AID MEASURES
Ingestion:
Inhalation:
Skin Contact:
Eye Contact:
ACGIH Carcinogens
Group A4 - Not
classifiable as a
human carcinogen
IARC Carcinogen
Group 2B; Monograph 65,
1996
Preexisting eye, skin and respiratory disorders may be aggravated by overexposure to this product.
Rinse mouth. Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical
attention. Never give anything by mouth to an unconscious person.
Move to fresh air in case of accidental inhalation of vapours. Obtain medical attention.
Wipe off material with paper towel or cloth Wash off with soap and water If skin irritation persists, call a
physician
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical
attention if irritation persists.
5. FIRE FIGHTING MEASURES
Flash Point °F(C°):
Recommended Extinguishing Media:
Special Fire-Fighting Procedures:
NTP
>200°F TCC
Carbon Dioxide, Dry Chemicals, Foam.
Water spray may be ineffective on flames but should be used to keep fireexposed containers cool.
1 of 3
Page 8 of 320
Product Name:
16BR BLACK SILICONE ADHESIVE
SEALANT 3 OZ
5. FIRE FIGHTING MEASURES
Item No. 81158
Unusual Fire/Explosion Hazards:
Oxides of carbon, Oxides of nitrogen, Methyl ethyl ketone, possibly methyl
ethyl ketoxime, Silica fume, Formaldehyde
None.
Lower Explosive Limit:
Upper Explosive Limit:
Not determined
Not determined
Hazardous Products of Combustion:
6. ACCIDENTAL RELEASE MEASURES
Spill Procedures:
Wipe or scrape up spill material. Maintain good ventilation for large spills. Place scrap material in a wellventilated area and allow to cure to rubber. Clean up spills thoroughly as residue is slippery.
7. HANDLING AND STORAGE
Storage:
Handling:
Store in a dry area below 90 degrees F. Keep container closed when not in use.
Do not take internally. Do not inhale vapors. Avoid contact with skin and eyes. Do not wear contact lenses.
Wash hands before eating and smoking.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eyes:
Skin:
Ventilation:
Respiratory Protection:
Comments:
Safety glasses.
Neoprene or nitrile gloves recommended.
General; local exhaust ventilation as necessary to control any air contaminants to within their exposure
limits (or to the lowest feasible levels when limits have not been established) during the use of this product.
An approved organic vapor respirator should be worn when exposures are expected to exceed the
applicable limits.
When heated to temperatures above 300 degrees F. in the presence of air, this product can form
formaldehyde vapors. Formaldehyde is a potential cancer hazard and a known skin and respiratory
sensitizer. Safe handling conditions may be maintained by keeping vapor concentrations below the OSHA
permissible limit for formaldehyde
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Odor:
Boiling Point:
pH:
Solubility in Water:
Specific Gravity:
VOC(Wt.%):
Vapor Pressure:
Vapor Density (Air=1):
Evaporation Rate:
Black paste
Mild
Not applicable, polymeric material
Does not apply
Polymerized
1.43
3.2%, 45.87 g/l
<5 mm Hg
3.0
Not Determined
10. STABILITY AND REACTIVITY
Chemical Stability:
Hazardous Polymerization:
Incompatabilities:
Conditions to Avoid:
Hazardous Products of Combustion:
Stable at normal conditions
Will not occur
Polymerized by contact with moisture., Strong oxidizers, Acids, Iron
Exposure to moisture.
Oxides of carbon, Oxides of nitrogen, Methyl ethyl ketone, possibly methyl
ethyl ketoxime, Silica fume, Formaldehyde
11. TOXICOLOGICAL INFORMATION
See Section 3
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended Method of Disposal: Disposal should be made in accordance with federal, state and local regulations.
NH - Not a RCRA Hazardous Waste Material
US EPA Waste Number:
Page 9 of 320
Product Name:
16BR BLACK SILICONE ADHESIVE
SEALANT 3 OZ
Item No. 81158
14. TRANSPORTATION INFORMATION
DOT (49CFR 172)
U.S. Department of Transportation - DOT - 49 CFR (Ground)
DOT Shipping Name:
Hazard Class:
UN/ID Number:
Not regulated
None
None
IATA (Air)
Proper Shipping Name:
Class or Division:
UN/ID Number:
Not regulated
None
None
IMDG (Vessel)
Proper Shipping Name:
Hazard Class:
UN Number:
Not regulated
None
None
Marine Pollutant:
None
15. REGULATORY INFORMATION
SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical.
NONE
California Proposition 65: No California Prop 65 chemicals are known to be present at or above the No Significant Risk Level
TSCA Inventory Status: All components of this product are listed (or exempt) on the EPA TSCA inventory.
16. OTHER INFORMATION
HEALTH 1, FLAMMABILITY 1 , REACTIVITY 0.
HEALTH 1, FLAMMABILITY 1, PHYSICAL HAZARD 0
(NFPA is a registered trademark of the National Fire Protection Association)
HMIS is a registered trademark of the National Paint and Coatings Association
Estimated NFPA Rating:
Estimated HMIS Classification:
Prepared By:
Company:
Telephone No.:
Denise Boyd, Manager-Environmental, Health & Safety
ITW Permatex 10 Columbus Blvd. Hartford, CT USA 06106
1-87-Permatex (877) 376-2839
Revision Date: June 11, 2012
Revision Number: 3
Page 10 of 320
Material Safety Data Sheet
Issue date: 02/02/2004
Revision Date: 02/02/2004
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product name:
272 Threadlocker High Strength
Product type:
Anaerobic Adhesive
Company address:
Henkel Loctite Corporation
1001 Trout Brook Crossing
Rocky Hill, Connecticut 06067
Item number:
27270
Region:
United States
Contact Information:
Telephone: 860.571.5100
Emergency telephone: 860.571.5100
Internet: www.loctite.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
Aromatic dimethacrylate ester
24448-20-2
%
60-100
ACGIH TLV
None
OSHA PEL
None
OTHER
None
Maleimide Resin
3006-93-7
10-30
None
None
None
Methacrylate ester
UNKNOWN
5-10
None
None
None
Cumene hydroperoxide
80-15-9
1-5
None
None
1 ppm (6 mg/m3) Skin (WEEL)
Hydroxyalkyl methacrylate
27813-02-1
1-5
None
None
1 ppm TWA; 3 ppm STEL
Silica, amorphous, fumed,
crystalline-free
112945-52-5
1-5
6 mg/m3 TWA
10 mg/m3 TWA
3 mg/m3 TWA respirable dust
1-Acetyl-2-phenylhydrazine
114-83-0
0.1-1
None
None
None
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HMIS:
Physical state:
Color:
Odor:
Liquid
Red
Mild
WARNING:
HEALTH:
FLAMMABILITY:
PHYSICAL HAZARD:
Personal Protection:
1*
1
1
See Section 8
CAUSES EYE IRRITATION.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION.
MAY BE HARMFUL IF SWALLOWED.
Relevant routes of exposure:
Skin, Inhalation, Eyes
Potential Health Effects
Item number:
27270
Product name: 272 Threadlocker High Strength
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Page 11 of 320
May cause respiratory tract irritation.
May cause allergic skin reaction.
Contact with eyes will cause irritation.
May be harmful if swallowed.
Inhalation:
Skin contact:
Eye contact:
Ingestion:
Existing conditions aggravated by
exposure:
Eye, skin, and respiratory disorders.
See Section 11 for additional toxicological information.
4. FIRST AID MEASURES
Inhalation:
Remove to fresh air. If symptoms develop and persist, get medical attention.
Skin contact:
Wash with soap and water. Remove contaminated clothing and shoes. Wash clothing before reuse.
Get medical attention if symptoms occur.
Eye contact:
Flush with copious amounts of water, preferably, lukewarm water for at least 15 minutes, holding
eyelids open all the time. Get medical attention.
Ingestion:
Do not induce vomiting. Keep individual calm. Obtain medical attention.
5. FIRE-FIGHTING MEASURES
Flash point:
Greater than 93ºC (200ºF)
Tagliabue closed cup
Autoignition temperature:
Not available
Flammable/Explosive limits-lower %:
Not available
Flammable/Explosive limits-upper %:
Not available
Extinguishing media:
Foam, dry chemical or carbon dioxide.
Special fire fighting procedures:
None
Unusual fire or explosion hazards:
None
Hazardous combustion products:
Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Toxic fumes. Irritating organic vapors.
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions:
Prevent product from entering drains or open waters.
Clean-up methods:
Ensure adequate ventilation. Soak up with inert absorbent. Store in a partly filled, closed container
until disposal.
7. HANDLING AND STORAGE
Handling:
Use only with adequate ventilation. Avoid contact with eyes, skin and clothing.
Storage:
For safe storage, store at or below 38°C (100°F).
Incompatible products:
Refer to Section 10.
For information on product shelf life contact Henkel Loctite Customer Service at (800) 243-4874.
Item number:
27270
Product name: 272 Threadlocker High Strength
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Page 12 of 320
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls:
No specific ventilation requirements noted, but forced ventilation may still be required if concentrations
exceed occupational exposure limts.
Respiratory protection:
Use NIOSH approved respirator if there is potential to exceed exposure limit(s).
Skin protection:
Use impermeable gloves and protective clothing as necessary to prevent skin contact. Neoprene
gloves. Butyl rubber gloves. Natural rubber gloves.
Eye/face protection:
Safety goggles or safety glasses with side shields.
See Section 2 for exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state:
Color:
Odor:
Vapor pressure:
pH:
Boiling point/range:
Melting point/range:
Specific gravity:
Vapor density:
Evaporation rate:
Solubility in water:
Partition coefficient (n-octanol/water):
VOC content:
Liquid
Red
Mild
Less than 5 mm Hg at 27ºC (80ºF)
Not applicable
Greater than 149ºC (300ºF)
Not available
1.11
Not available
Not available
Slight
Not available
8.1%; 89.9 grams/liter (EPA Method 24)
10. STABILITY AND REACTIVITY
Stability:
Stable.
Hazardous polymerization:
Will not occur.
Hazardous decomposition products:
Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Toxic fumes. Irritating organic vapors.
Incompatability:
Strong oxidizers.
Conditions to avoid:
See "Handling and Storage" (Section 7) and "Incompatabilty" (Section 10).
11. TOXICOLOGICAL INFORMATION
Product toxicity data:
Acute oral LD50 greater than 10, 000 mg/kg (rat). Acute LD50 (dermal): More than 1500 (rabbit).
Carcinogen Status
Hazardous components
Aromatic dimethacrylate ester
Maleimide Resin
Methacrylate ester
Cumene hydroperoxide
Hydroxyalkyl methacrylate
Silica, amorphous, fumed,
crystalline-free
1-Acetyl-2-phenylhydrazine
NTP Carcinogen
No
No
No
No
No
No
IARC Carcinogen
No
No
No
No
No
No
OSHA Carcinogen
No
No
No
No
No
No
No
No
No
Literature Referenced Target Organ & Other Health Effects
Item number:
27270
Product name: 272 Threadlocker High Strength
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Page 13 of 320
Hazardous components
Aromatic dimethacrylate ester
Maleimide Resin
Methacrylate ester
Cumene hydroperoxide
Hydroxyalkyl methacrylate
Silica, amorphous, fumed,
crystalline-free
1-Acetyl-2-phenylhydrazine
Health Effects/Target Organs
Allergen, Irritant
No Target Organs
No data
Allergen, Central nervous system, Corrosive, Irritant, Mutagen
Allergen, Irritant
Nuisance dust
Allergen, Blood, Kidney, Mutagen, Some evidence of carcinogenicity
12. ECOLOGICAL INFORMATION
Ecological information:
Not available
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal:
Dispose of according to Federal, State and local governmental regulations.
EPA hazardous waste number:
Not a RCRA hazardous waste.
14. TRANSPORT INFORMATION
U.S. Department of Transportation Ground (49 CFR):
Proper shipping name:
Unrestricted
Hazard class or division:
None
Identification number:
None
Packing group:
None
International Air Transportation (ICAO/IATA):
Proper shipping name:
Unrestricted
Hazard class or division:
None
Identification number:
None
Packing group:
None
WaterTransportation (IMO/IMDG):
Proper shipping name:
Hazard class or division:
Identification number:
Packing group:
Marine pollutant:
Item number:
Unrestricted
None
None
None
None
27270
Product name: 272 Threadlocker High Strength
4 of 5
Page 14 of 320
15. REGULATORY INFORMATION
United States Regulatory Information
TSCA 8 (b) Inventory Status:
TSCA 12 (b) Export Notification:
All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
None.
CERCLA/SARA Section 302 EHS:
CERCLA/SARA Section 311/312:
CERCLA/SARA 313:
None above reporting de minimus.
Immediate Health Hazard, Delayed Health Hazard
This product contains the following toxic chemicals subject to the reporting requirements of section
313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Cumene
hydroperoxide (CAS# 80-15-9) .
California Proposition 65:
This product contains a chemical known to the State of California to cause cancer and birth defects or
other reproductive harm. o-Toluidine (CAS# 95-53-4). Propylene oxide (CAS# 75-56-9). Toluene
(CAS# 108-88-3).
Canada Regulatory Information
CEPA DSL/NDSL Status:
WHMIS hazard class:
All components are listed on or are exempt from listing on the Domestic Substances List.
D.2.A, D.2.B
16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections:
Expanded chemical information in Section 2 and related sections.
Kyra Kozak Woods, Health and Regulatory Affairs Specialist
Prepared by:
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Loctite
Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Loctite Corporation has
no control. It is the user's responsibility to determine the suitability of Henkel Loctite's products or any production methods mentioned
herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against
any hazards that may be involved in the handling and use of any of Henkel Loctite Corporation's products. In light of the foregoing,
Henkel Loctite Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness
for a particular purpose, arising from sale or use of Henkel Loctite Corporation's products. Henkel Loctite Corporation further disclaims
any liability for consequential or incidental damages of any kind, including lost profits.
Item number:
27270
Product name: 272 Threadlocker High Strength
5 of 5
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Page 20 of 320
Permatex, Inc.
10 Columbus Blvd.
Hartford, CT 06106 USA
Telephone: 1-87-Permatex
(877) 376-2839
Emergency: 800-255-3924 (ChemTel)
International Emergency: +01-813-248-0585
Material Safety Data Sheet
1. PRODUCT IDENTIFICATION
Product Name:
Item No:
Product Type:
66BR CLEAR RTV SILICONE ADHESIVE SEALANT 3 OZ
80050
Silicone
2. COMPOSITION/INFORMATION ON INGREDIENTS
Component
POLY (DIMETHYLSILOXANE),
HYDROXY TERMINATED
70131-67-8
AMORPHOUS SILICA
7631-86-9
DISTILLATES (PETROLEUM),
HYDROTREATED MIDDLE
64742-46-7
ETHYLTRIACETOXYSILANE
17689-77-9
METHYLTRIACETOXYSILANE
4253-34-3
ACETIC ACID
64-19-7
Weight%
>60
ACGIH; TLV-TWA
Not listed
OSHA PEL
Not listed
<10
Not listed
20 mppcf
<7
5 mg/m3
Not listed
<5
Not listed
Not listed
<5
Not listed
Not listed
0.5-2.0
5 mg/m3
10 ppm; 25 mg/m3
3. HAZARDS IDENTIFICATION
Toxicity:
Primary Routes of Entry:
Signs and Symptoms of Exposure:
May cause eye and skin irritation. May irritate lips, gums, tongue, mouth, nose and throat. May irritate
respiratory system upon frequent or prolonged use. ****When this product is exposed to moisture, acetic
acid may be formed. Note: This product does not contain microcyrstalline silica.
Eye and skin contact, ingestion, inhalation
Acetic acid produced during curing irritates eyes, nose and throat..
Component
Weight%
<10
AMORPHOUS SILICA
7631-86-9
Medical Conditions Recognized as
Being Aggravated by Exposure:
4. FIRST AID MEASURES
Ingestion:
Inhalation:
Skin Contact:
Eye Contact:
NTP
ACGIH Carcinogens
IARC
Group 3 Monograph 68, 1997
Methyltriacetoxysilane: Eye, skin and pulmonary disorders.
Rinse mouth. If swallowed, DO NOT induce vomiting. Keep individual calm. Obtain medical attention.
Move to fresh air in case of accidental inhalation of vapours. Obtain medical attention.
Wipe off material with paper towel or cloth. Wash off with soap and water. If skin irritation persists, call a
physician.
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical
attention if irritation persists.
5. FIRE FIGHTING MEASURES
Hazardous Products of Combustion:
Unusual Fire/Explosion Hazards:
>200°F TCC
Carbon Dioxide, Dry Chemicals, Foam.
Water spray may be ineffective on flames but should be used to keep fireexposed containers cool.
Oxides of carbon, Silica fume, Formaldehyde, Acetic acid
None.
Lower Explosive Limit:
Not determined
Flash Point °F(C°):
Recommended Extinguishing Media:
Special Fire-Fighting Procedures:
1 of 3
Page 21 of 320
Product Name: 66BR CLEAR RTV SILICONE ADHESIVE
SEALANT 3 OZ
5. FIRE FIGHTING MEASURES
Item No: 80050
Not determined
Upper Explosive Limit:
6. ACCIDENTAL RELEASE MEASURES
Spill Procedures:
Wipe or scrape up spill material. Maintain good ventilation for large spills. Place scrap material in a wellventilated area and allow to cure to rubber. Clean up spills thoroughly as residue is slippery.
7. HANDLING AND STORAGE
Storage:
Handling:
Store away from water or moisture. Keep away from oxidizers.
Avoid contact with skin and eyes. Do not wear contact lenses. Use only in a well ventilated area. Do not
take internally. Wash thoroughly after handling.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eyes:
Skin:
Ventilation:
Respiratory Protection:
Comments:
Safety glasses.
Neoprene or nitrile gloves recommended.
General; local exhaust ventilation as necessary to control any air contaminants to within their exposure
limits (or to the lowest feasible levels when limits have not been established) during the use of this product.
An approved organic vapor respirator should be worn when exposures are expected to exceed the
applicable limits.
When heated to temperatures above 300 degrees F. in the presence of air, this product can form
formaldehyde vapors. Formaldehyde is a potential cancer hazard and a known skin and respiratory
sensitizer. Safe handling conditions may be maintained by keeping vapor concentrations below the OSHA
permissible limit for formaldehyde
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Odor:
Boiling Point:
pH:
Solubility in Water:
Specific Gravity:
VOC(Wt.%):
Vapor Pressure:
Vapor Density (Air=1):
Evaporation Rate:
Clear paste
Acetic acid
Not applicable, polymeric material
Does not apply
Polymerized
1.01
3.0%; 30 g/l
10 mm Hg @ 80°F
Not Determined
Not Determined
10. STABILITY AND REACTIVITY
Chemical Stability:
Hazardous Polymerization:
Incompatabilities:
Conditions to Avoid:
Hazardous Products of Combustion:
Stable at normal conditions
Will not occur
Polymerized by contact with moisture. Acetic acid liberated.
Exposure to moisture.
Oxides of carbon, Silica fume, Formaldehyde, Acetic acid
11. TOXICOLOGICAL INFORMATION
See Section 3
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended Method of Disposal: Disposal should be made in accordance with federal, state and local regulations..
NH - Not a RCRA Hazardous Waste Material
US EPA Waste Number:
14. TRANSPORTATION INFORMATION
DOT (49CFR 172)
Ground Transport (DOT)
DOT Shipping Name:
Hazard Class:
Not regulated
None
2 of 3
Page 22 of 320
Product Name: 66BR CLEAR RTV SILICONE ADHESIVE
SEALANT 3 OZ
Item No: 80050
14. TRANSPORTATION INFORMATION
UN/ID Number:
None
Proper Shipping Name:
Class or Division:
UN/ID Number:
Not regulated
None
None
Proper Shipping:
Hazard Class:
UN Number:
Not regulated
None
None
Marine Pollutant:
None
IATA
IMDG
15. REGULATORY INFORMATION
SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical.
NONE
California Proposition 65: No California Prop 65 chemicals are known to be present at or above the No Significant Risk Level
TSCA Inventory Status: All components of this product are listed (or exempt) on the EPA TSCA inventory.
16. OTHER INFORMATION
HEALTH 2, FLAMMABILITY 1 , REACTIVITY 1.
HEALTH 2, FLAMMABILILTY 1, PHYSICAL HAZARD 0
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Estimated NFPA Rating:
Estimated HMIS Classification:
Prepared By:
Company:
Denise Boyd, Manager-Environmental, Health & Safety
Permatex. Inc. 10 Columbus Blvd. Hartford, CT USA 06106
Telephone No.:
1-87-Permatex (877) 376-2839
Revision Date: June 01, 2011
3
Revision
Number:
3 of 3
Page 23 of 320
ITW Permatex
10 Columbus Blvd.
Hartford, CT 06106 USA
Telephone: 1-87-Permatex
(877) 376-2839
Emergency: 800-255-3924 (ChemTel)
International Emergency: +01-813-248-0585
Material Safety Data Sheet
1. PRODUCT IDENTIFICATION
Product Name:
Item No:
Product Type:
765-1221 NAPA HIGH TACK GASKET SEALANT(PTX80062) 4 FL.OZ
21146
Sealant
2. COMPOSITION/INFORMATION ON INGREDIENTS
Component
ACETONE
67-64-1
METHYL ESTER OF ROSIN
68186-14-1
N-HEXANE
110-54-3
ROSIN
8050-09-7
ACRYLONITRILE-BUTADIENE
POLYMER
9003-18-3
Weight%
35-45
ACGIH; TLV-TWA
500 ppm
OSHA PEL
1000 ppm; 2400 mg/m3
20-30
Not listed
15-25
50 ppm
5-15
Not listed
Not listed
<10
Not listed
Not listed
Not listed
500 ppm; 1800 mg/m3
3. HAZARDS IDENTIFICATION
Toxicity:
Primary Routes of Entry:
Signs and Symptoms of Exposure:
May cause eye, skin and respiratory irritation. Reports have associated repeated and prolonged
overexposure to solvents with permanent brain and nervous system damage (sometimes referred to as
"solvent" or "painter's syndrome"). Symptoms include fatigue, concentration difficulties, anxiety,
depression, rapid mood swings, and short-term memory loss. Aspiration hazard if swallowed. Prolonged
and repeated exposure to methyl ethyl ketone and/or n-hexane may cause peripheral neuropathy by
damaging peripheral nerve tissue (that of arms and legs) and result in muscular weakness and loss of
sensation.
Eye and skin contact, ingestion, inhalation
Excessive overexposure may cause giddiness, dizziness, headache, nausea and in extreme cases,
unconsciousness and respiratory depression. Overexposure may cause eye and skin redness, difficulty
breathing and vomiting.
Component
Weight%
35-45
ACETONE
67-64-1
Aggravated Medical Condition:
4. FIRST AID MEASURES
Ingestion:
Inhalation:
Skin Contact:
Eye Contact:
ACGIH Carcinogens
A4 - Not Classifiable
as a Human
Carcinogen
IARC Carcinogen
Persons with preexisting respiratory, liver, kidney, eye or skin diseases may be adversely affected.
Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never
give anything by mouth to an unconscious person.
Move to fresh air in case of accidental inhalation of vapours. Oxygen or artificial respiration if needed.
Obtain medical attention.
Wash off with soap and water. If skin irritation persists, call a physician.
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical
attention if irritation persists.
5. FIRE FIGHTING MEASURES
Flash Point °F(C°):
Recommended Extinguishing Media:
Special Fire-Fighting Procedures:
NTP
Not known
0°F
Carbon Dioxide, Dry Chemicals, Foam.
Firefighters should wear self-contained breathing apparatus. Water spray
may be ineffective on flames but should be used to keep fire-exposed
containers cool.
1 of 3
Page 24 of 320
Product Name:
765-1221 NAPA HIGH TACK GASKET
SEALANT(PTX80062) 4 FL.OZ
5. FIRE FIGHTING MEASURES
Item No. 21146
Hazardous Products of Combustion:
Unusual Fire/Explosion Hazards:
Oxides of carbon
Closed containers may rupture or explode when exposed to extreme heat.
Keep containers cool.
Lower Explosive Limit:
Upper Explosive Limit:
2.0
13.0
6. ACCIDENTAL RELEASE MEASURES
Spill Procedures:
Eliminate all sources of ignition. Maintain good ventilation. Take up with an inert absorbent. Store in a
closed waste container until disposal.
7. HANDLING AND STORAGE
Storage:
Handling:
Store away from heat, sparks or open flame. Do not store at temperatures above 100°F (38°C).
Do not use near heat, sparks or open flame. Vapors may accumulate readily and may ignite explosively.
Use only in a well ventilated area. Do not take internally. Avoid contact with skin and eyes. Wash hands
before eating and smoking.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eyes:
Skin:
Ventilation:
Respiratory Protection:
Safety glasses.
Neoprene or nitrile gloves recommended.
General; local exhaust ventilation as necessary to control any air contaminants to within their exposure
limits (or to the lowest feasible levels when limits have not been established) during the use of this product.
An approved organic vapor respirator should be worn when exposures are expected to exceed the
applicable limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Odor:
Boiling Point:
pH:
Solubility in Water:
Specific Gravity:
VOC(Wt.%):
Vapor Pressure:
Vapor Density (Air=1):
Evaporation Rate:
Red, tacky liquid
Solvent
135°F
Does not apply
Partial
0.872
16.6 %
400 mm Hg
2.5
Faster than ether
10. STABILITY AND REACTIVITY
Chemical Stability:
Hazardous Polymerization:
Incompatabilities:
Conditions to Avoid:
Hazardous Products of Combustion:
Stable at normal conditions
Will not occur
Strong oxidizers
Keep away from heat, sparks and open flame. - No smoking.
Oxides of carbon
11. TOXICOLOGICAL INFORMATION
See Section 3
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended Method of Disposal: Disposal should be made in accordance with federal, state and local regulations.
D001 as per 40CFR 261.21
US EPA Waste Number:
14. TRANSPORTATION INFORMATION
DOT (49CFR 172)
U.S. Department of Transportation - DOT - 49 CFR (Ground)
DOT Shipping Name:
Hazard Class:
Adhesives, Limited Quantity
Class 3, PG II
Page 25 of 320
Product Name:
765-1221 NAPA HIGH TACK GASKET
SEALANT(PTX80062) 4 FL.OZ
Item No. 21146
14. TRANSPORTATION INFORMATION
UN 1133
UN/ID Number:
IATA (Air)
Proper Shipping Name:
Class or Division:
UN/ID Number:
Consumer Commodity
Class 9
ID 8000
IMDG (Vessel)
Proper Shipping Name:
Hazard Class:
UN Number:
Adhesives, Limited Quantity
Class 3, PG II
UN 1133
Marine Pollutant:
None
15. REGULATORY INFORMATION
SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical.
N-HEXANE
California Proposition 65: WARNING: This product contains chemicals known to the State of California to cause cancer and birth
defects or other reproductive harm
TSCA Inventory Status: All components of this product are listed (or exempt) on the EPA TSCA inventory.
16. OTHER INFORMATION
HEALTH 2, FLAMMABILITY 3 , REACTIVITY 0.
HEALTH 2, FLAMMABILITY 3, PHYSICAL HAZARD 0
(NFPA is a registered trademark of the National Fire Protection Association)
HMIS is a registered trademark of the National Paint and Coatings Association
Estimated NFPA Rating:
Estimated HMIS Classification:
Prepared By:
Company:
Telephone No.:
Denise Boyd, Manager-Environmental, Health & Safety
ITW Permatex 10 Columbus Blvd. Hartford, CT USA 06106
1-87-Permatex (877) 376-2839
Revision Date: January 26, 2012
Revision Number: 7
Page 26 of 320
MATERIAL SAFETY DATA SHEET
IDENTITY- ABC DRY CHEMICAL
SECTION I. Chemical Product and Company Identification
Product Name:
Synonym:
Manufacturer:
Telephone:
Emergency:
ABC Dry Chemical Fire Extinguishant
Multi-purpose Dry Chemical
Buckeye Fire Equipment Company
110 Kings Road
Kings Mountain, NC 28086
704.739.7415
CHEMTREC 1.800.424.9300
Revision Date:
6/13
SECTION II. Hazard Identification and Emergency Overview
Emergency Overview: Product is a light yellow, fine solid powder that is odorless.
Adverse Health Effects and Symptoms: Product is a moderate irritant to the respiratory system and eyes; a
mild irritant to the skin. Symptoms may include shortness of breath, coughing, and irritation to the eyes,
lungs, and skin. Ingestion may cause gastric irritation, nausea, and diarrhea.
Exposure Guidelines:
OSHA PEL
ACGIH TLV
Monoamonium phosphate
Particulates Not Otherwise Classified
Total Dust- 15 mg/m³
Respirable Fraction- 5 mg/m³
Particulates Not Otherwise Classified
Total Dust- 10 mg/m³
Respirable Fraction- 3 mg/m³
Barium sulfate
Particulates Not Otherwise Classified
Total Dust- 15 mg/m³
Respirable Fraction- 5 mg/m³
6 mg/m³
6 mg/m³
.1 mg/m³
Not Regulated
Not Regulated
Particulates Not Otherwise Classified
Total Dust- 10 mg/m³
Respirable Fraction- 3 mg/m³
3 mg/m³
10 mg/m³
.1 mg/m³
Not Regulated
Not Regulated
Mica
Silica
Stannous octoate
Silicone
Pigment
Hazard Symbols:
HMIS RATINGS:
Health
1
Flammability
0
Reactivity
0
Personal Protective Equipment: use N-95 dust mask (See Section 8)
WHMIS (Canadian Workplace Hazardous Materials Identification)
D2B- May irritate eyes, mucous membranes, and/or skin
SECTION III. Composition/Information on Ingredients
Monoammonium phosphate
Barium Sulfate
Mica
Silica
Stannous octoate
Silicone
Pigment
Weight %*
85
10
<3
<2
< .3
< .1
< .1
CAS #
7722-76-1
7727-43-7
12001-26-2
7631-86-9
301-10-0
63148-57-2
6358-31-2
* % is rounded to the nearest appropriate number. Values are not to be considered product specifications
Page 1 of 4
Page 27 of 320
MATERIAL SAFETY DATA SHEET
IDENTITY- ABC DRY CHEMICAL
SECTION IV. First Aid Measures
Eye Exposure- Flush eyes with water until pain-free. If irritation develops or persists, seek medical attention.
Skin Exposure- Wash with plenty of soap and water. If irritation develops or persists, seek medical attention.
Inhalation- Move victim to fresh air. If irritation develops or persists, seek medical attention.
Ingestion- If victim is conscious and alert, give 2-3 glasses of water to drink. Do not induce vomiting. If
vomiting occurs and the victim is conscious, give additional water to further dilute the chemical. Prevent
aspiration of swallowed product by laying victim on side with head lower than their waist. Seek medical
attention. Do not leave victim unattended.
Medical Conditions Possibly Aggravated by Exposure- Inhalation of the product may aggravate existing
chronic respiratory conditions such as asthma, emphysema, or bronchitis. Contact with the skin may
aggravate an existing skin disease. Chronic overexposure may cause pneumoconiosis (“Dusty Lung” disease).
SECTION V. Firefighting Measures
Extinguishing Media: N/A. This product is an extinguishing agent. It is nonflammable and noncombustible.
Special Firefighting Procedures: N/A
Unusual Fire and Explosion Hazards: This product may decompose in fire and release oxides of carbon,
potassium, and nitrogen (Refer to Section X).
Sensitivity to Mechanical Impact or Static Discharge: None
SECTION VI. Accidental Release Measures
In case of accidental release, use the appropriate respiratory protection. Clean up the product using a vacuum
or wet sweep and shovel to minimize the generation of dust. Bag or drum the product for disposal. If the
product is used and/or contaminated, use personal protective equipment and containment means that are
appropriate for the composition of the mixture. Product should be prevented from entering waterways.
SECTION VII. Handling and Storage
Avoid eye, respiratory, and skin exposure. Use the appropriate personal protective equipment when handling.
Wash thoroughly after handling (Refer to Section VIII). Product should be stored in its original container or
extinguisher. When the product is contained under pressure (e.g., an extinguisher), inspect the container for
rust or damage that may compromise the container integrity. Do not store the product in high humidity and do
not mix with other extinguishing agents, particularly potassium bicarbonate based agents.
SECTION VIII. Exposure Controls and Personal Protection
During the use of this product on fires, exhaust gases and products of incomplete combustion are the main
respiratory hazards. In the manufacture of this product, employers and employees must use their collective
judgment in determining the on-the-job settings where the use of a dust mask or respirator is prudent. The
need for respiratory protection is not likely for short-term use in well-ventilated areas.
Respiratory Protection: Use an N-95 dust mask for limited exposures and use air-purifying respirators with
high efficiency particulate air filters (HEPA filters) for prolonged exposures.
Eye Protection: Wear chemical goggles or full-face air-purifying respirator.
Skin Protection: Use nitrile, latex, or similar gloves and coveralls. Good personal hygiene practices are
essential. After handling the product, avoid food, tobacco products, or other means of transferring the product
from hand to mouth until after thoroughly washing.
Page 2 of 4
Page 28 of 320
MATERIAL SAFETY DATA SHEET
IDENTITY- ABC DRY CHEMICAL
SECTION IX. Physical and Chemical Properties
Appearance and Odor: Light yellow fine powder that is odorless.
Apparent Density: 0.82
Solubility: The product is coated with water repellant silicone. Not immediately soluble in water.
pH: Approximately 4 -5
Flash Point: N/A
Flammability: N/A
Vapor Pressure: N/A
Boiling Point: N/A
Explosive or Oxidizing Properties: None
SECTION X. Stability and Reactivity
Stability: Stable
Incompatibles: Magnesium, strong oxidizers such as calcium hypochlorite (pool chlorine), strong alkalis, and
isocyanuric acids.
Decomposition Products: This product may decompose in fire and release carbon monoxide, carbon dioxide,
and sulfur dioxide. Oxides of phosphorous and ammonia have been reported.
Hazardous Polymerization: Will not occur
Hazardous Reactions: None
SECTION XI. Toxicological Information
Acute Toxicity:
Monoammonium phosphate LD50 (rat): > 1000mg/kg body weight.
Target organs in humans: respiratory system, eyes, and skin. This product is an irritant to
epithelial tissue and may aggravate dermatitis. No indication that the product causes
sensitization.
Chronic Toxicity: Pneumoconiosis, or “Dusty Lung” disease, may result from chronic exposure to any dust.
Reproductive Toxicity: This product is not known to have any reproductive effects.
SECTION XII. Ecological Information
Ecotoxicity: Negative effects are unknown. Provides nutrient nitrogen and phosphorous to plant life.
Degradability: Degrades rapidly in wet or humid environment.
Bioaccumulation: Unknown extent.
Mobility in Soil: Water-soluble. May leech in to groundwater.
SECTION XIII. Considerations for Disposal
This product is not a RCRA characteristically hazardous or listed hazardous waste. Dispose of according to
state or local laws, which may be more restrictive than federal regulations. Be aware that product used on a
fire may be altered or contaminated and thereby require different disposal considerations.
SECTION XIV. Transportation Information
This product is not defined as a hazardous material under U.S. Department of Transportation 49 CFR 172, or
by Transport Canada “Transportation of Dangerous Goods” regulations.
Please Note: Although this material is not considered hazardous, when contained in a stored pressure fire extinguisher
pressurized with a nonflammable gas, the extinguisher itself is considered hazardous material by the U.S. Department of
Transportation (USDOT) and Transport Canada (TC). Packaging of the fire extinguisher shall be identified with the
Proper Shipping Name (Fire Extinguisher) and the UN Identification Number (UN 1044). The USDOT hazard
class/division is 2.2 Nonflammable Gas. Packing Group = N/A
Page 3 of 4
Page 29 of 320
MATERIAL SAFETY DATA SHEET
IDENTITY- ABC DRY CHEMICAL
SECTION XV. Regulatory Information
International Inventory Status: All ingredients are on the following inventories
Country
U.S.A.
Canada
Europe
Australia
Japan
South Korea
Agency
TSCA
DSL
EINECS/ELINCS
AICS
MITI
KECL
European Risk and Safety Phrases:
EU ClassificationHarmful
R Phrases-
22
Harmful if swallowed
36/37/38 Irritating to eyes, respiratory system, and skin.
S Phrases-
26
36
In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice
Wear suitable protective clothing
U.S. Federal Regulatory Information:
None of the chemicals in this product are under SARA reporting requirements or have SARA
Threshold Planning Quantities or CERCLA Reportable Quantities, or are regulated under TSCA
8(d).
State Regulatory Information:
Chemicals in this product are covered under the specific State regulations noted:
Alaska
Designated Toxic and Hazardous Substances- None
California
Permissible Exposure Limits for Chemical Contaminants- None
Florida
Substance list- Mica dust
Illinois
Toxic Substance List- None
Kansas
Section 302/303 List- None
Massachusetts
Substance list- Mica dust
Minnesota
List of Hazardous Substances- None
Missouri
Employer Information/Toxic Substance List- None
New Jersey
Right to Know Hazardous Substance List- None
North Dakota
List of Hazardous Chemicals, Reportable Quantities- None
Pennsylvania
Hazardous Substance List- None
Rhode Island
Hazardous Substance List- Mica dust
Texas
Hazardous Substance List- No
West Virginia
Hazardous Substance List- None
Wisconsin
Toxic and Hazardous Substances- None
California Proposition 65- No component is listed on the California Proposition 65 List
SECTION XVI. Other Information
This MSDS conforms to the requirements under U.S., U.K., Canadian, Australian, and EU Regulations or
Standards. It conforms to the proposed 2003 ANSI Z400.1 format.
The information contained herein is given in good faith as typical values and not as product specifications. No
warranty, either expressed or implied, is hereby made.
Page 4 of 4
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Page 40 of 320
MATERIAL SAFETY DATA SHEET
AIR BRAKE ANTI FREEZE
SECTION I – MANUFACTURER’S NAME AND CONTACT INFORMATION
Manufacturer
E-Zoil Products, Inc.
2355 Bailey Avenue
Buffalo, NY 14215
NFPA Code:
Emergency 1-800-424-9300 Chemtrec
Information 716-892-4632
Date prepared July 1, 2005
Health 3
Fire 3
Reactivity 0
SECTION II – HAZARDOUS INGREDIENTS/IDENTITY INFORMATION
Methanol, Methyl Alcohol, Carinol
Alcohol Methylhydrate
CH3OH
CAS# 67-56-1
SECTION III – PHYSICAL & CHEMICAL CHARACTERISTICS
Boiling point 148°F
Vapor pressure 268mm @ 104°F
Vapor density 1.11
Specific gravity 0.7080 @ 77°F
Melting point minus 144°F
Colorless liquid mild alcohol odor
SECTION IV – FIRE & EXPLOSION HAZARD DATA
Flammable/Combustible: Yes
In the presence of an ignition source. Water spray, dry powder, AFFF (Aqueous Film Forming foam). Alcohol resistant type with
a 6% foam proportioning equipment or CO2.
Methanol burns with a clean clear flame which is almost invisible in daylight.
Concentrations of greater than 20% methanol in water can be ignited. Water may be ineffective depending upon depth of
methanol burning. Use fine water spray or fog to control fire spread and cool structures or containers. Fire fighters must wear full
face, positive pressure, self-contained breathing apparatus or airline and appropriate protective clothing.
Flash point 54°F tag closed LEL 6% UEL 36.5% tag open 61°F
Special fire fighting procedures: Use water spray or fog. Avoid spreading fire by flooding. Use alcohol type foam for larger
spills. Exposure to heat builds up pressure in closed drums. Cool with water and avoid sparks. Bulk vessels should be grounded.
Dispose of drum in accordance with proper local, state, and/or federal regulations.
SECTION V – REACTIVITY DATA
Stable
Conditions to avoid: Keep away from heat, sparks or open flame. Vapor flammable keep container closed.
Materials to avoid: Incompatible with strong oxidizers, strong acids, strong bases. May be corrosive to lead and aluminum.
Hazardous decomposition: Burning may produce carbon monoxide
SECTION VI – HEALTH HAZARD DATA
Routes of entry: Inhalation – Yes Skin – Yes Ingestion – Yes
Swallowing even small amounts of methanol can cause blindness and death other effects may be nausea, headache, abdominal
pain, vomiting and visual disturbances ranging from blurred vision to light sensitivity. If conscious give large amount of water or
milk and induce vomiting. Get medical attention immediately. Inhalation of high airborne concentration can also irritate mucous
membranes, cause headaches, sleepiness, nausea, confusion, loss of consciousness, digestive and visual disturbances and death.
Note: May be absorbed through the skin in toxic or lethal amounts. Causes mild irritation, redness, cracking and drying.
Page 41 of 320
First Aid:
Inhalation: Remove to fresh air. Keep individual quiet. For respiratory distress give oxygen and or CPR. Obtain medical
attention.
Eye: Flush with plenty of low-pressure water for at least 15 minutes. Retract eyelids often. Obtain emergency medical attention
Skin: Immediately remove contaminated clothing. Wash skin with soap and water. If irritation persists seek medical attention.
wash clothing before reuse. Wash or discard contaminated leather shoes or gloves
Ingestion: Induce vomiting by forcing finger down throat or give soapy water to drink. Repeat until vomit is clear. Get
immediate medical attention.
SECTION VII – PRECAUTIONS FOR SAFE HANDLING AND USE
Storage: Store in totally enclosed equipment, designed to avoid ignition and human contact. Tanks must be grounded and vented
and should be nitrogen blanketed. Tanks must be diked. Avoid storage with incompatible materials.
Handling: No smoking or open flame in storage, use or handling areas. Use explosion proof electrical equipment. Ensure proper
electrical grounding procedures are in place.
SECTION VIII – CONTROL MEASURES
Extremely flammable liquid. Release can cause an immediate fire/explosion hazard. Eliminate all ignition sources, stop spill and
use absorbent materials. If necessary, contain spill by diking. Maximize methanol recovery for recycling or reuse if applicable.
Collect liquid with explosion proof pumps. For small spills, collect with a non-combustible sorbent. Recover methanol or dilute
with water to reduce fire hazard. Prevent it from entering sewer, confined spaces, drains or waterways. Restrict access to
unprotected personnel. Full-face, positive pressure self-contained breathing apparatus or airline and protective clothing must be
worn.
SECTION IX – TRANSPORT INFORMATION
Chemical Family – Aliphatic alcohol
Proper shipping name – Methyl alcohol methanol
Hazardous class # (Flammable Liquid) PG II
UN 1230
Disclaimer of liability: the information in this msds was obtained from sources we believe are reliable, however the information is
provided without any warranty expressed or implied regarding its correctness. The conditions or methods of handling, storage, use
of , disposal of the product may be beyond our control or knowledge. For this reason we do not assume responsibility and
expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or
disposal of this product.
Page 42 of 320
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Material Safety
Data Sheet (MSDS)
Keyword
NAPA Part No.
Non-NAPA Part No.
533,SL2539
MATERIAL SAFETY DATA SHEET
Section 1: Product & Company Identification
Job Type Search
Enter Zip
Parts Store
Repair Shop
Collision Center
Truck Center
Product Name:
Product Number(s)
Air Tool Oil
SL2531-SL2533,SL2539
Manufactured By:
CRC Industries, Inc.
885 Louis Drive, Warminster, PA 18974
24-Hour Emergency Information: CHEMTREC
(215) 674-4300
(800)424-9300
--------------------------------------------------------------------------Section 2: Composition/Information on Ingredients
Component
CAS
ACGIH
OSHA
OTHER
%
NUMBER
TLV
PEL
LIMITS
Mineral Oil (heavy)
64741-96-4
5 mg/m3 5 mg/m3
(mist)
>90
Zinc Dithiophosphate
68649-42-3
NE
NE
NE
<1
Carboxylic Acid Amine
Soap Complex
Mixture
NE
NE
NE
1
---------------------------------------------------------------------------Section 3: Hazards Identification
____________________________________________________________________________
Emergency Overview
Appearance & Odor: Dark amber, semi-solid to solid material with faint odor
____________________________________________________________________________
Click here to apply for the
NAPA VISA© Card
Potential Health Effects:
Inhalation:
Irritation to nose, throat or upper resiratory tract
Eyes:
Irritation
Skin:
Irritation
Ingestion:
NA
Carcinogenicity:
OSHA:
No
Chronic Overexposure:
Medical Conditions Aggravated
by Exposure:
conditions.
IAARC:
NA
No
NTP:
No
Pr-existing skin and pre-respiratory
---------------------------------------------------------------------------Section 4: First Aid Measures
Inhalation:
necessary.
Remove to fresh air.
Give artificial respiration if
Eyes:
Flush with large amounts of water for 15 minutes.
Skin:
and water.
Remove contaminated clothing and wash area with soap
Ingestion:
Call a physician.
Do not induce vomiting.
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Page 2 of 3
---------------------------------------------------------------------------Section 5: Fire-Fighting Measures
Flashpoint:
>300 F
Method:
TCC
LEL: ND
UEL:
Extinguishing Media:
Carbon dioxide, dry chemical and foam
Hazardous Combustion Products: CO2 and carbon monoxide
Fire-Fighting Instructions:
Remove containers from fire area if
possible Use self-contained breathing
apparatus for fire fighting.
NFPA:
HMIS:
Health:
Health:
1
1
Flammability:
Flammability:
1
1
Reactivity:
Reactivity:
0
0
ND
PPE:
B
---------------------------------------------------------------------------Section 6: Accidental Release Measures
Spill/Leak Procedures: Area should be ventilated. Absorbant should be used
to pick up excess material. All used and unused product should be disposed
of in accordance with federal, state and local regulations.
---------------------------------------------------------------------------Section 7: Handling and Storage
Handling Procedures: Store in a cool, dry area.
---------------------------------------------------------------------------Section 8: Exposure Controls/Personal Protection
Engineering Controls: Adequate to prevent accumulation of vapors. Use
mechanical means if necessary to maintain levels below the exposure limits.
If working in a confined space, follow applicable OSHA regulations.
Respiratory: Use NIOSH/MSHA compliant respirators or self contained
breathing apparatus above exposure limits. Follow OSHA regulations
29 CFR 1910.134.
Protective Clothing/Equipment: Wear chemically protective gloves and
safety glasses. Use a splash apron and boots if splashing occurs.
---------------------------------------------------------------------------Section 9: Physical & Chemical Properties
Physical State:
solid
odor.
Specific Gravity:
Freezing Point:
Evaporation Rate:
pH:
Semi-
.85-.95
ND
Neg.
NA
Appearance & Odor:
Dark amber, semi-solid to
solid material w/ faint
Boiling Point:
Vapor Pressure:
Vapor density (air=1)
Solubility:
Volatile Organic Compounds:%:
3
g/L
27
>600 F
Neg.
>air
Neg.
lbs./gal:
0.23
---------------------------------------------------------------------------Section 10: Stability and Reactivity
Stability:
Chemical Incompatibilities:
Materials to Avoid:
water.
Hazardous Decomposition
Products:
Stable
Hazardous Polymerization:
Strong oxidizers
Strong oxidizing agents.
No
None
---------------------------------------------------------------------------Section 11: Toxicological Information
Long-term toxicological studies have not been conducted for this product.
See section 3 of this MSDS for acute symptoms of overexposure and
carcinogenicity information.
---------------------------------------------------------------------------Section 12: Ecological Information
Ecotoxicity:
Environmental Fate:
No data available.
No data available for bioegradation.
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Page 3 of 3
---------------------------------------------------------------------------Section 13: Disposal Considerations
Disposal: This material if discarded may be hazardous waste under U.S. EPA
RCRA regulations. All disposal activities must comply with federal, state
and local regulations. Contact your local or state environmental agency
for specific rules. Do not dump into sewers, on the ground or into body
of water.
---------------------------------------------------------------------------Section 14: Transportation Information
Shipping Name:
Not regulated
Hazard Class:
NA
UN Number: NA
Packing Group: NA
Label:
NA
Placard:
NA
Special Provisions: NA
---------------------------------------------------------------------------Section 15: Regulatory Information
TSCA:
All components are either listed under TSCA or are exempt.
SARA Title III:
Section 311/312: NA
Section 313*:
None
CERCLA/Superfund (RQ):
NA
Extremely Hazardous Substances:
No
California Prop 65:
No
*See section 2 for percentage
---------------------------------------------------------------------------Section 16: Additional Information
Prepared By:
Adam M. Selisker
Date:
March 29, 1999
Technical Information: (800) 521-3168
CRC #: SL2531
This information is accurate to the best CRC Industries' knowledge or
obtained from sources believed by CRC to be accurate. Before using any
product, read all warnings and directions on the label.
CAS:
ppm:
TCC:
LEL:
UEL:
PPE:
COC:
Chemical Abstract Service
Parts per Million
Tag Closed Cup
Lower Exposure Limit
Upper Exposure Limit
Personal Protection Equipment
Cleveland Closed Cup
NA:
ND:
NE:
g/L:
lbs./gal:
RQ:
Not Applicable
Not Determined
Not Established
grams per Liter
pounds per gallon
Reportable Quantity
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2/16/2004
CLN010
OATEY CLEAR CLEANER
Latest Revision Date...03/10/00
==================================================================================
Section 1 IDENTITY OF MATERIAL
TRADE NAME
OATEY CLEAR CLEANER
PRODUCT NUMBERS
30766, 30779, 30782, 30795, 30805
FORMULA
CH(3)COC(2)H(5)+CH(3)COCH(3)
SYNONYMS
Methyl Ethyl Ketone and Acetone
==================================================================================
SECTION 2 HAZARDOUS INGREDIENTS
INGREDIENTS
%
CAS NUMBER
SEC 313
Methyl Ethyl Ketone
60-80%
78-93-3
Yes
Acetone
20-40%
67-64-1
No
==================================================================================
SECTION 3 KNOWN HAZARDS UNDER 29 CFR 1910.1200
HAZARDS
YES
Combustible Liquid
Flammable Liquid
NO
HAZARDS
YES
X
Skin Hazard
X
Eye Hazard
X
X
X
NO
Pyrophoric Material
X
Toxic Agent
Explosive Material
X
Highly Toxic Agent
X
Unstable Material
X
Sensitizer
X
Water Reactive Material
X
Kidney Toxin
X
Oxidizer
X
Reproductive Toxin
Organic Peroxide
X
Blood Toxin
Corrosive Material
X
Nervous System Toxin
X
Compressed Gas
X
Lung Toxin
X
Irritant
Carcinogen NTP/IARC/OSHA
(see SECTION 6)
X
Liver Toxin
X
X
X
X
==================================================================================
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CLN010
SECTION 4 REGULATION
CHEMICAL
TLV (TWA)
PEL
STEL
Hazard Action
Level
Methyl Ethyl Ketone
200 ppm
200 ppm
300 ppm
N/A
590 mg/cu m
590 mg/cu m
885 mg/cum
500 ppm
1000 ppm
750 ppm
1200 mg/cu m
2400 mg/cu m
1800 mg/cu m
Acetone
N/A
==================================================================================
SECTION 5 REGULATED IDENTIFICATION
DOT PROPER SHIPPING NAME
CONSUMER COMMODITY ORM-D; For Gallons: Flammable Liquid, N.O.S., 3,
UN1993, PG II
DOT HAZARD CLASS
Class 3 Flammable Liquid
SHIPPING ID NUMBER
UN 1993 (Gallons Only)
EPA HAZARDOUS WASTE ID
NUMBER
F-003 & F-005
EPA HAZARD WASTE CLASS
Ignitable Waste/Toxic Waste
==================================================================================
SECTION 6 EFFECTS OF EXPOSURE
ENTRY ROUTE
INHALE - YES INGEST - YES SKIN - YES EYE - YES
INHALATION
May cause irritation of mucous membranes, nose & throat, headache, dizziness, nausea,
numbness of the extremities and narcosis in high concentrations. Has caused CNS depression
& liver damage in animals, & high concentrations have caused retardation of fetal
development in rats.
TARGET ORGANS
Eye, Skin, Lung, Central Nervous System
SKIN
Chronic contact may lead to irritation & dermatitis. Chronic exposure to vapors of high
concentration may cause dermatitis. May possibly be absorbed through the skin.
EYE
Vapors or direct contact may cause irritation.
INGESTION
May be aspirated into the lungs or cause systemic effects described under inhalation.
==================================================================================
SECTION 7 EMERGENCY AND FIRST AID PROCEDURES - 303/623-5716 COLLECT
SKIN
If irritation arises, wash thoroughly with soap and water. Seek medical attention if irritation persists.
EYES
If fumes cause irritation, move to fresh air and irrigate eyes with water for 15 minutes. If irritation
persists, seek medical attention. If eye is struck with wire, seek medical attention.
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CLN010
INHALATION
Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Keep
victim quiet and warm. Call a poison control center or physician immediately.
INGESTION
Drink water and call a poison control center or physician immediately. Avoid alcoholic beverages.
Never give anything by mouth to an unconscious person.
==================================================================================
SECTION 8 PHYSICAL AND CHEMICAL PROPERTIES
NFPA HAZARD SIGNAL
HEALTH 2 STABILITY 1 FLAMMABILITY 3 SPECIAL NONE
BOILING POINT
133 Degrees F / 66 C
MELTING POINT
N/A
VAPOR PRESSURE
186 mmHg @ 20 Degrees C
VAPOR DENSITY (AIR =
1)
2.0
VOLATILE
COMPONENTS
100%
SOLUBILITY IN WATER
27.1% @ 20 degrees C
PH
N/A
SPECIFIC GRAVITY
0.793
EVAPORATION RATE
(BUAC = 1) = 7.7
APPEARANCE
Clear Liquid
ODOR
Sharp, ether odor
WILL DISSOLVE IN
Water, organic solvents
MATERIAL IS
Liquid
==================================================================================
SECTION 9 FIRE AND EXPLOSION HAZARD DATA
FLAMMABILITY
LEL =2.15 % Volume UEL= 13.0 % Volume
FLASHPOINT AND METHOD
USED
0-3 Degrees F. / PMCC
STABILITY
Stable CONDITIONS TO AVOID: Heat, sparks and open flame. HAZARDOUS
DECOMP. PDTS: Carbon monoxide/ carbon dioxide/hydrogen chloride/smoke.
HAZARDOUS
POLYMERIZATION
Will Not Occur. CONDITIONS TO AVOID: None
INCOMPATIBILITY/ MAT. TO
AVOID
Acids, oxidizing materials, alkalis, chlorinated inorganics (potassium, calcium and sodium
hypochlorite), copper or copper alloys.
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CLN010
SPECIAL FIRE FIGHTING
PROCEDURE
FOR SMALL FIRES: Use dry chemical, CO2, water or foam extinguisher.
FOR LARGE FIRES: Evacuate area and call Fire Department immediately.
==================================================================================
SECTION 10 SPILL AND DISPOSAL INFORMATION
SPILL OR LEAK
PROCEDURES
Ventilate area, stop leak if it can be done without risk. Take up with sand, earth, or other
non-combustible absorbing material.
WASTE DISPOSAL
Dispose of according to local, state, and Federal regulations.
==================================================================================
SECTION 11 SAFE USAGE DATA
PROTECTIVE
EQUIPMENT TYPES
EYES: Safety glasses with side shields. RESPIRATORY: NIOSH-approved canister respirator in
absence of adequate ventilation. GLOVES: Rubber gloves. OTHER: Eye wash and safety shower
should be available.
VENTILATION
LOCAL EXHAUST: Open doors & windows. Exhaust ventilation capable of maintaining
emissions at the point of use below PEL. If used in enclosed area, use exhaust fans. Exhaust fans
should be explosion-proof or set up in a way that explosive concentrations of solvent vapors are
not exposed to electrical fixtures or hot surfaces.
PRECAUTIONS
HANDLING & STORAGE: Keep away from heat, sparks and flames; store in cool, dry place.
OTHER: Containers, even empties will retain residue and vapors.
==================================================================================
SECTION 12 MANUFACTURER OR SUPPLIER DATA
FIRM NAME & MAILING
ADDRESS
OATEY CO., 4700 West 160th Street, P.O. Box 35906 Cleveland, Ohio 44135
OATEY PHONE NUMBER
(216) 267-7100
EMERGENCY PHONE
NUMBER
For Emergency First Aid call (303) 623-5716 COLLECT For chemical transportation
emergencies ONLY, call Chemtrec at 1-800-424-9300
==================================================================================
SECTION 13 DISCLAIMER
The information herein has been compiled from sources believed to be reliable, up-to-date, and is accurate to the best of our
knowledge. However, Oatey cannot give any guarantees regarding information from other sources, and expressly does not make
warranties, nor assumes any liability for its use.
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®
– Material Safety Data Sheet –
Battery Cleaner (Spray)
SECTION I
Manufacturer’s Name:
Sprayon Products
(Battery Cleaner, Aerosol)
26300 Fargo Avenue, Bedford Heights, OH 44146
Date: May 2000
Distributor’s Name:
East Penn Manufacturing Co., Inc.
Deka Road, Lyon Station, PA 19536
Telephone Number for Information: (610) 682-6361
East Penn Product I.D.: 00321, 00323
Emergency Telephone Number: CHEMTREC: 1-800-424-9300,
In Washington D.C. or outside continental U.S., call 1-202-483-7616
SECTION II
HAZARDOUS INGREDIENTS/IDENTITY INFORMATION
Hazardous Components
Specific Chemical Identity
(Common Name (s))
Sodium Bicarbonate
Water
Propellant:
Isobutane
or
Butane
or
Propane
Detergents
2-Butoxy Ethanol
CAS #
#144-55-8
OSHA PEL
N/A
N/A
ACGIH TLV
N/A
N/A
Percent
<10.0
>90.0
#75-28-5
N/A
N/A
<10.0
#106-97-8
800 ppm
800 ppm
<10.0
#74-98-6
Mixture
#111-76-2
1000 ppm
N/A
25 ppm
2500 ppm
N/A
25 ppm
<10.0
<10.0
<10
SECTION III
PHYSICAL/CHEMICAL CHARACTERISTICS
Chemicals without propellent/Propeltent
Appearance and Odor: A quick breaking foam
Solubility in Water: Soluble in water
Freezing Point: 32°F/Not Determined
Boiling Point: 212°F/-213°F
Evaporation Rate: Not Determined
Specific Gravity (H20=1): 1.04/.095
Vapor Density (AIR=1): Not Determined
Vapor Pressure (mm Hg): Not Determined
% Volatile: 3%/97%
SECTION IV
FIRE AND EXPLOSION HAZARD DATA
Flash Point (Method Used): Propellant below 20°F (TOC)
Flammable Limits: Propellent
Extinguishing Media: Carbon dioxide, foam, dry chemicals
LEL: 1.9
UEL: 9.5
Unusual Fire and Explosion Hazards: Do not spray near open flame. Aerosol cans may explode. Flammable material.
Special Fire Fighting Procedures: Remove aerosol containers from fire area if possible.
SECTION V
REACTIVITY DATA
Stability: Stable
Conditions to Avoid: Do not store above 120°F to prevent cans from exploding
Hazardous Decomposition of By-Products: Carbon monoxide, carbon dioxide
Page 50 of 320
MSDS: Battery Cleaner (Spray): Page 2 of 2
SECTION VI
HEALTH HAZARD DATA
Primary Route(s) of Entry: Inhalation, skin and ingestion
Signs and Symptoms of Exposure: Inhalation: Over-exposure may result in light-headedness, staggering gait, giddiness, and
possible nausea. Skin and Eyes: May cause irritation. Ingestion: Harmful or fatal if swallowed.
Chronic Overexposure: Reports have associated repeated and prolong overexposure to solvents with permanent brain and nervous
system damage.
Medical Conditions Generally Aggravated by Exposure: None identified
Emergency and First Aid Procedures:
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Ingestion: Induce vomiting on the advice of a
physician. Eyes: Flush with water for 15 minutes. Skin: Remove contaminated clothing and wash with soap and water
SECTION VII
PRECAUTIONS FOR SAFE HANDLING AND USE
Steps to be Taken in Case Material is Released or Spilled: Remove all sources of ignition, ventilate, avoid breathing vapors, and
remove with inert absorbent.
Waste Disposal Method: Dispose of in accordance with local, state or applicable federal regulations.
Precautions to be Taken in Handling and Storing: Do not store above 120°F. Keep away from children. DO not puncture or
incinerate. Do not spray near fire or open flame.
SECTION VIII
CONTROL MEASURES
Respiratory Protection (Specific Type): Use NIOSH/MSHA compliant respirators or self contained breathing apparatus above
exposure limits.
Ventilation: Adequate to prevent accumulation of vapors.
Protective Clothing: Wear chemically protective gloves and safety glasses. Use splash aprons and boots if splashing occurs.
Eye and Face Protection: Safety glasses, face shield if splashing occurs.
Other Protective Equipment: Not needed.
SECTION IX
OTHER REGULATORY INFORMATION
Health (Blue)
Flammability (Red)
Reactivity (Yellow)
NFPA
1
4
0
HMIS
1
4
0
SARA Title III: Section 311/312: Acute Section 313: 2 Butoxy Ethanol
Extremely Hazardous Substance: No
For additional information concerning East Penn Manufacturing Co., Inc. products or questions concerning the content of this MSDS
please contact your East Penn representative.
This information is accurate to the best of East Penn Mfg. Co.’s knowledge or obtained from sources believed by East Penn to be
accurate. Before using any product, read all warnings and directions on the label.
Page 51 of 320
Material Safety Data Sheet
U.S. Department of Labor
May be used to comply with
OSHA's Hazard Communication Standard,
29 CFR 1910.1200. This Standard must be
consulted for specific requirements.
Occupational Safety and Health Administration
(Non-Mandatory Form)
Form Approved
OMB No. 1218-0072
IDENTITY (As Used on Label and List)
BernzOmatic BF55 Butane Fuel
Note: Blank spaces are not permitted. If any item is not
applicable, or no information is available, the space must be
marked to indicate that.
Section I
Manufacturer's Name
Emergency Telephone Number
BernzOmatic
800-654-9011
Address (Number, Street, City, State, and ZIP Code)
Telephone Number for Information
1 Bernzomatic Drive
Date Prepared
Medina, NY 14103
Signature of Preparer (optional)
800-424-9300
August 2010
Section II - Hazard Ingredients/Identity Information
Hazardous Components (Specific Chemical Identity;
Common Name(s))
Liquefied Petroleum Gas
N,Butane, volume
Isobutane, volume
(CAS #106-97-8)
(CAS #75-28-5)
OSHA PEL
ACGIH
TLV
1000 ppm
1000 ppm
1000 ppm
1000 ppm
Other Limits
Recommended
%
(optional
22%
78%
Section III - Physical/Chemical Characteristics
Boiling Point
-11.7°F
Specific Gravity (H2O = 1)
Vapor Pressure (mm Hg.)
Approx. 28 psig
Percent Volatile by Weight
Vapor Density (AIR = 1)
Greater than 2
Evaporation Rate
(Butyl Acetate = 1)
Solubility in Water
Less than 0.1% by weight @70°F
Appearance and Odor
Liquefied compressed gas, flash evaporates at room temperature when
released from can, colorless gas with essentially no odor.
0.5676
100%
Gas
Page 52 of 320
2
Section IV - Fire and Explosion Hazard Data
Flash Point (Method Used)
Less than -117ΕF
Flammable Limits
LEL
UEL
Extremely Flammable
LEL% 1.8
UEL% 8.4
(Reference - Consumer
Product Commission, flame
projection test for aerosol
products, per 16 CFR500.45)
Extinguishing Media
If feasible, stop flow of gas. Use water to cool fire-exposed cans, surroundings
and to protect personnel working on shut off. Water spray, dry powder or carbon
dioxide can be directed at flame area, if gas flow cannot be stopped, to reduce fire
intensity. DO NOT COMPLETELY EXTINGUISH FLAME UNLESS GAS
FLOW IS SHUT OFF!
