Weld-On 10274 16 oz. ABS-PVC 794 Transition Cement in Green Specification

Weld-On 10274 16 oz. ABS-PVC 794 Transition Cement in Green Specification
GHS SAFETY DATA SHEET
Date Revised: NOV 2014
WELD-ON® 794™ Low VOC PVC to ABS Plastic Pipe Transition Cement
Supersedes:
OCT 2013
SECTION I - PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME:
WELD-ON® 794™ Low VOC PVC to ABS Plastic Pipe Transition Cement
PRODUCT USE:
Low VOC Transition Cement for PVC to ABS Transition Joint
SUPPLER:
MANUFACTURER:
EMERGENCY: Transportation: CHEMTEL Tel. 800.255-3924, +1 813-248-0585 (International)
IPS Corporation
17109 South Main Street, Gardena, CA 90248-3127
P.O. Box 379, Gardena, CA 90247-0379
Tel. 1-310-898-3300
Medical: CHEMTEL Tel. 800.255-3924, +1 813-248-0585 (International)
SECTION 2 - HAZARDS IDENTIFICATION
GHS CLASSIFICATION:
Acute Toxicity:
Skin Irritation:
Skin Sensitization:
Eye:
Health
Category 4
Category 3
NO
Category 2
Acute Toxicity:
Chronic Toxicity:
GHS LABEL:
Environmental
None Known
None Known
Physical
Flammable Liquid
Signal Word:
WHMIS CLASSIFICATION:
Danger
Category 2
CLASS B, DIVISION 2
CLASS D, DIVISION 1B
Hazard Statements
Precautionary Statements
H225: Highly flammable liquid and vapor
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking
H319: Causes serious eye irritation
P261: Avoid breathing dust/fume/gas/mist/vapors/spray
H332: Harmful if inhaled
P280: Wear protective gloves/protective clothing/eye protection/face protection
H335: May cause respiratory irritation
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
H336: May cause drowsiness or dizziness
P403+P233: Store in a well ventilated place. Keep container tightly closed
H351: Suspected of causing cancer
P501: Dispose of contents/container in accordance with local regulation
EUH019: May form explosive peroxides
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
CAS#
Tetrahydrofuran (THF)
Methyl Ethyl Ketone (MEK)
Cyclohexanone
EINECS #
109-99-9
78-93-3
108-94-1
203-726-8
201-159-0
203-631-1
REACH
Pre-registration Number
CONCENTRATION
% by Weight
05-2116297729-22-0000
05-2116297728-24-0000
05-2116297718-25-0000
22 - 49
6 - 24
4 - 25
All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances maintained by the US EPA, or are exempt from that listing.
* Indicates this chemical is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 (40CFR372).
# indicates that this chemical is found on Proposition 65’s List of chemicals known to the State of California to cause cancer or reproductive toxicity.
SECTION 4 - FIRST AID MEASURES
Contact with eyes:
Skin contact:
Inhalation:
Ingestion:
Flush eyes immediately with plenty of water for 15 minutes and seek medical advice immediately.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water. If irritation develops, seek medical advice.
Remove to fresh air. If breathing is stopped, give artificial respiration. If breathing is difficult, give oxygen. Seek medical advice.
Rinse mouth with water. Give 1 or 2 glasses of water or milk to dilute. Do not induce vomiting. Seek medical advice immediately.
SECTION 5 - FIREFIGHTING MEASURES
Suitable Extinguishing Media:
Unsuitable Extinguishing Media:
Exposure Hazards:
Combustion Products:
Protection for Firefighters:
Dry chemical powder, carbon dioxide gas, foam, Halon, water fog.
Water spray or stream.
Inhalation and dermal contact
Oxides of carbon, hydrogen chloride and smoke
Health
Flammability
Reactivity
PPE
Self-contained breathing apparatus or full-face positive pressure airline masks.
HMIS
2
3
0
B
NFPA
2
3
0
0-Minimal
1-Slight
2-Moderate
3-Serious
4-Severe
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Personal precautions:
Keep away from heat, sparks and open flame.
Provide sufficient ventilation, use explosion-proof exhaust ventilation equipment or wear suitable respiratory protective equipment.
Prevent contact with skin or eyes (see section 8).
Environmental Precautions:
Prevent product or liquids contaminated with product from entering sewers, drains, soil or open water course.
