Recommended Use and Water-soluble cutting and grinding fluids

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Safety Data Sheet
1. Identification of the Substance/Preparation and of the Company
Product Name
Fine-cool (Concentrate Solution)
Recommended Use and Water-soluble cutting and grinding fluids
Manufacturer
Kyowa Oil Lubricants Co. Ltd.
Address
1-30-5 , Hayabuchi, Tsuzuki-cu,Yokohama- City,kanagawa, Japan
Phone
tel 045(591)2311 fax 045(591)2318
Email Address:info@kyouwa-oil.com
Date of creation
June 4.2006
Revised date
May 27.2015
Sales company
HEIWA TECHNICA CO., LTD.
2. Hazard Identification
GHS Classification:
Physical Hazards
Not applicable to the GHS Classification
Health Hazards
Acute toxicity (oral)
Category 5
Skin Corrosion/Irritation
Category 2
Serious Eye Damage/Eye Irritation
Category 2A
Respiratory sensitizers
Category1
STOT/Systemic Toxicity - Single Exposure
Category 2
STOT/Systemic Toxicity - Repeated Exposure
Category1
Pose an aspiration hazard
Category1
Label Elements
Pictograms/Symbols
Signal Word
Hazard Statements
Danger
May be harmful if inhaled
Skin irritancy
Causes serious eye damage
May cause an allergic skin reaction
May cause respiratory irritation
May cause damage to organs (lung)
The swallow, for fear of danger to life and enters airways
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Precautionary Statements
[Prevention]
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
Wash hands thoroughly after handling.
Do not eat, drink or smoke when using this product.
Contaminated work clothing should not be allowed out of the workplace.
[Response]
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER/doctor.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
If exposed or concerned: Get medical advice/attention.
Get medical advice/attention if you feel unwell.
Take off contaminated clothing and wash it before reuse.
[Storage]
Store locked up.
[Disposal]
Dispose of contents/container in accordance with regulations.
3. Composition/Information on Ingredients
Homogeneous / Mixture:
Mixture
Purpose:
Grinding fluid
Chemical name
Water and additives
Chemical or Structural Formula
Not specifiable
Components and Contents:
(CAS No)
Organic antirust
7.0%
(10043-35-3)
Inorganic alkali
3.0%
(95-14-7)
Antifoam
0.1%
(68439-51-0
Red colorant
0.0005%
(81-88-9)
Diethanolamine
1-10%
(111-42-2)
Triethanolamine
10-20%
(102-71-6)
Water
60-70%
(7732-18-5)
57-55-6
7631-86-9)
Industrial Safety and Health Law
Diethanolamine
1-10% (CAS No111-42-2)
Triethanolamine
10-20% (CAS No102-71-6)
PRTR Law:
NA
4. First-Aid Measures
Inhalation
Remove victim to fresh air and let him rinse mouth thoroughly with water.
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Wrapping a blanket and the like around him to keep warm for a rest, call a
doctor/physician immediately.
Skin Contact
Rinse skin with soap and water.
Eye Contact
Immediately rinse eyes with clean water for at least 15 minutes. Remove
contact lenses if present. Continue rinsing. If eye irritation persists,
get medical attention.
Ingestion
Call a doctor/physician immediately. Do not induce vomiting.
If affected, the mouth should be rinsed out thoroughly with water.
Expected Acute and
If swallowed, may suffer from diarrhea and vomiting.
Delayed Symptoms, and
May cause inflammation if in eyes.
Most Important Symptoms/ May cause inflammation if on skin.
Effects
May feel unwell if mist is inhaled.
5. Fire-Fighting Measures
Suitable Extinguishing Media
Foggy reinforcing agent, foam, powder, or carbon dioxide
Unsuitable Extinguishing Media
Jet water
Specific Hazards
A fire may cause irritating, corrosive, and/or toxic gas.
Specific Fire-Fighting Measures
Shut off the fire source.
