Safety Data Sheet
Material Name: Portland Cement (ASTM Type I/II, ASTM Type III, ASTM Type V, Block, Plastic,
Fast Set, Low Heat of Hydration)
Synonyms: Portland Cement; also known as Cement or Hydraulic Cement, Mortar, Class G
* * * Section 1 - Product and Company Identification * * *
Manufacturer Information
CALPORTLAND COMPANY
2025 E. Financial Way
Glendora, CA 91741
Phone: 626-852-6200 www.calportland.com
* * * Section 2 - Hazards Identification * * *
GHS Classification:
Acute Toxicity Oral - Category 4
Acute Toxicity Dermal - Category 4
Acute Toxicity Inhalation - Category 3
Skin Corrosion/Irritation - Category 1B
Eye Damage - Category 1
Respiratory Sensitization - Category 1
Skin Sensitization - Category 1
Carcinogenicity - Category 1A
Specific Target Organ Toxicity Repeat Exposure - Category 1
GHS LABEL ELEMENTS
Symbol(s)
Signal Word
Danger
Hazard Statements
Harmful if swallowed.
Harmful in contact with skin.
Toxic if inhaled.
Causes severe skin burns and eye damage.
Causes serious eye damage.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
May cause cancer.
Causes damage to organs through prolonged or repeated exposure (lungs).
Page 1 of 9
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Issue Date 09/11/12 Revision 1.0000
Print Date: 9/11/2012
Safety Data Sheet
Material Name: Portland Cement (ASTM Type I/II, ASTM Type III, ASTM Type V, Block, Plastic, Fast
Set, Low Heat of Hydration)
Precautionary Statements
Prevention
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Wear protective gloves/protective clothing/eye protection/face protection.
Contaminated work clothing must not be allowed out of the workplace.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
In case of inadequate ventilation wear respiratory protection.
Response
If swallowed: Rinse mouth. Do NOT induce vomiting. Immediately call a poison center/doctor.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a poison center or doctor/physician. Wash contaminated clothing before reuse.
If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a poison center or doctor/physician.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Immediately call a poison center/doctor.
Storage
Store in a well-ventilated place.
Store in an appropriate container or containment structure.
Disposal
Dispose of contents/container in accordance with local/regional/international regulations.
* * * Section 3 - Composition / Information on Ingredients * * *
CAS #
65997-15-1
Component
Cement, portland, chemicals
1317-65-3 Limestone
Percent
78-95
0-15
5-7
0-0.3 14808-60-7 Quartz
Component Information/Information on Non-Hazardous Components
General Product Information
Trace Elements: Portland cement is made from materials mined from the earth and is processed using energy provided by fuels. Trace amounts of naturally occurring, potentially harmful chemical might be detected during chemical analysis. For example, Portland cement may contain up to 1.50 % insoluble residue, some of which may be free crystalline silica. Other trace constituents may include calcium oxide, free magnesium oxide, potassium and sodium sulfate compounds, and trace metal compounds.
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Issue Date 09/11/12 Revision 1.0000
Print Date: 9/11/2012
Safety Data Sheet
Material Name: Portland Cement (ASTM Type I/II, ASTM Type III, ASTM Type V, Block, Plastic, Fast
Set, Low Heat of Hydration)
* * * Section 4 - First Aid Measures * * *
First Aid: Eyes
Immediately flush eyes thoroughly with water. Continue flushing eye for at least 15 minutes, including under lids, to remove all particles. Call physician immediately.
First Aid: Skin
Wash skin with cool water and pH-neutral soap or a mild detergent intended for use on skin. Seek medical treatment in all cases of prolonged exposure to wet cement, cement mixtures, liquids from fresh cement products, or prolonged wet skin exposure to the dry cement.
First Aid: Ingestion
Do not induce vomiting. If conscious, have the victim drink plenty of water and call a physician immediately.
First Aid: Inhalation
Remove to fresh air. Seek medical help if coughing and other symptoms do not subside. (Inhalation of gross amounts of Portland cement requires immediate medical attention.)
* * * Section 5 - Fire Fighting Measures * * *
General Fire Hazards
See Section 9 for Flammability Properties.
Non-combustible.
Hazardous Combustion Products
None
Extinguishing Media
Use appropriate extinguishing media for surrounding fire.
Unsuitable Extinguishing Media
None
Fire Fighting Equipment/Instructions
Firefighters should wear full protective gear.
