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ITW Red Head
HMIS
G5 Epoxy Adhesive Manufacturer MSDS Number: G5
SECTION 1 : Chemical Product and Company Identification
MSDS Name: G5 Epoxy Adhesive Manufacturer
Name:ITW Red Head Department: Concrete
Anchoring Systems Address:
2171 Executive Drive, Suite 100
Addison, IL 60101
Product Description:
Part A: Epoxy Resin Part B: Amine Hardener For
emergencies in the US, call CHEMTREC: 8004249300
Manufacturer MSDS Revision Date:
July, 2007
HMIS Health Hazard: 3 Fire Hazard: 1 Reactivity: 0 Personal Protection: B
General Use:
Chemical anchor used for commercial construction.
Product Codes:
SECTION 2 : Hazardous Ingredients/Identity Information
OSHA PEL TWA: Not Established ACGIH TLV TWA: Not Established Other Exposure
Guidelines:
STEL: Not Established
CI-A-02
OSHA PEL TWA: Not Established
ACGIH TLV TWA: Not
Established Other Exposure
Guidelines:
STEL: Not Established
CAS Number: *
*An asterisk indicates a substance whose identity is a trade secret of our
supplier
Abbreviations:
TLV = ACGIH Threshold Limit Value
PEL = OSHA Permissible Exposure
STEL = Short Term Exposure Limit
NA = Not Applicable
NE = None Established
SECTION 3 : Physical And Chemical Characteristics
Physical State/Appearance:
Part A: Paste
Part B: Paste
Color:
Part A: Beige
Part B: Gray
Boiling Point:
Part A: = > 400 deg F
Part B: = > 212 deg F
Solubility:
Water:
Part A: None
Part B: None
Specific Gravity:
Part A: = 1.2 g/cm3 (at 20 deg C)
Part B: = 1.7 g/cm3 (at 20 deg C)
FlashPoint:
> 212 deg F
SECTION 4 : Fire And Explosion Hazards
Fire:
Flammable Limits: Not applicable
Material will not burn unless preheated. Do not enter confined space without full
CI-A-02
bunker gear. Firefighters should use selfcontained breathing apparatus and
protective clothing.
Flash Point:
> 212 deg F
Extinguishing Media:
CO2, Dry Chemical, Foam, and Water Spray.
Fire Fighting Instructions:
Use selfcontained breathing apparatus.
Unusual Fire Hazards:
SECTION 5 : Health Hazards
Applies to all ingredients:
Route of Exposure:
Contact. Inhalation.
Carcinogenicity:
No ingredients are classified as carcinogens by IARC, NTP or OSHA
Aggravation of PreExisting Conditions:
Eye, skin and respiratory conditions.
Hazard Categories:
Immediate health hazard; delayed health hazard
Part A: Bisphenol A Epoxy Resin:
Potential Health Effects:
Part A: Eye and skin irritant. Possible skin sensitizer. May be irritating to eyes,
skin, nose and throat.
Part B: Amine Blend:
Potential Health Effects:
Part B: Corrosive. May cause eye and skin burns. Vapors may be irritating. May
cause burns if swallowed.
SECTION 6 : Emergency And First Aid Procedures
Eye Contact:
Flush immediately with water for at least 15 minutes. Seek medical advice.
Skin Contact:
Wash immediately with soap and water. Launder contaminated clothing before
reu
se.
Inhalati
on:
If symptoms occur, move to fresh air. Call a physician if symptoms persist.
Ingestion:
CI-A-02
Rinse mouth and then drink large quantities of water. Don’t give anything by
mouth
to an unconscious person. Seek medical attention. Do not induce vomiting
unless
directed
by
a
physician. Other First
Aid:
Referral to a physician is recommended if there is any question about the
seriousness of the exposure.
SECTION 7 :
Reactivity Data
Chemical Stability:
Stable
Conditions to Avoid:
Avoid elevated temperatures which may shorten the shelflife
of this product.
Incompatibilities with Other Materials:
Strong acids and oxidizing agents.
Hazardous Polymerization:
Will not occur.
Hazardous Decomposition Products:
SECTION 8 : Precautions For Safe Handling
Spill Cleanup Measures:
Collect with an absorbent material and place in a container for proper disposal.
For large spills, transfer to salvage vessels, and dispose of according to state,
local and Federal regulations. Flush area with water to remove residue.
Handling:
For professional use only. Keep away from children. Avoid contact with the
eyes and skin. Wash after using and before eating or smoking. Avoid
breathing vapors. Use only as directed; avoid uncontrolled mixing with other
materials, esp. polymerizable or combustible materials.
Storage:
For maximum shelf life, store in a cool dry area between 40 deg F and 80
deg F. Do not store above 110 deg F
Waste Disposal:
If this material becomes a waste, it would not be hazardous waste by RCRA
criteria (40CFR261). Dispose according to federal, state and local regulations.
EPA Waste Number:
Not regulated by EPA as a hazardous waste.
DOT Shipping Name:
Consumer commodity, ORMD
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DOT UN Number:
2735 DOT Hazard Class: 8 Corrosives NAERG Number: 153
SECTION 9 : Control Measures
Ventilation System:
Use in well ventilated areas.
Skin Protection Description:
Impermeable (neoprene or rubber)gloves are recommended.
Eye/Face Protection:
Wear safety glasses with side shields.
Respiratory Protection:
None normally required. Where ventilation is inadequate to control vapors, use
a NIOSH/OSHA approved respirator with organic vapor cartridges. Do not enter
confined spaces without an appropriate air supplied respirator.
SECTION 10 : Other Information
Applies to All Ingredients:
TSCA 8(b): Inventory Status
Chemical components are listed on TSCA inventory or are exempt as impurities.
Section 312 Hazard Category:
Acute: Yes Chronic: Yes OSHA 29 CFR 1200:
This MSDS has been prepared in accordance with the federal OSHA
Hazard Communication Standard 29 CFR 1910.1200.
Canada WHMIS:
WHMIS hazard class: D2B.
Canadian EPA: All ingredients are listed on the DSL or are exempt as impurities.
Part B: Amine Blend:
Section 313 Toxic Release Form:
This product contains an Amine Blend which is subject to reporting under
Section 313 or SARA Title III (40 CFR Part 372).
HMIS: Health Hazard: 3 Fire Hazard: 1 Reactivity: 0 Personal Protection: B
MSDS Revision Date:
July, 2007
Disclaimer:
The information and recommendations in this document are based on the best
information available to us at the time of preparation. We make no other
warranty, expressed or implied, as to its correctness or completeness, or as to
the results or reliance of this document.
Abbreviations:
TLV = ACGIH Threshold Limit Value
PEL = OSHA Permissible Exposure
CI-A-02
STEL = Short Term Exposure Limit
NA = Not Applicable
NE = None Established
Copyright© 19962009 Actio Corporation. All Rights Reserved.
CI-A-02
THE DOW CHEMICAL COMPANY
MATERIAL SAFETY DATA SHEET
Product Name: DOWTHERM* SR-1 Heat Transfer Fluid,
Dyed
MSDS#: 40647
Effective Date: 06/21/2002
Page 1 of 15
Dow (hereinafter, and for purposes of this MSDS only, refers to The Dow Chemical Company and to Dow
Chemical Canada Inc.) encourages and expects you to read and understand the entire MSDS, as there is
important information throughout the document. Dow expects you to follow the precautions identified in
this document unless your use conditions would necessitate other appropriate methods or actions.
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
1.1 IDENTIFICATION
Product Name
DOWTHERM* SR-1 Heat Transfer Fluid, Dyed
1.2 COMPANY IDENTIFICATION
The Dow Chemical Company
Midland, MI 48674
1.3 EMERGENCY TELEPHONE NUMBER
24-HOUR EMERGENCY TELEPHONE NUMBER: (989)636-4400.
Customer Information Number: 1-800-258-2436.
* or ® Indicates a Trademark of The Dow Chemical Company.
CI-C-01
MATERIAL SAFETY DATA SHEET
Product Name: DOWTHERM* SR-1 Heat Transfer Fluid,
Dyed
MSDS#: 40647
Effective Date: 06/21/2002
Page 2 of 15
2. COMPOSITION INFORMATION
Component
CAS #
Amount (%W/W )
Ethylene glycol
Dipotassium hydrogen phosphate
Water
107-21-1
7758-11-4
7732-18-5
> 95 %
< 3%
< 3%
3. HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Appearance
Pink
Physical
State
Liquid
Odor
Sweet
Hazards of
product
HARMFUL OR FATAL IF SWALLOWED.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
3.2 POTENTIAL HEALTH EFFECTS
Effects of Single Acute Overexposure
Inhalation At room temperature, exposure to vapor is minimal due to low volatility. With good
ventilation, single exposure is not expected to cause adverse effects. If material is heated or areas are
poorly ventilated, vapor/mist may accumulate and cause respiratory irritation and symptoms such as
headache & nausea.
Eye Contact May cause slight temporary eye irritation. Corneal injury is unlikely. Vapor or mist may
cause eye irritation.
CI-C-01
MATERIAL SAFETY DATA SHEET
Product Name: DOWTHERM* SR-1 Heat Transfer Fluid,
Dyed
MSDS#: 40647
Effective Date: 06/21/2002
Page 3 of 15
Skin Contact Brief contact is essentially nonirritating to skin. Prolonged contact may cause slight skin
irritation with local redness. May cause more severe response if skin is abraded (scratched or cut).
Skin Absorption Prolonged skin contact is unlikely to result in absorption of harmful amounts.
Repeated skin exposure to large quantities may result in the absorption of harmful amounts. Massive
contact with damaged skin or of material sufficiently hot to burn skin may result in absorption of potentially
lethal amounts.
Swallowing Oral toxicity is expected to be moderate in humans due to ethylene glycol even though
tests with animals show a lower degree of toxicity. Excessive exposure may cause central nervous system
effects, cardiopulmonary effects (metabolic acidosis), and kidney failure. Swallowing may result in severe
effects, even death. The lethal dose in adult humans for ethylene glycol is approximately 3 ounces (100
ml) (1/3 cup). In humans, expected to be moderately toxic if swallowed even though oral toxicity was low
when tested in animals. May cause nausea or vomiting. May cause abdominal discomfort or diarrhea.
Chronic, Prolonged or Repeated Overexposure
Effects of Repeated Overexposure
Repeated excessive exposure may cause irritation of the
upper respiratory tract. In humans, effects have been reported on the following organs: Central nervous
system. Observations in humans include: Nystagmus (involuntary eye movement). In animals, effects
have been reported on the following organs: Kidney, liver. Based on animal studies, ingestion of very large
amounts of ethylene glycol appears to be the major and possibly only route of exposure to produce birth
defects. Exposures by inhalation or skin contact, the primary routes of occupational exposure, had minimal
effect on the fetus, in animal studies. Ingestion of large amounts of ethylene glycol has been shown to
interfere with reproduction in animals.
Other Effects of Overexposure No information available.
See Section 11 for toxicological information and additional information about potential health
effects.
3.3 POTENTIAL ENVIRONMENTAL EFFECTS
See Section 12 for Ecological Information.
4. FIRST AID PROCEDURES
4.1 INHALATION
Move person to fresh air; if effects occur, consult a physician.
CI-C-01
MATERIAL SAFETY DATA SHEET
Product Name: DOWTHERM* SR-1 Heat Transfer Fluid,
Dyed
MSDS#: 40647
Effective Date: 06/21/2002
Page 4 of 15
4.2 EYE CONTACT
Flush eyes thoroughly with water for several minutes. Remove contact lenses after the initial 1-2
minutes and continue flushing for several additional minutes. If effects occur, consult a
physician, preferably an ophthalmologist.
4.3 SKIN CONTACT
Immediately flush skin with water while removing contaminated clothing and shoes. Get medical
attention if symptoms occur. Wash clothing before reuse. Discard contaminated articles
including leather items such as shoes.
4.4 SWALLOWING
Do not induce vomiting. Seek medical attention immediately. If person is fully conscious give 1
cup or 8 ounces (240 ml) of water. If medical advice is delayed and if an adult has swallowed
several ounces of chemical, then give 3-4 ounces (1/3-1/2 Cup) (90-120 ml) of hard liquor such
as 80 proof whiskey. For children, give proportionally less liquor at a dose of 0.3 ounces (1 1/2
tsp) (8 ml) liquor for each 10 pounds of body weight, or 2 ml per kg body weight [e.g., 1.2 ounce
(2 1/3 Tbsp) for a 40 pound child or 36 ml for an 18 kg child].
4.5 NOTES TO PHYSICIAN
If several ounces of EG have been ingested, early administration of ethanol may counter the
toxic effects (metabolic acidosis, renal damage). Consider hemodialysis or peritoneal dialysis &
thiamine 100 mg plus pyridoxine 50 mg IV every 6 hr.
If ethanol is used, a therapeutically effective blood concentration in the range of 100 - 150 mg/dl
may be achieved by a rapid loading dose followed by a continuous intravenous infusion. Consult
standard literature for details of treatment.
4-Methyl pyrazole (Antizol®) is an effective blocker of alcohol dehydrogenase and should be
used in the treatment of ethylene glycol, di- or triethylene glycol, ethylene glycol butyl ether, or
methanol intoxication if available.
Fomepizole protocol (Brent, J. et al., New England Journal of Medicine, Feb. 8, 2001, 344:6, p.
424-9): loading dose 15 mg/kg IV, follow by bolus dose of 10 mg/kg every 12 hours; after 48
hours, increase bolus dose to 15 mg/kg every 12 hours.
Continue fomepizole until serum methanol, EG, DEG, or TEG are undetectable. The signs and
symptoms of poisoning include anion gap metabolic acidosis, CNS depression, renal tubular
injury, and possible late stage cranial nerve involvement.
Respiratory symptoms, including pulmonary edema, may be delayed. Persons receiving
significant exposure should be observed 24-48 hours for signs of respiratory distress.
In severe poisoning, respiratory support with mechanical ventilation and positive end expiratory
pressure may be required.
If lavage is performed, suggest endotracheal and/or esophageal control. Danger from lung
aspiration must be weighed against toxicity when considering emptying the stomach.
CI-C-01
MATERIAL SAFETY DATA SHEET
Product Name: DOWTHERM* SR-1 Heat Transfer Fluid,
Dyed
MSDS#: 40647
Effective Date: 06/21/2002
Page 5 of 15
5. FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES - REFER TO SECTION 9, PHYSICAL AND
CHEMICAL PROPERTIES
5.2 EXTINGUISHING MEDIA
Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers.
Foam. Do not use direct water stream. May spread fire. Alcohol resistant foams (ATC type) are
preferred. General purpose synthetic foams (including AFFF) or protein foams may function, but
will be less effective.
5.3 FIRE FIGHTING PROCEDURES
Keep people away. Isolate fire and deny unnecessary entry. Use water spray to cool fire
exposed containers and fire affected zone until fire is out and danger of reignition has passed.
Fight fire from a protected location or safe distance. Consider the use of unmanned hose holders
or monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound
from venting safety device or discoloration of the container. Burning liquids may be extinguished
by dilution with water. Do not use direct water stream. May spread fire. Move container from
fire area if this is possible without hazard. Burning liquids may be moved by flushing with water
to protect personnel and minimize property damage.
5.4 SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting
clothing (includes fire fighting helmet, coat, pants, boots, and gloves). If protective equipment is
not available or not used, fight fire from a protected location or safe distance.
5.5 UNUSUAL FIRE AND EXPLOSION HAZARDS
Container may rupture from gas generation in a fire situation.
Violent steam generation or eruption may occur upon application of direct water stream to hot
liquids.
Liquid mist of this product can burn.
Flammable concentrations of vapor can accumulate at temperatures above flash point; see
Section 9.
5.6 HAZARDOUS COMBUSTION PRODUCTS
During a fire, smoke may contain the original material in addition to combustion products of
varying composition which may be toxic and/or irritating. Combustion products may include and
are not limited to: Carbon monoxide. Carbon dioxide.
6. ACCIDENTAL RELEASE MEASURES
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MATERIAL SAFETY DATA SHEET
Product Name: DOWTHERM* SR-1 Heat Transfer Fluid,
Dyed
MSDS#: 40647
Effective Date: 06/21/2002
Page 6 of 15
Steps to be Taken if Material is Released or Spilled:
Small spills: Absorb with materials such as: cat litter. sawdust. vermiculite. Zorb-all®. Collect
in suitable and properly labeled containers. Large spills: Dike area to contain spill. See Section
13, Disposal Considerations for additional information.
Personal Precautions: Use appropriate safety equipment. For additional information, refer to
Section 8, Exposure Controls and Personal Protection. Refer to Section 7, Handling for
additional precautionary measures.
Environmental Precautions: Prevent from entering into soil, ditches, sewers, waterways and/
or groundwater. See Section 12, Ecological Information.
7. HANDLING AND STORAGE
7.1 HANDLING
General Handling
Do not swallow.
Wash thoroughly after handling.
Avoid breathing vapor and mist.
Use with adequate ventilation.
Keep container closed.
See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION.
Ventilation
Provide general and/or local exhaust ventilation to control airborne levels below the exposure
guidelines.
Other Precautions
Spills of these organic materials on hot fibrous insulations may lead to lowering of the
autoignition temperatures possibly resulting in spontaneous combustion.
7.2 STORAGE
Do not store in opened or unlabeled containers. Do not store in: galvanized steel.
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
8.1 EXPOSURE LIMITS
Component
CI-C-01
Exposure Limits
Skin Form
MATERIAL SAFETY DATA SHEET
Product Name: DOWTHERM* SR-1 Heat Transfer Fluid,
Dyed
MSDS#: 40647
Ethylene glycol
100 mg/m3 CEILING ACGIH
100 mg/m3 CEILING Interim
IHG
Effective Date: 06/21/2002
Page 7 of 15
Aerosol
Aerosol and Vapor
In the Exposure Limits Chart above, if there is no specific qualifier (i.e., Aerosol) listed in the
Form Column for a particular limit, the listed limit includes all airborne forms of the substance
that can be inhaled.
A "Yes" in the Skin Column indicates a potential significant contribution to overall exposure by
the cutaneous (skin) route, including mucous membranes and the eyes, either by contact with
vapors or by direct skin contact with the substance. A "Blank" in the Skin Column indicates that
exposure by the cutaneous (skin) route is not a potential significant contributor to overall
exposure.
"Interim IHGs" are occupational exposure limits set by the original owner of this product prior to
the merger with Dow. These limits have not been reviewed per the Dow IHG process, but are
utilized during this period of merger integration until Dow can formally adopt or modify.
8.2 PERSONAL PROTECTION
Respiratory
Protection:
Atmospheric levels should be maintained below the exposure
guideline.
For most conditions, no respiratory protection should be needed;
however, if material is heated or sprayed, use an approved airpurifying respirator.
Ventilation:
Provide general and/or local exhaust ventilation to control airborne
levels below the exposure guidelines.
Eye Protection:
Use safety glasses.
If exposure causes eye discomfort, use a full-face respirator.
Other Protective
Equipment:
When prolonged or frequently repeated contact could occur, use
chemically protective clothing resistant to this material. Selection of
specific items such as faceshield, gloves, boots, apron, or full-body
suit will depend on operation.
If hands are cut or scratched, use gloves chemically resistant to this
material even for brief exposures.
When handling hot material, protect skin from thermal burns as well as
from skin absorption.
CI-C-01
MATERIAL SAFETY DATA SHEET
Product Name: DOWTHERM* SR-1 Heat Transfer Fluid,
Dyed
MSDS#: 40647
Effective Date: 06/21/2002
Page 8 of 15
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State:
Appearance:
Odor:
Liquid
Pink
Sweet
Flash Point - Closed Cup:
111 °C
232 °F
Tag Closed Cup ASTM D 56 (Values for
Ethylene Glycol)
Flammable Limits In Air:
Lower
Upper
3.2 %(V) (for ethylene glycol)
No test data available.
Autoignition Temperature:
Vapor Pressure:
398 °C
748 °F
2.2 mmHg 20 °C
Boiling Point (760 mmHg):
Vapor Density (air = 1):
163 °C
325 °F
> 1.0
Specific Gravity (H2O = 1):
1.1295
60 °C / 60 °C
Freezing Point: No test data available.
Melting Point: Not applicable (for liquids)
Solubility in Water (by weight):
pH:
100 %
No test data available.
10. STABILITY AND REACTIVITY
10.1 STABILITY/INSTABILITY
Thermally stable at recommended temperatures and pressures.
Conditions to Avoid: Exposure to elevated temperatures can cause product to decompose.
Generation of gas during decomposition can cause pressure in closed systems.
CI-C-01
MATERIAL SAFETY DATA SHEET
Product Name: DOWTHERM* SR-1 Heat Transfer Fluid,
Dyed
MSDS#: 40647
Effective Date: 06/21/2002
Page 9 of 15
Incompatible Materials: Avoid contact with: Strong acids. Strong bases. Strong oxidizers.
Thermal Decomposition: Decomposition products depend upon temperature, air supply and
the presence of other materials. Decomposition products can include and are not limited to:
Aldehydes. Alcohols. Ethers.
10.2 HAZARDOUS POLYMERIZATION
Will not occur.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Peroral
Based on information for a similar material:
Rat; LD50 = 8200 mg/kg
Percutaneous
Based on information for a similar material:
Rabbit; LD50 (> 2000) mg/kg
DEVELOPMENTAL TOXICITY
Based on animal studies, ingestion of very large amounts of ethylene glycol appears to be the
major and possibly only route of exposure to produce birth defects., Exposures by inhalation or
skin contact, the primary routes of occupational exposure, had minimal effect on the fetus, in
animal studies.
REPRODUCTIVE TOXICITY
Ingestion of large amounts of ethylene glycol has been shown to interfere with reproduction in
animals.
CHRONIC TOXICITY AND CARCINOGENICITY
Ethylene glycol did not cause cancer in long-term animal studies.
GENETIC TOXICOLOGY
CI-C-01
MATERIAL SAFETY DATA SHEET
Product Name: DOWTHERM* SR-1 Heat Transfer Fluid,
Dyed
MSDS#: 40647
Effective Date: 06/21/2002
Page 10 of 15
In Vitro
For the major component:, In vitro mutagenicity studies were negative.
In Vivo
For the major component:, Animal mutagenicity studies were negative.
SIGNIFICANT DATA WITH POSSIBLE RELEVANCE TO HUMANS
Repeated excessive exposure may cause irritation of the upper respiratory tract.
In humans, effects have been reported on the following organs:
Central nervous system.
Observations in humans include:
Nystagmus (involuntary eye movement).
In animals, effects have been reported on the following organs:
Kidney, liver.
12. ECOLOGICAL INFORMATION
12.1 ENVIRONMENTAL FATE
Based largely or completely on information for: Ethylene glycol. Material is readily
biodegradable. Passes OECD test(s) for ready biodegradability.
12.2 ECOTOXICITY
Based largely or completely on information for:, Ethylene glycol., Material is practically non-toxic
to aquatic organisms on an acute basis (LC50/EC50 >100 mg/L in most sensitive species
tested).
12.3 FURTHER INFORMATION
Based largely or completely on information for: Ethylene glycol. Bioconcentration potential is
low (BCF < 100 or Log Pow < 3). Potential for mobility in soil is very high (Koc between 0 and
50).
CI-C-01
MATERIAL SAFETY DATA SHEET
Product Name: DOWTHERM* SR-1 Heat Transfer Fluid,
Dyed
MSDS#: 40647
Effective Date: 06/21/2002
Page 11 of 15
13. DISPOSAL CONSIDERATIONS
13.1 DISPOSAL
DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER.
All disposal practices must be in compliance with all Federal, State/Provincial and local laws and
regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. DOW HAS
NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING
PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION
PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED
CONDITION AS DESCRIBED IN MSDS SECTION 2 (Composition/ Information On Ingredients).
FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a
licensed, permitted: recycler. reclaimer. incinerator or other thermal destruction device. As a
service to its customers, Dow can provide names of information resources to help identify waste
management companies and other facilities which recycle, reprocess or manage chemicals or
plastics, and that manage used drums. Telephone Dow's Customer Information Group at 1-800258-2436 or 1-989-832-1556 (U.S.), or 1-800-331-6451 (Canada) for further details .
14. TRANSPORT INFORMATION
14.1 U.S. D.O.T.
NON-BULK
Proper Shipping Name : NOT REGULATED
BULK
Proper Shipping Name : OTHER REGULATED SUBSTANCES, LIQUID, NOS
Technical Name : CONTAINS ETHYLENE GLYCOL
Hazard Class : 9
ID Number : NA3082
Packing Group : PG III
Reportable Quantity : 5,263 LB
CI-C-01
MATERIAL SAFETY DATA SHEET
Product Name: DOWTHERM* SR-1 Heat Transfer Fluid,
Dyed
MSDS#: 40647
Effective Date: 06/21/2002
Page 12 of 15
This information is not intended to convey all specific regulatory or operational
requirements/information relating to this product. Additional transportation system information
can be obtained through an authorized sales or customer service representative. It is the
responsibility of the transporting organization to follow all applicable laws, regulations and rules
relating to the transportation of the material.
15. REGULATORY INFORMATION
15.1 FEDERAL/NATIONAL
OSHA HAZARD COMMUNICATION STANDARD
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EMERGENCY PLANNING AND
COMMUNITY RIGHT TO KNOW ACT) SECTION 313
This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act 1986 and 40 CFR Part
372.
Component
Ethylene glycol
CAS #
107-21-1
Amount
> 95.0000 %
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EMERGENCY PLANNING AND
COMMUNITY RIGHT TO KNOW ACT) SECTION 302
To the best of our knowledge this product does not contain chemicals at levels which
require reporting under this statute.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EMERGENCY PLANNING AND
COMMUNITY RIGHT TO KNOW ACT)SECTIONS 311 AND 312
Delayed (Chronic) Health Hazard : Yes
Fire Hazard : No
Immediate (Acute) Health Hazard : Yes
CI-C-01
MATERIAL SAFETY DATA SHEET
Product Name: DOWTHERM* SR-1 Heat Transfer Fluid,
Dyed
MSDS#: 40647
Effective Date: 06/21/2002
Page 13 of 15
Reactive Hazard : No
Sudden Release of Pressure Hazard : No
TOXIC SUBSTANCES CONTROL ACT (TSCA)
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory
requirements.
CEPA - DOMESTIC SUBSTANCES LIST (DSL)
This product contains one or more substances which are not listed on the Canadian Domestic
Substances List (DSL). Contact your Dow representative for more information.
15.2 STATE/LOCAL
PENNSYLVANIA (WORKER AND COMMUNITY RIGHT TO KNOW ACT): PENNSYLVANIA HAZARDOUS SUBSTANCES
LIST AND/OR PENNSYLVANIA ENVIRONMENTAL HAZARDOUS SUBSTANCE LIST:
The following product components are cited in the Pennsylvania Hazardous Substance List
and/or the Pennsylvania Environmental Substance List, and are present at levels which require
reporting.
Component
CAS #
Amount
Ethylene glycol
107-21-1
> 95.0000 %
PENNSYLVANIA (WORKER AND COMMUNITY RIGHT TO KNOW ACT): PENNSYLVANIA SPECIAL HAZARDOUS
SUBSTANCES LIST:
To the best of our knowledge this product does not contain chemicals at levels which require
reporting under this statute.
CALIFORNIA PROPOSITION 65 (SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986)
This product contains no listed substances known to the State of California to cause cancer,
birth defects or other reproductive harm, at levels which would require a warning under the
statute.
CI-C-01
MATERIAL SAFETY DATA SHEET
Product Name: DOWTHERM* SR-1 Heat Transfer Fluid,
Dyed
MSDS#: 40647
Effective Date: 06/21/2002
Page 14 of 15
CALIFORNIA SCAQMD RULE 443.1 (SOUTH COAST AIR QUALITY M ANAGEMENT DISTRICT RULE 443.1,
LABELING OF MATERIALS CONTAINING ORGANIC SOLVENTS)
VOC:
Not determined.
This section provides selected regulatory information on this product including its components.
This is not intended to include all regulations. It is the responsibility of the user to know and
comply with all applicable rules, regulations and laws relating to the product being used.
16. OTHER INFORMATION
16.1 ADDITIONAL INFORMATION
Additional information on this and other Dow products may be obtained by visiting our web page
at www.dow.com.
Additional information on this product may be obtained by calling Dow's Customer Information
Group at 1-800-258-2436 (U.S.) or 1-800-331-6451 (Canada). Ask for a product brochure.
16.2 HAZARD RATING SYSTEM
NFPA ratings for this product are: H - 1
F- 1
R-0
These ratings are part of a specific hazard communication program and should be disregarded
where individuals are not trained in the use of this hazard rating system. You should be familiar
with the hazard communication programs applicable to your workplace.
16.3 RECOMMENDED USES AND RESTRICTIONS
For industrial use.
CI-C-01
MATERIAL SAFETY DATA SHEET
Product Name: DOWTHERM* SR-1 Heat Transfer Fluid,
Dyed
MSDS#: 40647
Effective Date: 06/21/2002
Page 15 of 15
Dow recommends that you use this product in a manner consistent with the listed use. If your
intended use is not consistent with Dow's stated use, please contact Dow's Customer
Information Group at 1-800-258-2436 (U.S.) or 1-800-331-6451 (Canada) for more information.
16.4 REVISION
Version: 1.0
Revision: 06/21/2002
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
16.5 LEGEND
Bacterial/NA
F
H
IHG
N/A
NFPA
O
R
TS
VOL/VOL
W
W/W
Non Acclimated Bacteria
Fire
Health
Industrial Hygiene Guideline
Not available
National Fire Protection Association
Oxidizer
Reactivity
Trade secret
Volume/Volume
Water Reactive
Weight/Weight
NOTICE: Dow urges each customer or recipient of this MSDS to study it carefully and consult
appropriate expertise, as necessary or appropriate, to become aware of and understand the data
contained in this MSDS and any hazards associated with the product. The information herein is
provided in good faith and believed to be accurate as of the effective date shown above.
However, no warranty, express or implied, is given., Regulatory requirements are subject to
change and may differ between various locations. It is the buyer's/user's responsibility to ensure
that its activities comply with all federal, state, provincial or local laws. The information
presented here pertains only to the product as shipped. Since conditions for use of the product
are not under the control of Dow, it is the buyer's/user's duty to determine the conditions
necessary for the safe use of this product., Due to the proliferation of sources for information
such as manufacturer-specific MSDSs, Dow is not and cannot be responsible for MSDSs
obtained from any source other than Dow. If you have obtained a Dow MSDS from a non-Dow
source or if you are not sure that a Dow MSDS is current, please contact Dow for the most
current version.
CI-C-01
Vulcan Oil & Chemical Products
A Division of
The Cincinnati Vulcan Company
5353 Spring Grove Avenue
Cincinnati, Ohio 45217
Phone: 513-242-2672
www.vulcanoil.com
Material Safety Data Sheet
Product Code: RI333
Revision Date: 03/26/2004
Revised By: MSDS Dept.
Page:
1
Section 1 - Product Identification
Product Name: RI 333 Rust Inhibited Coolant
Hazard Rating
Health
Fire
Reactivity
NFPA Code:
1
0
0
0=Least
1=Slight
2=Moderate 3=High
4=Extreme
________________________________________________________________________________
Section 2 - Hazardous Ingredients / Identity Information
Specific Identity; Common Names
OSHA PEL ACGIH TLV
Other
Proprietary Formula - Specific Chemical Identities Have Been Withheld
102-71-6
Alkanolamine
5 mg/m3
________________________________________________________________________________
Section 3 - Physical/Chemical Characteristics
Appearance
Blue liquid
Boiling Point, Deg. F
Not Known
Evaporation, BuAcetate=1
Slower than
Odor
Mild
Solubility in water
Complete
Vapor Density (Air=1)
Not Known
Vapor Pressure
Not Known
Pounds per Gallon
8.543
Specific Gravity
1.026
________________________________________________________________________________
Section 4 - Fire and Explosion Hazard Data
Flash Point COC:
NA
Flammable Limits: LEL-Not Known
UEL-Not Known
Extinguishing Media: Foam, dry chemical, water fog, carbon dioxide.
Special Fire Fighting Procedures: Cool fire exposed containers with water.
Do not enter a confined fire space without full bunker gear and NIOSH
approved supplied air breathing apparatus.
Unusual Fire and Explosion Hazards: Product is water based and will not
burn until water has evaporated.
________________________________________________________________________________
Section 5 - Reactivity Data
Stability - Stable.
Incompatibility - Strong acids. Nitrites. Oxidizing agents.
Hazardous Decomposition Products - Oxides of carbon. Oxides of nitrogen. Oxides
of sulfur.
Hazardous Polymerization - Will not occur.
Other This product contains amines. Do not mix with nitrite or other nitrosating
agents due to the potential for nitrosamine formation.
________________________________________________________________________________
Section 6 - Health Hazard Data
Routes of Entry: Inhalation-yes
Skin-yes
Ingestion-yes
Health Hazards:
The health hazards listed below are for components to this mixture. The active
ingredients are diluted in water in this mixture and the severity of the listed
health hazards for this product may be reduced. This product is designed to be
diluted significantly with water before product use. The severity of these
health hazards may be reduced further at usage concentrations.
(Acute and Chronic Overexposure)
Eyes - Corrosive. Irritation. Redness. Severe damage. Swelling. Tearing.
CI-C-02
continued...
Vulcan Oil & Chemical Products
A Division of
The Cincinnati Vulcan Company
5353 Spring Grove Avenue
Cincinnati, Ohio 45217
Phone: 513-242-2672
www.vulcanoil.com
...continued
Material Safety Data Sheet
Product Code: RI333
Revision Date: 03/26/2004
Revised By: MSDS Dept.
Page:
2
Skin - Corrosive. Repeated or prolonged contact may cause defatting, oil acne,
irritation or
allergic reaction in sensitive individuals.
Inhalation - Harmful if inhaled. Slight Irritation.
Ingestion - Diarrhea. Harmful if swallowed. Irritation. Lethargy. Nausea. Vomiting.
Swallowing this material can cause burns to the mouth and esophagus.
Asphyxiation can occur from swelling of the throat. Perforation of the esophgus
and stomach can occur.
Signs And Symptoms of Exposure - As Noted Above.
Medical Conditions Generally Aggravated By Exposure - None Known.
Other Precautions - NA
Other Long-term oral ingestion of ethanolamines by rats and guinea pigs produced
damage to liver and kidneys. Long-term cutaneous applications to animals of
ethanolamines also produced evidence of damage to liver and kidneys.
Carcinogenicity
NTP-No
IARC-No
OSHA-No
Emergency and First Aid Procedures: Inhalation - remove to fresh air. Skin
contact - wash using a mild soap. Eye contact - flush with water, see
a physician. Ingestion - call a physician.
________________________________________________________________________________
Section 7 - Precautions for Safe Handling and Use
Steps to be Taken in Case Material is Released or Spilled:
Dike area. Recover free product. Add a dry absorbent material to spill
area.
Waste Disposal Method: Dispose by methods consistent with local state and
federal regulations.
Precautions to be Taken in Handling and Storing:
Keep containers tightly
closed. Use and store this product with adequate ventilation. Avoid
inhalation of vapors and personal contact with the product. To
dissipate static electricity during transfer, ground and/or bond both
containers. Since emptied containers retain product residue, follow
warnings even after container is emptied. Residue or vapors may
explode on ignition; do not cut, drill, grind or weld on or near
container even when empty.
Other Precautions:
Not Applicable
________________________________________________________________________________
Section 8 - Control Measures
Respiratory Protection: Not normally required. Use NIOSH approved supplied
air breathing equipment if vapors are excessive.
Ventilation:
Local Exhaust :
Not normally required.
Mechanical (General):
Use general ventilation.
Protective Gloves: Use chemical-resistant gloves, if needed, to avoid skin
contact.
Eye Protection: Use splash goggles or face shield when eye contact may
occur.
Other Protective Clothing or Equipment: To prevent repeated or prolonged
skin contact, wear impervious apron/clothing and boots.
Work/Hygienic Practices: Minimize breathing vapor, mist or fumes. Wash
skin with soap and water after contact. Launder contaminated
clothing.
CI-C-02
continued...
Vulcan Oil & Chemical Products
A Division of
The Cincinnati Vulcan Company
Product Code: RI333
Revision Date: 03/26/2004
Revised By: MSDS Dept.
Page:
3
5353 Spring Grove Avenue
Cincinnati, Ohio 45217
Phone: 513-242-2672
www.vulcanoil.com
...continued
________________________________________________________________________________
Section 9 - Regulatory Information
DOT Information
DOT Proper Shipping Name:
None
DOT Hazard Code:
None
UN Number:
None
Material Safety Data Sheet
Section 313 Supplier Notification
This product contains the following chemicals subject to the reporting
requirements of section 313 of the Emergency Planning and Community RightTo-Know Act of 1986 (40 CFR 372):
CAS#
Common Name
None
Weight%
This information should be included in all MSDSs that are copied and
distributed for this material.
________________________________________________________________________________
Prepared according to the OSHA Hazard Communication Standard
(29 CFR 1910.1200) by Vulcan Oil & Chemical Products.
________________________________________________________________________________
The information set forth herein is furnished free of charge and is based
on technical data that Vulcan believes to be reliable. It is intended for
use by persons having technical skill and at their own discretion and risk.
Since conditions of use are outside our control, we make no warranties,
express or implied, and assume no liability in connection with any use of
the information. Nothing herein is to be taken as a license to operate
under or a recommendation to infringe any patents.
End of MSDS
CI-C-02
Material Safety Data Sheet
Revision Date: 06/09/2005
Issue date: 08/16/2005
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Item No. :
30565
Region:
Canada
Contact Information:
Telephone: 905.814.6511
Emergency telephone: 905.814.6511
Internet: www.loctite.com
Product name:
Aqua Power(TM) Cleaner & Degreaser
Product Use:
Cleaner
Company address:
Henkel Canada, Inc.
2225 Meadowpine Boulevard
Mississauga, Ontario L5N 7P2
2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
Water
7732-18-5
%
60-100
ACGIH TLV
None
OSHA PEL
None
OTHER
None
Xylene
1330-20-7
10-30
100 ppm TWA
150 ppm STEL
100 ppm TWA
435 mg/m³ TWA
None
Methyl ethyl ketone
78-93-3
5-10
200 ppm TWA
300 ppm STEL
200 ppm TWA
590 mg/m³ TWA
None
Ethyl benzene
100-41-4
5-10
100 ppm TWA
125 ppm STEL
100 ppm TWA
435 mg/m³ TWA
None
2-Propanol,1-(1,1-dimethylethoxy)57018-52-7
5-10
None
None
None
Propane
74-98-6
5-10
1000 ppm TWA
1800 mg/m³ TWA
None
Isobutane
75-28-5
5-10
None
None
Morpholine
110-91-8
1-5
1000 ppm TWA
1000 ppm TWA listed
under aliphatic
hydrocarbon gases alkane
C1-C4
1000 ppm TWA listed
under aliphatic
hydrocarbon gases alkane
C1-C4
20 ppm TWA
(skin)
20 ppm TWA
70 mg/m³ TWA
(skin)
None
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Physical state:
Color:
Aerosol Liquid
Clear
Odor:
Solvent
DANGER:
WHMIS hazard class:
CONTENTS UNDER PRESSURE.
Vapor Extremely Flammable
HARMFUL IF SWALLOWED OR INHALED.
Vapor Harmful
Relevant routes of exposure:
Skin, Inhalation, Eyes
Potential Health Effects
Item No. :
30565
CI-C-03
A, B.5, D.2.A, D.2.B
Product name: Aqua Power(TM) Cleaner & Degreaser
1 of 6
Inhalation:
Skin contact:
Eye contact:
Ingestion:
Existing conditions aggravated by
exposure:
Harmful by inhalation. Exposure to high doses may cause central nervous system depression. Such
doses may also cause adverse effects in the liver, kidneys, and lungs. Dizziness. Headache. Nausea.
Irritating to skin. Prolonged or repeated contact can cause or aggravate dermatitis or other skin
conditions.
Contact with eyes will cause irritation. Liquid, aerosols or vapor are irritating and can cause tearing,
reddening and swelling.
Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.
Skin disorders.
See Section 11 for additional toxicological information.
4. FIRST AID MEASURES
Inhalation:
Move to fresh air in case of accidental inhalation of vapours. If not breathing, give artificial respiration.
Get medical attention.
Skin contact:
Wash with soap and water. Remove contaminated clothing and shoes. Wash clothing before reuse.
Eye contact:
In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Ingestion:
If swallowed, seek medical advice immediately and show this container or label. Do not induce
vomiting.
5. FIRE-FIGHTING MEASURES
Flash point:
<0°C (<-17°F)
Autoignition temperature:
Not available
Flammable/Explosive limits-lower %:
Not available
Flammable/Explosive limits-upper %:
Not available
Extinguishing media:
Use dry chemical, CO2, water spray or `alcohol` foam.
Special fire fighting procedures:
Keep unnecessary personnel away. Remove all ignition sources. Use water spray to keep fire exposed
containers cool and disperse vapors.
Unusual fire or explosion hazards:
Contents under pressure. Do not puncture or incinerate pressurized containers.
Hazardous combustion products:
Oxides of carbon. Irritating organic fragments.
Sensitivity to mechanical impact:
Not available.
Sensitivity to static discharge:
Not available.
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions:
Prevent product from entering the drains.
Clean-up methods:
Remove all ignition sources. Ventilate area. For large spills absorb onto inert absorbent material and
place in sealed container for disposal.
Item No. :
Product name: Aqua Power(TM) Cleaner & Degreaser
30565
2 of 6
CI-C-03
7. HANDLING AND STORAGE
Handling:
When using, do not eat, drink or smoke. Avoid contact with eyes, skin and clothing. Avoid breathing
vapor and mist. Wash thoroughly after handling. Keep away from heat, spark and flame.
Storage:
Store away from ignition sources. Keep container closed.
Incompatible products:
Oxidizing agents.
For information on product shelf life contact Loctite Canada Customer Service at (905) 814-6511.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls:
Work should be done in an adequately ventilated area (i.e., ventilation sufficient to maintain
concentrations below one half of the PEL and other relevant standards). Local exhaust ventilation is
recommended when general ventilation is not sufficient to control airborne contamination.
Respiratory protection:
When workers are facing concentrations above the exposure limit they must use appropriate certified
respirators.
Skin protection:
Use impermeable gloves and protective clothing as necessary to prevent skin contact.
Eye/face protection:
Chemical splash goggles or safety glasses with side shields.
See Section 2 for exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state:
Color:
Odor:
Odor Threshold:
Vapor pressure:
pH:
Boiling point/range:
Melting point/range:
Specific gravity:
Vapor density:
Evaporation rate:
Solubility in water:
Partition coefficient (n-octanol/water):
VOC content:
Aerosol Liquid
Clear
Solvent
Not available
50 to 70 psig
9 - 11
Not available
Not available
Not available
Heavier than air
Slower than ether.
Dispersible
Not available
40%
10. STABILITY AND REACTIVITY
Stability:
Stable.
Hazardous polymerization:
Will not occur.
Hazardous decomposition products:
Oxides of carbon. Irritating organic fragments.
Incompatability:
Oxidizing agents. Strong acids and oxidizing agents.
Conditions to avoid:
Fire or intense heat may cause violent rupture of packages. Avoid temperatures above 120 °C (48.8
°F).
11. TOXICOLOGICAL INFORMATION
Product toxicity data:
Not available
Toxicologically synergistic products:
Not available.
Item No. :
Product name: Aqua Power(TM) Cleaner & Degreaser
30565
3 of 6
CI-C-03
Refer to the following for Irritancy of Product, Sensitization to Product, Carcinogenicity, Reproductive Toxicity, Teratogenicity, and
Mutagenicity.
Ingredient Toxicity Data & Carcinogen Status
Hazardous components
LD50s & LC50s
(NIOSH ) :
None
Water
7732-18-5
Xylene
1330-20-7
Oral LD50 (Rat)
= 4300 mg/kg
Inhalation LC50
(Rat) = 5000
ppm
Dermal LD50
(Rabbit) > 1700
mg/kg
Methyl ethyl ketone
Oral LD50 (Rat)
78-93-3
= 2737 mg/kg
Inhalation LC50
(Mouse) = 32
g/m3
Dermal LD50
(Rabbit) = 6480
mg/kg
Ethyl benzene
Dermal LD50
100-41-4
(Rabbit) = 17800
µL/kg
Oral LD50 (Rat)
= 3500 mg/kg
2-Propanol,1-(1,1-dimethylethoxy)None
57018-52-7
Propane
None
74-98-6
Isobutane
Inhalation LC50
75-28-5
(Rat) = 57 pph
Morpholine
Oral LD50 (Rat)
110-91-8
= 1450 mg/kg
Dermal LD50
(Rabbit) = 500
µL/kg
Other LD50s
and LC50s:
None
NTP
Carcinogen
No
IARC
Carcinogen
No
OSHA
Carcinogen
No
ACGIH Carcinogens
No
None
No
No
No
A4 - Not Classifiable
as a Human
Carcinogen
None
No
No
No
No
None
No
Group 2B
Yes
A3 - Confirmed
animal carcinogen
with unknown
relevance to humans
None
No
No
No
No
None
No
No
No
No
None
No
No
No
No
None
No
No
No
A4 - Not Classifiable
as a Human
Carcinogen
Literature Referenced Target Organ & Other Health Effects
Hazardous components
Water
7732-18-5
Xylene
1330-20-7
Methyl ethyl ketone
78-93-3
Ethyl benzene
100-41-4
2-Propanol,1-(1,1-dimethylethoxy)57018-52-7
Propane
74-98-6
Isobutane
75-28-5
Morpholine
110-91-8
Health Effects/Target Organs
No Target Organs
Cardiac, Central nervous system, Irritant, Kidney, Liver
Central nervous system, Irritant
Central nervous system, Irritant
No Target Organs
Cardiac, Central nervous system, Irritant
Cardiac, Central nervous system, Lung
Corrosive, Irritant, Kidney, Liver
12. ECOLOGICAL INFORMATION
Item No. :
Product name: Aqua Power(TM) Cleaner & Degreaser
30565
4 of 6
CI-C-03
Ecological information:
No specific studies have been conducted by Henkel on the ecotoxicity or environmental fate of this
material; however, commonly available data on the material indicate that uncontrolled releases to soil,
groundwater, or surface waters could entail acute and/or chronic ecological effects, depending on the
quantity and concentration of such releases. Releases of volatile components to the atmosphere are
not believed to entail significant ecological consequences provided such releases are within the
exposure levels set forth in this document. Accordingly, all appropriate measures should be taken to
avoid uncontrolled releases to the environment, and any spills or other uncontrolled releases which
may occur should be contained and cleaned up immediately in accordance with Section 6.
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal:
Dispose of in accordance with federal and local regulations.
14. TRANSPORT INFORMATION
Canada Transportation of Dangerous Goods - Ground:
Proper shipping name:
Aerosols, flammable
Hazard class or division:
2.1
Identification number:
UN 1950
Packing group:
None
International Air Transportation (ICAO/IATA):
Proper shipping name:
Aerosols, flammable
Hazard class or division:
2.1
Identification number:
UN 1950
Packing group:
None
WaterTransportation (IMO/IMDG):
Proper shipping name:
Hazard class or division:
Identification number:
Packing group:
Aerosols, flammable, n.o.s
2.1
UN 1950
None
15. REGULATORY INFORMATION
Canada Regulatory Information
CEPA DSL/NDSL Status:
All other components are listed on or are exempt from listing on the Domestic Substances List.
United States Regulatory Information
TSCA 8 (b) Inventory Status:
Item No. :
All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
Product name: Aqua Power(TM) Cleaner & Degreaser
30565
5 of 6
CI-C-03
16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet format.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all
the information required by the Controlled Product Regulations.
Prepared by:
Lou Fabrizio, Senior Health & Regulatory Affairs Specialist
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation
does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the
user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular
purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be
involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically
disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale
or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of
any kind, including lost profits.
Item No. :
Product name: Aqua Power(TM) Cleaner & Degreaser
30565
6 of 6
CI-C-03
MATERIAL SAFETY DATA SHEET
REAL COOL SNOOP®
January 2006
1. PRODUCT IDENTIFICATION
REAL COOL SNOOP®: Liquid leak detector to be used on external surfaces only. Optimum operating
temperatures are between -65°F and 200°F (-54°C and 93°C).
Manufactured by:
Swagelok Manufacturing Company
29495 F.A. Lennon Dr.
Solon, Ohio 44139
Tel: (440) 349-5600
Emergency Contact:
Chemtrec (800) 424-9300
2. INGREDIENTS
Ingredients
CAS #
WT%
PEL
Ethylene Glycol
Water
Surfactant
107-21-1
7732-18-5
Not Available
55-60
40-50
<5
None
None
None
3. HEALTH HAZARD INFORMATION
•
•
•
•
European Community Danger Group:.............. Xn - Harmful
Special Hazards for man or environment: ....... R 22 - Harmful if swallowed
LD50 ................................................................. Ethylene Glycol: 6000-13,000 mg/kg oral, rat
LC50 .................................................................. Ethylene Glycol: >5000 mg/l goldfish
Skin Contact
Skin Absorption
Routes of Entry
Eye Contact
Yes
Yes
Yes
Inhalation
Ingestion
Yes
Yes
4. FIRST AID MEASURES
•
If inhaled (Overexposure):
•
After contact with skin (Overexposure):
•
•
•
After contact with eyes:
minutes, seek medical
If swallowed:
Medical information:
•
Note to physician:
CI-C-04
Remove person from effected area to fresh air. Seek
immediate medical attention.
Wash thoroughly with soap and water. If severe irritation
develops, seek medical attention.
May cause eye irritation. Rinse thoroughly with water for 15
attention. Do not rub eyes.
Seek medical attention immediately.
Acute exposure to ethylene glycol may cause loss of appetite,
liver, kidney, and neural dysfunction.
Early administration of ethanol may counter the toxic effects
of ethylene glycol (metabolic acidosis and renal damage).
Hemodialysis or peritoneal dialysis have been of benefit.
Page 1 of 4
MATERIAL SAFETY DATA SHEET
REAL COOL SNOOP®
January 2006
5. FIRE FIGHTING MEASURES
•
Suitable extinguishing agents:
•
•
Not suitable for safety reasons:
Special dangers caused by substance
or preparation itself, by combustion
products or gases formed:
Additional information:
•
Alcohol resistant foams (ATC type) are preferred if available. Do not
use a direct water stream. General purpose synthetic foams (including
AFFF) or protein foams may function, but much less effectively.
None known.
May produce carbon monoxide and carbon dioxide. May produce
trace amounts of aldehydes and organic acids.
None.
Autoignition
UEL
LEL
Sensitivities
Not Applicable
Not Available
Not Available
Not Available
6. ACCIDENTAL RELEASE MEASURES
•
Measures for protection of people:
•
Measures for protection of the
environment:
Cleaning measures:
Additional information:
•
•
Put on necessary protective equipment. Eye and hand protection as
needed.
None required.
Use absorbent material and suitable cleaner.
None.
7. HANDLING AND STORAGE
•
•
•
Safety information:
Information on protection from fire
or explosion:
Additional information:
None.
None.
Recommended storage 45°F to 85°F (7°C to 29°C) for optimal
product performance.
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
•
•
•
•
Precautionary measures to protect
employees:
Respiratory protection:
Hand protection:
Eye protection:
•
Skin protection:
CI-C-04
None required.
None. Normal ventilation is adequate.
Rubber gloves are recommended to reduce exposure.
Safety glasses or goggles are recommended where there is a chance of
splashes.
As needed to minimize exposure. Wash hands after use.
Page 2 of 4
MATERIAL SAFETY DATA SHEET
REAL COOL SNOOP®
January 2006
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Odor
pH
Density
Vapor Pressure
Colorless liquid
Neutral
6.0-7.5
1.1 gm/cm3
0.12 mm Hg
Boiling Point
Melting Point
Flash Point
Flammability
Explosive
387°F/197°C
Not Applicable
>230°F/>110°C
Not Applicable
Not Applicable
10. STABILITY AND REACTIVITY
•
•
•
Conditions to avoid:
Excessive heat, sparks, and open flames.
Materials to avoid:
Oxidizing agents, acids, bases, and alkalis.
Hazardous decomposition products: See Section 5.
11. TOXICOLOGICAL INFORMATION
•
Acute toxic properties:
•
Health effects:
•
Additional health effects:
Sensitization
Not Available
Teratogenicity
Ethylene glycol
has been
reported to
cause birth
defects in lab
animals
Ingestion or prolonged exposure to ethylene glycol may cause loss of
appetite, liver, kidney, and neural dysfunction.
Ethylene glycol has been reported to cause birth defects in laboratory
animals.
None known.
Reproductive
Toxicity
Ingestion of large
amounts of ethylene
glycol has been
shown to interfere
with reproduction in
lab animals
Mutagenicity
Not Available
Synergistic
Products
Not Available
Carcinogenicity
Listed ingredients
are not suspected
carcinogens
according to NTP,
IARC, and OSHA
12. ECOLOGICAL INFORMATION
•
•
•
•
Mobility:
Degradability:
Accumulation:
Short/Long term effects
on ecotoxicity:
Comparable to water.
Biodegradable.
No adverse bioaccumulation or biomagnification effects known.
LC50 for goldfish > 5000 mg/L.
13. DISPOSAL CONSIDERATIONS
•
Appropriate methods of disposal:
•
European Community (EC)
considerations:
CI-C-04
Dispose of in a responsible manner. Do not pour on the ground, in
sewers, or in any body of water.
Use appropriate waste codes based on ingredients.
Page 3 of 4
MATERIAL SAFETY DATA SHEET
REAL COOL SNOOP®
January 2006
14. TRANSPORT INFORMATION
•
•
Transport precautions:
Additional information:
Consult applicable regulations when transporting this product.
None.
15. REGULATORY INFORMATION
•
EC regulations:
•
US/Canadian regulation listings:
•
•
EC Relevant risk:
EC Relevant safety:
•
Additional information:
This product has been classified under CHIP-96 guidelines based on
chemical content.
Ethlyene glycol: SARA 313 - Yes, TSCA - Yes
Canada’s Controlled Products – Yes.
Xn - Harmful danger group, R: 22.
S: 36/37/38 - Wear suitable gloves and eye/face protection.
S:20 - When using do not eat or drink.
S:2 - Keep out of reach of children.
Consult country codes for specific requirements.
16. OTHER INFORMATION
•
•
Further information contact:
Sources of information used
to compile document:
Environmental and Safety Department
CI-C-04
Your Swagelok Distributor or the contacts listed in Section 1 of this sheet.
Properties of individual ingredients were used to compile this document.
This Material Safety Data Sheet was designed to give the distributors
and users of REAL COOL SNOOP® information to handle and use the
product in a responsible manner.
Preparation Data
(440) 349-5955
January 2006
Page 4 of 4
MATERIAL SAFETY DATA SHEET
LPS CFC-Free Electro Contact Cleaner
Section 1 • Product and Company Identification
Manufacturer's Name: LPS Laboratories
Chemical Family: 2-methylpentane / Isopropanol
Telephone Number: 770-243-8800
Trade Name: LPS CFC Free Electro Contact Cleaner
Part Numbers: 03116 (aerosol), 03101, 03105, 03155
Emergency Telephone Number:
1-800-424-9300 Chemtrec;
Outside U.S.: (703) 527-3887
Address:
4647 Hugh Howell Road
Tucker, GA USA 30085-5052
Website: http://www.lpslabs.com
PLAIN LANGUAGE HAZARD SUMMARY
Material Safety Data Sheets can be confusing. Federal and State laws require us to include a great deal of technical
information that probably won’t help the non-professional. LPS includes this “PLAIN LANGUAGE HAZARD SUMMARY” to
address the questions and concerns of the average worker. If you have additional health, safety or product questions,
don’t hesitate to call us at 800/241-8334.
Worker Toxicity
LPS CFC FREE ELECTRO CONTACT CLEANER is designed for the removal of dirt, moisture, dust, flux, and oxides from
the internal components of electronic or precision equipment such as circuit boards, and the internal components of
electronic devices, including but not limited to, radios, compact disc (CD) players, digital video disc (DVD) players, and
computers. It contains isohexane and isopropyl alcohol which can be irritating to skin at a minimum and if handled
improperly can be dangerous. We suggest you wear gloves and avoid extended exposure to unprotected skin. Don’t get it
in your eyes (it stings), or breath large amounts of the vapor, (it will dry out your nasal passages and if you breathe large
amounts in poorly ventilated areas it can make you dizzy and even sick). Don’t spray LPS CFC FREE ELECTRO
CONTACT CLEANER for extended periods without adequate ventilation. If you’re going to perform work involving a lot of
product in a poorly ventilated area, use of a respirator or even a self-contained breathing apparatus may be necessary.
For more exposure and first aid information, refer to MSDS Sections 2, 8 and 11.
Flammability
LPS CFC FREE ELECTRO CONTACT CLEANER is extremely flammable, having a flash point below 32oF (0oC). Do not spray
onto live electrical equipment or in or around ignition sources. Store product away from heat sources.
Disposal
If you spill LPS CFC FREE ELECTRO CONTACT CLEANER, notify the proper environmental or safety department at your
company right away. If LPS CFC FREE ELECTRO CONTACT CLEANER becomes contaminated with another substance and is
rendered unusable for cleaning, the resulting mixture will fall under at least one hazardous classification. See section 13 for more
details.
Current Revision 6/27/05 – Previous Revision: 3/29/05 CI-C-05
page 1 of 7
MATERIAL SAFETY DATA SHEET
LPS CFC-Free Electro Contact Cleaner
Section 2 • Hazards Identification
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Emergency Overview: DANGER: Extremely Flammable. Aerosol contents under pressure. Harmful or Fatal if Swallowed.
Primary route(s) of entry: Skin and Eye contact. Inhalation.
Potential Acute Health Effects:
Eyes
Irritating to eyes
Skin
Repeated exposure may cause skin dryness or cracking.
Inhalation:
Excessive inhalation of vapors can cause irritation of the respiratory tract, nausea, dizziness or headache.
Ingestion:
Product has a low order of acute oral toxicity, but ingestion of large quantities may cause nausea,
vomiting, and gastrointestinal irritation. May cause injury if aspirated into lungs.
Potential Chronic Health Effects:
Carcinogenic Effects: NTP: No IARC: No OSHA: No
Mutagenic Effects: None
Teratogenic Effects: None
Medical conditions aggravated by exposure: Persons with pre-existing central nervous system (CNS) disease,
neurological conditions, skin disorders, chronic respiratory diseases, or impaired liver or kidney function should avoid
exposure.
Signs and Symptoms
Stinging in eyes. Repeated or prolonged skin contact can cause redness, irritation, and scaling of the skin (dermatitis).
Breathing of high vapor concentrations may cause headaches, stupor, irritation of throat and eyes, and kidney effects.
Section 3 • Composition / Information on Ingredients
Component
2-methylpentane
Isopropanol
Carbon dioxide (aerosol only)
CASRN
107-83-5
67-63-0
124-38-9
Percent by Weight
70-90%
5-20%
2-4%
Section 4 • First Aid Measures
Eyes:
Check for and remove contact lenses. If irritation or redness develops, flush eyes with cool, clean, low
pressure water for at least 15 minutes. Hold eyelids apart to ensure complete irrigation of the eye and
eyelid tissue. Do not use eye ointment. Seek medical attention immediately.
Skin:
Remove contaminated shoes and clothing. Clean affected area thoroughly with mild soap and water. Do
not use ointments. Seek medical attention if irritation persists.
Current Revision 6/27/05 – Previous Revision: 3/29/05 CI-C-05
page 2 of 7
MATERIAL SAFETY DATA SHEET
LPS CFC-Free Electro Contact Cleaner
Inhalation:
Immediately move victim to fresh air. If victim is not breathing, immediately begin rescue breathing. If
heart has stopped, immediately begin cardiopulmonary resuscitation (CPR). If breathing is difficult, seek
medical attention immediately.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. If spontaneous vomiting is about to occur, place victim’s head below
knees. If victim is drowsy or unconscious, place on the left side with head down. Do not leave victim
unattended. Seek medical attention immediately.
Section 5 • Fire Fighting Measures
Products of Combustion: Carbon monoxide and carbon dioxide.
Firefighting media: SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. Cool containing vessels with water jet in order to
prevent pressure build-up, autoignition or explosions.
Sensitivity to Impact: None. Sensitivity to Static Discharge: None.
Protection Clothing (Fire): Firefighters must use full bunker gear including NIOSH-approved positive pressure selfcontained breathing apparatus to protect against potential hazardous combustion or decomposition products and oxygen
deficiencies. Evacuate area and fight the fire from a maximum distance or use unmanned hose holders or monitor nozzles.
Special Remarks on Explosion Hazards: Aerosols may explode upon heating, spread fire and overcome sprinkler
systems.
Section 6 • Accidental Release Measures
Small Spill and Leak: Absorb with an inert material and dispose of properly.
Large Spill and Leak: For large spills, secure the area and control access. Dike far ahead of a liquid spill to ensure
complete collection. Pick up free liquid for disposal using absorbent pads, sand, or other inert non-combustible absorbent
materials. Place into appropriate waste containers for later disposal.
Section 7 • Handling and Storage
Handling: DO NOT spray into or around ignition sources. After handling, always wash hands thoroughly with soap and
water. Use only with adequate ventilation. Avoid breathing vapors or spray mists.
Storage: Keep container in a cool, well-ventilated area. Avoid all sources of ignition (spark or flame). Store below 120°F.
Precautions to be taken in handling and storage: Store aerosols as Level 3 Aerosol (NFPA 30B). Store all materials
in dry, well-ventilated area. Avoid breathing vapors.
Section 8 • Exposure Controls / Personal Protection
Ingredients
2-methylpentane
Isopropanol
Carbon Dioxide
(aerosol only)
CASRN
107-83-5
67-63-0
124-38-9
OSHA PEL-TWA
500 ppm
400 ppm
5,000 ppm
ACGIH-TLV
500 ppm
400 ppm
5,000 ppm
Current Revision 6/27/05 – Previous Revision: 3/29/05 CI-C-05
Other Limits
1000 ppm STEL (ACGIH)
500 ppm STEL (ACGIH)
30,000 STEL (ACGIH)
page 3 of 7
MATERIAL SAFETY DATA SHEET
LPS CFC-Free Electro Contact Cleaner
Engineering Controls: Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapors below their respective occupational exposure limits.
Personal Protection:
Eyes: Safety glasses.
Respiratory : Use appropriate respirator if ventilation is inadequate.
Hands: Use solvent resistant gloves.
General Hygiene Considerations: Wash thoroughly after handling. Have eye-wash facilities immediately available.
Section 9 • Physical and Chemical Properties
Appearance:
Liquid.
Color:
Colorless / water-white
Odour/Taste:
Characteristic.
Vapour Pressure:
352 mmHg @ 38 °C
Solubility Description:
<10% by weight.
Evaporation Rate:
<1(Ethyl Ether =1)
Boiling Point (°C):
60.5 @ 760mmHg
Flash Point (°C):
<-17°C (< 0oF)
Specific Gravity (Water=1):
0.65-0.68 @ 20 °C
Flash Point Method:
Tag-Closed Cup.
Vapour Density (air=1):
~3.0
Auto Ignition
Temperature (°C):
306°C (582.8°F)
V.O.C. Content:
100%, 665 g/L,
5.55 #/gal.
Partition Coefficient
(octanol/water):
<1
Flammable limits
(estimated):
LOWER: 0.6%
UPPER: 7%
Viscosity:
<3 cSt @ 25oC
Section 10 • Stability and Reactivity
Stability and Reactivity: The product is stable.
Incompatibility with Various Substances: Extremely reactive or incompatible with oxidizing agents.
Hazardous decomposition products: These products are carbon oxides (CO, CO2)
Hazardous polymerization: Will not occur.
Section 11 • Toxicological Information
Acute and Chronic Toxicity
A: General Product Information
Following exposure to vapors, this material can produce central nervous system depression. High atmospheric
concentrations can result in eye, nasal and respiratory tract irritation. However, if handled in accordance with good
industrial hygiene practice, this product will not present a significant hazard in the workplace.
Current Revision 6/27/05 – Previous Revision: 3/29/05 CI-C-05
page 4 of 7
MATERIAL SAFETY DATA SHEET
LPS CFC-Free Electro Contact Cleaner
Ingredients
2-methylpentane
Isopropanol
Carbon Dioxide (aerosol
only)
CASRN
107-83-5
67-63-0
124-38-9
LC-50
> 3125 ppm / 4 hours/rat
13 g/kg
Not available
LD-50
Not available
6 g/kg acute oral/ rat
Not appropriate
Section 12 • Ecological Information
Component Data: Acute Aquatic Toxicity
Component
2-methylpentane
CASRN
107-83-5
Isopropanol
67-63-0
Test
48-hour EC50
96-hour EC50
24-hour EC50
Toxicity Threshold
Species
Daphnia magna
Microcystis pyrifera
Daphnia magna
Chilomonas
paramecium
Results
2.1 mg/L
10 mg/L
> 10,000 mg/L
104 mg/L
Section 13 • Disposal Considerations
Waste Status:
In its purchased form, this material is a RCRA hazardous waste carrying waste codes D001 and D003
(aerosols only)
Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control
regulations.
Note:
Chemical additions to, processing of, or otherwise altering this material may make this waste
management information inaccurate, incomplete, or otherwise inappropriate. Furthermore, state and
local waste disposal requirements may be more restrictive than federal laws and regulations.
Section 14 • Transport Information
Aerosols Only
Mode
Shipping Name
Hazard
Class
Subclass
UN
Number
Technical
Name
Hazard Label
Packing
Group
D.O.T.
Ground
IATA (US)
Consumer
Commodity
Consumer
Commodity
AEROSOLS,
flammable
AEROSOL
ORM-D
NA
1950
NA
ORM-D
NA
Emergency
Response
Guide
NA
9
NA
8000
NA
Miscellaneous
NA
NA
2.1
NA
1950
NA
NA
NA
2.1
NA
1950
NA
NA
F-D, S-U
NA
NA
1950
NA
Flammable
Gas
Flammable
Gas
NA
NA
F-D, S-U
IATA
(non-US)
IMDG
(Regular)
IMDG
(Special)
Dangerous Goods in
Limited quantities of
Class 2
Current Revision 6/27/05 – Previous Revision: 3/29/05 CI-C-05
page 5 of 7
MATERIAL SAFETY DATA SHEET
LPS CFC-Free Electro Contact Cleaner
1-Gallon Containers
Mode
D.O.T.
Ground
IATA (US)
IATA (nonUS)
IMDG
(Regular)
Shipping
Name
Flammable
liquid, n.o.s.
Flammable
liquid, n.o.s.
Flammable
liquid, n.o.s.
Flammable
liquid, n.o.s.
Hazard
Class
3
Subclass
NA
UN
Number
1993
3
NA
1993
3
NA
1993
3
NA
1993
Technical
Name
Hexanes,
Isopropanol
Hexanes,
Isopropanol
Hexanes,
Isopropanol
Hexanes,
Isopropanol
Hazard
Label
Flammable
Liquid
Flammable
Liquid
Flammable
Liquid
Flammable
Liquid
Packing
Group
II
Emergency
Response Guide
NA
II
NA
II
NA
II
F-E, S-E
5 gallon containers must be shipped via “cargo aircraft only” for air transport.
55 gallon drums CANNOT be shipped by air !
Section 15 • Regulatory information
U.S. Federal
Regulations:
TSCA 8(b) inventory: All of the ingredients are listed on the TSCA inventory or are exempt.
RCRA Hazardous Waste No.: D003 (aerosols only), D001.
CERCLA Sections 102a/103 Hazardous Substances (40 CFR part 370) Reportable Quantity: none
SARA TITLE III Sections 311/312 hazardous Categorization (40 CFR part 370): Sudden Release of
Pressure (aerosol only), Fire Hazard, Immediate (Acute) Health Hazard, Delayed (Chronic) Health
Hazard.
SARA TITLE III Section 313: No individual section 313 component is present at or above 1%.
State
Regulations:
New Jersey RTK: 2-methylpentane (CASRN: 107-83-5), Isopropanol (CASRN: 67-63-0),
Carbon Dioxide aerosol propellant (CASRN: 124-38-9), 3-methylpentane (CASRN: 96-14-0)*
2,3-dimethylbutane (CASRN: 79-29-8)*, 2,2 dimethylbutane (CASRN: 75-83-2)*
*Denotes items at less than 0.5% in final preparation
California Proposition 65: None.
California and OTC States: This product conforms to current consumer regulations.
Current Revision 6/27/05 – Previous Revision: 3/29/05 CI-C-05
page 6 of 7
MATERIAL SAFETY DATA SHEET
LPS CFC-Free Electro Contact Cleaner
MSDS#13116
Responsible Name: Ed Williams
Technical Manager
Section 16 • Other Information
HMIS-III
Health:
[/] 1
Flammability:
3
Physical Hazard: 2 (aerosol)
0 (other)
NFPA
flammability
3
health
1
0
reactivity
Notice to Reader:
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its
subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination
of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with
caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Ed Williams, Technical Manager
LPS Laboratories
A division of Illinois Tool Works
Current Revision 6/27/05 – Previous Revision: 3/29/05 CI-C-05
Form #2551
page 7 of 7
US Safety Data Sheet
MOTOREX PROWELD 264
Date of issue / Reference
Replaces version of
Date of printing
12.06.01 pd
07.06.01 pd
13.06.2001 Sheet no.
Company
EUROLine Inc.; 16 Manchester Road; Carmel NY 10512, USA
Phone: (845) 228 0145; Fax: (845) 228 0127
1
Commercial product name and supplier
1.1
Commercial product name /
designation
1104
Page 1 of
MOTOREX PROWELD 264
NFPA
HMIS
0
1
0
-
H
1
F
0
R
0
C
0
1.2
Application / use
Welding protectant
1.3
Producer
BUCHER AG, Schmiertechnik, CH-4900 Langenthal
Telephone +41 62 919 75 75 - Telefax +41 62 919 75 95
1.4
Supplier
EUROLine Inc.; 16 Manchester Road; Carmel NY 10512, USA
Phone: (845) 228 0145; Fax: (845) 228 0127
1.5
TOX emergency number
EUROLine Inc.; 16 Manchester Road; Carmel NY 10512, USA
Fax: (845) 228 0127
1.6
Product No.
2
Composition
2.1
Ingredients
2.2
CAS No.
102-71-6
5-10%
Triethanolamine
CAS No.
78521-39-8
3-6 %
6-[[(4-Methyl-phenyl)sulfonyl]amino]-hexanoic acid
CAS No.
26316-40-5
1-3%
Ethylenediamine, ethoxylated
Further information
Further ingredients: water: >80%
3
Hazards identification
4
First aid measures
4.1
Eye contact
CI-C-06
No known hazard.
Flush eyes with plenty of water.
4
US Safety Data Sheet
MOTOREX PROWELD 264
Date of issue / Reference
Replaces version of
Date of printing
12.06.01 pd
07.06.01 pd
13.06.2001 Sheet no.
4.2
Skin contact
Remove residues with soap and water.
4.3
Ingestion
Do not induce vomitting.
Do not take in resorption stimulating agents.
Consult physician.
4.4
Inhalation
4.5
Further information
5
Fire-fighting measures
5.1
Suitable extinguishing media
Non-combustible product.
5.2
Extinguishing media to avoid
None known.
5.3
Flash point
1104
Page 2 of
4
°F
Not applicable.
°F
5.4
Ignition temperature
5.5
Explosion limits
Lower:
Upper:
not explosive
5.6
Further information
In case of fire carbon, sulphur and nitrogen oxides can be formed.
6
Accidental release measures
Do not allow to flow off into the drains or waters.
Spills should be contained by, and covered with suitable absorbent
material and removed for disposal.
7
Handling and storage
7.1
Handling
No specific requirements.
7.2
Industrial hygiene
Avoid eye contact.
7.3
Storage
Follow regulations for storage of water hazarding products.
vol.%
vol.%
Avoid freezing.
7.4
Place of storage
7.5
Fire- and explosion protection
8
Exposure controls / personal protection
8.1
Technical equipment
No specific requirements.
8.2
Control of treshold limits
None established for the mixture.
8.3
Personal protective equipment
8.3.1
Respiratory protection
8.3.2
Hand protection
CI-C-06
Water insoluble skin protectant cream.
US Safety Data Sheet
MOTOREX PROWELD 264
Date of issue / Reference
Replaces version of
Date of printing
12.06.01 pd
07.06.01 pd
13.06.2001 Sheet no.
1104
Page 3 of
8.3.3
Eye protection
8.3.4
Other
9
Physical and chemical properties
9.1
Appearance
liquid
9.2
Color
yellow fluorescent
9.3
Odor
low
9.4
Change in physical state
Boiling point
100 °C (1013 mbar)
9.5
Density
1.070 g/cm³ (20°C)
ISO 3675
9.6
Vapour pressure
9.7
Viscosity
<3 mm²/s (40°C)
ISO 3104
9.8
Solubility in water
miscible in all proportions
9.9
pH-value
8.4 - 8.6
9.10
Further information
10
Stability and reactivity
10.1
Thermal decomposition
Will decompose at temperatures above 200°C (392°F).
10.2
Hazardous decomposition
products
nitrogen oxides (NOx)
10.3
Hazardous reactions
No hazards known.
10.4
Further information
11
Health Hazard Data
11.1
Toxicity/Exposure limits
4
Test method:
Sulfur oxides.
The estimated oral LD50 for rats is >2000 mg/kg.
No adverse effects anticipated by this route of exposure incidental to
proper handling.
Not OSHA regulated
Not WHMIS regulated
11.2
Further information
12
Regulatory and supplemental
information
12.1
UN-No.
12.2
NFPA Storage
12.3
Further information
CI-C-06
This product does not require classification according to the criteria
of the Commission of the European Communities.
III b
US Safety Data Sheet
MOTOREX PROWELD 264
Date of issue / Reference
Replaces version of
Date of printing
12.06.01 pd
07.06.01 pd
13.06.2001 Sheet no.
1104
Page 4 of
4
None.
The above mentioned data correspond to our present state of knowledge and experience. The safety data
sheet serves as description of the products in regard to necessary safety measures. The indications have not
the meaning of guarantees on properties.
Alle vorstehenden Angaben entsprechen dem heutigen Stand unserer Kenntnisse und Erfahrungen. Das
Sicherheitsdatenblatt dient der Beschreibung der Produkte im Hinblick auf Sicherheitserfordernisse. Die
Angaben haben nicht die Bedeutung von Eigenschaftszusicherungen.
This safety data sheet has been generated with the safety database 'ChemManager', © ASSiST, Baslerstrasse 21, CH-4102 Binningen
CI-C-06
91/155/EEC
LPS LABORATORIES
MSDS
MATERIAL SAFETY DATA SHEET
Section 1 - Product Identification and Use
Manufacturer's Name:
LPS Laboratories
Trade Name:
LPS PreSolve®
Address (Number Street):
4647 Hugh Howell Road
Chemical Family:
Blended Compound
Address (City, State, Zip):
Tucker, GA 30085-5052
Part Numbers:
01420, 01422, 01428, 01405, 01455
Telephone Number: 770-934-7800
Emergency Telephone Number: 1-800-424-9300 Chemtrec
Outside U.S.: (703) 527-3887
Hazardous Materials Description and proper shipping name (49 CFR 172.101):
Compound, Boiler, Preserving Liquid
NMFC 50093 SUB 2 BRL/BXS CL55
CONSUMER COMMODITY ORM-D
TSCA Inventory:
All of the ingredients are listed on the TSCA inventory.
HMIS Labeling:
Health:
1
Flammability: 2
Reactivity:
0
Section 2 - Hazardous Ingredients / Identity Information
Ingredients
CAS Numbers
Solvent Naphtha (Petroleum)
Medium Aliphatic
8052-41-3
d-Limonene
5989-27-5
Carbon dioxide propellant (aerosol only)
124-38-9
%WW
OSHA PEL
30-50
50-70
2-3
100 ppm
N.E.
10,000 ppm
ACGIH
TLV
OTHER
LIMITS
100 ppm
200 ppm STEL
N.E.
None
5,000 ppm 30,000 ppm STEL
Section 3 - Physical / Chemical Characteristics
Boiling point (Fº ):
Approx. 315º F
Specific gravity (H20 = 1):
Vapor pressure ( mmHg) @ 100º F :
<5
Percent volatile by volume (%):
Vapor density (Air = 1):
4.8-5.3
Evaporation rate (n-Butyl Acetate= 1):
Solubility in water:
Slight
Appearance and odor: Clear, colorless liquid with mild citrus odor.
.808
100
0.15
Section 4 - Fire and Explosion Hazard
Flash point (method used): 105º F TCC
Flammable limits (by volume 25º C): LEL 0.7% UEL 6.0%
Extinguishing media: Foam, dry chemical, or carbon dioxide. Do not use a direct stream of water.
Special fire fighting procedures: Self-contained breathing apparatus should be provided to fire fighters. Water fog may be
used to cool closed containers.
Unusual fire and explosive hazards: Intensive heat created by fire will cause aerosols to burst.
CI-C-07
N.E. = Not established
N.A. = Not applicable
Section 5 - Health Hazard Data
Primary route(s) of entry: Inhalation, eyes.
Health hazard/effects of over exposure:
Inhalation: Headache, dizziness, nausea and anesthetic effects.
Eyes:
Irritation.
Skin:
Repeated or prolonged contact may cause drying and defatting of skin.
Ingestion: Low order of oral toxicity; however, minute amount aspirated into lungs during ingestion may cause severe
pulmonary injury.
Medical conditions aggravated by exposure: Pre-existing eye, skin and respiratory disorders may be aggravated.
Chemicals listed as potential carcinogen: NTP: No
IARC: No
OSHA: No
Emergency and first aid procedures:
Inhalation: Move to fresh air and contact physician. Administer oxygen if breathing is difficult.
Eyes:
Flush eyes with plenty of water, contact a physician.
Skin:
Wash with soap and water; apply medicated skin cream.
Ingestion: Do not induce vomiting. If vomiting occurs spontaneously, keep head below hips to prevent aspiration of liquid into
lungs. Get medical attention.
Section 6 - Reactivity Data
Stability: Stable Conditions to avoid: Avoid sparks or open flames. See handling and storage precautions.
Incompatibility (Materials to avoid): Strong oxidizing agents.
Hazardous decomposition products: Thermal decomposition may yield carbon monoxide.
Hazardous polymerization: Will not occur.
Section 7 - Precautions for Safe Handling and Use
Steps to be taken in case material is released or spilled: Ventilate area by opening doors and windows. Remove ignition sources.
Remove leaking container and transfer remaining product to another vessel. Prevent product from going into sewers and water
sources by diking or impounding. Using appropriate safety equipment, mop up or soak up with absorbent material, such as sand or
clay.
Waste disposal methods: Dispose of in accordance with local, state and federal regulations for petroleum distillates.
RCRA Hazardous Waste No.: This material has the RCRA characteristic of ignitability and would have the hazardous
waste number D001.
CERCLA Reportable Quantity: N.A.
SARA TITLE III Chemicals: None
Precautions to be taken in handling and storage: Store as Level 3 Aerosol (NFPA 30B). Store away from ignition sources and
avoid breathing vapors.
Section 8 - Control Measures
Respiratory Protection: None required if good ventilation is maintained. For enclosed areas, use NIOSH approved organic vapor
cartridge respirator or self-contained breathing apparatus.
Ventilation: Local exhaust is usually adequate. However, mechanical ventilation should be used when spraying in enclosed areas.
Vapor concentration should be minimized as much as possible.
Protective gloves: Use solvent resistant gloves for liquid handling.
Eye protection: For spraying or splashing of solvent, use face shield or goggles.
Other protective equipment: As necessary to prevent prolonged or repeated skin contact.
Work/hygienic practices: Wash hands with soap and water after use and/or before breaks, lunch and at the end of work periods.
Remove contaminated clothing and launder before reuse.
Section 9 - Preparation Date of MSDS
The foregoing technical information and recommendations are compiled from sources that are believed to be accurate and reliable.
However, they are supplied without warranty or guarantee of any kind either expressed or implied. The purchaser is responsible for
selecting and determining the suitability of products for purchaser’s particular needs and we disclaim any responsibility for improper
applications or misuse of our products in any manner whatsoever.
February 18, 2004
Fred Fugitt, Technical Services Chemist
Ed Williams, Manager of Research and Development
LPS Laboratories
CI-C-07
Form # 2686
MSDS LPS PreSolve
CI-C-07
Close Window
MATERIAL SAFETY DATA SHEET 1*
May be used to comply with OSHA's Hazard Communication Standard 29 CFR 1910.1200.
Standard must be consulted for specific requirements.
IDENTITY (As Used on Label and List)
RF-12, RF-28-3E, RF-34, RF-36, RF-38, RF-41, RF-42, RF-52, RF-52-T, RF-53, RF-54, RF-59, RF60, RF-87-1, RF-425, RF1005
SECTION 1
Manufacturer's Name: Scan-Pac Mfg. Inc.
Emergency Telephone Number: (262) 255-2320
Information Telephone Number: (262) 255-2320
Address: N84 W13510 Leon Rd., Menomonee Falls, WI. 53051
Date Prepared: March, 2002
SECTION 2 Hazardous Ingredients/Identity Information 2*
Hazardous Components
Common
Name
C.A.S. No.
OSHA PEL
ACGIH TLV
Barium
Sulfate
7727-43-7
5*-15* mg/m3
10.0 mg/m3
Graphite
7782-42-5
15mppcf
2.0 mg/m3
Calcium
Hydroxide
1305-62-0
5*-15**
mg/m3
5.0 mg/M3
Chromic
Oxide
1308-38-9
.5 mg/m3
.5 mg/m3
Iron Oxide
1309-32-1
10.0 mg/m3
5 mg/m3
Aluminum
Oxide
1344-28-1
5*-15**
mg/m3
10.0 mg/m3
* Respirable
**Total Dust
Synthetic
Vitreous
Fibres
SECTION 3 Physical/Chemical Characteristics
Boiling Point: NAP
Specific Gravity (H2O-1): 1.8 to 2.6
Vapor Pressure (mm Hg.): NAP
Melting Point: NK/NA
Vapor Density (Air - 1): NAP
Evaporation Rate (Butly Acetate-1) 0
Solubility in Water: NO
Appearance and Odor: Various colors, including green, browns & blacks, ridged, hard and no odor.
SECTION 4 Fire and Explosion Hazardous Data
Flash Point (Method Used): NK/NA
Flammable Limits: NK/NA
Extinguishing Media:Water
LEL: NK/NA
Special Fire Fighting Procedures: NK/NA
UEL: NK/NA
Unusual Fire and Explosion Hazards: NK/NA
SECTION 5 - Reactivity Data
Stability: Stable
Condition to Avoid: NA/NK
Incompatibility (Materials to Avoid): NK
Hazardous Decomposition or By-Products: Incomplete combustion will create carbon monoxide and dioxide.
CI-F-07
Hazardous Polymerization: Will not Occur
Conditions to Avoid: NA/NK
SECTION 6 - Health Hazard Data
Route(s) of Entry:
Inhalation:Yes
Skin: NK/NA
Ingestion:NK/NA
Health Hazards (Acute and Chronic):
Synthetic Vitreous fibre may cause mechanical irritation of mouth, nose, throat, eye, and skin. Graphite may cause
pneumoconiosis, other lung damage and/or irritation of the eye. Dust of autoclaved lime may cause irritations or injury to eyes,
skin or respiratory tract.
Carcinogencity: NTP: No
IRAC Regulated: No
OSHA Regulated: No
Signs and symptoms of Exposure:
Synthetic Vitreous Fibres:Itching and possible irritation of upper respiratory tract.
Graphite Dust: Eye irritation and coughing, wheezing, shortness of breath, impaired pulmonary functions.
Calcium Hydroxide: Irritation or burning sensations and burns to wet skin.
Mineral Wool Fiber: Skin, eyes or respiratory tract.
Emergency and First Aid Procedures: Should not be required in normal handling of product but if necessary flush eye with
water for 15 minutes at least, wash skin and remove from exposure to inhalation or contact.
SECTION 7 - Precautions for Safe Handling and Use
Steps to be Taken in Case Material is Released or Spilled: Grinding, drilling, milling, ect. Can result in the release of
airborne dust. Measures as outlined in Section 8 should be followed if this occurs.
Waste Disposal Method: Hazardous Ingredients - Comply with applicable Federal, State and Local regulations.
Precautions to be Taken in Handling and Storing: NA/NK
Other Precautions: NA/NK
SECTION 8 - Control Measures
Respiratory Protection (Specify Type): NIOSH approved for pneumoconiosis-fibrosis producing dusts and dusts with TLV
not less than 0.05 mg/M3.
Ventilation: Locan Exhaust: For Dust exposure exceeding TLV, Mechicanal (General): NAP, Special: NA/NK, Other: NA/NK
Protective Gloves: Suggested for sensitive persons.
Eye Protection: Should not be needed for normal handling of product. Eye protection is good practice where dust is
propelled.
Other Protective Clothing or Equipment: Long sleeved shirts or other protective clothing may beneficial to prevent skin
contact of sensitive persons.
Work/Hygienic Practices: Employees should be properly instructed in the use of control measures as indicated above when
there is a need.
NA - Not Available
NAP - Not Applicable
NK - Not Known
Close Window
Terms and Conditions
N84 W13510 Leon Rd. | Menomonee Falls, WI. 53051
262-255-2525 | fax 262-255-2528
Toll Free: 888-880-6388 | sales@scanpac.com
Designed by Top Floor Technologies
CI-F-07
Champion Technologies, Inc.
845 McKinley St
Eugene, OR 97402
Phone: (541) 687-8301
Toll-free: (800) 547-6180
Fax: (541) 344-0104
AFT-200
Material Safety Data Sheet
Revised:: 24 January 2005
I
Product Information
Product Name: AFT-200
Trade Name: None Assigned
II
NFPA ( 0 = No Hazard; 4 = Severe Hazard )
Health = 1
III
Reactivity = 0
Fire = 1
Ingredient Information
Hazardous Components
CAS Number
OSHA PEL (mg/m_)
ACGIH TLV (mg/m_)
65997-17-3
5
5
Brass (as wire)
7440-50-8 (Cu)
1314-13-2 (Zn)
1
5
1
5
Particulate, not regulated
Not Applicable
15
10
Fiberglass
IV
Physical Data
Boiling Point: (°F): NA
Evaporation Rate (Butyl Acetate = 1): NA
Vapor Pressure (mm Hg): NA
Specific Gravity (Water = 1): 1.69 (Typical)
Water Solubility (%): NA
Melting Point (°F): NA
Vapor Density (Air = 1): NA
% Volatile by Volume: NA
Appearance and Odor: Light tan, with evidence of woven structure and brass wire inclusion
V
Fire and Explosion Data
Flash Point (°F): NA
Flammable Limits: LEL = NA
UEL = NA
Extinguishing Media: Water, foam, dry chemical
Unusual Fire & Explosion Hazards: None
Special Fire Fighting Procedures: Self-contained breathing apparatus (SCBA) should be used in a sustained fire.
VI
Health Data: A - Summary Risks
Continuous Filament Fiberglass: Inadequate evidence of carcinogenicity in both human and animal scientific studies to link fiber to
human cancer. Therefore listed as Group 3.
Clinical Conditions Which May be Aggravated: Any condition generally aggravated by mechanical irritants in the air or on
the skin.
Target Organs: Skin, lungs
Acute Health Effects: Temporary irritation of the mouth, nose, and throat
Chronic Health Effects: None known
Primary Routes of Entry: Inhalation
CI-F-08
Page 2 of 2
VI
Health Data: B - Signs/Symptoms of Overexposure
Inhalation: May cause temporary upper respiratory irritation
Skin Contact: Acute: - Transient mechanical irritation
Chronic - None known.
Ingestion: Acute - unlikely occurrence. Observe individual & if symptoms develop, consult physician
Chronic - None known.
Eyes: Acute - Direct contact may cause mechanical irritation.
Chronic - None known.
VI
Health Data:
C - Emergency First Aid Procedures
Inhalation: Remove individual from exposure. Seek help if irritation persists.
Skin Contact: Wash with mild soap and water.
Ingestion: Unlikely occurrence. Consult physician if any unusual reaction is observed.
Eyes: Flush with running water for at least 10 minutes. If symptoms persist, seek immediate medical attention.
VII
Reactivity Data
Conditions to Avoid: Avoid creating dust. Use vacuum when possible.
Hazardous Decomposition Products: Incomplete combustion may release toxic products.
VIII
Spill or Leak Procedures
Procedure(s) for Spill/Leak: Use vacuum if dust is involved.
Waste Management: In accordance with national, state, and local regulations.
IX
Special Protection Information
Ventilation: Use exhaust ventilation when available.
Respirator: Use NIOSH approved nuisance dust respirator if TLV limits are exceeded.
Goggles:.Use may be appropriate in some operations.
Gloves: Use may reduce skin irritation in some handling situations
Miscellaneous: Wear long sleeved shirts and loose fitting clothing. Use good personal hygiene.
X
Special Considerations
Special Storage & Handling: Store in cool, dry area.
Label Information: “Any fiber or dust may be hazardous to your health. Use respirators and/or other dust control measures
as well as eye protection, when handling or processing this product. Do not ingest.”
Miscellaneous: After handling, wash with mild soap and water. Wash work clothes separately.
Note: The information and recommendations contained in this Material Safety Data Sheet are taken from sources which are believed to
be accurate. Champion Friction Company and Advanced Friction Technology make no warranty with respect to the accuracy of
the information or the suitability of the recommendations, and assumes no liability to any user of the information or recommendations.
MSDS-200.doc
Prepared / Revised by: William DeChent
CI-F-08
MATERIAL SAFETY DATA SHEET
FOR ZENIPLEX 2
Page 1
Keystone Lubricants Division
Total Fina Elf Lubricants USA, Inc.
5 N. Stiles Street, Linden NJ 07036
REVISION DATE
02-NOV-01
DATE ISSUED
06-JAN-03
————————————————————————————————————————————————————————————————————————————————
IDENTIFICATION AND EMERGENCY INFORMATION
————————————————————————————————————————————————————————————————————————————————
PRODUCT NAME:
PRODUCT #:
ZENIPLEX 2
800159
CHEMICAL NAME:
Petroleum-based Grease
CAS #'S:
Mixture
PRODUCT APPEARANCE AND ODOR:
Amber paste, petroleum odor
CHEMICAL FAMILY:
Grease
SYNONYMS:
NLGI Grade 2 Lubricating Grease
EMERGENCY TELEPHONE:
1-908-862-9300
————————————————————————————————————————————————————————————————————————————————
COMPONENTS AND HAZARD INFORMATION
————————————————————————————————————————————————————————————————————————————————
COMPONENTS:
W/W
HAZARD DATA (TLV, LD50, LC50, ETC.):
Lubricant basestock
CAS Nos. 64742-53-6
64742-52-5
5 mg/m3 ACGIH/OSHA TWA
(as an oil mist)
Aluminum-soap grease complexes
CAS Nos. 637-12-7
555-32-8
n/e
Sulfur-Phosphorous EP additive
CAS No. n/a (mixture)
n/e
Styrene-Ester Copolymer additive
CAS No. n/a (mixture)
n/e
Polybutene
CAS No. 9003-29-6
n/e
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS):
Health
Flammability
Reactivity
l
l
0
————————————————————————————————————————————————————————————————————————————————
TRANSPORTATION INFORMATION
————————————————————————————————————————————————————————————————————————————————
TRANSPORTATION INCIDENT INFORMATION:
DOT: Not regulated.
————————————————————————————————————————————————————————————————————————————————
EMERGENCY FIRST AID
————————————————————————————————————————————————————————————————————————————————
EYE CONTACT:
If splashed into the eyes, flush with clear water for l5 minutes or until
irritation subsides. If irritation persists, call a physician.
CI-G-01
MATERIAL SAFETY DATA SHEET
FOR ZENIPLEX 2
Page 2
Keystone Lubricants Division
Total Fina Elf Lubricants USA, Inc.
5 N. Stiles Street, Linden NJ 07036
REVISION DATE
DATE ISSUED
02-NOV-01
06-JAN-03
————————————————————————————————————————————————————————————————————————————————
EMERGENCY FIRST AID
————————————————————————————————————————————————————————————————————————————————
SKIN CONTACT:
In case of skin contact, remove contaminated clothing and wash skin
thoroughly with soap and water.
INHALATION:
Vapor pressure is very low. Vapor inhalation under ambient conditions is
normally not a problem. If overcome by vapor from hot product, immediately
remove from exposure and call a physician. If breathing is irregular or has
stopped, start resuscitation; administer oxygen if available. If overexposure
to oil mist, remove from further exposure until excessive oil mist condition
subsides.
INGESTION:
If ingested, do not induce vomiting. Call a physician immediately.
————————————————————————————————————————————————————————————————————————————————
FIRE AND EXPLOSION HAZARD INFORMATION
————————————————————————————————————————————————————————————————————————————————
FLASH POINT (MINIMUM):
AUTOIGNITION TEMPERATURE:
BASE OIL
N/E
l60°C (320°F) Test method: COC
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) - HAZARD IDENTIFICATION:
Health
Flammability
Reactivity
l
l
0
FLAMMABLE OR EXPLOSIVE LIMITS (approximate percent by volume in air):
BASE OIL
Estimated values: lower 1%
upper 6%
EXTINGUISHING MEDIA AND FIRE FIGHTING PROCEDURES:
Foam, water spray (fog), dry chemical, carbon dioxide and vaporizing liquid
type extinguishing agents may all be suitable for extinguishing fires involving
this type product, depending on size or potential size of fire and circumstances
related to the situation. Plan fire protection and response strategy through
consultation with local fire protection authorities or appropriate specialists.