Use powder or carbon dioxide extinguishers at the beginning of fire.
It is effective to intercept the air from a big fire with foam
extinguishers. Use of water may cause spreading of fire.
Cool the surrounding facilities with water spray.
Evacuate non essential
personnel around the fire.
Special Protective Actions for
Wearing protective glasses, protective clothing, and if necessary,
Fire-Fighting
respiratory protective equipment, start to fight fire on the windward
side.
6. Accidental Release Measures
Personal Precautions, Protective
Immediately isolate the spill area wide enough in all directions.
Equipment and Emergency Procedures
If skin or eye contact is possible, wear protective equipment. If mist
is produced, wear respiratory protective equipment to avoidinhalation.
Environmental Precautions
Take up as much as possible to avoid soil contamination and water
pollution. Avoid release to the environment
Collection/Neutralization
Eliminate the source of ignition of the surrounding.
and Methods/Materials
In the case of a large amount: Dike ahead of liquid spill area
for Containment
to minimize migration and then sweep into an empty
container for disposal in a safe place. After disposal, wash
away with plenty of water. In doing so, take care to prevent
the high concentration of wastes from entering public
HEIWA TECHNICA CO., LTD
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watercourses such as rivers.
In the case of a small amount: Take up into an empty
container by absorbing the spill with earth and sand or rags,
and furthermore sop up with rags thoroughly.
Prevention of Secondary
Remove all the ignition sources immediately. (Do not smoke
Hazards
Nearby and keep away from sparks and flames.)
Report to the related organs for help.
7. Handling and Storage
Handling
Technical Measures
Before repairing machinery with remnant oils on, remove them
thoroughly in a safe place. Take precautionary measures
Against static discharge and wear electro conductive clothing
and shoes.As vapors released from petroleum products are
heavier than air,they are liable to stagnate.
Due to it, attention should be paid to ventilation and fire.
Handle at room temperatures, paying attention to moisture and
To impurities not to mix with.
If skin or eye contact is possible, wear protective equipment. If
mist is produced, wear respiratory protective equipment to
avoid inhalation.
Use a pump and the like to take out of container.
Do not suck through a tube.
Do not weld, heat, hole, and cut off the container. Residues may
ignite involving explosion.
Local Exhaust Ventilation/
8. Exposure Controls/Personal Protection?.
Full Ventilation System
Avoiding Contact
Refer to ??10. Stability and Reactivity?.
Precautions for Safe Handling
Obtain special instructions before use.
Do not handle until all safety precautions have been read and
understood.
As this product contains ethanolamine, do not use antirust
Agents containing nitrite together.
Be cautious not to use any naked fire.
Wash hands thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Do not eat, drink or smoke when using this product.
Do not press an empty container. It may explode under pressure.
Do not drink.
Keep out of reach of children.
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Storage:
Technical Measures
Avoid heat, sparks, flames, and static electricity.
Keep container tightly closed.
Incompatible Materials
Refer to ?10. Stability and Reactivity?.
Conditions for Safe Storage
Store in a well-ventilated area.
Store avoiding exposure to direct sunlight.
Store away from oxidizer.
Store locked up.
Materials for Containers/Packaging
When replacing the container, use metal or glass container.
Some
kinds of resin-treated container may melt.
Use airtight, anti-breakage type containers.
8. Exposure Controls/Personal Protection
Engineering Controls
When mist and vapors are produced, seal off sources or provide
exhaust ventilation. Facilities for rinsing eyes and washing
a body are required near the workplace.
Permissible Concentration
Not specified
Standards for Allowable Density of Hazardous Substances in Labor Operation Air
Not established
Personal Protective Equipment
Respiratory Protection
Wear appropriate respiratory protection.
Hand Protection
If necessary, wear oil-resistant protective gloves.
Eye Protection
If diffusion is possible, wear eye protection
Skin and Body Protection
If necessary, wear protective clothing and face protection.
Hygienic Precautions
Wash hands thoroughly after handling.
