ANGEWANDTE CHEMIE 2000

ANGEWANDTE
CHEMIE
2000
Volume 39, Issue 17, 2000
2963
Cover Picture
Philip Kraft, Jerzy A. Bajgrowicz, Caroline Denis, Georg Fráter
Review
2980- Odds and Trends: Recent Developments in the Chemistry of
3010 Odorants
Philip Kraft, Jerzy A. Bajgrowicz, Caroline Denis, Georg Fráter
3012- Olefin Metathesis and Beyond
3043 Alois Fürstner
Essay
3045- Kekulé Escapes, Popper Notwithstanding
3047 Jerome A. Berson
Highlight
3049- New Strategies for the Development of an Asymmetric Version of
3052 the Baylis-Hillman Reaction
Peter Langer
3052- Nanoporous Structures by Design
3054 Michael J. Zaworotko
Communication
3055- Supramolecular Nanocircles Consisting of Streptavidin and DNA
3059 Christof M. Niemeyer, Michael Adler, Song Gao, Lifeng Chi
3059- Dynamic Observations of the Hydrolysis of a DPPC Monolayer at
3062 the Air/Water Interface Catalyzed by Phospholipase A2
Junbai Li, Zhijian Chen, Xiaoli Wang, Gerald Brezesinski, Helmuth Möhwald
3063- Uranium Hexakisamido Complexes
3066 Karsten Meyer, Daniel J. Mindiola, Thomas A. Baker, William M. Davis,
Christopher C. Cummins
3066- Base-Induced Disproportionation of Elemental Gold
3067 Anja-Verena Mudring, Martin Jansen
3067Se=C Interactions in Aldols of Chiral N-Acyl
3070 Unusual C-H
Selones Detected by Gradient-Selected H- Se HMQC NMR
Selones Detected by Gradient-Selected 1H-77Se HMQC NMR
Spectroscopy and X-ray Crystallography
Ryszard Michalczyk, Jürgen G. Schmidt, Eddie Moody, Zizhong Li, Ruilian
Wu, R. Bruce Dunlap, Jerome D. Odom, Louis A. Pete Silks III
3070- A Highly Active Catalyst System for Intermolecular Hydroacylation
3072 Chul-Ho Jun, Dae-Yon Lee, Hyuk Lee, Jun-Bae Hong
3072- Asymmetric Synthesis of a Chiral Secondary Grignard Reagent
3074 Reinhard W. Hoffmann, Bettina Hölzer, Oliver Knopff, Klaus Harms
3074- Unusually Stable Vinyl Cations
3077 Thomas Müller, Rita Meyer, Dirk Lennartz, Hans-Ullrich Siehl
3077- [(Cp*RuCl)2( -Cl)2]: Bond-Stretch or Spin-State Isomerism?
3079 John E. McGrady
3080- Silylated Cyclohexadienes: New Alternatives to Tributyltin Hydride
3082 in Free Radical Chemistry
Armido Studer, Stephan Amrein
3082- [{Au[ -N(SiMe3)2]}4]: The First Base-Free Gold Amide
3084 Scott D. Bunge, Oliver Just, William S. Rees, Jr.
3084- Umpolung of P-H Bonds
3086 Dietrich Gudat, Asadollah Haghverdi, Martin Nieger
3086- Stereoselective Synthesis and Palladium-Catalyzed
3090 Transformations of 2-Alkylidene- 5-vinyltetrahydrofurans
Peter Langer, Edith Holtz
3091- An Unusual Open-Framework Cobalt(ii) Phosphate with a Channel
3093 Structure That Exhibits Structural and Magnetic Transitions
Amitava Choudhury, S. Neeraj, Srinivasan Natarajan, C. N. R. Rao
3094- Formation of Extended Tapes of Cyclic Water Hexamers in an
3096 Organic Molecular Crystal Host
Radu Custelcean, Cerasela Afloroaei, Mircea Vlassa, Mihai Polverejan
3096- The First Solid-Phase Synthesis of a Peptide-Tethered Platinum(ii)
3099 Complex
Marc S. Robillard, A. Rob P. M. Valentijn, Nico J. Meeuwenoord, Gijs A. van
der Marel, Jacques H. van Boom, Jan Reedijk
3099- The First Structurally Characterized Aluminum Compounds with
3101 Terminal Acetylide Groups
Wenjun Zheng, Nadia C. Mösch-Zanetti, Herbert W. Roesky, Manuel Hewitt,
Fanica Cimpoesu, Thomas R. Schneider, Andreas Stasch, Jörg Prust
3101- Ruthenium-Catalyzed Enyne Metathesis of Acetylenic Boronates: A
3104
Concise Route for the Construction of Cyclic 1,3-Dienylboronic
Esters
Johanne Renaud, Claus-Dieter Graf, Lukas Oberer I
3104- A Light-Modulated Sequence-Specific DNA-Binding Peptide
3107 Ana M. Caamaño, M. Eugenio Vázquez, José Martínez-Costas, Luis Castedo,
José L. Mascareñas
3107- TEM Studies of Platinum Nanowires Fabricated in Mesoporous
3110 Silica MCM-41
Zheng Liu, Yasuhiro Sakamoto, Tetsu Ohsuna, Kenji Hiraga, Osamu Terasaki,
Chang Hyun Ko, Hyun June Shin, Ryong Ryoo
3110- Network Polysilanes: Synthesis, Electrical Conductivity, Charge3114 Transfer Interaction, and Photoconductivity
Takanobu Kobayashi, Hirokazu Shimura, Shin Mitani, Saeko Mashimo, Aiko
Amano, Toshihisa Takano, Minoru Abe, Hamao Watanabe, Masashi Kijima,
Hideki Shirakawa, Hiroyuki Yamaguchi
3114- Synthesis, Structure, and Magnetism of a Novel Alkoxide Bridged
3117 Nonacopper(ii) (Cu9O12) [3×3] Square Grid Generated by a Strict
Self-Assembly Process
Liang Zhao, Zhiqiang Xu, Laurence K. Thompson, Sarah L. Heath, David O.
Miller, Masaaki Ohba
3117- Highly Efficient Degradation of Thiophosphate Pesticides
3119 Catalyzed by Platinum and Palladium Aryl Oxime Metallacycles
Gregory M. Kazankov, Victoria S. Sergeeva, Elena N. Efremenko, Larissa
Alexandrova, Sergey D. Varfolomeev, Alexander D. Ryabov
3120- [{( 5-C5Me5)Fe}2( -H)4]: A Novel Dinuclear Iron Tetrahydrido
3122 Complex
Yasuhiro Ohki, Hiroharu Suzuki
3122- Asymmetric Alkylation of Nitroalkanes
3124 Barry M. Trost, Jean-Philippe Surivet
3124- Enantiomeric Self-Recognition: Cation-Templated Formation of
3127 Homochiral Isoguanosine Pentamers
Xiaodong Shi, James C. Fettinger, Mangmang Cai, Jeffery T. Davis
3127- Synthesis and Characterization of Iron Silasesquioxane
3130 Phosphane Complexes
Fuchen Liu, Kevin D. John, Brian L. Scott, R. Tom Baker, Kevin C. Ott,
William Tumas
3130- A Graphite-Like Complex with Large Cavities Constructed with the
3132 Complex Ligand [NiII(bpca)2]
Asako Kamiyama, Tomoko Noguchi, Takashi Kajiwara, Tasuku Ito
I
3133- A Parallel Library of all Seven A2+B2+C2 Th Regioisomeric
3137 Hexakisadducts of Fullerene C60: Inspiration from Werner's
Octahedral Stereoisomerism
Wenyuan Qian, Yves Rubin
3137- A Chip-Based Biosensor for the Functional Analysis of Single Ion
3140 Channels
Christian Schmidt, Michael Mayer, Horst Vogel
3140- A Room-Temperature Discotic Nematic Liquid Crystal
3142 Sandeep Kumar, Sanjay Kumar Varshney
Volume 39, Issue 18, 2000
3151
Cover Picture
Ivan S. Neretin, Konstantin A. Lyssenko, Mikhail Yu. Antipin, Yuri L.
Slovokhotov, Olga V. Boltalina, Pavel A. Troshin, Andrei Yu. Lukonin, Lev.