Special Fire Fighting Procedures
Avoid possible accumulations of vapors at floor level, as vapor is heavier than
air. Self-contained breathing apparatus and protective clothing should be worn
in fighting fires involving chemicals.
This product is extremely flammable at all times. Keep away from any sources
of inadvertent ignition, including heat, fire, sparks, or flame.
Unusual Fire and Explosion Hazards
This product presents an extreme fire hazard. Liquid very quickly evaporates,
even at low temperatures, and forms vapor (fumes) which can catch fire and burn
with explosive violence. Invisible vapor spreads easily and can be set on fire by
many sources such as pilot lights, welding equipment, and electrical motors and
switches.
For fires involving this material, do not enter any enclosed or confined fire space
without proper protective equipment. This may include self-contained breathing
Apparatus against the hazardous effects of normal products of combustion of
oxygen deficiency. Petroleum gases are heavier than air and travel along the
ground or into drains to possible distant ignition sources, causing an explosive
flashback.
Section V - Reactivity Data
Stability
Unstable
Stable
Conditions to Avoid
Stable when stored as
a liquid in cans under
its own pressure.
Contact with sparks, open flame or any
source of ignition.
Incompatibility (Materials to Avoid)
Hazardous Decomposition or Byproducts
May produce carbon monoxide when oxidized with deficiency of oxygen.
Hazardous
Polymerization
May Occur
Will Not Occur
Conditions to Avoid
X
N/A
16.2
Page 53 of 320
3
Section VI - Health Hazard Data
Route(s) of Entry:
Inhalation? YES
Skin? YES
Ingestion? NO
IARC Monographs? NO
OSHA Regulated? NO
Inhalation, skin contact,
eye contact
Health Hazards (Acute and Chronic)
Carcinogenicity:
NTP? NO
None of the components in this material are listed by IARC, NTP, OSHA, or ACGIH as a carcinogen.
Signs and Symptoms of Exposure
Inhalation
This product is an asphyxiate and may exhibit anesthetic properties at very high
concentrations. Initial symptoms of exposure at these concentrations are
disorentation, lack of coordination, rapid respiration, headache, and nausea.
Continued exposure May result in unconsciousness, coma, and possible death.
Skin Contact
Vapors are not irritating. Freeze burns or frostbite possible if skin is in
prolonged contact with vaporizing liquid.
Eye Contact
Same as skin contact.
Medical Conditions
Generally Aggravated by Exposure
Respiratory related chronic illnesses (i.e. asthma etc.)
Emergency and First Aid Procedures
Inhalation
Remove to fresh air. Artificial respiration, consult physician.
Skin Contact
Wash with soap and water. Remove soaked clothing to avoid prolonged skin
contact.
Eye Contact
Flush eyes well with running water for 15 minutes.
Ingestion
NA, product is gaseous at normal temperature and pressure.
16.3
Page 54 of 320
4
Section VII - Precautions for Safe Handling and Use
Steps to Be Taken in Case Material is Released or Spilled
Protect from any ignition source, keep away from heat, fire, sparks, or flame.
Ventilate area well. Avoid accumulation of vapor at low levels.
Waste Disposal Method
Dispose of in accordance with all local, state and federal regulations. Do not puncture or incinerate.
Precautions to Be taken in Handling and Storing
Do not store where temperature may exceed 120°F. Store away from, fire, sparks, or flame.
Store in suitable area for hazardous materials storage.
Other Precautions
D.O.T. Shipping
Classification
Butane, 2.1
Hazard Class
2.1
ID Number
UN1011
Label Required
Flammable Gas
TSCA Statement: All the components of this product are in compliance with the Toxic
Substances Control Act (TSCA) and are either listed on the TSCA Inventory or otherwise
exempted from listing.
16.4
Page 55 of 320
5
Section VIII - Control Measures
Respiratory Protection (Specify Type)
If TLV is exceeded wear NIOSH-approved self-contained breathing device or respirator.
Ventilation
Local Exhaust
Special
Mechanical (General)
Other
Must be adequate to maintaining
airborne concentrations below
established exposure limits,
particularly at floor level as vapors are
heavier than air.
Protective Gloves
Eye Protection
None needed for normal use. Thermal insulated gloves
when handling if prolonged exposure expected.
Safety glasses or goggles recommended
Other Protective Clothing or Equipment
Work/Hygienic Practices
Section IX - Special Precautions
Precautions to be taken in Handling and Storing
Do not use near heat, fire, flame or sparks. Avoid excessive breathing of vapor.
Do not spray in direction of body.
Use only
in accordance with directions.
Other Precautions
Each MSDS must be reviewed for correctness and completeness every three years.
Reviewed by ________________________ Reviewed by ________________________
Revision date ________________________ Revision date _______________________
16.5
Page 56 of 320
Material Safety Data Sheet
BG 109 - Compression Performance Restoration
(CPR)
1.
Product and company identification
Material uses
Manufacturer
: Other non-specified industry: Lubricant additives
: BG Products Inc.
701 S. Wichita Street
Wichita, KS, 67213, USA
www.bgprod.com
MSDS #
Validation date
Responsible name
: 109
: 12/30/2010.
: Kolin Anglin, Environmental Coordinator
316-265-2686
[email protected]
In case of emergency
: (800) 424-9300 (CHEMTREC)
2.
Hazards identification
Physical state
Odor
OSHA/HCS status
Emergency overview
: Liquid.
: oil
: This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
: WARNING!
FLAMMABLE LIQUID AND VAPOR. COMBUSTIBLE. MAY BE HARMFUL IF
SWALLOWED. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN
DAMAGE, BASED ON ANIMAL DATA.
Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Do not
eat, drink or smoke when using this product. Keep away from heat, sparks and flame.
Keep container tightly closed. Wash thoroughly after handling.
Potential acute health effects
Ingestion
:
Skin
:
Eyes
:
Potential chronic health effects
Chronic effects
:
Target organs
:
Harmful if swallowed.
May cause skin irritation.
May cause eye irritation.
Contains material that may cause target organ damage, based on animal data.
Contains material which may cause damage to the following organs: kidneys, liver,
mucous membranes, upper respiratory tract, skin, eyes, central nervous system (CNS).
Over-exposure signs/symptoms
No known significant effects or critical hazards.
Medical conditions
: Pre-existing disorders involving any target organs mentioned in this MSDS as being at
risk may be aggravated by over-exposure to this product.
aggravated by overexposure
See toxicological information (Section 11)
3.
Composition/information on ingredients
Name
CAS number
%
Distillates (petroleum), hydrotreated light paraffinic
Distillates (petroleum), hydrotreated heavy paraffinic
Cyclohexanone
4-methylpentan-2-ol
64742-55-8
64742-54-7
108-94-1
108-11-2
30 - 60
30 - 60
15 - 40
1-5
12/30/2010.
109
1/9
Page 57 of 320
BG 109 - Compression Performance Restoration (CPR)
3.
Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in
this section.
4.
First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
Protection of first-aiders
Notes to physician
5.
: Wash out mouth with water. Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical
attention immediately.
: No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
: No specific treatment. Treat symptomatically. Contact poison treatment specialist
immediately if large quantities have been ingested or inhaled.
Fire-fighting measures
Flammability of the product
Extinguishing media
Suitable
Not suitable
Special exposure hazards
Hazardous thermal
decomposition products
Special protective
equipment for fire-fighters
6.
: Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
attention immediately.
: In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. Clean
shoes thoroughly before reuse. Get medical attention immediately.
: Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.
: Flammable liquid. In a fire or if heated, a pressure increase will occur and the container
may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air
and will spread along the ground. Vapors may accumulate in low or confined areas or
travel a considerable distance to a source of ignition and flash back. Runoff to sewer
may create fire or explosion hazard.
: Use dry chemical, CO2, water spray (fog) or foam.
: Do not use water jet.
: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
: Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
: Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Accidental release measures
Personal precautions
: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment (see Section 8).
Environmental precautions
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods for cleaning up
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6.
Accidental release measures
Small spill
: Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Use spark-proof tools and explosionproof equipment. Dispose of via a licensed waste disposal contractor.
Large spill
: Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via
a licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see section 1 for emergency contact
information and section 13 for waste disposal.
7.
Handling and storage
Handling
: Put on appropriate personal protective equipment (see Section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and smoking.
Remove contaminated clothing and protective equipment before entering eating areas.
Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist.
Use only with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately
ventilated. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Store and use away from heat,
sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use non-sparking tools. Take
precautionary measures against electrostatic discharges. To avoid fire or explosion,
dissipate static electricity during transfer by grounding and bonding containers and
equipment before transferring material. Empty containers retain product residue and
can be hazardous. Do not reuse container.
Storage
: Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see section 10) and food and drink. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use
appropriate containment to avoid environmental contamination.
8.
Exposure controls/personal protection
Ingredient
Exposure limits
Distillates (petroleum), hydrotreated light
paraffinic
ACGIH TLV (United States, 2/2010).
TWA: 5 mg/m³ 8 hour(s). Form: Inhalable fraction. See Appendix C,
paragraph A. Inhalable Particulate Mass TLVs (IPM–TLVs) for those
materials that are hazardous when deposited anywhere in the
respiratory tract.
NIOSH REL (United States, 6/2009).
TWA: 5 mg/m³ 10 hour(s). Form: Mist
STEL: 10 mg/m³ 15 minute(s). Form: Mist
OSHA PEL (United States, 11/2006).
TWA: 5 mg/m³ 8 hour(s).
ACGIH TLV (United States, 2/2010).
TWA: 5 mg/m³ 8 hour(s). Form: Inhalable fraction. See Appendix C,
paragraph A. Inhalable Particulate Mass TLVs (IPM–TLVs) for those
materials that are hazardous when deposited anywhere in the
respiratory tract.
NIOSH REL (United States, 6/2009).
Distillates (petroleum), hydrotreated heavy
paraffinic
12/30/2010.
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8.
Exposure controls/personal protection
Cyclohexanone
4-methylpentan-2-ol
TWA: 5 mg/m³ 10 hour(s). Form: Mist
STEL: 10 mg/m³ 15 minute(s). Form: Mist
OSHA PEL (United States, 11/2006).
TWA: 5 mg/m³ 8 hour(s).
ACGIH TLV (United States, 2/2010). Absorbed through skin.
TWA: 20 ppm 8 hour(s).
STEL: 50 ppm 15 minute(s).
OSHA PEL 1989 (United States, 3/1989). Absorbed through skin.
TWA: 25 ppm 8 hour(s).
TWA: 100 mg/m³ 8 hour(s).
NIOSH REL (United States, 6/2009). Absorbed through skin.
TWA: 25 ppm 10 hour(s).
TWA: 100 mg/m³ 10 hour(s).
OSHA PEL (United States, 11/2006).
TWA: 50 ppm 8 hour(s).
TWA: 200 mg/m³ 8 hour(s).
ACGIH TLV (United States, 2/2010). Absorbed through skin.
TWA: 25 ppm 8 hour(s).
TWA: 104 mg/m³ 8 hour(s).
STEL: 40 ppm 15 minute(s).
STEL: 167 mg/m³ 15 minute(s).
OSHA PEL 1989 (United States, 3/1989). Absorbed through skin.
TWA: 25 ppm 8 hour(s).
TWA: 100 mg/m³ 8 hour(s).
STEL: 40 ppm 15 minute(s).
STEL: 165 mg/m³ 15 minute(s).
NIOSH REL (United States, 6/2009). Absorbed through skin.
TWA: 25 ppm 10 hour(s).
TWA: 100 mg/m³ 10 hour(s).
STEL: 40 ppm 15 minute(s).
STEL: 165 mg/m³ 15 minute(s).
OSHA PEL (United States, 11/2006). Absorbed through skin.
TWA: 25 ppm 8 hour(s).
TWA: 100 mg/m³ 8 hour(s).
Consult local authorities for acceptable exposure limits.
Recommended monitoring
: If this product contains ingredients with exposure limits, personal, workplace atmosphere
or biological monitoring may be required to determine the effectiveness of the ventilation
procedures
or other control measures and/or the necessity to use respiratory protective equipment.
Engineering measures
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas, vapor
or dust concentrations below any lower explosive limits. Use explosion-proof ventilation
equipment.
Hygiene measures
Personal protection
Respiratory
Hands
12/30/2010.
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety showers
are close to the workstation location.
: Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
: Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary.
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8.
Exposure controls/personal protection
Eyes
: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts.
Skin
: Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling
this product.
Environmental exposure
controls
: Emissions from ventilation or work process equipment should be checked to ensure they
comply with the requirements of environmental protection legislation. In some cases,
fume scrubbers, filters or engineering modifications to the process equipment will be
necessary to reduce emissions to acceptable levels.
9.
Physical and chemical properties
Physical state
Flash point
Auto-ignition temperature
Flammable limits
Color
Odor
pH
Boiling/condensation point
Melting/freezing point
Specific gravity
Vapor pressure
Vapor density
Odor threshold
Evaporation rate
Solubility
Pour point
Density
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Liquid.
Closed cup: 43°C (109.4°F)
Not available.
Not available.
Amber.
oil
Not available.
Not available.
Not available.
0.8767
Not available.
>1 [Air = 1]
Not available.
Not available.
Insoluble in the following materials: cold water and hot water.
-21°C (-5.8°F)
7.312 (lbs/gal)
10. Stability and reactivity
Chemical stability
Conditions to avoid
: The product is stable.
: Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Materials to avoid
: Reactive or incompatible with the following materials:
oxidizing materials
: Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
Hazardous decomposition
products
Possibility of hazardous
reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
11. Toxicological information
Acute toxicity
Product/ingredient name
12/30/2010.
Result
Species
109
Dose
Exposure
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BG 109 - Compression Performance Restoration (CPR)
11. Toxicological information
Distillates (petroleum),
hydrotreated light paraffinic
Cyclohexanone
4-methylpentan-2-ol
LC50 Inhalation Vapor
Rat
3900 mg/m3
4 hours
LC50 Inhalation Gas.
LD50 Oral
LD50 Oral
Rat
Rat
Rat
8000 ppm
1800 mg/kg
2590 mg/kg
4 hours
-
Carcinogenicity
Classification
Product/ingredient name
ACGIH
Distillates (petroleum),
A4
hydrotreated light paraffinic
Distillates (petroleum),
A4
hydrotreated heavy paraffinic
Cyclohexanone
A3
IARC
EPA
NIOSH
NTP
OSHA
-
-
-
-
-
-
-
-
-
-
3
-
-
-
-
12. Ecological information
Product/ingredient name
Result
Species
Exposure
Cyclohexanone
Acute LC50 527000 ug/L Fresh water
Fish - Pimephales promelas - 30
days - 20.2 mm - 0.127 g
96 hours
Partition coefficient: noctanol/water
: Not available.
13. Disposal considerations
Waste disposal
: The generation of waste should be avoided or minimized wherever possible. Significant
quantities of waste product residues should not be disposed of via the foul sewer but
processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Disposal of this product, solutions
and any by-products should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local authority requirements.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.
14. Transport information
Regulatory
information
UN number
Proper shipping
name
Classes
PG* Label
Additional
information
DOT Classification
UN1993
FLAMMABLE
LIQUIDS, N.O.S. (4methylpentan-2-ol)
3
III
-
IMDG Class
UN1993
FLAMMABLE
LIQUIDS, N.O.S. (4methylpentan-2-ol)
3
III
Emergency
schedules (EmS)
F-E, S-E
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14. Transport information
IATA-DGR Class
UN1993
FLAMMABLE
LIQUIDS, N.O.S. (4methylpentan-2-ol)
3
III
Passenger and
Cargo Aircraft
Quantity limitation:
60 L
Cargo Aircraft Only
Quantity limitation:
220 L
Limited Quantities Passenger Aircraft
Quantity limitation:
10 L
PG* : Packing group
15. Regulatory information
United States
HCS Classification
U.S. Federal regulations
Clean Air Act Section
112(b) Hazardous Air
Pollutants (HAPs)
: Combustible liquid
Target organ effects
: TSCA 8(a) IUR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): All components are listed or exempted.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: 4-methylpentan-2-ol; Cyclohexanone
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: 4methylpentan-2-ol: Fire hazard, Immediate (acute) health hazard; Cyclohexanone: Fire
hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard
: Listed
SARA 313
Product name
CAS number
Concentration
Form R - Reporting
requirements
2-(propyloxy)ethanol
2807-30-9
5 - 10
Supplier notification
2-(propyloxy)ethanol
2807-30-9
5 - 10
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall
include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
State regulations
Massachusetts
: The following components are listed: MINERAL OIL, PETROLEUM DISTILLATES,
HYDROTREATED LIGHT PARAFFINIC; CYCLOHEXANONE; METHYL ISOBUTYL
CARBINOL
New York
: The following components are listed: Cyclohexanone
New Jersey
: The following components are listed: GLYCOL ETHERS; CYCLOHEXANONE; METHYL
AMYL ALCOHOL; 2-PENTANOL, 4-METHYLPennsylvania
: The following components are listed: GLYCOL ETHERS; CYCLOHEXANONE; 2PENTANOL, 4-METHYLRhode Island
: None of the components are listed.
United States inventory
: All components are listed or exempted.
(TSCA 8b)
Canada
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15. Regulatory information
WHMIS (Canada)
: Class B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C
(200°F).
Class D-1B: Material causing immediate and serious toxic effects (Toxic).
Class D-2B: Material causing other toxic effects (Toxic).
Canadian lists
Canadian NPRI
: None of the components are listed.
CEPA Toxic substances
: None of the components are listed.
Canada inventory
: All components are listed or exempted.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
International regulations
International lists
: Australia inventory (AICS): All components are listed or exempted.
China inventory (IECSC): All components are listed or exempted.
Japan inventory: Not determined.
Korea inventory: All components are listed or exempted.
New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted.
Philippines inventory (PICCS): All components are listed or exempted.
16. Other information
Hazardous Material
Information System (U.S.A.)
:
Health
0
Flammability
0
Physical hazards
0
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR
1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented
HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS®
materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
National Fire Protection
:
Association (U.S.A.)
Flammability
2
Health
1
0
Instability/Reactivity
Special
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not
the complete and official position of the National Fire Protection Association, on the referenced subject which is
represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be
interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA
49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not,
anyone using the 704 systems to classify chemicals does so at their own risk.
Date of issue
Date of previous issue
Version
12/30/2010.
: 12/30/2010.
: No previous validation.
: 1
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16. Other information
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
12/30/2010.
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SAFETY DATA SHEET
BG 244
1.
Product and company identification
Manufacturer
: BG Products Inc.
701 S. Wichita Street
Wichita, KS, 67213, USA
www.bgprod.com
Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Fuel additives
MSDS #
: 244
Validation date
: 8/12/2014.
Responsible name
: Kolin Anglin, Environmental Coordinator
316-265-2686
[email protected]
: (800) 424-9300 (CHEMTREC)
In case of emergency
2.
Hazards identification
OSHA/HCS status
Classification of the
substance or mixture
: This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
: FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 4
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
ASPIRATION HAZARD - Category 1
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 85%
GHS label elements
Hazard pictograms
:
Signal word
: Danger
Hazard statements
: Flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Suspected of causing cancer.
May be fatal if swallowed and enters airways.
Precautionary statements
Prevention
Date of issue/Date of revision
: Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear
protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces,
sparks, open flames and other ignition sources. No smoking. Use explosion-proof
electrical, ventilating, lighting and all material-handling equipment. Use only nonsparking tools. Take precautionary measures against static discharge. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Avoid breathing vapor.
Wash hands thoroughly after handling.
: 8/12/2014.
Date of previous issue
: 9/6/2013.
Version
: 3.1
1/14
Page 66 of 320
BG 244
2.
Hazards identification
Response
Storage
Disposal
Hazards not otherwise
classified
3.
: IF exposed or concerned: Get medical attention. IF INHALED: Remove victim to fresh
air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or
physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or
physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water or shower. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical attention.
: Store locked up. Store in a well-ventilated place. Keep cool.
: Dispose of contents and container in accordance with all local, regional, national and
international regulations.
: None known.
Composition/information on ingredients
Substance/mixture
: Mixture
Other means of
: Not available.
identification
CAS number/other identifiers
CAS number
: Not applicable.
Product code
: 244
Ingredient name
%
CAS number
Naphtha (petroleum), hydrotreated heavy
Stoddard solvent
naphthalene
1,2,4-trimethylbenzene
ethylbenzene
15 - 40
10 - 30
1-5
0.5 - 1.5
0.1 - 1
64742-48-9
8052-41-3
91-20-3
95-63-6
100-41-4
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
4.
First aid measures
Description of necessary first aid measures
Eye contact
Inhalation
Skin contact
Date of issue/Date of revision
: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of
inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under medical surveillance for 48 hours.
: Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
: 8/12/2014.
Date of previous issue
: 9/6/2013.
Version
: 3.1
2/14
Page 67 of 320
BG 244
4.
First aid measures
Ingestion
: Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.
Most important symptoms/effects, acute and delayed
Potential acute health effects
Eye contact
: Causes serious eye irritation.
Inhalation
Skin contact
: Harmful if inhaled. Exposure to decomposition products may cause a health hazard.
Serious effects may be delayed following exposure.
: No known significant effects or critical hazards.
Ingestion
: May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach.
Over-exposure signs/symptoms
Eye contact
Inhalation
: Adverse symptoms may include the following:
pain or irritation
watering
redness
: No specific data.
Skin contact
: No specific data.
Ingestion
: Adverse symptoms may include the following:
nausea or vomiting
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician
Specific treatments
: In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
: No specific treatment.
Protection of first-aiders
: No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
See toxicological information (Section 11)
5.
Fire-fighting measures
Extinguishing media
Suitable extinguishing
media
Unsuitable extinguishing
media
Specific hazards arising
from the chemical
Hazardous thermal
decomposition products
Date of issue/Date of revision
: Use dry chemical, CO₂, water spray (fog) or foam.
: Do not use water jet.
: Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Runoff to sewer may
create fire or explosion hazard. Fire water contaminated with this material must be
contained and prevented from being discharged to any waterway, sewer or drain.
: Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
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: 9/6/2013.
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5.
Fire-fighting measures
Special protective actions
for fire-fighters
Special protective
equipment for fire-fighters
6.
: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
: Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency
personnel
: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities.
Methods and materials for containment and cleaning up
Small spill
Large spill
7.
: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Handling and storage
Precautions for safe handling
Protective measures
Date of issue/Date of revision
: Put on appropriate personal protective equipment (see Section 8). Avoid exposure obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not swallow.
Avoid breathing vapor or mist. Avoid release to the environment. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
: 8/12/2014.
Date of previous issue
: 9/6/2013.
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: 3.1
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7.
Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
8.
: Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
: Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.
Exposure controls/personal protection
Control parameters
Occupational exposure limits
Ingredient name
Exposure limits
Stoddard solvent
ACGIH TLV (United States, 6/2013).
TWA: 100 ppm 8 hours.
TWA: 525 mg/m³ 8 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 100 ppm 8 hours.
TWA: 525 mg/m³ 8 hours.
NIOSH REL (United States, 4/2013).
TWA: 350 mg/m³ 10 hours.
CEIL: 1800 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 500 ppm 8 hours.
TWA: 2900 mg/m³ 8 hours.
ACGIH TLV (United States, 6/2013).
Absorbed through skin.
TWA: 10 ppm 8 hours.
TWA: 52 mg/m³ 8 hours.
STEL: 15 ppm 15 minutes.
STEL: 79 mg/m³ 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 10 ppm 8 hours.
TWA: 50 mg/m³ 8 hours.
STEL: 15 ppm 15 minutes.
STEL: 75 mg/m³ 15 minutes.
NIOSH REL (United States, 4/2013).
TWA: 10 ppm 10 hours.
TWA: 50 mg/m³ 10 hours.
STEL: 15 ppm 15 minutes.
STEL: 75 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 10 ppm 8 hours.
TWA: 50 mg/m³ 8 hours.
ACGIH TLV (United States, 6/2013).
TWA: 25 ppm 8 hours.
TWA: 123 mg/m³ 8 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 25 ppm 8 hours.
TWA: 125 mg/m³ 8 hours.
NIOSH REL (United States, 4/2013).
Naphthalene
1,2,4-trimethylbenzene
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: 9/6/2013.
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8.
Exposure controls/personal protection
TWA: 25 ppm 10 hours.
TWA: 125 mg/m³ 10 hours.
ACGIH TLV (United States, 6/2013).
TWA: 20 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.
STEL: 125 ppm 15 minutes.
STEL: 545 mg/m³ 15 minutes.
NIOSH REL (United States, 4/2013).
TWA: 100 ppm 10 hours.
TWA: 435 mg/m³ 10 hours.
STEL: 125 ppm 15 minutes.
STEL: 545 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.
ethylbenzene
Appropriate engineering
controls
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation.
Environmental exposure
controls
Individual protection measures
Hygiene measures
Eye/face protection
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing.
: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts.
Skin protection
Hand protection
Body protection
Other skin protection
Respiratory protection
9.
: Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. In the case of mixtures, consisting of several substances, the protection
time of the gloves cannot be accurately estimated.
: Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
: Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
: Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary.
Physical and chemical properties
Physical state
: Liquid.
Flash point
: Closed cup: 50°C (122°F) [Pensky-Martens.]
Auto-ignition temperature
: Not available.
Flammable limits
: Not available.
Color
: Amber.
Odor
: Solvents
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: 9/6/2013.
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: 3.1
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9.
Physical and chemical properties
pH
: Not available.
Boiling/condensation point
: Not available.
Melting/freezing point
: Not available.
Specific gravity
: 0.883
Vapor pressure
: Not available.
Vapor density
: Not available.
Odor threshold
Evaporation rate
: Not available.
: Not available.
Viscosity
: Kinematic (40°C (104°F)): 0.0488 cm2/s (4.88 cSt)
Solubility
: Insoluble in the following materials: cold water and hot water.
Pour point
: <-40°C (<-40°F)
Density
: 7.37 (lbs/gal)
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
: No specific test data related to reactivity available for this product or its ingredients.
: The product is stable.
: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid
: Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
: Reactive or incompatible with the following materials:
oxidizing materials
: Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
Incompatible materials
Hazardous decomposition
products
Section 11. Toxicological information
Information on toxicological effects
Acute toxicity
Product/ingredient name
Result
Species
Naphtha (petroleum),
hydrotreated heavy
LC50 Inhalation Vapor
Rat
8500 mg/m³
4 hours
LD50 Oral
LD50 Dermal
LD50 Oral
LC50 Inhalation Vapor
LD50 Oral
LD50 Dermal
LD50 Oral
Rat
Rabbit
Rat
Rat
Rat
Rabbit
Rat
>6 g/kg
>20 g/kg
490 mg/kg
18000 mg/m³
5 g/kg
>5000 mg/kg
3500 mg/kg
4 hours
-
Naphthalene
1,2,4-trimethylbenzene
ethylbenzene
Dose
Exposure
Irritation/Corrosion
Product/ingredient name
Result
Species
Score
Exposure
Observation
Stoddard solvent
Eyes - Mild irritant
Human
-
-
Eyes - Moderate irritant
Rabbit
-
Skin - Mild irritant
Rabbit
-
Skin - Severe irritant
Rabbit
-
Eyes - Severe irritant
Rabbit
-
100 parts per
million
24 hours 500
milligrams
495
milligrams
24 hours 0.05
Mililiters
500
milligrams
Naphthalene
ethylbenzene
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: 8/12/2014.
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: 9/6/2013.
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: 3.1
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Section 11. Toxicological information
Skin - Mild irritant
Rabbit
-
24 hours 15
milligrams
-
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification
Product/ingredient name
OSHA
IARC
NTP
Naphthalene
ethylbenzene
-
2B
2B
Reasonably anticipated to be a human carcinogen.
-
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Name
Result
Naphtha (petroleum), hydrotreated heavy
ethylbenzene
ASPIRATION HAZARD - Category 1
ASPIRATION HAZARD - Category 1
Information on the likely
routes of exposure
: Not available.
Potential acute health effects
Eye contact
: Causes serious eye irritation.
Inhalation
Skin contact
: Harmful if inhaled. Exposure to decomposition products may cause a health hazard.
Serious effects may be delayed following exposure.
: No known significant effects or critical hazards.
Ingestion
: May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact
: Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation
: No specific data.
Skin contact
: No specific data.
Ingestion
: Adverse symptoms may include the following:
nausea or vomiting
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
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: 9/6/2013.
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: 3.1
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Section 11. Toxicological information
Potential immediate
effects
: Not available.
Potential delayed effects
: Not available.
Long term exposure
Potential immediate
effects
Potential delayed effects
: Not available.
: Not available.
Potential chronic health effects
Not available.
General
: No known significant effects or critical hazards.
Carcinogenicity
Mutagenicity
: Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
: No known significant effects or critical hazards.
Teratogenicity
: No known significant effects or critical hazards.
Developmental effects
: No known significant effects or critical hazards.
Fertility effects
: No known significant effects or critical hazards.
Numerical measures of toxicity
Acute toxicity estimates
Route
ATE value
Oral
Inhalation (vapors)
4100.8 mg/kg
10.47 mg/l
12. Ecological information
Toxicity
Product/ingredient name
Result
Species
Exposure
Naphthalene
Acute EC50 1600 µg/l Fresh water
Daphnia - Daphnia magna Neonate
Crustaceans - Palaemonetes
pugio
Fish - Melanotaenia fluviatilis Larvae
Fish - Oncorhynchus kisutch
Crustaceans - Elasmopus
pectenicrus - Adult
Fish - Pimephales promelas
Algae - Pseudokirchneriella
subcapitata
Algae - Pseudokirchneriella
subcapitata
Daphnia - Daphnia magna Neonate
Crustaceans - Americamysis
bahia
Fish - Oncorhynchus mykiss
Algae - Pseudokirchneriella
subcapitata
48 hours
Acute LC50 2350 µg/l Marine water
Acute LC50 213 µg/l Fresh water
1,2,4-trimethylbenzene
Chronic NOEC 0.67 ppm Fresh water
Acute LC50 4910 µg/l Marine water
ethylbenzene
Acute LC50 7720 µg/l Fresh water
Acute EC50 4600 µg/l Fresh water
Acute EC50 3600 µg/l Fresh water
Acute EC50 2930 µg/l Fresh water
Acute LC50 5200 µg/l Marine water
Acute LC50 4200 µg/l Fresh water
Chronic NOEC 1000 µg/l Fresh water
48 hours
96 hours
40 days
48 hours
96 hours
72 hours
96 hours
48 hours
48 hours
96 hours
96 hours
Persistence and degradability
Not available.
Bioaccumulative potential
Date of issue/Date of revision
: 8/12/2014.
Date of previous issue
: 9/6/2013.
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: 3.1
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12. Ecological information
Product/ingredient name
LogPow
BCF
Potential
Naphtha (petroleum),
hydrotreated heavy
Stoddard solvent
Naphthalene
1,2,4-trimethylbenzene
ethylbenzene
-
10 to 2500
high
3.16 to 7.06
3.4
3.63
3.6
36.5 to 168
243
-
high
low
low
low
Mobility in soil
Soil/water partition
coefficient (KOC)
: Not available.
Other adverse effects
: No known significant effects or critical hazards.
13. Disposal considerations
Disposal methods
: The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.
14. Transport information
DOT Classification
IMDG
IATA
UN number
UN1993
UN1993
UN1993
UN proper
shipping name
FLAMMABLE LIQUIDS, N.O.
S. (Stoddard solvent,
2-ethylhexyl nitrate). Marine
pollutant (2-ethylhexyl nitrate,
Stoddard solvent)
FLAMMABLE LIQUIDS, N.O.S.
(Stoddard solvent, 2-ethylhexyl
nitrate). Marine pollutant
(2-ethylhexyl nitrate, Stoddard
solvent)
FLAMMABLE LIQUIDS, N.O.S.
(Stoddard solvent, 2-ethylhexyl
nitrate)
Transport
3
hazard class(es)
3
3
Packing group
III
III
III
Environmental
hazards
No.
Yes.
No.
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: 8/12/2014.
Date of previous issue
: 9/6/2013.
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: 3.1
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14. Transport information
Additional
information
This product may be reclassified as "Combustible
Liquid," unless transported
by vessel or aircraft. Nonbulk packages (less than or
equal to 119 gal) of
combustible liquids, that are
marine pollutants, are not
regulated as hazardous
materials in package sizes
less than the product
reportable quantity, unless
transported by vessel.
The marine pollutant mark is not
required when transported in
sizes of ≤5 L or ≤5 kg.
Emergency schedules (EmS)
F-E, S-E
The environmentally
hazardous substance mark
may appear if required by
other transportation
regulations.
Passenger and Cargo
AircraftQuantity limitation: 60 L
Cargo Aircraft OnlyQuantity
limitation: 220 L
Limited Quantities Passenger AircraftQuantity
limitation: 10 L
Remarks
Marine Pollutant:
The marine pollutant mark is
not required when
transported on inland
waterways in sizes of ≤5 L or
≤5 kg or by road, rail, or
inland air in non-bulk sizes.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
Transport in bulk according
to Annex II of MARPOL
73/78 and the IBC Code
: Not available.
15. Regulatory information
U.S. Federal regulations
: TSCA 8(a) PAIR: naphthalene
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): Not determined.
Clean Water Act (CWA) 307: naphthalene; ethylbenzene; toluene; benzene
Clean Water Act (CWA) 311: naphthalene; ethylbenzene; xylene; toluene; benzene
Clean Air Act Section 112 : Listed
(b) Hazardous Air
Pollutants (HAPs)
SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ
: Not applicable.
SARA 311/312
Classification
: Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
Composition/information on ingredients
Date of issue/Date of revision
: 8/12/2014.
Date of previous issue
: 9/6/2013.
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: 3.1
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15. Regulatory information
Name
Fire hazard
Sudden
release of
pressure
Reactive
Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Stoddard solvent
naphthalene
Distillates (petroleum), hydrotreated light
1,2,4-trimethylbenzene
ethylbenzene
cumene
Yes.
No.
Yes.
Yes.
Yes.
Yes.
No.
No.
No.
No.
No.
No.
No.
No.
No.
No.
No.
No.
Yes.
Yes.
No.
No.
Yes.
Yes.
Yes.
Yes.
Yes.
Yes.
Yes.
Yes.
SARA 313
Product name
CAS number
Form R - Reporting
requirements
naphthalene
1,2,4-trimethylbenzene
ethylbenzene
91-20-3
95-63-6
100-41-4
Supplier notification
naphthalene
1,2,4-trimethylbenzene
ethylbenzene
91-20-3
95-63-6
100-41-4
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall
include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
State regulations
Massachusetts
New York
New Jersey
Pennsylvania
: The following components are listed: NAPHTHALENE; PSEUDOCUMENE;
STODDARD SOLVENT
: The following components are listed: Naphthalene; Ethylbenzene; Cumene; Benzene,
1-methylethyl: The following components are listed: NAPHTHALENE; MOTH FLAKES; ETHYL
BENZENE; BENZENE, ETHYL-; PSEUDOCUMENE; 1,2,4-TRIMETHYL BENZENE;
STODDARD SOLVENT; CUMENE; BENZENE, (1-METHYLETHYL): The following components are listed: NAPHTHALENE; BENZENE, ETHYL-;
PSEUDOCUMENE; STODDARD SOLVENT; BENZENE, (1-METHYLETHYL)-
California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer.
WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or
other reproductive harm.
Ingredient name
Cancer
Reproductive
No significant risk
level
Maximum
acceptable dosage
level
naphthalene
ethylbenzene
Yes.
Yes.
No.
No.
No.
No.
cumene
toluene
Yes.
No.
No.
Yes.
Yes.
41 µg/day (ingestion)
54 µg/day
(inhalation)
No.
No.
benzene
Yes.
Yes.
United States inventory
(TSCA 8b)
Canada
Date of issue/Date of revision
6.4 µg/day
(ingestion)
13 µg/day
(inhalation)
No.
7000 µg/day
(ingestion)
24 µg/day (ingestion)
49 µg/day
(inhalation)
: Not determined.
: 8/12/2014.
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: 9/6/2013.
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: 3.1
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15. Regulatory information
WHMIS (Canada)
: Class B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C
(200°F).
Class D-2A: Material causing other toxic effects (Very toxic).
Class D-2B: Material causing other toxic effects (Toxic).
Canadian lists
Canadian NPRI
: The following components are listed: Heavy aromatic solvent naphtha; Naphthalene;
Hydrotreated heavy naphtha; 1,2,4-Trimethylbenzene; Stoddard solvent; Hydrotreated
light distillate
: The following components are listed: Naphthalene
CEPA Toxic substances
Canada inventory
: Not determined.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
International regulations
International lists
: Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory: Not determined.
Korea inventory: Not determined.
Malaysia Inventory (EHS Register): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan inventory (CSNN): Not determined.
16. Other information
Hazardous Material Information System (U.S.A.)
Health
2
Flammability
2
Physical hazards
0
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
National Fire Protection Association (U.S.A.)
Flammability
2
Health
2
0
Instability/Reactivity
Special
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not
the complete and official position of the National Fire Protection Association, on the referenced subject which is
represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be
interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA
49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not,
anyone using the 704 systems to classify chemicals does so at their own risk.
History
Date of issue/Date of revision
: 8/12/2014.
Date of previous issue
: 9/6/2013.
Version
: 3.1
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16. Other information
Date of printing
: 8/12/2014.
Date of issue/Date of
revision
Date of previous issue
: 8/12/2014.
Version
: 3.1
Key to abbreviations
References
: 9/6/2013.
: ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
: Not available.
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Date of issue/Date of revision
: 8/12/2014.
Date of previous issue
: 9/6/2013.
Version
: 3.1
14/14
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according to Regulation (EC) No. 1907/2006 as amended by (EC) No. 1272/2008
Section 1. Identification of the Substance/Mixture and of the Company/Undertaking
1.1
Product Code:
Product Name:
1.2
Relevant identified uses of the substance or mixture and uses advised against:
1.3
Details of the Supplier of the Safety Data Sheet:
CYCLO INDUSTRIES, INC.
Company Name:
902 SOUTH US HIGHWAY 1
JUPITER, FL 33477
1.4
C116C
Brake & Parts Clean, Non-Chlorinated, 55 Gallon Drum
Web site address:
www.cyclo.com
Information:
First Aid Emergency (Outside U.S.)
Emergency telephone number:
First Aid Emergency
Emergency Contact:
CHEMTREC (703) 527-3887
Phone Number:
(800)843-7813
(312)906-6194
(800)752-7869
(800)424-9300
Section 2. Hazards Identification
2.1
Classification of the Substance or Mixture:
2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP]:
Flammable Liquids, Category 2
Skin Corrosion/Irritation, Category 2
Serious Eye Damage/Eye Irritation, Category 2A
Toxic To Reproduction, Category 2
Target Organ Systemic Toxicity (single exposure), Category 3
Target Organ Systemic Toxicity (repeated exposure), Category 2
Aspiration Toxicity, Category 1
Aquatic Toxicity (Acute), Category 2
Aquatic Toxicity (Chronic), Category 2
2.2
Label Elements:
2.2.1 Labeling according to Regulation (EC) No 1272/2008 [CLP]:
Danger
Warning
Danger
GHS Hazard Phrases:
H225: Highly flammable liquid and vapor.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H361: Suspected of damaging fertility or the unborn child.
H335: May cause respiratory irritation.
H373: May cause damage to {organs through prolonged or repeated exposure.
H304: May be fatal if swallowd and enters airways.
H411: Toxic to aquatic life with long lasting effects.
EUH066: Repeated exposure may cause skin dryness or cracking.
GHS Precaution Phrases:
P233: Keep container tightly closed.
P210: Keep away from heat/sparks/open flames/hot surfaces.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/lighting equipment.
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P243: Take precautionary measures against static discharge.
P242: Use only non-sparking tools.
P264: Wash hands thoroughly after handling.
P362+364: Take off contaminated clothing and wash it before reuse.
P271: Use only outdoors or in a well-ventilated area.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P273: Avoid release to the environment.
GHS Response Phrases:
P370+378: In case of fire, use carbon dioxide, dry chemicals or foam to extinguish.
P303+361+353: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with
water/shower.
P302+352: IF ON SKIN: Wash with plenty of soap and water.
P332+313: If skin irritation occurs, get medical advice/attention.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P337+313: If eye irritation persists, get medical advice/attention.
P309+311: Call a POISON CENTER or doctor/physician if exposed or you feel unwell.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P331: Do NOT induce vomiting.
GHS Storage and Disposal Phrases:
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.
P403+233: Store container tightly closed in well-ventilated place.
Hazard Rating System:
Flammability
Instability
4
Health
2
0
Special Hazard
2.3
Adverse Human Health
Effects and Symptoms:
Section 3. Composition/Information on Ingredients
Hazardous Components (Chemical Name)/
REACH Registration No.
Concentration
67-64-1
Acetone
108-88-3
142-82-5
CAS #
EC No./
EC Index No.
GHS Classification
40.0 -50.0 %
200-662-2
606-001-00-8
Flam. Liq. 2: H225
Eye Damage 2A: H319
TOST (SE) 3: H335 H336
Toluene
20.0 -30.0 %
203-625-9
601-021-00-3
Flam. Liq. 2: H225
Toxic Repro. 2: H361
Asp. Toxic. 1: H304
TOST (RE) 2: H373
Skin Corr. 2: H315
TOST (SE) 3: H335 H336
Heptane
10.0 -20.0 %
205-563-8
601-008-00-2
Flam. Liq. 2: H225
Asp. Toxic. 1: H304
Skin Corr. 2: H315
TOST (SE) 3: H335 H336
Aquatic (A) 1: H400
Aquatic (C) 1: H410
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Section 4. First Aid Measures
Description of First Aid If ingested, seek medical attention immediately. Aspiration hazard: Do not induce
vomiting or give anything by mouth because this material can enter the lungs and cause
Measures:
severe lung damage. Do not leave individual unattended. If inhaled, remove to fresh air.
If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Wash skin
with soap and water. Remove contaminated clothing and shoes, and launder before
reuse. Immediately flush eyes with large amounts of water for at least 15 minutes while
holding eyelids open. Call physician immediately if adverse reaction occurs.
4.1
Section 5. Fire Fighting Measures
5.1
Suitable Extinguishing Carbon dioxide, dry chemicals, foam.
Media:
5.2
Flammable Properties No data available.
and Hazards:
5.3
Flash Pt:
-4.00 F (-20.0 C)
Method Used: TAG Closed Cup
Explosive Limits:
LEL: No data.
Autoignition Pt:
No data.
Fire Fighting
Instructions:
SCBA should be used whenever chemical fires are present. Contents under pressure.
Cool exposed containers with water spray to prevent bursting.
UEL: No data.
Section 6. Accidental Release Measures
6.3
Methods and Material
For Containment and
Cleaning Up:
Wear appropriate protective clothing and equipment to prevent skin and eye contact.
Contain any liquid from leaking containers. Remove sources of ignition. Increase area
ventilation. Sweep or gather up material and place in proper container for disposal or
recovery. Do not allow to enter sanitary drains, sewer or surface and subsurface waters.
Section 7. Handling and Storage
7.1
Precautions To Be
Taken in Handling:
Danger: Extremely flammable. Keep away from heat and open flame. Use only in a
well-ventilated area. Keep out of the reach of children.
Section 8. Exposure Controls/Personal Protection
8.1
Exposure Parameters:
CAS #
Partial Chemical Name
Britain EH40
67-64-1
Acetone
TWA: 1210 mg/m3 (500 ppm) TWA: 1210 mg/m3 (500
STEL: 3620 mg/m3 (1500 ppm) ppm)
STEL: 2420 mg/m3 (1000
ppm)
108-88-3
Toluene
TWA: 191 mg/m3 (50 ppm)
STEL: 384 mg/m3 (100 ppm)
TWA: 192 mg/m3 (50 ppm)
TWA: 192 mg/m3
STEL: 384 mg/m3 (100 ppm) STEL: 384 mg/m3
142-82-5
Heptane
TWA: 2085 mg/m3 (500 ppm)
STEL: ()
TWA: 1668 mg/m3 (400
ppm)
STEL: 2085 mg/m3 (500
ppm)
TWA: 2085. mg/m3
Partial Chemical Name
OSHA TWA
ACGIH TWA
Other Limits
67-64-1
Acetone
PEL: 1000 ppm
TLV: 500 ppm
STEL: 750 ppm
No data.
108-88-3
Toluene
PEL: 200 ppm
STEL: 500 ppm/(10min)
CEIL: 300 ppm
TLV: 50 ppm
No data.
142-82-5
Heptane
PEL: 500 ppm
TLV: 400 ppm
No data.
CAS #
MIRS MSDS, (c) A V Systems, Inc.
France VL
Europe
TWA: 1210 mg/m3
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Exposure Controls:
8.2.1 Engineering Controls
(Ventilation etc.):
8.2.2
Page: 4
Exhaust ventilation. Showers. Eyewash stations.
Personal protection equipment:
Wear safety glasses or goggles to protect against exposure.
Eye Protection:
Protective Gloves:
Use chemical resistant gloves for prolonged skin contact.
Other Protective
Clothing:
Rubber apron.
Respiratory Equipment Use and approved NIOSH organic vapor respirator below the TLV. IF TLV is exceeded or
overexposure is likely, use positive pressure self contained breathing apparatus.
(Specify Type):
Section 9. Physical and Chemical Properties
9.1
Information on Basic Physical and Chemical Properties
Physical States:
[ ] Gas
Appearance and Odor:
Clear liquid Typical solvent odor.
pH:
NP
Melting Point:
No data.
Boiling Point:
No data.
Flash Pt:
-4.00 F (-20.0 C)
Evaporation Rate:
No data.
Explosive Limits:
LEL: No data.
Vapor Pressure (vs. Air or
mm Hg):
No data.
Vapor Density (vs. Air = 1):
No data.
Specific Gravity (Water = 1):
No data.
Solubility in Water:
Autoignition Pt:
9.2
[ X ] Liquid
[ ] Solid
Method Used: TAG Closed Cup
UEL: No data.
Negligible
No data.
Other Information
Percent Volatile:
45.0 % by weight.
Section 10. Stability and Reactivity
10.1
Reactivity:
No data available.
10.2
Stability:
Unstable [
10.3
Conditions To Avoid - No data available.
Hazardous Reactions:
Will occur [
Possibility of
Hazardous Reactions:
]
Stable [ X ]
]
Will not occur [ X ]
10.4
Conditions To Avoid - Keep away from heat, sparks and flame. Temperature over 120 degrees F.
Instability:
10.5
Incompatibility Materials To Avoid:
Strong acids. Strong oxidizing agents.
10.6
Hazardous
Decomposition Or
Byproducts:
Carbon monoxide. Carbon dioxide.
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Section 11. Toxicological Information
11.1
No data available.
Information on
Toxicological Effects:
CAS# 142-82-5:
Other Studies:, TDLo, Oral, Rat, 60.00 GM/KG, 3 W.
Results:
Kidney, Ureter, Bladder: Changes in liver weight.
- National Technical Information Service, Vol/p/yr: OTS0571116,
Other Studies:, TDLo, Oral, Rat, 260.0 GM/KG, 13 W.
Results:
Kidney, Ureter, Bladder: Changes in bladder weight.
Endocrine:Hypoglycemia.
Nutritional and Gross Metabolic:Weight loss or decreased weight gain.
- National Technical Information Service, Vol/p/yr: OTS0571116,
Other Studies:, TCLo, Inhalation, Rat, 4000. PPM, 6 D.
Results:
Brain and Coverings: Recordings from specific areas of CNS.
Sense Organs and Special Senses (Nose, Eye, Ear, and Taste): Ear: Changes in
cochlear structure or function.
Nutritional and Gross Metabolic:Weight loss or decreased weight gain.
- Pharmacology and Toxicology, Munksgaard International Pub., POB 2148, Copenhagen
K Denmark, Vol/p/yr: 76,41, 1995
Other Studies:, TDLo, Intraperitoneal, Rat, 9625. MG/KG, 7 D.
Results:
Liver: Other changes.
Blood:Changes in serum composition (e.g.
Biochemical:Enzyme inhibition, induction, or change in blood or tissue levels: Multiple
enzyme effects.
- Toxicology Letters., Elsevier Science Pub. B.V., POB 211, 1000 AE, Amsterdam 1000
AE Netherlands, Vol/p/yr: 14,169, 1982
Other Studies:, TDLo, Intraperitoneal, Rat, 8840. MG/KG, 45 D.
Results:
Liver: Other changes.
Biochemical:Enzyme inhibition, induction, or change in blood or tissue levels:
Phosphatases.
Biochemical:Enzyme inhibition, induction, or change in blood or tissue levels: Hepatic
microsomal mixed oxidase (dealkylation, hydroxylation, etc.)
- JAT, Journal of Applied Toxicology., John Wiley & Sons Ltd., Baffins Lane, Chichester,
W.Sussex PO19 1UD UK, Vol/p/yr: 8,81, 1988
Acute toxicity, TCLo, Inhalation, Human, 1000. PPM, 6 M.
Results:
Behavioral: Hallucinations, distorted perceptions.
- "U.S. Bureau of Mines Report of Investigation No. 2979," Patty, F.A., and W.P. Yant,
1929 Volume, Vol/p/yr: 2979,-, 1929
Acute toxicity, LC50, Inhalation, Rat, 103.0 GM/M3, 4 H.
Results:
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Behavioral: Change in motor activity (specific assay).
Behavioral: Alteration of classical conditioning.
- Gigiena Truda i Professional'nye Zabolevaniya.(Labor Hygiene and Occupational
Disease), V/O Mezhdunarodnaya Kniga, Moscow 113095 Russia, Vol/p/yr: 32(10),23,
1988
Acute toxicity, LCLO, Inhalation, Mouse, 59.00 GM/M3, 41 M.
Results:
Behavioral: Convulsions or effect on seizure threshold.
- Biochemische Zeitschrift., For publisher information, see EJBCAI, Berlin Germany,
Vol/p/yr: 115,235, 1921
Acute toxicity, LD50, Intravenous, Mouse, 222.0 MG/KG.
Results:
Brain and Coverings: Changes in circulation (hemorrhage,thrombosis, etc.
Lungs, Thorax, or Respiration:Dyspnea.
Gastrointestinal:Nausea or vomiting.
- Journal of Pharmaceutical Sciences., American Pharmaceutical Assoc., 2215
Constitution Ave., NW, Washington, DC 20037, Vol/p/yr: 67,566, 1978
CAS #
Hazardous Components (Chemical Name)
NTP
IARC
ACGIH
OSHA
67-64-1
Acetone
n.a.
n.a.
A4
n.a.
108-88-3
Toluene
n.a.
3
A4
n.a.
142-82-5
Heptane
n.a.
n.a.
n.a.
n.a.
Section 12. Ecological Information
Section 13. Disposal Considerations
13.1
Waste Disposal
Method:
Disposal should be made in accordance with federal, state and local regulations.
Section 14. Transport Information
14.1
LAND TRANSPORT (US DOT):
DOT Proper Shipping Name: Flammable Liquid, n.o.s (Acetone, Toluene, Heptane)
3
FLAMMABLE LIQUID
DOT Hazard Class:
UN1993
UN/NA Number:
Packing Group:
14.1
II
LAND TRANSPORT (European ADR/RID):
ADR/RID Shipping Name:
UN Number:
Hazard Class:
MIRS MSDS, (c) A V Systems, Inc.
1993
3 - FLAMMABLE LIQUID
Packing Group:
II
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MARINE TRANSPORT (IMDG/IMO):
IMDG/IMO Shipping Name:
UN Number:
Hazard Class:
Flammable Liquid, n.o.s (Acetone, Toluene, Heptane)
1993
Packing Group:
3 - FLAMMABLE LIQUID
IMDG Classification:
Marine Pollutant:
II
3
No
Section 15. Regulatory Information
EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists
CAS #
Hazardous Components (Chemical Name)
S. 302 (EHS)
S. 304 RQ
S. 313 (TRI)
67-64-1
Acetone
No
Yes 5000 LB
No
108-88-3
Toluene
No
Yes 1000 LB
Yes
142-82-5
Heptane
No
No
No
Hazardous Components (Chemical Name)
Other US EPA or State Lists
67-64-1
Acetone
CAA HAP,ODC: No; CWA NPDES: No; TSCA: Inventory, 4
Test; CA PROP.65: No; CA TAC, Title 8: Title 8; MA
Oil/HazMat: Yes; MI CMR, Part 5: Part 5; NC TAP: No; NJ
EHS: Yes - 0006; NY Part 597: Yes; PA HSL: Yes - E; SC
TAP: No; WI Air: Yes
108-88-3
Toluene
CAA HAP,ODC: HAP; CWA NPDES: Yes; TSCA: Inventory,
8A CAIR; CA PROP.65: Yes; CA TAC, Title 8: TAC, Title 8;
MA Oil/HazMat: Yes; MI CMR, Part 5: CMR, Part 5; NC TAP:
Yes; NJ EHS: Yes - 1866; NY Part 597: Yes; PA HSL: Yes E; SC TAP: Yes; WI Air: Yes
142-82-5
Heptane
CAA HAP,ODC: No; CWA NPDES: No; TSCA: Inventory, 4
Test, 8A PAIR; CA PROP.65: No; CA TAC, Title 8: Title 8; MA
Oil/HazMat: Yes; MI CMR, Part 5: No; NC TAP: No; NJ EHS:
Yes - 1339; NY Part 597: No; PA HSL: Yes - 1; SC TAP: No;
WI Air: No
CAS #
CAS #
Hazardous Components (Chemical Name)
International Regulatory Lists
67-64-1
Acetone
Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA:
Yes
108-88-3
Toluene
Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA:
Yes
142-82-5
Heptane
Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA:
Yes
Section 16. Other Information
Revision Date:
06/18/2013
Additional Information About Not for sale in CA.
This Product:
Company Policy or
Disclaimer:
MIRS MSDS, (c) A V Systems, Inc.
Cyclo Industries, Inc. provides the information contained herein in good faith but makes
no representation as to its comprehensiveness or accuracy. Individuals receiving this
information must exercise their independent judgment in determining its appropriateness
for a particular purpose. Cyclo Industries, Inc. makes no representations or warranties,
either expressed or implied, of merchantability, fitness for a particular purpose with
respect to the information set forth herein or to the product to which the information
refers. Accordingly, Cyclo Industries, Inc. will not be responsible for damages resulting
from use of or reliance upon this information.
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11304 - CAT ANTI-SEIZE COMPOUND GRAPHITE BASE
MATERIAL SAFETY DATA SHEET
CAT ANTI-SEIZE COMPOUND GRAPHITE BASE
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
TRADE NAME
CAT ANTI-SEIZE COMPOUND GRAPHITE BASE
PART No.
Chemtool, WXK2811000, Caterpillar, 4C-5591, 4C-5592, 4C-5593
PRODUCT USE
Antiseize Compound
SUPPLIER
Chemtool Incorporated
P.O. Box 538
8200 Ridgefield Road
Crystal Lake, IL 60039-0538 USA
Tel: (815) 459-1250
Fax: (815) 459-1955
EMERGENCY TELEPHONE
Rocky Mountain Poison Center
Denver, Colorado
In USA and Canada - (800) 458-5924
Outside USA and Canada - +01-303-893-1322
2. COMPOSITION, INFORMATION ON INGREDIENTS
INGREDIENT NAME
*GRAPHITE
DISTILLATES, PETROLEUM, HYDROTREATED HEAVY NAPHTHENIC
PETROLATUM
PETROLEUM OILS, 150 BRIGHT STOCK (CAS NOS 64742-62-7 & 64742-65-0)
*SILICA, CRYSTALLINE (COMMON NAME: QUARTZ)
CAS No.
7782-42-5
64742-52-5
8009-03-8
Mixture
14808-60-7
WEIGHT
40-60 %
10-30 %
10-30 %
7-13 %
<2 %
* This chemical(s) is hazardous according to OSHA/WHIMIS criteria
COMPOSITION COMMENTS
Refer to section eight for exposure limits on ingredients.
Chemical ingredients not regulated by OSHA or SARA are treated confidentially.
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HEALTH HAZARDS, GENERAL
Exposure to vapors generated at high temperatures may cause respiratory irritation.
SENSITIZATION
No known information.
1 /7
Page 87 of 320
11304 - CAT ANTI-SEIZE COMPOUND GRAPHITE BASE
CARCINOGENICITY
OSHA: Not regulated. See Section 11 for carcinogenicity data of ingredients.
TERATOGENICITY
No known information.
HEALTH WARNINGS
SKIN CONTACT. Slightly irritating. Repeated or prolonged contact can result in drying
of the skin. EYE CONTACT. Irritating. INHALATION. Heating can generate vapors that
may cause respiratory irritation, nausea and headaches. Inhalation hazard at room
temperature is unlikely due to the low volatility of this product. INGESTION. Can cause
stomach ache and vomiting.
ROUTE OF ENTRY
Inhalation. Skin and/or eye contact. Ingestion.
4. FIRST AID MEASURES
INHALATION
Vapor inhalation under ambient conditions is normally not a problem. If overcome by
vapor of hot product, immediately remove from source of exposure. Get medical
attention if any discomfort continues. For breathing difficulties oxygen may be
necessary.
EYES
Important! Immediately rinse with water for at least 15 minutes. Contact physician if
irritation persists.
SKIN
Remove contaminated clothing. Wash skin thoroughly with soap and water. Contact
physician if irritation persists.
INGESTION
DO NOT INDUCE VOMITING! Remove victim immediately from source of exposure.
Get medical attention immediately! Never give anything by mouth to an unconscious
person.
5. FIRE FIGHTING MEASURES
FLASH POINT (°C)
> 204 (400°F) Cd OC (Cleveland open cup).
FLAMMABILITY LIMIT - LOWER(%)
N/D
FLAMMABILITY LIMIT - UPPER(%)
N/D
EXTINGUISHING MEDIA
Dry chemicals, sand, dolomite etc. Foam. Carbon dioxide (CO2).
SPECIAL FIRE FIGHTING
PROCEDURES
Use water spray to keep fire exposed containers cool and disperse vapors. Water
spray may be used to flush spills away from exposures.
UNUSUAL FIRE & EXPLOSION
HAZARDS
Pressure will increase in over heated, closed containers.
HAZARDOUS COMBUSTION
PRODUCTS
Acrid smoke/fumes. Oxides of: Carbon.
PROTECTIVE MEASURES IN CASE OF
FIRE
Self-contained breathing equipment and chemical resistant clothing recommended.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Minimize skin contact.
2 /7
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11304 - CAT ANTI-SEIZE COMPOUND GRAPHITE BASE
PRECAUTIONS TO PROTECT THE
ENVIRONMENT
Keep product out of sewers and watercourses by diking or impounding. Advise
authorities if product has entered or may enter sewers, watercourses or extensive
land areas. Assure conformity with applicable government regulations.
SPILL CLEAN-UP PROCEDURES
Contain spill. Neutralize and absorb small amounts. Collect and return large amounts
to shipping container. Rinse spill area with water.
7. HANDLING AND STORAGE
HANDLING PRECAUTIONS
Do not reuse container. Keep lid closed when not in use. Keep away from heat,
sparks and open flame. Do not use in confined spaces without adequate ventilation
and/or respirator.
STORAGE PRECAUTIONS
Keep container closed when not in use. Keep away from heat, sparks and open
flame. Store separate from strong acids and oxidizers.
STORAGE CRITERIA
Chemical storage.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
COMPONENT
GRAPHITE
STD
OSHA
TWA
STEL
DISTILLATES, PETROLEUM, HYDROTREATED
HEAVY NAPHTHENIC
2 mg/m3 (resp)
5 mg/m3 (oil mist)
5 mg/m3 (oil mist)
PETROLEUM OILS, 150 BRIGHT STOCK (CAS NOS OSHA
64742-62-7 & 64742-65-0)
ACGIH
5 mg/m3 (oil mist)
OSHA
5 mg/m3 (oil mist)
0.3 mg/m3 (total)
INGREDIENT COMMENTS
10 mg/m3 (oil mist)
10 mg/m3 (oil mist)
0.1 mg/m3 (resp)
ACGIH
NIOSH
except graphite fibers
2.5 mg/m3 (resp)
ACGIH
SILICA, CRYSTALLINE (COMMON NAME:
QUARTZ)
STEL
15 mppcf
ACGIH
NIOSH
OSHA
TWA
0.05 mg/m3 (resp) **A2
**Ca
0.05 mg/m3
**ACGIH A2: Suspected Human Carcinogen.
**NIOSH Ca: Potential Occupational Carcinogen.
PROTECTIVE EQUIPMENT
ENGINEERING CONTROLS
Use engineering controls to reduce air contamination to permissible exposure level.
VENTILATION
No specific ventilation requirements noted, but forced ventilation may still be required
if air contamination exceeds acceptable level.
3 /7
Page 89 of 320
11304 - CAT ANTI-SEIZE COMPOUND GRAPHITE BASE
RESPIRATORS
No specific recommendation made, but respiratory protection may still be required
under exceptional circumstances when excessive air contamination exists.
PROTECTIVE GLOVES
Chemical resistant gloves required for prolonged or repeated contact.
EYE PROTECTION
Wear splash-proof eye goggles to prevent any possibility of eye contact.
PROTECTIVE CLOTHING
Wear appropriate clothing to prevent repeated or prolonged skin contact.
HYGIENIC WORK PRACTICES
Wash at the end of each work shift and before eating, smoking and using the toilet.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE/PHYSICAL STATE
Liquid.
COLOR
Black.
ODOR
Mild (or faint). Petroleum.
SOLUBILITY DESCRIPTION
Insoluble in water.
DENSITY
1.09
VAPOR DENSITY (air=1)
>1
EVAPORATION RATE
<1
pH-VALUE, CONC. SOLUTION
N/A
Temperature (°C)
15.6 (60°F)
Reference
BuAc=1
10. STABILITY AND REACTIVITY
STABILITY
Normally stable.
CONDITIONS TO AVOID
Avoid contact with acids. Strong oxidizing agents.
HAZARDOUS POLYMERIZATION
Will not occur.
POLYMERIZATION DESCRIPTION
Not applicable
HAZARDOUS DECOMPOSITION
PRODUCTS
Oxides of: Carbon.
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION
No experimental toxicological data on the preparation as such is available.
COMPONENT
GRAPHITE
TOXIC DOSE - LD 50
TOXIC CONC. - LC 50
CARCINOGENICITY
N/A.
N/A.
OSHA: Not regulated. NTP: Not listed. IARC: Not listed as a Group 1, 2A, or 2B
agent.
COMPONENT
DISTILLATES, PETROLEUM, HYDROTREATED HEAVY NAPHTHENIC
4 /7
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11304 - CAT ANTI-SEIZE COMPOUND GRAPHITE BASE
TOXIC DOSE - LD 50
TOXIC DOSE - LD 50 SKIN
TOXIC CONC. - LC 50
CARCINOGENICITY
> 5000 mg/kg (oral rat)
> 2000 mg/kg (skn rbt)
N/A.
The petroleum base oil contained in this product has been highly refined to
remove aromatics and improve performance characteristics. The base oil is not
listed as a carcinogen by NTP, IARC, or OSHA.
