en-GB - Maddocks UK Tradesite

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No.
2015/830
Revision date: 13/6/2017
Version:
8
Language:
en-GB,IE
Date of print: 14/6/2017
Cleaning tablets for fully automatic coffee
machines and thermos flasks with soil release
effect
Material number 00311560 / 00311769 / 00311823
Page:
1 of 10
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
1.1 Product identifier
Trade name:
Cleaning tablets for fully automatic coffee machines and thermos flasks with soil release
effect
1.2 Relevant identified uses of the substance or mixture and uses advised against
General use:
Cleaning agent
1.3 Details of the supplier of the safety data sheet
Company name:
Street/POB-No.:
Postal Code, city:
E-mail:
Telephone:
Telefax:
Dept.responsibleforinformation:
Additional information:
1.4 Emergency telephone number
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to EC regulation 1272/2008 (CLP)
Skin Irrit. 2; H315 Causes skin irritation.
Eye Dam. 1; H318 Causes serious eye damage.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No.
2015/830
Revision date: 13/6/2017
Version:
8
Language:
en-GB,IE
Date of print: 14/6/2017
Cleaning tablets for fully automatic coffee
machines and thermos flasks with soil release
effect
Material number 00311560 / 00311769 / 00311823
Page:
2 of 10
2.2 Label elements
Labelling (CLP)
Signal word:
Danger
Hazard statements:
H315
H318
Causes skin irritation.
Causes serious eye damage.
P102
Keep out of reach of children.
P280
Wear protective gloves and eye protection.
P302+P352
IF ON SKIN: Wash with plenty of water/soap.
IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
If skin irritation occurs: Get medical advice/attention.
Precautionary statements:
P305+P351+P338 IF
P332+P313
Special labelling
Contains 15-30% Sodium carbonate
Labelling for contents according to regulation (EC) No 648/2004, annex VII:
Contains
- 5% or over but less than 15% phosphonates
- 15% or over but less than 30% oxygen-based bleaching agents
Text for labelling:
2.3 Other hazards
May be harmful if swallowed. May intensify fire; oxidiser.
Contains phosphonates. May contribute to the eutrophication of water supplies.
Results of PBT and vPvB assessment:
No data available
SECTION 3: Composition / information on ingredients
3.1 Substances: not applicable
3.2 Mixtures
Chemical characterisation: Mixture
of inorganic salts with organic materials
Revision date: 13/6/2017
Version:
8
Language:
en-GB,IE
Date of print: 14/6/2017
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No.
2015/830
Cleaning tablets for fully automatic coffee
machines and thermos flasks with soil release
effect
Material number 00311560 / 00311769 / 00311823
Page:
3 of 10
Hazardous ingredients:
Ingredient
Designation
Content
Classification
EC No. 207-838-8
CAS 497-19-8
REACH 01-2119457268-30-xxxx
EC No. 239-707-6
CAS 15630-89-4
REACH 01-2119457026-42-xxxx
EC No. 201-069-1
CAS 77-92-9
EC No. 274-778-7
CAS 70693-62-8
Sodium carbonate
20 - 30 %
Eye Irrit. 2; H319.
Sodium
percarbonate
< 25 %
Citric acid,
anhydrous
< 10 %
Ox. Sol. 3; H272.
Acute Tox. 4; H302.
Eye Dam. 1; H318.
Eye Irrit. 2; H319.
Potassium
<5%
peroxymonosulfate
Met. Corr. 1; H290.
Acute Tox. 4; H302.
Skin Corr. 1B; H314.
Aquatic Chronic 3; H412.
Full text of H- and EUH-statements: see section 16.
Additional information:
Contains polyethylene glycol (CAS 25322-68-3). The maximum workplace exposure limits
are, where necessary, listed in section 8.