N. Sidorov, Roger Taylor
Review
3168- Multicomponent Reactions with Isocyanides
3210 Alexander Dömling, Ivar Ugi
3212- Force Spectroscopy of Molecular Systems - Single Molecule
3237 Spectroscopy of Polymers and Biomolecules
Andreas Janshoff, Marcus Neitzert, York Oberdörfer, Harald Fuchs
Highlight
3239- Does CH5+ Have (a) Structure? A Tough Test for Experiment and
3241 Theory
Peter R. Schreiner
3241- Organometallic Transformations Demonstrate That Fluorocarbons
3244 Are Reactive Molecules
Thomas G. Richmond
Communication
3245- Calcium-Dependent Carbohydrate-Carbohydrate Recognition
3249 between LewisX Blood Group Antigens
Armin Geyer, Christian Gege, Richard R. Schmidt
3249- Solid-Phase Synthesis of Doubly Labeled Peptide Nucleic Acids as
3252 Probes for the Real-Time Detection of Hybridization
Oliver Seitz
3252- Redox Switches with Chiroptical Signal Expression Based on
3255 Binaphthyl Boron Dipyrromethene Conjugates
Gerhard Beer, Christoph Niederalt, Stefan Grimme, Jörg Daub
3255- Allosteric Regulation of Artificial Phosphoesterase Activity by
3258 Metal Ions
Igor O. Fritsky, Reina Ott, Roland Krämer
3258- Hexacyclinic acid, a Polyketide from Streptomyces with a Novel
3261 Carbon Skeleton
Published Online: 13 Sep 2000
3261- The Dimerization of Chiral Allenes: Pairs of Enantiomers and Pairs
3263 of Homomers Furnish Different Diastereomers
Manfred Christl, Stefan Groetsch, Kurt Günther
3263- Five-Coordinate Carbides in Ti-Al-C Complexes
3266 James E. Kickham, Frédéric Guérin, Jeffrey C. Stewart, Douglas W. Stephan
3266- The First Example of an Equilibrium between a Carbene and an
3269 Isomeric Carbyne Transition Metal Complex
Pablo González-Herrero, Birgit Weberndörfer, Kerstin Ilg, Justin Wolf, Helmut
Werner
3269- Model Studies of Phytochrome Photochromism: Protein-Mediated
3271 Photoisomerization of a Linear Tetrapyrrole in the Absence of
Covalent Bonding
Ingo Lindner, Silvia E. Braslavsky, Kurt Schaffner, Wolfgang Gärtner
3273- C60F18, a Flattened Fullerene: Alias a Hexa-Substituted Benzene
3276 Ivan S. Neretin, Konstantin A. Lyssenko, Mikhail Yu. Antipin, Yuri L.
Slovokhotov, Olga V. Boltalina, Pavel A. Troshin, Andrei Yu. Lukonin, Lev.
N. Sidorov, Roger Taylor
3276- The First Microporous Framework Cerium Silicate
3279 João Rocha, Paula Ferreira, Luís D. Carlos, Artur Ferreira
3279- Is Hydrogen Tunneling Involved in AcylCoA Desaturase
3281 Reactions? The Case of a 9 Desaturase That Transforms (E)-11Tetradecenoic Acid into (Z,E)-9,11-Tetradecadienoic Acid
