MATERIAL SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2004
Date of print:
27.09.2010
Revision date:
09.09.2010
Date of first version: 08.09.2010
WMF Special-Cleaning Tablets 1,3 g
Material number 0063
Version 1, from batch 1034xx / Page: 1 of 5
1. Product and company identification
Identification of the substance or preparation
WMF Special-Cleaning Tablets 1,3 g
Trade name:
Use of the substance/ preparation
Cleaning agent
Company/undertaking identification
IBEDA-CHEMIE Klaus P. Christ GmbH
Am Eichelgärtchen 32
D-56283 Halsenbach
info@ibeda-chemie.com
+49 (0)6747-9501-0
+49 (0)6747-9501-11
Company name:
Street/POB-No.:
State/city/postal code:
Email:
Telephone:
Telefax:
Dept. responsible for information:
Herr Dohmann, Telephone: +49 (0)6747-9501-16
Emergency telephone
Beratungsstelle bei Vergiftung, Telephone: +49
(0)6131-19240
2. Hazards identification
Emergency overview
solid, Tablets
white
odorless
Warning
irritant
Physical state:
Color
Odor:
Regulatory status
This material is considered hazardous by the U.S. OSHA Hazard Communication
Standard (29 CFR 1910.1200) and SIMDUT in Canada.
Potential Health Effects
Irritating to eyes and skin.
Information pertaining to special dangers for human and environment
According to the pH value of 9,5-10,5 the product is not to be classified as corrosive.
May be harmful if swallowed.
Contains phosphonates. May contribute to the eutrophication of water supplies.
refer to chapter 11: Toxicological information
3. Composition/ Information on ingredients
Chemical characterization (preparation)
Mixture of inorganic salts with organic materials
Hazardous ingredients:
CAS No.
497-19-8
15630-89-4
5949-29-1
70693-62-8
Chemical name
Sodium carbonate
Sodium percarbonate
Citric acid monohydrate
Potassium peroxomonosulfate
Content
10-25 %
10-20 %
< 10 %
<5%
4. First-aid measures
After inhalation:
printed by IBEDA-CHEMIE
Provide fresh air. In case of respiratory difficulties seek medical attention.
... with QualiSys SUMDAT
MATERIAL SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2004
Date of print:
27.09.2010
Revision date:
09.09.2010
Date of first version: 08.09.2010
WMF Special-Cleaning Tablets 1,3 g
Material number 0063
In case of skin contact:
After eye contact:
After swallowing:
Version 1, from batch 1034xx / Page: 2 of 5
Remove residues with water. In case of skin reactions, consult a physician.
Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids
apart. Subsequently seek the immediate attention of an ophthalmologist.
Rinse mouth and drink large quantities of water. Consult physician.
Information to physician:
Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media:
Co-ordinate fire-fighting measures to the fire surroundings.
Special exposure hazards arising from the preparation itself, combustion products, resulting gases:
Fires in the immediate vicinity may cause the development of dangerous vapors.
In case of fire may be liberated: Sodium compounds, sulphur oxides, phosphorus
compounds, carbon monoxide and carbon dioxide.
Special protective equipment for firefighters:
Additional information:
Wear a self-contained breathing apparatus and chemical protective clothing.
Fire water reacts alkaline. Do not allow water used to extinguish fire to enter drains,
ground or waterways. Treat runoff as hazardous.
6. Accidental release measures
Personal precautions:
Avoid contact with skin and eyes.
Avoid generation of dust. Do not breathe dust.
Wear personal protection equipment.
Measures to protect the environment:
Methods for cleaning up:
Do not allow to penetrate into soil, waterbodies or drains.
Take up mechanically, placing in appropriate containers for disposal.
Wash spill area with plenty of water.
7. Handling and storage
Handling
Advices on safe handling
In case of dust: Withdraw by suction. Do not breathe dust.
Avoid contact with skin and eyes.
Storage
Requirements for storerooms and containers:
hints on joint storage
Store in a dry place.
Do not store together with highly inflammable or combustible materials.
8. Exposure controls / personal protection
Exposure guidelines
Additional information:
Please observe generally defined limit for dust:
OSHA-TWA VS: 15 mg/m³ (total dust)
OSHA-TWA VS: 5 mg/m³ (respirable fraction)
Engineering controls
Provide adequate ventilation. Vent dust from the work area.
See also information in chapter 7, section storage.
eye protection:
Body protection:
printed by IBEDA-CHEMIE
Tightly sealed safety glasses according to OSHA Standard - 29 CFR: 1910.133 or ANSI
Z87.1-2003.
Wear suitable protective clothing.
... with QualiSys SUMDAT
MATERIAL SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2004
Date of print:
27.09.2010
Revision date:
09.09.2010
Date of first version: 08.09.2010
WMF Special-Cleaning Tablets 1,3 g
Material number 0063
Version 1, from batch 1034xx / Page: 3 of 5
Protective gloves according to OSHA Standard - 29 CFR: 1910.138.
Glove material: Nitrile rubber or butyl caoutchouc (butyl rubber).
Observe glove manufacturer's instructions concerning penetrability and breakthrough time.
Personal protective equipment
Respiratory protection:
In case of dust: Dust mask/Particulates filter P2 according to OSHA Standard - 29 CFR:
1910.134 or ANSI Z88.2.