Regularly inspect protective equipment according to the
inspection table ofprotective equipment.
Do not eat, drink or smoke when using this product.
9. Physical and Chemical Properties
Physical State:
Appearance
Liquid
Color
Pale red transparent
Odor
Slightly amine odor
Boiling Point
No data available
Freezing Point
No data available
Decomposition temperature
No data available
Ignition point
No data available
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Flash point
No data available
Flammability
No data available
Explosive Range (Explosive Limits) No data available
Vapor Density (air=1)
No data available
Specific Gravity (Density)
1.1g/cm3 (15 )
Solubility
Dispersible in water
pH
9.7
10. Stability and Reactivity
Stability
I avoid contact with strong oxidizing agents
Possibility of Hazardous Reactions
when stored and stored in the dark at room
temperature, and is stable.
I avoid contact with strong oxidizing agents
hazardous reactions possible.
Conditions to Avoid
Contact with incompatible materials Incompatible
Materials be careful not to contact halogens, strong
acids, alkalis, and oxidizing substances.
Hazardous decomposition products.
Smoke, carbon monoxide, sulfur dioxide or alkalis
is produced during the combustion.
11. Toxicological Information
Acute Toxicity
Oral
Dermal
Skin Corrosion/Irritation
LD50=7269mg/Kg(Rabbit)( Triethanolamine)
LD50 2000ml/Kg(Rabbit)
Skin irritation has been observed by repeated exposure or
exposure to high concentrations in humans.
( Triethanolamine)
Serious Eye Damage/Eye Irritation
Irritation was observed in the eye irritation test with
rabbits. fully recovered after 14 days. ( Triethanolamine)
Respiratory or Skin Sensitization
Respiratory
No information available.
Skin Sensitization
There are reports of allergic contact dermatitis in humans.
Germ Cell Mutagenicity
Negative results ( Triethanolamine)
Carcinogenicity
Classified into group 3 in IARC.
Reproductive Toxicity
No information available.
( Triethanolamine)
Classified into Specific Target Organ Toxicity/Systemic (Single Exposure)
It has been reported that steam is to stimulate the
human nose. ( Triethanolamine)
Classified into Specific Target Organ Toxicity/Systemic (Repeated Exposure)
HEIWA TECHNICA CO., LTD
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No information available.
Aspiration Hazard
No information available.
12. Ecological Information
Ecotoxicity
No information available
Persistence and Degradability
No information available
Bioaccumulative
No information available
Potential
Mobility in Soil
No information available
Other Adverse Effects
No information available
Environmental Criteria
No information available
13. Disposal Considerations
Waste Residues
Dispose the waste according to national and local regulations.
Do not dump.
Contaminated Containers
Contaminated or empty container/packaging are to be disposed
And Packing
according to national and local regulations.
14. Transport Information
International Regulation
UN Classification
Special Precautions
Not applicable
Load the containers in a manner that they are certain not to
result in direct sunlight exposure, damage, corrosion, leak,
while being transported.
Do not place heavy load on top of the container.
HS code
3403.99000
15. Regulatory Information
No Information
16. Other Information
References:
1) Recommendation of Occupational Exposure Limits by Japan Society for Occupational Health
2) Thresholds limit values for chemical substances and physical agents and biological exposure
indices by ACGIH
3) National Institute of Technology and Evaluation
4) SDS of raw materials
1. As evaluations on hazards are not necessary satisfactory, special attention should be paid for use.
2. This SDS, summarizing matters to be attended to, is required for proper use of the product and is intended for
normal use.
HEIWA TECHNICA CO., LTD
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3. Referring to this MSDS, properly use and handle this product on the user?s own responsibility.
4. The contents of this MSDS are based on information available as of today and our knowledge.
The information, data, and evaluations herein are not guaranteed, and in addition, may be revised due
to revision of laws or knowledge newly obtained.
HEIWA TECHNICA CO., LTD
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