José Luís Abad, Francisco Camps, Gemma Fabriàs
3281- Molecular Recognition with Introverted Functionality
3283 Adam R. Renslo, Julius Rebek, Jr.
3284- Towards Synthetic Molecular Muscles: Contraction and Stretching
3287 of a Linear Rotaxane Dimer
M. Consuelo Jiménez, Christiane Dietrich-Buchecker, Jean-Pierre Sauvage
3287- Conformation Control of Oligosilanes Based on Configurationally
3290 Constrained Bicyclic Disilane Units
Kohei Tamao, Hayato Tsuji, Masayoshi Terada, Masahiro Asahara, Shigehiro
Yamaguchi, Akio Toshimitsu
3290- Asymmetric Synthesis of Baylis-Hillman-Type Allyl Alcohols via a
3292 Chiral Acetylenic Ester Titanium Alkoxide Complex
Daisuke Suzuki, Hirokazu Urabe, Fumie Sato
3293- Analysis of Solid-Phase Reactions: Product Identification and
3296 Quantification by Use of UV-Chromophore-Containing Dual-Linker
Analytical Constructs
Geoff M. Williams, Robin A. E. Carr, Miles S. Congreve, Corinne Kay,
Stephen C. McKeown, Peter J. Murray, Jan J. Scicinski, Stephen P. Watson
3296- Redox-Switched Control of Binding Strength in Hydrogen-Bonded
3299 Metallocene Complexes
Jonathan D. Carr, Simon J. Coles, Michael B. Hursthouse, Mark E. Light,
James H. R. Tucker, Joanna Westwood
3299- Toward Crystalline Covalent Solids: Crystal-to-Crystal Dihydrogen
3302 to Covalent Bonding Transformation in NaBH4 THEC
Radu Custelcean, Mircea Vlassa, James E. Jackson
3302- NMR and Theoretical Study of Acid Sites Formed by Adsorption of
3304 SO3 onto Oxide Surfaces
Jinhua Zhang, John B. Nicholas, James F. Haw
3304- Syntheses, Structures, and Magnetic Properties of Two
3307 Gadolinium(iii)-Copper(ii) Coordination Polymers by a Hydrothermal
Reaction
Yucang Liang, Rong Cao, Weiping Su, Maochun Hong, Wenjian Zhang
3307- Experimental Observation of Pentaatomic Tetracoordinate Planar
3310 Si- and Ge-Containing Molecules: MAl4- and MAl4
Alexander I. Boldyrev, Xi Li, Lai-Sheng Wang
3310- Control of Architecture in Block-Copolymer Vesicles
3312 Hongwei Shen, Adi Eisenberg
3312- Hydrogen-Bonded Hexamolybdenum Clusters: Formation of
3315 Inorganic-Organic Networks
Nicholas Prokopuk, Charles S. Weinert, David P. Siska, Charlotte L. Stern,
Duward F. Shriver
3315- A Combinatorial Approach to Polyketide-Type Libraries by Iterative
3319 Asymmetric Aldol Reactions Performed on Solid Support
Ian Paterson, Monica Donghi, Kai Gerlach
3319- Synthesis, Structure, and Reactivity of a 1 4,3 2-Diphosphaallene
3321 Tsuyoshi Kato, Heinz Gornitzka, Antoine Baceiredo, Guy Bertrand
3321- 4,5-Bis(diphenylphosphinoyl)-1,2,3-triazole: A Powerful New Ligand
3324 That Uses Two Different Modes of Chelation
Arnold L. Rheingold, Louise M. Liable-Sands, Swiatoslaw Trofimenko
Volume 39, Issue 19, 2000
3331
Cover Picture
Jens Krömer, Idoia Rios-Carreras, Gerda Fuhrmann, Christiane Musch, Markus
Wunderlin, Tony Debaerdemaeker, Elena Mena-Osteritz, Peter Bäuerle
Review
3348- Artificial Molecular Machines
3391 Vincenzo Balzani, Alberto Credi, Françisco M. Raymo, J. Fraser Stoddart
3392- The Chemistry of Form
3406 Stephen Mann
Highlight
3407- Condensative Chain Polymerization - A Way Towards Living
3409 Polycondensation?
Brigitte Voit
3409- Isopenicillin N Synthase: An Enzyme at Work
3411 Wolfdieter A. Schenk
Communication
3413- A New Type of Supramolecular Compound: Molybdenum-Oxide3417 Based Composites Consisting of Magnetic Nanocapsules with
Encapsulated Keggin-Ion Electron Reservoirs Cross-Linked to a
Two-Dimensional Network
Achim Müller, Samar K. Das, Paul Kögerler, Hartmut Bögge, Marc
Schmidtmann, Alfred X. Trautwein, Volker Schünemann, Erich Krickemeyer,
Wilhelm Preetz
3417- Linear Coupling of Three CO Ligands of Chromium Hexacarbonyl
3419 Leading to Functionalized Butenolides via Fischer Carbene
Complexes
Henri Rudler, Andrée Parlier, Victor Certal, Jacqueline Vaissermann
3419- Spectroscopy of the Formation of Microporous Transition Metal Ion
3422 Containing Aluminophosphates under Hydrothermal Conditions
Bert M. Weckhuysen, David Baetens, Robert A. Schoonheydt
3422- First Catalytic Aldol-Transfer Reaction via Aluminum Enolates: A
3425 New Way To Generate Aldol Adducts of Aldehydes from Aldol
Adducts of Ketones
Ilkka Simpura, Vesa Nevalainen
3425- Applications of a Nonlinear Organic Reaction of Carbamates To
3428
Proliferate Aliphatic Amines
Koji Arimitsu, Mana Miyamoto, Kunihiro Ichimura
3428- Probing the Conformation of Flexible Catalysts in Solution
3430 Jaume Balsells, Juan M. Betancort, Patrick J. Walsh
3430- A Three-Step Synthesis of Halomon
3432 Takayuki Sotokawa, Takeshi Noda, Sun Pi, Masahiro Hirama
3432- Synthesis of a Triazatriangulenium Salt
3434 Bo W. Laursen, Frederik C. Krebs
3435- Octahedral Grignard Reagents Can Be Chiral at Magnesium
3437 Marcus Vestergren, Björn Gustafsson, Öjvind Davidsson, Mikael Håkansson
3438- Design and Synthesis of Intramolecular Resonance-Energy
3440 Transfer Probes for Use in Ratiometric Measurements in Aqueous
Solution
Yasutomo Kawanishi, Kazuya Kikuchi, Hideo Takakusa, Shin Mizukami,
Yasuteru Urano, Tsunehiko Higuchi, Tetsuo Nagano
3440- The Catalytic Alkylation of Aromatic Imines by Wilkinson's
3442 Complex: The Domino Reaction of Hydroacylation and orthoAlkylation
Chul-Ho Jun, Jun-Bae Hong, Yeon-Hee Kim, Kwan-Yong Chung
3442- Microreactors for Dynamic, High Throughput Screening of
3445 Fluid/Liquid Molecular Catalysis
Claude de Bellefon, Nathalie Tanchoux, Sylvain Caravieilhes, Pierre
Grenouillet, Volker Hessel
3445- Macromolecular-Multisite Catalysts Obtained by Grafting
3447 Diaminoaryl Palladium(ii) Complexes onto a HyperbranchedPolytriallylsilane Support
Christian Schlenk, Arjan W. Kleij, Holger Frey, Gerard van Koten
3447- Effective Gelation of Water Using a Series of Bis-urea Dicarboxylic
3450 Acids
Lara A. Estroff, Andrew D. Hamilton
3451- Ruthenium-Based Four-Coordinate Olefin Metathesis Catalysts
3453 Melanie S. Sanford, Lawrence M. Henling, Michael W. Day, Robert H. Grubbs
3453- Calix[6]arene as a Wheel for Rotaxane Synthesis
3456 Arturo Arduini, Riccardo Ferdani, Andrea Pochini, Andrea Secchi, Franco
Ugozzoli
3456- Insulated Molecular Wires: Synthesis of Conjugated Polyrotaxanes
3460 by Suzuki Coupling in Water
Peter N. Taylor, Michael J. O'Connell, Luke A. McNeill, Michael J. Hall, Robin
T. Aplin, Harry L. Anderson
3460- [{Ti( 5-C5Me5)( -NH)}3( 3-N)]: An Efficient Entry to Single and
3463 Double Cube-Type Nitrido Complexes
Angel Abarca, Avelino Martín, Miguel Mena, Carlos Yélamos
3463- Novel Mode of C-C Bond Cleavage of Norbornadiene on a Dinuclear
3465 Ruthenium Complex
Yasuhiro Ohki, Hiroharu Suzuki
3465- Asymmetric, Catalytic Phenyl Transfer to Aldehydes:
3467 Enantioselective Synthesis of Diarylmethanols
Carsten Bolm, Nina Hermanns, Jens P. Hildebrand, Kilian Muñiz
3467- A Synthetic Azinomycin Analogue with Demonstrated DNA Cross3470 Linking Activity: Insights into the Mechanism of Action of this
Class of Antitumor Agent
John A. Hartley, Ali Hazrati, Lloyd R. Kelland, Ruzwana Khanim, Michael
Shipman, Franck Suzenet, Louise F. Walker
3470- Fascinating Alkali Halide Structures of Different Dimensionalities
3473 Incorporated in Host Lattices
R. Vaidhyanathan, S. Neeraj, P.A. Prasad, Srinivasan Natarajan, C.N.R. Rao
3473- Model Studies towards Diazonamide A: Synthesis of the
3478 Heterocyclic Core
K. C. Nicolaou, Scott A. Snyder, Klaus B. Simonsen, Alexandros E. Koumbis
3478- Triplet Di(9-anthryl)carbene Undergoes Trimerization
3480 Yasutake Takahashi, Masaaki Tomura, Ken-ichi Yoshida, Shigeru Murata,
Hideo Tomioka
3481- Synthesis of the First Fully -Conjugated Macrocyclic
3486 Oligothiophenes: Cyclo[n]thiophenes with Tunable Cavities in the
Nanometer Regime
Jens Krömer, Idoia Rios-Carreras, Gerda Fuhrmann, Christiane Musch, Markus
Wunderlin, Tony Debaerdemaeker, Elena Mena-Osteritz, Peter Bäuerle
3486- Investigating the Surface Morphology of Triacontyl Phases with
3489 Spin-Diffusion Solid-State NMR Spectroscopy
Martin Raitza, Jürgen Wegmann, Stefan Bachmann, Klaus Albert
3490- The Influence of Mismatches on Long-Distance Charge Transport
3491 through DNA
Bernd Giese, Stefan Wessely
3492- A Rectangular Zinc Cluster and a Rectangular Nickel Cluster That
3494 Exhibits Ferromagnetic Coupling
Rolf W. Saalfrank, Stefan Trummer, Uwe Reimann, Mubarik M. Chowdhry,
Frank Hampel, Oliver Waldmann
3494- Diastereoselective and Enantioselective Palladium-Catalyzed
3497 Allylic Substitution with Nonstabilized Ketone Enolates
Manfred Braun, Frank Laicher, Thorsten Meier
3497- Hydrogen-Bonded Analogues of Cavitands
3500 Alexander Shivanyuk, Thomas P. Spaniol, Kari Rissanen, Erkki Kolehmainen,
Volker Böhmer
3500- Synthesis of the Square-Planar Gallium Species K2[Ga4(C6H3-2,63503 Trip2)2] (Trip=C6H2-2,4,6-iPr3): The Role of Aryl-Alkali Metal Ion
Interactions in the Structure of Gallium Clusters
Brendan Twamley, Philip P. Power
3503- Light-Driven Microfabrication: Assembly of Multicomponent, Three3506 Dimensional Structures by Using Optical Tweezers
R. Erik Holmlin, Michele Schiavoni, Clifford Y. Chen, Stephen P. Smith, Mara
G. Prentiss, George M. Whitesides
Volume 39, Issue 20, 2000
3515
Cover Picture
Matthias Driess, Christian Monsé, Klaus Merz, Christoph van Wüllen
Review
3532- Asymmetric Activation
3556 Koichi Mikami, Masahiro Terada, Toshinobu Korenaga, Yousuke Matsumoto,
Makoto Ueki, Rémy Angelaud
3558- Catalytic Asymmetric Hetero-Diels-Alder Reactions of Carbonyl
3588 Compounds and Imines
Karl Anker Jørgensen
Highlight
3589- Hot Stones or Cold Soup? New Investigations on the Endogenous
3590 Origin of Organic Compounds on Earth
Kay Severin
3590- New and Selective Transition Metal Catalyzed Reactions of Allenes
3593 A. Stephen K. Hashmi L
Communication
3595- Fast, Convenient, and Efficient Molybdenum-Catalyzed Asymmetric
3598 Allylic Alkylation under Noninert Conditions: An Example of
Microwave-Promoted Fast Chemistry
Nils-Fredrik K. Kaiser, Ulf Bremberg, Mats Larhed, Christina Moberg, Anders
Hallberg
3598- A Novel Borosilicate Cage Compound with an Incomplete B4Si4
3601 Cube Structure: [(tBuSi)4(CH2=CHC6H4B)4O10]
Lorraine A. Neville, Trevor R. Spalding, George Ferguson
3601- Hydrogen Bonding Interactions in Amorphous Salicyl Salicylate
3604 Bryan Greener, Stephen J. Archibald, Michael Hodkinson
3604- Cooperative Asymmetric Catalysis with Dendrimeric [Co(salen)]
3607 Complexes
Rolf Breinbauer, Eric N. Jacobsen
3607- Structural Characterization of a Cyclohexameric meta3610 Phenyleneethynylene Made by Alkyne Metathesis with In Situ
Catalysts
Ping-Hua Ge, Wei Fu, Wolfgang A. Herrmann, Eberhardt Herdtweck, Charles
Campana, Richard D. Adams, Uwe H. F. Bunz
3610- Diisobutylaluminum-Promoted Regioselective De-O-benzylation of
3612 Perbenzylated Cyclodextrins: A Powerful New Strategy for the
Preparation of Selectively Modified Cyclodextrins
Alan J. Pearce, Pierre Sinaÿ
3613- Experimental Charge Densities of Semiconducting Cage Structures
3616 Containing Alkaline Earth Guest Atoms
Anders Bentien, Anders E. C. Palmqvist, J. Daniel Bryan, Susan Latturner,
Galen D. Stucky, Lars Furenlid, Bo B. Iversen
3616- Self-Assembly of Pentameric Porphyrin Light-Harvesting Antennae
3619 Complexes
Richard A. Haycock, Arkady Yartsev, Ulrike Michelsen, Villy Sundström,
Christopher A. Hunter
3620- A Refined Model for [Fe3S4]0 Clusters in Proteins
3622 Detlef Bentrop, Ivano Bertini, Marco Borsari, Grazia Cosenza, Claudio
Luchinat, Yohei Niikura
3622- The Total Synthesis of the Annonaceous Acetogenin,
3626 Muricatetrocin C
Darren J. Dixon, Steven V. Ley, Dominic J. Reynolds
3626- Development of a Diversity-Based Approach for the Discovery of
3629 Stereoselective Polymerization Catalysts: Identification of a
Catalyst for the Synthesis of Syndiotactic Polypropylene
Jun Tian, Geoffrey W. Coates
3630- Pentaatomic Tetracoordinate Planar Carbon, [CAl4]2-: A New
3632 Structural Unit and Its Salt Complexes
Xi Li, Hai-Feng Zhang, Lai-Sheng Wang, Grant D. Geske, Alexander I.