Labelling for contents according to regulation (EC) No 648/2004, annex VII:
Contains
- 5% or over but less than 15% phosphonates
- 15% or over but less than 30% oxygen-based bleaching agents
SECTION 4: First aid measures
4.1 Description of first aid measures
In case of inhalation:
Following skin contact:
After eye contact:
After swallowing:
Provide fresh air. In case of respiratory difficulties seek medical attention.
Remove residues with water. In case of skin reactions, consult a physician.
Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids
apart. Remove contact lenses, if present and easy to do. Continue rinsing. Subsequently
seek the immediate attention of an ophthalmologist.
Never give anything by mouth to an unconscious person. Rinse mouth and drink large
quantities of water.
Consult physician.
4.2 Most important symptoms and effects, both acute and delayed
Causes serious eye damage.
Causes skin irritation.
4.3 Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No.
2015/830
Revision date: 13/6/2017
Version:
8
Language:
en-GB,IE
Date of print: 14/6/2017
Cleaning tablets for fully automatic coffee
machines and thermos flasks with soil release
effect
Material number 00311560 / 00311769 / 00311823
Page:
4 of 10
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media:
Product is non-combustible. Extinguishing materials should therefore be selected
according to surroundings.
Extinguishing media which must not be used for safety reasons:
Full water jet
5.2 Special hazards arising from the substance or mixture
Fires in the immediate vicinity may cause the development of dangerous vapours.
In case of fire may be liberated: Sodium compounds, sulphur oxides, phosphorus
compounds, carbon monoxide and carbon dioxide.
5.3 Advice for firefighters
Special protective equipment for firefighters:
Additional information:
Wear a self-contained breathing apparatus and chemical protective clothing.
Hazchem-Code: Cool endangered containers with water spray and, if possible, remove from danger zone.
Use water spray jet to knock down vapours. Do not inhale dust or gases/vapours
generated by fire. Fire water reacts alkaline. Do not allow water used to extinguish fire to
enter drains, ground or waterways.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Avoid contact with skin, eyes, and clothing.
Avoid generation of dust. Do not breathe dust.
Wear personal protection equipment.
In case of dust formation: Ensure adequate ventilation, especially in confined areas.
6.2 Environmental precautions
Do not allow to penetrate into soil, waterbodies or drains.
6.3 Methods and material for containment and cleaning up
Avoid generation of dust.
Take up mechanically, placing in appropriate containers for disposal.
Wash spill area with plenty of water.
6.4 Reference to other sections
Refer additionally to section 8 and 13.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No.
2015/830
Revision date: 13/6/2017
Version:
8
Language:
en-GB,IE
Date of print: 14/6/2017
Cleaning tablets for fully automatic coffee
machines and thermos flasks with soil release
effect
Material number 00311560 / 00311769 / 00311823
Page:
5 of 10
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Advices on safe handling:
Avoid contact with skin, eyes, and clothing.
Avoid generation of dust. Do not breathe dust. Wear appropriate protective equipment.
When using do not eat, drink or smoke.
In case of dust formation: Provide adequate ventilation, and local exhaust as needed.
Precautions against fire and explosion:
Usual measures for fire prevention.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storerooms and containers:
Store container tightly closed in a dry and cool place.
Hints on joint storage:
Do not store together with highly inflammable or combustible materials.
Keep away from food, drink and animal feedingstuffs.
7.3 Specific end use(s)
Cleaning agent
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limit values:
Type
Limit value
Great Britain: WEL-TWA
Great Britain: WEL-TWA
Ireland: 8 hours
Ireland: 8 hours
10 mg/m³ Dust limit value inhalable fraction
4 mg/m³ Dust limit value respirable fraction
10 mg/m³ Dust limit value inhalable fraction
4 mg/m³ Dust limit value respirable fraction
8.2 Exposure controls
Provide adequate ventilation. Dust should be exhausted directly at the point of origin.
Personal protection equipment
Occupational exposure controls
Respiratory protection:
In case of dust formation: Dust mask/Particulates filter P2 according to EN 143.
Hand protection:
In case of handling larger quantities:
Protective gloves according to EN 374.
Glove material: Nitrile rubber or butyl caoutchouc (butyl rubber).
