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GHS SAFETY DATA SHEET

WELD-ON® 735™ Wet 'N Fast™ Low VOC Cement for PVC Plastic Pipe

Date Revised: APR 2015

Supersedes: NOV 2014

SECTION I - PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME:

WELD-ON® 735™ Wet 'N Fast™ Low VOC Cement for PVC Plastic Pipe

PRODUCT USE: Low VOC Solvent Cement for PVC Plastic Pipe

SUPPLIER: MANUFACTURER: IPS Corporation

17109 South Main Street, Gardena, CA 90248-3127

P.O. Box 379, Gardena, CA 90247-0379

Tel. 1-310-898-3300

EMERGENCY: Transportation: CHEMTEL Tel. 800.255-3924, +1 813-248-0585 (International) Medical: CHEMTEL Tel. 800.255-3924, +1 813-248-0585 (International)

SECTION 2 - HAZARDS IDENTIFICATION

GHS CLASSIFICATION:

Health

Acute Toxicity:

Skin Irritation:

Skin Sensitization:

Eye:

Category 4

Category 3

NO

Category 2

Acute Toxicity:

Chronic Toxicity:

Environmental

None Known

None Known

Flammable Liquid

Physical

Category 2

GHS LABEL: Signal Word:

Danger

WHMIS CLASSIFICATION: CLASS B, DIVISION 2

CLASS D, DIVISION 1B

Hazard Statements

H225: Highly flammable liquid and vapor

H319: Causes serious eye irritation

H335: May cause respiratory irritation

H336: May cause drowsiness or dizziness

H351: Suspected of causing cancer

EUH019: May form explosive peroxides

Precautionary Statements

P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking

P261: Avoid breathing dust/fume/gas/mist/vapors/spray

P280: Wear protective gloves/protective clothing/eye protection/face protection

P337+P313: Get medical advice/attention

P403+P233: Store in a well ventilated place. Keep container tightly closed

P501: Dispose of contents/container in accordance with local regulation

SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS

Tetrahydrofuran (THF)

Methyl Ethyl Ketone (MEK)

Acetone

CAS#

109-99-9

78-93-3

67-64-1

EINECS # REACH

Pre-registration Number

203-726-8 05-2116297729-22-0000

201-159-0 05-2116297728-24-0000

200-662-2 05-2116297713-35-0000

CONCENTRATION

% by Weight

46 - 56

4 - 17

10 - 25

All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances maintained by the US EPA, or are exempt from that listing.

* Indicates this chemical is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 (40CFR372).

# indicates that this chemical is found on Proposition 65’s List of chemicals known to the State of California to cause cancer or reproductive toxicity.

SECTION 4 - FIRST AID MEASURES

Contact with eyes:

Skin contact:

Inhalation:

Ingestion:

Likely Routes of Exposure:

Flush eyes immediately with plenty of water for 15 minutes and seek medical advice immediately.

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water. If irritation develops, seek medical advice.

Remove to fresh air. If breathing is stopped, give artificial respiration. If breathing is difficult, give oxygen. Seek medical advice.

Rinse mouth with water. Give 1 or 2 glasses of water or milk to dilute. Do not induce vomiting. Seek medical advice immediately.

Inhalation, Eye and Skin Contact

Acute symptoms and effects:

Inhalation: Severe overexposure may result in nausea, dizziness, headache. Can cause drowsiness, irritation of eyes and nasal passages.

Eye Contact: Vapors slightly uncomfortable. Overexposure may result in severe eye injury with corneal or conjunctival inflammation on contact with the liquid.

Skin Contact:

Ingestion:

Liquid contact may remove natural skin oils resulting in skin irritation. Dermatitis may occur with prolonged contact.

May cause nausea, vomiting, diarrhea and mental sluggishness.

Chronic (long-term) effects: Category 2 Carcinogen

SECTION 5 - FIREFIGHTING MEASURES

Suitable Extinguishing Media:

Unsuitable Extinguishing Media:

Exposure Hazards:

Combustion Products:

Protection for Firefighters:

Dry chemical powder, carbon dioxide gas, foam, Halon, water fog.

Water spray or stream.

Inhalation and dermal contact

Oxides of carbon, hydrogen chloride and smoke

Health

Flammability

Reactivity

PPE

Self-contained breathing apparatus or full-face positive pressure airline masks.