The following procedures for this type of product are based on the
recommendations in the National Fire Protection Association's "Fire Protection
Guide on Hazardous Materials", Eighth Edition (l984):
Use water spray, dry chemical, foam, or carbon dioxide. Water or foam may cause
frothing. Use water to keep fire-exposed containers cool. Water froth may be
used to flush spills away from exposure. Minimize breathing gases, vapor,
fumes, or decomposition products. Use supplied-air breathing equipment for
enclosed or confined spaces or as otherwise needed.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
n/a
"EMPTY" CONTAINER WARNING:
Empty containers retain residue (liquid or vapor) and can be dangerous. DO
NOT PRESSURIZE, WELD, CUT BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH
CONTAINERS TO HEAT, FLAME, SPARKS, OR OTHER SOURCES OF IGNITION; THEY MAY
EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to clean since residue is
CI-G-01
MATERIAL SAFETY DATA SHEET
FOR ZENIPLEX 2
Page 3
Keystone Lubricants Division
Total Fina Elf Lubricants USA, Inc.
5 N. Stiles Street, Linden NJ 07036
REVISION DATE
DATE ISSUED
02-NOV-01
06-JAN-03
————————————————————————————————————————————————————————————————————————————————
FIRE AND EXPLOSION HAZARD INFORMATION
————————————————————————————————————————————————————————————————————————————————
difficult to remove. "Empty" drums should be completely drained, properly
bunged, and returned to a drum reconditioner. All other containers should be
disposed of in an environmentally safe manner and in accordance with
government regulations. For work on tanks refer to Occupational Safety and
Health Administration regulations, ANSI Z49.l, and other governmental and
industrial references pertaining to cleaning, repairing, welding, or other
contemplated operations.
————————————————————————————————————————————————————————————————————————————————
HEALTH AND HAZARD INFORMATION
————————————————————————————————————————————————————————————————————————————————
EXPOSURE LIMIT FOR TOTAL PRODUCT: Monitor data listed in the
Components and Hazard Information section.
VARIABILITY AMONG INDIVIDUALS:
Health studies have shown that many petroleum hydrocarbons and synthetic
lubricants pose potential human health risks which vary from person to
person. As a precaution, exposure to liquids, vapors, mists, or fumes should
be minimized.
EFFECTS OF OVEREXPOSURE (Signs and symptoms of exposure):
Prolonged or repeated skin contact with this product tends to remove skin oils
possibly leading to irritation and dermatitis.
Product contacting the eye may cause irritation.
Product has a low order of oral and dermal toxicity.
Possible aspiration hazard.
Induced vomiting may cause aspiration of product into the lungs.
(See Emergency First Aid Section).
————————————————————————————————————————————————————————————————————————————————
PHYSICAL DATA
————————————————————————————————————————————————————————————————————————————————
The following data are approximate or typical values and should not be used
for precise design purposes.
BOILING RANGE:
Wide range
VAPOR PRESSURE:
< 0.l @ 38°C/l00°F
SPECIFIC GRAVITY (25°C/25°C):
(WATER = l)
< l.0
VAPOR DENSITY (AIR = l):
> 8
MOLECULAR WEIGHT:
Wide range
PERCENT VOLATILE BY VOLUME:
Negligible
EVAPORATION RATE @ l ATM. AND 25°C
(77°F) (n-BUTYL ACETATE = l):
< l.0
SOLUBILITY IN WATER @ l ATM. and 25°C
(77°F):
Negligible
POUR, CONGEALING OR MELTING POINT:
n/e
FREEZING POINT:
n/e
CI-G-01
MATERIAL SAFETY DATA SHEET
FOR ZENIPLEX 2
Page 4
Keystone Lubricants Division
Total Fina Elf Lubricants USA, Inc.
5 N. Stiles Street, Linden NJ 07036
REVISION DATE
DATE ISSUED
02-NOV-01
06-JAN-03
————————————————————————————————————————————————————————————————————————————————
REACTIVITY
————————————————————————————————————————————————————————————————————————————————
This product is stable and will NOT react violently with water. Hazardous
polymerization will not occur. Avoid contact with strong oxidants such as
liquid chlorine, concentrated oxygen, sodium hypochlorite or calcium
hypochlorite.
DECOMPOSITION PRODUCTS UNDER FIRE CONDITIONS:
Fumes, smoke, carbon monoxide, oxides of sulfur, aluminum and other
decomposition products, in case of incomplete combustion.
CONDITIONS TO AVOID:
Open flames.
————————————————————————————————————————————————————————————————————————————————
TOXICITY
————————————————————————————————————————————————————————————————————————————————
ORAL (Acute)
LD 50 > 500 mg/kg (total body weight)
DERMAL (Acute)
n/e
INHALATION (Acute)
n/a
EYE
Non irritating based on FHSA/OSHA regs.
CHRONIC, SUBCHRONIC, ETC.
n/e
Other:
OSHA Primary Skin Irritation Test: Caused moderate reddening of rabbit
skin (24 hour exposure), which lasted 72 hours.
OSHA Primary Eye Irritation Test: Caused very mild eye irritation
(conjunctiva) in rabbits.
Even though these studies showed some evidence of irritation, the
toxicology tests for these products confirm that they are neither
eye or skin irritants as defined by OSHA.
Medical Conditions Aggravated by Exposure:
Unknown
This product does NOT contain any ingredients identified as carcinogenic by
IRAC, NTP, or OSHA.
SARA Section 313 Status:
This material is not known to contain any
chemicals on the SARA Section 313 list at a
concentration greater than 1.0 percent or
carcinogenic chemical on that list at a
concentration greater than 0.1 percent.
————————————————————————————————————————————————————————————————————————————————
SPILL OR LEAK PROCEDURES
————————————————————————————————————————————————————————————————————————————————
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Keep product out of sewers and watercourses by diking or impounding. Absorb
with sand or inert material. Sweep or scoop up and remove. Prevent spread
of spill. Advise authorities if product has entered or may enter sewers,
watercourses or extensive land areas. Assure conformity with local regulations.
WASTE DISPOSAL METHOD:
CI-G-01
(Consult federal, state, or local authorities for
MATERIAL SAFETY DATA SHEET
FOR ZENIPLEX 2
Page 5
Keystone Lubricants Division
Total Fina Elf Lubricants USA, Inc.
5 N. Stiles Street, Linden NJ 07036
REVISION DATE
DATE ISSUED
02-NOV-01
06-JAN-03
————————————————————————————————————————————————————————————————————————————————
SPILL OR LEAK PROCEDURES
————————————————————————————————————————————————————————————————————————————————
proper disposal procedures.)
Assure conformity with applicable disposal regulations. Dispose of absorbed
material at an approved waste site or facility.
————————————————————————————————————————————————————————————————————————————————
PROTECTION AND PRECAUTIONS
————————————————————————————————————————————————————————————————————————————————
VENTILATION: (Always maintain below permissible exposure limits.)
Use local exhaust to capture vapor, mist or fumes, if necessary.
Provide ventilation sufficient to prevent exceeding recommended exposure
limit or buildup of explosive concentrations of vapor in air.
RESPIRATORY PROTECTION: (Use only NIOSH approved equipment.)
Normally not needed at ambient temperatures. Use supplied air respiratory
protection in confined or enclosed spaces, if needed. Use filter, dust, fume,
or mist respirator type under misting conditions. Use can or cartridge; gas
or vapor respirator type under conditions exceeding TWA standard.
PROTECTIVE GLOVES:
Use chemical-resistant gloves, if needed, to avoid prolonged or repeated skin
contact.
EYE PROTECTION:
Use splash goggles or face shield when eye contact may occur.
OTHER PROTECTIVE EQUIPMENT:
Use chemical-resistant apron or other impervious clothing, if needed, to
avoid contaminating regular clothing which could result in prolonged or
repeated skin contact.
WORK PRACTICES/ENGINEERING CONTROLS:
Keep containers closed when not in use.
or strong oxidants.
Do not handle near heat, sparks, flame,
PERSONAL HYGIENE:
Minimize breathing vapor, mist, or fumes. Avoid prolonged or repeated contact
with skin. Remove contaminated clothing; launder or dry-clean before reuse.
Remove contaminated shoes and thoroughly clean before reuse; discard if oilsoaked. Cleanse skin thoroughly after contact, before breaks and meals, and
at end of work period. Product is readily removed from skin by waterless hand
cleaners followed by washing thoroughly with soap and water.
————————————————————————————————————————————————————————————————————————————————
PREPARED BY: Luke McHale
REGULATORY MANAGER
————————————————————————————————————————————————————————————————————————————————
THE ABOVE INFORMATION IS ACCURATE TO THE BEST OF OUR KNOWLEDGE.
HOWEVER, SINCE DATA, SAFETY STANDARDS, AND GOVERNMENT REGULATIONS ARE
SUBJECT TO CHANGE AND THE CONDITIONS OF HANDLING AND USE, OR MISUSE
BEYOND OUR CONTROL, SELLER MAKES NO WARRANTY, EITHER EXPRESS OR
IMPLIED, WITH RESPECT TO THE COMPLETENESS OR CONTINUING ACCURACY OF THE
INFORMATION CONTAINED HEREIN AND DISCLAIMS ALL LIABILITY FOR RELIANCE
CI-G-01
MATERIAL SAFETY DATA SHEET
FOR ZENIPLEX 2 DRUM
Page 6
Keystone Lubricants Division
Total Fina Elf Lubricants USA, Inc.
5 N. Stiles Street, Linden NJ 07036
REVISION DATE
02-NOV-01
THEREON. USER SHOULD SATISFY HIMSELF THAT HE HAS ALL CURRENT DATA
RELEVANT TO HIS PARTICULAR USE.
CI-G-01
DATE ISSUED
06-JAN-03
Product Name: LIDOK EP 1
Revision Date: 10Jun2004
Page 1 of 8
______________________________________________________________________________________________________________________
MATERIAL SAFETY DATA SHEET
SECTION 1
PRODUCT AND COMPANY IDENTIFICATION
PRODUCT
Product Name: LIDOK EP 1
Product Description: Base Oil and Additives
Product Code: 641407-00, 97N369
Intended Use: Grease
COMPANY IDENTIFICATION
Supplier:
EXXON MOBIL CORPORATION
3225 GALLOWS RD.
FAIRFAX, VA. 22037 USA
24 Hour Health Emergency
609-737-4411
Transportation Emergency Phone
800-424-9300
ExxonMobil Transportation No.
281-834-3296
MSDS Requests
713-613-3661
Product Technical Information
800-662-4525, 800-947-9147
SECTION 2
COMPOSITION / INFORMATION ON INGREDIENTS
Reportable Hazardous Substance(s) or Complex Substance(s)
Name
CAS#
Concentration*
ZINC DIALKYL DITHIOPHOSPHATE
1 - 5%
68457-79-4
* All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume.
SECTION 3
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15).
POTENTIAL HEALTH EFFECTS
Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure
injection under skin may cause serious damage.
ENVIRONMENTAL HAZARDS
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
NFPA Hazard ID:
HMIS Hazard ID:
Health:
Health:
0
0
Flammability: 1
Flammability: 1
Reactivity: 0
Reactivity: 0
NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert
advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary
from person to person.
SECTION 4
CI-G-1A
FIRST AID MEASURES
Product Name: LIDOK EP 1
Revision Date: 10Jun2004
Page 2 of 8
______________________________________________________________________________________________________________________
INHALATION
Under normal conditions of intended use, this material is not expected to be an inhalation hazard.
SKIN CONTACT
Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the
body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by
a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be
minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent
of injury.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.
INGESTION
First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.
Inappropriate Extinguishing Media: Straight Streams of Water
FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams,
sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed
spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to
protect personnel.
Hazardous Combustion Products: Oxides of carbon, Aldehydes, Smoke, Fume, Sulfur oxides, Incomplete
combustion products
FLAMMABILITY PROPERTIES
Flash Point [Method]: >204°C (400°F) [ EST. FOR OIL, ASTM D-92 (COC)]
Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D
Autoignition Temperature: N/D
SECTION 6
ACCIDENTAL RELEASE MEASURES
NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations. U.S. regulations require reporting releases of this material to the environment which exceed the
reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National
Response Center can be reached at (800)424-8802.
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______________________________________________________________________________________________________________________
SPILL MANAGEMENT
Land Spill: Allow spilled material to solidify and scrape up with shovels into a suitable container for recycle or
disposal.
Water Spill: Confine the spill immediately with booms. Stop leak if you can do it without risk. Skim from
surface.
Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING AND STORAGE
HANDLING
Prevent small spills and leakage to avoid slip hazard.
Static Accumulator: This material is not a static accumulator.
STORAGE
Do not store in open or unlabelled containers.
SECTION 8
EXPOSURE CONTROLS / PERSONAL PROTECTION
NOTE: Limits/standards shown for guidance only. Follow applicable regulations.
ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a
level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
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______________________________________________________________________________________________________________________
No protection is ordinarily required under normal conditions of use and with adequate ventilation.
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Work conditions can greatly effect glove durability; inspect and replace worn or damaged
gloves. The types of gloves to be considered for this material include:
No protection is ordinarily required under normal conditions of use.
Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
No skin protection is ordinarily required under normal conditions of use. In accordance with good
industrial hygiene practices, precautions should be taken to avoid skin contact.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
ENVIRONMENTAL CONTROLS
See Sections 6, 7, 12, 13.
SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional
data.
GENERAL INFORMATION
Physical State: Solid
Form: Semi-fluid
Color: Brown
Odor: Characteristic
Odor Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15 °C ): 0.919
Flash Point [Method]: >204°C (400°F) [ EST. FOR OIL, ASTM D-92 (COC)]
Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D
Autoignition Temperature: N/D
Boiling Point / Range: > 315.6°C (600°F)
Vapor Density (Air = 1): N/D
Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20°C
Evaporation Rate (n-butyl acetate = 1): N/D
pH: N/A
Log Pow (n-Octanol/Water Partition Coefficient): > 3.5
Solubility in Water: Negligible
Viscosity: 160 cSt (160 mm²/sec ) at 40 °C
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______________________________________________________________________________________________________________________
Oxidizing Properties: See Sections 3, 15, 16.
OTHER INFORMATION
Freezing Point: N/D
Melting Point: 190°C (374°F)
DMSO Extract (mineral oil only), IP-346:
< 3 %wt
NOTE: Most physical properties above are for the oil component in the material.
SECTION 10
STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions.
CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition.
MATERIALS TO AVOID: Strong oxidizers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.
HAZARDOUS POLYMERIZATION: Will not occur.
SECTION 11
ACUTE TOXICITY
Route of Exposure
Inhalation
Toxicity (Rat): LC50 > 5000 mg/m³
Irritation: No end point data.
Ingestion
Toxicity (Rat): LD50 > 2000 mg/kg
Skin
Toxicity (Rabbit): LD50 > 2000 mg/kg
Irritation (Rabbit): Data available.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on assessment of the components.
Negligible hazard at ambient/normal handling temperatures.
Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar
materials.
Minimally Toxic. Based on test data for structurally similar
materials.
Negligible irritation to skin at ambient temperatures. Based on
assessment of the components.
Eye
Irritation (Rabbit): Data available.
May cause mild, short-lasting discomfort to eyes. Based on
assessment of the components.
CHRONIC/OTHER EFFECTS
Contains:
Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified
Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung nonspecific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test
animals.
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Revision Date: 10Jun2004
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______________________________________________________________________________________________________________________
Additional information is available by request.
The following ingredients are cited on the lists below: None.
1 = NTP CARC
2 = NTP SUS
SECTION 12
--REGULATORY LISTS SEARCHED-3 = IARC 1
5 = IARC 2B
4 = IARC 2A
6 = OSHA CARC
ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials.
ECOTOXICITY
Material -- Expected to be harmful to aquatic organisms. May cause long-term adverse effects in the aquatic
environment.
MOBILITY
Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to
partition to sediment and wastewater solids.
PERSISTENCE AND DEGRADABILITY
Biodegradation:
Base oil component -- Expected to be inherently biodegradable
BIOACCUMULATION POTENTIAL
Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may
reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.
DISPOSAL RECOMMENDATIONS
Suitable routes of disposal are supervised incineration or appropriate recycling methods in accordance with
applicable regulations and material characteristics at the time of disposal.
REGULATORY DISPOSAL INFORMATION
RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous
waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It
does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with
contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used
product may be regulated.
Empty Container Warning PRECAUTIONARY LABEL TEXT: Empty containers may retain residue and can be
dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH
CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY
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______________________________________________________________________________________________________________________
MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or clean container since residue is difficult
to remove. Empty drums should be completely drained, properly bunged and promptly returned to a drum
reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with
governmental regulations.
SECTION 14
TRANSPORT INFORMATION
LAND (DOT) : Not Regulated for Land Transport
LAND (TDG) : Not Regulated for Land Transport
SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code
AIR (IATA) : Not Regulated for Air Transport
SECTION 15
REGULATORY INFORMATION
OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not classified
as hazardous in accordance with OSHA 29 CFR 1910.1200.
NATIONAL CHEMICAL INVENTORY LISTING: AICS, EINECS, TSCA
Special Cases:
Inventory
NDSL
Status
Restrictions Apply
EPCRA: This material contains no extremely hazardous substances.
SARA (311/312) REPORTABLE HAZARD CATEGORIES: None.
SARA (313) TOXIC RELEASE INVENTORY:
Chemical Name
CAS Number
ZINC DIALKYL
68457-79-4
DITHIOPHOSPHATE
Typical Value
1 - 5%
The Following Ingredients are Cited on the Lists Below:
Chemical Name
CAS Number
DIPHENYLAMINE
122-39-4
ZINC DIALKYL
68457-79-4
DITHIOPHOSPHATE
List Citations
5, 9, 18
13, 15, 17
1 = ACGIH ALL
2 = ACGIH A1
3 = ACGIH A2
CI-G-1A
--REGULATORY LISTS SEARCHED-6 = TSCA 5a2
11 = CA P65 REPRO
7 = TSCA 5e
12 = CA RTK
8 = TSCA 6
13 = IL RTK
16 = MN RTK
17 = NJ RTK
18 = PA RTK
Product Name: LIDOK EP 1
Revision Date: 10Jun2004
Page 8 of 8
______________________________________________________________________________________________________________________
4 = OSHA Z
5 = TSCA 4
9 = TSCA 12b
10 = CA P65 CARC
14 = LA RTK
15 = MI 293
19 = RI RTK
Code key: CARC=Carcinogen; REPRO=Reproductive
SECTION 16
OTHER INFORMATION
N/D = Not determined, N/A = Not applicable
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:
No revision information is available.
--------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate
and reliable as of the date issued. ExxonMobil assumes no responsibility for accuracy of information unless the
document is the most current available from an official ExxonMobil distribution system. The information and
recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy
itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be
consulted to insure proper health, safety and other necessary information is included on the container. Appropriate
warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly
prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is
not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil
Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest.
----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only
MHC: 0, 0, 0, 0, 0, 0
PPEC: A
DGN: 2009921XUS (524700)
----------------------------------------------------------------------------------------------------------------------------------------------------Copyright 2002 Exxon Mobil Corporation, All rights reserved
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MATERIAL SAFETY DATA SHEET
76 Multiplex EP Grease 2
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name:
Product Code:
Sap Code:
Intended Use:
Chemical Family:
Responsible Party:
76 Multiplex EP Grease 2
5418020000
Grease
Petroleum hydrocarbon
Phillips 66 Company
Lubricants Division
P.O. Box 25376
Santa Ana, CA 92799-5376
For Additional MSDSs: 800-762-0942
Technical Information:
The intended use of this product is indicated above. If any additional use is known, please contact us at the
Technical Information number listed.
EMERGENCY OVERVIEW
24 Hour Emergency Telephone Numbers:
Spill, Leak, Fire or Accident
Call CHEMTREC
North America: (800)424-9300
Others: (703)527-3887 (collect)
California Poison Control System: (800) 356-3129
Health Hazards/Precautionary Measures: Avoid contact with eyes, skin and clothing. Wash thoroughly after
handling.
Physical Hazards/Precautionary Measures: Keep away from all sources of ignition.
Appearance:
Physical Form:
Odor:
Greenish black
Semi-solid
Mild, bland petroleum
NFPA Hazard Class:
HMIS Hazard Class
Health:
1 (Slight)
Flammability: 1 (Slight)
Reactivity:
0 (Least)
Not Evaluated
2. COMPOSITION/INFORMATION ON INGREDIENTS
HAZARDOUS COMPONENTS
% WEIGHT
EXPOSURE GUIDELINE
Agency
Limits
Zinc Compound
CAS# Proprietary
1-2
Type
Not Established
___________________________________________________________________________________________
% WEIGHT
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76 Multiplex EP Grease 2
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OTHER COMPONENTS
Agency
Limits
Lubricant Base Oil (Petroleum)
CAS# Various
70-90
(See: Oil Mist, If Generated)
Additives
CAS# Proprietary
10-25
Not Established
Raffinate, Low-Asphaltene Vacuum
Residues
CAS# 164907-77-1
1-5
Type
(See: Oil Mist, If Generated)
(See: Coal Tar Pitch Volatiles as Benzene Solubles)
____________________________________________________________________________________________
EXPOSURE GUIDELINE
REFERENCE
Limits
Agency
Type
Coal Tar Pitch Volatiles as Benzene
Solubles
CAS# 65996-93-2
0.2 mg/m3
0.2 mg/m3
80 mg/m3
ACGIH
OSHA
NIOSH
TWA
TWA
IDLH
Oil Mist, If Generated
CAS# None
5 mg/m3
10 mg/m3
5 mg/m3
2500 mg/m3
ACGIH
ACGIH
OSHA
NIOSH
TWA
STEL
TWA
IDLH
All components are listed on the TSCA inventory
The base oil for this product can be a mixture of any of the following highly refined petroleum streams:
CAS 64741-88-4; CAS 64741-89-5; CAS 64741-96-4; CAS 64741-97-5; CAS 64742-01-4; CAS 64742-52-5; CAS
64742-53-6; CAS 64742-54-7; CAS 64742-55-8; CAS 64742-56-9; CAS 64742-57-0; CAS 64742-62-7; CAS
64742-63-8; CAS 64742-65-0; CAS 72623-85-9; CAS 72623-86-0; CAS 72623-87-1
Note: State, local or other agencies or advisory groups may have established more stringent limits.
Consult an industrial hygienist or similar professional, or your local agencies, for further information.
3. HAZARDS IDENTIFICATION
Potential Health Effects:
Eye: Contact may cause mild eye irritation including stinging, watering, and redness.
Skin: Contact may cause mild skin irritation including redness, and a burning sensation. Prolonged or repeated
contact can worsen irritation by causing drying and cracking of the skin leading to dermatitis (inflammation).
No harmful effects from skin absorption are expected.
Inhalation (Breathing): No data available. However, inhalation is not an expected route of
exposure.
Ingestion (Swallowing): No harmful effects expected from ingestion.
Signs and Symptoms: Effects of overexposure may include irritation of the nose and throat,
irritation of the digestive tract, nausea and diarrhea.
Cancer: Inadequate evidence available to evaluate the cancer hazard of this material. See Section 11 for
carcinogenicity information of individual components, if any.
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Target Organs: No data available for this material.
Developmental: No data available for this material.
Pre-Existing Medical Conditions:
disorders.
Conditions aggravated by exposure may include skin
4. FIRST AID MEASURES
Eye: If irritation or redness develops, move victim away from exposure and into fresh air. Flush eyes
with clean water. If symptoms persist, seek medical attention.
Skin: Wipe material from skin and remove contaminated shoes and clothing. Cleanse affected area(s)
thoroughly by washing with mild soap and water and, if necessary, a waterless skin cleanser. If
irritation or redness develops and persists, seek medical attention.
Inhalation (Breathing): If respiratory symptoms develop, move victim away from source of exposure and into
fresh air. If symptoms persist, seek medical attention. If victim is not breathing, clear airway and immediately
begin artificial respiration. If breathing difficulties develop, oxygen should be administered by qualified
personnel. Seek immediate medical attention.
Ingestion (Swallowing): First aid is not normally required; however, if swallowed and symptoms develop, seek
medical attention.
Note To Physicians: High-pressure hydrocarbon injection injuries may produce substantial
necrosis of underlying tissue despite an innocuous appearing external wound. Often these injuries
require extensive emergency surgical debridement and all injuries should be evaluated by a
specialist in order to assess the extent of injury.
5. FIRE FIGHTING MEASURES
Flammable Properties:
Flash Point: 450°F/232°C (COC)
OSHA Flammability Class: Not applicable
LEL%: 0.9 / UEL%: 7.0
Autoignition Temperature: No Data
Burn Rate (solids): No Data
Unusual Fire & Explosion Hazards: This material may burn, but will not ignite readily.
Extinguishing Media: Dry chemical, carbon dioxide, foam, water, sand, or earth is recommended. Carbon dioxide
can displace oxygen. Use caution when applying carbon dioxide in confines spaces.
Fire Fighting Instructions: For fires beyond the incipient stage, emergency responders in the immediate hazard
area should wear bunker gear. When the potential chemical hazard is unknown, in enclosed or confined spaces, or
when explicitly required by DOT, a self contained breathing apparatus should be worn. In addition, wear other
appropriate protective equipment as conditions warrant (see Section 8).
Isolate immediate hazard area, keep unauthorized personnel out. Contain spill if it can be done with minimal risk.
Move undamaged containers from immediate hazard area if it can be done with minimal risk.
Cool equipment exposed to fire with water, if it can be done with minimal risk.
6. ACCIDENTAL RELEASE MEASURES
This material may burn, but will not ignite readily. Keep all sources of ignition away from spill/release. Stay
upwind and away from spill. Notify persons down wind of the spill/release, isolate immediate hazard area and keep
unauthorized personnel out. Contain spill if it can be done with minimal risk. Wear appropriate protective
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equipment including respiratory protection as conditions warrant (see Section 8).
Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems, and natural
waterways. Notify fire authorities and appropriate federal, state, and local agencies. Cleanup under expert
supervision is advised. Minimize dust generation. Sweep up and package appropriately for disposal. If spill of
any amount is made into or upon navigable waters, the contiguous zone, or adjoining shorelines, notify the National
Response Center (phone number 800-424-8802).
7. HANDLING AND STORAGE
Handling: The use of appropriate respiratory protection is advised when concentrations exceed any
established exposure limits (see Sections 2 and 8).
Do not wear contaminated clothing or shoes. Use good personal hygiene practices.
High pressure injection of hydrocarbon fuels, hydraulic oils or greases under the skin may have serious
consequences even though no symptoms or injury may be apparent. This can happen accidentally when using
high pressure equipment such as high pressure grease guns, fuel injection apparatus or from pinhole leaks in
tubing of high pressure hydraulic oil equipment.
"Empty" containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and
cause injury or death. "Empty" drums should be completely drained, properly bunged, and promptly shipped to
the supplier or a drum reconditioner. All containers should be disposed of in an environmentally safe
manner and in accordance with governmental regulations.
Before working on or in tanks which contain or have contained this material, refer to OSHA regulations, ANSI
Z49.1 and other references pertaining to cleaning, repairing, welding, or other contemplated operations.
Storage: Keep container(s) tightly closed. Use and store this material in cool, dry, well-ventilated
areas away from heat and all sources of ignition. Storage temperatures above 113°F may lead to thermal
decomposition, resulting in the generation of hydrogen sulfide and other sulfur containing gases. Store
only in approved containers. Keep away from any incompatible material (see Section 10). Protect
container(s) against physical damage.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering controls: If current ventilation practices are not adequate to maintain airborne concentrations below
the established exposure limits (see Section 2), additional ventilation or exhaust systems may be required.
Personal Protective Equipment (PPE):
Respiratory: Inhalation is not an expected route of exposure. However, a NIOSH certified
air purifying respirator with a Type 95 (R or P) particulate filter may be used under
conditions where airborne concentrations are expected to exceed exposure limits (see
Section 2).
Protection provided by air purifying respirators is limited (see manufacturer's respirator
selection guide). Use a positive pressure air supplied respirator if there is potential
for uncontrolled release, exposure levels are not known, or any other circumstances where
air purifying respirators may not provide adequate protection.
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2
requirements must be followed whenever workplace conditions warrant a respirator's use.
Skin: The use of gloves impervious to the specific material handled is advised to prevent skin
contact and possible irritation (see manufacturers literature for information on
permeability).
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Eye/Face: Approved eye protection to safeguard against potential eye contact, irritation, or
injury is recommended. Depending on conditions of use, a face shield may be necessary.
Other Protective Equipment: A source of clean water should be available in the work
area for flushing eyes and skin. Impervious clothing should be worn as needed.
9. PHYSICAL AND CHEMICAL PROPERTIES
Note: Unless otherwise stated, values are determined at 20°C (68°F) and 760 mm Hg (1 atm).
Burn Rate (solids only): No Data
Appearance: Greenish black
Physical State: Semi-solid
Odor: Mild, bland petroleum
Vapor Pressure (mm Hg): <0.01
Vapor Density (air=1): >5
Boiling Point/Range: >590°F / >310°C
Freezing/Melting Point: 545°F / 285'DC
Solubility in Water: Negligible
Specific Gravity: 0.89 @ 60°F
Percent Volatile: Negligible
Evaporation Rate (nBuAc=1): <1
Bulk Density: 7.42 lbs/gal
Flash Point: 450°F / 232°C (COC)
Flammable/Explosive Limits (%): LEL: 0.9 / UEL: 7.0
10. STABILITY AND REACTIVITY
Stability: Stable under normal ambient and anticipated storage and handling conditions of temperature and
pressure.
Conditions To Avoid: Extended exposure to high temperatures can cause decomposition.
Materials to Avoid (Incompatible Materials): Avoid contact with strong oxidants such as liquid chlorine,
concentrated oxygen, sodium hypochlorite or calcium hypochlorite.
Hazardous Decomposition Products: Combustion can yield carbon, nitrogen, sulfur, phosphorus, and zinc oxides .
Hydrogen sulfide and alkyl mercaptans may also be released. Thermal decomposition may produce hydrogen
sulfide and other sulfur-containing gases at temperatures greater than 113°F.
Hazardous Polymerization: Will not occur.
11. TOXICOLOGICAL INFORMATION
Lubricant Base Oil (Petroleum) (CAS# Various)
Carcinogenicity: The petroleum base oils contained in this product have been highly refined by a
variety of processes including solvent extraction, hydrotreating, and dewaxing to remove aromatics and
improve performance characteristics. None of the oils used are listed as a carcinogen by NTP, IARC, or
OSHA.
12. ECOLOGICAL INFORMATION
Not evaluated at this time
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13. DISPOSAL CONSIDERATIONS
This material, if discarded as produced, is not a RCRA "listed" or "characteristic" hazardous waste. Use which
results in chemical or physical change or contamination may subject it to regulation as a hazardous waste. Along
with properly characterizing all waste materials, consult state and local regulations regarding the proper disposal
of this material.
14. TRANSPORT INFORMATION
Note: Not classified as hazardous
15. REGULATORY INFORMATION
EPA SARA 311/312 (Title III Hazard Categories):
No
Acute Health:
Chronic Health:
No
No
Fire Hazard:
Pressure Hazard: No
Reactive Hazard: No
SARA 313 and 40 CFR 372:
This material contains the following chemicals subject to the reporting requirements of SARA 313 and 40
CFR 372:
Component
Zinc Compound
CAS Number
Weight %
Proprietary
1-2
California Proposition 65:
Warning: This material contains the following chemicals which are known to the State of California to cause cancer,
birth defects or other reproductive harm, and are subject to the requirements of California Proposition 65 (CA Health
& Safety Code Section 25249.5):
--None Known-Carcinogen Identification:
This material has not been identified as a carcinogen by NTP, IARC, or OSHA. See Section 11 for
carcinogenicity information of individual components, if any.
EPA (CERCLA) Reportable Quantity:
--None--
16. OTHER INFORMATION
Issue Date: 01/01/02
Previous Issue Date: 08/30/01
Product Code: 5418020000
Revised Sections: None
Previous Product Code: 5418020000
MSDS Number: 5418020000
Disclaimer of Expressed and Implied Warranties:
The information presented in this Material Safety Data Sheet is based on data believed to be accurate as of the date this Material Safety Data
Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER
WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION
PROVIDED ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF
THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. No responsibility is assumed for any damage or injury resulting from abnormal
use or from any failure to adhere to recommended practices. The information provided above, and the product, are furnished on the condition
that the person receiving them shall make their own determination as to the suitability of the product for their particular purpose and on the
condition that they assume the risk of their use. In addition, no authorization is given nor implied to practice any patented invention without a
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MSDS North America/ANSI Z400.1_USA / ENGLISH
/ ENGLISH
Material Safety Data Sheet
Section 1. Chemical Product and Company Identification
Product Name
ENERGREASE ® LC-M2
Supplier
BP Lubricants North America
9300 Pulaski Highway
Baltimore, Maryland 21220-2495
1 (800) 447-8735
EMERGENCY HEALTH
INFORMATION:
EMERGENCY SPILL
INFORMATION:
MSDS#
0000000638
Historic MSDS#:
None.
1 (800) 424-9300
CHEMTREC (USA)
1 (866) 4 BP - MSDS
(866-427-6737 Toll Free - North America)
email: bpcares@bp.com
OTHER PRODUCT
INFORMATION
Section 2. Composition, Information on Ingredients
CAS #
Name
1) DISTILLATES (PETROLEUM),
HYDROTREATED HEAVY NAPHTHENIC
2) LITHIUM SOAP
3) MOLYBDENUM DISULFIDE
4) ZINC COMPOUND
% by
Weight
64742-52-5
80-100
1317-33-5
5-20
3
1-3
Exposure Limits
ACGIH (United States).
TWA: 5 mg/m3 Form: OIL MIST, MINERAL
STEL: 10 mg/m3 Form: OIL MIST, MINERAL
OSHA (United States).
PEL: 5 mg/m3 Period: 8 hour(s). Form: OIL MIST,
MINERAL
None assigned.
ACGIH TLV (United States, 2000).
TWA: 10 mg/m3
OSHA Final Rule (United States, 1989).
TWA: 10 mg/m3
None assigned.
Section 3. Hazards Identification
Physical state
Solid paste.
Color
Gray.
Emergency Overview
This product has been evaluated and does not require any hazard warning on the label under established
regulatory criteria.
Prolonged or repeated contact can defat the skin and lead to irritation and/or dermatitis.
POTENTIAL HEALTH
EFFECTS
Eyes
No significant health hazards identified.
Skin
Prolonged or repeated contact can defat the skin and lead to irritation and/or dermatitis. High pressure skin
injections are serious medical emergencies. Injury will not appear serious at first; within a few hours, tissue will
become swollen, discolored and extremely painful.
Inhalation
No significant health hazards identified.
Ingestion
Causes gastrointestinal irritation and diarrhea.
See Toxicological Information (section 11)
Continued on Next Page
CI-G-04
ENERGREASE ® LC-M2
Page: 2/5
Section 4. First Aid Measures
Skin Contact
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if
irritation occurs.
Immediately wash exposed skin with soap and water. Remove contaminated clothing and shoes. Wash clothing
before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation occurs. Accidental high
pressure injection through the skin requires immediate medical attention.
Inhalation
If inhaled, remove to fresh air. Get medical attention if symptoms appear.
Ingestion
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person.If large quantities of this material are swallowed, call a physician immediately.
Eye Contact
Section 5. Fire Fighting Measures
Flammability of the Product May be combustible at high temperature.
Autoignition Temperature Not available.
OPEN CUP: 204°C (399.2°F) (Cleveland.).
Flash Points
Flammable Limits
Not available.
Products of Combustion
carbon oxides (CO, CO2), sulfur oxides (SO2, SO3...), oxides of phosphorus, other hazardous substances.
Unusual fire/explosion
hazards
None identified.
Fire Fighting Media
and Instructions
SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Protective Clothing (Fire)
Firefighters should wear full bunker gear, including a positive pressure self-contained breathing apparatus.
This material is not explosive as defined by established regulatory criteria.
Section 6. Accidental Release Measures
Large Spill and Leak
Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective
equipment (Section 8). Follow all fire fighting procedures (Section 5).
If emergency personnel are unavailable, contain spilled material. For small spills add absorbent (soil may be used
in the absence of other suitable materials) and use a non-sparking or explosion proof means to transfer material to
a sealed, appropriate container for disposal. For large spills dike spilled material or otherwise contain material to
ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal. Minimize
contact of spilled material with soils to prevent runoff to surface waterways.
Section 7. Handling and Storage
Handling
Storage
Avoid breathing vapors or spray mists. Do not ingest. Wash thoroughly after handling. Avoid prolonged or
repeated contact with skin.
Keep container tightly closed. Keep container in a cool, well-ventilated area.
Section 8. Exposure Controls, Personal Protection
Engineering Controls
Personal Protection
Eyes
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station
location.
Safety glasses with side shields.
Skin and Body
Avoid prolonged or repeated contact with skin. Wear protective clothing if prolonged or repeated contact is likely.
Respiratory
None required; however, use of adequate ventilation is good industrial practice. If ventilation is inadequate, use
a NIOSH certified respirator with an organic vapor cartridge and P95 particulate filter.
Wear protective gloves if prolonged or repeated contact is likely.
Hands
Chemical name
Continued on Next Page
Exposure Limits
CI-G-04
ENERGREASE ® LC-M2
1) DISTILLATES (PETROLEUM), HYDROTREATED
HEAVY NAPHTHENIC
2) MOLYBDENUM DISULFIDE
3) LITHIUM SOAP
4) ZINC COMPOUND
Page: 3/5
ACGIH (United States).
TWA: 5 mg/m3 Form: OIL MIST, MINERAL
STEL: 10 mg/m3 Form: OIL MIST, MINERAL
OSHA (United States).
PEL: 5 mg/m3 Period: 8 hour(s). Form: OIL MIST, MINERAL
ACGIH TLV (United States, 2000).
TWA: 10 mg/m3
OSHA Final Rule (United States, 1989).
TWA: 10 mg/m3
None assigned.
None assigned.
Consult local authorities for acceptable exposure limits.
Section 9. Physical and Chemical Properties
Physical state
Solid paste.
Odor
Bland.
pH
Not applicable.
Color
Gray.
Boiling/Condensation Point >371°C (699.8°F)
Melting/Freezing Point
Not available.
Specific Gravity
0.94 (Water = 1)
Vapor Pressure
negligible
Vapor Density
>1 (Air = 1)
Odor Threshold
Not available.
Evaporation Rate
negligible
Viscosity
Kinematic (40C): 500 cSt
LogKow
Not available.
Solubility
Insoluble in cold water.
Section 10. Stability and Reactivity
Stability and Reactivity
The product is stable.
Conditions to avoid
Keep away from heat, sparks and flame. Keep away from sources of ignition.
Incompatibility with
Various Substances
Strong oxidizing materials, strong acids, strong alkalis.
Hazardous Decomposition
Products
Products of Combustion: carbon oxides (CO, CO2), sulfur oxides (SO2, SO3...), oxides of phosphorus, other
hazardous substances.
Hazardous Polymerization Will not occur.
Section 11. Toxicological Information
Acute toxicity
LD50: Not available.
LC50: Not available.
Chronic toxicity
No component of this product at levels greater than 0.1% is identified as a carcinogen by ACGIH or the
International Agency for Research on Cancer (IARC). No component of this product present at levels greater than
0.1% is identified as a carcinogen by the U.S. National Toxicology Program (NTP) or the U.S. Occupational
Safety and Health Act (OSHA).
Other information
No significant health hazards identified.
Continued on Next Page
CI-G-04
ENERGREASE ® LC-M2
Page: 4/5
Section 12. Ecological Information
Ecotoxicity
Ecological testing has not been conducted on this product by BP.
Section 13. Disposal Considerations
Waste Information
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Consult your local or regional authorities.
Section 14. Transport Information
DOT Classification
Not a DOT controlled material (United States).
Not regulated.
Marine Pollutant
Not pollutant.
Special Provisions for
Transport
None identified.
ADR/RID Classification
UN number
Proper shipping name
Not applicable.
ADR/RID Class
Not applicable.
Packing Group
Not applicable.
Not regulated.
IMO/IMDG Classification
Proper shipping name
Not regulated.
IMDG Class
Not applicable.
UN number
Not applicable.
Packing Group
Not regulated.
Marine Pollutant
Not pollutant.
ICAO/IATA Classification
Proper shipping name
Not regulated.
IATA Class
Not applicable.
UN number
Not applicable.
Packing Group
Not applicable.
Section 15. Regulatory Information
U.S. Regulations
US INVENTORY (TSCA): Listed on inventory.
SARA Title III Section 302 Extremely Hazardous Substances (40 CFR Part 355):: This product is not regulated
under Section 302 of SARA and 40 CFR Part 355.
SARA Title III Sections 311/312 Hazardous Categorization (40 CFR Part 370):: Defined as non-hazardous by OSHA
under 29 CFR 1910.1200(d).
SARA 313 toxic chemical notification and release reporting: ZINC COMPOUNDS, 3.0%
CERCLA Sections 102a/103 Hazardous Substances (40 CFR Part 302.4):: This material is not regulated under
CERCLA Sections 103 and 107.
State Regulations
No products were found.
California prop. 65: No products were found.
Continued on Next Page
CI-G-04
ENERGREASE ® LC-M2
Page: 5/5
AUSTRALIAN INVENTORY (AICS): Not determined.
Other Regulations
CANADA INVENTORY (DSL): In compliance.
CHINA INVENTORY (IECS): Not determined.
EC INVENTORY (EINECS/ELINCS): Not determined.
JAPAN INVENTORY (ENCS): Not determined.
KOREA INVENTORY (ECL): Not determined.
PHILIPPINE INVENTORY (PICCS): Not determined.
Section 16. Other Information
This product has been evaluated and does not require any hazard warning on the label under established
regulatory criteria.
Prolonged or repeated contact can defat the skin and lead to irritation and/or dermatitis.
Label Requirements
Hazardous Material
Information System
(U.S.A.)
Health
Fire Hazard
Reactivity
1 National Fire
1 Protection Association
(U.S.A.)
0
1
Health
1
Fire Hazard
0
Reactivity
Specific Hazard
HISTORY
11/26/2001.
1
Product Stewardship
Date of issue
Version
Prepared by
Notice to Reader
NOTICE : This Material Safety Data Sheet is based upon data considered to be accurate at the time of its preparation. Despite our efforts, it may not be up to date
or applicable to the circumstances of any particular case. We are not responsible for any damage or injury resulting from abnormal use, from any failure to
follow appropriate practices or from hazards inherent in the nature of the product. This Material Safety Data Sheet conforms to the requirements of ANSI
Z400.1.
022
00
CI-G-04
Reprints/Updates of this document are available at our website:
http://www.cimcool.com
Material Safety Data Sheet
CIMGUARD® 61
CORROSION PREVENTIVE
DATE EFFECTIVE: 10-07-2005
1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
.
Manufacturer:
Milacron Marketing Company, Global Industrial Fluids
3000 Disney Street
Cincinnati, OH 45209 United States
Emergency:
Telephone (USA): 1-800-424-9300 (CHEMTREC)
Telephone (Outside USA): 1-703-527-3887 (CHEMTREC)
General Information:
Telephone: 1-513-458-8199
Generic Name:
Corrosion Preventive
2 EMERGENCY INFORMATION
.
Product is flammable. Vapors are heavier than air. Vapors may travel across the ground and reach a
remote ignition source causing a flashback fire danger. Vapors concentrated in confined areas, such
as truck trailer, may cause irritation to the eyes, nose, and throat and may cause dizziness.
Prolonged inhalation may result in central nervous system depression and may be fatal. Pulmonary
aspiration hazard if swallowed and/or vomiting occurs - can enter lungs and cause damage. Product
is a primary eye irritant. Product may be a primary skin irritant. Highway spills could result in slippery
conditions. No other significant health effects are associated with this material.
3 POTENTIAL HEALTH EFFECTS OF DIRECT EXPOSURE
.
Product
Inhalation:
Central nervous system depressant. Extended
exposure to mist may cause upper respiratory
irritation.
Eye Contact:
Product is a primary eye irritant.
Skin Contact:
Product may be a primary skin irritant.
Ingestion:
Not orally toxic. Pulmonary aspiration hazard if
swallowed and/or vomiting occurs - can enter
lungs and cause damage.
Medical Conditions generally aggravated by exposure
May aggravate existing skin irritation where further defatting or skin penetration could occur.
Mild skin irritation (redness and dryness of hands) may be experienced when the product has been
contaminated by certain oils or by dissolved metals. When problems occur, use of oil-resistant
barrier creams may be a temporary control measure. Contact Milacron Marketing Company, Global
Industrial Fluids Technical Services at 1-513-458-8199 for specific recommendations.
Material Name: CIMGUARD® 61
29RGP417
Effective Date: 10-07-2005
CI-G-06
1/ 7
When used in applications generating high levels of mist, operator exposure can be minimized by
proper ventilation, use of mist collectors or splash guards, as appropriate. If there is doubt about
actual mist levels present, monitoring should be conducted. Contact Milacron Marketing Company,
Global Industrial Fluids at 1-513-458-8199 for specific recommendations.
Carcinogen Listings:
NTP: No
IARC: No
OSHA: No
Signs and symptoms of exposure
Acute
Eye injury may result from contact with product. Skin irritation can result from improper use and
handling of product.
4 EMERGENCY AND FIRST AID PROCEDURES
.
Eyes
In case of eye contact, flush immediately with running water for at least 15 minutes, and get prompt
medical attention.
Skin Contact
For skin contact flush with large amounts of water while removing contaminated clothing. Remove
contaminated shoes and clothing and launder before reuse. If irritation persists, get medical attention.
Product is not irritating to the skin when used as recommended and good personal hygiene is
practiced.
Ingestion
If the material is swallowed, DO NOT INDUCE VOMITING. Immediately contact a physician and obtain
treatment. Do not give liquids. Swallowing small quantities of product may cause nausea, diarrhea or
abdominal distress.
Inhalation
Inhalation can occur in applications where high mist levels are generated. OSHA has set a PEL of 15
mg/m³ for any airborne particulate as a nuisance level of exposure. NIOSH has set a REL of 0.5 mg/m³
for metalworking fluid mist. If symptoms are experienced, remove source of contamination or move
victim to fresh air. If symptoms persist, get medical attention.
5 CONTROL MEASURES
.
Respiratory protection
Product is not volatile.
In applications where time-weighted exposures are 0.5 to 5 mg/m³, mist reduction through improved
ventilation, mist collection or process modification is recommended by NIOSH. Where this is not
possible, NIOSH recommends the use of any air purifying, half-mask respirator including a disposable
respirator, equipped with any P- or R-series particulate filter. If the average exposure will exceed 5
mg/m³, NIOSH recommends use of a powered, air-purifying respirator equipped with a hood or helmet
and a HEPA filter. If respiratory problems are present when mist levels are < 0.5 mg/m³, respiratory
protection should be based on the individual recommendation of a qualified health care provider.
Caution
The appropriate use and type of respirator is dependent upon use of the product and local operating
conditions.
Ventilation
For most applications, normal shop ventilation is adequate. However, when high mist levels are
generated or where machines are close together or ventilation is inadequate, operators may experience
respiratory irritation. For such applications, use of splash guards or mist collectors is recommended.
Material Name: CIMGUARD® 61
29RGP417
Effective Date: 10-07-2005
CI-G-06
2/ 7
Eye protection
Proper metalworking plant eye protection required when handling product.
Other protective clothing or equipment
Use effective metalworking plant protective clothing as appropriate.
Work / Hygiene Practices
Good personal hygiene should always be followed.
Protective Gloves
Impervious gloves, such as nitrile gloves, are recommended when handling product.
6 HAZARDOUS INGREDIENTS / IDENTITY INFORMATION
.
These ingredients may contribute to the acute product hazards listed under the Potential Health
Effects section. Other substances, not hazardous under the OSHA Hazard Communication
Standard, may be present. Further composition information may be available to health professionals
as provided in the Standard.
Component
CAS #
Percent
PETROLATUM OXIDIZED, CALCIUM SALT
68425-34-3
30 - 60
ALIPHATIC HYDROCARBONS
8052-41-3
30 - 60
7 FIRE AND EXPLOSION HAZARD DATA
.
Extinguishing Media
Chemical foam, carbon dioxide, or dry chemical
Fire Fighting Equipment/Instructions
Do not enter confined space without full bunker gear, including a positive pressure, NIOSH-approved,
self-contained, breathing apparatus.
Unusual Fire & Explosion Hazards
Vapor or gas may spread to distant ignition sources and flash back.
Hazardous Combustion Products
Smoke, fumes, and oxides of carbon
Flash Point:
Lower Explosive Limit:
Upper Explosive Limit:
HMIS RATINGS
Health
Flammability Classification
Reactivity
NFPA RATINGS
Health
Flammability Classification
Reactivity
106 °F (41.1 °C) Pensky-Martens Closed Cup
1%
6%
1
2
0
1
2
0
8 ACCIDENTAL RELEASE MEASURES
.
Material Name: CIMGUARD® 61
29RGP417
Effective Date: 10-07-2005
CI-G-06
3/ 7
Contain the spill, collect on absorbent material, and discard as dictated by Federal, state and local
regulations that may apply. Flush area thoroughly with water.
Reportable Quantity:
None
9 WASTE DISPOSAL
.
For Used Product
Disposal procedures must comply with local, county, state and Federal regulations. Contact Milacron
Marketing Company, Global Industrial Fluids at 1-513-458-8199 for assistance.
For Unused Product
Product is a hazardous waste as defined under 40 CFR 261. Contact Milacron Marketing Company,
Global Industrial Fluids at 1-513-458-8199 for assistance.
Empty Containers
CAUTION: Empty containers retain residue (liquid and/or vapor) and may be dangerous. DO NOT
PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE THIS CONTAINER TO
HEAT, FLAME, SPARKS OR OTHER SOURCES OF IGNITION: IT MAY EXPLODE AND CAUSE
INJURY OR DEATH. Do not attempt to clean drums since residue is difficult to remove. Empty drums
should be completely drained, promptly bunged, and promptly returned to a drum reconditioner. Empty
disposable bulk containers should be drained, sealed, and properly discarded. Empty recyclable bulk
containers should be drained, sealed, and recycled. Empty pails and jugs should be drained and
properly discarded.
Empty containers will contain a residue which is considered a hazardous waste under RCRA
regulations.
10 HANDLING AND STORAGE
.
Electrostatic Accumulation Hazard: Use proper grounding or bonding procedures. Additional
information regarding the safe handling of products with static accumulation potential can be ordered
from the American Petroleum Institute (API) request API Recommended Practice 2003 or from the
National Fire Protection Association (NFPA) request NFPA 77. Avoid all contact of product with eyes
or skin. Wash thoroughly after handling. Do not swallow. Do not store product in direct sunlight or
elevated temperatures. If frozen, thaw completely at room temperature prior to use. Use only as
recommended by Milacron Marketing Company, Global Industrial Fluids .
Other Precautions
Product is flammable. Do not heat. Avoid open flames, sparks, and temperatures approaching the
flash point.
11 PHYSICAL / CHEMICAL CHARACTERISTICS
.
Boiling Point:
Not Applicable
Specific Gravity:
0.89 @ 77°F
Evaporation Rate:
Slower than ethyl ether
Solubility (H2O):
Insoluble
Volatile Organic Content (by 54 %
ASTM D2369):
pH (Concentrate):
Not Applicable
Recommended Starting
Dilution:
Use undiluted
Appearance/Odor:
Clear/Solvent
Material Name: CIMGUARD® 61
29RGP417
Effective Date: 10-07-2005
CI-G-06
4/ 7
12 REACTIVITY
.
Stability
Stable under normal conditions.
Conditions to avoid
Use as directed.
Materials to avoid
Avoid contact with strong acids or oxidizers to product.
Hazardous Polymerization
Will not occur.
Combustion Products
Smoke, fumes, and oxides of carbon
13 TRANSPORTATION INFORMATION
.
BY LAND
Hazardous Materials Description and Proper Shipping Name (49 CFR 172.101)
Flammable liquids, n.o.s. (CONTAINS ALPHATIC HYDROCARBONS)
Hazard Class (49 CFR 172.101): 3
Identification Number:
UN1993
Packaging Group:
III
U.S. Harmonized Tariff Code:
3403.99.0000
BY AIR OR VESSEL
Hazardous Materials Description and Proper Shipping Name (49 CFR 172.101)
Flammable liquids, n.o.s. (CONTAINS ALPHATIC HYDROCARBONS)
Hazard Class (49 CFR 172.101): 3
Identification Number:
UN1993
Packaging Group:
III
14 REGULATORY INFORMATION
.
EXPOSURE GUIDELINES
REGULATED MATERIAL
ALIPHATIC HYDROCARBONS
METALWORKING FLUID MIST
NIOSH REL
OSHA PEL
100 ppm
OSHA STEL ACGIH TLV ACGIH STEL
100 ppm
0.5 mg/m³
CERCLA
No components of this product are present at levels which require reporting under 40 CFR 302.4.
EPCRA (SARA) TITLE III Extremely Hazardous Substances (302):
None
Hazardous Substances (311/312)
Product is a hazardous substance as defined under the OSHA Hazard Communication Standard and
may be reportable under the provisions of SARA Sections 311 and 312.
Material Name: CIMGUARD® 61
29RGP417
Effective Date: 10-07-2005
CI-G-06
5/ 7
HAZARD CATEGORIES
Acute Health: Yes
Chronic Health: No
Fire: Yes
Sudden Release of Pressure: No
Reactive: No
RCRA
Product meets the definition of a hazardous waste as defined under 40 CFR 261.
TSCA
The ingredients of this product are on the TSCA inventory.
State Right to Know
Many states have enacted Community Right-To-Know laws which require information beyond that
mandated by federal laws. Since some of these laws are inconsistent with the federal laws, the
information in this sheet may not fully meet the requirements of every state.
Toxic Substances (313)
Component
CAS #
None
Max % Comments
%
GLOSSARY OF ABBREVIATIONS
ACGIH
American Conference of Governmental Industrial Hygenists
CAS
Chemical Abstracts Service
CERCLA
Comprehensive Environmental Response Compensation and Liability Act
CFR
Code of Federal Regulations
COC
Cleveland Open Cup
DOT
Department of Transportation
EPCRA
Emergency Planning and Community Right-to-Know Act (aka SARA)
IARC
International Agency for Research on Cancer
NIOSH
National Institute for Occupational Safety and Health
NTP
National Toxicology Program
OSHA
Occupational Safety and Health Administration
PEL
Permissible Exposure Limit
RCRA
Resource Conservation and Recovery Act
REC
Recommended
REL
Recommended Exposure Limit
SARA
Superfund Amendments and Reauthorization Act
STEL
Short-Term Exposure Limit
TCLP
Toxicity Characteristics Leaching Procedure
TLV
Threshold Limit Value
TSCA
Toxic Substances Control Act
VOC
Volatile Organic Compounds
Material Name: CIMGUARD® 61
29RGP417
Effective Date: 10-07-2005
CI-G-06
6/ 7
Disclaimer
NOTE: The opinions expressed herein are those of qualified experts within Milacron Marketing
Company, Global Industrial Fluids and of their suppliers. We believe that the information contained
herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and
of these opinions and the condition and use of the product are not within the control of Milacron
Marketing Company, Global Industrial Fluids , it is the user's obligation to determine the conditions of
safe use of the product.
Material Name: CIMGUARD® 61
29RGP417
Effective Date: 10-07-2005
CI-G-06
7/ 7
£
LUBRIPLATE
MATERIAL SAFETY DATA SHEET
Section 1
PRODUCT NAME OR NUMBER
LUBRIPLATE No. 1200-2
FORMULA
Lithium Soap, Mineral Oil and Additives
GENERIC/CHEMICAL NAME:
Petroleum Lubricating Grease
USDA AUTHORIZATION:
H-2
Manufacturer's Name
Fiske Brothers Refining Co.
Address
1500 Oakdale Ave., Toledo, Ohio 43605 - 129 Lockwood St., Newark, NJ 07105
Emergency Telephone Number
1-800-255-3924 - CHEM-TEL (24 hour)
Telephone Number for Information
419-691-2491 - Toledo Office
Section 2 - Hazardous Ingredients/Identity Information
Hazardous Components
Non-hazardous
OSHA PEL
ACGIH TLV
Hazardous Material Identification System (HMIS):
Not a Controlled Product under (WHMIS) - Canada
Other Limits Recommended
Health - 1,
% (optional)
Flammability - 1,
Reactivity - 0
Special Protection: See Section 9
Section 3 - Health Hazard Data
Threshold Limit Value 5 mg/m3 for oil mist in air. OSHA Regulation 29 CFR 1910.1000 - 0.5 mg/m3 for Antimony Compound (as Sb)
Effects of Overexposure Prolonged or repeated skin contact may cause skin irritation. Product contacting the eyes may cause eye irritation.
Human health risks vary from person to person. As a precaution, exposure to liquids, vapors, mists and fumes should be minimized. This
product has a low order of acute oral toxicity, but minute amounts aspirated into the lungs during ingestion may cause mild to severe
pulmonary injury.
Carcinogenicity:
NTP? No
IARC Monographs? No
OSHA Regulated? No
Section 4 - Emergency and First Aid Procedures
EYE CONTACT: Flush with clear water for 15 minutes or until irritation subsides. If irritation persists, consult a physician.
SKIN CONTACT: Remove any contaminated clothing and wash with soap and warm water. If injected by high pressure under skin,
regardless of the appearance or its size, contact a physician IMMEDIATELY. Delay may cause loss of affected part of the body.
INHALATION: Vapor pressure is very low and inhalation at room temperature is not a problem. If overcome by vapor from hot product,
immediately remove from exposure and call a physician.
INGESTION: If ingested, call a physician immediately. Do not induce vomiting.
Section 5 - Fire and Explosion Hazard Data
Flash Point (Method Used)
COC - 425oF
Extinguishing Media
Foam, Dry Chemical, Carbon Dioxide or Water Spray (Fog)
Special Fire Fighting Procedures
Cool exposed containers with water. Use air-supplied breathing equipment for
enclosed or confined spaces.
Do not store or mix with strong oxidants. Empty containers retain residue.
Do not cut, drill, grind, or weld, as they may explode.
Unusual Fire and Explosion Hazards
CI-G-07
Flammable Limits
LEL 0.9%
UEL 7.0%
PRODUCT NAME OR NUMBER - LUBRIPLATE No. 1200-2
Section 6 - Physical/Chemical Characteristics
Boiling Point
>550oF
Specific Gravity (H 2O = 1)
0.941
Vapor Pressure (mm Hg.)
<0.01
Melting Point
Semi-solid
Vapor Density (AIR = 1)
>5
Evaporation Rate
(Butyl Acetate = 1)
<0.01
Solubility in Water
Negligible
Appearance and Odor
Off-white grease with mineral oil odor.
Section 7 - Reactivity Data
Unstable
Stable
X
Incompatibility (Materials to Avoid)
Stability
Conditions to Avoid
N/A
Avoid contact with strong oxidants like liquid chlorine, concentrated oxygen.
Hazardous Decomposition or Byproducts May form SO 2. If incomplete combustion, Carbon Monoxide.
Hazardous Polymerization
May Occur
Will Not Occur X
Conditions to Avoid N/A
Section 8 - Spill or Leak Procedures
Steps to be taken in case material is released or spilled
Scrape up grease, wash remainder with suitable petroleum solvent or add absorbent. Keep petroleum products out of sewers and water
courses. Advise authorities if product has entered or may enter sewers and water courses.
Waste disposal method
Assure conformity with applicable disposal regulations. Dispose of absorbed material at an approved waste disposal facility or site.
SARA/TITLE III, Section 313 Status -
Zinc Compounds - <6%
Antimony Compounds - <3%
Section 9 - Special Protection Information
Respiratory Protection (Specify type)
Normally not needed
Ventilation
Used to capture fumes and vapors
Local Exhaust
Mechanical (General)
Protective Gloves Use oil-resistant gloves, if needed.
Other Protective Equipment
Special N/A
Other N/A
Eye Protection If chance of eye contact, wear goggles.
Use oil-resistant apron, if needed.
Section 10 - Special Precautions
Precautions to be taken in handling and storing
Keep containers closed when not in use. Do not handle or store near heat, sparks, flame, or strong oxidants.
Other Precautions
Remove oil-soaked clothing and launder before reuse. Cleanse skin thoroughly after contact.
The above information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Fiske
Brothers Refining Company. The data on these sheets relates only to the specific material designated herein. Fiske Brothers
Refining Company assumes no legal responsibility for use or reliance upon this data.
Date Prepared: January, 2006
CI-G-07
Prepared by: James R. Kontak

LUBRIPLATE
MATERIAL SAFETY DATA SHEET
Section 1
PRODUCT NAME OR NUMBER
LUBRIPLATE No. 1242, No. 1241, No. 1240
FORMULA
Lithium Soap, Mineral Oil and Additives
GENERIC/CHEMICAL NAME:
Petroleum Lubricating Grease
USDA AUTHORIZATION:
H-2 (1242)
Manufacturer's Name
Fiske Brothers Refining Co.
Address
1500 Oakdale Ave., Toledo, Ohio 43605 - 129 Lockwood St., Newark, NJ 07105
Emergency Telephone Number
1-800-255-3924 - CHEM-TEL (24 hour)
Telephone Number for Information
419-691-2491 - Toledo Office
Section 2 - Hazardous Ingredients/Identity Information
Hazardous Components
Non-hazardous
OSHA PEL
ACGIH TLV
Hazardous Material Identification System (HMIS):
Not a Controlled Product under (WHMIS) - Canada
Other Limits Recommended
Health - 1,
% (optional)
Flammability - 1,
Reactivity - 0
Special Protection: See Section 9
Section 3 - Health Hazard Data
Threshold Limit Value 5 mg/m3 for oil mist in air. OSHA Regulation 29 CFR 1910.1000 - 0.5 mg/m3 for Antimony Compound (as Sb)
Effects of Overexposure Prolonged or repeated skin contact may cause skin irritation. Product contacting the eyes may cause eye irritation.
Human health risks vary from person to person. As a precaution, exposure to liquids, vapors, mists and fumes should be minimized. This
product has a low order of acute oral toxicity, but minute amounts aspirated into the lungs during ingestion may cause mild to severe
pulmonary injury.
Carcinogenicity:
NTP? No
IARC Monographs? No
OSHA Regulated? No
Section 4 - Emergency and First Aid Procedures
EYE CONTACT: Flush with clear water for 15 minutes or until irritation subsides. If irritation persists, consult a physician.
SKIN CONTACT: Remove any contaminated clothing and wash with soap and warm water. If injected by high pressure under skin,
regardless of the appearance or its size, contact a physician IMMEDIATELY. Delay may cause loss of affected part of the body.
INHALATION: Vapor pressure is very low and inhalation at room temperature is not a problem. If overcome by vapor from hot product,
immediately remove from exposure and call a physician.
INGESTION: If ingested, call a physician immediately. Do not induce vomiting.
Section 5 - Fire and Explosion Hazard Data
Flash Point (Method Used)
COC - 475oF
Extinguishing Media
Foam, Dry Chemical, Carbon Dioxide or Water Spray (Fog)
Special Fire Fighting Procedures
Cool exposed containers with water. Use air-supplied breathing equipment for
enclosed or confined spaces.
Do not store or mix with strong oxidants. Empty containers retain residue.
Do not cut, drill, grind, or weld, as they may explode.
Unusual Fire and Explosion Hazards
Flammable Limits
LEL 0.9%
UEL 7.0%
PRODUCT NAME OR NUMBER - LUBRIPLATE No. 1242, No. 1241, No. 1240
Section 6 - Physical/Chemical Characteristics
Boiling Point
>550oF
Specific Gravity (H 2O = 1)
0.90 - 0.94
Vapor Pressure (mm Hg.)
<0.01
Melting Point
Semi-solid
Vapor Density (AIR = 1)
>5
Evaporation Rate
(Butyl Acetate = 1)
<0.01
Solubility in Water
Negligible
Appearance and Odor
Off-white grease with mineral oil odor.
Section 7 - Reactivity Data
Stability
Unstable
Stable
X
Incompatibility (Materials to Avoid)
Conditions to Avoid
N/A
Avoid contact with strong oxidants like liquid chlorine, concentrated oxygen.
Hazardous Decomposition or Byproducts May form SO 2. If incomplete combustion, Carbon Monoxide.
Hazardous Polymerization
May Occur
Will Not Occur X
Conditions to Avoid N/A
Section 8 - Spill or Leak Procedures
Steps to be taken in case material is released or spilled
Scrape up grease, wash remainder with suitable petroleum solvent or add absorbent. Keep petroleum products out of sewers and water
courses. Advise authorities if product has entered or may enter sewers and water courses.
Waste disposal method
Assure conformity with applicable disposal regulations. Dispose of absorbed material at an approved waste disposal facility or site.
SARA/TITLE III, Section 313 Status - Zinc Compounds - < 6%
Antimony Compounds - <3%
Section 9 - Special Protection Information
Respiratory Protection (Specify type)
Normally not needed
Ventilation
Used to capture fumes and vapors
Local Exhaust
Mechanical (General)
Protective Gloves Use oil-resistant gloves, if needed.
Other Protective Equipment
Special N/A
Other N/A
Eye Protection If chance of eye contact, wear goggles.
Use oil-resistant apron, if needed.
Section 10 - Special Precautions
Precautions to be taken in handling and storing
Keep containers closed when not in use. Do not handle or store near heat, sparks, flame, or strong oxidants.
Other Precautions
Remove oil-soaked clothing and launder before reuse. Cleanse skin thoroughly after contact.
The above information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Fiske
Brothers Refining Company. The data on these sheets relates only to the specific material designated herein. Fiske Brothers
Refining Company assumes no legal responsibility for use or reliance upon this data.
Date Prepared: January, 2006
Prepared by: James R. Kontak

LUBRIPLATE
MATERIAL SAFETY DATA SHEET
Section 1
PRODUCT NAME OR NUMBER
LUBRIPLATE EMB
FORMULA
Lithium Soap, Mineral Oil and Additives
GENERIC/CHEMICAL NAME:
Petroleum Lubricating Grease
USDA AUTHORIZATION:
H-2
Manufacturer's Name
Fiske Brothers Refining Co.
Address
1500 Oakdale Ave., Toledo, Ohio 43605 - 129 Lockwood St., Newark, NJ 07105
Emergency Telephone Number
1-800-255-3924 - CHEM-TEL (24 hour)
Telephone Number for Information
419-691-2491 - Toledo Office
Section 2 - Hazardous Ingredients/Identity Information
Hazardous Components
Non-hazardous
OSHA PEL
ACGIH TLV
Hazardous Material Identification System (HMIS):
Not a Controlled Product under (WHMIS) - Canada
Other Limits Recommended
Health - 1,
% (optional)
Flammability - 1,
Reactivity - 0
Special Protection: See Section 9
Section 3 - Health Hazard Data
Threshold Limit Value 5 mg/m3 for oil mist in air. OSHA Regulation 29 CFR 1910.1000 - 0.5 mg/m3 for Antimony Compound (as Sb)
Effects of Overexposure Prolonged or repeated skin contact may cause skin irritation. Product contacting the eyes may cause eye irritation.
Human health risks vary from person to person. As a precaution, exposure to liquids, vapors, mists and fumes should be minimized. This
product has a low order of acute oral toxicity, but minute amounts aspirated into the lungs during ingestion may cause mild to severe
pulmonary injury.
Carcinogenicity:
NTP? No
IARC Monographs? No
OSHA Regulated? No
Section 4 - Emergency and First Aid Procedures
EYE CONTACT: Flush with clear water for 15 minutes or until irritation subsides. If irritation persists, consult a physician.
SKIN CONTACT: Remove any contaminated clothing and wash with soap and warm water. If injected by high pressure under skin,
regardless of the appearance or its size, contact a physician IMMEDIATELY. Delay may cause loss of affected part of the body.
INHALATION: Vapor pressure is very low and inhalation at room temperature is not a problem. If overcome by vapor from hot product,
immediately remove from exposure and call a physician.
INGESTION: If ingested, call a physician immediately. Do not induce vomiting.
Section 5 - Fire and Explosion Hazard Data
Flash Point (Method Used)
COC - 425oF
Extinguishing Media
Foam, Dry Chemical, Carbon Dioxide or Water Spray (Fog)
Special Fire Fighting Procedures
Cool exposed containers with water. Use air-supplied breathing equipment for
enclosed or confined spaces.
Do not store or mix with strong oxidants. Empty containers retain residue.
Do not cut, drill, grind, or weld, as they may explode.
Unusual Fire and Explosion Hazards
Flammable Limits
LEL 0.9%
UEL 7.0%
PRODUCT NAME OR NUMBER - LUBRIPLATE EMB
Section 6 - Physical/Chemical Characteristics
Boiling Point
>550oF
Specific Gravity (H 2O = 1)
0.92
Vapor Pressure (mm Hg.)
<0.01
Melting Point
Semi-solid
Vapor Density (AIR = 1)
>5
Evaporation Rate
(Butyl Acetate = 1)
<0.01
Solubility in Water
Negligible
Appearance and Odor
Yellowish, off-white grease with mineral oil odor.
Section 7 - Reactivity Data
Stability
Unstable
Stable
X
Incompatibility (Materials to Avoid)
Conditions to Avoid
N/A
Avoid contact with strong oxidants like liquid chlorine, concentrated oxygen.
Hazardous Decomposition or Byproducts May form SO 2. If incomplete combustion, Carbon Monoxide.
Hazardous Polymerization
May Occur
Will Not Occur X
Conditions to Avoid N/A
Section 8 - Spill or Leak Procedures
Steps to be taken in case material is released or spilled
Scrape up grease, wash remainder with suitable petroleum solvent or add absorbent. Keep petroleum products out of sewers and water
courses. Advise authorities if product has entered or may enter sewers and water courses.
Waste disposal method
Assure conformity with applicable disposal regulations. Dispose of absorbed material at an approved waste disposal facility or site.
SARA/TITLE III, Section 313 Status - Zinc Compounds - <3%
Antimony Compounds - <3%
Section 9 - Special Protection Information
Respiratory Protection (Specify type)
Normally not needed
Ventilation
Used to capture fumes and vapors
Local Exhaust
Mechanical (General)
Protective Gloves Use oil-resistant gloves, if needed.
Other Protective Equipment
Special N/A
Other N/A
Eye Protection If chance of eye contact, wear goggles.
Use oil-resistant apron, if needed.
Section 10 - Special Precautions
Precautions to be taken in handling and storing
Keep containers closed when not in use. Do not handle or store near heat, sparks, flame, or strong oxidants.
Other Precautions
Remove oil-soaked clothing and launder before reuse. Cleanse skin thoroughly after contact.
The above information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Fiske
Brothers Refining Company. The data on these sheets relates only to the specific material designated herein. Fiske Brothers
Refining Company assumes no legal responsibility for use or reliance upon this data.
Date Prepared: January, 2006
Prepared by: James R. Kontak
file:///C|/Drawing%20Files/MSDS/CI-G-08,%20GLISSEAL%20N%20-%20Vacuum%20Grease.txt
GLISSEAL N - VACUUM GREASE - RED
Material Safety Data Sheet
SECTION I - Material Identity
SECTION II - Manufacturer's Information
SECTION III - Physical/Chemical Characteristics
SECTION IV - Fire and Explosion Hazard Data
SECTION V - Reactivity Data
SECTION VI - Health Hazard Data
SECTION VII - Precautions for Safe Handling and Use
SECTION VIII - Control Measures
SECTION IX - Label Data
SECTION X - Transportation Data
SECTION XI - Site Specific/Reporting Information
SECTION XII - Ingredients/Identity Information
SECTION I - Material Identity
Item Name
Part Number/Trade Name
National Stock Number
CAGE Code
Part Number Indicator
MSDS Number
HAZ Code
GLISSEAL N - VACUUM GREASE - RED
9150L4163532027
12394
A
192784
B
SECTION II - Manufacturer's Information
Manufacturer Name
CINCINNATI INC)
Street
City
State
Country
Zip Code
Emergency Phone
Information Phone
ATOMERGIC CHEMETALS CORP (DIST
222 SHERWOOD AVENUE
FARMINGDALE
NY
US
11735
516-694-9000
516-694-9000
CI-G-08
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MSDS Preparer's Information
Date MSDS Prepared/Revised
Active Indicator
Y
18FEB03
Alternate Vendors
SECTION III - Physical/Chemical Characteristics
Appearance/Odor
Boiling Point
Melting Point
Vapor Pressure
Vapor Density
Specific Gravity
Evaporation Rate
Solubility in Water
Chemical pH
Container Type
Container Pressure Code
Temperature Code
Product State Code
RED GREASE
NR
NR
0.000015
NR
1
NR
INSOLUBLE
NR
R
1
4
L
SECTION IV - Fire and Explosion Hazard Data
Flash Point
300
Flash Point Method
UNK
Lower Explosion Limit
NR
Upper Explosion Limit
NR
Extinguishing Media
NR
Special Fire Fighting Procedures
NONE
Unusual Fire/Explosion Hazards
NONE
SECTION V - Reactivity Data
Stability
YES
Stability Conditions to Avoid
NR
Materials to Avoid
NR
Hazardous Decomposition Products
NONE
CI-G-08
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Hazardous Polymerization
NR
SECTION VI - Health Hazard Data
Route of Entry: Skin
U
Route of Entry: Ingestion
U
Route of Entry: Inhalation
U
Health Hazards - Acute and Chronic
ON THE BASIS OF THE DATA AVAILABLE
TO US, GLISSEAL N IS NOT DANGEROUS WITHING THE MEANING OF THE EEC
DIRECTIVES. ONE SHOULD HOWEVER, OBSERVE THE USUAL PRECAUTIONERY
MESSURES
FOR HANDLING CHEMICALS
Symptoms of Overexposure
NR
Medical Cond. Aggrevated by Exposure NR
Emergency/First Aid Procedures
NR
SECTION VII - Precautions for Safe Handling and Use
Steps if Material Released/Spilled
TAKE UP WITH AN OIL ABSORBENT
MATERIAL
Neutralizing Agent
NR
Waste Disposal Method
DAN BE DISPOSED WITH REGULAR
HOUSEHOLD WASTE
Handling and Storage Precautions
NO SPECIAL PRECAUTIONS FOR
HANDLING AND STORAGE
Other Precautions
NR
SECTION VIII - Control Measures
Respiratory Protection
NA
Ventilation
NR
Protective Gloves
NR
Eye Protection
NA
Other Protective Equipment
NA
Work Hygenic Practices
WASH THOROUGHLY AFTER HANDLING
SECTION IX - Label Data
CI-G-08
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file:///C|/Drawing%20Files/MSDS/CI-G-08,%20GLISSEAL%20N%20-%20Vacuum%20Grease.txt
Protect Eye
Protect Skin
Protect Respiratory
Chronic Indicator
Contact Code
Fire Code
Health Code
React Code
NO
NO
NO
UNKNOWN
UNKNOWN
UNKNOWN
UNKNOWN
UNKNOWN
SECTION X - Transportation Data
SECTION XI - Site Specific/Reporting Information
Volatile Organic Compounds (P/G)
Volatile Organic Compounds (G/L)
0
0
SECTION XII - Ingredients/Identity Information
Ingredient #
Ingredient Name
CAS Number
Proprietary
Percent
Ingredient #
Ingredient Name
CAS Number
Proprietary
Percent
01
PARAFFIN BASED OIL
1003
NO
0
02
SILICON DIOXIDE
1003
NO
0
CI-G-08
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CI-G-09
MATERIAL SAFETY DATA SHEET
Review Date: 03/27/2003
-------------------------------------------------------------------------------SECTION 1
PRODUCT AND COMPANY IDENTIFICATION
-------------------------------------------------------------------------------PRODUCT:
ALVANIA® EP Grease 0
MSDS NUMBER:
57071E - 5
PRODUCT CODE(S):
71123, 7112300001, 7112302120, 7112302400, 7112335203
MANUFACTURER ADDRESS:
SOPUS Products, P.O. Box 4427, Houston, TX.
77210-4427
TELEPHONE NUMBERS
Spill Information: (877) 242-7400
Health Information: (877) 504-9351
MSDS Assistance Number: (877) 276-7285
-------------------------------------------------------------------------------SECTION 2
PRODUCT/INGREDIENTS
-------------------------------------------------------------------------------CAS#
CONCENTRATION
Industrial Grease
Mixture
80 - 89.99 %weight
Mixture
5 - 9.99 %weight
zinc)
Mixture
5 - 9.99 %weight
INGREDIENTS
Highly refined petroleum oil
Proprietary additives (conta
Lithium grease thickener
-------------------------------------------------------------------------------SECTION 3
HAZARDS IDENTIFICATION
-------------------------------------------------------------------------------EMERGENCY OVERVIEW
Appearance & Odor:
Brown, smooth grease. Slight Hydrocarbon Odor.
Health Hazards: No known immediate health hazards. High-pressure injection
under the skin may cause serious damage.
Physical Hazards: No known physical hazards.
NFPA Rating (Health, Fire, Reactivity): 0, 1, 0
Hazard Rating:
Least - 0
Slight - 1
Moderate - 2
High - 3
Extreme - 4
Inhalation:
Inhalation of vapors (generated at high temperatures only) or oil mist may
cause mild irritation of the nose, throat, and respiratory tract.
Eye Irritation:
May be irritating to the eyes causing a burning sensation, redness, swelling
and/or blurred vision.
Skin Contact:
May be irritating to the skin causing a burning sensation, redness and/or
swelling. Release of the material during high-pressure applications may
result in injection under the skin causing possible extensive tissue damage
CI-G-10
which is difficult to heal.
skin contact.
Other adverse effects not expected from brief
Ingestion:
Lubricating greases are generally no more than slightly toxic if swallowed.
Other Health Effects:
Material may release hydrogen sulfide (H2S), a highly toxic and extremely
flammable gas, when heated to 180 Degrees F or higher. H2S can cause
irritation of the eyes and respiratory tract, headache, dizziness, nausea,
vomitting, diarrhea, and pulmonary edema. The odor ("rotten egg") threshold
is 0.02 ppm. Do not depend on sense of smell for warning; H2S rapidly
deadens the sense of smell.
Signs and Symptoms:
Irritation as noted above. Local necrosis is evidenced by delayed onset of
pain and tissue damage a few hours following injection.
Aggravated Medical Conditions:
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure
to this product.
For additional health information, refer to section 11.
-------------------------------------------------------------------------------SECTION 4
FIRST AID MEASURES
-------------------------------------------------------------------------------Inhalation:
Remove victim to fresh air and provide oxygen if breathing is difficult. Get
medical attention. If the victim has difficulty breathing or tightness of the
chest, is dizzy, vomiting or unresponsive, give 100% oxygen with rescue
breathing or CPR as required and transport to the nearest medical facility.
Skin:
Remove contaminated clothing and shoes and wipe excess from skin. Flush skin
with water, then wash with soap and water. If irritation occurs, get medical
attention. Do not reuse clothing until cleaned.
If material is injected
under the skin, transport to the nearest medical facility for additional
treatment. If redness, swelling, pain and/or blisters occur, transport to the
nearest medical facility for additional treatment.
Eye:
Flush eyes with large amounts of water for at least 15 minutes. If redness,
burning, blurred vision or swelling persist, transport to nearest medical
facility for additional treatment.
Ingestion:
Do not induce vomiting. In general, no treatment is necessary unless large
quantities of product are ingested. However, get medical attention. Have
victim rinse mouth out with water, then drink sips of water to remove taste
from mouth. If vomiting occurs spontaneously, keep head below hips to prevent
aspiration.
Note to Physician:
In general, emesis induction is unnecessary in high viscosity, low volatility
products such as oils and greases.
CI-G-10
-------------------------------------------------------------------------------SECTION 5
FIRE FIGHTING MEASURES
-------------------------------------------------------------------------------Flash Point [Method]:
>400 ºF/>204.44 ºC [ Pensky-Martens Closed Cup]
Extinguishing Media:
Material will float and can be re-ignited on surface of water. Use water fog,
foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Do not use a
direct stream of water.
Fire Fighting Instructions:
Do not enter confined fire space without full bunker gear (helmet with face
shield, bunker coats, gloves and rubber boots), including a positive pressure,
NIOSH approved, self-contained breathing apparatus. This material is
non-flammable.
Unusual Fire Hazards:
Material may ignite when preheated.
-------------------------------------------------------------------------------SECTION 6
ACCIDENTAL RELEASE MEASURES
-------------------------------------------------------------------------------Protective Measures:
May burn although not readily ignitable.
Spill Management:
Scoop up excess grease.
Clean area with appropriate cleaner.
Place in container for proper disposal.
Reporting:
CERCLA: Product is covered by EPA's Comprehensive Environmental Response,
Compensation and Liability Act (CERCLA) petroleum exclusion. Releases to air,
land, or water are not reportable under CERCLA (Superfund).
CWA: This product is an oil as defined under Section 311 of EPA's Clean Water
Act (CWA). Spills into or leading to surface waters that cause a sheen must be
reported to the National Response Center, 1-800-424-8802.
-------------------------------------------------------------------------------SECTION 7
HANDLING AND STORAGE
-------------------------------------------------------------------------------Precautionary Measures:
Avoid heat, open flames, including pilot lights, and strong oxidizing agents.
Use explosion-proof ventilation to prevent vapor accumulation. Ground all
handling equipment to prevent sparking. Avoid contact with eyes, skin and
clothing. Wash thoroughly after handling.
Material may release hydrogen sulfide (H2S), a highly toxic and extremely
flammable gas, when heated to 180 Degrees F or higher. H2S may collect in the
headspace of the container.
CI-G-10
Handling:
Wash with soap and water before eating, drinking, smoking, applying cosmetics,
or using toilet. Launder contaminated clothing before reuse. Properly
dispose of contaminated leather articles such as shoes or belts that cannot be
decontaminated. Contaminated leather articles including shoes cannot be
decontaminated and should be destroyed to prevent reuse.
Storage:
Do not store in open or unlabeled containers. Store in a cool, dry place with
adequate ventilation. Keep away from open flames and high temperatures.
Container Warnings:
Keep containers closed when not in use. Containers, even those that have been
emptied, can contain explosive vapors. Do not cut, drill, grind, weld or
perform similar operations on or near containers.
-------------------------------------------------------------------------------SECTION 8
EXPOSURE CONTROLS/PERSONAL PROTECTION
-------------------------------------------------------------------------------Li-Hydroxystearate
Oil mist, mineral
Oil mist, mineral
ACGIH TLV TWA: 10 mg/m3
ACGIH TLV TWA: 5 mg/m3 STEL: 10 mg/m3
OSHA PEL TWA: 5 mg/m3
EXPOSURE CONTROLS
Adequate ventilation to control airborne concentrations.
PERSONAL PROTECTION
Personal protective equipment (PPE) selections vary based on potential
exposure conditions such as handling practices, concentration and ventilation.
Information on the selection of eye, skin and respiratory protection for use
with this material is provided below.
Eye Protection:
Chemical Goggles, or Safety glasses with side shields
Skin Protection:
Use protective clothing which is chemically resistant to this material.
Selection of protective clothing depends on potential exposure conditions and
may include gloves, boots, suits and other items. The selection(s) should
take into account such factors as job task, type of exposure and durability
requirements.
Published literature, test data and/or glove and clothing manufacturers
indicate the best protection is provided by:
Neoprene, or Nitrile Rubber
Respiratory Protection:
If engineering controls do not maintain airborne concentrations to a level
which is adequate to protect worker health, an approved respirator must be
worn. Respirator selection, use and maintenance should be in accordance with
the requirements of the OSHA Respiratory Protection Standard, 29 CFR 1910.134.
Types of respirator(s) to be considered in the selection process include:
For Vapors: Air Purifying, R or P style prefilter & organic cartridge,
NIOSH approved respirator. Self-contained breathing apparatus for use in
CI-G-10
environments with unknown concentrations or emergency situations.
-------------------------------------------------------------------------------SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
-------------------------------------------------------------------------------Appearance & Odor: Brown, smooth grease. Slight Hydrocarbon Odor.
Substance Chemical Family:
Lubricants
Appearance:
Brown, smooth grease.
Drop Point:
Flash Point:
> 350 ºF
> 400 ºF [Pensky-Martens Closed Cup]
Solubility (in Water):
Specific Gravity:
Stability:
Negligible
> 0.9
Stable
-------------------------------------------------------------------------------SECTION 10
REACTIVITY AND STABILITY
-------------------------------------------------------------------------------Stability:
Material is stable under normal conditions.
Conditions to Avoid:
Avoid heat and open flames.
Materials to Avoid:
Avoid contact with strong oxidizing agents.
Hazardous Decomposition Products:
Thermal decomposition products are highly dependent on combustion conditions.
A complex mixture of airborne solids, liquids and gases will evolve when this
material undergoes pyrolysis or combustion. 4-Vinylcyclohexene, Carbon
Monoxide, Carbon Dioxide, Hydrogen Sulfide, Nitrogen Oxidesand other
unidentified organic compounds may be formed upon combustion.
-------------------------------------------------------------------------------SECTION 11
TOXICOLOGICAL INFORMATION
-------------------------------------------------------------------------------Acute Toxicity
Dermal LD50 >5.0 g/kg(Rabbit)
OSHA: Non-Toxic Based on components(s)
Oral LD50 >5.0 g/kg(Rat)
OSHA: Non-Toxic Based on components(s)
Carcinogenicity Classification
Industrial Grease
NTP: No IARC: No ACGIH: No OSHA: No
--------------------------------------------------------------------------------
CI-G-10
SECTION 12
ECOLOGICAL INFORMATION
-------------------------------------------------------------------------------Environmental Impact Summary:
There is no ecological data available for this product. However, this product
is an oil. It is persistent and does not readily biodegrade. However, it
does not bioaccumulate.
-------------------------------------------------------------------------------SECTION 13
DISPOSAL CONSIDERATIONS
-------------------------------------------------------------------------------RCRA Information:
Under RCRA, it is the responsibility of the user of the material to determine,
at the time of the disposal, whether the material meets RCRA criteria for
hazardous waste. This is because material uses, transformations, mixtures,
processes, etc. may affect the classification. Refer to the latest EPA, state
and local regulations regarding proper disposal.
-------------------------------------------------------------------------------SECTION 14
TRANSPORT INFORMATION
-------------------------------------------------------------------------------US Department of Transportation Classification
This material is not subject to DOT regulations under 49 CFR Parts 171-180.
Oil: This product is an oil under 49CFR (DOT) Part 130. If shipped by rail or
highway in a tank with a capacity of 3500 gallons or more, it is subject to
these requirements. Mixtures or solutions containing 10% or more of this
product may also be subject to this rule.
International Air Transport Association
Not regulated under IATA rules.
International Maritime Organization Classification
Not regulated under International Maritime Organization rules.
-------------------------------------------------------------------------------SECTION 15
REGULATORY INFORMATION
-------------------------------------------------------------------------------FEDERAL REGULATORY STATUS
OSHA Classification:
Under normal conditions of use or in a foreseeable emergency, this product
does not meet the definition of a hazardous chemical when evaluated according
to the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
Ozone Depleting Substances (40 CFR 82 Clean Air Act):
This material does not contain nor was it directly manufactured with any Class
CI-G-10
I or Class II ozone depleting substances.
Superfund Amendment & Reauthorization Act (SARA) Title III:
There are no components in this product on the SARA 302 list.
SARA Hazard Categories (311/312):
Immediate Health:YES
Delayed Health:NO
Reactivity:NO
Fire:NO
Pressure:NO
SARA Toxic Release Inventory (TRI) (313):
There are no components in this product on the SARA 313 list.
Toxic Substances Control Act (TSCA) Status:
All component(s) of this material is(are) listed on the EPA/TSCA Inventory of
Chemical Substances.
This product may be subject to export notification under TSCA Section 12(b);
Contains: Ethanol, 2-[2-(2-ethoxyethoxy)ethoxy]Other Chemical Inventories:
Component(s) of this material is (are) listed on the Australian AICS,
Canadian DSL, Chinese Inventory, European EINECS, Korean Inventory,
Philippines PICCS,
State Regulation
The following chemicals
product specific health
be applicable for state
requirements you should
are specifically listed by individual states; other
and safety data in other sections of the MSDS may also
requirements. For details on your regulatory
contact the appropriate agency in your state.
-------------------------------------------------------------------------------SECTION 16
OTHER INFORMATION
-------------------------------------------------------------------------------Revision#: 5
Review Date: 03/27/2003
Revision Date: 03/27/2003
Revisions since last change (discussion): This Material Safety Data Sheet
(MSDS) has been newly reviewed to fully comply with the guidance contained in
the ANSI MSDS standard (ANSI Z400.1-1998).
We encourage you to take the
opportunity to read the MSDS and review the information contained therein.
-------------------------------------------------------------------------------SECTION 17
LABEL INFORMATION
-------------------------------------------------------------------------------READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF
PRODUCT. THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) FOR USE IN THE WORKPLACE. THIS LABEL
IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED FOR SALE TO CONSUMERS AND
MAY NOT CONFORM WITH THE REQUIREMENTS OF THE CONSUMER PRODUCT SAFETY ACT OR
OTHER RELATED REGULATORY REQUIREMENTS.
PRODUCT CODE(S):
71123, 7112300001, 7112302120, 7112302400, 7112335203
ALVANIA® EP Grease 0
CI-G-10
CAUTION!
MAY CAUSE SKIN AND EYE IRRITATION. PROLONGED OR REPEATED SKIN CONTACT MAY
CAUSE OIL ACNE OR DERMATITIS. HIGH-PRESSURE INJECTION UNDER SKIN MAY CAUSE
SERIOUS DAMAGE.
Precautionary Measures:
Avoid prolonged or repeated contact with eyes, skin and clothing. Avoid
breathing of vapors, fumes, or mist. Use only with adequate ventilation.
Wash thoroughly after handling.
FIRST AID
Inhalation: Remove victim to fresh air and provide oxygen if breathing is
difficult. Get medical attention. If the victim has difficulty breathing or
tightness of the chest, is dizzy, vomiting or unresponsive, give 100% oxygen
with rescue breathing or CPR as required and transport to the nearest medical
facility.
Skin Contact: Remove contaminated clothing and shoes and wipe excess from
skin. Flush skin with water, then wash with soap and water. If irritation
occurs, get medical attention. Do not reuse clothing until cleaned.
If
material is injected under the skin, transport to the nearest medical facility
for additional treatment. If redness, swelling, pain and/or blisters occur,
transport to the nearest medical facility for additional treatment.
Eye Contact: Flush eyes with large amounts of water for at least 15 minutes.
If redness, burning, blurred vision or swelling persist, transport to nearest
medical facility for additional treatment.
Ingestion: Do not induce vomiting. In general, no treatment is necessary
unless large quantities of product are ingested. However, get medical
attention. If vomiting occurs spontaneously, keep head below hips to prevent
aspiration. Have victim rinse mouth out with water, then drink sips of water
to remove taste from mouth.
FIRE
In case of fire,
Use water fog, 'alcohol foam', dry chemical or carbon
dioxide (CO2) to extinguish flames. Do not use a direct stream of water.
Material will float and can be re-ignited on surface of water.
SPILL OR LEAK
Scoop up excess grease. Clean area with appropriate cleaner.
CONTAINS: Highly refined petroleum oils, Mixture; Proprietary additives
(contains <1% zinc), Mixture; Lithium grease thickener, Mixture
NFPA Rating (Health, Fire, Reactivity):
0, 1, 0
TRANSPORTATION
US Department of Transportation Classification
This material is not subject to DOT regulations under 49 CFR Parts 171-180.
Oil: This product is an oil under 49CFR (DOT) Part 130. If shipped by rail or
highway in a tank with a capacity of 3500 gallons or more, it is subject to
these requirements. Mixtures or solutions containing 10% or more of this
product may also be subject to this rule.
CAUTION:
CI-G-10
Misuse of empty containers can be hazardous.
Empty containers can
be hazardous if used to store toxic, flammable, or reactive materials.
Cutting or welding of empty containers might cause fire, explosion or toxic
fumes from residues. Do not pressurize or expose to open flames or heat.
Keep container closed and drum bungs in place.
Name and Address
SOPUS Products
P.O. Box 4427
Houston, TX 77210-4427
ADMINISTRATIVE INFORMATION
MANUFACTURER ADDRESS: SOPUS Products, P.O. Box 4427, Houston, TX.
77210-4427
THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE TO
US AT THIS TIME, AND IS BELIEVED TO BE ACCURATE BASED UPON THAT : IT IS
PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT, FOR PURPOSE OF HAZARD
COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE PRODUCT PERFORMANCE
INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE WITH
RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED HEREIN.
YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY, PROCESS, USE OR
DISTRIBUTE, AND ARE ENCOURAGED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH
SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN.
TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT
TO THE PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE APPROPRIATE
GOVERNMENT AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH MATTERS, OR BE
RESPONSIBLE FOR ANY INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. THE
UNDERLYING DATA, AND THE INFORMATION PROVIDED HEREIN AS A RESULT OF THAT DATA,
IS THE PROPERTY OF SOPUS PRODUCTS AND IS NOT TO BE THE SUBJECT OF SALE OR
EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF SOPUS PRODUCTS.
44476-11213-100R-10/11/2005
CI-G-10
DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 1 of 7
DOW CORNING(R) 111 VALVE LUBRICANT & SEALANT
1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY
24 Hour Emergency Telephone:
Customer Service:
Product Disposal Information:
CHEMTREC:
Dow Corning Corporation
South Saginaw Road
Midland, Michigan 48686
MSDS No.: 01889834
(989) 496-5900
(989) 496-6000
(989) 496-6315
(800) 424-9300
Revision Date: 2002/01/22
Generic Description:
Physical Form:
Color:
Odor:
Silicone grease.
Grease
Translucent white
Odorless
NFPA Profile: Health
0 Flammability
1 Instability/Reactivity
0
Note: NFPA = National Fire Protection Association
2. OSHA HAZARDOUS COMPONENTS
None present. This is not a hazardous material as defined in the OSHA Hazard Communication Standard.