Methods for Cleaning up:
Clean up with sand or other inert absorbent material. Transfer to a closable steel vessel.
Materials not to be used for clean up:
Aluminum or plastic containers
SECTION 7 - HANDLING AND STORAGE
Handling:
Storage:
Avoid breathing of vapor, avoid contact with eyes, skin and clothing.
Keep away from ignition sources, use only electrically grounded handling equipment and ensure adequate ventilation/fume exhaust hoods.
Do not eat, drink or smoke while handling.
Store in ventilated room or shade below 44°C (110°F) and away from direct sunlight.
Keep away from ignition sources and incompatible materials: caustics, ammonia, inorganic acids, chlorinated compounds, strong oxidizers and isocyanates.
Follow all precautionary information on container label, product bulletins and solvent cementing literature.
SECTION 8 - PRECAUTIONS TO CONTROL EXPOSURE / PERSONAL PROTECTION
EXPOSURE LIMITS:
Component
Tetrahydrofuran (THF)
Methyl Ethyl Ketone (MEK)
Cyclohexanone
ACGIH TLV
ACGIH STEL
50 ppm
200 ppm
20 ppm
100 ppm
300 ppm
50 ppm
OSHA PEL
200 ppm
200 ppm
50 ppm
OSHA STEL:
OSHA
PEL-Ceiling
CAL/OSHA PEL
CAL/OSHA
Ceiling
CAL/OSHA STEL
N/E
N/E
N/E
N/E
N/E
N/E
200 ppm
200 ppm
25 ppm
N/E
N/E
N/E
250 ppm
300 ppm
N/E
Engineering Controls:
Use local exhaust as needed.
Monitoring:
Maintain breathing zone airborne concentrations below exposure limits.
Personal Protective Equipment (PPE):
Eye Protection:
Avoid contact with eyes, wear splash-proof chemical goggles, face shield, safety glasses (spectacles) with brow guards and side shields,
etc. as may be appropriate for the exposure.
Skin Protection:
Prevent contact with the skin as much as possible. Butyl rubber gloves should be used for frequent immersion.
Use of solvent-resistant gloves or solvent-resistant barrier cream should provide adequate protection when normal adhesive application
practices and procedures are used for making structural bonds.
Respiratory Protection: Prevent inhalation of the solvents. Use in a well-ventilated room. Open doors and/or windows to ensure airflow and air changes. Use local
exhaust ventilation to remove airborne contaminants from employee breathing zone and to keep contaminants below levels listed above.
With normal use, the Exposure Limit Value will not usually be reached. When limits approached, use respiratory protection equipment.
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GHS SAFETY DATA SHEET
Date Revised: NOV 2014
WELD-ON® 794™ Low VOC PVC to ABS Plastic Pipe Transition Cement
Supersedes:
OCT 2013
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Green, medium syrupy liquid
Odor:
Ketone
Odor Threshold:
pH:
Not Applicable
Melting/Freezing Point:
-108.5°C (-163.3°F) Based on first melting component: THF
Boiling Range:
Boiling Point:
66°C (151°F) Based on first boiling component: THF
Evaporation Rate:
Flash Point:
-20°C (-4°F) TCC based on THF
Flammability:
Specific Gravity:
0.927 @23°C ( 73°F)
Flammability Limits:
Solubility:
Solvent portion soluble in water. Resin portion separates out.
Partition Coefficient n-octanol/water:
Not Available
Vapor Pressure:
Auto-ignition Temperature:
321°C (610°F) based on THF
Vapor Density:
Decomposition Temperature:
Not Applicable
Other Data: Viscosity:
When applied as directed, per SCAQMD Rule 1168, Test Method 316A,VOC content is: < 510 g/l.
VOC Content:
0.88 ppm (Cyclohexanone)
66°C (151°F) to 156°C (313°F)
> 1.0 (BUAC = 1)
Category 2
LEL: 1.1% based on Cyclohexanone
UEL: 11.8% based on THF
129 mm Hg @ 20°C (68°F)based on THF
>2 (Air = 1)
Medium bodied
SECTION 10 - STABILITY AND REACTIVITY
Stability:
Hazardous decomposition products:
Conditions to avoid:
Incompatible Materials:
Stable
None in normal use. When forced to burn, this product gives off oxides of carbon, hydrogen chloride and smoke.
Keep away from heat, sparks, open flame and other ignition sources.