Boldyrev
3633- Ferromagnetic Ordering in a Two-Dimensional Copper Complex
3635 with Dual End-to-End and End-On Azide Bridges
Zhen Shen, Jing-Lin Zuo, Song Gao, You Song, Chi-Ming Che, Hoong-Kun
Fun, Xiao-Zeng You
3635- Asymmetric Conjugate Addition of Azide to , -Unsaturated
3638 Carbonyl Compounds Catalyzed by Simple Peptides
Thomas E. Horstmann, David J. Guerin, Scott J. Miller
3638- The First Dendrimer-Based Enantioselective Fluorescent Sensor for
3641 the Recognition of Chiral Amino Alcohols
Vincent J. Pugh, Qiao-Sheng Hu, Lin Pu
3641- Catalyst for DNA Ligation: Towards a Two-Stage Replication Cycle
3643 Jingdong Ye, Yahaloma Gat, David G. Lynn
3644- From Cubane to Supercubane: The Design, Synthesis, and
3646
Structure of a Three-Dimensional Open Framework Based on a
Ln4O4 Cluster
Bao-Qing Ma, Da-Shun Zhang, Song Gao, Tian-Zhu Jin, Chun-Hua Yan,
Guang-Xian Xu
3646- Remarkable Anionic Axial Ligand Effects of Iron(iii) Porphyrin
3649 Complexes on the Catalytic Oxygenations of Hydrocarbons by H2O2
and the Formation of Oxoiron(iv) Porphyrin Intermediates by mChloroperoxybenzoic Acid
Wonwoo Nam, Mi H. Lim, So-Young Oh, Jung H. Lee, Ha J. Lee, Seung K.
Woo, Cheal Kim, Woonsup Shin
3649- Dynamics of Hole Trapping by G, GG, and GGG in DNA
3652 William B. Davis, Izabela Naydenova, Reinhard Haselsberger, Alexander
Ogrodnik, Bernd Giese, Maria E. Michel-Beyerle
3652- From Glycals to Glycopeptides: A Convergent and Stereoselective
3656 Total Synthesis of a High Mannose N-Linked Glycopeptide
Zhi-Guang Wang, XuFang Zhang, David Live, Samuel J. Danishefsky
3656- Chemical Synthesis and DNA Photocleavage of the Intercalator3658 Carbohydrate Hybrid Moiety of the Neocarzinostatin Chromophore
Kazunobu Toshima, Shigeki Takai, Yutaka Maeda, Ryusuke Takano, Shuichi
Matsumura
3658- Alkane Carbonylation with Carbon Monoxide on Sulfated Zirconia:
3660 NMR Observation of Ketone and Carboxylic Acid Formation from
Isobutane and CO
Alexander G. Stepanov, Mikhail V. Luzgin, Alexey V. Krasnoslobodtsev, Vera
P. Shmachkova, Nina S. Kotsarenko
3660- Nucleoglycoconjugates: Design and Synthesis of a New Class of
3663 DNA-Carbohydrate Conjugates
Terry L. Sheppard, Chi-Huey Wong, Gerald F. Joyce
3664- Aligned Coaxial Nanowires of Carbon Nanotubes Sheathed with
3667 Conducting Polymers
Mei Gao, Shaoming Huang, Liming Dai, Gordon Wallace, Ruiping Gao,
Zhonglin Wang
3667- Living Coordination Polymerization of Allene Derivatives Bearing
3669 Hydroxy Groups by -Allylnickel Catalyst
Masanori Taguchi, Ikuyoshi Tomita, Takeshi Endo
3669- Novel Group-Transfer Three-Component Coupling of Silyltellurides,
3671 Carbonyl Compounds, and Isocyanides
Hiroshi Miyazoe, Shigeru Yamago, Jun-ichi Yoshida
3671- Structural Characterization of Novel Olefinic Cation Radicals: X-ray
3674 Crystallographic Evidence of - Hyperconjugation
Jay K. Kochi, Rajendra Rathore, Chengjian Zhu, and, Sergey V. Lindeman
3674- The First Templated Borogermanate (C2N2H10)2[(BO2.5)2(GeO2)3]:
3676 Linkage of Tetrahedra of Significantly Different Sizes
Mike S. Dadachov, Kai Sun, Tony Conradsson, Xiaodong Zou
3676- Dodecacarbonyltetracobalt Catalysis in the Thermal Pauson-Khand
3680 Reaction
Marie E. Krafft, Llorente V. R. Boñaga
3681- The First Stable Diazonium Ion on Solid Support - Investigations on
3683 Stability and Usage as Linker and Scavenger in Solid-Phase
Organic Synthesis
Stefan Dahmen, Stefan Bräse
3684- Perstannylated Ammonium and Phosphonium Ions: Organometallic
3686 Onium Ions That Are also Base-Stabilized Stannylium Ions
Matthias Driess, Christian Monsé, Klaus Merz, Christoph van Wüllen
3686- New and Facile Entry to Nitrilium Phosphane Ylide Complex
3688 Chemistry by Using 7-Phosphanorbornadiene Complexes
Rainer Streubel, Udo Schiemann, Peter G. Jones, Ngoc Hoa Tran Huy, François
Mathey
3688- Spin Frustration in a Dimeric MnII Complex with a Metallocene3691 Substituted -Nitronyl Nitroxide Radical
Daniel Ruiz-Molina, Christian Sporer, Klaus Wurst, Peter Jaitner, Jaume
Veciana
3691- Al5Br7 5 THF - The First Saltlike Aluminum Subhalide
3694 Christoph Klemp, Gregor Stößer, Ingo Krossing, Hansgeorg Schnöckel
3695- Efficient Enantioselective Extraction of Tris(diimine)ruthenium(ii)
3697 Complexes by Chiral, Lipophilic TRISPHAT Anions
Jérôme Lacour, Catherine Goujon-Ginglinger, Sonya Torche-Haldimann,
Jonathan J. Jodry
3697- Pb22- as Ligand in [Ph4P]2[{W(CO)5}4Pb2]
3699 Peter Rutsch, Gottfried Huttner
3699- Strong Field Iron(ii) Complex Converted by Light into a Long-Lived
3700 High-Spin State
Franz Renz, Hiroki Oshio, Vadim Ksenofontov, Markus Waldeck, Hartmut
Spiering, Philipp Gütlich
3701- In situ Transfer of Parahydrogen-Induced Nuclear Spin Polarization
3703 - Structural Characterization of Hydrogenation Intermediates
Patrick Hübler, Joachim Bargon
3703- Hexaaryltetragermabuta-1,3-diene: A Molecule with Conjugated Ge-
3705
Ge Double Bonds
Helmut Schäfer, Wolfgang Saak, Manfred Weidenbruch
3705- Functionalized Tellurium(ii) Thiolates: Tellurium Bis(23706 hydroxyethanethiolate) Hydrate, the First H2O-TeII Complex
Holger Fleischer, Dieter Schollmeyer
3707- Asymmetric Activation/Deactivation of Racemic Ru Catalysts for
3710 Highly Enantioselective Hydrogenation of Ketonic Substrates
Koichi Mikami, Toshinobu Korenaga, Takeshi Ohkuma, Ryoji Noyori
Volume 39, Issue 21, 2000
3721 Cover Picture
Anja Schwögler, Lars T. Burgdorf, Thomas Carell
Review
3740- Organoselenium Chemistry in Stereoselective Reactions
3749 Thomas Wirth
3750- Wherefore Art Thou Copper? Structures and Reaction Mechanisms
3771 of Organocuprate Clusters in Organic Chemistry
Eiichi Nakamura, Seiji Mori
3772- Ionic Liquids - New Solutions for Transition Metal Catalysis
3789 Peter Wasserscheid, Wilhelm Keim
Correspondence
3791- On Closed-Shell Interactions, Polar Covalences, d Shell Holes, and
3794 Direct Images of Orbitals: The Case of Cuprite
J. M. Zuo, M. O'Keeffe, M. Kim, J. C. H. Spence
3794- Final Comment on the Discussions of The Case of Cuprite
3796 Shu Guang Wang, W. H. Eugen Schwarz
Highlight
3797- Stable Systems with a Triple Bond to Silicon or Its Homologues:
3800 Another Challenge
Peter Jutzi
Communication
3801- Monosaccharide-Alkyl Glycoside Glass Phases: Plasticization with
3804 Hydrophilic and Hydrophobic Molecules
Iqbal Gill, Rao Valivety
3804- Enzymatic Glycosylation in Plasticized Glass Phases: A Novel and
3808 Efficient Route to O-Glycosides
Iqbal Gill, Rao Valivety
3808- (CN3H6)4[Zn3(SeO3)5]: The First Organically Templated Selenite
3810 William T. A. Harrison, Mark L. F. Phillips, Jesse Stanchfield, Tina M. Nenoff
3810- Correlation of the Topology of the Electron Density of Pyrite-Type
3813 Transition Metal Sulfides with Their Catalytic Activity in
Hydrodesulfurization
Yosslen Aray, Jesus Rodriguez, David Vega, Eloy Nouel Rodriguez-Arias
3813- Higher Adducts of C60 by Tether-Directed Remote Functionalization:
3816 X-Ray Crystal Structure and Reactivity of a Chiral HexakisCyclopropanated Fullerene with all Addends Located along an
Equatorial Belt
Craig R. Woods, Jean-Pascal Bourgeois, Paul Seiler, François Diederich
3816- High-Throughput Structure Verification of a Substituted 43819 Phenylbenzopyran Library by Using 2D NMR Techniques
Harald Schröder, Peter Neidig, Gérard Rossé
3819- Molecular Topology: Easy Self-Assembly of an Organometallic
3822 Doubly Braided [2]Catenane
Christopher P. McArdle, Jagadese J. Vittal, Richard J. Puddephatt
3823- Target-Accelerated Combinatorial Synthesis and Discovery of
3828 Highly Potent Antibiotics Effective Against Vancomycin-Resistant
Bacteria
K. C. Nicolaou, Robert Hughes, Suk Young Cho, Nicolas Winssinger, Christian
Smethurst, Harald Labischinski, Rainer Endermann
3829- Photoinduced Electron Transfer from a Porphyrin to an Electron
3831 Acceptor in an Antibody-Combining Site
Hiroyasu Yamaguchi, Mikiharu Kamachi, Akira Harada
3831- Hexagonal Layered Materials Composed of [M2(O2CCF3)4] (M=Ru and
3835 Rh) Donors and TCNQ Acceptors
Hitoshi Miyasaka, Cristian S. Campos-Fernández, Rodolphe Clérac, Kim R.