3. EFFECTS OF OVEREXPOSURE
Acute Effects
Eye:
Direct contact may cause temporary redness and discomfort.
Skin:
No significant irritation expected from a single short-term exposure.
Inhalation:
No significant effects expected from a single short-term exposure.
Oral:
Low ingestion hazard in normal use.
Prolonged/Repeated Exposure Effects
Skin:
No known applicable information.
Inhalation:
No known applicable information.
Oral:
No known applicable information.
Signs and Symptoms of Overexposure
No known applicable information.
Medical Conditions Aggravated by Exposure
No known applicable information.
The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar
compositions, component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology
information.
CI-G-12
DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 2 of 7
DOW CORNING(R) 111 VALVE LUBRICANT & SEALANT
4. FIRST AID MEASURES
Eye:
Immediately flush with water.
Skin:
No first aid should be needed.
Inhalation:
No first aid should be needed.
Oral:
No first aid should be needed.
Comments:
Treat symptomatically.
5. FIRE FIGHTING MEASURES
Flash Point:
> 214 °F / > 101.1 °C (Closed Cup)
Autoignition
Temperature:
Not determined.
Flammability Limits in Air: Not determined.
Extinguishing Media:
On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide
(CO2), dry chemical or water spray. Water can be used to cool fire exposed containers.
Fire Fighting Measures:
Self-contained breathing apparatus and protective clothing should be worn in fighting
large fires involving chemicals. Determine the need to evacuate or isolate the area
according to your local emergency plan. Use water spray to keep fire exposed
containers cool.
Unusual Fire Hazards:
None.
Hazardous Decomposition Products
Thermal breakdown of this product during fire or very high heat conditions may evolve the following hazardous
decomposition products: Silicon dioxide. Carbon oxides and traces of incompletely burned carbon compounds.
Formaldehyde.
6. ACCIDENTAL RELEASE MEASURES
CI-G-12
DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 3 of 7
DOW CORNING(R) 111 VALVE LUBRICANT & SEALANT
Containment/Clean up:
Determine whether to evacuate or isolate the area according to your local emergency
plan. Observe all personal protection equipment recommendations described in
Sections 5 and 8. For large spills, provide diking or other appropriate containment to
keep material from spreading. If diked material can be pumped, store recovered
material in appropriate container. Clean up remaining materials from spill with suitable
absorbant. Clean area as appropriate since some silicone materials, even in small
quantities, may present a slip hazard. Final cleaning may require use of steam,
solvents or detergents. Dispose of saturated absorbant or cleaning materials
appropriately, since spontaneous heating may occur. Local, state and federal laws and
regulations may apply to releases and disposal of this material, as well as those
materials and items employed in the cleanup of releases. You will need to determine
which federal, state and local laws and regulations are applicable. Sections 13 and 15
of this MSDS provide information regarding certain federal and state requirements.
Note: See section 8 for Personal Protective Equipment for Spills. Call Dow Corning Corporation, (989) 496-5900,
if additional information is required.
7. HANDLING AND STORAGE
Use with adequate ventilation. Avoid eye contact.
Use reasonable care and store away from oxidizing materials.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Component Exposure Limits
There are no components with workplace exposure limits.
Engineering Controls
Local Ventilation:
General Ventilation:
None should be needed.
Recommended.
Personal Protective Equipment for Routine Handling
Eyes:
Use proper protection - safety glasses as a minimum.
Skin:
Washing at mealtime and end of shift is adequate.
Suitable Gloves:
No special protection needed.
Inhalation:
No respiratory protection should be needed.
Suitable Respirator:
None should be needed.
Personal Protective Equipment for Spills
Eyes:
Use proper protection - safety glasses as a minimum.
Skin:
Washing at mealtime and end of shift is adequate.
CI-G-12
DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 4 of 7
DOW CORNING(R) 111 VALVE LUBRICANT & SEALANT
Inhalation/Suitable
Respirator:
No respiratory protection should be needed.
Precautionary Measures: Avoid eye contact. Use reasonable care.
Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may
require added precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical Form:
Color:
Odor:
Specific Gravity @ 25°C:
Viscosity:
Freezing/Melting Point:
Boiling Point:
Vapor Pressure @ 25°C:
Vapor Density:
Solubility in Water:
pH:
Volatile Content:
Grease
Translucent white
Odorless
1.1
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Note: The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing
specifications.
10. STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Hazardous
Polymerization:
Conditions to Avoid:
Hazardous polymerization will not occur.
Materials to Avoid:
Oxidizing material can cause a reaction.
None.
11. TOXICOLOGICAL INFORMATION
Special Hazard Information on Components
No known applicable information.
12. ECOLOGICAL INFORMATION
Environmental Fate and Distribution
Complete information is not yet available.
Environmental Effects
Complete information is not yet available.
CI-G-12
DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 5 of 7
DOW CORNING(R) 111 VALVE LUBRICANT & SEALANT
Fate and Effects in Waste Water Treatment Plants
Complete information is not yet available.
Hazard Parameters (LC50 or EC50)
Acute Aquatic Toxicity (mg/L)
Acute Terrestrial Toxicity
Ecotoxicity Classification Criteria
High
Medium
<=1
>1 and <=100
<=100
>100 and <= 2000
Low
>100
>2000
This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993.
This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information
presented in the section concerning the overall ecological safety of this material.
13. DISPOSAL CONSIDERATIONS
RCRA Hazard Class (40 CFR 261)
When a decision is made to discard this material, as received, is it classified as a hazardous waste? No
State or local laws may impose additional regulatory requirements regarding disposal.
Call Dow Corning Corporate Environmental Management, (989) 496-6315, if additional information is required.
14. TRANSPORT INFORMATION
DOT Road Shipment Information (49 CFR 172.101)
Not subject to DOT.
Ocean Shipment (IMDG)
Not subject to IMDG code.
Air Shipment (IATA)
Not subject to IATA regulations.
Call Dow Corning Transportation, (989) 496-8577, if additional information is required.
15. REGULATORY INFORMATION
Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
TSCA Status:
All chemical substances in this material are included on or exempted from listing on the
TSCA Inventory of Chemical Substances.
EPA SARA Title III Chemical Listings
Section 302 Extremely Hazardous Substances:
None.
CI-G-12
DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 6 of 7
DOW CORNING(R) 111 VALVE LUBRICANT & SEALANT
Section 304 CERCLA Hazardous Substances:
None.
Section 312 Hazard Class:
Acute: No
Chronic: No
Fire: No
Pressure: No
Reactive: No
Section 313 Toxic Chemicals:
None present or none present in regulated quantities.
Supplemental State Compliance Information
California
Warning: This product contains the following chemical(s) listed by the State of California under the Safe Drinking
Water and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or
other reproductive harm.
None known.
Massachusetts
Wt %
Component Name
7.0 - 13.0
Silica, amorphous
Wt %
Component Name
63148-62-9
> 60.0
Polydimethylsiloxane
7631-86-9
7.0 - 13.0
Silica, amorphous
70131-67-8
7.0 - 13.0
Dimethyl siloxane, hydroxy-terminated
CAS Number
7631-86-9
New Jersey
CAS Number
Pennsylvania
CAS Number
Wt %
Component Name
63148-62-9
> 60.0
Polydimethylsiloxane
7631-86-9
7.0 - 13.0
CI-G-12
Silica, amorphous
DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 7 of 7
DOW CORNING(R) 111 VALVE LUBRICANT & SEALANT
70131-67-8
7.0 - 13.0
Dimethyl siloxane, hydroxy-terminated
16. OTHER INFORMATION
Prepared by: Dow Corning Corporation
These data are offered in good faith as typical values and not as product specifications. No warranty, either
expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are
believed to be generally applicable. However, each user should review these recommendations in the specific
context of the intended use and determine whether they are appropriate.
(R) indicates Registered Trademark
CI-G-12
Material Safety Data Sheet
May be used to comply with
OSHA's Hazard Communication Standard
29 CFR 1910.1200. Standard must be consulted
for specific requirements
U.S. Department of Labor
Occupational Safety and Health Administration
(Non-Mandatory Form)
Form Approved
OMB No. 1218-0072
IDENTITY (as used on Label and List)
Note: Blank spaces are not permitted. If any item is
not applicable, or no information is available, the
space must be marked to indicate that.
SUPER LUBE GREASE
Part Numbers- 82340, 21010, 21030, 21036, 41150, 41160
41050, 41030, 41120, 41140, 21013, 21015, 11520
SECTION I
Manufacturer's Name: SYNCO CHEMICAL CORPORATION
Address:
24 DaVINCI DRIVE
BOHEMIA, NY 11716
Emergency Telephone Number:
800-424-9300
Telephone Number for Information: 631-567-5300
Date Prepared: January 1, 2005
Signature of Preparer (Optional):
SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION
Hazardous Components
(Specific Chemical/Identity; Common Name(s)
OSHA PEL
ACGIH TLV
SYNTHETIC HYDROCARBON
HYDRO TREATED POLYMER
ANTI-OXIDANT
FUMED SILICA
THERMAL STABILIZER
POLYTETRAFLUORETHYLENE
POLYGLYCOL
PROPRIETARY ADDITIVES
CAS# 68037-01-4
CAS# 8042-47-5
CAS# 41484-35-9
CAS# 68611-44-9
CAS# 68648-89-5
CAS# 9002-84-0
CAS# 025322-69-4
Recommended Percentages
70-80%
10-20%
.5-2%
7-10%
3-5%
.5-2%
1-2%
.25 -1%
ALL INGREDIENTS ARE TSCA LISTED
SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS
Boiling Point
Vapor Pressure (mm Hg.)
Vapor Density (AIR = 1)
Solubility in Water
Appearance and Odor
N/A
Specific Gravity (H2O = 1)
0.87 + 0.02
N/E
Melting Point
N/A
N/E
Evaporation Rate (Butyl Acetate = 1)
N/E
Not Soluble in Water
Translucent White to Slightly Yellow, Slight Odor
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
Flash Point (Method used)
>428°F (220°C) COC Flammable Limits: N/A LEL: N/E
UEL: N/E
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam
Special Fire Fighting Procedures: Self-contained respiratory protection should be provided for fighting fires in confined
areas.
Unusual Fire and Explosion Hazards: None Known
CI-G-13
SUPER LUBE GREASE, page 2
SECTION V - REACTIVITY DATA
Unstable
Stable: YES
Stability:
Conditions to Avoid: None Known
Incompatibility (materials to avoid): May React with strong oxidizing agents.
Hazardous Decomposition or Byproducts: Burning may produce carbon monoxide.
May occur
Will not occur: YES
Hazardous
Polymerization:
Conditions to Avoid: None Known
SECTION VI - HEALTH HAZARD DATA
Route(s) of Entry:
INHALATION?
SKIN? YES
INGESTION? YES
Health Hazards (Acute and Chronic): No Evidence of adverse effect from available information on swallowing. SKIN
ABSORBTION and INHALATION: May cause slight irritation in contact with skin and eyes.
Carcinogenicity:
NTP?
Not Listed
IARC MONOGRAPHS?
Not Listed
OSHA REGULATIONS?
Not Listed
Signs and Symptoms of Exposure: Contact with Eye may result in slight irritation. Prolonged or repeated skin contact may
cause mild irritation.
Medical Conditions Generally Aggravated by Exposure: N/E
Emergency and First Aid Procedures: SKIN: Remove by wiping and wash with soap and water. EYES: Wash with
copious amounts of water.
SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE
Steps to be Taken in Case Material is Released or Spilled: Spills should be absorbed or scraped up.
Waste Disposal Method: Use method outlined in local EPA and Governmental Regulations. Contact your local EPA office.
Precautions to be Taken in Handling and Storage: Good manufacturing practices should be followed in handling and
storage.
Other Precautions: Surface subject to spills with this product can become slippery.
SECTION VIII - CONTROL MEASURES
Respiratory Protection (Specify Type): None Required
Ventilation
Local Exhaust:
N/A
Mechanical (General) N/A
Special: N/A
Other: N/A
Protective Gloves: None under Normal Use
Eye Protection: None under Normal Use
Other Protective Clothing or Equipment: None under Normal Use
Work Hygienic Practices: Normal Precautions common to good manufacturing practices should be followed.
HMIS CODES
FIRE:
HEALTH:
REACTANCE:
OTHER:
CI-G-13
1
0
0
0
SLG.960627.2
MATERIAL SAFETY DATA SHEET
S00100
01 00
===========================================================================
Section 1 −− PRODUCT AND COMPANY IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT NUMBER
HMIS CODES
Health
2*
S00100
Flammability
4
Reactivity
0
PRODUCT NAME
SPRAYON* White Lithium Lube
MANUFACTURER’S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN−WILLIAMS COMPANY
(216) 566−2917
Consumer Group − Industrial
Cleveland, OH 44115
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
24−JAN−06
(800) 251−2486
===========================================================================
Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
9
74−98−6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
21
106−97−8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
20
110−54−3 Hexane
ACGIH TLV
50 ppm
127 mm
OSHA PEL
50 ppm
14
107−83−5 Isohexane Isomers
ACGIH TLV
500 ppm
317 mm
ACGIH TLV
1000 ppm STEL
OSHA PEL
500 ppm
OSHA PEL
1000 ppm STEL
26
64742−52−5 Heavy Naphthenic Petroleum Oil
ACGIH TLV
5 mg/m3 as Mist
OSHA PEL
5 mg/m3 as Mist
5
64742−53−6 Highly refined Naphthenic Oil
ACGIH TLV
5 mg/m3 as Mist
OSHA PEL
5 mg/m3 as Mist
1
110−82−7 Cyclohexane
ACGIH TLV
100 ppm
100 mm
OSHA PEL
300 ppm
2
1314−13−2 Zinc Oxide
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
Continued on page 2
CI-G-14
S00100
page 2
===========================================================================
Section 3 −− HAZARDS IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
===========================================================================
Section 4 −− FIRST AID MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
EYES:
Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re−use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 −− FIRE FIGHTING MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
FLASH POINT
LEL
UEL
Propellant < 0 F
1.0
9.5
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self−contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build−up and possible autoignition or explosion when exposed to
extreme heat.
Continued on page 3
CI-G-14
S00100
page 3
===========================================================================
Section 6 −− ACCIDENTAL RELEASE MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 −− HANDLING AND STORAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated − Do not
smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
===========================================================================
Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
Continued on page 4
CI-G-14
S00100
page 4
===========================================================================
Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT WEIGHT
5.75 lb/gal
688 g/l
SPECIFIC GRAVITY
0.69
BOILING POINT
<0 − 179 F
<−18 − 81 C
MELTING POINT
Not Available
VOLATILE VOLUME
72 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical)
Volatile Weight 65.00 % Less Water and Federally Exempt Solvents
===========================================================================
Section 10 −− STABILITY AND REACTIVITY
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITY −− Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 −− TOXICOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Prolonged and repeated exposure to Hexane may cause damage to nerve
tissue of the arms and legs (peripheral neuropathy), resulting in muscular
weakness and loss of sensation. This effect may be increased by the
presence of Methyl Ethyl Ketone.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
TOXICOLOGY DATA
Continued on page 5
CI-G-14
S00100
page 5
===========================================================================
CAS No.
Ingredient Name
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
74−98−6
Propane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
106−97−8
Butane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
110−54−3
Hexane
LC50
RAT
4HR
Not Available
LD50
RAT
28700
mg/kg
107−83−5
Isohexane Isomers
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
64742−52−5
Heavy Naphthenic Petroleum Oil
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
64742−53−6
Highly refined Naphthenic Oil
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
110−82−7
Cyclohexane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
1314−13−2
Zinc Oxide
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
===========================================================================
Section 12 −− ECOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 −− DISPOSAL CONSIDERATIONS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
===========================================================================
Section 14 −− TRANSPORT INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No data available.
===========================================================================
Section 15 −− REGULATORY INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
Continued on page 6
CI-G-14
S00100
page 6
===========================================================================
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
110−54−3 Hexane
20
110−82−7 Cyclohexane
1
Zinc Compound
2
1.4
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 −− OTHER INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.
The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.
CI-G-14
CAMBRIDGE MILL PRODUCTS, INC.; 3049 ALLIANCE RD. N.W; MALVERN, OH 44644 PH: 330-863-1121
MATERIAL SAFETY DATA INFORMATION
CMP 91S High Vacuum Silicone Grease
HMIS RATING
Health: 1
Flammability: 1
Reactivity: 0
Special: X
SECTION 1 -- LOCATION
Location:
Telephone:
Date Prepared:
3049 Alliance Road N.W.
Malvern, Ohio 44644
330-863-1121
January 1, 2006
SECTION II -- HAZARDOUS INGREDIENTS/IDENTITY
Hazardous Component(s) Chemical and Common Name(s)... Blended Silicone Grease
CAS No.
63148-62-9
112945-52-5
93%
7%
Silicone
Synthetic Amorphous Silicon Dioxide, Crystalline Free
To the best of our knowledge, the above listed component(s) is not hazardous according to OSHA (1910.1200) or one or more State
Right-to-Know lists.
SECTION III -- PHYSICAL & CHEMICAL CHARACTERISTICS
Appearance and Odor:
Specific Gravity @ 22 (C):
Vapor Pressure @ 25 (C):
Vapor Density (Air=1):
Solubility in Water:
Reactivity in Water:
Melting Point:
Translucent White; Mild Odor
.97
Not Applicable
Not Applicable
Insoluble
Not Applicable
Not Applicable
SECTION IV -- FIRE & EXPLOSION DATA
Flash Point:
Flammable Limits (%):
Extinguishing Media:
>625˚ (F) 329˚ (C)
No Data Available
Water Fog, Carbon Dioxide, Dry Chemical, Foam
Method Used: C.O.C.
Special Fire Fighting Procedures: For fires involving this material, do not enter any enclosed or confined fire space without proper
protective equipment, including self-contained breathing apparatus.
Unusual Fire and Explosion Hazards: Do not weld, heat, or drill container. Residue may ignite with explosive violence if heated
sufficiently.
THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESSED OR IMPLIED, IS MADE.
Page 1
CI-G-15
CAMBRIDGE MILL PRODUCTS, INC.; 3049 ALLIANCE RD. N.W; MALVERN, OH 44644 PH: 330-863-1121
SECTION V -- PHYSICAL HAZARDS (REACTIVITY DATA)
Stability:
Conditions to Avoid:
Hazardous Polymerization:
Incompatibility (Materials to Avoid):
Hazardous Decomposition Products:
Product is stable under normal conditions.
None known at this time.
Will not occur.
Oxidizing materials can cause a reaction.
Carbon Monoxide, Carbon Dioxide, Formaldehyde, Silicon Dioxide.
SECTION VI -- HEALTH HAZARDS
Eyes:
May cause temporary discomfort.
Skin:
Single, prolonged exposure causes no known adverse affects.
Inhalation:
No irritation to nose or throat expected. No injury is likely from relatively short exposure.
Ingestion:
Amounts transferred to the mouth by fingers, etc., during normal operations should not cause injury.
Medical Conditions Generally Aggravated by Exposure: No known adverse chronic health effects, but unnecessary exposure to any
chemical should be avoided. This product, as with any chemical, may enhance allergic conditions on certain people. We do
not know of any medical conditions that may be aggravated by exposure to this product.
Chemical Listed as Carcinogen or Potential Carcinogen:
IARC Monographs: No
OSHA: No.
National Toxicology Program: No
Routes of Entry
Inhalation:
If respiratory discomfort or irritation occurs, move person to fresh air.
Eyes:
Flush eyes with cool water for 15 minutes. Seek Medical attention if irritation persists.
Skin:
Wipe off and wash thoroughly with soap and water.
Ingestion:
None known.
SECTION VII -- SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES
Precautions to be Taken in Handling and Storage: Minimum feasible handling temperatures should be maintained. Periods of exposure to
high temperature should be minimized. Water contamination should be avoided.
Other Precautions: At elevated temperatures, this product is sensitive to contamination. If this product becomes contaminated with strong
acids, bases, or some metallic compounds and oxidizing agents, the flash point and viscosity may change and should be re-determined.
Steps to be Taken in Case of Release or Spill: Wipe up or soak up in an inert material and put in a container for disposal.
Waste Disposal Methods (Consult Federal, State, Local Regulations): Under RCRA, it is the responsibility of the user of products to
determine at the time of disposal whether product meets RCRA criteria for hazardous waste. This is because uses, transformations,
mixture, processes, etc., may render the resulting material hazardous.
THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESSED OR IMPLIED, IS MADE.
Page 2
CI-G-15
CAMBRIDGE MILL PRODUCTS, INC.; 3049 ALLIANCE RD. N.W; MALVERN, OH 44644 PH: 330-863-1121
SECTION VIII -- SPECIAL PROTECTION INFORMATION/CONTROL MEASURES
Respiratory Protection:
None required if exposures are within permissible concentrations of 5.0mg/m3 of air for mineral oil mist
averaged over an eight-hour daily exposure (ACGIH 1984-85).
Ventilation:
Normal.
Protective Gloves:
Impervious gloves when prolonged contact cannot be avoided.
Eye Protection:
Chemical type goggles/face shield.
Other Protective Equipment:
None considered necessary at this time.
Work/Hygienic Practices:
Employees should exercise reasonable personal cleanliness.
Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for
particular uses are beyond our control; all risks of use of the product are therefore assumed by the user and we expressly disclaim all
warranties of every kind and nature, including warranties of merchantability and fitness for a particular purpose in respect to the
use or suitability of the product. Nothing is intended as a recommendation for uses which infringe valid patents or as extending license
under valid patents. Appropriate warnings and safe handling procedures should be provided to handlers and users.
ATTENTION:
Misuse of empty containers can be hazardous. Empty containers can be hazardous if used to store toxic, flammable,
or reactive materials. Cutting or welding of empty containers might cause fire, explosion or toxic fumes from
residues. Do not pressurize or expose to open flame or heat. Keep container closed and drum bungs in place.
REGULATORY INFORMATION:
D.O.T. SHIPPING NAME:
D.O.T. HAZARD CLASS:
D.O.T. IDENTIFICATION NUMBER:
NOT APPLICABLE
NOT APPLICABLE
NOT APPLICABLE
THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESSED OR IMPLIED, IS MADE.
Page 3
CI-G-15
NYOGEL 773A
Product: 773A
Revision Date: 2003/02/10
Section 1 : PRODUCT AND COMPANY IDENTIFICATION
Manufacturer: Nye Lubricants, Inc.
12 Howland Road
Fairhaven, MA 02719 U.S.A.
Manufacturer emergency phone Chemtrec* 800−424−9300.
number: 508−996−6721 (8:00AM − 5:00PM ET weekdays).
Product name: Nyogel 773A.
Chemical family: Lubricating grease.
HMIS
H 1
F 1
R 0
PPE Sec. 8
Section 2 : INGREDIENT INFORMATION
C.A.S.
Conc% wgt/wgt
Ingredient Name
OSHA−PEL TWA
OSHA−PEL STEL
ACGIH−TLV TWA
ACGIH−TLV STEL
NIOSH REL TWA
NIOSH REL STEL
NIOSH IDLH
OIL MIST
5 MG/M3
NOT AVAILABLE
5 MG/M3
NOT AVAILABLE
5 MG/M3
10 MG/M3
2500 MG/M3
Section 2A: ADDITIONAL INGREDIENT INFORMATION
Note: Product formulation is Proprietary.
No ingredients are known to be hazardous under normal usage.
Section 3 : HAZARD IDENTIFICATION
Emergency overview: May irritate eyes. Prolonged or repeated skin contact may cause irritation. Inhalation of oil
mist or vapors from material at high temperatures may irritate respiratory passages.
Route of entry: Skin contact, eye contact, inhalation and ingestion.
Effects of acute exposure
Eye contact: May cause irritation.
Skin contact: May cause irritation on prolonged or repeated contact.
Inhalation: Oil mist and vapors at high temperatures may irritate respiratory passages.
Ingestion: May cause gastro−intestinal irritation.
Effects of chronic exposure: See effects of acute exposure.
Carcinogenic effects: IARC, NTP, and OSHA do not list this product or its ingredients as carcinogens.
Medical conditions aggravated by
None known.
exposure:
Target organs: Respiratory passages at high temperatures, eyes, skin.
NYOGEL 773A
CI-G-17
Page 1 of 5
Section 4 : FIRST AID MEASURES
Skin contact: Remove contaminated clothing.
Wash thoroughly with soap and water.
Seek medical attention if irritation persists.
Eye contact: Flush with water for at least 15 minutes.
Obtain immediate medical attention.
Inhalation: Remove victim to fresh air. If not breathing, qualified personnel should administer artificial
respiration. Get medical attention.
If breathing is difficult, administer oxygen.
Ingestion: Obtain immediate medical attention.
Do not induce vomiting, unless directed to do so by a physician.
Section 5 : FIRE FIGHTING MEASURES
Flammability: Not flammable.
Conditions of flammability: At temperatures at or above flash point.
Extinguishing media: Carbon dioxide, dry chemical, foam.
Water spray.
Special procedures: Self−contained breathing apparatus required.
Firefighters should wear the usual protective gear.
Do not let firefighting water runoff enter a sewer.
Auto−ignition temperature: Not available.
Flash point (°C), method: Closed Cup.
ASTM D−93.
>400°F (204°C).
Lower flammability
Not available.
limit (% vol):
Upper flammability
Not available.
limit (% vol):
Explosion Data
Sensitivity to static discharge: Not available.
Sensitivity to mechanical impact: Not available.
Hazardous combustion products: Carbon monoxide (CO).
Traces of other toxic fumes.
Rate of burning: Not available.
Explosive power: Not available.
Section 6 : ACCIDENTAL RELEASE MEASURES
Leak/Spill: Contain the spill.
Prevent entry into drains, sewers, and other waterways.
Area will be slippery until cleaned.
Wear appropriate protective equipment.
Wipe or scrape up spilled material.
Wash spill area after material pick up is complete.
Transfer to an approved container for disposal or recovery.
Observe precautions from other sections.
Follow applicable OSHA (29 CFR 1910.120), state and local regulations.
NYOGEL 773A
CI-G-17
Page 2 of 5
Section 7 : HANDLING AND STORAGE
Handling procedures and equipment: Wash thoroughly after using, particularly before eating or smoking.
Do not eat, drink or smoke in handling area.
Avoid contamination of cigarettes or other tobacco products.
Launder contaminated clothing prior to reuse.
Users should be alert to the possibility that very small percentages of the population may
display unexpected allergic reactions to otherwise innocuous industrial lubricants and raw
materials.
Storage requirements: Store away from incompatible materials.
Do not store in open or unlabelled containers.
Section 8 : EXPOSURE CONTROLS / PERSONAL PROTECTION
Precautionary Measures
Gloves/Type:
Chemical resistant gloves.
Avoid skin contact.
Respiratory/Type: None required under normal use.
If exposure limit is exceeded, wear a NIOSH approved respirator.
Avoid breathing oil mist.
Eye/Type: Avoid eye contact.
Safety glasses, goggles or face shield.
In accordance with OSHA 29 CFR 1910.133.
Footwear/Type: Safety shoes per local regulations.
Clothing/Type: Wear adequate protective clothes.
Apron
Other/Type: Eye wash facility should be in close proximity.
Emergency shower should be in close proximity.
Ventilation requirements: Local ventilation is generally not necessary under normal conditions of use with adequate
general ventilation. Ventilation and other forms of engineering controls are the preferred
means for controlling chemical exposures.
Section 9 : PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Semi−solid.
Appearance & odor: Slight odour.
Light yellow.
Smooth grease.
Odor threshold (ppm): Not available.
Vapour pressure (mmHg): Negligible.
NYOGEL 773A
CI-G-17
Page 3 of 5
Vapour density (air=1): Not available.
Volatiles (%): None
Evaporation rate
Not available.
(butyl acetate = 1):
Boiling point (°C): Not volatile.
Freezing point (°C): Non−melting.
pH: Not available.
Specific gravity @ 20 °C: Not available.
Solubility in water (%): Insoluble.
Coefficient of water\oil dist.: Not available.
VOC: None
Section 10 : STABILITY AND REACTIVITY
Chemical stability: Stable under normal conditions.
Conditions of instability: Pyrolysis.
Hazardous polymerization: Will not occur.
Incompatible substances: Strong oxidizing agents.
Hazardous decomposition products: See hazardous combustion products.
Section 11 : TOXICOLOGICAL INFORMATION
Sensitization to product: Not available.
Reproductive effects: Not available.
Teratogenicity: Not available.
Mutagenicity: Not available.
Synergistic materials: Not available.
Section 12 : ECOLOGICAL INFORMATION
Environmental toxicity: No data at this time.
Environmental fate: No data at this time.
Section 13 : DISPOSAL CONSIDERATIONS
Waste disposal: Contact a licensed waste−disposal contractor for detailed recommendations.
Many states classify waste lubricants as "hazardous", which means disposal can only be a
licensed firm. Follow applicable Federal, state, and local regulations.
Section 14 : TRANSPORT INFORMATION
DOT: Not regulated.
Section 15 : REGULATORY INFORMATION
USA Regulatory Information
SARA hazard catagories sections Immediate (Acute) Health Hazard: No.
311/312: Delayed (Chronic) Health Hazard: No.
Fire Hazard: No.
Sudden Release of Pressure: No.
Reactive: No.
NYOGEL 773A
CI-G-17
Page 4 of 5
SARA Section 313: Not regulated.
TSCA inventory: All components of this product are listed on the TSCA inventory.
Section 16 : OTHER INFORMATION
Supplier MSDS date: 2003/02/10
Data prepared by: GSM
Disclaimer: While the information and recommendations set forth herein are believed to be accurate as of
the date hereof, Nye Lubricants, Inc. makes no warranty with respect thereto and disclaims all
liability with respect thereon.
NYOGEL 773A
CI-G-17
Page 5 of 5
Material Safety Data Sheet
Product name: MICROLUBE GB 0 (# 020232)
Date: July 2002
Replaces: July 1995
Page: 1 of 3
______________________________________________________________________________
Section 1 - Product and Company Identification
Company: Klüber Lubrication North America L.P.
54 Wentworth Avenue
Emergency telephone #.: 1-800-424-9300 (Chemtrec)
Londonderry, N.H. 03053
Phone: (603)434-7704
Fax: (603)434-8046
Product Name and Article #: Microlube GB 0 (# 020232)
Product Use: Lubricating Grease
¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯
Section 2 - Composition/Information on Ingredients
Ingredient
TLV
PEL
5 mg/m3 (mist)
Mineral oil
5 mg/m3 (mist)
Zinc compound
N/Ap
N/Ap
Silica
3 mg/m3 (PNOC)
5 mg/m3
¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯
Section 3 - Hazards Identification
Eye Contact: May cause mild irritation upon immediate contact.
Skin contact: Prolonged or repeated contact may cause the removal of skin oils, possibly leading to
irritation or dermatitis.
Inhalation: Vapor inhalation under ambient conditions will not occur. Vapor pressure is very low. The
inhalation of vapors (generated at extremely high temperature only) or oil mist may cause a mild
irritation of the mucous membranes of the upper respiratory tract. Harmful concentrations of mists
and/or vapors are unlikely to occur through reasonable and customary use of this product.
Ingestion: No acute or chronic effects expected. However, minute amounts aspirated into the lungs
during ingestion or vomiting may cause mild to severe pulmonary injury.
¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯
Section 4 - Emergency and First Aid Procedures
After contact with eyes: Flush eyes with plenty of water for 15 minutes. If irritation persists, or if an infection
develops, seek medical attention.
After contact with skin: Wash off with soap and plenty of water. Apply skin cream if necessary. Seek medical
attention if irritation or infection occurs. Remove contaminated clothing and wash before reuse.
After inhalation: If overcome by product vapor heated to extreme temperatures, immediately move from
exposure and get medical attention. If breathing is irregular, start resuscitation or administer oxygen if available.
If overexposed to oil mist, remove from further exposure until excessive oil mist condition subsides.
After ingestion: If large amounts are swallowed, do not induce vomiting. Get medical attention.
Advice to doctor: Treat symptomatically.
¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯
Section 5 - Exposure Controls
Eye protection: Wear safety goggles if splashes may occur. Do not wear contact lenses when using
chemicals.
Hand protection: Wear chemical resistant gloves.
Body protection: Wear clean, body-covering clothing to minimize dermal exposure.
Ventilation: Under normal conditions of use, no special ventilation is required. However, if vaporized or misted
and limits in Section 2 are exceeded, use local exhaust.
Respiratory protection: No special respiratory protection is required. However, if product is overheated
beyond conditions of normal use, or misted, and the limits in Section 2 are exceeded, wear the appropriate
NIOSH-approved respiratory protection.
Other protection measures: Safety showers, eye wash fountains, and washing facilities should be readily
available.
¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯
The information herein is given in good faith, but without warranty, express or implied. All risks of use of the product are therefore assumed
by the user. Appropriate warnings and safe handling procedures must be provided to handlers and users.
CI-G-18
Material Safety Data Sheet
Product name: MICROLUBE GB 0 (# 020232)
Date: July 2002
Replaces: July 1995
Page: 2 of 3
______________________________________________________________________________
Section 6 - Fire Fighting Measures
Flash point: N/Av
Method Used: DIN ISO 2592
Lower explosion limit: N/Av
Upper explosion limit: N/Av
Extinguishing media: Water spray, foam, dry powder, carbon dioxide (CO2)
Unusual fire and explosion hazards: Empty metal containers retain product residue. Do not
pressurize, cut, weld, drill, solder or expose container to heat, flame, sparks, or other sources of ignition:
it may explode, causing serious injury or death. Exposure to heat builds up pressure in container. Cool
with water spray.
Special fire Fighting Procedures: If leak or spill has not ignited, use water spray to disperse any vapor and to
flush spills away from ignition sources. Use self-contained breathing apparatus for enclosed or confined spaces
or as otherwise needed. Do not use direct stream of water, material may float and re-ignite.
¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯
Section 7 - Accidental Release Measures
If product leaks or is inadvertently spilled, eliminate ignition sources isolate surrounding spill area with the proper
containment system to prevent the spill from reaching waterways. Add absorbent and soak up the product.
Collect product and absorbent, place in a chemical waste container for proper disposal.
_______________________________________________________________________________________
Section 8 - Handling and Storage
Avoid contact with skin and remove soiled or soaked clothing. Wash hands with soap and water before eating,
drinking, and/or smoking. Clean skin thoroughly after work and if necessary, apply skin cream.
Store product under normal temperature and pressure.
Store product away from heat sources and food products.
_______________________________________________________________________________________
Section 9 - Physical and Chemical Properties
Boiling Point: N/Av
Pour Point: N/Av
Method: DIN ISO 3016
Vapor Pressure (mm Hg.): N/Av
Density: N/Av
Method: DIN 51757
Solubility in Water: Insoluble
Specific Gravity (H20 = 1): 0.90
Evaporation rate (ether = 1): N/Av
Appearance and odor: Red-brown grease with a neutral odor.
¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯
Section 10 - Stability and Reactivity
Stability: Stable
Conditions to avoid: Open flames and other sources of heat
Materials to avoid: Strong oxidizing agents such as pure oxygen
Hazardous decomposition products: Fumes, smoke, carbon monoxide and carbon dioxide.
Hazardous polymerization: Will not occur
¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯
The information herein is given in good faith, but without warranty, express or implied. All risks of use of the product are therefore assumed
by the user. Appropriate warnings and safe handling procedures must be provided to handlers and users.
CI-G-18
Material Safety Data Sheet
Product name: MICROLUBE GB 0 (# 020232)
Date: July 2002
Replaces: July 1995
Page: 3 of 3
______________________________________________________________________________
Section 11 - Toxicological Information
Acute toxicity: N/Av for this product.
Chronic toxicity: N/Av for this product.
¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯
Section 12- Disposal Considerations
Under RCRA, it is the user’s responsibility to determine, at the time of disposal, whether the product meets any
of the criteria for a hazardous waste defined in 40 CFR 261. As a new product it would not be considered
RCRA hazardous waste.
_______________________________________________________________________________________
Section 13- Transportation Information
Proper Shipping Name
Hazard Class or Division
UN ID
Packing Group
N/Ap
¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯
Section 14 – Regulatory Information
All product components comply with all applicable rules and orders under the Toxic Substance Control
Act (TSCA).
x
The Zinc Compound in this product is regulated by the CWA 304 – Water Quality Criteria, is a CWA
307 – Priority Pollutant, is a CERCLA Hazardous Substance, is a SARA Title III Section 313
chemical, is a DOT/RSPA substance, is on the California, Connecticut, Illinois, Massachusetts and
New Jersey chemical inventory lists and is on the Canadian NPRI.
x
The Silica in this product is a NIOSH group 2 pesticide, is an IARC group 3 Carcinogen – Evidence
of carcinogenicity in humans is inadequate, is on the WHMIS Ingredient Disclosure List, and is on
the California, Illinois, Massachusetts, New Jersey, Kentucky, Pennsylvania, North Carolina,
Minnesota and North Carolina chemical inventory lists.
¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯
Section 15 - Additional Information
HMIS Rating: Health -1
Flammability - 1
Reactivity - 0
Personal Protection - B
Unk. = Unknown N/Ap = Not Applicable N/Av = Not Available
~ = Approximately
¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯
The information herein is given in good faith, but without warranty, express or implied. All risks of use of the product are therefore assumed
by the user. Appropriate warnings and safe handling procedures must be provided to handlers and users.
CI-G-18
Reprints/Updates of this document are available at our website:
http://www.cimcool.com
Material Safety Data Sheet
CIMSTAR® 55
METALWORKING FLUID CONCENTRATE
DATE EFFECTIVE: 02-27-2006
1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
.
Manufacturer:
Milacron Marketing Company, Global Industrial Fluids
3000 Disney Street
Cincinnati, OH 45209 United States
Emergency:
Telephone (USA): 1-800-424-9300 (CHEMTREC)
Telephone (Outside USA): 1-703-527-3887 (CHEMTREC)
General Information:
Telephone: 1-513-458-8199
Generic Name:
Water Soluble Metalworking Fluid Concentrate
2 EMERGENCY INFORMATION
.
Product is alkaline. Product is a primary eye irritant. Product may be a primary skin irritant. Highway
spills could result in slippery conditions. No other significant health effects are associated with this
material.
3 POTENTIAL HEALTH EFFECTS OF DIRECT EXPOSURE
.
Product
Product at Use Dilution
Inhalation:
Not Applicable
Extended exposure to mist may cause upper
respiratory irritation.
Eye Contact:
Product is a primary eye irritant.
Will cause stinging sensation in the eye.
Skin Contact:
Product may be a primary skin irritant.
Not irritating to the skin when used as directed
and good personal hygiene is practiced.
Ingestion:
Not orally toxic.
Swallowing small quantities may cause diarrhea,
nausea or vomiting.
Medical Conditions generally aggravated by exposure
May aggravate existing skin irritation where further defatting or skin penetration could occur.
Mild skin irritation (redness and dryness of hands) may be experienced when the diluted product has
been contaminated by certain oils, by dissolved metals, or when mix ratio is too strong. When
problems occur, use of water-resistant barrier creams may be a temporary control measure.
Contact Milacron Marketing Company, Global Industrial Fluids Technical Services at 1-513-458-8199
for specific recommendations.
Material Name: CIMSTAR® 55
46JPH311
Effective Date: 02-27-2006
CI-L-01
1/ 6
When used in applications generating high levels of mist, operator exposure can be minimized by
proper ventilation, use of mist collectors or splash guards, as appropriate. If there is doubt about
actual mist levels present, monitoring should be conducted. Contact Milacron Marketing Company,
Global Industrial Fluids at 1-513-458-8199 for specific recommendations.
Carcinogen Listings:
NTP: No
IARC: No
OSHA: No
Signs and symptoms of exposure
Acute
Eye injury may result from contact with product. Skin irritation can result from improper use and
handling of product.
4 EMERGENCY AND FIRST AID PROCEDURES
.
Eyes
In case of eye contact, flush immediately with running water for at least 15 minutes, and get prompt
medical attention.
Skin Contact
For skin contact flush with large amounts of water while removing contaminated clothing. Remove
contaminated shoes and clothing and launder before reuse. If irritation persists, get medical attention.
Diluted product is not irritating to the skin when used as recommended and good personal hygiene is
practiced.
Ingestion
If the material is swallowed, get immediate medical attention or advice. DO NOT INDUCE VOMITING.
Give two glasses of water or milk. Immediately contact a physician and obtain treatment. Swallowing
small quantities of diluted product may cause nausea, diarrhea or abdominal distress.
Inhalation
Inhalation can occur in applications where high mist levels are generated. OSHA has set a PEL of 15
mg/m³ for any airborne particulate as a nuisance level of exposure. NIOSH has set a REL of 0.5 mg/m³
for metalworking fluid mist. If symptoms are experienced, remove source of contamination or move
victim to fresh air. If symptoms persist, get medical attention.
5 CONTROL MEASURES
.
Respiratory protection
Product is not volatile.
In applications where time-weighted exposures are 0.5 to 5 mg/m³, mist reduction through improved
ventilation, mist collection or process modification is recommended by NIOSH. Where this is not
possible, NIOSH recommends the use of any air purifying, half-mask respirator including a disposable
respirator, equipped with any P- or R-series particulate filter. If the average exposure will exceed 5
mg/m³, NIOSH recommends use of a powered, air-purifying respirator equipped with a hood or helmet
and a HEPA filter. If respiratory problems are present when mist levels are < 0.5 mg/m³, respiratory
protection should be based on the individual recommendation of a qualified health care provider.
Caution
The appropriate use and type of respirator is dependent upon use of the product and local operating
conditions.
Ventilation
For most applications, normal shop ventilation is adequate. However, when high mist levels are
generated or where machines are close together or ventilation is inadequate, operators may experience
respiratory irritation. For such applications, use of splash guards or mist collectors is recommended.
Material Name: CIMSTAR® 55
46JPH311
Effective Date: 02-27-2006
CI-L-01
2/ 6
Eye protection
Proper metalworking plant eye protection required when handling product concentrate.
Other protective clothing or equipment
Use effective metalworking plant protective clothing as appropriate.
Work / Hygiene Practices
Good personal hygiene should always be followed.
Protective Gloves
Impervious gloves, such as nitrile gloves, are recommended when handling product concentrate.
6 HAZARDOUS INGREDIENTS / IDENTITY INFORMATION
.
These ingredients may contribute to the acute product hazards listed under the Potential Health
Effects section. Other substances, not hazardous under the OSHA Hazard Communication
Standard, may be present. Further composition information may be available to health professionals
as provided in the Standard.
Component
CAS #
Percent
SEVERELY-HYDROTREATED NAPHTHENIC
PETROLEUM DISTILLATES
MONOETHANOLAMINE
64742-52-5
141-43-5
1-5
MONOISOPROPANOLAMINE
78-96-6
1-5
SODIUM ALKYLBENZENE SULFONATE
68411-30-3
1-5
ALKOXYLATED LINEAR ALCOHOLS
68987-81-5
1-5
10 - 30
7 FIRE AND EXPLOSION HAZARD DATA
.
Extinguishing Media
Not Applicable
Hazardous Combustion Products
Smoke, fumes, oxides of nitrogen, and oxides of carbon
Flash Point:
Lower Explosive Limit:
Upper Explosive Limit:
HMIS RATINGS
Health
Flammability Classification
Reactivity
NFPA RATINGS
Health
Flammability Classification
Reactivity
Not Applicable
Not Applicable
Not Applicable
1
0
0
1
0
0
8 ACCIDENTAL RELEASE MEASURES
.
Contain the spill, collect on absorbent material, and discard as dictated by Federal, state and local
regulations that may apply. Flush area thoroughly with water.
Material Name: CIMSTAR® 55
46JPH311
Effective Date: 02-27-2006
CI-L-01
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Reportable Quantity:
None
9 WASTE DISPOSAL
.
For Used Product
Disposal procedures must comply with local, county, state and Federal regulations. If pre-treatment is
needed, ultrafiltration, emulsion breaking or evaporation may be used. Contact Milacron Marketing
Company, Global Industrial Fluids at 1-513-458-8199 for assistance.
For Unused Product
Product is not a hazardous waste as defined under 40 CFR 261. Contact Milacron Marketing Company,
Global Industrial Fluids at 1-513-458-8199 for assistance.
Empty Containers
Empty containers will contain a residue which is not considered a hazardous waste under RCRA
regulations. Drums can be drained to a "drip dry" condition by inversion and can be offered for
recycling or scrap.
10 HANDLING AND STORAGE
.
Avoid all contact of product with eyes or skin. Wash thoroughly after handling. Do not swallow. Do not
store product concentrate in direct sunlight or elevated temperatures. Use only as recommended by
Milacron Marketing Company, Global Industrial Fluids . If frozen, thaw completely at room temperature
prior to use.
Other Precautions
Contains amines. Do not add sodium nitrite or other nitrosating agents to this product because
suspected cancer-causing nitrosamines may be formed.
11 PHYSICAL / CHEMICAL CHARACTERISTICS
.
Boiling Point:
212 °F (100 °C)
Specific Gravity:
1.02
Evaporation Rate:
Like water when diluted
Solubility (H2O):
100 % Miscible
Volatile Organic Content (by 9 %
ASTM D2369):
pH (Concentrate):
9.5
pH (Mix):
8.8 @ 5%
Recommended Starting
Dilution:
5%
Appearance/Odor:
Clear/Chemical
12 REACTIVITY
.
Stability
Stable under normal conditions.
Conditions to avoid
Use as directed.
Materials to avoid
Avoid contact with strong acids or oxidizers to product.
Material Name: CIMSTAR® 55
46JPH311
Effective Date: 02-27-2006
CI-L-01
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Hazardous Polymerization
Will not occur.
Combustion Products
Smoke, fumes, oxides of nitrogen, and oxides of carbon
13 TRANSPORTATION INFORMATION
.
BY LAND
Hazardous Materials Description and Proper Shipping Name (49 CFR 172.101)
Not a Hazardous Material
U.S. Harmonized Tariff Code:
3403.99.0000
BY AIR OR VESSEL
Hazardous Materials Description and Proper Shipping Name (49 CFR 172.101)
Not a Hazardous Material
14 REGULATORY INFORMATION
.
EXPOSURE GUIDELINES
REGULATED MATERIAL
MONOETHANOLAMINE
METALWORKING FLUID MIST
MINERAL OIL (MIST)
NIOSH REL
0.5 mg/m³
5 mg/m³
OSHA PEL
3 ppm
OSHA STEL ACGIH TLV ACGIH STEL
6 ppm
3 ppm
6 ppm
5 mg/m³
5 mg/m³
CERCLA
No components of this product are present at levels which require reporting under 40 CFR 302.4.
EPCRA (SARA) TITLE III Extremely Hazardous Substances (302):
None
Hazardous Substances (311/312)
Product is a hazardous substance as defined under the OSHA Hazard Communication Standard and
may be reportable under the provisions of SARA Sections 311 and 312.
HAZARD CATEGORIES
Acute Health: Yes
Chronic Health: No
Fire: No
Sudden Release of Pressure: No
Reactive: No
RCRA
Product concentrate does not meet the definition of a hazardous waste as defined under 40 CFR 261.
It is possible that in use, the product may be contaminated by metals or by chlorinated solvents and the
final waste may meet the TCLP definition. Each facility should assess each waste stream to determine
if the used fluid should be treated as a hazardous waste.
TSCA
The ingredients of this product are on the TSCA inventory.
Material Name: CIMSTAR® 55
46JPH311
Effective Date: 02-27-2006
CI-L-01
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State Right to Know
Many states have enacted Community Right-To-Know laws which require information beyond that
mandated by federal laws. Since some of these laws are inconsistent with the federal laws, the
information in this sheet may not fully meet the requirements of every state.
Toxic Substances (313)
Component
CAS #
None
Max % Comments
%
GLOSSARY OF ABBREVIATIONS
ACGIH
American Conference of Governmental Industrial Hygenists
CAS
Chemical Abstracts Service
CERCLA
Comprehensive Environmental Response Compensation and Liability Act
CFR
Code of Federal Regulations
COC
Cleveland Open Cup
DOT
Department of Transportation
EPCRA
Emergency Planning and Community Right-to-Know Act (aka SARA)
IARC
International Agency for Research on Cancer
NIOSH
National Institute for Occupational Safety and Health
NTP
National Toxicology Program
OSHA
Occupational Safety and Health Administration
PEL
Permissible Exposure Limit
RCRA
Resource Conservation and Recovery Act
REC
Recommended
REL
Recommended Exposure Limit
SARA
Superfund Amendments and Reauthorization Act
STEL
Short-Term Exposure Limit
TCLP
Toxicity Characteristics Leaching Procedure
TLV
Threshold Limit Value
TSCA
Toxic Substances Control Act
VOC
Volatile Organic Compounds
Disclaimer
NOTE: The opinions expressed herein are those of qualified experts within Milacron Marketing
Company, Global Industrial Fluids and of their suppliers. We believe that the information contained
herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and
of these opinions and the condition and use of the product are not within the control of Milacron
Marketing Company, Global Industrial Fluids , it is the user's obligation to determine the conditions of
safe use of the product.
Material Name: CIMSTAR® 55
46JPH311
Effective Date: 02-27-2006
CI-L-01
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Invoil 20
Material Safety Data Sheet
Revision Date October 2004
For Chemical Emergency Call Chemtrex 800-424-9300
1. Substance/Company Identification
PRODUCT NAME:
MANUFACTURER:
Invoil 20
CAS NUMBER: 64742-65-0
Inland Vacuum Industries
Churchville NY 14428
(585) 293-3330
2. Composition/ Ingredients
GENERIC NAME:
100% Solvent refined Neutral paraffinic oil
CHEMICAL FORMULA: (CH2)n 20 =< n =< 40
HAZARDOUS INGREDIENTS: None
3. Hazards Identification
POSSIBLE ENTRY ROUTES: Ingestion, inhalation of oil mists
This product is not classified as hazardous.
ACUTE EFFECTS: Exposure to oils mists may cause nausea and eye
irritation. Detailed studies have not been made, but material is not
expected to be dermatitic or a sensitizer.
CHRONIC EFFECTS: Unknown.
4. First Aid Measures
SKIN: Wash with soap and water.
EYES: Flush with water. Contact a physician!
INGESTION: If swallowed, do not induce vomiting.
Small amounts in mouth may be washed out. Contact a physician.
5. Fire Fighting Measures
FLASH POINT: >213 C
METHOD USED: Cleveland Open Cup
EXPLOSIVE LIMITS LOWER: Unknown UPPER: Unknown
EXTINGUISHING MEDIA: Water fog, chemical foam or carbon
dioxide. NFPA Class III B Material.
SPECIAL FIREFIGHTING PROCEDURES: Wear breathing gear
when fighting fires in enclosed spaces; incomplete combustion of this
material produces carbon monoxide!
UNUSUAL FIRE AND/OR EXPLOSION HAZARDS: None
6. Accidental Release Measures
PROCEDURE TO BE FOLLOWED IN EVENT OF RELEASE: Small
spills may be wiped up with a rag. Large spills should be picked up
immediately with an absorbent.
7. Handling and Storage
HANDLING: None known
STORAGE: None known
8. Exposure Controls/Personal Protection ENGINEERING CONTROL MEASURES: None required
RESPIRATORY PROTECTION: See notes on ventilation below.
VENTILATION: Good general ventilation at source of vapor.
PROTECTIVE GLOVES: Yes - made of oil-impermeable rubber
SAFETY GLASSES/GOGGLES: Yes - glasses should have side shields
OTHER PROTECTIVE EQUIPMENT: None should be required under
normal use.
CI-L-02
www.inlandvacuum.com
Invoil 20
Page 2
9. Physical & Chemical Properties
PHYSICAL STATE: Liquid
VAPOR PRESSURE: < .0001 Torr @ 25C
BOILING POINT: >200 C
EVAPORATION RATE (ether = 1): Nil
VAPOR DENSITY: approximately 14
WT % VOLATILES: Nil
SPECIFIC GRAVITY: 0.87
VISCOSITY: 58 cst @ 40 C
SOLUBILITY IN WATER: Nil
APPEARANCE: Pale yellow viscous liquid with a faint
petroleum odor.
10. Stability & Reactivity
STABILITY: Material is stable
CONDITIONS TO AVOID: Continuous exposure to temperatures > 200 C
INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers
HAZARDOUS DECOMPOSITION PRODUCTS: Incomplete combustion
may produce carbon monoxide.
11. Toxicological Information
ACUTE ORAL LD50(MG/KG): None known
ACUTE DERMAL LD50: None
ACUTE INHALATION: US Gov't 8 hr TWA limit for exposure to oil mists
is 5 mg per cubic meter
12. Ecological Information
ENVIRONMENTAL: When used and/or disposed of as indicated, no adverse
environmental effects are foreseen.
MOBILITY: Non-volatile and insoluble in water.
DEGRADABILITY: Slowly biodegradable in aerobic conditions.
13. Disposal Considerations
Product and packaging must be disposed of in accordance with Federal,
State and local regulations.
14. Transport Classification
Not classified as hazardous for transport by air, sea or road.
15. Regulatory Information
TSCA: This material is in compliance with the TOXIC SUBSTANCE
CONTROL ACT (15 USC 2601-2629) and is listed in the TSCA Inventory.
HAZARD CATEGORIES FOR SARA 311/312 REPORTING
HEALTH
Immediate (Acute)
No
HEALTH
Delayed (Chronic)
No
PHYSICAL
Fire
No
PHYSICAL
Sudden rlease of pressure
No
PHYSICAL
Reactive
No
PHYSICAL
Nuisance Mist/ Dust Only
No
01=SARA 313
11=NJRTK
21=TSCA Sect 5(a)(2)
02=MASS RTK
12=CERCLA 302.4
22=TSCA Sect 6
03=NTP Carcinogen
13=MN RTK
23=TSCA Sect 12(b)
04=CA Prop 65-Carcin 14=ACGIM TWA
24=TSCA Sect 8(a)
05=CAProp65-ReprotTox 15=ACGIH STEL
25=TSCA Sect 8(d)
06=IARC Group 1
16=ACGIH Calc TLV
26=TSCA Sect 4(a)
07=IARC Group 2A
17=OSHA PEL
27=Canadian WHMIS
08=IARC Group 2B
18=DOT Marine Pollutant 28=OSHA CEILING
09=SARA 302/304
20=EPA Carcinogen
10=PA RTK
CI-L-02
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Invoil 20
Page3
The following components of this material are found on the regulatory lists
indicated.
DISTILLATES, HYDROTREATED HEAVY PARAFFINIC
Is found on lists: 14,15,17
NEW JERSEY RTK CLASSIFICATION:
Under the New Jersey Right-to-Know Act L. 1983 Chapter 315 N.J.S.A.
34:5A-1 et.seq., the product is to be identified as follows:
PETROLEUM OIL
16. Other Information
NFPA RATING
FLAMMABILITY
HEALTH HAZARD
REACTIVITY
SPECIAL HAZARD
CI-L-02
1
0
0
NONE
www.inlandvacuum.com
MATERIAL SAFETY DATA SHEET
LPS 1 Greaseless Lubricant
Section 1 • Product and Company Identification
Manufacturer's Name: LPS Laboratories
Chemical Family: Petroleum Distillates
Trade Name: LPS 1 Greaseless Lubricant
Telephone Number: 770-243-8800
Part Numbers: 00116(aerosol) 00122, 01128,
00105, 00155
Emergency Telephone Number:
1-800-424-9300 Chemtrec;
Outside U.S.: (703) 527-3887
Address:
4647 Hugh Howell Road
Tucker, GA USA 30085-5052
Website: http://www.lpslabs.com
PLAIN LANGUAGE HAZARD SUMMARY
Material Safety Data Sheets can be confusing. Federal and State laws require us to include a great deal of technical
information that probably won’t help the non-professional. LPS includes this “PLAIN LANGUAGE HAZARD SUMMARY” to
address the questions and concerns of the average worker. If you have additional health, safety or product questions,
don’t hesitate to call us at 800/241-8334.
Worker Toxicity
LPS 1 GREASELESS LUBRICANT is a specialized light duty lubricant designed to displace moisture and prevent rust and
corrosion on steel, aluminum and other metals. LPS 1 also reduces friction, heat, noise, or wear between moving parts. It
contains petroleum distillates and mineral oil that can be irritating to skin. Avoid extended exposure to unprotected skin.
Don’t get it in your eyes (it stings), or breath the vapor (if working on hot surfaces or heated tanks). Vapors from heated
LPS 1 can make you dizzy and even sick. For more exposure and first aid information, refer to MSDS Sections 2, 8 and
11.
Flammability
LPS 1 GREASELESS LUBRICANT is combustible having a flash point typically above 170oF and an autoignition
temperature over 400oF. Under normal use conditions flammability isn’t a concern, but don’t apply the product onto redhot metal surfaces or near sparks.
Disposal
LPS 1 in non-aerosol form is not hazardous for disposal; however, if it becomes contaminated with another substance, the
resulting mixture may fall under a hazardous classification. See section 13 for more details.
Current Revision 8/29/05 – Previous Revision: 5/10/05
CI-L-03
page 1 of 7
MATERIAL SAFETY DATA SHEET
LPS 1 Greaseless Lubricant
Section 2 • Hazards Identification
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Emergency Overview: DANGER: Aerosol contents under pressure. Harmful or Fatal if Swallowed.
Primary route(s) of entry: Skin and Eye contact. Inhalation.
Potential Acute Health Effects:
Eyes:
Irritating to eyes
Skin:
Repeated exposure may cause skin dryness or cracking.
Inhalation:
Excessive inhalation of vapors can cause irritation of the respiratory tract, nausea, dizziness or headache.
Ingestion:
Product has a low order of acute oral toxicity, but ingestion of large quantities may cause nausea,
vomiting, and gastrointestinal irritation. May cause injury if aspirated into lungs.
Potential Chronic Health Effects:
Carcinogenic Effects: NTP: No IARC: No OSHA: No
Mutagenic Effects: None
Teratogenic Effects: None
Medical conditions aggravated by exposure: Persons with pre-existing central nervous system (CNS) disease,
neurological conditions, skin disorders, chronic respiratory diseases, or impaired liver or kidney function should avoid
exposure.
Signs and Symptoms
Stinging in eyes. Repeated or prolonged skin contact can cause redness, irritation, and scaling of the skin (dermatitis).
Breathing of high vapor concentrations may cause headaches, stupor, irritation of throat and eyes, and kidney effects.
Section 3 • Composition / Information on Ingredients
Component
CASRN
Percent by Weight
Distillates (Petroleum), Hydrotreated Light
Distillates (Petroleum), Hydrotreated Middle
Carbon Dioxide propellant (aerosol only)
64742-47-8
64742-46-7
124-38-9
70 - 80%
20 - 30 %
1 - 4%
Section 4 • First Aid Measures
Eyes:
Check for and remove contact lenses. If irritation or redness develops, flush eyes with cool, clean, lowpressure water for at least 15 minutes. Hold eyelids apart to ensure complete irrigation of the eye and
eyelid tissue. Do not use eye ointment. Seek medical attention immediately.
Current Revision 8/29/05 – Previous Revision: 5/10/05
CI-L-03
page 2 of 7
MATERIAL SAFETY DATA SHEET
LPS 1 Greaseless Lubricant
Section 4 • First Aid Measures - continued
Skin:
Remove contaminated shoes and clothing. Clean affected area thoroughly with mild soap and water. Do
not use ointments. Seek medical attention if irritation persists.
Inhalation:
Immediately move victim to fresh air. If victim is not breathing, immediately begin rescue breathing. If
heart has stopped, immediately begin cardiopulmonary resuscitation (CPR). If breathing is difficult, seek
medical attention immediately.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. If spontaneous vomiting is about to occur, place victim’s head below
knees. If victim is drowsy or unconscious, place on the left side with head down. Do not leave victim
unattended. Seek medical attention immediately.
Section 5 • Fire Fighting Measures
Products of Combustion: Carbon monoxide and carbon dioxide.
Firefighting media: SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. Cool containing vessels with water jet in order to
prevent pressure build-up, autoignition or explosions.
Sensitivity to Impact: None
Sensitivity to Static Discharge: None
Protection Clothing (Fire): Firefighters must use full bunker gear including NIOSH-approved positive pressure self-contained
breathing apparatus to protect against potential hazardous combustion or decomposition products and oxygen deficiencies.
Evacuate area and fight the fire from a maximum distance or use unmanned hose holders or monitor nozzles.
Special Remarks on Explosion Hazards: Aerosols may explode upon heating, spread fire and overcome sprinkler systems.
Section 6 • Accidental Release Measures
Small Spill and Leak: Absorb with an inert material and dispose of properly.
Large Spill and Leak: For large spills, secure the area and control access. Dike far ahead of a liquid spill to ensure complete
collection. Pick up free liquid for disposal using absorbent pads, sand, or other inert non-combustible absorbent materials.
Place into appropriate waste containers for later disposal.
Section 7 • Handling and Storage
Handling: DO NOT spray into or around ignition sources. After handling, always wash hands thoroughly with soap and
water. Use only with adequate ventilation. Avoid breathing vapors or spray mists.
Storage: Keep container in a cool, well-ventilated area. Avoid all sources of ignition (spark or flame). Store below 120°F.
Precautions to be taken in handling and storage: Store aerosols as Level 3 Aerosol (NFPA 30B). Store all materials in
dry, well-ventilated area. Avoid breathing vapors.
Current Revision 8/29/05 – Previous Revision: 5/10/05
CI-L-03
page 3 of 7
MATERIAL SAFETY DATA SHEET
LPS 1 Greaseless Lubricant
Section 8 • Exposure Controls / Personal Protection
Ingredients
Distillates (Petroleum),
Hydrotreated Light
Distillates (Petroleum),
Hydrotreated Middle
Carbon Dioxide propellant
(aerosol only)
CASRN
64742-47-8
OSHA PEL-TWA
Not established
5mg/m3 /8 hrs
ACGIH-TLV
Not
established
5mg/m3 /8 hrs
Other Limits
100 ppm (supplier recommended
TWA)
10 mg/m3 UK ST EXP (15 min.)
64742-46-7
124-38-9
10,000 ppm
5,000 ppm
30,000 ppm ACGIH STEL
Engineering Controls: Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapors below their respective occupational exposure limits.
Personal Protection:
Eyes: Safety glasses.
Respiratory : Use appropriate respirator if ventilation is inadequate.
Hands: Use solvent resistant gloves.
General Hygiene Considerations: Wash thoroughly after handling. Have eye-wash facilities immediately available.
Section 9 • Physical and Chemical Properties
Appearance:
Liquid.
Colour:
Pale amber.
Odor/Taste:
Characteristic.
Vapor Pressure:
<0.05mmHg @ 20 °C
Solubility Description:
Not soluble in
water.
Evaporation Rate:
<0.1(BuAc=1)
Boiling Point (°C):
213 @ 760mmHg
Flash Point (°C):
79°C (175oF)
Specific Gravity (Water=1):
0.79-0.81 @ 20 °C
Flash Point Method:
Tag-Closed Cup.
Vapour Density (air=1):
>1
Auto Ignition
Temperature (°C):
>228 C(442 F)
V.O.C. Content:
0 g/L
Partition Coefficient
(octanol/water):
<1
Flammable limits
(estimated):
LOWER: 0.6%
UPPER: 7%
Viscosity:
<3.8 cSt @ 40oC
pH:
Not applicable
Current Revision 8/29/05 – Previous Revision: 5/10/05
CI-L-03
o
o
page 4 of 7
MATERIAL SAFETY DATA SHEET
LPS 1 Greaseless Lubricant
Section 10 • Stability and Reactivity
Stability and Reactivity: The product is stable.
Incompatibility with Various Substances: Extremely reactive or incompatible with oxidizing agents.
Hazardous decomposition products: These products are carbon oxides (CO, CO2)
Hazardous polymerization: Will not occur.
Section 11 • Toxicological Information
Acute and Chronic Toxicity
A: General Product Information
Following exposure to vapors, this material can produce central nervous system depression. High atmospheric
concentrations can result in eye, nasal and respiratory tract irritation. However, if handled in accordance with good
industrial hygiene practice, this product will not present a significant hazard in the workplace.
Ingredients
Distillates (Petroleum), Hydrotreated Light
Distillates (Petroleum), Hydrotreated Middle
Carbon Dioxide propellant (aerosol only)
CASRN
64742-47-8
64742-46-7
124-38-9
LC-50
>6.8 mg/L
Not available
Not available
LD-50
> 5 g/kg acute oral / rat
Not available
Not appropriate
Section 12 • Ecological Information
Component Data: Acute Aquatic Toxicity
Component
CASRN
Test
Species
Results
Distillates (Petroleum), Hydrotreated Light
64742-47-8
96-hour LC50
Oncorhynchus mykiss
2,900 µgL
Distillates (Petroleum), Hydrotreated Middle
64742-46-7
Carbon Dioxide propellant (aerosol only)
124-38-9
48-hour EC50
96-hour EC50
48-hour EC50
96-hour EC50
Daphnia magna
Microcystis pyrifera
Daphnia magna
Microcystis pyrifera
Not established
Not established
Not established
Not established
For the 64742-47-8 component, no toxicity has been observed in water due to extremely low water solubility. If material is
spilled on soil, some potential toxic effects could occur before biodegradation could remove material.
If spilled, the 64742-46-7 constituent may kill grasses and small plants by interfering with transpiration. Spilled material
may coat gill structures of fish resulting in suffocation if spilled in shallow, running water. This product may be toxic to
amphibians by preventing dermal respiration. This product may also cause gastrointestinal distress to birds and mammals
through ingestion. Biodegradation of this product is possible within 90 to 120 days in aerobic environments at
temperatures above 21oC.
Current Revision 8/29/05 – Previous Revision: 5/10/05
CI-L-03
page 5 of 7
MATERIAL SAFETY DATA SHEET
LPS 1 Greaseless Lubricant
Section 13 • Disposal Considerations
Waste Status:
In its purchased form, non-aerosol material does not meet the definition of a RCRA hazardous waste. However,
full aerosols are a RCRA hazardous waste carrying waste code D003.
Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Note:
Chemical additions to, processing of, or otherwise altering this material may make this waste management
information inaccurate, incomplete, or otherwise inappropriate. Furthermore, state and local waste disposal
requirements may be more restrictive than federal laws and regulations.
Section 14 • Transport Information
Aerosols Only
Mode
Shipping Name
Hazard
Class
Subclass
UN
Number
Technical
Name
Hazard Label
Packing
Group
D.O.T.
Ground
IATA (US)
Consumer
Commodity
Consumer
Commodity
AEROSOLS,
flammable
AEROSOL
ORM-D
NA
1950
NA
ORM-D
NA
Emergency
Response
Guide
NA
9
NA
8000
NA
Miscellaneous
NA
NA
2.1
NA
1950
NA
NA
NA
2.1
NA
1950
NA
NA
F-D, S-U
NA
NA
1950
NA
Flammable
Gas
Flammable
Gas
NA
NA
F-D, S-U
IATA
(non-US)
IMDG
(Regular)
IMDG
(Special)
Dangerous Goods in
Limited quantities of
Class 2
Non-Aerosols of this product are not regulated by any mode of transportation.
Section 15 • Regulatory information
U.S. Federal
Regulations:
TSCA 8(b) inventory: All of the ingredients are listed on the TSCA inventory or are exempt.
RCRA Hazardous Waste No.: D003 (aerosols only)
CERCLA Sections 102a/103 Hazardous Substances (40 CFR part 302) Reportable Quantity: none
SARA TITLE III Sections 311/312 hazardous Categorization (40 CFR part 370): Sudden Release of Pressure
(aerosol only), Fire Hazard, Immediate (Acute) Health Hazard, Delayed (Chronic) Health Hazard.
SARA TITLE III Section 313: No individual section 313 component is present at or above 1%.
Hazardous Air Pollutants (U.S. EPA): None
State
Regulations:
New Jersey RTK: Distillates (Petroleum), Hydrotreated Light (CASRN: 64742-47-8) Distillates (Petroleum),
Hydrotreated Middle (CASRN: 64742-46-7), Carbon Dioxide Propellant (CASRN: 124-38-9) Calcium Sulfonate
(CASRN:61789-86-4), Sorbitan Trioleate (CASRN: 26266-58-0),
California Proposition 65: None.
California and OTC States: This product conforms to consumer regulations.
Current Revision 8/29/05 – Previous Revision: 5/10/05
CI-L-03
page 6 of 7
MATERIAL SAFETY DATA SHEET
LPS 1 Greaseless Lubricant
MSDS# 10116
Responsible Name: Ed Williams
Technical Manager
Section 16 • Other Information
HMIS-III
Health:
[/] 1
Flammability:
2
Physical Hazard: 2 (aerosol)
0 (other)
NFPA
flammability
2
health
1
0
reactivity
Notice to Reader:
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its
subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination
of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with
caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Ed Williams, Technical Manager
LPS Laboratories
A division of Illinois Tool Works
Current Revision 8/29/05 – Previous Revision: 5/10/05
CI-L-03
Form #2500
page 7 of 7
Product Name: MOBILTEMP SHC 32
Revision Date: 01Dec2005
Page 1 of 8
______________________________________________________________________________________________________________________
MATERIAL SAFETY DATA SHEET
SECTION 1
PRODUCT AND COMPANY IDENTIFICATION
PRODUCT
Product Name: MOBILTEMP SHC 32
Product Description: Synthetic Base Stocks and Additives
Product Code: 640219-00, 970894
Intended Use: Grease
COMPANY IDENTIFICATION
Supplier:
EXXON MOBIL CORPORATION
3225 GALLOWS RD.
FAIRFAX, VA. 22037 USA
24 Hour Health Emergency
609-737-4411
Transportation Emergency Phone
800-424-9300
ExxonMobil Transportation No.
281-834-3296
MSDS Requests
713-613-3661
Product Technical Information
800-662-4525, 800-947-9147
MSDS Internet Address
http://www.exxon.com, http://www.mobil.com
SECTION 2
COMPOSITION / INFORMATION ON INGREDIENTS
Reportable Hazardous Substance(s) or Complex Substance(s)
Name
CAS#
Concentration*
1-NAPHTHYLAMINE, N-PHENYLPENTAERYTHRITOL
SODIUM NITRITE
0.1 - 1.0%
1 - 5%
0.1 - 1.0%
90-30-2
115-77-5
7632-00-0
* All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume.
SECTION 3
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15).
POTENTIAL HEALTH EFFECTS
Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure
injection under skin may cause serious damage.
ENVIRONMENTAL HAZARDS
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
NFPA Hazard ID:
HMIS Hazard ID:
Health:
Health:
0
0
Flammability: 1
Flammability: 1
Reactivity: 0
Reactivity: 0
NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert
advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary
CI-L-04
Product Name: MOBILTEMP SHC 32
Revision Date: 01Dec2005
Page 2 of 8
______________________________________________________________________________________________________________________
from person to person.
SECTION 4
FIRST AID MEASURES
INHALATION
Under normal conditions of intended use, this material is not expected to be an inhalation hazard.
SKIN CONTACT
Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the
body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by
a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be
minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent
of injury.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.
INGESTION
First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.
Inappropriate Extinguishing Media: Straight Streams of Water
FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams,
sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed
spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to
protect personnel.
Hazardous Combustion Products: Aldehydes, Oxides of carbon, Sulfur oxides, Smoke, Fume, Incomplete
combustion products
FLAMMABILITY PROPERTIES
Flash Point [Method]: >204°C (400°F) [ EST. FOR OIL, ASTM D-92 (COC)]
Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D
Autoignition Temperature: N/D
SECTION 6
ACCIDENTAL RELEASE MEASURES
NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations. U.S. regulations require reporting releases of this material to the environment which exceed the
reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The National
CI-L-04
Product Name: MOBILTEMP SHC 32
Revision Date: 01Dec2005
Page 3 of 8
______________________________________________________________________________________________________________________
Response Center can be reached at (800)424-8802.
SPILL MANAGEMENT
Land Spill: Allow spilled material to solidify and scrape up with shovels into a suitable container for recycle or
disposal.
Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Skim from
surface.
Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7
HANDLING AND STORAGE
HANDLING
Prevent small spills and leakage to avoid slip hazard.
Static Accumulator: This material is not a static accumulator.
STORAGE
Do not store in open or unlabelled containers.
SECTION 8
EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMIT VALUES
Exposure limits/standards (Note: Exposure limits are not additive)
Source
PENTAERYTHRITOL
PENTAERYTHRITOL
PENTAERYTHRITOL
Form
Respirable
fraction.
Total dust.
Limit / Standard
TWA
5 mg/m3
Note
N/A
Source
OSHA Z1
TWA
TWA
N/A
N/A
OSHA Z1
ACGIH
15 mg/m3
10 mg/m3
NOTE: Limits/standards shown for guidance only. Follow applicable regulations.
ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation.
CI-L-04
Product Name: MOBILTEMP SHC 32
Revision Date: 01Dec2005
Page 4 of 8
______________________________________________________________________________________________________________________
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a
level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
No protection is ordinarily required under normal conditions of use and with adequate ventilation.
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Work conditions can greatly effect glove durability; inspect and replace worn or damaged
gloves. The types of gloves to be considered for this material include:
No protection is ordinarily required under normal conditions of use.
Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
No skin protection is ordinarily required under normal conditions of use. In accordance with good
industrial hygiene practices, precautions should be taken to avoid skin contact.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
ENVIRONMENTAL CONTROLS
See Sections 6, 7, 12, 13.
SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional
data.
GENERAL INFORMATION
Physical State: Solid
Form: Semi-fluid
Color: Red
Odor: Characteristic
Odor Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15 °C ): 0.952
CI-L-04
Product Name: MOBILTEMP SHC 32
Revision Date: 01Dec2005
Page 5 of 8
______________________________________________________________________________________________________________________
Flash Point [Method]: >204°C (400°F) [ EST. FOR OIL, ASTM D-92 (COC)]
Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D
Autoignition Temperature: N/D
Boiling Point / Range: > 316°C (600°F)
Vapor Density (Air = 1): N/D
Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20°C
Evaporation Rate (n-butyl acetate = 1): N/D
pH: N/A
Log Pow (n-Octanol/Water Partition Coefficient): > 3.5
Solubility in Water: Negligible
Viscosity: 29.2 cSt (29.2 mm²/sec ) at 40 °C
Oxidizing Properties: See Sections 3, 15, 16.
OTHER INFORMATION
Freezing Point: N/D
Melting Point: N/D
NOTE: Most physical properties above are for the oil component in the material.
SECTION 10
STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions.
CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition.
MATERIALS TO AVOID: Strong oxidizers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.
HAZARDOUS POLYMERIZATION: Will not occur.
SECTION 11
ACUTE TOXICITY
Route of Exposure
Inhalation
Toxicity (Rat): LC50 > 5000 mg/m3
Irritation: No end point data.
Ingestion
Toxicity (Rat): LD50 > 2000 mg/kg
Skin
Toxicity (Rabbit): LD50 > 2000 mg/kg
Irritation (Rabbit): Data available.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on assessment of the components.
Negligible hazard at ambient/normal handling temperatures.
Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar
materials.
Minimally Toxic. Based on test data for structurally similar
materials.
Negligible irritation to skin at ambient temperatures. Based on
assessment of the components.
Eye
Irritation (Rabbit): Data available.
CI-L-04
May cause mild, short-lasting discomfort to eyes. Based on
Product Name: MOBILTEMP SHC 32
Revision Date: 01Dec2005
Page 6 of 8
______________________________________________________________________________________________________________________
assessment of the components.
CHRONIC/OTHER EFFECTS
Contains:
Synthetic base oils: Not expected to cause significant health effects under conditions of normal use, based on
laboratory studies with the same or similar materials. Not mutagenic or genotoxic. Not sensitizing in test
animals and humans.
Phenyl-alpha-naphthylamine (PAN): Undiluted PAN is a skin sensitizer. Human testing with lubricants
containing 1.0% PAN caused no reactions indicative of sensitization.
Additional information is available by request.
The following ingredients are cited on the lists below: None.
1 = NTP CARC
2 = NTP SUS
SECTION 12
--REGULATORY LISTS SEARCHED-3 = IARC 1
5 = IARC 2B
4 = IARC 2A
6 = OSHA CARC
ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials.
ECOTOXICITY
Material -- Expected to be harmful to aquatic organisms. May cause long-term adverse effects in the aquatic
environment.
MOBILITY
Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to
partition to sediment and wastewater solids.
PERSISTENCE AND DEGRADABILITY
Biodegradation:
Base oil component -- Expected to be inherently biodegradable
BIOACCUMULATION POTENTIAL
Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may
reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.
DISPOSAL RECOMMENDATIONS
Suitable routes of disposal are supervised incineration, preferentially with energy recovery, or appropriate
CI-L-04
Product Name: MOBILTEMP SHC 32
Revision Date: 01Dec2005
Page 7 of 8
______________________________________________________________________________________________________________________
recycling methods in accordance with applicable regulations and material characteristics at the time of disposal.
REGULATORY DISPOSAL INFORMATION
RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous
waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It
does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with
contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used
product may be regulated.
Empty Container Warning PRECAUTIONARY LABEL TEXT: Empty containers may retain residue and can be
dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH
CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY
MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or clean container since residue is difficult
to remove. Empty drums should be completely drained, properly bunged and promptly returned to a drum
reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with
governmental regulations.
SECTION 14
TRANSPORT INFORMATION
LAND (DOT) : Not Regulated for Land Transport
LAND (TDG) : Not Regulated for Land Transport
SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code
AIR (IATA) : Not Regulated for Air Transport
SECTION 15
REGULATORY INFORMATION
OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not classified
as hazardous in accordance with OSHA 29 CFR 1910.1200.
NATIONAL CHEMICAL INVENTORY LISTING: AICS, EINECS, TSCA
EPCRA: This material contains no extremely hazardous substances.
SARA (311/312) REPORTABLE HAZARD CATEGORIES: None.
SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification
requirements of the SARA 313 Toxic Release Program.
The Following Ingredients are Cited on the Lists Below:*
Chemical Name
CAS Number
DIPHENYLAMINE
122-39-4
PENTAERYTHRITOL
115-77-5
CI-L-04
List Citations
5, 9
1, 4, 13, 16, 19
Product Name: MOBILTEMP SHC 32
Revision Date: 01Dec2005
Page 8 of 8
______________________________________________________________________________________________________________________
1 = ACGIH ALL
2 = ACGIH A1
3 = ACGIH A2
4 = OSHA Z
5 = TSCA 4
--REGULATORY LISTS SEARCHED-6 = TSCA 5a2
11 = CA P65 REPRO
7 = TSCA 5e
12 = CA RTK
8 = TSCA 6
13 = IL RTK
9 = TSCA 12b
14 = LA RTK
10 = CA P65 CARC
15 = MI 293
16 = MN RTK
17 = NJ RTK
18 = PA RTK
19 = RI RTK
Code key: CARC=Carcinogen; REPRO=Reproductive
* EPA recently added new chemical substances to its TSCA Section 4 test rules. Please contact the supplier to confirm
whether the ingredients in this product currently appear on a TSCA 4 or TSCA 12b list.
SECTION 16
OTHER INFORMATION
N/D = Not determined, N/A = Not applicable
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:
No revision information is available.
--------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate
and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current
available from ExxonMobil. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for
convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any
affiliates in which they directly or indirectly hold any interest.
----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only
MHC: 0, 0, 0, 0, 0, 0
PPEC: A
DGN: 2009817XUS (555181)
----------------------------------------------------------------------------------------------------------------------------------------------------Copyright 2002 Exxon Mobil Corporation, All rights reserved
CI-L-04
Vulcan Oil & Chemical Products
5353 Spring Grove Avenue
Cincinnati, Ohio 45217
Phone: 513-242-2672
Product Code:ARIES series
Revision Date: 01/21/2004
Material Safety Data Sheet
Page 1 of 4
Section 1 - Product Identification
Product Name: Aries Antiwear Hydraulic Oil Series- ISO 10-460
Hazard Rating
Health
Fire
Reactivity
NFPA Code:
1
1
0
0=Least
1=Slight
2=Moderate 3=High
4=Extreme
________________________________________________________________________________
Section 2 - Hazardous Ingredients / Identity Information
Specific Identity; Common Names
OSHA PEL ACGIH TLV
Other
Proprietary Formula - Specific Chemical Identities Have Been Withheld
These products may contain one or more of the following:
64741-95-3
Deasphalted Residuum
64742-01-4
Petroleum Hydrocarbon
64742-52-5
Heavy Naphthenic Hydrotreated Distillates
64742-56-9
Hydrotreated light paraffinic neutral
-
-
5 mg/m3
(mist)
5 mg/m3
(mist)
5 mg/m3
(mist)
5mg/m3
(mist)
5 mg/m3
5 mg/m3
64742-65-0
Petroleum Distillates, Solvent Dewaxed Heavy Para- 5mg/m3
ffinic (Severely refined paraffinic oil)
(mist)
5mg/m3
(mist)
Stel
10mg/m3
TSCA
All components of these products are included in the TCSA inventory or are regulated
under FIFRA.
________________________________________________________________________________
Section 3 - Physical/Chemical Characteristics
Appearance
Amber liquid
Boiling Point, Deg. F
Not Known
Evaporation, BuAcetate=1
Slower than
Evaporation Rate Ether=1
Slower than
Odor
Mild
Solubility in water
Negligible
Vapor Density (Air=1)
Not Known
Vapor Pressure
Not Known
Pounds per Gallon
7.1-7.4
Specific Gravity
0.85-0.89
________________________________________________________________________________
Section 4 - Fire and Explosion Hazard Data
Flash Point COC:
>300F
Flammable Limits: LEL-Not Known
UEL-Not Known
Extinguishing Media: Foam, dry chemical, water fog, carbon dioxide. Do not
CI-L-05
Vulcan Oil & Chemical Products
5353 Spring Grove Avenue
Cincinnati, Ohio 45217
Phone: 513-242-2672
Product Code:ARIES series
Revision Date: 01/21/2004
Material Safety Data Sheet
Page 2 of 4
use a direct stream of water.
Special Fire Fighting Procedures: Cool fire exposed containers with water.
Do not enter a confined fire space without full bunker gear and NIOSH
approved supplied air breathing apparatus.
Unusual Fire and Explosion Hazards: Not Applicable
________________________________________________________________________________
Section 5 - Reactivity Data
Stability - Stable.
Incompatibility - Strong acids. Strong oxidizing agents.
Hazardous Decomposition Products - Aldehydes. Hydrogen sulfide. Oxides of
carbon. Oxides of nitrogen. Oxides of phosphorus. Oxides of sulfur.
Hazardous Polymerization - Will not occur.
Other - Not Applicable.
________________________________________________________________________________
Section 6 - Health Hazard Data
Routes of Entry: Inhalation-yes
Skin-yes
Ingestion-yes
Health Hazards :
Health hazards for components to this mixture are listed below:
(Acute and Chronic Overexposure)
Eyes - Moderate irritation. Redness.
Skin - Prolonged and repeated contact can defat the skin which may result in
dryness, dermatitis, and cracking of the skin.
Repeated or prolonged contact may cause defatting, oil acne, irritation or
allergic reaction in sensitive individuals.
Inhalation - Irritation of nasal and respiratory passages.
Ingestion - Abdominal cramps. Diarrhea. Gastrointestinal irritation. Nausea.
Stomach discomfort. Vomiting. Pulmonary aspiration hazard if swallowed and vomiting
occurs.
Signs And Symptoms of Exposure - As Noted Above.
Medical Conditions Generally Aggravated By Exposure - None Known.
Other Precautions - NA
Other - Components have been associated with photosensitivity, an abnormal
sensitivity of skin to sunlight.
Carcinogenicity
NTP-No
IARC-No
OSHA-No
Emergency and First Aid Procedures:
Inhalation - remove to fresh air. If breathing is difficult, give oxygen.
If breathing is stopped, begin artificial respiration. Get medical attention.
Skin contact - wash skin thoroughly with soap and water. Remove and wash
contaminated clothing before reuse. If product is injected into or under the
skin, or into any part of the body, regardless of the appearance of the wound
or its size, the individual should be evaluated immediately by a physician as
a surgical emergency. Even though initial symptoms from high pressure injection
may be minimal or absent, early surgical treatment within the first few hours
may significantly reduce the ultimate extent of the injury.
CI-L-05
Vulcan Oil & Chemical Products
5353 Spring Grove Avenue
Cincinnati, Ohio 45217
Phone: 513-242-2672
Product Code:ARIES series
Revision Date: 01/21/2004
Material Safety Data Sheet
Page 3 of 4
Eye contact - flush with water for at least 15 minutes or until irritation
subsides, get medical attention.
Ingestion - DO NOT induce vomiting; get medical attention immediately.
________________________________________________________________________________
Section 7 - Precautions for Safe Handling and Use
Steps to be Taken in Case Material is Released or Spilled:
Dike area. Recover free product. Add a dry absorbent material to spill
area.
Waste Disposal Method: Dispose by methods consistent with local state and
federal regulations.
Precautions to be Taken in Handling and Storing:
Keep containers tightly
closed. Use and store this product with adequate ventilation. Avoid
inhalation of vapors and personal contact with the product. To
dissipate static electricity during transfer, ground and/or bond both
containers. Since emptied containers retain product residue, follow
warnings even after container is emptied. Residue or vapors may
explode on ignition; do not cut, drill, grind or weld on or near
container even when empty.
Other Precautions:
Not Applicable
________________________________________________________________________________
Section 8 - Control Measures
Respiratory Protection: Not normally required. Use NIOSH approved supplied
air breathing equipment if vapors are excessive.
Ventilation:
Local Exhaust :
Not normally required.
Mechanical (General):
Use general ventilation.
Protective Gloves: Use chemical-resistant gloves, if needed, to avoid skin
contact.
Eye Protection: Use splash goggles or face shield when eye contact may
occur.
Other Protective Clothing or Equipment: To prevent repeated or prolonged
skin contact, wear impervious apron/clothing and boots.
Work/Hygienic Practices: Minimize breathing vapor, mist or fumes. Wash
skin with soap and water after contact. Launder contaminated
clothing.
________________________________________________________________________________
Section 9 - Regulatory Information
DOT Information
DOT Proper Shipping Name:
None
DOT Hazard Code:
None
UN Number:
None
Section 313 Supplier Notification
This product contains the following chemicals subject to the reporting
requirements of section 313 of the Emergency Planning and Community RightTo-Know Act of 1986 (40 CFR 372):
CAS#
Common Name
Weight%
This information should be included in all MSDSs that are copied and
distributed for this material.
CI-L-05
Vulcan Oil & Chemical Products
5353 Spring Grove Avenue
Cincinnati, Ohio 45217
Phone: 513-242-2672
Product Code:ARIES series
Revision Date: 01/21/2004
Material Safety Data Sheet
Page 4 of 4
________________________________________________________________________________
The information set forth herein is furnished free of charge and is based
on technical data that Vulcan believes to be reliable. It is intended for
use by persons having technical skill and at their own discretion and risk.
Since conditions of use are outside our control, we make no warranties,
express or implied, and assume no liability in connection with any use of
the information. Nothing herein is to be taken as a license to operate
under or a recommendation to infringe any patents.
CI-L-05
Vulcan Oil & Chemical Products
5353 Spring Grove Avenue
Cincinnati, Ohio 45217
Phone: 513-242-2672
Product Code: STGR Series
Revision Date:
11/23/94
Material Safety Data Sheet
Page 1 of 3
Section 1 - Product Identification
Product Name: Stearogear Gear Oils - XL-1,L-2,LL-3,M-6,M-7,H-10,H-10S,H-115,
H-Lite,Heavy,Heavy 150,Heavy 250,Extra Heavy 250,Extra Heavy 500
Hazard Rating
Health
Fire
Reactivity
NFPA Code:
1
1
0
0=Least
1=Slight
2=Moderate 3=High
4=Extreme
________________________________________________________________________________
Section 2 - Hazardous Ingredients / Identity Information
Specific Identity; Common Names
OSHA PEL ACGIH TLV
Other
Proprietary Formula - Specific Chemical Identities Have Been Withheld
These products contain one or more of the following:
64741-95-3
Deasphalted Residuum
64742-52-5
Heavy Naphthenic Hydrotreated Distillates
64742-54-7
Distillates(petroleum), hydrotreated heavy
paraffinic
64742-57-0
Residual oils(petroleum), hydrotreated
64742-62-0
Residual oils(petroleum), solvent-dewaxed
-
-
5 mg/m3
(mist)
5mg/m3
(mist)
5 mg/m3
(mist)
5 mg/m3
(mist)
5 mg/m3
(mist)
5mg/m3
(mist)
5 mg/m3
(mist)
5 mg/m3
(mist)
64742-65-0
Distillates(petroleum), solvent-dewaxed heavy
5 mg/m3
5mg/m3
paraffinic
(mist)
(mist)
________________________________________________________________________________
Section 3 - Physical/Chemical Characteristics
Appearance
Amber-Dark amber liquid
Boiling Point, Deg. F
Not Known
Evaporation, BuAcetate=1
Slower than
Odor
Mild
Solubility in water
Negligible
Vapor Density (Air=1)
Not Known
Vapor Pressure
Not Known
Pounds per Gallon
approx. 7.5
Specific Gravity
~ 0.9
________________________________________________________________________________
Section 4 - Fire and Explosion Hazard Data
Flash Point COC:
>350F
Flammable Limits: LEL-Not Known
UEL-Not Known
Extinguishing Media: Foam, dry chemical, water fog, carbon dioxide. Do not
use a direct stream of water.
Special Fire Fighting Procedures: Cool fire exposed containers with water.
Do not enter a confined fire space without full bunker gear and NIOSH
approved supplied air breathing apparatus.
Unusual Fire and Explosion Hazards: Not Applicable
CI-L-06
Vulcan Oil & Chemical Products
5353 Spring Grove Avenue
Cincinnati, Ohio 45217
Phone: 513-242-2672
Product Code: STGR Series
Revision Date:
11/23/94
Material Safety Data Sheet
Page 2 of 3
________________________________________________________________________________
Section 5 - Reactivity Data
Stability - Stable.
Incompatibility - Oxidizing agents.
Hazardous Decomposition Products - Oxides of carbon. Oxides of nitrogen. Oxides
of phosphorus. Oxides of sulfur.
Free aromatic amine may be released in reducing atmosphere.
Hazardous Polymerization - Will not occur.
Other - Not Applicable.
________________________________________________________________________________
Section 6 - Health Hazard Data
Routes of Entry: Inhalation-yes
Skin-yes
Ingestion-yes
Health Hazards :
Health hazards for components to this mixture are listed below:
(Acute and Chronic Overexposure)
Eyes - Moderate irritation.
Skin - Irritation.
Prolonged and repeated contact can defat the skin which may result in dryness,
dermatitis, and cracking of the skin.
Components have been associated with photosensitivity, an abnormal sensitivity
of skin to sunlight.
Inhalation - Irritation of nasal and respiratory passages.
Ingestion - Diarrhea. Gastrointestinal irritation. Nausea. Vomiting.
Pulmonary aspiration hazard if swallowed and vomiting occurs.
Signs And Symptoms of Exposure - As Noted Above.
Medical Conditions Generally Aggravated By Exposure - None Known.
Other Precautions - NA
Other - NA
Carcinogenicity
NTP-No
IARC-No
OSHA-No
Emergency and First Aid Procedures:
Inhalation - remove to fresh air. If breathing is difficult, give oxygen.
If breathing is stopped, begin artificial respiration. Get medical attention.
Skin contact - wash skin thoroughly with soap and water. Remove and wash
contaminated clothing before reuse. If product is injected into or under the
skin, or into any part of the body, regardless of the appearance of the wound
or its size, the individual should be evaluated immediately by a physician as
a surgical emergency. Even though initial symptoms from high pressure injection
may be minimal or absent, early surgical treatment within the first few hours
may significantly reduce the ultimate extent of the injury.
Eye contact - flush with water for at least 15 minutes or until irritation
subsides, get medical attention.
Ingestion - DO NOT induce vomiting; get medical attention immediately.
________________________________________________________________________________
Section 7 - Precautions for Safe Handling and Use
Steps to be Taken in Case Material is Released or Spilled:
Dike area. Recover free product. Add a dry absorbent material to spill
area.
Waste Disposal Method: Dispose by methods consistent with local state and
federal regulations.
CI-L-06
Vulcan Oil & Chemical Products
5353 Spring Grove Avenue
Cincinnati, Ohio 45217
Phone: 513-242-2672
Product Code: STGR Series
Revision Date:
11/23/94
Material Safety Data Sheet
Page 3 of 3
Precautions to be Taken in Handling and Storing:
Keep containers tightly
closed. Use and store this product with adequate ventilation. Avoid
inhalation of vapors and personal contact with the product. To
dissipate static electricity during transfer, ground and/or bond both
containers. Since emptied containers retain product residue, follow
warnings even after container is emptied. Residue or vapors may
explode on ignition; do not cut, drill, grind or weld on or near
container even when empty.
Other Precautions:
Not Applicable
_______________________________________________________________________________
Section 8 - Control Measures
Respiratory Protection: Not normally required. Use NIOSH approved supplied
air breathing equipment if vapors are excessive.
Ventilation:
Local Exhaust :
Not normally required.
Mechanical (General):
Use general ventilation.
Protective Gloves: Use chemical-resistant gloves, if needed, to avoid skin
contact.
Eye Protection: Use splash goggles or face shield when eye contact may
occur.
Other Protective Clothing or Equipment: To prevent repeated or prolonged
skin contact, wear impervious apron/clothing and boots.
Work/Hygienic Practices: Minimize breathing vapor, mist or fumes. Wash
skin with soap and water after contact. Launder contaminated
clothing.
_______________________________________________________________________________
Section 9 - Regulatory Information
DOT Information
DOT Proper Shipping Name:
None
DOT Hazard Code:
None
UN Number:
None
Section 313 Supplier Notification
This product contains the following chemicals subject to the reporting
requirements of section 313 of the Emergency Planning and Community RightTo-Know Act of 1986 (40 CFR 372):
CAS#
Common Name
None
Weight%
This information should be included in all MSDSs that are copied and
distributed for this material.