Observe glove manufacturer's instructions concerning penetrability and breakthrough time.
Eye protection:
In case of handling larger quantities:
Tightly sealed goggles according to EN 166.
Body protection:
Wear suitable protective clothing.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No.
2015/830
Revision date: 13/6/2017
Version:
8
Language:
en-GB,IE
Date of print: 14/6/2017
Cleaning tablets for fully automatic coffee
machines and thermos flasks with soil release
effect
Material number 00311560 / 00311769 / 00311823
Page:
General protection and hygiene measures:
Avoid contact with skin, eyes, and clothing. Change contaminated clothing.
Do not breathe dust. Wear appropriate protective equipment.
Have eye wash bottle or eye rinse ready at work place.
After work, wash hands and face. When using do not eat, drink or smoke.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Form: solid, Tablets
Colour: white
odourless
No data available
Appearance:
Odour:
Odour threshold:
pH value:
Melting point/freezing point:
Initial boiling point and boiling range:
Flash point/flash point range:
Evaporation rate:
Flammability:
Explosion limits:
Vapour pressure:
Vapour density:
Density:
Water solubility:
Partition coefficient: n-octanol/water:
Auto-ignition temperature:
Decomposition temperature:
Viscosity, kinematic:
Explosive properties:
Oxidizing characteristics:
at 10%: 9 - 10 g/cm³
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
approx. 2 g/cm³
soluble
No data available
No data available
No data available
No data available
No data available
No data available
9.2 Other information
No data available
Additional information:
SECTION 10: Stability and reactivity
10.1 Reactivity
Product is hygroscopic.
10.2 Chemical stability
Stable under recommended storage conditions.
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No.
2015/830
Revision date: 13/6/2017
Version:
8
Language:
en-GB,IE
Date of print: 14/6/2017
Cleaning tablets for fully automatic coffee
machines and thermos flasks with soil release
effect
Material number 00311560 / 00311769 / 00311823
Page:
7 of 10
10.3 Possibility of hazardous reactions
No hazardous reactions known.
10.4 Conditions to avoid
humidity. Excessive heating. Avoid generation of dust.
10.5 Incompatible materials
Strong acids and alkalis
10.6 Hazardous decomposition products
Thermal decomposition:
In case of fire may be liberated: Sodium compounds, sulphur oxides, phosphorus
compounds, carbon monoxide and carbon dioxide.
No data available
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Toxicological effects:
The statements are derived from the properties of the single components. No toxicological
data is available for the product as such.
Acute toxicity (oral): Based on available data, the classification criteria are not met.
ATEmix (calculated): 2000 mg/kg < ATE <= 5000 mg/kg.
Information about Potassium peroxymonosulfate:
LD50 Rat, oral: 1200 - 2050 mg/kg.
Harmful if swallowed.
Information about sodium percarbonate:
LD50 Rat, oral: 1034 - 2020 mg/kg.
Harmful if swallowed.
Acute toxicity (dermal): Lack of data.
Acute toxicity (inhalative): Lack of data.
Skin corrosion/irritation: Skin Irrit. 2; H315 = Causes skin irritation.
Eye damage/irritation: Eye Dam. 1; H318 = Causes serious eye damage.
Sensitisation to the respiratory tract: Lack of data.
Skin sensitisation: Lack of data.
Germ cell mutagenicity/Genotoxicity: Lack of data.
Carcinogenicity: Lack of data.
Reproductive toxicity: Lack of data.
Effects on or via lactation: Lack of data.
Specific target organ toxicity (single exposure): Lack of data.
Specific target organ toxicity (repeated exposure): Lack of data.
Aspiration hazard: Lack of data.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No.
2015/830
Revision date: 13/6/2017
Version:
8
Language:
en-GB,IE
Date of print: 14/6/2017
Cleaning tablets for fully automatic coffee
machines and thermos flasks with soil release
effect
Material number 00311560 / 00311769 / 00311823
Page:
8 of 10
Symptoms
In case of ingestion:
Irritations of mucous membranes in the mouth, pharynx, oesophagus and gastrointestinal
tract.