Dunbar
3835- Supramolecular Chemistry of Anionic Cobalt(iii) Bis(dicarbollide)
3839 and Cyclotriveratrylene in the Solid State and the Gas Phase
Michaele J. Hardie, Colin L. Raston
3839- Novel Oligosaccharide Binding to the Cerium(iv) Bis(porphyrinate)
3842 Double Decker: Effective Amplification of a Binding Signal through
Positive Homotropic Allosterism
Atsushi Sugasaki, Masato Ikeda, Masayuki Takeuchi, Seiji Shinkai
3843- Open Square-Grid Coordination Polymers of the Dimensions 20×20
3845 Å: Remarkably Stable and Crystalline Solids Even after Guest
Removal
Kumar Biradha, Yoshito Hongo, Makoto Fujita
3845- The Electrical Properties of Gold Nanoparticle Assemblies Linked
3848 by DNA
So-Jung Park, Anne A. Lazarides, Chad A. Mirkin, Paul W. Brazis, Carl R.
Kannewurf, Robert L. Letsinger
3849- Rapid, Reversible Oxygen Atom Transfer between an
3851 Oxomanganese(v) Porphyrin and Bromide: A Haloperoxidase Mimic
with Enzymatic Rates
Ning Jin, James L. Bourassa, Steven C. Tizio, John T. Groves
3851- The High-Valent Compound of Cytochrome P450: The Nature of the
3855 Fe-S Bond and the Role of the Thiolate Ligand as an Internal
Electron Donor
François Ogliaro, Shimrit Cohen, Michael Filatov, Nathan Harris, Sason Shaik
3855- Formation of Novel Ordered Mesoporous Silicas with Square
3859 Channels and Their Direct Observation by Transmission Electron
Microscopy
Tatsuo Kimura, Takayuki Kamata, Minekazu Fuziwara, Yuri Takano, Mizue
Kaneda, Yasuhiro Sakamoto, Osamu Terasaki, Yoshiyuki Sugahara, Kazuyuki
Kuroda
3859- Second-Order Nonlinear Optical Properties of Functionalized
3862 Ionophores: Cation-Steered Modulation of the First
Hyperpolarizability
Stephan Houbrechts, Yuji Kubo, Tomokazu Tozawa, Sumio Tokita, Tatsuo
Wada, Hiroyuki Sasabe
3862- Self-Assembled Organometallic Block Copolymer Nanotubes
3865 Jose Raez, Raluca Barjovanu, Jason A. Massey, Mitchell A. Winnik, Ian
Manners
3866- A Three-Step Entry to the Aspirochlorine Family of Antifungal
3868 Agents
Zhicai Wu, Lawrence J. Williams, Samuel J. Danishefsky
3868- Ion-Specific Aggregation in Conjugated Polymers: Highly Sensitive
3872 and Selective Fluorescent Ion Chemosensors
Jinsang Kim, D. Tyler McQuade, Sean K. McHugh, Timothy M. Swager
3872- [{Ir( 5-C5Me5)(CO)}6Hg8][CF3CO2]6, a Mixed-Metal Cluster with an
3873 Ir6Hg6 Twelve-Membered Ring and Additional Hg Centers and MetalMetal Bonds
Giuseppina Chiaradonna, Giovanni Ingrosso, Fabio Marchetti
3874- Synthesis of Thymine Glycol Containing Oligonucleotides from a
3876 Building Block with the Oxidized Base
Shigenori Iwai
3876- A Concise Stereoselective Route to the Pentacyclic Frameworks of
3879 Arisugacin A and Territrem B
Luke R. Zehnder, Richard P. Hsung, Jiashi Wang, Geoffrey M. Golding
3879- Formation of the Unprecedented Trilithio-Capped
3881 Heteroadamantanyl Iminoalane Anion [(HAl)4(NPh)6{Li(OEt2)}3]-: An
Open Cage Derived from a Rhombododecahedron
Kenneth W. Henderson, Alan R. Kennedy, Arlene E. McKeown, Robert E.
Mulvey
3881- New Fused Bicyclic Cyclotrigermanes from Cycloaddition Reactions
3884 of Cyclotrigermene
Norihisa Fukaya, Masaaki Ichinohe, Akira Sekiguchi
3884- Direct Bromination of Keggin Fragments To Give [PW9O28Br6]3-: A
3886 Polyoxotungstate with a Hexabrominated Face
R. John Errington, Richard L. Wingad, William Clegg, Mark R. J. Elsegood
3886- Control of Xanthine Oxidase Activity by Light
3888 Lin Ai Tai, Kuo Chu Hwang
3889- Highly Enantioselective Rh-Catalyzed Hydrogenation Reactions
3890 Based on Chiral Monophosphite Ligands
Manfred T. Reetz, Gerlinde Mehler
3891- Super-High-Throughput Screening of Enantioselective Catalysts by
3893 Using Capillary Array Electrophoresis
Manfred T. Reetz, Klaus M. Kühling, Alfred Deege, Heike Hinrichs, Detlev
Belder
3894- Novel Nickel(ii) Complexes for the Catalytic Copolymerization of
3896 Ethylene and Carbon Monoxide: Polyketone Synthesis in
Supercritical Carbon Dioxide
Wolfgang Kläui, Jochen Bongards, Guido J. Reiß
3896- A Soluble Polymer-Bound Ruthenium Carbene Complex: A Robust
3898 and Reusable Catalyst for Ring-Closing Olefin Metathesis
Qingwei Yao
3898- Synthesis and Application of a Permanently Immobilized Olefin3901 Metathesis Catalyst
Stephan C. Schürer, Simon Gessler, Nicole Buschmann, Siegfried Blechert
3901- Speciation in Solution: Silicate Oligomers in Aqueous Solutions
3905 Detected by Mass Spectrometry
Patrick Bussian, Frank Sobott, Bernhard Brutschy, Wolfgang Schrader, Ferdi
Schüth
3905- Stepwise Assembled Photoactive Films Containing Donor-Linked
3909 Fullerenes
Chuping Luo, Dirk M. Guldi, Michele Maggini, Enzo Menna, Simonetta
Mondini, Nicholas A. Kotov, Maurizio Prato
3909- Breaking the Rule: Synthesis and Molecular Structure of Dinuclear
3911 Rhodium Complexes with Bridging and Semibridging
Trialkylphosphane Ligands
Thomas Pechmann, Carsten D. Brandt, Helmut Werner
3912- Cisplatin Changes the Mechanics of Single DNA Molecules
3915 Rupert Krautbauer, Hauke Clausen-Schaumann, Hermann E. Gaub
3915- Spherical Aromaticity in Ih Symmetrical Fullerenes: The 2(N+1)2 Rule
3917 Andreas Hirsch, Zhongfang Chen, Haijun Jiao
3918- Self-Repairing DNA Based on a Reductive Electron Transfer through
3920 the Base Stack
Anja Schwögler, Lars T. Burgdorf, Thomas Carell
3921- Room Temperature Oxidation of Carbon Monoxide Catalyzed by
3922 Hydrous Ruthenium Dioxide
Ling Zang, Horst Kisch
3923- The Cl4+ Ion
3925 Stefan Seidel, Konrad Seppelt
3925- [{Ag(tBuNH2)2}4][{Ag(tBuNH2)(tBuN=CHCH3)}2][Ag12(CF3CO2)14]: A
3929 Compound with an Ag128+ Cluster Core
Peter Reiß, Florian Weigend, Reinhart Ahlrichs, Dieter Fenske
3929- Synthesis, Crystal Structure, and Binding Properties of the Mixed
3933 Valence Clusters [Cu32As30(dppm)8] and [Cu26Te12(PEt2Ph)12]
Reinhart Ahlrichs, Jörn Besinger, Andreas Eichhöfer, Dieter Fenske, Axel
Gbureck
3933- A Blue Luminescent Starburst Molecule and Its Orange
3935 Luminescent Trinuclear PdII Complex: 1,3,5-tris(7-azaindol-1yl)benzene (tabH) and [PdII3(tab)2Cl4]
Qingguo Wu, Andrea Hook, Suning Wang
Volume 39, Issue 22, 2000
3945
Cover Picture
Nguyet T. Tran, Douglas R. Powell, Lawrence F. Dahl
Review
3964- Fischer Carbene Complexes as Chemical Multitalents: The
4002 Incredible Range of Products from Carbenepentacarbonylmetal , Unsaturated Complexes
Armin de Meijere, Heiko Schirmer, Michael Duetsch
4004- Piezoelectric Mass-Sensing Devices as Biosensors - An Alternative
4032 to Optical Biosensors?