________________________________________________________________________________
The information set forth herein is furnished free of charge and is based
on technical data that Vulcan believes to be reliable. It is intended for
use by persons having technical skill and at their own discretion and risk.
Since conditions of use are outside our control, we make no warranties,
express or implied, and assume no liability in connection with any use of
the information. Nothing herein is to be taken as a license to operate
under or a recommendation to infringe any patents.
CI-L-06
Vulcan Oil & Chemical Products
A Division of
The Cincinnati Vulcan Company
5353 Spring Grove Avenue
Cincinnati, Ohio 45217
Phone: 513-242-2672
www.vulcanoil.com
Material Safety Data Sheet
Product Code: SCO650RP
Revision Date: 01/20/2004
Revised By: MSDS Dept.
Page:
1
Section 1 - Product Identification
Product Name: SCO 650-RP Rust Inhibited Steam Cylinder Oil
Hazard Rating
Health
Fire
Reactivity
NFPA Code:
1
1
0
0=Least
1=Slight
2=Moderate 3=High
4=Extreme
________________________________________________________________________________
Section 2 - Hazardous Ingredients / Identity Information
Specific Identity; Common Names
OSHA PEL ACGIH TLV
Other
Proprietary Formula - Specific Chemical Identities Have Been Withheld
64742-01-4
Residual oils, petroleum, solvent-refined
64742-57-0
Residual oils (petroleum), hydrotreated
5 mg/m3
(mist)
5 mg/m3
(mist)
5 mg/m3
(mist)
5 mg/m3
(mist)
64742-62-7
Residual oils (petroleum), solvent-dewaxed
5 mg/m3
5 mg/m3
(mist)
(mist)
________________________________________________________________________________
Section 3 - Physical/Chemical Characteristics
Appearance
Dark liquid
Boiling Point, Deg. F
Not Known
Evaporation, BuAcetate=1
Slower than
Odor
Mild
Solubility in water
Negligible
Vapor Density (Air=1)
Not Known
Vapor Pressure
Not Known
Pounds per Gallon
7.484
Specific Gravity
0.899
________________________________________________________________________________
Section 4 - Fire and Explosion Hazard Data
Flash Point COC:
>350F
Flammable Limits: LEL-Not Known
UEL-Not Known
Extinguishing Media: Foam, dry chemical, water fog, carbon dioxide. Do not
use a direct stream of water.
Special Fire Fighting Procedures: Cool fire exposed containers with water.
Do not enter a confined fire space without full bunker gear and NIOSH
approved supplied air breathing apparatus.
Unusual Fire and Explosion Hazards: Not Applicable
________________________________________________________________________________
Section 5 - Reactivity Data
Stability - Stable.
Incompatibility - Oxidizing agents.
Hazardous Decomposition Products - Acrolein. Oxides of carbon. Oxides of
nitrogen. Oxides of sulfur.
Hazardous Polymerization - Will not occur.
Other - Not Applicable.
________________________________________________________________________________
Section 6 - Health Hazard Data
Routes of Entry: Inhalation-yes
Skin-yes
Ingestion-yes
Health Hazards :
Health hazards for components to this mixture are listed below:
CI-L-07
continued...
Vulcan Oil & Chemical Products
A Division of
The Cincinnati Vulcan Company
5353 Spring Grove Avenue
Cincinnati, Ohio 45217
Phone: 513-242-2672
www.vulcanoil.com
...continued
(Acute and Chronic Overexposure)
Material Safety Data Sheet
Product Code: SCO650RP
Revision Date: 01/20/2004
Revised By: MSDS Dept.
Page:
2
Eyes - Moderate irritation.
Skin - Slight irritation.
Repeated or prolonged contact may cause defatting, oil acne, irritation or
allergic reaction in sensitive individuals.
Inhalation - Dizziness. Irritation of nasal and respiratory passages. Nausea.
Watering of eyes.
Ingestion - Diarrhea. Gastrointestinal irritation. Nausea. Vomiting.
Pulmonary aspiration hazard if swallowed and vomiting occurs.
Signs And Symptoms of Exposure - As Noted Above.
Medical Conditions Generally Aggravated By Exposure - None Known.
Other Precautions - NA
Other - NA
Carcinogenicity
NTP-No
IARC-No
OSHA-No
Emergency and First Aid Procedures:
Inhalation - remove to fresh air. If breathing is difficult, give oxygen.
If breathing is stopped, begin artificial respiration. Get medical attention.
Skin contact - wash skin thoroughly with soap and water. Remove and wash
contaminated clothing before reuse. If product is injected into or under the
skin, or into any part of the body, regardless of the appearance of the wound
or its size, the individual should be evaluated immediately by a physician as
a surgical emergency. Even though initial symptoms from high pressure injection
may be minimal or absent, early surgical treatment within the first few hours
may significantly reduce the ultimate extent of the injury.
Eye contact - flush with water for at least 15 minutes or until irritation
subsides, get medical attention.
Ingestion - DO NOT induce vomiting; get medical attention immediately.
________________________________________________________________________________
Section 7 - Precautions for Safe Handling and Use
Steps to be Taken in Case Material is Released or Spilled:
Dike area. Recover free product. Add a dry absorbent material to spill
area.
Waste Disposal Method: Dispose by methods consistent with local state and
federal regulations.
Precautions to be Taken in Handling and Storing:
Keep containers tightly
closed. Use and store this product with adequate ventilation. Avoid
inhalation of vapors and personal contact with the product. To
dissipate static electricity during transfer, ground and/or bond both
containers. Since emptied containers retain product residue, follow
warnings even after container is emptied. Residue or vapors may
explode on ignition; do not cut, drill, grind or weld on or near
container even when empty.
Other Precautions:
Not Applicable
________________________________________________________________________________
Section 8 - Control Measures
Respiratory Protection: Not normally required. Use NIOSH approved supplied
air breathing equipment if vapors are excessive.
CI-L-07
continued...
Vulcan Oil & Chemical Products
A Division of
The Cincinnati Vulcan Company
Product Code: SCO650RP
Revision Date: 01/20/2004
Revised By: MSDS Dept.
Page:
3
5353 Spring Grove Avenue
Cincinnati, Ohio 45217
Phone: 513-242-2672
www.vulcanoil.com
...continued
Ventilation:
Local Exhaust :
Not normally required.
Mechanical (General):
Use general ventilation.
Protective Gloves: Use chemical-resistant gloves, if needed, to avoid skin
contact.
Eye Protection: Use splash goggles or face shield when eye contact may
occur.
Other Protective Clothing or Equipment: To prevent repeated or prolonged
skin contact, wear impervious apron/clothing and boots.
Work/Hygienic Practices: Minimize breathing vapor, mist or fumes. Wash
skin with soap and water after contact. Launder contaminated
clothing.
________________________________________________________________________________
Section 9 - Regulatory Information
DOT Information
DOT Proper Shipping Name:
None
DOT Hazard Code:
None
UN Number:
None
Material Safety Data Sheet
Section 313 Supplier Notification
This product contains the following chemicals subject to the reporting
requirements of section 313 of the Emergency Planning and Community RightTo-Know Act of 1986 (40 CFR 372):
CAS#
Common Name
None
Weight%
This information should be included in all MSDSs that are copied and
distributed for this material.
________________________________________________________________________________
Prepared according to the OSHA Hazard Communication Standard
(29 CFR 1910.1200) by Vulcan Oil & Chemical Products.
________________________________________________________________________________
The information set forth herein is furnished free of charge and is based
on technical data that Vulcan believes to be reliable. It is intended for
use by persons having technical skill and at their own discretion and risk.
Since conditions of use are outside our control, we make no warranties,
express or implied, and assume no liability in connection with any use of
the information. Nothing herein is to be taken as a license to operate
under or a recommendation to infringe any patents.
End of MSDS
CI-L-07
Material Safety Data Sheet
Anderol 2100 HTCL
Series
Section 1. Chemical product and company identification
Common name
Synonym
Trade name
MSDS#
Material use
Supplier/Manufacturer
In case of emergency
:
:
:
:
:
:
Anderol 2100 HTCL Series
Lubricant.
Anderol 2100 HTCL; 2150 HTCL; 2220 HTCL; 2320 HTCL; 2460 HTCL;
EH1050
Lubricant.
Anderol Inc., 215 Merry Lane, East Hanover, NJ 07936
Tel: (973) 887-7410 Fax: (973) 887-8422
: CHEMTREC: 800-424-9300 (United States)
Section 2. Hazards identification
Physical state
Emergency overview
: Liquid (Clear).
: No specific hazard.
USE WITH CARE.
Follow good industrial hygiene practice.
: Dermal contact. Eye contact. Inhalation. Ingestion.
Routes of entry
Potential acute health effects
:
Eyes
:
Skin
:
Inhalation
:
Ingestion
Potential chronic health
:
effects
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Carcinogenic effects: Not applicable.
Mutagenic effects: Not applicable.
Teratogenic effects: Not applicable.
See toxicological information (section 11)
Section 3. Composition, Information on Ingredients
This material is classified as not hazardous under OSHA regulations in the United States, the WHMIS in Canada, the
NOM-018-STPS-2000 in Mexico and Brazil NBR 14725:2001.
See Chapters 8, 11 and 14 for details.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
Notes to physician
: Check for and remove any contact lenses. In case of contact, immediately flush skin
with plenty of water for at least 20 minutes while removing contaminated clothing and
shoes. Get medical attention if irritation occurs.
: Wash with soap and water. Get medical attention if irritation occurs.
: If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medical
attention if symptoms appear.
: Do not induce vomiting. Never give anything by mouth to an unconscious person. Get
medical attention if symptoms appear.
: Not available.
Section 5. Fire fighting measures
Flammability of the product : May be combustible at high temperature.
Flash point
: Open cup: 266°C (510.8°F) (Cleveland.).
Products of combustion
: The final products of combustion are carbon oxides and water. Nitrogen, sulfur and
metal oxides may also be produced in some cases.
Fire-fighting media and
: Use an extinguishing agent suitable for the surrounding fire.
instructions
Date of issue
: 07/15/2005
CI-L-08
Page: 1/4
Anderol 2100 HTCL Series
Special protective
equipment for fire-fighters
Special remarks on fire
hazards
No specific hazard.
: Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
: Container explosion may occur under fire conditions or when heated. Cool closed
containers exposed to fire with water.
Section 6. Accidental release measures
: Immediately contact emergency personnel. Keep unnecessary personnel away. Use
suitable protective equipment.
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Methods for cleaning up
: If emergency personnel are unavailable, contain spilled material. For small spills, add
absorbent (soil may be used in the absence of other suitable materials), scoop up
material and place in a sealable, liquid-proof container for disposal. For large spills, dike
spilled material or otherwise contain material to ensure runoff does not reach a
waterway. Place spilled material in an appropriate container for disposal.
Personal precautions
Section 7. Handling and storage
: Wash thoroughly after handling.
: Keep container tightly closed. Keep container in a cool, well-ventilated area.
Handling
Storage
Section 8. Exposure controls, personal protection
Engineering controls
: Good general ventilation should be sufficient to control airborne levels.
Ensure that eyewash stations and safety showers are close to the
workstation location.
Personal protection
Eye protection
: Safety glasses with side shields.
Respiratory protection
: Not applicable.
Hand protection
: Natural rubber (latex).
Skin protection/Body
: Not applicable.
Personal protection in case : Safety glasses, goggles or face shield. Impervious gloves. Full suit. Boots. Wear
MSHA/NIOSH-approved self-contained breathing apparatus or equivalent and full
of a large spill
protective gear.
Consult local authorities for acceptable exposure limits.
Section 9. Physical and chemical properties
Physical state
Color
Odor
Specific gravity
Date of issue
:
:
:
:
: 07/15/2005
Liquid (Clear).
Yellow.
Mild.
0.92 (Water = 1)
CI-L-08
Page: 2/4
Anderol 2100 HTCL Series
Section 10. Stability and reactivity
Stability and reactivity
: The product is stable.
Incompatibility with various : Reactive with oxidizing materials.
substances
Hazardous polymerization : Will not occur.
Section 11. Toxicological information
Acute Effects
Eyes
Skin
Inhalation
Ingestion
Potential chronic health
effects
:
:
:
:
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Carcinogenic effects: Not applicable.
Mutagenic effects: Not applicable.
Teratogenic effects: Not applicable.
Section 12. Ecological information
Products of degradation
: The final products of biodegradation are carbon oxides and water. Nitrogen and sulfur
oxides and metal salts may also be produced in some cases.
Section 13. Disposal considerations
: The generation of waste should be avoided or minimized wherever possible. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers. Disposal of this product, solutions and any by-products should at all times
comply with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements.
Waste disposal
Consult your local or regional authorities.
Section 14. Transport information
Classification
Brazil/ Mexico/ TDG/ DOT/ IMDG/ IATA : Not regulated.
Label
Not applicable.
Additional information
Not applicable.
Section 15. Regulatory information
United States
U.S. Federal regulations
Date of issue
: TSCA 8(b) inventory: All components listed.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: No products were found.
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No
products were found.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean Air Act (CAA) 112 accidental release prevention: No products were found.
Clean Air Act (CAA) 112 regulated flammable substances: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
: 07/15/2005
CI-L-08
Page: 3/4
Anderol 2100 HTCL Series
State regulations
Canada
WHMIS (Canada)
Mexico
Classification
: Pennsylvania RTK: Triphenyl phosphate: (generic environmental hazard)
Massachusetts RTK: Triphenyl phosphate; Benzotriazole
New Jersey: Triphenyl phosphate; 1-Naphthaleneamine, N-Phenyl-AR-(1,1,3,3Tetramethylbutyl)California prop. 65: No products were found.
: Not controlled under WHMIS (Canada).
CEPA DSL: All components listed.
:
Flammability
1
Health
0
0
Reactivity
Special
International regulations
International lists
: Australia (NICNAS); CHINA INVENTORY (IECS); JAPAN INVENTORY (ENCS);
KOREA INVENTORY (ECL); PHILIPPINE INVENTORY (PICCS): All components listed.
Section 16. Other information
Hazardous Material
:
Information System (U.S.A.)
National Fire Protection
Association (U.S.A.)
Health
0
Fire hazard
1
Reactivity
0
Personal protection
C
:
Flammability
1
Health
0
0
Instability
Special
References
: ANSI Z400.1, MSDS Standard, 2004. - Manufacturer's Material Safety Data Sheet. 29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of Hazardous
Materials, UN#, Proper Shipping Names, PG. - Canada Gazette Part II, Vol. 122, No. 2.
Registration SOR/88-64, 31 December 1987. Hazardous Products Act "Ingredient
Disclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules,
Clear Language version 2002. - Official Mexican Standards NOM-018-STPS-2000 and
NOM-004-SCT2-1994. Brazil NBR 14725:2001.
Responsible name
: Mr. Max Naggar
Date of issue
: 07/15/2005
Version
: 1
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named
supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Date of issue
: 07/15/2005
CI-L-08
Page: 4/4
SAFETY DATA SHEET according to Regulation (EC)No 1907/2006
Date of last alteration:
Jan. 27, 2010
1. Identification of the substance / preparation and company
Product name:
NEOVAC SA-H
Company:
MORESCO Corporation
5-3, MINATOJIMAMINAMIMACHI 5-CHOME,
CHUO-KU, KOBE-CITY, HYOGO 650-0047
JAPAN
Telephone: 03(3273)7526
Telefax:
03(3281)7756
2. Hazards identification
Physical hazards:
Not Classified
Health hazards:
Not Classified
Environmental hazards:
Not Classified
3. Composition / Information on ingredients
Substance
Wt %
Cas№
Alkyl diphenyl ether
99~100
153454-38-7、85967-29-9
Lubricating oil additive
approx. 1%
2082-79-3、123-28-4
4. First aid measures
General:
In case of symptoms or any doubt, contact a physician.
Inhalation:
Remove to outside air.
Eye contact:
Immediately flush eyes with plenty of water for at least
15 minutes. If irritation persists, get medical attention.
Skin contact:
Wash with mild soap and water. If irritation persists,
seek medical attention.
Ingestion:
Do not induce vomiting. Get medical attention.
Other information:
None
5. Fire-fighting measures
Extinguishing media:
(NEOVAC SA-H)
Dry chemical, CO2, Foam
Page 1/4
CI-L-09
(according to 1907/2006)
6. Accidental release measures
Measures after spillage or leaking:
Eliminate ignition sources.
Recover free liquid into an empty container.
Personal precautions:
Use with adequate ventilation.
Wear safety gloves and glasses.
7. Handling and storage
Handling:
Use with adequate ventilation.
Wear safety gloves and goggles.
Storage:
Store indoors and close tightly with cap.
Keep the storage temperature in the range from 0℃ to 40℃.
Keep away from heat, open flame, sparks and other possible
ignition sources.
Prevent accumulation of static electricity.
Keep away from halogens, strong acids, alkaline agents and
oxidizing agents.
8. Exposure control / Personal protection
Exposure limits (TLV):
No information
Skin protection:
Safety gloves
Eye protection:
Safety goggles
Respiratory protection:
Not normally required.
9. Physical and chemical properties
Physical state at 20 °C:
Liquid
Color:
Light yellow
Odor:
Slight oily odor
Pour point:
-20°C max.
Initial boiling point:
150℃ / 0.1 Torr
Flash point:
250°C min. (COC)
Auto ignition temperature:
No information
Explosion limits
- lower:
No information
- higher:
No information
Vapor pressure:
No information
Density (15 °C):
0.90 g/cm3
pH:
Not applicable
Solubility in water:
Negligible
(NEOVAC SA-H)
Page 2/4
CI-L-09
(according to 1907/2006)
10. Stability and reactivity
Stability:
Stable under normal conditions
Hazardous reactions:
Unknown (Will not occur)
Materials to avoid:
Strong oxidizing agents
Hazardous decomposition products: Unknown (Will not occur)
11. Toxicological information
dermal toxicity:
no data
skin irritation:
no data
eye irritation:
no data
skin sessitisation:
no data
12. Ecological information
acute fish:
No data
acute Daphnia:
No data
algae:
No data
ready biodegradability(28days):
No data
13. Disposal considerations
Product disposal:
Dispose the waste according to local regulations.
Container/packaging disposal:
Contaminated or empty container/packaging are to be
disposed according to local regulations.
14. Transport information
Flash point
250°C min.
UN-No:
not applicable
ADR/RID class:
not applicable
Hazard Identification N°:
not applicable
ADNR:
not applicable
IMDG-class:
not applicable
ICAO/IATA
not applicable
Technical name:
Lubricating Oil
15. Regulatory information
Regulation (EC)No 1907/2006
U.S.federal law
Pre-registered
registered in TSCA
16. Other information
This product should be stored, handled and used in accordance with good industrial hygiene practices
and in conformity with any legal regulation. The information contained herein is based on the present
state of our knowledge and is intended to describe our products from the point of view of safety
(NEOVAC SA-H)
Page 3/4
CI-L-09
(according to 1907/2006)
requirements. It should not therefore be construed as guaranteeing specific properties.
(NEOVAC SA-H)
Page 4/4
CI-L-09
(according to 1907/2006)
CI-L-10
CI-L-10
CI-L-10
CI-L-10
CI-L-10
CI-L-10
CI-L-10
MATERIAL SAFETY DATA SHEET
Review Date: 05/23/2003
SECTION 1
PRODUCT:
PRODUCT AND COMPANY IDENTIFICATION
DIALA® Oil AX
MSDS NUMBER: 60030E - 14
PRODUCT CODE(S): 68690, 68702, 69702
MANUFACTURER
SOPUS Products
P.O. Box 4427
Houston, TX. 77210-4427
SECTION 2
TELEPHONE NUMBERS
Spill Information: (877) 242-7400
Health Information: (877) 504-9351
MSDS Assistance Number: (877) 276-7285
PRODUCT/INGREDIENTS
INGREDIENTS
Dielectric Oil
Highly refined petroleum oils
SECTION 3
CAS#
Mixture
CONCENTRATION
100
%volume
HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Health Hazards: May be harmful or fatal if swallowed. Do not induce vomiting. May cause aspiration
pneumonitis.
Physical Hazards: No known physical hazards.
NFPA Rating (Health, Fire, Reactivity): 0, 1, 0
Hazard Rating: Least - 0 Slight - 1 Moderate - 2 High - 3 Extreme - 4
Inhalation:
Inhalation of vapors (generated at high temperatures only) or oil mist may cause mild irritation of the nose, throat, and
respiratory tract.
Eye Irritation:
Lubricating oils are generally considered no more than minimally irritating to the eyes.
Skin Contact:
Lubricating oils are generally considered no more than minimally irritating to the skin. Prolonged and repeated contact
may result in defatting and drying of the skin that may cause various skin disorders such as dermatitis, folliculitis or oil
acne.
Ingestion:
This material may be harmful or fatal if swallowed. Ingestion may result in vomiting; aspiration (breathing) of vomitus into
lungs must be avoided as even small quantities may result in aspiration pneumonitis.
DIALA® Oil AX
MSDS# 60030E
Page: 1 of 8
CI-L-11
14
Signs and Symptoms:
Irritation as noted above. Aspiration pneumonitis may be evidenced by coughing, labored breathing and cyanosis (bluish
skin); in severe cases death may occur.
Aggravated Medical Conditions:
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure to this product.
For additional health information, refer to section 11.
SECTION 4
FIRST AID MEASURES
Inhalation:
Remove victim to fresh air and provide oxygen if breathing is difficult. Get medical attention.
Skin:
Remove contaminated clothing and shoes and wipe excess from skin. Flush skin with water, then wash with soap and
water. If irritation occurs, get medical attention. Do not reuse clothing until cleaned.
Eye:
Flush with water. If irritation occurs, get medical attention.
Ingestion:
Do NOT induce vomiting. If vomiting occurs spontaneously, keep head below hips to prevent aspiration of liquid into
lungs. Get medical attention.
SECTION 5
Flash Point [Method]:
FIRE FIGHTING MEASURES
>300 ºF/>148.89 ºC [ Cleveland Open Cup]
Extinguishing Media:
This material is non-flammable. Material will float and can be re-ignited on surface of water. Use water fog, 'alcohol foam',
dry chemical or carbon dioxide (CO2) to extinguish flames. Do not use a direct stream of water.
Fire Fighting Instructions:
Do not enter confined fire space without full bunker gear (helmet with face shield, bunker coats, gloves and rubber boots),
including a positive pressure, NIOSH approved, self-contained breathing apparatus. This material is non-flammable.
Unusual Fire Hazards:
Material may ignite when preheated.
SECTION 6
ACCIDENTAL RELEASE MEASURES
Protective Measures:
May burn although not readily ignitable.
Wear appropriate personal protective equipment when cleaning up spills. Refer to Section 8.
Spill Management:
DIALA® Oil AX
MSDS# 60030E
Page: 2 of 8
CI-L-11
14
FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels.
FOR SMALL SPILLS: Soak up residue with an absorbent such as clay, sand or other suitable material. Place in
non-leaking container and seal tightly for proper disposal.
Reporting:
CERCLA: Product is covered by EPA's Comprehensive Environmental Response, Compensation and Liability Act
(CERCLA) petroleum exclusion. Releases to air, land, or water are not reportable under CERCLA (Superfund).
CWA: This product is an oil as defined under Section 311 of EPA's Clean Water Act (CWA). Spills into or leading to
surface waters that cause a sheen must be reported to the National Response Center, 1-800-424-8802.
SECTION 7
HANDLING AND STORAGE
Precautionary Measures:
Wash with soap and water before eating, drinking, smoking, applying cosmetics, or using toilet. Launder contaminated
clothing before reuse. Properly dispose of contaminated leather articles such as shoes or belts that cannot be
decontaminated. Avoid heat, open flames, including pilot lights, and strong oxidizing agents. Use explosion-proof
ventilation to prevent vapor accumulation. Ground all handling equipment to prevent sparking.
Storage:
Do not store in open or unlabeled containers. Store in a cool, dry place with adequate ventilation. Keep away from open
flames and high temperatures.
Container Warnings:
Keep containers closed when not in use. Containers, even those that have been emptied, can contain explosive vapors.
Do not cut, drill, grind, weld or perform similar operations on or near containers.
SECTION 8
Chemical
Oil mist, mineral
Oil mist, mineral
EXPOSURE CONTROLS/PERSONAL PROTECTION
Limit
ACGIH TLV
OSHA PEL
TWA
5 mg/m3
5 mg/m3
STEL
10 mg/m3
Ceiling
Notation
Exposure Controls
Provide adequate ventilation to control airborne concentrations below the exposure guidelines/limits.
Personal Protection
Personal protective equipment (PPE) selections vary based on potential exposure conditions such as handling practices,
concentration and ventilation. Information on the selection of eye, skin and respiratory protection for use with this material
is provided below.
Eye Protection:
Chemical Goggles, or Safety glasses with side shields
Skin Protection:
Use protective clothing which is chemically resistant to this material. Selection of protective clothing depends on potential
exposure conditions and may include gloves, boots, suits and other items. The selection(s) should take into account such
factors as job task, type of exposure and durability requirements.
DIALA® Oil AX
MSDS# 60030E
Page: 3 of 8
CI-L-11
14
Published literature, test data and/or glove and clothing manufacturers indicate the best protection is provided by:
Neoprene, or Nitrile Rubber
Respiratory Protection:
If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an
approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the
requirements of the OSHA Respiratory Protection Standard, 29 CFR 1910.134.
Types of respirator(s) to be considered in the selection process include:
For Mist: Air Purifying, R or P style NIOSH approved respirator.
For Vapors: Air Purifying, R or P style prefilter & organic cartridge, NIOSH approved respirator. Self-contained
breathing apparatus for use in environments with unknown concentrations or emergency situations.
SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
Substance Chemical Family: Petroleum Hydrocarbon
Boiling Point
Dielectric Strength
20 KV - 40 KV
Flash Point
> 400 ºF
> 300 ºF [Cleveland
Open Cup]
Pour Point
< -40 ºF
Specific Gravity
0.88 - 0.89
Viscosity
< 20 cSt @ 40 ºC
SECTION 10
REACTIVITY AND STABILITY
Stability:
Material is stable under normal conditions.
Conditions to Avoid:
Avoid heat and open flames.
Materials to Avoid:
Avoid contact with strong oxidizing agents.
Hazardous Decomposition Products:
Thermal decomposition products are highly dependent on combustion conditions. A complex mixture of airborne solids,
liquids and gases will evolve when this material undergoes pyrolysis or combustion. Carbon Monoxide, Carbon Dioxideand
other unidentified organic compounds may be formed upon combustion.
SECTION 11
TOXICOLOGICAL INFORMATION
TEST
Result
Dermal LD50
Oral LD50
>2 g/kg(Rabbit)
>5 g/kg(Rat)
Acute Toxicity
OSHA
Classification
Non-Toxic
Non-Toxic
DIALA® Oil AX
Based on components(s)
Based on components(s)
MSDS# 60030E
Page: 4 of 8
CI-L-11
Material Tested
14
Chemical Name
Dielectric Oil
NTP
No
SECTION 12
Carcinogenicity Classification
IARC
ACGIH
Not Reviewed by No
IARC
OSHA
No
ECOLOGICAL INFORMATION
Environmental Impact Summary:
There is no ecological data available for this product. However, this product is an oil. It is persistent and does not readily
biodegrade. However, it does not bioaccumulate.
SECTION 13
DISPOSAL CONSIDERATIONS
RCRA Information:
Under RCRA, it is the responsibility of the user of the material to determine, at the time of the disposal, whether the
material meets RCRA criteria for hazardous waste. This is because material uses, transformations, mixtures, processes,
etc. may affect the classification. Refer to the latest EPA, state and local regulations regarding proper disposal.
SECTION 14
TRANSPORT INFORMATION
US Department of Transportation Classification
This material is not subject to DOT regulations under 49 CFR Parts 171-180.
Oil: This product is an oil under 49CFR (DOT) Part 130. If shipped by rail or highway in a tank with a capacity of 3500
gallons or more, it is subject to these requirements. Mixtures or solutions containing 10% or more of this product may also
be subject to this rule.
International Air Transport Association
Not regulated under IATA rules.
International Maritime Organization Classification
Not regulated under International Maritime Organization rules.
SECTION 15
REGULATORY INFORMATION
Federal Regulatory Status
OSHA Classification:
Product is hazardous according to the OSHA Hazard Communication Standard, 29 CFR 1910.1200, because it carries the
occupational exposure limit for mineral oil mist.
Ozone Depleting Substances (40 CFR 82 Clean Air Act):
This material does not contain nor was it directly manufactured with any Class I or Class II ozone depleting substances.
Superfund Amendment & Reauthorization Act (SARA) Title III:
DIALA® Oil AX
MSDS# 60030E
Page: 5 of 8
CI-L-11
14
There are no components in this product on the SARA 302 list.
SARA Hazard Categories (311/312):
Immediate Health
Delayed Health
Fire
Pressure
Reactivity
NO
NO
NO
NO
NO
SARA Toxic Release Inventory (TRI) (313):
There are no components in this product on the SARA 313 list.
Toxic Substances Control Act (TSCA) Status:
All component(s) of this material is(are) listed on the EPA/TSCA Inventory of Chemical Substances.
Other Chemical Inventories:
Component(s) of this material is (are) listed on the Australian AICS, Canadian DSL, Chinese Inventory, European
EINECS, Korean Inventory, Philippines PICCS,
State Regulation
This material is not regulated by California Prop 65, New Jersey Right-to-Know Chemical List or Pennsylvania
Right-To-Know Chemical List. However for details on your regulation requirements you should contact the appropriate
agency in your state.
SECTION 16
OTHER INFORMATION
Revision#: 14
Review Date: 05/23/2003
Revision Date: 05/23/2003
Revisions since last change (discussion): This Material Safety Data Sheet (MSDS) has been newly reviewed
to fully comply with the guidance contained in the ANSI MSDS standard (ANSI Z400.1-1998). We encourage
you to take the opportunity to read the MSDS and review the information contained therein.
SECTION 17
LABEL INFORMATION
READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF PRODUCT.
THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD COMMUNICATION STANDARD (29
CFR 1910.1200) FOR USE IN THE WORKPLACE. THIS LABEL IS NOT INTENDED TO BE USED WITH PACKAGING
INTENDED FOR SALE TO CONSUMERS AND MAY NOT CONFORM WITH THE REQUIREMENTS OF THE
CONSUMER PRODUCT SAFETY ACT OR OTHER RELATED REGULATORY REQUIREMENTS.
PRODUCT CODE(S): 68690, 68702, 69702
DIALA® Oil AX
CAUTION!
ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE. PROLONGED OR
REPEATED SKIN CONTACT MAY CAUSE OIL ACNE OR DERMATITIS.
DIALA® Oil AX
MSDS# 60030E
Page: 6 of 8
CI-L-11
14
Precautionary Measures:
Avoid prolonged or repeated contact with eyes, skin and clothing. Do not take internally. Wash thoroughly after
handling.
FIRST AID
Inhalation: Remove victim to fresh air and provide oxygen if breathing is difficult. Get medical attention.
Skin Contact: Remove contaminated clothing and shoes and wipe excess from skin. Flush skin with water, then wash
with soap and water. If irritation occurs, get medical attention. Do not reuse clothing until cleaned.
Eye Contact: Flush with water. If irritation occurs, get medical attention.
Ingestion: Do NOT induce vomiting. If vomiting occurs spontaneously, keep head below hips to prevent aspiration of
liquid into lungs. Get medical attention.
FIRE
In case of fire, Use water fog, 'alcohol foam', dry chemical or carbon dioxide (CO2) to extinguish flames. Do not use a
direct stream of water. Material will float and can be re-ignited on surface of water.
SPILL OR LEAK
Dike and contain spill.
FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels.
FOR SMALL SPILLS: Soak up residue with an absorbent such as clay, sand or other suitable material. Place in
non-leaking container and seal tightly for proper disposal.
CONTAINS: Highly refined petroleum oils, Mixture
NFPA Rating (Health, Fire, Reactivity): 0, 1, 0
TRANSPORTATION
US Department of Transportation Classification
This material is not subject to DOT regulations under 49 CFR Parts 171-180.
Oil: This product is an oil under 49CFR (DOT) Part 130. If shipped by rail or highway in a tank with a capacity of 3500
gallons or more, it is subject to these requirements. Mixtures or solutions containing 10% or more of this product may also
be subject to this rule.
CAUTION: Misuse of empty containers can be hazardous. Empty containers can be hazardous if used to store toxic,
flammable, or reactive materials. Cutting or welding of empty containers might cause fire, explosion or toxic fumes from
residues. Do not pressurize or expose to open flames or heat. Keep container closed and drum bungs in place.
Name and Address
SOPUS Products
P.O. Box 4427
Houston, TX 77210-4427
MANUFACTURER ADDRESS:
ADMINISTRATIVE INFORMATION
SOPUS Products, P.O. Box 4427, Houston, TX. 77210-4427
DIALA® Oil AX
MSDS# 60030E
Page: 7 of 8
CI-L-11
14
THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE TO US AT THIS TIME,
AND IS BELIEVED TO BE ACCURATE BASED UPON THAT : IT IS PROVIDED INDEPENDENTLY OF ANY SALE OF
THE PRODUCT, FOR PURPOSE OF HAZARD COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE
PRODUCT PERFORMANCE INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE
WITH RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED HEREIN. YOU ARE
URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY, PROCESS, USE OR DISTRIBUTE, AND ARE
ENCOURAGED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE
INFORMATION CONTAINED HEREIN.
TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE
PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT
AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH MATTERS, OR BE RESPONSIBLE FOR ANY INJURY FROM
THE USE OF THE PRODUCT DESCRIBED HEREIN. THE UNDERLYING DATA, AND THE INFORMATION PROVIDED
HEREIN AS A RESULT OF THAT DATA, IS THE PROPERTY OF SOPUS PRODUCTS AND IS NOT TO BE THE
SUBJECT OF SALE OR EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF SOPUS PRODUCTS.
44136-10558-100R-04/21/2005
DIALA® Oil AX
MSDS# 60030E
Page: 8 of 8
CI-L-11
14
MATERIAL SAFETY DATA SHEET
===========================================================================
IDENTITY: HALOCARBON 4.2, 6.3, 27, 56, 95, 200, 400, 700, 1000N OILS
===========================================================================
SECTION I: MANUFACTURER
HALOCARBON PRODUCTS CORPORATION
P.O. Box 661
River Edge, N.J. 07661
Emergency Number:
Customer Service & Sales:
(803) 278 3504
(201) 262 8899
Prepared by: Dr. Lee G. Sprague
============================================================================
SECTION II: CHEMICAL IDENTITY
Components
Polychlorotrifluoroethylene
CAS
No.
9002-83-9
OSHA
PEL
NONE
ACGIH
TLV
NONE
Other
Limits
NONE
S Oils contain a proprietary rust inhibitor.
OSHA HAZARD RATING:
These products contain the following toxic chemical(s) subject to
Section 313 Title III reporting requirements (40 CFR Part 372):
NONE
============================================================================
SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS
Boiling Point
: Decomposes > 200 C
Melting Point
: N/A
Specific Gravity(H2O=1): ca 1.9 (38 C)
Vapor Pressure: <= 0.1 mm Hg (21 C)
Vapor Density(Air=1): N/A
Solubility in Water : Negligible
Appearance and Odor: Colorless oil with slight ethereal odor.
============================================================================
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
Flash Point/Method: None
Flammability Limits in Air
Extinguishing Media:
-
LEL:
Autoignition Temp:
N/A
UEL: N/A
Not determined.
Use agent suitable for surrounding fire.
Special Fire Fighting Procedures:
leakage.
Wear SCBA if there is danger of
Unusual Fire and Explosion Hazards: Thermal decomposition products are
toxic and corrosive. See Section V.
CI-L-12
============================================================================
SECTION V - REACTIVITY DATA
Unstable
Stable
[ ]
[X]
Conditions to Avoid:
N/A
Incompatibility (Materials to Avoid): Reacts with active metals like sodium
and potassium, amines (including additives), liquid fluorine and liquid
chlorine trifluoride. Caution should be used with aluminum and magnesium
under conditions of large shear forces such as those found in threaded
connections.
Hazardous Decomposition or By-products: The decomposition to toxic, nonsludge forming volatiles occurs rapidly at 325C, noticeably at 300C and in
lesser amounts at lower temperatures. Therefore, the maximum safe operating
temperature recommended is 200C and maximum short-term temperature
recommended is 260C in scrupulously clean systems.
Hazardous Polymerization [ ] May Occur
Conditions To Avoid: N/A
CI-L-12
[X] Will Not Occur
============================================================================
SECTION VI - HEALTH HAZARD DATA
These products contain a complex mixture of polymers of chlorotrifluoroehtylene (CTFE) which will vary from batch to batch.
Halocarbon 27 oil caused no deaths in rats dosed daily for 21 days with
2.5 g/kg orally. Symptoms attributed to fluoride poisoning by metabolism in
the liver were noted. Enlargement of the livers and kidneys in the treated
animal support this conclusion.
Extensive studies have been conducted on lighter, more volatile
Halocarbon oils. Based on all the available data in three species of
animals, limited exposure to Halocarbon oil should not be harmful to any
portion of the human anatomy. Studies conducted by the Air Force have
demonstrated liver toxicity in rodents but not in primates. The observed
liver toxicity is believed to be specific for rodents and not relevant to
humans. All mutagenicity studies were negative.
Halocarbon oils are not irritating to skin but skin protection should be
used to prevent repeated exposure and the possibility of sensitization.
In the absence of chronic toxicity data on these products, exposure to these
products and their vapors should be avoided since the potential for human
toxicity cannot be ruled out. Proper ventilation and work practices should
be employed.
Primary routes of entry: [ ] Inhalation
[X] Skin
[ ] Eyes
[ ] Oral
Acute Effects of Overexposure: From the animal studies, signs of fluoride
poisoning may be expected. These include nausea, shortness of breath and
loss of appetite.
Chronic Effects of Overexposure:
Carcinogenicity listing:
Unknown
[No ] NTP
[No ] IARC
[No ] Other:
[No ] OSHA
First Aid
Inhalation:
Skin:
Eye:
Oral:
Remove to fresh air. Apply artificial respiration if
needed. Seek medical help.
Wash with soap and water.
Flush eyes with water for at least 15 minutes. Seek medical
help.
Try to induce vomiting. Seek medical help.
Medical Conditions Generally Aggravated by Exposure:
Other Health Hazards:
CI-L-12
None known.
None known.
============================================================================
SECTION VII - PROTECTION INFORMATION
Respiratory:
None normally required.
Ventilation:
Adequate general ventilation plus local exhaust at point of
emission.
Eye and Face:
Gloves:
For large spills wear SCBA.
Safety glasses/goggles or face shield.
Impervious gloves.
Other equipment:
None normally required.
============================================================================
SECTION VIII - SPILL, LEAK AND DISPOSAL PROCEDURES
Spill, Leak or Release: Spills may be picked up with an absorbent such
as vermiculite and held in covered container for disposal.
Waste Disposal:
May be incinerated by licensed waste disposal company.
Observe all federal, state and local regulations.
============================================================================
SECTION IX - OTHER INFORMATION
1.
Hazardous Materials/Dangerous Goods Shipping Regulations
U.S. (49 CFR):
Proper Shipping Name:
Non-Hazardous Material
IATA:
Proper Shipping Name:
Non-Dangerous Goods
IMDG:
Proper Shipping Name:
Non-Dangerous Goods
2. Other Information: HMIS Labeling: H 1; F 0; R 0; P B
============================================================================
REVISED: JANUARY 18, 2005
CI-L-12
Rofin-Sinar Part# 8305038
CI-L-13
CI-L-13
MATERIAL SAFETY DATA SHEET
Revision Date: 12/17/2003
PRODUCT AND COMPANY IDENTIFICATION
SECTION 1
PRODUCT: Omala® Fluid HD
MSDS NUMBER: 67551E - 5
PRODUCT CODE(S): 65131
220
MANUFACTURER
SOPUS Products
P.O. Box 4453
Houston, TX. 77210-4453
TELEPHONE NUMBERS
Spill Information: (877) 242-7400
Health Information: (877) 504-9351
MSDS Assistance Number: (877) 276-7285
PRODUCT/INGREDIENTS
SECTION 2
INGREDIENTS
Synthetic Gear Oil
Synthetic hydrocarbon base oil (PAO)
Polymer additives
CAS#
Mixture
Proprietary
CONCENTRATION
90 - 99
1-5
%volume
%volume
HAZARDS IDENTIFICATION
SECTION 3
EMERGENCY OVERVIEW
Appearance & Odor: Pale yellow liquid. Mild odor.
Health Hazards: No known immediate health hazards.
Physical Hazards: No known physical hazards.
NFPA Rating (Health, Fire, Reactivity): 0, 1, 0
Hazard Rating:Least - 0 Slight - 1 Moderate - 2 High - 3
Extreme - 4
Inhalation:
Inhalation of vapors (generated at high temperatures only) or oil mist may cause mild irritation of the nose, throat, and
respiratory tract.
Eye Irritation:
Lubricating oils are generally considered no more than minimally irritating to the eyes.
Skin Contact:
Lubricating oils are generally considered no more than minimally irritating to the skin. Prolonged and repeated contact
Omala® Fluid HD 220
MSDS# 67551E
Page of
CL-L-14
5
may result in defatting and drying of the skin that may cause various skin disorders such as dermatitis, folliculitis or oil
acne.
Ingestion:
Lubricating oils are generally no more than slightly toxic if swallowed.
Signs and Symptoms:
Irritation as noted above.
Aggravated Medical Conditions:
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure to this product.
For additional health information, refer to section 11.
FIRST AID MEASURES
SECTION 4
Inhalation:
Remove victim to fresh air and provide oxygen if breathing is difficult. Get medical attention.
Skin:
Remove contaminated clothing and shoes and wipe excess from skin. Flush skin with water, then wash with soap and
water. If irritation occurs, get medical attention. Do not reuse clothing until cleaned.
Eye:
Flush with water. If irritation occurs, get medical attention.
Ingestion:
Do not induce vomiting. In general, no treatment is necessary unless large quantities of product are ingested. However,
get medical attention.
Note to Physician:
In general, emesis induction is unnecessary in high viscosity, low volatility products such as oils and greases.
FIRE FIGHTING MEASURES
SECTION 5
Flash Point [Method]:
500 ºF -510 ºF/260 ºC -265.56 ºC [ Cleveland Open Cup]
Extinguishing Media:
Material will float and can be re-ignited on surface of water. Use water fog, 'alcohol foam', dry chemical or carbon dioxide
(CO2) to extinguish flames. Do not use a direct stream of water.
Fire Fighting Instructions:
Material will not burn unless preheated. Do not enter confined fire space without full bunker gear (helmet with face shield,
bunker coats, gloves and rubber boots), including a positive pressure, NIOSH approved, self-contained breathing
apparatus.
Omala® Fluid HD 220
MSDS# 67551E
Page of
CL-L-14
5
ACCIDENTAL RELEASE MEASURES
SECTION 6
Protective Measures:
May burn although not readily ignitable.
Wear appropriate personal protective equipment when cleaning up spills. Refer to Section 8.
Spill Management:
FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels.
FOR SMALL SPILLS: Soak up residue with an absorbent such as clay, sand or other suitable material. Place in
non-leaking container and seal tightly for proper disposal.
Reporting:
CERCLA: Product is covered by EPA's Comprehensive Environmental Response, Compensation and Liability Act
(CERCLA) petroleum exclusion. Releases to air, land, or water are not reportable under CERCLA (Superfund).
CWA: This product is an oil as defined under Section 311 of EPA's Clean Water Act (CWA). Spills into or leading to
surface waters that cause a sheen must be reported to the National Response Center, 1-800-424-8802.
HANDLING AND STORAGE
SECTION 7
Precautionary Measures:
Wash with soap and water before eating, drinking, smoking, applying cosmetics, or using toilet. Launder contaminated
clothing before reuse. Properly dispose of contaminated leather articles such as shoes or belts that cannot be
decontaminated. Avoid heat, open flames, including pilot lights, and strong oxidizing agents. Use explosion-proof
ventilation to prevent vapor accumulation. Ground all handling equipment to prevent sparking.
Storage:
Store in a cool, dry place with adequate ventilation. Keep away from open flames and high temperatures.
Container Warnings:
Keep containers closed when not in use. Containers, even those that have been emptied, can contain explosive vapors.
Do not cut, drill, grind, weld or perform similar operations on or near containers.
EXPOSURE CONTROLS/PERSONAL PROTECTION
SECTION 8
Chemical
Limit
TWA
STEL
Polyalphaolefin
ACGIH TLV
5 mg/m3
10 mg/m3
Polyalphaolefin
OSHA PEL
5 mg/m3
Ceiling
Notation
Exposure Controls
Omala® Fluid HD 220
MSDS# 67551E
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Adequate ventilation to control airborne concentrations below the exposure guidelines/limits.
Personal Protection
Personal protective equipment (PPE) selections vary based on potential exposure conditions such as handling practices,
concentration and ventilation. Information on the selection of eye, skin and respiratory protection for use with this material
is provided below.
Eye Protection:
Safety glasses with side shields
Skin Protection:
Use protective clothing which is chemically resistant to this material. Selection of protective clothing depends on potential
exposure conditions and may include gloves, boots, suits and other items. The selection(s) should take into account such
factors as job task, type of exposure and durability requirements.
Published literature, test data and/or glove and clothing manufacturers indicate the best protection is provided by:
Neoprene, or Nitrile Rubber
Respiratory Protection:
If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an
approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the
requirements of the OSHA Respiratory Protection Standard, 29 CFR 1910.134.
Types of respirator(s) to be considered in the selection process include:
For Mist: Air Purifying, R or P style NIOSH approved respirator.
For Vapors: Air Purifying, R or P style prefilter & organic cartridge, NIOSH approved respirator.
Self-contained breathing apparatus for use in environments with unknown concentrations or emergency
situations.
PHYSICAL AND CHEMICAL PROPERTIES
SECTION 9
Appearance & Odor: Pale yellow liquid. Mild odor.
Substance Chemical Family: Lubricants
500 ºF - 510 ºF
Flash Point
[Cleveland Open Cup]
Specific Gravity
0.85
Pour Point
> -40 ºF
Viscosity
220 cSt - 460 cSt @ 40 ºC
REACTIVITY AND STABILITY
SECTION 10
Omala® Fluid HD 220
MSDS# 67551E
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Stability:
Material is stable under normal conditions.
Conditions to Avoid:
Avoid heat and open flames.
Materials to Avoid:
Avoid contact with strong oxidizing agents.
Hazardous Decomposition Products:
Thermal decomposition products are highly dependent on combustion conditions. A complex mixture of airborne solids,
liquids and gases will evolve when this material undergoes pyrolysis or combustion. Carbon Monoxide, Carbon Dioxide
and other unidentified organic compounds may be formed upon combustion.
TOXICOLOGICAL INFORMATION
SECTION 11
Acute Toxicity
OSHA
Classification
TEST
Result
Material Tested
Dermal LD50
>2 g/kg(Rabbit)
Non-Toxic
Based on components(s)
Oral LD50
>2 g/kg(Rat)
Non-Toxic
Based on components(s)
Carcinogenicity Classification
Chemical Name
NTP
Synthetic Gear Oil
No
IARC
Not Reviewed by
IARC
ACGIH
OSHA
No
No
ECOLOGICAL INFORMATION
SECTION 12
Environmental Impact Summary:
There is no ecological data available for this product. However, this product is an oil. It is persistent and does not readily
biodegrade. However, it does not bioaccumulate.
DISPOSAL CONSIDERATIONS
SECTION 13
RCRA Information:
Under RCRA, it is the responsibility of the user of the material to determine, at the time of the disposal, whether the
material meets RCRA criteria for hazardous waste. This is because material uses, transformations, mixtures, processes,
Omala® Fluid HD 220
MSDS# 67551E
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etc. may affect the classification. Refer to the latest EPA, state and local regulations regarding proper disposal.
TRANSPORT INFORMATION
SECTION 14
US Department of Transportation Classification
This material is not subject to DOT regulations under 49 CFR Parts 171-180.
Oil: This product is an oil under 49CFR (DOT) Part 130. If shipped by rail or highway in a tank with a capacity of 3500
gallons or more, it is subject to these requirements. Mixtures or solutions containing 10% or more of this product may also
be subject to this rule.
International Air Transport Association
Not regulated under IATA rules.
International Maritime Organization Classification
Not regulated under International Maritime Organization rules.
REGULATORY INFORMATION
SECTION 15
Federal Regulatory Status
OSHA Classification:
Product is hazardous according to the OSHA Hazard Communication Standard, 29 CFR 1910.1200, because it carries the
occupational exposure limit for mineral oil mist.
Ozone Depleting Substances (40 CFR 82 Clean Air Act):
This material does not contain nor was it directly manufactured with any Class I or Class II ozone depleting substances.
Superfund Amendment & Reauthorization Act (SARA) Title III:
There are no components in this product on the SARA 302 list.
SARA Hazard Categories (311/312):
Immediate Health
Delayed Health
Fire
Pressure
Reactivity
NO
NO
NO
NO
NO
SARA Toxic Release Inventory (TRI) (313):
There are no components in this product on the SARA 313 list.
Toxic Substances Control Act (TSCA) Status:
All component(s) of this material is(are) listed on the EPA/TSCA Inventory of Chemical Substances.
Omala® Fluid HD 220
MSDS# 67551E
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Other Chemical Inventories:
Component(s) of this material is (are) listed on the Australian AICS, Canadian DSL, European EINECS,
State Regulation
This material is not regulated by California Prop 65, New Jersey Right-to-Know Chemical List or Pennsylvania
Right-To-Know Chemical List. However for details on your regulation requirements you should contact the appropriate
agency in your state.
OTHER INFORMATION
SECTION 16
Revision#: 5
Revision Date: 12/17/2003
Revisions since last change (discussion): This Material Safety Data Sheet (MSDS) has been newly reviewed
to fully comply with the guidance contained in the ANSI MSDS standard (ANSI Z400.1-1998). We encourage
you to take the opportunity to read the MSDS and review the information contained therein.
LABEL INFORMATION
SECTION 17
READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF PRODUCT.
THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD COMMUNICATION STANDARD (29
CFR 1910.1200) FOR USE IN THE WORKPLACE. THIS LABEL IS NOT INTENDED TO BE USED WITH PACKAGING
INTENDED FOR SALE TO CONSUMERS AND MAY NOT CONFORM WITH THE REQUIREMENTS OF THE
CONSUMER PRODUCT SAFETY ACT OR OTHER RELATED REGULATORY REQUIREMENTS.
PRODUCT CODE(S): 65131
Omala® Fluid HD 220
ATTENTION!
PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE OIL ACNE OR DERMATITIS.
Precautionary Measures:
Avoid prolonged or repeated contact with eyes, skin and clothing. Wash thoroughly after handling.
FIRST AID
Omala® Fluid HD 220
MSDS# 67551E
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Inhalation: Remove victim to fresh air and provide oxygen if breathing is difficult. Get medical attention.
Skin Contact: Remove contaminated clothing and shoes and wipe excess from skin. Flush skin with water, then wash
with soap and water. If irritation occurs, get medical attention. Do not reuse clothing until cleaned.
Eye Contact: Flush with water. If irritation occurs, get medical attention.
Ingestion: Do not induce vomiting. In general, no treatment is necessary unless large quantities of product are ingested.
However, get medical attention.
FIRE
In case of fire, Use water fog, 'alcohol foam', dry chemical or carbon dioxide (CO2) to extinguish flames. Do not use a
direct stream of water. Material will float and can be re-ignited on surface of water.
SPILL OR LEAK
Dike and contain spill.
FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels.
FOR SMALL SPILLS: Soak up residue with an absorbent such as clay, sand or other suitable material. Place in
non-leaking container and seal tightly for proper disposal.
CONTAINS: Synthetic hydrocarbon base oil (PAO), Mixture; Polymer additives, Proprietary
NFPA Rating (Health, Fire, Reactivity): 0, 1, 0
TRANSPORTATION
US Department of Transportation Classification
This material is not subject to DOT regulations under 49 CFR Parts 171-180.
Oil: This product is an oil under 49CFR (DOT) Part 130. If shipped by rail or highway in a tank with a capacity of 3500
gallons or more, it is subject to these requirements. Mixtures or solutions containing 10% or more of this product may also
be subject to this rule.
CAUTION: Misuse of empty containers can be hazardous. Empty containers can be hazardous if used to store toxic,
flammable, or reactive materials. Cutting or welding of empty containers might cause fire, explosion or toxic fumes from
residues. Do not pressurize or expose to open flames or heat. Keep container closed and drum bungs in place.
Name and Address
SOPUS Products
P.O. Box 4453
Houston, TX 77210-4453
Omala® Fluid HD 220
MSDS# 67551E
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ADMINISTRATIVE INFORMATION
MANUFACTURER ADDRESS: SOPUS Products, P.O. Box 4453, Houston, TX. 77210-4453
Company Product Stewardship & Regulatory Compliance Contact: Timothy W Childs
Phone Number: (281) 874-7708
THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE TO US AT THIS TIME,
AND IS BELIEVED TO BE ACCURATE BASED UPON THAT : IT IS PROVIDED INDEPENDENTLY OF ANY SALE OF
THE PRODUCT, FOR PURPOSE OF HAZARD COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE
PRODUCT PERFORMANCE INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE
WITH RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED HEREIN. YOU ARE
URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY, PROCESS, USE OR DISTRIBUTE, AND ARE
ENCOURAGED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE
INFORMATION CONTAINED HEREIN.
TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE
PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT
AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH MATTERS, OR BE RESPONSIBLE FOR ANY INJURY FROM
THE USE OF THE PRODUCT DESCRIBED HEREIN. THE UNDERLYING DATA, AND THE INFORMATION PROVIDED
HEREIN AS A RESULT OF THAT DATA, IS THE PROPERTY OF SOPUS PRODUCTS AND IS NOT TO BE THE
SUBJECT OF SALE OR EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF SOPUS PRODUCTS.
37911-10910-100R-12/17/2003
Omala® Fluid HD 220
MSDS# 67551E
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600510-00 MOBIL VACTRA OIL NO. 4
MATERIAL SAFETY DATA BULLETIN
---------------------------------------------------------------------------------------------------------------------------------------------------1. PRODUCT AND COMPANY IDENTIFICATION
-------------------------------------------------------------------------PRODUCT NAME: MOBIL VACTRA OIL NO. 4
SUPPLIER: EXXONMOBIL CORPORATION
3225 GALLOWS RD.
FAIRFAX, VA
22037
24 - Hour Health and Safety Emergency (call collect): 609-737-4411
24 - Hour Transportation Emergency:
CHEMTREC: 800-424-9300
202-483-7616
LUBES AND FUELS: 281-834-3296
Product and Technical Information:
Lubricants and Specialties: 800-662-4525
800-443-9966
Fuels Products: 800-947-9147
MSDS Fax on Demand: 613-228-1467
MSDS Internet Website: http://emmsds.ihssolutions.com/
-------------------------------------------------------------------------2. COMPOSITION/INFORMATION ON INGREDIENTS
-------------------------------------------------------------------------CHEMICAL NAMES AND SYNONYMS: PET. HYDROCARBONS AND ADDITIVES
GLOBALLY REPORTABLE MSDS INGREDIENTS:
None.
See Section 8 for exposure limits (if applicable).
-------------------------------------------------------------------------3. HAZARDS IDENTIFICATION
-------------------------------------------------------------------------Under normal conditions of use, this product is not considered hazardous
according to regulatory guidelines (See section 15).
EMERGENCY OVERVIEW: Brown Liquid. DOT ERG No. : NA
POTENTIAL HEALTH EFFECTS: Under normal conditions of intended use,
this product does not pose a risk to health. Excessive exposure
may result in eye, skin or respiratory irritation.
For further health effects/toxicological data, see Section 11.
-------------------------------------------------------------------------4. FIRST AID MEASURES
-------------------------------------------------------------------------EYE CONTACT: Flush thoroughly with water. If irritation occurs, call
a physician.
SKIN CONTACT: Wash contact areas with soap and water. Remove and
clean oil soaked clothing daily and wash affected area. (See
Section 16 - Injection Injury)
INHALATION: Not expected to be a problem. However, if respiratory
irritation, dizziness, nausea, or unconsciousness occurs due to
excessive vapor or mist exposure, seek immediate medical
assistance. If breathing has stopped, assist ventilation with a
CI-L-15
mechanical device or mouth-to-mouth resuscitation.
INGESTION: Not expected to be a problem. Seek medical attention if
discomfort occurs. Do not induce vomiting.
-------------------------------------------------------------------------5. FIRE-FIGHTING MEASURES
-------------------------------------------------------------------------EXTINGUISHING MEDIA: Carbon dioxide, foam, dry chemical and water fog.
SPECIAL FIRE FIGHTING PROCEDURES: Water or foam may cause frothing.
Use water to keep fire exposed containers cool. Water spray may
be used to flush spills away from exposure. Prevent runoff from
fire control or dilution from entering streams, sewers, or
drinking water supply.
SPECIAL PROTECTIVE EQUIPMENT: For fires in enclosed areas, fire
fighters must use self-contained breathing apparatus.
UNUSUAL FIRE AND EXPLOSION HAZARDS: None.
COMBUSTION PRODUCTS: Fumes, smoke, carbon monoxide, sulfur oxides,
aldehydes and other decomposition products, in the case of
incomplete combustion.
Flash Point C(F): 242(468) (ASTM D-92).
Flammable Limits (approx.% vol.in air) LEL: 0.9%,
UEL: 7.0%
NFPA HAZARD ID:
Health: 0, Flammability: 1, Reactivity: 0
-------------------------------------------------------------------------6. ACCIDENTAL RELEASE MEASURES
-------------------------------------------------------------------------NOTIFICATION PROCEDURES: Report spills/releases as required to
appropriate authorities. U.S. Coast Guard and EPA regulations
require immediate reporting of spills/releases that could reach
any waterway including intermittent dry creeks. Report
spill/release to Coast Guard National Response Center toll free
number (800)424-8802. In case of accident or road spill notify
CHEMTREC (800) 424-9300.
PROCEDURES IF MATERIAL IS RELEASED OR SPILLED:
LAND SPILL: Shut off source taking normal safety precautions. Take
measures to minimize the effects on ground water. Recover by
pumping or contain spilled material with sand or other suitable
absorbent and remove mechanically into containers. If necessary,
dispose of adsorbed residues as directed in Section 13.
WATER SPILL: Confine the spill immediately with booms. Warn other
ships in the vicinity. Notify port and other relevant authorities.
Remove from the surface by skimming or with suitable absorbents. If
permitted by regulatory authorities the use of suitable dispersants
should be considered where recommended in local oil spill
procedures.
ENVIRONMENTAL PRECAUTIONS: Prevent material from entering sewers,
water sources or low lying areas; advise the relevant authorities
if it has, or if it contaminates soil/vegetation.
PERSONAL PRECAUTIONS: See Section 8
-------------------------------------------------------------------------7. HANDLING AND STORAGE
-------------------------------------------------------------------------HANDLING: No special precautions are
hygiene practices. See Section
protection advice when handling
STORAGE: Keep containers closed when
CI-L-15
necessary beyond normal good
8 for additional personal
this product.
not in use. Do not store in open
or unlabelled containers. Store away from strong oxidizing
agents and combustible materials. Do not store near heat,
sparks, flame or strong oxidants.
SPECIAL PRECAUTIONS: Prevent small spills and leakages to avoid slip
hazard.
EMPTY CONTAINER WARNING: Empty containers retain residue (liquid
and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD,
BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT,
FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION;
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to
refill or clean container since residue is difficult to remove.
Empty drums should be completely drained, properly bunged and
promptly returned to a drum reconditioner. All containers should
be disposed of in an environmentally safe manner and in
accordance with governmental regulations.
-------------------------------------------------------------------------8. EXPOSURE CONTROLS/PERSONAL PROTECTION
-------------------------------------------------------------------------OCCUPATIONAL EXPOSURE LIMITS:
When mists/aerosols can occur, the following are recommended: 5 mg/m3
(as oil mist)- ACGIH Threshold Limit Value (TLV), 10 mg/m3 (as oil mist)
- ACGIH Short Term Exposure Limit (STEL), 5 mg/m3 (as oil mist) - OSHA
Permissible Exposure Limit (PEL)
VENTILATION: If mists are generated, use adequate ventilation, local
exhaust or enclosures to control below exposure limits.
RESPIRATORY PROTECTION: If mists are generated, and/or when
ventilation is not adequate, wear approved respirator.
EYE PROTECTION: If eye contact is likely, safety glasses with side
shields or chemical type goggles should be worn.
SKIN PROTECTION: Not normally required. When splashing or liquid
contact can occur frequently, wear oil resistant gloves and/or
other protective clothing. Good personal hygiene practices
should always be followed.
-------------------------------------------------------------------------9. PHYSICAL AND CHEMICAL PROPERTIES
-------------------------------------------------------------------------Typical physical properties are given below.
for specific details.
APPEARANCE: Liquid
COLOR: Brown
ODOR: Mild
ODOR THRESHOLD-ppm: NE
pH: NA
BOILING POINT C(F): > 316(600)
MELTING POINT C(F): NA
FLASH POINT C(F): 242(468) (ASTM D-92)
FLAMMABILITY (solids): NE
AUTO FLAMMABILITY C(F): NA
EXPLOSIVE PROPERTIES: NA
OXIDIZING PROPERTIES: NA
VAPOR PRESSURE-mmHg 20 C: < 0.1
VAPOR DENSITY: > 2.0
EVAPORATION RATE: NE
RELATIVE DENSITY, 15/4 C: 0.89
SOLUBILITY IN WATER: Negligible
PARTITION COEFFICIENT: > 3.5
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Consult Product Data Sheet
VISCOSITY AT 40 C, cSt:
220.0
VISCOSITY AT 100 C, cSt: NE
POUR POINT C(F): -6(21)
FREEZING POINT C(F): NE
VOC: < 4.00 (Wt. %); 0.287 lbs/gal
DMSO EXTRACT, IP-346 (WT.%): <3, for mineral oil only
NA=NOT APPLICABLE NE=NOT ESTABLISHED D=DECOMPOSES
FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING REPRESENTATIVE
-------------------------------------------------------------------------10. STABILITY AND REACTIVITY
-------------------------------------------------------------------------STABILITY (THERMAL, LIGHT, ETC.): Stable.
CONDITIONS TO AVOID: Extreme heat and high energy sources of ignition.
INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS: Product does not decompose at
ambient temperatures.
HAZARDOUS POLYMERIZATION: Will not occur.
-------------------------------------------------------------------------11. TOXICOLOGICAL DATA
----------------------------------------------------------------------------ACUTE TOXICOLOGY--ORAL TOXICITY (RATS): Practically non-toxic (LD50: greater than 2000
mg/kg). ---Based on testing of similar products and/or the
components.
DERMAL TOXICITY (RABBITS): Practically non-toxic (LD50: greater than
2000 mg/kg). ---Based on testing of similar products and/or the
components.
INHALATION TOXICITY (RATS): Practically non-toxic (LC50: greater
than 5 mg/l). ---Based on testing of similar products and/or the
components.
EYE IRRITATION (RABBITS): Practically non-irritating. (Draize score:
greater than 6 but 15 or less). ---Based on testing of similar
products and/or the components.
SKIN IRRITATION (RABBITS): Practically non-irritating. (Primary
Irritation Index: greater than 0.5 but less than 3). ---Based
on testing of similar products and/or the components.
OTHER ACUTE TOXICITY DATA: Although an acute inhalation study was not
performed with this product, a variety of mineral and synthetic
oils, such as those in this product, have been tested. These
samples had virtually no effect other than a nonspecific
inflammatory response in the lung to the aerosolized mineral oil.
The presence of additives in other tested formulations (in
approximately the same amounts as in the present formulation) did
not alter the observed effects.
---SUBCHRONIC TOXICOLOGY (SUMMARY)--No significant adverse effects were found in studies using repeated
dermal applications of similar formulations to the skin of
laboratory animals for 13 weeks at doses significantly higher
than those expected during normal industrial exposure. The
animals were evaluated extensively for effects of exposure
(hematology, serum chemistry, urinalysis, organ weights,
microscopic examination of tissues etc.).
---REPRODUCTIVE TOXICOLOGY (SUMMARY)--No teratogenic effects would be expected from dermal exposure, based
on laboratory developmental toxicity studies of major components
in this formulation and/or materials of similar composition.
CI-L-15
---CHRONIC TOXICOLOGY (SUMMARY)--Repeated and/or prolonged exposure may cause irritation to the skin,
eyes or respiratory tract. Overexposure to oil mist may result
in oil droplet deposition and/or granuloma formation. For
mineral base oils: Base oils in this product are severely
solvent refined and/or severely hydrotreated. Chronic mouse skin
painting studies of severely treated oils showed no evidence of
carcinogenic effects. These results are confirmed on a
continuing basis using various screening methods such as Modified
Ames Test, IP-346, and/or other analytical methods. For
synthetic base oils: The base oils in this product have been
tested in the Ames assay and other tests of mutagenicity with
negative results. These base oils are not expected to be
carcinogenic with chronic dermal exposures.
---SENSITIZATION (SUMMARY)--Not expected to be sensitizing based on tests of this product,
components, or similar products.
-------------------------------------------------------------------------12. ECOLOGICAL INFORMATION
-------------------------------------------------------------------------ENVIRONMENTAL FATE AND EFFECTS:
In the absence of specific environmental data for this product, this
assessment is based on information for representative products.
ECOTOXICITY: Available ectoxicity data (LL50 >1000 mg/L) indicates
that adverse effects to aquatic organisms are not expected from
this product.
MOBILITY: When released into the environment, adsorption to sediment
and soil will be the predominant behavior.
PERSISTENCE AND DEGRADABILITY: This product is expected to be
inherently biodegradable.
BIOACCUMULATIVE POTENTIAL: Bioaccumulation is unlikely due to the very
low water solubility of this product, therefore bioavailability
to aquatic organisms is minimal.
-------------------------------------------------------------------------13. DISPOSAL CONSIDERATIONS
-------------------------------------------------------------------------WASTE DISPOSAL: Product is suitable for burning in an enclosed,
controlled burner for fuel value. Such burning may be limited
pursuant to the Resource Conservation and Recovery Act. In
addition, the product is suitable for processing by an approved
recycling facility or can be disposed of at an appropriate
government waste disposal facility. Use of these methods is
subject to user compliance with applicable laws and regulations
and consideration of product characteristics at time of disposal.
RCRA INFORMATION: The unused product, in our opinion, is not
specifically listed by the EPA as a hazardous waste (40 CFR,
Part 261D), nor is it formulated to contain materials which
are listed hazardous wastes. It does not exhibit the hazardous
characteristics of ignitability, corrosivity, or reactivity. The
unused product is not formulated with substances covered by the
Toxicity Characteristic Leaching Procedure (TCLP). However, used
product may be regulated.
-------------------------------------------------------------------------14. TRANSPORT INFORMATION
--------------------------------------------------------------------------
CI-L-15
USA DOT: NOT REGULATED BY USA DOT.
RID/ADR: NOT REGULATED BY RID/ADR.
IMO: NOT REGULATED BY IMO.
IATA: NOT REGULATED BY IATA.
STATIC ACCUMULATOR (50 picosiemens or less):
YES
-------------------------------------------------------------------------15. REGULATORY INFORMATION
-------------------------------------------------------------------------US OSHA HAZARD COMMUNICATION STANDARD: When used for its intended
purposes, this product is not classified as hazardous in
accordance with OSHA 29 CFR 1910.1200.
EU Labeling: Product is not dangerous as defined by the European Union
Dangerous Substances/Preparations Directives. EU labeling not
required.
Governmental Inventory Status: All components comply with TSCA,
EINECS/ELINCS, AICS, METI, DSL, KOREA, and PHILIPPINES.
U.S. Superfund Amendments and Reauthorization Act (SARA) Title III:
This product contains no "EXTREMELY HAZARDOUS SUBSTANCES".
SARA (311/312) REPORTABLE HAZARD CATEGORIES: None.
This product contains no chemicals subject to the supplier notification
requirements of SARA (313) toxic release program.
The following product ingredients are cited on the lists below:
CHEMICAL NAME
CAS NUMBER
LIST CITATIONS
----------------------------------*** NO REPORTABLE INGREDIENTS ***
--- REGULATORY LISTS SEARCHED --1=ACGIH ALL 6=IARC 1
11=TSCA 4
16=CA P65 CARC
21=LA RTK
2=ACGIH A1
7=IARC 2A
12=TSCA 5a2 17=CA P65 REPRO 22=MI 293
3=ACGIH A2
8=IARC 2B
13=TSCA 5e
18=CA RTK
23=MN RTK
4=NTP CARC
9=OSHA CARC 14=TSCA 6
19=FL RTK
24=NJ RTK
5=NTP SUS
10=OSHA Z
15=TSCA 12b 20=IL RTK
25=PA RTK
26=RI RTK
Code key: CARC=Carcinogen; SUS=Suspected Carcinogen; REPRO=Reproductive
-------------------------------------------------------------------------16. OTHER INFORMATION
-------------------------------------------------------------------------USE: WAY OIL
NOTE: PRODUCTS OF EXXON MOBIL CORPORATION AND ITS AFFILIATED COMPANIES
ARE NOT FORMULATED TO CONTAIN PCBS.
Health studies have shown that many hydrocarbons pose potential human
health risks which may vary from person to person. Information provided
on this MSDS reflects intended use. This product should not be used for
other applications. In any case, the following advice should be
considered:
INJECTION INJURY WARNING: If product is injected into or under the skin,
or into any part of the body, regardless of the appearance of the wound
or its size, the individual should be evaluated immediately by a
physician as a surgical emergency. Even though initial symptoms from
high pressure injection may be minimal or absent, early surgical
treatment within the first few hours may significantly reduce the
ultimate extent of injury.
INDUSTRIAL LABEL
Under normal conditions of intended use, this product does not pose a
risk to health. Excessive exposure may result in eye, skin or
respiratory irritation. Always observe good hygiene measures. First
CI-L-15
Aid: Wash skin with soap and water. Flush eyes with water. If
overcome by fumes or vapor, remove to fresh air. If ingested do not
induce vomiting. If symptoms persist seek medical assistance. Read
and understand the MSDS before using this product.
*************************************************************************
For Internal Use Only: MHC: 1* 1* 1* 1* 1*, MPPEC: A, TRN: 600510-00,
ELIS: 400319, CMCS97: 970855, REQ: US - MARKETING, SAFE USE: L
EHS Approval Date: 16JUN2003
*************************************************************************
*************************************************************************
Legally required information is given in accordance with applicable
Information given herein is offered in good faith as accurate, but
without guarantee. Conditions of use and suitability of the product for
particular uses are beyond our control; all risks of use of the product
are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL
WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO
THE USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a
recommendation for uses which infringe valid patents or as extending
any license under valid patents. Appropiate warnings and safe handling
procedures should be providedto handlers and users. Use or retransmission of the information contained herein in any other format
than the format as presented is strictly prohibited. ExxonMobil neither
represents nor warrants that the format, content or product formulas
contained in this document comply with the laws of any other country
except the United States of America.
*************************************************************************
Copyright 2001 Exxon Mobil Corporation, All rights reserved
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DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 1 of 6
MOLYKOTE(R) G-N METAL ASSEMBLY PASTE
1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY
Revision Date: 2004/07/26
MSDS No.: 02076683
Product Information: (800) 248-2481
Product Safety: (888) 335-1331
CANUTEC: (613) 996-6666
SUPPLIER:
Dow Corning Canada Inc.
15-6400 Millcreek Drive, Suite 416
Mississauga, ON L5N 3E7
Canada
24 Hour Emergency Telephone: (989) 496-5900
MANUFACTURER:
Dow Corning Corporation
South Saginaw Road
Midland, Michigan 48686
WHMIS CLASSIFICATION: Class D, Division 2, Subdivision B.
Material Usage: Lubricant
2. COMPOSITION / INFORMATION ON INGREDIENTS
CAS Number
Wt %
Component Name
64741-89-5
40.0 - 70.0
Solvent-refined light paraffinic petroleum distillate
1317-33-5
15.0 - 40.0
Molybdenum disulfide
7446-26-6
10.0 - 30.0
Zinc pyrophosphate
7631-86-9
1.0 - 5.0
Silica, amorphous
7784-30-7
1.0 - 5.0
Aluminum phosphate
The ingredients listed above are controlled products as defined in CPR, am. SOR/88-555.
3. EFFECTS OF OVEREXPOSURE
EMERGENCY OVERVIEW
Generic Description:
Physical Form:
Colour:
Odour:
Inorganic compounds in mineral oil
Paste
Charcoal gray
Slight
++++++++++++++++++++++++++++++++++++++++++++
POTENTIAL HEALTH EFFECTS
Acute Effects
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Material Safety Data Sheet
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MOLYKOTE(R) G-N METAL ASSEMBLY PASTE
Eye:
Direct contact may cause mild irritation.
Skin:
No significant irritation expected from a single short-term exposure.
Inhalation:
Vapor may irritate nose and throat. Vapor overexposure may cause drowsiness.
Oral:
Low ingestion hazard in normal use.
Prolonged/Repeated Exposure Effects
Skin:
Repeated or prolonged contact may cause defatting and drying of skin which may result
in skin irritation and dermatitis.
Inhalation:
Overexposure by inhalation may injure the following organ(s):Nervous system.
Oral:
Repeated ingestion or swallowing large amounts may injure internally.
Signs and Symptoms of Overexposure
No known applicable information.
Medical Conditions Aggravated by Exposure
No known applicable information.
The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar
compositions, component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology
information.
4. FIRST AID MEASURES
Eye:
Immediately flush with water for 15 minutes.
Skin:
Remove from skin and wash thoroughly with soap and water or waterless cleanser. Get
medical attention if irritation or other ill effects develop or persist.
Inhalation:
Remove to fresh air. Get medical attention if ill effects persist.
Oral:
Get medical attention.
Comments:
Treat according to person's condition and specifics of exposure.
5. FIRE FIGHTING MEASURES
Flash Point:
> 212 °F / > 100 °C (Closed Cup)
Autoignition
Temperature:
Not available.
Flammability Limits in Air: Not available.
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MOLYKOTE(R) G-N METAL ASSEMBLY PASTE
Extinguishing Media:
On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide
(CO2), dry chemical or water spray. Water can be used to cool fire exposed containers.
Fire Fighting Measures:
Self-contained breathing apparatus and protective clothing should be worn in fighting
large fires involving chemicals. Determine the need to evacuate or isolate the area
according to your local emergency plan. Use water spray to keep fire exposed containers
cool.
Unusual Fire Hazards:
None.
Hazardous Decomposition Products
Thermal breakdown of this product during fire or very high heat conditions may evolve the following hazardous
decomposition products: Carbon oxides and traces of incompletely burned carbon compounds. Nitrogen oxides.
Sulfur oxides. Metal oxides. Phosphorous oxides. Formaldehyde.
6. ACCIDENTAL RELEASE MEASURES
Containment/Clean up:
Observe all personal protection equipment recommendations described in Sections 5
and 8. Wipe up or scrape up and contain for salvage or disposal. Clean area as
appropriate since spilled materials, even in small quantities, may present a slip hazard.
Final cleaning may require use of steam, solvents or detergents. Dispose of saturated
absorbant or cleaning materials appropriately, since spontaneous heating may occur.
Local, provincial, federal laws and regulations may apply to releases and disposal of this
material, as well as those materials and items employed in the cleanup of releases.
Note: See section 8 for Personal Protective Equipment for Spills. Call Dow Corning Corporation, (989) 496-5900, if
additional information is required.
7. HANDLING AND STORAGE
Use with adequate ventilation. Avoid eye contact. Avoid skin contact. Avoid breathing vapor, mist, dust, or fumes.
Keep container closed. Do not take internally.
Use reasonable care and store away from oxidizing materials.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Component Exposure Limits
Consult local authorities for acceptable provincial values.
CAS Number
Component Name
Exposure Limits
64741-89-5
Solvent-refined light paraffinic petroleum
distillate
Observe oil mist limits. OSHA PEL (final rule) and
ACGIH TLV: TWA 5 mg/m3; ACGIH STEL 10 mg/m3.
LD50: > 15 g/kg - Oral Rat
1317-33-5
Molybdenum disulfide
Observe molybdenum limits. OSHA PEL (final rule):
TWA 5 mg/m3 and ACGIH TLV: TWA 0.5 mg/m3
respirable fraction for soluble compounds as Mo.
OSHA PEL (final rule): TWA 15 mg/m3 total dust and
ACGIH TLV: TWA 10 mg/m3 inhalable fraction, 3
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Material Safety Data Sheet
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MOLYKOTE(R) G-N METAL ASSEMBLY PASTE
mg/m3 respirable fraction for metal and insoluble
compounds as Mo.
7784-30-7
Aluminum phosphate
Observe aluminum (soluble salts) limits. OSHA PEL
(final rule) and ACGIH TLV, as aluminum: TWA 2
mg/m3.
LD50: > 5 g/kg - Oral Mouse
7631-86-9
Silica, amorphous
OSHA PEL (final rule): TWA 80mg/m3/%SiO2. NIOSH
REL: TWA 6mg/m3.
Engineering Controls
Local Ventilation:
General Ventilation:
Recommended.
Recommended.
Personal Protective Equipment for Routine Handling
Eyes:
Use proper protection - safety glasses as a minimum.
Skin:
Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed
as soon as practical and thoroughly cleaned before reuse. Chemical protective gloves
are recommended.
Suitable Gloves:
Neoprene Rubber(R). Polyvinylalcohol. Nitrile Rubber. Polyvinylchloride.
Inhalation:
Use respiratory protection unless adequate local exhaust ventilation is provided or air
sampling data show exposures are within recommended exposure guidelines. Industrial
Hygiene Personnel can assist in judging the adequacy of existing engineering controls.
Suitable Respirator:
General and local exhaust ventilation is recommended to maintain vapor exposures
below recommended limits. Where concentrations are above recommended limits as
determined by air sampling or are unknown, appropriate respiratory protection should be
worn. Follow CSA Standard Z94.4-93 and use NIOSH/MHSA approved respirators.
Personal Protective Equipment for Spills
Eyes:
Use full face respirator.
Skin:
Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed
as soon as practical and thoroughly cleaned before reuse. Chemical protective gloves
are recommended.
Inhalation/Suitable
Respirator:
Respiratory protection recommended. Follow CSA Standard Z94.4-93 and use
NIOSH/MHSA approved respirators. Protection provided by air purifying respirators
against exposure to any hazardous chemical is limited. Use a positive pressure air
supplied respirator if there is any potential for uncontrolled release, exposure levels are
unknown, or any other circumstance where air purifying respirators may not provide
adequate protection.
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Material Safety Data Sheet
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MOLYKOTE(R) G-N METAL ASSEMBLY PASTE
Precautionary Measures: Avoid eye contact. Avoid skin contact. Avoid breathing vapor, mist, dust, or fumes. Keep
container closed. Do not take internally. Use reasonable care.
Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may
require added precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical Form:
Color:
Odor:
Odor Threshold:
Specific Gravity @ 25°C:
Viscosity:
Freezing/Melting Point:
Boiling Point:
Vapor Pressure @ 25°C:
Vapor Density:
Evaporation Rate:
Solubility in Water:
Coefficient of Water/Oil
Distribution:
pH:
Volatile Content:
Paste
Charcoal gray
Slight
Not available.
1.35
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Note: The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing
specifications.
10. STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Hazardous
Polymerization:
Conditions to Avoid:
Hazardous polymerization will not occur.
Materials to Avoid:
Oxidizing material can cause a reaction.
None.
11. TOXICOLOGICAL INFORMATION
Special Hazard Information on Components
No known applicable information.
12. ECOLOGICAL INFORMATION
Environmental Fate and Distribution
Complete information is not yet available.
Environmental Effects
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Material Safety Data Sheet
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MOLYKOTE(R) G-N METAL ASSEMBLY PASTE
Complete information is not yet available.
Fate and Effects in Waste Water Treatment Plants
Complete information is not yet available.
Ecotoxicity Classification Criteria
High
Medium
<=1
>1 and <=100
<=100
>100 and <= 2000
Hazard Parameters (LC50 or EC50)
Acute Aquatic Toxicity (mg/L)
Acute Terrestrial Toxicity
Low
>100
>2000
This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993.
This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented
in the section concerning the overall ecological safety of this material.
13. DISPOSAL CONSIDERATIONS
Can be incinerated in accordance with local regulations.
Call local hazardous waste disposal company or provincial waste authorities for more information.
14. TRANSPORT INFORMATION
Check product label for transportation information. Call Dow Corning Transportation, (989) 496-8577, if additional
information is required.
15. REGULATORY INFORMATION
This product has been classified in accordance with the hazard criteria of the CPR, and the MSDS contains all the
information required by the CPR.
WHMIS
CLASSIFICATION:
Class D, Division 2, Subdivision B.
DSL STATUS:
All chemical substances in this material are included on or exempted from the DSL.
16. OTHER INFORMATION
Prepared by: Dow Corning Corporation
These data are offered in good faith as typical values and not as product specifications. No warranty, either
expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are
believed to be generally applicable. However, each user should review these recommendations in the specific
context of the intended use and determine whether they are appropriate.
(R) indicates Registered Trademark
CI-L-16
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CI-L-17
Product Name: EXXON SPARTAN EP 220
Revision Date: 26Jun2007
Page 1 of 8
______________________________________________________________________________________________________________________
MATERIAL SAFETY DATA SHEET
PRODUCT AND COMPANY IDENTIFICATION
SECTION 1
PRODUCT
Product Name: EXXON SPARTAN EP 220
Product Description: Base Oil and Additives
Product Code: 16057
Intended Use: Gear oil
COMPANY IDENTIFICATION
Supplier:
Canada Imperial Oil Limited, An Affliate of Exxon Mobil Corporation
P.O. Box 2480, Station M
Calgary, ALBERTA. T2P 3M9 Canada
24 Hour Health Emergency
519-339-2145
Transportation Emergency Phone
519-339-2145
Supplier General Contact
1-800-567-3776
COMPOSITION / INFORMATION ON INGREDIENTS
SECTION 2
No Reportable Hazardous Substance(s) or Complex Substance(s).
HAZARDS IDENTIFICATION
SECTION 3
This material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15).
POTENTIAL HEALTH EFFECTS
Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure
injection under skin may cause serious damage.
NFPA Hazard ID:
HMIS Hazard ID:
Health:
Health:
0
0
Flammability: 1
Flammability: 1
Reactivity: 0
Reactivity: 0
NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert
advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary
from person to person.
SECTION 4
FIRST AID MEASURES
INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use
adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use
mouth-to-mouth resuscitation.
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______________________________________________________________________________________________________________________
SKIN CONTACT
Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the
body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by
a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be
minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent
of injury.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.
INGESTION
First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.
Inappropriate Extinguishing Media: Straight Streams of Water
FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams,
sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed
spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to
protect personnel.
Hazardous Combustion Products: Sulfur oxides, Aldehydes, Smoke, Fume, Oxides of carbon, Incomplete
combustion products
FLAMMABILITY PROPERTIES
Flash Point [Method]: 232C (450F) [ ASTM D-92]
Flammable Limits (Approximate volume % in air): LEL: 0.9
Autoignition Temperature: 365°C (689°F)
SECTION 6
UEL: 7.0
ACCIDENTAL RELEASE MEASURES
NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations. In the event of a spill or accidental release, notify relevant authorities in accordance with all
applicable regulations. US regulations require reporting releases of this material to the environment which
exceed the applicable reportable quantity or oil spills which could reach any waterway including intermittent dry
creeks. The National Response Center can be reached at (800)424-8802.
SPILL MANAGEMENT
Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent.
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Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other
shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist
before using dispersants.
Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways,
sewers, basements or confined areas.
SECTION 7
HANDLING AND STORAGE
HANDLING
Prevent small spills and leakage to avoid slip hazard.
Static Accumulator: This material is a static accumulator.
STORAGE
Do not store in open or unlabelled containers.
SECTION 8
EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols
can occur, the following are recommended: 5 mg/m³ - ACGIH TLV, 10 mg/m³ - ACGIH STEL, 5 mg/m³ - OSHA PEL.
NOTE: Limits/standards shown for guidance only. Follow applicable regulations.
ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a
level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
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______________________________________________________________________________________________________________________
No special requirements under ordinary conditions of use and with adequate ventilation.
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Work conditions can greatly affect glove durability; inspect and replace worn or damaged
gloves. The types of gloves to be considered for this material include:
No protection is ordinarily required under normal conditions of use.
Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
No skin protection is ordinarily required under normal conditions of use. In accordance with good
industrial hygiene practices, precautions should be taken to avoid skin contact.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
ENVIRONMENTAL CONTROLS
See Sections 6, 7, 12, 13.
SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional
data.
GENERAL INFORMATION
Physical State: Liquid
Form: Clear
Color: Amber
Odor: Characteristic
Odor Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15 C ): 0.89
Flash Point [Method]: 232C (450F) [ ASTM D-92]
Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0
Autoignition Temperature: 365°C (689°F)
Boiling Point / Range: 350C (662F) - 615C (1139F)
Vapor Density (Air = 1): N/D
Vapor Pressure: [N/D at 20 °C ] | < 1 kPa (7.5 mm Hg) at 38C
Evaporation Rate (n-butyl acetate = 1): < 0.1
pH: N/A
Log Pow (n-Octanol/Water Partition Coefficient): > 3.5
Solubility in Water: Negligible
Viscosity: 220 cSt (220 mm2/sec ) at 40 C
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Oxidizing Properties: See Sections 3, 15, 16.
OTHER INFORMATION
Freezing Point: N/D
Melting Point: N/A
Pour Point:
-15°C (5°F)
DMSO Extract (mineral oil only), IP-346:
< 3 %wt
STABILITY AND REACTIVITY
SECTION 10
STABILITY: Material is stable under normal conditions.
CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition.
MATERIALS TO AVOID: Strong oxidizers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.
HAZARDOUS POLYMERIZATION: Will not occur.
SECTION 11
ACUTE TOXICITY
Route of Exposure
Inhalation
Toxicity (Rat): LC50 > 5000 mg/m3
Irritation: Data available.
Ingestion
Toxicity (Rat): LD50 > 2000 mg/kg
Skin
Toxicity (Rabbit): LD50 > 2000 mg/kg
Irritation (Rabbit): Data available.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar
materials.
Negligible hazard at ambient/normal handling temperatures.
Based on assessment of the components.
Minimally Toxic. Based on test data for structurally similar
materials.
Minimally Toxic. Based on test data for structurally similar
materials.
Negligible irritation to skin at ambient temperatures. Based on test
data for structurally similar materials.
Eye
Irritation (Rabbit): Data available.
May cause mild, short-lasting discomfort to eyes. Based on test
data for structurally similar materials.
CHRONIC/OTHER EFFECTS
For the product itself:
Repeated and/or prolonged exposure may cause irritation to the skin, eyes, or respiratory tract.
Contains:
Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified
Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung nonspecific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test
animals.
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______________________________________________________________________________________________________________________
Additional information is available by request.
The following ingredients are cited on the lists below: None.
1 = NTP CARC
2 = NTP SUS
SECTION 12
--REGULATORY LISTS SEARCHED-3 = IARC 1
5 = IARC 2B
4 = IARC 2A
6 = OSHA CARC
ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials.
ECOTOXICITY
Material -- Not expected to be harmful to aquatic organisms.
MOBILITY
Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to
partition to sediment and wastewater solids.
PERSISTENCE AND DEGRADABILITY
Biodegradation:
Base oil component -- Expected to be inherently biodegradable
BIOACCUMULATION POTENTIAL
Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may
reduce the bioconcentration or limit bioavailability.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.
DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of undesirable combustion products.
REGULATORY DISPOSAL INFORMATION
RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous
waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It
does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with
contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used
product may be regulated.
Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and
can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be
completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken
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______________________________________________________________________________________________________________________
for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with
governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14
TRANSPORT INFORMATION
LAND (DOT) : Not Regulated for Land Transport
LAND (TDG) : Not Regulated for Land Transport
SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code
AIR (IATA) : Not Regulated for Air Transport
SECTION 15
REGULATORY INFORMATION
OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not classified
as hazardous in accordance with OSHA 29 CFR 1910.1200.
NATIONAL CHEMICAL INVENTORY LISTING: DSL, TSCA
EPCRA: This material contains no extremely hazardous substances.
SARA (311/312) REPORTABLE HAZARD CATEGORIES: None.
SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification
requirements of the SARA 313 Toxic Release Program.
The Following Ingredients are Cited on the Lists Below: None.
1 = ACGIH ALL
2 = ACGIH A1
3 = ACGIH A2
4 = OSHA Z
5 = TSCA 4
--REGULATORY LISTS SEARCHED-6 = TSCA 5a2
11 = CA P65 REPRO
7 = TSCA 5e
12 = CA RTK
8 = TSCA 6
13 = IL RTK
9 = TSCA 12b
14 = LA RTK
10 = CA P65 CARC
15 = MI 293
16 = MN RTK
17 = NJ RTK
18 = PA RTK
19 = RI RTK
Code key: CARC=Carcinogen; REPRO=Reproductive
OTHER INFORMATION
SECTION 16
N/D = Not determined, N/A = Not applicable
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:
Revision Changes:
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______________________________________________________________________________________________________________________
Section 13: Empty Container Warning was modified.
Section 08: Hand Protection was modified.
Section 01: Company Mailing Address was modified.
Section 15: List Citation Table - Header was modified.
Section 06: Notification Procedures was modified.
Section 15: TSCA Class 2 Statement was deleted.
--------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate
and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current
available from ExxonMobil. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for
convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any
affiliates in which they directly or indirectly hold any interest.
----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only
MHC: 0, 0, 0, 0, 0, 0
PPEC: A
DGN: 5014370 (1012504)
----------------------------------------------------------------------------------------------------------------------------------------------------Copyright 2002 Exxon Mobil Corporation, All rights reserved
6/22/2010
CI-L-18
Material Safety Data Sheet
PLEXIGLAS® G ACRYLIC SHEET
1. PRODUCT AND COMPANY IDENTIFICATION
Company
Arkema Inc.
2000 Market Street
Philadelphia, Pennsylvania 19103
Altuglas International
Customer Service Telephone Number:
(800) 523-1532
(Monday through Friday, 8:30 AM to 5:30 PM EST)
Emergency Information
CHEMTREC: (800) 424-9300
(24 hrs., 7 days a week)
Rocky Mountain Poison Center: (303) 623-5716
(24 hrs., 7 days a week)
Transportation:
Medical:
Product Information
PLEXIGLAS® G ACRYLIC SHEET
Not available
Not available
acrylic copolymer
Special applications, in general
Product name:
Synonyms:
Molecular formula:
Chemical family:
Product use:
2. HAZARDS IDENTIFICATION
Emergency Overview
Color:
Physical state:
Form:
Odor:
clear
solid
sheets
odourless
CAUTION!
PROCESSING MAY RELEASE VAPORS AND/OR FUMES WHICH CAUSE EYE, SKIN AND RESPIRATORY
TRACT IRRITATION.
Potential Health Effects
Primary routes of exposure:
Inhalation and skin contact.
Signs and symptoms of acute exposure:
High molecular weight polymer. The product, in the form supplied, is not anticipated to produce significant adverse
human health effects. Product dust may be irritating to eyes, skin and respiratory system. Effects due to processing
releases: Irritating to eyes, respiratory system and skin. Inhalation of fume may cause flu-like symptoms. (severity of
effects depends on extent of exposure) Prolonged or repeated exposure may cause: headache, drowsiness, nausea,
weakness.
Remarks:
Product code: 11630
Version 1.1
Issued on: 10/29/2008
CI-M-01
Page: 1 / 8
Material Safety Data Sheet
PLEXIGLAS® G ACRYLIC SHEET
Handle in accordance with good industrial hygiene and safety practice. (sheets) Secondary operations, such as
grinding, sanding or sawing, can produce dust which may present a respiratory hazard. This product may release
fume and/or vapor of variable composition depending on processing time and temperature.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
CAS-No.
Wt/Wt
Polymethyl methacrylate copolymers
Proprietary*
99 - 100 %
OSHA
Hazardous
N
The substance(s) marked with a "Y" in the Hazard column above, are those identified as hazardous chemicals under
the criteria of the OSHA Hazard Communication Standard (29 CFR 1910.1200).
*The specific chemical identity is withheld because it is trade secret information of Arkema Inc.
While this material is not classified as hazardous under Federal OSHA regulations, this MSDS contains valuable
information critical to the safe handling and proper use of this product. This MSDS should be retained and available
for employees and other users of this product.
4. FIRST AID MEASURES
Inhalation:
If inhaled, remove to fresh air.
Skin:
In case of contact, immediately flush skin with plenty of water. If molten polymer gets on the skin, cool rapidly with
cold water. Do not peel solidified product off the skin. Obtain medical treatment for thermal burns. Remove material
from clothing. Wash clothing before reuse.
Eyes:
Immediately flush eye(s) with plenty of water. Obtain medical treatment for thermal burns.
Ingestion:
If swallowed, DO NOT induce vomiting. Get medical attention. Never give anything by mouth to an unconscious
person.
5. FIRE-FIGHTING MEASURES
Flash point
not applicable
Auto-ignition temperature:
860 °F (460 °C)
Lower flammable limit (LFL):
not applicable
Upper flammable limit (UFL):
not applicable
Extinguishing media (suitable):
Dry chemical, water spray, carbon dioxide, foam
Protective equipment:
Product code: 11630
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Material Safety Data Sheet
PLEXIGLAS® G ACRYLIC SHEET
Fire fighters and others who may be exposed to products of combustion should wear full fire fighting turn out gear
(full Bunker Gear) and self-contained breathing apparatus (pressure demand / NIOSH approved or equivalent).