COMPONENT
PETROLATUM
TOXIC DOSE - LD 50
TOXIC DOSE - LD 50 SKIN
TOXIC CONC. - LC 50
CARCINOGENICITY
> 2000 (estimated) mg/kg (oral rat)
> 2000 (estimated) mg/kg (skn rbt)
N/A.
The supplier states that product has no carcinogenic effects known in humans,
nor would any be expected.
COMPONENT
SILICA, CRYSTALLINE (COMMON NAME: QUARTZ)
TOXICOLOGICAL DATA
Carcinogenicity. WHMIS D2A > 0.1%
Chronic toxicity. WHMIS D2A > 1.0%
N/A.
N/A.
OSHA: Not regulated. IARC Group 1 designation: The agent is carcinogenic to
humans with sufficient evidence in humans. NTP-K designation: Known to be a
carcinogen with sufficient evidence from studies in humans.
TOXIC DOSE - LD 50
TOXIC CONC. - LC 50
CARCINOGENICITY
12. ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION
There is no ecological data on the product itself.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHODS
Spilled material, unused contents and empty containers must be disposed of in
accordance with local, state and federal regulations.
14. TRANSPORT INFORMATION
DOT HAZARD CLASS
Not regulated.
TDGR CLASS
Not Regulated. Non réglementé.
SEA TRANSPORT NOTES
Not regulated per IMDG.
AIR TRANSPORT NOTES
Not regulated per IATA.
15. REGULATORY INFORMATION
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11304 - CAT ANTI-SEIZE COMPOUND GRAPHITE BASE
US FEDERAL REGULATIONS
COMPONENT
SARA 302 CERCLA
SARA 313
GRAPHITE
No
No
No
DISTILLATES, PETROLEUM, HYDROTREATED HEAVY NAPHTHENIC
PETROLATUM
PETROLEUM OILS, 150 BRIGHT STOCK (CAS NOS 64742-62-7 & 64742-65-0)
SILICA, CRYSTALLINE (COMMON NAME: QUARTZ)
No
No
No
No
No
No
No
No
No
No
No
No
CLEAN AIR ACT
SARA HAZARD CATEGORIES
Chronic
US STATE REGULATIONS
CA
C
COMPONENT
SILICA, CRYSTALLINE (COMMON NAME: QUARTZ)
STATE REGULATORY STATUS
MA
FL
MN
NJ
PA
RI
PROPOSITION 65: This product may contain the following chemical(s) considered by
the State of California's Safe Drinking Water and Toxic Enforcement Act of 1986 as
causing cancer or reproductive toxicity, and for which warnings are now required:
Crystalline silica, cancer hazard, CAS# 14808-60-7
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM - WHMIS
This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations and the MSDS contains all the information required
by the Controlled Products Regulations.
LABEL(S) FOR SUPPLY
CONTROLLED PRODUCT
CLASSIFICATION
D2A - Chronic Very Toxic Material
Risk phrases
R-49 May cause cancer by inhalation.
GLOBAL INVENTORIES
CAN
US
COMPONENT
PETROLATUM
DSL
Yes
PETROLEUM OILS, 150 BRIGHT STOCK (CAS NOS DSL
Yes
64742-62-7 & 64742-65-0)
SILICA, CRYSTALLINE (COMMON NAME: QUARTZ) DSL
Yes
DISTILLATES, PETROLEUM, HYDROTREATED
DSL
Yes
HEAVY NAPHTHENIC
GRAPHITE
DSL
Yes
EU
EINECS
EINECS
AUS
Yes
Yes
JAP
Yes
Yes
KOR PHLP CHN
Yes
No
Yes
Yes Yes Yes
EINECS
EINECS
Yes
Yes
Yes
Yes
Yes
Yes
EINECS
Yes
No
Yes
Yes
Yes
Yes
Yes
Yes
Yes
6 /7
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11304 - CAT ANTI-SEIZE COMPOUND GRAPHITE BASE
All components of this product comply with new substance notification requirements
under the Canadian Environmental Protection Act (CEPA).
16. OTHER INFORMATION
NFPA-HMIS HAZARD RATING
HEALTH
Irritation, minor residual injury (1) - HMIS/NFPA
FLAMMABILITY
Burns only if pre-heated (1) - HMIS/NFPA
REACTIVITY
Normally Stable (0) - HMIS/NFPA
PERSONAL PROTECTION INDEX
B - Safety Eyewear and Gloves
REVISION COMMENTS
Section 15: US Regulatory Status.
PREPARED BY
Chemtool Incorporated, Regulatory Dept.
Replacement MSDS of
2008-10-06
DATE
2009-09-22
PRINTING DATE:
2009-09-22
DISCLAIMER
While the information and recommendations set forth herein are believed to be
accurate as of the date thereof, the company makes no warranty with respect thereto
and disclaims all liability from reliance therein.
* Information revised since previous MSDS version
7 /7
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MATERIAL SAFETY DATA SHEET
CAT ASSEMBLY LUBRICANT
1. PRODUCT AND COMPANY IDENTIFICATION
TRADE NAME
CAT ASSEMBLY LUBRICANT
Product number
Chemtool, 8425300000, Caterpillar, 207-1600, 207-1601
PRODUCT USE
Rubber Lubricant Emulsion
MANUFACTURER
Chemtool Incorporated
P.O. Box 538
8200 Ridgefield Road
Crystal Lake, IL 60039-0538
Tel: (815) 459-1250
Fax: (815) 459-1955
SUPPLIER
Caterpillar, Inc.
100 N. E. Adams Street
Peoria, Illinoiis 61629 USA
Tel: 01 309-679-1000
*CONTACT PERSON
Chemtool Inc.
EMERGENCY TELEPHONE
Rocky Mountain Poison Center
Denver, Colorado
In USA and Canada - (800) 458-5924
Outside USA and Canada - +01-303-893-1322
*Date of last issue
2009-09-23
2. COMPOSITION AND INFORMATION ON INGREDIENTS
CAS No.
7732-18-5
Proprietary
Proprietary
61791-12-6
110-63-4
INGREDIENT NAME
WATER
NEOPENTYL GLYCOL ESTER
GLYCOL MONOTALLATE
*CASTOR OIL, ETHOXYLATED
*1,4-BUTANEDIOL
WEIGHT
70-85 %
7-13 %
3-7 %
1-5 %
0.5-1.5 %
* This chemical(s) is hazardous according to OSHA/WHIMIS criteria
COMPOSITION COMMENTS
Refer to section eight for exposure limits on ingredients.
Chemical ingredients not regulated by OSHA, SARA, state or federal agencies are
treated confidentially.
1 /7
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12660 - CAT ASSEMBLY LUBRICANT
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HEALTH HAZARDS, GENERAL
No specific health warnings noted.
SENSITIZATION
No known information.
CARCINOGENICITY
IARC: Not listed as a Group 1, 2A, or 2B agent. OSHA: Not regulated. NTP: Not listed.
TERATOGENICITY
No known information.
HEALTH WARNINGS
INGESTION. Can cause discomfort. INHALATION. Spray mist can irritate airways and
lungs. SKIN CONTACT. EYE CONTACT. Slightly irritating.
ROUTE OF ENTRY
Inhalation. Ingestion. Skin and/or eye contact.
4. FIRST AID MEASURES
INHALATION
Remove victim immediately from source of exposure. When breathing is difficult,
properly trained personnel may assist affected person by administering 100% oxygen.
Perform artificial respiration if breathing has stopped. Get medical attention.
EYES
Important! Immediately rinse with water for at least 15 minutes. Get medical attention if
any discomfort continues.
SKIN
Remove contaminated clothing. Wash skin thoroughly with soap and water. Get medical
attention if any discomfort continues.
INGESTION
DO NOT INDUCE VOMITING! Administer large amounts of water. Get medical attention
immediately! NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK
FLUIDS!
5. FIRE FIGHTING MEASURES
FLASH POINT (°C)
> 100 (212 F)
FLAMMABILITY LIMIT - LOWER(%)
N/A
FLAMMABILITY LIMIT - UPPER(%)
N/A
FLAMMABILITY CLASS
No Uniform Fire Code noted.
EXTINGUISHING MEDIA
Use: Foam. Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc.
SPECIAL FIRE FIGHTING
PROCEDURES
Use water to keep fire exposed containers cool and disperse vapors.
UNUSUAL FIRE & EXPLOSION
HAZARDS
Volume and pressure increases strongly when heated. Risk of container explosion in
fire.
HAZARDOUS COMBUSTION
PRODUCTS
Acrid smoke/fumes. Oxides of: Carbon.
PROTECTIVE MEASURES IN CASE
OF FIRE
Self-contained breathing equipment and chemical resistant clothing recommended.
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12660 - CAT ASSEMBLY LUBRICANT
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Minimize skin contact.
PRECAUTIONS TO PROTECT THE
ENVIRONMENT
Keep product out of sewers and watercourses by diking or impounding. Advise
authorities if product has entered or may enter sewers, watercourses or extensive land
areas. Assure conformity with applicable government regulations.
SPILL CLEAN-UP PROCEDURES
Absorb with inert, damp, noncombustible material, then flush area with water.
7. HANDLING AND STORAGE
HANDLING PRECAUTIONS
Avoid spilling, skin and eye contact. Containers to be kept tightly closed. ***Eye wash
must be available at the work place.***
STORAGE PRECAUTIONS
Keep away from heat, sparks and open flame. Store isolated from oxidizing materials.
STORAGE CRITERIA
Chemical storage.
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
INGREDIENT COMMENTS
Recommended Exposure Limits are based on OIl Mist.
PROTECTIVE EQUIPMENT
ENGINEERING CONTROLS
Use engineering controls to reduce air contamination to permissible exposure level.
VENTILATION
No specific ventilation requirements noted, but forced ventilation may still be required if
air contamination exceeds acceptable level.
RESPIRATORS
No specific recommendation made, but respiratory protection may still be required under
exceptional circumstances when excessive air contamination exists.
PROTECTIVE GLOVES
For prolonged or repeated skin contact use suitable protective gloves. Use protective
gloves made of: Neoprene, nitrile, polyethylene or PVC.
EYE PROTECTION
Wear splash-proof eye goggles to prevent any possibility of eye contact.
PROTECTIVE CLOTHING
Wear appropriate clothing to prevent repeated or prolonged skin contact.
HYGIENIC WORK PRACTICES
Wash at the end of each work shift and before eating, smoking and using the toilet.
9. PHYSICAL AND CHEMICAL PROPERTIES
3 /7
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12660 - CAT ASSEMBLY LUBRICANT
APPEARANCE/PHYSICAL STATE
Liquid.
COLOR
Off-white. White. to Light (or pale). Beige.
ODOR
Mild (or faint).
SOLUBILITY DESCRIPTION
Disperses.
BOILING POINT (°C, range)
100 (212°F)
MELT./FREEZ. POINT (°C, interval)
0 (32°F)
DENSITY
0.965
pH-VALUE, CONC. SOLUTION
8.7
pH-VALUE, DILUTED SOLUTION
8.1
Pressure
760mmHg
Temperature (°C)
15.6 (60°F)
Concentration %M
5%
10. STABILITY AND REACTIVITY
STABILITY
Normally stable.
CONDITIONS TO AVOID
Avoid heat, flames and other sources of ignition. Avoid contact with strong oxidizers.
HAZARDOUS POLYMERIZATION
Will not polymerize.
POLYMERIZATION DESCRIPTION
Not relevant.
HAZARDOUS DECOMPOSITION
PRODUCTS
Oxides of: Carbon.
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION
No experimental toxicological data on the preparation as such is available.
COMPONENT
NEOPENTYL GLYCOL ESTER
TOXIC DOSE - LD 50
TOXIC CONC. - LC 50
No Information Available (NIA).
No Information Available (NIA).
COMPONENT
1,4-BUTANEDIOL
12. ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION
COMPONENT
No data on possible environmental effects have been found.
1,4-BUTANEDIOL
4 /7
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12660 - CAT ASSEMBLY LUBRICANT
13. DISPOSAL CONSIDERATIONS
Confirm disposal procedures with environmental engineer and local regulations.
DISPOSAL METHODS
14. TRANSPORT INFORMATION
DOT HAZARD CLASS
Not regulated.
U.S. DOT HAZARD LABEL
No DOT label requirement
TDGR CLASS
Not Regulated.
SEA TRANSPORT NOTES
Not regulated per IMDG.
*AIR TRANSPORT NOTES
Not regulated per IATA.
15. REGULATORY INFORMATION
US FEDERAL REGULATIONS
COMPONENT
SARA 302 CERCLA
NEOPENTYL GLYCOL ESTER
No
No
No
GLYCOL MONOTALLATE
No
No
No
CASTOR OIL, ETHOXYLATED
No
No
No
1,4-BUTANEDIOL
No
No
No
SARA 313
CLEAN AIR ACT
*SARA HAZARD CATEGORIES
Acute Chronic
US STATE REGULATIONS
STATE REGULATORY STATUS
CALIFORNIA PROPOSITION 65: This product ***DOES NOT*** contain chemicals
considered by the State of California's Safe Drinking Water and Toxic Enforcement Act
of 1986 as causing cancer or reproductive toxicity, and for which warnings are now
required.
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM - WHMIS
*
This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulations and the MSDS contains all the information required by the
Controlled Products Regulations.
*LABEL(S) FOR SUPPLY
5 /7
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12660 - CAT ASSEMBLY LUBRICANT
*CONTROLLED PRODUCT
CLASSIFICATION
D2B - Irritating and/or Chronically Toxic Materials
*Risk phrases
R-20 Harmful by inhalation.
R-22 Harmful if swallowed.
R-36 Irritating to eyes.
R-38 Irritating to skin.
COMPONENT
NEOPENTYL GLYCOL ESTER
GLYCOL MONOTALLATE
CASTOR OIL, ETHOXYLATED
1,4-BUTANEDIOL
GLOBAL INVENTORIES
CAN
US
DSL
Yes
DSL
Yes
DSL
Yes
DSL
Yes
EU
EINECS
EINECS
NLP
EINECS
AUS
Yes
Yes
Yes
Yes
JAP
No
No
Yes
Yes
KOR
Yes
No
Yes
Yes
PHLP
No
No
Yes
Yes
CHN
No
No
Yes
No
*
CANADA CEPA: All components of this product comply with new substance notification
requirements under the Canadian Environmental Protection Act (CEPA).
*USA (TSCA)
All components in this product are listed on the US Toxic Substances Control Act
(TSCA) Inventory or are exempt from TSCA Inventory requirements.
*CANADA (DSL)
All components in this product are listed on the Canada Domestic Substances List
(DSL) or are exempt from DSL requirements.
*AUSTRALIA (AICS)
All components in this product are listed on the Australian Inventory of Chemical
Substances (AICS) or are exempt from AICS requirements.
16. OTHER INFORMATION
NFPA-HMIS HAZARD RATING
HEALTH
Irritation, minor residual injury (1) - HMIS/NFPA
*FLAMMABILITY
Burns only if pre-heated (1) - HMIS/NFPA
REACTIVITY
Normally Stable (0) - HMIS/NFPA
*NPCA HMIS HAZARD INDEX
Slight: Slightly Toxic - May cause slight irritation (1).
PERSONAL PROTECTION INDEX
B - Safety Eyewear and Gloves
*NPCA HMIS FLAMMABILITY
INDEX
Burns only if pre-heated (1).
*NPCA HMIS REACTIVITY INDEX
Normally stable (0).
*Tariff Code (Schedule B)
3403.99.0000 Other lubricating preparations, not containing petroleum oils.
*REVISION COMMENTS
Section 2: Percentage Composition
Section 15: Inventory Status
6 /7
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12660 - CAT ASSEMBLY LUBRICANT
*PREPARED BY
John Dingess
James McBriarty
Maria Maka
*REVISION No.
2
*Replacement of MSDS generated
2008-10-07
*DATE
2009-09-23
DISCLAIMER
While the information and recommendations set forth herein are believed to be accurate
as of the date thereof, the company makes no warranty with respect thereto and
disclaims all liability from reliance therein.
* Information revised since previous MSDS version
PRINTING DATE:
2009-09-23
7 /7
Page 100 of 320
12446 - CAT BEARING MOUNT COMPOUND
MATERIAL SAFETY DATA SHEET
CAT BEARING MOUNT COMPOUND
1. PRODUCT AND COMPANY IDENTIFICATION
TRADE NAME
CAT BEARING MOUNT COMPOUND
Product number
Chemtool, 8427400000, 8428900000, Caterpillar, 4C-4032, 7M-7456
SUPPLIER
Chemtool Incorporated
P.O. Box 538
8200 Ridgefield Road
Crystal Lake, IL 60039-0538 USA
Tel: (815) 459-1250
Fax: (815) 459-1955
EMERGENCY TELEPHONE
Rocky Mountain Poison Center
Denver, Colorado
In USA and Canada - (800) 458-5924
Outside USA and Canada - +01-303-893-1322
*Date of last issue
2008-11-06
2. COMPOSITION AND INFORMATION ON INGREDIENTS
INGREDIENT NAME
*2-PROPENOIC ACID, 2-METHYL-, 1,2-ETHANEDIYLBIS(OXY-2,1-ETHANEDIYL)
ESTER
*2-PROPENOIC ACID, 2-METHYL-, 2-HYDROXYETHYL ESTER
*1,2-BENZISOTHIAZOL-3(2H)-ONE, 1,1-DIOXIDE (COMMON NAME: SACCHARIN)
CAS No.
109-16-0
WEIGHT
40-60 %
868-77-9
81-07-2
10-20 %
1-3 %
* This chemical(s) is hazardous according to OSHA/WHIMIS criteria
*COMPOSITION COMMENTS
Refer to section eight for exposure limits on ingredients.
Chemical ingredients not regulated by OSHA, SARA, state or federal agencies are
treated confidentially.
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes and skin. May cause sensitisation by skin contact.
INHALATION
No specific health warnings noted.
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12446 - CAT BEARING MOUNT COMPOUND
INGESTION
No specific health warnings noted.
SKIN
Irritating to skin.
EYES
Irritating to eyes.
SENSITIZATION
May cause sensitization, an allergic reaction, which becomes evident on reexposure to
this chemical.
TERATOGENICITY
No known information.
HEALTH WARNINGS
EYE CONTACT. Irritating. SKIN CONTACT. Mild dermatitis, allergic skin rash.
ROUTE OF ENTRY
Skin and/or eye contact. Inhalation.
4. FIRST AID MEASURES
INHALATION
Remove victim immediately from source of exposure. Get medical attention if any
discomfort continues.
EYES
Important! Immediately rinse with water for at least 15 minutes. Get medical attention if
any discomfort continues.
SKIN
Immediately remove contaminated clothing. Wash skin thoroughly with soap and water.
Get medical attention if irritation persists after washing.
INGESTION
DO NOT induce vomiting. Get medical attention immediately. Do not give victim
anything to drink if he is unconscious.
5. FIRE FIGHTING MEASURES
FLASH POINT (°C)
99 (210 F) TCC (Tag closed cup).
FLAMMABILITY LIMIT - LOWER(%)
N/D
FLAMMABILITY LIMIT - UPPER(%)
N/D
EXTINGUISHING MEDIA
Use: Carbon dioxide (CO2). Foam. Dry chemicals.
SPECIAL FIRE FIGHTING
PROCEDURES
Use water to keep fire exposed containers cool and disperse vapors. Water spray may
be used to flush spills away from exposures and dilute spills to non-flammable mixtures.
Avoid water in straight hose stream; will scatter and spread fire. Keep run-off water out
of sewers and water sources. Dike for water control.
HAZARDOUS COMBUSTION
PRODUCTS
Irritating gases/vapors/fumes. Oxides of: Carbon. Nitrogen.
6. ACCIDENTAL RELEASE MEASURES
SPILL CLEAN-UP PROCEDURES
Carefully collect spilled material in closed containers and leave for disposal according to
local regulations. Provide good ventilation. Use appropriate protective clothing. Rinse
area with water. Do not let washing down water contaminate ponds or waterways.
7. HANDLING AND STORAGE
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12446 - CAT BEARING MOUNT COMPOUND
HANDLING PRECAUTIONS
Keep away from heat, sparks and open flame. Provide good ventilation. Containers to
be kept tightly closed. Avoid spilling, skin and eye contact.
STORAGE PRECAUTIONS
Keep away from heat, sparks and open flame. Store below 75°F. Store isolated from
oxidizing materials.
STORAGE CRITERIA
Chemical storage.
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
*INGREDIENT COMMENTS
No exposure limits indicated for ingredient(s).
PROTECTIVE EQUIPMENT
VENTILATION
No specific ventilation requirements noted, but forced ventilation may still be required if
air contamination exceeds acceptable level.
RESPIRATORS
No specific recommendation made, but respiratory protection may still be required under
exceptional circumstances when excessive air contamination exists.
PROTECTIVE GLOVES
For prolonged or repeated skin contact use suitable protective gloves.
EYE PROTECTION
Use eye protection.
PROTECTIVE CLOTHING
Wear appropriate clothing to prevent repeated or prolonged skin contact.
HYGIENIC WORK PRACTICES
Wash at the end of each work shift and before eating, smoking and using the toilet.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE/PHYSICAL STATE
Liquid.
COLOR
Green.
ODOR
Mild (or faint).
SOLUBILITY DESCRIPTION
Slightly soluble in water.
BOILING POINT (°C, range)
> 149 (300°F)
MELT./FREEZ. POINT (°C, interval)
N/D
SPECIFIC GRAVITY
1.1
VAPOR DENSITY (air=1)
N/D
Pressure
VAPOR PRESSURE
< 5 mmHg
Temperature (°C)
EVAPORATION RATE
N/D
Reference
25 (77°F)
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12446 - CAT BEARING MOUNT COMPOUND
10. STABILITY AND REACTIVITY
STABILITY
Normally stable.
CONDITIONS TO AVOID
Avoid contact with acids and oxidizing substances.
HAZARDOUS POLYMERIZATION
Will not polymerize.
HAZARDOUS DECOMPOSITION
PRODUCTS
No specific hazardous decomposition products noted.
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION
No experimental toxicological data on the preparation as such is available.
COMPONENT
2-PROPENOIC ACID, 2-METHYL-,
1,2-ETHANEDIYLBIS(OXY-2,1-ETHANEDIYL) ESTER
TOXICOLOGICAL DATA
TOXIC DOSE - LD 50
TOXIC CONC. - LC 50
SENSITIZATION
Irritating effects. WHMIS (Canada) D2B - R36/38 Sartomer
COMPONENT
2-PROPENOIC ACID, 2-METHYL-, 2-HYDROXYETHYL ESTER
TOXICOLOGICAL DATA
TOXIC DOSE - LD 50
TOXIC DOSE - LD 50 SKIN
TOXIC CONC. - LC 50
SENSITIZATION
Irritating effects. WHMIS (Canada) D2B - R36/38, R43 csst.qc.ca
No Information Available (NIA).
No Information Available (NIA).
May cause sensitization, an allergic reaction, which becomes evident on reexposure to
this chemical.
5050 mg/kg (oral rat)
> 5000 mg/kg (skn rbt)
No Information Available (NIA).
May cause sensitization, an allergic reaction, which becomes evident on reexposure to
this chemical.
12. ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION
No data on possible environmental effects have been found.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHODS
Dispose of in accordance with Local Authority requirements. Confirm disposal
procedures with environmental engineer and local regulations.
14. TRANSPORT INFORMATION
DOT HAZARD CLASS
Non-Hazardous (No label required).
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12446 - CAT BEARING MOUNT COMPOUND
*TDGR CLASS
Not Regulated.
SEA TRANSPORT NOTES
Not regulated per IMDG.
AIR TRANSPORT NOTES
Not regulated per IATA.
15. REGULATORY INFORMATION
US FEDERAL REGULATIONS
COMPONENT
SARA 302 CERCLA
SARA 313
2-PROPENOIC ACID, 2-METHYL-, 1,2-ETHANEDIYLBIS(OXY-2,1-ETHANEDIYL)
ESTER
2-PROPENOIC ACID, 2-METHYL-, 2-HYDROXYETHYL ESTER
No
No
No
No
No
No
1,2-BENZISOTHIAZOL-3(2H)-ONE, 1,1-DIOXIDE (COMMON NAME: SACCHARIN)
No
100 lbs
Yes
See Section 2 for Addtional Information
CLEAN AIR ACT
*SARA HAZARD CATEGORIES
Acute Chronic
US STATE REGULATIONS
CA
MA
COMPONENT
1,2-BENZISOTHIAZOL-3(2H)-ONE, 1,1-DIOXIDE
No
(COMMON NAME: SACCHARIN)
*STATE REGULATORY STATUS
FL
MN
NJ
PA
RI
ESHS
CALIFORNIA PROPOSITION 65: This product ***DOES NOT*** contain chemicals
considered by the State of California's Safe Drinking Water and Toxic Enforcement Act
of 1986 as causing cancer or reproductive toxicity, and for which warnings are now
required.
PENNSYLVANIA RIGHT-TO-KNOW: This product contains the following chemicals that
the state of Pennsylvania has identified as Special Hazardous Substances (SHS),
Environmental Hazards (EH), or both (ESHS). The PA regulations require that the
MSDS identify all SHS or EH chemicals by chemical name, common name, and CAS
Number if they comprise 0.01% or more.
1,2-Benzisothiazol-3(2H)-one, 1,1-dioxide, Environmental and Special Hazards, CAS#
81-07-2
Hydroperoxide, 1-methyl-1phenylethyl, Environmental Hazard, CAS# 80-15-9 <1.0%
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM - WHMIS
This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulations and the MSDS contains all the information required by the
Controlled Products Regulations.
*LABEL(S) FOR SUPPLY
5 /6
Page 105 of 320
12446 - CAT BEARING MOUNT COMPOUND
CONTROLLED PRODUCT
CLASSIFICATION
D2B - Irritating and/or Chronically Toxic Materials
Risk phrases
R-36/38 Irritating to eyes and skin.
R-43 May cause sensitization by skin contact.
COMPONENT
2-PROPENOIC ACID, 2-METHYL-,
1,2-ETHANEDIYLBIS(OXY-2,1-ETHANEDIYL)
ESTER
2-PROPENOIC ACID, 2-METHYL-,
2-HYDROXYETHYL ESTER
1,2-BENZISOTHIAZOL-3(2H)-ONE, 1,1-DIOXIDE
(COMMON NAME: SACCHARIN)
GLOBAL INVENTORIES
CAN
US
DSL
Yes
EU
EINECS
AUS
Yes
JAP
Yes
KOR PHLP CHN
Yes Yes Yes
DSL
Yes
EINECS
No
No
No
No
No
DSL
Yes
EINECS
No
No
No
No
No
CANADA CEPA: All components of this product comply with new substance notification
requirements under the Canadian Environmental Protection Act (CEPA).
16. OTHER INFORMATION
NFPA-HMIS HAZARD RATING
HEALTH
Temporary incapacitation, injury (2) - HMIS/NFPA
FLAMMABILITY
Burns only if pre-heated (1) - HMIS/NFPA
REACTIVITY
Normally Stable (0) - HMIS/NFPA
PERSONAL PROTECTION INDEX
B - Safety Eyewear and Gloves
*Tariff Code (Schedule B)
3214.90.0000 Other non-refractory surfacing preparations for façades, indoor walls,
floors, ceilings or the like.
PREPARED BY
James P. McBriarty
*Replacement of MSDS generated
2007-03-22
*DATE
2008-11-06
DISCLAIMER
While the information and recommendations set forth herein are believed to be accurate
as of the date thereof, the company makes no warranty with respect thereto and
disclaims all liability from reliance therein.
* Information revised since previous MSDS version
PRINTING DATE:
2008-11-06
6 /6
Page 106 of 320
10080 - CAT CEMENT
REVISION DATE:
MATERIAL SAFETY DATA SHEET
CAT CEMENT
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
TRADE NAME
CAT CEMENT
PART No.
5H-2471
PRODUCT USE
Contact Adhesive
SUPPLIER
Chemtool Incorporated
P.O. Box 538
8200 Ridgefield Road
Crystal Lake, IL 60039-0538 USA
Tel: (815) 459-1250
Fax: (815) 459-1955
EMERGENCY TELEPHONE
Rocky Mountain Poison Center Denver, Colorado
(800) 458-5924 U.S. and Canada.
(303) 893-1322 Outside U.S.
2. COMPOSITION, INFORMATION ON INGREDIENTS
CAS No.
78-93-3
67-64-1
110-54-3
108-88-3
128-37-0
1309-48-4
INGREDIENT NAME
BUTANONE, 2- (COMMON NAME: METHYL ETHYL KETONE)
ACETONE
HEXANE
BENZENE, METHYLPHENOL, 2,6-BIS(1,1-DIMETHYLETHYL)-4-METHYLMAGNESIUM OXIDE (MgO)
WEIGHT
10-30 %
10-30 %
10-30 %
10-30 %
1-5 %
1-5 %
COMPOSITION COMMENTS
Refer to section eight for exposure limits on ingredients.
Chemical ingredients not regulated by OSHA or SARA are treated confidentially.
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Highly flammable. Harmful by inhalation. Irritating to eyes and skin. Harmful, danger
of serious damage to health by prolonged exposure through inhalation. Harmful to
aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Possible risk of impaired fertility. Repeated exposure may cause skin dryness or
cracking. Vapours may cause drowsiness and dizziness.
ACUTE EFFECTS
HEALTH HAZARDS, GENERAL
Harmful: danger of serious damage to health by prolonged exposure through
inhalation. Irritating to eyes, respiratory system, and skin.
1 /7
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10080 - CAT CEMENT
REVISION DATE:
CHRONIC EFFECTS
SENSITIZATION
No known information.
CARCINOGENICITY
IARC: Not listed. OSHA: Not regulated. NTP: Not listed.
TERATOGENICITY
Possible risk of impaired fertility.
HEALTH WARNINGS
INHALATION. Repeated severe exposures or steady prolonged exposure to solvents
may cause permanent injury. SKIN CONTACT. Slightly irritating. Repeated or
prolonged contact can result in drying of the skin. The product/chemical has a
defatting effect on the skin. EYE CONTACT. Strongly irritating. INGESTION. Can cause
stomach ache and vomiting. Can cause internal injury.
OTHER INFORMATION
ROUTE OF ENTRY
Inhalation. Ingestion. Skin and/or eye contact. Skin absorption.
4. FIRST AID MEASURES
INHALATION
Remove victim immediately from source of exposure. When breathing is difficult,
properly trained personnel may assist affected person by administering 100%
oxygen. If breathing stops, provide artificial respiration. Get medical attention.
EYES
Important! Immediately rinse with water for at least 15 minutes. Get medical attention
if any discomfort continues.
SKIN
Remove contaminated clothing. Wash skin thoroughly with soap and water. Get
medical attention if irritation persists after washing.
INGESTION
DO NOT induce vomiting. Get medical attention immediately. Drink large amounts of
water. Do not give victim anything to drink of he is unconscious.
5. FIRE FIGHTING MEASURES
FLASH POINT (°C)
< 20 TCC (Tag closed cup).
FLAMMABILITY LIMIT - LOWER(%)
N/D
FLAMMABILITY LIMIT - UPPER(%)
N/D
EXTINGUISHING MEDIA
Use: Alcohol resistant foam. Carbon dioxide (CO2). Dry chemicals, sand, dolomite
etc.
SPECIAL FIRE FIGHTING PROCEDURES Use water to keep fire exposed containers cool and disperse vapors. Water spray
may be used to flush spills away from exposures and dilute spills to non-flammable
mixtures. Avoid water in straight hose stream; will scatter and spread fire. Keep
run-off water out of sewers and water sources. Dike for water control.
UNUSUAL FIRE & EXPLOSION
HAZARDS
Vapors may ignite. Volume and pressure increases strongly when heated. Risk of
container explosion in fire.
HAZARDOUS COMBUSTION PRODUCTSCarbon dioxide (CO2). Carbon monoxide (CO).
PROTECTIVE MEASURES IN CASE OF
FIRE
Firefighters exposed to combustion gases/decomposition products should use a
respiratory protective device.
2 /7
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10080 - CAT CEMENT
REVISION DATE:
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Minimize skin contact. Avoid breathing vapors. Wear an appropriate respirator if
exposure exceeds recommended guidelines. Remove sources of ignition.
PRECAUTIONS TO PROTECT THE
ENVIRONMENT
Keep product out of sewers and watercourses by diking or impounding. Advise
authorities if product has entered or may enter sewers, watercourses or extensive
land areas. Assure conformity with applicable government regulations.
SPILL CLEAN-UP PROCEDURES
Carefully collect spilled material in closed containers and leave for disposal
according to local regulations. Provide good ventilation. Use appropriate protective
clothing. Rinse area with water. Do not let washing down water contaminate ponds or
waterways.
7. HANDLING AND STORAGE
HANDLING PRECAUTIONS
Ventilate well, avoid breathing vapors. Use approved respirator if air contamination is
above accepted level. Do not use in confined spaces without adequate ventilation
and/or respirator. Avoid spilling, skin and eye contact. Keep away from heat, sparks
and open flame. Eye wash and emergency shower must be available at the work
place.
STORAGE PRECAUTIONS
Keep away from heat, sparks and open flame. Store separated from: Acids. Oxidizing
materials.
STORAGE CRITERIA
Flammable liquid storage.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
COMPONENT
STD
OSHA
TWA
200 ppm
STEL
300 ppm
ACETONE
ACGIH
OSHA
200 ppm
750 ppm
300 ppm
1000 ppm
ACGIH
OSHA
750 ppm
50 ppm
1000 ppm
HEXANE
BENZENE, METHYL-
ACGIH
OSHA
50 ppm
100 ppm
ACGIH
OSHA
50 ppm
BUTANONE, 2- (COMMON NAME: METHYL
ETHYL KETONE)
PHENOL,
2,6-BIS(1,1-DIMETHYLETHYL)-4-METHYLMAGNESIUM OXIDE (MgO)
TWA
STEL
150 ppm
10 mg/m3
ACGIH
10 mg/m3
OSHA
10 mg/m3
ACGIH
10 mg/m3
PROTECTIVE EQUIPMENT
3 /7
Page 109 of 320
10080 - CAT CEMENT
REVISION DATE:
ENGINEERING CONTROLS
Use engineering controls to reduce air contamination to permissible exposure level.
VENTILATION
No specific ventilation requirements noted, but forced ventilation may still be required
if air contamination exceeds acceptable level.
RESPIRATORS
No specific recommendation made, but respiratory protection may still be required
under exceptional circumstances when excessive air contamination exists.
PROTECTIVE GLOVES
Chemical resistant gloves required for prolonged or repeated contact. Use protective
gloves made of: Neoprene, nitrile, polyethylene or PVC.
EYE PROTECTION
Wear splash-proof eye goggles to prevent any possibility of eye contact.
PROTECTIVE CLOTHING
Wear appropriate clothing to prevent repeated or prolonged skin contact.
HYGIENIC WORK PRACTICES
Wash at the end of each work shift and before eating, smoking and using the toilet.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE/PHYSICAL STATE
Liquid.
COLOR
Green.
ODOR
Solvent.
SOLUBILITY DESCRIPTION
Insoluble in water.
DENSITY
0.80
VAPOR DENSITY (air=1)
> 1.0
VAPOR PRESSURE
N/D
Temperature (°C)
EVAPORATION RATE
< 1.0
Reference
pH-VALUE, CONC. SOLUTION
N/A
Temperature (°C)
16
BuAc=1
10. STABILITY AND REACTIVITY
STABILITY
Normally stable.
CONDITIONS TO AVOID
Avoid heat, flames and other sources of ignition. Avoid contact with oxidizers or
reducing agents.
HAZARDOUS POLYMERIZATION
Will not polymerize.
POLYMERIZATION DESCRIPTION
Not relevant.
HAZARDOUS DECOMPOSITION
PRODUCTS
Oxides of: Carbon.
4 /7
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10080 - CAT CEMENT
REVISION DATE:
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION
No experimental toxicological data on the preparation as such is available.
12. ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION
No data on possible environmental effects have been found.
BIOACCUMULATION
Not known.
BIODEGRADABILITY
Not known.
ACUTE AQUATIC TOXICITY
Not determined.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHODS
Confirm disposal procedures with environmental engineer and local regulations.
14. TRANSPORT INFORMATION
DOT PROPER SHIPPING NAME
Consumer Commodity,
DOT HAZARD CLASS
ORM-D (Other Regulated Material D).
LABEL FOR TRANSPORT
UN No. SEA
UN1133
IMDG CLASS
3
IMDG PACK GR.
II
EmS No.
3-05
MFAG TABLE No.
330
SEA TRANSPORT NOTES
Adhesives
UN No., AIR
UN1133
ICAO CLASS
3
AIR PACK GR.
II
5 /7
Page 111 of 320
10080 - CAT CEMENT
REVISION DATE:
Adhesives
AIR TRANSPORT NOTES
15. REGULATORY INFORMATION
US FEDERAL REGULATIONS
COMPONENT
SARA 302 CERCLA
BUTANONE, 2- (COMMON NAME: METHYL ETHYL KETONE)
ACETONE
HEXANE
BENZENE, METHYLPHENOL, 2,6-BIS(1,1-DIMETHYLETHYL)-4-METHYLMAGNESIUM OXIDE (MgO)
N/A
N/A
N/A
N/A
N/A
N/A
5 000 lbs
5 000 lbs
1 lb (air)
1 000 lbs
N/A
N/A
SARA 313
Yes
N/A
Yes
Yes
N/A
N/A
See Section 2 for Addtional Information
CLEAN AIR ACT
SARA(311/312) HAZARD CATEGORIES Acute Chronic Fire
US STATE REGULATIONS
STATE REGULATORY STATUS
PROPOSITION 65: This product may contain the following chemical(s) considered by
the State of California's Safe Drinking Water and Toxic Enforcement Act of 1986 as
causing cancer or reproductive toxicity, and for which warnings are now required:
Toluene, CAS # 108-88-3
Lead, <1ppm
Cadmium, <1ppm
Formaldehyde, CAS # 50-00-0
Benzene, CAS # 71-43-2, <100ppm
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM - WHIMIS
INVENTORIES
CAN
US
COMPONENT
BUTANONE, 2- (COMMON NAME: METHYL ETHYL DSL
Yes
KETONE)
ACETONE
DSL
Yes
HEXANE
DSL
Yes
PHENOL,
DSL
Yes
2,6-BIS(1,1-DIMETHYLETHYL)-4-METHYLMAGNESIUM OXIDE (MgO)
DSL
Yes
BENZENE, METHYLDSL
Yes
EU
NAV
AUS
NAV
JAP
NAV
KOR CHN
NAV NAV
PHLP
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
NAV
16. OTHER INFORMATION
6 /7
Page 112 of 320
10080 - CAT CEMENT
REVISION DATE:
HEALTH
Temporary incapacitation, injury (2) - HMIS/NFPA
FLAMMABILITY
Ignites easily (3) - HMIS/NFPA
REACTIVITY
Normally Stable (0) - HMIS/NFPA
REVISION COMMENTS
Section 2: Ingredients
Section 3: Hazard Identification
PREPARED BY
John Dingess
James W. Hermann
REVISION No./Repl. MSDS of
2003-11-17
DATE
2004-06-11
PRINTING DATE:
2004-06-11
DISCLAIMER
While the information and recommendations set forth herein are believed to be
accurate as of the date thereof, Chemtool Incorporated makes no warranty with
respect thereto and disclaims all liability from reliance therein.
7 /7
Page 113 of 320
10019 - CAT LIQUID GASKET-A
MATERIAL SAFETY DATA SHEET
CAT LIQUID GASKET-A
1. PRODUCT AND COMPANY IDENTIFICATION
TRADE NAME
CAT LIQUID GASKET-A
PART No.
Chemtool, 8431000000, Caterpillar, 9U-5839, 138-8436, 3-0029432
PRODUCT USE
Gasket Sealer
SUPPLIER
Chemtool Incorporated
P.O. Box 538
8200 Ridgefield Road
Crystal Lake, IL 60039-0538 USA
Tel: (815) 459-1250
Fax: (815) 459-1955
EMERGENCY TELEPHONE
Rocky Mountain Poison Center
Denver, Colorado
In USA and Canada - (800) 458-5924
Outside USA and Canada - +01-303-893-1322
*Date of last issue
2008-11-06
2. COMPOSITION AND INFORMATION ON INGREDIENTS
CAS No.
67-64-1
9003-18-3
1309-37-1
122-39-4
INGREDIENT NAME
*ACETONE
2-PROPENENITRILE, POLYMER WITH 1,3-BUTADIENE
*IRON OXIDE (Fe2O3)
*DIPHENYLAMINE
WEIGHT
70-90 %
10-30 %
1-3 %
<0.2
* This chemical(s) is hazardous according to OSHA/WHIMIS criteria
*COMPOSITION COMMENTS
Refer to section eight for exposure limits on ingredients.
Chemical ingredients not regulated by OSHA, SARA, state or federal agencies are
treated confidentially.
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Highly flammable liquid. Irritating to eyes. Repeated exposure may cause skin
1 /7
Page 114 of 320
10019 - CAT LIQUID GASKET-A
dryness or cracking. Vapours may cause drowsiness and dizziness.
SENSITIZATION
No known information.
CARCINOGENICITY
IARC: Not listed as a Group 1, 2A, or 2B agent. OSHA: Not regulated. NTP: Not listed.
TERATOGENICITY
No known information.
HEALTH WARNINGS
INHALATION. The solvent vapors are harmful and will cause headache, nausea and
intoxication. SKIN CONTACT. Irritating. Repeated or prolonged contact can result in
drying of the skin. The product/chemical has a defatting effect on the skin. EYE
CONTACT. Strongly irritating. INGESTION. Can cause stomach ache and vomiting.
ROUTE OF ENTRY
Skin and/or eye contact. Skin absorption.
4. FIRST AID MEASURES
INHALATION
Remove victim immediately from source of exposure. When breathing is difficult,
properly trained personnel may assist affected person by administering 100% oxygen.
If breathing stops, provide artificial respiration. Get medical attention.
EYES
Important! Immediately rinse with water for at least 15 minutes. Get medical attention
if any discomfort continues.
SKIN
Remove contaminated clothing. Wash skin thoroughly with soap and water. Get
medical attention if irritation persists after washing.
INGESTION
DO NOT induce vomiting. Get medical attention immediately. Never give anything by
mouth to an unconscious person.
5. FIRE FIGHTING MEASURES
FLASH POINT (°C)
-20 (-4 F) TCC (Tag closed cup).
FLAMMABILITY LIMIT - LOWER(%)
2.2
FLAMMABILITY LIMIT - UPPER(%)
13.0
EXTINGUISHING MEDIA
Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc. Alcohol resistant foam.
SPECIAL FIRE FIGHTING
PROCEDURES
Use water to keep fire exposed containers cool and disperse vapors. Water spray
may be used to flush spills away from exposures and dilute spills to non-flammable
mixtures. Avoid water in straight hose stream; will scatter and spread fire. Keep run-off
water out of sewers and water sources. Dike for water control. Use special protective
clothing. Regular protection may not be safe. Prevent inhalation of fumes and gases.
UNUSUAL FIRE & EXPLOSION
HAZARDS
Volume and pressure increases strongly when heated. Risk of container explosion in
fire.
HAZARDOUS COMBUSTION
PRODUCTS
Acrid smoke/fumes. Oxides of: Carbon. Nitrogen.
PROTECTIVE MEASURES IN CASE OF
FIRE
Self-contained breathing equipment and chemical resistant clothing recommended.
6. ACCIDENTAL RELEASE MEASURES
2 /7
Page 115 of 320
10019 - CAT LIQUID GASKET-A
PERSONAL PRECAUTIONS
Minimize skin contact. Avoid breathing vapors. Wear an appropriate respirator if
exposure exceeds recommended guidelines. Remove sources of ignition.
PRECAUTIONS TO PROTECT THE
ENVIRONMENT
Keep product out of sewers and watercourses by diking or impounding. Advise
authorities if product has entered or may enter sewers, watercourses or extensive
land areas. Assure conformity with applicable government regulations.
SPILL CLEAN-UP PROCEDURES
Carefully collect spilled material in closed containers and leave for disposal
according to local regulations. Provide good ventilation. Use appropriate protective
clothing. Rinse area with water. Do not let washing down water contaminate ponds or
waterways.
7. HANDLING AND STORAGE
HANDLING PRECAUTIONS
Ventilate well, avoid breathing vapors. Use approved respirator if air contamination is
above accepted level. Keep away from heat, sparks and open flame. Avoid spilling,
skin and eye contact. Eye wash and emergency shower must be available at the work
place. Containers to be kept tightly closed. Do not use in confined spaces without
adequate ventilation and/or respirator.
STORAGE PRECAUTIONS
Keep away from heat, sparks and open flame. Store separate from strong acids and
oxidizers. Store in accordance with local regulations.
STORAGE CRITERIA
Flammable liquid storage.
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
COMPONENT
ACETONE
IRON OXIDE (Fe2O3)
STD
OSHA
TWA
STEL
N/E
TWA
1000 ppm
ACGIH
500 ppm
750 ppm
1188 mg/m3
250 ppm
N/E
NIOSH
OSHA
STEL
2400 mg/m3
1782 mg/m3
10 mg/m3 (fume)
ACGIH
5 mg/m3 as Fe
(dust & fume)
PROTECTIVE EQUIPMENT
ENGINEERING CONTROLS
Use engineering controls to reduce air contamination to permissible exposure level.
VENTILATION
No specific ventilation requirements noted, but forced ventilation may still be required
if air contamination exceeds acceptable level.
RESPIRATORS
Respiratory protection must be used if air concentration exceeds acceptable level.
PROTECTIVE GLOVES
Chemical resistant gloves required for prolonged or repeated contact.
EYE PROTECTION
Wear splash-proof eye goggles to prevent any possibility of eye contact.
3 /7
Page 116 of 320
10019 - CAT LIQUID GASKET-
PROTECTIVE CLOTHING
Wear appropriate clothing to prevent repeated or prolonged skin contact.
HYGIENIC WORK PRACTICES
Wash at the end of each work shift and before eating, smoking and using the toilet.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE/PHYSICAL STATE
Liquid.
COLOR
Red.
ODOR
Solvent.
SOLUBILITY DESCRIPTION
Slightly soluble in water.
BOILING POINT (°C, range)
56 (133°F)
Pressure
DENSITY
0.8
Temperature (°C)
VAPOR DENSITY (air=1)
> 1.0
VAPOR PRESSURE
N/D
Temperature (°C)
EVAPORATION RATE
< 1.0
Reference
pH-VALUE, CONC. SOLUTION
N/A
760mmHg
15.6 (60°F)
BuAc=1
10. STABILITY AND REACTIVITY
STABILITY
Normally stable.
CONDITIONS TO AVOID
Avoid heat, flames and other sources of ignition. Avoid contact with oxidizers or
reducing agents.
HAZARDOUS POLYMERIZATION
Will not polymerize.
HAZARDOUS DECOMPOSITION
PRODUCTS
Oxides of: Carbon. Nitrogen.
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION
No experimental toxicological data on the preparation as such is available.
COMPONENT
ACETONE
TOXICOLOGICAL DATA
TOXIC DOSE - LD 50
TOXIC DOSE - LD 50
TOXIC CONC. - LC 50
Irritating effects. WHMIS (Canada) Eye. D2B - R36
5800 mg/kg (oral rat)
20000 mg/kg (oral rat)
120 mg/l (inh-rat)
COMPONENT
2-PROPENENITRILE, POLYMER WITH 1,3-BUTADIENE
TOXIC DOSE - LD 50
TOXIC CONC. - LC 50
No Information Available (NIA).
No Information Available (NIA).
4 /7
Page 117 of 320
10019 - CAT LIQUID GASKET
12. ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION
No data on possible environmental effects have been found.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHODS
Spilled material, unused contents and empty containers must be disposed of in
accordance with local, state and federal regulations.
14. TRANSPORT INFORMATION
DOT PROPER SHIPPING NAME
Acetone
DOT HAZARD CLASS
3
IDENTIFICATION No.
UN1090
PACKING GROUP
II
REPORTABLE QUANTITY (RQ)
5,882 pounds due to ACETONE.
LABEL FOR TRANSPORT
UN No. SEA
UN1090
IMDG CLASS
3
IMDG PACK GR.
II
SEA TRANSPORT NOTES
acetone
UN No., AIR
UN1090
ICAO CLASS
3
AIR PACK GR.
II
AIR TRANSPORT NOTES
acetone
15. REGULATORY INFORMATION
5 /7
Page 118 of 320
10019 - CAT LIQUID GASKET-A
US FEDERAL REGULATIONS
COMPONENT
SARA 302 CERCLA
SARA 313
ACETONE
No
5 000 lbs
No
2-PROPENENITRILE, POLYMER WITH 1,3-BUTADIENE
IRON OXIDE (Fe2O3)
DIPHENYLAMINE
No
No
No
No
No
No
No
No
Yes
See Section 2 for Addtional Information
CLEAN AIR ACT
SARA HAZARD CATEGORIES
Acute Chronic Fire
US STATE REGULATIONS
*STATE REGULATORY STATUS
CALIFORNIA PROPOSITION 65: This product ***DOES NOT*** contain chemicals
considered by the State of California's Safe Drinking Water and Toxic Enforcement Act
of 1986 as causing cancer or reproductive toxicity, and for which warnings are now
required.
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM - WHMIS
This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations and the MSDS contains all the information required
by the Controlled Products Regulations.
LABEL(S) FOR SUPPLY
CONTROLLED PRODUCT
CLASSIFICATION
B2 - Flammable Liquids
D2B - Chronic Toxic Material
Risk phrases
R-11 Highly flammable.
R-36 Irritating to eyes.
R-66 Repeated exposure may cause skin dryness or cracking.
R-67 Vapours may cause drowsiness and dizziness.
COMPONENT
ACETONE
2-PROPENENITRILE, POLYMER WITH
1,3-BUTADIENE
IRON OXIDE (Fe2O3)
DIPHENYLAMINE
GLOBAL INVENTORIES
CAN
US
DSL
Yes
DSL
Yes
DSL
DSL
Yes
Yes
EU
EINECS
Polymer
AUS
Yes
No
JAP
Yes
No
KOR PHLP CHN
Yes Yes Yes
No
No
No
EINECS
EINECS
No
Yes
Yes
Yes
Yes
Yes
Yes
Yes
No
Yes
TSCA 12(b) Export Notification
Yes
COMPONENT
DIPHENYLAMINE
6 /7
Page 119 of 320
10019 - CAT LIQUID GASKET-A
CANADA CEPA: All components of this product comply with new substance
notification requirements under the Canadian Environmental Protection Act (CEPA).
TSCA 12(b) NOTICE: This product contains one or more components that require
reporting under TSCA Section 12(b) when exported. This product may be subject to
US EPA requirement for one-time export notification per country. Contact the
Regulatory Compliance Manager for more information.
16. OTHER INFORMATION
NFPA-HMIS HAZARD RATING
HEALTH
Irritation, minor residual injury (1) - HMIS/NFPA
FLAMMABILITY
Ignites easily (3) - HMIS/NFPA
REACTIVITY
Normally Stable (0) - HMIS/NFPA
PERSONAL PROTECTION INDEX
B - Safety Eyewear and Gloves
*REVISION COMMENTS
Section 1: Name Change
PREPARED BY
John Dingess
James P. McBriarty
Replacement of MSDS generated
2008-10-08
*DATE
2008-11-06
PRINTING DATE:
2008-11-06
DISCLAIMER
While the information and recommendations set forth herein are believed to be
accurate as of the date thereof, the company makes no warranty with respect thereto
and disclaims all liability from reliance therein.
* Information revised since previous MSDS version
7 /7
Page 120 of 320
Material Safety Data Sheet
CAT MINERAL SPIRITS
1. Product and company identification
Supplier
Material uses
: Chemtool Incorporated
801 West Rockton Road
Rockton, IL 61072 U.S.A.
Tel: +01 815.957.4140
Fax: +01 815.624.0292
: Industrial applications: Solvent. Cleaning agent for machinery and equipment.
Product code
: 8499000000
MSDS #
: 1148
Validation date
: 2/6/2014.
In case of emergency
: INFOTRAC
U.S. and Canada - 800.535.5053
Outside the U.S. and Canada - +1 352.323.3500
2. Hazards identification
Emergency overview
Physical state
: Liquid [Clear.]
Color
: Colorless
Odor
: Hydrocarbon.
Signal word
: WARNING!
Hazard statements
: FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF SWALLOWED. MAY
CAUSE EYE AND SKIN IRRITATION.
: Use only with adequate ventilation. Keep away from heat, sparks and flame. Keep
container tightly closed.
: This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
: Dermal contact. Eye contact. Inhalation. Ingestion.
Precautionary measures
OSHA/HCS status
Routes of entry
Potential acute health effects
Inhalation
: Inhalation of high concentrations of vapor may affect the central nervous system.
Ingestion
: Aspiration hazard if swallowed. Can enter lungs and cause damage.
Skin
: May cause skin irritation. Repeated exposure may cause skin dryness or cracking.
Eyes
: May cause eye irritation.
Potential chronic health effects
Validated on 2/6/2014.
1/13
Page 121 of 320
MSDS # : 1148
2. Hazards identification
Chronic effects
: No known significant effects or critical hazards.
Carcinogenicity
: No known significant effects or critical hazards.
Mutagenicity
: No known significant effects or critical hazards.
Teratogenicity
: No known significant effects or critical hazards.
Developmental effects
: No known significant effects or critical hazards.
Fertility effects
: No known significant effects or critical hazards.
Over-exposure signs/symptoms
Inhalation
: No specific data.
Ingestion
: No specific data.
Skin
: No specific data.
Eyes
: No specific data.
Medical conditions
aggravated by overexposure
: None known.
See toxicological information (Section 11)
3. Composition/information on ingredients
United States
Name
CAS number
%
Solvent naphtha (petroleum), medium aliph.
64742-88-7
~100.0
Name
CAS number
%
Solvent naphtha (petroleum), medium aliph.
64742-88-7
~100.0
Canada
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
Protection of first-aiders
Validated on 2/6/2014.
: Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
attention immediately.
: In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. Clean
shoes thoroughly before reuse. Get medical attention immediately.
: Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.
: Wash out mouth with water. Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical
attention immediately.
: No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
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4. First aid measures
Notes to physician
: No specific treatment. Treat symptomatically. Contact poison treatment specialist
immediately if large quantities have been ingested or inhaled.
5. Fire-fighting measures
Flammability of the product
: Flammable liquid. In a fire or if heated, a pressure increase will occur and the container
may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air
and will spread along the ground. Vapors may accumulate in low or confined areas or
travel a considerable distance to a source of ignition and flash back. Runoff to sewer
may create fire or explosion hazard.
Extinguishing media
Suitable
Not suitable
Special exposure hazards
Hazardous thermal
decomposition products
Special protective
equipment for fire-fighters
: Use dry chemical, CO₂, water spray (fog) or foam.
: Do not use water jet.
: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
: No specific data.
: Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
6. Accidental release measures
Personal precautions
Environmental precautions
: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment (see Section 8).
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods for cleaning up
Small spill
Large spill
Validated on 2/6/2014.
: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
3/13
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7. Handling and storage
Handling
Storage
: Put on appropriate personal protective equipment (see Section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and smoking.
Remove contaminated clothing and protective equipment before entering eating areas.
Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist.
Use only with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately
ventilated. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Store and use away from heat,
sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use non-sparking tools. Take
precautionary measures against electrostatic discharges. To avoid fire or explosion,
dissipate static electricity during transfer by grounding and bonding containers and
equipment before transferring material. Empty containers retain product residue and
can be hazardous. Do not reuse container.
: Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
8. Exposure controls/personal protection
United States
Ingredient
Exposure limits
Solvent naphtha (petroleum), medium aliph.
OSHA PEL 1989 (United States, 3/1989).
TWA: 100 ppm 8 hours.
TWA: 400 mg/m³ 8 hours.
OSHA PEL (United States, 2/2013).
TWA: 100 ppm 8 hours.
TWA: 400 mg/m³ 8 hours.
Canada
Occupational exposure limits
TWA (8 hours)
STEL (15 mins)
Ceiling
Ingredient
List name
ppm
mg/
m³
Other
ppm
mg/
m³
Other
ppm
mg/
m³
Other
Solvent naphtha (petroleum),
medium aliph.
QC 12/2012
400
1590
-
-
-
-
-
-
-
Notations
Mexico
Occupational exposure limits
No exposure limit value known.
Consult local authorities for acceptable exposure limits.
Validated on 2/6/2014.
4/13
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MSDS # : 1148
8. Exposure controls/personal protection
Recommended monitoring
procedures
Engineering measures
Hygiene measures
: If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Personal protection
Respiratory
Hands
Eyes
Skin
Environmental exposure
controls
: Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
: Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts. If contact is possible, the following protection should be worn, unless the
assessment indicates a higher degree of protection: safety glasses with side-shields.
: Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
When there is a risk of ignition from static electricity, wear anti-static protective clothing.
For the greatest protection from static discharges, clothing should include anti-static
overalls, boots and gloves.
: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
9. Physical and chemical properties
Physical state
: Liquid [Clear.]
Flash point
: Closed cup: 41°C (105.8°F) [Pensky-Martens.]
Auto-ignition temperature
: 316°C (600.8°F)
Flammable limits
: Lower: 1%
Upper: 7%
: Colorless
Color
Validated on 2/6/2014.
5/13
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MSDS # : 1148
9. Physical and chemical properties
Odor
: Hydrocarbon.
pH
: Not applicable.
Boiling/condensation point
: 179°C (354.2°F)
Melting/freezing point
: Not available.
Density
Vapor pressure
: 0.77 to 0.79 g/cm³
: 0.067 kPa (0.5 mm Hg) [room temperature]
Vapor density
: 5.48 [Air = 1]
Volatility
: Not available.
Evaporation rate
: 151 (ether (anhydrous) = 1)
Viscosity
: Kinematic (40°C (104°F)): <0.02 cm2/s (<2 cSt)
Dispersibility properties
: Not available.
Solubility
: Insoluble in the following materials: cold water.
10. Stability and reactivity
Chemical stability
: The product is stable.
Conditions to avoid
: Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
: Reactive or incompatible with the following materials:
oxidizing materials
: Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
Incompatible materials
Hazardous decomposition
products
Possibility of hazardous
reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
11. Toxicological information
United States
Acute toxicity
Conclusion/Summary
: Aspiration hazard if swallowed. Can enter lungs and cause damage.
Chronic toxicity
Conclusion/Summary
: Inhalation of high concentrations of vapor may affect the central nervous system.
Irritation/Corrosion
Conclusion/Summary
Skin
Eyes
Respiratory
: May cause skin irritation. Prolonged or repeated contact can defat the skin and lead to
irritation, cracking and/or dermatitis.
: May cause eye irritation.
: Repeated or prolonged inhalation of vapors may lead to chronic respiratory irritation.
May be harmful if inhaled. Pre-existing respiratory disorders may be aggravated by overexposure to this product.
Sensitizer
Conclusion/Summary
Skin
Respiratory
Validated on 2/6/2014.
: No specific information is available in our database regarding the skin sensitizing
properties of this product. Sensitization not suspected for humans.
: Sensitization not suspected for humans.
6/13
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11. Toxicological information
Carcinogenicity
Conclusion/Summary
: No known effect according to our database. Carcinogenicity not suspected for humans.
Mutagenicity
Conclusion/Summary
: No known effect according to our database. Mutagenicity not suspected for humans.
Teratogenicity
Conclusion/Summary
: No known effect according to our database. Teratogenicity not suspected for humans.
Reproductive toxicity
Conclusion/Summary
: Not considered to be dangerous to humans, according to our database.
Canada
Acute toxicity
Conclusion/Summary
: Aspiration hazard if swallowed. Can enter lungs and cause damage.
Chronic toxicity
Conclusion/Summary
: Inhalation of high concentrations of vapor may affect the central nervous system.
Irritation/Corrosion
Conclusion/Summary
Skin
Eyes
Respiratory
: May cause skin irritation. Prolonged or repeated contact can defat the skin and lead to
irritation, cracking and/or dermatitis.
: May cause eye irritation.
: Repeated or prolonged inhalation of vapors may lead to chronic respiratory irritation.
May be harmful if inhaled. Pre-existing respiratory disorders may be aggravated by overexposure to this product.
Sensitizer
Conclusion/Summary
Skin
Respiratory
: No specific information is available in our database regarding the skin sensitizing
properties of this product. Sensitization not suspected for humans.
: Sensitization not suspected for humans.
Carcinogenicity
Conclusion/Summary
: No known effect according to our database. Carcinogenicity not suspected for humans.
Mutagenicity
Conclusion/Summary
: No known effect according to our database. Mutagenicity not suspected for humans.
Teratogenicity
Conclusion/Summary
: No known effect according to our database. Teratogenicity not suspected for humans.
Reproductive toxicity
Conclusion/Summary
: Not considered to be dangerous to humans, according to our database.
Mexico
Acute toxicity
Conclusion/Summary
: Aspiration hazard if swallowed. Can enter lungs and cause damage.
Chronic toxicity
Conclusion/Summary
: Inhalation of high concentrations of vapor may affect the central nervous system.
Irritation/Corrosion
Conclusion/Summary
Skin
Validated on 2/6/2014.
: May cause skin irritation. Prolonged or repeated contact can defat the skin and lead to
irritation, cracking and/or dermatitis.
7/13
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11. Toxicological information
Eyes
: May cause eye irritation.
Respiratory
: Repeated or prolonged inhalation of vapors may lead to chronic respiratory irritation.
May be harmful if inhaled. Pre-existing respiratory disorders may be aggravated by overexposure to this product.
Sensitizer
Conclusion/Summary
Skin
Respiratory
: No specific information is available in our database regarding the skin sensitizing
properties of this product. Sensitization not suspected for humans.
: Sensitization not suspected for humans.
Carcinogenicity
Conclusion/Summary
: No known effect according to our database. Carcinogenicity not suspected for humans.
Mutagenicity
Conclusion/Summary
: No known effect according to our database. Mutagenicity not suspected for humans.
Teratogenicity
Conclusion/Summary
: No known effect according to our database. Teratogenicity not suspected for humans.
Reproductive toxicity
Conclusion/Summary
: Not considered to be dangerous to humans, according to our database.
12. Ecological information
Ecotoxicity
: No known significant effects or critical hazards.
United States
Aquatic ecotoxicity
Conclusion/Summary
: There are no data available on the mixture itself.
Persistence/degradability
Conclusion/Summary
: This product has not been tested for biodegradation. This product shows a high
bioaccumulation potential.
Canada
Aquatic ecotoxicity
Conclusion/Summary
: There are no data available on the mixture itself.
Persistence/degradability
Conclusion/Summary
: This product has not been tested for biodegradation. This product shows a high
bioaccumulation potential.
Mexico
Aquatic ecotoxicity
Conclusion/Summary
: There are no data available on the mixture itself.
Persistence/degradability
Conclusion/Summary
Validated on 2/6/2014.
: This product has not been tested for biodegradation. This product shows a high
bioaccumulation potential.
8/13
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MSDS # : 1148
13. Disposal considerations
Waste disposal
: The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
: D001 [Ignitable materials]
RCRA classification
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.
14. Transport information
Regulatory
information
UN number
Proper shipping
name
Classes
PG* Label
Additional
information
DOT Classification
UN1268
Petroleum distillates,
n.o.s.