General protection and hygiene measures:
Wash hands before breaks and after work.
Remove contaminated clothing.
Provide a conveniently located eye rinse station.
9. Physical and chemical properties
Appearance
solid, Tablets
white
odorless
Physical state:
Color
Odor:
Important health, safety and environmental information
approx. 2 g/cm³
9.5-10.5 (10%-solution)
soluble
Density:
pH value:
Water solubility:
10. Stability and reactivity
Materials to avoid
strong acids and alkalis
Hazardous decomposition products
In case of fire may be liberated: Sodium compounds, sulphur oxides, phosphorus
compounds, carbon monoxide and carbon dioxide.
11. Toxicological information
Toxicological Tests:
After inhalation:
After swallowing:
In case of skin contact:
After eye contact:
May cause irritations.
Irritations of mucous membranes in the mouth, pharynx, oesophagus and gastrointestinal
tract.
May be harmful if swallowed.
Irritant.
Irritant.
General remarks
Information about Potassium peroxomonosulfate:
LD50 Rat, oral: 1200 - 2050 mg/kg.
Harmful if swallowed.
Information about Sodium percarbonate:
LD50 Rat, oral: 1034 - 2000 mg/kg.
Harmful if swallowed.
printed by IBEDA-CHEMIE
... with QualiSys SUMDAT
MATERIAL SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2004
Date of print:
27.09.2010
Revision date:
09.09.2010
Date of first version: 08.09.2010
WMF Special-Cleaning Tablets 1,3 g
Material number 0063
Version 1, from batch 1034xx / Page: 4 of 5
12. Ecological information
Ecotoxicity
Aquatic toxicity:
Harmful effects on water organisms by modification of pH-value.
Contains phosphonates. May contribute to the eutrophication of water supplies.
Information about Potassium peroxomonosulfate:
Bacterial toxicity:
EC50 Pseudomonas putida: 179 mg/L/18h.
Daphnia toxicity:
NOEC Daphnia magna: 1,8 mg/L/24h (OECD 202).
LC50 Daphnia magna: 5,3 mg/L/24h (OECD 202).
Fish toxicity:
NOEC Brachydanio rerio (zebra-fish): 32 mg/L/96h (OECD 203).
Source: IUCLID.
Additional ecological information
General information:
Do not allow to enter into ground-water, surface water or drains.
13. Disposal considerations
Product
Recommendation:
Dispose of waste according to applicable legislation.
Smaller amounts: Dilute with plenty of water.
14. Transport information
USA: Department of Transportation (DOT)
Not controlled under DOT.
Proper Shipping Name
Sea transport (IMDG)
Not restricted
Proper shipping name:
Air transport (IATA)
Not restricted
Proper shipping name:
Land transport (ADR/RID)
Not restricted
Product designation:
Canada: Transportation of Dangerous Goods (TDG)
Not controlled under TDG.
Shipping Name
Further information
No dangerous good in sense of these transport regulations.
15. Regulatory information
U.S. Federal Regulations
Sodium carbonate:
Sodium percarbonate:
Citric acid monohydrate:
Potassium peroxomonosulfate:
TSCA Inventory: listed
TSCA HPVC: not listed
TSCA Inventory: listed
TSCA HPVC: not listed
TSCA listed: Citric acid anhydrous CAS 77-92-9
TSCA Inventory: listed
TSCA HPVC: not listed
U.S. State Regulations
California Proposition 65 Status: This product does not contain chemicals currently on
the California list of known carcinogens and/or reproductive toxins.
printed by IBEDA-CHEMIE
... with QualiSys SUMDAT
MATERIAL SAFETY DATA SHEET
in accordance with 29 CFR 1910.1200 and ANSI standard Z400.1-2004
Date of print:
27.09.2010
Revision date:
09.09.2010
Date of first version: 08.09.2010
WMF Special-Cleaning Tablets 1,3 g
Material number 0063
Version 1, from batch 1034xx / Page: 5 of 5
National regulations - EC member states
Code letter and hazard symbol:
Xi
R phrase(s):
R 36/38
S phrase(s):
S2
S 24/25
S 26
Text for labeling
irritant
Irritating to eyes and skin.
Keep out of the reach of children.
Avoid contact with skin and eyes.
In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
Contains sodium percarbonate and Potassium peroxomonosulfate.
Contains 15-30% phosphonates, 15-30% oxygen-based bleaching agents.
16. Other information
Hazard rating systems
0
1
0
NFPA Hazard Rating:
Health: 1 (Slight)
Fire: 0 (Minimal)
Reactivity: 0 (Minimal)
HMIS Version III Rating:
Health: 1 (Slight)
Flammability: 0 (Minimal)
Physical Hazard: 0 (Minimal)
Personal Protection: X = Consult your supervisor
JT Baker Storage Color Code: Green (General Storage)
HEALTH
1
FLAMMABILITY
0
PHYSICAL HAZARD
0
X
Group that issues data sheet
Contact person:
see chapter 1, department responsible for information.
The information in this data sheet has been established to our best knowledge and was up-to-date at time of
revision. It does not represent a guarantee for the properties of the product described in terms of the legal
warranty regulations.
printed by IBEDA-CHEMIE
... with QualiSys SUMDAT
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