3m™ espe™ ketac™ cem radiopaque powder

3M™ ESPE™ KETAC™ CEM RADIOPAQUE POWDER
02/25/16
Safety Data Sheet
Copyright,2016,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:
Issue Date:
16-2590-4
02/25/16
Version Number:
Supercedes Date:
9.00
11/13/15
SECTION 1: Identification
1.1. Product identifier
3M™ ESPE™ KETAC™ CEM RADIOPAQUE POWDER
Product Identification Numbers
LE-F100-1399-4, 70-2011-0044-6, 70-2011-0340-8
1.2. Recommended use and restrictions on use
Recommended use
Dental Product, Luting Cement
Restrictions on use
For use by dental professionals
1.3. Supplier’s details
MANUFACTURER:
DIVISION:
ADDRESS:
Telephone:
3M
Oral Care Solutions Division
3M Center, St. Paul, MN 55144-1000, USA
1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
This document has been prepared in accordance with the U.S. OSHA Hazard Communication Standard, which requires the
inclusion of all known hazards of the product or ingredients regardless of the potential risk. The risks of the hazards
communicated in this document may vary depending on the potential for exposure.
2.1. Hazard classification
Serious Eye Damage/Irritation: Category 2A.
2.2. Label elements
Signal word
Warning
Symbols
Exclamation mark |
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Pictograms
Hazard Statements
Causes serious eye irritation.
Precautionary Statements
Prevention:
Wear eye/face protection.
Wash thoroughly after handling.
Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
2.3. Hazards not otherwise classified
None.
SECTION 3: Composition/information on ingredients
Ingredient
NUC - OXIDE GLASS CHEMICALS (non-fibrous)
COPOLYMER ACRYLIC ACID-MALEIC ACID
C.A.S. No.
65997-17-3
29132-58-9
% by Wt
80 - 90 Trade Secret *
< 20 Trade Secret *
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye Contact:
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
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Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
5.3. Special protective actions for fire-fighters
No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Observe precautions from other sections.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate
authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid eye contact. Avoid prolonged or repeated skin contact. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not eat,
drink or smoke when using this product. Wash thoroughly after handling.
7.2. Conditions for safe storage including any incompatibilities
No special storage requirements.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient
C.A.S. No. Agency
Limit type
Additional Comments
NUC - OXIDE GLASS
65997-17-3 Manufacturer
TWA(as dust):10 mg/m3
CHEMICALS (non-fibrous)
determined
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
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8.2.1. Engineering controls
Use in a well-ventilated area.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety Glasses with side shields
Skin/hand protection
See Section 7.1 for additional information on skin protection.
Respiratory protection
Respiratory protection is not required.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Solid
General Physical Form:
Powder
Specific Physical Form:
Odorless, white powder
Odor, Color, Grade:
No Data Available
Odor threshold
Not Applicable
pH
No Data Available
Melting point
Not Applicable
Boiling Point
No flash point
Flash Point
No Data Available
Evaporation rate
Not Classified
Flammability (solid, gas)
Not Applicable
Flammable Limits(LEL)
Not Applicable
Flammable Limits(UEL)
Not Applicable
Vapor Pressure
Not Applicable
Vapor Density
No Data Available
Density
>=1 [Ref Std: WATER=1]
Specific Gravity
Nil
Solubility in Water
No Data Available
Solubility- non-water
No Data Available
Partition coefficient: n-octanol/ water
No Data Available
Autoignition temperature
No Data Available
Decomposition temperature
Not Applicable
Viscosity
No Data Available
Volatile Organic Compounds
No Data Available
Percent volatile
No Data Available
VOC Less H2O & Exempt Solvents
SECTION 10: Stability and reactivity
10.1. Reactivity
This material is considered to be non reactive under normal use conditions.
10.2. Chemical stability
Stable.
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10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
None known.
10.5. Incompatible materials
None known.
10.6. Hazardous decomposition products
Substance
Carbon monoxide
Carbon dioxide
Condition
Not Specified
Not Specified
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
This document has been prepared in accordance with the U.S. OSHA Hazard Communication Standard, which
requires the inclusion of all known hazards of the product or ingredients regardless of the potential risk. The risks of
the hazards communicated in this document may vary depending on the potential for exposure.
The information below represents toxicological information associated with the individual components of the uncured
product. Once properly mixed and/or cured, the product is safe for its intended use.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Skin Contact:
Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching.
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Ingestion:
May be harmful if swallowed.
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
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Acute Toxicity
Name
Overall product
Route
Ingestion
NUC - OXIDE GLASS CHEMICALS (non-fibrous)
Dermal
NUC - OXIDE GLASS CHEMICALS (non-fibrous)
Ingestion
COPOLYMER ACRYLIC ACID-MALEIC ACID
Dermal
COPOLYMER ACRYLIC ACID-MALEIC ACID
Ingestion
Species
Value
No data available; calculated ATE 2,000 - 5,000
mg/kg
LD50 estimated to be > 5,000 mg/kg
LD50 estimated to be 2,000 - 5,000 mg/kg
Professio
nal
judgeme
nt
Rat
LD50 estimated to be > 5,000 mg/kg
Name
Species
Value
NUC - OXIDE GLASS CHEMICALS (non-fibrous)
Professio
nal
judgeme
nt
No significant irritation
Name
Species
Value
NUC - OXIDE GLASS CHEMICALS (non-fibrous)
Professio
nal
judgeme
nt
No significant irritation
LD50 > 5,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Serious Eye Damage/Irritation
Skin Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity
For the component/components, either no data are currently available or the data are not sufficient for classification.
Carcinogenicity
For the component/components, either no data are currently available or the data are not sufficient for classification.
Reproductive Toxicity
Reproductive and/or Developmental Effects
For the component/components, either no data are currently available or the data are not sufficient for classification.
Target Organ(s)
Specific Target Organ Toxicity - single exposure
For the component/components, either no data are currently available or the data are not sufficient for classification.
Specific Target Organ Toxicity - repeated exposure
For the component/components, either no data are currently available or the data are not sufficient for classification.
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
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on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Dispose of waste product in a permitted industrial waste facility.
EPA Hazardous Waste Number (RCRA): Not regulated
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
Immediate Hazard - Yes
Delayed Hazard - No
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
This material contains one or more substances not listed on the TSCA Inventory. Commercial use of this material is regulated
by the FDA.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification
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Health: 2 Flammability: 1 Instability: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Document Group:
Issue Date:
16-2590-4
02/25/16
Version Number:
Supercedes Date:
9.00
11/13/15
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M
3M USA SDSs are available at www.3M.com
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