Andreas Janshoff, Hans-Joachim Galla, Claudia Steinem
Highlight
4033- New Developments in the Origins of the Homochirality of
4036 Biologically Relevant Molecules
Helmut Buschmann, Richard Thede, Detlef Heller
4036- The Wanzlick Equilibrium
4038 Volker P. W. Böhm, Wolfgang A. Herrmann
Correspondence
4039- Comments on the Terminology for Applications of Temporarily
4040 Attached Solubility-Modifying Moieties in Combinatorial Chemistry
Andreas Link
Communication
4041- Inorganic Layered Double Hydroxides as Nonviral Vectors
4045 Jin-Ho Choy, Seo-Young Kwak, Yong-Joo Jeong, Jong-Sang Park
4045- Epoxidation Catalysis by a Manganese Corrole and Isolation of an
4047 Oxomanganese(v) Corrole
Zeev Gross, Galina Golubkov, Liliya Simkhovich
4048- Structural, Electrochemical, and Photophysical Properties of
4051 Gallium(iii) 5,10,15-Tris(pentafluorophenyl)corrole
Jesper Bendix, Ivan J. Dmochowski, Harry B. Gray, Atif Mahammed, Liliya
Simkhovich, Zeev Gross
4051- Evidence for the Formation of a RuIII-RuIII Bond in a Ruthenium
4053 Corrole Homodimer
François Jérôme, Béatrice Billier, Jean-Michel Barbe, Enrique Espinosa,
Slimane Dahaoui, Claude Lecomte, Roger Guilard
4053- A Triangular Triplatinum Complex with Electron-Releasing SiPh2
4055 and PMe3 Ligands: [{Pt( -SiPh2)(PMe3)}3]
Kohtaro Osakada, Makoto Tanabe, Tomoaki Tanase
4055- Synthesis of a Versatile Tridentate Anthracene Ligand and its
4058 Application for the Synthesis of Hypervalent Pentacoordinate
Boron Compounds (10-B-5)
Makoto Yamashita, Yohsuke Yamamoto, Kin-ya Akiba, Shigeru Nagase
4058- Diels-Alder Type Addition of 1,3-Dienes to a Disulfide Bridging
4061 Ligand in Diruthenium Complexes
Hiroyasu Sugiyama, Yong-Shou Lin, Kazuko Matsumoto
4061- Regiospecific Hydride Transfer from cis-[Ru(bpy)2(CO)(CHO)]+ to
4063 NAD+ Model Compounds: A Model for Enzymatic Reactions by
Aldehyde Dehydrogenases
Hideo Konno, Kazuhiko Sakamoto, Osamu Ishitani
4063- A New Self-Assembling System for Targeted Gene Delivery
4067 Michael A. W. Eaton, Terence S. Baker, Catherine F. Catterall, Kenneth Crook,
Graham S. Macaulay, Barbara Mason, Timothy J. Norman, David Parker, Justin
J. B. Perry, Richard J. Taylor, Alison Turner, A. Neil Weir
4067- A Versatile Periodate-Coupled Fluorogenic Assay for Hydrolytic
4070 Enzymes
Fabrizio Badalassi, Denis Wahler, Gérard Klein, Paolo Crotti, Jean-Louis
Reymond
4070- Formation of a Giant Supramolecular Porphyrin Array by Self4073 Coordination
Kazuya Ogawa, Yoshiaki Kobuke
4073- Enantioselective Total Synthesis of (+)-Gelsemine: Determination
4075 of Its Absolute Configuration
Satoshi Yokoshima, Hidetoshi Tokuyama, Tohru Fukuyama
4076- (-)-Rhizochalin is a Dimeric Enantiomorphic (2R)-Sphingolipid:
4079 Absolute Configuration of Pseudo-C2v-Symmetric Bis-2-amino-3alkanols by CD
Tadeusz F. Molinski, Tatyana N. Makarieva, Valentin A. Stonik
4079- Amphoteric Character of 2-Vinyloxiranes: Synthetic Equivalents of
4082
, -Unsaturated Aldehydes and a Vinylogous Enolate
Mark Lautens, Stéphane G. Ouellet, Stéphane Raeppel
4082- Total Synthesis of (+)-Eurylene and (+)-14-Deacetyleurylene
4084 Yoshiki Morimoto, Koji Muragaki, Toshiyuki Iwai, Yukio Morishita, Takamasa
Kinoshita
4084- Cuprophilicity: Spectroscopic and Structural Evidence for Cu-Cu
4088 Bonding Interactions in Luminescent Dinuclear Copper(i)
Complexes with Bridging Diphosphane Ligands
Chi-Ming Che, Zhong Mao, Vincent M. Miskowski, Man-Chung Tse, ChiKeung Chan, Kung-Kai Cheung, David Lee Phillips, King-Hung Leung
4088- Low-Temperature Activation of Dioxygen and Hydrocarbon
4090 Oxidation Catalyzed by a Phosphovanadomolybdate: Evidence for
a Mars-van Krevelen Type Mechanism in a Homogeneous Liquid
Phase
Alexander M. Khenkin, Ronny Neumann
4090- Oxidosqualene Cyclase Residues that Promote Formation of
4092 Cycloartenol, Lanosterol, and Parkeol
Michelle M. Meyer, Michael J. R. Segura, William K. Wilson, Seiichi P. T.
Matsuda
4093- A New Efficient Synthesis of (R,R)-2,2 -Bipyrrolidine: An Interesting
4095 Chiral 1,2-Diamine with C2 Symmetry
Alexandre Alexakis, Axel Tomassini, Cyril Chouillet, Sylvain Roland, Pierre
Mangeney, Gerald Bernardinelli
4096- Isolation of a Pyridinium Alkoxy Ion Bridged Dimeric Zinc Complex
4098 for the Coupling Reactions of CO2 and Epoxides
Hoon Sik Kim, Jai Jun Kim, Byung Gwon Lee, Ok Sang Jung, Ho Gyeom Jang,
Sang Ook Kang
4098- Rational Construction of Chiral Octanuclear Metallacycles
4101 Consisting of Octahedral CoIII, Square-Planar PdII, and Linear AuI or
AgI Ions
Takumi Konno, Yu Chikamoto, Ken-ichi Okamoto, Tadashi Yamaguchi,
Tasuku Ito, Masakazu Hirotsu
4101- Proton-Coupled Electron Transfer from Sulfur: A S-H/S-D Kinetic
4104 Isotope Effect of 31.1
My-Hang V. Huynh, Peter S. White, Thomas J. Meyer
4104- The First Highly Enantioselective Rh-Catalyzed Enyne
4106 Cycloisomerization
Ping Cao, Xumu Zhang
4106- Rhodium-Mediated Asymmetric Hydroformylation with a Novel
4108 Bis(diazaphospholidine) Ligand
Simon Breeden, David J. Cole-Hamilton, Douglas F. Foster, Gary J. Schwarz,
Martin Wills
4108- arachno-[Sn8]6- or closo-[Li2Sn8]4-? Synthesis and Characterization
4110 of A4Li2Sn8 (A=Rb, K)
Svilen Bobev, Slavi C. Sevov
4111- Reductive Samariation of Anomeric 2-Pyridyl Sulfones with
4114 Catalytic Nickel: An Unexpected Improvement in the Synthesis of
1,2-trans-Diequatorial C-Glycosyl Compounds
Nicolas Miquel, Gilles Doisneau, Jean-Marie Beau
4114- Formation of Optically Active Aromatic -Amino Acids by Catalytic
4116 Enantioselective Addition of Imines to Aromatic Compounds
Steen Saaby, Xiangming Fang, Nicholas Gathergood, Karl Anker Jørgensen
4117- Hydrogen/Deuterium Exchange Catalyzed by an Unusually Stable
4118 Mercury-Toluene Complex
Alexander S. Borovik, Simon G. Bott, Andrew R. Barron
4119- Stabilization of a Reactive Cationic Species by Supramolecular
4121 Encapsulation
Marco Ziegler, Julia L. Brumaghim, Kenneth N. Raymond
4121- Nanosized Pd145(CO)x(PEt3)30 Containing a Capped Three-Shell 1454125 Atom Metal-Core Geometry of Pseudo Icosahedral Symmetry