Further firefighting advice:
Fire fighting equipment should be thoroughly decontaminated after use.
Fire and explosion hazards:
Heated material can form flammable vapors with air.
6. ACCIDENTAL RELEASE MEASURES
In case of spill or leak:
Pick up and transfer to properly labelled containers. Consult a regulatory specialist to determine appropriate state or
local reporting requirements, for assistance in waste characterization and/or hazardous waste disposal and other
requirements listed in pertinent environmental permits.
7. HANDLING AND STORAGE
Handling
General information on handling:
Avoid breathing processing fumes or vapors.
Avoid breathing dust.
Handle in accordance with good industrial hygiene and safety practices.
These practices include avoiding unnecessary exposure and removal of material from eyes, skin and clothing.
Storage
General information on storage conditions:
Avoid extreme temperatures.
Storage incompatibility – General:
Store away from sources of heat and light.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Airborne Exposure Guidelines:
2-Propenoic acid, 2-methyl-, methyl ester (80-62-6)
US. ACGIH Threshold Limit Values
Time Weighted Average (TWA):
Short Term Exposure Limit (STEL):
50 ppm
100 ppm
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
PEL:
Product code: 11630
100 ppm (410 mg/m3)
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Material Safety Data Sheet
PLEXIGLAS® G ACRYLIC SHEET
Only those components with exposure limits are printed in this section. Limits with skin contact designation above have skin contact
effect. Air sampling alone is insufficient to accurately quantitate exposure. Measures to prevent significant cutaneous absorption
may be required. Limits with a sensitizer designation above mean that exposure to this material may cause allergic reactions.
Engineering controls:
Investigate engineering techniques to reduce exposures below airborne exposure limits. Provide ventilation if
necessary to control exposure levels below airborne exposure limits (see above). If practical, use local
mechanical exhaust ventilation at sources of air contamination such as open process equipment.
Respiratory protection:
Avoid breathing processing fumes or vapors. Avoid breathing dust. Where airborne exposure is likely or
airborne exposure limits are exceeded (if applicable, see above), use NIOSH approved respiratory protection
equipment appropriate to the material and/or its components and substances released during processing.
Consult respirator manufacturer to determine appropriate type equipment for a given application. Observe
respirator use limitations specified by NIOSH or the manufacturer. For emergency and other conditions where
there may be a potential for significant exposure or where exposure limit may be significantly exceeded, use an
approved full face positive-pressure, self-contained breathing apparatus or positive-pressure airline with
auxiliary self-contained air supply. Respiratory protection programs must comply with 29 CFR § 1910.134.
Skin protection:
Processing of this product releases vapors or fumes which may cause skin irritation. Minimize skin
contamination by following good industrial hygiene practice. Wearing protective gloves is recommended. Wash
hands and contaminated skin thoroughly after contact with processing fumes or vapors. Wash thoroughly after
handling.
Eye protection:
Processing of this product releases vapors or fumes which may cause eye irritation. Use good industrial
practice to avoid eye contact. Where eye contact may be likely, wear chemical goggles and have eye flushing
equipment available.
9. PHYSICAL AND CHEMICAL PROPERTIES
Color:
clear
Physical state:
solid
Form:
sheets
Odor:
odourless
pH:
not applicable
Density:
not applicable
Vapor pressure:
not applicable
Vapor density:
not applicable
Boiling point/boiling
range:
not applicable
Freezing point:
not applicable
Product code: 11630
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Material Safety Data Sheet
PLEXIGLAS® G ACRYLIC SHEET
Melting point/range:
not applicable
Solubility in water:
insoluble
% Volatiles:
0%
10. STABILITY AND REACTIVITY
Stability:
The product is stable under normal handling and storage conditions
Hazardous reactions:
Hazardous polymerization does not occur.
Materials to avoid:
None under normal conditions of use.
Conditions / hazards to avoid:
Avoid flames, welding arcs, potential ignition sources, or other high temperature sources which induce thermal
decomposition.
Hazardous decomposition products:
Thermal decomposition may yield acrylic monomers. Thermal decomposition begins to generate monomer vapor at
>570F (>300 C).
11. TOXICOLOGICAL INFORMATION
Data on this material and/or its components are summarized below.
Data for Polymethyl methacrylate copolymers (Proprietary)
Acute toxicity
Oral:
Practically nontoxic. (rat) LD50 = 8,000 mg/kg. (similar material)
Genotoxicity
Assessment in Vitro:
No genetic changes were observed in laboratory tests using: bacteria, human cells
Genotoxicity
Assessment in Vivo:
No genetic changes were observed in laboratory tests using: animals
Other information
Biocompatibility testing for this polymer or its extracts has generally shown that the material is inert.
Human experience
Product code: 11630
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Material Safety Data Sheet
PLEXIGLAS® G ACRYLIC SHEET
Skin contact:
Skin: Irritant but not a sensitizer. Mechanical irritation. (studied using human volunteers)
12. ECOLOGICAL INFORMATION
Chemical Fate and Pathway
No data are available.
Ecotoxicology
No data are available.
13. DISPOSAL CONSIDERATIONS
Waste disposal:
Where possible recycling is preferred to disposal or incineration. If recycling is not an option, incinerate or dispose of
in accordance with federal, state, and local regulations. Pigmented, filled and/or solvent laden product may require
special disposal practices in accordance with federal, state and local regulations. Consult a regulatory specialist to
determine appropriate state or local reporting requirements, for assistance in waste characterization and/or
hazardous waste disposal and other requirements listed in pertinent environmental permits. Note: Chemical
additions to, processing of, or otherwise altering this material may make this waste management information
incomplete, inaccurate, or otherwise inappropriate. Furthermore, state and local waste disposal requirements may
be more restrictive or otherwise different from federal laws and regulations.
14. TRANSPORT INFORMATION
US Department of Transportation (DOT): not regulated
International Maritime Dangerous Goods Code (IMDG): not regulated
15. REGULATORY INFORMATION
Chemical Inventory Status
EU. EINECS
EINECS
Does not conform
US. Toxic Substances Control Act
TSCA
The components of this product are all on
the TSCA Inventory.
Australia. Industrial Chemical (Notification and
Assessment) Act
AICS
Conforms to
Canada. Canadian Environmental Protection Act
DSL
(CEPA). Domestic Substances List (DSL). (Can. Gaz.
Part II, Vol. 133)
All components of this product are on the
Canadian DSL list.
Japan. Kashin-Hou Law List
ENCS (JP)
Conforms to
Korea. Toxic Chemical Control Law (TCCL) List
KECI (KR)
Conforms to
Product code: 11630
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Material Safety Data Sheet
PLEXIGLAS® G ACRYLIC SHEET
Philippines. The Toxic Substances and Hazardous
and Nuclear Waste Control Act
PICCS (PH)
Conforms to
China. Inventory of Existing Chemical Substances
IECSC (CN)
Conforms to
New Zealand. Inventory of Chemicals (NZIoC), as
published by ERMA New Zealand
NZIOC
Does not conform
United States – Federal Regulations
SARA Title III – Section 302 Extremely Hazardous Chemicals:
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
302.
SARA Title III - Section 311/312 Hazard Categories:
No SARA Hazards
SARA Title III – Section 313 Toxic Chemicals:
SARA 313: This material does not contain any chemical components with known CAS numbers that
exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) - Reportable
Quantity (RQ):
The components in this product are either not CERCLA regulated, regulated but present in negligible concentrations,
or regulated with no assigned reportable quantity.
OSHA Regulated Carcinogens (NTP, IARC, OSHA Listed):
NTP:
No component of this product present at levels greater than or equal to 0.1% is identified as a known or
anticipated carcinogen by NTP.
IARC:
No component of this product present at levels greater than or equal to 0.1% is identified as probable,
possible or confirmed human carcinogen by IARC.
OSHA:
No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen
or potential carcinogen by OSHA.
United States – State Regulations
Massachusetts Right to Know
No components are subject to the Massachusetts Right to Know Act.
Product code: 11630
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Material Safety Data Sheet
PLEXIGLAS® G ACRYLIC SHEET
New Jersey Right to Know
No components are subject to the New Jersey Right to Know Act.
Pennsylvania Right to Know
Chemical Name
Polymethyl methacrylate copolymers
CAS-No.
Proprietary
California Prop. 65
This product does not contain any chemicals known to the State of California to cause cancer, birth
defects, or any other reproductive defects.
16. OTHER INFORMATION
Latest Revision(s):
Revised Section(s):
Reference number:
Date of Revision:
Date Printed:
Updated Section 2 and 9
000000036586
10/29/2008
10/29/2008
PLEXIGLAS® is a registered trademark of Arkema Inc.
Arkema Inc. believes that the information and recommendations contained herein (including data and
statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR
PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR
IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided
herein relates only to the specific product designated and may not be valid where such product is used in
combination with any other materials or in any process. Further, since the conditions and methods of use
are beyond the control of Arkema Inc., Arkema Inc. expressly disclaims any and all liability as to any results
obtained or arising from any use of the product or reliance on such information.
Product code: 11630
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Material Safety Data Sheet
Version 1.6
Revision Date 07/20/2004
MSDS Number 300000000099
Print Date 03/05/2006
1. PRODUCT AND COMPANY IDENTIFICATION
Product name
: Nitrogen
Chemical formula
: N2
Synonyms
: Nitrogen, Nitrogen gas, Gaseous Nitrogen, GAN
Product Use Description
: General Industrial
Company
: Air Products and Chemicals,Inc
7201 Hamilton Blvd.
Allentown, PA 18195-1501
Telephone
: 800-345-3148
Emergency telephone number
: 800-523-9374 USA
01-610-481-7711 International
2. COMPOSITION/INFORMATION ON INGREDIENTS
Components
CAS Number
Nitrogen
7727-37-9
Concentration
(Volume)
100 %
Concentration is nominal. For the exact product composition, please refer to Air Products technical
specifications.
3. HAZARDS IDENTIFICATION
Emergency Overview
High pressure gas.
Can cause rapid suffocation.
Self contained breathing apparatus (SCBA) may be required.
Potential Health Effects
Inhalation
: In high concentrations may cause asphyxiation. Asphyxiation may bring about
unconsciousness without warning and so rapidly that victim may be unable to
protect themselves.
Eye contact
: No adverse effect.
Skin contact
: No adverse effect.
Ingestion
: Ingestion is not considered a potential route of exposure.
Chronic Health Hazard
: Not applicable.
Exposure Guidelines
1/7
Air Products and Chemicals,Inc
CI-N-01
Nitrogen
Material Safety Data Sheet
Version 1.6
Revision Date 07/20/2004
MSDS Number 300000000099
Print Date 03/05/2006
Primary Routes of Entry
: Inhalation
Target Organs
: None known.
Symptoms
: Exposure to oxygen deficient atmosphere may cause the following symptoms:
Dizziness. Salivation. Nausea. Vomiting. Loss of mobility/consciousness.
Aggravated Medical Condition
None.
Environmental Effects
Not harmful.
4. FIRST AID MEASURES
General advice
: Remove victim to uncontaminated area wearing self contained breathing
apparatus. Keep victim warm and rested. Call a doctor. Apply artificial
respiration if breathing stopped.
Eye contact
: Not applicable.
Skin contact
: Not applicable.
Ingestion
: Ingestion is not considered a potential route of exposure.
Inhalation
: Remove to fresh air. If breathing has stopped or is labored, give assisted
respirations. Supplemental oxygen may be indicated. If the heart has stopped,
trained personnel should begin cardiopulmonary resuscitation immediately. In
case of shortness of breath, give oxygen.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
: All known extinguishing media can be used.
Specific hazards
: Upon exposure to intense heat or flame, cylinder will vent rapidly and or rupture
violently. Product is nonflammable and does not support combustion. Move
away from container and cool with water from a protected position. Keep
containers and surroundings cool with water spray.
Special protective equipment
for fire-fighters
: Wear self contained breathing apparatus for fire fighting if necessary.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
: Evacuate personnel to safe areas. Wear self-contained breathing apparatus
when entering area unless atmosphere is proved to be safe. Monitor oxygen
level. Ventilate the area.
Environmental precautions
: Do not discharge into any place where its accumulation could be dangerous.
Prevent further leakage or spillage if safe to do so.
2/7
Air Products and Chemicals,Inc
CI-N-01
Nitrogen
Material Safety Data Sheet
Version 1.6
Revision Date 07/20/2004
MSDS Number 300000000099
Print Date 03/05/2006
Methods for cleaning up
: Ventilate the area.
Additional advice
: If possible, stop flow of product. Increase ventilation to the release area and
monitor oxygen level. If leak is from cylinder or cylinder valve, call the Air
Products emergency telephone number. If the leak is in the user’s system,
close the cylinder valve, safely vent the pressure, and purge with an inert gas
before attempting repairs.
7. HANDLING AND STORAGE
Handling
Protect cylinders from physical damage; do not drag, roll, slide or drop. Do not allow storage area temperature
to exceed 50°C (122°F). Only experienced and properl y instructed persons should handle compressed gases.
Before using the product, determine its identity by reading the label. Know and understand the properties and
hazards of the product before use. When doubt exists as to the correct handling procedure for a particular gas,
contact the supplier. Do not remove or deface labels provided by the supplier for the identification of the cylinder
contents. When moving cylinders, even for short distances, use a cart (trolley, hand truck, etc.) designed to
transport cylinders. Leave valve protection caps in place until the container has been secured against either a
wall or bench or placed in a container stand and is ready for use. Use an adjustable strap wrench to remove
over-tight or rusted caps. Before connecting the container, check the complete gas system for suitability,
particularly for pressure rating and materials. Before connecting the container for use, ensure that back feed
from the system into the container is prevented. Ensure the complete gas system is compatible for pressure
rating and materials of construction. Ensure the complete gas system has been checked for leaks before use.
Employ suitable pressure regulating devices on all containers when the gas is being emitted to systems with
lower pressure rating than that of the container. Never insert an object (e.g. wrench, screwdriver, pry bar, etc.)
into valve cap openings. Doing so may damage valve, causing a leak to occur. Open valve slowly. If user
experiences any difficulty operating cylinder valve discontinue use and contact supplier. Close container valve
after each use and when empty, even if still connected to equipment. Never attempt to repair or modify
container valves or safety relief devices. Damaged valves should be reported immediately to the supplier. Close
valve after each use and when empty. Replace outlet caps or plugs and container caps as soon as container is
disconnected from equipment. Do not subject containers to abnormal mechanical shocks which may cause
damage to their valve or safety devices. Never attempt to lift a cylinder by its valve protection cap or guard. Do
not use containers as rollers or supports or for any other purpose than to contain the gas as supplied. Never
strike an arc on a compressed gas cylinder or make a cylinder a part of an electrical circuit. Do not smoke while
handling product or cylinders. Never re-compress a gas or a gas mixture without first consulting the supplier.
Never attempt to transfer gases from one cylinder/container to another. Always use backflow protective device
in piping. When returning cylinder install valve outlet cap or plug leak tight. Never use direct flame or electrical
heating devices to raise the pressure of a container. Containers should not be subjected to temperatures above
50°C (122°F). Prolonged periods of cold temperature below -30°C (-20°F) should be avoided.
Storage
Full containers should be stored so that oldest stock is used first. Containers should be stored in a purpose build
compound which should be well ventilated, preferably in the open air. Stored containers should be periodically
checked for general condition and leakage. Observe all regulations and local requirements regarding storage of
containers. Protect containers stored in the open against rusting and extremes of weather. Containers should
not be stored in conditions likely to encourage corrosion. Containers should be stored in the vertical position and
properly secured to prevent toppling. The container valves should be tightly closed and where appropriate valve
outlets should be capped or plugged. Container valve guards or caps should be in place. Keep containers tightly
closed in a cool, well-ventilated place. Store containers in location free from fire risk and away from sources of
heat and ignition. Full and empty cylinders should be segregated. Do not allow storage temperature to exceed
50°C (122°F). Return empty containers in a timely ma nner.
3/7
Air Products and Chemicals,Inc
CI-N-01
Nitrogen
Material Safety Data Sheet
Version 1.6
Revision Date 07/20/2004
MSDS Number 300000000099
Print Date 03/05/2006
Technical measures/Precautions
Containers should be segregated in the storage area according to the various categories (e.g. flammable, toxic,
etc.) and in accordance with local regulations. Keep away from combustible material.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures
Provide natural or mechanical ventilation to prevent oxygen deficient atmospheres below 19.5% oxygen.
Personal protective equipment
Respiratory protection
: Self contained breathing apparatus (SCBA) or positive pressure airline with
mask are to be used in oxygen-deficient atmosphere. Air purifying respirators
will not provide protection. Users of breathing apparatus must be trained.
Hand protection
: Sturdy work gloves are recommended for handling cylinders.
The breakthrough time of the selected glove(s) must be greater than the
intended use period.
Eye protection
: Safety glasses recommended when handling cylinders.
Skin and body protection
: Safety shoes are recommended when handling cylinders.
Special instructions for
protection and hygiene
: Ensure adequate ventilation, especially in confined areas.
Remarks
: Simple asphyxiant.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form
: Compressed gas.
Color
: Colorless gas
Odor
: No odor warning properties.
Molecular Weight
: 28 g/mol
Relative vapor density
: 0.97 (air = 1)
Density
: 0.075 lb/ft3 (0.0012 g/cm3) at 70 °F (21 °C)
Note: (as vapor)
Specific Volume
: 13.80 ft3/lb (0.8615 m3/kg) at 70 °F (21 °C)
Boiling point/range
: -321 °F (-196 °C)
Critical temperature
: -233 °F (-147 °C)
Melting point/range
: -346 °F (-210 °C)
4/7
Air Products and Chemicals,Inc
CI-N-01
Nitrogen
Material Safety Data Sheet
Version 1.6
Revision Date 07/20/2004
MSDS Number 300000000099
Print Date 03/05/2006
Water solubility
: 0.02 g/l
10. STABILITY AND REACTIVITY
Stability
: Stable under normal conditions.
Hazardous decomposition
products
: None.
11. TOXICOLOGICAL INFORMATION
Acute Health Hazard
Ingestion
: No data is available on the product itself.
Inhalation
: No data is available on the product itself.
Skin.
: No data is available on the product itself.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects
Aquatic toxicity
: No data is available on the product itself.
Toxicity to other organisms
: No data available.
Persistence and degradability
Mobility
: No data available.
Bioaccumulation
: No data is available on the product itself.
Further information
No ecological damage caused by this product.
13. DISPOSAL CONSIDERATIONS
Waste from residues / unused
products
: Contact supplier if guidance is required. Return unused product in orginal
cylinder to supplier.
Contaminated packaging
: Return cylinder to supplier.
14. TRANSPORT INFORMATION
CFR
Proper shipping name
Class
: Nitrogen, compressed
: 2.2
5/7
Air Products and Chemicals,Inc
CI-N-01
Nitrogen
Material Safety Data Sheet
Version 1.6
Revision Date 07/20/2004
MSDS Number 300000000099
Print Date 03/05/2006
UN/ID No.
: UN1066
IATA
Proper shipping name
Class
UN/ID No.
: Nitrogen, compressed
: 2.2
: UN1066
IMDG
Proper shipping name
Class
UN/ID No.
: NITROGEN, COMPRESSED
: 2.2
: UN1066
CTC
Proper shipping name
Class
UN/ID No.
: NITROGEN, COMPRESSED
: 2.2
: UN1066
Further Information
Avoid transport on vehicles where the load space is not separated from the driver’s compartment. Ensure vehicle
driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an
emergency.
15. REGULATORY INFORMATION
OSHA Hazard Communication Standard (29 CFR 1910.1200) Hazard Class(es)
Compressed Gas.
Country
Regulatory list
Notification
USA
EU
Canada
Australia
South Korea
China
Philippines
Japan
TSCA
EINECS
DSL
AICS
ECL
SEPA
PICCS
ENCS
Included on Inventory.
Included on Inventory.
Included on Inventory.
Included on Inventory.
Included on Inventory.
Included on Inventory.
Included on Inventory.
Included on Inventory.
EPA SARA Title III Section 312 (40 CFR 370) Hazard Classification:
Sudden Release of Pressure Hazard.
US. California Safe Drinking Water & Toxic Enforcement Act (Proposition 65)
This product does not contain any chemicals known to State of California to cause cancer, birth defects or any other
harm.
16. OTHER INFORMATION
NFPA Rating
6/7
Air Products and Chemicals,Inc
CI-N-01
Nitrogen
Material Safety Data Sheet
Version 1.6
Revision Date 07/20/2004
MSDS Number 300000000099
Print Date 03/05/2006
Health
Fire
Instability
Special
:
:
:
:
0
0
0
SA
HMIS Rating
Health
Flammability
Physical hazard
Prepared by
: 0
: 0
: 3
: Air Products and Chemicals, Inc. Global EH&S Product Safety Department
For additional information, please visit our Product Stewardship web site at
http//www.airproducts.com/productstewardship/
7/7
Air Products and Chemicals,Inc
CI-N-01
Nitrogen
The enclosed sheets are for the Rofin-Sinar DC-025 laser gas. Since the gas bottle
supplied by Rofin-Sinar Inc. is a special proprietary mix, the MSDS sheets are supplied
for each gas consisting of:
1.
2.
3.
4.
5.
6.
Nitrogen
Carbon Dioxide
Carbon Monoxide
Oxygen
Xenon
Helium.
CI-N-02
MGI16625
Page 001 of 007
-----------------------------------------------------------------------------SECTION 1
CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
-----------------------------------------------------------------------------MG INDUSTRIES
EMERGENCY CONTACT:
3 GREAT VALLEY PARKWAY
CHEMTREC:
MALVERN, PENNSYLVANIA 19355
1-800-424-9300
PHONE: 610-695-7400
FAX: 610-695-7596
SUBSTANCE: NITROGEN, COMPRESSED GAS
TRADE NAMES/SYNONYMS:
DIATOMIC NITROGEN; DINITROGEN; NITROGEN; NITROGEN-14; NITROGEN GAS; STCC
4904565; UN 1066; N2; MGI16625; RTECS QW9700000
CHEMICAL FAMILY: inorganic, gas
CREATION DATE: May 07 1990
REVISION DATE: Dec 08 1998
-----------------------------------------------------------------------------SECTION 2
COMPOSITION, INFORMATION ON INGREDIENTS
-----------------------------------------------------------------------------COMPONENT: NITROGEN, COMPRESSED GAS
CAS NUMBER: 7727-37-9
EC NUMBER (EINECS): 231-783-9
PERCENTAGE: 100.0
-----------------------------------------------------------------------------SECTION 3
HAZARDS IDENTIFICATION
-----------------------------------------------------------------------------NFPA RATINGS (SCALE 0-4): HEALTH=1 FIRE=0 REACTIVITY=0
EC CLASSIFICATION (CALCULATED): No classification assigned.
EMERGENCY OVERVIEW:
PHYSICAL DESCRIPTION: Odorless, tasteless, colorless, inert gas.
MAJOR HEALTH HAZARDS: difficulty breathing
PHYSICAL HAZARDS: Containers may rupture or explode if exposed to heat.
POTENTIAL HEALTH EFFECTS:
INHALATION:
SHORT TERM EXPOSURE: nausea, vomiting, symptoms of drunkenness, tingling
sensation, suffocation, convulsions, coma
LONG TERM EXPOSURE: no information on significant adverse effects
SKIN CONTACT:
SHORT TERM EXPOSURE: no information on significant adverse effects
LONG TERM EXPOSURE: no information on significant adverse effects
EYE CONTACT:
SHORT TERM EXPOSURE: irritation
LONG TERM EXPOSURE: no information on significant adverse effects
INGESTION:
MGI16625
Page 002 of 007
SHORT TERM EXPOSURE: no information on significant adverse effects
LONG TERM EXPOSURE: no information is available
CARCINOGEN STATUS:
OSHA: N
NTP: N
IARC: N
-----------------------------------------------------------------------------SECTION 4
FIRST AID MEASURES
-----------------------------------------------------------------------------INHALATION: When safe to enter area, remove from exposure. Use a bag valve
mask or similar device to perform artificial respiration (rescue breathing)
if needed. Keep warm and at rest. Get medical attention immediately.
SKIN CONTACT: Wash if needed. If frostbite, freezing, or cryogenic burns
occur, warm affected area in warm water. If this is not available, gently
wrap affected parts in blankets. Allow circulation to return naturally. Get
medical attention immediately.
EYE CONTACT: Wash eyes immediately with large amounts of water, occasionally
lifting upper and lower lids, until no evidence of chemical remains. Get
medical attention immediately.
INGESTION: It is unlikely that emergency treatment will be required. Get
medical attention, if needed.
NOTE TO PHYSICIAN: For inhalation, consider oxygen.
-----------------------------------------------------------------------------SECTION 5
FIRE FIGHTING MEASURES
-----------------------------------------------------------------------------FIRE AND EXPLOSION HAZARDS: Negligible fire hazard. Containers may rupture or
explode if exposed to heat.
EXTINGUISHING MEDIA: carbon dioxide, regular dry chemical
Large fires: Use regular foam or flood with fine water spray.
1 of 4
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FIRE FIGHTING: Move container from fire area if it can be done without risk.
Cool containers with water spray until well after the fire is out. Stay away
from the ends of tanks. Withdraw immediately in case of rising sound from
venting safety device or any discoloration of tanks due to fire. For tank,
rail car or tank truck, evacuation radius: 800 meters (1/2 mile).
-----------------------------------------------------------------------------SECTION 6
ACCIDENTAL RELEASE MEASURES
-----------------------------------------------------------------------------OCCUPATIONAL RELEASE:
Stop leak if possible without personal risk. Keep unnecessary people away,
isolate hazard area and deny entry. Stay upwind and keep out of low areas.
MGI16625
Page 003 of 007
-----------------------------------------------------------------------------SECTION 7
HANDLING AND STORAGE
-----------------------------------------------------------------------------Store and handle in accordance with all current regulations and standards.
Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. Keep separated from
incompatible substances.
-----------------------------------------------------------------------------SECTION 8
EXPOSURE CONTROLS, PERSONAL PROTECTION
-----------------------------------------------------------------------------EXPOSURE LIMITS:
NITROGEN, COMPRESSED GAS:
No occupational exposure limits established.
VENTILATION: Provide local exhaust ventilation system. Ensure compliance with
applicable exposure limits.
EYE PROTECTION: For the gas: Eye protection not required, but recommended. For
the liquid: Wear splash resistant safety goggles. Contact lenses should not
be worn. Provide an emergency eye wash fountain and quick drench shower in
the immediate work area.
CLOTHING: For the gas: Protective clothing is not required. For the liquid:
Wear appropriate protective, cold insulating clothing.
GLOVES: Wear insulated gloves.
RESPIRATOR: Under conditions of frequent use or heavy exposure, respiratory
protection may be needed. Respiratory protection is ranked in order from
minimum to maximum. Consider warning properties before use.
For Unknown Concentrations or Immediately Dangerous to Life or Health Any supplied-air respirator with full facepiece and operated in a
pressure-demand or other positive-pressure mode in combination with a
separate escape supply.
Any self-contained breathing apparatus with a full facepiece.
-----------------------------------------------------------------------------SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
-----------------------------------------------------------------------------PHYSICAL DESCRIPTION: Odorless, tasteless, colorless, inert gas.
MOLECULAR WEIGHT: 28.0134
MOLECULAR FORMULA: N2
BOILING POINT: -321 F (-196 C)
FREEZING POINT: -346 F (-210 C)
VAPOR PRESSURE: 760 mmHg @ -196 C
VAPOR DENSITY (air=1): 0.967
SPECIFIC GRAVITY: Not applicable
DENSITY: 1.2506 g/L
WATER SOLUBILITY: 1.6% @ 20 C
PH: Not applicable
VOLATILITY: 100%
ODOR THRESHOLD: Not available
MGI16625
Page 004 of 007
EVAPORATION RATE: Not applicable
VISCOSITY: 0.01787 cP @ 27 C
COEFFICIENT OF WATER/OIL DISTRIBUTION: Not applicable
SOLVENT SOLUBILITY:
Soluble: liquid ammonia
Slightly Soluble: alcohol
-----------------------------------------------------------------------------SECTION 10
STABILITY AND REACTIVITY
-----------------------------------------------------------------------------REACTIVITY: Stable at normal temperatures and pressure.
CONDITIONS TO AVOID: Protect from physical damage and heat. Containers may
rupture or explode if exposed to heat.
INCOMPATIBILITIES: metals, oxidizing materials
NITROGEN:
LITHIUM: May ignite in the gas.
MAGNESIUM: Violent reaction with the liquid on ignition.
NEODYMIUM: Vigorous reaction.
OZONE: Mixtures of the gases may be explosive.
TITANIUM: Will burn in nitrogen atmosphere.
HAZARDOUS DECOMPOSITION:
Thermal decomposition products: oxides of nitrogen
POLYMERIZATION: Will not polymerize.
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-----------------------------------------------------------------------------SECTION 11
TOXICOLOGICAL INFORMATION
-----------------------------------------------------------------------------HEALTH EFFECTS:
INHALATION:
NITROGEN: Nitrogen inhaled under increased atmospheric pressure, (>1.5
atmospheres), may dissolve in the fat-containing brain cells, and act as an
anesthetic, causing narcosis. Persons who have been exposed to increased
pressure for a time and who are suddenly released from the pressure may
develop decompression sickness. Repeated exposure, without complete
decompression, may result in decompression sickness. See information on
simple asphyxiants.
ACUTE EXPOSURE:
SIMPLE ASPHYXIANTS: The symptoms of asphyxia depend on the rapidity with
which the oxygen deficiency develops and how long it continues. In sudden
acute asphyxia, unconsciousness may be immediate. With slow development
there may be rapid respiration and pulse, air hunger, dizziness, reduced
awareness, tightness in the head, tingling sensations, incoordination,
faulty judgement, emotional instability, and rapid fatigue. As the
asphyxia progresses, nausea, vomiting, collapse, unconsciousness,
convulsions, deep coma and death are possible.
CHRONIC EXPOSURE:
MGI16625
Page 005 of 007
SIMPLE ASPHYXIANTS: No data available.
SKIN CONTACT:
ACUTE EXPOSURE:
NITROGEN: No adverse effect have been reported from the gas.
CHRONIC EXPOSURE:
NITROGEN: No adverse effects have been reported.
EYE CONTACT:
ACUTE EXPOSURE:
NITROGEN: May cause irritation if sprayed directly into the eyes.
CHRONIC EXPOSURE:
NITROGEN: No adverse effects have been reported.
INGESTION:
ACUTE EXPOSURE:
NITROGEN: Ingestion of a gas is unlikely.
CHRONIC EXPOSURE:
NITROGEN: No data available.
-----------------------------------------------------------------------------SECTION 12
ECOLOGICAL INFORMATION
-----------------------------------------------------------------------------Not available
-----------------------------------------------------------------------------SECTION 13
DISPOSAL CONSIDERATIONS
-----------------------------------------------------------------------------Dispose in accordance with all applicable regulations.
-----------------------------------------------------------------------------SECTION 14
TRANSPORT INFORMATION
-----------------------------------------------------------------------------U.S. DOT 49 CFR 172.101 SHIPPING NAME-UN NUMBER:
Nitrogen, compressed-UN1066
U.S. DOT 49 CFR 172.101 HAZARD CLASS OR DIVISION:
2.2
U.S. DOT 49 CFR 172.101 AND SUBPART E LABELING REQUIREMENTS:
Nonflammable gas
U.S. DOT 49 CFR 172.101 PACKAGING AUTHORIZATIONS:
EXCEPTIONS: 49 CFR 173.306
NON-BULK PACKAGING: 49 CFR 173.302
BULK PACKAGING: 49 CFR 173.314, 315
U.S. DOT 49 CFR 172.101 QUANTITY LIMITATIONS:
PASSENGER AIRCRAFT OR RAILCAR: 75 kg
MGI16625
Page 006 of 007
CARGO AIRCRAFT ONLY: 150 kg
LAND TRANSPORT ADR/RID:
SUBSTANCE NAME: Nitrogen, compressed
UN NUMBER: UN1066
ADR/RID CLASS: 2
ITEM NUMBER: 1(a)/1A
WARNING SIGN/LABEL: 2/2; 13
HAZARD ID NUMBER: 20
AIR TRANSPORT IATA/ICAO:
CORRECT TECHNICAL NAME: Nitrogen, compressed
UN/ID NUMBER: UN1066
IATA/ICAO CLASS: 2.2
LABEL: Nonflammable gas
MARITIME TRANSPORT IMDG:
CORRECT TECHNICAL NAME: Nitrogen, compressed
UN/ID NUMBER: UN1066
IMDG CLASS: 2(2.2)
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EmS No.: 2-04
MFAG Table No.: none
MARINE POLLUTANT: N
-----------------------------------------------------------------------------SECTION 15
REGULATORY INFORMATION
-----------------------------------------------------------------------------U.S. REGULATIONS:
TSCA INVENTORY STATUS: Y
TSCA 12(b) EXPORT NOTIFICATION: Not listed.
CERCLA SECTION 103 (40CFR302.4): N
SARA SECTION 302 (40CFR355.30): N
SARA SECTION 304 (40CFR355.40): N
SARA SECTION 313 (40CFR372.65): N
SARA HAZARD CATEGORIES, SARA SECTIONS 311/312 (40CFR370.21):
ACUTE: Y
CHRONIC: N
FIRE: N
REACTIVE: N
SUDDEN RELEASE: Y
OSHA PROCESS SAFETY (29CFR1910.119): N
STATE REGULATIONS:
California Proposition 65: N
EUROPEAN REGULATIONS:
EC NUMBER (EINECS): 231-783-9
GERMAN REGULATIONS:
WATER HAZARD CLASS (WGK): 0 (Official German Classification)
MGI16625
Page 007 of 007
-----------------------------------------------------------------------------SECTION 16
OTHER INFORMATION
-----------------------------------------------------------------------------COPYRIGHT 1984-1999 MDL INFORMATION SYSTEMS, INC. ALL RIGHTS RESERVED.
THIS MSDS IS SUPPLIED PURSUANT TO OSHA REGULATIONS. OTHER GOVERNMENT
REGULATIONS MUST BE REVIEWED FOR APPLICABILITY TO THIS PRODUCT. WE BELIEVE THE
INFORMATION SOURCE IS RELIABLE AND THE INFORMATION IS ACCURATE AS OF THE DATE
HEREOF, HOWEVER, ACCURACY OR COMPLETENESS IS NOT GUARANTEED AND NO WARRANTY OF
ANY TYPE IS GRANTED. THE INFORMATION RELATES ONLY TO THIS SPECIFIC PRODUCT. IF
COMBINED WITH OTHER MATERIALS, ALL COMPONENT PROPERTIES MUST BE CONSIDERED.
Home | Who We Are | Products & Services | Applications | Locations | Around MG | Product Catalog | Search |
Contact Us
Copyright © 1997 by Messer - MG Industries
4 of 4
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MGI04260
Page 001 of 008
-----------------------------------------------------------------------------SECTION 1
CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
-----------------------------------------------------------------------------MG INDUSTRIES
EMERGENCY CONTACT:
3 GREAT VALLEY PARKWAY
CHEMTREC:
MALVERN, PENNSYLVANIA 19355
1-800-424-9300
PHONE: 610-695-7400
FAX: 610-695-7596
SUBSTANCE: CARBON DIOXIDE, GAS
TRADE NAMES/SYNONYMS:
CARBONIC ACID GAS; CARBONIC ANHYDRIDE; CARBON DIOXIDE; CARBON OXIDE; STCC
4904535; UN 1013; CO2; MGI04260; RTECS FF6400000
CHEMICAL FAMILY: oxides of carbon
CREATION DATE: May 04 1990
REVISION DATE: Sep 10 1998
-----------------------------------------------------------------------------SECTION 2
COMPOSITION, INFORMATION ON INGREDIENTS
-----------------------------------------------------------------------------COMPONENT: CARBON DIOXIDE, GAS
CAS NUMBER: 124-38-9
EC NUMBER (EINECS): 204-696-9
PERCENTAGE: 100
-----------------------------------------------------------------------------SECTION 3
HAZARDS IDENTIFICATION
-----------------------------------------------------------------------------NFPA RATINGS (SCALE 0-4): HEALTH=1 FIRE=0 REACTIVITY=0
EC CLASSIFICATION (CALCULATED): No classification assigned.
EMERGENCY OVERVIEW:
PHYSICAL DESCRIPTION: Colorless, odorless gas, with a slight acidic taste.
MAJOR HEALTH HAZARDS: difficulty breathing
PHYSICAL HAZARDS: Containers may rupture or explode if exposed to heat.
POTENTIAL HEALTH EFFECTS:
INHALATION:
SHORT TERM EXPOSURE: ringing in the ears, nausea, irregular heartbeat,
headache, drowsiness, dizziness, tingling sensation, visual disturbances,
suffocation, convulsions, coma
LONG TERM EXPOSURE: no information on significant adverse effects
SKIN CONTACT:
SHORT TERM EXPOSURE: blisters, frostbite
LONG TERM EXPOSURE: no information on significant adverse effects
EYE CONTACT:
SHORT TERM EXPOSURE: irritation, blurred vision
LONG TERM EXPOSURE: no information on significant adverse effects
MGI04260
Page 002 of 008
INGESTION:
SHORT TERM EXPOSURE: frostbite
LONG TERM EXPOSURE: no information is available
CARCINOGEN STATUS:
OSHA: N
NTP: N
IARC: N
-----------------------------------------------------------------------------SECTION 4
FIRST AID MEASURES
-----------------------------------------------------------------------------INHALATION: When safe to enter area, remove from exposure. Use a bag valve
mask or similar device to perform artificial respiration (rescue breathing)
if needed. Keep warm and at rest. Get medical attention immediately.
SKIN CONTACT: Wash if needed. If frostbite, freezing, or cryogenic burns
occur, warm affected area in warm water. If this is not available, gently
wrap affected parts in blankets. Allow circulation to return naturally. Get
medical attention immediately.
EYE CONTACT: It is unlikely that emergency treatment will be required. Wash
with large amounts of water or normal saline until no evidence of chemical
remains (at least 15-20 minutes). Get medical attention immediately.
INGESTION: It is unlikely that emergency treatment will be required. Get
medical attention, if needed.
NOTE TO PHYSICIAN: For inhalation, consider oxygen.
-----------------------------------------------------------------------------SECTION 5
FIRE FIGHTING MEASURES
-----------------------------------------------------------------------------FIRE AND EXPLOSION HAZARDS: Negligible fire hazard.
EXTINGUISHING MEDIA: carbon dioxide, regular dry chemical
Large fires: Use regular foam or flood with fine water spray.
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FIRE FIGHTING: Move container from fire area if it can be done without risk.
Cool containers with water spray until well after the fire is out. Stay away
from the ends of tanks. For tank, rail car or tank truck, evacuation radius:
800 meters (1/2 mile). Use extinguishing agents appropriate for surrounding
fire. Cool containers with water spray until well after the fire is out.
Apply water from a protected location or from a safe distance. Do not get
water directly on material. Reduce vapors with water spray. Avoid inhalation
of material or combustion by-products. Stay upwind and keep out of low
areas. Consider downwind evacuation if material is leaking.
-----------------------------------------------------------------------------SECTION 6
ACCIDENTAL RELEASE MEASURES
-----------------------------------------------------------------------------OCCUPATIONAL RELEASE:
MGI04260
Page 003 of 008
Do not touch spilled material. Stop leak if possible without personal risk.
Keep unnecessary people away, isolate hazard area and deny entry. Ventilate
closed spaces before entering.
-----------------------------------------------------------------------------SECTION 7
HANDLING AND STORAGE
-----------------------------------------------------------------------------Cylinder temperature should not exceed 125 F (52 C).
29 CFR Subpart "H"-Hazardous Materials.
National Fire Protection Association publication #55, "Standard for the
Storage, Use and Handling of Compressed and Liquified Gases in Portable
Cylinders".
Compressed Gas Association publication P-1, "Safe Handling of Compressed Gases
in Containers".
Store and handle in accordance with current regulations and standards:
OSHA 29 CFR 1910.101
-----------------------------------------------------------------------------SECTION 8
EXPOSURE CONTROLS, PERSONAL PROTECTION
-----------------------------------------------------------------------------EXPOSURE LIMITS:
CARBON DIOXIDE, GAS:
CARBON DIOXIDE:
5000 ppm (9000 mg/m3) OSHA TWA
10000 ppm (18000 mg/m3) OSHA TWA (vacated by 58 FR 35338, June 30, 1993)
30000 ppm (54000 mg/m3) OSHA STEL (vacated by 58 FR 35338, June 30, 1993)
5000 ppm (9000 mg/m3) ACGIH TWA
30000 ppm (54000 mg/m3) ACGIH STEL
5000 ppm (9000 mg/m3) NIOSH recommended TWA 10 hour(s)
30000 ppm (54000 mg/m3) NIOSH recommended STEL
9000 mg/m3 (5000 ml/m3) DFG MAK 4 times/shift
9000 mg/m3 (5000 ml/m3) EC MAK 4 times/shift
5000 ppm (9150 mg/m3) UK OES TWA
15000 ppm (27400 mg/m3) UK OES STEL
MEASUREMENT METHOD: Gas collection bag; Gas chromatography with thermal
conductivity detector; NIOSH III # S249
VENTILATION: Based on available information, additional ventilation is not
required. Ensure compliance with applicable exposure limits.
EYE PROTECTION: Eye protection not required, but recommended.
CLOTHING: For the gas: Protective clothing is not required. For the liquid:
Wear appropriate protective, cold insulating clothing.
GLOVES: Protective gloves are not required, but recommended.
RESPIRATOR: The following respirators and maximum use concentrations are drawn
from NIOSH and/or OSHA.
40,000 ppm
Any supplied-air respirator.
Any self-contained breathing apparatus with a full facepiece.
MGI04260
Page 004 of 008
Escape Any appropriate escape-type, self-contained breathing apparatus.
For Unknown Concentrations or Immediately Dangerous to Life or Health Any supplied-air respirator with full facepiece and operated in a
pressure-demand or other positive-pressure mode in combination with a
separate escape supply.
Any self-contained breathing apparatus with a full facepiece.
-----------------------------------------------------------------------------SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
-----------------------------------------------------------------------------PHYSICAL DESCRIPTION: Colorless, odorless gas, with a slight acidic taste.
MOLECULAR WEIGHT: 44.01
MOLECULAR FORMULA: C-O2
BOILING POINT: Not available
FREEZING POINT: -71 F (-57 C) @ 4000 mmHg
SUBLIMATION POINT: -110 F (-79 C)
VAPOR PRESSURE: 43700 mmHg @ 21 C
VAPOR DENSITY (air=1): 1.5
SPECIFIC GRAVITY (water=1): 1.522 @ 21 C
WATER SOLUBILITY: soluble
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PH: acidic in solution
VOLATILITY: Not applicable
ODOR THRESHOLD: Not available
EVAPORATION RATE: Not applicable
COEFFICIENT OF WATER/OIL DISTRIBUTION: Not applicable
SOLVENT SOLUBILITY:
Soluble: alcohol, acetone, hydrocarbons, organic solvents
-----------------------------------------------------------------------------SECTION 10
STABILITY AND REACTIVITY
-----------------------------------------------------------------------------REACTIVITY: Stable at normal temperatures and pressure.
CONDITIONS TO AVOID: Protect from physical damage and heat. Containers may
rupture or explode if exposed to heat. Avoid contact with water or moisture.
INCOMPATIBILITIES: combustible materials, oxidizing materials, metal salts,
reducing agents, metal carbide, metals, bases
CARBON DIOXIDE:
ACRYLALDEHYDE: Exothermic polymerization.
BARIUM PEROXIDE: Incandescent reaction.
CESIUM OXIDE: Ignition.
DIETHYL MAGNESIUM: Ignition.
ETHYLENEIMINE: Explosive polymerization.
HYDRAZINE: Decomposition.
METAL ACETYLIDES: Ignition or incandescence.
METAL HYDRIDES: Reduction reaction.
METALS: Dusts of many metals suspended in carbon dioxide atmospheres are
ignitable and explosive; some bulk metals will burn in the gas at elevated
temperatures.
POTASSIUM: Mixtures of the solids are impact-sensitive.
MGI04260
Page 005 of 008
POTASSIUM-SODIUM ALLOY: Mixtures of the solids are impact-sensitive.
SODIUM: Mixtures of the solids are impact-sensitive.
SODIUM PEROXIDE: Highly exothermic reaction; may be explosive in the
presence of metals.
POLYMERIZATION: Will not polymerize.
-----------------------------------------------------------------------------SECTION 11
TOXICOLOGICAL INFORMATION
-----------------------------------------------------------------------------CARBON DIOXIDE, GAS:
TOXICITY DATA:
9 pph/5 minute(s) inhalation-human LCLo; 90000 ppm/5 minute(s)
inhalation-mammal LCLo; 10000 ppm/24 hour(s)-30 day(s) continuous
inhalation-rat TCLo; 27000 ppm/24 hour(s)-30 day(s) continuous
inhalation-rabbit TCLo
ACUTE TOXICITY LEVEL: Insufficient Data.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: heart or cardiovascular disorders,
respiratory disorders
REPRODUCTIVE EFFECTS DATA:
6 pph inhalation-rat TCLo/24 hour(s) 10 day(s) pregnant female continuous; 6
pph inhalation-rat TCLo/24 hour(s) 10 day(s) pregnant female continuous; 55
pph inhalation-mouse TCLo/2 hour(s) 3 day(s) male; 55 pph inhalation-mouse
TCLo/4 hour(s) 6 day(s) male; 2 pph inhalation-mouse TCLo/8 hour(s) 10
day(s) pregnant female continuous; 13 pph inhalation-rabbit TCLo/4 hour(s)
9-12 day(s) pregnant female continuous
HEALTH EFFECTS:
INHALATION:
ACUTE EXPOSURE:
CARBON DIOXIDE: In the solid or liquid form carbon dioxide is very
volatile, readily releasing the gas. At concentrations from 2-10% it may
cause acidic taste, dyspnea, headache, vertigo, nausea, labored breathing,
weakness, drowsiness, mental confusion, and increase in blood pressure,
pulse, and respiratory rate. Exposure to 10% for a few minutes has been
reported to cause visual disturbances, tinnitus, tremors, profuse
perspiration, restlessness, paresthesias, general feeling of discomfort,
loss of consciousness, and coma. Concentrations of 25-30% may cause coma
and convulsions within one minute. Tachycardia and arrhythmias are
possible. Concentrations of 50% may cause symptoms of hypocalcemia
including carpopedal spasms. Excessive carbon dioxide for a time period of
not more than 5 minutes was reported to cause effects on vision with
constriction of visual fields, enlargement of blind spots, photophobia,
loss of convergence and accommodation, and deficient dark adaptation as
well as headache, insomnia, and personality changes, largely depression
and irritability. Even when there is sufficient oxygen present to prevent
simple asphyxiation by carbon dioxide, high concentrations may cause
adverse effects by interfering with its normal elimination from the body.
Initially, exposure to increased carbon dioxide concentrations results in
a compensatory increase in both rate and depth of ventilation. Beyond a
certain point, however, this may reverse to hypoventilation resulting in
respiratory acidosis. Death from asphyxia may occur if the concentration
and duration of exposure are sufficient. Reproductive effects have been
reported in animals.
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MGI04260
Page 006 of 008
CHRONIC EXPOSURE:
CARBON DIOXIDE: It has been reported that persons may tolerate 1.5% in
inhaled air for prolonged periods without adverse effects, but calcium/
phosphorus metabolism may be affected with serum levels of calcium and
urinary phosphorus progressively falling. At 2% concentration, deepened
respiration may occur. At 3% impairment of performance has been noted. It
has, however, been demonstrated that the development of tolerance may
occur during prolonged exposure to low levels. Reproductive effects have
been reported in animals.
SKIN CONTACT:
ACUTE EXPOSURE:
CARBON DIOXIDE: No adverse effects have been reported from exposure to the
gas. Due to rapid evaporation, the liquid or solid may cause frostbite
with redness, tingling and pain or numbness. In more severe cases, the
skin may become hard and white and develop blisters.
CHRONIC EXPOSURE:
CARBON DIOXIDE: No adverse effects are expected from exposure at low
levels.
EYE CONTACT:
ACUTE EXPOSURE:
CARBON DIOXIDE: At high concentrations in air, carbon dioxide may cause a
stinging sensation of the eyes. 200,000 ppm of the gas may cause
irritation. Due to rapid evaporation, the liquid or solid may cause
frostbite with redness, pain, and blurred vision.
CHRONIC EXPOSURE:
CARBON DIOXIDE: No adverse effects are expected from exposure to low
levels.
INGESTION:
ACUTE EXPOSURE:
CARBON DIOXIDE: Ingestion of a gas is unlikely. If the liquid or solid is
swallowed, frostbite damage to the lips, mouth and mucous membranes may
occur.
CHRONIC EXPOSURE:
CARBON DIOXIDE: No data available.
-----------------------------------------------------------------------------SECTION 12
ECOLOGICAL INFORMATION
-----------------------------------------------------------------------------ECOTOXICITY DATA:
FISH TOXICITY: 150000 ug/L 48 day(s) (Mortality) Brown trout (Salmo trutta)
-----------------------------------------------------------------------------SECTION 13
DISPOSAL CONSIDERATIONS
-----------------------------------------------------------------------------Dispose in accordance with all applicable regulations.
MGI04260
Page 007 of 008
-----------------------------------------------------------------------------SECTION 14
TRANSPORT INFORMATION
-----------------------------------------------------------------------------U.S. DOT 49 CFR 172.101 SHIPPING NAME-UN NUMBER:
Carbon dioxide-UN1013
U.S. DOT 49 CFR 172.101 HAZARD CLASS OR DIVISION:
2.2
U.S. DOT 49 CFR 172.101 AND SUBPART E LABELING REQUIREMENTS:
Nonflammable gas
U.S. DOT 49 CFR 172.101 PACKAGING AUTHORIZATIONS:
EXCEPTIONS: 49 CFR 173.306
NON-BULK PACKAGING: 49 CFR 173.302, 304
BULK PACKAGING: 49 CFR 173.302, 314, 315
U.S. DOT 49 CFR 172.101 QUANTITY LIMITATIONS:
PASSENGER AIRCRAFT OR RAILCAR: 75 kg
CARGO AIRCRAFT ONLY: 150 kg
LAND TRANSPORT ADR/RID:
SUBSTANCE NAME: Carbon dioxide
UN NUMBER: UN1013
ADR/RID CLASS: 2
ITEM NUMBER: 5(a)/2A
WARNING SIGN/LABEL: 2/2; 13
HAZARD ID NUMBER: 20
AIR TRANSPORT IATA/ICAO:
CORRECT TECHNICAL NAME: Carbon dioxide
UN/ID NUMBER: UN1013
IATA/ICAO CLASS: 2.2
LABEL: Nonflammable gas
MARITIME TRANSPORT IMDG:
CORRECT TECHNICAL NAME: Carbon dioxide
UN/ID NUMBER: UN1013
IMDG CLASS: 2(2.2)
EmS No.: 2-09
MFAG Table No.: 615
MARINE POLLUTANT: N
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-----------------------------------------------------------------------------SECTION 15
REGULATORY INFORMATION
-----------------------------------------------------------------------------U.S. REGULATIONS:
TSCA INVENTORY STATUS: Y
TSCA 12(b) EXPORT NOTIFICATION: Not listed.
CERCLA SECTION 103 (40CFR302.4): N
SARA SECTION 302 (40CFR355.30): N
SARA SECTION 304 (40CFR355.40): N
MGI04260
Page 008 of 008
SARA SECTION 313 (40CFR372.65): N
SARA HAZARD CATEGORIES, SARA SECTIONS 311/312 (40CFR370.21):
ACUTE: Y
CHRONIC: N
FIRE: N
REACTIVE: N
SUDDEN RELEASE: Y
OSHA PROCESS SAFETY (29CFR1910.119): N
STATE REGULATIONS:
California Proposition 65: N
EUROPEAN REGULATIONS:
EC NUMBER (EINECS): 204-696-9
GERMAN REGULATIONS:
WATER HAZARD CLASS (WGK): 0 (Official German Classification)
-----------------------------------------------------------------------------SECTION 16
OTHER INFORMATION
-----------------------------------------------------------------------------COPYRIGHT 1984-1999 MDL INFORMATION SYSTEMS, INC. ALL RIGHTS RESERVED.
THIS MSDS IS SUPPLIED PURSUANT TO OSHA REGULATIONS. OTHER GOVERNMENT
REGULATIONS MUST BE REVIEWED FOR APPLICABILITY TO THIS PRODUCT. WE BELIEVE THE
INFORMATION SOURCE IS RELIABLE AND THE INFORMATION IS ACCURATE AS OF THE DATE
HEREOF, HOWEVER, ACCURACY OR COMPLETENESS IS NOT GUARANTEED AND NO WARRANTY OF
ANY TYPE IS GRANTED. THE INFORMATION RELATES ONLY TO THIS SPECIFIC PRODUCT. IF
COMBINED WITH OTHER MATERIALS, ALL COMPONENT PROPERTIES MUST BE CONSIDERED.
Home | Who We Are | Products & Services | Applications | Locations | Around MG | Product Catalog | Search |
Contact Us
Copyright © 1997 by Messer - MG Industries
5 of 5
CI-N-02
7/21/99 12:07
MGI04290
Page 001 of 010
-----------------------------------------------------------------------------SECTION 1
CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
-----------------------------------------------------------------------------MG INDUSTRIES
EMERGENCY CONTACT:
3 GREAT VALLEY PARKWAY
CHEMTREC:
MALVERN, PENNSYLVANIA 19355
1-800-424-9300
PHONE: 610-695-7400
FAX: 610-695-7596
SUBSTANCE: CARBON MONOXIDE
TRADE NAMES/SYNONYMS:
CARBON OXIDE; CARBON OXIDE (CO); STCC 4905709; UN 1016; CO; MGI04290; RTECS
FG3500000
CHEMICAL FAMILY: inorganic, gas
CREATION DATE: May 04 1990
REVISION DATE: Sep 10 1998
-----------------------------------------------------------------------------SECTION 2
COMPOSITION, INFORMATION ON INGREDIENTS
-----------------------------------------------------------------------------COMPONENT: CARBON MONOXIDE
CAS NUMBER: 630-08-0
EC NUMBER (EINECS): 211-128-3
EC INDEX NUMBER: 006-001-00-2
PERCENTAGE: 100.0
-----------------------------------------------------------------------------SECTION 3
HAZARDS IDENTIFICATION
-----------------------------------------------------------------------------NFPA RATINGS (SCALE 0-4): HEALTH=2 FIRE=4 REACTIVITY=0
EC CLASSIFICATION (ASSIGNED):
F+ Extremely Flammable
T Toxic
Reproductive Toxin Category 1
R 12-23-48/23-61
EC Classification may be inconsistent with independently-researched data.
EMERGENCY OVERVIEW:
PHYSICAL DESCRIPTION: Odorless, tasteless, colorless gas.
MAJOR HEALTH HAZARDS: No significant target effects reported.
PHYSICAL HAZARDS: Flammable gas. May cause flash fire.
POTENTIAL HEALTH EFFECTS:
INHALATION:
SHORT TERM EXPOSURE: reproductive effects, blisters, nausea, vomiting, chest
pain, headache, drowsiness, dizziness, fainting, hearing loss, dilated
MGI04290
Page 002 of 010
pupils, blindness, suffocation, lung congestion, blood disorders, kidney
damage, liver enlargement, liver damage, reproductive effects, convulsions,
coma
LONG TERM EXPOSURE: no information on significant adverse effects
SKIN CONTACT:
SHORT TERM EXPOSURE: blisters, frostbite
LONG TERM EXPOSURE: no information is available
EYE CONTACT:
SHORT TERM EXPOSURE: frostbite, blurred vision
LONG TERM EXPOSURE: no information is available
INGESTION:
SHORT TERM EXPOSURE: frostbite
LONG TERM EXPOSURE: no information is available
CARCINOGEN STATUS:
OSHA: N
NTP: N
IARC: N
-----------------------------------------------------------------------------SECTION 4
FIRST AID MEASURES
-----------------------------------------------------------------------------INHALATION: When safe to enter area, remove from exposure. Use a bag valve
mask or similar device to perform artificial respiration (rescue breathing)
if needed. Keep warm and at rest. Get medical attention immediately.
SKIN CONTACT: Wash if needed. If frostbite, freezing, or cryogenic burns
occur, warm affected area in warm water. If this is not available, gently
wrap affected parts in blankets. Allow circulation to return naturally. Get
medical attention immediately.
EYE CONTACT: It is unlikely that emergency treatment will be required. Wash
with large amounts of water or normal saline until no evidence of chemical
remains (at least 15-20 minutes). Get medical attention immediately.
INGESTION: It is unlikely that emergency treatment will be required. Get
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medical attention, if needed.
NOTE TO PHYSICIAN: For inhalation, consider oxygen.
-----------------------------------------------------------------------------SECTION 5
FIRE FIGHTING MEASURES
-----------------------------------------------------------------------------FIRE AND EXPLOSION HAZARDS: Severe explosion hazard. Vapor/air mixtures are
explosive. Containers may rupture or explode if exposed to heat. Vapors or
gases may ignite at distant ignition sources and flash back.
Vapors are only slightly lighter than air and may travel to a source of
ignition and flash back.
EXTINGUISHING MEDIA: Let burn unless leak can be stopped immediately. Large
fires: Use regular foam or flood with fine water spray.
FIRE FIGHTING: Move container from fire area if it can be done without risk.
MGI04290
Page 003 of 010
Cool containers with water spray until well after the fire is out. Stay away
from the ends of tanks. For fires in cargo or storage area: Cool containers
with water from unmanned hose holder or monitor nozzles until well after
fire is out. If this is impossible then take the following precautions: Keep
unnecessary people away, isolate hazard area and deny entry. Let the fire
burn. Withdraw immediately in case of rising sound from venting safety
device or any discoloration of tanks due to fire. For tank, rail car or tank
truck: Evacuation radius: 800 meters (1/2 mile). Stop flow of gas.
LOWER FLAMMABLE LIMIT: 12.5%
UPPER FLAMMABLE LIMIT: 74%
AUTOIGNITION: 1128 F (609 C)
-----------------------------------------------------------------------------SECTION 6
ACCIDENTAL RELEASE MEASURES
-----------------------------------------------------------------------------WATER RELEASE:
Subject to California Safe Drinking Water and Toxic Enforcement Act of 1986
(Proposition 65). Keep out of water supplies and sewers.
OCCUPATIONAL RELEASE:
Avoid heat, flames, sparks and other sources of ignition. Stop leak if
possible without personal risk. Reduce vapors with water spray. Keep
unnecessary people away, isolate hazard area and deny entry. Remove sources of
ignition. Ventilate closed spaces before entering.
-----------------------------------------------------------------------------SECTION 7
HANDLING AND STORAGE
-----------------------------------------------------------------------------Store and handle in accordance with all current regulations and standards.
Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. Keep separated from
incompatible substances.
-----------------------------------------------------------------------------SECTION 8
EXPOSURE CONTROLS, PERSONAL PROTECTION
-----------------------------------------------------------------------------EXPOSURE LIMITS:
CARBON MONOXIDE:
50 ppm (55 mg/m3) OSHA TWA
35 ppm (40 mg/m3) OSHA TWA (vacated by 58 FR 35338, June 30, 1993)
200 ppm (229 mg/m3) OSHA ceiling (vacated by 58 FR 35338, June 30, 1993)
25 ppm (29 mg/m3) ACGIH TWA
35 ppm (40 mg/m3) NIOSH recommended TWA 8 hour(s)
200 ppm (229 mg/m3) NIOSH recommended ceiling
33 mg/m3 (30 ml/m3) DFG MAK 4 times/shift
50 ppm (58 mg/m3) UK OES TWA
300 ppm (349 mg/m3) UK OES STEL
MEASUREMENT METHOD: Gas collection bag; Electrochemical analysis; NIOSH
III # S340
VENTILATION: Provide local exhaust or process enclosure ventilation system.
MGI04290
Page 004 of 010
Ventilation equipment should be explosion-resistant if explosive
concentrations of material are present. Ensure compliance with applicable
exposure limits.
EYE PROTECTION: For the gas: Eye protection not required, but recommended. For
the liquid: Wear splash resistant safety goggles. Contact lenses should not
be worn. Provide an emergency eye wash fountain and quick drench shower in
the immediate work area.
CLOTHING: For the gas: Protective clothing is not required. For the liquid:
Wear appropriate protective, cold insulating clothing.
GLOVES: Wear insulated gloves.
RESPIRATOR: The following respirators and maximum use concentrations are drawn
from NIOSH and/or OSHA.
350 ppm
Any supplied-air respirator.
875 ppm
Any supplied-air respirator.
1200 ppm
Any air-purifying respirator with a full facepiece and a canister providing
protection against this substance.
End of service life indicator required (ESLI).
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Any self-contained breathing apparatus with a full facepiece.
Any supplied-air respirator with a full facepiece.
Escape Any air-purifying respirator with a full facepiece and a canister providing
protection against this substance.
End of service life indicator required (ESLI).
Any appropriate escape-type, self-contained breathing apparatus.
For Unknown Concentrations or Immediately Dangerous to Life or Health Any supplied-air respirator with full facepiece and operated in a
pressure-demand or other positive-pressure mode in combination with a
separate escape supply.
Any self-contained breathing apparatus with a full facepiece.
-----------------------------------------------------------------------------SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
-----------------------------------------------------------------------------PHYSICAL DESCRIPTION: Odorless, tasteless, colorless gas.
MOLECULAR WEIGHT: 28.01
MOLECULAR FORMULA: C-O
BOILING POINT: -314 F (-192 C)
FREEZING POINT: -326 F (-199 C)
VAPOR PRESSURE: 760 mmHg @ -191 C
VAPOR DENSITY (air=1): 0.968
SPECIFIC GRAVITY: Not applicable
DENSITY: 1.250 g/L @ 0 C
WATER SOLUBILITY: 2.3% @ 20 C
PH: Not applicable
VOLATILITY: Not applicable
ODOR THRESHOLD: Not available
EVAPORATION RATE: Not applicable
MGI04290
Page 005 of 010
VISCOSITY: 0.01657 cP @ 0 C
COEFFICIENT OF WATER/OIL DISTRIBUTION: Not applicable
SOLVENT SOLUBILITY:
Soluble: alcohol, benzene, acetic acid, ethyl acetate, chloroform, cuprous
chloride solutions
-----------------------------------------------------------------------------SECTION 10
STABILITY AND REACTIVITY
-----------------------------------------------------------------------------REACTIVITY: Stable at normal temperatures and pressure.
CONDITIONS TO AVOID: Avoid heat, flames, sparks and other sources of ignition.
Minimize contact with material. Avoid inhalation of material or combustion
by-products. Keep out of water supplies and sewers.
INCOMPATIBILITIES: oxidizing materials, halogens, metal oxides, metals,
combustible materials
CARBON MONOXIDE:
BARIUM PEROXIDE: Violent reaction.
BROMINE PENTAFLUORIDE: Violent reaction and possible ignition.
BROMINE TRIFLUORIDE: Explosion hazard.
CESIUM MONOXIDE: Ignites in the presence of moisture or when heated.
CHLORINE: Violent reaction.
CHLORINE DIOXIDE: Explodes.
CHLORINE TRIFLUORIDE: Explosive reaction.
COPPER (POWDER) + WATER: Explosive complex.
COPPER(II)PERCHLORATE + WATER: Explosive complex.
DINITROGEN OXIDE: Fire and explosion hazard.
FLUORINE + OXYGEN: May explode above 30 C.
IODINE HEPTAFLUORIDE: Ignition.
IRON(III) OXIDE: Possible explosion hazard.
LITHIUM: Forms compound which detonates violently on contact with water.
NITROGEN TRIFLUORIDE: Explosive reaction upon ignition.
OXIDIZERS (STRONG): Fire and explosion hazard.
OXYGEN (LIQUID): Forms explosive mixture.
OXYGEN DIFLUORIDE: Explodes when sparked.
PEROXODISULFURYL DIFLUORIDE: Explosive reaction above 20 C.
POTASSIUM: Forms explosive compound.
SILVER(I) OXIDE: Extremely exothermic reaction.
SODIUM: Forms explosive, shock-sensitive compound.
HAZARDOUS DECOMPOSITION:
Thermal decomposition products: oxides of carbon
POLYMERIZATION: Will not polymerize.
-----------------------------------------------------------------------------SECTION 11
TOXICOLOGICAL INFORMATION
-----------------------------------------------------------------------------CARBON MONOXIDE:
TOXICITY DATA:
600 mg/m3/10 minute(s) inhalation-human TCLo; 4000 ppm/30 minute(s)
MGI04290
Page 006 of 010
inhalation-man LCLo; 650 ppm/45 minute(s) inhalation-man TCLo; 5000 ppm/5
minute(s) inhalation-human LCLo; 1807 ppm/4 hour(s) inhalation-rat LC50;
2444 ppm/4 hour(s) inhalation-mouse LC50; 4000 ppm/46 minute(s)
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inhalation-dog LCLo; 4000 ppm inhalation-rabbit LCLo; 5718 ppm/4 hour(s)
inhalation-guinea pig LC50; 5000 ppm/5 minute(s) inhalation-mammal LCLo;
1334 ppm inhalation-wild bird LC50; 1800 ppm/1 hour(s)-14 day(s)
intermittent inhalation-rat TCLo; 30 mg/m3/8 hour(s)-10 week(s) intermittent
inhalation-rat TCLo; 96 ppm/24 hour(s)-90 day(s) continuous inhalation-rat
TCLo; 250 ppm/5 hour(s)-20 day(s) intermittent inhalation-rat TCLo; 5983
mg/kg/18 week(s) intermittent subcutaneous-rat TDLo; 200 ppm/24 hour(s)-90
day(s) continuous inhalation-monkey TCLo; 200 mg/m3/3 hour(s)-13 week(s)
intermittent inhalation-rabbit TCLo; 50 ppm/24 hour(s)-8 week(s) continuous
inhalation-rabbit TCLo; 200 mg/m3/5 hour(s)-4 week(s) intermittent
inhalation-guinea pig TCLo; 200 ppm/24 hour(s)-90 day(s) continuous
inhalation-guinea pig TCLo
ACUTE TOXICITY LEVEL:
Moderately Toxic: inhalation
TARGET ORGANS: blood
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: blood system disorders, heart or
cardiovascular disorders, hormonal disorders, respiratory disorders
MUTAGENIC DATA:
micronucleus test - mouse inhalation 1500 ppm 10 minute(s); sister chromatid
exchange - mouse inhalation 2500 ppm 10 minute(s)
REPRODUCTIVE EFFECTS DATA:
150 ppm inhalation-rat TCLo/24 hour(s) 1-22 day(s) pregnant female
continuous; 150 ppm inhalation-rat TCLo/24 hour(s) 1-22 day(s) pregnant
female continuous; 1 mg/m3 inhalation-rat TCLo/24 hour(s) 72 day(s) pre
pregnancy continuous; 150 ppm inhalation-rat TCLo/24 hour(s) 0-20 day(s)
pregnant female continuous; 75 ppm inhalation-rat TCLo/24 hour(s) 0-20
day(s) pregnant female continuous; 65 ppm inhalation-mouse TCLo/24 hour(s)
7-18 day(s) pregnant female continuous; 250 ppm inhalation-mouse TCLo/7
hour(s) 6-15 day(s) pregnant female continuous; 125 ppm inhalation-mouse
TCLo/24 hour(s) 7-18 day(s) pregnant female continuous; 8 pph
inhalation-mouse TCLo/1 hour(s) 8 day(s) pregnant female continuous; 8 pph
inhalation-mouse TCLo/1 hour(s) 8 day(s) pregnant female continuous; 180 ppm
inhalation-rabbit TCLo/24 hour(s) 1-30 day(s) pregnant female continuous
ADDITIONAL DATA: Alcohol may enhance the toxic effects.
HEALTH EFFECTS:
INHALATION:
ACUTE EXPOSURE:
CARBON MONOXIDE: Carbon monoxide is not detectable by odor and headache
should be taken as a warning that a dangerous concentration is being
inhaled. In sudden exposures to high concentrations, weakness and
dizziness may be the only symptoms preceding collapse. The amount of
carboxyhemoglobin formed in the blood is dependent on concentration and
duration of exposure, ambient temperature, physical exertion, health, and
individual metabolism. Symptoms are usually not noticeable until the
carboxyhemoglobin level reaches 10%. At 10-40%, symptoms may include
increasingly severe headache, dyspnea on exertion, decreased manual
dexterity, impaired judgement and memory, irritability, emotional
instability, dizziness, fatigue, drowsiness, confusion, nausea, vomiting,
palpitations, and impaired vision and hearing. With continuing exposure,
there is a progressive worsening of all symptoms. At 40-60%, anginal pain,
incoordination, hallucinations, lethargy, syncope and collapse, and
MGI04290
Page 007 of 010
increased respiration and pulse may occur. At 60-80% there may be
decreased respiration, blood pressure and pulse, and deepening coma with
intermittent convulsions and incontinence of urine and feces. Rarely,
there may be a pink or red skin discoloration, but cyanosis or pallor is
more common. Other reported signs and symptoms include increased
temperature, dilated pupils, perspiration, muscle spasms, hyperreflexia,
aching limbs, and retinal hemorrhage or venous engorgement. Above 70-80%,
rapid death from respiratory or cardiac arrest usually occurs. Death may
also be caused by myocardial or cerebral infarction. Cerebral edema may
also occur. In non-fatal cases or when death is not immediate, primary or
secondary effects of tissue hypoxia and some atypical reactions may
develop. There may be myocarditis, pulmonary edema, bronchopneumonia,
pancreatitis, hepatomegaly, liver and kidney damage, albuminuria,
glycosuria, and oliguria. Hemolytic anemia, thrombocytopenic purpura,
polycythemia and leukocytosis have been reported. Rhabdomyolysis with
myoglobinuria and acute renal failure are possible, especially with
pressure injury. Erythema, edema and blisters may develop, especially over
pressure areas. Eye effects may include retrobulbar neuritis with
neuroretinal edema and partial or complete, temporary or permanent
blindness. Temporary or permanent hearing loss may also occur. Complete
recovery is the usual course. However, signs and symptoms of nerve or
brain injury with neuropathies and various motor and mental defects, some
of which resemble multiple sclerosis or parkinsonism, may develop several
days to weeks after apparent recovery, especially from prolonged hypoxic
coma. The onset may be sudden with numerous possible effects, including
dementia, deterioration of neurological status and sometimes slowly
resolving or permanent disability or death. A study of 63 patients 3 years
after carbon monoxide poisoning indicated that 13% showed gross
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neuropsychiatric damage; 33% showed deterioration of personality; and 43%
reported memory impairment. Carbon monoxide readily crosses the placental
barrier. Acute non-lethal intoxication may result in miscarriage or
permanent neurologic sequelae such, as cerebral palsy, in the newborn.
CHRONIC EXPOSURE:
CARBON MONOXIDE: Although carbon monoxide is not a cumulative poison,
chronic exposure to low to moderate levels may result in repeated bouts of
oxygen deprivation and resultant effects including cardiovascular or
central nervous system damage. Reported signs and symptoms include
polycythemia, lassitude, malaise, anorexia, nausea, vomiting, headache,
dizziness, ataxia, syncope, glycosuria, weakness of the limbs, joint and
neuromuscular pain, muscle spasm, loss of sensation in the fingers,
positive Romberg's sign, auditory and visual disturbances and impaired
vigilance. Irritability, personality changes, impaired memory and
difficulty concentrating are also possible. The development of
atherosclerosis may be facilitated. The development of congestive heart
failure may be indicated by dyspnea, anginal pain and cardiac
irregularities. Relatively long and severe exposure may cause cerebral
congestion and edema resulting in long-lasting mental or nervous damage.
During pregnancy, prolonged exposure to low levels, as in smoking, has
been associated with smaller babies and increased neonatal mortalities.
Rats exposed prenatally to low levels had offspring that exhibited signs
of functional deficit in the central nervous system; minor skeletal
anomalies were noted in mice. Other reproductive effects have been
reported in animals.
MGI04290
Page 008 of 010
SKIN CONTACT:
ACUTE EXPOSURE:
CARBON MONOXIDE: No adverse effects have been reported from the gas. Due
to rapid evaporation, the liquid may cause frostbite with redness,
tingling and pain or numbness. In more severe cases, the skin may become
hard and white and blisters may develop.
CHRONIC EXPOSURE:
CARBON MONOXIDE: No data available.
EYE CONTACT:
ACUTE EXPOSURE:
CARBON MONOXIDE: No adverse effects have been reported from the gas. Due
to rapid evaporation, the liquid may cause frostbite with redness, pain
and blurred vision.
CHRONIC EXPOSURE:
CARBON MONOXIDE: No data available.
INGESTION:
ACUTE EXPOSURE:
CARBON MONOXIDE: Ingestion of a gas is unlikely. If liquid is swallowed,
frostbite damage to the lips, mouth and mucous membranes may occur.
CHRONIC EXPOSURE:
CARBON MONOXIDE: No data available.
-----------------------------------------------------------------------------SECTION 12
ECOLOGICAL INFORMATION
-----------------------------------------------------------------------------ECOTOXICITY DATA:
FISH TOXICITY: 75000 ug/L 1 day(s) LC100 (Mortality) Orangespotted sunfish
(Lepomis humilis)
-----------------------------------------------------------------------------SECTION 13
DISPOSAL CONSIDERATIONS
-----------------------------------------------------------------------------Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste
Number(s): D001. Dispose in accordance with all applicable regulations.
-----------------------------------------------------------------------------SECTION 14
TRANSPORT INFORMATION
-----------------------------------------------------------------------------U.S. DOT 49 CFR 172.101 SHIPPING NAME-UN NUMBER:
Carbon monoxide, compressed.-UN1016
U.S. DOT 49 CFR 172.101 HAZARD CLASS OR DIVISION:
2.3
U.S. DOT 49 CFR 172.101 AND SUBPART E LABELING REQUIREMENTS:
Poison gas; Flammable gas
MGI04290
Page 009 of 010
U.S. DOT 49 CFR 172.101 PACKAGING AUTHORIZATIONS:
EXCEPTIONS: None
NON-BULK PACKAGING: 49 CFR 173.302
BULK PACKAGING: 49 CFR 173.314, 315
U.S. DOT 49 CFR 172.101 QUANTITY LIMITATIONS:
PASSENGER AIRCRAFT OR RAILCAR: Forbidden
CARGO AIRCRAFT ONLY: 25 kg
LAND TRANSPORT ADR/RID:
SUBSTANCE NAME: Carbon monoxide/Carbon monoxide, compressed
UN NUMBER: UN1016
ADR/RID CLASS: 2
ITEM NUMBER: 1(bt)/1TF
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WARNING SIGN/LABEL: 6.1; 3/6.1; 3; 13
HAZARD ID NUMBER: 236/263
AIR TRANSPORT IATA/ICAO:
CORRECT TECHNICAL NAME: Carbon monoxide
UN/ID NUMBER: UN1016
IATA/ICAO CLASS: 2.3
LABEL: Toxic gas; Flammable gas
MARITIME TRANSPORT IMDG:
CORRECT TECHNICAL NAME: Carbon monoxide
UN/ID NUMBER: UN1016
IMDG CLASS: 2(2.3)
SUBSIDIARY RISK LABEL: Flammable gas
EmS No.: 2-01
MFAG Table No.: 616
MARINE POLLUTANT: N
-----------------------------------------------------------------------------SECTION 15
REGULATORY INFORMATION
-----------------------------------------------------------------------------U.S. REGULATIONS:
TSCA INVENTORY STATUS: Y
TSCA 12(b) EXPORT NOTIFICATION: Not listed.
CERCLA SECTION 103 (40CFR302.4): N
SARA SECTION 302 (40CFR355.30): N
SARA SECTION 304 (40CFR355.40): N
SARA SECTION 313 (40CFR372.65): N
SARA HAZARD CATEGORIES, SARA SECTIONS 311/312 (40CFR370.21):
ACUTE: Y
CHRONIC: N
FIRE: Y
REACTIVE: N
SUDDEN RELEASE: Y
OSHA PROCESS SAFETY (29CFR1910.119): N
STATE REGULATIONS:
California Proposition 65: Y
Known to the state of California to cause the following:
Carbon monoxide
MGI04290
Page 010 of 010
Developmental toxicity (Jul 01, 1989)
EUROPEAN REGULATIONS:
EC NUMBER (EINECS): 211-128-3
EC RISK AND SAFETY PHRASES:
R 12
Extremely flammable.
R 23
Toxic by inhalation.
R 48/23
Toxic: danger of serious damage to health by prolonged
exposure through inhalation.
R 61
May cause harm to unborn child.
S 45
In case of accident or if you feel unwell, seek medical
advice immediately (show the label where possible).
S 53
Avoid exposure - obtain special instructions before use.
GERMAN REGULATIONS:
WATER HAZARD CLASS (WGK): 0 (Official German Classification)
-----------------------------------------------------------------------------SECTION 16
OTHER INFORMATION
-----------------------------------------------------------------------------COPYRIGHT 1984-1999 MDL INFORMATION SYSTEMS, INC. ALL RIGHTS RESERVED.
THIS MSDS IS SUPPLIED PURSUANT TO OSHA REGULATIONS. OTHER GOVERNMENT
REGULATIONS MUST BE REVIEWED FOR APPLICABILITY TO THIS PRODUCT. WE BELIEVE THE
INFORMATION SOURCE IS RELIABLE AND THE INFORMATION IS ACCURATE AS OF THE DATE
HEREOF, HOWEVER, ACCURACY OR COMPLETENESS IS NOT GUARANTEED AND NO WARRANTY OF
ANY TYPE IS GRANTED. THE INFORMATION RELATES ONLY TO THIS SPECIFIC PRODUCT. IF
COMBINED WITH OTHER MATERIALS, ALL COMPONENT PROPERTIES MUST BE CONSIDERED.
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Contact Us
Copyright © 1997 by Messer - MG Industries
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MGI12831
Page 001 of 009
-----------------------------------------------------------------------------SECTION 1
CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
-----------------------------------------------------------------------------MG INDUSTRIES
EMERGENCY CONTACT:
3 GREAT VALLEY PARKWAY
CHEMTREC:
MALVERN, PENNSYLVANIA 19355
1-800-424-9300
PHONE: 610-695-7400
FAX: 610-695-7596
SUBSTANCE: OXYGEN, COMPRESSED GAS
TRADE NAMES/SYNONYMS:
OXYGEN; DIOXYGEN; MOLECULAR OXYGEN; OXYGEN MOLECULE; PURE OXYGEN; STCC
4904350; UN 1072; O2; MGI12831; RTECS RS2060000
CHEMICAL FAMILY: inorganic, gas
CREATION DATE: May 07 1990
REVISION DATE: Sep 10 1998
-----------------------------------------------------------------------------SECTION 2
COMPOSITION, INFORMATION ON INGREDIENTS
-----------------------------------------------------------------------------COMPONENT: OXYGEN, COMPRESSED GAS
CAS NUMBER: 7782-44-7
EC NUMBER (EINECS): 231-956-9
EC INDEX NUMBER: 008-001-00-8
PERCENTAGE: 100.0
-----------------------------------------------------------------------------SECTION 3
HAZARDS IDENTIFICATION
-----------------------------------------------------------------------------NFPA RATINGS (SCALE 0-4): HEALTH=1 FIRE=0 REACTIVITY=0
EC CLASSIFICATION (ASSIGNED):
O Oxidizing
R 8
EC Classification may be inconsistent with independently-researched data.
EMERGENCY OVERVIEW:
PHYSICAL DESCRIPTION: Odorless, colorless, tasteless, gas.
MAJOR HEALTH HAZARDS: No significant target effects reported.
PHYSICAL HAZARDS: Containers may rupture or explode if exposed to heat. May
ignite combustibles.
POTENTIAL HEALTH EFFECTS:
INHALATION:
SHORT TERM EXPOSURE: irritation, nausea, asthma, irregular heartbeat,
dizziness, tingling sensation, dilated pupils, blindness, lung congestion,
blood disorders, convulsions
MGI12831
Page 002 of 009
LONG TERM EXPOSURE: chest pain, lung damage
SKIN CONTACT:
SHORT TERM EXPOSURE: blisters, frostbite
LONG TERM EXPOSURE: no information on significant adverse effects
EYE CONTACT:
SHORT TERM EXPOSURE: irritation, blurred vision
LONG TERM EXPOSURE: no information on significant adverse effects
INGESTION:
SHORT TERM EXPOSURE: frostbite
LONG TERM EXPOSURE: no information is available
CARCINOGEN STATUS:
OSHA: N
NTP: N
IARC: N
-----------------------------------------------------------------------------SECTION 4
FIRST AID MEASURES
-----------------------------------------------------------------------------INHALATION: Remove from exposure immediately. Use a bag valve mask or similar
device to perform artificial respiration (rescue breathing) if needed. Get
medical attention.
SKIN CONTACT: Wash if needed. If frostbite, freezing, or cryogenic burns
occur, warm affected area in warm water. If this is not available, gently
wrap affected parts in blankets. Allow circulation to return naturally. Get
medical attention immediately.
EYE CONTACT: Wash eyes immediately with large amounts of water, occasionally
lifting upper and lower lids, until no evidence of chemical remains. Get
medical attention immediately.
INGESTION: It is unlikely that emergency treatment will be required. Get
medical attention, if needed.
-----------------------------------------------------------------------------SECTION 5
FIRE FIGHTING MEASURES
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-----------------------------------------------------------------------------FIRE AND EXPLOSION HAZARDS: Negligible fire hazard. Oxidizer. May ignite or
explode on contact with combustible materials. Containers may rupture or
explode if exposed to heat.
EXTINGUISHING MEDIA: carbon dioxide, regular dry chemical
Large fires: Use regular foam or flood with fine water spray.
FIRE FIGHTING: Move container from fire area if it can be done without risk.
Cool containers with water spray until well after the fire is out. Stay away
from the ends of tanks. For fires in cargo or storage area: Cool containers
with water from unmanned hose holder or monitor nozzles until well after
fire is out. If this is impossible then take the following precautions: Keep
unnecessary people away, isolate hazard area and deny entry. Let the fire
burn. Use extinguishing agents appropriate for surrounding fire. Cool
containers with water. Apply water from a protected location or from a safe
MGI12831
Page 003 of 009
distance.
-----------------------------------------------------------------------------SECTION 6
ACCIDENTAL RELEASE MEASURES
-----------------------------------------------------------------------------OCCUPATIONAL RELEASE:
Stop leak if possible without personal risk. Avoid contact with combustible
materials. Keep unnecessary people away, isolate hazard area and deny entry.
Ventilate closed spaces before entering.
-----------------------------------------------------------------------------SECTION 7
HANDLING AND STORAGE
-----------------------------------------------------------------------------Store and handle in accordance with all current regulations and standards.
Subject to storage regulations: U.S. OSHA 29 CFR 1910.104.
-----------------------------------------------------------------------------SECTION 8
EXPOSURE CONTROLS, PERSONAL PROTECTION
-----------------------------------------------------------------------------EXPOSURE LIMITS:
OXYGEN, COMPRESSED GAS:
No occupational exposure limits established.
VENTILATION: Provide local exhaust ventilation system. Ensure compliance with
applicable exposure limits.
EYE PROTECTION: For the gas: Eye protection not required, but recommended. For
the liquid: Wear splash resistant safety goggles. Contact lenses should not
be worn. Provide an emergency eye wash fountain and quick drench shower in
the immediate work area.
CLOTHING: For the gas: Protective clothing is not required. For the liquid:
Wear appropriate protective, cold insulating clothing.
GLOVES: Wear insulated gloves.
RESPIRATOR: Under conditions of frequent use or heavy exposure, respiratory
protection may be needed. Respiratory protection is ranked in order from
minimum to maximum. Consider warning properties before use.
Any chemical cartridge respirator with organic vapor cartridge(s).
Any chemical cartridge respirator with a full facepiece and organic vapor
cartridge(s).
Any air-purifying respirator with a full facepiece and an organic vapor
canister.
For Unknown Concentrations or Immediately Dangerous to Life or Health Any supplied-air respirator with full facepiece and operated in a
pressure-demand or other positive-pressure mode in combination with a
separate escape supply.
Any self-contained breathing apparatus with a full facepiece.
MGI12831
Page 004 of 009
-----------------------------------------------------------------------------SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
-----------------------------------------------------------------------------PHYSICAL DESCRIPTION: Odorless, colorless, tasteless, gas.
MOLECULAR WEIGHT: 31.9988
MOLECULAR FORMULA: O2
BOILING POINT: -297 F (-183 C)
FREEZING POINT: -360 F (-218 C)
VAPOR PRESSURE: 760 mmHg @ -183 C
VAPOR DENSITY (air=1): 1.1
SPECIFIC GRAVITY: Not applicable
DENSITY: 1.309 g/L @ 25 C
WATER SOLUBILITY: 3.2% @ 25 C
PH: Not applicable
VOLATILITY: Not applicable
ODOR THRESHOLD: Not available
EVAPORATION RATE: Not applicable
VISCOSITY: 0.02075 cP @ 25 C
COEFFICIENT OF WATER/OIL DISTRIBUTION: Not applicable
SOLVENT SOLUBILITY:
Soluble: alcohol
-----------------------------------------------------------------------------SECTION 10
STABILITY AND REACTIVITY
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-----------------------------------------------------------------------------REACTIVITY: Stable at normal temperatures and pressure.
CONDITIONS TO AVOID: Avoid contact with combustible materials. Protect from
physical damage and heat. Containers may rupture or explode if exposed to
heat.
INCOMPATIBILITIES: combustible materials, halo carbons, metals, bases,
reducing agents, amines, metal salts, oxidizing materials
OXYGEN:
ACETALDEHYDE: Rapid oxidation progressing to explosion.
ACETYLENE: Mixtures of the gases may explode on heating or compression; the
liquids form a powerful explosive.
POLY(ACRYLONITRILE-BUTADIENE): Forms impact-sensitive mixture with the
liquid.
SEC-ALCOHOLS: Forms explosive peroxides.
ALKALI METALS: Ignition.
ALKALINE-EARTH METALS: Ignition.
ALKALINE-EARTH PHOSPHIDES: Incandescence on heating.
ALLYLIC COMPOUNDS: May form explosive peroxides.
ALUMINUM BOROHYDRIDE: Explosive reaction.
AMMONIA: Possible explosion.
BERYLLIUM BOROHYDRIDE: Explosive reaction.
BORON ARSENOTRIBROMIDE: Ignites on contact with the gas.
BORON TRICHLORIDE: Vigorous reaction on sparking.
BUTEN-3-YNE: Forms explosive peroxides.
CARBON: May ignite in the gas; forms explosive mixtures with the liquid.
CARBON DISULFIDE: Possible ignition.
MGI12831
Page 005 of 009
CARBON MONOXIDE (LIQUID): Forms explosive mixture with the liquid.
CHLOROTRIFLUOROETHYLENE: Forms explosive peroxides.
COMBUSTIBLE MATERIALS: The flammability of combustible compounds greatly
increases with an increase in oxygen concentration; some materials may
become spontaneously combustible or explosive. Contact of combustible
compounds with liquid oxygen is likely to result in a dangerous explosion.
CYANOGEN (LIQUID): Forms explosive mixture with the liquid.
CYCLOHEXANE-1,2-DIONE BIS(PHENYLHYDRAZONE): Forms explosive compound.
CYCLOOCTATETRAENE: May form explosive peroxides.
DIBORANE: Explosive mixture on heating.
DIBORON TETRAFLUORIDE: Explosive mixture.
DIMETHYLKETENE: Forms explosive peroxide.
DIMETHYL SULFIDE: Explosive reaction above 210 C.
DIOXANE: May form explosive peroxides.
ETHERS: May form explosive peroxides.
FLAMMABLE MATERIALS: The flammability of materials greatly increases as the
oxygen concentration increases; some compounds may become spontaneously
combustible or explosive. Contact with liquid oxygen is likely to result
in
dangerous explosions.
FLUORINE + HYDROGEN: Explosive mixture.
HALOGENATED HYDROCARBONS: Many halogenated hydrocarbons ignite or explode
with
the gas under pressure; contact with the liquid may result in a dangerous
explosion.
HYDRAZINE: Forms explosive mixtures.
HYDROCARBONS: Mixtures with the gas may ignite or explode particularly under
pressure or when heated; contact with the liquid is likely to result in a
dangerous explosion.
HYDROGEN: Explosive mixture, particularly in the presence of a catalyst.
HYDROGEN SULFIDE: Explosive mixture.
LITHIATED DIALKYLNITROSAMINES: May form explosive compounds.
LITHIUM HYDRIDE (POWDER): Very powerful explosive with the liquid.
METALS: Many metals ignite or explode in the gas, particularly if heated or
in
powder form. Contact of metal powders with the liquid is likely to result
in a dangerous explosion.
METAL HALIDES: Ignition.
METAL HYDRIDES: Ignition or explosion.
METHANE (LIQUID): Forms explosive mixture with the liquid.
METHOXYCYCLOOCTATETRAENE: Forms explosive compound.
NICKEL CARBONYL: Ignites or explodes at low pressure.
NITROGEN (LIQUID): Explosive if subjected to radiation.
NON-METAL HYDRIDES: May ignite or explode.
OXYGEN DIFLUORIDE: Explosive mixture.
PHENYLDICHLOROAMINE: Explosive reaction.
PHOSPHINE: Forms explosive mixture.
PHOSPHOROUS: Vigorous reaction.
PHOSPHORUS TRIBROMIDE: Explosive reaction.
PHOSPHOROUS TRIFLUORIDE: Explosive reaction.
PHOSPHOROUS TRIOXIDE: Ignition.
POLY(CYANOETHYLSILOXANE): Forms impact sensitive mixture with the liquid.
POLY(DIMETHYLSILOXANE): Forms impact sensitive mixture with the liquid.
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POLYSTYRENE: Forms impact-sensitive mixture with the liquid.
POLYMERS: Contact with the liquid may result in rapid, hazardous oxidation
MGI12831
Page 006 of 009
with possible explosions.
POTASSIUM CARBONYL: Violent reaction.
POTASSIUM PEROXIDE: Violent reaction.
PROPYLENE OXIDE: Explosive mixture.
SILANE + CHLORINE: Explosive mixture.
SILANES: Ignition or explosion.
STYRENE: Forms explosive peroxide.
TEFLON (POLYTETRAFLUOROETHYLENE): Ignites at high temperature and reduced
pressure.
TETRABORON DECAHYDRIDE: Explosive mixture.
TETRAFLUOROETHYLENE: Forms explosive peroxides.
TETRAFLUOROHYDRAZINE: Explosion in the presence of organic matter.
TETRAHYDROFURAN: Forms explosive peroxides.
TETRAPHOSPHORUS HEXAOXIDE: Ignition.
TRIRHENIUM CHLORIDE: May form explosive chlorine oxides on heating.
VINYL COMPOUNDS: May form explosive peroxides.
POLYMERIZATION: Will not polymerize.
-----------------------------------------------------------------------------SECTION 11
TOXICOLOGICAL INFORMATION
-----------------------------------------------------------------------------OXYGEN, COMPRESSED GAS:
TOXICITY DATA:
100 pph/14 hour(s) inhalation-human TCLo
MUTAGENIC DATA:
cytogenetic analysis - human lymphocyte 40 pph 4 day(s); cytogenetic
analysis - hamster ovary 20 pph 3 day(s)-continuous; cytogenetic analysis hamster lung 80 pph; sister chromatid exchange - hamster ovary 20 pph;
mutation in mammalian somatic cells - hamster lung 95 pph 24 hour(s);
cytogenetic analysis - chicken embryo 80 pph
REPRODUCTIVE EFFECTS DATA:
12 pph inhalation-woman TCLo/10 minute(s) 26-39 week(s) pregnant female
continuous; 10 pph inhalation-rat TCLo/12 hour(s) 22 day(s) pregnant female
continuous; 10 pph inhalation-rat TCLo/9 hour(s) 22 day(s) pregnant female
continuous; 10 pph inhalation-mouse TCLo/24 hour(s) 8 day(s) pregnant female
continuous
ADDITIONAL DATA: Toxic action is greatly enhanced by exercise or by presence
of moderate amounts of carbon dioxide.
HEALTH EFFECTS:
INHALATION:
ACUTE EXPOSURE:
OXYGEN: Pure oxygen, especially if not properly humidified, may cause
mucous membrane irritation and pulmonary edema after 24 hours. Air
normally contains 20-21% oxygen. As exposure to higher concentrations
and/or greater than atmospheric pressure continues symptoms of toxicity
may develop and increase in severity. Respiratory system effects may
include a progressive decrease in vital capacity, tightness in the chest
and discomfort, coughing, congestion, tracheobronchitis, pneumonia, edema,
atelectasis and increased depth of respiration, rapid panting or
asthma-like attacks, apnea in inspiratory position, fibroblastic
proliferation, and hyperplasia of alveolar cells. Cardiovascular system
effects may include bradycardia, hyperthermia or hypothermia and
MGI12831
Page 007 of 009
peripheral vasoconstriction. The nervous system may be affected with mood
changes, nausea, dizziness, slowing of mental processess, malaise,
hilarity, apprehension, paresthesias including tingling of fingers and
toes, fasciculation of the lips and face, muscular twitching, visual and
auditory hallucinations, general convulsions and epileptic seizures, loss
of consciousness and collapse. At increased atmospheric pressures, vision
may be affected. Symptoms may include photophobia, amblyopia, mydriasis,
bilateral progressive constriction of visual field, impaired central
vision, constriction of retinal vasculature, and possible loss of vision.