3
III
This product may be
re-classified as
"Combustible Liquid,"
unless transported by
vessel or aircraft.
Non-bulk packages
(less than or equal to
119 gal) of
combustible liquids
are not regulated as
hazardous materials.
Limited quantity
Yes.
Packaging
instruction
Passenger aircraft
Quantity limitation: 60
L
Cargo aircraft
Quantity limitation:
220 L
Special provisions
B1, IB3, T4, TP1,
TP29
Validated on 2/6/2014.
9/13
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MSDS # : 1148
14. Transport information
TDG Classification
UN1268
PETROLEUM
3
DISTILLATES, N.O.S.
III
Explosive Limit and
Limited Quantity
Index
1
Passenger Carrying
Road or Rail Index
5
Mexico
Classification
UN1268
DESTILADOS DE
PETROLEO, N.E.P.
3
III
Special provisions
223
ADR/RID Class
UN1268
PETROLEUM
3
DISTILLATES, N.O.S.
III
Hazard identification
number
30
Limited quantity
5L
Special provisions
640 (E)
Tunnel code
(D/E)
IMDG Class
UN1268
PETROLEUM
3
DISTILLATES, N.O.S.
III
Emergency
schedules (EmS)
F-E, S-E
Special provisions
223, 955
IATA-DGR Class
UN1268
Petroleum distillates,
n.o.s.
3
III
Passenger and
Cargo Aircraft
Quantity limitation: 60
L
Packaging
instructions: 355
Cargo Aircraft Only
Quantity limitation:
220 L
Packaging
instructions: 366
Limited Quantities Passenger Aircraft
Quantity limitation: 10
L
Packaging
instructions: Y344
Special provisions
A3
Validated on 2/6/2014.
10/13
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MSDS # : 1148
14. Transport information
PG* : Packing group
15. Regulatory information
United States
HCS Classification
: Combustible liquid
U.S. Federal regulations
: TSCA 8(a) CDR Exempt/Partial exemption: All components are listed or exempted.
United States inventory (TSCA 8b): All components are listed or exempted.
SARA 302/304: No products were found.
SARA 311/312 Hazards identification: Fire hazard
Clean Air Act Section 112 : Not listed
(b) Hazardous Air
Pollutants (HAPs)
Clean Air Act Section 602
Class I Substances
: Not listed
Clean Air Act Section 602
Class II Substances
: Not listed
DEA List I Chemicals
(Precursor Chemicals)
: Not listed
DEA List II Chemicals
(Essential Chemicals)
: Not listed
SARA 313
Product name
Form R - Reporting
requirements
Supplier notification
:
No listed substance
:
No listed substance
CAS number
Concentration
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall
include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
State regulations
Connecticut Carcinogen Reporting
Connecticut Hazardous Material Survey
Florida substances
Illinois Chemical Safety Act
Illinois Toxic Substances Disclosure to Employee
Act
Louisiana Reporting
Louisiana Spill
Massachusetts Spill
Massachusetts Substances
Michigan Critical Material
Minnesota Hazardous Substances
New Jersey Spill
New Jersey Toxic Catastrophe Prevention Act
Validated on 2/6/2014.
:
:
:
:
:
None of the components are listed.
None of the components are listed.
None of the components are listed.
None of the components are listed.
None of the components are listed.
:
:
:
:
:
:
:
:
None of the components are listed.
None of the components are listed.
None of the components are listed.
None of the components are listed.
None of the components are listed.
None of the components are listed.
None of the components are listed.
None of the components are listed.
11/13
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MSDS # : 1148
15. Regulatory information
New Jersey Hazardous Substances
New York Acutely Hazardous Substances
New York Toxic Chemical Release Reporting
Pennsylvania RTK Hazardous Substances
Rhode Island Hazardous Substances
:
:
:
:
:
None of the components are listed.
None of the components are listed.
None of the components are listed.
None of the components are listed.
None of the components are listed.
California Prop. 65
None of the components are listed.
United States inventory
(TSCA 8b)
: All components are listed or exempted.
Canada
WHMIS (Canada)
: Class B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C
(200°F).
Canadian lists
Canadian NPRI
: The following components are listed: Solvent naphtha medium aliphatic
CEPA Toxic substances
: None of the components are listed.
Canada inventory; DSL/
NDSL
: All components are listed or exempted.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
Mexico
Classification
:
2
Health
1
Flammability
0
Reactivity
Special
International regulations
International lists
: Australia inventory (AICS): All components are listed or exempted.
China inventory (IECSC): All components are listed or exempted.
Japan inventory: Not determined.
Korea inventory: All components are listed or exempted.
Malaysia Inventory (EHS Register): All components are listed or exempted.
New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted.
Philippines inventory (PICCS): All components are listed or exempted.
Taiwan inventory (CSNN): Not determined.
Europe inventory : All components are listed or exempted.
Chemical Weapons
Convention List Schedule
I Chemicals
: Not listed
Chemical Weapons
Convention List Schedule
II Chemicals
: Not listed
Chemical Weapons
Convention List Schedule
III Chemicals
: Not listed
Validated on 2/6/2014.
12/13
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MSDS # : 1148
16. Other information
Label requirements
Hazardous Material
Information System (U.S.A.)
: FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF SWALLOWED. MAY
CAUSE EYE AND SKIN IRRITATION.
:
Health
1
Flammability
2
Physical hazards
0
C
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
National Fire Protection
Association (U.S.A.)
:
Flammability
2
Health
1
0
Instability/Reactivity
Special
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not
the complete and official position of the National Fire Protection Association, on the referenced subject which is
represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be
interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA
49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not,
anyone using the 704 systems to classify chemicals does so at their own risk.
Date of issue
Date of previous issue
: 2/6/2014.
Version
: 1.01
Prepared by
: Regulatory Department, Chemtool Inc.
: 2/6/2014.
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Validated on 2/6/2014.
13/13
Page 133 of 320
12447 - CAT RETAINING COMPOUND
Revision date
MATERIAL SAFETY DATA SHEET
CAT RETAINING COMPOUND
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
TRADE NAME
CAT RETAINING COMPOUND
PART No.
Chemtool, 842600, Caterpillar, 4C-9506, 4C-9507
SUPPLIER
Chemtool Incorporated
P.O. Box 538
8200 Ridgefield Road
Crystal Lake, IL 60039-0538 USA
Tel: (815) 459-1250
Fax: (815) 459-1955
EMERGENCY TELEPHONE
Rocky Mountain Poison Center Denver, Colorado
(800) 458-5924 U.S. and Canada.
(303) 893-1322 Outside U.S.
2. COMPOSITION, INFORMATION ON INGREDIENTS
INGREDIENT NAME
*2-PROPENOIC ACID, 2-METHYL-, OXYBIS(2,1-ETHANEDIYLOXY-2,1-ETHANEDIYL)
ESTER
*2-PROPENOIC ACID, 2-METHYL-, 2-HYDROXYETHYL ESTER
CAS No.
109-17-1
WEIGHT
40-60 %
868-77-9
10-20 %
* This chemical(s) is hazardous according to OSHA/WHIMIS criteria
*COMPOSITION COMMENTS
Refer to section eight for exposure limits on ingredients.
Chemical ingredients not regulated by OSHA or SARA are treated confidentially.
MSDS and Label were prepared for product use in United States and Canada except
Florida, Massachusetts, Michigan, New Jersey, Pennsylvania, and Rhode Island.
Contact Chemtool Regulatory Compliance Manager for documents for product use in
other states.
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes and skin. May cause sensitisation by skin contact.
INHALATION
No specific health warnings noted.
INGESTION
No specific health warnings noted.
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SKIN
Irritating to skin.
EYES
Irritating to eyes.
SENSITIZATION
May cause sensitization, an allergic reaction, which becomes evident on reexposure
to this chemical.
TERATOGENICITY
No known information.
HEALTH WARNINGS
EYE CONTACT. Irritating. SKIN CONTACT. Mild dermatitis, allergic skin rash.
ROUTE OF ENTRY
Skin and/or eye contact. Inhalation.
4. FIRST AID MEASURES
INHALATION
Remove victim immediately from source of exposure. Get medical attention if any
discomfort continues.
EYES
Important! Immediately rinse with water for at least 15 minutes. Get medical attention
if any discomfort continues.
SKIN
Immediately remove contaminated clothing. Wash skin thoroughly with soap and
water. Get medical attention if irritation persists after washing.
INGESTION
DO NOT induce vomiting. Get medical attention immediately. Do not give victim
anything to drink if he is unconscious.
5. FIRE FIGHTING MEASURES
FLASH POINT (°C)
99 (210 F) TCC (Tag closed cup).
FLAMMABILITY LIMIT - LOWER(%)
N/D
FLAMMABILITY LIMIT - UPPER(%)
N/D
EXTINGUISHING MEDIA
Use: Carbon dioxide (CO2). Foam. Dry chemicals.
SPECIAL FIRE FIGHTING
PROCEDURES
Use water to keep fire exposed containers cool and disperse vapors. Water spray
may be used to flush spills away from exposures and dilute spills to non-flammable
mixtures. Avoid water in straight hose stream; will scatter and spread fire. Keep run-off
water out of sewers and water sources. Dike for water control.
HAZARDOUS COMBUSTION
PRODUCTS
Irritating gases/vapors/fumes. Oxides of: Carbon. Nitrogen.
6. ACCIDENTAL RELEASE MEASURES
SPILL CLEAN-UP PROCEDURES
Carefully collect spilled material in closed containers and leave for disposal
according to local regulations. Provide good ventilation. Use appropriate protective
clothing. Rinse area with water. Do not let washing down water contaminate ponds or
waterways.
7. HANDLING AND STORAGE
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HANDLING PRECAUTIONS
Keep away from heat, sparks and open flame. Provide good ventilation. Containers to
be kept tightly closed. Avoid spilling, skin and eye contact.
STORAGE PRECAUTIONS
Keep away from heat, sparks and open flame. Store below 75°F. Store isolated from
oxidizing materials.
STORAGE CRITERIA
Chemical storage.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
PROTECTIVE EQUIPMENT
VENTILATION
No specific ventilation requirements noted, but forced ventilation may still be required
if air contamination exceeds acceptable level.
RESPIRATORS
No specific recommendation made, but respiratory protection may still be required
under exceptional circumstances when excessive air contamination exists.
PROTECTIVE GLOVES
For prolonged or repeated skin contact use suitable protective gloves.
EYE PROTECTION
Use eye protection.
PROTECTIVE CLOTHING
Wear appropriate clothing to prevent repeated or prolonged skin contact.
HYGIENIC WORK PRACTICES
Wash at the end of each work shift and before eating, smoking and using the toilet.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE/PHYSICAL STATE
Liquid.
COLOR
Green.
ODOR
Mild (or faint).
SOLUBILITY DESCRIPTION
Slightly soluble in water.
BOILING POINT (°C, range)
> 149
MELT./FREEZ. POINT (°C, interval)
N/D
DENSITY
1.1
VAPOR DENSITY (air=1)
N/D
VAPOR PRESSURE
EVAPORATION RATE
Pressure
760mmHg
Temperature (°C)
20
< 5 mmHg
Temperature (°C)
25 (77 F)
N/D
Reference
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10. STABILITY AND REACTIVITY
STABILITY
Normally stable.
CONDITIONS TO AVOID
Avoid contact with acids and oxidizing substances.
HAZARDOUS POLYMERIZATION
Will not polymerize.
HAZARDOUS DECOMPOSITION
PRODUCTS
No specific hazardous decomposition products noted.
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION
No experimental toxicological data on the preparation as such is available.
TOXICOLOGICAL DATA
TOXIC DOSE - LD 50
TOXIC DOSE - LD 50 SKIN
TOXIC CONC. - LC 50
2-PROPENOIC ACID, 2-METHYL-, OXYBIS(2,1-ETHANEDIYLOXY-2,1-ETHANEDIYL)
ESTER
Chronic toxicity. WHMIS: D2B
> 10000 est. mg/kg (oral rat)
> 5000 est. mg/kg (skn rbt)
N/A.
COMPONENT
2-PROPENOIC ACID, 2-METHYL-, 2-HYDROXYETHYL ESTER
TOXICOLOGICAL DATA
TOXIC DOSE - LD 50
TOXIC CONC. - LC 50
Chronic toxicity. WHMIS: D2B
5050 mg/kg (oral rat)
N/A.
COMPONENT
12. ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION
No data on possible environmental effects have been found.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHODS
Dispose of in accordance with Local Authority requirements. Confirm disposal
procedures with environmental engineer and local regulations.
14. TRANSPORT INFORMATION
DOT HAZARD CLASS
Non-Hazardous (No label required).
*TDGR CLASS
Not Regulated. Non réglementé.
SEA TRANSPORT NOTES
Not regulated per IMDG.
AIR TRANSPORT NOTES
Not regulated per IATA.
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15. REGULATORY INFORMATION
US FEDERAL REGULATIONS: COMPONENT
SARA 302 CERCLA
SARA 313
2-PROPENOIC ACID, 2-METHYL-, OXYBIS(2,1-ETHANEDIYLOXY-2,1-ETHANEDIYL)
ESTER
2-PROPENOIC ACID, 2-METHYL-, 2-HYDROXYETHYL ESTER
No
No
No
No
No
No
*SARA HAZARD CATEGORIES
Acute Chronic
STATE REGULATORY STATUS
PROPOSITION 65: This product ***DOES NOT*** contain chemicals considered by
the State of California's Safe Drinking Water and Toxic Enforcement Act of 1986 as
causing cancer or reproductive toxicity, and for which warnings are now required.
*WORKPLACE HAZARDOUS
MATERIALS INFORMATION SYSTEM WHMIS
This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations and the MSDS contains all the information required
by the Controlled Products Regulations.
*CONTROLLED PRODUCT
CLASSIFICATION
D2B - Chronic Toxic Material
INVENTORIES: COMPONENT
2-PROPENOIC ACID, 2-METHYL-,
2-HYDROXYETHYL ESTER
2-PROPENOIC ACID, 2-METHYL-,
OXYBIS(2,1-ETHANEDIYLOXY-2,1-ETHANEDIYL)
ESTER
*
CAN
DSL
US
Yes
EU
EINECS
AUS
JAP
KOR CHN
PHLP
DSL
Yes
EINECS
Yes
Yes
Yes
Yes
Yes
All components of this product comply with new substance notification requirements
under the Canadian Environmental Protection Act (CEPA).
16. OTHER INFORMATION
HEALTH
Temporary incapacitation, injury (2) - HMIS/NFPA
FLAMMABILITY
Burns only if pre-heated (1) - HMIS/NFPA
REACTIVITY
Normally Stable (0) - HMIS/NFPA
*NPCA HMIS PERS. PROTECT. INDEX
B - Safety Eyewear and Gloves
PREPARED BY
James W. Hermann
*Replacement MSDS of
2005-03-22
*DATE
2008-04-25
PRINTING DATE:
2008-04-25
DISCLAIMER
While the information and recommendations set forth herein are believed to be
accurate as of the date thereof, Chemtool Incorporated makes no warranty with
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respect thereto and disclaims all liability from reliance therein.
6 /6
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CIGWELD Arcair DC Gouging Carbons
Hazard Alert Code: MODERATE
Chemwatch Material Safety Data Sheet
Issue Date: 5-Dec-2011
X9317SP
CHEMWATCH 17929
Version No:6.1.1.1
Page 1 of 9
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
CIGWELD Arcair DC Gouging Carbons
SYNONYMS
"22043003C, 22053003C, 22063003C, 22082003C DC Carbon Cutting and Gouging Electrodes"
PRODUCT NUMBERS
22043003, 22053003, 22063003, 24104003, 24124003, 35033003, 22155006, 22043003C, 22053003C, 22063003C, 22082003C
PRODUCT USE
Copper coated carbon electrodes for air arc cutting and gouging of steel plate
and non-oxidising metals using Direct Current Electrode Positive (DCEP) and
Direct Current Electrode Negative (DCEN).
SUPPLIER
Company: Cigweld Pty Ltd
Address:
71 Gower Street
Preston
VIC, 3072
Australia
Telephone: +61 3 9474 7400
Telephone: +1 1300 654 674
Emergency Tel:+61 3 9474 7400
Email: [email protected]
Website: http://www.cigweld.com.au/
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code.
CHEMWATCH HAZARD RATINGS
Flammability
Toxicity
Body Contact
Reactivity
Chronic
SCALE:
RISK
■ Harmful by inhalation.
Min/Nil=0
Low=1
Moderate=2
High=3
Extreme=4
SAFETY
• Avoid contact with skin.
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Hazard Alert Code: MODERATE
Chemwatch Material Safety Data Sheet
Issue Date: 5-Dec-2011
X9317SP
■ Limited evidence of a
carcinogenic effect.
■ Cumulative effects may result
following exposure*.
■ May produce discomfort of the
respiratory system*.
■ Possible respiratory
sensitiser*.
* (limited evidence).
CHEMWATCH 17929
Version No:6.1.1.1
Page 2 of 9
Section 2 - HAZARDS IDENTIFICATION
• Wear suitable protective clothing.
• Wear suitable gloves.
• Use only in well ventilated areas.
• Keep container in a well ventilated place.
• To clean the floor and all objects contaminated by this
material, use water and detergent.
• Keep away from food, drink and animal feeding stuffs.
• If swallowed, IMMEDIATELY contact Doctor or Poisons
Information Centre. (show this container or label).
• In case of accident by inhalation: remove casualty to fresh
air and keep at rest.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME
copper coated carbon rod
upon use generates
welding fumes
as
iron oxide fume
copper fume
action of arc on air may generate
ozone
nitrogen oxides
CAS RN
%
Not avail.
>60
1309-37-1.
7440-50-8.
10028-15-6
Mixture
Section 4 - FIRST AID MEASURES
SWALLOWED
• Not considered a normal route of entry.
EYE
• Particulate bodies from welding spatter may be removed carefully.
• DO NOT attempt to remove particles attached to or embedded in eye.
• Lay victim down, on stretcher if available and pad BOTH eyes, make sure dressing does not press on the injured eye by placing
thick pads under dressing, above and below the eye.
• Seek urgent medical assistance, or transport to hospital.
• For "arc eye", i.e. welding flash or UV light burns to the eye:
• Place eye pads or light clean dressings over both eyes.
• Seek medical assistance.
SKIN
■ If skin or hair contact occurs:
• Flush skin and hair with running water (and soap if available).
• Seek medical attention in event of irritation.
INHALED
• If fumes or combustion products are inhaled remove from contaminated area.
• Lay patient down. Keep warm and rested.
• Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid
procedures.
• Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket
mask as trained. Perform CPR if necessary.
NOTES TO PHYSICIAN
Copper, magnesium, aluminium, antimony, iron, manganese, nickel, zinc (and their compounds) in welding, brazing, galvanising or
smelting operations all give rise to thermally produced particulates of smaller dimension than may be produced if the metals are
divided mechanically. Where insufficient ventilation or respiratory protection is available these particulates may produce "metal
fume fever" in workers from an acute or long term exposure.
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Hazard Alert Code: MODERATE
Chemwatch Material Safety Data Sheet
Issue Date: 5-Dec-2011
X9317SP
CHEMWATCH 17929
Version No:6.1.1.1
Page 3 of 9
Section 4 - FIRST AID MEASURES
• Onset occurs in 4-6 hours generally on the evening following exposure. Tolerance develops in workers but may be lost over the
weekend. (Monday Morning Fever)
• Pulmonary function tests may indicate reduced lung volumes, small airway obstruction and decreased carbon monoxide diffusing
capacity but these abnormalities resolve after several months.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
• There is no restriction on the type of extinguisher which may be used.
FIRE FIGHTING
• Alert Fire Brigade and tell them location and nature of hazard.
• Wear breathing apparatus plus protective gloves in the event of a fire.
• Prevent, by any means available, spillage from entering drains or water courses.
• Use fire fighting procedures suitable for surrounding area.
FIRE/EXPLOSION HAZARD
• Non combustible.
• Not considered to be a significant fire risk, however containers may burn.
• In a fire may decompose on heating and produce toxic / corrosive fumes.
FIRE INCOMPATIBILITY
■ Welding electrodes should not be allowed to come into contact with strong acids or other substances which are corrosive to
metals.
Welding arc and metal sparks can ignite combustibles.
HAZCHEM
None
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
Clean up all spills immediately.
Avoid contact with skin and eyes.
Wear impervious gloves and safety glasses.
Use dry clean up procedures and avoid generating dust.
Place in suitable containers for disposal.
MAJOR SPILLS
Minor hazard.
• Clear area of personnel.
• Alert Fire Brigade and tell them location and nature of hazard.
• Control personal contact with the substance, by using protective equipment if risk of overexposure exists.
• Prevent, by any means available, spillage from entering drains or water courses.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
■ Earth all lines and equipment.
• Limit all unnecessary personal contact.
• Wear protective clothing when risk of exposure occurs.
• Use in a well-ventilated area.
• Avoid contact with incompatible materials.
SUITABLE CONTAINER
No restriction on the type of containers.
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Hazard Alert Code: MODERATE
Chemwatch Material Safety Data Sheet
Issue Date: 5-Dec-2011
X9317SP
CHEMWATCH 17929
Version No:6.1.1.1
Page 4 of 9
Section 7 - HANDLING AND STORAGE
• Check that containers are clearly labelled.
STORAGE INCOMPATIBILITY
Avoid storage with oxidisers and strong acids.
STORAGE REQUIREMENTS
• Keep dry.
• Store under cover.
• Protect containers against physical damage.
• Observe manufacturer's storage and handling recommendations contained within this MSDS.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source
Material
__________
Australia
Exposure
Standards
__________
ozone (Ozone)
TWA
ppm
______
0.1
TWA
mg/m³
______
STEL
ppm
______
STEL
mg/m³
______
Peak
ppm
______
Peak
mg/m³
______
TWA
F/CC
______
Notes
______
MATERIAL DATA
NITROGEN OXIDES:
WELDING FUMES:
For nitric oxide:
Odour Threshold: 0.3 to 1 ppm.
NOTE: Detector tubes for nitrogen oxide, measuring in excess of 10 ppm, are commercially available.<</>.
OZONE:
WELDING FUMES:
for ozone:
NOTE: Detector tubes for ozone, measuring in excess of 0.05 ppm, are commercially available.
Exposure at 0.2 ppm appears to produce mild acute but not cumulative effects.
CIGWELD ARCAIR DC GOUGING CARBONS:
None assigned. Refer to individual constituents.
WELDING FUMES:
In addition to complying with any individual exposure standards for specific contaminants, where current manual welding
processes are used, the fume concentration inside the welder's helmet should not exceed 5 mg/m3, when collected in accordance
with the appropriate standard (AS 3640, for example).
ES* TWA: 5 mg/m3
TLV* TWA: 5 mg/m3, B2 (a substance of variable composition)
OES* TWA: 5 mg/m3
Most welding, even with primitive ventilation, does not produce exposures inside the welding helmet above 5 mg/m3.
During use the gases nitric oxide, nitrogen peroxide and ozone may be produced by the consumption of the electrode or the
action of the welding arc on the atmosphere.
NOTE: Detector tubes for carbon monoxide, measuring in excess of 2 ppm, are commercially available for detection of carbon
monoxide.
200 ppm carbon monoxide in air will produce headache, mental dullness and dizziness in a few hours; 600 ppm will produce
identical symptoms in less than half and hour and may produce unconsciousness in 1.5 hours; 4000 ppm is fatal in less than an
hour.<</>.
IRON OXIDE FUME:
For iron oxide (ferric oxide):
Inhalation of iron oxide dust or fume may produce a benign pneumoconiosis (siderosis). The TLV-TWA is recommended to minimise
the potential for development of X-ray changes in the lung on long-term exposure.
NITROGEN OXIDES:
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Hazard Alert Code: MODERATE
Chemwatch Material Safety Data Sheet
Issue Date: 5-Dec-2011
X9317SP
CHEMWATCH 17929
Version No:6.1.1.1
Page 5 of 9
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
For nitrous oxide:
The human reproductive, haematologic and nervous systems show toxic effects after nitrous oxide exposures. Similarities
between epidemiologic and animal studies allow the establishment of a TLV-TWA even in the absence of clearly defined doseresponse relationships in humans.
for nitrogen dioxide
Odour Threshold Value: 0.11-0.14 ppm
NOTE: Detector tubes for nitrogen dioxide, measuring in excess of 0.5 ppm, are commercially available.
The TLV-TWA is considered to be sufficiently low to reduce the potential for immediate injury or adverse physiological effects
from prolonged daily exposures.
Short exposures of workmen to nitrogen dioxide concentrations averaging 25 to 38 ppm resulted in observable physiological
response, but exposures of 3 to 5 minutes at 80 ppm produced tightness of the chest.
PERSONAL PROTECTION
RESPIRATOR
•Type NO Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)
EYE
■ Welding helmet with suitable filter. Welding hand shield with suitable filter.
• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,
describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a
review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and
first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of
chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at
the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed
hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent].
For most open welding/brazing operations, goggles, even with appropriate filters, will not afford sufficient facial protection
for operators. Where possible use welding helmets or handshields corresponding to AS 1336 and AS 1338 which provide the maximum
possible facial protection from flying particles and fragments.
HANDS/FEET
■ Welding Gloves
Safety footwear.
OTHER
■ Overalls.
• Eyewash unit.
Aprons, sleeves, shoulder covers, leggings or spats of pliable flame resistant leather or other suitable materials may also be
required in positions where these areas of the body will encounter hot metal.
ENGINEERING CONTROLS
■ For manual arc welding operations the nature of ventilation is determined by the location of the work.
• For outdoor work, natural ventilation is generally sufficient.
• For indoor work, conducted in open spaces, use mechanical (general exhaust or plenum) ventilation. (Open work spaces exceed 300
cubic metres per welder)
• For work conducted in limited or confined spaces, mechanical ventilation, using local exhaust systems, is required. (In
confined spaces always check that oxygen has not been depleted by excessive rusting of steel or snowflake corrosion of
aluminium)
Mechanical or local exhaust ventilation may not be required where the process working time does not exceed 24 mins.
If risk of inhalation or overexposure exists, wear SAA approved respirator or work in fume hood.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Carbon electrode with copper coating.
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CIGWELD Arcair DC Gouging Carbons
Hazard Alert Code: MODERATE
Chemwatch Material Safety Data Sheet
Issue Date: 5-Dec-2011
X9317SP
CHEMWATCH 17929
Version No:6.1.1.1
Page 6 of 9
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
Does not mix with water.
Sinks in water.
State
Melting Range (°C)
Boiling Range (°C)
Flash Point (°C)
Decomposition Temp (°C)
Autoignition Temp (°C)
Upper Explosive Limit (%)
Lower Explosive Limit (%)
Manufactured
Not available
Not applicable
Not applicable
Not available
Not available
Not available
Not available
Volatile Component (%vol)
Negligible
Molecular Weight
Viscosity
Solubility in water (g/L)
pH (1% solution)
pH (as supplied)
Vapour Pressure (kPa)
Specific Gravity (water=1)
Relative Vapour Density
(air=1)
Evaporation Rate
Not applicable
Not Applicable
Immiscible
Not applicable
Not applicable
Not Applicable
2.0 (bulk)
Not available
Not applicable
Section 10 - STABILITY AND REACTIVITY
CONDITIONS CONTRIBUTING TO INSTABILITY
• Presence of incompatible materials.
• Product is considered stable.
• Hazardous polymerisation will not occur.
For incompatible materials - refer to Section 7 - Handling and Storage.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
■ Not normally a hazard due to physical form of product.
EYE
■ Fumes from welding/brazing operations may be irritating to the eyes.
Arc rays can injure eyes.
SKIN
■ Not normally a hazard due to physical form of product.
Arc rays can burn skin.
INHALED
■ Fumes evolved during welding operations may be irritating to the upper-respiratory tract and may be harmful if inhaled.
Persons with impaired respiratory function, airway diseases and conditions such as emphysema or chronic bronchitis, may incur
further disability if excessive concentrations of particulate are inhaled.
If prior damage to the circulatory or nervous systems has occurred or if kidney damage has been sustained, proper screenings
should be conducted on individuals who may be exposed to further risk if handling and use of the material result
in excessive exposures.
Copper poisoning following exposure to copper dusts and fume may result in headache, cold sweat and weak pulse. Capillary, kidney,
liver and brain damage are the longer term manifestations of such poisoning.
Harmful levels of ozone may be found when working in confined spaces. Symptoms of exposure include irritation of the upper
membranes of the respiratory tract and lungs as well as pulmonary (lung) changes including irritation, accumulation of fluid
(congestion and oedema) and in some cases haemorrhage.
CHRONIC HEALTH EFFECTS
■ Principal route of exposure is inhalation of welding fumes from electrodes and workpiece. Reaction products arising from
electrode core and flux appear as welding fume depending on welding conditions, relative volatilities of metal oxides and any
coatings on the workpiece.
Welding fume with high levels of ferrous materials may lead to particle deposition in the lungs (siderosis) after long exposure.
This clears up when exposure stops.
Ozone is suspected to produce lung cancer in laboratory animals; no reports of this effect have been documented in exposed human
populations.
Other welding process exposures can arise from radiant energy UV flash burns, thermal burns or electric shock
continued...
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CIGWELD Arcair DC Gouging Carbons
Hazard Alert Code: MODERATE
Chemwatch Material Safety Data Sheet
Issue Date: 5-Dec-2011
X9317SP
CHEMWATCH 17929
Version No:6.1.1.1
Page 7 of 9
Section 11 - TOXICOLOGICAL INFORMATION
The welding arc emits ultraviolet radiation at wavelengths that have the potential to produce skin tumours in animals and in overexposed individuals, however, no confirmatory studies of this effect in welders have been reported.
TOXICITY AND IRRITATION
■ Not available. Refer to individual constituents.
CARCINOGEN
iron oxide fume
International Agency for
Research on Cancer (IARC) Agents Reviewed by the IARC
Monographs
Group
3
Not classifiable as
to its
carcinogenicity to
humans
Section 12 - ECOLOGICAL INFORMATION
No data
Ecotoxicity
Ingredient
welding fumes
iron oxide fume
copper fume
ozone
nitrogen oxides
Persistence:
Water/Soil
No Data
Available
No Data
Available
No Data
Available
No Data
Available
No Data
Available
Persistence: Air
Bioaccumulation
Mobility
No Data
Available
No Data
Available
No Data
Available
No Data
Available
No Data
Available
No Data
Available
No Data
Available
LOW
No Data
Available
No Data
Available
No Data
Available
No Data
Available
No Data
Available
LOW
No Data
Available
Section 13 - DISPOSAL CONSIDERATIONS
• Recycle wherever possible or consult manufacturer for recycling options.
• Consult State Land Waste Management Authority for disposal.
• Bury residue in an authorised landfill.
• Recycle containers if possible, or dispose of in an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
HAZCHEM:
None (ADG7)
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: ADG7, IATA, IMDG
Section 15 - REGULATORY INFORMATION
Indications of Danger:
Xn Harmful
POISONS SCHEDULE
None
continued...
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CIGWELD Arcair DC Gouging Carbons
Hazard Alert Code: MODERATE
Chemwatch Material Safety Data Sheet
Issue Date: 5-Dec-2011
X9317SP
CHEMWATCH 17929
Version No:6.1.1.1
Page 8 of 9
Section 15 - REGULATORY INFORMATION
REGULATIONS
Regulations for ingredients
iron oxide fume (CAS: 1309-37-1) is found on the following regulatory lists;
"Australia - South Australia Controlled Substances (Poisons) Regulations - Schedule E: Schedule 2 poisons authorised to be sold
by holder of a medicine sellers licence", "Australia Exposure Standards", "Australia FAISD Handbook - First Aid Instructions,
Warning Statements, and General Safety Precautions", "Australia Hazardous Substances Information System - Consolidated Lists",
"Australia High Volume Industrial Chemical List (HVICL)", "Australia Inventory of Chemical Substances (AICS)", "Australia
Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 4", "Australia Standard for the Uniform
Scheduling of Medicines and Poisons (SUSMP) - Schedule 5", "Australia Standard for the Uniform Scheduling of Medicines and
Poisons (SUSMP) - Schedule 6", "FisherTransport Information", "International Agency for Research on Cancer (IARC) - Agents
Reviewed by the IARC Monographs", "International Council of Chemical Associations (ICCA) - High Production Volume List",
"International Numbering System for Food Additives", "OECD List of High Production Volume (HPV) Chemicals", "SigmaAldrichTransport Information"
copper fume (CAS: 7440-50-8) is found on the following regulatory lists;
"Acros Transport Information", "Australia - Australian Capital Territory - Environment Protection Regulation: Ambient
environmental standards (AQUA/1 to 6 - inorganic chemicals)", "Australia - Australian Capital Territory - Environment Protection
Regulation: Ambient environmental standards (Domestic water supply - inorganic chemicals)", "Australia - Australian Capital
Territory - Environment Protection Regulation: Ambient environmental standards (IRRIG - inorganic chemicals)", "Australia Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (STOCK - inorganic chemicals)",
"Australia - Australian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause
environmental harm - Domestic water supply quality", "Australia - Australian Capital Territory - Environment Protection
Regulation: Pollutants entering waterways taken to cause environmental harm (Aquatic habitat)", "Australia - Australian Capital
Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause environmental harm (IRRIG)",
"Australia - Australian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause
environmental harm (STOCK)", "Australia ADI list - Acceptable daily intakes for agricultural and veterinary chemicals",
"Australia Drinking Water Guideline Values For Physical and Chemical Characteristics", "Australia Exposure Standards", "Australia
Hazardous Substances Information System - Consolidated Lists", "Australia High Volume Industrial Chemical List (HVICL)",
"Australia Inventory of Chemical Substances (AICS)", "Australia National Environment Protection (Ambient Air Quality) Measure Schedule 1: Pollutants", "Australia National Environment Protection (Ambient Air Quality) Measure - Schedule 2 Table 1: Standards
and Goal for Pollutants other than Particles as PM2.5", "Australia National Pollutant Inventory", "Australia Standard for the
Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix A", "Australia Standard for the Uniform Scheduling of Medicines
and Poisons (SUSMP) - Schedule 4", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5",
"Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6", "IMDG Code - Substance Index",
"International Maritime Dangerous Goods Requirements (IMDG Code) - Marine Pollutants", "OECD List of High Production Volume (HPV)
Chemicals", "OSPAR National List of Candidates for Substitution – Norway", "Sigma-AldrichTransport Information", "United Nations
Consolidated List of Products Whose Consumption and/or Sale Have Been Banned, Withdrawn, Severely Restricted or Not Approved by
Governments", "WHO Guidelines for Drinking-water Quality - Guideline values for chemicals that are of health significance in
drinking-water"
ozone (CAS: 10028-15-6) is found on the following regulatory lists;
"Australia - Victoria Occupational Health and Safety Regulations - Schedule 9: Materials at Major Hazard Facilities (And Their
Threshold Quantity) Table 2", "Australia Drinking Water Guideline Values For Physical and Chemical Characteristics", "Australia
Exposure Standards", "Australia Hazardous Substances Information System - Consolidated Lists", "Australia National Environment
Protection (Ambient Air Quality) Measure - Schedule 1: Pollutants", "Australia National Environment Protection (Ambient Air
Quality) Measure - Schedule 2 Table 1: Standards and Goal for Pollutants other than Particles as PM2.5", "Australia Quarantine
and Inspection Service List of chemical compounds that are accepted solely for use at establishments registered to prepare meat
and meat products for the purpose of the Export Control Act 1982", "OECD List of High Production Volume (HPV) Chemicals", "United
Nations Consolidated List of Products Whose Consumption and/or Sale Have Been Banned, Withdrawn, Severely Restricted or Not
Approved by Governments"
No data for CIGWELD Arcair DC Gouging Carbons (CW: 17929)
No data for welding fumes (CAS: , Not avail)
No data for nitrogen oxides (CAS: , Mixture)
Section 16 - OTHER INFORMATION
■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as
independent review by the Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.
continued...
Page 147 of 320
CIGWELD Arcair DC Gouging Carbons
Hazard Alert Code: MODERATE
Chemwatch Material Safety Data Sheet
Issue Date: 5-Dec-2011
X9317SP
CHEMWATCH 17929
Version No:6.1.1.1
Page 9 of 9
Section 16 - OTHER INFORMATION
■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether
the reported Hazards are Risks in the workplace or other settings.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written
permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 5-Dec-2011
Print Date: 16-Apr-2014
This is the end of the MSDS.
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SAFETY DATA SHEET
19904
Section 1. Identification
Product name
: Dri­Graph Graphite Lubricant
Product code
: 19904
Other means of
identification
: Not available.
Product type
: Aerosol.
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
Manufacturer
: Lawson Products, Inc.
8770 W. Bryan Mawr, Suite 900
Chicago, IL 60631-3515
773­304­5050 Emergency telephone
number of the company
: (888) 426-4851
Section 2. Hazards identification
OSHA/HCS status
Classification of the
substance or mixture
: This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
: FLAMMABLE AEROSOLS - Category 1
GASES UNDER PRESSURE - Compressed gas
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
TOXIC TO REPRODUCTION (Unborn child) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation and Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 59.5%
GHS label elements
Hazard pictograms
:
Signal word
Hazard statements
: Danger
: Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
Suspected of damaging the unborn child.
May be fatal if swallowed and enters airways.
May cause respiratory irritation.
May cause drowsiness and dizziness.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
General
Date of issue/Date of revision
: Read label before use. Keep out of reach of children. If medical advice is needed, have
product container or label at hand.
: 9/19/2014.
Date of previous issue
: 8/21/2014.
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: 1.06
1/13
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Section 2. Hazards identification
Prevention
Response
Storage
Disposal
Supplemental label
elements
Hazards not otherwise
classified
: Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear eye
or face protection. Keep away from heat, hot surfaces, sparks, open flames and other
ignition sources. No smoking. Pressurized container: Do not pierce or burn, even after
use. Do not spray on an open flame or other ignition source. Use only outdoors or in a
well-ventilated area. Do not breathe dust or mist. Wash hands thoroughly after
handling.
: Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF
SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce
vomiting. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical attention.
: Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.
Dispose of contents and container in accordance with all local, regional, national and
international regulations.
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.
Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do
not discard empty can in trash compactor.
: None known.
Section 3. Composition/information on ingredients
Substance/mixture
: Mixture
Other means of
identification
: Not available.
CAS number/other identifiers
Ingredient name
% by weight
CAS number
Heptane
2-Propanol
Propane
Butane
Toluene
43.5
23.9
14.8
14.2
1.5
64742-49-0
67-63-0
74-98-6
106-97-8
108-88-3
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First aid measures
Description of necessary first aid measures
Eye contact
Date of issue/Date of revision
: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
: 9/19/2014.
Date of previous issue
: 8/21/2014.
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: 1.06
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Section 4. First aid measures
Inhalation
Skin contact
Ingestion
: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
: Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
: Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.
Most important symptoms/effects, acute and delayed
Potential acute health effects
Eye contact
: Causes serious eye irritation.
Inhalation
: Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness. May cause respiratory irritation.
: No known significant effects or critical hazards.
Skin contact
Ingestion
: Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. Irritating to mouth, throat and stomach.
Over-exposure signs/symptoms
Eye contact
Inhalation
Skin contact
Ingestion
Date of issue/Date of revision
: Adverse symptoms may include the following:
pain or irritation
watering
redness
: Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
: Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
: Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations
: 9/19/2014.
Date of previous issue
: 8/21/2014.
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: 1.06
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Section 4. First aid measures
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician
Specific treatments
Protection of first-aiders
: Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
: No specific treatment.
: No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Extinguishing media
Suitable extinguishing
media
: Use an extinguishing agent suitable for the surrounding fire.
Unsuitable extinguishing
media
: None known.
Specific hazards arising
from the chemical
Hazardous thermal
decomposition products
Special protective actions
for fire-fighters
Special protective
equipment for fire-fighters
: Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard.
: Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
: Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency
personnel
: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Environmental precautions
Date of issue/Date of revision
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
: 9/19/2014.
Date of previous issue
: 8/21/2014.
Version
: 1.06
4/13
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Section 6. Accidental release measures
Methods and materials for containment and cleaning up
Small spill
Large spill
: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Section 7. Handling and storage
Precautions for safe handling
Protective measures
: Put on appropriate personal protective equipment (see Section 8). Pressurized
container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do
not pierce or burn, even after use. Avoid exposure - obtain special instructions before
use. Avoid exposure during pregnancy. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Store and use away from
heat, sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use only non-sparking tools.
Empty containers retain product residue and can be hazardous.
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
: Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
: Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
and well-ventilated area, away from incompatible materials (see Section 10) and food
and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use
appropriate containment to avoid environmental contamination.
Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
Ingredient name
Exposure limits
2-Propanol
ACGIH TLV (United States, 6/2013).
TWA: 200 ppm 8 hours.
STEL: 400 ppm 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 400 ppm 10 hours.
TWA: 980 mg/m³ 10 hours.
STEL: 500 ppm 15 minutes.
STEL: 1225 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 400 ppm 8 hours.
TWA: 980 mg/m³ 8 hours.
NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.
Propane
Date of issue/Date of revision
: 9/19/2014.
Date of previous issue
: 8/21/2014.
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: 1.06
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Section 8. Exposure controls/personal protection
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
NIOSH REL (United States, 10/2013).
TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 6/2013).
STEL: 1000 ppm 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 200 ppm 8 hours.
CEIL: 300 ppm
AMP: 500 ppm 10 minutes.
NIOSH REL (United States, 10/2013).
TWA: 100 ppm 10 hours.
TWA: 375 mg/m³ 10 hours.
STEL: 150 ppm 15 minutes.
STEL: 560 mg/m³ 15 minutes.
ACGIH TLV (United States, 6/2013).
TWA: 20 ppm 8 hours.
Butane
Toluene
Appropriate engineering
controls
Environmental exposure
controls
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Individual protection measures
Hygiene measures
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection
: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection
Body protection
Other skin protection
Date of issue/Date of revision
: Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
: Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
: Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
: 9/19/2014.
Date of previous issue
: 8/21/2014.
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: 1.06
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Section 8. Exposure controls/personal protection
Respiratory protection
: Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Section 9. Physical and chemical properties
Appearance
Physical state
: Liquid.
Color
: Not available.
Odor
Odor threshold
pH
: Not available.
: Not available.
Melting point
: Not available.
: Not available.
Boiling point
: Not available.
Flash point
: Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Evaporation rate
: 4.5 (butyl acetate = 1)
Flammability (solid, gas)
: Not available.
Lower and upper explosive
(flammable) limits
: Lower: 1%
Upper: 12.7%
Vapor pressure
: 13.5 kPa (101.325 mm Hg) [at 20°C]
Vapor density
Relative density
: 1.55 [Air = 1]
: 0.66
Solubility
: Not available.
Partition coefficient: noctanol/water
: Not available.
Auto-ignition temperature
: Not available.
Decomposition temperature
: Not available.
Viscosity
: Kinematic (40°C (104°F)): <0.07 cm2/s (<7 cSt)
Aerosol product
Type of aerosol
: Spray
Heat of combustion
: 37.75 kJ/g
Section 10. Stability and reactivity
Reactivity
: No specific test data related to reactivity available for this product or its ingredients.
Chemical stability
: The product is stable.
Possibility of hazardous
reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid
: Avoid all possible sources of ignition (spark or flame).
Incompatible materials
: No specific data.
Hazardous decomposition
products
: Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
Date of issue/Date of revision
: 9/19/2014.
Date of previous issue
: 8/21/2014.
Version
: 1.06
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Section 11. Toxicological information
Information on toxicological effects
Acute toxicity
Product/ingredient name
Result
Species
2-Propanol
LD50 Dermal
LD50 Oral
LC50 Inhalation Vapor
LC50 Inhalation Vapor
LD50 Oral
Rabbit
Rat
Rat
Rat
Rat
Butane
Toluene
Dose
Exposure
12800 mg/kg
5000 mg/kg
658000 mg/m³
49 g/m³
636 mg/kg
4 hours
4 hours
-
Irritation/Corrosion
Product/ingredient name
Result
Species
Score
Exposure
Observation
2-Propanol
Eyes - Moderate irritant
Rabbit
-
-
Eyes - Moderate irritant
Eyes - Severe irritant
Rabbit
Rabbit
-
Skin - Mild irritant
Rabbit
-
Eyes - Mild irritant
Rabbit
-
Eyes - Mild irritant
Rabbit
-
Eyes - Severe irritant
Rabbit
-
Skin - Mild irritant
Pig
-
Skin - Mild irritant
Rabbit
-
Skin - Moderate irritant
Rabbit
-
Skin - Moderate irritant
Rabbit
-
24 hours 100
milligrams
10 milligrams
100
milligrams
500
milligrams
0.5 minutes
100
milligrams
870
Micrograms
24 hours 2
milligrams
24 hours 250
microliters
435
milligrams
24 hours 20
milligrams
500
milligrams
Toluene
-
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification
Product/ingredient name
OSHA
IARC
NTP
2-Propanol
Toluene
-
3
3
-
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Date of issue/Date of revision
: 9/19/2014.
Date of previous issue
: 8/21/2014.
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: 1.06
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Section 11. Toxicological information
Name
Category
Route of
exposure
Target organs
Heptane
Category 3
Not applicable.
2-Propanol
Category 3
Not applicable.
Propane
Category 3
Not applicable.
Butane
Category 3
Not applicable.
Toluene
Category 3
Not applicable.
Respiratory tract
irritation and
Narcotic effects
Respiratory tract
irritation and
Narcotic effects
Respiratory tract
irritation and
Narcotic effects
Respiratory tract
irritation and
Narcotic effects
Respiratory tract
irritation and
Narcotic effects
Name
Category
Route of
exposure
Target organs
Heptane
2-Propanol
Propane
Butane
Toluene
Category 2
Category 2
Category 2
Category 2
Category 2
Not determined
Not determined
Not determined
Not determined
Not determined
Not determined
Not determined
Not determined
Not determined
Not determined
Specific target organ toxicity (repeated exposure)
Aspiration hazard
Name
Result
Heptane
ASPIRATION HAZARD - Category 1
Information on the likely
routes of exposure
: Not available.
Potential acute health effects
Eye contact
: Causes serious eye irritation.
Inhalation
Skin contact
Ingestion
: Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness. May cause respiratory irritation.
: No known significant effects or critical hazards.
: Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. Irritating to mouth, throat and stomach.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact
: Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation
: Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Date of issue/Date of revision
: 9/19/2014.
Date of previous issue
: 8/21/2014.
Version
: 1.06
9/13
Page 165 of 320
Skin contact
Ingestion
reduced fetal weight
increase in fetal deaths
skeletal malformations
: Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
: Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate
: Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate
: Not available.
effects
Potential delayed effects
: Not available.
Potential chronic health effects
Not available.
General
: May cause damage to organs through prolonged or repeated exposure.
Carcinogenicity
: No known significant effects or critical hazards.
Mutagenicity
: No known significant effects or critical hazards.
Teratogenicity
Developmental effects
Fertility effects
: Suspected of damaging the unborn child.
: No known significant effects or critical hazards.
: No known significant effects or critical hazards.
Numerical measures of toxicity
Acute toxicity estimates
Route
ATE value
Oral
5691.6 mg/kg
Section 12. Ecological information
Toxicity
Product/ingredient name
Result
Species
Exposure
2-Propanol
Acute LC50 1400000 µg/l Marine water
Acute LC50 1400000 µg/l
Acute EC50 433 ppm Marine water
Acute EC50 12500 µg/l Fresh water
Crustaceans - Crangon crangon
Fish - Gambusia affinis
Algae - Skeletonema costatum
Algae - Pseudokirchneriella
subcapitata
Crustaceans - Gammarus
pseudolimnaeus - Adult
Daphnia - Daphnia magna Juvenile (Fledgling, Hatchling,
Weanling)
Fish - Oncorhynchus kisutch - Fry
Algae - Pseudokirchneriella
48 hours
96 hours
96 hours
72 hours
Toluene
Acute EC50 11600 µg/l Fresh water
Acute EC50 6000 µg/l Fresh water
Acute LC50 5500 µg/l Fresh water
Chronic NOEC 500000 µg/l Fresh water
Date of issue/Date of revision
: 9/19/2014.
Date of previous issue
: 8/21/2014.
Version
48 hours
48 hours
96 hours
96 hours
: 1.06
10/13
Page 166 of 320
Section 12. Ecological information
Chronic NOEC 1000 µg/l Fresh water
subcapitata
Daphnia - Daphnia magna
21 days
Persistence and degradability
Not available.
Bioaccumulative potential
Product/ingredient name
LogPow
BCF
Potential
Heptane
Toluene
-
10 to 2500
90
high
low
Mobility in soil
Soil/water partition
coefficient (KOC)
: Not available.
Other adverse effects
: No known significant effects or critical hazards.
Section 13. Disposal considerations
Disposal methods
: The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Do not
puncture or incinerate container.
Section 14. Transport information
DOT
Classification
TDG
Classification
Mexico
Classification
IATA
IMDG
UN number
UN1950
UN1950
UN1950
UN1950
UN1950
UN proper
shipping name
AEROSOLS
AEROSOLS
AEROSOLS
AEROSOLS,
flammable
AEROSOLS
Transport
hazard class(es)
2.1
2.1
2.1
Packing group
-
-
-
-
-
Environmental
hazards
No.
No.
No.
No.
No.
Additional
information
Special
provisions
LIMITED
QUANTITY
Special
provisions
LIMITED
QUANTITY
Special
provisions
(ERG#126)
Special
provisions
LIMITED
QUANTITY
Emergency
schedules (EmS)
LIMITED
QUANTITY, F-D,
S-U
Date of issue/Date of revision
: 9/19/2014.
Date of previous issue
2.1
: 8/21/2014.
2.1
Version
: 1.06
11/13
Page 167 of 320
Section 14. Transport information
Special precautions for user : Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
Transport in bulk according
to Annex II of MARPOL
73/78 and the IBC Code
: Not available.
Section 15. Regulatory information
U.S. Federal regulations
:
SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
State regulations
California Prop. 65
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
Section 16. Other information
Hazardous Material Information System (U.S.A.)
Health
2
Flammability
4
Physical hazards
0
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA).
The customer is responsible for determining the PPE code for this material.
Notice to reader
Date of issue/Date of revision
: 9/19/2014.
Date of previous issue
: 8/21/2014.
Version
: 1.06
12/13
Page 168 of 320
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Regulatory requirements are subject to change and may differ between various
locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all
country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of
the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use
of this product. The customer/buyer/user should not use the product for any purpose other than the purpose
shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling
instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the
manufacturer cannot be responsible for SDSs obtained from any other source.
Date of issue/Date of revision
: 9/19/2014.
Date of previous issue
: 8/21/2014.
Version
: 1.06
13/13
Page 169 of 320
PRO CHEM, INC.
MATERIAL SAFETY DATA SHEET
1475 BLUEGRASS LAKES PKWY.
ALPHARETTA, GA 30004
EMERGENCY/INFO # (800) 241-8180
ADDITIONAL EMERGENCY # INFO TRAC 1-800-535-5053
HEALTH
FIRE
REACTIVITY
P.P.E.
DURA BOND (TUBES) / 1475
SEPTEMBER 2008
PAGE 1
1
1
0
B
Complies With USDL Safety and Health Regulations, (29 CFR 1910.200)
SECTION 1 – Chemical and Company Identification
SECTION 8 – Exposure Controls/Personal Protection
Epoxy Putty
Mixture
PRODUCT CLASS:
CAS #:
SECTION 2 – Composition on Ingredients
INGREDIENT
NAME
Glycidyl
Ethers of
Bisphenol A
Resins
Tri(Dimethyla
minomethyl)
Phenol
Zinc Sulfide
CAS #
%
TSCA
HMIS
25068-38-6
10-30
Y
H:2, F:1,
R:0,
PPI:B
90-72-2
0.5-1.5
Y
H:2, F:1,
R:1, PPI:D
1314-98-3
0.5-1.5
Y
H:2, F:1,
R:1, PPI:E
***All ingredients in this product are listed in the T.S.C.A. inventory.
ACGIH
TLV
N/EST
ACGIH
TLV-C
N/EST
ACGIH
STEL
N/EST
OSHA
STEL
N/EST
OSHA
PEL
N/EST
5.00 ppm
N/EST
N/EST
N/EST
N/EST
5.00
3
mg/m
N/EST
N/EST
N/EST
N/EST
SECTION 3 – Hazards Information
PERMISSIBLE EXPOSURE LEVEL:
EFFECTS OF OVEREXPOSURE:
N/A
N/A
SECTION 4 – First Aid Measures
NOTE:
Never give anything by mouth to an unconscious person.
SECTION 5 – Fire Fighting Measures
FLAMMABILITY CLASS:
FLASH RANGE:
None, Not Applicable
EXPLOSIVE RANGE:
None, Not Applicable
EXTINGUISHING MEDIA:
Water spray, foam, CO2, Dry Chemicals.
UNUSUAL HAZARDS:
N/A
FIRE FIGHTING: Fire fighters and others who may be exposed to the products of combustion should
be equipped with NIOSH-approved positive pressure self-contained breathing apparatus (SCBA) and
full protective clothing.
SECTION 6 – Accidental Release Measures
PROTECTIVE EQUIPMENT TYPES:
EYES: Safety glasses or goggles.
RESPIRATORY: None required with well-ventilated area.
GLOVES: Appropriate impervious gloves. Consult glove manufacturer to determine the proper
type.
OTHER: N/A
VENTILATION:
GENERAL MECHANICAL:
None required.
LOCAL EXHAUST:
Use to keep exposures below recommendation. Only if heated
above 100°F.
SECTION 9 – Physical and Chemical Properties
FORM:
Putty
APPEARANCE/COLOR:
White/neutral
Sulfur, Mercaptan
ODOR:
SOLUBILITY (IN WATER):
Insoluble in water
pH VALUE:
Not Applicable
BOILING POINT:
Not Applicable
MELTING POINT:
Not Applicable
VAPOR PRESSURE (mmHg): Not Applicable
EVAPORATION RATE:
Non-Volatile
VAPOR DENSITY:
Non-Volatile
% VOLATILE WEIGHT:
0%
% VOLATILE:
< 1%
VOC:
< 1%
MOLECULAR WEIGHT:
0.
SPECIFIC GRAVITY:
1.9
HEAVY ELEMENTS (PPM):
NOTE: The physical data represented above are typical values and should not be construed as a
specification. For additional physical data and details on use, please obtain a technical data sheet for
this product.
SECTION 10 – Stability and Reactivity
STABILITY:
This product is stable.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBILITY:
None
CONDITIONS TO AVOID:
None
HAZARDOUS DECOMPOSITION PRODUCTS: None.
SECTION 11 – Toxicological Information
STEPS TO BE TAKEN: SPILLS OR LEAKS: Dispose of in normal manner.
SECTION 7 – Handling and Storage
Page 170 of 320
STORAGE TEMPERATURE:
< 90°F (32°C)
STORAGE CONDITIONS:
Store in cool, dry, well-ventilated area.
TRANSFER: No special precautions are needed. Follow good manufacturing and handling practices.
PERSONAL HYGIENE: Wash thoroughly after handling, especially before eating, drinking, smoking,
and using restroom facilities. Wash contaminated goggles, faceshield, and gloves. Professionally
launder contaminated clothing before re-use.
EMPTY CONTAINER PRECAUTIONS: ATTENTION! This container can be hazardous when empty.
Follow label cautions even after the container is empty since empty containers could retain product
residues. Do not re-use empty containers for food, clothing, or products for human or animal
consumption, or where skin contact can occur.
Glycidyl Ethers of Bisphenol A Resins
Tri (Dimethylaminomethyl) Phenol
ROUTE
ORAL
SKIN
ORAL
SPECIES
RAT, ADULT
RABBIT,
ADULT
RAT, ADULT
EXPOSURE AND DOSE
LD50 5000. MG/KG
LD50 20000. MG/KG
LD50 1630. MG/KG
SECTION 12 – Ecological Information
No data available.
SECTION 13 – Disposal Consideration
WASTE DISPOSAL METHOD: Incinerate in furnace or bury in landfill in accordance with all
applicable regulations; not a hazardous waste.
THIS INFORMATION MUST BE ON ALL MSDS’S COPIED AND DISTRIBUTED FOR THIS MATERIAL.
NO WARRANTY IS EXPRESSED/IMPLIED REGARDING THE ACCURACY OF THIS DATA OR
RESULTS OBTAINED FROM USE. PROCHEM ASSUMES NO RESPONSIBILITY FOR PERSONAL
INJURY OR PROPERTY DAMAGE TO USER. VENDEE/USER ASSUMES ALL RISKS ASSOCIATED
WITH USE.
PRO CHEM, INC.
MATERIAL SAFETY DATA SHEET
1475 BLUEGRASS LAKES PKWY.
ALPHARETTA, GA 30004
EMERGENCY/INFO # (800) 241-8180
ADDITIONAL EMERGENCY # INFO TRAC 1-800-535-5053
DURA BOND (TUBES) / 1475
SEPTEMBER 2008
PAGE 2
HEALTH
FIRE
REACTIVITY
P.P.E.
1
1
0
B
Complies With USDL Safety and Health Regulations, (29 CFR 1910.200)
SECTION 14 – Transport Information
DOT HAZARD CLASS:
SHIPPING NAME:
None
Putty, NMFC 150110
SECTION 15 – Regulatory Information
INGREDIENT NAME:
Zinc Sulfide
CAS NUMBER
1314-98-3
PERCENT
0.5 – 1.5
SECTION 16 – Other Information
NOTE: User responsibility: A bulletin such as this cannot be expected to cover all possible individual
situations. As the user has the responsibility to provide a safe workplace, all aspects of an individual
operations should be examined to determine if, or where, precautions – in addition to those described
herein – are required. Any health hazard and safety information herein should be passed on to your
customers or employees as the case may be.
DISCLAIMER OF LIABILITY: The information contained herein is, to the best of our knowledge and
belief, accurate. However, since the conditions of handling and use are beyond our control, we make
no guarantee of results, and assume no liability for damages incurred by the use of this material. All
chemicals may present unknown health hazards and should be used with caution. Although certain
hazards are described herein, we can not guarantee that these are the only hazards which exist. Final
determination of suitability of the chemical is the sole responsibility of the user. No representation or
warranties, either expressed or implied, of merchantability, fitness for a particular purpose or any other
nature are made hereunder with respect to the information refers. It is the responsibility of the user to
comply with all applicable federal, state, and local laws and regulations.
Page 171 of 320
THIS INFORMATION MUST BE ON ALL MSDS’S COPIED AND DISTRIBUTED FOR THIS MATERIAL.
NO WARRANTY IS EXPRESSED/IMPLIED REGARDING THE ACCURACY OF THIS DATA OR
RESULTS OBTAINED FROM USE. PROCHEM ASSUMES NO RESPONSIBILITY FOR PERSONAL
INJURY OR PROPERTY DAMAGE TO USER. VENDEE/USER ASSUMES ALL RISKS ASSOCIATED
WITH USE.
There was a PDF conversion failure for Product Name: DuraMAX Windshield Washer Solvent (NF) (-20 Degree)
CAS Number:
Manufacturer: RelaDyne LLC
SDS Date: 10/22/2013
To complete your binder, please link a different SDS for this product or print the SDS manually from
http://www.msdsonline.com/Legacy/Partners/Show-Document/Default.aspx?ShowId=AnjORAjcTCo%3d
and add to your binder. We are currently researching solutions to this issue. Thank you for your patience.
Page 172 of 320
Page 173 of 320
Page 174 of 320
Page 175 of 320
Tuesday, April 19, 2011
Page 1 of 4
MSDS - Material Safety Data Sheet
Product Name: GUNK INDUSTRIAL GLASS CLEANER
MSDS No.: PDWGC-5G
I. Basic Information:
Manufacturer: RADIATOR SPECIALTY COMPANY
Contact: Robert Geer
Address: 600 RADIATOR ROAD
Information Telephone Number: 704-684--181 1
City, ST Zip: INDIAN TRAIL, NC 28079
Emergency Contact: RMPDC (877-740-5015)
Country:
Emergency Telephone Number: 303-623-5716
Emergency Restrictions:
Product Name: GUNK INDUSTRIAL GLASS CLEANER
MSDS No.: PDWGC-5G
Issue Date: 04/14/2008
Supersedes Date: Not Available
II. Hazards Identification:
EMERGENCY OVERVIEW
CAUTION: Eye Irritant.
OSHA Regulatory Status
While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this MSDS contains valuable
information critical to the safe handling and proper use of the product.
Potential Health Effects
Route(s) of Entry:
Absorption, Eye, Inhalation, and Ingestion.
Health Hazards (Acute and Chronic):
See signs and symptoms below
Signs and Symptoms:
Eye Contact: Direct spray of vapors may be irritating or harmful to eyes.
Skin Contact: Prolonged contact may cause irritation due to defatting of skin.
Inhalation: High concentration of vapors may irritate nose and throat and cause headaches and nausea.
Ingestion: Can cause irritation, gastric disturbances, and nausea..
Medical Conditions Generally Aggravated by Exposure:
None Known
Other Health Warnings:
None Known
Potential Environmental Effects
Not Available
III. Composition/Information on Ingredients:
Chemical Name
CAS No.
% Range
Ammonium hydroxide
1336-21-6
0.1 - 1.0
Tripropylene Glycol Monomethyl Ether
25498-49-1
3.0 - 7.0
Trade Secret
IV. First Aid Measures:
Emergency and First Aid Procedures:
Eye Contact: Flush eyes with water for 15 minutes while lifting upper and lower eyelid. Get prompt medical attention.
Skin Contact: Wash with soap and water. If irritation persists, get prompt medical attention.
Inhalation: Move to fresh air. If breathing becomes difficult, give oxygen and get prompt medical attention.
Ingestion: Drink water or milk. Call Poison Control Center, physician, or hospital emergency room immediately.
Note to Physicians:
.
N/E
Page 176 of 320
Tuesday, April 19, 2011
Page 2 of 4
MSDS - Material Safety Data Sheet
Product Name: GUNK INDUSTRIAL GLASS CLEANER
MSDS No.: PDWGC-5G
V. Fire Fighting Measures:
Suitable Extinguishing Media:
Water Fog, Foam, Carbon Dioxide, Dry Chemical
Unsuitable Extinguishing Media:
None
Products of Combustion:
Carbon dioxide, carbon monoxide
Protection of Firefighters:
Wear self-contained positive pressure breathing apparatus and protective clothes. Use shield to protect from rupturing and venting containers. At
elevated temperatures containers may vent, rupture or burst, even violently
VI. Accidental Release Measures:
Personal Precautions:
Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed.
Environmental Precautions:
Prevent run-off to sewers, streams, or other bodies of water. If run-off occurs, notify proper authorities as required that a spill has occured.
Methods for Containment:
Dike or contain spill and absorb with inert materials (sand, sawdust, absorbent sweeping compounds, rags, etc).
Methods for Cleanup:
Scoop absorbed waste into a chemical waste container. Neutralize remaining traces of material and flush with water followed by liberal covering with
sodium bicarbonate. All clean-up material should be removed and placed in approved containers for disposal. Rinse water may be disposed of
down a sanitary sewer system if authorized by the local municipality.
Other Information:
None
VII. Handling and Storage:
Handling Precautions:
Use with adequate ventilation. Do not take internally.
Storage Precautions:
Avoid contact with strong oxidizing agents.
Do not store at temperatures above 120 F.