* * * Section 6 - Accidental Release Measures * * *
Recovery and Neutralization
Stop the flow of material, if this is without risk.
Materials and Methods for Clean-Up
Collect dry material using a scoop. Avoid actions that cause dust to become airborne. Avoid inhalation of dust and contact with skin. Scrape up wet material and place in an appropriate container. Allow the material to dry before disposal.
Emergency Measures
Isolate area. Keep unnecessary personnel away.
Personal Precautions and Protective Equipment
Wear appropriate personal protective equipment as described in Section 8.
Environmental Precautions
Do not attempt to wash Portland cement down sewers or storm drains.
Prevention of Secondary Hazards
None
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Issue Date 09/11/12 Revision 1.0000
Print Date: 9/11/2012
Safety Data Sheet
Material Name: Portland Cement (ASTM Type I/II, ASTM Type III, ASTM Type V, Block, Plastic, Fast
Set, Low Heat of Hydration)
* * * Section 7 - Handling and Storage * * *
Handling Procedures
Avoid prolonged or repeated breathing of dust. Avoid contact with eyes and skin. Promptly remove dusty clothing or clothing which is wet with cement fluids and launder before reuse. Wash thoroughly after exposure to dust or wet cement mixtures.
Storage Procedures
Store product in a cool, dry, ventilated area. Protect against physical damage and moisture. Keep cement dry until used. Normal temperature and pressures do not affect the material.
Incompatibilities
Wet Portland cement is alkaline. As such it is incompatible with acids, ammonium salts and aluminum metal.
* * * Section 8 - Exposure Controls / Personal Protection * * *
Component Exposure Limits
Cement, portland, chemicals (65997-15-1)
ACGIH: 1 mg/m3 TWA (particulate matter containing no asbestos and <1% crystalline silica, respirable fraction)
OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
NIOSH: 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust)
Limestone (1317-65-3)
OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
NIOSH: 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust)
Gypsum (Ca(SO4).2H2O) (13397-24-5)
ACGIH: 10 mg/m3 TWA (inhalable fraction, listed under Calcium sulfate)
OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
NIOSH: 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust)
Quartz (14808-60-7)
ACGIH: 0.025 mg/m3 TWA (respirable fraction)
NIOSH: 0.05 mg/m3 TWA (respirable dust)
Engineering Measures
Avoid actions that cause dust to become airborne. Use local exhaust or general dilution ventilation to control exposure within applicable limits.
Personal Protective Equipment: Respiratory
Use local or general ventilation to control exposures below applicable exposure limits. NIOSH or MSHA approved particulate filter respirators should be used in the context of respiratory protection program meeting the requirements of the OSHA respiratory protection standard [29 CFR 1910.134] to control exposures when ventilation or other controls are inadequate or discomfort or irritation is experienced. Respirator and/or filter cartridge selection should be based on American National Standards Institute (ANSI) Standards Z88.2 Practices for Respiratory Protection.
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Issue Date 09/11/12 Revision 1.0000
Print Date: 9/11/2012
Safety Data Sheet
Material Name: Portland Cement (ASTM Type I/II, ASTM Type III, ASTM Type V, Block, Plastic, Fast
Set, Low Heat of Hydration)
Personal Protective Equipment: Hands
Where prolonged exposure to unhardened concrete products might occur, wear impervious gloves to eliminate skin contact. Do not rely on barrier creams; barrier creams should not be used in place of gloves. Periodically wash areas contacted by wet cement or its dry ingredients with a pH neutral soap and water. Wash again at the end of the work. If irritation occurs, immediately wash the affected area and seek treatment.
Personal Protective Equipment: Eyes
When engaged in activities where wet concrete or its dry ingredients could contact the eye, wear safety glasses with side shields or goggles. In extremely dusty environments and unpredictable environments, wear unvented or indirectly vented goggles to avoid eye irritation or injury. Contact lenses should not be worn when working with
Portland cement or fresh cement products.
Personal Protective Equipment: Skin and Body
Where prolonged exposure to unhardened concrete products might occur, wear impervious clothing to eliminate skin contact. Where required, wear boots that are impervious to water to eliminate foot and ankle exposure. If clothing becomes saturated with wet concrete, it should be removed and replaced with clean dry clothing.
* * * Section 9 - Physical & Chemical Properties * * *
Appearance: Gray powder.