However, no change in the visual fields or visual acuity was found after
breathing pure oxygen for four and one-half hours at normal atmospheric
pressures. Animal studies indicate exposure to oxygen under high pressure
has caused hemolytic anemia. In pregnant women exposed to 100% oxygen for
20 minutes, the response was a fetal cardiac rate which decreased and
became variable.
CHRONIC EXPOSURE:
OXYGEN: Inhalation of pure oxygen for periods up to 16 hours per day for
many days at atmospheric pressure has caused no observed injury to man.
Administration at atmospheric pressures at concentrations of 60% and 80%
may be followed by adverse effects, including severe cough, acute chest
pain associated with a decrease in vital capacity, intra-alveolar edema
and atelectasis. It is possible that prolonged low-level injury may
produce severe fibrotic changes in the lungs. However, after a human was
exposed to high concentrations of oxygen for 150 days, severe irreversible
retinal atrophy occurred. Dogs exposed to pure oxygen for 48 hours were
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found to develop retinal and choroidal detachments. Reproductive effects
have been reported in animal studies.
SKIN CONTACT:
ACUTE EXPOSURE:
OXYGEN: No adverse effects have been reported from the gas. Due to rapid
evaporation, the liquid may cause frostbite with redness, tingling and
pain or numbness. In more severe cases, the skin may become hard and white
and develop blisters.
CHRONIC EXPOSURE:
OXYGEN: No adverse effects have been reported.
EYE CONTACT:
ACUTE EXPOSURE:
OXYGEN: May cause irritation if not properly humidified. Due to rapid
evaporation, the liquid may cause frostbite with redness, pain and blurred
vision.
CHRONIC EXPOSURE:
OXYGEN: No adverse effects have been reported.
INGESTION:
ACUTE EXPOSURE:
OXYGEN: Ingestion of a gas is unlikly. If the liquid is swallowed,
frostbite damage of the lips, mouth and mucous membranes may occur.
CHRONIC EXPOSURE:
OXYGEN: No data available.
MGI12831
Page 008 of 009
-----------------------------------------------------------------------------SECTION 12
ECOLOGICAL INFORMATION
-----------------------------------------------------------------------------Not available
-----------------------------------------------------------------------------SECTION 13
DISPOSAL CONSIDERATIONS
-----------------------------------------------------------------------------Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste
Number(s): D001. Dispose in accordance with all applicable regulations.
-----------------------------------------------------------------------------SECTION 14
TRANSPORT INFORMATION
-----------------------------------------------------------------------------U.S. DOT 49 CFR 172.101 SHIPPING NAME-UN NUMBER:
Oxygen, compressed-UN1072
U.S. DOT 49 CFR 172.101 HAZARD CLASS OR DIVISION:
2.2
U.S. DOT 49 CFR 172.101 AND SUBPART E LABELING REQUIREMENTS:
Nonflammable gas; Oxidizer
U.S. DOT 49 CFR 172.101 PACKAGING AUTHORIZATIONS:
EXCEPTIONS: 49 CFR 173.306
NON-BULK PACKAGING: 49 CFR 173.302
BULK PACKAGING: 49 CFR 173.314, 315
U.S. DOT 49 CFR 172.101 QUANTITY LIMITATIONS:
PASSENGER AIRCRAFT OR RAILCAR: 75 kg
CARGO AIRCRAFT ONLY: 150 kg
LAND TRANSPORT ADR/RID:
SUBSTANCE NAME: Oxygen, compressed
UN NUMBER: UN1072
ADR/RID CLASS: 2
ITEM NUMBER: 1(a)/1O
WARNING SIGN/LABEL: 2; 05/2; 05; 13
HAZARD ID NUMBER: 20/25
AIR TRANSPORT IATA/ICAO:
CORRECT TECHNICAL NAME: Oxygen, compressed
UN/ID NUMBER: UN1072
IATA/ICAO CLASS: 2.2
LABEL: Nonflammable gas; Oxidizer
MARITIME TRANSPORT IMDG:
CORRECT TECHNICAL NAME: Oxygen, compressed
UN/ID NUMBER: UN1072
IMDG CLASS: 2(2.2)
SUBSIDIARY RISK LABEL: Oxidizer
MGI12831
Page 009 of 009
EmS No.: 2-04
MFAG Table No.: none
MARINE POLLUTANT: N
-----------------------------------------------------------------------------SECTION 15
REGULATORY INFORMATION
-----------------------------------------------------------------------------U.S. REGULATIONS:
TSCA INVENTORY STATUS: Y
TSCA 12(b) EXPORT NOTIFICATION: Not listed.
CERCLA SECTION 103 (40CFR302.4): N
SARA SECTION 302 (40CFR355.30): N
SARA SECTION 304 (40CFR355.40): N
SARA SECTION 313 (40CFR372.65): N
5 of 6
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SARA HAZARD CATEGORIES, SARA SECTIONS 311/312 (40CFR370.21):
ACUTE: N
CHRONIC: N
FIRE: Y
REACTIVE: N
SUDDEN RELEASE: Y
OSHA PROCESS SAFETY (29CFR1910.119): N
STATE REGULATIONS:
California Proposition 65: N
EUROPEAN REGULATIONS:
EC NUMBER (EINECS): 231-956-9
EC RISK AND SAFETY PHRASES:
R 8
Contact with combustible material may cause fire.
S 2
Keep out of reach of children.
S 17
Keep away from combustible material.
GERMAN REGULATIONS:
WATER HAZARD CLASS (WGK): 0 (Official German Classification)
-----------------------------------------------------------------------------SECTION 16
OTHER INFORMATION
-----------------------------------------------------------------------------COPYRIGHT 1984-1999 MDL INFORMATION SYSTEMS, INC. ALL RIGHTS RESERVED.
THIS MSDS IS SUPPLIED PURSUANT TO OSHA REGULATIONS. OTHER GOVERNMENT
REGULATIONS MUST BE REVIEWED FOR APPLICABILITY TO THIS PRODUCT. WE BELIEVE THE
INFORMATION SOURCE IS RELIABLE AND THE INFORMATION IS ACCURATE AS OF THE DATE
HEREOF, HOWEVER, ACCURACY OR COMPLETENESS IS NOT GUARANTEED AND NO WARRANTY OF
ANY TYPE IS GRANTED. THE INFORMATION RELATES ONLY TO THIS SPECIFIC PRODUCT. IF
COMBINED WITH OTHER MATERIALS, ALL COMPONENT PROPERTIES MUST BE CONSIDERED.
Home | Who We Are | Products & Services | Applications | Locations | Around MG | Product Catalog | Search |
Contact Us
Copyright © 1997 by Messer - MG Industries
6 of 6
CI-N-02
7/21/99 12:01
MGI25130
Page 001 of 006
-----------------------------------------------------------------------------SECTION 1
CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
-----------------------------------------------------------------------------MG INDUSTRIES
EMERGENCY CONTACT:
3 GREAT VALLEY PARKWAY
CHEMTREC:
MALVERN, PENNSYLVANIA 19355
1-800-424-9300
PHONE: 610-695-7400
FAX: 610-695-7596
SUBSTANCE: XENON
TRADE NAMES/SYNONYMS:
XENON ATOM; STCC 4904595; UN 2036; XE; MGI25130; RTECS ZE1280000
CHEMICAL FAMILY: inorganic, gas
CREATION DATE: May 07 1990
REVISION DATE: Sep 10 1998
-----------------------------------------------------------------------------SECTION 2
COMPOSITION, INFORMATION ON INGREDIENTS
-----------------------------------------------------------------------------COMPONENT: XENON
CAS NUMBER: 7440-63-3
EC NUMBER (EINECS): 231-172-7
PERCENTAGE: 100.0
-----------------------------------------------------------------------------SECTION 3
HAZARDS IDENTIFICATION
-----------------------------------------------------------------------------NFPA RATINGS (SCALE 0-4): HEALTH=1 FIRE=0 REACTIVITY=0
EC CLASSIFICATION (CALCULATED): No classification assigned.
EMERGENCY OVERVIEW:
PHYSICAL DESCRIPTION: Odorless, colorless, tasteless gas.
MAJOR HEALTH HAZARDS: difficulty breathing
PHYSICAL HAZARDS: Containers may rupture or explode if exposed to heat.
POTENTIAL HEALTH EFFECTS:
INHALATION:
SHORT TERM EXPOSURE: nausea, vomiting, symptoms of drunkenness, suffocation,
convulsions, coma
LONG TERM EXPOSURE: no information is available
SKIN CONTACT:
SHORT TERM EXPOSURE: no information is available
LONG TERM EXPOSURE: no information is available
EYE CONTACT:
SHORT TERM EXPOSURE: no information is available
LONG TERM EXPOSURE: no information is available
INGESTION:
SHORT TERM EXPOSURE: no information on significant adverse effects
MGI25130
Page 002 of 006
LONG TERM EXPOSURE: no information is available
CARCINOGEN STATUS:
OSHA: N
NTP: N
IARC: N
-----------------------------------------------------------------------------SECTION 4
FIRST AID MEASURES
-----------------------------------------------------------------------------INHALATION: Remove from exposure immediately. Use a bag valve mask or similar
device to perform artificial respiration (rescue breathing) if needed. Get
medical attention.
SKIN CONTACT: Remove contaminated clothing, jewelry, and shoes immediately.
Wash with soap or mild detergent and large amounts of water until no
evidence of chemical remains (at least 15-20 minutes). Get medical
attention, if needed.
EYE CONTACT: Wash eyes immediately with large amounts of water or normal
saline, occasionally lifting upper and lower lids, until no evidence of
chemical remains. Get medical attention immediately.
INGESTION: It is unlikely that emergency treatment will be required. Get
medical attention, if needed.
-----------------------------------------------------------------------------SECTION 5
FIRE FIGHTING MEASURES
-----------------------------------------------------------------------------FIRE AND EXPLOSION HAZARDS: Negligible fire hazard. Containers may rupture or
explode if exposed to heat.
EXTINGUISHING MEDIA: carbon dioxide, regular dry chemical
Large fires: Use regular foam or flood with fine water spray.
FIRE FIGHTING: Move container from fire area if it can be done without risk.
Cool containers with water spray until well after the fire is out. Stay away
1 of 4
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from the ends of tanks. Withdraw immediately in case of rising sound from
venting safety device or any discoloration of tanks due to fire. For tank,
rail car or tank truck, evacuation radius: 800 meters (1/2 mile).
-----------------------------------------------------------------------------SECTION 6
ACCIDENTAL RELEASE MEASURES
-----------------------------------------------------------------------------OCCUPATIONAL RELEASE:
Stop leak if possible without personal risk. Keep unnecessary people away,
isolate hazard area and deny entry. Stay upwind and keep out of low areas.
MGI25130
Page 003 of 006
-----------------------------------------------------------------------------SECTION 7
HANDLING AND STORAGE
-----------------------------------------------------------------------------Cylinder temperature should not exceed 125 F (52 C).
29 CFR Subpart "H"-Hazardous Materials.
National Fire Protection Association publication #55, "Standard for the
Storage, Use and Handling of Compressed and Liquified Gases in Portable
Cylinders".
Compressed Gas Association publication P-1, "Safe Handling of Compressed Gases
in Containers".
Store and handle in accordance with current regulations and standards:
OSHA 29 CFR 1910.101
-----------------------------------------------------------------------------SECTION 8
EXPOSURE CONTROLS, PERSONAL PROTECTION
-----------------------------------------------------------------------------EXPOSURE LIMITS:
XENON:
No occupational exposure limits established.
VENTILATION: Provide local exhaust ventilation system. Ensure compliance with
applicable exposure limits.
EYE PROTECTION: Wear splash resistant safety goggles. Provide an emergency eye
wash fountain and quick drench shower in the immediate work area.
CLOTHING: Protective clothing is not required.
GLOVES: Protective gloves are not required, but recommended.
RESPIRATOR: Under conditions of frequent use or heavy exposure, respiratory
protection may be needed. Respiratory protection is ranked in order from
minimum to maximum. Consider warning properties before use.
For Unknown Concentrations or Immediately Dangerous to Life or Health Any supplied-air respirator with full facepiece and operated in a
pressure-demand or other positive-pressure mode in combination with a
separate escape supply.
Any self-contained breathing apparatus with a full facepiece.
-----------------------------------------------------------------------------SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
-----------------------------------------------------------------------------PHYSICAL DESCRIPTION: Odorless, colorless, tasteless gas.
MOLECULAR WEIGHT: 131.30
MOLECULAR FORMULA: XE
BOILING POINT: -162 F (-108 C)
FREEZING POINT: -170 F (-112 C)
VAPOR PRESSURE: 760 mmHg @ -108 C
VAPOR DENSITY (air=1): 4.561
SPECIFIC GRAVITY: Not applicable
DENSITY: 5.8878 g/L
WATER SOLUBILITY: 0.108%
MGI25130
Page 004 of 006
PH: Not applicable
VOLATILITY: Not applicable
ODOR THRESHOLD: Not available
EVAPORATION RATE: Not applicable
VISCOSITY: 0.02324 cP @ 27 C
COEFFICIENT OF WATER/OIL DISTRIBUTION: Not applicable
-----------------------------------------------------------------------------SECTION 10
STABILITY AND REACTIVITY
-----------------------------------------------------------------------------REACTIVITY: Stable at normal temperatures and pressure.
CONDITIONS TO AVOID: Protect from physical damage and heat. Containers may
rupture or explode if exposed to heat.
INCOMPATIBILITIES: halogens
XENON:
CATALYSTS: Interaction may be explosive in the presence of finely divided
nickel fluoride or silver difluoride, or nickel(III) oxide, silver(I)
oxide, or if initiated by heating.
FLUORINE: Interaction may be explosive in the presence of finely divided
nickel fluoride or silver difluoride, or nickel(III) oxide silver(I)
oxide,
or if initiated by heating.
POLYMERIZATION: Will not polymerize.
-----------------------------------------------------------------------------SECTION 11
TOXICOLOGICAL INFORMATION
2 of 4
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-----------------------------------------------------------------------------HEALTH EFFECTS:
INHALATION:
ACUTE EXPOSURE:
XENON: May act as a simple asphyxiant by displacing oxygen. At high
concentrations the gas may cause narcosis and anesthesia. Concentrations
of simple asphyxiants above 33% may cause rapid respiration, dyspnea,
reduced mental alertness and muscular coordination. At higher levels,
faulty judgement, depressed sensations, emotional instability and rapid
fatigue may occur. As the asphyxia progresses, there may be nausea,
vomiting, prostration, unconsciousness, convulsions, deep coma, and death.
CHRONIC EXPOSURE:
XENON: No data available.
SKIN CONTACT:
ACUTE EXPOSURE:
XENON: No data available.
CHRONIC EXPOSURE:
XENON: No data available.
EYE CONTACT:
MGI25130
Page 005 of 006
ACUTE EXPOSURE:
XENON: No data available.
CHRONIC EXPOSURE:
XENON: No data available.
INGESTION:
ACUTE EXPOSURE:
XENON: Ingestion of a gas is unlikely.
CHRONIC EXPOSURE:
XENON: No data available.
-----------------------------------------------------------------------------SECTION 12
ECOLOGICAL INFORMATION
-----------------------------------------------------------------------------Not available
-----------------------------------------------------------------------------SECTION 13
DISPOSAL CONSIDERATIONS
-----------------------------------------------------------------------------Dispose in accordance with all applicable regulations.
-----------------------------------------------------------------------------SECTION 14
TRANSPORT INFORMATION
-----------------------------------------------------------------------------U.S. DOT 49 CFR 172.101 SHIPPING NAME-UN NUMBER:
Xenon, compressed.-UN2036
U.S. DOT 49 CFR 172.101 HAZARD CLASS OR DIVISION:
2.2
U.S. DOT 49 CFR 172.101 AND SUBPART E LABELING REQUIREMENTS:
Nonflammable gas
U.S. DOT 49 CFR 172.101 PACKAGING AUTHORIZATIONS:
EXCEPTIONS: 49 CFR 173.306
NON-BULK PACKAGING: 49 CFR 173.302
BULK PACKAGING: None
U.S. DOT 49 CFR 172.101 QUANTITY LIMITATIONS:
PASSENGER AIRCRAFT OR RAILCAR: 75 kg
CARGO AIRCRAFT ONLY: 150 kg
LAND TRANSPORT ADR/RID:
SUBSTANCE NAME: Xenon/Xenon, compressed
UN NUMBER: UN2036
ADR/RID CLASS: 2
ITEM NUMBER: 5(a)/1A
WARNING SIGN/LABEL: 2/2; 13
HAZARD ID NUMBER: 20
MGI25130
Page 006 of 006
AIR TRANSPORT IATA/ICAO:
CORRECT TECHNICAL NAME: Xenon
UN/ID NUMBER: UN2036
IATA/ICAO CLASS: 2.2
LABEL: Nonflammable gas
MARITIME TRANSPORT IMDG:
CORRECT TECHNICAL NAME: Xenon
UN/ID NUMBER: UN2036
IMDG CLASS: 2(2.2)
EmS No.: 2-09
MFAG Table No.: none
MARINE POLLUTANT: N
-----------------------------------------------------------------------------SECTION 15
REGULATORY INFORMATION
-----------------------------------------------------------------------------U.S. REGULATIONS:
TSCA INVENTORY STATUS: Y
TSCA 12(b) EXPORT NOTIFICATION: Not listed.
CERCLA SECTION 103 (40CFR302.4): N
3 of 4
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SARA SECTION 302 (40CFR355.30): N
SARA SECTION 304 (40CFR355.40): N
SARA SECTION 313 (40CFR372.65): N
SARA HAZARD CATEGORIES, SARA SECTIONS 311/312 (40CFR370.21):
ACUTE: Y
CHRONIC: N
FIRE: N
REACTIVE: N
SUDDEN RELEASE: Y
OSHA PROCESS SAFETY (29CFR1910.119): N
STATE REGULATIONS:
California Proposition 65: N
EUROPEAN REGULATIONS:
EC NUMBER (EINECS): 231-172-7
-----------------------------------------------------------------------------SECTION 16
OTHER INFORMATION
-----------------------------------------------------------------------------COPYRIGHT 1984-1999 MDL INFORMATION SYSTEMS, INC. ALL RIGHTS RESERVED.
THIS MSDS IS SUPPLIED PURSUANT TO OSHA REGULATIONS. OTHER GOVERNMENT
REGULATIONS MUST BE REVIEWED FOR APPLICABILITY TO THIS PRODUCT. WE BELIEVE THE
INFORMATION SOURCE IS RELIABLE AND THE INFORMATION IS ACCURATE AS OF THE DATE
HEREOF, HOWEVER, ACCURACY OR COMPLETENESS IS NOT GUARANTEED AND NO WARRANTY OF
ANY TYPE IS GRANTED. THE INFORMATION RELATES ONLY TO THIS SPECIFIC PRODUCT. IF
COMBINED WITH OTHER MATERIALS, ALL COMPONENT PROPERTIES MUST BE CONSIDERED.
Home | Who We Are | Products & Services | Applications | Locations | Around MG | Product Catalog | Search |
Contact Us
Copyright © 1997 by Messer - MG Industries
4 of 4
CI-N-02
7/21/99 12:06
MGI10640
Page 001 of 007
-----------------------------------------------------------------------------SECTION 1
CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
-----------------------------------------------------------------------------MG INDUSTRIES
EMERGENCY CONTACT:
3 GREAT VALLEY PARKWAY
CHEMTREC:
MALVERN, PENNSYLVANIA 19355
1-800-424-9300
PHONE: 610-695-7400
FAX: 610-695-7596
SUBSTANCE: HELIUM
TRADE NAMES/SYNONYMS:
HELIUM GAS; HELIUM COMPRESSED; HELIUM-4; ATOMIC HELIUM; STCC 4904540; UN 1046;
HE; MGI10640; RTECS MH6520000
CHEMICAL FAMILY: inorganic, gas
CREATION DATE: May 04 1990
REVISION DATE: Sep 10 1998
-----------------------------------------------------------------------------SECTION 2
COMPOSITION, INFORMATION ON INGREDIENTS
-----------------------------------------------------------------------------COMPONENT: HELIUM
CAS NUMBER: 7440-59-7
EC NUMBER (EINECS): 231-168-5
PERCENTAGE: 100.0
-----------------------------------------------------------------------------SECTION 3
HAZARDS IDENTIFICATION
-----------------------------------------------------------------------------NFPA RATINGS (SCALE 0-4): HEALTH=1 FIRE=0 REACTIVITY=0
EC CLASSIFICATION (CALCULATED): No classification assigned.
EMERGENCY OVERVIEW:
PHYSICAL DESCRIPTION: Odorless, colorless, tasteless, inert gas.
MAJOR HEALTH HAZARDS: difficulty breathing
PHYSICAL HAZARDS: Containers may rupture or explode if exposed to heat.
POTENTIAL HEALTH EFFECTS:
INHALATION:
SHORT TERM EXPOSURE: nausea, vomiting, dizziness, tingling sensation,
suffocation, convulsions, coma
LONG TERM EXPOSURE: no information on significant adverse effects
SKIN CONTACT:
SHORT TERM EXPOSURE: blisters, frostbite
LONG TERM EXPOSURE: no information is available
EYE CONTACT:
SHORT TERM EXPOSURE: frostbite, blurred vision
LONG TERM EXPOSURE: no information is available
INGESTION:
MGI10640
Page 002 of 007
SHORT TERM EXPOSURE: frostbite
LONG TERM EXPOSURE: no information is available
CARCINOGEN STATUS:
OSHA: N
NTP: N
IARC: N
-----------------------------------------------------------------------------SECTION 4
FIRST AID MEASURES
-----------------------------------------------------------------------------INHALATION: When safe to enter area, remove from exposure. Use a bag valve
mask or similar device to perform artificial respiration (rescue breathing)
if needed. Keep warm and at rest. Get medical attention immediately.
SKIN CONTACT: Wash if needed. If frostbite, freezing, or cryogenic burns
occur, warm affected area in warm water. If this is not available, gently
wrap affected parts in blankets. Allow circulation to return naturally. Get
medical attention immediately.
EYE CONTACT: It is unlikely that emergency treatment will be required. Wash
with large amounts of water or normal saline until no evidence of chemical
remains (at least 15-20 minutes). Get medical attention immediately.
INGESTION: It is unlikely that emergency treatment will be required. Get
medical attention, if needed.
NOTE TO PHYSICIAN: For inhalation, consider oxygen.
-----------------------------------------------------------------------------SECTION 5
FIRE FIGHTING MEASURES
-----------------------------------------------------------------------------FIRE AND EXPLOSION HAZARDS: Negligible fire hazard. Containers may rupture or
explode if exposed to heat.
EXTINGUISHING MEDIA: carbon dioxide, regular dry chemical
Large fires: Use regular foam or flood with fine water spray.
1 of 4
CI-N-02
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FIRE FIGHTING: Move container from fire area if it can be done without risk.
Cool containers with water spray until well after the fire is out. Stay away
from the ends of tanks. Withdraw immediately in case of rising sound from
venting safety device or any discoloration of tanks due to fire. For tank,
rail car or tank truck, evacuation radius: 800 meters (1/2 mile).
-----------------------------------------------------------------------------SECTION 6
ACCIDENTAL RELEASE MEASURES
-----------------------------------------------------------------------------OCCUPATIONAL RELEASE:
Stop leak if possible without personal risk. Keep unnecessary people away,
isolate hazard area and deny entry. Stay upwind and keep out of low areas.
MGI10640
Page 003 of 007
-----------------------------------------------------------------------------SECTION 7
HANDLING AND STORAGE
-----------------------------------------------------------------------------Cylinder temperature should not exceed 125 F (52 C).
29 CFR Subpart "H"-Hazardous Materials.
National Fire Protection Association publication #55, "Standard for the
Storage, Use and Handling of Compressed and Liquified Gases in Portable
Cylinders".
Compressed Gas Association publication P-1, "Safe Handling of Compressed Gases
in Containers".
Store and handle in accordance with current regulations and standards:
OSHA 29 CFR 1910.101
-----------------------------------------------------------------------------SECTION 8
EXPOSURE CONTROLS, PERSONAL PROTECTION
-----------------------------------------------------------------------------EXPOSURE LIMITS:
HELIUM:
No occupational exposure limits established.
VENTILATION: Based on available information, additional ventilation is not
required. Ensure compliance with applicable exposure limits.
EYE PROTECTION: For the gas: Eye protection not required, but recommended. For
the liquid: Wear splash resistant safety goggles. Contact lenses should not
be worn. Provide an emergency eye wash fountain and quick drench shower in
the immediate work area.
CLOTHING: For the gas: Protective clothing is not required. For the liquid:
Wear appropriate protective, cold insulating clothing.
GLOVES: Wear insulated gloves.
RESPIRATOR: Under conditions of frequent use or heavy exposure, respiratory
protection may be needed. Respiratory protection is ranked in order from
minimum to maximum. Consider warning properties before use.
For Unknown Concentrations or Immediately Dangerous to Life or Health Any supplied-air respirator with full facepiece and operated in a
pressure-demand or other positive-pressure mode in combination with a
separate escape supply.
Any self-contained breathing apparatus with a full facepiece.
-----------------------------------------------------------------------------SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
-----------------------------------------------------------------------------PHYSICAL DESCRIPTION: Odorless, colorless, tasteless, inert gas.
MOLECULAR WEIGHT: 4.0026
MOLECULAR FORMULA: HE
BOILING POINT: -452 F (-269 C)
FREEZING POINT: -458 F (-272 C) @ 26 atm
VAPOR PRESSURE: 1719 mmHg @ -268 C
VAPOR DENSITY (air=1): 0.138
MGI10640
Page 004 of 007
SPECIFIC GRAVITY: Not applicable
DENSITY: 0.1785 g/L @ 0 C
WATER SOLUBILITY: 0.94% @ 0 C
PH: Not applicable
VOLATILITY: Not applicable
ODOR THRESHOLD: Not available
EVAPORATION RATE: Not applicable
VISCOSITY: 0.02012 cP @ 26.8 C
COEFFICIENT OF WATER/OIL DISTRIBUTION: Not applicable
SOLVENT SOLUBILITY:
Insoluble: alcohol
-----------------------------------------------------------------------------SECTION 10
STABILITY AND REACTIVITY
-----------------------------------------------------------------------------REACTIVITY: Stable at normal temperatures and pressure.
CONDITIONS TO AVOID: Protect from physical damage and heat. Containers may
rupture or explode if exposed to heat.
INCOMPATIBILITIES:
HELIUM:
No data available.
POLYMERIZATION: Will not polymerize.
------------------------------------------------------------------------------
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SECTION 11
TOXICOLOGICAL INFORMATION
-----------------------------------------------------------------------------HEALTH EFFECTS:
INHALATION:
Do not breathe gas.
HELIUM: Inhalation of mixtures of helium and oxygen may cause distorted
speech, increased loss of body heat, and gas emboli at the junction of skin
and subcutaneous fat or body fat and blood vessels. See information on
simple asphyxiants.
ACUTE EXPOSURE:
SIMPLE ASPHYXIANTS: The symptoms of asphyxia depend on the rapidity with
which the oxygen deficiency develops and how long it continues. In sudden
acute asphyxia, unconsciousness may be immediate. With slow development
there may be rapid respiration and pulse, air hunger, dizziness, reduced
awareness, tightness in the head, tingling sensations, incoordination,
faulty judgement, emotional instability, and rapid fatigue. As the
asphyxia progresses, nausea, vomiting, collapse, unconsciousness,
convulsions, deep coma and death are possible.
CHRONIC EXPOSURE:
SIMPLE ASPHYXIANTS: No data available.
SKIN CONTACT:
ACUTE EXPOSURE:
MGI10640
Page 005 of 007
HELIUM: No adverse effects have been reported from the gas. Due to rapid
evaporation, the liquid may cause frostbite with redness, tingling and
pain or numbness. In more severe cases, the skin may become hard and white
and develop blisters.
CHRONIC EXPOSURE:
HELIUM: No data available.
EYE CONTACT:
ACUTE EXPOSURE:
HELIUM: No adverse effects have been reported from the gas. Due to rapid
evaporation, the liquid may cause frostbite with redness, pain, and
blurred vision.
CHRONIC EXPOSURE:
HELIUM: No data available.
INGESTION:
ACUTE EXPOSURE:
HELIUM: Ingestion of a gas is unlikely. If liquid is swallowed, frostbite
damage to the lips, mouth and mucous membranes may occur.
CHRONIC EXPOSURE:
HELIUM: No data available.
-----------------------------------------------------------------------------SECTION 12
ECOLOGICAL INFORMATION
-----------------------------------------------------------------------------Not available
-----------------------------------------------------------------------------SECTION 13
DISPOSAL CONSIDERATIONS
-----------------------------------------------------------------------------Dispose in accordance with all applicable regulations.
-----------------------------------------------------------------------------SECTION 14
TRANSPORT INFORMATION
-----------------------------------------------------------------------------U.S. DOT 49 CFR 172.101 SHIPPING NAME-UN NUMBER:
Helium, compressed-UN1046
U.S. DOT 49 CFR 172.101 HAZARD CLASS OR DIVISION:
2.2
U.S. DOT 49 CFR 172.101 AND SUBPART E LABELING REQUIREMENTS:
Nonflammable gas
U.S. DOT 49 CFR 172.101 PACKAGING AUTHORIZATIONS:
EXCEPTIONS: 49 CFR 173.306
NON-BULK PACKAGING: 49 CFR 173.302
BULK PACKAGING: 49 CFR 173.302, 314
MGI10640
Page 006 of 007
U.S. DOT 49 CFR 172.101 QUANTITY LIMITATIONS:
PASSENGER AIRCRAFT OR RAILCAR: 75 kg
CARGO AIRCRAFT ONLY: 150 kg
LAND TRANSPORT ADR/RID:
SUBSTANCE NAME: Helium, compressed
UN NUMBER: UN1046
ADR/RID CLASS: 2
ITEM NUMBER: 1(a)/1A
WARNING SIGN/LABEL: 2/2; 13
HAZARD ID NUMBER: 20
AIR TRANSPORT IATA/ICAO:
CORRECT TECHNICAL NAME: Helium, compressed
UN/ID NUMBER: UN1046
IATA/ICAO CLASS: 2.2
LABEL: Nonflammable gas
MARITIME TRANSPORT IMDG:
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CORRECT TECHNICAL NAME: Helium, compressed
UN/ID NUMBER: UN1046
IMDG CLASS: 2(2.2)
EmS No.: 2-04
MFAG Table No.: none
MARINE POLLUTANT: N
-----------------------------------------------------------------------------SECTION 15
REGULATORY INFORMATION
-----------------------------------------------------------------------------U.S. REGULATIONS:
TSCA INVENTORY STATUS: Y
TSCA 12(b) EXPORT NOTIFICATION: Not listed.
CERCLA SECTION 103 (40CFR302.4): N
SARA SECTION 302 (40CFR355.30): N
SARA SECTION 304 (40CFR355.40): N
SARA SECTION 313 (40CFR372.65): N
SARA HAZARD CATEGORIES, SARA SECTIONS 311/312 (40CFR370.21):
ACUTE: Y
CHRONIC: N
FIRE: N
REACTIVE: N
SUDDEN RELEASE: Y
OSHA PROCESS SAFETY (29CFR1910.119): N
STATE REGULATIONS:
California Proposition 65: N
EUROPEAN REGULATIONS:
EC NUMBER (EINECS): 231-168-5
-----------------------------------------------------------------------------SECTION 16
OTHER INFORMATION
-----------------------------------------------------------------------------COPYRIGHT 1984-1999 MDL INFORMATION SYSTEMS, INC. ALL RIGHTS RESERVED.
MGI10640
Page 007 of 007
THIS MSDS IS SUPPLIED PURSUANT TO OSHA REGULATIONS. OTHER GOVERNMENT
REGULATIONS MUST BE REVIEWED FOR APPLICABILITY TO THIS PRODUCT. WE BELIEVE THE
INFORMATION SOURCE IS RELIABLE AND THE INFORMATION IS ACCURATE AS OF THE DATE
HEREOF, HOWEVER, ACCURACY OR COMPLETENESS IS NOT GUARANTEED AND NO WARRANTY OF
ANY TYPE IS GRANTED. THE INFORMATION RELATES ONLY TO THIS SPECIFIC PRODUCT. IF
COMBINED WITH OTHER MATERIALS, ALL COMPONENT PROPERTIES MUST BE CONSIDERED.
Home | Who We Are | Products & Services | Applications | Locations | Around MG | Product Catalog | Search |
Contact Us
Copyright © 1997 by Messer - MG Industries
4 of 4
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MGI11120
Page 001 of 008
-----------------------------------------------------------------------------SECTION 1
CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
-----------------------------------------------------------------------------MG INDUSTRIES
EMERGENCY CONTACT:
3 GREAT VALLEY PARKWAY
CHEMTREC:
MALVERN, PENNSYLVANIA 19355
1-800-424-9300
PHONE: 610-695-7400
FAX: 610-695-7596
SUBSTANCE: HYDROGEN
TRADE NAMES/SYNONYMS:
HYDROGEN GAS; HYDROGEN COMPRESSED; HYDROGEN (H2); DIHYDROGEN; STCC 4905746; UN
1049; H2; MGI11120; RTECS MW8900000
CHEMICAL FAMILY: inorganic, gas
CREATION DATE: May 04 1990
REVISION DATE: Sep 10 1998
-----------------------------------------------------------------------------SECTION 2
COMPOSITION, INFORMATION ON INGREDIENTS
-----------------------------------------------------------------------------COMPONENT: HYDROGEN
CAS NUMBER: 1333-74-0
EC NUMBER (EINECS): 215-605-7
EC INDEX NUMBER: 001-001-00-9
PERCENTAGE: 100.0
-----------------------------------------------------------------------------SECTION 3
HAZARDS IDENTIFICATION
-----------------------------------------------------------------------------NFPA RATINGS (SCALE 0-4): HEALTH=1 FIRE=4 REACTIVITY=0
EC CLASSIFICATION (ASSIGNED):
F+ Extremely Flammable
R 12
EC Classification may be inconsistent with independently-researched data.
EMERGENCY OVERVIEW:
PHYSICAL DESCRIPTION: Odorless, colorless, tasteless gas.
MAJOR HEALTH HAZARDS: difficulty breathing
PHYSICAL HAZARDS: Flammable gas. May cause flash fire.
POTENTIAL HEALTH EFFECTS:
INHALATION:
SHORT TERM EXPOSURE: nausea, vomiting, dizziness, tingling sensation,
suffocation, convulsions, coma
LONG TERM EXPOSURE: no information on significant adverse effects
SKIN CONTACT:
MGI11120
Page 002 of 008
SHORT TERM EXPOSURE: blisters, frostbite
LONG TERM EXPOSURE: no information is available
EYE CONTACT:
SHORT TERM EXPOSURE: frostbite, blurred vision
LONG TERM EXPOSURE: no information is available
INGESTION:
SHORT TERM EXPOSURE: frostbite
LONG TERM EXPOSURE: no information is available
CARCINOGEN STATUS:
OSHA: N
NTP: N
IARC: N
-----------------------------------------------------------------------------SECTION 4
FIRST AID MEASURES
-----------------------------------------------------------------------------INHALATION: When safe to enter area, remove from exposure. Use a bag valve
mask or similar device to perform artificial respiration (rescue breathing)
if needed. Keep warm and at rest. Get medical attention immediately.
SKIN CONTACT: Wash if needed. If frostbite, freezing, or cryogenic burns
occur, warm affected area in warm water. If this is not available, gently
wrap affected parts in blankets. Allow circulation to return naturally. Get
medical attention immediately.
EYE CONTACT: It is unlikely that emergency treatment will be required. Wash
with large amounts of water or normal saline until no evidence of chemical
remains (at least 15-20 minutes). Get medical attention immediately.
INGESTION: It is unlikely that emergency treatment will be required. Get
medical attention, if needed.
NOTE TO PHYSICIAN: For inhalation, consider oxygen.
-----------------------------------------------------------------------------SECTION 5
FIRE FIGHTING MEASURES
------------------------------------------------------------------------------
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FIRE AND EXPLOSION HAZARDS: Severe fire hazard. Severe explosion hazard.
Vapor/air mixtures are explosive. Containers may rupture or explode if
exposed to heat. Electrostatic discharges may be generated by flow or
agitation resulting in ignition or explosion.
EXTINGUISHING MEDIA: carbon dioxide, regular dry chemical
Large fires: Flood with fine water spray.
FIRE FIGHTING: Move container from fire area if it can be done without risk.
Cool containers with water spray until well after the fire is out. Stay away
from the ends of tanks. For fires in cargo or storage area: Cool containers
with water from unmanned hose holder or monitor nozzles until well after
fire is out. If this is impossible then take the following precautions: Keep
unnecessary people away, isolate hazard area and deny entry. Let the fire
burn. Withdraw immediately in case of rising sound from venting safety
MGI11120
Page 003 of 008
device or any discoloration of tanks due to fire. For tank, rail car or tank
truck: Stop leak if possible without personal risk. Let burn unless leak can
be stopped immediately. For smaller tanks or cylinders, extinguish and
isolate from other flammables. Evacuation radius: 800 meters (1/2 mile). Do
not attempt to extinguish fire unless flow of material can be stopped first.
Flood with fine water spray. Cool containers with water spray until well
after the fire is out. Apply water from a protected location or from a safe
distance. Avoid inhalation of material or combustion by-products. Stay
upwind and keep out of low areas. Evacuate if fire gets out of control or
containers are directly exposed to fire. Evacuation radius: 500 meters (1/3
mile). Consider downwind evacuation if material is leaking. Stop flow of
gas.
LOWER FLAMMABLE LIMIT: 4.0%
UPPER FLAMMABLE LIMIT: 75%
AUTOIGNITION: 932 F (500 C)
-----------------------------------------------------------------------------SECTION 6
ACCIDENTAL RELEASE MEASURES
-----------------------------------------------------------------------------OCCUPATIONAL RELEASE:
Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled
material. Stop leak if possible without personal risk. Reduce vapors with
water spray. Keep unnecessary people away, isolate hazard area and deny entry.
Remove sources of ignition. Ventilate closed spaces before entering.
-----------------------------------------------------------------------------SECTION 7
HANDLING AND STORAGE
-----------------------------------------------------------------------------Cylinder temperature should not exceed 125 F (52 C).
29 CFR Subpart "H"-Hazardous Materials.
National Fire Protection Association publication #55, "Standard for the
Storage, Use and Handling of Compressed and Liquified Gases in Portable
Cylinders".
Compressed Gas Association publication P-1, "Safe Handling of Compressed Gases
in Containers".
Store and handle in accordance with current regulations and standards:
OSHA 29 CFR 1910.101. Store in a cool, dry place. Ventilation required.
Store outside or in a detached building.
-----------------------------------------------------------------------------SECTION 8
EXPOSURE CONTROLS, PERSONAL PROTECTION
-----------------------------------------------------------------------------EXPOSURE LIMITS:
HYDROGEN:
No occupational exposure limits established.
VENTILATION: Provide local exhaust ventilation system. Ventilation equipment
should be explosion-resistant if explosive concentrations of material are
present. Ensure compliance with applicable exposure limits.
EYE PROTECTION: For the gas: Eye protection not required, but recommended. For
MGI11120
Page 004 of 008
the liquid: Wear splash resistant safety goggles. Contact lenses should not
be worn. Provide an emergency eye wash fountain and quick drench shower in
the immediate work area.
CLOTHING: For the gas: Protective clothing is not required. For the liquid:
Wear appropriate protective, cold insulating clothing.
GLOVES: Wear insulated gloves.
RESPIRATOR: Under conditions of frequent use or heavy exposure, respiratory
protection may be needed. Respiratory protection is ranked in order from
minimum to maximum. Consider warning properties before use.
For Unknown Concentrations or Immediately Dangerous to Life or Health Any supplied-air respirator with full facepiece and operated in a
pressure-demand or other positive-pressure mode in combination with a
separate escape supply.
Any self-contained breathing apparatus with a full facepiece.
-----------------------------------------------------------------------------SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
-----------------------------------------------------------------------------PHYSICAL DESCRIPTION: Odorless, colorless, tasteless gas.
MOLECULAR WEIGHT: 2.0
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MOLECULAR FORMULA: H2
BOILING POINT: -423 F (-253 C)
FREEZING POINT: -434 F (-259 C)
VAPOR PRESSURE: 760 mmHg @ -253 C
VAPOR DENSITY (air=1): 0.07
SPECIFIC GRAVITY: Not applicable
DENSITY: 0.08987 g/L @ 0 C
WATER SOLUBILITY: 1.82% @ 20 C
PH: Not applicable
VOLATILITY: Not applicable
ODOR THRESHOLD: Not available
EVAPORATION RATE: Not applicable
VISCOSITY: 0.008957 cP @ 26.8 C
COEFFICIENT OF WATER/OIL DISTRIBUTION: Not applicable
SOLVENT SOLUBILITY:
Slightly Soluble: alcohol, ether
-----------------------------------------------------------------------------SECTION 10
STABILITY AND REACTIVITY
-----------------------------------------------------------------------------REACTIVITY: Stable at normal temperatures and pressure.
CONDITIONS TO AVOID: Avoid heat, flames, sparks and other sources of ignition.
Minimize contact with material. Containers may rupture or explode if exposed
to heat.
INCOMPATIBILITIES: metals, oxidizing materials, metal oxides, combustible
materials, halogens, metal salts, halo carbons
HYDROGEN:
MGI11120
Page 005 of 008
ALKALINE METALS: Ignition at elevated temperatures.
CALCIUM CARBONATE + MAGNESIUM (POWDER): Explosion on heating.
CHLORINE DIOXIDE: Detonates when sparked or on contact with platinum sponge.
COPPER (II) OXIDE: Violent explosion when heated.
DICHLORINE OXIDE: Detonates on ignition.
DIFLUORODIAZENE: Explosive reaction above 90 C.
DINITROGEN OXIDE: Sensitizes hydrogen-oxygen mixtures.
DINITROGEN TETRAOXIDE: Sensitizes hydrogen-oxygen mixtures.
DIOXANE + NICKEL (CATALYST): Explosive reaction above 200 C.
FLUORINE PERCHLORATE: Ignition.
HALOGENS: Ignition or explosive reaction.
INTERHALOGENS: Ignition or explosive reaction.
ISOPROPYL ALCOHOL + PALLADIUM: Ignition.
NITROANISOLE + NICKEL (CATALYST): Explosion.
NITROGEN (LIQUID) + ALKENES: May form explosive products.
NITROGEN OXIDE: Sensitizes hydrogen-oxygen mixutres.
NITROGEN TRIFLUORIDE: Explosive reaction on ignition.
NITROSYL CHLORIDE: Causes ignition in hydrogen-oxygen mixtures.
NITRYL FLUORIDE: Explosion @ 200-300 C.
OXIDIZERS: Ignition or explosion.
OXYGEN: Flammable, explosive mixtures, particularly in the presence of a
catalyst.
OXYGEN DIFLUORIDE: Explodes if ignited.
OZONE (SOLID): Highly explosive mixtures with liquid hydrogen.
PALLADIUM(II) OXIDE: Incandesces on contact.
PALLADIUM TRIFLUORIDE: Reduces with incandescence.
1-PENTOL: Explosive reaction on heating.
POLY(CARBON MONOFLUORIDE): Deflagration above 400 C.
1,1,1-TRIS(AZIDOMETHYL)ETHANE + CATALYST: Possible explosion.
1,1,1-TRIS(HYDROXYMETHYL)NITROMETHANE + CATALYST: Possible explosion.
UNSATURATED HYDROCARBONS: Hydrogenation of unsaturated hydrocarbons in the
presence of a catalyst may proceed with explosive violence if conditions
are not properly controlled.
XENON HEXAFLUORIDE: Violent reaction.
POLYMERIZATION: Will not polymerize.
-----------------------------------------------------------------------------SECTION 11
TOXICOLOGICAL INFORMATION
-----------------------------------------------------------------------------HEALTH EFFECTS:
INHALATION:
HYDROGEN: See information on simple asphyxiants.
ACUTE EXPOSURE:
SIMPLE ASPHYXIANTS: The symptoms of asphyxia depend on the rapidity with
which the oxygen deficiency develops and how long it continues. In sudden
acute asphyxia, unconsciousness may be immediate. With slow development
there may be rapid respiration and pulse, air hunger, dizziness, reduced
awareness, tightness in the head, tingling sensations, incoordination,
faulty judgement, emotional instability, and rapid fatigue. As the
asphyxia progresses, nausea, vomiting, collapse, unconsciousness,
convulsions, deep coma and death are possible.
MGI11120
Page 006 of 008
CHRONIC EXPOSURE:
SIMPLE ASPHYXIANTS: No data available.
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SKIN CONTACT:
ACUTE EXPOSURE:
HYDROGEN: No adverse effects have been reported from the gas. Due to rapid
evaporation, the liquid may cause frostbite with redness, tingling and
pain or numbness. In more severe cases, the skin may become hard and white
and develop blisters.
CHRONIC EXPOSURE:
HYDROGEN: No data available.
EYE CONTACT:
ACUTE EXPOSURE:
HYDROGEN: No adverse effects have been reported from the gas. Due to rapid
evaporation, the liquid may cause frostbite with redness, pain and blurred
vision.
CHRONIC EXPOSURE:
HYDROGEN: No data available.
INGESTION:
ACUTE EXPOSURE:
HYDROGEN: Ingestion of a gas is unlikely. If liquid is swallowed,
frostbite damage to the lips, mouth and mucous membranes may occur.
CHRONIC EXPOSURE:
HYDROGEN: No data available.
-----------------------------------------------------------------------------SECTION 12
ECOLOGICAL INFORMATION
-----------------------------------------------------------------------------Not available
-----------------------------------------------------------------------------SECTION 13
DISPOSAL CONSIDERATIONS
-----------------------------------------------------------------------------Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste
Number(s): D001. Dispose in accordance with all applicable regulations.
-----------------------------------------------------------------------------SECTION 14
TRANSPORT INFORMATION
-----------------------------------------------------------------------------U.S. DOT 49 CFR 172.101 SHIPPING NAME-UN NUMBER:
Hydrogen, compressed-UN1049
U.S. DOT 49 CFR 172.101 HAZARD CLASS OR DIVISION:
2.1
U.S. DOT 49 CFR 172.101 AND SUBPART E LABELING REQUIREMENTS:
Flammable gas
MGI11120
Page 007 of 008
U.S. DOT 49 CFR 172.101 PACKAGING AUTHORIZATIONS:
EXCEPTIONS: 49 CFR 173.306
NON-BULK PACKAGING: 49 CFR 173.302
BULK PACKAGING: 49 CFR 173.302, 314
U.S. DOT 49 CFR 172.101 QUANTITY LIMITATIONS:
PASSENGER AIRCRAFT OR RAILCAR: Forbidden
CARGO AIRCRAFT ONLY: 150 kg
LAND TRANSPORT ADR/RID:
SUBSTANCE NAME: Hydrogen, compressed
UN NUMBER: UN1049
ADR/RID CLASS: 2
ITEM NUMBER: 1(b)/1F
WARNING SIGN/LABEL: 3/3; 13
HAZARD ID NUMBER: 23
AIR TRANSPORT IATA/ICAO:
CORRECT TECHNICAL NAME: Hydrogen, compressed
UN/ID NUMBER: UN1049
IATA/ICAO CLASS: 2.1
LABEL: Flammable gas
MARITIME TRANSPORT IMDG:
CORRECT TECHNICAL NAME: Hydrogen, compressed
UN/ID NUMBER: UN1049
IMDG CLASS: 2(2.1)
EmS No.: 2-02
MFAG Table No.: none
MARINE POLLUTANT: N
-----------------------------------------------------------------------------SECTION 15
REGULATORY INFORMATION
-----------------------------------------------------------------------------U.S. REGULATIONS:
TSCA INVENTORY STATUS: Y
TSCA 12(b) EXPORT NOTIFICATION: Not listed.
CERCLA SECTION 103 (40CFR302.4): N
SARA SECTION 302 (40CFR355.30): N
SARA SECTION 304 (40CFR355.40): N
SARA SECTION 313 (40CFR372.65): N
SARA HAZARD CATEGORIES, SARA SECTIONS 311/312 (40CFR370.21):
ACUTE: Y
CHRONIC: N
FIRE: Y
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REACTIVE: N
SUDDEN RELEASE: N
OSHA PROCESS SAFETY (29CFR1910.119): N
STATE REGULATIONS:
California Proposition 65: N
EUROPEAN REGULATIONS:
EC NUMBER (EINECS): 215-605-7
MGI11120
Page 008 of 008
EC RISK AND SAFETY PHRASES:
R 12
Extremely flammable.
S 2
Keep out of reach of children.
S 9
Keep container in a well-ventilated place.
S 16
Keep away from sources of ignition - No smoking.
S 33
Take precautionary measures against static discharges.
GERMAN REGULATIONS:
WATER HAZARD CLASS (WGK): 0 (Official German Classification)
-----------------------------------------------------------------------------SECTION 16
OTHER INFORMATION
-----------------------------------------------------------------------------COPYRIGHT 1984-1999 MDL INFORMATION SYSTEMS, INC. ALL RIGHTS RESERVED.
THIS MSDS IS SUPPLIED PURSUANT TO OSHA REGULATIONS. OTHER GOVERNMENT
REGULATIONS MUST BE REVIEWED FOR APPLICABILITY TO THIS PRODUCT. WE BELIEVE THE
INFORMATION SOURCE IS RELIABLE AND THE INFORMATION IS ACCURATE AS OF THE DATE
HEREOF, HOWEVER, ACCURACY OR COMPLETENESS IS NOT GUARANTEED AND NO WARRANTY OF
ANY TYPE IS GRANTED. THE INFORMATION RELATES ONLY TO THIS SPECIFIC PRODUCT. IF
COMBINED WITH OTHER MATERIALS, ALL COMPONENT PROPERTIES MUST BE CONSIDERED.
Home | Who We Are | Products & Services | Applications | Locations | Around MG | Product Catalog | Search |
Contact Us
Copyright © 1997 by Messer - MG Industries
5 of 5
CI-N-02
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MATERIAL SAFETY
DATA SHEET
Prepared to U.S. OSHA, CMA, ANSI and Canadian WHMIS Standards
1. PRODUCT AND COMPANY INFORMATION
CHEMICAL NAME; CLASS:
NITROGEN
SYNONYMS: NF Nitrogen, Nitrogen @ 99%+ UHP (Ultra Zero) CEMs
CHEMICAL FAMILY NAME: Inert Gas
FORMULA: N2
NOTE: Nitrogen May Be Supplied By Pipeline At Pressures TO 600 psig.
PRODUCT USE:
MANUFACTURED/SUPPLIED FOR:
ADDRESS:
Document Number: 10070
Medical, Inerting and General Analytical
Or Synthetic Chemical Uses
2700 Post Oak Drive
Houston, TX 77056-8229
CHEMTREC: 1-800-424-9300
EMERGENCY PHONE:
BUSINESS PHONE:
General MSDS Information 1-713/896-2896
Fax on Demand:
1-800/231-1366
NITROGEN - N2 MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 1 OF 7
2. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: Nitrogen is a colorless, odorless gas. The main health hazard associated with
releases of this gas is asphyxiation, by displacement of oxygen.
SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE: The most significant route of over-exposure for
Nitrogen is by inhalation.
INHALATION: High concentrations of this gas can cause an oxygen-deficient environment. Individuals breathing
such an atmosphere may experience symptoms which include headaches, ringing in ears, dizziness, drowsiness,
unconsciousness, nausea, vomiting, and depression of all the senses. Under some circumstances of overexposure, death may occur. The following effects associated with various levels of oxygen are as follows:
CONCENTRATION
SYMPTOM OF EXPOSURE
12-16% Oxygen:
Breathing and pulse rate increased, muscular coordination slightly disturbed.
10-14% Oxygen:
Emotional upset, abnormal fatigue, disturbed respiration.
6-10% Oxygen:
Nausea and vomiting, collapse or loss of consciousness.
Below 6%:
Convulsive movements, possible respiratory collapse, and death.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. Over-exposure to Nitrogen
may cause the following health effects:
ACUTE: The most significant hazard associated with this gas is inhalation of oxygen-deficient atmospheres.
Symptoms of oxygen deficiency include respiratory difficulty, ringing in ears, headaches, shortness of breath,
wheezing, headache, dizziness, indigestion, nausea, and, at high concentrations, unconsciousness or death may
occur. The skin of a victim of over-exposure may have a blue color.
CHRONIC: Chronic exposure to oxygen-deficient atmospheres (below 18% oxygen in air) may affect the heart and
nervous system.
TARGET ORGANS: ACUTE: Respiratory system.
CHRONIC: Heart, central nervous system.
3. COMPOSITION and INFORMATION ON INGREDIENTS
CHEMICAL NAME
CAS #
mole %
EXPOSURE LIMITS IN AIR
ACGIH-TLV
TWA
STEL
ppm
ppm
Nitrogen
7727-37-9
Maximum Impurities
OSHA-PEL
TWA
STEL
ppm
ppm
NIOSH
IDLH
ppm
OTHER
ppm
> 99.99 %
There are no specific exposure limits for Nitrogen. Nitrogen is a simple asphyxiant
(SA). Oxygen levels should be maintained above 19.5%.
< 0.01%
None of the trace impurities in Nitrogen contribute significantly to the hazards
associated with the product. All hazard information pertinent to Nitrogen has been
provided in this Material Safety Data Sheet, per the requirements of the OSHA Hazard
Communication Standard (29 CFR 1910.1200) and State equivalents standards.
This material is classified as hazardous under OSHA regulations in the United States and the WHMIS in
Canada.
NE = Not Established.
See Section 16 for Definitions of Terms Used.
NOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-2004 format. This product has been
classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
NITROGEN - N2 MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 2 OF 7
4. FIRST-AID MEASURES
RESCUERS SHOULD NOT ATTEMPT TO RETRIEVE VICTIMS OF EXPOSURE TO NITROGEN
WITHOUT ADEQUATE PERSONAL PROTECTIVE EQUIPMENT. At a minimum, Self-Contained
Breathing Apparatus Remove victim(s) to fresh air, as quickly as possible. Only trained personnel should
administer supplemental oxygen and/or cardio-pulmonary resuscitation, if necessary. Victim(s) must be taken for
medical attention. Rescuers should be taken for medical attention, if necessary. Take copy of label and MSDS to
physician or other health professional with victim(s).
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing respiratory conditions may be aggravated
by over-exposure to Nitrogen.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and reduce over-exposure.
5. FIRE-FIGHTING MEASURES
FLASH POINT: Not applicable.
AUTOIGNITION TEMPERATURE: Not applicable.
FLAMMABLE LIMITS (in air by volume, %):
Lower (LEL): Not applicable.
Upper (UEL): Not applicable.
FIRE EXTINGUISHING MATERIALS: Non-flammable, inert gas. Use extinguishing media appropriate for
surrounding fire.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Nitrogen does not burn; however, containers, when involved in
fire, may rupture or burst in the heat of the fire.
Explosion Sensitivity to Mechanical Impact: Not Sensitive.
Explosion Sensitivity to Static Discharge: Not Sensitive.
SPECIAL FIRE-FIGHTING PROCEDURES: Structural fire-fighters must wear Self-Contained Breathing Apparatus
and full protective equipment.
6. ACCIDENTAL RELEASE MEASURES
LEAK RESPONSE: Evacuate immediate area. Uncontrolled releases should be responded to by trained personnel
using pre-planned procedures. Proper protective equipment should be used. In case of a leak, clear the affected
area, protect people, and respond with trained personnel. Minimum Personal Protective Equipment should be Level
B: Self-Contained Breathing Apparatus. Locate and seal the source of the leaking gas. Allow the gas, which is
lighter than air to dissipate. Monitor the surrounding area for oxygen. The atmosphere must have at least 19.5
percent oxygen before personnel can be allowed in the area without Self-Contained Breathing Apparatus. If leaking
incidentally from the cylinder or its valve, contact your supplier.
7. HANDLING AND STORAGE
Nitrogen may be supplied by pipeline at pressures up to 600 psig.
WORK PRACTICES AND HYGIENE PRACTICES: Be aware of any signs of dizziness or fatigue; exposures to
fatal concentrations of Nitrogen could occur without any significant warning symptoms, due to oxygen deficiency.
STORAGE AND HANDLING PRACTICES: Cylinders should be stored upright and be firmly secured to prevent
falling or being knocked-over. Cylinders can be stored in the open, but in such cases, should be protected against
extremes of weather and from the dampness of the ground to prevent rusting. Cylinders should be stored in dry,
well-ventilated areas away from sources of heat, ignition and direct sunlight. Keep storage area clear of materials
which can burn. Do not allow area where cylinders are stored to exceed 52°C (125°F). Store containers away from
heavily trafficked areas and emergency exits. Store away from process and production areas, away from elevators,
building and room exits or main aisles leading to exits. Protect cylinders against physical damage.
Use a check valve or other protective device in the discharge line to prevent hazardous backflow. Never tamper with
pressure relief valves and cylinders. Keep the smallest amount necessary on-site at any one time. Full and empty
cylinders should be segregated. Use a first-in, first-out inventory systems to prevent full containers from being stored
for long periods of time.
SPECIAL PRECAUTIONS FOR HANDLING GAS CYLINDERS: Compressed gases can present significant safety
hazards. The following rules are applicable to work situations in which cylinders are being used.
NITROGEN - N2 MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 3 OF 7
7. HANDLING AND STORAGE (Continued)
Before Use: Move cylinders with a suitable hand-truck. Do not drag, slide or roll cylinders. Do not drop cylinders or
permit them to strike each other. Secure cylinders firmly. Leave the valve protection cap (where provided) in-place
until cylinder is ready for use.
During Use: Use designated CGA fittings and other support equipment. Do not use adapters. Do not heat cylinder
by any means to increase the discharge rate of the product from the cylinder. Do not use oils or grease on gashandling fittings or equipment. Immediately contact the supplier if there are any difficulties associated with operating
cylinder valve. Never insert an object (e.g wrench, screwdriver, pry bar, etc.) into valve cap openings. Doing so may
damage valve, causing a leak to occur. Use an adjustable strap wrench to remove over-tight or rusted caps. Never
strike an arc, on a compressed gas cylinder or make a cylinder part of and electric circuit.
After Use: Close main cylinder valve. Replace valve protection cap. Mark empty cylinders “EMPTY”.
NOTE: Use only DOT or ASME code containers designed for gas storage. Close valve after each use and when
empty.
STANDARD VALVE CONNECTIONS FOR U.S. AND CANADA: Use the proper CGA connections, DO NOT
USE ADAPTERS:
THREADED:
0-3000 psig
CGA 580
3001-5500 psig
CGA 680
5501-7500 psig
CGA 677
PIN-INDEXED YOKE:
0-3000 psig
CGA 960 (Medical Use)
ULTRA HIGH INTEGRITY:
0-3000 psig
CGA 718
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices
indicated in Section 6 (Accidental Release Measures). Make certain application equipment is locked and tagged-out
safely. Always use product in areas where adequate ventilation is provided.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation. Local exhaust ventilation is
preferred, because it prevents chemical dispersion into the work place by eliminating it at its source. If appropriate,
install automatic monitoring equipment to detect the level of oxygen.
RESPIRATORY PROTECTION: Maintain oxygen levels above 19.5% in the workplace. Use supplied air
respiratory protection if oxygen levels are below 19.5% or during emergency response to a release of Nitrogen. If
respiratory protection is needed, use only protection authorized in the U.S. Federal OSHA Standard (29 CFR
1910.134), applicable U.S. State regulations, or the Canadian CSA Standard Z94.4-93. Oxygen levels below 19.5%
are considered IDLH by OSHA. In such atmospheres, use of a full-facepiece pressure/demand SCBA or a full
facepiece, supplied air respirator with auxiliary self-contained air supply is required under OSHAs Respiratory
Protection Standard (1910.134-1998).
EYE PROTECTION: Safety glasses. If necessary, refer to U.S. OSHA 29 CFR 1910.133, or Canadian Standards.
HAND PROTECTION: Wear gloves when handling cylinders of Nitrogen. Otherwise, wear glove protection
appropriate to the specific operation for which Nitrogen is used. If necessary, refer to U.S. OSHA 29 CFR 1910.138
or appropriate Standards of Canada.
BODY PROTECTION: Use body protection appropriate for task. Safety shoes are recommended when handling
cylinders. If a hazard of injury to the feet exists due to falling objects, rolling objects, where objects may pierce the
soles of the feet or where employee’s feet may be exposed to electrical hazards, use foot protection, as described in
U.S. OSHA 29 CFR.
9. PHYSICAL and CHEMICAL PROPERTIES
GAS DENSITY @ 0°C (32°F) and 1 atm: .072 lbs/cu ft (1.153 kg/m3)
FREEZING/MELTING POINT @ 10 psig: -210°C (-345.8°F)
BOILING POINT: -195.8°C (-320.4°F)
SPECIFIC GRAVITY (air = 1) @ 21.1°C (70°F): 0.906
pH: Not applicable.
SOLUBILITY IN WATER vol/vol @ 0°C (32°F) and 1 atm: 0.023 MOLECULAR WEIGHT: 28.01
EVAPORATION RATE (nBuAc = 1): Not applicable.
EXPANSION RATIO: Not applicable.
ODOR THRESHOLD: Not applicable. Odorless.
SPECIFIC VOLUME (ft3/lb): 13.8
VAPOR PRESSURE @ (21.1°C) 70°F psig: Not applicable.
COEFFICIENT WATER/OIL DISTRIBUTION: Not applicable.
APPEARANCE AND COLOR: Nitrogen is a colorless, odorless gas.
HOW TO DETECT THIS SUBSTANCE (warning properties): There are no unusual warning properties associated
with a release of Nitrogen.
NITROGEN - N2 MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 4 OF 7
10. STABILITY and REACTIVITY
STABILITY: Normally stable in gaseous state.
DECOMPOSITION PRODUCTS: None.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Titanium is the only element that will burn in
Nitrogen. Lithium reacts slowly with Nitrogen at ambient temperatures.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Contact with incompatible materials. Cylinders exposed to high temperatures or direct
flame can rupture or burst.
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: There are no specific toxicology data for Nitrogen. Nitrogen is a simple asphyxiant, which acts to
displace oxygen in the environment.
SUSPECTED CANCER AGENT: Nitrogen is not found on the following lists: FEDERAL OSHA Z LIST, NTP,
CAL/OSHA, IARC; therefore it is not considered to be, nor suspected to be a cancer-causing agent by these
agencies.
IRRITANCY OF PRODUCT: Not applicable.
SENSITIZATION OF PRODUCT: Nitrogen is not a sensitizer.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects Nitrogen on the
human reproductive system.
Mutagenicity: Nitrogen is not expected to cause mutagenic effects in humans.
Embryotoxicity: Nitrogen is not expected to cause embryotoxic effects in humans.
Teratogenicity: Nitrogen is not expected to cause teratogenic effects in humans.
Reproductive Toxicity: Nitrogen is not expected to cause adverse reproductive effects in humans.
REPRODUCTIVE TOXICITY INFORMATION (continued): A mutagen is a chemical which causes permanent
changes to genetic material (DNA) such that the changes will propagate through generation lines. An embryotoxin
is a chemical which causes damage to a developing embryo (i.e. within the first eight weeks of pregnancy in
humans), but the damage does not propagate across generational lines. A teratogen is a chemical which causes
damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin
is any substance which interferes in any way with the reproductive process.
BIOLOGICAL EXPOSURE
determined for Nitrogen.
INDICES (BEIs):
Currently, Biological Exposure Indices (BEIs) have not been
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL STABILITY: Nitrogen occurs naturally in the atmosphere. The gas will be dissipated rapidly in
well-ventilated areas.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: Any adverse effect on animals would be related to oxygen
deficient environments. No adverse effect is anticipated to occur to plant-life, except for frost produced in the
presence of rapidly expanding gases.
EFFECT OF CHEMICAL ON AQUATIC LIFE: No evidence is currently available on Nitrogen’s effects on aquatic
life.
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate Federal, State,
and local regulations. Return cylinders with any residual product to Air Liquide. Do not dispose of locally. For
emergency disposal, secure the cylinder and slowly discharge the gas to the atmosphere in a well-ventilated area or
outdoors.
NITROGEN - N2 MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 5 OF 7
14. TRANSPORTATION INFORMATION
THIS GAS IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF
TRANSPORTATION.
PROPER SHIPPING NAME:
Nitrogen, compressed
HAZARD CLASS NUMBER and DESCRIPTION:
2.2 (Non-Flammable Gas)
UN IDENTIFICATION NUMBER:
UN 1066
PACKING GROUP:
Not Applicable.
DOT LABEL(S) REQUIRED:
Non-Flammable Gas
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (2000): 121
MARINE POLLUTANT: Nitrogen is not classified by the DOT as a Marine Pollutant (as defined by 49 CFR
172.101, Appendix B).
SPECIAL SHIPPING INFORMATION: Cylinders should be transported in a secure position, in a well-ventilated
vehicle. The transportation of compressed gas cylinders in automobiles or in closed-body vehicles present
serious safety hazards and should be discouraged.
NOTE: Shipment of compressed gas cylinders which have not been filled with the owners consent is a violation of
Federal law (49 CFR, Part 173.301 (b).
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This gas mixture is
considered as Dangerous Goods, per regulations of Transport Canada. The use of the above U.S. DOT
information from the U.S. 49 CFR regulations is allowed for shipments that originate in the U.S. For shipments via
ground vehicle or rail that originate in Canada, the following information is applicable.
PROPER SHIPPING NAME:
Nitrogen, compressed
HAZARD CLASS NUMBER and DESCRIPTION:
2.2 (Compressed Gas)
UN IDENTIFICATION NUMBER:
UN 1066
PACKING GROUP:
Not Applicable
HAZARD LABEL(S) REQUIRED:
Class 2.2 (Compressed Gas)
SPECIAL PROVISIONS:
None
EXPLOSIVE LIMIT & LIMITED QUANTITY INDEX:
0.12
ERAP INDEX:
None
PASSENGER CARRYING SHIP INDEX:
None
PASSENGER CARRYING ROAD OR RAIL VEHICLE INDEX: 75
MARINE POLLUTANT: Not applicable.
15. REGULATORY INFORMATION
ADDITIONAL U.S. REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS: Nitrogen is not subject to the reporting requirements of Sections 302,
304 and 313 of Title III of the Superfund Amendments and Reauthorization Act.
U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for any
component of this product. The default Federal MSDS submission and inventory requirement filing threshold of
10,000 lb (4,540 kg) therefore applies, per 40 CFR 370.20.
U.S. TSCA INVENTORY STATUS: Nitrogen is listed on the TSCA Inventory.
U.S. CERCLA REPORTABLE QUANTITY (RQ): Not applicable.
OTHER U.S. FEDERAL REGULATIONS:
• Generally recognized as safe (GRAS), as a direct human food ingredient when used as a propellant, aerating
agent and gas, per 21, CFR, 184.1540. Nitrogen NF is regulated by the FDA as a prescription drug.
• Depending on specific operations involving the use of Nitrogen, the regulations of the Process Safety
Management of Highly Hazardous Chemicals may be applicable (29 CFR 1910.119). Under this regulation
Nitrogen is not listed in Appendix A.
• Nitrogen does not contain any Class I or Class II ozone depleting chemicals (40 CFR part 82).
• Nitrogen is not listed as a Regulated Substance, per 40 CFR, Part 68, of the Risk Management for Chemical
Releases.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): Nitrogen is not
on the California Proposition 65 lists.
OTHER CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: Nitrogen is listed on the DSL Inventory.
Nitrogen is categorized as a Controlled Product, Hazard Class A as per the Controlled Product Regulations.
NITROGEN - N2 MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 6 OF 7
15. REGULATORY INFORMATION (Continued)
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: Nitrogen is not
on the CEPA Priorities Substances Lists.
CANADIAN WHMIS REGULATIONS: Nitrogen is categorized as a Controlled Product, Hazard Class A, as per the
Controlled Product Regulations.
16. OTHER INFORMATION
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
NFPA RATING
FLAMMABILITY
HEALTH HAZARD
3
(BLUE)
0
HEALTH
0
3
REACTIVITY
FLAMMABILITY HAZARD
PHYSICAL HAZARD
(RED)
0
(YELLOW)
0
OTHER
PROTECTIVE EQUIPMENT
EYES
RESPIRATORY
HANDS
BODY
See Section 8
For Routine Industrial Use and Handling Applications
MIXTURES: When two or more gases or liquefied gases are mixed, their hazardous properties may combine to create
additional, unexpected hazards. Obtain and evaluate the safety information for each component before you produce
the mixture. Consult an Industrial Hygienist or other trained person when you make your safety evaluation of the end
product. Remember, gases and liquids have properties which can cause serious injury or death.
Further information about gas mixtures can be found in the following pamphlets published by: Compressed Gas
Association Inc. (CGA), 4221 Walney Road, 5th Floor, Chantilly, VA 20151-2923 Telephone: (703) 788-2700.
G-10.1
P-1
P-9
P-14
SB-2
AV-1
PREPARED BY:
“Commodity Specification for Nitrogen”
“Safe Handling of Compressed Gases in Containers”
“Inert Gases, Argon, Nitrogen and Helium”
“Accident Prevention in Oxygen-Rich, Oxygen-Deficient Atmospheres”
“Oxygen Deficient Atmospheres”
“Safe Handling and Storage of Compressed Gases”
“Handbook of Compressed Gases”
CHEMICAL SAFETY ASSOCIATES, Inc.
Po Box 3519, La Mesa, CA 91944-3519
619/670-0609
Fax on Demand:
1-800/231-1366
This Material Safety Data Sheet is offered pursuant to OSHA’s Hazard Communication Standard, 29 CFR, 1910.1200. Other government
regulations must be reviewed for applicability to Nitrogen. To the best of Air Liquide’s knowledge, the information contained herein is reliable
and accurate as of this date; however, accuracy, suitability or completeness are not guaranteed and no warranties of any type, either express
or implied, are provided. The information contained herein relates only to this specific product. If Nitrogen is combined with other materials,
all component properties must be considered. Data may be changed from time to time. Be sure to consult the latest edition.
NITROGEN - N2 MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 7 OF 7
MATERIAL SAFETY
DATA SHEET
Prepared to U.S. OSHA, CMA, ANSI and Canadian WHMIS Standards
1. PRODUCT IDENTIFICATION
CHEMICAL NAME; CLASS:
CARBON DIOXIDE
SYNONYMS: Carbon Anhydride; Carbonic Acid Gas; Carbonic Anhydride; Carbon Dioxide USP;
Carbon Dioxide, Refrigerated Liquid; Dry Ice
CHEMICAL FAMILY NAME: Acid Anhydride
FORMULA: CO2
Document Number: 10040
For carbonation, chilling and freezing, medical,
inerting, pH control, fire protection, and
general analytical/synthetic
chemical uses.
PRODUCT USE:
MANUFACTURED/SUPPLIED FOR:
ADDRESS:
9101-LBJ-FREEWAY,SUITE-800
DALLAS,TX-75243
CHEMTREC: 1-800-424-9300
EMERGENCY PHONE:
BUSINESS PHONE:
General MSDS Information 1-972/301-5200
Fax on Demand:
1-800/231-1366
2. COMPOSITION and INFORMATION ON INGREDIENTS
CHEMICAL NAME
CAS #
mole %
EXPOSURE LIMITS IN AIR
ACGIH-TLV
TWA
STEL
ppm
ppm
Carbon Dioxide
124-38-9
> 99.5%
5000
30,000
OSHA-PEL
TWA
STEL
ppm
ppm
NIOSH
IDLH
ppm
5000
40,000
< 0.5%
ppm
NIOSH REL:
TWA = 5000
STEL = 30,000 (ceiling)
DFG-MAK:
TWA = 5000
PEAK = 2•MAK, 60 min.
momentary value
None of the trace impurities in this product contribute significantly to the hazards associated
with the product. All pertinent hazard information has been provided in this document, per the
requirements of the Federal Occupational Safety and Health Administration Standard (29
CFR 1910.1200), U.S. State equivalent Standards and Canadian Workplace Hazardous
Materials Identification System Standards (CPR 4).
10,000
(Vacated
1989 PEL)
Maximum Impurities
30,000
(Vacated
1989 PEL)
OTHER
NE = Not Established.
See Section 16 for Definitions of Terms Used.
NOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been
classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
CARBON DIOXIDE - CO2 MSDS
EFFECTIVE DATE: JANUARY 1, 2005
PAGE 1 OF 9
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: Carbon Dioxide is a colorless, odorless gas, or a colorless, odorless liquid in a highpressure container. Over-exposure to Carbon Dioxide can increase respiration and heart rate, possibly resulting
in circulatory insufficiency, which may lead to coma and death. At concentrations between 2 and 10%, Carbon
Dioxide can cause nausea, dizziness, headache, mental confusion, increased blood pressure and respiratory
rate. Exposure to Carbon Dioxide can also cause asphyxiation, through displacement of oxygen. If the gas
concentration reaches 10% or more, suffocation can occur within minutes. The liquid will rapidly boil to the gas at
standard temperatures and pressures. Contact with the cold gas can cause freezing of exposed tissue.
Moisture in the air could lead to the formation of carbonic acid which can be irritating to the eyes. All forms of
Carbon Dioxide are non-combustible.
CARBON DIOXIDE, LIQUEFIED
CARBON DIOXIDE GAS
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
HEALTH
1
HEALTH
(RED)
0
FLAMMABILITY
(YELLOW)
0
REACTIVITY
(BLUE)
FLAMMABILITY
REACTIVITY
PROTECTIVE EQUIPMENT
EYES
RESPIRATORY
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
HANDS
See
Section 8
B
3
(BLUE)
(RED)
0
(YELLOW)
0
PROTECTIVE EQUIPMENT
BODY
EYES
See
Section 8
RESPIRATORY
HANDS
See
Section 8
For routine industrial applications
X
BODY
See
Section 8
For routine industrial applications
SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE: The most significant routes of over-exposure for
this gas are by inhalation, and skin or eye contact. Symptoms of such exposure are as follows:
INHALATION: Carbon Dioxide is an asphyxiant and a powerful cerebral vasodilator. If the concentration of Carbon
Dioxide reaches 10% or more, suffocation can occur within minutes. At concentrations between 2 and 10%, Carbon
Dioxide can cause nausea, dizziness, headache, mental confusion, increased blood pressure and respiratory rate.
Carbon Dioxide initially stimulates respiration and then causes respiratory depression. High concentrations result
in narcosis. Repeated inhalation of low concentrations (3-5%) have no known permanent harmful effects.
Symptoms in humans are as follows:
CONCENTRATION
EFFECT
1%
Slight increase in breathing rate.
2%
Breathing rate increases to 50% above normal level. Prolonged exposure can cause
headache, tiredness.
3%
Breathing increases to twice normal rate and becomes labored. Weak narcotic effect.
Impaired hearing, headache, increase in blood pressure and pulse rate.
4-5%
Breathing increases to approximately four times normal rate, symptoms of intoxication
become evident and slight choking may be felt.
5-10%
Characteristic sharp odor noticeable.
Very labored breathing, headache, visual
impairment and ringing in the ears. Judgment may be impaired, followed within minutes
by loss of consciousness.
50-100%
Unconsciousness occurs more rapidly above 10% level. Prolonged exposure to high
concentrations may eventually result in death from asphyxiation.
High concentrations of this gas can also cause an oxygen-deficient environment. However, the asphyxiating
properties of Carbon Dioxide will be reached before oxygen-deficiency is a factor.
CARBON DIOXIDE - CO2 MSDS
EFFECTIVE DATE: JANUARY 1, 2005
PAGE 2 OF 9
3. HAZARD IDENTIFICATION (Continued)
CONTACT WITH SKIN or EYES: Contact of the cold gas with the skin can lead to frostbite or dermatitis (red,
cracked, irritated skin), depending upon concentration and duration of exposure. Contact of the cold gas, or solid dry
ice with the eyes can cause pain, redness, burns, and severe exposure could cause blindness.
OTHER POTENTIAL HEALTH EFFECTS: Symptoms of frostbite include change in skin color to white or grayishyellow. The pain after contact with cold gas can quickly subside. Moisture in the air could lead to the formation of
carbonic acid, which can be irritating to the eyes.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. Over-exposure to Carbon
Dioxide may cause the following health effects:
ACUTE: Carbon Dioxide is an asphyxiant and a powerful cerebral vasodilator. Inhaling large quantities causes
rapid circulatory insufficiency, which can lead to coma or death. At low concentrations, inhalation of Carbon Dioxide
can cause nausea, dizziness, visual disturbances, shaking, headache, mental confusion, sweating, increased
heartbeat, and elevated blood pressure and respiratory rate. High concentrations of the gas in air may cause eye
irritation. Contact with the eyes can cause damage to the retinal ganglion cells.
CHRONIC: There are currently no known adverse health effects associated with chronic exposure to this gas.
TARGET ORGANS: ACUTE: Respiratory system, central nervous system, eyes. CHRONIC: None known.
4. FIRST-AID MEASURES
RESCUERS SHOULD NOT ATTEMPT TO RETRIEVE VICTIMS OF EXPOSURE TO THIS PRODUCT
WITHOUT ADEQUATE PERSONAL PROTECTIVE EQUIPMENT. At a minimum, Self-Contained
Breathing Apparatus equipment should be worn.
Remove victim(s) to fresh air, as quickly as possible. Trained personnel should administer supplemental oxygen
and/or cardio-pulmonary resuscitation, if necessary. Victim(s) must be taken for medical attention. Rescuers should
be taken for medical attention, if necessary. Take copy of label and MSDS to physician or other health professional
with victim(s).
SKIN EXPOSURE: Remove any clothing that may restrict circulation to any frozen area. Do not rub frozen parts as
tissue damage may occur. As soon as practicable, place any affected area in warm water bath which has a
temperature that does not exceed 105°F (40°C). NEVER USE HOT WATER. NEVER USE DRY HEAT. If area of
frostbite is extensive, remove clothing while showering with warm water. If warm water is not available, or is
impractical to use, wrap the affected parts gently in blankets. Alternatively, if the fingers or hands are frostbitten,
place the affected area of the body in the armpit. Encourage victim to gently exercise the affected part while being
warmed. Seek immediate medical attention.
Frozen tissue is painless and appears waxy, with a possible yellow color. Frozen tissue will become swollen, painful
and prone to infection when thawed. If the frozen part of the body has been thawed by the time medical attention
has been obtained, cover the area with a dry sterile dressing and a large bulky protective covering.
EYE EXPOSURE: If irritation of the eye develops after exposure to gas, open victim's eyes while under gentle
running water. Use sufficient force to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes.
Seek medical assistance immediately, preferably an ophthalmologist.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing respiratory conditions may be aggravated
by over-exposure to this product.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and reduce over-exposure.
5. FIRE-FIGHTING MEASURES
FLASH POINT: Not applicable.
AUTOIGNITION TEMPERATURE: Not applicable.
FLAMMABLE LIMITS (in air by volume, %):
Lower (LEL): Not applicable.
Upper (UEL): Not applicable.
FIRE EXTINGUISHING MATERIALS: Carbon Dioxide is commonly used as an extinguishing agent for Class B and
Class C fires. Use extinguishing media appropriate for the surrounding fire.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Carbon Dioxide does not burn; however, containers, when
involved in fire, may rupture or burst in the heat of the fire. Dusts of various reactive metals (e.g., magnesium,
zircon, titanium alloys), are readily ignited and explode in the presence of Carbon Dioxide. In the presence of
moisture, cesium oxide ignites on contact with Carbon Dioxide. Metal acetylides or hydrides will also ignite or
explode. (continued on following page)
CARBON DIOXIDE - CO2 MSDS
EFFECTIVE DATE: JANUARY 1, 2005
PAGE 3 OF 9
5. FIRE-FIGHTING MEASURES (Continued)
HEALTH
CARBON DIOXIDE
GAS
CARBON DIOXIDE
LIQUEFIED
NFPA RATING
NFPA RATING
FLAMMABILITY
FLAMMABILITY
0
0
0
1
HEALTH
REACTIVITY
0
3
REACTIVITY
OTHER
OTHER
UNUSUAL FIRE AND EXPLOSION HAZARDS (continued): Liquid
Carbon Dioxide will vaporize rapidly when accidentally released, forming an oxygen-deficient vapor cloud.
Additionally, if large concentrations of Carbon Dioxide gas are present, the water vapor in the surrounding air will
condense, creating a dense fog . Evacuate the surrounding area; visibility may be obscured in such a vapor cloud
making it difficult to find fire exits or equipment. Pressure in a high pressure container can build-up due to heat and it
may rupture if pressure relief devices should fail to function. Contact with cold, gaseous or solid Carbon Dioxide may
cause frostbite.
Explosion Sensitivity to Mechanical Impact: Not sensitive.
Explosion Sensitivity to Static Discharge: Not sensitive.
SPECIAL FIRE-FIGHTING PROCEDURES: Structural fire-fighters must wear Self-Contained Breathing Apparatus
and full protective equipment.
6. ACCIDENTAL RELEASE MEASURES
LEAK RESPONSE: Evacuate immediate area. Uncontrolled releases should be responded to by trained personnel
using pre-planned procedures. Proper protective equipment should be used. In case of a leak, clear the affected
area, protect people, and respond with trained personnel.
Minimum Personal Protective Equipment should be Level B: protective clothing, leather or thermally insulating
gloves and Self-Contained Breathing Apparatus. Locate and seal the source of the leaking gas. Allow the gas to
dissipate. Monitor the surrounding area for Carbon Dioxide and oxygen levels. The level of Carbon Dioxide must be
below 3%, and the atmosphere must have at least 19.5 percent oxygen before personnel can be allowed in the area
without Self-Contained Breathing Apparatus.
RESPONSE TO PRESSURIZED-LIQUID RELEASE: Clear the affected area. After the gas is formed, follow the
instructions provided above. If the area must be entered by emergency personnel, SCBA, leather or insulated
gloves, an safety shoes must be worn.
7. HANDLING and USE
WORK PRACTICES AND HYGIENE PRACTICES: Be aware of any signs of dizziness or fatigue; exposures to
fatal concentrations of this product could occur without any significant warning symptoms.
STORAGE AND HANDLING PRACTICES: Cylinders should be stored upright and be firmly secured to prevent
falling or being knocked-over. Cylinders can be stored in the open, but in such cases, should be protected against
extremes of weather and from the dampness of the ground to prevent rusting. Cylinders should be stored in dry,
well-ventilated areas away from sources of heat, ignition and direct sunlight. Keep storage area clear of materials
which can burn. Do not allow area where cylinders are stored to exceed 52°C (125°F). Store containers away from
heavily trafficked areas and emergency exits. Store away from process and production areas, away from elevators,
building and room exits or main aisles leading to exits. Protect cylinders against physical damage. Isolate from
other non-compatible chemicals (refer to Section 10, Stability and Reactivity).
Storage containers and equipment should not be located in sub-surface or enclosed areas, unless engineered to
maintain a concentration of Carbon Dioxide below the TLV (TLV = 5000 ppm) in the event of a release. Relief
valves should be vented to a well-ventilated external location. Consider installation of leak detection and alarm
for storage and use areas. Have appropriate extinguishing equipment in the storage area ( i.e. sprinkler system,
portable fire extinguishers).
Use a check valve in the discharge line to prevent hazardous backflow. Never tamper with pressure relief valves
and cylinders. (continued on following page)
CARBON DIOXIDE - CO2 MSDS
EFFECTIVE DATE: JANUARY 1, 2005
PAGE 4 OF 9
7. HANDLING and USE (Continued)
STORAGE AND HANDLING PRACTICES (continued): Full and empty cylinders should be segregated. Use a
first-in, first-out inventory systems to prevent full containers from being stored for long periods of time.
SPECIAL PRECAUTIONS FOR HANDLING GAS CYLINDERS: Compressed gases can present significant safety
hazards. The following rules are applicable to work situations in which cylinders are being used.
Before Use: Move cylinders with a suitable hand-truck. Do not drag, slide or roll cylinders. Do not drop cylinders or
permit them to strike each other. Secure cylinders firmly. Leave the valve protection cap (where provided) in-place
until cylinder is ready for use.
During Use: Use designated CGA fittings and other support equipment. Do not use adapters. Do not heat cylinder
by any means to increase the discharge rate of the product from the cylinder. Do not use oils or grease on gashandling fittings or equipment. Leak-check system with leak detection solution. Immediately contact the supplier if
there are any difficulties associated with operating cylinder valve. Never insert an object (e.g., wrench, screwdriver,
pry bar, etc.) into valve cap openings. Doing so may damage the valve, causing a leak to occur. Use an adjustable
strap wrench to remove over-tight or rusted caps. Never strike an arc, on a compressed gas cylinder or make a
cylinder part of and electric circuit.
After Use: Close main cylinder valve. Replace valve protection cap. Mark empty cylinders “EMPTY”.
SPECIAL PRECAUTIONS FOR HANDLING PRESSURIZED CONTAINERS OF LIQUID CARBON DIOXIDE:
Cold liquids can present significant safety hazards. Never allow any unprotected part of the body to touch
uninsulated pipes or vessels which contain cold fluids. The extremely cold metal of the container will cause moist
flesh to stick fast and tear when one attempts to withdraw from it. The following rules are applicable to work
situations in which liquid containers are being used.
Check all hoses and transfer equipment before filing them with the liquid. Replace any worn or cut hoses prior to
use. Liquid Carbon Dioxide is extremely cold and is under pressure. A leak will result in the formation of “Dry Ice”
particles which will be forcibly ejected from the system, possibly injuring the operator. A complete hose failure can
result in a large release of Carbon Dioxide and violent movement of the hose and associated equipment, which may
cause severe injury or death. Special care must be taken when depressurizing and disconnecting hoses. Releasing
the contents of a liquid-filled line to atmospheric pressure may result in the formation of a solid dry ice plug in the line.
This plug will prevent further removal of the liquid behind the plug, resulting in either an unexpected, rapid release of
Carbon Dioxide as the line warms, or the catastrophic failure of the line as the liquid warms behind the plug.
Sufficient vapor pressure must be applied and maintained behind the liquid before opening a discharge valve. This
action will prevent the depressurization of the liquid to the point of solid formation before it exits the line.
High-pressure containers for liquid product are equipped with pressure relief devices to control internal pressure.
Under normal conditions, these containers will periodically vent small amounts of product. Some metals such as
carbon steel may become brittle at low temperatures and will easily fracture. Prevent entrapment of liquid in closed
systems or piping without pressure relief devices.
NOTE: Use only DOT or ASME-approved code containers. Close valve after each use and when empty.
STANDARD CYLINDER VALVE CONNECTIONS FOR U.S. AND CANADA: Use the proper CGA connections,
DO NOT USE ADAPTERS:
THREADED:
CGA 320
PIN-INDEXED YOKE:
CGA 940 (Medical Use)
ULTRA HIGH INTEGRITY:
716
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices
indicated in Section 6 (Accidental Release Measures). Make certain application equipment is locked and tagged-out
safely. Purge gas handling equipment with inert gas (i.e. nitrogen) before attempting repairs. Always use product in
areas where adequate ventilation is provided.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation. Carbon Dioxide accumulates in
low-lying areas with limited air movement. Natural or mechanical ventilation should be available in the worker’s
breathing zone to prevent levels of Carbon Dioxide above exposure limits (see Section 2, Composition and
Information on Ingredients). Local exhaust ventilation is preferred, because it prevents dispersion of this gas into the
work place by eliminating it at its source. Areas of Carbon Dioxide use should be engineered to remove vapor from
the lowest possible level and exhaust vapor to a well-ventilated area or to the outside. Carbon Dioxide levels should
be monitored to assure levels are maintained below the TLV. If appropriate, install automatic monitoring equipment
to detect the levels of Carbon Dioxide and of oxygen.
CARBON DIOXIDE - CO2 MSDS
EFFECTIVE DATE: JANUARY 1, 2005
PAGE 5 OF 9
8. EXPOSURE CONTROLS - PERSONAL PROTECTION (Continued)
RESPIRATORY PROTECTION: Maintain Carbon Dioxide levels below those listed in Section 2 (Composition and
Information on Ingredients) and oxygen levels above 19.5% in the workplace. Use supplied air respiratory protection
if Carbon Dioxide levels are above the IDLH (40,000 ppm) or during emergency response to a release of this
product. If respiratory protection is needed, use only protection authorized in the U.S. Federal OSHA Standard (29
CFR 1910.134), applicable U.S. State regulations, or the Canadian CSA Standard Z94.4-93. Oxygen levels below
19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-facepiece pressure/demand SCBA or a
full facepiece, supplied air respirator with auxiliary self-contained air supply is required under OSHAs Respiratory
Protection Standard (1910.134-1998). Respiratory selection guidelines from NIOSH for Carbon Dioxide are provided
below for information.
RESPIRATORY EQUIPMENT
CONCENTRATION
Up to 40,000 ppm:
Supplied Air Respirator (SAR); or full-facepiece Self-Contained Breathing Apparatus
(SCBA).
Emergency or Planned Entry Into Unknown Concentrations or IDLH Conditions: Positive pressure, full-facepiece
SCBA; or positive pressure, full-facepiece SAR with an auxiliary positive pressure SCBA.
Escape:
Escape-type SCBA.
NOTE:
The IDLH concentration for Carbon Dioxide is 40,000 ppm.
EYE PROTECTION: Safety glasses. Use faceshields when handling Liquid Carbon Dioxide in high pressure
containers. If necessary, refer to U.S. OSHA 29 CFR 1910.133, or Canadian Standards.
HAND PROTECTION: Wear leather or thermally insulated gloves when handling cylinders of this product.
Otherwise, wear glove protection appropriate to the specific operation for which this product is used. If necessary,
refer to U.S. OSHA 29 CFR 1910.138 or appropriate Standards of Canada.
BODY PROTECTION: Use body protection appropriate for task. Safety shoes are recommended when handling
cylinders. When handling the liquid in high pressure containers, long sleeve shirts and trousers are recommended.
If a hazard of injury to the feet exists due to falling objects, rolling objects, where objects may pierce the soles of the
feet or where employee’s feet may be exposed to electrical hazards, use foot protection, as described in U.S. OSHA
29 CFR.
HEARING PROTECTION: Discharges of Liquid Carbon Dioxide and of the vapor can produce noise levels requiring
hearing protection.
9. PHYSICAL and CHEMICAL PROPERTIES
GAS DENSITY @ 21.1°C (70°F) and 1 atm: 0.1144 lb/ft3 (1.833 kg/m3)
LIQUID DENSITY @ 21.1°C (70°F) and 838 psig (5778 kPa): 47.35 lb/ft3 (761.3 kg/m3)
FREEZING/MELTING POINT: (sublimation temperature) -78.5°C (-109.3°F)
TRIPLE POINT: -55.6°C (-69.9°F) @ 60.4 psig (416 kPa)
pH: 3.7 at 1 atm (form carbonic acid)
SPECIFIC GRAVITY (air = 1) @ 70°F (21.1°C): 1.522
MOLECULAR WEIGHT: 44.01
ODOR THRESHOLD: Odorless.
EXPANSION RATIO: Not applicable.
EVAPORATION RATE (nBuAc = 1): Not applicable.
SPECIFIC VOLUME (ft3/lb): 8.76
VAPOR PRESSURE @ 21.1°C (70°F) psig: 838 psig (5778 kPa) SUBLIMATION POINT: -78.5°C (-109.3°F)
SOLUBILITY IN WATER vol/vol 20°C (68°F) and 1 atm: 0.90
COEFFICIENT WATER/OIL DISTRIBUTION: Not applicable.
APPEARANCE AND COLOR: This product is a colorless, odorless gas, or colorless, odorless, volatile liquid stored
under high pressure. As this gas is slightly acidic, some individuals may notice a slightly pungent odor and biting
taste.
HOW TO DETECT THIS SUBSTANCE (warning properties): There are no unusual warning properties associated
with a release of this product, except the potential of a vapor cloud in the event of a large release.
10. STABILITY and REACTIVITY
STABILITY: Normally stable.
DECOMPOSITION PRODUCTS: Carbon Dioxide will produce Carbon Monoxide and Oxygen when heated to
temperatures above 3000°F (1648°C).
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Carbon Dioxide will ignite and explode when
heated with powdered aluminum, beryllium, cerium alloys, chromium, magnesium-aluminum alloys, manganese,
thorium, titanium, and zirconium. In the presence of moisture, Carbon Dioxide will ignite with cesium oxide. Metal
acetylides will also ignite and explode on contact with Carbon Dioxide. Carbon Dioxide will react with alkaline
materials to form carbonates and bicarbonates.
HAZARDOUS POLYMERIZATION: Will not occur.
CARBON DIOXIDE - CO2 MSDS
EFFECTIVE DATE: JANUARY 1, 2005
PAGE 6 OF 9
10. STABILITY and REACTIVITY (Continued)
CONDITIONS TO AVOID: Avoid exposing cylinders or bulk storage containers of Carbon Dioxide to extremely high
temperatures, which could cause the cylinders or storage containers to rupture or burst.
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: Carbon Dioxide gas is an asphyxiant gas, which has physiological effects at high concentrations.
High concentrations can also result in narcosis. The following toxicological information is available for Carbon
Dioxide.