VIII. Exposure Controls/Personal Protection:
Chemical Name
OSHA PEL
ACGIH TLV
Other Limits
Ammonium hydroxide
25 ppm (TWA)
25 ppm
Not Available
Tripropylene Glycol Monomethyl Ether
N/E
N/E
Not Available
Engineering Controls:
See above for applicable exposure limits. Use with adequate ventilation. If TLV is exceeded, wear NIOSH approved respirator.
Personal Protective Equipment:
For prolonged exposure wear protective safety glasses, gloves, and apron. Wash hands before handling food.
Page 177 of 320
Tuesday, April 19, 2011
Page 3 of 4
MSDS - Material Safety Data Sheet
Product Name: GUNK INDUSTRIAL GLASS CLEANER
MSDS No.: PDWGC-5G
IX. Physical and Chemical Properties:
Boiling Point: 212 F
Melting Point: N/A
Boiling Range: N/D
Freezing Point: N/D
Solubility In Water: Soluble
Evaporation Rate (Butyl Acetate = 1): < 1
Flash Point: None
Flash Point Method: TCC
Odor Threshold: N/D
Appearance and Odor: Clear liquid with alcohol-ammonia odor.
Vapor Density (AIR = 1): N/D
Vapor Pressure (mm Hg.): N/D
pH Range: 11 - 12
Partition Coefficient:
Decomposition Temp: N/D
Auto-Ignition Temp: N/D
Lower Explosive Limit: N/D
N/D
Upper Explosive Limit: N/D
Specific Gravity (H20 = 1): 1.00
Other Information: N/D
X. Stability and Reactivity:
Stability:
Stable
Conditions to Avoid:
Avoid heat, sparks, or flames.
Incompatible Materials:
Avoid contact with strong oxidizing agents
Hazardous Decomposition Products:
Carbon Monoxide, Carbon Dioxide
Possibility of Hazardous Reactions:
Will not occur
XI. Toxicological Information:
No data available.
XII. Ecological Information:
No data available
XIII. Disposal Considerations:
DISPOSAL: This container may be recycled in a recycling centers when empty. Before offering for recycling, empty the can or bottle by using the
product according to the label. If recycling is not available, wrap the empty container and discard in the trash. Do not dump into sewers, on the
ground, or into any body of water. Dispose of unused product in accordance with all local, state government and federal laws and regulations
XIV. Transport Information:
Shipping Name: Not Available
DOT Hazard Class: Not Available
DOT Subsidiary Hazard Class: Not Available
UN/NA#: Not Available
Packing Group:
Not Available
Transportation Information:
Page 178 of 320
Tuesday, April 19, 2011
Page 4 of 4
MSDS - Material Safety Data Sheet
Product Name: GUNK INDUSTRIAL GLASS CLEANER
MSDS No.: PDWGC-5G
Shipping Name: Not regulated
DOT Hazard Class: Not regulates
The DOT description is provided to assist in the proper shipping classification of this product and may not be suitable for international and air
shipping purposes.
ICAO/IATA (US): Not regulated
International:
ICAO/IATA: Not regulated
IMDG: Not Regulated
XV. Regulatory Information:
See Section 2 for SARA Reportable Chemicals.
USA TSCA: All components of this material are listed on the US TSCA Inventory.
States Right to Know:
Massachusetts: 1336-21-6
Pennsylvania: 1336-21-6
XVI. Other Information:
Chemical State:
X
Chemical Type:
Liquid
Gas
Pure
Mixture
X
Solid
1
Hazard Category:
X
Acute
Chronic
Fire
Pressure
Reactive
1
0
Additional Manufacturer Warnings:
Do not used in confined area without proper ventilation. Contact lenses
may cause further damage in case of splash into eye. KEEP AWAY
FROM CHILDREN AND ANIMALS!
1
N/E: Not Established
N/D: Not Determined
N/A: Not Applicable
N/AV: Not Available
0
1
A
Additional Product Information:
While Radiator Specialty Company believes this data is accurate as of the revision date, we make no warranty with respect to the
data and we expressly disclaim all liability for reliance thereon. The data is offered solely for information, investigation, and
verification. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or
disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance.
Page 179 of 320
HARDSURFACING
MSDS NO: HARDSURFACING ELECTRODES
REVISED: 07/14/2005
CHANGE NUMBER : SE2455
MATERIAL SAFETY DATA SHEET
For U.S. Manufactured or Distributed Welding Consumables and Related Products. May be used to comply with OSHA's Hazard Communication Standard, 29 CFR 1910.1200
and Superfund Amendments and Reauthorization Act (SARA) of 1986 Public Law 99-499. Standard must be consulted for specific requirements.
SECTION 1 - IDENTIFICATION
Manufacturer/Supplier Name:
HOBART BROTHERS
|Telephone No: (937) 332-4000
Address:
400 TRADE SQUARE EAST, TROY, OH 45373
|Emergency No: (800) 424-9300
Trade Name:
FROGALLOY, HARDALLOY, SMOOTHARC, CHROME-MANG, AND GP HARDSURFACING ELECTRODES
Product Type for:
HARDSURFACING ELECTRODES
| Classification: None
SECTION 2 - HAZARDOUS INGREDIENTS
IMPORTANT
This section covers the hazardous ingredients from which this product is manufactured. The fumes and gases produced during welding with normal use of this product are
also addressed in Section 5. The term "hazardous" in this section should be interpreted as a term required and defined in OSHA Hazard Communication Standard (29 CFR Part
1910.1200).
EXPOSURE LIMIT (mg/m3)
HAZARDOUS INGREDIENTS
% WEIGHT CAS NO.
OSHA PEL
ACGIH TLV
IRON+
40-80
7439-89-6
CALCIUM CARBONATE
0-10
1317-65-3
FLUORSPAR
TITANIUM DIOXIDE
MOLYBDENUM
0-10
0-17
0-6
7789-75-5
13463-67-7
7439-98-7
#CHROMIUM
1-30
7440-47-3
SILICA++
(Amorphous Silica Fume)
TUNGSTEN
#MANGANESE
1-10
14808-60-7
69012-64-2
7440-33-7
7439-96-5
SILICON
TITANIUM+
##ALUMINUM
MAGNESIUM CARBONATE
#NICKEL
COLUMBIUM+
SILICATE BINDERS
0-1
0.5-15
<8
0-5
0-3
7440-21-3
7440-32-6
7429-90-5
0-5
0-10
546-93-0
7440-02-0
0-4
<5
7440-03-1
---------
5 R*
10 (Oxide Fume)
5 R*
5 (as CaO)
2.5 (as F)
5 R*
5 R*
1 (Metal)
0.5 (Cr II & Cr III Compounds)
0.1 CL** (Cr VI Compounds)
0.1 R*
0.8
1,3 STEL***
5 CL** (Dust)
1, 3 STEL*** (Fume)
5 R*
5 R*
5 R*
5 (Fume)
5 R*
1 (Metal)
1 (Soluble Compounds)
1 (Insoluble Compounds)
5 R*
Not Established
3R*
5 (Oxide Fume) {A4}
10
2 (as CaO)
2.5 (as F) {A4}
10 {A4}
0.5 R*(Soluble Compounds){A3}♦
10 I* (Elemental/Metal and Insoluble)
3 R* (Elemental/Metal and Insoluble)
0.5 (Metal) {A4}
0.5 (Cr III Compounds) {A4}
0.05 (Cr VI Soluble Compounds) {A1}
0.1 R*
2 R*
1, 3 STEL***
0.2♦♦
(Dust & Fume)
10
3R*
10
5 (Fume)
10
1.5 (Metal) {A5}
0.1 (Soluble Compounds) {A4}
0.2 (Insoluble Compounds) {A1}
3R*
Not Established
R* - Respirable Fraction.
I* - Inhalable Fraction.
** - Ceiling Limit.
*** - Short Term Exposure Limit.
{A1} - Confirmed Human Carcinogen per ACGIH.
{A3} - Confirmed Animal Carcinogen with Unknown Relevance to Humans per ACGIH.
{A4} - Not Classifiable as a Human Carcinogen per ACGIH.
{A5} - Not Suspected as a Human Carcinogen per ACGIH.
+ - As a nuisance particulate covered under "Particulates Not Otherwise Regulated" by OSHA or "Particulates Not Otherwise Classified" by ACGIH.
++ - Crystalline silica is bound within the product as it exists in the package. However, research indicates silica is present in welding fume in the amorphous (noncrystalline)
form.
# - Reportable material under Section 313 of SARA.
## - Reportable material under Section 313 of SARA as dust or fume.
♦ - 2002 ACGIH listed under Notice of Intended Changes. A2 - "Suspected Human Carcinogen ".
♦♦ - 2002 ACGIH listed under Notice of Intended Changes. Limits of 0.03 mg/m3 (respirable fraction) are proposed and should be considered as trial limits.
The exposure limit for welding fume has been established at 5 mg/m3 with OSHA's PEL and ACGIH's TLV. The individual complex compounds within the fume may
have lower exposure limits than the general welding fume PEL/TLV. An Industrial Hygienist, the OSHA Permissible Exposure Limits For Air Contaminants (29 CFR
1910.1000), and the ACGIH Threshold Limit Values should be consulted to determine the specific fume constituents present and their respective exposure limits.
SECTION 3 - PHYSICAL/CHEMICAL CHARACTERISTICS
Welding consumables applicable to this sheet as shipped are solid and nonvolatile as shipped.
SECTION 4 - FIRE AND EXPLOSION HAZARD DATA
Welding consumables applicable to this sheet as shipped are nonreactive, nonflammable, nonexplosive and essentially nonhazardous until welded. Welding arcs and sparks
can ignite combustibles and flammable products. See American National Standard Z49.1 referenced in Section 7.
SECTION 5 - REACTIVITY DATA - HAZARDOUS DECOMPOSITION PRODUCTS
Welding fumes and gases cannot be classified simply. The composition and quantity of both are dependent upon the metal being welded, the process, procedures and
electrodes used. Most fume ingredients are present as complex oxides and compounds and not as pure metals.
Other conditions which also influence the composition and quantity of the fumes and gases to which workers may be exposed include: coatings on the metal being welded
(such as paint, plating or galvanizing), the number of welders and the volume of the work area, the quality and amount of ventilation, the position of the welder's head with
respect to the fume plume, as well as the presence of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from cleaning and degreasing activities).
When the electrode is consumed, the fume and gas decomposition products generated are different in percent and form from the ingredients listed in Section 2. Decomposition
products of normal operation include those originating from the volatilization, reaction or oxidation of the materials shown in Section 2, plus those from the base metal and
coating, etc., as noted above.
Reasonably expected constituents of the fume would include: Primarily - iron oxides. Secondarily - complex oxides of calcium, fluorides, titanium, molybdenum, chromium
and nickel compounds, silicon, tungsten, manganese, aluminum, magnesium, and columbium.
Monitor for the materials identified in Section 2. Fumes from the use of these products may contain chromium, nickel, manganese, fluorides, calcium oxides,
amorphous silica fume, and tungsten which have exposure limits lower than the 5 mg/m3 PEL/TLV for general welding fume.
Gaseous reaction products may include carbon monoxide and carbon dioxide. Ozone and nitrogen oxides may be formed by the radiation from the arc.
One recommended way to determine the composition and quantity of fumes and gases to which workers are exposed is to take an air sample inside the welder's helmet if worn
or in the worker's breathing zone. [See ANSI/AWS F1.1, available from the "American Welding Society", P.O. Box 351040, Miami, FL 33135. Also, from AWS is F1.3
"Evaluating Contaminants in the Welding Environment - A Sampling Strategy Guide", which gives additional advice on sampling.]
HARDSURFACING
418742
Page
180 of 320
Page 1 of 2
SECTION 6 - HEALTH HAZARD DATA
EFFECTS OF OVEREXPOSURE:
Electric arc welding may create one or more of the following health hazards:
ARC RAYS can injure eyes and burn skin.
FUMES AND GASES can be dangerous to your health.
ELECTRIC SHOCK can kill. See Section 7.
PRIMARY ROUTES OF ENTRY are the respiratory system, eyes and/or skin.
SHORT-TERM (ACUTE) OVEREXPOSURE EFFECTS:
WELDING FUMES - May result in discomfort such as dizziness, nausea or dryness or irritation of nose, throat or eyes.
IRON, IRON OXIDE - None are known. Treat as nuisance dust or fume.
CALCIUM OXIDE - Dust or fumes may cause irritation of the respiratory system, skin and eyes.
FLUORIDES - Fluoride compounds evolved may cause skin and eye burns, pulmonary edema and bronchitis.
TITANIUM DIOXIDE - Irritation of respiratory system.
MOLYBDENUM - Irritation of the eyes, nose and throat.
CHROMIUM - Inhalation of fume with chromium (VI) compounds can cause irritation of the respiratory tract, lung damage and asthma-like symptoms. Swallowing
chromium (VI) salts can cause severe injury or death. Dust on skin can form ulcers. Eyes may be burned by chromium (VI) compounds. Allergic reactions may occur in
some people.
SILICA (AMORPHOUS) - Dust and fumes may cause irritation of the respiratory system, skin and eyes.
TUNGSTEN - Dust may cause irritation of the skin and eyes. Inhalation of dust may cause acute airways obstructive asthma which is reversible following overexposure.
Symptoms are tightening chest and productive cough.
MANGANESE - Metal fume fever characterized by chills, fever, upset stomach, vomiting, irritation of the throat and aching of body. Recovery is generally complete within
48 hours of the overexposure.
ALUMINUM, ALUMINUM OXIDE - Irritation of the respiratory system.
MAGNESIUM, MAGNESIUM OXIDE - Overexposure to the oxide may cause metal fume fever characterized by metallic taste, tightness of chest and fever. Symptoms
may last 24 to 48 hours following overexposure.
NICKEL, NICKEL COMPOUNDS - Metallic taste, nausea, tightness in chest, metal fume fever, allergic reaction.
COLUMBIUM - Dust or fumes may cause irritation of the respiratory system, skin and eyes.
LONG-TERM (CHRONIC) OVEREXPOSURE EFFECTS:
WELDING FUMES - Excess levels may cause bronchial asthma, lung fibrosis, pneumoconiosis or "siderosis."
IRON, IRON OXIDE FUMES - Can cause siderosis (deposits of iron in lungs) which some researchers believe may affect pulmonary function. Lungs will clear in time
when exposure to iron and its compounds ceases. Iron and magnetite (Fe3O4) are not regarded as fibrogenic materials.
CALCIUM OXIDE - Prolonged overexposure may cause ulceration of the skin and perforation of the nasal septum, dermatitis and pneumonia.
FLUORIDES - Serious bone erosion (Osteoporosis) and mottling of teeth.
TITANIUM DIOXIDE - Pulmonary irritation and slight fibrosis.
MOLYBDENUM - Prolonged overexposure may result in loss of appetite, weight loss, loss of muscle coordination, difficulty in breathing and anemia.
CHROMIUM - Ulceration and perforation of nasal septum. Respiratory irritation may occur with symptoms resembling asthma. Studies have shown that chromate
production workers exposed to hexavalent chromium compounds have an excess of lung cancers. Chromium (VI) compounds are more readily absorbed through the skin
than chromium (III) compounds. Good practice requires the reduction of employee exposure to chromium (III) and (VI) compounds.
SILICA (AMORPHOUS) - Research indicates that silica is present in welding fume in the amorphous form. Long term overexposure may cause pneumoconiosis.
Noncrystalline forms of silica (amorphous silica) are considered to have little fibrotic potential.
TUNGSTEN - Long term overexposure may cause pulmonary fibrosis characterized by a rapid onset of cough, sputum and dyspnea on exertion.
MANGANESE - Long term overexposure to manganese compounds may affect the central nervous system. Symptoms may be similar to Parkinson's Disease and can
include slowness, changes in handwriting, gait impairment, muscle spasms and cramps and less commonly, tremor and behavioral changes. Employees who are exposed to
manganese compounds should be seen by a physician for early detection of neurologic problems.
ALUMINUM, ALUMINUM OXIDE - Pulmonary fibrosis and emphysema.
MAGNESIUM, MAGNESIUM OXIDE - No adverse long term health effects have been reported in the literature.
NICKEL, NICKEL COMPOUNDS - Lung fibrosis or pneumoconiosis. Studies of nickel refinery workers indicated a higher incidence of lung and nasal cancers.
COLUMBIUM - No adverse long term health effects have been reported in the literature.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
Persons with pre-existing impaired lung functions (asthma-like conditions).
EMERGENCY AND FIRST AID PROCEDURES:
Call for medical aid. Employ first aid techniques recommended by the American Red Cross.
Eyes & Skin: If irritation or flash burns develop after exposure, consult a physician.
CARCINOGENICITY:
Chromium VI and nickel compounds must be considered carcinogens according to OSHA (29 CFR 1910.1200). Chromium VI compounds are classified as IARC Group 1
and NTP Group 1 carcinogens. Nickel compounds are classified as IARC Group 1 and NTP Group 2 carcinogens. Welding fumes must be considered as possible carcinogens
under OSHA (29 CFR 1910.1200).
CALIFORNIA PROPOSITION 65:
WARNING: These products contain or produce chemicals known to the State of California to cause cancer and birth defects (or other reproductive harm). (California Health
& Safety Code Section 25249.5 et seq.).
SECTION 7 - PRECAUTIONS FOR SAFE HANDLING & USE/APPLICABLE CONTROL MEASURES
Read and understand the manufacturer's instructions and the precautionary label on the product. See American National Standard Z49.1; Safety in Welding and Cutting
published by the American Welding Society, P.O. Box 351040, Miami, FL 33135 and OSHA Publication 2206 (29 CFR 1910), U.S. Government Printing Office, Washington,
DC 20402 for more detail on any of the following.
VENTILATION: Use enough ventilation, local exhaust at the arc or both to keep the fumes and gases below PEL/TLVs in the worker's breathing zone and the general
area. Train the welder to keep his head out of the fumes.
RESPIRATORY PROTECTION: Use NIOSH approved or equivalent fume respirator or air supplied respirator when welding in confined space or where local exhaust
or ventilation does not keep exposure below PEL/TLVs.
EYE PROTECTION: Wear helmet or use face shield with filter lens. As a rule of thumb begin with Shade Number 14. Adjust if needed by selecting the next lighter
and/or darker shade number. Provide protective screens and flash goggles, if necessary, to shield others.
PROTECTIVE CLOTHING: Wear hand, head and body protection which help to prevent injury from radiation, sparks and electrical shock. See ANSI Z49.1. At a
minimum this includes welder's gloves and a protective face shield, and may include arm protectors, aprons, hats, shoulder protection as well as dark nonsynthetic clothing.
Train the welder not to touch live electrical parts and to insulate himself from work and ground.
PROCEDURE FOR CLEANUP OF SPILLS OR LEAKS: Not applicable
WASTE DISPOSAL: Prevent waste from contaminating surrounding environment. Discard any product, residue, disposable container or liner in an environmentally
acceptable manner, in full compliance with Federal, State and Local regulations.
SPECIAL PRECAUTIONS (IMPORTANT): Maintain exposure below the PEL/TLVs. Use industrial hygiene monitoring to ensure that your use of this material does
not create exposures which exceed PEL/TLVs. Always use exhaust ventilation. Refer to the following sources for important additional information: ANSI Z49.1 from the
American Welding Society, P.O. Box 351040, Miami, FL 33135 and OSHA (29 CFR 1910) from the U.S. Department of Labor, Washington, DC 20210.
Hobart Brothers believes this data to be accurate and to reflect expert opinion regarding current research. However, Hobart Brothers cannot make any expressed
or implied warranty as to this information.
418742
Page
181 of 320
Page 2 of 2
Spectrum Group
Division of United Industries Corp.
P. O. Box 142642
St. Louis, MO 63114-0642
Hazardous Material Identification
System – (HMIS)
Material Safety Data Sheet
HEALTH – 1
REACTIVITY – 0
FLAMMABILITY –2
PERSONAL –
Complies with OSHA’s Hazard Communication Standard, 29 CFR 1910.1200
I Trade Name: Hot Shot® Wasp & Hornet Killer3
Product Type: Aerosol insecticide
Product Item Number: 13415.11
Formula Code Number:
EPA Registration Number
Manufacturer
For Chemical Emergency:
For Information:
Prepared by:
Date Prepared:
Chemsico
Division of United Industries Corporation
8494 Chapin Industrial Drive
St. Louis, MO 63114
9688-190-8845
II Hazards Ingredient/Identity Information
Chemical
Mineral spirits
CAS# 8012-95-1
Propylene glycol monobutyl
ether CAS# 5131-66-8
Lambda-cyhalothrin
CAS# 91465-08-6
Prallethrin
CAS# 23031-36-9
Hydrocarbon Propellant blend
CAS #75-28-5/106-97-8/74-98-6
Emergency Telephone Numbers
1-800-633-2873
1-800-917-5431
Charlie Duckworth
October 18, 2010
III Physical and Chemical Characteristics
%
4.00
OSHA PEL
100 ppm
ACGIH TLV
100 ppm
6.00
None
None
0.01
NA
2000 mg/kg (skin)
0.025
NE
NE
5.00
NE
NE
Appearance & Odor:
Boiling Point:
Melting Point:
Vapor Pressure:
Specific Gravity:
Vapor Density:
Narrow Jet spray and glycol ether odor.
NA
NA
110 psig at 54° C/130° F
0.993 (H2O = 1)
Greater than 1 (Air = 1)
Solubility in Water:
Evaporation Rate:
Greater than 87%
Less than 1 (Butyl Acetate = 1)
IV Fire and Explosive Hazards Data
V Reactivity Data
119° F (TCC) (liquid portion)
Flash Point:
Flame Extension:
0-inches (Level 1 Aerosol)
Flammable Limits:
NA
Autoignition Temperature:
NA
Fire Extinguishing Media:
Water fog, Carbon dioxide, Dry chemical
Decomposition Temperature: NA
Special Fire-Fighting Keep cans cool. Use equipment or shielding to
Procedures:
protect personnel against bursting, rupturing or
venting cans.
Unusual Fire & Explosion Hazards: At elevated temperatures (over
54° C/130° F), cans may vent, rupture or burst. Also see Section V.
Stability:
Polymerization:
Conditions to Avoid:
Incompatible Materials:
Hazardous Decomposition
or Byproducts:
VI Health Hazard Data
VII Precautions for Safe Handling and Use
Avoid contact with skin and clothing. First Aid: Take off
contaminated clothing. Rinse skin immediately with
plenty of water for 15-20 minutes. Call a Poison Control
Center or doctor for treatment advice.
Ingestion:
First Aid: Immediately call a Poison Control Center or
doctor. Do not induce vomiting unless told to do so by a
Poison Control Center or doctor. Do not give any liquid
to the person. Do not give anything by mouth to an
unconscious person.
Special Notes: Have the product container with you when calling a
Poison Control Center or doctor, or going for treatment.
Health conditions Aggravated by Exposure: None known
Ingredients listed by NTP, OSHA, or IARC
as Carcinogens or Potential Carcinogens: None
Skin Contact:
VIII Control Measures
Read and follow label directions. They are your best guide to using this
product effectively, and give necessary safety precautions to protect
your health.
Stable
Will not occur
Temperatures over 130° F
NA
Carbon dioxide, carbon monoxide
Steps to be Taken in Case Material is Released or Spilled:
Avoid breathing vapors. Avoid contact with liquid. Remove ignition
sources. Soak up spills with absorbent material.
Waste Disposal:
Do not puncture or incinerate containers. If empty: Place in trash or
offer for recycling if available. If partly filled: Call local solid waste for
disposal instructions.
Handling & Storage Precautions:
Do not store where temperatures can exceed 54° C/130° F.
IX Transportation Data
DOT: Consumer Commodity, ORM-D, Un-1950
IMDG: UN-1950, Aerosols, 2.1
IATA: UN-1950, Aerosols, Flammable, 2.1
The information and statements herein are believed to be reliable but are not to be construed as warranty or representation for which we
assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular
purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE.
Page 182 of 320
80-925
INTER-LUBE
DELAYED VISCOSITY PENETRATING GREASE
HMIS RATING
NFPA 704 RATING
Health
2
Flammability
4
Reactivity
0
MATERIAL
SAFETY DATA
SHEET
Health
2
Flammability
4
Reactivity
0
KIMBALL-MIDWEST
P.O. BOX 2470
COLUMBUS, OH 43216-2470
CORPORATE TELEPHONE: 614-219-6100
EMERGENCY TELEPHONE: 800-424-9300
NFPA 30B LEVEL
3
1. PRODUCT IDENTIFICATION
SPECIAL HEALTH EFFECTS
CARCINOGEN (OSHA Guidelines) ........ Presently not on any lists.
PART NUMBER............................................. 80-925
PRODUCT NAME ........................................ Inter-Lube Delayed Viscosity Penetrating
Grease
CHEMICAL FAMILY..................................... N/A
DOT SHIPPING ............................................ Limited Quantity (LQ)
6. REACTIVITY
STABILITY ..................................................................................... Stable
INCOMPATIBILITIES .................................................................. High temperatures.
2. HAZARDOUS INGREDIENTS
SPECIFIC CHEMICAL IDENTITY, COMMON NAMES
*Hexane (110-54-3)
Paraffinic Petroleum Distillates (64742-65-0)
Propane, Isobutane, n-Butane (68746-76-8)
Aliphatic Hydrocarbon (64742-63-8)
FIRST AID PROCEDURES
EYE CONTACT ..................................Immediately flush exposed areas with water for at
least 15 minutes, lifting upper and lower eyelids
occasionally. Seek medical attention.
SKIN CONTACT ................................Immediately flush exposed areas with water for at least
15 minutes. If irritation persists, get medical attention.
Remove contaminated clothing and launder before
reuse.
INGESTION ......................................Do NOT induce vomiting. Obtain medical attention
immediately. Never give anything by mouth to an
unconscious or convulsing victim. Keep person warm
and quiet.
INHALATION ....................................Remove to fresh air. If breathing is difficult, give oxygen.
Obtain medical attention.
OSHA PEL
ACGIH TLV
STEL
%
-
50ppm
5mg/m3
800ppm
5mg/m3
-
N/A
N/A
N/A
N/A
Allchemicalcompoundsmarkedwithanasterisk(*)aretoxicchemicalssubjecttothereportingofSection313of
Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372. You must
notifyeachpersontowhomthismixtureoftradenameproductissold.Thisstatementmustnotbedetached.Any
copy or redistribution of this Material Safety Data Sheet shall include this statement. **Ceiling
3. PHYSICAL DATA
BOILING POINT (RANGE).........................................................-23 to 500°F
VAPOR PRESSURE PSIG @ 70°F............................................. N/A
VAPOR DENSITY (AIR = 1) ...................................................... >1
SOLUBILITY IN WATER ............................................................. Negligible
SPECIFIC GRAVITY (H2O = 1) ................................................ 0.7065
MELTING/FREEZING POINT ................................................... N/A
EVAPORATION RATE (61%=1)............................................... >1
VOC content (by weight) ....................................................... 45.8%
APPEARANCE AND ODOR ..................................................... Pale Yellow liquid/Solvent odor
4. FIRE AND EXPLOSION DATA
FLASH POINT .............................................................................. <0 °F
HAZARDOUS DECOMPOSITION
PRODUCTS .................................................................................. In fire, will decompose to carbon
dioxide, carbon monoxide.
HAZARDOUS POLYMERIZATION ......................................... Will not occur under normal
conditions.
HAZARDOUS POLYMERIZATION CONDITIONS..... ......... None known.
7. PRECAUTIONS FOR SAFE HANDLING & USE
PROTECTIVE EQUIPMENT
REQUIREMENTS ..............................Self contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients
below acceptable limit. Safety glasses or chemical splash
goggles.
WASH REQUIREMENTS ................Wash with soap and water.
SPILL OR LEAK PROCEDURES ....Absorb spill with inert material (e.g. dry sand
or earth), then place in chemical waste container.
Dispose as hazardous waste.
WASTE DISPOSAL METHODS.....Dispose of in accordance with local, state, and federal
regulations.
HANDLING & STORAGE ...............Wash thoroughly after handling. Keep away from
heat, sparks, and flames. Store below 120oF.
OTHER PRECAUTIONS ..................Use NIOSH approved respirator with an organic
vapor cartridge; avoid prolonged breathing of
vapors; protection provided by air purifying
respirators is limited.
UPPER EXPLOSIVE LIMIT (%) ................................................. 12.8
8. ADDITIONAL INFORMATION
LOWER EXPLOSIVE LIMIT (%) ................................................ 1.0
Use self-contained breathing apparatus if TLV limits are exceeded. Do not eat
or smoke while using. Wash hands after use. Use positive pressure air supplied
respirator if there is potential for uncontrolled release, if exposure levels are
unknown, or in any circumstance where air purifying respirators may not provide
adequate protection.
EXTINGUISHING MEDIA.......................................................... Dry chemical, CO2,Water Fog
SPECIAL FIREFIGHTING PROCEDURES .............................. Aerosol cans may rupture
when heated. As in any fire,
wear self-contained breathing
apparatus pressure-demand
(MSHA/NIOSH approved or
equivalent) and full protective
gear.
FIRE AND EXPLOSION HAZARDS......................................... Heated cans may burst.
5. HEALTH EFFECTS DATA
SHORT TERM EFFECTS OF EXPOSURE
ROUTE OF ENTRY ...........................Skin absorption, Inhalation, Ingestion, Eye contact,
Skin contact
HEALTH HAZARDS
(ACUTE AND CHRONIC) ...............Prolonged and repeated overexposure to hexane
may cause damage to nerve tissue of the arms and
legs (peripheral neuropathy), resulting in muscular
weakness and loss of sensation. Repeated and
prolonged overexposure to solvents may cause
permanent brain and nervous system damage.
EYE CONTACT ..................................Eye irritant. Will cause redness and burning
sensation.
INGESTION .......................................Aspiration hazard if swallowed.
THE INFORMATION GIVEN AND THE RECOMMENDATIONS MADE HEREIN
APPLY TO OUR PRODUC T(S) ALONE AND ARE NOT COMBINED WITH
OTHER PRODUCTS. SUCH INFORMATION IS BASED UPON OUR RESEARCH
AND ON DATA FROM OTHER RELIABLE SOURCES AND IS BELIE VED
TO BE ACCURATE. NO GUARANTEE OF ACCURACY IS MADE. IT IS
T H E P U R C H A S E R ’S R E S P O N S I B I L I T Y B E F O R E U S I N G A N Y P R O D U C T
TO VERIFY THIS DATA UNDER THEIR OWN OPERATING CONDITIONS
AND TO DETERMINE WHETHER THE PRODUC T IS SUITABLE FOR THEIR
PURPOSES.
INHALATION ....................................Effects of overexposure include irritation of respiratory
tract, headache, dizziness, nausea, and loss of
coordination. Extreme overexposure may result in
unconsciousness and possibly death.
SKIN CONTACT ................................Skin irritant. Will cause defatting of skin. Effects are
reversible.
5. HEALTH EFFECTS DATA CON’T.
COPYRIGHT© 1984 KIMBALL MIDWEST UPDATE 4/12
Page 183 of 320
MATERIAL SAFETY DATA SHEET
45854
07 00
DATE OF PREPARATION
May 28, 2014
SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
45854
PRODUCT NAME
KRYLON® CONTRACTOR™ Marking Paint, Fluorescent Orange
MANUFACTURER'S NAME
Krylon Products Group
Cleveland, OH 44115
Telephone Numbers and Websites
Product Information
(800) 247-3268
www.krylon.com
Regulatory Information (216) 566-2902
www.paintdocs.com
Medical Emergency (216) 566-2917
Transportation Emergency* (800) 424-9300
*for Chemical Emergency ONLY (spill, leak, fire, exposure, or
accident)
page 1 of 6
Page 184 of 320
45854
SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS
% by Weight
15
7
8
4
1
1
7
0.3
2
10
CAS Number
74-98-6
106-97-8
110-54-3
107-83-5
96-14-0
79-29-8
64742-89-8
100-41-4
1330-20-7
67-64-1
20
14808-60-7
7
7727-43-7
Ingredient
Units
Propane
ACGIH TLV
1000 PPM
OSHA PEL
1000 PPM
Butane
ACGIH TLV
1000 PPM
OSHA PEL
800 PPM
Hexane
ACGIH TLV
50 PPM
OSHA PEL
50 PPM
2-Methylpentane
ACGIH TLV
Not Available
OSHA PEL
Not Available
3-Methylpentane
ACGIH TLV
500 PPM
OSHA PEL
Not Available
2,3-Dimethylbutane
ACGIH TLV
Not Available
OSHA PEL
Not Available
Lt. Aliphatic Hydrocarbon Solvent
ACGIH TLV
100 PPM
OSHA PEL
100 PPM
Ethylbenzene
ACGIH TLV
20 PPM
OSHA PEL
100 PPM
OSHA PEL
125 PPM STEL
Xylene
ACGIH TLV
100 PPM
ACGIH TLV
150 PPM STEL
OSHA PEL
100 PPM
OSHA PEL
150 PPM STEL
Acetone
ACGIH TLV
500 PPM
ACGIH TLV
750 PPM STEL
OSHA PEL
1000 PPM
Quartz
ACGIH TLV
0.025 mg/m3 as Resp. Dust
OSHA PEL
0.1 mg/m3 as Resp. Dust
Barium Sulfate
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
Vapor Pressure
760 mm
760 mm
127 mm
211 mm
211 mm
230 mm
53 mm
7.1 mm
5.9 mm
180 mm
SECTION 3 — HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
HMIS Codes
Health 2*
Flammability 3
Reactivity 0
May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death.
Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems:
the liver
the urinary system
the reproductive system
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
page 2 of 6
Page 185 of 320
45854
SECTION 4 — FIRST AID MEASURES
EYES:
SKIN:
INHALATION:
INGESTION:
Flush eyes with large amounts of water for 15 minutes. Get medical attention.
Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
If affected, remove from exposure. Restore breathing. Keep warm and quiet.
Do not induce vomiting. Get medical attention immediately.
SECTION 5 — FIRE FIGHTING MEASURES
FLASH POINT
LEL
UEL
EXTINGUISHING MEDIA
Propellant < 0 °F
1.0
12.8
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately
apparent. Obtain medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus should be used.
Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure
build-up and possible autoignition or explosion when exposed to extreme heat.
SECTION 6 — ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
SECTION 7 — HANDLING AND STORAGE
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off
stoves, electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children.
SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous
levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts
are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction).
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure
limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this
product, underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear
chemical resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal.
page 3 of 6
Page 186 of 320
45854
SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES
7.40 lb/gal
887 g/l
0.89
<0 - 292 °F
<-18 - 144 °C
Not Available
80%
Faster than
ether
VAPOR DENSITY Heavier than air
SOLUBILITY IN WATER Not Available
pH 7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
Volatile Weight 47.96%
Less Water and Federally Exempt Solvents
PRODUCT WEIGHT
SPECIFIC GRAVITY
BOILING POINT
MELTING POINT
VOLATILE VOLUME
EVAPORATION RATE
SECTION 10 — STABILITY AND REACTIVITY
STABILITY — Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
SECTION 11 — TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
Prolonged and repeated exposure to Hexane may cause damage to nerve tissue of the arms and legs (peripheral neuropathy), resulting in
muscular weakness and loss of sensation. This effect may be increased by the presence of Methyl Ethyl Ketone.
Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage.
Ethylbenzene is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient
evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high ethylbenzene concentrations resulted in increases in
certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals
exposed to lower concentrations. There is no evidence that ethylbenzene causes cancer in humans.
Crystalline Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when
sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer.
page 4 of 6
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45854
TOXICOLOGY DATA
CAS No.
74-98-6
106-97-8
110-54-3
107-83-5
96-14-0
79-29-8
64742-89-8
100-41-4
1330-20-7
67-64-1
14808-60-7
7727-43-7
Ingredient Name
Propane
LC50 RAT
LD50 RAT
4HR
Not Available
Not Available
LC50 RAT
LD50 RAT
4HR
Not Available
Not Available
LC50 RAT
LD50 RAT
4HR
Not Available
28700 mg/kg
LC50 RAT
LD50 RAT
4HR
Not Available
Not Available
LC50 RAT
LD50 RAT
4HR
Not Available
Not Available
LC50 RAT
LD50 RAT
Lt. Aliphatic Hydrocarbon Solvent
LC50 RAT
LD50 RAT
Ethylbenzene
LC50 RAT
LD50 RAT
Xylene
LC50 RAT
LD50 RAT
Acetone
LC50 RAT
LD50 RAT
Quartz
LC50 RAT
LD50 RAT
Barium Sulfate
LC50 RAT
LD50 RAT
4HR
Not Available
Not Available
4HR
Not Available
Not Available
4HR
Not Available
3500 mg/kg
4HR
5000 ppm
4300 mg/kg
4HR
Not Available
5800 mg/kg
4HR
Not Available
Not Available
4HR
Not Available
Not Available
Butane
Hexane
2-Methylpentane
3-Methylpentane
2,3-Dimethylbutane
SECTION 12 — ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.
SECTION 13 — DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution.
SECTION 14 — TRANSPORT INFORMATION
Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping
description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of
transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport.
US Ground (DOT)
May be classed as LTD. QTY. OR ORM-D
UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)
Canada (TDG)
May be classed as LTD. QTY. OR ORM-D
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)
IMO
May be shipped as Limited Quantity
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U
IATA/ICAO
UN1950, AEROSOLS, FLAMMABLE, 2.1, LIMITED QUANTITY
page 5 of 6
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45854
SECTION 15 — REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
110-54-3
Hexane
8
100-41-4
Ethylbenzene
0.3
1330-20-7
Xylene
2
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory.
% Element
SECTION 16 — OTHER INFORMATION
This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the
MSDS contains all of the information required by the CPR.
The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other
additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no
warranties, express or implied, and assume no liability in connection with any use of this information.
page 6 of 6
Page 189 of 320
Material Safety Data Sheet
Revision Number: 007.0
Issue date: 02/07/2014
1. PRODUCT AND COMPANY IDENTIFICATION
Product name:
Product use:
LOCTITE® 620™ RETAINING
COMPOUND
Anaerobic Adhesive
Company address:
Henkel Canada Corporation
2515 Meadowpine Boulevard
Mississauga, Ontario L5N 6C3
IDH number:
234768
Item number:
62005
Region:
Canada
Contact information:
Telephone: 905.814.6511
MEDICAL EMERGENCY Phone: Poison Control Center
1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com
2. HAZARDS IDENTIFICATION
Physical state:
Color:
Odor:
EMERGENCY OVERVIEW
WHMIS hazard class:
Liquid
Green
Mild
WARNING:
D.2.A, D.2.B
CAUSES EYE IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION.
MAY BE HARMFUL IF SWALLOWED.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
MAY CAUSE SKIN IRRITATION.
Relevant routes of exposure:
Skin, Inhalation, Eyes, Ingestion
Potential Health Effects
Inhalation:
Skin contact:
Eye contact:
Ingestion:
May cause respiratory tract irritation.
May cause allergic skin reaction. May cause skin irritation.
Contact with eyes will cause irritation.
May be harmful if swallowed.
Existing conditions aggravated by
exposure:
Eye, skin, and respiratory disorders.
See Section 11 for additional toxicological information.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous components
CAS NUMBER
%
2-Propenoic acid, 2-methyl-, (1-methylethylidene)
Maleimide resin
Hydroxyalkyl methacrylate
Cumene hydroperoxide
Silica, amorphous, fumed, crystal-free
Cumene
1-Acetyl-2-phenylhydrazine
24448-20-2
3006-93-7
27813-02-1
80-15-9
112945-52-5
98-82-8
114-83-0
60 - 100
10 - 30
1-5
1-5
1-5
0.1 - 1
0.1 - 1
4. FIRST AID MEASURES
Inhalation:
Move to fresh air. If symptoms develop and persist, get medical attention.
IDH number: 234768
Product name: LOCTITE® 620™ RETAINING COMPOUND
Page 1 of 5
Page 190 of 320
Skin contact:
Wash with soap and water. Remove contaminated clothing and footwear.
Wash clothing before reuse. If symptoms develop and persist, get medical
attention.
Eye contact:
Flush with copious amounts of water, preferably, lukewarm water for at least
15 minutes, holding eyelids open all the time. Get medical attention.
Ingestion:
Do not induce vomiting. Keep individual calm. Get medical attention.
5. FIRE FIGHTING MEASURES
Flash point:
> 93.3 °C (> 199.94 °F) Tagliabue closed cup
Autoignition temperature:
Not available.
Flammable/Explosive limits - lower:
Not available.
Flammable/Explosive limits - upper:
Not available.
Extinguishing media:
Foam, dry chemical or carbon dioxide.
Special firefighting procedures:
None
Unusual fire or explosion hazards:
None
Hazardous combustion products:
Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Toxic fumes. Irritating
organic vapours.
Sensitivity to Mechanical Impact:
Not available.
Sensitivity to static discharge:
Not available.
6. ACCIDENTAL RELEASE MEASURES
Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.
Environmental precautions:
Do not allow product to enter sewer or waterways.
Clean-up methods:
Ensure adequate ventilation. Soak up with inert absorbent material (e.g. sand,
silica gel, acid binder, universal binder, sawdust). Store in a partly filled,
closed container until disposal.
7. HANDLING AND STORAGE
Handling:
Avoid contact with eyes, skin and clothing. Use only with adequate ventilation.
Storage:
For safe storage, store at or below 38 °C (100.4 °F)
Keep in a cool, well ventilated area away from heat, sparks and open flame.
Keep container tightly closed until ready for use.
For information on product shelf life contact Henkel Canada Customer Service at 800-263-5043.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.
IDH number: 234768
Product name: LOCTITE® 620™ RETAINING COMPOUND
Page 2 of 5
Page 191 of 320
Hazardous components
ACGIH TLV
OSHA PEL
AIHA WEEL
OTHER
2-Propenoic acid, 2-methyl-, (1-methylethylidene)
Maleimide resin
None
None
None
None
None
None
Hydroxyalkyl methacrylate
None
None
None
None
None
1 ppm TWA
3 ppm STEL
None
None
1 ppm (6 mg/m3)
TWA
(SKIN)
None
10 mg/m3 TWA
Inhalable dust.
3 mg/m3 TWA
Respirable fraction.
20 MPPCF TWA
0.8 mg/m3 TWA
None
None
None
None
None
None
Cumene hydroperoxide
Silica, amorphous, fumed, crystal-free
Cumene
50 ppm TWA
1-Acetyl-2-phenylhydrazine
None
50 ppm (245
mg/m3) PEL
(SKIN)
None
Engineering controls:
No specific ventilation requirements noted, but forced ventilation may still be
required if concentrations exceed occupational exposure limits.
Respiratory protection:
Use a NIOSH approved supplied air respirator with an organic cartridge if the
potential to exceed established exposure limits exists.
Eye/face protection:
Safety goggles or safety glasses with side shields.
Skin protection:
Use impermeable gloves and protective clothing as necessary to prevent skin
contact. Neoprene gloves.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state:
Color:
Odor:
Odor threshold:
pH:
Vapor pressure:
Boiling point/range:
Melting point/ range:
Specific gravity:
Vapor density:
Flash point:
Flammable/Explosive limits - lower:
Flammable/Explosive limits - upper:
Autoignition temperature:
Evaporation rate:
Solubility in water:
Partition coefficient (n-octanol/water):
VOC content:
Liquid
Green
Mild
Not available.
Not applicable
< 5 mm hg (27 °C (80.6 °F))
> 149 °C (> 300.2 °F)
Not available.
1.1
Not available.
> 93.3 °C (> 199.94 °F) Tagliabue closed cup
Not available.
Not available.
Not available.
Not available.
Slight
Not available.
0.19 %; 2.24 g/l
10. STABILITY AND REACTIVITY
Stability:
Stable
Hazardous reactions:
Will not occur.
Hazardous decomposition products:
Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Toxic fumes. Irritating
organic vapours.
Incompatible materials:
Strong oxidizing agents.
Conditions to avoid:
See "Handling and Storage" (Section 7) and "Incompatibility" (Section 10).
11. TOXICOLOGICAL INFORMATION
Acute oral product toxicity:
LD50 (rat) > 10,000 mg/kg
IDH number: 234768
Product name: LOCTITE® 620™ RETAINING COMPOUND
Page 3 of 5
Page 192 of 320
Acute dermal product toxicity:
LD50 (rabbit) > 2,000 mg/kg (Estimated)
Toxicologically synergistic products:
Not available.
Refer to the following for Irritancy of Product, Sensitization to Product, Carcinogenicity, Reproductive Toxicity, Teratogenicity,
and Mutagenicity.
Hazardous Component(s)
NTP Carcinogen
IARC Carcinogen
OSHA Carcinogen
(Specifically Regulated)
2-Propenoic acid, 2-methyl-, (1methylethylidene)
Maleimide resin
Hydroxyalkyl methacrylate
Cumene hydroperoxide
Silica, amorphous, fumed, crystal-free
Cumene
1-Acetyl-2-phenylhydrazine
No
No
No
No
No
No
No
No
No
No
No
No
No
Group 2B
No
No
No
No
No
No
No
Hazardous components
LD50s and LC50s
2-Propenoic acid, 2-methyl-, (1methylethylidene)
Maleimide resin
Hydroxyalkyl methacrylate
Cumene hydroperoxide
Health Effects/Target Organs
None
Irritant, Allergen
None
None
No Target Organs
Irritant, Allergen
Allergen, Central nervous system, Corrosive,
Irritant, Mutagen
Nuisance dust
None
Silica, amorphous, fumed, crystal-free
None
Oral LD50 (RAT) = 2.91 g/kg
Oral LD50 (RAT) = 1,400 mg/kg
Inhalation LC50 (RAT, 4 h) = 8,000 mg/l
Cumene
1-Acetyl-2-phenylhydrazine
Central nervous system, Irritant, Lung
Allergen, Blood, Kidney, Mutagen, Some
evidence of carcinogenicity
None
12. ECOLOGICAL INFORMATION
Ecological information:
Not available.
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal:
Follow all local, state, federal and provincial regulations for disposal.
14. TRANSPORT INFORMATION
The shipping classification in this section are for bulk packaging only. Shipping classification may be different for non-bulk packaging
as exceptions may apply. Refer to shipping documents for package specific transportation classification.
Canada Transportation of Dangerous Goods - Ground
Proper shipping name:
Not regulated
Hazard class or division:
None
Identification number:
None
Packing group:
None
International Air Transportation (ICAO/IATA)
Proper shipping name:
Hazard class or division:
Identification number:
Packing group:
Environmentally hazardous substance, liquid, n.o.s.
9
UN 3082
III
IDH number: 234768
Product name: LOCTITE® 620™ RETAINING COMPOUND
Page 4 of 5
Page 193 of 320
Water Transportation (IMO/IMDG)
Proper shipping name:
Hazard class or division:
Identification number:
Packing group:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
9
UN 3082
III
15. REGULATORY INFORMATION
Canada Regulatory Information
CEPA DSL/NDSL Status:
All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.
United States Regulatory Information
TSCA 8 (b) Inventory Status:
All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections: 7, 9 and 16
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR), and
the MSDS contains all the information required by the CPR.
Prepared by: Diane Annis, Sr. Regulatory Affairs Specialist
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.
IDH number: 234768
Product name: LOCTITE® 620™ RETAINING COMPOUND
Page 5 of 5
Page 194 of 320
Page 195 of 320
Page 196 of 320
Material Safety Data Sheet
0168MAR019
06/02/2006
MSDS ID NO.:
Revision date:
1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Product code:
MR0270
Product name:
Synonym:
Marathon Dexron-III/Mercon Automatic Transmission Fluid
Marathon Dexron-II Automatic Transmission Fluid; Marathon Dexron-III/Mercon
Automatic Transmission Fluid; Marathon Dexron ATF; Marathon Mercon ATF
Motor/Lube Oil
Mixture
Chemical Family:
Formula:
Manufacturer:
Marathon Petroleum Company LLC
539 South Main Street
Findlay OH 45840
Other information:
Emergency telephone number:
419-421-3070
877-627-5463
2. COMPOSITION/INFORMATION ON INGREDIENTS
Automatic Transmission Fluid (ATF) is a complex mixture of highly refined lubricating oil base stocks and additives.
Product information:
Name
CAS Number
Weight %
Marathon Dexron-III/Mercon
Automatic Transmission Fluid
Mixture
100
Name
CAS Number
Weight %
Petroleum Distillates, Hydrotreated
Heavy Paraffinic
64742-54-7
93-95
Additives
Not specified
5-7
ACGIH Exposure
Limits:
OSHA - Vacated
PELs - Time
Weighted Ave
Other:
ACGIH Exposure
Limits:
OSHA - Vacated
PELs - Time
Weighted Ave
Other:
Component Information:
Notes:
Mineral Oil Mist
(MOM)
=5 mg/m3 TWA
= 10 mg/m3 STEL
The manufacturer has voluntarily elected to reflect exposure limits contained in
OSHA's 1989 air contaminants standard in its MSDS's, even though certain of those
exposure limits were vacated in 1992.
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
AUTOMATIC TRANSMISSION FLUID IS A NON-VOLATILE AND NON-COMBUSTIBLE, RED COLORED LIQUID, BUT
WILL IGNITE AND BURN AT ELEVATED TERMPERATURES.
OSHA WARNING LABEL:
MSDS ID NO.: 0168MAR019
Product name: Marathon Dexron-III/Mercon
Automatic Transmission Fluid
Page 1 of 7
Page 197 of 320
THIS PRODUCT HAS BEEN EVALUATED AND DOES NOT REQUIRE ANY HAZARD WARNING LABEL UNDER
THE OSHA HAZARD COMMUNICATION STANDARD.
CONSUMER WARNING LABEL:
A CONSUMER WARNING LABEL IS NOT APPLICABLE FOR THIS PRODUCT.
Inhalation:
No acute effects expected from routine operations. Overheating of product may
produce vapors which can cause respiratory irritation, dizziness and nausea.
Ingestion:
Product has a low order of acute toxicity. This is based on data from components or
similar products.
Skin contact:
Prolonged or repeated liquid contact can cause dermatitis, folliculitis or oil acne.
Eye contact:
Liquid or vapor contact may result in slight eye irritation.
Carcinogenic Evaluation:
Product information:
Name
Marathon Dexron-III/Mercon
Automatic Transmission Fluid
Mixture
Notes:
IARC
Carcinogens:
NE
NTP
Carcinogens:
ACGIH Carcinogens:
OSHA - Select
Carcinogens:
The International Agency for Research on Cancer (IARC) has determined that there
is no evidence that severely solvent-refined oils are carcinogenic to experimental
animals.
Component Information:
4. FIRST AID MEASURES
Inhalation:
If affected, move person to fresh air. If breathing is difficult, administer oxygen. If not
breathing or if no heartbeat, give artificial respiration or cardiopulmonary
resuscitation (CPR). Immediately call a physician. If symptoms or irritation occur with
any exposure, call a physician.
Skin contact:
Wash with soap and large amounts of water. Remove contaminated clothing. If
symptoms or irritation occur, call a physician.
If product is accidentally injected into or under the skin, regardless of wound size or
initial absence of symptoms, the individual should be evaluated immediately by a
physician as a surgical emergency.
Ingestion:
Not expected to be acutely toxic. If large amounts are swallowed, immediately call a
physician.
Eye contact:
Flush eyes with large amounts of tepid water for at least 15 minutes. If symptoms or
irritation occur, call a physician.
Notes to physician:
High velocity injection under the skin may result in serious injury. If left untreated the
affected area is subject to infection, disfigurement, lack of blood circulation and may
require amputation. When dispensed by high pressure equipment this material can
easily penetrate the skin and leave a bloodless puncture wound. Material injected
into a finger can be deposited into the palm of the hand. Within 24-48 hours the
patient may experience swelling, discoloration, and throbbing pain in the affected
area. Immediate treatment by a surgical specialist is recommended.
MSDS ID NO.: 0168MAR019
Product name: Marathon Dexron-III/Mercon
Automatic Transmission Fluid
Page 2 of 7
Page 198 of 320
Medical conditions aggravated
by exposure:
Skin contact could aggravate an existing skin disorder or dermatitis condition.
5. FIRE FIGHTING MEASURES
Suitable extinguishing media:
Specific hazards:
Special protective equipment for firefighters:
For small fires, Class B fire extinguishing media such as
CO2, dry chemical, foam (AFFF/ATC) or water spray can be
used. For large fires, water spray, fog or foam (AFFT/ATC)
can be used. Fire fighting should be attempted only by those
who are adequately trained and equipped with proper
protective equipment.
This material is not combustible per the OSHA Hazard
Communication Standard, but will ignite and burn at elevated
temperatures.
Avoid using straight water streams. Water spray and foam
(AFFF/ATC) must be applied carefully to avoid frothing and
from as far a distance as possible. Avoid excessive water
spray application. Use water spray to cool exposed surfaces
from as far a distance as possible. Keep run-off water out of
sewers and water sources.
Flash point:
Autoignition temperature:
Flammable limits in air - lower (%):
Flammable limits in air - upper (%):
>365 F, >185 C (COC)
No data available.
No data available.
No data available.
NFPA rating:
Health: 1
Flammability: 1
Reactivity: 0
Other: -
HMIS classification:
Health: 1
Flammability: 1
Reactivity: 0
Special: *See Section 8 for guidance in selection of
personal protective equipment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions:
Keep public away. Isolate and evacuate area. Shut off source if safe to do so.
Advise authorities and National Response Center (800-424-8802) if substance has
entered a watercourse or sewer. Advise local and state emergency services
agencies, if appropriate. Contain liquid with sand or soil. Recover and return free
product to proper containers. Use suitable absorbent materials such as vermiculite,
sand, or clay to clean up residual liquids.
7. HANDLING AND STORAGE
Handling:
Comply with all applicable EPA, OSHA, NFPA and consistent state and local requirements. Use appropriate grounding
and bonding practices. Store in properly closed containers that are appropriately labeled and in a cool well-ventilated
area. Do not cut, drill, grind or weld on empty containers since they may contain explosive residues. Do not pressurize
or expose to heat, open flames, strong oxidizers or other sources of ignition.
Avoid repeated and prolonged skin contact. Exercise good personal hygiene including removal of soiled clothing and
prompt washing with soap and water.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT
MSDS ID NO.: 0168MAR019
Product name: Marathon Dexron-III/Mercon
Automatic Transmission Fluid
Page 3 of 7
Page 199 of 320
Local or general exhaust required when using at elevated temperatures that
generate vapors or mists.
Engineering measures:
Respiratory protection:
Not required under normal conditions and adequate ventilation. Approved organic
vapor chemical cartridge or supplied air respirators should be worn when significant
vapors are generated. Observe respirator protection factor criteria cited in ANSI
Z88.2. Self-contained breathing apparatus should be used for fire fighting.
Skin and body protection:
Use chemical resistant gloves such as neoprene, nitrile, or PVA to prevent prolonged
or repeated skin contact.
Eye protection:
No special eye protection is normally required.
Hygiene measures:
No data available.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Appearance:
Physical state (Solid/Liquid/Gas):
Substance type (Pure/Mixture):
Color:
Odor:
Molecular weight:
pH:
Boiling point/range (5-95%):
Melting point/range:
Decomposition temperature:
Specific gravity:
Density:
Bulk density:
Vapor density:
Vapor pressure:
Evaporation rate:
Solubility:
Solubility in other solvents:
Partition coefficient (n-octanol/water):
VOC content(%):
Viscosity:
Red Liquid
Liquid
Mixture
Red
Hydrocarbon
Not determined.
Neutral
No data available.
Not determined.
Not applicable.
Not determined
7.29 lbs/gal @ 60 F
No data available.
No data available.
<1 mm Hg @ 100 F
No data available.
<1%
No data available.
No data available.
No data available.
36.1 cSt @ 40 C
7.7 cSt @ 100 C
10. STABILITY AND REACTIVITY
Stability:
The material is stable at 70 F, 760 mm pressure.
Polymerization:
Will not occur.
Hazardous decomposition products:
Carbon monoxide, carbon dioxide, aldehydes and
hydrocarbons.
Materials to avoid:
Strong oxidizers such as nitrates, chlorates, peroxides.
Conditions to avoid:
Heat and open flames.
11. TOXICOLOGICAL INFORMATION
Acute toxicity:
Product information:
MSDS ID NO.: 0168MAR019
Product name: Marathon Dexron-III/Mercon
Automatic Transmission Fluid
Page 4 of 7
Page 200 of 320
Name
Marathon Dexron-III/Mercon
Automatic Transmission Fluid
CAS Number
Mixture
Inhalation:
LD50 = 2.18 to >4 mg/l
[Rat]
Dermal:
LD50 >2 gm/kg
[Rabbit]
Oral:
LD50 >5 ml/kg
[Rat]
Based on data from components this product is considered to have a low order of acute oral and dermal toxicity. Chronic
skin painting studies with severely solvent refined neutral oils did not produce evidence of skin cancer in mice.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects:
Water accomated fractions (WAF) of highly refined base oils did not produce acute
toxicity in fish (100-1000 mg/l), fresh water algae (500 mg/l) or daphnia (10,000 mg/l)
in 48-96 hour LC50 studies.
Used motor and/or lube oils can be toxic to birds and fish.
13. DISPOSAL CONSIDERATIONS
This material as supplied and by itself, when discarded or
disposed of, is not an EPA RCRA hazardous waste
according to federal regulations. This material could become
a hazardous waste if mixed or contaminated with a
hazardous waste or other substance(s). It is the
responsibility of the user to determine if disposal material is
hazardous according to federal, state and local regulations.
Cleanup Considerations:
Don't pollute. Conserve resources. Send used product to
recycling center. Dispose of cleanup materials in
accordance with applicable local, state and federal
regulations.
14. TRANSPORT INFORMATION
49 CFR 172.101:
DOT:
Transport Information:
This material when transported via US commerce is NOT REGULATED by DOT
regulations.
Not applicable.
Not applicable.
Packing group:
DOT reportable quantity (lbs):
TDG (Canada):
Packing group:
Regulated substances:
Not applicable.
Not applicable.
15. REGULATORY INFORMATION
Federal Regulatory Information:
US TSCA Chemical Inventory Section 8(b):
This product and/or its components are listed on the TSCA
Chemical Inventory.
OSHA Hazard Communication Standard:
This product has been evaluated and determined not to be
hazardous as defined in OSHA's Hazard Communication
Standard.
EPA Superfund Amendment & Reauthorization Act (SARA):
MSDS ID NO.: 0168MAR019
Product name: Marathon Dexron-III/Mercon
Automatic Transmission Fluid
Page 5 of 7
Page 201 of 320
SARA Section 302:
This product contains the following component(s) that have been listed on EPA's
Extremely Hazardous Substance (EHS) List:
Name
Petroleum Distillates, Hydrotreated
Heavy Paraffinic
Additives
SARA Section 304:
CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs
NA
NA
This product contains the following component(s) identified either as an EHS or a
CERCLA Hazardous substance which in case of a spill or release may be subject to
SARA reporting requirements:
Name
Petroleum Distillates, Hydrotreated
Heavy Paraffinic
Additives
SARA Section 311/312:
CERCLA/SARA - Hazardous Substances and their Reportable Quantities
NA
NA
The following EPA hazard categories apply to this product:
None
SARA Section 313:
This product contains the following component(s) that may be subject to reporting on
the Toxic Release Inventory (TRI) From R:
Name
Petroleum Distillates, Hydrotreated
Heavy Paraffinic
Additives
CERCLA/SARA 313 Emission reporting:
None
None
State and Community Right-To-Know Regulations:
The following component(s) of this material are identified on the regulatory lists below:
Petroleum Distillates, Hydrotreated Heavy Paraffinic
Louisiana Right-To-Know:
California Proposition 65:
New Jersey Right-To-Know:
Pennsylvania Right-To-Know:
Massachusetts Right-To Know:
Florida substance List:
Rhode Island Right-To-Know:
Michigan critical materials register list:
Massachusetts Extraordinarily Hazardous
Substances:
California - Regulated Carcinogens:
Pennsylvania RTK - Special Hazardous
Substances:
New Jersey - Special Hazardous Substances:
New Jersey - Environmental Hazardous
Substances List:
Illinois - Toxic Air Contaminants
New York - Reporting of Releases Part 597 List of Hazardous Substances:
Additives
Louisiana Right-To-Know:
California Proposition 65:
New Jersey Right-To-Know:
Pennsylvania Right-To-Know:
Massachusetts Right-To Know:
MSDS ID NO.: 0168MAR019
Not Listed
Not Listed
Not Listed.
Not Listed.
Not Listed.
Not Listed.
Not Listed
Not Listed.
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed.
Not Listed.
Not Listed.
Product name: Marathon Dexron-III/Mercon
Automatic Transmission Fluid
Page 6 of 7
Page 202 of 320
Florida substance List:
Rhode Island Right-To-Know:
Michigan critical materials register list:
Massachusetts Extraordinarily Hazardous
Substances:
California - Regulated Carcinogens:
Pennsylvania RTK - Special Hazardous
Substances:
New Jersey - Special Hazardous Substances:
New Jersey - Environmental Hazardous
Substances List:
Illinois - Toxic Air Contaminants
New York - Reporting of Releases Part 597 List of Hazardous Substances:
Not Listed.
Not Listed
Not Listed.
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Canadian Regulatory Information:
Canada DSL/NDSL Inventory:
This product and/or its components are listed either on the Domestic Substances List
(DSL) or are exempt.
16. OTHER INFORMATION
Additional Information:
No data available.
Prepared by:
Craig M. Parker Manager, Toxicology and Product Safety
The information and recommendations contained herein are based upon tests believed to be reliable. However,
Marathon Petroleum Company LLC (MPC) does not guarantee their accuracy or completeness nor shall any of this
information constitute a warranty, whether expressed or implied, as to the safety of the goods, the merchantability of the
goods, or the fitness of the goods for a particular purpose. Adjustment to conform to actual conditions of usage maybe
required. MPC assumes no responsibility for results obtained or for incidental or consequential damages, including lost
profits arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made
or implied.
End of Safety Data Sheet
MSDS ID NO.: 0168MAR019
Product name: Marathon Dexron-III/Mercon
Automatic Transmission Fluid
Page 7 of 7
Page 203 of 320
Material Safety Data Sheet
0191MAR019
06/02/2006
MSDS ID NO.:
Revision date:
1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Product code:
MR1621, MR1623, MR1625
Product name:
Synonym:
Chemical Family:
Formula:
Marathon Marafluid 4 Transmission & Drive Train Fluid
Marafluid 4; SAE 30 Marafluid 4; SAE 50 Marafluid 4; 10W Marafluid 4
Motor/Lube Oil
Mixture
Manufacturer:
Marathon Petroleum Company LLC
539 South Main Street
Findlay OH 45840
Other information:
Emergency telephone number:
419-421-3070
877-627-5463
2. COMPOSITION/INFORMATION ON INGREDIENTS
Lube oil is a complex mixture of highly refined lubricating base stocks and additives.
Product information:
Name
CAS Number
Weight %
Marathon Marafluid 4 Transmission &
Drive Train Fluid
Mixture
100
Name
CAS Number
Weight %
Distillates, Petroleum SolventRefined Heavy Paraffinic
64741-88-4
0-80
Residual Oils (Petroleum). Solvent
Refined
64742-01-4
0-70
Additives
Zinc Alkyl Dithiophosphate
Not specified
68649-42-3
5-7
1.1-1.5
ACGIH Exposure
Limits:
OSHA - Vacated
PELs - Time
Weighted Ave
Other:
ACGIH Exposure
Limits:
OSHA - Vacated
PELs - Time
Weighted Ave
Other:
Component Information:
Notes:
MSDS ID NO.: 0191MAR019
Mineral Oil Mist
(MOM)
=5 mg/m3 TWA
= 10 mg/m3 STEL
Mineral Oil Mist
(MOM)
=5 mg/m3 TWA
= 10 mg/m3 STEL
The manufacturer has voluntarily elected to reflect exposure limits contained in
OSHA's 1989 air contaminants standard in its MSDS's, even though certain of those
exposure limits were vacated in 1992.