Oxidizers, strong acids and bases, amines, ammonia
SECTION 11 - TOXICOLOGICAL INFORMATION
Likely Routes of Exposure:
Inhalation, Eye and Skin Contact
Acute symptoms and effects:
Inhalation:
Severe overexposure may result in nausea, dizziness, headache. Can cause drowsiness, irritation of eyes and nasal passages.
Eye Contact:
Vapors slightly uncomfortable. Overexposure may result in severe eye injury with corneal or conjunctival inflammation on contact with the liquid.
Skin Contact:
Liquid contact may remove natural skin oils resulting in skin irritation. Dermatitis may occur with prolonged contact.
Ingestion:
May cause nausea, vomiting, diarrhea and mental sluggishness.
Chronic (long-term) effects:
Category 2 Carcinogen
LD50
LC50
Toxicity:
Target Organs
Inhalation 3 hrs. 21,000 mg/m3 (rat)
Tetrahydrofuran (THF)
Oral: 2842 mg/kg (rat)
STOT SE3
Inhalation 8 hrs. 23,500 mg/m3 (rat)
Methyl Ethyl Ketone (MEK)
Oral: 2737 mg/kg (rat), Dermal: 6480 mg/kg (rabbit)
STOT SE3
Cyclohexanone
Oral: 1535 mg/kg (rat), Dermal: 948 mg/kg (rabbit)
Inhalation 4 hrs. 8,000 PPM (rat)
Reproductive Effects
Not Established
Teratogenicity
Not Established
Mutagenicity
Not Established
Embryotoxicity
Not Established
Sensitization to Product
Not Established
Synergistic Products
Not Established
SECTION 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Mobility:
Degradability:
Bioaccumulation:
None Known
In normal use, emission of volatile organic compounds (VOC's) to the air takes place, typically at a rate of < 510 g/l.
Not readily biodegradable
Minimal to none
SECTION 13 - WASTE DISPOSAL CONSIDERATIONS
Follow local and national regulations. Consult disposal expert.
SECTION 14 - TRANSPORT INFORMATION
Proper Shipping Name:
Hazard Class:
Secondary Risk:
Identification Number:
Packing Group:
Label Required:
Marine Pollutant:
Adhesives
3
None
UN 1133
PG II
Class 3 Flammable Liquid
NO
EXCEPTION for Ground Shipping
DOT Limited Quantity: Up to 5L per inner packaging, 30 kg gross weight per package.
Consumer Commodity: Depending on packaging, these quantities may qualify under DOT as "ORM-D" .
TDG INFORMATION
TDG CLASS:
FLAMMABLE LIQUID 3
SHIPPING NAME:
ADHESIVES
UN NUMBER/PACKING GROUP:
UN 1133, PG II
SECTION 15 - REGULATORY INFORMATION
Precautionary Label Information: Highly Flammable, Irritant, Carc. Cat. 2
Symbols:
F, Xi
Risk Phrases:
R11: Highly flammable.
R20: Harmful by inhalation.
R36/37: Irritating to eyes and respiratory system.
Safety Phrases:
S9: Keep container in a well-ventilated place.
S16: Keep away from sources of ignition - No smoking.
S25: Avoid contact with eyes.
Ingredient Listings: USA TSCA, Europe EINECS, Canada DSL, Australia
AICS, Korea ECL/TCCL, Japan MITI (ENCS)
R66: Repeated exposure may cause skin dryness or cracking
R67: Vapors may cause drowsiness and dizziness
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S33: Take precautionary measures against static discharges.
S46: If swallowed, seek medical advise immediately and show this container or label.
SECTION 16 - OTHER INFORMATION
Specification Information:
Department issuing data sheet:
E-mail address:
IPS, Safety Health & Environmental Affairs
<[email protected]>
Training necessary:
Reissue date / reason for reissue:
Intended Use of Product:
Yes, training in practices and procedures contained in product literature.
11/20/2014 / Updated GHS Standard Format
Transition Cement for PVC to ABS Transition Joint
All ingredients are compliant with the requirements of the European
Directive on RoHS (Restriction of Hazardous Substances).
This product is intended for use by skilled individuals at their own risk. The information contained herein is based on data considered accurate based on current state of
knowledge and experience. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof.
Filename: W-O794LoVoc 11-14.xls
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11/20/2014 9:41 AM
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