HMIS

2

3

0

B

NFPA

2

3

0

0-Minimal

1-Slight

2-Moderate

3-Serious

4-Severe

SECTION 6 - ACCIDENTAL RELEASE MEASURES

Personal precautions: Keep away from heat, sparks and open flame.

Environmental Precautions:

Methods for Cleaning up:

Materials not to be used for clean up:

Provide sufficient ventilation, use explosion-proof exhaust ventilation equipment or wear suitable respiratory protective equipment.

Prevent contact with skin or eyes (see section 8).

Prevent product or liquids contaminated with product from entering sewers, drains, soil or open water course.

Clean up with sand or other inert absorbent material. Transfer to a closable steel vessel.

Aluminum or plastic containers

SECTION 7 - HANDLING AND STORAGE

Handling: Avoid breathing of vapor, avoid contact with eyes, skin and clothing.

Keep away from ignition sources, use only electrically grounded handling equipment and ensure adequate ventilation/fume exhaust hoods.

Do not eat, drink or smoke while handling.

Storage: Store in ventilated room or shade below 44°C (110°F) and away from direct sunlight.

Keep away from ignition sources and incompatible materials: caustics, ammonia, inorganic acids, chlorinated compounds, strong oxidizers and isocyanates.

Follow all precautionary information on container label, product bulletins and solvent cementing literature.

SECTION 8 - PRECAUTIONS TO CONTROL EXPOSURE / PERSONAL PROTECTION

EXPOSURE LIMITS: Component

Tetrahydrofuran (THF)

Methyl Ethyl Ketone (MEK)

Acetone

ACGIH TLV

50 ppm

200 ppm

500 ppm

ACGIH STEL

100 ppm

300 ppm

750 ppm

OSHA PEL

200 ppm

200 ppm

1000 ppm

OSHA STEL

N/E

N/E

N/E

OSHA

PEL-Ceiling

N/E

N/E

N/E

CAL/OSHA

PEL

200 ppm

200 ppm

500 ppm

CAL/OSHA

Ceiling

N/E

N/E

3000 ppm

CAL/OSHA STEL

250 ppm

300 ppm

750 ppm

Engineering Controls: Use local exhaust as needed.

Monitoring: Maintain breathing zone airborne concentrations below exposure limits.

Personal Protective Equipment (PPE):

Eye Protection: Avoid contact with eyes, wear splash-proof chemical goggles, face shield, safety glasses (spectacles) with brow guards and side shields, etc. as may be appropriate for the exposure.

Skin Protection: Prevent contact with the skin as much as possible. Butyl rubber gloves should be used for frequent immersion.

Use of solvent-resistant gloves or solvent-resistant barrier cream should provide adequate protection when normal adhesive application practices and procedures are used for making structural bonds.

Respiratory Protection: Prevent inhalation of the solvents. Use in a well-ventilated room. Open doors and/or windows to ensure airflow and air changes. Use local exhaust ventilation to remove airborne contaminants from employee breathing zone and to keep contaminants below levels listed above.

With normal use, the Exposure Limit Value will not usually be reached. When limits approached, use respiratory protection equipment.

Filename: W-O735LoVoc 4-15.xls Page 1 of 2 4/21/2015 10:01 AM

GHS SAFETY DATA SHEET

WELD-ON® 735™ Wet 'N Fast™ Low VOC Cement for PVC Plastic Pipe

Date Revised: APR 2015

Supersedes: NOV 2014

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

Appearance:

Odor:

pH:

Melting/Freezing Point:

Boiling Point:

Flash Point:

Specific Gravity :

Solubility:

Blue, medium syrupy liquid

Ketone

Not Applicable

-108.5°C (-163.3°F) Based on first melting component: THF

56°C (133°F) Based on first boiling component: Acetone

Partition Coefficient n-octanol/water:

Auto-ignition Temperature:

Decomposition Temperature:

VOC Content:

-20°C (-4°F) TCC based on Acetone

0.926 @23°C ( 73°F)

Solvent portion soluble in water. Resin portion separates out.