Product name: Marathon Marafluid 4
Transmission & Drive Train Fluid
Page 1 of 8
Page 204 of 320
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
THIS LUBRICANT IS A NON-VOLATILE AND NON-COMBUSTIBLE, AMBER COLORED LIQUID, BUT WILL IGNITE
AND BURN AT ELEVATED TEMPERATURES.
OSHA WARNING LABEL:
THIS PRODUCT HAS BEEN EVALUATED AND DOES NOT REQUIRE ANY HAZARD WARNING LABEL UNDER
THE OSHA HAZARD COMMUNICATION STANDARD.
CONSUMER WARNING LABEL:
A CONSUMER WARNING LABEL IS NOT APPLICABLE FOR THIS PRODUCT.
Inhalation:
No acute effects expected from routine operations. Overheating of product may
produce vapors which can cause respiratory irritation, dizziness and nausea.
Ingestion:
Product has a low order of acute toxicity. This is based on data from components or
similar products.
Skin contact:
Prolonged or repeated liquid contact can cause dermatitis, folliculitis or oil acne.
Eye contact:
Liquid or vapor contact may result in slight eye irritation.
Carcinogenic Evaluation:
Product information:
Name
Marathon Marafluid 4 Transmission &
Drive Train Fluid
Mixture
Notes:
IARC
Carcinogens:
NE
NTP
Carcinogens:
ACGIH Carcinogens:
OSHA - Select
Carcinogens:
The International Agency for Research on Cancer (IARC) has determined that there
is no evidence that severely solvent-refined oils are carcinogenic to experimental
animals.
Component Information:
4. FIRST AID MEASURES
Inhalation:
If affected, move person to fresh air. If breathing is difficult, administer oxygen. If not
breathing or if no heartbeat, give artificial respiration or cardiopulmonary
resuscitation (CPR). Immediately call a physician. If symptoms or irritation occur with
any exposure, call a physician.
Skin contact:
Wash with soap and large amounts of water. Remove contaminated clothing. If
symptoms or irritation occur, call a physician.
If product is accidentally injected into or under the skin, regardless of wound size or
initial absence of symptoms, the individual should be evaluated immediately by a
physician as a surgical emergency.
Ingestion:
Not expected to be acutely toxic. If large amounts are swallowed, immediately call a
physician.
Eye contact:
Flush eyes with large amounts of tepid water for at least 15 minutes. If symptoms or
irritation occur, call a physician.
MSDS ID NO.: 0191MAR019
Product name: Marathon Marafluid 4
Transmission & Drive Train Fluid
Page 2 of 8
Page 205 of 320
Notes to physician:
High velocity injection under the skin may result in serious injury. If left untreated the
affected area is subject to infection, disfigurement, lack of blood circulation and may
require amputation. When dispensed by high pressure equipment this material can
easily penetrate the skin and leave a bloodless puncture wound. Material injected
into a finger can be deposited into the palm of the hand. Within 24-48 hours the
patient may experience swelling, discoloration, and throbbing pain in the affected
area. Immediate treatment by a surgical specialist is recommended.
Medical conditions aggravated
by exposure:
Skin contact could aggravate an existing skin disorder or dermatitis condition.
5. FIRE FIGHTING MEASURES
Suitable extinguishing media:
Specific hazards:
Special protective equipment for firefighters:
For small fires, Class B fire extinguishing media such as
CO2, dry chemical, foam (AFFF/ATC) or water spray can be
used. For large fires, water spray, fog or foam (AFFT/ATC)
can be used. Fire fighting should be attempted only by those
who are adequately trained and equipped with proper
protective equipment.
This material is not combustible per the OSHA Hazard
Communication Standard, but will ignite and burn at elevated
temperatures.
Avoid using straight water streams. Water spray and foam
(AFFF/ATC) must be applied carefully to avoid frothing and
from as far a distance as possible. Avoid excessive water
spray application. Use water spray to cool exposed surfaces
from as far a distance as possible. Keep run-off water out of
sewers and water sources.
Flash point:
Autoignition temperature:
Flammable limits in air - lower (%):
Flammable limits in air - upper (%):
440, 480, 500 F (COC)
No data available.
No data available.
No data available.
NFPA rating:
Health: 1
Flammability: 1
Reactivity: 0
Other: -
HMIS classification:
Health: 1
Flammability: 1
Reactivity: 0
Special: *See Section 8 for guidance in selection of
personal protective equipment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions:
Keep public away. Isolate and evacuate area. Shut off source if safe to do so.
Advise authorities and National Response Center (800-424-8802) if substance has
entered a watercourse or sewer. Advise local and state emergency services
agencies, if appropriate. Contain liquid with sand or soil. Recover and return free
product to proper containers. Use suitable absorbent materials such as vermiculite,
sand, or clay to clean up residual liquids.
7. HANDLING AND STORAGE
Handling:
MSDS ID NO.: 0191MAR019
Product name: Marathon Marafluid 4
Transmission & Drive Train Fluid
Page 3 of 8
Page 206 of 320
Comply with all applicable EPA, OSHA, NFPA and consistent state and local requirements. Use appropriate grounding
and bonding practices. Store in properly closed containers that are appropriately labeled and in a cool well-ventilated
area. Do not cut, drill, grind or weld on empty containers since they may contain explosive residues. Do not pressurize
or expose to heat, open flames, strong oxidizers or other sources of ignition.
Avoid repeated and prolonged skin contact. Exercise good personal hygiene including removal of soiled clothing and
prompt washing with soap and water.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT
Engineering measures:
Local or general exhaust required when using at elevated temperatures that
generate vapors or mists.
Respiratory protection:
Not required under normal conditions and adequate ventilation. Approved organic
vapor chemical cartridge or supplied air respirators should be worn when significant
vapors are generated. Observe respirator protection factor criteria cited in ANSI
Z88.2. Self-contained breathing apparatus should be used for fire fighting.
Skin and body protection:
Use chemical resistant gloves such as neoprene, nitrile, or PVA to prevent prolonged
or repeated skin contact.
Eye protection:
No special eye protection is normally required.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Appearance:
Physical state (Solid/Liquid/Gas):
Substance type (Pure/Mixture):
Color:
Odor:
Molecular weight:
pH:
Boiling point/range (5-95%):
Melting point/range:
Decomposition temperature:
Specific gravity:
Density:
Bulk density:
Vapor density:
Vapor pressure:
Evaporation rate:
Solubility:
Solubility in other solvents:
Partition coefficient (n-octanol/water):
VOC content(%):
Viscosity:
Amber Liquid
Liquid
Mixture
Amber
Hydrocarbon
Not determined.
Neutral
No data available.
Not determined.
Not applicable.
Not determined
7.37, 7.46 or 7.53 lbs/gal @ 60 F
No data available.
No data available.
<1 mm Hg @ 100 F
No data available.
<1%
No data available.
>4.9
No data available.
48.5, 97.5 or 241 cSt @40 C
7.0, 10.9 or 19.8 cSt @ 100 C
10. STABILITY AND REACTIVITY
Stability:
The material is stable at 70 F, 760 mm pressure.
Polymerization:
Will not occur.
MSDS ID NO.: 0191MAR019
Product name: Marathon Marafluid 4
Transmission & Drive Train Fluid
Page 4 of 8
Page 207 of 320
Hazardous decomposition products:
Carbon monoxide, carbon dioxide, aldehydres, hydrogen
sulfide, oxides of sulfur and oxides of nitrogen.
Materials to avoid:
Strong oxidizers such as nitrates, chlorates, peroxides.
Conditions to avoid:
Heat and open flames.
11. TOXICOLOGICAL INFORMATION
Acute toxicity:
Product information:
Name
Marathon Marafluid 4 Transmission &
Drive Train Fluid
CAS Number
Mixture
Inhalation:
LD50 = 2.18 to >4 mg/l
[Rat[
Dermal:
LD50 >2 gm/kg
[Rabbit]
Oral:
LD50 >5 ml/kg
[Rat]
Based on data from components this product is considered to have a low order of acute oral and dermal toxicity. Chronic
skin painting studies with severely solvent refined neutral oils did not produce evidence of skin cancer in mice.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects:
Water accomated fractions (WAF) of highly refined base oils did not produce acute
toxicity in fish (100-1000 mg/l), fresh water algae (500 mg/l) or daphnia (10,000 mg/l)
in 48-96 hour LC50 studies.
Used motor and/or lube oils can be toxic to birds and fish.
13. DISPOSAL CONSIDERATIONS
This material as supplied and by itself, when discarded or
disposed of, is not an EPA RCRA hazardous waste
according to federal regulations. This material could become
a hazardous waste if mixed or contaminated with a
hazardous waste or other substance(s). It is the
responsibility of the user to determine if disposal material is
hazardous according to federal, state and local regulations.
Cleanup Considerations:
Don't pollute. Conserve resources. Send used product to
recycling center. Dispose of cleanup materials in
accordance with applicable local, state and federal
regulations.
14. TRANSPORT INFORMATION
49 CFR 172.101:
DOT:
Transport Information:
This material when transported via US commerce is NOT REGULATED by DOT
regulations.
Packing group:
DOT reportable quantity (lbs):
TDG (Canada):
Packing group:
Regulated substances:
MSDS ID NO.: 0191MAR019
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Product name: Marathon Marafluid 4
Transmission & Drive Train Fluid
Page 5 of 8
Page 208 of 320
15. REGULATORY INFORMATION
Federal Regulatory Information:
US TSCA Chemical Inventory Section 8(b):
This product and/or its components are listed on the TSCA
Chemical Inventory.
OSHA Hazard Communication Standard:
This product has been evaluated and determined not to be
hazardous as defined in OSHA's Hazard Communication
Standard.
EPA Superfund Amendment & Reauthorization Act (SARA):
SARA Section 302:
This product contains the following component(s) that have been listed on EPA's
Extremely Hazardous Substance (EHS) List:
Name
Distillates, Petroleum SolventRefined Heavy Paraffinic
Residual Oils (Petroleum). Solvent
Refined
Additives
Zinc Alkyl Dithiophosphate
SARA Section 304:
CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs
NA
NA
NA
NA
This product contains the following component(s) identified either as an EHS or a
CERCLA Hazardous substance which in case of a spill or release may be subject to
SARA reporting requirements:
Name
Distillates, Petroleum SolventRefined Heavy Paraffinic
Residual Oils (Petroleum). Solvent
Refined
Additives
Zinc Alkyl Dithiophosphate
SARA Section 311/312:
CERCLA/SARA - Hazardous Substances and their Reportable Quantities
NA
NA
NA
NA
The following EPA hazard categories apply to this product:
None
SARA Section 313:
This product contains the following component(s) that may be subject to reporting on
the Toxic Release Inventory (TRI) From R:
Name
Distillates, Petroleum SolventRefined Heavy Paraffinic
Residual Oils (Petroleum). Solvent
Refined
Additives
Zinc Alkyl Dithiophosphate
CERCLA/SARA 313 Emission reporting:
None
None
None
None
State and Community Right-To-Know Regulations:
The following component(s) of this material are identified on the regulatory lists below:
Distillates, Petroleum Solvent-Refined Heavy Paraffinic
Louisiana Right-To-Know:
California Proposition 65:
New Jersey Right-To-Know:
Pennsylvania Right-To-Know:
Massachusetts Right-To Know:
Florida substance List:
MSDS ID NO.: 0191MAR019
Not Listed
Not Listed
Not Listed.
Not Listed.
Not Listed.
Not Listed.
Product name: Marathon Marafluid 4
Transmission & Drive Train Fluid
Page 6 of 8
Page 209 of 320
Rhode Island Right-To-Know:
Michigan critical materials register list:
Massachusetts Extraordinarily Hazardous
Substances:
California - Regulated Carcinogens:
Pennsylvania RTK - Special Hazardous
Substances:
New Jersey - Special Hazardous Substances:
New Jersey - Environmental Hazardous
Substances List:
Illinois - Toxic Air Contaminants
New York - Reporting of Releases Part 597 List of Hazardous Substances:
Residual Oils (Petroleum). Solvent Refined
Louisiana Right-To-Know:
California Proposition 65:
New Jersey Right-To-Know:
Pennsylvania Right-To-Know:
Massachusetts Right-To Know:
Florida substance List:
Rhode Island Right-To-Know:
Michigan critical materials register list:
Massachusetts Extraordinarily Hazardous
Substances:
California - Regulated Carcinogens:
Pennsylvania RTK - Special Hazardous
Substances:
New Jersey - Special Hazardous Substances:
New Jersey - Environmental Hazardous
Substances List:
Illinois - Toxic Air Contaminants
New York - Reporting of Releases Part 597 List of Hazardous Substances:
Additives
Louisiana Right-To-Know:
California Proposition 65:
New Jersey Right-To-Know:
Pennsylvania Right-To-Know:
Massachusetts Right-To Know:
Florida substance List:
Rhode Island Right-To-Know:
Michigan critical materials register list:
Massachusetts Extraordinarily Hazardous
Substances:
California - Regulated Carcinogens:
Pennsylvania RTK - Special Hazardous
Substances:
New Jersey - Special Hazardous Substances:
New Jersey - Environmental Hazardous
Substances List:
Illinois - Toxic Air Contaminants
New York - Reporting of Releases Part 597 List of Hazardous Substances:
Zinc Alkyl Dithiophosphate
Louisiana Right-To-Know:
California Proposition 65:
MSDS ID NO.: 0191MAR019
Not Listed
Not Listed.
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed.
Not Listed.
Not Listed.
Not Listed.
Not Listed
Not Listed.
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed.
Not Listed.
Not Listed.
Not Listed.
Not Listed
Not Listed.
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Product name: Marathon Marafluid 4
Transmission & Drive Train Fluid
Page 7 of 8
Page 210 of 320
New Jersey Right-To-Know:
Pennsylvania Right-To-Know:
Massachusetts Right-To Know:
Florida substance List:
Rhode Island Right-To-Know:
Michigan critical materials register list:
Massachusetts Extraordinarily Hazardous
Substances:
California - Regulated Carcinogens:
Pennsylvania RTK - Special Hazardous
Substances:
New Jersey - Special Hazardous Substances:
New Jersey - Environmental Hazardous
Substances List:
Illinois - Toxic Air Contaminants
New York - Reporting of Releases Part 597 List of Hazardous Substances:
Not Listed.
Not Listed.
Not Listed.
Not Listed.
Not Listed
Not Listed.
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Canadian Regulatory Information:
Canada DSL/NDSL Inventory:
This product and/or its components are listed either on the Domestic Substances List
(DSL) or are exempt.
16. OTHER INFORMATION
Additional Information:
No data available.
Prepared by:
Craig M. Parker Manager, Toxicology and Product Safety
The information and recommendations contained herein are based upon tests believed to be reliable. However,
Marathon Petroleum Company LLC (MPC) does not guarantee their accuracy or completeness nor shall any of this
information constitute a warranty, whether expressed or implied, as to the safety of the goods, the merchantability of the
goods, or the fitness of the goods for a particular purpose. Adjustment to conform to actual conditions of usage maybe
required. MPC assumes no responsibility for results obtained or for incidental or consequential damages, including lost
profits arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made
or implied.
End of Safety Data Sheet
MSDS ID NO.: 0191MAR019
Product name: Marathon Marafluid 4
Transmission & Drive Train Fluid
Page 8 of 8
Page 211 of 320
Material Safety Data Sheet
0170MAR019
06/02/2006
MSDS ID NO.:
Revision date:
1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Product code:
MR0346, MR0350, MR0355, MR0357,
Product name:
Synonym:
Marathon Multi-Purpose Hydraulic Oil
Marathon Multipurpose Hydraulic Oil; ISO 32 Multi-Purpose Hydraulic Oil; ISO 46
Multi-Purpose Hydraulic Oil; ISO 68 Multi-Purpose Hydraulic Oil; ISO 100 MultiPurpose Hydraulic Oil
Motor/Lube Oil
Mixture
Chemical Family:
Formula:
Manufacturer:
Marathon Petroleum Company LLC
539 South Main Street
Findlay OH 45840
Other information:
Emergency telephone number:
419-421-3070
877-627-5463
2. COMPOSITION/INFORMATION ON INGREDIENTS
Lube oil is a complex mixture of highly refined lubricating base stocks and additives.
Product information:
Name
CAS Number
Weight %
Marathon Multi-Purpose Hydraulic Oil
Mixture
100
Name
CAS Number
Weight %
Distillates, Petroleum SolventRefined Heavy Paraffinic
64741-88-4
30-99
Petroleum Distillates, Hydrotreated
Heavy Paraffinic
64742-54-7
0-70
Additives
Not specified
<1
ACGIH Exposure
Limits:
OSHA - Vacated
PELs - Time
Weighted Ave
Other:
ACGIH Exposure
Limits:
OSHA - Vacated
PELs - Time
Weighted Ave
Other:
Component Information:
Notes:
MSDS ID NO.: 0170MAR019
Mineral Oil Mist
(MOM)
=5 mg/m3 TWA
= 10 mg/m3 STEL
Mineral Oil Mist
(MOM)
=5 mg/m3 TWA
= 10 mg/m3 STEL
The manufacturer has voluntarily elected to reflect exposure limits contained in
OSHA's 1989 air contaminants standard in its MSDS's, even though certain of those
exposure limits were vacated in 1992.
Product name: Marathon Multi-Purpose Hydraulic
Oil
Page 1 of 8
Page 212 of 320
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
THIS PRODUCT IS A NON-VOLATILE AND NON-COMBUSTIBLE, YELLOW BROWN COLORED LIQUID, BUT WILL
IGNITE AND BURN AT ELEVATED TEMPERATURES.
OSHA WARNING LABEL:
THIS PRODUCT HAS BEEN EVALUATED AND DOES NOT REQUIRE ANY HAZARD WARNING LABEL UNDER
THE OSHA HAZARD COMMUNICATION STANDARD.
CONSUMER WARNING LABEL:
A CONSUMER WARNING LABEL IS NOT APPLICABLE FOR THIS PRODUCT.
Inhalation:
No acute effects expected from routine operations. Overheating of product may
produce vapors which can cause respiratory irritation, dizziness and nausea.
Ingestion:
Product has a low order of acute toxicity. This is based on data from components or
similar products.
Skin contact:
Prolonged or repeated liquid contact can cause dermatitis, folliculitis or oil acne.
Eye contact:
Liquid or vapor contact may result in slight eye irritation.
Carcinogenic Evaluation:
Product information:
Name
Marathon Multi-Purpose Hydraulic Oil
Mixture
Notes:
IARC
Carcinogens:
NE
NTP
Carcinogens:
ACGIH Carcinogens:
OSHA - Select
Carcinogens:
The International Agency for Research on Cancer (IARC) has determined that there
is no evidence that severely solvent-refined oils are carcinogenic to experimental
animals.
Component Information:
4. FIRST AID MEASURES
Inhalation:
If affected, move person to fresh air. If breathing is difficult, administer oxygen. If not
breathing or if no heartbeat, give artificial respiration or cardiopulmonary
resuscitation (CPR). Immediately call a physician. If symptoms or irritation occur with
any exposure, call a physician.
Skin contact:
Wash with soap and large amounts of water. Remove contaminated clothing. If
symptoms or irritation occur, call a physician.
If product is accidentally injected into or under the skin, regardless of wound size or
initial absence of symptoms, the individual should be evaluated immediately by a
physician as a surgical emergency.
Ingestion:
Not expected to be acutely toxic. If large amounts are swallowed, immediately call a
physician.
Eye contact:
Flush eyes with large amounts of tepid water for at least 15 minutes. If symptoms or
irritation occur, call a physician.
MSDS ID NO.: 0170MAR019
Product name: Marathon Multi-Purpose Hydraulic
Oil
Page 2 of 8
Page 213 of 320
Notes to physician:
High velocity injection under the skin may result in serious injury. If left untreated the
affected area is subject to infection, disfigurement, lack of blood circulation and may
require amputation. When dispensed by high pressure equipment this material can
easily penetrate the skin and leave a bloodless puncture wound. Material injected
into a finger can be deposited into the palm of the hand. Within 24-48 hours the
patient may experience swelling, discoloration, and throbbing pain in the affected
area. Immediate treatment by a surgical specialist is recommended.
Medical conditions aggravated
by exposure:
Skin contact could aggravate an existing skin disorder or dermatitis condition.
5. FIRE FIGHTING MEASURES
Suitable extinguishing media:
Specific hazards:
Special protective equipment for firefighters:
For small fires, Class B fire extinguishing media such as
CO2, dry chemical, foam (AFFF/ATC) or water spray can be
used. For large fires, water spray, fog or foam (AFFT/ATC)
can be used. Fire fighting should be attempted only by those
who are adequately trained and equipped with proper
protective equipment.
This material is not combustible per the OSHA Hazard
Communication Standard, but will ignite and burn at elevated
temperatures.
Avoid using straight water streams. Water spray and foam
(AFFF/ATC) must be applied carefully to avoid frothing and
from as far a distance as possible. Avoid excessive water
spray application. Use water spray to cool exposed surfaces
from as far a distance as possible. Keep run-off water out of
sewers and water sources.
Flash point:
Autoignition temperature:
Flammable limits in air - lower (%):
Flammable limits in air - upper (%):
400, 405, 410 or >420 F
No data available.
No data available.
No data available.
NFPA rating:
Health: 1
Flammability: 1
Reactivity: 0
Other: -
HMIS classification:
Health: 1
Flammability: 1
Reactivity: 0
Special: *See Section 8 for guidance in selection of
personal protective equipment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions:
Keep public away. Isolate and evacuate area. Shut off source if safe to do so.
Advise authorities and National Response Center (800-424-8802) if substance has
entered a watercourse or sewer. Advise local and state emergency services
agencies, if appropriate. Contain liquid with sand or soil. Recover and return free
product to proper containers. Use suitable absorbent materials such as vermiculite,
sand, or clay to clean up residual liquids.
7. HANDLING AND STORAGE
Handling:
MSDS ID NO.: 0170MAR019
Product name: Marathon Multi-Purpose Hydraulic
Oil
Page 3 of 8
Page 214 of 320
Comply with all applicable EPA, OSHA, NFPA and consistent state and local requirements. Use appropriate grounding
and bonding practices. Store in properly closed containers that are appropriately labeled and in a cool well-ventilated
area. Do not cut, drill, grind or weld on empty containers since they may contain explosive residues. Do not pressurize
or expose to heat, open flames, strong oxidizers or other sources of ignition.
Avoid repeated and prolonged skin contact. Exercise good personal hygiene including removal of soiled clothing and
prompt washing with soap and water.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT
Engineering measures:
Local or general exhaust required when using at elevated temperatures that
generate vapors or mists.
Respiratory protection:
Not required under normal conditions and adequate ventilation. Approved organic
vapor chemical cartridge or supplied air respirators should be worn when significant
vapors are generated. Observe respirator protection factor criteria cited in ANSI
Z88.2. Self-contained breathing apparatus should be used for fire fighting.
Skin and body protection:
Use chemical resistant gloves such as neoprene, nitrile, or PVA to prevent prolonged
or repeated skin contact.
Eye protection:
No special eye protection is normally required.
Hygiene measures:
No data available.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Appearance:
Physical state (Solid/Liquid/Gas):
Substance type (Pure/Mixture):
Color:
Odor:
Molecular weight:
pH:
Boiling point/range (5-95%):
Melting point/range:
Decomposition temperature:
Specific gravity:
Density:
Bulk density:
Vapor density:
Vapor pressure:
Evaporation rate:
Solubility:
Solubility in other solvents:
Partition coefficient (n-octanol/water):
VOC content(%):
Viscosity:
Yellow Brown Liquid
Liquid
Mixture
Yellow-brown
Hydrocarbon
Not determined.
Neutral
>425 F
Not determined.
Not applicable.
Not determined
7.28, 7.32, 7.36 or 7.39 lbs/gal @ 60 F
No data available.
No data available.
<1 mm Hg @ 100 F
No data available.
<1%
No data available.
>4.9
No data available.
32.5, 46.0, 69.8 or 100.0 cSt @ 40 C
5.2, 6.6, 8.3 or 11.2 cSt @ 100 C
10. STABILITY AND REACTIVITY
Stability:
The material is stable at 70 F, 760 mm pressure.
Polymerization:
Will not occur.
MSDS ID NO.: 0170MAR019
Product name: Marathon Multi-Purpose Hydraulic
Oil
Page 4 of 8
Page 215 of 320
Hazardous decomposition products:
Carbon monoxide, carbon dioxide, aldehydes, hydrogen
sulfide, oxides of sulfur, oxides of nitrogen and oxides of
phosphorous.
Materials to avoid:
Strong oxidizers such as nitrates, chlorates, peroxides.
Conditions to avoid:
Heat and open flames.
11. TOXICOLOGICAL INFORMATION
Acute toxicity:
Product information:
Name
Marathon Multi-Purpose Hydraulic Oil
CAS Number
Mixture
Inhalation:
LD50 = 2.18 to >4 mg/l
[Rat]
Dermal:
LD50 >2 gm/kg
[Rabbit]
Oral:
LD50 > 5 ml/kg
[Rat]
Based on data from components this product is considered to have a low order of acute oral and dermal toxicity. Chronic
skin painting studies with severely solvent refined neutral oils did not produce evidence of skin cancer in mice.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects:
Water accomated fractions (WAF) of highly refined base oils did not produce acute
toxicity in fish (100-1000 mg/l), fresh water algae (500 mg/l) or daphnia (10,000 mg/l)
in 48-96 hour LC50 studies.
Used motor and/or lube oils can be toxic to birds and fish.
13. DISPOSAL CONSIDERATIONS
This material as supplied and by itself, when discarded or
disposed of, is not an EPA RCRA hazardous waste
according to federal regulations. This material could become
a hazardous waste if mixed or contaminated with a
hazardous waste or other substance(s). It is the
responsibility of the user to determine if disposal material is
hazardous according to federal, state and local regulations.
Cleanup Considerations:
Don't pollute. Conserve resources. Send used product to
recycling center. Dispose of cleanup materials in
accordance with applicable local, state and federal
regulations.
14. TRANSPORT INFORMATION
49 CFR 172.101:
DOT:
Transport Information:
This material when transported via US commerce is NOT REGULATED by DOT
regulations.
Packing group:
DOT reportable quantity (lbs):
TDG (Canada):
Packing group:
MSDS ID NO.: 0170MAR019
Not applicable.
Not applicable.
Not applicable.
Product name: Marathon Multi-Purpose Hydraulic
Oil
Page 5 of 8
Page 216 of 320
Not applicable.
Regulated substances:
15. REGULATORY INFORMATION
Federal Regulatory Information:
US TSCA Chemical Inventory Section 8(b):
This product and/or its components are listed on the TSCA
Chemical Inventory.
OSHA Hazard Communication Standard:
This product has been evaluated and determined not to be
hazardous as defined in OSHA's Hazard Communication
Standard.
EPA Superfund Amendment & Reauthorization Act (SARA):
SARA Section 302:
This product contains the following component(s) that have been listed on EPA's
Extremely Hazardous Substance (EHS) List:
Name
Distillates, Petroleum SolventRefined Heavy Paraffinic
Petroleum Distillates, Hydrotreated
Heavy Paraffinic
Additives
SARA Section 304:
CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs
NA
NA
NA
This product contains the following component(s) identified either as an EHS or a
CERCLA Hazardous substance which in case of a spill or release may be subject to
SARA reporting requirements:
Name
Distillates, Petroleum SolventRefined Heavy Paraffinic
Petroleum Distillates, Hydrotreated
Heavy Paraffinic
Additives
SARA Section 311/312:
CERCLA/SARA - Hazardous Substances and their Reportable Quantities
NA
NA
NA
The following EPA hazard categories apply to this product:
None
SARA Section 313:
This product contains the following component(s) that may be subject to reporting on
the Toxic Release Inventory (TRI) From R:
Name
Distillates, Petroleum SolventRefined Heavy Paraffinic
Petroleum Distillates, Hydrotreated
Heavy Paraffinic
Additives
CERCLA/SARA 313 Emission reporting:
None
None
None
State and Community Right-To-Know Regulations:
The following component(s) of this material are identified on the regulatory lists below:
Distillates, Petroleum Solvent-Refined Heavy Paraffinic
Louisiana Right-To-Know:
California Proposition 65:
New Jersey Right-To-Know:
Pennsylvania Right-To-Know:
Massachusetts Right-To Know:
Florida substance List:
Rhode Island Right-To-Know:
MSDS ID NO.: 0170MAR019
Not Listed
Not Listed
Not Listed.
Not Listed.
Not Listed.
Not Listed.
Not Listed
Product name: Marathon Multi-Purpose Hydraulic
Oil
Page 6 of 8
Page 217 of 320
Michigan critical materials register list:
Massachusetts Extraordinarily Hazardous
Substances:
California - Regulated Carcinogens:
Pennsylvania RTK - Special Hazardous
Substances:
New Jersey - Special Hazardous Substances:
New Jersey - Environmental Hazardous
Substances List:
Illinois - Toxic Air Contaminants
New York - Reporting of Releases Part 597 List of Hazardous Substances:
Petroleum Distillates, Hydrotreated Heavy Paraffinic
Louisiana Right-To-Know:
California Proposition 65:
New Jersey Right-To-Know:
Pennsylvania Right-To-Know:
Massachusetts Right-To Know:
Florida substance List:
Rhode Island Right-To-Know:
Michigan critical materials register list:
Massachusetts Extraordinarily Hazardous
Substances:
California - Regulated Carcinogens:
Pennsylvania RTK - Special Hazardous
Substances:
New Jersey - Special Hazardous Substances:
New Jersey - Environmental Hazardous
Substances List:
Illinois - Toxic Air Contaminants
New York - Reporting of Releases Part 597 List of Hazardous Substances:
Additives
Louisiana Right-To-Know:
California Proposition 65:
New Jersey Right-To-Know:
Pennsylvania Right-To-Know:
Massachusetts Right-To Know:
Florida substance List:
Rhode Island Right-To-Know:
Michigan critical materials register list:
Massachusetts Extraordinarily Hazardous
Substances:
California - Regulated Carcinogens:
Pennsylvania RTK - Special Hazardous
Substances:
New Jersey - Special Hazardous Substances:
New Jersey - Environmental Hazardous
Substances List:
Illinois - Toxic Air Contaminants
New York - Reporting of Releases Part 597 List of Hazardous Substances:
Not Listed.
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed.
Not Listed.
Not Listed.
Not Listed.
Not Listed
Not Listed.
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed.
Not Listed.
Not Listed.
Not Listed.
Not Listed
Not Listed.
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Canadian Regulatory Information:
Canada DSL/NDSL Inventory:
MSDS ID NO.: 0170MAR019
This product and/or its components are listed either on the Domestic Substances List
(DSL) or are exempt.
Product name: Marathon Multi-Purpose Hydraulic
Oil
Page 7 of 8
Page 218 of 320
16. OTHER INFORMATION
Additional Information:
No data available.
Prepared by:
Craig M. Parker Manager, Toxicology and Product Safety
The information and recommendations contained herein are based upon tests believed to be reliable. However,
Marathon Petroleum Company LLC (MPC) does not guarantee their accuracy or completeness nor shall any of this
information constitute a warranty, whether expressed or implied, as to the safety of the goods, the merchantability of the
goods, or the fitness of the goods for a particular purpose. Adjustment to conform to actual conditions of usage maybe
required. MPC assumes no responsibility for results obtained or for incidental or consequential damages, including lost
profits arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made
or implied.
End of Safety Data Sheet
MSDS ID NO.: 0170MAR019
Product name: Marathon Multi-Purpose Hydraulic
Oil
Page 8 of 8
Page 219 of 320
Material Safety Data Sheet
0162MAR019
12/07/2010
MSDS ID NO.:
Revision date:
1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Marathon Multipower-3 15W-40 Motor Oil
Multipower-3 15W-40 Motor Oil; Multipower-3 15W-40 Heavy Duty Motor Oil
Motor/Lube Oil
Mixture
Product name:
Synonym:
Chemical Family:
Formula:
Manufacturer:
Marathon Petroleum Company LP
539 South Main Street
Findlay OH 45840
Other information:
Emergency telephone number:
419-421-3070
877-627-5463
2. COMPOSITION/INFORMATION ON INGREDIENTS
Motor oil is a complex mixture of highly refined lubricating oil base stocks and additives.
Product information:
Name
CAS Number
Weight %
Marathon Multipower-3 15W-40
Motor Oil
Mixture
100
Name
CAS Number
Weight %
Distillates, Petroleum SolventRefined Heavy Paraffinic
64741-88-4
89-93
Additives
Zinc Dialkyl Dithiophosphate
Not specified
68457-79-4
7-11
1.2-1.5
ACGIH Exposure
Limits:
OSHA - Vacated
PELs - Time
Weighted Ave
Other:
ACGIH Exposure
Limits:
OSHA - Vacated
PELs - Time
Weighted Ave
Other:
Component Information:
Notes:
MSDS ID NO.: 0162MAR019
Mineral Oil Mist
(MOM)
=5 mg/m3 TWA
= 10 mg/m3 STEL
The manufacturer has voluntarily elected to reflect exposure limits contained in
OSHA's 1989 air contaminants standard in its MSDS's, even though certain of those
exposure limits were vacated in 1992.
Product name: Marathon Multipower-3 15W-40
Motor Oil
Page 1 of 9
Page 220 of 320
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
MOTOR OIL IS A NON-VOLATILE AND NON-COMBUSTIBLE, AMBER COLORED LIQUID, BUT WILL IGNITE AND
BURN AT ELEVATED TEMPERATURES.
Inhalation:
No acute effects expected from routine operations. Overheating of product may produce vapors which can cause
respiratory irritation, dizziness and nausea.
Ingestion:
Product has a low order of acute toxicity. This is based on data from components or similar products.
Skin contact:
Prolonged or repeated liquid contact can cause dermatitis, folliculitis or oil acne.
Eye contact:
Liquid or vapor contact may result in slight eye irritation.
Carcinogenic Evaluation:
Product information:
Name
Marathon Multipower-3 15W-40
Motor Oil
Mixture
IARC
Carcinogens:
NE
NTP
Carcinogens:
ACGIH Carcinogens:
OSHA - Select
Carcinogens:
The International Agency for Research on Cancer (IARC) has determined that there
is no evidence that severely solvent-refined oils are carcinogenic to experimental
animals.
Notes:
Component Information:
Name
Distillates, Petroleum SolventRefined Heavy Paraffinic
64741-88-4
IARC
Carcinogens:
Supplement 7 [1987],
Monograph 33 [1984]
NTP
Carcinogens:
ACGIH Carcinogens:
OSHA - Select
Carcinogens:
Present
4. FIRST AID MEASURES
Eye Contact:
Flush eyes with large amounts of tepid water for at least 15 minutes. If symptoms or
irritation occur, call a physician.
Skin Contact:
Wash with soap and large amounts of water. Remove contaminated clothing. If
symptoms or irritation occur, call a physician.
If product is accidentally injected into or under the skin, regardless of wound size or
initial absence of symptoms, the individual should be evaluated immediately by a
physician as a surgical emergency.
Ingestion:
Not expected to be acutely toxic. If large amounts are swallowed, immediately call a
physician.
Inhalation:
MSDS ID NO.: 0162MAR019
Product name: Marathon Multipower-3 15W-40
Motor Oil
Page 2 of 9
Page 221 of 320
4. FIRST AID MEASURES
If affected, move person to fresh air. If breathing is difficult, administer oxygen. If not
breathing or if no heartbeat, give artificial respiration or cardiopulmonary
resuscitation (CPR). Immediately call a physician. If symptoms or irritation occur with
any exposure, call a physician.
NOTES TO PHYSICIAN:
No data available.
Medical Conditions
Aggravated
By Exposure:
Skin contact could aggravate an existing skin disorder or dermatitis condition.
5. FIRE FIGHTING MEASURES
Suitable extinguishing media:
Specific hazards:
Special protective equipment for firefighters:
Flash point:
Autoignition temperature:
Flammable limits in air - lower (%):
Flammable limits in air - upper (%):
For small fires, Class B fire extinguishing media such as
CO2, dry chemical, foam (AFFF/ATC) or water spray can be
used. For large fires, water spray, fog or foam (AFFF/ATC)
can be used. Fire fighting should be attempted only by those
who are adequately trained and equipped with proper
protective equipment.
This material is not combustible per the OSHA Hazard
Communication Standard, but will ignite and burn at elevated
temperatures.
Avoid using straight water streams. Water spray and foam
(AFFF/ATC) must be applied carefully to avoid frothing and
from as far a distance as possible. Avoid excessive water
spray application. Use water spray to cool exposed surfaces
from as far a distance as possible. Keep run-off water out of
sewers and water sources.
>425 F, 218.3 C
No data available.
No data available.
No data available.
NFPA rating:
Health: 1
Flammability: 1
Instability: 0
Other: -
6. ACCIDENTAL RELEASE MEASURES
Personal precautions:
Keep public away. Isolate and evacuate area. Shut off source if safe to do so.
Advise authorities and National Response Center (800-424-8802) if the product has
entered a water course or sewer. Advise local and state emergency services
agencies, if appropriate. Contain liquid with sand or soil. Recover and return free
product to proper containers. Use suitable absorbent materials such as vermiculite,
sand, or clay to clean up residual liquids.
7. HANDLING AND STORAGE
Handling:
MSDS ID NO.: 0162MAR019
Product name: Marathon Multipower-3 15W-40
Motor Oil
Page 3 of 9
Page 222 of 320
7. HANDLING AND STORAGE
Comply with all applicable EPA, OSHA, NFPA and consistent state and local requirements. Use appropriate grounding
and bonding practices. Store in properly closed containers that are appropriately labeled and in a cool well-ventilated
area. Do not cut, drill, grind or weld on empty containers since they may contain explosive residues. Do not pressurize
or expose to heat, open flames, strong oxidizers or other sources of ignition.
Avoid repeated and prolonged skin contact. Exercise good personal hygiene including removal of soiled clothing and
prompt washing with soap and water.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT
Engineering measures:
Local or general exhaust required when using at elevated temperatures that
generate vapors or mists.
Respiratory protection:
Not required under normal conditions and adequate ventilation. Approved organic
vapor chemical cartridge or supplied air respirators should be worn when significant
vapors are generated. Observe respirator assigned protection factors (APFs)
criteria cited in federal OSHA 1910.134. Self-contained breathing apparatus should
be used for fire fighting.
Skin and body protection:
Use chemical resistant gloves such as neoprene, nitrile, or PVA to prevent prolonged
or repeated skin contact.
Eye protection:
No special eye protection is normally required.
Hygiene measures:
No data available.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Appearance:
Physical state (Solid/Liquid/Gas):
Substance type (Pure/Mixture):
Color:
Odor:
Molecular weight:
pH:
Boiling point/range (5-95%):
Melting point/range:
Decomposition temperature:
Specific gravity:
Density:
Bulk density:
Vapor density:
Vapor pressure:
Evaporation rate:
Solubility:
Solubility in other solvents:
Partition coefficient (n-octanol/water):
VOC content(%):
Viscosity:
Amber Liquid
Liquid
Mixture
Amber
Hydrocarbon
Not determined.
Neutral
>425 F, >218.3 C
Not determined.
Not applicable.
0.890 @ 60 F
7.44 lbs/gal @ 60 F
No data available.
No data available.
<1 mm Hg @ 100 F
No data available.
<1%
No data available.
>4.9
No data available.
118.1 cSt @ 40 C
15.0 cSt @ 100 C
10. STABILITY AND REACTIVITY
MSDS ID NO.: 0162MAR019
Product name: Marathon Multipower-3 15W-40
Motor Oil
Page 4 of 9
Page 223 of 320
10. STABILITY AND REACTIVITY
Stability:
The material is stable at 70 F, 760 mm pressure.
Polymerization:
Will not occur.
Hazardous decomposition products:
Carbon monoxide, carbon dioxide, hydrogen sulfide, oxides
of sulfur, oxides of nitrogen, oxides of phosphorous, oxides
of magnesium, boric oxide, calcium oxide and zinc oxide. ,
Thermal decomposition may produce hydrogen sulfide and
other sulfur-containing gases at temperatures greater than
150 F.
Materials to avoid:
Strong oxidizers such as nitrates, chlorates, peroxides.
Conditions to avoid:
Heat and open flames.
11. TOXICOLOGICAL INFORMATION
Acute toxicity:
Product information:
Name
Marathon Multipower-3 15W-40
Motor Oil
CAS Number
Mixture
Inhalation:
LD50 = 2.18 to > 4mg/l
[Rat]
Dermal:
LD50 > 2 gm/kg
[Rabbit]
Oral:
LD50 > 5 ml/kg
[Rat]
Toxicology Information:
Based on data from components this product is considered to have a low order of
acute oral and dermal toxicity. Chronic skin painting studies with severely solvent
refined neutral oils did not produce evidence of skin cancer in mice.
This product contains approximately 0-1.5% of a zinc alkyl dithiophosphate (ZDDP)
additive. ZDDP has been found to have weak mutagenic activity in cultured cells.
Repeated dermal exposures of ZDDP produced severe skin irritation, significant
weight loss and testicular atrophy in male rabbits but not male rats at high
concentrations. Subsequent research showed that the testicular effect was due to the
severe stress and weight loss as seen with other caustic materials and not a direct
effect of ZDDP. The concentration of ZDDP in this product is significantly lower than
exposure levels that produced these effects in rabbits.
Used motor oil applied to the skin of rabbits at doses of 8 ml/kg/day, 5 days/wk, for
two weeks, produced significant weight loss and skin irritation but no mortality. Used
motor oil was found to produce skin tumors in mice in lifetime skin painting studies.
Solvent extracts of used motor oils were found to be positive in the Ames
mutagenicity test.
12. ECOTOXICOLOGICAL INFORMATION
Mobility:
No data available.
Ecotoxicity:
No data available.
Bioaccummulation:
No data available.
MSDS ID NO.: 0162MAR019
Product name: Marathon Multipower-3 15W-40
Motor Oil
Page 5 of 9
Page 224 of 320
12. ECOTOXICOLOGICAL INFORMATION
Persistance/Biodegradation:
Water accomated fractions (WAF) of highly refined base oils did not produce acute
toxicity in fish (100-1000 mg/l), fresh water algae (500 mg/l) or daphnia (10,000 mg/l)
in 48-96 hour LC50 studies.
Used motor and/or lube oils can be toxic to birds and fish.
13. DISPOSAL CONSIDERATIONS
This material as supplied and by itself, when discarded or
disposed of, is not an EPA RCRA hazardous waste
according to federal regulations. This material could become
a hazardous waste if mixed or contaminated with a
hazardous waste or other substance(s). It is the
responsibility of the user to determine if disposal material is
hazardous according to federal, state and local regulations.
Cleanup Considerations:
Don't pollute. Conserve resources. Send used product to
recycling center. Dispose of cleanup materials in
accordance with applicable local, state and federal
regulations.
14. TRANSPORT INFORMATION
49 CFR 172.101:
DOT:
This material when transported via US commerce is NOT REGULATED by DOT
regulations.
Not applicable.
Packing group:
Not applicable.
DOT reportable quantity (lbs):
Transport Information:
15. REGULATORY INFORMATION
US Federal Regulatory
Information:
US TSCA Chemical Inventory Section 8(b):
This product and/or its components are listed on the TSCA
Chemical Inventory.
OSHA Hazard Communication Standard:
This product has been evaluated and determined not to be
hazardous as defined in OSHA's Hazard Communication
Standard.
EPA Superfund Amendment & Reauthorization Act (SARA):
MSDS ID NO.: 0162MAR019
Product name: Marathon Multipower-3 15W-40
Motor Oil
Page 6 of 9
Page 225 of 320
SARA Section 302:
This product contains the following component(s) that have been listed on EPA's
Extremely Hazardous Substance (EHS) List:
Name
Distillates, Petroleum SolventRefined Heavy Paraffinic
Additives
Zinc Dialkyl Dithiophosphate
SARA Section 304:
CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs
NA
NA
NA
This product contains the following component(s) identified either as an EHS or a
CERCLA Hazardous substance which in case of a spill or release may be subject to
SARA reporting requirements:
Name
Distillates, Petroleum SolventRefined Heavy Paraffinic
Additives
Zinc Dialkyl Dithiophosphate
SARA Section 311/312
CERCLA/SARA - Hazardous Substances and their Reportable Quantities
NA
NA
NA
The following EPA hazard categories apply to this product:
None
SARA Section 313:
This product contains the following component(s) that may be subject to reporting on
the Toxic Release Inventory (TRI) From R:
Name
Distillates, Petroleum SolventRefined Heavy Paraffinic
Additives
Zinc Dialkyl Dithiophosphate
CERCLA/SARA 313 Emission reporting:
None
None
= 1.0 % de minimis concentration
State and Community Right-To-Know Regulations:
The following component(s) of this material are identified on the regulatory lists below:
Distillates, Petroleum Solvent-Refined Heavy Paraffinic
Louisiana Right-To-Know:
California Proposition 65:
New Jersey Right-To-Know:
Pennsylvania Right-To-Know:
Massachusetts Right-To Know:
Florida substance List:
Rhode Island Right-To-Know:
Michigan critical materials register list:
Massachusetts Extraordinarily Hazardous
Substances:
California - Regulated Carcinogens:
Pennsylvania RTK - Special Hazardous
Substances:
New Jersey - Special Hazardous Substances:
New Jersey - Environmental Hazardous
Substances List:
Illinois - Toxic Air Contaminants
New York - Reporting of Releases Part 597 List of Hazardous Substances:
Additives
Louisiana Right-To-Know:
California Proposition 65:
MSDS ID NO.: 0162MAR019
Not Listed
Not Listed
Not Listed.
Not Listed.
Not Listed.
Not Listed.
Not Listed
Not Listed.
Not Listed
Not Listed
Not Listed
carcinogen
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Product name: Marathon Multipower-3 15W-40
Motor Oil
Page 7 of 9
Page 226 of 320
Distillates, Petroleum Solvent-Refined Heavy Paraffinic
New Jersey Right-To-Know:
Pennsylvania Right-To-Know:
Massachusetts Right-To Know:
Florida substance List:
Rhode Island Right-To-Know:
Michigan critical materials register list:
Massachusetts Extraordinarily Hazardous
Substances:
California - Regulated Carcinogens:
Pennsylvania RTK - Special Hazardous
Substances:
New Jersey - Special Hazardous Substances:
New Jersey - Environmental Hazardous
Substances List:
Illinois - Toxic Air Contaminants
New York - Reporting of Releases Part 597 List of Hazardous Substances:
Zinc Dialkyl Dithiophosphate
Louisiana Right-To-Know:
California Proposition 65:
New Jersey Right-To-Know:
Pennsylvania Right-To-Know:
Massachusetts Right-To Know:
Florida substance List:
Rhode Island Right-To-Know:
Michigan critical materials register list:
Massachusetts Extraordinarily Hazardous
Substances:
California - Regulated Carcinogens:
Pennsylvania RTK - Special Hazardous
Substances:
New Jersey - Special Hazardous Substances:
New Jersey - Environmental Hazardous
Substances List:
Illinois - Toxic Air Contaminants
New York - Reporting of Releases Part 597 List of Hazardous Substances:
Not Listed.
Not Listed.
Not Listed.
Not Listed.
Not Listed
Not Listed.
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
sn 3012
Environmental hazard
Not Listed.
Not Listed.
Not Listed
= 100 lb Annual usage threshold
Not Listed
Not Listed
Not Listed
Not Listed
SN 3012 TPQ 500 lb (Category Code N982. Includes any
unique chemical substance that contains the named metal
as part of that chemical structure)
Not Listed
Not Listed
Canadian Regulatory Information:
Canada DSL/NDSL Inventory:
This product and/or its components are listed either on the Domestic Substances List
(DSL) or are exempt.
NOTE:
Not Applicable.
16. OTHER INFORMATION
Additional Information:
No data available.
Prepared by:
Mark S. Swanson, Manager, Toxicology and Product Safety
MSDS ID NO.: 0162MAR019
Product name: Marathon Multipower-3 15W-40
Motor Oil
Page 8 of 9
Page 227 of 320
The information and recommendations contained herein are based upon tests believed to be reliable. However,
Marathon Petroleum Company LP (MPC) does not guarantee their accuracy or completeness nor shall any of this
information constitute a warranty, whether expressed or implied, as to the safety of the goods, the merchantability of the
goods, or the fitness of the goods for a particular purpose. Adjustment to conform to actual conditions of usage maybe
required. MPC assumes no responsibility for results obtained or for incidental or consequential damages, including lost
profits arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made
or implied.
End of Safety Data Sheet
MSDS ID NO.: 0162MAR019
Product name: Marathon Multipower-3 15W-40
Motor Oil
Page 9 of 9
Page 228 of 320
Material Safety Data Sheet
0163MAR019
06/02/2006
MSDS ID NO.:
Revision date:
1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Product code:
MR0211, MR0222, MR0230, MR0242, MR0246
Product name:
Synonym:
Marathon Multipower-3 Motor Oil
Multipower-3 Heavy Duty Motor Oil; 10W Multipower-3 HD Motor Oil; 20W
Multipower-3 HD Motor Oil; 30 Multipower-3 HD Motor Oil; 40 Multipower-3 HD
Motor Oil; 50 Multipower 3 HD Motor Oil
Motor/Lube Oil
Mixture
Chemical Family:
Formula:
Manufacturer:
Marathon Petroleum Company LLC
539 South Main Street
Findlay OH 45840
Other information:
Emergency telephone number:
419-421-3070
877-627-5463
2. COMPOSITION/INFORMATION ON INGREDIENTS
Motor oil is a complex mixture of highly refined lubricating oil base stocks and additives.
Product information:
Name
CAS Number
Weight %
Marathon Multipower-3 Motor Oil
Mixture
100
Name
CAS Number
Weight %
Distillates, Solvent-refined Heavy
Paraffinic
64741-88-4
20-93
Petroleum Distillates, Hydrotreated
Heavy Paraffinic
64742-54-7
0-70
Additives
Zinc Dialkyl Dithiophosphate
Not specified
68457-79-4
7-10
1.2-1.5
ACGIH Exposure
Limits:
OSHA - Vacated
PELs - Time
Weighted Ave
Other:
ACGIH Exposure
Limits:
OSHA - Vacated
PELs - Time
Weighted Ave
Other:
Component Information:
Notes:
MSDS ID NO.: 0163MAR019
Mineral Oil Mist
(MOM)
=5 mg/m3 TWA
= 10 mg/m3 STEL
Mineral Oil Mist
(MOM)
=5 mg/m3 TWA
= 10 mg/m3 STEL
The manufacturer has voluntarily elected to reflect exposure limits contained in
OSHA's 1989 air contaminants standard in its MSDS's, even though certain of those
exposure limits were vacated in 1992.
Product name: Marathon Multipower-3 Motor Oil
Page 1 of 9
Page 229 of 320
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
MOTOR OIL IS A NON-VOLATILE AND NON-COMBUSTIBLE, AMBER COLORED LIQUID, BUT WILL IGNITE AND
BURN AT ELEVATED TEMPERATURES.
OSHA WARNING LABEL:
THIS PRODUCT HAS BEEN EVALUATED AND DOES NOT REQUIRE ANY HAZARD WARNING LABEL UNDER
THE OSHA HAZARD COMMUNICATION STANDARD.
CONSUMER WARNING LABEL:
A CONSUMER WARNING LABEL IS NOT APPLICABLE FOR THIS PRODUCT.
Inhalation:
No acute effects expected from routine operations. Overheating of product may
produce vapors which can cause respiratory irritation, dizziness and nausea.
Ingestion:
Product has a low order of acute toxicity. This is based on data from components or
similar products.
Skin contact:
Prolonged or repeated liquid contact can cause dermatitis, folliculitis or oil acne.
Eye contact:
Liquid or vapor contact may result in slight eye irritation.
Carcinogenic Evaluation:
Product information:
Name
Marathon Multipower-3 Motor Oil
Mixture
Notes:
IARC
Carcinogens:
NE
NTP
Carcinogens:
ACGIH Carcinogens:
OSHA - Select
Carcinogens:
The International Agency for Research on Cancer (IARC) has determined that there
is no evidence that severely solvent-refined oils are carcinogenic to experimental
animals.
Component Information:
4. FIRST AID MEASURES
Inhalation:
If affected, move person to fresh air. If breathing is difficult, administer oxygen. If not
breathing or if no heartbeat, give artificial respiration or cardiopulmonary
resuscitation (CPR). Immediately call a physician. If symptoms or irritation occur with
any exposure, call a physician.
Skin contact:
Wash with soap and large amounts of water. Remove contaminated clothing. If
symptoms or irritation occur, call a physician.
If product is accidentally injected into or under the skin, regardless of wound size or
initial absence of symptoms, the individual should be evaluated immediately by a
physician as a surgical emergency.
Ingestion:
Not expected to be acutely toxic. If large amounts are swallowed, immediately call a
physician.
Eye contact:
Flush eyes with large amounts of tepid water for at least 15 minutes. If symptoms or
irritation occur, call a physician.
MSDS ID NO.: 0163MAR019
Product name: Marathon Multipower-3 Motor Oil
Page 2 of 9
Page 230 of 320
Notes to physician:
High velocity injection under the skin may result in serious injury. If left untreated the
affected area is subject to infection, disfigurement, lack of blood circulation and may
require amputation. When dispensed by high pressure equipment this material can
easily penetrate the skin and leave a bloodless puncture wound. Material injected
into a finger can be deposited into the palm of the hand. Within 24-48 hours the
patient may experience swelling, discoloration, and throbbing pain in the affected
area. Immediate treatment by a surgical specialist is recommended.
Medical conditions aggravated
by exposure:
Skin contact could aggravate an existing skin disorder or dermatitis condition.
5. FIRE FIGHTING MEASURES
Suitable extinguishing media:
Specific hazards:
Special protective equipment for firefighters:
For small fires, Class B fire extinguishing media such as
CO2, dry chemical, foam (AFFF/ATC) or water spray can be
used. For large fires, water spray, fog or foam (AFFT/ATC)
can be used. Fire fighting should be attempted only by those
who are adequately trained and equipped with proper
protective equipment.
This material is not combustible per the OSHA Hazard
Communication Standard, but will ignite and burn at elevated
temperatures.
Avoid using straight water streams. Water spray and foam
(AFFF/ATC) must be applied carefully to avoid frothing and
from as far a distance as possible. Avoid excessive water
spray application. Use water spray to cool exposed surfaces
from as far a distance as possible. Keep run-off water out of
sewers and water sources.
Flash point:
Autoignition temperature:
Flammable limits in air - lower (%):
Flammable limits in air - upper (%):
>425 F, 218.3 C
No data available.
No data available.
No data available.
NFPA rating:
Health: 1
Flammability: 1
Reactivity: 0
Other: -
HMIS classification:
Health: 1
Flammability: 1
Reactivity: 0
Special: *See Section 8 for guidance in selection of
personal protective equipment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions:
Keep public away. Isolate and evacuate area. Shut off source if safe to do so.
Advise authorities and National Response Center (800-424-8802) if substance has
entered a watercourse or sewer. Advise local and state emergency services
agencies, if appropriate. Contain liquid with sand or soil. Recover and return free
product to proper containers. Use suitable absorbent materials such as vermiculite,
sand, or clay to clean up residual liquids.
7. HANDLING AND STORAGE
Handling:
MSDS ID NO.: 0163MAR019
Product name: Marathon Multipower-3 Motor Oil
Page 3 of 9
Page 231 of 320
Comply with all applicable EPA, OSHA, NFPA and consistent state and local requirements. Use appropriate grounding
and bonding practices. Store in properly closed containers that are appropriately labeled and in a cool well-ventilated
area. Do not cut, drill, grind or weld on empty containers since they may contain explosive residues. Do not pressurize
or expose to heat, open flames, strong oxidizers or other sources of ignition.
Avoid repeated and prolonged skin contact. Exercise good personal hygiene including removal of soiled clothing and
prompt washing with soap and water.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT
Engineering measures:
Local or general exhaust required when using at elevated temperatures that
generate vapors or mists.
Respiratory protection:
Not required under normal conditions and adequate ventilation. Approved organic
vapor chemical cartridge or supplied air respirators should be worn when significant
vapors are generated. Observe respirator protection factor criteria cited in ANSI
Z88.2. Self-contained breathing apparatus should be used for fire fighting.
Skin and body protection:
Use chemical resistant gloves such as neoprene, nitrile, or PVA to prevent prolonged
or repeated skin contact.
Eye protection:
No special eye protection is normally required.
Hygiene measures:
No data available.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Appearance:
Physical state (Solid/Liquid/Gas):
Substance type (Pure/Mixture):
Color:
Odor:
Molecular weight:
pH:
Boiling point/range (5-95%):
Melting point/range:
Decomposition temperature:
Specific gravity:
Density:
Bulk density:
Vapor density:
Vapor pressure:
Evaporation rate:
Solubility:
Solubility in other solvents:
Partition coefficient (n-octanol/water):
VOC content(%):
Viscosity:
Amber Liquid
Liquid
Mixture
Amber
Hydrocarbon
Not determined.
Neutral
No data available.
Not determined.
Not applicable.
Not determined
7.31, 7.37, 7.42, 7.46 or 7.50 lbs/gal @ 60 F
No data available.
No data available.
<1 mm Hg @ 100 F
No data available.
<1%
No data available.
>4.9
No data available.
37.5, 52.2, 86.9, 138.3, 203.9 cSt @ 40 C
6.4, 8.0, 11.0, 14.6, 20.0 cSt @ 100 C
10. STABILITY AND REACTIVITY
Stability:
The material is stable at 70 F, 760 mm pressure.
Polymerization:
Will not occur.
MSDS ID NO.: 0163MAR019
Product name: Marathon Multipower-3 Motor Oil
Page 4 of 9
Page 232 of 320
Hazardous decomposition products:
Carbon monoxide, carbon dioxide, hydrogen sulfide, oxides
of sulfur, oxides of nitrogen, oxides of phosphorous, oxides
of magnesium, boric oxide, calcium oxide and zinc oxide. ,
Thermal decomposition may produce hydrogen sulfide and
other sulfur-containing gases at temperatures greater than
150 F.
Materials to avoid:
Strong oxidizers such as nitrates, chlorates, peroxides.
Conditions to avoid:
Heat and open flames.
11. TOXICOLOGICAL INFORMATION
Acute toxicity:
Product information:
Name
Marathon Multipower-3 Motor Oil
CAS Number
Mixture
Inhalation:
LD50 = 2.18 to >4 mg/l
[Rat]
Dermal:
LD50 > 2 gm/kg
[Rabbit]
Oral:
LD50 > 5 ml/kg
[Rat]
Based on data from components this product is considered to have a low order of acute oral and dermal toxicity. Chronic
skin painting studies with severely solvent refined neutral oils did not produce evidence of skin cancer in mice.
This product contains approximately 0-1.5% of a zinc alkyl dithiophosphate (ZDDP) additive. ZDDP has been found to
have weak mutagenic activity in cultured cells. Repeated dermal exposures of ZDDP produced severe skin irritation,
significant weight loss and testicular atrophy in male rabbits but not male rats at high concentrations. Subsequent
research showed that the testicular effect was due to the severe stress and weight loss as seen with other caustic
materials and not a direct effect of ZDDP. The concentration of ZDDP in this product is significantly lower than exposure
levels that produced these effects in rabbits.
Used motor oil applied to the skin of rabbits at doses of 8 ml/kg/day, 5 days/wk, for two weeks, produced significant
weight loss and skin irritation but no mortality. Used motor oil was found to produce skin tumors in mice in lifetime skin
painting studies. Solvent extracts of used motor oils were found to be positive in the Ames mutagenicity test.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects:
Water accomated fractions (WAF) of highly refined base oils did not produce acute
toxicity in fish (100-1000 mg/l), fresh water algae (500 mg/l) or daphnia (10,000 mg/l)
in 48-96 hour LC50 studies.
Used motor and/or lube oils can be toxic to birds and fish.
13. DISPOSAL CONSIDERATIONS
Cleanup Considerations:
This material as supplied and by itself, when discarded or
disposed of, is not an EPA RCRA hazardous waste
according to federal regulations. This material could become
a hazardous waste if mixed or contaminated with a
hazardous waste or other substance(s). It is the
responsibility of the user to determine if disposal material is
hazardous according to federal, state and local regulations.
Don't pollute. Conserve resources. Send used product to
recycling center. Dispose of cleanup materials in
accordance with applicable local, state and federal
regulations.
MSDS ID NO.: 0163MAR019
Product name: Marathon Multipower-3 Motor Oil
Page 5 of 9
Page 233 of 320
14. TRANSPORT INFORMATION
49 CFR 172.101:
DOT:
Transport Information:
This material when transported via US commerce is NOT REGULATED by DOT
regulations.
Not applicable.
Not applicable.
Packing group:
DOT reportable quantity (lbs):
TDG (Canada):
Packing group:
Regulated substances:
Not applicable.
Not applicable.
15. REGULATORY INFORMATION
Federal Regulatory Information:
US TSCA Chemical Inventory Section 8(b):
This product and/or its components are listed on the TSCA
Chemical Inventory.
OSHA Hazard Communication Standard:
This product has been evaluated and determined not to be
hazardous as defined in OSHA's Hazard Communication
Standard.
