Sicherheitsdatenblatt 0062 (en-GB)

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH)
and Regulation (EU) No 2015/830
Revision date: 8/7/2015
Version:
6, from batch 1034xx
Language:
en-GB,IE
Date of print: 30/7/2015
WMF Special-Cleaning Tablets
Material number 0062
Page:
1 of 9
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
1.1 Product identifier
Trade name:
WMF Special-Cleaning Tablets
1.2 Relevant identified uses of the substance or mixture and uses advised against
General use:
Cleaning agent
1.3 Details of the supplier of the safety data sheet
Company name:
Street/POB-No.:
Postal Code, city:
E-mail:
Telephone:
Telefax:
IBEDA-CHEMIE Klaus P. Christ GmbH
Am Eichelgärtchen 32
56283 Halsenbach
Germany
info@ibeda-chemie.com
+49 (0)6747-9501-0
+49 (0)6747-9501-11
Dept. responsible for information:
Herr Dohmann, Telephone: +49 (0)6747-9501-16
1.4 Emergency telephone number
Beratungsstelle bei Vergiftung, Telephone: +49 (0)6131-19240
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to EC regulation 1272/2008 (CLP)
Skin Irrit. 2; H315 Causes skin irritation.
Eye Dam. 1; H318 Causes serious eye damage.
2.2 Label elements
Labelling (CLP)
Signal word:
Danger
Hazard statements:
H315
H318
printed by IBEDA-CHEMIE
Causes skin irritation.
Causes serious eye damage.
... with Qualisys SUMDAT
Revision date: 8/7/2015
Version:
6, from batch 1034xx
Language:
en-GB,IE
Date of print: 30/7/2015
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH)
and Regulation (EU) No 2015/830
WMF Special-Cleaning Tablets
Material number 0062
Page:
2 of 9
Precautionary statements:
P102
Keep out of reach of children.
P264
Wash hands and face thoroughly after handling.
Wear protective gloves/protective clothing/eye protection/face protection.
P280
P302+P352
IF ON SKIN: Wash with plenty of water/soap.
IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER/doctor.
If skin irritation occurs: Get medical advice/attention.
P305+P351+P338 IF
P310
P332+P313
Special labelling
Contains sodium percarbonate and Potassium peroxomonosulfate.
Contains 5-15% phosphonates, 15-30% oxygen-based bleaching agents.
Text for labelling:
2.3 Other hazards
May be harmful if swallowed.
Contains phosphonates. May contribute to the eutrophication of water supplies.
Contains Sodium percarbonate: May intensify fire; oxidiser.
SECTION 3: Composition / information on ingredients
3.1 Substances: not applicable
3.2 Mixtures
Chemical characterisation: Mixture
of inorganic salts with organic materials
Hazardous ingredients:
Ingredient
Designation
Content
Classification
EC No. 207-838-8
CAS 497-19-8
REACH 01-2119457268-30-xxxx
EC No. 239-707-6
CAS 15630-89-4
REACH 01-2119457026-42-xxxx
EC No. 201-069-1
CAS 77-92-9
EC No. 274-778-7
CAS 70693-62-8
Sodium carbonate
25 - 50 %
Eye Irrit. 2; H319.
Sodium
percarbonate
10 - 20 %
Citric acid,
anhydrous
5 - 10 %
Ox. Sol. 3; H272.
Acute Tox. 4; H302.
Eye Dam. 1; H318.
Eye Irrit. 2; H319.
Potassium
<5%
peroxomonosulfate
Met. Corr. 1; H290.
Acute Tox. 4; H302.
Skin Corr. 1B; H314.
Aquatic Chronic 3; H412.
Full text of H- and EUH-statements: see section 16.
SECTION 4: First aid measures
4.1 Description of first aid measures
In case of inhalation:
Following skin contact:
printed by IBEDA-CHEMIE
Provide fresh air. In case of respiratory difficulties seek medical attention.
Remove residues with water. In case of skin reactions, consult a physician.
... with Qualisys SUMDAT
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH)
and Regulation (EU) No 2015/830
Revision date: 8/7/2015
Version:
6, from batch 1034xx
Language:
en-GB,IE
Date of print: 30/7/2015
WMF Special-Cleaning Tablets
Material number 0062
After eye contact:
After swallowing:
Page:
3 of 9
Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids
apart. Subsequently seek the immediate attention of an ophthalmologist.
Rinse mouth and drink large quantities of water. Never give anything by mouth to an
unconscious person.
Consult physician.
4.2 Most important symptoms and effects, both acute and delayed
Irritations of mucous membranes in the mouth, pharynx, oesophagus and gastrointestinal
tract.
4.3 Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media:
Co-ordinate fire-fighting measures to the fire surroundings.
5.2 Special hazards arising from the substance or mixture
Fires in the immediate vicinity may cause the development of dangerous vapours.
In case of fire may be liberated: Sodium compounds, sulphur oxides, phosphorus
compounds, carbon monoxide and carbon dioxide.
5.3 Advice for firefighters
Special protective equipment for firefighters:
Additional information:
Wear a self-contained breathing apparatus and chemical protective clothing.