Physical State: Solid
Vapor Pressure: Not Applicable
Boiling Point: Not Applicable
Solubility (H2O): Slightly soluble
Evaporation Rate: Not Applicable
Octanol/H2O Coeff.: Not Determined
Flash Point Method: None
Odor: None pH: 12-13 (in water)
Vapor Density: Not Applicable
Melting Point: Not Applicable
Specific Gravity: 3.15
VOC: Not Determined
Flash Point: None
Upper Flammability Limit
(UFL):
None
Burning Rate: None Lower Flammability Limit
(LFL):
None
Auto Ignition: Not Combustible
* * * Section 10 - Chemical Stability & Reactivity Information * * *
Chemical Stability
This is a stable material.
Hazardous Reaction Potential
Will not occur.
Conditions to Avoid
Unintentional contact with water.
Incompatible Products
Wet Portland cement is alkaline. As such it is incompatible with acids, ammonium salts and aluminum metal.
Hazardous Decomposition Products
Will not spontaneously occur. Adding water results in hydration and produces (caustic) calcium hydroxide.
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Issue Date 09/11/12 Revision 1.0000
Print Date: 9/11/2012
Safety Data Sheet
Material Name: Portland Cement (ASTM Type I/II, ASTM Type III, ASTM Type V, Block, Plastic, Fast
Set, Low Heat of Hydration)
* * * Section 11 - Toxicological Information * * *
Acute Toxicity
Component Analysis - LD50/LC50
Quartz (14808-60-7)
Oral LD50 Rat 500 mg/kg
Potential Health Effects: Skin Corrosion Property/Stimulativeness
Discomfort or pain cannot be relied upon to alert a person to a hazardous skin exposure. Consequently, the only effective means of avoiding skin injury or illness involves minimizing skin contact, particularly contact with wet cement. Exposed persons may not feel discomfort until hours after the exposure has ended and significant injury has occurred. Exposure during the handling or mixing of the dry ingredients in Portland cement may cause drying of the skin with consequent mild irritation or more significant effects attributable to aggravation of other conditions.
Exposure to wet concrete may cause more severe skin effects including thickening, cracking or fissuring of the skin. Prolonged exposure can cause severe skin damage in the form of (caustic) chemical burns.
Potential Health Effects: Eye Critical Damage/ Stimulativeness
Exposure to airborne dust during the handling or mixing of the dry ingredients in Portland cement may cause immediate or delayed irritation or inflammation. Eye contact by splashes of wet concrete may cause effects ranging from moderate eye irritation to chemical burns and blindness. Such exposures require immediate first aid
(see Section 4) and medical attention to prevent significant damage to the eye.
Potential Health Effects: Ingestion
Although inadvertent ingestion of small quantities of wet concrete or its dry ingredients are not known to be harmful, accidental ingestion of larger quantities can be harmful and requires immediate medical attention.
Potential Health Effects: Inhalation
Exposure to Portland cement in excess of the applicable TLV or PEL (see section 2) may cause or aggravate other lung conditions. The ingredients in Portland cement may contain trace amounts of crystalline silica.
Exposure to these ingredients in excess of the applicable TLV or PEL (see Section 2) may cause or aggravate other lung conditions. Exposure to Portland cement may cause irritation to the moist mucous membranes of the nose, throat, and upper respiratory system. It may also leave unpleasant deposits in the nose.
Respiratory Organs Sensitization/Skin Sensitization
May cause allergy or asthma symptoms or breathing difficulties if inhaled. Some individuals may exhibit an allergic response upon exposure to wet concrete. The response may appear in a variety of forms ranging from a mild rash to severe skin ulcers. Persons already sensitized may react to their first contact with the product. Other persons may first experience this effect after years of contact with Portland cement products.
Generative Cell Mutagenicity
This product is not reported to have any mutagenic effects.
Carcinogenicity
A: General Product Information
May cause cancer.
Prolonged and repeated exposure to airborne free respirable crystalline silica can result in lung disease and/or lung cancer. IARC states that crystalline silica in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (Group 1).