EPA Superfund Amendment & Reauthorization Act (SARA):
SARA Section 302:
This product contains the following component(s) that have been listed on EPA's
Extremely Hazardous Substance (EHS) List:
Name
Distillates, Solvent-refined Heavy
Paraffinic
Petroleum Distillates, Hydrotreated
Heavy Paraffinic
Additives
Zinc Dialkyl Dithiophosphate
SARA Section 304:
CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs
NA
NA
NA
NA
This product contains the following component(s) identified either as an EHS or a
CERCLA Hazardous substance which in case of a spill or release may be subject to
SARA reporting requirements:
Name
CERCLA/SARA - Hazardous Substances and their Reportable Quantities
Distillates, Solvent-refined Heavy
NA
Paraffinic
Petroleum Distillates, Hydrotreated
NA
Heavy Paraffinic
Additives
NA
Zinc Dialkyl Dithiophosphate
= 1000 lb final RQ no reporting of releases of this hazardous substance is required if the diameter of the pieces
of the solid metal released is equal to or exceeds 0.004 inches
= 454 kg final RQ no reporting of releases of this hazardous substance is required if the diameter of the solid
metal released is equal to or exceeds 0.004 inches
SARA Section 311/312:
The following EPA hazard categories apply to this product:
None
SARA Section 313:
MSDS ID NO.: 0163MAR019
This product contains the following component(s) that may be subject to reporting on
the Toxic Release Inventory (TRI) From R:
Product name: Marathon Multipower-3 Motor Oil
Page 6 of 9
Page 234 of 320
Name
Distillates, Solvent-refined Heavy
Paraffinic
Petroleum Distillates, Hydrotreated
Heavy Paraffinic
Additives
Zinc Dialkyl Dithiophosphate
CERCLA/SARA 313 Emission reporting:
None
None
None
= 1.0 percent de minimis concentration Chemical Category N982
= 1.0 percent de minimis concentration only fume or dust
State and Community Right-To-Know Regulations:
The following component(s) of this material are identified on the regulatory lists below:
Distillates, Solvent-refined Heavy Paraffinic
Louisiana Right-To-Know:
California Proposition 65:
New Jersey Right-To-Know:
Pennsylvania Right-To-Know:
Massachusetts Right-To Know:
Florida substance List:
Rhode Island Right-To-Know:
Michigan critical materials register list:
Massachusetts Extraordinarily Hazardous
Substances:
California - Regulated Carcinogens:
Pennsylvania RTK - Special Hazardous
Substances:
New Jersey - Special Hazardous Substances:
New Jersey - Environmental Hazardous
Substances List:
Illinois - Toxic Air Contaminants
New York - Reporting of Releases Part 597 List of Hazardous Substances:
Petroleum Distillates, Hydrotreated Heavy Paraffinic
Louisiana Right-To-Know:
California Proposition 65:
New Jersey Right-To-Know:
Pennsylvania Right-To-Know:
Massachusetts Right-To Know:
Florida substance List:
Rhode Island Right-To-Know:
Michigan critical materials register list:
Massachusetts Extraordinarily Hazardous
Substances:
California - Regulated Carcinogens:
Pennsylvania RTK - Special Hazardous
Substances:
New Jersey - Special Hazardous Substances:
New Jersey - Environmental Hazardous
Substances List:
Illinois - Toxic Air Contaminants
New York - Reporting of Releases Part 597 List of Hazardous Substances:
Additives
Louisiana Right-To-Know:
California Proposition 65:
New Jersey Right-To-Know:
Pennsylvania Right-To-Know:
Massachusetts Right-To Know:
Florida substance List:
MSDS ID NO.: 0163MAR019
Not Listed
Not Listed
Not Listed.
Not Listed.
Not Listed.
Not Listed.
Not Listed
Not Listed.
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed.
Not Listed.
Not Listed.
Not Listed.
Not Listed
Not Listed.
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed.
Not Listed.
Not Listed.
Not Listed.
Product name: Marathon Multipower-3 Motor Oil
Page 7 of 9
Page 235 of 320
Rhode Island Right-To-Know:
Michigan critical materials register list:
Massachusetts Extraordinarily Hazardous
Substances:
California - Regulated Carcinogens:
Pennsylvania RTK - Special Hazardous
Substances:
New Jersey - Special Hazardous Substances:
New Jersey - Environmental Hazardous
Substances List:
Illinois - Toxic Air Contaminants
New York - Reporting of Releases Part 597 List of Hazardous Substances:
Zinc Dialkyl Dithiophosphate
Louisiana Right-To-Know:
California Proposition 65:
New Jersey Right-To-Know:
Pennsylvania Right-To-Know:
Massachusetts Right-To Know:
Florida substance List:
Rhode Island Right-To-Know:
Michigan critical materials register list:
Massachusetts Extraordinarily Hazardous
Substances:
California - Regulated Carcinogens:
Pennsylvania RTK - Special Hazardous
Substances:
New Jersey - Special Hazardous Substances:
New Jersey - Environmental Hazardous
Substances List:
Illinois - Toxic Air Contaminants
New York - Reporting of Releases Part 597 List of Hazardous Substances:
Not Listed
Not Listed.
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
sn 2021 (dust and fume)
environmental hazard (any compound of this substance is
also an environmental hazard)
Present
Not Listed.
Flammable
Annual usage threshold = 100 pounds; All compounds
containing the listed elements must also be reported.
Not Listed
Not Listed
Not Listed
Not Listed
SN 2021 (fume or dust)
SN 3012; Category Code N982; includes any unique
chemical substance that contains the named metal as part
of that chemical structure
Not Listed
= 1,000 lbs Air RQ
= 100 lbs Land/Water RQ
Canadian Regulatory Information:
Canada DSL/NDSL Inventory:
Name
Zinc Dialkyl Dithiophosphate
This product and/or its components are listed either on the Domestic Substances List
(DSL) or are exempt.
Canada - WHMIS: Classifications of Substances:
B4; D2B
Canada - WHMIS: Ingredient Disclosure:
16. OTHER INFORMATION
Additional Information:
No data available.
Prepared by:
Craig M. Parker Manager, Toxicology and Product Safety
The information and recommendations contained herein are based upon tests believed to be reliable. However,
Marathon Petroleum Company LLC (MPC) does not guarantee their accuracy or completeness nor shall any of this
information constitute a warranty, whether expressed or implied, as to the safety of the goods, the merchantability of the
goods, or the fitness of the goods for a particular purpose. Adjustment to conform to actual conditions of usage maybe
required. MPC assumes no responsibility for results obtained or for incidental or consequential damages, including lost
profits arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made
or implied.
MSDS ID NO.: 0163MAR019
Product name: Marathon Multipower-3 Motor Oil
Page 8 of 9
Page 236 of 320
End of Safety Data Sheet
MSDS ID NO.: 0163MAR019
Product name: Marathon Multipower-3 Motor Oil
Page 9 of 9
Page 237 of 320
Page 238 of 320
Page 239 of 320
Page 240 of 320
Page 241 of 320
Page 242 of 320
Permatex, Inc.
10 Columbus Blvd.
Hartford, CT 06106 USA
Telephone: 1-87-Permatex
(877) 376-2839
Emergency: 800-255-3924 (ChemTel)
International Emergency: +01-813-248-0585
Material Safety Data Sheet
1. PRODUCT IDENTIFICATION
Product Name:
Item No:
Product Type:
NAPA 765-1188 THREAD SEALANT W/PTFE 4 FL.OZ
21127
Sealant
2. COMPOSITION/INFORMATION ON INGREDIENTS
Component
ETHANOL
64-17-5
TALC
14807-96-6
CASTOR OIL
8001-79-4
POLYVINYL RESIN
63148-65-2
2-PROPANOL
67-63-0
TITANIUM DIOXIDE
13463-67-7
METHANOL
67-56-1
POLYTETRAFLUOROETHYLENE
9002-84-0
Weight%
20-40
ACGIH; TLV-TWA
1000 ppm
OSHA PEL
1000 ppm; 1900 mg/m3
20-40
2 mg/m3
20 mppcf
20-40
Not listed
Not listed
<10
Not listed
Not listed
<5
200 ppm
400 ppm; 980 mg/m3
<3
10 mg/m3
15 mg/m3
<2
200 ppm
200 ppm; 260 mg/m3
<2
Not listed
Not listed
3. HAZARDS IDENTIFICATION
Toxicity:
Primary Routes of Entry:
Signs and Symptoms of Exposure:
Component
ETHANOL
64-17-5
TALC
14807-96-6
May cause eye, skin and respiratory irritation. Methanol may cause blindness or death if swallowed.
Eye and skin contact, ingestion, inhalation
Excessive accidental exposure may cause headache, dizziness, nausea and mild respiratory irritation.
Overexposure may cause eye and skin redness.
Weight%
20-40
20-40
2-PROPANOL
67-63-0
<5
TITANIUM DIOXIDE
13463-67-7
<3
POLYTETRAFLUOROETHYLENE
9002-84-0
<2
Medical Conditions Recognized as
Being Aggravated by Exposure:
NTP
ACGIH Carcinogens
IARC
A4 - Not Classifiable
as a Human
Carcinogen
male rat-some
A4- Not classifiable as Group 3 Supplement 7, 1987
evidence, female rat- a human carcinogen
Monograph 42, 1987
clear evidence, male
mice-no evidence,
female mice-no
evidence
A4 - Not classifiable Group 3 Monograph 71, 1999;
as a human
Supp.7, 1987; Monograph 15,
carcinogen
1977
male rat-negative,
A4
Group 2B; Vol 93,2006; Vol
female rat-negative,
47,1989
male mice-negative,
female mice-negative
Group 3 Supplement 7, 1987;
Monograph 19, 1979
Preexisting eye, skin and respiratory disorders may be aggravated by overexposure to this product.
1 of 3
Page 243 of 320
Product Name: NAPA 765-1188 THREAD SEALANT
W/PTFE 4 FL.OZ
4. FIRST AID MEASURES
Ingestion:
Inhalation:
Skin Contact:
Eye Contact:
Item No: 21127
Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never
give anything by mouth to an unconscious person.
Move to fresh air in case of accidental inhalation of vapours. Oxygen or artificial respiration if needed.
Obtain medical attention.
Wash off with soap and water. If skin irritation persists, call a physician.
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical
attention if irritation persists.
5. FIRE FIGHTING MEASURES
Hazardous Products of Combustion:
Unusual Fire/Explosion Hazards:
74°F TCC
Carbon Dioxide, Dry Chemicals, Foam.
Firefighters should wear self-contained breathing apparatus. Water spray
may be ineffective on flames but should be used to keep fire-exposed
containers cool.
Oxides of carbon, Fluoride compounds
Closed containers may rupture or explode when exposed to extreme heat.
Lower Explosive Limit:
Upper Explosive Limit:
2.3
12.7
Flash Point °F(C°):
Recommended Extinguishing Media:
Special Fire-Fighting Procedures:
6. ACCIDENTAL RELEASE MEASURES
Spill Procedures:
Eliminate all sources of ignition. Maintain good ventilation. Take up with an inert absorbent. Store in a
closed waste container until disposal. Residues may be cleaned up with isopropyl alcohol.
7. HANDLING AND STORAGE
Storage:
Handling:
Store away from heat, sparks or open flame. Do not store at temperatures above 100°F (38°C).
Avoid contact with skin and eyes. Do not inhale vapors. Keep container closed when not in use.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eyes:
Skin:
Ventilation:
Respiratory Protection:
Safety glasses.
Neoprene or nitrile gloves recommended.
General; local exhaust ventilation as necessary to control any air contaminants to within their exposure
limits (or to the lowest feasible levels when limits have not been established) during the use of this product.
An approved organic vapor respirator should be worn when exposures are expected to exceed the
applicable limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Odor:
Boiling Point:
pH:
Solubility in Water:
Specific Gravity:
VOC(Wt.%):
Vapor Pressure:
Vapor Density (Air=1):
Evaporation Rate:
White paste
Alcoholic
180° F
Does not apply
Partial
1.06-1.10
36.5%; 395 g/L
33 mm Hg @ 68°F
2.07
7.7 (ether = 1)
10. STABILITY AND REACTIVITY
Chemical Stability:
Hazardous Polymerization:
Incompatabilities:
Conditions to Avoid:
Hazardous Products of Combustion:
Stable at normal conditions
Will not occur
Strong oxidizers
Keep away from heat, sparks and open flame. - No smoking.
Oxides of carbon, Fluoride compounds
11. TOXICOLOGICAL INFORMATION
See Section 3
12. ECOLOGICAL INFORMATION
2 of 3
Page 244 of 320
Product Name: NAPA 765-1188 THREAD SEALANT
W/PTFE 4 FL.OZ
Item No: 21127
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended Method of Disposal: Disposal should be made in accordance with federal, state and local regulations..
D001 as per 40CFR 261.21
US EPA Waste Number:
14. TRANSPORTATION INFORMATION
DOT (49CFR 172)
Ground Transport (DOT)
DOT Shipping Name:
Hazard Class:
UN/ID Number:
Consumer Commodity (not more than one liter)
ORM-D
None
Proper Shipping Name:
Class or Division:
UN/ID Number:
Consumer Commodity (Not more than 1 liter)
Class 9
ID 8000
Proper Shipping:
Hazard Class:
UN Number:
Adhesives containing flammable liquid, Limited Quantity
Class 3 PGIII
UN 1133
Marine Pollutant:
None
IATA
IMDG
15. REGULATORY INFORMATION
SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical.
Methanol
California Proposition 65: No California Prop 65 chemicals are known to be present.
TSCA Inventory Status: All components of this product are listed (or exempt) on the EPA TSCA inventory.
16. OTHER INFORMATION
HEALTH 2, FLAMMABILITY 3 , REACTIVITY 0.
HEALTH 2, FLAMMABILITY 3, PHYSICAL HAZARD 0
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Estimated NFPA Rating:
Estimated HMIS Classification:
Prepared By:
Company:
Denise Boyd, Manager-Environmental, Health & Safety
Permatex. Inc. 10 Columbus Blvd. Hartford, CT USA 06106
Telephone No.:
1-87-Permatex (877) 376-2839
Revision Date: August 11, 2010
7
Revision
Number:
3 of 3
Page 245 of 320
Permatex, Inc.
10 Columbus Blvd.
Hartford, CT 06106 USA
Telephone: 1-87-Permatex
(877) 376-2839
Emergency: 800-255-3924
International Emergency: +01-813-248-0585
Material Safety Data Sheet
1. PRODUCT IDENTIFICATION
Product Name:
Item No:
Product Type:
NAPA 765-1482 HI-TEMP RED RTV GASKET MAKER 7.25 OZ.
81919
Silicone (Barrier Pack)
2. COMPOSITION/INFORMATION ON INGREDIENTS
Component
POLY (DIMETHYLSILOXANE),
HYDROXY TERMINATED
70131-67-8
AMORPHOUS SILICA
7631-86-9
DISTILLATES (PETROLEUM),
HYDROTREATED MIDDLE
64742-46-7
IRON OXIDE
1309-37-1
ETHYLTRIACETOXYSILANE
17689-77-9
METHYLTRIACETOXYSILANE
4253-34-3
TITANIUM DIOXIDE
13463-67-7
NITROGEN
7727-37-9
ACETIC ACID
64-19-7
Weight%
>60
ACGIH; TLV-TWA
Not listed
OSHA PEL
Not listed
5-15
Not listed
20 mppcf
<7
5 mg/m3
Not listed
<5
5 mg/m3
10 mg/m3
<3
Not listed
Not listed
<3
Not listed
Not listed
<2
10 mg/m3
15 mg/m3
<3
Not listed
Not listed
0.5-2.0
5 mg/m3
10 ppm; 25 mg/m3
3. HAZARDS IDENTIFICATION
Toxicity:
Primary Routes of Entry:
Signs and Symptoms of Exposure:
Component
AMORPHOUS SILICA
7631-86-9
IRON OXIDE
1309-37-1
TITANIUM DIOXIDE
13463-67-7
Medical Conditions Recognized as
Being Aggravated by Exposure:
4. FIRST AID MEASURES
Ingestion:
Inhalation:
Skin Contact:
Eye Contact:
May cause eye and skin irritation. May irritate lips, gums, tongue, mouth, nose and throat. May irritate
respiratory system upon frequent or prolonged use. ****When this product is exposed to moisture, acetic
acid may be formed. Note: This product does not contain microcyrstalline silica.
Eye and skin contact, ingestion, inhalation
Acetic acid produced during curing irritates eyes, nose and throat..
Weight%
5-15
NTP
IARC
Group 3 Monograph 68, 1997
<5
<2
ACGIH Carcinogens
male rat-negative,
female rat-negative,
male mice-negative,
female mice-negative
A4 - Not Classifiable Group 3, Supplement 7 1987;
Monograph 1 1972
A4
Group 2B; Vol 93,2006; Vol
47,1989
Methyltriacetoxysilane: Eye, skin and pulmonary disorders.
Rinse mouth. If swallowed, DO NOT induce vomiting. Keep individual calm. Obtain medical attention.
Move to fresh air in case of accidental inhalation of vapours. Obtain medical attention.
Wipe off material with paper towel or cloth. Wash off with soap and water. If skin irritation persists, call a
physician.
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical
attention if irritation persists.
1 of 3
Page 246 of 320
Product Name: NAPA 765-1482 HI-TEMP RED RTV
GASKET MAKER 7.25 OZ.
Item No: 81919
5. FIRE FIGHTING MEASURES
>200°F TCC
Carbon Dioxide, Dry Chemicals, Foam.
***Warning: This container is pressurized with nitrogen. Do not remove
rubber plug. Keep containers cool. Use equipment or shielding required to
protect against bursting or venting of containers.
Oxides of carbon, Oxides of nitrogen, Oxides of sulfur, Acetic acid, Metal
oxide fumes, Silica fume, Formaldehyde
Contents under pressure. Heated cans may burst. Use equipment or
shielding to protect personnel from bursting containers.
Flash Point °F(C°):
Recommended Extinguishing Media:
Special Fire-Fighting Procedures:
Hazardous Products of Combustion:
Unusual Fire/Explosion Hazards:
Not determined
Not determined
Lower Explosive Limit:
Upper Explosive Limit:
6. ACCIDENTAL RELEASE MEASURES
Spill Procedures:
Eliminate all sources of ignition. Wipe or scrape up spill material. Maintain good ventilation for large spills.
Place scrap material in a well-ventilated area and allow to cure to rubber. Clean up spills thoroughly as
residue is slippery.
7. HANDLING AND STORAGE
Storage:
Handling:
Store away from heat, sparks or open flame. Do not store at temperatures above 100°F (38°C). Exposure
to high temperatures may cause container to burst. Keep away from oxidizers. Store away from water or
moisture.
Avoid contact with skin and eyes. Do not wear contact lenses. Use only in a well ventilated area. Do not
take internally.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eyes:
Skin:
Ventilation:
Respiratory Protection:
Comments:
Safety glasses.
Neoprene or nitrile gloves recommended.
General; local exhaust ventilation as necessary to control any air contaminants to within their exposure
limits (or to the lowest feasible levels when limits have not been established) during the use of this product.
An approved organic vapor respirator should be worn when exposures are expected to exceed the
applicable limits.
When heated to temperatures above 300 degrees F. in the presence of air, this product can form
formaldehyde vapors. Formaldehyde is a potential cancer hazard and a known skin and respiratory
sensitizer. Safe handling conditions may be maintained by keeping vapor concentrations below the OSHA
permissible limit for formaldehyde
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Odor:
Boiling Point:
pH:
Solubility in Water:
Specific Gravity:
VOC(Wt.%):
Vapor Pressure:
Vapor Density (Air=1):
Evaporation Rate:
Red paste
Acetic acid
Not applicable, polymeric material
Does not apply
Polymerized
1.04
3.0%; 0.25 lb/gal; 30 g/l
66 mm Hg
>1
Not determined
10. STABILITY AND REACTIVITY
Chemical Stability:
Hazardous Polymerization:
Incompatabilities:
Conditions to Avoid:
Hazardous Products of Combustion:
Stable at normal conditions
Will not occur.
Polymerized by contact with moisture. Acetic acid liberated.
Moisture while storing. Do not expose to heat or store at temperatures
above 120 F.
Oxides of carbon, Oxides of nitrogen, Oxides of sulfur, Acetic acid, Metal
oxide fumes, Silica fume, Formaldehyde
11. TOXICOLOGICAL INFORMATION
See Section 3
2 of 3
Page 247 of 320
Product Name: NAPA 765-1482 HI-TEMP RED RTV
GASKET MAKER 7.25 OZ.
Item No: 81919
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended Method of Disposal: Disposal should be made in accordance with federal, state and local regulations..
NH - Not a RCRA Hazardous Waste Material
US EPA Waste Number:
14. TRANSPORTATION INFORMATION
DOT (49CFR 172)
Ground Transport (DOT)
DOT Shipping Name:
Hazard Class:
UN/ID Number:
Consumer Commodity
ORM-D
None
Proper Shipping Name:
Class or Division:
UN/ID Number:
Consumer Commodity (Not more than 1 liter)
Class 9
ID 8000
Proper Shipping:
Hazard Class:
UN Number:
Aerosols, Limited Quantity
Class 2.2
UN 1950
Marine Pollutant:
None
IATA
IMDG
15. REGULATORY INFORMATION
SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical.
NONE
California Proposition 65: No California Prop 65 chemicals are known to be present at or above the No Significant Risk Level
TSCA Inventory Status: All components of this product are listed (or exempt) on the EPA TSCA inventory.
16. OTHER INFORMATION
HEALTH 2, FLAMMABILITY 1 , REACTIVITY 1.
HEALTH 2, FLAMMABILILTY 1, PHYSICAL HAZARD 0
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Estimated NFPA Rating:
Estimated HMIS Classification:
Prepared By:
Company:
Denise Boyd, Manager-Environmental, Health & Safety
Permatex. Inc. 10 Columbus Blvd. Hartford, CT USA 06106
Telephone No.:
1-87-Permatex (877) 376-2839
Revision Date: October 27, 2009
6
Revision
Number:
3 of 3
Page 248 of 320
Manufactured For
Balkamp Inc.
2601 S. Holt Rd.
Indianapolis, IN 46241 (317-381-2272)
Material Safety Data Sheet
Manufactured for:
ARC
2601 S. Holt Rd.
Indianapolis, IN 46241
1-317-244-7241
Product Name: NAPA BRAKE FLUID – DOT 3
Product Numbers: 35-012, 35-032, 35-101, 35-155
24 Hour Emergency Phone Number: To be supplied by customer
NFPA Hazard Identification:
Fire – 1
Health-2
Reactivity-0
1.
Ingredients
Component Name/
CAS Number
Hazardous
In Blend
Percentage
Min Max
Exposure
Limit
Units
Cylcol Ether
Mixture
Yes
50 to 80
OSHA PEL
ACGIH TLV
No Limit
No Limit
Lubricity Additive
Mixture
No
10 to 35
OSHA PEL
ACGIH TLV
No Limit
No Limit
Oxidation Inhibitor
Mixture
No
< 10
OSHA PEL
ACGIH TLV
No Limit
No Limit
Corrosion Inhibitor
Mixture
No
< 1
OSHA PEL
ACGIH TLV
No Limit
No Limit
This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200)
2.
Physical Properties
Appearance:
Odor:
Pale Yellow Liquid
No Data
Molecular Weight: No Data
Specific Gravity (H²O=1): 1.03
Solubility In H²O: Soluble
Boiling Point: 430F (221 C) Minimum
Vapor Pressure: <1.
Freezing Point: No Data
% Volatiles by Volume: Negligible
Evaporation Rate: Negligible
Vapor Density (Air=1): No Data
PH: No Data
Pour Point: No Data
Page 249 of 320
3.
Fire and Explosive Hazards
Flash Point:
Method Used:
280F
COC
Flammable Limits in Air by % Vol.: No Data
Auto Ignition Temp: No Data
Extinguishing Media:
Water fog, foam, dry chemical or carbon dioxide
Manufactured For
Balkamp Inc.
2601 S. Holt Rd.
Indianapolis, IN 46241 (317-381-2272)
Material Safety Data Sheet
Product Name: NAPA BRAKE FLUID – DOT 3
Product Numbers: 35-012, 35-032, 35-101, 35-155
Special Fire Fighting Procedures:
Water may be ineffective but can be used to cool containers
exposed to heat or flame. Caution should be exercised when
using water or foam as frothing may occur. Especially if
sprayed into containers or hot, burning liquid. Do not use
direct water stream as it may spread the fire.
Unusual Fire and Explosion Hazards:
Dense smoke may be generated while burning. Carbon
monoxide, carbon dioxide and other oxides may be generated
as products of combustion.
4.
Reactivity Data
Stability:
Stable
Conditions to Avoid:
Elevated Temperatures May Decompose Active Ingredient
Incompatibilities:
May React with Strong Oxidizing Agents
Hazardous Decomposition:
None
Hazardous Polymerization:
Will Not Occur
5.
Health Hazard Summary
Eyes:
Avoid Eye Contact. May cause Moderate Eye Irritation.
Skin Contact:
Avoid skin contact. Minimally irritating to the skin upon
direct contact. Prolonged or repeated contact may cause skin
irritation. May be absorbed through the skin. Contact with
extremely hot material or damaged skin may result in
absorption of potentially harmful or lethal amounts.
Inhalation:
Avoid prolonged inhalation of vapors. Not a probable
inhalation hazard at room temperature due to its low vapor
pressure. Overexposure may lead to drowsiness, numbness
and headache followed by dizziness and nausea.
Ingestion:
Do not ingest. Ingestion of large quantities may be fatal.
Page 250 of 320
Health Data:
Prolonged and repeated exposure to large quantities may cause
skin irritation and drowsiness. Ingestion of large, single doses
of chemicals similar to those in this product, can be harmful,
even fatal. There is no relevant information available on the
major components. The minor components when tested
separately (usually by ingestion) caused kidney, liver,
gastronitestinal, testicular and central nervous system effects,
Manufactured For
Balkamp Inc.
2601 S. Holt Rd.
Indianapolis, IN 46241 (317-381-2272)
Material Safety Data Sheet
Product Name: NAPA BRAKE FLUID – DOT 3
Product Numbers: 35-012, 35-032, 35-101, 35-155
bladder stones, nausea and vomiting. Not carcinogenic
according to the OSHA hazard communication standard.
6. Recommended First Aid Treatment
Eyes:
Flush with large amounts of water for at least 15 minutes or
until irritation subsides. Consult physician if irritation or pain
persists.
Skin:
Remove contaminated clothing and flush with water and mild
Soap. If redness or irritation persists, seek medical attention.
Inhalation:
If breathing becomes difficult, remove to fresh air
immediately. See medical attention.
Ingestion:
Do not induce vomiting. Seek medical attention.
7. Health Protection Information
Ventilation:
Adequate ventilation must be provided to maintain
concentrations below the specified exposure or flammable
limits if vapor or mist is generated when the material is
heated.
Respiration Protection:
Respiratory protection is not required under conditions of
normal use. If vapor or mist is generated when material is
heated or handled. Use a Niosh approved organic vapor
respirator with a dust and mist filter.
Skin Protection:
None required in normal use. For prolonged or repeated
contact, use impervious clothing (gloves, aprons etc.) to cover
exposed body parts.
Eye Protection:
Not required under normal use. Use splash-proof safety
glasses or plastic face shields if splashing may occur.
Other:
Consumption of food and beverage should be avoided in work
areas where hydrocarbons are present. Always wash hands
and face with soap and water before eating, drinking or
smoking.
Page 251 of 320
8.
Environmental Procedures
Spills or Releases:
Notify appropriate authorities of spills. Contain spill
immediately. Do not allow spill to enter sewers or
watercourses. Remove all sources of ignition. Absorb with
Manufactured For
Balkamp Inc.
2601 S. Holt Rd.
Indianapolis, IN 46241 (317-381-2272)
Material Safety Data Sheet
Product Name: NAPA BRAKE FLUID – DOT 3
Product Numbers: 35-012, 35-032, 35-101, 35-155
Appropriate inert material such as sand, clay etc. Large spills
may be picked up using vacuum pumps, shovels, buckets or
other means and placed in drums or other suitable containers.
Waste Disposal:
Procedures
Dispose in accordance with federal, state and local
regulations.
9.
Storage and Handling Requirements
Handling Procedures:
Store in closed containers away from heat, sparks, flame or
oxidizing materials. Do not transfer to unmarked containers.
Use in well ventilated areas. Fire extinguishers should be kept
readily available as per NFPA 30 and OSHA 1910.106Flammable and Combustible Liquids.
10. Shipping Information
DOT Label:
Not regulated
11. Regulatory Information
This product contains the following SARA Title III, Section 313 Reportable Chemicals at or greater than
1.0% (0.1% for Carcinogens).
Glycolethers
CAS#
<100%
All ingredients of this product are listed on the Toxic Substances Control Act (TSCA) Inventory.
NOTE: The information contained herein is based on data considered accurate and available to us.
However, no warranty is expressed or implied regarding accuracy of the data or results to be obtained from
the use thereof. It is user’s obligation to determine conditions of safe use of the product and we assume no
responsibility for its use.
Original Issue: 11-15-99
Page 252 of 320
Page 253 of 320
H1BAK1347
NAPA Lith-Ease Grease (Plastic Tub 1 pound)
765-1393
============================================================================
MATERIAL SAFETY DATA SHEET
Effective Date: 9-6-94
Revision Date:
none
NAPA Lith-Ease Grease (Plastic Tub 1 pound) 765-1393
Code: AGS
Page: 1
============================================================================
Section 1 - Product and Company Identification
PRODUCT NAME: NAPA Lith-Ease Grease (Plastic Tub 1 pound)
MANUFACTURER'S NAME:
NUMBER
AGS Company
2651 Hoyt St.
Muskegon Hts. , MI 49444
INFORMATION
765-1393
EMERGENCY TELEPHONE
(800)255-3924
MISCELLANEOUS
(616)733-2101
============================================================================
Section 2 - Hazardous Ingredients
HAZARDOUS INGREDIENT
CAS NO.
WGT. %
TLV
--------------------------------------------------------------------------White Lithium Grease
Not Assigned
100%
5 cu. m.
NOTE:
============================================================================
Section 3 - Hazards Indentification
EYES:
May cause irritation.
SKIN:
May cause irritation on prolonged or repeated contact.
INGESTION:
INHALATION:
Contains petroleums, may cause diarrhea and nausea.
When at elevated temperature or aerosolized, may cause
irritation of the respiratory tract.
OTHER EFFECTS:
Not known.
============================================================================
Section 4 - First Aid Measures
EYES:
Flush with water for at least 15 minutes.
Call a physician
Page 254 of 320
immediately.
SKIN:
Wash thoroughly with soap and water.
INGESTION:
INHALATION:
Do not induce vomiting.
Call a physician immediately.
Of oil mist from grease; remove victim to fresh air.
Administer oxygen or artificial respiration as required.
Consult a physician.
============================================================================
MATERIAL SAFETY DATA SHEET
Effective Date: 9-6-94
Revision Date:
none
NAPA Lith-Ease Grease (Plastic Tub 1 pound) 765-1393
Code: AGS
Page: 2
============================================================================
Section 5 - Firefighting Measures
FLASH POINT
:
METHOD
:
AUTO IGNITION TEMP:
400F
C.O.C.
Not Determined
FLAMMABLE LIMITS:
LEL: Not Determined
UEL: Not Determined
EXTINGUISHING MEDIA:
sand or
Dry chemical, carbon dioxide, foam, water fog,
earth.
SPECIAL PROCEDURES:
UNUSUAL HAZARDS:
Wear self-contained breathing apparatus.
Dense smoke.
============================================================================
Section 6 - Environmental Release Measures
SPILL PROCEDURE:
Transfer bulk of material to a container.
residue with an absorbent material.
Remove the
============================================================================
Section 7 - Handling and Storage
CONDITIONS TO AVOID:
None listed.
============================================================================
Section 8 - Exposure Controls/Personal Protection
VENTILATION REQUIREMENTS:
General exhaust exceptable where a TLV of 5
cu.
Page 255 of 320
m. as mineral oil will not be exceeded.
EYES
:
GLOVES
:
CLOTHING
:
RESPIRATORY:
OTHER:
Yes
Yes
No
No
Eye wash in work area.
============================================================================
MATERIAL SAFETY DATA SHEET
Effective Date: 9-6-94
Revision Date:
none
NAPA Lith-Ease Grease (Plastic Tub 1 pound) 765-1393
Code: AGS
Page: 3
============================================================================
Section 9 - Physical and Chemical Properties
pH SUPPLIED
:
pH DILUTED
:
WATER SOLUBILITY:
SPECIFIC GRAVITY:
MELTING POINT
:
BOILING POINT
:
% VOLATILES
:
VAPOR PRESSURE :
VAPOR DENSITY
:
EVAPORATION RATE:
APPEARANCE
:
Not Applicable
Not Applicable
Nil
(Water=1) 0.90
360F (min.)
Not Applicable
Not Applicable
Not Applicable
Not Applicable
Not Applicable
Pale yellow semi-solid with mineral oil odor.
============================================================================
Section 10 - Stability and Reactivity
UNSTABLE AND/OR AUTO REACTIVE:
INCOMPATIBLE MATERIALS:
Stable
Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS:
CO and carbon dioxide.
============================================================================
Section 11 - Toxicological Information
Not available.
============================================================================
Section 12 - Ecological Information
Not available.
============================================================================
Page 256 of 320
Section 13 - Disposal Considerations
DISPOSAL METHOD:
Removal by an approved, licensed waste hauler.
EPA WASTE I.D. NO.:
Not Reg.
============================================================================
Section 14 - Transport Information
Not available.
============================================================================
Section 15 - Regulatory Information
Not available.
============================================================================
MATERIAL SAFETY DATA SHEET
Effective Date: 9-6-94
Revision Date:
none
NAPA Lith-Ease Grease (Plastic Tub 1 pound) 765-1393
Code: AGS
Page: 4
============================================================================
Section 16 - Other Information
TRADE NAME
:
COMMON NAME
:
CONATINER SIZE:
NAPA White Lithium Grease
Lith-Ease
Plastic Tube, 1 pound
NFPA:
HEALTH
:
FLAMMABILITY
:
REACTIVITY
:
SPECIFIC HAZARD:
0
1
0
N/A
HMIS:
HEALTH
:
FLAMMABILITY
:
REACTIVITY
:
PROTECTIVE EQUIPMENT:
0
1
0
A
***The information herein is given in good faith,
no warranty, expressed or implied, is made.***
Page 257 of 320
Page 258 of 320
Page 259 of 320
MSDS No:
Issue Date:
Page:
CEM040E8
11 Nov 2008
1 of 5
MATERIAL SAFETY DATA SHEET
SECTION 1
Trade Name:
Product No.:
PRODUCT AND COMPANY IDENTIFICATION
OATEY PVC HEAVY DUTY CLEAR CEMENT
30850, 30863, 30876, 30882, 31008, 31011, 31950, 31951, 31952,
31953
Product Use:
Cement for PVC Plastic Pipe
Formula:
PVC Resin in Solvent Solution
Synonyms:
PVC Plastic Pipe Cement
Firm Name &
OATEY CO. 4700 West 160th Street P.O. Box 35906 Cleveland,
Mailing Address:
Ohio 44135, U.S.A.
http://www.oatey.com
Oatey Phone Number: (216) 267-7100 or (800) 321-9532
Emergency Phone
For Emergency First Aid call 1-877-740-5015. For
Numbers:
chemical transportation emergencies ONLY, call Chemtrec at
1-800-424-9300. Outside the U.S. 1-703-527-3887.
Prepared By:
Technical Department
Preparation Date:
November 11, 2008
SECTION 2
INGREDIENTS:
Tetrahydrofuran
COMPOSITION/INFORMATION ON INGREDIENTS
%wt/wt : CAS NUMBER: ACGIH TLV TWA:
40 - 60%
109-99-9
50 ppm(skin)
100 ppm STEL
Methyl Ethyl Ketone
0 – 28%
78-93-3
200 ppm
300 ppm
Acetone
0 - 20%
67-64-1
500 ppm
750 ppm STEL
PVC Resin
12 - 20%
9002-86-2
10 mg/m3
(Non-hazardous)
Cyclohexanone
10 - 20%
108-94-1
20 ppm(skin)
50 ppm STEL
Amorphous Fumed Silica 1 - 4%
112945-52-5 10 mg/m3
(Non-hazardous)
OSHA Hazard Classification:
OSHA PEL TWA: OTHER:
200 ppm
25 ppm (Mfg)
200 ppm
None
1000 ppm
None
15 mg/m3
None
50 ppm
None
None
Established
None
Flammable, irritant, organ effects
SECTION 3
HAZARDS IDENTIFICATION
Emergency Overview:
Clear liquid with an ether-like odor. Extremely flammable liquid and vapor. Vapors
may cause flash fire. May cause eye and skin irritation. Inhalation of vapors or
mist may cause respiratory irritation and central nervous system effects. Swallowing
may cause irritation, nausea, vomiting, diarrhea and kidney or liver disorders.
Aspiration hazard. May be fatal if swallowed. Symptoms may be delayed.
SECTION 4
FIRST AID MEASURES
CALL 1-877-740-5015 or 1-303-623-5716 COLLECT
Skin:
Remove contaminated clothing immediately. Wash all exposed areas with
soap and water. Get medical attention if irritation develops. Remove
dried cement with Oatey Plumber's Hand Cleaner or baby oil.
Eyes:
If material gets into eyes or if fumes cause irritation, immediately
flush eyes with plenty of water until chemical is removed. If
irritation persists, get medical attention immediately.
Inhalation: If symptoms of exposure develop, remove to fresh air. If breathing
becomes difficult, administer oxygen. Administer artificial
respiration if breathing has stopped. Seek immediate medical attention.
Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water. Never give anything
by mouth to a person who is unconscious or drowsy. Get immediate
medical attention by calling a Poison Control Center, or hospital
emergency room. If medical advice cannot be obtained, then take the
person and product to the nearest medical emergency treatment center
or hospital.
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MSDS No:
Issue Date:
Page:
CEM040E8
11 Nov 2008
2 of 5
SECTION 5
FIRE FIGHTING MEASURES
Flashpoint / Method: 14 - 23 Degrees F. (-10 to -5 Degrees C) / CCCFP
Flammability:
LEL = 1.8 % Volume, UEL = 11.8 % Volume
Extinguishing
Use dry chemical, CO2, or foam to extinguish fire. Cool fire
Media:
exposed container with water. Water may be ineffective as an
extinguishing agent.
Special Fire
Firefighters should wear positive pressure self-contained
Fighting
breathing apparatus and full protective clothing for fires in
Procedure:
areas where chemicals are used or stored
Unusual Fire and
Extremely flammable liquid. Keep away from heat and all
Explosion
sources of ignition including sparks, flames, lighted
Hazards:
cigarettes and pilot lights. Containers may rupture or
explode in the heat of a fire. Vapors are heavier than air
and may travel to a remote ignition source and flash back.
This product contains tetrahydrofuran that may form explosive
organic peroxide when exposed to air or light or with age.
Hazardous
Combustion will produce toxic and irritating vapors including
Decomposition
carbon monoxide, carbon dioxide and hydrogen chloride.
Products:
SECTION 6
Spill or
Leak
Procedures:
ACCIDENTAL RELEASE MEASURES
Remove all sources of ignition and ventilate area. Stop leak if it
can be done without risk. Personnel cleaning up the spill should
wear appropriate personal protective equipment, including respirators
if vapor concentrations are high. Soak up spill with an inert
absorbent such as sand, earth or other non-combusting material. Put
absorbent material in covered, labeled metal containers. Prevent
liquid from entering watercourses, sewers and natural waterways.
Report releases to authorities as required. See Section 13 for
disposal information.
SECTION 7
Handling:
HANDLING AND STORAGE
Avoid contact with eyes, skin and clothing. Avoid breathing vapors
or mists. Use with adequate ventilation (equivalent to outdoors).
Wash thoroughly after handling. Do not eat, drink or smoke in the
work area. Keep product away from heat, sparks, flames and all other
sources of ignition. No smoking in storage or use areas. Keep
containers closed when not in use.
Store in a cool, dry, well-ventilated area away from incompatible
materials. Keep containers closed when not in use.
"Empty" containers retain product residue and can be hazardous.
Follow all MSDS precautions in handling empty containers. Do not cut
or weld on or near empty or full containers.
Storage:
Other:
SECTION 8
Ventilation:
Respiratory
Protection:
Skin
Protection:
EXPOSURE CONTROLS/PERSONAL PROTECTION
Open doors & windows. Provide ventilation capable of maintaining
emissions at the point of use below recommended exposure limits. If
used in enclosed area, use exhaust fans. Exhaust fans should be
explosion-proof or set up in a way that flammable concentrations of
solvent vapors are not exposed to electrical fixtures or hot
surfaces.
For operations where the exposure limit may be exceeded, a NIOSH
approved organic vapor respirator or supplied air respirator is
recommended. Equipment selection depends on contaminant type and
concentration, select in accordance with 29 CFR 1910.134 and good
industrial hygiene practice. For firefighting, use self-contained
breathing apparatus.
Rubber gloves are suitable for normal use of the product. For long
exposures chemical resistant gloves may be required such as 4H(tm)
Page 261 of 320
Eye
Protection:
Other:
MSDS No:
Issue Date:
Page:
or Silver Shield(tm) to avoid prolonged skin contact.
Safety glasses with side shields or safety goggles.
CEM040E8
11 Nov 2008
3 of 5
Eye wash and safety shower should be available.
SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point:
151 Degrees F / 66 Degrees C
Melting Point:
Not applicable
Vapor Pressure:
145 mmHg @ 20 Degrees C
Vapor Density:
(Air = 1) 2.5
Volatile Components: 80-84%
Solubility In Water: Negligible
pH:
Not applicable
Specific Gravity:
0.93 +/- 0.02 @ 20 Degrees C
Evaporation Rate:
(BUAC = 1) = 5.5 - 8.0
Appearance:
Clear Liquid
Odor:
Ether-Like
Will Dissolve In:
Tetrahydrofuran
Material Is:
Liquid
SECTION 10
STABILITY AND REACTIVITY
Stability:
Stable.
Conditions To Avoid: Avoid heat, sparks, flames and other sources of ignition.
Hazardous
Combustion will produce toxic and irritating vapors
Decomposition
including carbon monoxide, carbon dioxide and hydrogen
Products:
chloride.
Incompatibility/
Oxidizing agents, alkalis, amines, ammonia, acids, chlorine
Materials To Avoid:
compounds, chlorinated inorganics (potassium, calcium and
sodium hypochlorite) and hydrogen peroxides. May attack
plastic, resins and rubber.
Hazardous Polymerization:
Will not occur.
SECTION 11
Inhalation:
Skin:
Eye:
Ingestion:
Chronic
Toxicity:
Toxicity Data:
TOXICOLOGICAL INFORMATION
Vapors or mists may cause mucous membrane and respiratory
irritation, coughing, headache, dizziness, dullness, nausea,
shortness of breath and vomiting. High concentrations may cause
central nervous system depression, narcosis and unconsciousness.
May cause kidney, liver and lung damage.
May cause irritation with redness, itching and pain. Methyl
ethyl ketone and cyclohexanone may be absorbed through the skin
causing effects similar to those listed under inhalation.
Vapors may cause irritation. Direct contact may cause irritation
with redness, stinging and tearing of the eyes. May cause eye
damage.
Swallowing may cause abdominal pain, nausea, vomiting and
diarrhea. Aspiration during swallowing or vomiting can cause
chemical pneumonia and lung damage. May cause kidney and liver
damage.
Prolonged or repeated overexposure cause dermatitis and damage
to the kidney, liver, lungs and central nervous system.
Acetone:
Oral rat LD50: 5,800 mg/kg
Inhalation rat LC50: 50,100 mg/m3/8 hours
Cyclohexanone:
Oral rat LD50: 1,620 mg/kg
Inhalation rat LC50: 8,000 ppm/4 hours
Skin rabbit LD50: 1 mL/kg
Tetrahydrofuran:
Oral rat LD50: 1,650 mg/kg
Inhalation rat LC50: 21,000 ppm/3 hours
Methyl Ethyl Ketone: Oral rat LD50: 2,737 mg/kg
Inhalation rat LC50: 23,500 mg/m3/8 hours
Skin rabbit LD50: 6,480 mg/kg
Page 262 of 320
Sensitization:
Carcinogenicity:
Mutagenicity:
Reproductive
Toxicity:
Medical
Conditions
Aggravated By
Exposure:
SECTION 12
VOC
Information:
VOC Level:
SECTION 13
MSDS No: CEM040E8
Issue Date: 11 Nov 2008
Page: 4 of 5
None of the components are known to cause sensitization.
None of the components are listed as a carcinogen or suspect
carcinogen by NTP, IARC or OSHA. The National Toxicology Program
has reported that exposure of mice and rats to tetrahydrofuran
(THF) vapor levels up to 1800 ppm 6 hr/day, 5 days/week for their
lifetime caused an increased incidence of kidney tumors in male
rats and liver tumors in female mice. The significance of these
findings for human health is unclear at this time, and may be
related to "species specific" effects. Elevated incidences of
tumors in humans have not been reported for THF. ACGIH has
classified cyclohexanone (CYH) and tetrahydrofuran as “A3,”
Confirmed Animal Carcinogens with Unknown Relevance to Humans.
Cyclohexanone has been positive in bacterial and mammalian
assays. Acetone, methyl ethyl ketone and tetrahydrofuran are
generally thought not to be mutagenic.
Methyl ethyl ketone and cyclohexanone have been shown to cause
embryofetal toxicity and birth defects in laboratory animals.
Acetone and tetrahydrofuran has been found to cause adverse
developmental effects only when exposure levels cause other
toxic effects to the mother.
Persons with pre-existing skin, lung, kidney or liver disorders
may be at increased risk from exposure to this product.
ECOLOGICAL INFORMATION
This product is not expected to be toxic to aquatic organisms.
Cyclohexanone: 96 hour LC50 values for fish is over 100 mg/l.
Tetrahydrofuran: 96 hour LC50 fathead minnow: 2160 mg/L.
Acetone: 96 hour LC50 for fish is greater than 100 mg/L.
Methyl Ethyl Ketone: 96 hour LC50 for fish is greater than 100 mg/L.
This product emits VOC's (volatile organic compounds) in its use.
Make sure that use of this product complies with local VOC emission
regulations, where they exist.
Maximum 650 g/L per SCAQMD Test Method 316A.
DISPOSAL CONSIDERATIONS
Waste Disposal:
Dispose in accordance with current local, state and federal
regulations.
RCRA Hazardous Waste Number:
U002, U057, U159, U213
EPA Hazardous Waste ID Number:
D001, D035, F003, F005
EPA Hazard Waste Class:
Ignitable Waste. Toxic Waste (Methyl Ethyl Ketone content)
SECTION 14
TRANSPORT INFORMATION
DOT
UN/NA Number:
Proper Shipping Name:
Hazard Class:
Packing Group:
Hazard Labels:
IMDG
UN Number:
Proper Shipping Name:
Hazard Class:
Packing Group:
Label:
Less than 1 Liter (0.3 gal) Greater than 1 Liter (0.3 gal)
None
Consumer Commodity
ORM-D
None
None
UN1133
Adhesives
3
II
None (Limited Quantities
are excepted
from labeling)
Flashpoint (deg C)
-10 to -5 Degrees C
2008 North American Emergency Response Guidebook Number:
UN1133
Adhesives
3
PGII
Flammable Liquid
UN1133
Adhesives
3
II
Class 3 (Flammable
Liquid)
-10 to -5 Degrees C
127
Page 263 of 320
MSDS No:
Issue Date:
Page:
SECTION 15
REGULATORY
Hazard Category for Section
311/312:
Section 302 Extremely
Hazardous Substances (TPQ):
Section 313 Toxic Chemicals:
CEM040E8
11 Nov 2008
5 of 5
INFORMATION
Acute Health, Chronic Health, Flammable
This product does not contain chemicals regulated
under SARA Section 302.
This product does not contain chemicals subject to
SARA Title III Section 313 Reporting requirements.
CERCLA 103 Reportable
Spills of this product over the RQ (reportable
Quantity:
quantity) must be reported to the National Response
Center. The RQ for the product, based on the RQ for
Tetrahydrofuran (60% maximum) of 1,000 lbs, is 1,667
lbs. Many states have more stringent release
reporting requirements. Report spills required under
federal, state and local regulations.
California Proposition 65:
This product contains trace amounts of chemicals
known to the State of California to cause cancer.
Under normal use conditions, exposure to these
chemicals at levels above the State of California “No
Significant Risk Level” (NSRL) are unlikely. Oatey
Strongly encourages the use of proper personal
protective equipment (PPE) and ventilation guidelines
noted in Section 8 to minimize exposure to these
chemicals.
TSCA Inventory:
All of the components of this product are listed on
the TSCA inventory.
Canadian WHIMS Classification:
Class B, Division 2; Class D, Division 2,
Subdivision B; Class D, Division 2, Subdivision A.
This product has been classified in accordance with
the hazard criteria of the Controlled Products
Regulations (CPR) and the MSDS contains all the
information required by the CPR.
SECTION 16
OTHER INFORMATION
NFPA and HMIS:
NFPA Hazard Signal: Health: 2
Flammability: 3
HMIS Hazard Signal: Health: 2* Flammability: 3
Reactivity: 1
Reactivity: 1
Special: None
PPE: G
Disclaimer:
The information herein has been compiled from sources believed to be reliable, upto-date, and is accurate to the best of our knowledge. However, Oatey cannot give
any guarantees regarding information from other sources, and expressly does not make
warranties, nor assumes any liability for its use.
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Class C Solutions Group, a business of MSC Industrial Supply Co. - PB PENETRATING CATALYST (AEROSOL)
Material Safety Data Sheet
Supply Co. - PB PENETRATING CATALYST (AEROSOL)
Document Nbr: 063199
Class C Parts IDs 16GDLTWINPK,21431,C37043,CD21431
"BLASTER"(R*)
CONFORMS TO OSHA HAZCOM 2012 & NOM-018-STPS-2000 STANDARDS
SAFETY DATA SHEET
------SECTION 1: IDENTIFICATION -----1.1 PRODUCT IDENTIFIER:
PRODUCT NAME: PB PENETRATING CATALYST (AEROSOL)
PRODUCT CODE: 16-PB, 8-PB, 8-PBS, PBTS, 20-PB
1.2 RECOMMENDED USE OF CHEMICAL AND RESTRICTIONS ON USE:
USE: LUBRICANT
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
NAME/ADDRESS:
THE BLASTER CORPORATION
8500 SWEET VALLEY DRIVE
VALLEY VIEW, OHIO 44125
USA
TELEPHONE NUMBER:
T: (216) 901-5800
F: (216) 901-5801
1.4 EMERGENCY TELEPHONE NUMBER:
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: (800) 424-9300
DATE OF PREPARATION: MAY 26, 2014
VERSION #: 1.0
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------SECTION 2: HAZARD(S) IDENTIFICATION -----2.1 CLASSIFICATION OF THE CHEMICAL ACCORDING TO OSHA HAZCOM 2012:
HAZARD CLASS:
FLAMMABLE AEROSOL 2
GASES UNDER PRESSURE (DISSOLVED GAS)
SERIOUS EYE IRRITATION 2A
CARCINOGENICITY 2
ASPIRATION HAZARD 1
2.2 LABEL ELEMENTS ACCORDING TO OSHA HAZCOM 2012:
HAZARD PICTOGRAM:
FLAME
GAS CYLINDER
EXCLAMATION MARK
HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD STATEMENT:
FLAMMABLE AEROSOL. CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES SERIOUS EYE IRRITATION. SUSPECTED OF CAUSING CANCER. MAY BE FATAL
IF SWALLOWED AND ENTERS AIRWAYS.
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. WASH HANDS THOROUGHLY AFTER HANDLING.
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. WEAR PROTECTIVE GLOVES/PROTECTIVE
CLOTHING/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR. DO NOT INDUCE VOMITING.
STORAGE:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
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50 DEG. C/122 DEG. F. STORE IN A WELL-VENTILATED PLACE. STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
2.3 ADDITIONAL INFORMATION:
HAZARDS NOT OTHERWISE CLASSIFIED: NOT APPLICABLE.
8% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE TOXICITY.
THIS PRODUCT IS A HAZARDOUS CHEMICAL AS DEFINED BY NOM-018-STPS-2000.
MEXICO CLASSIFICATION:
2
4
0
BLUE = HEALTH
RED = FLAMMABILITY
YELLOW = REACTIVITY
WHITE = SPECIAL
HAZARD RATING:
0 = MINIMAL
1 = SLIGHT
2 = MODERATE
3 = SEVERE
4 = EXTREME
------SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS -----3.1 MIXTURES:
INGREDIENT
UN #
H/F/R/*
CAS NO
DISTILLATES (PETROLEUM),
HYDROTREATED LIGHT
NOT
AVAILABLE
NOT AVAILABLE
64742-47-8
50 - 60
SOLVENT NAPHTHA
(PETROLEUM), HEAVY
AROMATIC
UN1270
NOT AVAILABLE
64742-94-5
20 - 30
DISTILLATES (PETROLEUM),
HYDROTREATED HEAVY
NAPHTHENIC
NOT
AVAILABLE
NOT AVAILABLE
64742-52-5
20 - 30
CARBON DIOXIDE
UN1013
1/0/0
124-38-9
1-5
NAPHTHALENE
UN1334/
UN2304
2/2/0
91-20-3
2-3
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DINONYLPHENOL,
ETHOXYLATED, PHOSPHATED
NOT
AVAILABLE
NOT AVAILABLE
39464-64-7 0.5 - 1.5
THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS
A TRADE SECRET IN ACCORDANCE WITH PARAGRAPH (I) OF SUBSECTION 1910.1200.
* PER NOM-018-STPS-2000
------SECTION 4: FIRST - AID MEASURES -----4.1 DESCRIPTION OF THE FIRST AID MEASURE:
EYE:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST
15 MINUTES. IF EASY TO DO, REMOVE CONTACT LENSES, IF WORN. IF IRRITATION
PERSISTS, GET MEDICAL ATTENTION.
SKIN:
IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER. REMOVE
CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE REUSE. CALL A
PHYSICIAN IF IRRITATION DEVELOPS AND PERSISTS.
INHALATION:
IF BREATHING IS DIFFICULT, REMOVE TO FRESH AIR AND KEEP AT REST IN A
POSITION COMFORTABLE FOR BREATHING. GET MEDICAL ADVICE/ATTENTION IF YOU
FEEL UNWELL.
INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL
PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET
IMMEDIATE MEDICAL ADVICE/ATTENTION.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
EYE:
CAUSES SERIOUS EYE IRRITATION. SYMPTOMS MAY INCLUDE DISCOMFORT OR PAIN,
EXCESS BLINKING AND TEAR PRODUCTION, WITH MARKED REDNESS AND SWELLING OF
THE CONJUNCTIVA.
SKIN:
MAY CAUSE SKIN IRRITATION. SYMPTOMS MAY INCLUDE REDNESS, DRYING, DEFATTING
AND CRACKING OF THE SKIN.
INHALATION:
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. THIS PRODUCT MAY BE ASPIRATED
INTO THE LUNGS AND CAUSE CHEMICAL PNEUMONITIS. MAY CAUSE STOMACH DISTRESS,
NAUSEA OR VOMITING.
INGESTION: MAY CAUSE RESPIRATORY TRACT IRRITATION.
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENTS
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NEEDED:
NOTE TO PHYSICIANS: SYMPTOMS MAY NOT APPEAR IMMEDIATELY.
SPECIFIC TREATMENTS:
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY
(SHOW THE LABEL OR SDS WHERE POSSIBLE).
------SECTION 5: FIRE-FIGHTING MEASURES -----5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA: DRY CHEMICAL, CARBON DIOXIDE OR FOAM.
UNSUITABLE EXTINGUISHING MEDIA:
WATER MAY BE INEFFECTIVE FOR EXTINGUISHING FIRE.
5.2 SPECIAL HAZARDS ARISING FROM THE CHEMICAL:
PRODUCTS OF COMBUSTION:
MAY INCLUDE, AND ARE NOT LIMITED TO: OXIDES OF CARBON, HYDROCARBONS.
5.3 SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE FIGHTERS:
KEEP UPWIND OF FIRE. WEAR FULL FIRE FIGHTING TURN-OUT GEAR (FULL BUNKER
GEAR) AND RESPIRATORY PROTECTION (SCBA). COOL CLOSED CONTAINERS EXPOSED
TO FIRE WITH WATER. DO NOT USE A SOLID WATER STREAM AS IT MAY SCATTER AND
SPREAD FIRE. CONTAINERS MAY EXPLODE WHEN HEATED.
------SECTION 6: ACCIDENTAL RELEASE MEASURES -----6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8. ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL. ELIMINATE SOURCES
OF IGNITION.
6.2 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING - UP:
METHODS FOR CONTAINMENT:
CONTAIN AND/OR ABSORB SPILL WITH INERT MATERIAL (E.G. SAND, VERMICULITE),
THEN PLACE IN A SUITABLE CONTAINER. DO NOT FLUSH TO SEWER OR ALLOW TO ENTER
WATERWAYS. USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (PPE).
METHODS FOR CLEANING-UP:
SCOOP UP MATERIAL AND PLACE IN A DISPOSAL CONTAINER. VAPORS MAY BE HEAVIER
THAN AIR AND MAY TRAVEL ALONG THE GROUND TO A DISTANT IGNITION SOURCE AND
FLASH BACK. PROVIDE VENTILATION.
------SECTION 7: HANDLING AND STORAGE -----7.1 PRECAUTIONS FOR SAFE HANDLING:
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HANDLING:
KEEP AWAY FROM SOURCES OF IGNITION. - NO SMOKING. AVOID CONTACT WITH SKIN
AND EYES. AVOID BREATHING DUST/FUME/GAS/MIST/VAPOURS/SPRAY. DO NOT SWALLOW.
WHEN USING DO NOT EAT, DRINK OR SMOKE. DO NOT SPRAY ON AN OPEN FLAME OR
OTHER IGNITION SOURCE. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. (SEE SECTION 8)
GENERAL HYGIENE ADVICE:
LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS BEFORE EATING,
DRINKING, OR SMOKING.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
KEEP LOCKED UP AND OUT OF REACH OF CHILDREN. DO NOT EXPOSE TO TEMPERATURES
EXCEEDING 50 DEG. C / 122 DEG. F. STORE IN DRY, COOL, WELL-VENTILATED AREA.
(SEE SECTION 10)
------SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION -----8.1 CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT
OSHA-PEL
ACGIH-TLV
DISTILLATES (PETROLEUM), HYDROTREATED
LIGHT
100 PPM
200 MG/M3
SOLVENT NAPHTHA (PETROLEUM), HEAVY
AROMATIC
NOT AVAILABLE.
NOT AVAILABLE.
DISTILLATES (PETROLEUM), HYDROTREATED
HEAVY NAPHTHENIC
5 MG/M3 (MIST)
5 MG/M3 (MIST)
CARBON DIOXIDE
5000 PPM
9000 MG/M3
5000 PPM
NAPHTHALENE
10 PPM
50 MG/M3
10 PPM
DINONYLPHENOL, ETHOXYLATED, PHOSPHATED
NOT AVAILABLE.
NOT AVAILABLE.
8.2 EXPOSURE CONTROLS:
ENGINEERING CONTROLS:
USE VENTILATION ADEQUATE TO KEEP EXPOSURES (AIRBORNE LEVELS OF DUST, FUME,
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VAPOR, ETC.) BELOW RECOMMENDED EXPOSURE LIMITS.
8.3 INDIVIDUAL PROTECTIVE MEASURES:
PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: SAFETY GLASSES WITH SIDE-SHIELDS.
SKIN PROTECTION:
HAND PROTECTION: WEAR CHEMICALLY RESISTANT PROTECTIVE GLOVES.
BODY PROTECTION: WEAR SUITABLE PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION:
A NIOSH APPROVED RESPIRATOR IS RECOMMENDED IN POORLY VENTILATED AREAS OR
WHEN PERMISSIBLE EXPOSURE LIMITS MAY BE EXCEEDED. RESPIRATOR SELECTION MUST
BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS, THE HAZARDS OF THE PRODUCT
AND THE SAFE WORKING LIMITS OF THE SELECTED RESPIRATOR.
GENERAL HEALTH AND SAFETY MEASURES:
DO NOT EAT, SMOKE OR DRINK WHERE MATERIAL IS HANDLED, PROCESSED OR STORED.
WASH HANDS CAREFULLY BEFORE EATING OR SMOKING. HANDLE ACCORDING TO
ESTABLISHED INDUSTRIAL HYGIENE AND SAFETY PRACTICES. ENSURE THAT EYEWASH
STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION LOCATION.
------SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES -----9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE: VISCOUS / OILY.
COLOR: ORANGE.
ODOR: HEAVY AROMATIC.
ODOR THRESHOLD: NOT AVAILABLE.
PHYSICAL STATE: GAS/PRESSURIZED LIQUID.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE: 177.8 DEG. C (352 DEG. F)
FLASH POINT: 65.6 DEG. C (150 DEG. F)
EVAPORATION RATE: <1 (N-BUTYL ACETATE = 1)
FLAMMABILITY: FLAMMABLE.
LOWER FLAMMABILITY/EXPLOSIVE LIMIT: NOT AVAILABLE.
UPPER FLAMMABILITY/EXPLOSIVE LIMIT: NOT AVAILABLE.
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VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: >1 (AIR = 1)
RELATIVE DENSITY/SPECIFIC GRAVITY: 0.91 (WATER = 1)
SOLUBILITY: NEGLIGIBLE.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
OXIDIZING PROPERTIES: NOT AVAILABLE.
EXPLOSIVE PROPERTIES: NOT AVAILABLE.
VOC CONTENT: <25%
FLAME PROJECTION: 0 CM
HEAT OF COMBUSTION: 45.8 KJ/G
------SECTION 10: STABILITY AND REACTIVITY -----10.1 REACTIVITY: NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
10.2 CHEMICAL STABILITY:
STABLE UNDER NORMAL STORAGE CONDITIONS. FLAMMABLE AEROSOL. CONTENTS UNDER
PRESSURE. CONTAINER MAY EXPLODE IF HEATED. DO NOT PUNCTURE. DO NOT BURN.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
10.4 CONDITIONS TO AVOID:
HEAT. INCOMPATIBLE MATERIALS. SOURCES OF IGNITION. EXCESSIVE WATER.
10.5 INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS. STRONG REDUCING AGENTS. MOISTURE.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
MAY INCLUDE, AND ARE NOT LIMITED TO: OXIDES OF CARBON, HYDROCARBONS.
------SECTION 11: TOXICOLOGICAL INFORMATION -----11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
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LIKELY ROUTES OF EXPOSURE:
SKIN CONTACT, EYE CONTACT, INHALATION, AND INGESTION.
SYMPTOMS RELATED TO PHYSICAL/CHEMICAL/TOXICOLOGICAL CHARACTERISTICS:
EYE:
CAUSES SERIOUS EYE IRRITATION. SYMPTOMS MAY INCLUDE DISCOMFORT OR PAIN,
EXCESS BLINKING AND TEAR PRODUCTION, WITH MARKED REDNESS AND SWELLING OF
THE CONJUNCTIVA.
SKIN:
MAY CAUSE SKIN IRRITATION. SYMPTOMS MAY INCLUDE REDNESS, DRYING, DEFATTING
AND CRACKING OF THE SKIN.
INGESTION:
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. THIS PRODUCT MAY BE ASPIRATED
INTO THE LUNGS AND CAUSE CHEMICAL PNEUMONITIS. MAY CAUSE STOMACH DISTRESS,
NAUSEA OR VOMITING.
INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION.
ACUTE TOXICITY:
INGREDIENT
IDLH
LC50
LD50
DISTILLATES (PETROLEUM),
HYDROTREATED LIGHT
NOT
AVAILABLE.
INHALATION:
>5.2 MG/L 4H
RAT
ORAL:
>5000 MG/KG,
RAT
DERMAL:
>2000 MG/KG,
RABBIT
SOLVENT NAPHTHA (PETROLEUM),
HEAVY AROMATIC
NOT
AVAILABLE.
INHALATION:
>5.28 MG/L 4H,
RAT
ORAL:
>5000 MG/KG,
RAT
DERMAL:
>2000 MG/KG,
RABBIT
DISTILLATES (PETROLEUM),
HYDROTREATED HEAVY
NAPHTHENIC
NOT
AVAILABLE.
INHALATION:
>5.0 MG/L 4H,
RAT
ORAL:
>5000 MG/KG,
RAT
DERMAL:
>5000 MG/KG,
RABBIT
CARBON DIOXIDE
40000 PPM
NOT AVAILABLE.
NOT AVAILABLE.
NAPHTHALENE
250 PPM
NOT AVAILABLE.
ORAL:
490 MG/KG, RAT
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DERMAL:
>2500 MG/KG,
RAT
DERMAL:
>20 G/KG,
RABBIT
DINONYLPHENOL, ETHOXYLATED,
PHOSPHATED
NOT
AVAILABLE.