Not Available

Odor Threshold:

Boiling Range:

Evaporation Rate:

Flammability:

Flammability Limits:

Vapor Pressure:

1 ppm (Acetone)

56°C (133°F) to 80°C (176°F)

> 1.0 (BUAC = 1)

Category 2

LEL: 1.4% based on MEK

UEL: 12.8% based on Acetone

190 mm Hg @ 20°C (68°F) Acetone

321°C (610°F) based on THF

Not Applicable

Vapor Density:

Other Data: Viscosity:

When applied as directed, per SCAQMD Rule 1168, Test Method 316A,VOC content is: < 510 g/l.

>2.0 (Air = 1)

Medium bodied

SECTION 10 - STABILITY AND REACTIVITY

Stability:

Hazardous decomposition products:

Conditions to avoid:

Incompatible Materials:

Stable

None in normal use. When forced to burn, this product gives off oxides of carbon, hydrogen chloride and smoke.

Keep away from heat, sparks, open flame and other ignition sources.

Oxidizers, strong acids and bases, amines, ammonia

SECTION 11 - TOXICOLOGICAL INFORMATION

Toxicity:

Tetrahydrofuran (THF)

Methyl Ethyl Ketone (MEK)

Acetone

LD

50

Oral: 2842 mg/kg (rat)

Oral: 2737 mg/kg (rat), Dermal: 6480 mg/kg (rabbit)

Oral: 5800 mg/kg (rat)

LC

50

Inhalation 3 hrs. 21,000 mg/m

3

(rat)

Inhalation 8 hrs. 23,500 mg/m

3

(rat)

Inhalation 50,100 mg/m

3

(rat)

Target Organs

STOT SE3

STOT SE3

STOT SE3

Reproductive Effects

Not Established

Teratogenicity

Not Established

Mutagenicity

Not Established

Embryotoxicity

Not Established

Sensitization to Product

Not Established

SECTION 12 - ECOLOGICAL INFORMATION

Ecotoxicity:

Mobility:

Degradability:

Bioaccumulation:

None Known

In normal use, emission of volatile organic compounds (VOC's) to the air takes place, typically at a rate of < 510 g/l.

Not readily biodegradable

Minimal to none.

Synergistic Products

Not Established

SECTION 13 - WASTE DISPOSAL CONSIDERATIONS

Follow local and national regulations. Consult disposal expert.

SECTION 14 - TRANSPORT INFORMATION

Proper Shipping Name:

Hazard Class:

Secondary Risk:

Identification Number:

Packing Group:

Label Required:

Marine Pollutant:

Adhesives

3

None

UN 1133

PG II

Class 3 Flammable Liquid

NO

EXCEPTION for Ground Shipping

DOT Limited Quantity: Up to 5L per inner packaging, 30 kg gross weight per package.

Consumer Commodity: Depending on packaging, these quantities may qualify under DOT as "ORM-D" .

TDG INFORMATION

TDG CLASS:

SHIPPING NAME:

UN NUMBER/PACKING GROUP:

FLAMMABLE LIQUID 3

ADHESIVES

UN 1133, PG II

SECTION 15 - REGULATORY INFORMATION

Precautionary Label Information: Highly Flammable, Irritant, Carc. Cat. 2

Symbols: F, Xi

Risk Phrases: R11: Highly flammable.

R36/37: Irritating to eyes and respiratory system.

Safety Phrases: S2: Keep out of the reach of children

S9: Keep container in a well-ventilated place.

S16: Keep away from sources of ignition - No smoking.

Ingredient Listings: USA TSCA, Europe EINECS, Canada DSL, Australia

AICS, Korea ECL/TCCL, Japan MITI (ENCS)

R66: Repeated exposure may cause skin dryness or cracking

R67: Vapors may cause drowsiness and dizziness

S25: Avoid contact with eyes.

S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S33: Take precautionary measures against static discharges.

SECTION 16 - OTHER INFORMATION

Specification Information:

Department issuing data sheet:

E-mail address:

Training necessary:

Reissue date / reason for reissue:

Intended Use of Product:

IPS, Safety Health & Environmental Affairs

<[email protected]>

All ingredients are compliant with the requirements of the European

Directive on RoHS (Restriction of Hazardous Substances).

Yes, training in practices and procedures contained in product literature.

4/21/2015 / Updated GHS Standard Format

Solvent Cement for PVC Plastic Pipe

This product is intended for use by skilled individuals at their own risk. The information contained herein is based on data considered accurate based on current state of knowledge and experience. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof.

Filename: W-O735LoVoc 4-15.xls Page 2 of 2 4/21/2015 10:01 AM

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