SECTION 12: Ecological information
12.1 Toxicity
Aquatic toxicity:
Information about Potassium peroxymonosulfate:
Bacterial toxicity:
EC50 Pseudomonas putida: 179 mg/L/18h.
Daphnia toxicity:
NOEC Daphnia magna (Big water flea): 1.8 mg/L/24h (OECD 202).
LC50 Daphnia magna (Big water flea): 5.3 mg/L/24h (OECD 202).
Fish toxicity:
NOEC Brachydanio rerio (zebra-fish): 32 mg/L/96h (OECD 203).
12.2 Persistence and degradability
Further details:
The surfactant contained in this mixture complies with the biodegradability criteria as laid
down in Regulation (EC) No. 648/2004 on detergents.
12.3 Bioaccumulative potential
Partition coefficient: n-octanol/water:
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
No data available
12.6 Other adverse effects
General information:
Contains phosphonates. May contribute to the eutrophication of water supplies.
Do not allow to enter into ground-water, surface water or drains.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product
Waste key number:
Recommendation:
20 01 29* = Detergents containing hazardous substances
* = Evidence for disposal must be provided.
Dispose of waste according to applicable legislation.
Smaller amounts: Dilute with plenty of water.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No.
2015/830
Revision date: 13/6/2017
Version:
8
Language:
en-GB,IE
Date of print: 14/6/2017
Cleaning tablets for fully automatic coffee
machines and thermos flasks with soil release
effect
Material number 00311560 / 00311769 / 00311823
Page:
Contaminated packaging
Recommendation:
Waste key number 150101 - paper and cardboard packaging
Waste key number 150102 - Plastic packaging: PVC/PVDC
Waste key number 150104 - Metallic packaging: Aluminium
SECTION 14: Transport information
14.1 UN number
ADR/RID, IMDG, IATA-DGR:
not applicable
14.2 UN proper shipping name
ADR/RID, IMDG, IATA-DGR:
Not restricted
14.3 Transport hazard class(es)
ADR/RID, IMDG, IATA-DGR:
not applicable
14.4 Packing group
ADR/RID, IMDG, IATA-DGR:
not applicable
14.5 Environmental hazards
Marine pollutant:
no
14.6 Special precautions for user
ADR, ADN, IMDG, IATA: No dangerous good in sense of these transport regulations.
14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
No data available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance
or mixture
National regulations - Great Britain
Hazchem-Code:
No data available
15.2 Chemical Safety Assessment
For this mixture a chemical safety assessment is not required.
9 of 10
Revision date: 13/6/2017
Version:
8
Language:
en-GB,IE
Date of print: 14/6/2017
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) and Regulation (EU) No.
2015/830
Cleaning tablets for fully automatic coffee
machines and thermos flasks with soil release
effect
Material number 00311560 / 00311769 / 00311823
Page:
10 of 10
SECTION 16: Other information
Further information
Wording of the H-phrases under paragraph 2 and 3:
H272 = May intensify fire; oxidiser.
H290 = May be corrosive to metals.
H302 = Harmful if swallowed.
H314 = Causes severe skin burns and eye damage.
H315 = Causes skin irritation.
H318 = Causes serious eye damage.
H319 = Causes serious eye irritation.
H412 = Harmful to aquatic life with long lasting effects.
General revision
11/12/2013
Department issuing data sheet
Contact person:
see section 1: Dept. responsible for information
Reason of change:
Date of first version:
For abbreviations and acronyms, see: ECHA Guidance on information requirements and chemical safety
assessment, chapter R.20 (Table of terms and abbreviations).
The information in this data sheet has been established to our best knowledge and was up-to-date at time of
revision. It does not represent a guarantee for the properties of the product described in terms of the legal
warranty regulations.
Most recent product information is available at:
http://sumdat.net/0x2nwe9f