Hazchem-Code: Fire water reacts alkaline. Do not allow water used to extinguish fire to enter drains,
ground or waterways. Treat runoff as hazardous.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Avoid contact with skin and eyes.
Avoid generation of dust. Do not breathe dust.
Wear personal protection equipment.
6.2 Environmental precautions
Do not allow to penetrate into soil, waterbodies or drains.
6.3 Methods and material for containment and cleaning up
Take up mechanically, placing in appropriate containers for disposal.
Wash spill area with plenty of water.
6.4 Reference to other sections
Refer additionally to section 8 and 13.
printed by IBEDA-CHEMIE
... with Qualisys SUMDAT
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH)
and Regulation (EU) No 2015/830
Revision date: 8/7/2015
Version:
6, from batch 1034xx
Language:
en-GB,IE
Date of print: 30/7/2015
WMF Special-Cleaning Tablets
Material number 0062
Page:
4 of 9
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Advices on safe handling:
In case of dust formation: Withdraw by suction. Do not breathe dust.
Avoid contact with skin and eyes.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storerooms and containers:
Hints on joint storage:
Storage class:
Store in a dry place.
Do not store together with highly inflammable or combustible materials.
13 = Non-combustible solids
7.3 Specific end use(s)
Cleaning agent
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limit values:
Type
Limit value
Great Britain: WEL-TWA
Great Britain: WEL-TWA
Ireland: 8 hours
Ireland: 8 hours
10 mg/m³ Dust limit value inhalable fraction
4 mg/m³ Dust limit value respirable fraction
10 mg/m³ Dust limit value inhalable fraction
4 mg/m³ Dust limit value respirable fraction
8.2 Exposure controls
Provide adequate ventilation. Vent dust from the work area.
Personal protection equipment
Occupational exposure controls
Respiratory protection:
Respiratory protection must be worn whenever the WEL levels have been exceeded.
Particulates filter P2 according to EN 143.
Hand protection:
Protective gloves according to EN 374.
Glove material: Nitrile rubber or butyl caoutchouc (butyl rubber).
Observe glove manufacturer's instructions concerning penetrability and breakthrough time.
Eye protection:
Tightly sealed goggles according to EN 166.
Body protection:
Wear suitable protective clothing.
General protection and hygiene measures:
Avoid contact with skin and eyes.
Wash hands before breaks and after work.
Remove contaminated clothing.
Provide a conveniently located eye rinse station.
When using do not eat or drink.
printed by IBEDA-CHEMIE
... with Qualisys SUMDAT
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH)
and Regulation (EU) No 2015/830
Revision date: 8/7/2015
Version:
6, from batch 1034xx
Language:
en-GB,IE
Date of print: 30/7/2015
WMF Special-Cleaning Tablets
Material number 0062
Page:
5 of 9
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Form: solid, Tablets
Colour: white
odourless
no data available
Appearance:
Odour:
Odour threshold:
at 10%: 10.5
no data available
no data available
no data available
no data available
no data available
no data available
pH value:
Melting point/freezing point:
Initial boiling point and boiling range:
Flash point/flash point range:
Evaporation rate:
Flammability:
Explosion limits:
no data available
no data available
approx. 2 g/cm³
soluble
no data available
no data available
no data available
no data available
no data available
no data available
Vapour pressure:
Vapour density:
Density:
Water solubility:
Partition coefficient: n-octanol/water:
Auto-ignition temperature:
Thermal decomposition:
Viscosity, kinematic:
Explosive properties:
Oxidizing characteristics:
9.2 Other information
no data available
Additional information:
SECTION 10: Stability and reactivity
10.1 Reactivity
Product is hygroscopic. Product reacts alkaline.
10.2 Chemical stability
Product is stable under normal storage conditions.
10.3 Possibility of hazardous reactions
No hazardous reaction when handled and stored according to provisions.
10.4 Conditions to avoid
no data available
10.5 Incompatible materials
strong acids and alkalis
printed by IBEDA-CHEMIE
... with Qualisys SUMDAT
Revision date: 8/7/2015
Version:
6, from batch 1034xx
Language:
en-GB,IE
Date of print: 30/7/2015
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH)
and Regulation (EU) No 2015/830
WMF Special-Cleaning Tablets
Material number 0062
Page:
6 of 9
10.6 Hazardous decomposition products
Thermal decomposition:
In case of fire may be liberated: Sodium compounds, sulphur oxides, phosphorus
compounds, carbon monoxide and carbon dioxide.
no data available
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Toxicological effects:
Acute toxicity (oral): Based on available data, the classification criteria are not met.
May be harmful if swallowed.
Acute toxicity (dermal): Lack of data.
Acute toxicity (inhalative): Lack of data.
Skin corrosion/irritation: Skin Irrit. 2; H315 = Causes skin irritation.
Eye damage/irritation: Eye Dam. 1; H318 = Causes serious eye damage.
Sensitisation to the respiratory tract: Lack of data.
Skin sensitisation: Lack of data.