NOT AVAILABLE.
NOT AVAILABLE.
CALCULATED OVERALL CHEMICAL ACUTE TOXICITY VALUES:
LC50 (INHALATION)
LD50 (ORAL)
LD50 (DERMAL)
>5 MG/L 4H, RAT
>2000 MG/KG, RAT
>2000 MG/KG, RABBIT
INGREDIENT
CHEMICAL LISTED AS CARCINOGEN
OR POTENTIAL CARCINOGEN
(NTP, IARC, OSHA, ACGIH, CP65)*
DISTILLATES (PETROLEUM), HYDROTREATED
LIGHT
NOT LISTED.
SOLVENT NAPHTHA (PETROLEUM), HEAVY
AROMATIC
NOT LISTED.
DISTILLATES (PETROLEUM), HYDROTREATED
HEAVY NAPHTHENIC
NOT LISTED.
CARBON DIOXIDE
NOT LISTED.
NAPHTHALENE
G-A4, I-2B, N-2, CP65
DINONYLPHENOL, ETHOXYLATED, PHOSPHATED
NOT LISTED.
* SEE SECTION 15 FOR MORE INFORMATION.
11.2 DELAYED, IMMEDIATE, AND CHRONIC EFFECTS OF SHORT- AND LONG-TERM EXPOSURE:
SKIN CORROSION/IRRITATION:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY SENSITIZATION:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SKIN SENSITIZATION:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
STOT-SINGLE EXPOSURE:
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BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
CHRONIC HEALTH EFFECTS:
CARCINOGENICITY: POSSIBLE CARCINOGEN.
GERM CELL MUTAGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
REPRODUCTIVE TOXICITY:
DEVELOPMENTAL:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
FERTILITY: BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
STOT-REPEATED EXPOSURE:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
ASPIRATION HAZARD: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
OTHER INFORMATION: NOT AVAILABLE.
------SECTION 12: ECOLOGICAL INFORMATION -----12.1 ECOTOXICITY:
ACUTE/CHRONIC TOXICITY:
MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT.
12.2 PERSISTENCE AND DEGRADABILITY: NOT AVAILABLE.
12.3 BIOACCUMULATIVE POTENTIAL:
BIOACCUMULATION: NOT AVAILABLE.
12.4 MOBILITY IN SOIL: NOT AVAILABLE.
12.5 OTHER ADVERSE EFFECTS: NOT AVAILABLE.
------SECTION 13: DISPOSAL CONSIDERATIONS -----13.1 WASTE TREATMENT METHODS:
DISPOSAL METHOD:
THIS MATERIAL MUST BE DISPOSED OF IN ACCORDANCE WITH ALL LOCAL, STATE,
PROVINCIAL, AND FEDERAL REGULATIONS. THE GENERATION OF WASTE SHOULD BE
AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
OTHER DISPOSAL RECOMMENDATIONS:
FLAMMABLE VAPOURS MAY ACCUMULATE IN THE CONTAINER.
DO NOT INCINERATE EMPTY CONTAINERS.
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------SECTION 14: TRANSPORT INFORMATION -----14.1 UN NUMBER:
DOT
NOM-004-SCT2-1994
UN1950
UN1950
14.2 UN PROPER SHIPPING NAME:
DOT
NOM-004-SCT2-1994
AEROSOLS, FLAMMABLE, LIMITED
QUANTITIES
AEROSOLS, FLAMMABLE, LIMITED QUANTITIES
14.3 TRANSPORT HAZARD CLASS (ES):
DOT
NOM-004-SCT2-1994
2.1
2.1
14.4 PACKING GROUP:
DOT
NOM-004-SCT2-1994
NOT APPLICABLE.
NOT APPLICABLE.
14.5 ENVIRONMENTAL HAZARDS: NOT AVAILABLE.
14.6 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT AVAILABLE.
14.7 SPECIAL PRECAUTIONS FOR USER:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
THE BLASTER CORPORATION DOES NOT RECOMMEND SHIPPING THEIR AEROSOL PRODUCTS
BY AIR.
------SECTION 15: REGULATORY INFORMATION -----15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATIONS SPECIFIC FOR
THE CHEMICAL:
US:
SDS PREPARED PURSUANT TO THE HAZARD COMMUNICATION STANDARD (CFR 29 1910.1200)
HAZCOM 2012
MEXICO: SDS PREPARED PURSUANT TO NOM-018-STPS-2000.
SARA TITLE III:
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INGREDIENT
SECTION 302 SECTION 304
CERCLA
(EHS)
EHS RQ (LBS.) RQ (LBS.)
TPQ (LBS.)
SECTION 313
DISTILLATES
(PETROLEUM),
HYDROTREATED LIGHT
NOT LISTED. NOT LISTED.
NOT LISTED. NOT LISTED.
SOLVENT NAPHTHA
(PETROLEUM), HEAVY
AROMATIC
NOT LISTED. NOT LISTED.
NOT LISTED. NOT LISTED.
DISTILLATES
(PETROLEUM),
HYDROTREATED HEAVY
NAPHTHENIC
NOT LISTED. NOT LISTED.
NOT LISTED. NOT LISTED.
CARBON DIOXIDE
NOT LISTED. NOT LISTED.
NOT LISTED. NOT LISTED.
NAPHTHALENE
NOT LISTED. NOT LISTED.
100
DINONYLPHENOL,
ETHOXYLATED,
PHOSPHATED
NOT LISTED. NOT LISTED.
NOT LISTED. NOT LISTED.
313
STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
GLOBAL INVENTORIES:
INGREDIENT
USA TSCA
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT
YES.
SOLVENT NAPHTHA (PETROLEUM), HEAVY AROMATIC
YES.
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC
YES.
CARBON DIOXIDE
YES.
NAPHTHALENE
YES.
DINONYLPHENOL, ETHOXYLATED, PHOSPHATED
YES.
NFPA-NATIONAL FIRE PROTECTION ASSOCIATION:
HEALTH
2
FIRE
4
REACTIVITY 0
HMIS-HAZARDOUS MATERIALS IDENTIFICATION SYSTEM:
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HEALTH
2*
FIRE
4
PHYSICAL HAZARD 0
HAZARD RATING:
0 = MINIMAL
1 = SLIGHT
2 = MODERATE
3 = SEVERE
4 = EXTREME
SOURCE AGENCY CARCINOGEN CLASSIFICATIONS:
CP65: CALIFORNIA PROPOSITION 65
OSHA (O): OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION.
ACGIH (G): AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS.
A1 - CONFIRMED HUMAN CARCINOGEN.
A2 - SUSPECTED HUMAN CARCINOGEN.
A3 - ANIMAL CARCINOGEN.
A4 - NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
A5 - NOT SUSPECTED AS A HUMAN CARCINOGEN.
IARC (I): INTERNATIONAL AGENCY FOR RESEARCH ON CANCER.
1 - THE AGENT (MIXTURE) IS CARCINOGENIC TO HUMANS.
2A - THE AGENT (MIXTURE) IS PROBABLY CARCINOGENIC TO HUMANS; THERE IS
LIMITED EVIDENCE OF CARCINOGENICITY IN HUMANS AND SUFFICIENT EVIDENCE OF
CARCINOGENICITY IN EXPERIMENTAL ANIMALS.
2B - THE AGENT (MIXTURE) IS POSSIBLY CARCINOGENIC TO HUMANS; THERE IS
LIMITED EVIDENCE OF CARCINOGENICITY IN HUMANS IN THE ABSENCE OF SUFFICIENT
EVIDENCE OF CARCINOGENICITY IN EXPERIMENTAL ANIMALS.
3 - THE AGENT (MIXTURE, EXPOSURE CIRCUMSTANCE) IS NOT CLASSIFIABLE AS TO
ITS CARCINOGENICITY TO HUMANS.
4 - THE AGENT (MIXTURE, EXPOSURE CIRCUMSTANCE) IS PROBABLY NOT CARCINOGENIC
TO HUMANS.
NTP (N): NATIONAL TOXICOLOGY PROGRAM.
1 - KNOWN TO BE CARCINOGENS.
2 - REASONABLY ANTICIPATED TO BE CARCINOGENS.
------SECTION 16: OTHER INFORMATION -----DATE OF PREPARATION: MAY 26, 2014
VERSION: 1.0
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REVISION DATE: MAY 26, 2014
DISCLAIMER:
WE BELIEVE THE STATEMENTS, TECHNICAL INFORMATION AND RECOMMENDATIONS
CONTAINED HEREIN ARE RELIABLE, BUT THEY ARE GIVEN WITHOUT WARRANTY OR
GUARANTEE OF ANY KIND. THE INFORMATION CONTAINED IN THIS DOCUMENT APPLIES
TO THIS SPECIFIC MATERIAL AS SUPPLIED. IT MAY NOT BE VALID FOR THIS MATERIAL
IF IT IS USED IN COMBINATION WITH ANY OTHER MATERIALS. IT IS THE USER'S
RESPONSIBILITY TO SATISFY ONESELF AS TO THE SUITABILITY AND COMPLETENESS
OF THIS INFORMATION FOR THE USER'S OWN PARTICULAR USE.
PREPARED BY: NEXREG COMPLIANCE INC.
PHONE: (519) 488-5126
WWW.NEXREG.COM
PREPARED FOR: THE BLASTER CORPORATION
TRADE NAME: PB PENETRATING CATALYST (AEROSOL)
PRINT DATE: 2014-05-26
NEXREG
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Material Safety Data Sheet
Revision Number: 006.0
Issue date: 01/11/2012
1. PRODUCT AND COMPANY IDENTIFICATION
Product name:
Product type:
Permatex× Medium Strength
Threadlocker Blue
Anaerobic Sealant
IDH number:
303074
Item number:
24240
Region:
United States
Contact information:
Telephone: 860.571.5100
MEDICAL EMERGENCY Phone: Poison Control Center
1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com
Company address:
Henkel Corporation
One Henkel Way
Rocky Hill, Connecticut 06067
2. HAZARDS IDENTIFICATION
Physical state:
Color:
Odor:
EMERGENCY OVERVIEW
HMIS:
HEALTH:
FLAMMABILITY:
PHYSICAL HAZARD:
Personal Protection:
Liquid
Blue
Mild
WARNING:
*2
1
1
See MSDS Section 8
CAUSES EYE IRRITATION.
MAY CAUSE SKIN IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
Relevant routes of exposure:
Skin, Inhalation, Eyes
Potential Health Effects
Inhalation:
Skin contact:
Eye contact:
Ingestion:
May cause respiratory tract irritation.
May cause allergic skin reaction. May cause skin irritation.
Contact with eyes will cause irritation.
Not expected to be harmful by ingestion.
Existing conditions aggravated by
exposure:
Eye, skin, and respiratory disorders.
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR
1910.1200).
See Section 11 for additional toxicological information.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous components
CAS NUMBER
%
Polyglycol dimethacrylate
Oleic acid 5.5EO
Saccharin
Silica, amorphous, fumed, crystal-free
Cumene hydroperoxide
Propanediol-1,2
Titanium dioxide
Cumene
25852-47-5
9004-96-0
81-07-2
112945-52-5
80-15-9
57-55-6
13463-67-7
98-82-8
60 - 100
10 - 30
1-5
1-5
1-5
1-5
0.1 - 1
0.1 - 1
IDH number: 303074
Product name: Permatex× Medium Strength Threadlocker Blue
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4. FIRST AID MEASURES
Inhalation:
Move to fresh air. If breathing is difficult, give oxygen. If breathing has
stopped, give artificial respiration. Keep warm and quiet. Get medical
attention.
Skin contact:
Wash with soap and water. Remove contaminated clothing and footwear.
Wash clothing before reuse. If symptoms develop and persist, get medical
attention.
Eye contact:
Flush with copious amounts of water, preferably, lukewarm water for at least
15 minutes, holding eyelids open all the time. Get medical attention.
Ingestion:
Do not induce vomiting. Keep individual calm. Get medical attention.
5. FIRE FIGHTING MEASURES
Flash point:
> 93.3 °C (> 199.94 °F) Tagliabue closed cup
Flame projection:
Not applicable
Autoignition temperature:
Not determined
Flammable/Explosive limits - lower:
2.6 % (propylene glycol)
Flammable/Explosive limits - upper:
12.5 % (propylene glycol)
Extinguishing media:
Foam, dry chemical or carbon dioxide.
Special firefighting procedures:
None
Unusual fire or explosion hazards:
None
Hazardous combustion products:
Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic
vapours.
6. ACCIDENTAL RELEASE MEASURES
Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.
Environmental precautions:
Do not allow product to enter sewer or waterways.
Clean-up methods:
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder,
universal binder, sawdust). Store in a partly filled, closed container until
disposal.
7. HANDLING AND STORAGE
Handling:
Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist.
Wash thoroughly after handling.
Storage:
For safe storage, store at or below 38 °C (100.4 °F)
Keep in a cool, well ventilated area away from heat, sparks and open flame.
Keep container tightly closed until ready for use.
For information on product shelf life contact Henkel Customer Service at (800) 243-4874.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.
IDH number: 303074
Product name: Permatex× Medium Strength Threadlocker Blue
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Hazardous components
ACGIH TLV
OSHA PEL
AIHA WEEL
OTHER
Polyglycol dimethacrylate
Oleic acid 5.5EO
Saccharin
None
None
None
10 mg/m3 TWA
Inhalable dust.
3 mg/m3 TWA
Respirable fraction.
None
None
None
None
None
None
None
None
None
20 MPPCF TWA
0.8 mg/m3 TWA
None
None
Silica, amorphous, fumed, crystal-free
Cumene hydroperoxide
None
Propanediol-1,2
None
Titanium dioxide
10 mg/m3 TWA
Cumene
50 ppm TWA
None
None
1 ppm (6 mg/m3)
TWA
(SKIN)
10 mg/m3 TWA
Aerosol.
15 mg/m3 TWA
Total dust.
50 ppm (245
mg/m3) TWA
(SKIN)
None
None
None
None
None
None
Engineering controls:
No specific ventilation requirements noted, but forced ventilation may still be
required if concentrations exceed occupational exposure limits.
Respiratory protection:
Use NIOSH approved respirator if there is potential to exceed exposure
limit(s).
Eye/face protection:
Safety goggles or safety glasses with side shields.
Skin protection:
Use impermeable gloves and protective clothing as necessary to prevent skin
contact. Neoprene gloves. Butyl rubber gloves. Natural rubber gloves.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state:
Color:
Odor:
Odor threshold:
pH:
Vapor pressure:
Boiling point/range:
Melting point/ range:
Specific gravity:
Vapor density:
Flash point:
Flame projection:
Flammable/Explosive limits - lower:
Flammable/Explosive limits - upper:
Autoignition temperature:
Evaporation rate:
Solubility in water:
Partition coefficient (n-octanol/water):
VOC content:
IDH number: 303074
Liquid
Blue
Mild
Not available.
Not applicable
< 5 mm hg (27 °C (80.6 °F))
> 149 °C (> 300.2 °F)
Not available.
1.1 at 23.9 °C (75.02 °F)
Not available.
> 93.3 °C (> 199.94 °F) Tagliabue closed cup
Not applicable
2.6 % (propylene glycol)
12.5 % (propylene glycol)
Not determined
Not available.
Slight
Not available.
4.48 %; 49.3 g/l EPA Method 24
Product name: Permatex× Medium Strength Threadlocker Blue
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10. STABILITY AND REACTIVITY
Stability:
Stable
Hazardous reactions:
Will not occur.
Hazardous decomposition products:
Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic
vapours.
Incompatible materials:
Strong oxidizing agents. Free radical initiators. Strong reducing agents.
Alkalis. Oxygen scavengers. Other polymerization initiators. Copper. Iron.
Zinc. Aluminum. Rust.
Conditions to avoid:
See "Handling and Storage" (Section 7) and "Incompatibility" (Section 10).
11. TOXICOLOGICAL INFORMATION
Acute oral product toxicity:
LD50 (rat) > 10,000 mg/kg
Acute dermal product toxicity:
LD50 (rabbit) > 5,000 mg/kg
Hazardous components
Polyglycol dimethacrylate
Oleic acid 5.5EO
Saccharin
Silica, amorphous, fumed, crystal-free
Cumene hydroperoxide
Propanediol-1,2
Titanium dioxide
Cumene
NTP Carcinogen
IARC Carcinogen
No
No
No
No
No
No
No
No
No
No
No
No
No
No
Group 2B
Group 2B
Hazardous components
Polyglycol dimethacrylate
Oleic acid 5.5EO
Saccharin
Silica, amorphous, fumed, crystal-free
Cumene hydroperoxide
Propanediol-1,2
Titanium dioxide
Cumene
OSHA Carcinogen
(Specifically Regulated)
No
No
No
No
No
No
No
No
Health Effects/Target Organs
Irritant, Allergen
Irritant
No Target Organs
Nuisance dust
Allergen, Central nervous system, Corrosive, Irritant, Mutagen
Irritant
Irritant, Respiratory, Some evidence of carcinogenicity
Central nervous system, Irritant, Lung
12. ECOLOGICAL INFORMATION
Ecological information:
IDH number: 303074
Not available.
Product name: Permatex× Medium Strength Threadlocker Blue
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13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal:
Follow all local, state, federal and provincial regulations for disposal.
Hazardous waste number:
Not a RCRA hazardous waste.
14. TRANSPORT INFORMATION
The shipping classifications in this sections are for non-bulk packaging only (unless otherwise specified). Shipping classification may
be different for bulk packaging.
U.S. Department of Transportation Ground (49 CFR)
Proper shipping name:
Not regulated
Hazard class or division:
None
Identification number:
None
Packing group:
None
International Air Transportation (ICAO/IATA)
Proper shipping name:
Hazard class or division:
Identification number:
Packing group:
Not regulated
None
None
None
Water Transportation (IMO/IMDG)
Proper shipping name:
Hazard class or division:
Identification number:
Packing group:
Not regulated
None
None
None
15. REGULATORY INFORMATION
United States Regulatory Information
TSCA 8 (b) Inventory Status:
TSCA 12(b) Export Notification:
All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
None above reporting de minimus
CERCLA/SARA Section 302 EHS:
CERCLA/SARA Section 311/312:
CERCLA/SARA 313:
None above reporting de minimus
Immediate Health, Delayed Health
This product contains the following toxic chemicals subject to the reporting requirements of
section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40
CFR 372). Cumene hydroperoxide (CAS# 80-15-9).
California Proposition 65:
This product contains a chemical known in the State of California to cause cancer. This
product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.
Canada Regulatory Information
CEPA DSL/NDSL Status:
WHMIS hazard class:
All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.
D.2.A, D.2.B
16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections: 3, 8, 11
Prepared by: Kyra Kozak Woods, Manager, Regulatory Affairs
IDH number: 303074
Product name: Permatex× Medium Strength Threadlocker Blue
Page 5 of 6
Page 284 of 320
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.
IDH number: 303074
Product name: Permatex× Medium Strength Threadlocker Blue
Page 6 of 6
Page 285 of 320
Material Safety Data Sheet
16-Apr-2009
Revision Date
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product code
Product name
Recommended Use
DN4380
Persist
Lubricant
Supplier
Drummond American
A Lawson Products Company
600 Corporate Woods Parkway
Vernon Hills, IL 60061
(847) 913-9313
Emergency telephone number
(888) 426-4851
2. HAZARDS IDENTIFICATION
Color Red
Odor Oily
Aggravated Medical Conditions
Dermatitis.
Principal Routes of Exposure
Skin absorption.
Form Solid
Potential health effects
Eyes
Irritation.
Skin
May cause eye/skin irritation.
Inhalation
Extreme overexposure may cause. Headaches. Dizziness. Drowsiness .
Ingestion
May cause the following effects. Vomiting. Nausea. Diarrhea.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
Petroleum distillates (naphtha)
CAS-No
8002-05-9
Weight %
75-90
4. FIRST AID MEASURES
Eye contact
Wash off with plenty of water. Seek medical attention if irritation persists.
Skin contact
Remove and wash contaminated clothing before re-use. Wash area thoroughly with
soap and water.
Ingestion
Do not induce vomiting. Give several glasses of water. Seek medical attention.
Inhalation
Remove to fresh air.
Page 1 / 6
Page 286 of 320
Product code DN4380
Product name Persist
______________________________________________________________________________________
5. FIRE FIGHTING MEASURES
Flash point °C
Flash point °F
Method
> 204
> 400
Open cup
Autoignition temperature °C
Autoignition temperature °F
Not Applicable
Not Applicable
Flammability Limits (% in Air)
Upper
Lower
No data available
No data available
Suitable extinguishing media
Dry chemical. Carbon dioxide. Foam. Water.
Special protective equipment for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
Fire and Explosion Hazards
Empty containers contain residue and/or vapors. Do not weld, cut, pressurize, braze, solder, drill, grind, or expose such
containers to heat, sparks, flame, static electricity, or other sources of ignition. They may explode and cause injury or
death.
Sensitivity to shock
No information available.
Sensitivity to static discharge
No information available.
6. ACCIDENTAL RELEASE MEASURES
Methods for cleaning up
Eliminate all sources of ignition. Do not allow product to reach sewage system, soil, surface or ground water, or any water
course. Notify proper authorities if entry occurs. Soak up with inert absorbent material. Pick up and transfer to properly
labelled containers.
7. HANDLING AND STORAGE
Handling
Avoid prolonged inhalation of vapor or mist. Keep away from open flames, hot surfaces and sources of ignition. Empty
containers are very hazardous .
Storage
Keep container tightly closed. Keep out of the reach of children.
Page 2 / 6
Page 287 of 320
Product name Persist
Product code DN4380
______________________________________________________________________________________
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure limits
Chemical Name
Petroleum distillates
(naphtha)
OSHA PEL (TWA)
-
OSHA PEL (Ceiling)
-
ACGIH OEL (TWA)
-
ACGIH OEL (STEL)
-
Ventilation and Environmental Controls
None required.
Hygiene measures
Wash hands before breaks and immediately after handling the product.
Personal protective equipment
Respiratory protection
None required.
Hand Protection
Oil resistant gloves.
Eye protection
Use safety eyewear designed to protect against splash of liquids.
Skin and body protection
Apron.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form
Odor
pH
Vapor pressure
Evaporation Rate
Water solubility
Solid
Oily
Not Applicable
< 0.01 mmHG @ 70F
Not Applicable
Negligible
Color
Odor Threshold
Specific Gravity
Vapor density
VOC Content
Partition Coefficient
(n-octanol/water)
Red
Not Applicable
0.80
12 (air=1)
< 5%
Not Applicable
Boiling point/range °C
Melting point/range °C
Flash point °C
Not Applicable
No data available
> 204
Boiling point/range °F
Melting point/range °F
Flash point °F
Not Applicable
No data available
> 400
10. STABILITY AND REACTIVITY
Stability
Stable.
Conditions to avoid
Do not use on oxygen lines .
Page 3 / 6
Page 288 of 320
Product name Persist
Product code DN4380
______________________________________________________________________________________
Incompatability
Chlorine. Oxygen. Incompatible with oxidizing agents.
Hazardous Decomposition Products
Carbon oxides. Unidentifiable organic materials.
Polymerization
Hazardous polymerization does not occur.
11. TOXICOLOGICAL INFORMATION
Component Information
Chemical Name
Petroleum distillates
(naphtha)
8002-05-9
LD50 (oral,rat)
4300 mg/kg
LD50 (dermal,rat/rabbit)
4300
LC50 (inhalation,rat)
4300 mg/kg
Synergistic Products
None known
Potential health effects
Sensitization
None known
Chronic toxicity
See Section 2 .
Mutagenic effects
None known
Teratogenic effects
None known
Reproductive toxicity
None known
Target Organ Effects
See Section 2
Carcinogenic effects
See table below
Chemical Name
ACGIH OEL Carcinogens
IARC
Petroleum distillates
(naphtha)
Not Listed
Not Listed
NTP - Known NTP - Suspected
Carcinogens
Human
Carcinogens
Not Listed
Not Listed
OSHA RTK
Carcinogens
Not Listed
12. ECOLOGICAL INFORMATION
No Information Available
Petroleum distillates (naphtha)
Water Flea Data
Daphnia magna hEC50 24 (36 mg/L)
Page 4 / 6
Page 289 of 320
Product code DN4380
Product name Persist
______________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Waste from residues / unused products
Dispose in accordance with federal, state, and local regulations.
14. TRANSPORT INFORMATION
DOT
Not Regulated
TDG
Not Regulated
IMDG/IMO
Not Regulated
IATA
Not Regulated
MEX
Not Regulated
15. REGULATORY INFORMATION
Chemical Name
Petroleum distillates
(naphtha)
New Jersey - RTK
Listed
Chemical Name
Petroleum distillates (naphtha)
CPRC
Pennsylvania - RTK
Listed
EINECS
X
DSL
X
NDSL
-
California Prop. 65
Not Listed
TSCA
X
This product has been classified in accordance with the hazard criteria of the
Controlled Product Regulations and the MSDS contains all of the information
required by the Controlled Product Regulations
Page 5 / 6
Page 290 of 320
Product code DN4380
Product name Persist
______________________________________________________________________________________
16. OTHER INFORMATION
NFPA
Health
Flammability
Reactivity
Prepared By
HMIS
1
1
0
Health
Flammability
Physical Hazard
1
1
0
J. Cameron, Regulatory Affairs Coordinator
The information accumulated herein is believed to be accurate, but is not warranted to be, whether originating with the
company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and
suitable to their circumstances.
Page 6 / 6
Page 291 of 320
Page 292 of 320
SAFETY DATA SHEET
1. Identification
Product identifier
Propane
Other means of identification
SDS number
WC002
UN1075
Product code
Recommended use
Portable fuel.
Recommended restrictions
None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer/Supplier
Address
Contact person
E-mail address
Telephone number
Emergency telephone
number
Worthington Cylinder Corporation
300 E. Breed St., Chilton, WI 5301
United States
Ann Stiefvater
[email protected]
1-920-849-1740
1-703-527-3887 International / CHEMTREC 1-800-424-9300 Domestic
2. Hazard(s) identification
Physical hazards
Flammable gases
Category 1
Gases under pressure
Liquefied gas
Health hazards
Not classified.
OSHA defined hazards
Not classified.
Label elements
Signal word
Danger
Hazard statement
Extremely flammable gas. Contains gas under pressure; may explode if heated.
Precautionary statement
Prevention
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Response
Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Eliminate all ignition
sources if safe to do so.
Storage
Protect from sunlight. Store in a well-ventilated place.
Disposal
Dispose of waste and residues in accordance with local authority requirements.
Hazard(s) not otherwise
classified (HNOC)
May displace oxygen and cause rapid suffocation.
3. Composition/information on ingredients
Mixtures
Chemical name
CAS number
%
Propane
74-98-6
87.5-100
Ethane
74-84-0
0-7
Propylene
115-07-1
0-5
Butane
106-97-8
0-2.5
Propane
919503 Version #: 02
SDS US
Revision date: 11-September-2014
Issue date: 05-May-2014
1/8
Page 293 of 320
Additives
Chemical name
Ethyl Mercaptan
Composition comments
CAS number
%
75-08-1
<0.005
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
4. First-aid measures
Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.
Call a physician or poison control center immediately.
Remove contaminated clothing immediately and wash skin with soap and water. Get medical
attention if irritation develops and persists. If frostbite occurs, immerse involved area in warm water
(between 100 F/38 C and 110 F/43 C, not exceeding 112 F/44 C). Keep immersed for 20 to 40
minutes. Seek medical assistance.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention immediately.
Ingestion is not a typical route of exposure for gases or liquefied gases.
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Exposure to rapidly expanding gas or vaporizing liquid may cause frostbite ("cold burn"). Very high
exposure can cause suffocation from lack of oxygen. May cause drowsiness or dizziness.
Indication of immediate
medical attention and special
treatment needed
Exposure may aggravate pre-existing respiratory disorders. Treat symptomatically.
General information
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
5. Fire-fighting measures
Suitable extinguishing media
Dry chemical, CO2, water spray, fog, or foam.
Unsuitable extinguishing
media
None known.
Specific hazards arising from
the chemical
Selection of respiratory protection for firefighting: follow the general fire precautions indicated in
the workplace.
Special protective equipment
and precautions for firefighters
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Fire-fighting
equipment/instructions
Move container from fire area if it can be done without risk.
General fire hazards
Do not extinguish fires unless gas flow can be stopped safely; explosive re-ignition may occur.
Promptly isolate the scene by removing all persons from the vicinity of the incident. No action shall
be taken involving any personal risk or without suitable training. For fires involving this material,
do not enter any enclosed or confined fire space without proper protective equipment, including
self-contained breathing apparatus. Stop flow of material. Use water to keep fire exposed
containers cool and to protect personnel effecting shutoff. If a leak or spill has not ignited, use
water spray to disperse the vapors and to protect personnel attempting to stop leak. Prevent
runoff from fire control or dilution from entering streams, sewers or drinking water supply.
Extremely flammable gas.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Environmental precautions
Evacuate the area promptly. No action shall be taken involving any personal risk or without
suitable training. Keep unnecessary personnel away.
Ensure adequate ventilation. In case of inadequate ventilation, use respiratory protection. Wear
appropriate personal protective equipment (See Section 8).
Ventilate well, stop flow of gas or liquid if possible. Immediately contact emergency personnel.
Should not be released into the environment. Prevent further leakage or spillage if safe to do so.
Prevent from entering into soil, ditches, sanitary sewers, waterways and/or groundwater.
7. Handling and storage
Precautions for safe handling
Propane
919503 Version #: 02
Eliminate all sources of ignition. Wear appropriate personal protective equipment (See Section 8).
Eating, drinking, and smoking should be prohibited in areas where this material is handled, stored,
and processed. Do not breathe gas. Do not get in eyes, on skin, on clothing. Use only with
adequate ventilation.
SDS US
Revision date: 11-September-2014
Issue date: 05-May-2014
2/8
Page 294 of 320
Conditions for safe storage,
including any incompatibilities
Store in accordance with local, regional, national, and international regulations. Secure cylinders in
an upright position at all times, close all valves when not in use. Store in a cool, dry, well-ventilated
place. Keep container tightly closed and sealed until ready for use. Protect cylinders from damage.
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
Type
Value
Propane (CAS 74-98-6)
PEL
Additives
Type
1800 mg/m3
1000 ppm
Value
Ethyl Mercaptan (CAS
75-08-1)
Ceiling
25 mg/m3
10 ppm
US. ACGIH Threshold Limit Values
Components
Type
Value
Butane (CAS 106-97-8)
Propylene (CAS 115-07-1)
Additives
STEL
TWA
Type
1000 ppm
500 ppm
Value
Ethyl Mercaptan (CAS
75-08-1)
TWA
0.5 ppm
US. NIOSH: Pocket Guide to Chemical Hazards
Components
Type
Value
Butane (CAS 106-97-8)
TWA
Propane (CAS 74-98-6)
TWA
Additives
Type
1900 mg/m3
800 ppm
1800 mg/m3
1000 ppm
Value
Ethyl Mercaptan (CAS
75-08-1)
Ceiling
1.3 mg/m3
0.5 ppm
Biological limit values
No biological exposure limits noted for the ingredient(s).
Appropriate engineering
controls
Provide adequate ventilation and minimize the risk of inhalation of gas. Use process enclosures,
local exhaust ventilation, or other engineering controls to control airborne levels below
recommended exposure limits.
Individual protection measures, such as personal protective equipment
Wear approved safety glasses or goggles.
Eye/face protection
Skin protection
Hand protection
Respiratory protection
Thermal hazards
General hygiene
considerations
Wear appropriate chemical resistant gloves.
Wear protective clothing appropriate for the risk of exposure.
Other
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn.
Contact with liquefied gas might cause frostbites, in some cases with tissue damage. Wear
appropriate thermal protective clothing, when necessary.
Do not eat, drink or smoke when using the product. Wash thoroughly after handling. Provide
eyewash station and safety shower. Handle in accordance with good industrial hygiene and safety
practices.
9. Physical and chemical properties
Appearance
Colorless gas.
Physical state
Gas.
Form
Compressed liquefied gas.
Color
Colorless.
Odor
Propane
919503 Version #: 02
Rotten egg.
SDS US
Revision date: 11-September-2014
Issue date: 05-May-2014
3/8
Page 295 of 320
Odor threshold
Not available.
pH
Not applicable.
Melting point/freezing point
-306.4 °F (-188 °C)
Initial boiling point and boiling
range
-43.6 °F (-42 °C) 14.7 psia
Flash point
-155.2 °F (-104.0 °C)
Evaporation rate
Not applicable.
Flammability (solid, gas)
Extremely flammable gas.
Upper/lower flammability or explosive limits
Explosive limit - lower (%)
2.15 %
Explosive limit - upper (%)
9.6 %
Vapor pressure
127 psig (21°C / 70°F)
Vapor density
Not available.
Relative density
0.504 (liquid)
1.5 (vapor) (air=1) @ 15°C / 60°F
Solubility(ies)
Solubility (water)
Slightly soluble in water.
Partition coefficient
(n-octanol/water)
1.77
Auto-ignition temperature
809.6 °F (432 °C)
Decomposition temperature
Not available.
Viscosity
Not applicable.
Other information
Molecular weight
45 g/mol
100 %
Percent volatile
10. Stability and reactivity
Reacts violently with strong oxidants, nitrites, inorganic chlorides, chlorites and perchlorates
causing fire and explosion hazard.
Stable under normal temperature conditions and recommended use.
Reactivity
Chemical stability
Possibility of hazardous
reactions
Polymerization will not occur.
Conditions to avoid
Heat, flames and sparks.
Incompatible materials
Strong oxidizing agents. Strong acids. Halogens.
Hazardous decomposition
products
Carbon oxides. Hydrocarbons.
11. Toxicological information
Information on likely routes of exposure
Not likely, due to the form of the product.
Ingestion
Inhalation
High concentrations: Suffocation (asphyxiant) hazard - if allowed to accumulate to concentrations
that reduce oxygen below safe breathing levels. Breathing of high concentrations may cause
dizziness, light-headedness, headache, nausea and loss of coordination. Continued inhalation
may result in unconsciousness.
Skin contact
Contact with liquefied gas may cause frostbite.
Eye contact
Contact with liquefied gas may cause frostbite.
Symptoms related to the
physical, chemical and
toxicological characteristics
Exposure to rapidly expanding gas or vaporizing liquid may cause frostbite ("cold burn"). Very
high exposure can cause suffocation from lack of oxygen. May cause drowsiness or dizziness.
Information on toxicological effects
Acute toxicity
Propane
919503 Version #: 02
High concentration: Suffocation (asphyxiant) hazard - if allowed to accumulate to concentrations
that reduce oxygen below safe breathing levels.
SDS US
Revision date: 11-September-2014
Issue date: 05-May-2014
4/8
Page 296 of 320
Components
Species
Test Results
Mouse
680 mg/l, 2 Hours
Rat
658 mg/l, 4 Hours
Rat
> 1442 mg/l, 15 Minutes
Mouse
680 mg/l, 2 Hours
Rat
658 mg/l, 4 Hours
Species
Test Results
Acute
Dermal
LD50
Rat
> 2000 mg/kg
Inhalation
LC50
Mouse
4420 mg/l, 4 Hours
Oral
LD50
Rat
682 mg/kg
Butane (CAS 106-97-8)
Acute
Inhalation
LC50
Propane (CAS 74-98-6)
Acute
Inhalation
LC50
Propylene (CAS 115-07-1)
Acute
Inhalation
LC50
Additives
Ethyl Mercaptan (CAS 75-08-1)
Skin corrosion/irritation
Contact with liquefied gas might cause frostbites, in some cases with tissue damage.
Serious eye damage/eye
irritation
Direct contact with liquefied gas may cause eye damage from frostbite.
Respiratory or skin sensitization
Not classified.
Respiratory sensitization
Not classified.
Skin sensitization
Germ cell mutagenicity
Not classified.
Carcinogenicity
Not classified.
IARC Monographs. Overall Evaluation of Carcinogenicity
Propylene (CAS 115-07-1)
3 Not classifiable as to carcinogenicity to humans.
Not classified.
Reproductive toxicity
Specific target organ toxicity single exposure
Not classified.
Specific target organ toxicity repeated exposure
Not classified.
Aspiration hazard
Not classified.
12. Ecological information
Ecotoxicity
Not expected to be harmful to aquatic organisms.
Persistence and degradability
The product is readily biodegradable.
Bioaccumulative potential
The product is not expected to bioaccumulate.
Partition coefficient n-octanol / water (log Kow)
Propane (CAS Mixture)
Butane (CAS 106-97-8)
Propane (CAS 74-98-6)
Propylene (CAS 115-07-1)
May evaporate quickly.
Mobility in soil
Mobility in general
Propane
919503 Version #: 02
1.77
2.89
2.36
1.77
May evaporate quickly.
SDS US
Revision date: 11-September-2014
Issue date: 05-May-2014
5/8
Page 297 of 320
None known.
Other adverse effects
13. Disposal considerations
Use the container until empty. Do not dispose of any non-empty container. Empty containers have
residual vapor that is flammable and explosive. Cylinders should be emptied and returned to a
hazardous waste collection point. Do not puncture or incinerate even when empty. Dispose in
accordance with all applicable regulations.
D001: Waste Flammable material with a flash point <140 °F
Disposal instructions
Hazardous waste code
Waste from residues / unused
products
Dispose in accordance with all applicable regulations.
Contaminated packaging
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
14. Transport information
DOT
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Packing group
Environmental hazards
Marine pollutant
Special precautions for user
Special provisions
Packaging exceptions
Packaging non bulk
Packaging bulk
IATA
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Environmental hazards
ERG Code
Special precautions for user
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Environmental hazards
Marine pollutant
EmS
Special precautions for user
Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
UN1075
Propane
2.1
Not applicable.
No
Read safety instructions, SDS and emergency procedures before handling.
19, T50
306
304
314, 315
UN1075
Propane
2.1
2.1
Not applicable.
No
10L
Read safety instructions, SDS and emergency procedures before handling.
UN1075
PROPANE
2.1
2.1
Not applicable.
No
F-D, S-U
Read safety instructions, SDS and emergency procedures before handling.
This product is a compressed or liquefied gas and when transported in bulk is covered under IGC
code.
15. Regulatory information
US federal regulations
Propane
919503 Version #: 02
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
SDS US
Revision date: 11-September-2014
Issue date: 05-May-2014
6/8
Page 298 of 320
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Butane (CAS 106-97-8)
LISTED
Ethyl Mercaptan (CAS 75-08-1)
LISTED
Propane (CAS 74-98-6)
LISTED
Propylene (CAS 115-07-1)
LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - No
Hazard categories
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - Yes
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
Yes
SARA 313 (TRI reporting)
Chemical name
Propylene
CAS number
% by wt.
115-07-1
0-5
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Butane (CAS 106-97-8)
Ethyl Mercaptan (CAS 75-08-1)
Propane (CAS 74-98-6)
Propylene (CAS 115-07-1)
Hazardous substance
Clean Water Act (CWA)
Section 112(r) (40 CFR
68.130)
Safe Drinking Water Act
(SDWA)
Not regulated.
US state regulations
US. Massachusetts RTK - Substance List
Butane (CAS 106-97-8)
Ethyl Mercaptan (CAS 75-08-1)
Propane (CAS 74-98-6)
Propylene (CAS 115-07-1)
US. New Jersey Worker and Community Right-to-Know Act
Butane (CAS 106-97-8)
Ethyl Mercaptan (CAS 75-08-1)
Propane (CAS 74-98-6)
Propylene (CAS 115-07-1)
US. Pennsylvania Worker and Community Right-to-Know Law
Butane (CAS 106-97-8)
Ethyl Mercaptan (CAS 75-08-1)
Propane (CAS 74-98-6)
Propylene (CAS 115-07-1)
US. Rhode Island RTK
Butane (CAS 106-97-8)
Ethyl Mercaptan (CAS 75-08-1)
Propane (CAS 74-98-6)
Propylene (CAS 115-07-1)
US. California Proposition 65
Propane
919503 Version #: 02
SDS US
Revision date: 11-September-2014
Issue date: 05-May-2014
7/8
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US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
International Inventories
Country(s) or region
Australia
Inventory name
Australian Inventory of Chemical Substances (AICS)
On inventory (yes/no)*
Yes
Canada
Domestic Substances List (DSL)
Canada
Non-Domestic Substances List (NDSL)
China
Inventory of Existing Chemical Substances in China (IECSC)
Yes
Europe
European Inventory of Existing Commercial Chemical
Substances (EINECS)
Yes
Europe
European List of Notified Chemical Substances (ELINCS)
Japan
Inventory of Existing and New Chemical Substances (ENCS)
Yes
Korea
Existing Chemicals List (ECL)
Yes
New Zealand
New Zealand Inventory
Yes
Philippines
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
Yes
United States & Puerto Rico
Toxic Substances Control Act (TSCA) Inventory
Yes
Yes
No
No
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date
05-May-2014
Revision date
11-September-2014
Version #
02
NFPA Ratings
4
2
Disclaimer
Propane
919503 Version #: 02
0
All information in this Material Safety Data Sheet is believed to be accurate and reliable. However,
no guarantee or warranty of any kind is made with regard to the accuracy of information or the
suitability of the recommendations contained herein. It is the user’s responsibility to assess the
safety and toxicity of this product under their own conditions of use and to comply with all
applicable laws and regulations.
SDS US
Revision date: 11-September-2014
Issue date: 05-May-2014
8/8
Page 300 of 320
Commercial Refrigeration, Marine R-12 R-22 Alternative Refrigerants, Home
HOME ABOUT RMS MSDS DISTRIBUTORS
SERVICES
Overview
Recovery
RECORD KEEPING
SOFTWARE
Reclamation
Banking
REFRIGERANTS Choice R-420A Choice R-421A Choice R-421B
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[email protected]
RMS-2100
RMS-2101
RELATED LINKS
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Sales
Quick Change RR-417A
134A
RMS-2200
RMS-2300
770.777.0597 / 800.347.5872 phone
770.777.0599 fax
610 McFarland/400 Drive Alpharetta, GA 30004 USA
Quick Change R-134A MSDS
Overview
Tech Service Bulletin
MSDS
MSDS in compliance with OSHA Communication Standard 09 CPR 1910.1200 Dept. of Labor.
Effective Date:
Product Name:
August 1995
R-134a
Emergency #:
Chem Trac 1-800-424-9300
Section A:
General Information
Trade Name:
R-134a
CAS No.:
811-97-2
Chemical
Name:
1,1,1,2-Tetrafluoroethane
Synonym:
HFC 134a
Formula:
CH2FCF3
Refrigerant Management Services
Contact:
610 McFarland/400 Drive
Alpharetta, Georgia 30004
Phone: 1-800-347-5872
Fax: 770-777-0599
Section B:
First Aid Measures
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Commercial Refrigeration, Marine R-12 R-22 Alternative Refrigerants, Home
Inhalation: If high concentrations are inhaled, immediately remove to fresh air. Keep person
calm. If breathing has stopped, give mouth-to-mouth resuscitation. If breathing is difficult, give
oxygen, as necessary, provided a qualified operator is available. Call a physician.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Call a
physician.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes, while
removing contaminated clothing and shoes. Call a physician. Wash contaminated clothing
before reuse. Treat for frostbite if necessary by gently warming affected area.
Ingestion: Ingestion is not considered a potential route of exposure.
Note to Physician: Because of possible disturbances of cardiac rhythm, catecholamine
drugs, such as epinephrine should only be used with special caution in situations of
emergency life support.
Section C:
Hazards Information
Inhalation: Ethane, 1,1,1,2-tetrafluoro: Gross overexposure may cause, central nervous system
depression with dizziness, confusion, uncoordination, drowsiness or unconsciousness. Irregular
heart beat with a strange sensation in the chest “heart thumping”, apprehension, light-headedness,
and feeling of fainting, dizziness, weakness, sometimes progressing to loss of consciousness and
death. Suffocation, if air is displaced by vapors.
Skin: Ethane, 1,1,1,2-tetrafluoro: Immediate effects of overexposure may include: frostbite if
liquid or escaping vapor contacts the skin.
Eyes: Ethane, 1,1,1,2-tetrafluoro: “Frostbite-like” effects may occur if the liquid or escaping
vapors contact the eyes.
Additional Health Effects: Ethane, 1,1,1,2-tetrafluoro: Increased susceptibility to the effects of
this material may be observed in persons with pre-existing disease of the central nervous system,
cardiovascular system.
Carcinogenicity Information: None of the components present in this material at concentrations
equal to or greater than 0.1% are listed by IARC, NTP, OSHA or ACGIH as a carcinogen.
Section D:
Precautions / Procedures
Flash Point: Will not burn.
Flammable limits in Air,% by Volume: LEL -Not applicable
UEL - Not applicable
Auto Ignition: >743°C (> 1369°F)
Fire Extinguishing Agents: Any standard agent. Use media most suitable for surrounding
material.
Special Fire Fighting Precautions: HFC-134a is not flammable at ambient temperatures and
atmospheric pressure. However, HFC-134a has been shown in tests to be combustible at
pressure as low as 5.5 psig at 177°C (351°F) when mixed with air at concentrations of generally
more than 60 volume % air. At lower temperatures, higher pressures are required for
combustibility. Experimental data have also been reported which indicate combustibility of HFC134a in the presence of certain concentrations of chlorine.
Fire & Explosion Hazards: Cylinders may rupture under fire conditions. Decomposition may
occur. Contact of welding or soldering torch flame with high concentrations of refrigerant can
result in visible changes in the size and color of the torch flame. This flame effect will only
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occur in concentrations of product well above the recommended exposure limit, therefore stop all
work and ventilate the area before proceeding. Use forced ventilation to disperse refrigerant
vapors from the work area before using any open flames.
Ventilation: Ventilate area, especially low or enclosed places where heavy vapors may collect.
Remove open flames. Use self-contained breathing apparatus (SCBA) if large spill or leak
occurs.
Normal Handling: Use with sufficient ventilation to keep employee exposure below
recommended limits. HFC-134a should not be mixed with air for leak testing or used for any
other purpose above atmospheric pressure. See Flammable Properties section. Contact with
chlorine or other strong oxidizing agents should also be avoided.
Storage: Store in a clean, dry place. Do not heat above 52°C (126°F).
Section E:
Personal Protective Equipment
Engineering Controls: Normal ventilation for standard manufacturing procedures is generally
adequate. Local exhaust should be used when large amounts are released. Mechanical
ventilation should be used in low or enclosed places. Refrigerant concentration monitors may be
necessary to determine vapor concentrations in work areas prior to use of torches or other open
flames, or if employees are entering enclosed areas.
Personal Protection: Impervious gloves and chemical splash goggles should be used when
handling liquid. Under normal manufacturing conditions, no respiratory protection is required
when using this product. Self-contained breathing apparatus (SCBA) is required if a large
release occurs.
Exposure Guideline: PEL (OSHA) - None established
TLV (ACGIH) - None established
WEEL (AIHA) - 1000 ppm, 8 hr. TWA
Physical and Chemical Properties:
Boiling Point:
-26.5°C (-15.7°F) @ 736 mm Hg
Vapor Pressure:
96 psia @ 25°C (77°F)
Vapor Density (Air=1): 3.6 @ 25°C (77°F)
% Volatiles:
100 WT%
Solubility in Water:
0.15 WT% @ 25°C (77°F) @ 14.7 psia
Odor:
Ether (slight)
Form:
Liquefied gas
Color:
Colorless
Liquid Density:
1.21 g/cm3 @ 25°C (77°F)
Section F:
Reactivity Data
Stability:
Stable
Conditions to Avoid: Avoid open flames and high temperatures.
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Incompatibility:
Incompatible with alkali or alkaline earth metals – powdered Al, Zn, Be,
etc
Decomposition:
Decomposition products are hazardous. This material can be decomposed
by high temperatures, (open flames, glowing metal surfaces, etc.) forming
hydrofluoric acid and possibly carbonyl fluoride.
Polymerization:
Will not occur.
Section G
Toxicological Information
Animal Data:
Ethane, 1,1,1,2-tetrafluoro
Eye:
A short duration spray of vapor produced very slight eye irritation.
Skin:
Animal testing indicates this material is a slight skin irritant, but not
a skin sensitizer.
Inhalation:
4 hour, ALC, rat: 567,000 ppm.
Single exposure caused:
Cardiac sensitization, a potentially fatal disturbance of heart rhythm
associated with a heightened sensitivity to the action of
epinephrine. Lowest observed adverse effect level for cardiac
sensitization; 75,000 ppm. Single exposure caused: lethargy,
narcosis, and increased respiratory rates. These effects were
temporary. Single exposure to near lethal doses caused: pulmonary
edema. Repeated exposure caused: increased adrenals, liver, and
spleen weight, decreased uterine, prostate weight. Repeated dosing
of higher concentrations caused the following temporary effects:
tremors and incoordination.
Carcinogenic, Development, Reproductive, Mutagenic Effects: In a two-year inhalation study,
HFC-134a at a concentration of 50,000 ppm, produced an increase in late-occuring benign
testicular tumors, testicular hyperplasia and testicular weight. The no-effect-level for this study
was 10,000 ppm. Animal data show slight fetotoxicity but only at exposure levels producing
other toxic effects in the adult animal. Reproductive data on male mice show: no change in
reproductive performance. Tests have shown that this material does not cause genetic damage in
bacterial or mammalian cell cultures, or in animals. In animal testing, this material has not
caused permanent genetic damage in reproductive cells of mammals (has not produced heritable
genetic damage).
Section H:
Environmental
Aquatic Toxicity
48 hour EC50 – Daphnia magna: 980 mg/L
96 hour LC50 – Rainbow trout: 450 mg/L
Waste disposal:
Contaminated HFC-134a can be recovered by distillation or
removed to a permitted waste disposal facility. Comply with
Federal, state and local regulations.
Section I:
Regulatory Information
Title III Hazard Classifications Section 311, 312
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Acute:
Yes
Chronic:
Yes
Fire:
No
Reactivity:
No
Pressure:
Yes
Hazard Chemical Lists:
SARA Extremely Hazardous
Substance:
No
CERCLA Hazardous Substance:
No
SARA Toxic Chemical:
No
Section J:
Additional Information
NFPA, NPCA-HMIS Rating
Health
1
Flammability
0
Reactivity
1
Personal protection rating to be supplied by user depending on use condition.
This product safety data sheet is offered solely for your information, consideration and
investigation. RMS of Georgia, L.L.C. provides no warranties either expressed or implied and
assumes no responsibility for the accuracy or completeness of the data contained herein.
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Material Safety Data Sheet
Rinker 711 Pipe Joint Lubricant (Water Dispersible)
Date of Preparation: July 2006
Section 1 - Chemical Product and Company Identification
Product/Chemical Name: Rinker 711 Pipe Joint Lubricant
Chemical Formula: 2006-7
Manufacturer: JTM Products, Inc., 31025 Carter Street, Solon, OH 44139, Phone (440) 287-2302, FAX (440) 287-3095
(CHEM-TEL 24-hour emergency: (800) 255-3924)
Section 2 - Composition / Information on Ingredients
Blend of soap, fatty oils and other non-toxic ingredients.
Section 3 - Hazards Identification
 Emergency Overview 
Potential Health Effects
Primary Entry Routes: Not Hazardous
Carcinogenicity: IARC, NTP, and OSHA do not list the ingredients in Rinker 711 Pipe Joint Lubricant as
carcinogens.
HMIS
H 1
F
1
R
0
†
PPE
†Sec. 8
Section 4 - First Aid Measures
Eye Contact: Flush with copious volumes of water for 15 minutes while holding eyelids open.
Skin Contact: Wash with water. If irritation persists, call a physician.
If swallowed, do not induce vomiting. Drink plenty of water and call a physician immediately.
Section 5 - Fire-Fighting Measures
Flash Point: >220 °F (>104 °C)
LEL: NA
NFPA
Flash Point Method: NA, contains water
UEL: NA
1
Autoignition Temperature: NA
Flammability Classification: 0
0
1
Extinguishing Media: Water, water fog, alcohol foam, carbon dioxide or dry chemical are all suitable.
—
Unusual Fire or Explosion Hazards: None
Hazardous Combustion Products: None
Fire-Fighting Instructions: Do not release runoff from fire control methods to sewers or waterways.
Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products, wear a self-contained breathing
apparatus (SCBA) with a full facepiece operated in pressure-demand or positive-pressure mode.
Section 6 - Accidental Release Measures
Spill /Leak Procedures:
Containment: For large spills, dike far ahead of spill for later disposal.
Cleanup: Place the bulk of any spilled material into drums, then rinse any remaining material to sewage treatment facility, in
accordance with any applicable regulations.
Regulatory Requirements: Follow applicable OSHA regulations (29 CFR 1910.120).
Section 7 - Handling and Storage
Handling Precautions: No special precautions are required.
Storage Requirements: No special precautions are required.
Regulatory Requirements: No known regulatory requirement for handling and storage.
Section 8 - Exposure Controls / Personal Protection
Engineering Controls:
Ventilation: Provide general or local exhaust ventilation systems.
Administrative Controls:
Respiratory Protection: If respirators are used, OSHA requires a written respiratory protection program that includes at least:
medical certification, training, fit-testing, periodic environmental monitoring, maintenance, inspection, cleaning, and convenient,
sanitary storage areas.
Page 1 of 2
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Rinker 711 Pipe Joint Lubricant (Water Dispersible)
Protective Clothing/Equipment: Wear chemically protective gloves to prevent prolonged or repeated skin contact. Wear
protective eyeglasses or chemical safety goggles, per OSHA eye- and face-protection regulations (29 CFR 1910.133). Contact
lenses are not eye protective devices. Appropriate eye protection must be worn instead of, or in conjunction with contact lenses.
Safety Stations: Make emergency eyewash stations, safety/quick-drench showers, and washing facilities available in work area.
Contaminated Equipment: Launder before reuse. Remove this material from your shoes and clean personal protective
equipment.
Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before
eating, drinking, smoking, using the toilet, or applying cosmetics.
Section 9 - Physical and Chemical Properties
Physical State: Paste-like
Appearance and Odor: amber paste, mild odor
Vapor Pressure: NA
Vapor Density (Air=1): NA
Density: ~9.1 lbs./gal.
Specific Gravity (H2O=1, at 4 °C): ~1.1
pH: NA
Water Solubility: partially solubility in water
Boiling Point: >220 °F
Freezing/Melting Point: <32 °F
Viscosity: viscous paste
Refractive Index: unknown
% Volatile: 4
Evaporation Rate: NA
Section 10 - Stability and Reactivity
Stability: Rinker 711 Pipe Joint Lubricant is stable at room temperature in closed containers under normal storage and handling
conditions.
Polymerization: Hazardous polymerization will not occur.
Chemical Incompatibilities:
Conditions to Avoid: Reactive alloys such as aluminum, brass, bronze. Also avoid contact with strong acids & strong oxidizing
agents.
Hazardous Decomposition Products: Thermal oxidative decomposition of Rinker 711 Pipe Joint Lubricant can produce oxides
of carbon.
Section 11- Toxicological Information
Toxicity Data:
Eye Effects: Eye irritant.
Skin Effects: Slight skin irritant if allowed to remain in contact.
Section 12 - Ecological Information
Ecotoxicity:
Environmental Fate
Environmental Transport: Unknown.
Environmental Degradation: Unknown.
Soil Absorption/Mobility: Unknown.
Section 13 - Disposal Considerations
Disposal: Contact your supplier or a licensed contractor for detailed recommendations. Follow applicable Federal, state, and
local regulations.
Section 14 - Transport Information
Not hazardous under DOT regulations.
Section 15 - Regulatory Information
EPA Regulations: None apply.
Section 16 - Other Information
Prepared By: J. Cahoon
Approved By: J. Cahoon
Disclaimer: JTM PRODUCTS, INC. makes no warranty, expressed or implied, as to the accuracy, completeness, or reliability of
information contained herein, except that such information is, to the best of JTM’s knowledge and belief, accurate as of the date
indicated. It is for the purchaser and/or user to decide whether this information is suitable for his purposes.
Page 2 of 2
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Material Safety Data Sheet
SECTION I - Material Identity
SECTION II - Manufacturer's Information
SECTION III - Physical/Chemical Characteristics
SECTION IV - Fire and Explosion Hazard Data
SECTION V - Reactivity Data
SECTION VI - Health Hazard Data
SECTION VII - Precautions for Safe Handling and Use
SECTION VIII - Control Measures
SECTION IX - Label Data
SECTION X - Transportation Data
SECTION XI - Site Specific/Reporting Information
SECTION XII - Ingredients/Identity Information
SECTION I - Material Identity
Item Name
Part Number/Trade Name
National Stock Number
CAGE Code
Part Number Indicator
MSDS Number
HAZ Code
STIHL 2-CYCLE ENGINE OIL
9150P1402-60
5L113
A
186678
B
SECTION II - Manufacturer's Information
Manufacturer Name
P.O. Box
Street
City
State
Country
Zip Code
Emergency Phone
Information Phone
WESTLAND OIL COMPANY
8098
P.O. BOX 8098
SHREVEPORT
LA
US
71148
(318) 688-1300
(318) 688-1300
MSDS Preparer's Information
Street
City
P.O. BOX 8098
SHREVEPORT
Page 308 of 320
State
Zip Code
Date MSDS Prepared/Revised
Date of Technical Review
Active Indicator
LA
71148
31OCT90
14JUN89
N
Alternate Vendors
Vendor #5 CAGE
BGVCL
SECTION III - Physical/Chemical Characteristics
Appearance/Odor
Boiling Point
Melting Point
Vapor Pressure
Vapor Density
Specific Gravity
Decomposition Temperature
Evaporation Rate
Solubility in Water
Percent Volatiles by Volume
Chemical pH
Corrosion Rate
Container Pressure Code
Temperature Code
Product State Code
DARK EMERALD GREEN
N/K
0.2
< 5
> 5
0.8810
N/K
0.2
NEGLIGABLE
8
N/K
N/K
1
4
L
SECTION IV - Fire and Explosion Hazard Data
Flash Point
Flash Point Method
Lower Explosion Limit
Upper Explosion Limit
Extinguishing Media
Special Fire Fighting Procedures
Unusual Fire/Explosion Hazards
175
PMCC
0.9
7.0
WATER SPRAY, DRY CHEMICAL,
FOAM OR CO2
WATER OR FOAM MAY CAUSE
FROTHING. USE WATER TO COOL
FIRE-EXPOSED CONTAINERS
IF A LEAK OR SPILL ISN'T
IGNITED, USE WATER TO DISPERSE
VAPORS & PROTECT PERSONNEL
SECTION V - Reactivity Data
Stability
Stability Conditions to Avoid
YES
HEAT & FLAME. PROLONGED
BREATHING OF MIST OR VAPOR.
PROLONGED OR REPEATED CONTACT
W/SKIN
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Materials to Avoid
Hazardous Decomposition Products
Hazardous Polymerization
Polymerization Conditions to Avoid
LD50 - LD50 Mixture
STRONG OXIDIZERS
CO, CO2, ALDEHYDES, KETONES,
COMBUSTION PRODUCTS OF
NITROGEN & SULFUR
NO
N/R
PRACTICALLY NON-TOXIC
SECTION VI - Health Hazard Data
Route of Entry: Skin
Route of Entry: Ingestion
Route of Entry: Inhalation
Health Hazards - Acute and Chronic
Carcinogenity: NTP
Carcinogenity: IARC
Carcinogenity: OSHA
Explanation of Carcinogenity
Symptoms of Overexposure
Medical Cond. Aggrevated by Exposure
Emergency/First Aid Procedures
YES
YES
YES
EYES/SKIN: MINIMALLY
IRRITATING. INHALATION:
DROWSINESS & UNCONSCIOUSNESS
POSSIBLE UPON EXPOSURE TO HIGH
CONCENTRATIONS IN POORLY
VENTILATED CONFINED SPACES
NO
NO
NO
NONE
EYES/SKIN: MINIMALLY
IRRITATING. INHALATION:
DROWSINESS & UNCONSCIOUSNESS
POSSIBLE UPON EXPOSURE TO HIGH
CONCENTRATIONS IN POORLY
VENTILATED CONFINED SPACES
N/K
EYES: WASH W/PLENTY OF WATER.
SKIN: WASH EXPOSED AREAS
W/SOAP & WATER. INGESTION:
DON'T INDUCE VOMITING.
ASPIRATION MAY CAUSE CHEMICAL
PNEUMONIA. INHALATION: SHOULD
SYMPTOMS NOTED UNDER
OVEREXPOSURE OCCUR, REMOVE TO
FRESH AIR. IF NOT BREATHING,
APPLY ARTIFICAL RESPIRATION
SECTION VII - Precautions for Safe Handling and Use
Steps if Material Released/Spilled
Neutralizing Agent
Waste Disposal Method
WIPE UP OR ABSORB ON SUITABLE
MATERIAL & SHOVEL UP
N/K
UNDER RCRA, IT IS THE
RESPONSIBILITY OF THE USER OF
PRODUCTS TO DETERMINE, AT THE
TIME OF DISPOSAL, WHETHER
PRODUCT MEETS RCRA CRITERIA
FOR HAZARDOUS WASTE. UNUSED
PRODUCT IS NOT A HAZARDOUS
WASTE
Page 310 of 320
Handling and Storage Precautions
Other Precautions
MINIMUM FEASIBLE HANDLING
TEMPERATURES SHOULD BE
MAINTAINED. WATER
CONTAMINATION SHOULD BE
AVOIDED
PERIODS OF EXPOSURE TO HIGH
TEMPEATURES SHOULD BE
MINIMIZED
SECTION VIII - Control Measures
Respiratory Protection
Ventilation
Protective Gloves
Eye Protection
Other Protective Equipment
Work Hygenic Practices
Supplemental Health/Safety Data
Disposal Code
N/K
NORMAL
RUBBER (OPTIONAL)
GOGGLES, FACE SHIELD
N/R
CLEANSING AREAS SEVERAL TIMES
DAILY W/SOAP & WATER.
LAUDERING OR DRY CLEANING
SOILED WORK CLOTHING AT LEAST
WEEKLY
N/R
O
SECTION IX - Label Data
Protect Eye
Protect Skin
Protect Respiratory
Chronic Indicator
Contact Code
Fire Code
Health Code
React Code
Specific Hazard and Precaution
YES
YES
YES
NO
SLIGHT
UNKNOWN
UNKNOWN
UNKNOWN
NO TARGET ORGANS LISTED FOR
CHRONIC EXPOSURES
SECTION X - Transportation Data
Container Quantity
Unit of Measure
2.6
OZF
SECTION XI - Site Specific/Reporting Information
Volatile Organic Compounds (P/G)
Volatile Organic Compounds (G/L)
0
0
SECTION XII - Ingredients/Identity Information
Page 311 of 320
Ingredient #
Ingredient Name
CAS Number
Percent
Ingredient #
Ingredient Name
CAS Number
NIOSH Number
Proprietary
Percent
OSHA PEL
ACGIH TLV
Recommended Limit
Ingredient #
Ingredient Name
CAS Number
NIOSH Number
Proprietary
Percent
OSHA PEL
ACGIH TLV
Recommended Limit
01
LUBRICATING OIL (>85%)
64742547
85
02
ADDITIVES (<10%)
ADDITIVE
1003000AS
NO
10
N/K
N/K
N/K
03
STODDARD SOLVENT (<10%)
8052413
WJ8925000
NO
10
500 PPM
100 PPM; 9293
100 PPM
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