LCLo (Inhalation-Human) 9 pph/5 minutes
LCLo
(Inhalation-Mammal-species
unspecified) 90000 ppm/5 minutes
TCLo
(Inhalation-Rat)
10000
ppm/24
hours/days-continuous:
Blood:
other
changes
TCLo (Inhalation-Rat) 6 pph/24 hours: female
10 day(s) after conception: Reproductive:
Specific Developmental Abnormalities:
musculoskeletal system, cardiovascular
(circulatory) system, respiratory system
TCLo (Inhalation-Rabbit) 27,000 ppm/24
hours/30 days-continuous : Behavioral:
somnolence (general depressed activity)
TCLo (Inhalation-Rat) 6 pph/24 hours: female
10 day(s) after conception: Reproductive:
Effects on Newborn: growth statistics
(e.g.%, reduced weight gain)
TCLo (Inhalation-Rabbit) 13 pph/4 hours:
female 9-12 day(s) after conception:
Reproductive: Specific Developmental
Abnormalities: musculoskeletal system
TCLo (Inhalation-Mouse) 55 pph/2 hours:
male 3 day(s) pre-mating: Reproductive:
Paternal Effects: spermatogenesis (incl.
genetic material, sperm morphology,
motility, and count)
TCLo (Inhalation-Mouse) 55 pph/4 hours:
male 6 day(s) pre-mating: Reproductive:
Fertility: male fertility index (e.g. # males
impregnating females per # males
exposed to fertile nonpregnant females)
TCLo (Inhalation-Mouse) 2 pph/8 hours:
female 10 day(s) after conception:
Reproductive: Fertility: post-implantation
mortality (e.g. dead and/or resorbed
implants per total number of implants);
Specific Developmental Abnormalities:
musculoskeletal system
SUSPECTED CANCER AGENT: Carbon Dioxide is not found on the following lists: FEDERAL OSHA Z LIST, NTP,
CAL/OSHA, IARC, and therefore is not considered to be, nor suspected to be a cancer-causing agent by these
agencies.
IRRITANCY OF PRODUCT: Contact with rapidly expanding gases can cause frostbite and damage to exposed skin
and eyes.
SENSITIZATION OF PRODUCT: Carbon Dioxide is not a skin or respiratory sensitizer.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of Carbon Dioxide
on the human reproductive system.
Mutagenicity: This product is not expected to cause mutagenic effects in humans.
Embryotoxcity: This product has not been reported to cause embryotoxic effects.
Teratogenicity: This product is not expected to cause teratogenic effects in humans. Clinical studies involving test
animals exposed to high concentrations of Carbon Dioxide indicate teratogenic effects.
Reproductive Toxicity: This product is not expected to cause adverse reproductive effects in humans. Clinical
studies involving test animals exposed to high concentrations of Carbon Dioxide indicate reproductive effects.
A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will
propagate through generation lines. An embryotoxin is a chemical which causes damage to a developing embryo
(i.e. within the first eight weeks of pregnancy in humans), but the damage does not propagate across generational
lines. A teratogen is a chemical which causes damage to a developing fetus, but the damage does not propagate
across generational lines. A reproductive toxin is any substance which interferes in any way with the reproductive
process.
BIOLOGICAL EXPOSURE INDICES (BEIs): Currently, Biological Exposure Indices (BEIs) have not been
determined for this compound.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL STABILITY: Carbon Dioxide occurs naturally in the atmosphere. The gas will be dissipated
rapidly in well-ventilated areas.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: No adverse effect is anticipated to occur to animal or plantlife, except for frost produced in the presence of rapidly expanding gases.
EFFECT OF CHEMICAL ON AQUATIC LIFE: No evidence is currently available on this product’s effects on aquatic
life.
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate Federal, State,
and local regulations. Return cylinders with any residual product to Air Liquide. Do not dispose of locally.
For emergency disposal, secure the cylinder and slowly discharge the gas to the atmosphere in a well-ventilated
area or outdoors.
CARBON DIOXIDE - CO2 MSDS
EFFECTIVE DATE: JANUARY 1, 2005
PAGE 7 OF 9
14. TRANSPORTATION INFORMATION
THIS MATERIAL IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF
TRANSPORTATION.
FOR GAS
FOR LIQUID
PROPER SHIPPING NAME:
Carbon dioxide
Carbon Dioxide, refrigerated
liquid
HAZARD CLASS NUMBER and DESCRIPTION: 2.2 (Non-Flammable Gas) 2.2 (Non-Flammable Gas)
UN IDENTIFICATION NUMBER:
UN 1013
UN 2187
PACKING GROUP:
Not applicable.
Not applicable.
DOT LABEL(S) REQUIRED:
Non-Flammable Gas
Non-Flammable Gas
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (20006): 120
MARINE POLLUTANT: Carbon Dioxide is not classified by the DOT as a Marine Pollutant (as defined by 49 CFR
172.101, Appendix B).
SPECIAL SHIPPING INFORMATION: Cylinders should be transported in a secure position, in a well-ventilated
vehicle. The transportation of compressed gas cylinders in automobiles or in closed-body vehicles present serious
safety hazards and should be discouraged.
NOTE: Shipment of compressed gas cylinders which have not been filled with the owners consent is a violation of
Federal law (49 CFR, Part 173.301 (b).
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This material is
considered as dangerous goods, per regulations of Transport Canada. Use the above U.S. DOT information for
the preparation of Canadian Shipments.
15. REGULATORY INFORMATION
ADDITIONAL U.S. REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS: Carbon Dioxide is not subject to the reporting requirements of
Sections 302, 304 and 313 of Title III of the Superfund Amendments and Reauthorization Act.
U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for any
component of this product. The default Federal MSDS submission and inventory requirement filing threshold of
10,000 lb (4,540 kg) therefore applies, per 40 CFR 370.20.
U.S. TSCA INVENTORY STATUS: Carbon Dioxide is listed on the TSCA Inventory.
U.S. CERCLA REPORTABLE QUANTITY (RQ): Not applicable.
OTHER U.S. FEDERAL REGULATIONS:
• Generally recognized as safe (GRAS) as a direct human food ingredient when used as a leavening agent,
processing aid, propellant, aerating agent and gas.
• Carbon Dioxide USP is regulated by the FDA as a prescription drug.
• Carbon Dioxide is subject to the reporting requirements of CFR 29 1910.1000. Carbon Dioxide is listed on Table
Z.1.
• Depending on specific operations involving the use of this product, the regulations of the Process Safety
Management of Highly Hazardous Chemicals may be applicable (29 CFR 1910.119). Under this regulation
Carbon Dioxide is not listed in Appendix A.
• Carbon Dioxide does not contain any Class I or Class II ozone depleting chemicals (40 CFR part 82).
• Carbon Dioxide is not listed as a Regulated Substance, per 40 CFR, Part 68, of the Risk Management for
Chemical.
U.S. STATE REGULATORY INFORMATION: Carbon Dioxide is covered under the following specific State
regulations:
Alaska - Designated Toxic and Hazardous
Substances: Carbon Dioxide.
California - Permissible Exposure Limits
for Chemical Contaminants: Carbon
Dioxide.
Florida - Substance List: Carbon Dioxide.
Illinois - Toxic Substance List: Carbon
Dioxide.
Kansas - Section 302/313 List: No.
Massachusetts - Substance List: Carbon
Dioxide.
Michigan - Critical Materials List: No.
Minnesota - List of Hazardous Substances:
Carbon Dioxide.
Missouri - Employer Information/Toxic
Substance List: Carbon Dioxide.
New Jersey - Right to Know Hazardous
Substance List: Carbon Dioxide.
North Dakota - List of Hazardous
Chemicals, Reportable Quantities: No.
Pennsylvania - Hazardous Substance List:
Carbon Dioxide.
Rhode Island - Hazardous Substance List:
Carbon Dioxide.
Texas - Hazardous Substance List: No.
West Virginia - Hazardous Substance List:
Carbon Dioxide.
Wisconsin - Toxic and Hazardous
Substances: Carbon Dioxide.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65):
Dioxide is not on the California Proposition 65 lists.
CARBON DIOXIDE - CO2 MSDS
EFFECTIVE DATE: JANUARY 1, 2005
PAGE 8 OF 9
Carbon
15. REGULATORY INFORMATION (Continued)
OTHER CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: Carbon Dioxide is listed on the DSL Inventory.
CANADIAN WHMIS REGULATIONS: Carbon Dioxide is categorized as a Controlled Product, Hazard Class A as
per the Controlled Product Regulations.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: Carbon Dioxide
is not on the CEPA Priorities Substances Lists.
16. OTHER INFORMATION
MIXTURES: When two or more gases or liquefied gases are mixed, their hazardous properties may combine to
create additional, unexpected hazards. Obtain and evaluate the safety information for each component before
you produce the mixture. Consult an Industrial Hygienist or other trained person when you make your safety
evaluation of the end product. Remember, gases and liquids have properties which can cause serious injury or
death.
Further information about Carbon Dioxide can be found in the following pamphlets published by: Compressed
Gas Association Inc. (CGA), 4221 Walney Road 5th floor, Chantilly, VA 20151-2923. Telephone: (703) 788-2700.
G-6
G-6.1
G-6.2
G-6.3
G-6.5
G-6.6
P-1
P-7
P-14
SB-2
AV-1
AV-7
“Carbon Dioxide”
“Standard for Low Pressure Carbon Dioxide Systems at Customer Sites”
“Commodity Specification for Carbon Dioxide “
“Carbon Dioxide Cylinder Filling and Handling Procedures”
“Standard for Small Stationary Carbon Dioxide Systems
“Standard for Elastomer-Type Bulk Transfer Hose
“Safe Handling of Compressed Gases in Containers”
“Standard for the Re-Qualification of Cargo Tank Hose
“Accident Prevention in Oxygen-Rich and Oxygen Deficient Atmospheres”
“Oxygen Deficient Atmospheres”
“Safe Handling and Storage of Compressed Gases”
“Characteristics and Safe Handling of Carbon Dioxide”
PREPARED BY:
CHEMICAL SAFETY ASSOCIATES, Inc.
PO Box 3519, La Mesa, CA 91944-3519
619/670-0609
Fax on Demand:
1-800/231-1366
This Material Safety Data Sheet is offered pursuant to OSHA’s Hazard Communication Standard, 29 CFR, 1910.1200. Other government
regulations must be reviewed for applicability to this product. To the best of Air Liquide’s knowledge, the information contained herein is
reliable and accurate as of this date; however, accuracy, suitability or completeness are not guaranteed and no warranties of any type, either
express or implied, are provided. The information contained herein relates only to this specific product. If this product is combined with other
materials, all component properties must be considered. Data may be changed from time to time. Be sure to consult the latest edition.
CARBON DIOXIDE - CO2 MSDS
EFFECTIVE DATE: JANUARY 1, 2005
PAGE 9 OF 9
MATERIAL SAFETY
DATA SHEET
Prepared to U.S. OSHA, CMA, ANSI and Canadian WHMIS Standards
1. PRODUCT AND COMPANY INFORMATION
CHEMICAL NAME; CLASS:
CARBON MONOXIDE
SYNONYMS: Carbonic Oxide; Carbon Oxide.
CHEMICAL FAMILY NAME: Non-Metal Oxide Gas
FORMULA: CO
Document Number: 20022
For general analytical/synthetic chemical uses.
PRODUCT USE:
MANUFACTURED/SUPPLIED FOR:
ADDRESS:
EMERGENCY PHONE:
2700 Post Oak Drive
Houston, TX 77056-8229
CHEMTREC: 1-800-424-9300
BUSINESS PHONE:
General MSDS Information:1-713/896-2896
Fax on Demand:
1-800/231-1366
CARBON MONOXIDE - CO MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 1 OF 9
2. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: Carbon Monoxide is a colorless, odorless, poisonous and flammable gas. Carbon
Monoxide is an extremely flammable, poison gas. Carbon Monoxide is a chemical asphyxiant and may be fatal if
inhaled. Exposure to Carbon Monoxide can cause nausea, dizziness, headaches, and collapse. Carbon
Monoxide poses a serious fire hazard when it is accidentally released. Flame or high temperature impinging on a
localized area of the cylinder of Carbon Monoxide can cause the cylinder to explode without activating the
cylinder’s relief devices. Provide adequate fire protection during emergency response situations.
SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE: The most significant route of over-exposure for
Carbon Monoxide is by inhalation.
INHALATION: Carbon monoxide is classified as a chemical asphyxiant, producing a toxic action by combining with
the hemoglobin of the blood and replacing the available oxygen. Through this replacement, the body is deprived of
the required oxygen, and asphyxiation occurs.
Since the affinity of carbon monoxide for hemoglobin is about 200-300 times that of oxygen, only a small amount of
Carbon Monoxide will cause a toxic reaction to occur. Carbon Monoxide exposures in excess of 50 ppm will
produce symptoms of poisoning if breathed for a sufficiently long time. Other effects of exposure can be
summarized as follows:
CONCENTRATION OF GAS
OBSERVED EFFECT
All exposure levels:
Over-exposure to Carbon Monoxide can be indicated by the lips and fingernails
turning bright red.
Slight symptoms (headache, discomfort) after several hours of exposure.
Headache and discomfort experienced within 2-3 hours of exposure.
200 ppm:
400 ppm:
1,000 -2000 ppm:
Within 30 minutes, slight palpitations of the heart occur. Within 1.5 hours, there is a
tendency to stagger. Within 2 hours, there is mental confusion, headache, and
nausea.
2000-2500 ppm:
Unconsciousness within 30 minutes.
>2500 ppm:
Potential for collapse and death before warning symptoms are produced.
NOTE: At high altitudes, individuals may be more susceptible to Carbon Monoxide over-exposures. Development of
symptoms may also occur more rapidly if individuals are doing physically demanding tasks. Individuals who have
heart conditions may experience a more rapid onset of symptoms. During recovery, victims can experience
headaches, vision problems, and memory loss.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. Over-exposure to Carbon
Monoxide may cause the following health effects:
ACUTE: Carbon Monoxide is a toxic gas. Symptoms of Carbon Monoxide poisoning can develop gradually, or can
arise suddenly, depending on the concentration and duration of exposure. Lips and fingernails will turn bright red,
which is a significant sign of Carbon Monoxide over-exposure. Other symptoms of over-exposure can include
headache, shortness of breath, wheezing, dizziness, indigestion, and nausea.
At high concentrations
unconsciousness or death may occur. Symptoms can include blurred vision and memory loss.
CHRONIC: Clinical studies indicate that there is a relationship between exposure to Carbon Monoxide in specific
occupations (i.e., fire-fighters, foundry workers) and an increased incidence of cardiovascular problems. Carbon
Monoxide is a reproductive toxin. Refer to Section 11 of this MSDS for further information.
TARGET ORGANS: Respiratory system, circulatory system, cardiovascular system, reproductive system.
CARBON MONOXIDE - CO MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 2 OF 9
3. COMPOSITION and INFORMATION ON INGREDIENTS
CHEMICAL NAME
CAS #
mole %
EXPOSURE LIMITS IN AIR
ACGIH-TLV
Carbon Monoxide
630-08-0
> 99.0%
OSHA-PEL
TWA
ppm
STEL
ppm
TWA
ppm
25
NE
50
35
(Vacated
1989 PEL)
Maximum Impurities
< 1.0%
STEL
ppm
OTHER
IDLH
ppm
1200
200 ceiling
(Vacated
1989 PEL)
ppm
NIOSH REL:
TWA = 35
STEL = 200 ceiling
DFG MAKs:
TWA = 30
PEAK = 2•MAK, 30
min., average value
DFG MAK Pregnancy
Risk Classification: B
None of the trace impurities in this product contribute significantly to the hazards
associated with the product. All hazard information pertinent to Carbon Monoxide has
been provided in this Material Safety Data Sheet, per the requirements of the OSHA
Hazard Communication Standard (29 CFR 1910.1200) and State equivalents standards.
This material is classified as hazardous under OSHA regulations in the United States and the WHMIS in
Canada.
NE = Not Established.
See Section 16 for Definitions of Terms Used.
NOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-2004 format. This product has been
classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
4. FIRST-AID MEASURES
RESCUERS SHOULD NOT ATTEMPT TO RETRIEVE VICTIMS OF EXPOSURE TO CARBON
MONOXIDE WITHOUT ADEQUATE PERSONAL PROTECTIVE EQUIPMENT. At a minimum, SelfContained Breathing Apparatus and Fire-Retardant equipment should be worn. Adequate fire
protection must be provided during rescue situations. Victim(s) must be taken for medical attention.
Rescuers should be taken for medical attention if necessary. Take copy of label and MSDS to physician or other
health professional with victim(s). Remove victim(s) to fresh air as quickly as possible. Only trained personnel
should administer supplemental oxygen and/or cardio-pulmonary resuscitation if necessary.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing respiratory conditions may be aggravated
by over-exposure to Carbon Monoxide. Carbon Monoxide can aggravate some diseases of the cardiovascular
system such as coronary artery disease and angina pectoris.
RECOMMENDATIONS TO PHYSICIANS:
Treat symptoms and reduce over-exposure. Provide oxygen.
Hyperbaric oxygen is the most efficient antidote to Carbon Monoxide poisoning, with the optimum range being 2-2.5
atm. A special mask, or preferably, a compression chamber to utilize oxygen at these pressures is required. Avoid
administering stimulant drugs.
5. FIRE-FIGHTING MEASURES
FLASH POINT:: Not applicable. Flammable gas.
AUTOIGNITION TEMPERATURE: 607°C (1125°F)
FLAMMABLE LIMITS (in air by volume, %):
Lower (LEL): 12.5%
Upper (UEL): 74.2%
FIRE EXTINGUISHING MATERIALS: Extinguish fires of this gas by shutting-off the source of the gas. Use water
spray to cool fire-exposed structures and equipment.
UNUSUAL FIRE AND EXPLOSION HAZARDS: An extreme explosion hazard exists in areas in which the gas has
been released but the material has not yet ignited. Carbon Monoxide decomposes to carbon and carbon dioxide
between 400-700°C.
DANGER! Fires impinging (direct flame) on the outside surface of unprotected cylinders of Carbon Monoxide can
be very dangerous. Exposure to fire could cause a catastrophic failure of the cylinder releasing the contents into a
fireball and explosion of released gas. The resulting fire and explosion can result in severe equipment damage and
personnel injury or death over a large area around the cylinder. For massive fires in large areas, use unmanned
hose holder or monitor nozzles; if this is not possible, withdraw from area and allow fire to burn.
CARBON MONOXIDE - CO MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 3 OF 9
5. FIRE-FIGHTING MEASURES (Continued)
Explosion Sensitivity to Mechanical Impact: Not Sensitive.
Explosion Sensitivity to Static Discharge: Static discharge may cause this gas to ignite explosively, upon a release
of this gas. Due to low electrical conductivity, this substance can generate electrostatic charges during handling
operations.
SPECIAL FIRE-FIGHTING PROCEDURES: Structural firefighters must wear Self-Contained Breathing Apparatus
and full protective equipment. If water is not available for cooling or protection of cylinder exposures, evacuate the
area. The North American Emergency Response Guidebook (Guide #115) recommends 0.5 miles.
6. ACCIDENTAL RELEASE MEASURES
LEAK RESPONSE: Evacuate immediate area. Uncontrolled releases should be responded to by trained personnel
using pre-planned procedures. Proper protective equipment should be used. Eliminate any possible sources of
ignition and provide maximum explosion-proof ventilation. If the gas is leaking from a cylinder or valve, contact the
supplier. Adequate fire protection must be provided. Use only non-sparking tools and equipment during the
response. Minimum Personal Protective Equipment should be Level B: fire-retardant protective clothing, gloves
and Self-Contained Breathing Apparatus. Locate and seal the source of the leaking gas. Protect personnel
attempting the shut off with water-spray. Allow the gas to dissipate. Monitor the surrounding area for Carbon
Monoxide levels. Colorimetric tubes can be used to detect the presence of Carbon Monoxide. The level of Carbon
Monoxide must be at acceptable levels (see Section 2, Composition on Information and Ingredients) before
personnel can be allowed in the area without Self-Contained Breathing Apparatus. Combustible gas concentration
must be below 10% of the LEL (12.5%) prior to entry. Attempt to close the main source valve prior to entering the
area. If this does not stop the release (or if it is not possible to reach the valve), allow the gas to release in place or
remove the cylinder to a safe area and allow the gas to be released there.
THIS IS AN EXTREMELY FLAMMABLE, POISON GAS. Protection of all personnel and the area must be
maintained.
7. HANDLING AND STORAGE
WORK PRACTICES AND HYGIENE PRACTICES: Be aware of any signs of dizziness or fatigue; exposures to
fatal concentrations of Carbon Monoxide could occur without any significant warning symptoms. Non-sparking tools
should be used. Do not attempt to repair, adjust, or in any other way modify the cylinders containing Carbon
Monoxide. If there is a malfunction or another type of operational problem, contact nearest distributor immediately.
STORAGE AND HANDLING PRACTICES: Cylinders should be stored upright (with valve-protection cap in place)
and firmly secured to prevent falling or being knocked over. Cylinders can be stored in the open, but in such cases
should be protected against extremes of weather and from the dampness of the ground to prevent rusting. Cylinders
should be stored in dry, well-ventilated areas away from sources of heat, ignition and direct sunlight. Keep storage
area clear of materials that can burn. Do not allow area where cylinders are stored to exceed 52°C (125°F). Store
containers away from heavily trafficked areas and emergency exits. Store away from process and production areas,
elevators, building and room exits, or main aisles leading to exits. Protect cylinders against physical damage.
Cylinders should be separated from oxygen cylinders or other oxidizers by a minimum distance of 20 ft. or by a
barrier of non-combustible material at least 5 ft. high, having a fire-resistance rating of at least 0.5 hours. Isolate
from other incompatible chemicals (refer to Section 10, Stability and Reactivity).
Storage areas must meet national electrical codes for Class 1 Hazardous Areas. Post “No Smoking or Open
Flames” signs in storage or use areas. Consider installation of leak detection and alarm for storage and use areas.
Have appropriate extinguishing equipment in the storage area (i.e., sprinkler system, portable fire extinguishers).
Keep the smallest amount necessary on-site at any one-time. Full and empty cylinders should be segregated. Use a
first-in, first-out inventory system to prevent full containers from being stored for long periods of time.
SPECIAL PRECAUTIONS FOR HANDLING GAS CYLINDERS: Compressed gases can present significant safety
hazards. The following rules are applicable to work situations in which cylinders are being used:
Before Use: Move cylinders with a suitable hand truck. Do not drag, slide, or roll cylinders. Do not drop cylinders
or permit them to strike each other. Secure cylinders firmly. Leave the valve protection cap (where provided) in
place until cylinder is ready for use.
CARBON MONOXIDE - CO MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 4 OF 9
7. HANDLING AND STORAGE (Continued)
During Use: Use designated CGA fittings and other support equipment. Do not use adapters. Use piping and
equipment adequately designed to withstand pressures to be encountered. Do not use oils or grease on gashandling fittings or equipment. Do not “crack” valve open before connecting it since self-ignition may occur. Leak
check system with leak detection solution, never with flame. Immediately contact the supplier if there are any
difficulties associated with operating cylinder valve. Never insert an object (e.g., wrench, screwdriver, pry bar, etc.)
into valve cap openings. Doing so may damage valve, causing a leak to occur. Use an adjustable strap wrench to
remove overly tight or rusted caps. Never strike an arc on a compressed gas cylinder or make a cylinder part of an
electric circuit.
After Use: Close main cylinder valve. Valves should be closed tightly. Replace valve protection cap. Mark empty
cylinders “EMPTY”.
NOTE: Use only DOT or ASME code containers designed for flammable gas storage. Earth-ground and bond all
lines and equipment associated with Carbon Monoxide. Close valve after each use and when empty.
STANDARD VALVE CONNECTIONS FOR U.S. AND CANADA: Use the proper connections; DO NOT USE
ADAPTERS:
THREADED: 0-3000 PSIG - CGA 350
PIN-INDEXED YOKE: Not Applicable.
ULTRA HIGH INTEGRITY: 724
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices
indicated in Section 6 (Accidental Release Measures). Make certain application equipment is locked and tagged-out
safely. Purge gas handling equipment with inert gas (e.g., nitrogen) before attempting repairs. Always use product
in areas where adequate ventilation is provided.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Carbon Monoxide detectors should be installed in or near areas
where Carbon Monoxide is being used or stored (if appropriate, install automatic monitoring equipment to detect the
level of oxygen and the presence of potentially explosive air-gas mixtures). Use with adequate ventilation.
Provide natural or explosion-proof ventilation adequate to ensure Carbon Monoxide does not reach its lower
flammability limit of 12.5%. Local exhaust ventilation is preferred because it prevents gas dispersion into the work
place by eliminating it at its source.
RESPIRATORY PROTECTION: Maintain Carbon Monoxide levels below the TLV (see Section 2, Composition and
Information on Ingredients). Use only respiratory protection authorized in the U.S. Federal OSHA Respiratory
Protection Standard (29 CFR 1910.134), or equivalent U.S. State standards, and Canadian CSA Standard Z94.493. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-facepiece
pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air supply is required
under OSHA’s Respiratory Protection Standard (1910.134-1998). The following are NIOSH recommendations for
Carbon Monoxide concentrations in air:
CONCENTRATION
RESPIRATORY EQUIPMENT
Up to 350 ppm
Supplied Air Respirator (SAR).
Up to 875 ppm
SAR operated in a continuous flow mode.
Up to 1200 ppm
Gas mask with canister to protect against carbon monoxide or full-facepiece Self-Contained
Breathing Apparatus (SCBA) or full-facepiece SAR.
Emergency or Planned Entry into Unknown Concentration or IDLH Conditions: Positive pressure, full-facepiece
SCBA or positive pressure, full-facepiece SAR with an auxiliary positive pressure SCBA.
Escape:
Gas mask with canister to protect against carbon monoxide or escape-type SCBA.
NOTE: End of Service Life Indicator (ESLI) required for gas masks.
The IDLH concentration for Carbon Monoxide is 1200 ppm.
EYE PROTECTION: Safety glasses.
HAND PROTECTION: Note: Carbon Monoxide is mildly corrosive to nickel and iron. Natural rubber and neoprene
are attacked by Carbon Monoxide. Wear gloves when handling cylinders of Carbon Monoxide.
BODY PROTECTION: Use body protection appropriate for task. Safety shoes are recommended when handling
cylinders. Fire retardant clothing may be appropriate under some circumstances of use.
CARBON MONOXIDE - CO MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 5 OF 9
9. PHYSICAL and CHEMICAL PROPERTIES
GAS DENSITY @ 21.1°C (70°F) and 1 atm: 0.0725 lb/ft3 (1.161 kg/m3)
BOILING POINT @ 1 atm: -191.5°C (-312.7°F)
FREEZING/MELTING POINT @ 1 atm: -207°C (-340.6°F)
SPECIFIC GRAVITY (air = 1) @ 21.1°C (70°F) and 1 atm: 0.9676
pH: Not applicable.
SOLUBILITY IN WATER vol/vol @ 0°C (32°F): 0.035
MOLECULAR WEIGHT: 28.01
EVAPORATION RATE (nBuAc = 1): Not applicable.
EXPANSION RATIO: Not applicable.
ODOR THRESHOLD: Not applicable.
SPECIFIC VOLUME (ft3/lb): 13.8
VAPOR PRESSURE @21.1°C (70°F) psig: Gas, ambient.
COEFFICIENT WATER/OIL DISTRIBUTION: Not applicable.
APPEARANCE AND COLOR: Colorless, odorless gas.
HOW TO DETECT THIS SUBSTANCE (warning properties): There are no distinct warning properties. In terms of
leak detection, fittings and joints can be painted with a soap solution to detect leaks, which will be indicated by a
bubble formation.
10. STABILITY and REACTIVITY
STABILITY: Stable.
DECOMPOSITION PRODUCTS: Carbon Monoxide burns to form carbon and carbon dioxide between 400-700°C.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Strong oxidizers (i.e. chlorine, bromine,
pentafluoride, oxygen, oxygen difluoride, and nitrogen trifluoride). Carbon Monoxide is mildly corrosive to nickel and
iron (especially at high temperatures and pressures). Natural rubber and neoprene are attacked by Carbon
Monoxide. Carbon Monoxide is also incompatible with the following substances: metal oxides, nickel, iron,
chromium, alkali and alkaline earth metals, aluminum powder, iodine heptafluoride, sulfur, bromine, bromine
trifluoride, bromine pentafluoride, chlorine dioxide, and peroxodisulfuryl difluoride.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Contact with incompatible materials and exposure to heat, sparks, and other sources of
ignition. If the cylinders are exposed to extremely high temperatures, these cylinders can rupture or burst.
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: The following toxicity data are available for Carbon Monoxide:
TCLo (inhalation, mouse) = 65 ppm/24
hours (7-18 preg): reproductive
effects
TCLo (inhalation, mouse) = 8 pph/1 hour
(female 8D post): teratogenic effects
3
TCLo (inhalation, human) = 600 mg/m /10
minutes
LCLo (inhalation, man) = 4000 ppm/30
minutes
TCLo (inhalation, man) = 650 ppm/45
minutes: central nervous system and
blood system effects.
LCLo (inhalation, human) = 5000 ppm/5
minutes
LCLo (inhalation, dog) = 4000 ppm/46
minutes
LCLo (inhalation, rabbit) = 4000 ppm
LC50 (inhalation, guinea pig) = 5718
ppm/4 hours
LCLo (inhalation, mammal) = 5000 ppm/5
minutes
LD50 (inhalation, wild bird) = 1334 ppm
SUSPECTED CANCER AGENT: Carbon Monoxide is not found on the following lists: FEDERAL OSHA Z LIST,
NTP, CAL/OSHA, and IARC and therefore is neither considered to be nor suspected to be a cancer-causing agent
by these agencies.
IRRITANCY OF PRODUCT: Contact with rapidly expanding gases can be irritating to exposed skin and eyes.
SENSITIZATION TO THE PRODUCT: Carbon Monoxide is not a skin or respiratory sensitizer.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of Carbon
Monoxide on the human reproductive system.
Mutagenicity: Carbon Monoxide is not expected to cause mutagenic effects in humans. In one available animal
study, Carbon Monoxide increased chromosomal damage in the blood of mice.
Embryotoxicity: Carbon Monoxide has not been reported to cause embryotoxic effects.
Teratogenicity: Carbon Monoxide can cause teratogenic effects in humans. Severe exposure to Carbon Monoxide
during pregnancy has caused adverse effects and the death of the fetus. In general, maternal symptoms are an
indicator of the potential risk to the fetus since Carbon Monoxide is toxic to the mother before it is toxic to the fetus.
CARBON MONOXIDE - CO MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 6 OF 9
11. TOXICOLOGICAL INFORMATION (Continued)
Reproductive Toxicity: Carbon Monoxide is not expected to cause adverse reproductive effects in humans.
A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will propagate
through generational lines. An embryotoxin is a chemical which causes damage to a developing embryo (i.e. within the first
eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a
chemical which causes damage to a developing fetus, but the damage does not propagate across generational lines. A
reproductive toxin is any substance which interferes in any way with the reproductive process.
BIOLOGICAL EXPOSURE INDICES (BEIs):
Monoxide, as follows:
CHEMICAL DETERMINANT
CARBON MONOXIDE
• Carboxyhemoglobin in blood
• Carbon monoxide in end-exhaled air
Biological Exposure Indices (BEIs) are applicable for Carbon
SAMPLING TIME
• End of shift
• End of shift
BEI
• 3.5% of hemoglobin
• 20 ppm
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL STABILITY: Carbon Monoxide occurs naturally in the atmosphere. The gas will be dissipated
rapidly in well-ventilated areas.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: Carbon Monoxide can be deadly to exposed animal life,
producing symptoms similar to those experienced by humans. This gas may also be harmful to plant life.
EFFECT OF CHEMICAL ON AQUATIC LIFE: No evidence is currently available regarding Carbon Monoxide’s
effects on aquatic life.
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate Federal, State,
and local regulations. Return cylinders with any residual product to Air Liquide. Do not dispose of locally.
14. TRANSPORTATION INFORMATION
THIS MATERIAL IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF
TRANSPORTATION.
PROPER SHIPPING NAME:
Carbon monoxide, compressed
HAZARD CLASS NUMBER and DESCRIPTION:
2.3 (Poison Gas)
UN IDENTIFICATION NUMBER:
UN 1016
PACKING GROUP:
Not applicable.
DOT LABEL(S) REQUIRED:
Poison Gas, Flammable Gas
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (2000): 119
SPECIAL PROVISION: Carbon Monoxide is poisonous by inhalation. Shipments must be properly described as
inhalation hazards. ZONE D.
MARINE POLLUTANT: Carbon Monoxide is not classified by the DOT as a Marine Pollutant (as defined by 49
CFR 172.101, Appendix B).
SPECIAL SHIPPING INFORMATION: Cylinders should be transported in a secure position in a well-ventilated
vehicle. The transportation of compressed gas cylinders in automobiles or in closed-body vehicles present
serious safety hazards and should be discouraged.
NOTE: Shipment of compressed gas cylinders which have not been filled with the owner’s consent is a violation of
Federal law (49 CFR, Part 173.301 (b).
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This material is
considered as dangerous goods, per regulations of Transport Canada. Use the above information for the
preparation of Canadian Shipments.
CARBON MONOXIDE - CO MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 7 OF 9
15. REGULATORY INFORMATION
ADDITIONAL UNITED STATES REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS: Carbon Monoxide is not subject to the reporting requirements of
Sections 302, 304, and 313 of Title III of the Superfund Amendments and Reauthorization Act.
U.S. SARA Threshold Planning Quantity: Not applicable.
U.S. CERCLA REPORTABLE QUANTITY (RQ): Not applicable.
CANADIAN DSL INVENTORY STATUS: Carbon Monoxide is listed on the DSL Inventory.
U.S. TSCA INVENTORY STATUS: Carbon Monoxide is listed on the TSCA Inventory.
OTHER U.S. FEDERAL REGULATIONS:
• Carbon Monoxide is subject to the requirements of CFR 29 1910.1000. Carbon Monoxide is listed on Table Z.1.
• Carbon Monoxide does not contain any Class I or Class II ozone depleting chemicals (40 CFR part 82).
• Depending on specific operations involving the use of Carbon Monoxide, the regulations of the Process Safety
Management of Highly Hazardous Chemicals may be applicable (29 CFR 1910.119). Carbon Monoxide is not
listed in Appendix A of this regulation, however, any process that involves a flammable gas on-site, in one
location, in quantities of 10,000 lbs (4,553 kg) or greater is covered under this regulation unless it is used as a
fuel.
• Carbon Monoxide is listed under Table 3 as a Regulated Substance, per 40 CFR, Part 68, of the Risk
Management for Chemical Releases as a flammable substance.
U.S. STATE REGULATORY INFORMATION: Carbon Monoxide is covered under specific State regulations, as
denoted below:
Alaska - Designated Toxic and Hazardous
Substances: Carbon Monoxide.
California - Permissible Exposure Limits
for Chemical Contaminants: Carbon
Monoxide.
Florida - Substance List: Carbon Monoxide.
Illinois - Toxic Substance List: Carbon
Monoxide.
Kansas - Section 302/313 List: None.
Michigan - Critical Materials Register: No.
Massachusetts - Substance List: Carbon
Monoxide.
Minnesota - List of Hazardous Substances:
Carbon Monoxide.
Missouri - Employer Information/Toxic
Substance List: Carbon Monoxide.
New Jersey - Right to Know Hazardous
Substance List: Carbon Monoxide.
North Dakota - List of Hazardous
Chemicals, Reportable Quantities: No.
Pennsylvania - Hazardous Substance List:
Carbon Monoxide.
Rhode Island - Hazardous Substance List:
Carbon Monoxide.
Texas - Hazardous Substance List: No.
West Virginia - Hazardous Substance List:
None.
Wisconsin - Toxic and Hazardous
Substances: No.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): Carbon
Monoxide is on the California Proposition 65 lists. WARNING: Carbon Monoxide is a chemical known to the State
of California to cause birth defects or other reproductive harm.
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: Carbon Monoxide is on the DSL Inventory.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: Carbon
Monoxide is not on the CEPA Priorities Substances Lists.
CANADIAN WHMIS REGULATIONS: Carbon Monoxide is categorized as a Controlled Product, Hazard Classes
A, B1, D1A, and D2A as per the Controlled Product Regulations.
CARBON MONOXIDE - CO MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 8 OF 9
16. OTHER INFORMATION
NFPA RATING
HAZARDOUS MATERIAL INFORMATION
SYSTEM
FLAMMABILITY
HEALTH
4
HEALTH
0
3
1
(BLUE)
REACTIVITY
FLAMMABILITY
(RED)
4
(YELLOW)
0
OTHER
REACTIVITY
PROTECTIVE EQUIPMENT B
EYES
RESPIRATORY
HANDS
BODY
See Section 8
For routine industrial applications
MIXTURES: When two or more gases or liquefied gases are mixed, their hazardous properties may combine to
create additional, unexpected hazards. Obtain and evaluate the safety information for each component before
you produce the mixture. Consult an Industrial Hygienist or other trained person when you make your safety
evaluation of the end product. Remember, gases and liquids have properties which can cause serious injury or
death.
Further information on Carbon Monoxide can be found in the following pamphlets published by: Compressed
Gas Association Inc. (CGA), 4221 Walney Road 5th floor, Chantilly, VA 20151-2923. Telephone: (703) 788-2700.
P-1
SB-2
AV-1
“Safe Handling of Compressed Gases in Containers”
“Oxygen Deficient Atmospheres”
“Safe Handling and Storage of Compressed Gases”
“Handbook of Compressed Gases”
PREPARED BY:
CHEMICAL SAFETY ASSOCIATES, Inc.
9163 Chesapeake Drive, San Diego, CA 92123-1002
858/565-0302
Fax on Demand:
1-800/231-1366
This Material Safety Data Sheet is offered pursuant to OSHA’s Hazard Communication Standard, 29 CFR, 1910.1200. Other government
regulations must be reviewed for applicability to Carbon Monoxide. To the best of Air Liquide’s knowledge, the information contained herein
is reliable and accurate as of this date; however, accuracy, suitability or completeness are not guaranteed and no warranties of any type,
either express or implied, are provided. The information contained herein relates only to this specific product. If Carbon Monoxide is
combined with other materials, all component properties must be considered. Data may be changed from time to time. Be sure to consult
the latest edition.
CARBON MONOXIDE - CO MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 9 OF 9
MATERIAL SAFETY
DATA SHEET
Prepared to U.S. OSHA, CMA, ANSI and Canadian WHMIS Standards
1. PRODUCT AND COMPANY INFORMATION
CHEMICAL NAME; CLASS:
OXYGEN
SYNONYMS: Oxygen USP, Aviator’s Breathing Oxygen (ABO)
CHEMICAL FAMILY NAME: Oxidizing Gas
FORMULA: O2
NOTE: Oxygen may be supplied by pipeline at pressures up to 600 PSIG.
Document Number: 10074
Medical, welding and general analytical
or synthetic chemical uses.
PRODUCT USE:
MANUFACTURED/SUPPLIED FOR:
ADDRESS:
EMERGENCY PHONE:
2700 Post Oak Drive
Houston, TX 77056-8229
CHEMTREC: 1-800-424-9300
BUSINESS PHONE:
General MSDS Information 1-713/896-2896
Fax on Demand:
1-800/231-1366
OXYGEN - O2 MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 1 OF 9
2. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: Oxygen is a colorless, odorless gas. The main health hazard associated with
releases of this gas is its powerful oxidizing power. In high oxygen content atmospheres, common combustible
materials can become highly flammable. Emergency responders must practice extreme caution when
approaching oxygen releases because of the extreme fire potential.
SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE: The most significant route of over-exposure for
this product is by inhalation.
INHALATION: High concentrations (80% or more) of this gas can cause an oxygen-rich environment. Individuals
breathing such an atmosphere for durations of 17-24 hours may experience symptoms which include nasal
stuffiness, nausea, dizziness, bronchial irritation (cough), sore throat, hypothermia, increased depth of respiration,
bradycardia, pulmonary discomfort (including chest pain), peripheral vasoconstriction, amblyopia (loss of vision).
Inhalation of pure oxygen at atmospheric pressure or less can cause pulmonary irritation and edema after 24 hours.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. Over-exposure to Oxygen
may cause the following health effects:
ACUTE: Individuals breathing oxygen-enriched atmospheres may experience nasal stuffiness, nausea, dizziness,
coughing, sore throat, hypothermia, disturbed breathing, chest pain, and loss of vision.
CHRONIC: There are currently no known adverse health effects associated with chronic exposure to this gas.
TARGET ORGANS: Respiratory system.
3. COMPOSITION and INFORMATION ON INGREDIENTS
CHEMICAL NAME
CAS #
mole %
EXPOSURE LIMITS IN AIR
ACGIH
TLV
ppm
Oxygen
7782-44-7
Maximum Impurities
STEL
ppm
PEL
ppm
OSHA
STEL
ppm
IDLH
ppm
OTHER
99.5%
There are no specific exposure limits for Oxygen. Oxygen levels should be maintained
above 19.5% and below 23.5%
<0.5%
None of the trace impurities in this product contribute significantly to the hazards
associated with the product. All hazard information pertinent to this product has been
provided in this Material Safety Data Sheet, per the requirements of the OSHA Hazard
Communication Standard (29 CFR 1910.1200) and State equivalents standards.
This material is classified as hazardous under OSHA regulations in the United States and the WHMIS in
Canada.
NE = Not Established
C = Ceiling Limit
See Section 16 for Definitions of Terms Used.
NOTE: all WHMIS required information is included. It is located in appropriate sections based on the ANSI Z400.1-2004 format.
OXYGEN - O2 MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 2 OF 9
4. FIRST-AID MEASURES
Remove victim(s) to fresh air, as quickly as possible, or if in elevated pressures, reduce oxygen pressure to 1
atmosphere. Physician should be advised of victim’s exposure to a high oxygen concentration. Trained personnel
should administer medical aid such as cardio-pulmonary resuscitation, if necessary. Supplemental oxygen is not
normally appropriate. Victims tend to recover rapidly, when removed from the hypoxic exposure.
Take copy of label and MSDS to physician or other health professional with victim(s). Medical care providers should
refer to Section 11 (Toxicology Information) of this MSDS for additional information.
5. FIRE-FIGHTING MEASURES
FLASH POINT: Not applicable.
AUTOIGNITION TEMPERATURE: Not applicable.
FLAMMABLE LIMITS (in air by volume, %):
Lower (LEL): Not applicable.
Upper (UEL): Not applicable.
FIRE EXTINGUISHING MATERIALS: Non-flammable gas. Use extinguishing media appropriate for surrounding
fire.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Oxygen does not burn; however, cylinders, when involved in fire,
may rupture or burst in the heat of the fire. Oxygen will support and accelerate combustion. Common combustible
materials will burn more readily in elevated oxygen environments, and some materials which are non-combustible in
air will burn in an oxygen-enriched atmosphere. Direct water onto cylinders to keep cool. Shut-off the flow of
oxygen or move cylinders from fire area if it can be done safely. Rescue personnel should be aware of the extreme
fire hazards associated with oxygen-enriched atmospheres.
Water Spray: YES
Carbon Dioxide: YES
Foam: YES
Halon: YES
Dry Chemical: YES
Other: Any "ABC” Class.
Explosion Sensitivity to Mechanical Impact: Not Sensitive.
Explosion Sensitivity to Static Discharge: Not Sensitive.
SPECIAL FIRE-FIGHTING PROCEDURES: Structural fire-fighters must wear Self-Contained Breathing Apparatus
and full protective equipment. Other information for pre-planning can be found in the North American Emergency
Response Guidebook.
6. ACCIDENTAL RELEASE MEASURES
LEAK RESPONSE: Evacuate immediate area. Uncontrolled releases should be responded to by trained personnel
using pre-planned procedures. Proper protective equipment should be used. In case of a leak, clear the affected
area, protect people, eliminate sources of ignition, and respond with trained personnel. Adequate fire protection
must be provided.
Minimum Personal Protective Equipment should be Level B: fire protective clothing, mechanically-resistant, fire
protective gloves and Self-Contained Breathing Apparatus. In general, DO NOT ENTER AN AREA IF THE
OXYGEN CONTENT EXCEEDS 23.5%. USE VENTILATION TO REDUCE THE OXYGEN LEVELS. Attempt to
close the main source valve prior to entering the area. If this does not stop the release (or if it is not possible to
reach the valve), allow the gas to release in-place or remove it to a safe area and allow the gas to be released there.
Remove sources of heat, ignition, and, if possible, separate combustibles from the leak. Monitor the surrounding
area for oxygen levels.
If leaking incidentally from the cylinder or its valve, contact your supplier.
OXYGEN - O2 MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 3 OF 9
7. HANDLING AND STORAGE
STORAGE AND HANDLING PRACTICES: Cylinders should be stored upright and be firmly secured to prevent
falling or being knocked-over. Cylinders can be stored in the open, but in such cases, should be protected against
extremes of weather and from the dampness of the ground to prevent rusting. Cylinders should be stored in dry,
well-ventilated areas away from sources of heat, ignition and direct sunlight. Keep storage area clear of materials
which can burn. Do not allow area where cylinders are stored to exceed 52°C (125°F). Store containers away from
heavily trafficked areas and emergency exits. Store away from process and production areas, away from elevators,
building and room exits or main aisles leading to exits. Cylinders should be separated from flammable materials by a
minimum distance of 20 ft or by a barrier of non-combustible material at least 5 ft high, having a fire resistance rating
of at least ½ hour. Protect cylinders against physical damage. Isolate from other non compatible chemicals (refer to
Section 10, Stability and Reactivity). Post “No Smoking or Open Flames” signs in storage or use areas.
Consider installation of leak detection and alarm for storage and use areas.
equipment in the storage area ( i.e. sprinkler system, portable fire extinguishers).
Have appropriate extinguishing
SPECIAL PRECAUTIONS FOR USE OF OXYGEN: All gauges, valves, regulators, piping and equipment to be
used in oxygen service must be cleaned for oxygen service in accordance with CGA pamphlet G-4.1 Use piping
and equipment adequately designed to withstand pressures to be encountered. Oxygen is not to be used as a
substitute for compressed air. Never use an oxygen jet for cleaning purposes of any sort, especially clothing, as it
increases the likelihood of an engulfing fire. Use a check valve or other protective apparatus in any line or piping
from the cylinder to prevent reverse flow. Never tamper with pressure relief valves and cylinders.
Personnel who have been exposed to high concentrations of oxygen should stay in a well-ventilated or open area
for 30 minutes before going into a confined space or near an ignition source. Use non-sparking ventilation
systems, approved explosion-proof equipment, and appropriate electrical systems. Electrical equipment used in gashandling operations, or located in storage areas, should be non-sparking or explosion-proof
Keep the smallest amount necessary on-site at any one time. Full and empty cylinders should be segregated. Use
a first-in, first-out inventory systems to prevent full containers from being stored for long periods of time.
SPECIAL PRECAUTIONS FOR HANDLING GAS CYLINDERS: Compressed gases can present significant safety
hazards. The following rules are applicable to work situations in which cylinders are being used.
Before Use: Move cylinders with a suitable hand-truck. Do not drag, slide or roll cylinders. Do not drop cylinders or
permit them to strike each other. Secure cylinders firmly. Leave the valve protection cap (where provided) in-place
until cylinder is ready for use.
During Use: Use designated CGA fittings and other support equipment. Do not use adapters. Do not heat cylinder
by any means to increase the discharge rate of the product from the cylinder. Do not use oils or grease on gashandling fittings or equipment. Leak-check system with leak detection solution, never with flame. Immediately
contact the supplier if there are any difficulties associated with operating cylinder valve. Never insert an object (e.g
wrench, screwdriver, pry bar, etc.) into valve cap openings. Doing so may damage valve, causing a leak to occur.
Use an adjustable strap wrench to remove over-tight or rusted caps. Never strike an arc, on a compressed gas
cylinder or make a cylinder part of and electric circuit.
After Use: Close main cylinder valve. Valves should be closed tightly. Replace valve protection cap. Mark empty
cylinders “EMPTY”.
NOTE: Use only DOT or ASME code containers. Close valve after each use and when empty. Cylinders must not
be recharged except by or with the consent of owner. For additional information, refer to American National
Standards (ANSI) Z49.1 Safety in Welding and Cutting published by the American Welding Society, PO Box 351040,
Miami, FL 33135; National Fire Protection Association (NFPA) 51. See Section 16, (Other Information) for
additional pamphlets developed by the Compressed Gas Association (CGA).
OXYGEN - O2 MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 4 OF 9
7. HANDLING AND STORAGE (Continued)
STANDARD VALVE CONNECTIONS FOR U.S. AND CANADA: Use the proper CGA connections, DO NOT
USE ADAPTERS:
THREADED:
PIN-INDEXED YOKE:
ULTRA HIGH INTEGRITY:
0-3000 psig
CGA 540
3001-4000 psig CGA 577
4001-5500 psig CGA 701
0-3000 psig
CGA 870 (Medical Use)
0-3000 psig
714
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices
indicated in Section 6 (Accidental Release Measures). Make certain application equipment is locked and tagged-out
safely. Purge gas handling equipment with inert gas (i.e. nitrogen) before attempting repairs. Always use product in
areas where adequate ventilation is provided.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation. Local exhaust ventilation is
preferred, because it prevents dispersion of this gas into the work place by eliminating it at its source. If appropriate,
install automatic monitoring equipment to detect the level of oxygen.
RESPIRATORY PROTECTION: Maintain oxygen levels above 19.5% and below 23.5% in the workplace. Use
supplied air respiratory protection if oxygen levels are below 19.5%. DO NOT ENTER AN AREA IF THE OXYGEN
CONTENT EXCEEDS 23.5%.
EYE PROTECTION: Safety glasses.
HAND PROTECTION: Wear gloves when handling cylinders of this product. Otherwise, wear glove protection
appropriate to the specific operation for which this product is used.
BODY PROTECTION: Use body protection appropriate for task. Safety shoes are recommended when handling
cylinders.
9. PHYSICAL and CHEMICAL PROPERTIES
GAS DENSITY @ 0°C (32°F) and 1 atm: 0.083 lb/cu ft (1.326 kg/m3)
BOILING POINT: -183.0°C (-297.4°F)
FREEZING/MELTING POINT @ 10 psig: -218.8°C (-361.8°F)
SPECIFIC GRAVITY (air = 1) @ 70°F (21.1°C): 1.105
pH: Not applicable.
SOLUBILITY IN WATER vol/vol at 0°C and 1 atm: 0.04.91
MOLECULAR WEIGHT: 32.00
EVAPORATION RATE (nBuAc = 1): Not applicable.
EXPANSION RATIO: Not applicable.
ODOR THRESHOLD: Not applicable.
VOLUME (ft3/lb): 12.1
VAPOR PRESSURE @ 21.1°C (70°F) psig: Not applicable.
COEFFICIENT WATER/OIL DISTRIBUTION: Not applicable.
APPEARANCE AND COLOR: This product is a colorless, odorless gas at normal temperature and pressure.
HOW TO DETECT THIS SUBSTANCE (warning properties): There are no unusual warning properties associated
with a release of this product. An oxygen monitor can be used to detect oxygen levels.
10. STABILITY and REACTIVITY
STABILITY: Normally stable.
DECOMPOSITION PRODUCTS: None.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Oxygen is incompatible with combustible and
flammable materials, chlorinated hydrocarbons, hydrazine, reduced boron compounds, ethers, phosphine,
phosphorous tribromide, phosphorous trioxide, tetrafluorethylene, and compounds which readily form peroxides.
Oxygen may form explosive compounds when exposed to combustible material, or oil, grease, and other
hydrocarbon materials.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Avoid contact with incompatible materials. Cylinders exposed to high temperatures or
direct flame can rupture or burst.
OXYGEN - O2 MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 5 OF 9
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: Oxygen is the vital element in the atmosphere in which we live and breathe. The atmosphere
contains approximately 21% oxygen. Breathing higher concentrations could lead to oxygen toxicity and pneumonia.
Breathing lower oxygen concentrations could lead to hypoxia. The following toxicity data are for oxygen:
Human toxicological data and teratogenic data are available for Oxygen; however, the effects have occurred after prolonged exposure to Oxygen
(inhalation effects of TCLo after 14 hours) and with exposure of very high concentration of Oxygen at greater than normal atmosphere.
Premature infants exposed to high oxygen concentrations may suffer delayed retinal damage which can progress to retinal detachment and
blindness. Retinal damage may also occur in adults exposed to 100% oxygen for extended periods of time (24 to 48 hours).
At two or more atmospheres, central nervous system (CNS) toxicity occurs. Symptoms include nausea, vomiting, dizziness or vertigo, muscle
twitching, vision changes, and loss of consciousness and generalized seizures. At three atmospheres, CNS toxicity occurs in less than two hours,
and at six atmospheres in only a few minutes.
SUSPECTED CANCER AGENT: Oxygen is not found on the following lists: FEDERAL OSHA Z LIST, NTP,
CAL/OSHA, IARC; therefore it is not considered to be, nor suspected to be a cancer-causing agent by these
agencies.
IRRITANCY OF PRODUCT: None.
SENSITIZATION OF PRODUCT: Oxygen is not a sensitizer.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of Oxygen on the
human reproductive system.
Mutagenicity: Mutation data have been reported for oxygen; these data have been obtained in studies exposing
specific animal tissues to relatively high concentrations (80%) of oxygen.
Embryotoxcity: Oxygen is not expected to cause embryotoxic effects in humans. For further information see
following paragraph.
Teratogenicity Human teratogenic effects have been reported after inhalation of 12 pph oxygen for 10 minutes
during 26-29 weeks of pregnancy; these effects include developmental abnormalities of the fetal cardiovascular
system; Exposure of pregnant hamsters to 3-4 atmospheres of 100% oxygen for periods of 2-3 hours produced
teratogenic effects in a small, but significant number of fetuses. One quarter of the mother hamsters developed
central nervous system symptoms.
Reproductive Toxicity: Oxygen is not expected to cause adverse reproductive effects in humans.
A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will
propagate through generation lines. An embryotoxin is a chemical which causes damage to a developing embryo
(i.e. within the first eight weeks of pregnancy in humans), but the damage does not propagate across generational
lines. A teratogen is a chemical which causes damage to a developing fetus, but the damage does not propagate
across generational lines. A reproductive toxin is any substance which interferes in any way with the reproductive
process.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing respiratory conditions may be aggravated
by over-exposure to this product. Persons with chronic obstructive pulmonary disease can retain carbon dioxide
abnormally. If oxygen is administered to such persons, raising the oxygen concentration in the blood depresses the
breathing rate and raises the retained carbon dioxide levels in the blood to a dangerous level in these persons.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and reduce over-exposure. Symptoms of overexposure usually are relieved quickly. Immediate sedation and anticonvulsive therapy should be provided, as
needed.
BIOLOGICAL EXPOSURE INDICES (BEIs): Currently, Biological Exposure Indices (BEIs) are not applicable for
this compound.
ADDITIONAL NOTES TO PHYSICIANS: Animal studies suggest that the administration of certain drugs, including
phenothiazine drugs and chloroquine, increase the susceptibility to toxicity from oxygen at high pressures. Animal
studies also indicate that vitamin “E” deficiency may increase susceptibility to toxicity to oxygen toxicity.
Airway obstruction during high oxygen tension may cause alveolar collapse following absorption of the oxygen.
Similarly, occlusion of the Eustachian tubes may cause retraction of the eardrum and obstruction of the paranasal
sinuses may produce “vacuum-type” headache. All individuals exposed for long periods to oxygen at high
pressure and who exhibit overt oxygen toxicity should have ophthalmologic examinations.
OXYGEN - O2 MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 6 OF 9
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL STABILITY: Oxygen occurs naturally in the atmosphere. The gas will be dissipated rapidly in
well-ventilated areas.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: No adverse effect is anticipated to occur to animal or plantlife, except for frost produced in the presence of rapidly expanding gases.
EFFECT OF CHEMICAL ON AQUATIC LIFE: No evidence is currently available on this product’s effects on aquatic
life.
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate Federal, State,
and local regulations. Return cylinders with any residual product to Air Liquide. Do not dispose of locally.
For emergency disposal, secure the cylinder and slowly discharge the gas to the atmosphere in a well-ventilated
area or outdoors, away from all sources of ignition.
14. TRANSPORTATION INFORMATION
THIS MATERIAL IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF
TRANSPORTATION.
PROPER SHIPPING NAME:
Oxygen, compressed
HAZARD CLASS NUMBER and DESCRIPTION: 2.2 (Non-Flammable Gas)
UN IDENTIFICATION NUMBER:
UN 1072
PACKING GROUP:
Not applicable.
DOT LABEL(S) REQUIRED:
Non-Flammable Gas, Oxidizer or Oxygen
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (1996): 122
MARINE POLLUTANT: Oxygen is not classified by the DOT as a Marine Pollutant (as defined by 49 CFR 172.101,
Appendix B).
SPECIAL SHIPPING INFORMATION: Cylinders should be transported in a secure position, in a well-ventilated
vehicle. The transportation of compressed gas cylinders in automobiles or in closed-body vehicles present serious
safety hazards and should be discouraged.
NOTE: Shipment of compressed gas cylinders which have not been filled with the owners consent is a violation of
Federal law (49 CFR, Part 173.301 (b).
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: THIS MATERIAL IS
CONSIDERED AS DANGEROUS GOODS. Use the above information for the preparation of Canadian Shipments.
15. REGULATORY INFORMATION
U.S. SARA REPORTING REQUIREMENTS: Oxygen is not subject to the reporting requirements of Sections 302,
304 and 313 of Title III of the Superfund Amendments and Reauthorization Act. This product is subject to the
reporting requirements of Sections 311 and 312 of Title III of the Superfund Amendments and Reauthorization Act
(40 CFR 370.21).
U.S. SARA THRESHOLD PLANNING QUANTITY: Not applicable.
U.S. CERCLA REPORTABLE QUANTITY (RQ): Not applicable.
CANADIAN DSL INVENTORY STATUS: Oxygen is listed on the DSL Inventory.
U.S. TSCA INVENTORY STATUS: Oxygen is listed on the TSCA Inventory.
OTHER U.S. FEDERAL REGULATIONS:
• Oxygen USP is regulated by the FDA as a prescription drug.
• Depending on specific operations involving the use of this product, the regulations of the Process Safety
Management of Highly Hazardous Chemicals may be applicable (29 CFR 1910.119). Under this regulation
Oxygen is not listed in Appendix A.
• Oxygen does not contain any Class I or Class II ozone depleting chemicals (40 CFR part 82).
• Oxygen is not listed as a Regulated Substance, per 40 CFR, Part 68, of the Risk Management for Chemical.
CALIFORNIA PROPOSITION 65: Oxygen is not on the California Proposition 65 lists.
OXYGEN - O2 MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 7 OF 9
15. REGULATORY INFORMATION (Continued)
U.S. STATE REGULATORY INFORMATION: Oxygen is covered under the following specific State regulations:
Alaska - Designated Toxic and
Hazardous Substances: No.
California - Permissible Exposure
Limits for Chemical Contaminants:
No.
Florida - Substance List: Oxygen.
Illinois - Toxic Substance List: No.
Kansas - Section 302/313 List: No.
Massachusetts - Substance List:
Oxygen.
Michigan - Critical Materials Register:
No.
Minnesota
List
of
Hazardous
Substances: No.
Missouri - Employer Information/Toxic
Substance List: No.
New Jersey - Right to Know Hazardous
Substance List: Oxygen.
North Dakota - List of Hazardous
Chemicals, Reportable Quantities: No.
Pennsylvania - Hazardous Substance List:
Oxygen.
Rhode Island - Hazardous Substance List:
Oxygen.
Texas - Hazardous Substance List: No.
West Virginia - Hazardous Substance List:
No.
Wisconsin
Toxic
and
Hazardous
Substances: No.
OTHER CANADIAN REGULATIONS: Oxygen is categorized as a Controlled Product, Hazard Classes A, and C as
per the Controlled Product Regulations.
16. OTHER INFORMATION
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
NFPA RATING
FLAMMABILITY
HEALTH HAZARD
3
(BLUE)
0
HEALTH
0
3
REACTIVITY
FLAMMABILITY HAZARD
PHYSICAL HAZARD
(RED)
0
(YELLOW)
0
OTHER
PROTECTIVE EQUIPMENT
EYES
RESPIRATORY
HANDS
BODY
See Section 8
For Routine Industrial Use and Handling Applications
MIXTURES: When two or more gases or liquefied
gases are mixed, their hazardous properties may combine to create additional, unexpected hazards. Obtain and
evaluate the safety information for each component before you produce the mixture. Consult an Industrial
Hygienist or other trained person when you make your safety evaluation of the end product. Remember, gases
and liquids have properties which can cause serious injury or death. Further information about oxygen can be
found in the following pamphlets published by: Compressed Gas Association Inc. (CGA), 4221 Walney Road 5th
floor, Chantilly, VA 20151-2923. Telephone: (703) 788-2700.
G-4
G-4.1
G-4.3
G-4.4
G-4.6
P-1
P-14
SB-7
SB-8
AV-1
AV-8
AV-10
“Oxygen”
“Cleaning Equipment of Oxygen Service”
“Commodity Specification for Oxygen”
“Industrial Practices for Gaseous Oxygen Transmission and Distribution Piping Systems”
“Oxygen Compressor Installation Guide”
“Safe Handling of Compressed Gases in Containers”
“Accident Prevention in Oxygen-Rich and Oxygen Deficient Atmospheres”
“Rupture of Oxygen Cylinders in the Diving Industry”
“Use of Oxy-fuel Gas Welding and Cutting Apparatus”
“Safe Handling and Storage of Compressed Gases”
“Characteristics and Safe Handling of Cryogenic Liquid and Gaseous Oxygen”
“Safe Handling and Use of Medical Equipment and Gases in a Homecare Environment”
‘Handbook of Compressed Gases”
OXYGEN - O2 MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 8 OF 9
16. OTHER INFORMATION (Continued)
PREPARED BY:
CHEMICAL SAFETY ASSOCIATES, Inc.
9163 Chesapeake Drive, San Diego, CA 92123-1002
619/565-0302
Fax on Demand: 1-800/231-1366
This Material Safety Data Sheet is offered pursuant to OSHA’s Hazard Communication Standard, 29 CFR, 1910.1200. Other government
regulations must be reviewed for applicability to this product. To the best of Air Liquide’s knowledge, the information contained herein is
reliable and accurate as of this date; however, accuracy, suitability or completeness are not guaranteed and no warranties of any type, either
express or implied, are provided. The information contained herein relates only to this specific product. If this product is combined with other
materials, all component properties must be considered. Data may be changed from time to time. Be sure to consult the latest edition.
OXYGEN - O2 MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 9 OF 9
MATERIAL SAFETY
DATA SHEET
Prepared to U.S. OSHA, CMA, ANSI and Canadian WHMIS Standards
1. PRODUCT AND COMPANY INFORMATION
CHEMICAL NAME; CLASS:
XENON
SYNONYMS: Not applicable.
CHEMICAL FAMILY NAME: Inert Gas
FORMULA: Xe
Document Number: 20173
Inerting; ionized light conduction; filling of
electron tubes; and general analytical
or synthetic chemical uses.
PRODUCT USE:
MANUFACTURED/SUPPLIED FOR:
ADDRESS:
EMERGENCY PHONE:
2700 Post Oak Drive
Houston, TX 77056-8229
CHEMTREC: 1-800-424-9300
BUSINESS PHONE:
General MSDS Information 1-713/896-2896
Fax on Demand:
1-800/231-1366
XENON - Xe MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 1 OF 7
2. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: Xenon is a colorless, odorless gas.
releases of this gas is asphyxiation, by displacement of oxygen.
The main health hazard associated with
SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE: The most significant route of over-exposure for
this gas is by inhalation.
INHALATION: High concentrations of this gas can cause an oxygen-deficient environment. Individuals breathing
such an atmosphere may experience symptoms which include headaches, ringing in ears, dizziness, drowsiness,
unconsciousness, nausea, vomiting, and depression of all the senses.
Under some circumstances of over-exposure, death may occur, due to the displacement of oxygen. The following
effects associated with various levels of oxygen are as follows:
CONCENTRATION
SYMPTOM OF EXPOSURE
12-16% Oxygen:
Breathing and pulse rate increased, muscular coordination slightly disturbed.
10-14% Oxygen:
Emotional upset, abnormal fatigue, disturbed respiration.
6-10% Oxygen:
Nausea and vomiting, collapse or loss of consciousness.
Below 6%:
Convulsive movements, possible respiratory collapse, and death.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. Over-exposure to Xenon may
cause the following health effects:
ACUTE: The most significant hazard associated with this gas is inhalation of oxygen-deficient atmospheres.
Symptoms of oxygen deficiency include respiratory difficulty, ringing in ears, headaches, shortness of breath,
wheezing, headache, dizziness, indigestion, nausea, and, at high concentrations, unconsciousness or death may
occur. The skin of a victim of over-exposure may have a blue color.
CHRONIC: There are currently no known adverse health effects associated with chronic exposure to this product.
TARGET ORGANS: Respiratory system.
3. COMPOSITION and INFORMATION ON INGREDIENTS
CHEMICAL NAME
CAS #
mole %
EXPOSURE LIMITS IN AIR
ACGIH-TLV
Xenon
7440-63-3
100%
OSHA-PEL
TWA
STEL
TWA
STEL
IDLH
ppm
ppm
ppm
ppm
ppm
OTHER
There are no specific exposure limits for Xenon. Xenon is a simple asphyxiant (SA).
Oxygen levels should be maintained above 19.5%.
This material is classified as hazardous under OSHA regulations in the United States and the WHMIS
in Canada.
NE = Not Established
See Section 16 for Definitions of Terms Used.
NOTE: all WHMIS required information is included. It is located in appropriate sections based on the ANSI Z400.1-2004 format.
4 FIRST-AID MEASURES
RESCUERS SHOULD NOT ATTEMPT TO RETRIEVE VICTIMS OF EXPOSURE TO THIS PRODUCT
WITHOUT ADEQUATE PERSONAL PROTECTIVE EQUIPMENT. At a minimum, Self-Contained
Breathing Apparatus should be worn.
Remove victim(s) to fresh air, as quickly as possible. If not breathing, give artificial respiration If breathing is difficult,
give oxygen Only trained personnel should administer supplemental oxygen. Victim(s) must be taken for medical
attention. Rescuers should be taken for medical attention, if necessary. Take copy of label and MSDS to physician
or other health professional with victim(s).
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing respiratory conditions may be aggravated
by over-exposure to Xenon.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and reduce over-exposure.
XENON - Xe MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 2 OF 7
5. FIRE-FIGHTING MEASURES
FLASH POINT: Not applicable.
AUTOIGNITION TEMPERATURE: Not applicable.
FLAMMABLE LIMITS (in air by volume, %):
Lower (LEL): Not applicable.
Upper (UEL): Not applicable.
FIRE EXTINGUISHING MATERIALS: Non-flammable, inert gas. Use extinguishing media appropriate for
surrounding fire.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Xenon does not burn; however, containers, when involved in fire,
may rupture or burst in the heat of the fire.
Explosion Sensitivity to Mechanical Impact: Not Sensitive.
Explosion Sensitivity to Static Discharge: Not Sensitive.
SPECIAL FIRE-FIGHTING PROCEDURES: Structural fire-fighters must wear Self-Contained Breathing Apparatus
and full protective equipment.
6. ACCIDENTAL RELEASE MEASURES
LEAK RESPONSE: Evacuate immediate area. Uncontrolled releases should be responded to by trained personnel
using pre-planned procedures. Proper protective equipment should be used. In case of a leak, clear the affected
area, protect people, and respond with trained personnel.
Minimum Personal Protective Equipment should be: Level B: Self-Contained Breathing Apparatus. Locate and
seal the source of the leaking gas. Allow the gas, which is heavier than air, to dissipate. Monitor the surrounding
area for oxygen levels. The atmosphere must have at least 19.5 percent oxygen before personnel can be allowed in
the area without Self-Contained Breathing Apparatus.
If leaking incidentally from the cylinder or its valve, contact your supplier.
7. HANDLING AND STORAGE
WORK PRACTICES AND HYGIENE PRACTICES: Be aware of any signs of dizziness or fatigue; exposures to
fatal concentrations of this product could occur without any significant warning symptoms, due to oxygen deficiency.
STORAGE AND HANDLING PRACTICES: Cylinders should be stored upright and be firmly secured to prevent
falling or being knocked-over. Cylinders can be stored in the open, but in such cases, should be protected against
extremes of weather and from the dampness of the ground to prevent rusting. Cylinders should be stored in dry,
well-ventilated areas away from sources of heat, ignition and direct sunlight. Keep storage area clear of materials
which can burn. Do not allow area where cylinders are stored to exceed 52°C (125°F). Xenon is much heavier than
air and should not be stored in areas where the gas will accumulate and cause an oxygen deficient atmosphere.
Store containers away from heavily trafficked areas and emergency exits. Store away from process and production
areas, away from elevators, building and room exits or main aisles leading to exits. Protect cylinders against
physical damage.
Use a check valve or other protective device in the discharge line to prevent hazardous backflow. Never tamper with
pressure relief valves and cylinders.
Keep the smallest amount necessary on-site at any one time. Full and empty cylinders should be segregated. Use
a first-in, first-out inventory systems to prevent full containers from being stored for long periods of time.
SPECIAL PRECAUTIONS FOR HANDLING GAS CYLINDERS: Compressed gases can present significant safety
hazards. The following rules are applicable to work situations in which cylinders are being used.
Before Use: Move cylinders with a suitable hand-truck. Do not drag, slide or roll cylinders. Do not drop cylinders or
permit them to strike each other. Secure cylinders firmly. Leave the valve protection cap (where provided) in-place
until cylinder is ready for use.
During Use: Use designated CGA fittings and other support equipment. Do not use adapters. Do not heat cylinder
by any means to increase the discharge rate of the product from the cylinder. Do not use oils or grease on gashandling fittings or equipment. Immediately contact the supplier if there are any difficulties associated with operating
cylinder valve.
Never insert an object (e.g wrench, screwdriver, pry bar, etc.) into valve cap openings. Doing so may damage valve,
causing a leak to occur. Use an adjustable strap wrench to remove over-tight or rusted caps. Never strike an arc,
on a compressed gas cylinder or make a cylinder part of and electric circuit.
XENON - Xe MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 3 OF 7
7. HANDLING AND STORAGE (Continued)
After Use: Close main cylinder valve. Valves should be closed tightly. Replace valve protection cap. Mark empty
cylinders “EMPTY”.
NOTE: Use only DOT or ASME code containers designed for gas storage. Close valve after each use and when
empty.
STANDARD VALVE CONNECTIONS FOR U.S. AND CANADA: Use the proper CGA connections, DO NOT
USE ADAPTERS:
THREADED:
PIN-INDEXED YOKE:
ULTRA HIGH INTEGRITY:
0-3000 psig
3001-5500 psig
5501-7500 psig
Not applicable.
Not applicable.
CGA 580
CGA 680
CGA 677
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices
indicated in Section 6 (Accidental Release Measures). Make certain application equipment is locked and tagged-out
safely. Always use product in areas where adequate ventilation is provided.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation. Local exhaust ventilation is
preferred, because it prevents gas dispersion into the work place by eliminating it at its source. If appropriate, install
automatic monitoring equipment to detect the level of oxygen.
RESPIRATORY PROTECTION: Maintain oxygen levels above 19.5% in the workplace. Use only respiratory
protection authorized in the U.S. Federal OSHA Respiratory Protection Standard (29 CFR 1910.134), or equivalent
U.S. State standards, and Canadian CSA Standard Z94.4-93. Oxygen levels below 19.5% are considered IDLH by
OSHA. In such atmospheres, use of a full-facepiece pressure/demand SCBA or a full facepiece, supplied air
respirator with auxiliary self-contained air supply is required under OSHA’s Respiratory Protection Standard
(1910.134-1998).
EYE PROTECTION: Safety glasses.
HAND PROTECTION: Wear leather gloves or glove protection appropriate to the specific operation for which this
product is used.
BODY PROTECTION: Use body protection appropriate for task. Safety shoes are recommended when handling
cylinders.
9. PHYSICAL and CHEMICAL PROPERTIES
GAS DENSITY @ 21.1°C (70°F) and 1 atm: 0.3416 lbs ft3 (5.472 kg/m3)
BOILING POINT @ 1 atm: -108.2°C (-162.6°F)
FREEZING/MELTING POINT @ 10 psig: -168°F (-111°C)
SPECIFIC GRAVITY (air = 1) @ 21.1°C (70°F): 4.560
pH: Not applicable.
SOLUBILITY IN WATER vol/vol @ 20°C (68°F) and 1 atm: 0.108
MOLECULAR WEIGHT: 131.3
EVAPORATION RATE (nBuAc = 1): Not applicable.
EXPANSION RATIO: Not applicable.
ODOR THRESHOLD: Not applicable. Odorless.
SPECIFIC VOLUME (ft3/lb): 2.927
VAPOR PRESSURE @ 21.1°C (70°F) psig: Not applicable.
COEFFICIENT WATER/OIL DISTRIBUTION: Not applicable.
APPEARANCE AND COLOR: This product is a colorless, odorless gas.
HOW TO DETECT THIS SUBSTANCE (warning properties): There are no unusual warning properties associated
with a release of this product.
10. STABILITY and REACTIVITY
STABILITY: Normally stable, inert gas.
DECOMPOSITION PRODUCTS: None.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: None. Xenon is an inert gas.
HAZARDOUS POLYMERIZATION: Will not occur.
XENON - Xe MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 4 OF 7
10. STABILITY and REACTIVITY (Continued)
CONDITIONS TO AVOID: Avoid exposing cylinders to extremely high temperatures, which could cause the
cylinders to rupture or burst.
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: There are no specific toxicology data for Xenon. Xenon is a simple asphyxiant, which acts to
displace oxygen in the environment.
SUSPECTED CANCER AGENT: Xenon is not found on the following lists: FEDERAL OSHA Z LIST, NTP,
CAL/OSHA, IARC, and therefore is not considered to be, nor suspected to be a cancer-causing agent by these
agencies.
IRRITANCY OF PRODUCT: Not applicable.
SENSITIZATION OF PRODUCT: Xenon is not a sensitizer.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects Xenon on the
human reproductive system.
Mutagenicity: Xenon is not expected to cause mutagenic effects in humans.
Embryotoxicity: Xenon is not expected to cause embryotoxic effects in humans.
Teratogenicity: Xenon is not expected to cause teratogenic effects in humans.
Reproductive Toxicity: Xenon is not expected to cause adverse reproductive effects in humans.
A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will
propagate through generation lines. An embryotoxin is a chemical which causes damage to a developing embryo
(i.e. within the first eight weeks of pregnancy in humans), but the damage does not propagate across generational
lines. A teratogen is a chemical which causes damage to a developing fetus, but the damage does not propagate
across generational lines. A reproductive toxin is any substance which interferes in any way with the reproductive
process.
BIOLOGICAL EXPOSURE INDICES (BEIs): Currently, Biological Exposure Indices (BEIs) are not applicable for
Xenon.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL STABILITY: Xenon occurs naturally in the atmosphere. The gas will be dissipated rapidly in
well-ventilated areas.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: Any adverse effect on animals would be related to oxygen
deficient environments. No adverse effect is anticipated to occur to plant-life, except for frost produced in the
presence of rapidly expanding gases.
EFFECT OF CHEMICAL ON AQUATIC LIFE: No evidence is currently available on this product’s effects on aquatic
life.
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate Federal, State,
and local regulations. Return cylinders with any residual product to Air Liquide. Do not dispose of locally.
For emergency disposal, secure the cylinder and slowly discharge the gas to the atmosphere in a well-ventilated
area or outdoors.
14. TRANSPORTATION INFORMATION
THIS MATERIAL IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF
TRANSPORTATION.
PROPER SHIPPING NAME:
Xenon, compressed
HAZARD CLASS NUMBER and DESCRIPTION: 2.2 (Non-Flammable Gas)
UN IDENTIFICATION NUMBER:
UN 2036
PACKING GROUP:
Not applicable.
DOT LABEL(S) REQUIRED:
Non-Flammable Gas
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (1996): 121
MARINE POLLUTANT: Xenon is not classified by the DOT as a Marine Pollutant (as defined by 49 CFR 172.101,
Appendix B).
XENON - Xe MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 5 OF 7
14. TRANSPORTATION INFORMATION (Continued)
SPECIAL SHIPPING INFORMATION: Cylinders should be transported in a secure position, in a well-ventilated
vehicle. The transportation of compressed gas cylinders in automobiles or in closed-body vehicles present serious
safety hazards and should be discouraged.
NOTE: Shipment of compressed gas cylinders which have not been filled with the owners consent is a violation of
Federal law (49 CFR, Part 173.301 (b).
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: THIS MATERIAL IS
CONSIDERED AS DANGEROUS GOODS. Use the above information for the preparation of Canadian Shipments.
15. REGULATORY INFORMATION
SARA REPORTING REQUIREMENTS: Xenon is not subject to the reporting requirements of Sections 302, 304
and 313 of Title III of the Superfund Amendments and Reauthorization Act.
SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for Xenon. The
default Federal MSDS submission and inventory requirement filing threshold of 10,000 lbs (4,540 kg) therefore
applies, per 40 CFR 370.20.
TSCA INVENTORY STATUS: Xenon is listed on the TSCA Inventory.
CERCLA REPORTABLE QUANTITIES (RQ): Not applicable.
CALIFORNIA PROPOSITION 65: Xenon is not on the California Proposition 65 lists.
STATE REGULATORY INFORMATION: Xenon is covered under the following specific State regulations:
Alaska - Designated Toxic and Hazardous
Substances: No.
California - Permissible Exposure Limits
for Chemical Contaminants: No.
Florida - Substance List: No.
Illinois - Toxic Substance List: No.
Kansas - Section 302/313 List: No.
Massachusetts - Substance List: No.
Minnesota
List
of
Hazardous
Substances: No.
Missouri - Employer Information/Toxic
Substance List: No.
New Jersey - Right to Know Hazardous
Substance List: Xenon.
North Dakota - List of Hazardous
Chemicals, Reportable Quantities:
No.
Pennsylvania - Hazardous Substance
List: No.
Rhode Island - Hazardous Substance
List: No.
Texas - Hazardous Substance List: No.
West Virginia - Hazardous Substance
List: No.
Wisconsin - Toxic and Hazardous
Substances: No.
OTHER FEDERAL REGULATIONS:
• Xenon does not contain any Class I or Class II ozone depleting chemicals (40 CFR part 82).
• Xenon is not listed as a Regulated Substance, per 40 CFR, Part 68, of the Risk Management for Chemical
Accidental Release Prevention.
• Xenon is not subject to the reporting requirements of Section 112(r) of the Clean Air Act.
• Xenon is not listed in Appendix A as a highly hazardous chemical, per 29 CFR 1910.119: Process Safety
Management of Highly Hazardous Chemicals.
OTHER CANADIAN REGULATIONS: Xenon is categorized as a Controlled Product, Hazard Class A, as per the
Controlled Product Regulations.
XENON - Xe MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 6 OF 7
16. OTHER INFORMATION
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
NFPA RATING
FLAMMABILITY
HEALTH
0
HEALTH
0
0
0
(BLUE)
REACTIVITY
FLAMMABILITY
(RED)
0
(YELLOW)
0
OTHER
REACTIVITY
PROTECTIVE EQUIPMENT B
EYES
RESPIRATORY
HANDS
BODY
See Section 8
For routine industrial applications
MIXTURES: When two or more gases or liquefied gases are
mixed, their hazardous properties may combine to create additional, unexpected hazards. Obtain and evaluate
the safety information for each component before you produce the mixture. Consult an Industrial Hygienist or
other trained person when you make your safety evaluation of the end product. Remember, gases and liquids
have properties which can cause serious injury or death.
Further information about Xenon can be found in the following pamphlets published by: Compressed Gas
Association Inc. (CGA), 4221 Walney Road 5th floor, Chantilly, VA 20151-2923. Telephone: (703) 788-2700.
P-1
P-14
SB-2
AV-1
PREPARED BY:
“Safe Handling of Compressed Gases in Containers”
"Accident Prevention in Oxygen-Rich, Oxygen-Deficient Atmospheres"
"Oxygen Deficient Atmospheres"
"Safe Handling and Storage of Compressed Gases"
“Handbook of Compressed Gases”
CHEMICAL SAFETY ASSOCIATES, Inc.
9163 Chesapeake Drive, San Diego, CA 92123-1002
858/565-0302
Fax on Demand:
1-800/231-1366
This Material Safety Data Sheet is offered pursuant to OSHA’s Hazard Communication Standard, 29 CFR, 1910.1200. Other government
regulations must be reviewed for applicability to this product. To the best of Air Liquide’s knowledge, the information contained herein is
reliable and accurate as of this date; however, accuracy, suitability or completeness are not guaranteed and no warranties of any type, either
express or implied, are provided. The information contained herein relates only to this specific product. If this product is combined with other
materials, all component properties must be considered. Data may be changed from time to time. Be sure to consult the latest edition.
XENON - Xe MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 7 OF 7
MATERIAL SAFETY
DATA SHEET
Prepared to U.S. OSHA, CMA, ANSI and Canadian WHMIS Standards
1. PRODUCT AND COMPANY INFORMATION
CHEMICAL NAME; CLASS:
HELIUM
SYNONYMS: Helium USP
CHEMICAL FAMILY NAME: Inert Gas
FORMULA: He
Document Number: 10047
Medical and general analytical or
synthetic chemical uses.
PRODUCT USE:
MANUFACTURED/SUPPLIED BY:
ADDRESS:
EMERGENCY PHONE:
2700 Post Oak Drive
Houston, TX 77056-8229
CHEMTREC: 1-800-424-9300
BUSINESS PHONE:
General MSDS Information 1-713/896-2896
Fax on Demand:
1-800/231-1366
HELIUM - HE MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 1 OF 8
2. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: Helium is a colorless, odorless gas.
releases of this gas is asphyxiation, by displacement of oxygen.
The main health hazard associated with
SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE: The most significant route of over-exposure for
Helium is by inhalation.
INHALATION: High concentrations of this gas can cause an oxygen-deficient environment. Individuals breathing
such an atmosphere may experience symptoms which include headaches, ringing in ears, dizziness, drowsiness,
unconsciousness, nausea, vomiting, and depression of all the senses. Under some circumstances of overexposure, death may occur. The following effects associated with various levels of oxygen are as follows:
CONCENTRATION
SYMPTOM OF EXPOSURE
12-16% Oxygen:
Breathing and pulse rate increased, muscular coordination slightly disturbed.
10-14% Oxygen:
Emotional upset, abnormal fatigue, disturbed respiration.
6-10% Oxygen:
Nausea and vomiting, collapse or loss of consciousness.
Below 6%:
Convulsive movements, possible respiratory collapse, and death.
WARNING: The practice of intentionally inhaling helium for a voice altering effect is extremely dangerous and may
result in serious injury or death.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. Over-exposure to Helium may
cause the following health effects:
ACUTE: The most significant hazard associated with this gas is inhalation of oxygen-deficient atmospheres.
Symptoms of oxygen deficiency include respiratory difficulty, ringing in ears, headaches, shortness of breath,
wheezing, headache, dizziness, indigestion, nausea, and, at high concentrations, unconsciousness or death may
occur. The skin of a victim of over-exposure may have a blue color.
CHRONIC: There are currently no known adverse health effects associated with chronic exposure to this gas.
TARGET ORGANS: ACUTE: Respiratory system.
CHRONIC: None known.
3. COMPOSITION and INFORMATION ON INGREDIENTS
CHEMICAL NAME
CAS #
mole %
EXPOSURE LIMITS IN AIR
ACGIH
Helium
7440-59-7
Maximum Impurities
OSHA
NIOSH
TLV
STEL
PEL
STEL
IDLH
ppm
ppm
ppm
ppm
ppm
OTHER
ppm
99.95%
There are no specific exposure limits for Helium. Helium is a simple asphyxiant
(SA). Oxygen levels should be maintained above 19.5%.
< .05%
None of the trace impurities in Helium contribute significantly to the hazards
associated with the product. All hazard information pertinent to Helium has been
provided in this Material Safety Data Sheet, per the requirements of the OSHA
Hazard Communication Standard (29 CFR 1910.1200) and State equivalents
standards.
This material is classified as hazardous under OSHA regulations in the United States and the WHMIS in
Canada.
NE = Not Established.
See Section 16 for Definitions of Terms Used.
NOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-2004 format. This product has been
classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
HELIUM - HE MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 2 OF 8
4. FIRST-AID MEASURES
RESCUERS SHOULD NOT ATTEMPT TO RETRIEVE VICTIMS OF EXPOSURE TO HELIUM
WITHOUT ADEQUATE PERSONAL PROTECTIVE EQUIPMENT. At a minimum, Self-Contained
Breathing Apparatus should be worn
Remove victim(s) to fresh air, as quickly as possible. Trained personnel should administer supplemental oxygen
and/or cardio-pulmonary resuscitation, if necessary. Only trained personnel should administer supplemental oxygen.
Victim(s) must be taken for medical attention. Rescuers should be taken for medical attention, if necessary. Take
copy of label and MSDS to physician or other health professional with victim(s).
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing respiratory conditions may be aggravated
by over-exposure to Helium.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and reduce over-exposure.
5. FIRE-FIGHTING MEASURES
FLASH POINT: Not applicable.
AUTOIGNITION TEMPERATURE: Not applicable.
FLAMMABLE LIMITS (in air by volume, %):
Lower (LEL): Not applicable.
Upper (UEL): Not applicable.
FIRE EXTINGUISHING MATERIALS: Non-flammable, inert gas.
surrounding fire.
Use extinguishing media appropriate for
UNUSUAL FIRE AND EXPLOSION HAZARDS: Helium does not burn; however, containers, when involved in fire,
may rupture or burst in the heat of the fire.
Explosion Sensitivity to Mechanical Impact: Not Sensitive.
Explosion Sensitivity to Static Discharge: Not Sensitive.
SPECIAL FIRE-FIGHTING PROCEDURES: Structural fire-fighters must wear Self-Contained Breathing Apparatus
and full protective equipment.
6. ACCIDENTAL RELEASE MEASURES
LEAK RESPONSE: Evacuate immediate area. Uncontrolled releases should be responded to by trained personnel
using pre-planned procedures. Proper protective equipment should be used. In case of a leak, clear the affected
area, protect people, and respond with trained personnel. Minimum Personal Protective Equipment should be
Level B: Self-Contained Breathing Apparatus. Locate and seal the source of the leaking gas. Allow the gas,
which is lighter than air to dissipate. Monitor the surrounding area for oxygen. The atmosphere must have at least
19.5 percent oxygen before personnel can be allowed in the area without Self-Contained Breathing Apparatus. If
leaking incidentally from the cylinder or its valve, contact your supplier.
7. HANDLING AND STORAGE
WORK PRACTICES AND HYGIENE PRACTICES: Be aware of any signs of dizziness or fatigue; exposures to
fatal concentrations of Helium could occur without any significant warning symptoms, due to oxygen deficiency.
STORAGE AND HANDLING PRACTICES: Cylinders should be stored upright and be firmly secured to prevent
falling or being knocked-over. Cylinders can be stored in the open, but in such cases, should be protected against
extremes of weather and from the dampness of the ground to prevent rusting. Cylinders should be stored in dry,
well-ventilated areas away from sources of heat, ignition and direct sunlight. Keep storage area clear of materials
which can burn. Do not allow area where cylinders are stored to exceed 52°C (125°F). Store containers away from
heavily trafficked areas and emergency exits. Store away from process and production areas, away from elevators,
building and room exits or main aisles leading to exits. Protect cylinders against physical damage.
Use a check valve or other protective device in the discharge line to prevent hazardous backflow. Never tamper with
pressure relief valves and cylinders.
Keep the smallest amount necessary on-site at any one time. Full and empty cylinders should be segregated. Use
a first-in, first-out inventory systems to prevent full containers from being stored for long periods of time.
HELIUM - HE MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 3 OF 8
7. HANDLING AND STORAGE (Continued)
SPECIAL PRECAUTIONS FOR HANDLING GAS CYLINDERS: Compressed gases can present significant safety
hazards. The following rules are applicable to work situations in which cylinders are being used.
Before Use: Move cylinders with a suitable hand-truck. Do not drag, slide or roll cylinders. Do not drop cylinders or
permit them to strike each other. Secure cylinders firmly. Leave the valve protection cap (where provided) in-place
until cylinder is ready for use.
During Use: Use designated CGA fittings and other support equipment. Do not use adapters. Do not heat cylinder
by any means to increase the discharge rate of the product from the cylinder. Do not use oils or grease on gashandling fittings or equipment. Immediately contact the supplier if there are any difficulties associated with operating
cylinder valve. Never insert an object (e.g wrench, screwdriver, pry bar, etc.) into valve cap openings. Doing so may
damage valve, causing a leak to occur. Use an adjustable strap wrench to remove over-tight or rusted caps. Never
strike an arc, on a compressed gas cylinder or make a cylinder part of and electric circuit.
After Use: Close main cylinder valve. Replace valve protection cap. Mark empty cylinders “EMPTY”.
NOTE: Use only DOT or ASME code containers designed for gas storage. Close valve after each use and when
empty. Cylinders must not be recharged except by or with the consent of owner.
STANDARD VALVE CONNECTIONS FOR U.S. AND CANADA: Use the proper CGA connections, DO NOT
USE ADAPTERS:
THREADED:
0-3000 psig
CGA 580
3001-5500 psig
CGA 680
5501-7500 psig
CGA 677
PIN-INDEXED YOKE:
0-3000 psig
CGA 930 (Medical Use)
ULTRA HIGH INTEGRITY:
0-3000 psig
CGA 718
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices
indicated in Section 6 (Accidental Release Measures). Make certain application equipment is locked and tagged-out
safely. Always use product in areas where adequate ventilation is provided.
SPECIAL SAFETY PRECAUTIONS FOR FILLING OF HELIUM BALLOONS: Observe the following precautions
when handling compressed gas helium cylinders for balloon filing. Don’t let an accident spoil the fun of
using helium-filled balloons.
•
•
•
•
•
•
Never remove the cylinder valve protection cap until the cylinder is secured (chained, tied, etc.) in an up-right
position and ready for use.
WARNING: High Pressure Cylinder. If a cylinder would get knocked-over after the cap is removed, the
valve could be broken-off, causing the cylinder to be propelled violently.
Use only a regulator which is designed for balloon filling.
After attaching the balloon filling regulator and opening the valve, leak-check connections using a soap and
water solution. Do not Use equipment that is leaking.
Do not breath helium from the cylinders, filling regulators or from helium filled balloons.
Never allow children to operate balloon filling equipment.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation. Local exhaust ventilation is
preferred, because it prevents chemical dispersion into the work place by eliminating it at its source. If appropriate,
install automatic monitoring equipment to detect the level of oxygen.
RESPIRATORY PROTECTION: Maintain oxygen levels above 19.5% in the workplace. Use supplied air
respiratory protection if oxygen levels are below 19.5% or during emergency response to a release of Helium. If
respiratory protection is required, follow the requirements of the Federal OSHA Respiratory Protection Standard (29
CFR 1910.134), or equivalent State standards. If respiratory protection is needed, use only protection authorized in
the U.S. Federal OSHA Standard (29 CFR 1910.134), applicable U.S. State regulations, or the Canadian CSA
Standard Z94.4-93. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a fullfacepiece pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air supply is
required under OSHAs Respiratory Protection Standard (1910.134-1998).
HELIUM - HE MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 4 OF 8
8. EXPOSURE CONTROLS - PERSONAL PROTECTION (Continued)
EYE PROTECTION: Safety glasses. If necessary, refer to U.S. OSHA 29 CFR 1910.133, or Canadian Standards.
HAND PROTECTION: Wear gloves when handling cylinders of Helium. Otherwise, wear glove protection
appropriate to the specific operation for which Helium is used. If necessary, refer to U.S. OSHA 29 CFR 1910.138
or appropriate Standards of Canada.
BODY PROTECTION: Use body protection appropriate for task. Safety shoes are recommended when handling
cylinders. If a hazard of injury to the feet exists due to falling objects, rolling objects, where objects may pierce the
soles of the feet or where employee’s feet may be exposed to electrical hazards, use foot protection, as described in
U.S. OSHA 29 CFR.
9. PHYSICAL and CHEMICAL PROPERTIES
GAS DENSITY @ 0°C (32°F) and 1 atm: 0.0103 lbs/cu ft (1.165 kg/m3)
BOILING POINT: -268.9°C (-452.1°F)
FREEZING/MELTING POINT @ 10 psig: Not Applicable.
SPECIFIC GRAVITY (air = 1) @ 21.1°C (70°F): 0.1381
pH: Not applicable.
SOLUBILITY IN WATER vol/vol @ 0°C (32°F) and 1 atm: 0.0094 MOLECULAR WEIGHT: 4.00
EVAPORATION RATE (nBuAc = 1): Not applicable.
EXPANSION RATIO: Not applicable.
ODOR THRESHOLD: Not applicable. Odorless.
SPECIFIC VOLUME (ft3/lb): 96.7
VAPOR PRESSURE @ 21.1°C (70°F) (psig): Not applicable.
COEFFICIENT WATER/OIL DISTRIBUTION: Not applicable.
APPEARANCE AND COLOR: Helium is a colorless, odorless gas at normal temperature and pressure..
HOW TO DETECT THIS SUBSTANCE (warning properties): There are no unusual warning properties associated
with a release of Helium.
10. STABILITY and REACTIVITY
STABILITY: Normally stable, inert gas.
DECOMPOSITION PRODUCTS: None.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: None. Helium is an inert gas.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Cylinders exposed to high temperatures or direct flame can rupture or burst.
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: There are no specific toxicology data for Helium. Helium is a simple asphyxiant, which acts to
displace oxygen in the environment.
SUSPECTED CANCER AGENT: Helium is not found on the following lists: FEDERAL OSHA Z LIST, NTP,
CAL/OSHA, IARC, and therefore is not considered to be, nor suspected to be a cancer-causing agent by these
agencies.
IRRITANCY OF PRODUCT: Not applicable.
SENSITIZATION OF PRODUCT: Helium is not a sensitizer.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects Helium on the
human reproductive system.
Mutagenicity: Helium is not expected to cause mutagenic effects in humans.
Embryotoxcity: No embryotoxic effects have been described for Helium.
Teratogenicity: Helium is not expected to cause teratogenic effects in humans.
Reproductive Toxicity: Helium is not expected to cause adverse reproductive effects in humans.