Germ cell mutagenicity/Genotoxicity: Lack of data.
Carcinogenicity: Lack of data.
Reproductive toxicity: Lack of data.
Effects on or via lactation: Lack of data.
Specific target organ toxicity (single exposure): Lack of data.
Specific target organ toxicity (repeated exposure): Lack of data.
Aspiration hazard: Lack of data.
Symptoms
In case of inhalation: May cause irritations.
After eye contact: Redness, pain, corneal opacity.
General remarks
Information about Potassium peroxomonosulfate:
LD50 Rat, oral: 1200 - 2050 mg/kg.
Harmful if swallowed.
Information about Sodium percarbonate:
LD50 Rat, oral: 1034 - 2000 mg/kg.
Harmful if swallowed.
printed by IBEDA-CHEMIE
... with Qualisys SUMDAT
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH)
and Regulation (EU) No 2015/830
Revision date: 8/7/2015
Version:
6, from batch 1034xx
Language:
en-GB,IE
Date of print: 30/7/2015
WMF Special-Cleaning Tablets
Material number 0062
Page:
7 of 9
SECTION 12: Ecological information
12.1 Toxicity
Aquatic toxicity:
Harmful effects on water organisms by modification of pH-value.
Contains phosphonates. May contribute to the eutrophication of water supplies.
Information about Potassium peroxomonosulfate:
Bacterial toxicity:
EC50 Pseudomonas putida: 179 mg/L/18h.
Daphnia toxicity:
NOEC Daphnia magna: 1,8 mg/L/24h (OECD 202).
LC50 Daphnia magna: 5,3 mg/L/24h (OECD 202).
Fish toxicity:
NOEC Brachydanio rerio (zebra-fish): 32 mg/L/96h (OECD 203).
Source: IUCLID.
12.2. Persistence and degradability
Further details:
The surfactants contained in this preparation comply with the biodegradability criteria as
laid down in Regulation (EC) No.648/2004 on detergents.
12.3 Bioaccumulative potential
Partition coefficient: n-octanol/water:
no data available
12.4 Mobility in soil
no data available
12.5 Results of PBT and vPvB assessment
no data available
12.6 Other adverse effects
General information:
Do not allow to enter into ground-water, surface water or drains.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product
Waste key number:
Recommendation:
20 01 29* = Detergents containing dangerous substances
* = Evidence for disposal must be provided.
Dispose of waste according to applicable legislation.
Smaller amounts: Dilute with plenty of water.
Contaminated packaging
Recommendation:
Waste key number 150101 - paper and cardboard packaging
Waste key number 150102 - Plastic packaging: PVC/PVDC
Waste key number 150104 - Metallic packaging: Aluminium
printed by IBEDA-CHEMIE
... with Qualisys SUMDAT
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH)
and Regulation (EU) No 2015/830
Revision date: 8/7/2015
Version:
6, from batch 1034xx
Language:
en-GB,IE
Date of print: 30/7/2015
WMF Special-Cleaning Tablets
Material number 0062
Page:
8 of 9
SECTION 14: Transport information
14.1 UN number
ADR/RID, IMDG, IATA-DGR:
not applicable
14.2 UN proper shipping name
ADR/RID, IMDG, IATA-DGR:
Not restricted
14.3 Transport hazard class(es)
ADR/RID, IMDG, IATA-DGR:
not applicable
14.4 Packing group
ADR/RID, IMDG, IATA-DGR:
not applicable
14.5 Environmental hazards
Marine pollutant:
No
14.6 Special precautions for user
No dangerous good in sense of these transport regulations.
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
no data available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance
or mixture
National regulations - Great Britain
Hazchem-Code:
No data available
15.2 Chemical Safety Assessment
For this mixture a chemical safety assessment is not required.
printed by IBEDA-CHEMIE
... with Qualisys SUMDAT
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH)
and Regulation (EU) No 2015/830
Revision date: 8/7/2015
Version:
6, from batch 1034xx
Language:
en-GB,IE
Date of print: 30/7/2015
WMF Special-Cleaning Tablets
Material number 0062
Page:
9 of 9
SECTION 16: Other information
Further information
Wording of the H-phrases under paragraph 2 and 3:
H272 = May intensify fire; oxidiser.
H290 = May be corrosive to metals.
H302 = Harmful if swallowed.
H314 = Causes severe skin burns and eye damage.
H315 = Causes skin irritation.
H318 = Causes serious eye damage.
H319 = Causes serious eye irritation.
H412 = Harmful to aquatic life with long lasting effects.
General revision (Regulation (EU) No 2015/830)
2/10/2009
Department issuing data sheet
Reason of change:
Date of first version:
Contact person:
see section 1: Dept. responsible for information
For abbreviations and acronyms, see: ECHA Guidance on information requirements and chemical safety
assessment, chapter R.20 (Table of terms and abbreviations).
The information in this data sheet has been established to our best knowledge and was up-to-date at time of
revision. It does not represent a guarantee for the properties of the product described in terms of the legal
warranty regulations.
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... with Qualisys SUMDAT