Nguyet T. Tran, Douglas R. Powell, Lawrence F. Dahl
4127- A Novel CSiP Ring from the Reaction of a Complexed
4130 Phosphinidene and a Silene
Mark J. M. Vlaar, Andreas W. Ehlers, Frans J. J. de Kanter, Marius Schakel,
Anthony L. Spek, Martin Lutz, Nadejda Sigal, Yitzhak Apeloig, Koop
Lammertsma
4130- Virtual Screening for Bioactive Molecules by Evolutionary De Novo
4133 Design
Gisbert Schneider, Odile Clément-Chomienne, Laurence Hilfiger, Petra
Schneider, Stefan Kirsch, Hans-Joachim Böhm, Werner Neidhart
4133- Chirally Modified n-Butyllithium: Tuning the Composition,
4136 Structure, and Enantioselectivity with Modular Fencholates
Bernd Goldfuss, Melanie Steigelmann, Frank Rominger
4136- C-H Activation by Direct Borane-Hydrocarbon Dehydrogenation:
4139 Kinetic and Thermodynamic Aspects
Bernd Goldfuss, Paul Knochel, Lars O. Bromm, Kolja Knapp,
4139- Multilevel Molecular Electronic Species: Electrochemical Reduction
4142 of a [2×2] CoII4 Grid-Type Complex by 11 Electrons in 10 Reversible
Steps
Mario Ruben, Esther Breuning, Jean-Paul Gisselbrecht, Jean-Marie Lehn
4142- Repetitive Application of Perfluoro-Tagged Pd Complexes for Stille
4145 Couplings in a Fluorous Biphasic System
Siegfried Schneider, Willi Bannwarth
4145- A Li10 Cage Containing the [C6H11P -C(Ph) -N]2- Ion: Umpolung in
4148
the Oligomerization of a Nitrile
Neil Feeder, Yvonne G. Lawson, Paul R. Raithby, Jeremy M. Rawson,
Alexander Steiner, Jody A. Wood, Anthony D. Woods, Dominic S. Wright
4148- Stabilization of a Pentastibacyclopentadienyl Ligand in the Triple4150 Decker Sandwich Complexes [{( 5-1,2,4-tBu3C5H2)Mo}2( , 5-Sb5)]
and [( 5-1,2,4-tBu3C5H2)Mo( , 5-Sb5)Mo( 5-1,4-tBu2-2-MeC5H2)]
Hans Joachim Breunig, Neil Burford, Roland Rösler
41504153 Alla Zamyatina, Sabine Gronow, Clemens Oertelt, Michael Puchberger, Helmut
Brade, Paul Kosma
4153- A New Highly Efficient Catalyst System for the Coupling of
4155 Nonactivated and Deactivated Aryl Chlorides with Arylboronic
Acids
Alexander Zapf, Andreas Ehrentraut, Matthias Beller
4156- A Palladium-Catalyzed Synthesis of Amidines from Aryl Halides
4158 C. Gustaf Saluste, Richard J. Whitby, Mark Furber
4158- Cobalt on Charcoal: A Convenient and Inexpensive Heterogeneous
4160 Pauson-Khand Catalyst
Seung Uk Son, Sang Ick Lee, Young Keun Chung
4160- (CuI)2P8Se3: An Adduct of D3-Symmetrical P8Se3 Cage Molecules
4162 with Cu2I2 Rhomboids
Arno Pfitzner, Sara Reiser, Tom Nilges
4162- The Structure of the FeIVO44- Ion
4163 Mark T. Weller, Andrew L. Hector
Volume 39, Issue 23, 2000
4173
Cover Picture
Alfred Wittinghofer, Herbert Waldmann
Review
4192- Ras - A Molecular Switch Involved in Tumor Formation
4214 Alfred Wittinghofer, Herbert Waldmann
4216- Nematic Liquid Crystals for Active Matrix Displays: Molecular
4235 Design and Synthesis
Peer Kirsch, Matthias Bremer
Highlight
4237- An Eldorado for Homogeneous Catalysis?
4239 Gerald Dyker
4240- Molecular Gold - Multinuclear Gold(i) Complexes
4242 Vivian W.-W. Yam, Eddie C.-C. Cheng
4242- Single Fullerene Molecules and the Wave-Particle Dualism
4244 K. O. Greulich
Correspondence
4245- Reexamination of the Evidence for Solvent-Induced Intramolecular
4247 Electrophilic Catalysis by a cis Vicinal Hydroxyl Group in
Ribonucleoside Phosphorylation Reactions
Paul M. Cullis, Martin J. P. Harger, Michael Lee
Communication
4249- New Mesotextured Hybrid Materials Made from Assemblies of
4254 Dendrimers and Titanium(iv)-Oxo-Organo Clusters
Galo J. de A. A. Soler-Illia, Laurence Rozes, Mary Kate Boggiano, Clément
Sanchez, Cédric-Olivier Turrin, Anne-Marie Caminade, Jean-Pierre Majoral
4254- Functionalized Fullerene as an Artificial Vector for Transfection
4257 Eiichi Nakamura, Hiroyuki Isobe, Naoki Tomita, Masaya Sawamura, Shigeki
Jinno, Hiroto Okayama
4257- Ternary Complexes Between DNA, Polyamine, and Cucurbituril: A
4260 Modular Approach to DNA-Binding Molecules
Hiroyuki Isobe, Naoki Tomita, Jae Wook Lee, Hee-Joon Kim, Kimoon Kim,
Eiichi Nakamura
4260- Complexation of Antimony(iii) by Trypanothione
4262 Siucheong Yan, Keyang Ding, Li Zhang, Hongzhe Sun
4262- Supramolecular Modification of the Periphery of Dendrimers
4265 Resulting in Rigidity and Functionality
Maurice W. P. L. Baars, Annika J. Karlsson, Victor Sorokin, Bas F. W. de
Waal, E. W. Meijer
4266- Charge-Transfer Diamondoid Lattices: An Unprecedentedly Huge
4268 and Highly Catenating Diamondoid Network Arising from a
Tetraphenol as a Tetrahedral Node and Benzoquinone as a Linear
Spacer
D. Shekhar Reddy, Takehisa Dewa, Ken Endo, Yasuhiro Aoyama
4268- Catalyst Screening Using an Array of Thermistors
4271 Ashley R. Connolly, John D. Sutherland
4271- [Cu(2-pyrazinecarboxylato)2HgI2] HgI2: An Open
4273 Noninterpenetrating CuII-HgII Mixed-Metal Cuboidal Framework
Encapsulating Nearly Linear HgI2 Guest Molecules
Yu-Bin Dong, Mark D. Smith, Hans-Conrad zur Loye
4274- Synthesis and Structure of a Monomeric Aluminum(i) Compound
4276 [{HC(CMeNAr)2}Al] (Ar=2,6-iPr2C6H3): A Stable Aluminum Analogue
of a Carbene
Chunming Cui, Herbert W. Roesky, Hans-Georg Schmidt, Mathias Noltemeyer,
Haijun Hao, Fanica Cimpoesu
4276- Alumoxane Hydride and Aluminum Chalcogenide Hydride
4279 Compounds with Pyrazolato Ligands
Wenjun Zheng, Nadia C. Mösch-Zanetti, Herbert W. Roesky, Mathias
Noltemeyer, Manuel Hewitt, Hans-Georg Schmidt, Thomas R. Schneider
4279- Stereochemical Assignment of the C21-C38 Portion of the
4281 Desertomycin/Oasomycin Class of Natural Products by Using
Universal NMR Databases: Prediction
Yoshihisa Kobayashi, Choon-Hong Tan, Yoshito Kish
4282- Stereochemical Assignment of the C21-C38 Portion of the
4284 Desertomycin/Oasomycin Class of Natural Products by Using
Universal NMR Databases: Proof
Choon-Hong Tan, Yoshihisa Kobayashi, Yoshito Kishi
4284- Tuning the Regiospecificity of Cleavage in FeIII Catecholate
4287 Complexes: Tridentate Facial versus Meridional Ligands
Du-Hwan Jo, Lawrence Que, Jr.
4287- An Unusually Shallow Distance-Dependence for Triplet-Energy
4290
Transfer
Anthony Harriman, Abderrahim Khatyr, Raymond Ziessel, Andrew C.