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Issue Date 09/11/12 Revision 1.0000
Print Date: 9/11/2012
Safety Data Sheet
Material Name: Portland Cement (ASTM Type I/II, ASTM Type III, ASTM Type V, Block, Plastic, Fast
Set, Low Heat of Hydration)
B: Component Carcinogenicity
Cement, portland, chemicals (65997-15-1)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
Quartz (14808-60-7)
ACGIH: A2 - Suspected Human Carcinogen
NIOSH: potential occupational carcinogen
NTP: Known Human Carcinogen (respirable size) (Select Carcinogen)
IARC: Monograph 100C [2012] (listed under Crystalline silica inhaled in the form of quartz or cristobalite from occupational sources); Monograph 68 [1997] (Group 1 (carcinogenic to humans))
Reproductive Toxicity
This product is not reported to have any reproductive toxicity effects.
Specified Target Organ General Toxicity: Single Exposure
This product is not reported to have any single exposure specific target organ toxicity effects.
Specified Target Organ General Toxicity: Repeated Exposure
Causes damage to organs through prolonged or repeated exposure (lungs).
Aspiration Respiratory Organs Hazard
This product is not reported to have any aspiration hazards.
* * * Section 12 - Ecological Information * * *
Ecotoxicity
A: General Product Information
This product is not reported to have any ecotoxicity effects.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
No ecotoxicity data are available for this product's components.
Persistence/Degradability
No information available for the product.
Bioaccumulation
No information available for the product.
Mobility in Soil
No information available for the product.
* * * Section 13 - Disposal Considerations * * *
Waste Disposal Instructions
See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations.
Disposal of Contaminated Containers or Packaging
Dispose of contents/container in accordance with local/regional/national/international regulations.
* * * Section 14 - Transportation Information * * *
DOT Information
Shipping Name: Not Regulated.
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Issue Date 09/11/12 Revision 1.0000
Print Date: 9/11/2012
Safety Data Sheet
Material Name: Portland Cement (ASTM Type I/II, ASTM Type III, ASTM Type V, Block, Plastic, Fast
Set, Low Heat of Hydration)
* * * Section 15 - Regulatory Information * * *
Regulatory Information
US Federal Regulations
Component Analysis
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section
313 (40 CFR 372.65), or CERCLA (40 CFR 302.4).
State Regulations
Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS CA MA MN NJ PA RI
Limestone
65997-15-1 No Yes Yes Yes Yes No
1317-65-3 No Yes Yes Yes Yes No
13397-24-5 No No Yes Yes Yes No
14808-60-7 No Yes Yes Yes Yes No Quartz
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of
1986 (Proposition 65):
WARNING! This product contains chemicals known to the state of California to cause cancer, birth defects, or other reproductive harm.
Component Analysis - WHMIS IDL
No components are listed in the WHMIS IDL.
Additional Regulatory Information
Component Analysis - Inventory
Cement, portland, chemicals 65997-15-1 Yes DSL EINECS
Gypsum (Ca(SO4).2H2O) 13397-24-5 No DSL No
Page 8 of 9
____________________________________________________________
Issue Date 09/11/12 Revision 1.0000
Print Date: 9/11/2012
Safety Data Sheet
Material Name: Portland Cement (ASTM Type I/II, ASTM Type III, ASTM Type V, Block, Plastic, Fast
Set, Low Heat of Hydration)
* * * Section 16 - Other Information * * *
Hazardous Material Information System (HMIS):
Health 1
Flammability 0
Physical Hazard 0
Personal Protection B
NFPA/HMIS Definitions: 0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme
Protective Equipment: Safety glasses, gloves
Key/Legend
EPA = Environmental Protection Agency; TSCA = Toxic Substance Control Act; ACGIH = American Conference of Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NIOSH = National
Institute for Occupational Safety and Health; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration., NJTSR = New Jersey Trade Secret Registry.
Literature References
None
Other Information
SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE
MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF
ANY INFORMATION PROVIDED BY CALPORTLAND, except that the product shall conform to contracted specifications. The information provided herein was believed by CalPortland Company to be accurate at the time of preparation or prepared from sources believed to be reliable, but it is the responsibility of the user to investigate and understand other pertinent sources of information to comply with all laws and procedures applicable to the safe handling and use of the product and to determine the suitability of the product for its intended use. Buyer's exclusive remedy shall be for damages and no claim of any kind, whether as to product delivered or for nondelivery of product, and whether based on contract, breach of warranty, negligence, or otherwise shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, negligence or otherwise.
End of Sheet
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Issue Date 09/11/12 Revision 1.0000
Print Date: 9/11/2012