A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will
propagate through generation lines. An embryotoxin is a chemical which causes damage to a developing embryo
(i.e. within the first eight weeks of pregnancy in humans), but the damage does not propagate across generational
lines. A teratogen is a chemical which causes damage to a developing fetus, but the damage does not propagate
across generational lines. A reproductive toxin is any substance which interferes in any way with the reproductive
process.
BIOLOGICAL EXPOSURE INDICES (BEIs): Currently, Biological Exposure Indices (BEIs) are not applicable for
Helium.
HELIUM - HE MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 5 OF 8
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL STABILITY: Helium occurs naturally in the atmosphere. The gas will be dissipated rapidly in
well-ventilated areas.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: Any adverse effect on animals would be related to oxygen
deficient environments. No adverse effect is anticipated to occur to plant-life, except for frost produced in the
presence of rapidly expanding gases.
EFFECT OF CHEMICAL ON AQUATIC LIFE: No evidence is currently available on Helium’s effects on aquatic life.
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate Federal, State,
and local regulations. Return cylinders with any residual product to Air Liquide. Do not dispose of locally.
For emergency disposal, secure the cylinder and slowly discharge the gas to the atmosphere in a well-ventilated
area or outdoors.
14. TRANSPORTATION INFORMATION
THIS MATERIAL IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF
TRANSPORTATION.
PROPER SHIPPING NAME:
Helium, compressed
HAZARD CLASS NUMBER and DESCRIPTION:
2.2 (Non-Flammable Gas)
UN IDENTIFICATION NUMBER:
UN 1046
PACKING GROUP:
Not applicable.
DOT LABEL(S) REQUIRED:
Non-Flammable Gas
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (2000): 121
MARINE POLLUTANT: Helium is not classified by the DOT as a Marine Pollutant (as defined by 49 CFR 172.101,
Appendix B).
SPECIAL SHIPPING INFORMATION: Cylinders should be transported in a secure position, in a well-ventilated
vehicle. The transportation of compressed gas cylinders in automobiles or in closed-body vehicles present
serious safety hazards and should be discouraged.
NOTE: Shipment of compressed gas cylinders which have not been filled with the owners consent is a violation of
Federal law (49 CFR, Part 173.301 (b).
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This material is
considered as dangerous goods, per regulations of Transport Canada. Use the above U.S. DOT information for
the preparation of Canadian Shipments.
15. REGULATORY INFORMATION
ADDITIONAL U.S. REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS: Helium is not subject to the reporting requirements of Sections 302,
304 and 313 of Title III of the Superfund Amendments and Reauthorization Act.
U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for any
component of this product. The default Federal MSDS submission and inventory requirement filing threshold of
10,000 lb (4,540 kg) therefore applies, per 40 CFR 370.20.
U.S. TSCA INVENTORY STATUS: Helium is listed on the TSCA Inventory.
U.S. CERCLA REPORTABLE QUANTITY (RQ): Not applicable.
OTHER U.S. FEDERAL REGULATIONS:
• Generally recognized as safe (GRAS), as a direct human food ingredient when used as processing agent, per 21,
CFR, 184.1540. Helium USP is regulated by the FDA as a prescription drug.
• Depending on specific operations involving the use of Helium, the regulations of the Process Safety Management
of Highly Hazardous Chemicals may be applicable (29 CFR 1910.119). Under this regulation Helium is not listed
in Appendix A.
• Helium does not contain any Class I or Class II ozone depleting chemicals (40 CFR part 82).
• Helium is not listed as a Regulated Substance, per 40 CFR, Part 68, of the Risk Management for Chemical
Releases.
HELIUM - HE MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 6 OF 8
15. REGULATORY INFORMATION (Continued)
U.S. STATE REGULATORY INFORMATION: Helium is covered under the following specific State regulations:
Alaska - Designated Toxic and Hazardous
Substances: Helium.
California - Permissible Exposure Limits
for Chemical Contaminants: Helium.
Florida - Substance List: Helium.
Illinois - Toxic Substance List: Helium.
Kansas - Section 302/313 List: No.
Massachusetts - Substance List: Helium.
Minnesota - List of Hazardous Substances:
Helium.
Missouri - Employer Information/Toxic
Substance List: Helium
New Jersey - Right to Know Hazardous
Substance List: Helium.
North Dakota - List of Hazardous
Chemicals, Reportable Quantities: No.
Pennsylvania - Hazardous Substance List:
Helium.
Rhode Island - Hazardous Substance List:
Helium.
Texas - Hazardous Substance List: No.
West Virginia - Hazardous Substance List:
No.
Wisconsin - Toxic and Hazardous
Substances: No.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): Helium is not
on the California Proposition 65 lists.
OTHER CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: Helium is listed on the DSL Inventory.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: Helium is not
on the CEPA Priorities Substances Lists.
CANADIAN WHMIS REGULATIONS: Helium is categorized as a Controlled Product, Hazard Class A as per the
Controlled Product Regulations.
16. OTHER INFORMATION
NFPA RATING
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
FLAMMABILITY
HEALTH
0
HEALTH
0
0
0
(BLUE)
REACTIVITY
FLAMMABILITY
(RED)
0
(YELLOW)
0
OTHER
REACTIVITY
PROTECTIVE EQUIPMENT
EYES
RESPIRATORY
HANDS
B
BODY
See Section 8
For routine industrial applications
MIXTURES: When two or more gases or liquefied
gases are mixed, their hazardous properties may combine to create additional, unexpected hazards. Obtain and
evaluate the safety information for each component before you produce the mixture. Consult an Industrial
Hygienist or other trained person when you make your safety evaluation of the end product. Remember, gases
and liquids have properties which can cause serious injury or death.
HELIUM - HE MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 7 OF 8
16. OTHER INFORMATION (Continued)
Further information about Helium can be found in the following pamphlets published by: Compressed Gas
Association Inc. (CGA), 4221 Walney Road 5th floor, Chantilly, VA 20151-2923. Telephone: (703) 788-2700.
G-9.1
P-1
P-9
P-14
SB-2
AV-1
PREPARED BY:
‘’Commodity Specification for Helium”
“Safe Handling of Compressed Gases in Containers”
“Inert Gases, Argon, Nitrogen and Helium”
“Accident Prevention in Oxygen-Rich, Oxygen-Deficient Atmospheres”
“Oxygen Deficient Atmospheres”
“Safe Handling and Storage of Compressed Gases”
“Handbook of Compressed Gases”
CHEMICAL SAFETY ASSOCIATES, Inc.
9163 Chesapeake Drive, San Diego, CA 92123-1002
858/565-0302
Fax on Demand:
1-800/231-1366
This Material Safety Data Sheet is offered pursuant to OSHA’s Hazard Communication Standard, 29 CFR, 1910.1200. Other government
regulations must be reviewed for applicability to Helium. To the best of Air Liquide’s knowledge, the information contained herein is reliable
and accurate as of this date; however, accuracy, suitability or completeness are not guaranteed and no warranties of any type, either express
or implied, are provided. The information contained herein relates only to this specific product. If Helium is combined with other materials, all
component properties must be considered. Data may be changed from time to time. Be sure to consult the latest edition.
HELIUM - HE MSDS
EFFECTIVE DATE: AUGUST 31, 2005
PAGE 8 OF 8
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Instructions for Clean Up
of
Broken or Burnt ZnSe Lenses
Broken ZnSe Lenses
Toxicity studies to determine the health risks of handling or ingesting ZnSe have shown
that this material is not toxic. However, long-term affects of ZnSe dust inhalation are
unknown. ZnSe is normally machined or ground using wet slurries to minimize any dust
which could result in inhalation. In general, good work practices should be followed
such as washing hands after handling ZnSe to avoid any transfer of ZnSe dust into the
mouth from handling food, etc.
If a ZnSe lens is broken, II-VI recommends that large pieces be gathered and placed in
an appropriate container for later disposal. Small dust size pieces should be wiped up
with a wet cloth or paper towel to avoid airborne dust. Broken or scrap ZnSe pieces
should be disposed of in a properly licensed industrial disposal facility. ZnSe optics can
be returned to II-VI for proper disposal.
Burnt ZnSe Lenses
If a ZnSe lens is burnt or melted due to the absorption of the CO2 laser, the ZnSe will
decompose into ZnO and SeO2. The clean up of the decomposed ZnSe should be
conducted by wiping the area with a wet cloth or paper towel to avoid airborne dust.
The decomposed ZnSe may require abrasion to remove the ZnO and SeO2 from
surrounding lens mounts and beam delivery tubes. This should be cleaned up with a
piece of wet sandpaper or other like method. The resulting material should be properly
disposed of in a properly licensed industrial waste facility.
Disposal of Used or Broken Optics
Please contact our corporate offices at 724-352-4455 to reach our Warranty Return
group who will issue a Return Authorization Number for the return of used or broken
optics to be disposed of.
12-6-05
CI-O-02
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CI-O-03
SILICON
MATERIAL SAFETY DATA SHEET
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product Identity: Silicon
NOTE: In the form in which this product is sold it is not regulated. This Material Safety Data Sheet is provided for
information only.
MSDS Preparer:
Lattice Materials Corp.
516 E. Tamarack St.
Bozeman, MT 59715
Date of Last Review/Edit: May 2, 2003
Product Use: Silicon is used to make elements for infrared optical devices, and in solar arrays and panels to
generate electricity.
SECTION 2. COMPOSITION / INFORMATION ON INGREDIENTS
Ingredient
Silicon
Approximate Percent
by Weight
100
C.A.S. Number
7440-21-3
Occupational Exposure Limits
LD50/LC50
(OELs)
Species & Route
OSHA PEL
15 mg/m
3
ACGIH TLV
10 mg/m
3
No Data
NOTE: OELs for individual jurisdictions may differ from OSHA PELs. Check with local authorities for the applicable OELs in your jurisdiction.
OSHA – Occupational Safety and Health Administration; ACGIH – American Conference of Governmental Industrial Hygienists; OEL –
Occupational Exposure Limit, PEL – Permissible Exposure Limit, TLV – Threshold Limit Value, REL – Recommended Exposure Limit.
Trade Names and Synonyms: None.
SECTION 3. HAZARDS IDENTIFICATION
Emergency Overview: Silicon is relatively non-toxic and poses little immediate hazard to personnel or the
environment in an emergency situation.
Potential Health Effects: Elemental silicon is relatively non-toxic to humans by all routes of exposure. No
chronic health effects have been reported in humans occupationally exposed to silicon. It is not considered a
human carcinogen by the OSHA, NTP, ACGIH, IARC or EU. (see Toxicological Information, Section 11).
May 2, 2003
CI-O-04
Silicon
1
Potential environmental Effects: Silicon has low toxicity and limited bioavailability in the environment. It poses
no immediate ecological risk. However, contamination of soil and water should be prevented. (see Ecological
Information, Section 12)
SECTION 4. FIRST AID MEASURES
Eye Contact: Flush with warm, running water including under the eyelids, to remove foreign object. If irritation
persists, seek medical attention.
Skin Contact: Remove contaminated clothing and wash affected area with soap and warm water.
Inhalation: Remove victim from exposure area to fresh air immediately. If breathing has stopped, give artificial
respiration. Medical oxygen may be administered, if available, where breathing is difficult. Seek immediate
medical attention.
Ingestion: If victim is conscious, dilute stomach contents with 2-4 cupfuls of water or milk. Do not induce
vomiting. Seek medical attention immediately and bring a copy of this MSDS. Never give anything by mouth to
an unconscious person.
SECTION 5. FIRE FIGHTING MEASURES
Fire and Explosion Hazards: Elemental silicon is flammable when exposed to flame or by chemical reaction
with oxidizing agents. May have a violent reaction with alkali carbonates; oxidants; (Al+PbO); Ca; CsC2; CaF2; F2;
IF3; MnF3; Rb2C2; FNO; AgF; and NaK alloy. When heated, it will react with water or steam to produce hydrogen
gas.
Extinguishing Media: Flammable solid in powdered form. If involved in fire, do not use water, CO2, or
halogenated extinguishing agents. Use dry chemical extinguishing agents, dry sand, or dry ground dolomite.
Fire Fighting: No special firefighting procedures needed. Use normal procedures which include wearing
NIOSH/MSHA approved self-contained breathing apparatus, flame and chemical resistant clothing; hats, boots
and gloves. If without risk, remove material from fire area. Cool container with water from maximum distance.
Fumes from fire are hazardous. Isolate runoff to prevent environmental pollution.
Flashpoint and Method: Not Applicable
Upper and Lower Flammable Limit: Not Applicable
SECTION 6. ACCIDENTAL RELEASE MEASURES
Procedures for Cleanup: Control source of spillage if possible to do so safely. Clean up spilled material
immediately, observing precautions in Section 8, Personal Protection and using method which will minimize dust
generation (e.g., vacuum solids, dampen material and shovel or wet sweep). Return uncontaminated spilled
material to the process if possible. Place contaminated materials in suitable labeled containers for recovery or
disposal. Treat or dispose of waste material in accordance with all local, regional, and national requirements.
Personal Precautions: Protective clothing, gloves, and respirator equipment are recommended for persons
exposed to potentially hazardous levels of silicon dust. Close-fitting safety goggles may be necessary in some
circumstances to prevent eye contact with the dust.
May 2, 2003
CI-O-04
Silicon
2
Environmental Precautions: Silicon is considered to have low toxicity. However, there is limited information on
the effects and fate of silicon in the environment. Good management practices should be applied in the storage
and use of silicon and its compounds.
SECTION 7. HANDLING AND STORAGE
Store silicon in a dry, covered area away from incompatible materials and protect from physical damage. Solid
metal suspected of containing moisture should be THOROUGHLY DRIED before being added to a molten bath,
otherwise residual moisture could expand explosively and spatter molten material out of the bath. Always
practice good personal hygiene. Refrain from eating, drinking, or smoking in work areas. Thoroughly wash
hands in appropriate, designated areas before eating, drinking, or smoking. No special packaging materials are
required.
SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Protective Clothing: Gloves and coveralls or other work clothing are recommended to prevent prolonged or
repeated direct skin contact when silicon is processed. Eye protection should be worn. Where hot or molten
material is handled, heat resistant gloves, goggles or faceshield, and clothing to protect from hot material splash
should be worn. Safety type boots are recommended.
Ventilation: Use adequate local or general ventilation to maintain the concentration at or below the PEL, TLV.
Mechanical exhaust is recommended.
Respirators: Where dust or fumes are generated and cannot be controlled to within acceptable levels by
engineering means, use appropriate NIOSH-approved respiratory protection equipment (a 42CFR84 Class N, R.
or P-95 particulate filter cartridge).
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Steel gray pieces
Odor:
None
Physical State
Solid
pH
Not Applicable
Vapor Pressure:
1 mm at 1724°C
Vapor Density:
Not Applicable
Boiling Point/Range:
2355-2600°C
Freezing/Melting
Point Range:
1410-1420°C
Specific Gravity:
2.33 gm/cc
Evaporation Rate:
Not Applicable
Coefficient of Water/Oil
Distribution:
Not Applicable
Odor Threshold:
None
Solubility:
Insoluble in water
May 2, 2003
CI-O-04
Silicon
3
SECTION 10. STABILITY AND REACTIVITY
Stability & Reactivity: Stable under normal temperatures and pressures.
Incompatibilities: Alkali carbonates, (Al+PbO), Ca, Cs2C2, Cl2, CoF2, F2, IF3, MnF3, Rb2C2, FNO, AgF, NaK
alloy, water and steam.
Hazardous Decomposition Products: Hydrogen gas.
SECTION 11. TOXICOLOGICAL INFORMATION
General: To the best of our knowledge the chemical, physical and toxicological properties of silicon have not
been thoroughly investigated and recorded.
Acute:
Skin/Eyes: Direct contact with skin or eyes may cause mild local mechanical irritation.
Inhalation: Inhalation of silicon dust may be irritating to the respiratory system. Symptoms may include
coughing, sneezing and/or shortness of breath.
Ingestion: No acute health effects recorded.
Chronic: No chronic health effects recorded.
SECTION 12. ECOLOGICAL INFORMATION
As an element, silicon is insoluble and therefore, presents minimal environmental risk. However, little is known
about the toxicity of silicon compounds and care should be taken to prevent environmental contamination.
SECTION 13. DISPOSAL CONSIDERATIONS
If material cannot be returned to process, dispose of only in accordance with applicable regulations.
Notice to Reader
Although reasonable precautions have been taken in the preparation of the data contained herein, it is offered
solely for your information, consideration and investigation. Lattice Materials Corporation extends no warranty
and assumes no responsibility for the accuracy of the content and expressly disclaims all liability for reliance
thereon. This material safety data sheet provides guidelines for the safe handling and processing of this product;
it does not and cannot advise on all possible situations. Therefore, your specific use of this product should be
evaluated to determine if additional precautions are required. Individuals exposed to this product should read and
understand this information and be provided pertinent training prior to working with this product.
May 2, 2003
CI-O-04
Silicon
4
CI-O-05
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MATERIAL SAFETY DATA SHEET
SECTION 1 - PRODUCT AND COMPANY INFORMATION
PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
EMERGENCY PHONE NUMBERS (412) 434-4515 (U.S.)
(24 hours/day):
(514) 645-1320 (Canada)
01-800-00-21-400 (Mexico)
0532-3889090 (China)
TECHNICAL
(740) 363-9610 (DELAWARE, OH) 8:00 a.m. INFORMATION:
5:00 p.m. EST
PRODUCT SAFETY/MSDS INFORMATION: (412) 492-5555 7:00 a.m.
- 4:30 p.m. EST
Product ID:
DAR-1 (0808-T0)
PRODUCT NAME: DELSTAR ACRYLIC ENAMEL
SYNONYMS:
None
ISSUE DATE:
06/10/2005
EDITION NO.:
2
CHEMICAL
ALKYD
FAMILY:
EMERGENCY OVERVIEW:
Flammable. Keep away from heat, sparks, flames, and other sources of
ignition. Do not smoke. Extinguish all flames and pilot lights. Turn off
stoves, heaters, electrical motors, and other sources of ignition during
use and until all vapors/odors are gone.CAUSES SEVERE EYE
IRRITATION. MAY CAUSE MODERATE SKIN IRRITATION. VAPOR
AND/OR SPRAY MIST MAY BE HARMFUL IF INHALED. VAPOR
IRRITATES EYES, NOSE, AND THROAT.HARMFUL IF SWALLOWED.
SECTION 2 - COMPOSITION INFORMATION
The following ingredient(s) marked with an "x" are considered
hazardous under applicable U.S. OSHA and/or Canadian WHMIS
regulations. If no ingredients are listed, then there are no U.S. OSHA
and/or Canadian WHMIS hazardous ingredients in this product.
Material/
CAS Number
TITANIUM DIOXIDE
13463-67-7
XYLENES
1330-20-7
METHYL (N-AMYL) KETONE
110-43-0
ETHYL BENZENE
100-41-4
AROMATIC NAPHTHA
64742-95-6
NAPHTHA
8052-41-3
METHYL ETHYL KETONE
78-93-3
CARBON BLACK
1333-86-4
TOLUENE
108-88-3
AROMATIC HYDROCARBON
64742-94-5
Percent
Hazardous
40 - 70
X
40 - 70
X
7 - 13
X
5 - 10
X
1-5
X
1-5
X
1-5
X
1-5
X
0.5-1.5
X
0.5-1.5
X
SECTION 3 - HAZARDS IDENTIFICATION
ACUTE OVEREXPOSURE EFFECTS
EYE CONTACT:
Causes severe eye irritation. Redness, itching, burning sensation and
visual disturbances may indicate excessive eye contact.
SKIN CONTACT:
May cause moderate skin irritation. Dryness, itching, cracking, burning,
redness, and swelling are conditions associated with excessive skin
contact.
SKIN ABSORPTION:
Skin absorption not expected to occur.
INHALATION:
Vapor and/or spray mist may be harmful if inhaled. Vapor irritates eyes,
nose, and throat.
INGESTION:
Harmful if swallowed.
SIGNS & SYMPTOMS OF OVEREXPOSURE:
Repeated exposure to high vapor concentrations may cause irritation of
the respiratory system and permanent brain and nervous system
damage. Eye watering, headaches, nausea, dizziness and loss of
coordination are indications that solvent levels are too high. Intentional
misuse by deliberately concentrating and inhaling the contents can be
harmful or fatal. Dryness, itching, cracking, burning, redness, and
swelling are conditions associated with excessive skin contact.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Not
applicable.
CHRONIC OVEREXPOSURE EFFECTS
Avoid long-term and repeated contact.
Repeated exposure to vapors above recommended exposure limits (see
Section 8) may cause irritation of the respiratory system and permanent
brain and nervous system damage. Intentional misuse by deliberately
concentrating and inhaling the contents can be harmful or fatal. This
product contains toluene. Toluene inhalation in animals (greater than
1500 ppm) and intentional inhalation of toluene-containing products by
humans (e.g. glue) has caused adverse fetal development effects. High
exposures to xylenes in some animal studies have been reported to
cause health effects on the developing embryo and fetus. These effects
were often at levels toxic to the mother.
The effects of long-term, low level exposures to this product have not
been determined. Safe handling of this material on a long-term basis
should emphasize the prevention of all contact with this material to avoid
any effects from repetitive acute exposures. See Section 11, of this
MSDS for a detailed list of chronic health effects information available on
individual ingredients in this product.
SECTION 4 - FIRST AID MEASURES
If ingestion, irritation, any type of overexposure or symptoms of
overexposure occur during or persists after use of this product, contact a
POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN
immediately; have Material Safety Data Sheet information available.
EYE CONTACT:
Remove contact lens and pour a gentle stream of warm water through the
affected eye for at least 15 minutes. If irritation persists, contact a poison
control center, emergency room, or physician as further treatment may be
necessary.
SKIN CONTACT:
Run a gentle stream of water over the affected area for 15 minutes. A
mild soap may be used if available. If any symptoms persist, contact a
poison control center, emergency room, or physician as further treatment
may be necessary.
INHALATION:
Remove from area to fresh air. If symptomatic, contact a poison control
center, emergency room or physician for treatment information.
INGESTION:
Gently wipe or rinse the inside of the mouth with water. Sips of water
may be given. Never give anything by mouth to an unconscious person.
Contact a poison control center, emergency room or physician right away
as further treatment may be necessary.
SECTION 5 - FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
__________________________________________________________________
Page 1 of 5
CI-P-01
_______________________________________________________________________________________________________________
PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
Product ID: DAR-1 (0808-T0)
PRODUCT NAME: DELSTAR ACRYLIC ENAMEL
FLASHPOINT: 50 Degrees F ( 10 Degrees C)
FLASHPOINT TEST METHOD:
Pensky-Martens Closed Cup
UEL: Not Available.
LEL: 1.2
AUTOIGNITION TEMPERATURE:
Not Available.
EXTINGUISHING MEDIA:
Use National Fire Protection Association (NFPA) Class B extinguishers
(carbon dioxide, dry chemical, or universal aqueous film forming foam)
designed to extinguish NFPA Class IB flammable liquid fires. Water spray
may be ineffective. Water spray may be used to cool closed containers
to prevent pressure build-up and possible autoignition or explosion when
exposed to extreme heat.
PROTECTION OF FIREFIGHTERS:
Fire-fighters should wear self-contained breathing apparatus and full
protective clothing.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
When this product is used, the overspray and other combustible materials
such as paint booth filters, rags, masking materials, etc., contaminated by
coating material are subject to spontaneous combustion. Wetting the
contaminated materials and not packing them tightly together in refuse
containers will minimize the potential for this to occur. Keep this product
away from heat, sparks, flame, and other sources of ignition (i.e., pilot
lights, electric motors, static electricity). Invisible vapors can travel to a
source of ignition and flash back. Do not smoke while using this product.
Keep containers tightly closed when not in use. Closed containers may
explode when overheated. Do not apply to hot surfaces. Toxic gases
may form when this product comes in contact with extreme heat. May
produce hazardous decomposition products when exposed to extreme
heat. Extreme heat includes, but is not limited to, flame cutting, brazing,
and welding.
SECTION 6 - ACCIDENTAL RELEASE MEASURE
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
Provide maximum ventilation. Only personnel equipped with proper
respiratory, skin, and eye protection should be permitted in the area.
Remove all sources of ignition. Take up spilled material with sand,
vermiculite, or other noncombustible absorbent material and place in
clean, empty containers for disposal. Only the spilled material and the
absorbant should be placed in this container.
SECTION 7 - HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN DURING HANDLING AND STORAGE:
Vapors may collect in low areas. If this material is part of a multiple
component system, read the Material Safety Data Sheet(s) for the other
component or components before blending as the resulting mixture may
have the hazards of all of its parts. Containers should be grounded when
pouring. Avoid free fall of liquids in excess of a few inches.
STORAGE:
Do not store above 120 degrees F.(48 degrees C.). Store large quantities
in buildings designed and protected for storage of NFPA Class IB
flammable liquids.
SKIN/GLOVES:
Wear protective clothing to prevent skin contact. Apron and gloves
should be constructed of: nitrile rubber. No specific
permeation/degradation testing have been done on protective clothing for
this product. Recommendations for skin protection are based on
infrequent contact with this product. For frequent contact or total
immersion, contact a manufacturer of protective clothing for appropriate
chemical impervious equipment. Clean contaminated clothing and shoes.
RESPIRATOR:
Overexposure to vapors may be prevented by ensuring proper ventilation
controls, vapor exhaust or fresh air entry. A NIOSH- approved air
purifying respirator with the appropriate chemical cartridges or a positivepressure, air-supplied respirator may also reduce exposure. Read the
respirator manufacturer's instructions and literature carefully to determine
the type of airborne contaminants against which the respirator is effective,
its limitations, and how it is to be properly fitted and used. Provide general
dilution or local exhaust ventilation in volume and pattern to keep the
concentration of ingredients listed in Section 2 below the lowest
suggested exposure limits, the LEL below the stated limit, and to remove
decomposition products during welding or flame cutting.
GENERAL HYGIENE - ESTABLISHED EXPOSURE LIMITS
If Threshold Limit Values (TLVs) have been established by ACGIH,
OSHA, Ontario or PPG, they will be listed below. These limits are
intended for use in the practice of industrial hygiene as guidelines or
recommendations in the control of potential workplace health hazards.
These limits are not a relative index of toxicity and should not be used by
anyone without industrial hygiene training.
Material/
CAS Number
TITANIUM DIOXIDE
13463-67-7
XYLENES
1330-20-7
METHYL (N-AMYL)
KETONE
110-43-0
ETHYL BENZENE
100-41-4
NAPHTHA
8052-41-3
METHYL ETHYL
KETONE
78-93-3
CARBON BLACK
1333-86-4
TOLUENE
108-88-3
Percent
ACGIH TLV
3
ACGIH OSHA PEL
OSHA
STEL
STEL
3
Not
10 mg/m
Not
established
established
150 ppm
100 ppm
150 ppm
40 - 70
10 mg/m
40 - 70
100 ppm
7 - 13
50 ppm
Not
established
100 ppm
Not
established
5 - 10
100 ppm
125 ppm
100 ppm
125 ppm
1-5
100 ppm
100 ppm
1-5
200 ppm
Not
established
300 ppm
Not
established
300 ppm
1-5
3.5 mg/m3
0.5-1.5
200 ppm
Not
3.5 mg/m3
Not
established
established
S- 50 ppm
Not
100 ppm
150 ppm
established
Key: OSHA=Occupational Safety and Health Administration;
PEL=Permissable Exposure Limit; Ceiling=PEL Ceiling Limit; STEL=PEL
Short-Term Exposure Limit; Skin=OSHA Skin Designation.
SECTION 8 - EXPOSURE CONTROLS & PERSONAL PROTECTION
ENGINEERING CONTROLS:
Provide general dilution or local exhaust ventilation in volume and pattern
to keep the concentration of ingredients listed in Section 8 below the
lowest suggested exposure limits, the LEL below the stated limit, and to
remove decomposition products during welding or flame cutting.
PERSONAL PROTECTIVE EQUIPMENT
EYES:
Wear chemical-type splash goggles when possibility exists for eye
contact due to splashing or spraying liquid, airborne particles, or vapors.
__________________________________________________________________
Page 2 of 5
CI-P-01
_______________________________________________________________________________________________________________
PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
Product ID: DAR-1 (0808-T0)
PRODUCT NAME: DELSTAR ACRYLIC ENAMEL
Material/
CAS Number
TITANIUM DIOXIDE
13463-67-7
XYLENES
1330-20-7
METHYL (N-AMYL)
KETONE
110-43-0
ETHYL BENZENE
100-41-4
NAPHTHA
8052-41-3
METHYL ETHYL
KETONE
78-93-3
CARBON BLACK
1333-86-4
TOLUENE
108-88-3
Percent
40 - 70
Ontario
TWA
10 mg/m3
40 - 70
100 ppm
7 - 13
25 ppm
5 - 10
100 ppm
1-5
1-5
Ontario PPG IPEL
STEL
Not
Not
established established
150 ppm
Not
established
Not
Not
established established
PPG STEL
Not
established
Not
established
Not
established
Not
Not
established established
3
525 MG/m
Not
Not
Not
established established established
200 ppm
300 ppm
Not
250 PPM
established
1-5
3.5 mg/m3
0.5-1.5
50 PPM
125 ppm
Not
Not
Not
established established established
Not
Not
Not
established established established
Key: ACGIH=American Conference of Governmental Industrial
Hygienists; OSHA=Occupational Safety and Health Administration;
TLV=Threshold Limit Value; TWA=Time Weighted Average;
PEL=Permissible Exposure Limit; IPEL=Internal Permissible Exposure
Limit; Ceiling=TLV or PEL Ceiling Limit; STEL=TLV or PEL Short-Term
Exposure Limit; Skin= Skin Absorption Designation. [C- Ceiling Limit; SPotential Skin Aborption; R-Respirable Dust]
Additional Information Not applicable.
SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES
(FORMULA VALUES, NOT SALES SPECIFICATIONS)
SPECIFIC GRAVITY:
1.062
PHYSICAL STATE:
Liquid
Percent Solids:
43-74
Percent Volatile by Volume:
54-63
pH:
Not available.
ODOR THRESHOLD:
Not available.
Vapour Pressure:
7.1 mmHg
ODOR/APPEARANCE:
Viscous liquid with an odor
characteristic of the solvents listed in
Section 2.
VAPOR DENSITY:
HEAVIER THAN AIR
Evaporation Rate:
78
BOILING POINT OR RANGE:
172- 399Degrees F
Freezing Point or Range:
Not Applicable.
Melting Point or Range(°C):
Not Applicable.
Not Applicable.
Octanol/Water Partition
Coefficient:
WEIGHT PER GALLON:
8.85 (U.S.) / 10.6 (IMPERIAL)
SECTION 10 - STABILITY AND REACTIVITY
STABILITY:
This product is normally stable and will not undergo hazardous reactions.
CONDITIONS TO AVOID:
None Known.
INCOMPATIBLE MATERIALS:
Avoid contact with strong alkalies, strong mineral acids, or strong
oxidizing agents.
HAZARDOUS POLYMERIZATION:
None Known.
HAZARDOUS DECOMPOSITION PRODUCTS:
- Carbon monoxide - Carbon dioxide - Lower molecular weight polymer
fractions
SECTION 11 - TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Material/
CAS Number
XYLENES
1330-20-7
METHYL (N-AMYL)
KETONE
110-43-0
ETHYL BENZENE
100-41-4
AROMATIC
NAPHTHA
64742-95-6
NAPHTHA
8052-41-3
METHYL ETHYL
KETONE
78-93-3
CARBON BLACK
1333-86-4
TOLUENE
108-88-3
AROMATIC
HYDROCARBON
64742-94-5
Percent
40 - 70
ORAL
LD50 (g/kg)
4.30 g/kg
DERMAL
LD50 (g/kg)
1.70 g/kg
INHALATION
LC50 (mg/l)
21.88 mg/L. 4 h
7 - 13
1.67 g/kg
12.60 g/kg
Not Available
5 - 10
3.50 g/kg
17.80 g/kg
Not Available
1-5
8.40 g/kg
3.48 g/kg
Not Available
1-5
5.00 g/kg
Not Available
5.50 mg/L. 4 h
1-5
2.74 g/kg
13.00 g/kg
Not Available
1-5
15.40 g/kg
3.00 g/kg
Not Available
0.5-1.5
5.00 g/kg
12.12 g/kg
Not Available
0.5-1.5
3.20 g/kg
1.69 g/kg
.59 mg/L. 4 h
CHRONIC TOXICITY
Target Organs:
- Kidney - Liver - Carcinogen - Embryotoxin - Teratogen - Brain - Central
nervous system - Lung
Mutagenicity Toxicity:
This has not been tested for this product.
Reproductive Toxicity:
This has not been tested for this product.
SUPPLEMENTAL HEALTH INFORMATION:
Material/
CAS
Number
TITANIUM
DIOXIDE
13463-67-7
Percent
ETHYL
BENZENE
100-41-4
5 - 10
METHYL
ETHYL
KETONE
78-93-3
1-5
CARBON
BLACK
1333-86-4
1-5
Ingredient Specific Animal Data:
40 - 70
This product contains titanium dioxide. Animals inhaling
massive quantities of titanium dioxide dust in a long-term
study developed lung tumors. Studies with humans
involved in manufacture of this pigment indicate no
increased risk of cancer from exposure.
Ethylbenzene has been reported by NTP to cause cancer
in laboratory animals following a chronic (2 year)
inhalation exposure. Dose levels of 75, 250 and 750 ppm
were used, with evidence of carcinogenicity found in the
kidneys of rats and the lung and liver of mice at 750 ppm.
The No Observed Effect Level (NOEL) was 75 ppm. The
relevance of these findings to humans is uncertain, but
appropriate safeguards should be employed to reduce or
eliminate inhalation exposure to ethylbenzene.
This product contains methyl ethyl ketone (MEK). MEK
has been shown to cause minor embryotoxic/fetotoxic
effects in laboratory animals exposed for prolonged
periods at high concentrations via inhalation. The
potential for human exposure to high concentrations is
expected to be low due to the irritating effects of MEK at
low concentrations.
This product contains carbon black which has been rated
an IARC 2B carcinogen due to animal data.
SECTION 12 - ECOLOGICAL INFORMATION
POTENTIAL ENVIRONMENTAL EFFECTS
Ecotoxicity:
No Information Available.
__________________________________________________________________
Page 3 of 5
CI-P-01
_______________________________________________________________________________________________________________
PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
Product ID: DAR-1 (0808-T0)
PRODUCT NAME: DELSTAR ACRYLIC ENAMEL
ENVIRONMENTAL FATE
Mobility:
Biodegradation:
Bioaccumulation:
No Information Available.
No Information Available.
No Information Available.
PHYSICAL/CHEMICAL
Hydrolysis:
Photolysis:
No Information Available.
No Information Available.
SECTION 13 - DISPOSAL CONSIDERATIONS
Provide maximum ventilation, only personnel equipped with proper
respiratory and skin and eye protection should be permitted in the area.
Take up spilled material with sawdust, vermiculite, or other absorbent
material and place in containers for disposal.
Waste material must be disposed of in accordance with federal, state,
provincial and local environmental control regulations. Empty containers
should be recycled by an appropriately licensed reconditioner/salvager or
disposed of through a permitted waste management facility. Additional
disposal information is contained on the Environmental Data Sheet for
this product, which can be obtained from your PPG representative.
SECTION 14 - TRANSPORTATION INFORMATION
Proper Shipping Name:
NOT AVAILABLE
NOS Technical Name:
NOT AVAILABLE
Hazard Class:
N.A.
Subsidiary Class(es):
N.A.
UN Number:
N.A.
Packing Group:
N.A.
USA - RQ Hazardous Substances: NOT AVAILABLE
USA-RQ Hazardous Substance NOT AVAILABLE
Threshold Ship Weight:
Marine Pollutant Name:
NOT AVAILABLE
SECTION 15 - REGULATORY INFORMATION
INVENTORY STATUS
U.S. TSCA: This product and/or all of its components are listed on the
U.S. TSCA Inventory or is otherwise exempt from TSCA Inventory
reporting requirements.
FEDERAL REGULATIONS
US Regulations
Material/
CAS Number
Percent
TITANIUM DIOXIDE
13463-67-7
XYLENES
1330-20-7
METHYL (N-AMYL)
KETONE
110-43-0
ETHYL BENZENE
100-41-4
AROMATIC
NAPHTHA
64742-95-6
NAPHTHA
8052-41-3
METHYL ETHYL
KETONE
78-93-3
CARBON BLACK
1333-86-4
TOLUENE
108-88-3
AROMATIC
HYDROCARBON
64742-94-5
40 - 70
CERCLA HS - SARA EHSRQ (LBS)
TPQ (LBS)
Not Listed
Not Listed
SARA 313
Not Listed
40 - 70
100 lbs
Not Listed
Listed
7 - 13
Not Listed
Not Listed
Not Listed
5 - 10
1000 lbs
Not Listed
Listed
1-5
Not Listed
Not Listed
Not Listed
1-5
Not Listed
Not Listed
Not Listed
1-5
5000 lbs
Not Listed
Listed
1-5
Not Listed
Not Listed
Not Listed
0.5-1.5
1000 lbs
Not Listed
Listed
0.5-1.5
Not Listed
Not Listed
Not Listed
SARA 311/312
Health (acute):
Yes
Health (chronic):
Yes
Fire (flammable):
Yes
Pressure:
No
Reactivity:
No
WHMIS HAZARD CLASS: - Class B, Division 6 - Class D, Division 2,
Subdivision A - Class D, Division 2, Subdivision B
STATE/PROVINCIAL REGULATIONS
CALIFORNIA PROP. 65: WARNING: This product contains a
chemical(s) known to the State of California to cause cancer and birth
defects or other reproductive harm.
Additional Information
Percent
Material/
CAS Number
ETHYL BENZENE
100-41-4
CARBON BLACK
1333-86-4
IARC
Group
1(Kno
wn
Human
Carc.)
5 - 10
N
1-5
N
IARC IARC ACGIH NTP
Group 2B (
Carc. Known
2A Suspec
Carc.
(Proba ted
ble
Carc.)
Carc.)
N
Y
N
N
N
Y
N
N
OSHA
Carc.
Y
Y
Key: IARC- International Agency on the Research of Cancer; ACGIHAmerican Conference of Governmental Industrial Hygienists; NTPNational Toxicology Program *Denotes chemical as NTP Known
Carcinogen; + Denotes NTP Possible Carcinogen;
OSHAOccupational Safety and Health Administration.
SECTION 16 - OTHER INFORMATION
Hazard Rating Systems
NFPA Rating: 2 30
HMIS Rating: 2*30
Rating System: 0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe,
*=Chronic Effects.
__________________________________________________________________
Page 4 of 5
CI-P-01
_______________________________________________________________________________________________________________
PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
Product ID: DAR-1 (0808-T0)
PRODUCT NAME: DELSTAR ACRYLIC ENAMEL
HMIS=Hazardous Materials Identification System; NFPA=National Fire
Protection Association;
Safe handling of this product requires that all of the information on the
MSDS be evaluated for specific work environments and conditions of use.
PREPARED BY: Product Safety Department
REASON FOR REVISION: Section 1 has been updated. Section 3 has
been updated. Section 2 has been updated. Changes to this section may
also result in changes in sections 8, 11 and/or 15. Section 4 has been
updated. Section 5 has been updated. Section 7 has been updated.
Section 8 has been updated. Section 9 has been updated. Section 16 has
been updated. Section 10 has been updated. Date. Edition.
Updated MSDS
format.
This Material Safety Data Sheet has been prepared in accordance with
Canada's Workplace Hazardous Materials Information System (WHMIS)
and the OSHA Hazard Communication Standard (29 CFR 1910.1200),
the supplier notification requirements of SARA Title III, Section 313 and
other applicable right-to-know regulations.
Additional environmental information is contained on the Environmental
Data Sheet for this product, which can be obtained from your PPG
representative.
DAR-1 000000 (00348184.001)(06/09/05)
050608, 000, 0808
*** END OF MSDS ***
__________________________________________________________________
Page 5 of 5
CI-P-01
MATERIAL SAFETY DATA SHEET
25216
01 00
===========================================================================
Section 1 −− PRODUCT AND COMPANY IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT NUMBER
HMIS CODES
Health
2*
25216
Flammability
4
Reactivity
0
PRODUCT NAME
OMNI−PAK* for Lacquer, Acrylic, Vinyl
MANUFACTURER’S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN−WILLIAMS COMPANY
(216) 566−2917
Consumer Group − Industrial
Cleveland, OH 44115
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
04−MAR−06
(800) 251−2486
===========================================================================
Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
22
74−98−6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
0.7
100−41−4 Ethylbenzene
ACGIH TLV
100 ppm
7.1 mm
ACGIH TLV
125 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
125 ppm STEL
4
1330−20−7 Xylene
ACGIH TLV
100 ppm
5.9 mm
ACGIH TLV
150 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
150 ppm STEL
4
123−42−2 Diacetone Alcohol
ACGIH TLV
50 ppm
1.2 mm
OSHA PEL
50 ppm
70
67−64−1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
===========================================================================
Section 3 −− HAZARDS IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
Continued on page 2
CI-P-01
25216
page 2
===========================================================================
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
===========================================================================
Section 4 −− FIRST AID MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
EYES:
Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re−use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 −− FIRE FIGHTING MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
FLASH POINT
LEL
UEL
Propellant < 0 F
1.0
12.8
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self−contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build−up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 −− ACCIDENTAL RELEASE MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 −− HANDLING AND STORAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STORAGE CATEGORY
Not Available
Continued on page 3
CI-P-01
25216
page 3
===========================================================================
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated − Do not
smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
===========================================================================
Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
===========================================================================
Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT WEIGHT
5.94 lb/gal
711 g/l
SPECIFIC GRAVITY
0.71
BOILING POINT
<0 − 342 F
<−18 − 172 C
MELTING POINT
Not Available
VOLATILE VOLUME
100 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical)
Volatile Weight 30.40 % Less Water and Federally Exempt Solvents
Continued on page 4
CI-P-01
25216
page 4
===========================================================================
Section 10 −− STABILITY AND REACTIVITY
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITY −− Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 −− TOXICOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CHRONIC HEALTH HAZARDS
Ethylbenzene is classified by IARC as possibly carcinogenic to humans
(2B) based on inadequate evidence in humans and sufficient evidence in
laboratory animals.
Lifetime inhalation exposure of rats and mice to high
ethylbenzene concentrations resulted in increases in certain types of
cancer, including kidney tumors in rats and lung and liver tumors in mice.
These effects were not observed in animals exposed to lower concentrations.
There is no evidence that ethylbenzene causes cancer in humans.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary and reproductive systems.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
TOXICOLOGY DATA
CAS No.
Ingredient Name
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
74−98−6
Propane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
100−41−4
Ethylbenzene
LC50
RAT
4HR
Not Available
LD50
RAT
3500
mg/kg
1330−20−7
Xylene
LC50
RAT
4HR
5000
ppm
LD50
RAT
4300
mg/kg
123−42−2
Diacetone Alcohol
LC50
RAT
4HR
Not Available
LD50
RAT
4000.
mg/kg
67−64−1
Acetone
LC50
RAT
4HR
Not Available
LD50
RAT
5800
mg/kg
===========================================================================
Section 12 −− ECOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ECOTOXICOLOGICAL INFORMATION
No data available.
Continued on page 5
CI-P-01
25216
page 5
===========================================================================
Section 13 −− DISPOSAL CONSIDERATIONS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
===========================================================================
Section 14 −− TRANSPORT INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No data available.
===========================================================================
Section 15 −− REGULATORY INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
100−41−4 Ethylbenzene
0.6
1330−20−7 Xylene
4
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 −− OTHER INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.
The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.
CI-P-01
MATERIAL SAFETY DATA SHEET
S60340
01 00
===========================================================================
Section 1 −− PRODUCT AND COMPANY IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT NUMBER
HMIS CODES
Health
2
S60340
Flammability
4
Reactivity
0
PRODUCT NAME
KRYLON* TOUGH COAT* Latex, Gray Primer
MANUFACTURER’S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN−WILLIAMS COMPANY
(216) 566−2917
Consumer Group − Industrial
Cleveland, OH 44115
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
04−MAR−06
(800) 251−2486
===========================================================================
Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
1
71−36−3 1−Butanol
ACGIH TLV
20 ppm (Skin)
5.5 mm
OSHA PEL
50 ppm (Skin) CEILING
7
111−76−2 2−Butoxyethanol
ACGIH TLV
20 ppm
0.88 mm
OSHA PEL
25 ppm
7
67−64−1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
38
115−10−6 Dimethyl Ether
ACGIH TLV Not Available
760 mm
OSHA PEL Not Available
10
14807−96−6 Talc
ACGIH TLV
2 mg/m3 as Resp. Dust
OSHA PEL
2 mg/m3 as Resp. Dust
2
13463−67−7 Titanium Dioxide
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
===========================================================================
Section 3 −− HAZARDS IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
Continued on page 2
CI-P-02
S60340
page 2
===========================================================================
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
===========================================================================
Section 4 −− FIRST AID MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
EYES:
Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re−use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 −− FIRE FIGHTING MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
FLASH POINT
LEL
UEL
Propellant < 0 F
1.1
27.0
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Alcohol Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers may explode (due to the build−up of pressure) when
exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self−contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build−up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 −− ACCIDENTAL RELEASE MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 −− HANDLING AND STORAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STORAGE CATEGORY
Not Available
Continued on page 3
CI-P-02
S60340
page 3
===========================================================================
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated − Do not
smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
===========================================================================
Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
Continued on page 4
CI-P-02
S60340
page 4
===========================================================================
Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT WEIGHT
7.42 lb/gal
889 g/l
SPECIFIC GRAVITY
0.89
BOILING POINT
<0 − 343 F
<−18 − 172 C
MELTING POINT
Not Available
VOLATILE VOLUME
88 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical)
Volatile Weight 46.98 % Less Water and Federally Exempt Solvents
===========================================================================
Section 10 −− STABILITY AND REACTIVITY
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITY −− Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 −− TOXICOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary and blood forming systems.
Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung
cancer, however, such exposure levels are not attainable in the workplace.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
TOXICOLOGY DATA
Continued on page 5
CI-P-02
S60340
page 5
===========================================================================
CAS No.
Ingredient Name
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
71−36−3
1−Butanol
LC50
RAT
4HR
8000
ppm
LD50
RAT
790
mg/kg
111−76−2
2−Butoxyethanol
LC50
RAT
4HR
Not Available
LD50
RAT
470
mg/kg
67−64−1
Acetone
LC50
RAT
4HR
Not Available
LD50
RAT
5800
mg/kg
115−10−6
Dimethyl Ether
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
14807−96−6
Talc
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
13463−67−7
Titanium Dioxide
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
===========================================================================
Section 12 −− ECOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 −− DISPOSAL CONSIDERATIONS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
===========================================================================
Section 14 −− TRANSPORT INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No data available.
===========================================================================
Section 15 −− REGULATORY INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
71−36−3 1−Butanol
1
Zinc Compound
2
0.7
Glycol Ethers
7
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
Continued on page 6
CI-P-02
S60340
page 6
===========================================================================
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 −− OTHER INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.
The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.
CI-P-02
MATERIAL SAFETY DATA SHEET
1613
01 00
===========================================================================
Section 1 −− PRODUCT AND COMPANY IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT NUMBER
HMIS CODES
Health
2*
1613
Flammability
4
Reactivity
0
PRODUCT NAME
KRYLON* Interior/Exterior Paint, Semi Flat Black
MANUFACTURER’S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN−WILLIAMS COMPANY
(216) 566−2917
KRYLON Products Group
Cleveland, OH 44115
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
28−MAY−05
(800) 832−2541
===========================================================================
Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
15
74−98−6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
7
106−97−8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
2
100−41−4 Ethylbenzene
ACGIH TLV
100 ppm
7.1 mm
ACGIH TLV
125 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
125 ppm STEL
9
1330−20−7 Xylene
ACGIH TLV
100 ppm
5.9 mm
ACGIH TLV
150 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
150 ppm STEL
1
71−36−3 1−Butanol
ACGIH TLV
20 ppm (Skin)
5.5 mm
OSHA PEL
50 ppm (Skin) CEILING
43
67−64−1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
7
78−93−3 Methyl Ethyl Ketone
ACGIH TLV
200 ppm
70 mm
ACGIH TLV
300 ppm STEL
OSHA PEL
200 ppm
OSHA PEL
300 ppm STEL
1
108−10−1 Methyl Isobutyl Ketone
ACGIH TLV
50 ppm
16 mm
ACGIH TLV
75 ppm STEL
OSHA PEL
50 ppm
OSHA PEL
75 ppm STEL
Continued on page 2
CI-P-03
1613
page 2
===========================================================================
5
108−65−6 1−Methoxy−2−Propanol Acetate
ACGIH TLV Not Available
1.8 mm
OSHA PEL Not Available
1
1333−86−4 Carbon Black
ACGIH TLV
3.5 mg/m3
OSHA PEL
3.5 mg/m3
===========================================================================
Section 3 −− HAZARDS IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
===========================================================================
Section 4 −− FIRST AID MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
EYES:
Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re−use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 −− FIRE FIGHTING MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
FLASH POINT
LEL
UEL
Propellant < 0 F
1.0
13.1
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
Continued on page 3
CI-P-03
1613
page 3
===========================================================================
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self−contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build−up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 −− ACCIDENTAL RELEASE MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 −− HANDLING AND STORAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated − Do not
smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
===========================================================================
Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
Removal of old paint by sanding, scraping or other means may generate
dust or fumes that contain lead. Exposure to lead dust or fumes may cause
brain damage or other adverse health effects, especially in children or
pregnant women. Controlling exposure to lead or other hazardous substances
requires the use of proper protective equipment, such as a properly fitted
respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1−800−424−LEAD
(in US) or contact your local health authority.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
Continued on page 4
CI-P-03
1613
page 4
===========================================================================
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
===========================================================================
Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT WEIGHT
6.25 lb/gal
749 g/l
SPECIFIC GRAVITY
0.75
BOILING POINT
<0 − 302 F
<−18 − 150 C
MELTING POINT
Not Available
VOLATILE VOLUME
93 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical)
Volatile Weight 47.24 % Less Water and Federally Exempt Solvents
===========================================================================
Section 10 −− STABILITY AND REACTIVITY
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITY −− Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
Continued on page 5
CI-P-03
1613
page 5
===========================================================================
Section 11 −− TOXICOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CHRONIC HEALTH HAZARDS
Ethylbenzene is classified by IARC as possibly carcinogenic to humans
(2B) based on inadequate evidence in humans and sufficient evidence in
laboratory animals.
Lifetime inhalation exposure of rats and mice to high
ethylbenzene concentrations resulted in increases in certain types of
cancer, including kidney tumors in rats and lung and liver tumors in mice.
These effects were not observed in animals exposed to lower concentrations.
There is no evidence that ethylbenzene causes cancer in humans.
Carbon Black is classified by IARC as possibly carcinogenic to humans
(group 2B) based on experimental animal data, however, there is
insufficient evidence in humans for its carcinogenicity.
Methyl Ethyl Ketone may increase the nervous system effects of other
solvents.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, blood forming and reproductive
systems.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
TOXICOLOGY DATA
CAS No.
Ingredient Name
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
74−98−6
Propane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
106−97−8
Butane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
100−41−4
Ethylbenzene
LC50
RAT
4HR
Not Available
LD50
RAT
3500
mg/kg
1330−20−7
Xylene
LC50
RAT
4HR
5000
ppm
LD50
RAT
4300
mg/kg
71−36−3
1−Butanol
LC50
RAT
4HR
8000
ppm
LD50
RAT
790
mg/kg
67−64−1
Acetone
LC50
RAT
4HR
Not Available
LD50
RAT
5800
mg/kg
78−93−3
Methyl Ethyl Ketone
LC50
RAT
4HR
Not Available
LD50
RAT
2740
mg/kg
108−10−1
Methyl Isobutyl Ketone
LC50
RAT
4HR
Not Available
LD50
RAT
2080
mg/kg
108−65−6
1−Methoxy−2−Propanol Acetate
LC50
RAT
4HR
Not Available
LD50
RAT
8500
mg/kg
1333−86−4
Carbon Black
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
Continued on page 6
CI-P-03
1613
page 6
===========================================================================
Section 12 −− ECOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 −− DISPOSAL CONSIDERATIONS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
===========================================================================
Section 14 −− TRANSPORT INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No data available.
===========================================================================
Section 15 −− REGULATORY INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
100−41−4 Ethylbenzene
2
1330−20−7 Xylene
9
71−36−3 1−Butanol
1
78−93−3 Methyl Ethyl Ketone
7
108−10−1 Methyl Isobutyl Ketone
1
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 −− OTHER INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.
The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.
CI-P-03
The MSDS format adheres to the standards and regulatory requirements
of the United States and may not meet regulatory requirements
in other countries.
DuPont
Material Safety Data Sheet
Page
1
---------------------------------------------------------------------"FREON" 22
2008FR
Revised 28-APR-2004
------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL PRODUCT/COMPANY IDENTIFICATION
---------------------------------------------------------------------Material Identification
Corporate MSDS Number
Formula
Molecular Weight
CAS Name
:
:
:
:
DU000025
CHClF2
86.47
"FREON" 22
Tradenames and Synonyms
Freon 22
CHLORODIFLUOROMETHANE
HCFC-22
CC0335
Dymel 22
Company Identification
MANUFACTURER/DISTRIBUTOR
DuPont Fluoroproducts
1007 Market Street
Wilmington, DE 19898
PHONE NUMBERS
Product Information
Transport Emergency
Medical Emergency
: 1-800-441-7515 (outside the U.S.
302-774-1000)
: CHEMTREC 1-800-424-9300(outside U.S.
703-527-3887)
: 1-800-441-3637 (outside the U.S.
302-774-1000)
---------------------------------------------------------------------COMPOSITION/INFORMATION ON INGREDIENTS
---------------------------------------------------------------------Components
Material
*"FREON" 22 METHANE, CHLORODIFLUORO-
CAS Number
75-45-6
%
100
* Disclosure as a toxic chemical is required under Section 313 of
Title III of the Superfund Amendments and Reauthorization Act of 1986
and 40 CFR part 372.
CI-R-01
2008FR
DuPont
Material Safety Data Sheet
Page
2
---------------------------------------------------------------------HAZARDS IDENTIFICATION
---------------------------------------------------------------------# Potential Health Effects
Inhalation of high concentrations of vapor is harmful and
may cause heart irregularities, unconsciousness or death.
Intentional misuse or deliberate inhalation can be fatal.
Vapors are heavier than air and pose a threat of suffocation
if trapped in enclosed or low places. Liquid contact can
cause frostbite. Inhalation may cause dizziness, headache,
confusion, incoordination, and loss of consciousness.
Immediate effects of overexposure by inhalation may include
central nervous system depression with dizziness, confusion,
incoordination, drowsiness or unconsciousness. Gross
overexposure may cause irregular heart beat with a strange
sensation in the chest, "heart thumping", apprehension,
lightheadedness, feeling of fainting, dizziness, weakness,
sometimes progressing to loss of consciousness and death.
Other effects include fatality from gross over-exposure.
Short-term overexposure by skin contact may cause frostbite,
if liquid or escaping vapor contacts the skin. Repeated
and/or prolonged exposure may cause defatting of the skin
with itching, redness or rash. Data to evaluate the skin
permeation hazard of this compound are insufficient. There
are no reports of human sensitization.
Contact with the vapor or aerosol may cause eye irritation
with tearing, pain or blurred vision.
Increased susceptibility to the effects of this material may
be observed in persons with pre-existing disease of the
central nervous system, cardiovascular system.
Carcinogenicity Information
None of the components present in this material at concentrations
equal to or greater than 0.1% are listed by IARC, NTP, OSHA or ACGIH
as a carcinogen.
---------------------------------------------------------------------FIRST AID MEASURES
---------------------------------------------------------------------First Aid
INHALATION
If inhaled, immediately remove to fresh air. Keep person
calm. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Call a physician.
SKIN CONTACT
In case of contact, flush area with lukewarm water.
CI-R-01
Do not
2008FR
DuPont
Material Safety Data Sheet
Page
3
(FIRST AID MEASURES - Continued)
use hot water.
If frostbite has occurred, call a physician.
EYE CONTACT
In case of contact, immediately flush eyes with plenty of
water for at least 15 minutes. Call a physician.
INGESTION
Ingestion is not considered a potential route of exposure.
Notes to Physicians
THIS MATERIAL MAY MAKE THE HEART MORE SUSCEPTIBLE TO
ARRHYTHMIAS. Catecholamines such as adrenaline, and other
compounds having similar effects, should be reserved for
emergencies and then used only with special caution.
---------------------------------------------------------------------FIRE FIGHTING MEASURES
---------------------------------------------------------------------Flammable Properties
Flash Point
Autodecomposition
: Will not burn
: 632 C (1170 F)
Other burning materials may cause "FREON" 22 to burn weakly.
Chlorodifluoromethane is not flammable at ambient
temperatures and atmospheric pressure. However,
chlorodifluoromethane has been shown in tests to be
combustible at pressures as low as 60 psig at ambient
temperature when mixed with air at concentrations of 65
volume % air. Experimental data have also been reported
which indicate combustibility of "FREON" 22 in the presence
of certain concentrations of chlorine.
Fire and Explosion Hazards:
Cylinders may rupture under fire conditions.
may occur.
Decomposition
Extinguishing Media
As appropriate for combustibles in area. Extinguishant
for other burning material in area is sufficient to stop
burning.
Fire Fighting Instructions
Use water spray or fog to cool containers. Self-contained
breathing apparatus (SCBA) is required if cylinders rupture
or contents are released under fire conditions. Water
runoff should be contained and neutralized prior to release.
CI-R-01
2008FR
DuPont
Material Safety Data Sheet
Page
4
---------------------------------------------------------------------ACCIDENTAL RELEASE MEASURES
---------------------------------------------------------------------Safeguards (Personnel)
NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL)
sections before proceeding with clean-up. Use appropriate
PERSONAL PROTECTIVE EQUIPMENT during clean-up.
Accidental Release Measures
Ventilate area, especially low or enclosed places where
heavy vapors might collect. Remove open flames. Use
self-contained breathing apparatus (SCBA) for large spills
or releases.
---------------------------------------------------------------------HANDLING AND STORAGE
---------------------------------------------------------------------Handling (Personnel)
Use with sufficient ventilation to keep employee exposure
below recommended limits. "FREON" 22 should not be mixed
with air for leak testing. In general, it should not be
used or allowed to be present with high concentrations of
air above atmospheric pressure. Contact with chlorine or
other strong oxidizing agents should also be avoided.
Storage
Clean, dry area.
Do not heat above 52 C (125 F).
---------------------------------------------------------------------EXPOSURE CONTROLS/PERSONAL PROTECTION
---------------------------------------------------------------------Engineering Controls
Normal ventilation for standard manufacturing procedures is
generally adequate. Local exhaust should be used when large
amounts are released. Mechanical ventilation should be
used in low or enclosed places.
Personal Protective Equipment
Impervious gloves and chemical splash goggles should be used
when handling liquid. Under normal manufacturing
conditions, no respiratory protection is required when
using this product. Self-contained breathing apparatus
(SCBA) is required if a large release occurs.
Exposure Guidelines
CI-R-01
2008FR
DuPont
Material Safety Data Sheet
Exposure Limits
"FREON" 22
PEL
(OSHA)
TLV
(ACGIH)
AEL * (DuPont)
Page
5
: None Established
: 1,000 ppm, 3,540 mg/m3, 8 Hr. TWA, A4
: None Established
* AEL is DuPont’s Acceptable Exposure Limit. Where governmentally
imposed occupational exposure limits which are lower than the AEL
are in effect, such limits shall take precedence.
---------------------------------------------------------------------PHYSICAL AND CHEMICAL PROPERTIES
---------------------------------------------------------------------Physical Data
Boiling Point
Vapor Pressure
Vapor Density
% Volatiles
Evaporation Rate
Solubility in Water
pH
Odor
Form
Color
Liquid Density
:
:
:
:
:
:
:
:
:
:
:
-40.8 C (-41.4 F)
151 psig @ 25 C (77 F)
3.03 (Air=1.0) @ 25 C (77 F)
100 WT%
>1 (CCl4=1.0)
0.3 WT% @ 25 C (77 F)
Neutral
Slight ethereal
Liquified Gas.
Clear, Colorless.
1.194 g/cm3 @ 25 C (77 F)
---------------------------------------------------------------------STABILITY AND REACTIVITY
---------------------------------------------------------------------Chemical Stability
Material is stable.
temperatures.
However, avoid open flames and high
Incompatibility with Other Materials
Incompatible with alkali or alkaline earth metals--powdered
Al, Zn, Be, etc.
Decomposition
Decomposition products are hazardous. "FREON" 22 can be
decomposed by high temperatures (open flames, glowing metal
surfaces, etc.) forming hydrochloric and hydrofluoric acids,
and possibly carbonyl halides. These materials are toxic
and irritating. Contact should be avoided.
Polymerization
Polymerization will not occur.
CI-R-01
2008FR
DuPont
Material Safety Data Sheet
Page
6
---------------------------------------------------------------------TOXICOLOGICAL INFORMATION
---------------------------------------------------------------------# Animal Data
INHALATION:
4 hour, LC50, rat: 220,000 ppm.
Inhalation 4 hour, LC50, rat: 220,000 ppm
Animal testing indicates this material is a slight eye
irritant.
Animal testing indicates this material is a skin irritant,
but not a skin sensitizer.
Long-term exposure by ingestion caused no significant
toxicological effects.
Single inhalation exposure to high doses caused central nerv
depression. inactivity or anaesthesia, lung noise, altered
respiratory rate, histopathological changes of the liver,
cardiac sensitization, a potentially fatal disturbance of
heart rhythm associated with a heightened sensitivity to the
action of epinephrine. Repeated exposure caused no
significant toxicological effects. Long-term exposure
caused reduced weight gain, increased adrenals, kidney,
liver, and pituitary weight.
In chronic inhalation studies, HCFC-22, at a concentration
of 50,000 ppm (v/v), produced a small, but statistically
significant increase of late-occurring tumors involving
salivary glands in male rats, but not female rats or male or
female mice. In the same studies, no increased incidence of
tumors was seen in either species at concentrations of
10,000 ppm or 1000 ppm (v/v). Animal data show
developmental effects only at exposure levels producing
other toxic effects in the adult animal. This material is
not considered a unique developmental hazard to the
conceptus. Reproductive data on male animals show no change
in reproductive performance. Specific studies to evaluate
the effect on female reproductive performance have not been
conducted; however, limited information obtained from
studies on developmental toxicity do not indicate adverse
effects on female reproductive performance. This material
produces genetic damage in bacterial cell cultures. In
mammalian cell cultures and animals, this material has not
produced genetic toxicity. In animal testing, this material
has not caused permanent genetic damage in reproductive
cells of mammals (has not produced heritable genetic
damage).
CI-R-01
2008FR
DuPont
Material Safety Data Sheet
Page
7
---------------------------------------------------------------------ECOLOGICAL INFORMATION
---------------------------------------------------------------------Ecotoxicological Information
Aquatic Toxicity:
"FREON" 22
48 hour EC50 - Daphnia magna: 433 mg/L
---------------------------------------------------------------------DISPOSAL CONSIDERATIONS
---------------------------------------------------------------------Waste Disposal
Comply with Federal, State, and local regulations. Reclaim
by distillation or remove to a permitted waste disposal
facility.
---------------------------------------------------------------------TRANSPORTATION INFORMATION
---------------------------------------------------------------------Shipping Information
DOT/IMO
Proper Shipping Name
Hazard Class
UN No.
DOT/IMO Label
:
:
:
:
CHLORODIFLUOROMETHANE
2.2
1018
NONFLAMMABLE GAS
Shipping Containers
Tank Cars.
Tank Trucks.
Cylinders.
---------------------------------------------------------------------REGULATORY INFORMATION
---------------------------------------------------------------------U.S. Federal Regulations
TSCA Inventory Status
: Reported/Included.
TITLE III HAZARD CLASSIFICATIONS SECTIONS 311, 312
Acute
Chronic
Fire
Reactivity
Pressure
:
:
:
:
:
Yes
No
No
No
Yes
HAZARDOUS CHEMICAL LISTS
SARA Extremely Hazardous Substance: No
CERCLA Hazardous Substance
: No
CI-R-01
2008FR
DuPont
Material Safety Data Sheet
Page
8
(REGULATORY INFORMATION - Continued)
SARA Toxic Chemical
- See Components Section
---------------------------------------------------------------------OTHER INFORMATION
---------------------------------------------------------------------NFPA, NPCA-HMIS
NPCA-HMIS Rating
Health
Flammability
Reactivity
: 1
: 0
: 1
Personal Protection rating to be supplied by user depending on use
conditions.
---------------------------------------------------------------------The data in this Material Safety Data Sheet relates only to the
specific material designated herein and does not relate to use in
combination with any other material or in any process.
Responsibility for MSDS : MSDS Coordinator
>
: DuPont Fluoroproducts
Address
: Wilmington, DE 19898
Telephone
: (800) 441-7515
# Indicates updated section.
This information is based upon technical information believed to be
reliable. It is subject to revision as additional knowledge and
experience is gained.
End of MSDS
CI-R-01
MATERIAL SAFETY DATA SHEET
LOX-8 PASTE
SECTION 1: Product and Company Identification
Product Name: Lox-8 Paste
Synonyms: Oxygen-compatible Thread Sealant
Manufacturer: Fluoramics Inc.
Address: 18 Industrial Avenue, Mahwah, NJ 07430
Emergency Phone: 201-825-8110
Information Phone: 1-800-922-0075
Fax Number: 201-825-7035
Chemical Name: Hydrophobic Paste & Filler of PTFE
Chemical Family: Mixture
Product use: Thread Sealant
SECTION 2: Composition/Information on Ingredients
Ingredient
Polychlorotrifluoroethylene
Polytetrafluoroethylene
Silicondioxide Aerogel
Pigment Cobalt Titanate
Green Spinel
CAS
No.
9002
83 9
9002
84 0
686 11
44 9
68186
85 6
%
Wt.
40 60
40 60
.5 2
.5 5
SECTION 3: Hazards Identification
Route of Entry:
Signs & Symptoms of Exposure: PTFE polymer, when thermally
decomposed, may cause polymer fume fever and flu-like symptoms.
Eyes: May cause irritation. Use goggles if contact is probable
Skin: May cause irritation to sensitive skin. Use protective garment when
applicable
Ingestion: Contact a physician
Inhalation: Use a local exhaust if possible
CI-S-01
SECTION 4: First Aid Measures
Eyes: Flush eyes with copious amounts of water
Skin: Remove by wiping and wash with soap and water
Ingestion: Contact a physician
Inhalation: Remove to fresh air
SECTION 5: Fire Fighting Measures
Flash point & method used: N/A
Flammability limits in air by volume: Non-combustible
Extinguisher media: Incombustible
Special fire fighting procedures: none
Unusual fire and explosion hazards: In extreme fire situation, protection
from hydrogen fluoride fumes should be employed
Health
Flammability
Reactivity
Personal
Protection
NFPA
Codes
HMIS
Codes
1
1
0
1
1
0
B
SECTION 6: Accidental Release Measures
Non-hazardous. Disposal to conform with local, state and federal regulations
SECTION 7: Handling and storage
Do not store below 35F (1.6C)
Precautions: Strictly enforce NO SMOKING rule for workers handling
material
SECTION 8: Exposure control/Personal protection
Use normal personal hygiene and good housekeeping.
Respiratory protection: If exposed to high temperature processing fumes,
wear self-contained breathing apparatus.
Use protective gloves.
SECTION 9: Physical and chemical properties
CI-S-01
Appearance: green
Odor: None
Physical: paste
Boiling point: Mixture
Melting point: N/A
Vapor pressure: <.01
Solubility in water: dispersible
Specific gravity H20=1: CA 2.0
Evaporation rate (butyl acetate=1): Less than 1
SECTION 10: Stabilty and reactivity
Stability: stable
Conditions to avoid: Temperatures above 250F without adequate
ventilation. Will not polymerize
Incompatibility: Melted alkali metals, Interhalogen compounds
Hazardous decomposition products: HF,CI2, Hydrogen Fluoride gas Perfluorocarbon Olefins are evolved above 250C. At 650C (1202F), COF2
(carbonyl fluoride) is the principal toxic product. At above 650C, major
products are CF4 and CO2.
SECTION 11: Toxicological information
No toxicology data available
SECTION 12: Ecological information
No ecological information is available
SECTION 13: Disposal considerations
Waste disposal methods: Land fill is preferred but disposal methods must
conform with local, state and federal regulations.
SECTION 14: Transport information
Transport information: N/A
SECTION 15: Regulatory information
Non-hazardous product. Not applicable
SECTION 16: Other information
Date prepared: February 8, 2006
CI-S-01
DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 1 of 7
Version: 1.3
Revision Date: 2006/01/23
DOW CORNING(R) 732 MULTI -PURPOSE SEALANT CLEAR
1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY
24 Hour Emergency Telephone:
Customer Service:
Product Disposal Information:
CHEMTREC:
Dow Corning Corporation
South Saginaw Road
Midland, Michigan 48686
MSDS No.: 01890573
Revision Date: 2006/01/23
Generic Description:
Physical Form:
Color:
Odor:
Silicone elastomer
Paste
Colorless
Acetic acid odor
NFPA Profile: Health
2 Flammability
1 Instability/Reactivity
Note: NFPA = National Fire Protection Association
2. OSHA HAZARDOUS COMPONENTS
CAS Number
Wt %
Component Name
17689-77-9
1.0 - 5.0
Ethyltriacetoxysilane
4253-34-3
1.0 - 5.0
Methyltriacetoxysilane
The above components are hazardous as defined in 29 CFR 1910.1200.
3. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
Acute Effects
Eye:
Direct contact may cause moderate irritation.
Skin:
May cause moderate irritation.
Inhalation:
Irritates respiratory passages very slightly.
Oral:
Low ingestion hazard in normal use.
Prolonged/Repeated Exposure Effects
Skin:
No known applicable information.
Inhalation:
No known applicable information.
Oral:
No known applicable information.
CI-S-02
(989) 496-5900
(989) 496-6000
(989) 496-6315
(800) 424-9300
0
DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 2 of 7
Version: 1.3
Revision Date: 2006/01/23
DOW CORNING(R) 732 MULTI -PURPOSE SEALANT CLEAR
Signs and Symptoms of Overexposure
No known applicable information.
Medical Conditions Aggravated by Exposure
No known applicable information.
The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions,
component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology information.
4. FIRST AID MEASURES
Eye:
Immediately flush with water for 15 minutes. Get medical attention.
Skin:
Remove from skin and wash thoroughly with soap and water or waterless cleanser. Get
medical attention if irritation or other ill effects develop or persist.
Inhalation:
No first aid should be needed.
Oral:
No first aid should be needed.
Comments:
Treat according to person's condition and specifics of exposure.
5. FIRE FIGHTING MEASURES
Flash Point:
Not applicable.
Autoignition Temperature:
Not determined.
Flammability Limits in Air:
Not determined.
Extinguishing Media:
On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide
(CO2), dry chemical or water spray. Water can be used to cool fire exposed containers.
Fire Fighting Measures:
Self-contained breathing apparatus and protective clothing should be worn in fighting large
fires involving chemicals. Determine the need to evacuate or isolate the area according to
your local emergency plan. Use water spray to keep fire exposed containers cool.
Unusual Fire Hazards:
None.
Hazardous Decomposition Products
Thermal breakdown of this product during fire or very high heat conditions may evolve the following hazardous
decomposition products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide.
Formaldehyde.
6. ACCIDENTAL RELEASE MEASURES
CI-S-02
DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 3 of 7
Version: 1.3
Revision Date: 2006/01/23
DOW CORNING(R) 732 MULTI -PURPOSE SEALANT CLEAR
Containment/Clean up:
Observe all personal protection equipment recommendations described in Sections 5 and 8.
Wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate since
spilled materials, even in small quantities, may present a slip hazard. Final cleaning may
require use of steam, solvents or detergents. Dispose of saturated absorbant or cleaning
materials appropriately, since spontaneous heating may occur. Local, state and federal laws
and regulations may apply to releases and disposal of this material, as well as those materials
and items employed in the cleanup of releases. You will need to determine which federal,
state and local laws and regulations are applicable. Sections 13 and 15 of this MSDS provide
information regarding certain federal and state requirements.
Note: See section 8 for Personal Protective Equipment for Spills. Call (989) 496-5900, if additional information is
required.
7. HANDLING AND STORAGE
Use with adequate ventilation. Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide
ventilation during use to control HOAc within exposure guidelines or use respiratory protection. Avoid eye contact.
Keep container closed and store away from water or moisture.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Component Exposure Limits
CAS Number
Component Name
Exposure Limits
17689-77-9
Ethyltriacetoxysilane
See acetic acid comments.
4253-34-3
Methyltriacetoxysilane
See acetic acid comments.
Acetic acid is formed upon contact with water or humid air. Provide adequate ventilation to control exposures within
guidelines of OSHA PEL: TWA 10 ppm and ACGIH TLV: TWA 10 ppm, STEL 15 ppm.
Engineering Controls
Local Ventilation:
General Ventilation:
None should be needed.
Recommended.
Personal Protective Equipment for Routine Handling
Eyes:
Use proper protection - safety glasses as a minimum.
Skin:
Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as
soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are
recommended.
Suitable Gloves:
Silver Shield(R). 4H(R).
CI-S-02
DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 4 of 7
Version: 1.3
Revision Date: 2006/01/23
DOW CORNING(R) 732 MULTI -PURPOSE SEALANT CLEAR
Inhalation:
No respiratory protection should be needed.
Suitable Respirator:
None should be needed.
Personal Protective Equipment for Spills
Eyes:
Use proper protection - safety glasses as a minimum.
Skin:
Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as
soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are
recommended.
Inhalation/Suitable
Respirator:
No respiratory protection should be needed.
Precautionary Measures:
Avoid eye contact. Use reasonable care.
Comments:
Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation
during use to control HOAc within exposure guidelines or use respiratory protection.
Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require
added precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical Form:
Color:
Odor:
Specific Gravity @ 25°C:
Viscosity:
Freezing/Melting Point:
Boiling Point:
Vapor Pressure @ 25°C:
Vapor Density:
Solubility in Water:
pH:
Volatile Content:
Paste
Colorless
Acetic acid odor
1.04
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Note: The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing
specifications.
10. STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Hazardous
Polymerization:
Conditions to Avoid:
Hazardous polymerization will not occur.
CI-S-02
None.
DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 5 of 7
Version: 1.3
Revision Date: 2006/01/23
DOW CORNING(R) 732 MULTI -PURPOSE SEALANT CLEAR
Materials to Avoid:
Oxidizing material can cause a reaction. Water, moisture, or humid air can cause hazardous
vapors to form as described in Section 8.
11. TOXICOLOGICAL INFORMATION
Special Hazard Information on Components
No known applicable information.
12. ECOLOGICAL INFORMATION
Environmental Fate and Distribution
Complete information is not yet available.
Environmental Effects
Complete information is not yet available.
Fate and Effects in Waste Water Treatment Plants
Complete information is not yet available.
Hazard Parameters (LC50 or EC50)
Acute Aquatic Toxicity (mg/L)
Acute Terrestrial Toxicity
Ecotoxicity Classification Criteria
High
Medium
<=1
>1 and <=100
<=100
>100 and <= 2000
Low
>100
>2000
This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993.
This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the
section concerning the overall ecological safety of this material.
13. DISPOSAL CONSIDERATIONS
RCRA Hazard Class (40 CFR 261)
When a decision is made to discard this material, as received, is it classified as a hazardous waste? No
State or local laws may impose additional regulatory requirements regarding disposal.
Call (989) 496-6315, if additional information is required.
14. TRANSPORT INFORMATION
DOT Road Shipment Information (49 CFR 172.101)
Not subject to DOT.
Ocean Shipment (IMDG)
CI-S-02
DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 6 of 7
Version: 1.3
Revision Date: 2006/01/23
DOW CORNING(R) 732 MULTI -PURPOSE SEALANT CLEAR
Not subject to IMDG code.
Air Shipment (IATA)
Not subject to IATA regulations.
Call Dow Corning Transportation, (989) 496-8577, if additional information is required.
15. REGULATORY INFORMATION
Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
TSCA Status:
All chemical substances in this material are included on or exempted from listing on the TSCA
Inventory of Chemical Substances.
EPA SARA Title III Chemical Listings
Section 302 Extremely Hazardous Substances (40 CFR 355):
None.
Section 304 CERCLA Hazardous Substances (40 CFR 302):
None.
Section 311/312 Hazard Class (40 CFR 370):
Acute: Yes
Chronic: No
Fire: No
Pressure: No
Reactive: No
Section 313 Toxic Chemicals (40 CFR 372):
None present or none present in regulated quantities.
Supplemental State Compliance Information
California
Warning: This product contains the following chemical(s) listed by the State of California under the Safe Drinking Water
and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other
reproductive harm.
None known.
Massachusetts
CAS Number
CI-S-02
Wt %
Component Name
DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 7 of 7
Version: 1.3
Revision Date: 2006/01/23
DOW CORNING(R) 732 MULTI -PURPOSE SEALANT CLEAR
7631-86-9
7.0 - 13.0
Silica, amorphous
CAS Number
Wt %
Component Name
70131-67-8
> 60.0
Dimethyl siloxane, hydroxy-terminated
7631-86-9
7.0 - 13.0
Silica, amorphous
17689-77-9
1.0 - 5.0
Ethyltriacetoxysilane
4253-34-3
1.0 - 5.0
Methyltriacetoxysilane
New Jersey
Pennsylvania
CAS Number
Wt %
Component Name
70131-67-8
> 60.0
Dimethyl siloxane, hydroxy-terminated
7631-86-9
7.0 - 13.0
Silica, amorphous
16. OTHER INFORMATION
Prepared by: Dow Corning Corporation
These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or
implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally
applicable. However, each user should review these recommendations in the specific context of the intended use and
determine whether they are appropriate.
(R) indicates Registered Trademark
CI-S-02
W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: FlameSafe® FS 1900 Series Firestop Sealant
MSDS ID Number: Z-01646
MSDS Date: 12/08/2005
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
FlameSafe® FS 1900 Series Firestop Sealant
Product Name:
Z-01646
MSDS Number:
Z-01569
Cancelled MSDS Number:
12/08/2005
MSDS Date:
Polyvinyl Acetate & Acrylic Latex Based Emulsion
Chemical Family Name:
Intumescent, Elastomeric Firestop
Product Use:
Mixture-NA
Chemical Formula:
CAS # (Chemical Abstracts Service Mixture-NA
Number):
Manufactured by:
W.R. Grace & Co.-Conn.
62 Whittemore Avenue
Cambridge, MA 02140
Grace Canada, Inc.
294 Clements Road West
Ajax, Ontario L1S 3C6
In Case of Emergency Call:
In USA: (617) 876-1400 In Canada: (905) 683-8561
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient
2-Propenoic acid, polymer..
Dipentaerythritol
Graphite
Melamine
Methenamine
Phenol, isopropylated, phosphate (3:1)
Phenol-formaldehyde polymer
Polyvinyl Acetate Emulsion
Pseudocumene
Silicic acid, sodium salt
Talc
Triphenyl phosphate
Zinc borate
CAS#
052640-81-0
000126-58-9
007782-42-5
000108-78-1
000100-97-0
068937-41-7
009003-35-4
NJ801415075P
000095-63-6
001344-09-8
014807-96-6
000115-86-6
001332-07-6
Percent (max)
10-20
1-5
1-5
1-5
<1
5-10
1-5
10-20
<1
5-10
1-5
1-5
1-5
SECTION 3 - HAZARDS IDENTIFICATION
Emergency Overview:
Warning!
Causes mild to moderate eye irritation.
Causes respiratory tract irritation.
May be harmful if ingested.
Causes digestive tract irritation if ingested.
Harmful if absorbed through skin.
HMIS Rating:
Health:
Flammability:
Reactivity:
Personal Protective Equipment:
2*
0
0
B (See Section 8)
Potential Health Effects:
Inhalation: Causes respiratory tract irritation.
Prolonged inhalation may cause sensitization.
Effects include: Nausea, sneezing, coughing, itching, tightness of chest and wheezing.
Hypersensitive individuals may experience allergic respiratory reaction.
Page 1 of 7
CI-S-03
W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: FlameSafe® FS 1900 Series Firestop Sealant
MSDS ID Number: Z-01646
MSDS Date: 12/08/2005
Eye Contact: Eye contact causes mild to moderate irritation.
Skin Contact: Acute skin contact is not expected to cause irritation.
Hypersensitive individuals may develop an allergic reaction resulting in dermatitis, rash or hives.
Skin Absorption: Harmful if absorbed through the skin.
Ingestion: Harmful if ingested.
If ingested, causes irritation to the linings of the mouth, esophagus and stomach.
Effects include the following: No other effects expected unless listed below.
Reproductive and developmental effects have been reported for certain ingredients. Long-term
repeated ingestion of small amounts of product may cause a decrease in red blood cells or liver
and kidney damage. Phenol-formaldehyde polymer has tested positive as a mutagen.
SECTION 4 - FIRST AID MEASURES:
Skin Contact: Wash with soap and water.
If discomfort or irritation persists, consult a physician.
Remove contaminated clothing and wash before reuse.
Eye Contact: If discomfort or irritation persists, consult a physician.
Flush eyes with water for at least 15 minutes while holding eyelids open.
Ingestion: If discomfort or irritation persists, consult a physician.
Never give anything by mouth to an unconscious person.
Do not induce vomiting.
Inhalation: If symptoms develop, get fresh air. If symptoms persist, consult a physician.
If breathing has stopped, give artificial respiration then oxygen if needed.
SECTION 5 - FIRE AND EXPLOSION HAZARD DATA
Flash Point:
Flash Point Method:
Lower Explosion Limit:
Upper Explosion Limit:
Auto-Ignition Temperature:
>212°F/100°C
Estimated
Not Available
Not Available
Not Available
NFPA Rating:
Health:
Flammability:
Reactivity:
1
0
0
Extinguishing Media: Product will not support combustion. Use alcohol foam, Carbon dioxide,
dry chemical or water to treat surrounding fire.
Special Fire Fighting Procedures:
Wear self-contained breathing apparatus and complete personal protective equipment when
potential for exposure to vapors or products of combustion exist. Isolate area and keep
unnecessary people away.
No special procedures specific to this product.
Unusual Fire and Explosion Hazards: During fire, oxides of nitrogen may be evolved.
SECTION 6 - ACCIDENTAL RELEASE MEASURES:
Spills/Leaks: Use proper personal protective equipment. Do not flush to sewer or allow to enter
waterways. Keep unnecessary people away.
SECTION 7 - HANDLING AND STORAGE
Precautionary Measures:
Avoid contact with eyes, skin and clothing.
Do not take internally.
Practice good personal hygiene to avoid ingestion.
Use only with adequate ventilation.
Wash clothing before reuse.
FOR PROFESSIONAL USE ONLY. KEEP OUT OF CHILDREN'S REACH.
Page 2 of 7
CI-S-03
W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: FlameSafe® FS 1900 Series Firestop Sealant
MSDS ID Number: Z-01646
MSDS Date: 12/08/2005
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT
EXPOSURE GUIDELINES (US)
Ingredient
2-Propenoic acid, polymer..
Dipentaerythritol
Graphite
Melamine
Methenamine
Nitric acid
Phenol, isopropylated,
phosphate (3:1)
Phenol-formaldehyde polymer
Polyvinyl Acetate Emulsion
Pseudocumene
Silicic acid, sodium salt
Sulfuric acid
Talc
Triphenyl phosphate
Zinc borate
ACGIH TLV
TWA
STEL
2 mg/m3 TWA (respirable
fraction) (all
forms except
graphite
fibers)
2 ppm TWA
4 ppm
STEL
Ceiling
-
TWA
respirable dust:
2.5 mg/m3 TWA
-
2 ppm TWA; 5
mg/m3 TWA
OSHA PEL
STEL
-
Other
Ceiling
-
-
-
-
-
-
-
-
-
-
4 ppm STEL;
10 mg/m3
STEL
-
1 mg/m3 TWA
3 mg/m3
STEL
-
-
1 mg/m3 TWA
-
-
-
-
respirable dust
(less than 1%
crystalline silica):
2 mg/m3 TWA
(Listed under
-
-
-
-
-
3 mg/m3 TWA
-
-
-
-
2 mg/m3 TWA
(this TLV is
for the
respirable
fraction of
dust for Talc
3 mg/m3 TWA
-
*Contains formaldehyde below 0.1% threshold. Product is capable of releasing formaldehyde under
certain conditions. Exposure during typical application is expected to be insignificant. Exposure to
formaldehyde vapor is a potential concern if product is applied under confined space conditions. Consult
appropriate exposure guidelines for formaldehyde. (OSHA: 0.75 ppm-TWA, 2.0 ppm - STEL, ACGIH 0.3
ppm Ceiling)
EXPOSURE GUIDELINES (CANADA)
Employers should consult provincial regulatory limits for exposure guidelines which may vary locally.
Engineering Controls:
Not generally required.
Personal Protective Equipment:
Respiratory Protection: Respiratory protection is not generally required. However, if exposure
limits (Section 8) are exceeded or respiratory irritation develops due to inhalation, a NIOSH
approved respirator is recommended.
A NIOSH approved respirator for Formaldehyde vapor is required whenever exposures exceed
regulatory limits. For additional information, refer to US OSHA Regulations 29 CFR 1910.§ 134.
Skin Protection: Impervious (PVC, latex or nitrile) gloves should be worn anytime direct contact
is possible.
Eye Protection: Safety glasses or goggles should be worn.
Work/Hygienic Practices: Use good personal hygiene practices.
None beyond those noted above.
Page 3 of 7
CI-S-03
W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: FlameSafe® FS 1900 Series Firestop Sealant
MSDS ID Number: Z-01569
MSDS Date: 11/05/2002
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Liquid
Red Mastic. Mild latex odor.
Not Determined
Not Available
Not Applicable
>1
Appreciable
Not Available
1
>212°F/100°C
Unknown
Not Applicable
10.86 g/l
Physical State:
Appearance/Odor:
Odor Threshold: (ppm)
pH:
Vapor Pressure: (Mm Hg)
Vapor Density: (Air = 1)
Solubility In Water:
Specific Gravity: (Water = 1)
Evaporation Rate: (Butyl Acetate = 1)
Boiling Point:
Viscosity:
Bulk Density: (Pounds/Cubic Foot)(Pcf)
% Volatiles (gr/L): (70°F)(21°C)
SECTION 10 - STABILITY AND REACTIVITY
Stable
Chemical Stability:
Oxidizing materials and Strong acids.
Conditions To Avoid:
Will not polymerize.
Hazardous Polymerization:
Carbon dioxide, Carbon monoxide, Low molecular weight
Hazardous Decomposition
hydrocarbons and Aldehydes.
Products:
SECTION 11 - TOXICOLOGICAL INFORMATION
Ingredient(No data unless listed.)
Melamine
CAS Number
000108-78-1
Triphenyl phosphate
000115-86-6
LD50 and LC50
Inhalation LC50 Rat : 3248 mg/m3; Oral
LD50 Rat : 3161 mg/kg;
Oral LD50 Rat : 3500 mg/kg;
Oral LD50 Mouse : 1320 mg/kg;
Carcinogenicity:
Ingredient
2-Propenoic acid, polymer..
Dipentaerythritol
Graphite
Melamine
Phenol, isopropylated, phosphate (3:1)
Phenol-formaldehyde polymer
Polyvinyl Acetate Emulsion
Silicic acid, sodium salt
Sulfuric acid
Talc
Triphenyl phosphate
Zinc borate
IARC
Group 1
No
No
No
No
No
No
No
No
Yes
No
No
No
IARC
Group 2A
No
No
No
No
No
No
No
No
No
No
No
No
IARC
Group 2B
No
No
No
No
No
No
No
No
No
No
No
No
NTP
Known
No
No
No
No
No
No
No
No
No
No
No
No
NTP
Suspect
No
No
No
No
No
No
No
No
No
No
No
No
OSHA
No
No
No
No
No
No
No
No
Yes
No
No
No
*Contains formaldehyde below 0.1% threshold. Product is capable of releasing formaldehyde under certain
conditions. Exposures during typical applications are expected to be insignificant. Exposure to
formaldehyde vapor is a potential concern if product is applied under confined space conditions. NTP:
Suspect Carcinogen. IARC: Group 2A. OSHA: Potential.
Mutagenicity:
Teratogenicity:
Reproductive Toxicity:
Phenol-formaldehyde polymer in this product has tested positive as a
mutagen.
No information available.
No information available.
SECTION 12 - ECOLOGICAL INFORMATION
Environmental Fate:
www.graceconstruction.com
CI-S-03
No data available for product.
Page 4 of 7
12/14/2005
W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: FlameSafe® FS 1900 Series Firestop Sealant
MSDS ID Number: Z-01569
MSDS Date: 11/05/2002
No
data
available
for
product.
Ecotoxicity:
www.graceconstruction.com
CI-S-03
Page 5 of 7
12/14/2005
W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: FlameSafe® FS 1900 Series Firestop Sealant
MSDS ID Number: Z-01569
MSDS Date: 11/05/2002
SECTION 13 - DISPOSAL CONSIDERATIONS
Waste Disposal Procedures:
Consult all regulations (federal, state, provincial, local) or a
qualified waste disposal firm when characterizing waste for
disposal. According to EPA (40 CFR § 261), waste of this product
is not defined as hazardous. Dispose of waste in accordance with
all applicable regulations.
SECTION 14 - TRANSPORTATION INFORMATION
Not Applicable
Not Applicable
Nonhazardous
Not Applicable
Not Applicable
Proper Shipping Name:
UN/NA Number:
Domestic Hazard Class:
Surface Freight Classification:
Label/Placard Required:
SECTION 15 - REGULATORY INFORMATION
REGULATORY CHEMICAL LISTS:
CERCLA (Comprehensive Response Compensation and Liability Act):
(None present unless listed below)
Chemical Name
Zinc borate
CAS #
001332-07-6
Wt %
3.9
CERCLA RQ
1,000
SARA Title III (Superfund Amendments and Reauthorization Act)
SARA Section 312/Tier I & II Hazard Categories:
Health Immediate (acute)
Yes
Health Delayed (chronic)
Yes
Flammable
No
Reactive
No
Pressure
No
302 Reportable Ingredients (Identification Threshold 1%.):
Chemical Name
CAS #
Wt %
SARA 302 TPQ
313 Reportable Ingredients (Chemicals present below reporting threshold are exempt):
Chemical Name
Acetaldehyde
Acrylamide
Acrylonitrile
Cumene
Ethyl acrylate
Ethylene Glycol
Formaldehyde
Nitric acid
Pseudocumene
Sulfuric acid
Vinyl acetate
Xylenes (o-, m-, p- isomers)
Zinc Compounds
CAS #
000075-07-0
000079-06-1
000107-13-1
000098-82-8
000140-88-5
000107-21-1
000050-00-0
007697-37-2
000095-63-6
007664-93-9
000108-05-4
001330-20-7
RR-00578-7
Wt %
.0015
.0009
.0003
.0201
.0024
.081
.0363
.45
.4288
.45
.0907
.0402
3.9
National Volatile Organic Compound Emission Standards For Architectural Coatings:
10.86 g/l
Volatile Organic Content: (gr/L)
D2 B
WHMIS Classification(s):
This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations (CPR). This MSDS contains all the information required by the CPR.
www.graceconstruction.com
CI-S-03
Page 6 of 7
12/14/2005
W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: FlameSafe® FS 1900 Series Firestop Sealant
MSDS ID Number: Z-01569
MSDS Date: 11/05/2002
State Regulatory Information:
California Proposition 65: WARNING! This product contains substances known to the state of
California to cause cancer, birth defects or other reproductive harm.
Massachusetts Hazardous Substance List(Identification threshold 0.001%(1ppm)):
Chemical Name
Acetaldehyde
Acrylamide
Acrylonitrile
Ethyl acrylate
Formaldehyde
Nitric acid
Sulfuric acid
Vinyl acetate
CAS #
000075-07-0
000079-06-1
000107-13-1
000140-88-5
000050-00-0
007697-37-2
007664-93-9
000108-05-4
Wt %
.0015
.0009
.0003
.0024
.0363
.45
.45
.0907
New Jersey Hazardous Substance List(Identification threshold (0.1%)):
Chemical Name
Nitric acid
Pseudocumene
Sulfuric acid
CAS #
007697-37-2
000095-63-6
007664-93-9
Wt %
.45
.42
.45
Pennsylvania Hazardous Substance List(Identification threshold 0.01%):
Chemical Name
Formaldehyde
CAS #
000050-00-0
Wt %
.036
CHEMICAL INVENTORY STATUS:
All chemicals in this product are listed or exempt from listing in the following countries:
US
TSCA
Yes
CANADA
DSL
Yes
NDSL
No
EUROPE
EINECS/ELINCS
Not
Determined
AUSTRALIA
AICS
Not
Determined
JAPAN
ENCS
Not
Determined
KOREA
ECL
Not
Determined
PHILIPPINES
PICCS
Not
Determined
SECTION 16 - OTHER INFORMATION
Non-Hazardous Ingredient Disclosure:
Chemical Name
Water
Prepared by:
Approved by:
Approved Date:
CAS Number
007732-18-5
EH&S Department
EH&S Department
12/08/2005
Disclaimer:
"The data included herein are presented in accordance with various environment, health and safety
regulations. It is the responsibility of a recipient of the data to remain currently informed on chemical hazard
information, to design and update its own program and to comply with all national, federal, state and local
laws and regulations applicable to safety, occupational health, right-to-know and environmental protection."
www.graceconstruction.com
CI-S-03
Page 7 of 7
12/14/2005
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