Benniston
4290- The Distinct Effect of the o-Carboranyl Fragment: Its Influence on
4292 the I-I Distance in R3PI2 Complexes
Francesc Teixidor, Rosario Núñez, Clara Viñas, Reijo Sillanpää, Raikko
Kivekäs
4292- Remote Enantioselection Transmitted by an Achiral Peptide
4295 Nucleic Acid Backbone
Igor A. Kozlov, Leslie E. Orgel, Peter E. Nielsen
4295- ZnBr2-Catalyzed Insertions of Carbonyl Compounds into
4299 Silacyclopropanes: Regiochemical Reversal Dependent on Metal
Salt
Annaliese K. Franz, K. A. Woerpel
4299- A Linker Scaffold to Present Dimers of Pharmacophores Prepared
4301 by Solid-Phase Syntheses
Mookda Pattarawarapan, Kevin Burgess
4301- First Generation Light-Harvesting Dendrimers with a [Ru(bpy)3]2+
4305 Core and Aryl Ether Ligands Functionalized with Coumarin 450
Xiaoli Zhou, Daniel S. Tyson, Felix N. Castellano
4306- Highly Regio- and Enantioselective Reduction of 3,54308 Dioxocarboxylates
Michael Wolberg, Werner Hummel, Christian Wandrey, Michael Müller
4308- Revision of the Absolute Configuration of Salicylihalamide A
4310 through Asymmetric Total Synthesis
Yusheng Wu, Lothar Esser, Jef K. De Brabander
4310- Clean and Efficient Catalytic Reduction of Perchlorate
4313 Mahdi M. Abu-Omar, Lee D. McPherson, Joachin Arias, Virginie M. Béreau
4314- The First Entry to Complex Bakkanes: A Highly Effective
4316 Retroaldol-Aldol-Based Approach to (-)-Bakkenolides III, B, C, and
H
Olivier Hamelin, Yanyun Wang, Jean-Pierre Deprés, Andrew E. Greene
4316- A Tandem Sulfur Transfer/Reduction/Michael Addition Mediated by
4319 Benzyltriethylammonium Tetrathiomolybdate
Kandikere Ramaiah Prabhu, Pennadam S. Sivanand, Srinivasan Chandrasekaran
4319- Transition Metal Complexes as Photosensitizers for Near-Infrared
4321 Lanthanide Luminescence
Stephen I. Klink, Henk Keizer, Frank C. J. M. van Veggel
4321- A Novel Iron-Based Catalyst for the Biphasic Oxidation of Benzene
4323 to Phenol with Hydrogen Peroxide
Daniele Bianchi, Rossella Bortolo, Roberto Tassinari, Marco Ricci, Rodolfo
Vignola
4324- Cyclodextrin Bilayer Vesicles
4326 Bart Jan Ravoo, Raphael Darcy
4327- Selective Enhancement of the One-Electron Oxidation of Guanine
4329 by Base Pairing with Cytosine
Kiyohiko Kawai, Yasuharu Wata, Nobuyuki Ichinose, Tetsuro Majima
4331- First Synthesis of the Dendralene Family of Fundamental
4333 Hydrocarbons
Simon Fielder, Daryl D. Rowan, Michael S. Sherburn
4333- The Hexaazidogermanate(iv) Ion: Syntheses, Structures, and
4336 Reactions
Alexander C. Filippou, Peter Portius, Dirk U. Neumann, Klaus-Dieter
Wehrstedt
4337- Selective Trimerization of -Olefins with Triazacyclohexane
4339 Complexes of Chromium as Catalysts
Randolf D. Köhn, Matthias Haufe, Gabriele Kociok-Köhn, Siegfried Grimm,
Peter Wasserscheid, Wilhelm Keim
4339- Identification of a New Sex Pheromone from the Silk Dragline of the
4341 Tropical Wandering Spider Cupiennius salei
Mirjam Papke, Stefan Schulz, Harald Tichy, Ewald Gingl, Rudolf Ehn
4341- Analysis of the Silkworm Moth Pheromone Binding Protein4343 Pheromone Complex by Electrospray-Ionization Mass
Spectrometry
Neil J. Oldham, Jürgen Krieger, Heinz Breer, Annette Fischedick, Michal
Hoskovec, Ale Svato
4343- Chemo-, Regio-, and Stereoselective Cyclization of 1,34346 Bis(trimethylsilyloxy)-1,3-butadienes with Functionalized Epoxides
Peter Langer, Tobias Eckardt
4346- Eight-Membered Carbocycles from a Dötz-Like Reaction
4348 José Barluenga, Fernando Aznar, M. Angel Palomero
4348- Combinatorial Solid-Phase Synthesis of Multivalent Cyclic
4352 Neoglycopeptides
Valentin Wittmann, Sonja Seeberger
4352- Wound-Activated Chemical Defense in Unicellular Planktonic Algae
4354 Georg Pohnert
4355- Remote Stereocontrol in Organocopper Chemistry: Highly
4356 Enantioselective Synthesis of Vinylallenes by 1,5-Substitution of
Enyne Acetates
Norbert Krause, Martin Purpura
4357- A New Class of Easily Obtained Carbonate-Related 3-Ligands and
4359 a Protein-Sized Doughnut-Shaped Coordination Oligomer
Iris M. Müller, Richard Robson
4359- Catalytic Enantioselective Fluorination of -Ketoesters
4362 Lukas Hintermann, Antonio Togni
4362- Octahedral SeO66- and Square-Pyramidal SeO54-, Two New
4364 Oxoselenate Anions
Helmut Haas, Martin Jansen
4364- Total Synthesis of (+)-Ratjadone
4366 Mathias Christmann, Ulhas Bhatt, Monika Quitschalle, Eckhard Claus, Markus
Kalesse
4367- Combinatorial Testing of Supported Catalysts for the
4369 Heterogeneous Polymerization of Olefins
Martin Stork, Andreas Herrmann, Tanja Nemnich, Markus Klapper, Klaus
Müllen
4369- An Allosteric Ribozyme Regulated by Doxycyline
4373 Nicolas Piganeau, Andreas Jenne, Vincent Thuillier, Michael Famulok
4373- Homoleptic Phosphoraneiminato Complexes of Rare Earth
4375 Elements as Initiators for Ring-Opening Polymerization of Lactones
Thorsten Gröb, Gert Seybert, Werner Massa, Frank Weller, Ravi Palaniswami,
Andreas Greiner, Kurt Dehnicke
4376- Tailored Alkene Oligomerization with H-ZSM-57 Zeolite
4379 Johan A. Martens, Raman Ravishankar, Igor E. Mishin, Pierre A. Jacobs
4379- Tribochemical Activation of Iron Oxide for the Reduction of NO with
4382 CO: How Lattice Defects Can Influence the Catalytic Activity
Thomas Rühle, Olaf Timpe, Norbert Pfänder, Robert Schlögl
Volume 39, Issue 24, 2000
4391
Cover Picture
Burckhard Seelig, Sonja Keiper, Friedrich Stuhlmann, Andres Jäschke
Review
4414- New Applications of Polyfunctional Organometallic Compounds in
4435 Organic Synthesis
Andreas Boudier, Lars O. Bromm, Matthias Lotz, Paul Knochel
4436- Electron Spin Polarization and Time-Resolved Electron
4461 Paramagnetic Resonance: Applications to the Paradigms of
Molecular and Supramolecular Photochemistry
Nicholas J. Turro, Mark H. Kleinman, Erdem Karatekin
Essay
4463- How Capillary Electrophoresis Sequenced the Human Genome
4468 Norman J. Dovichi, Jianzhong Zhang
Highlight
4469- The Pharmaceutical Potential of Manganese-Based Superoxide
4470 Dismutase Mimics
Roland Krämer
Correspondence
4471- How Can Metallic Ferromagnetism Be Explained? Itinerant
4475 Ferromagnetism of the Transition Metals: Our Present
Understanding
Gernot Stollhoff
4475- Reply
4476 Gregory A. Landrum, Richard Dronskowski
Communication
4477- Complete Structural Characterization by Ab Initio X-Ray Powder
4480 Diffraction of [{Re( -H)(CO)4}n] and [{Re( -H)(CO)4}6], Inorganic
Analogues of Polyethylene and Cyclohexane
Norberto Masciocchi, Giuseppe D'Alfonso, Luca Garavaglia, Angelo Sironi
4481- Annelated Heptathiophene: A Fragment of a Carbon-Sulfur Helix
4483 Andrzej Rajca, Hua Wang, Maren Pink, Suchada Rajca
4483- Towards the DRED of Resin-Supported Combinatorial Libraries: A
4485 Non-Invasive Methodology Based on Bead Self-Encoding and
Multispectral Imaging
Hicham Fenniri, Hartmut G. Hedderich, Kenneth S. Haber, Jihane Achkar,
Brian Taylor, Dor Ben-Amotz
4485- Polymorphism in p-Hydroxybenzoic Acid: The Effect of
4488 Intermolecular Hydrogen Bonding in Controlling Proton Order
versus Disorder in the Carboxylic Acid Dimer Motif
Benson M. Kariuki, Clare L. Bauer, Kenneth D. M. Harris, Simon J. Teat
4488- Structure Determination of an Oligopeptide Directly from Powder
4491 Diffraction Data
Emilio Tedesco, Giles W. Turner, Kenneth D. M. Harris, Roy L. Johnston,
Benson M. Kariuki
4492- Aromatic Aminations by Heterogeneous Ni0/C Catalysis
4494 Bruce H. Lipshutz, Hiroshi Ueda
4494- Application of a Spin-Labeled Spin-Trap to the Detection of Nitric
4496 Oxide (NO)
Lucien Marx, André Rassat
4496- Novel NO Biosensor Based on the Surface Derivatization of GaAs
4500 by Hinged Iron porphyrins
Deng Guo Wu, Gonen Ashkenasy, Dmitry Shvarts, Rachel V. Ussyshkin, Ron
Naaman, Abraham Shanzer, David Cahen
4500- Stereoselective Synthesis of Highly Functionalized C-Glycosides
4502 based on Acetal [1,2] and [1,4] Wittig Rearrangements
Katsuhiko Tomooka, Hiroshi Yamamoto, Takeshi Nakai
4502- Stereoselective Total Synthesis of Zaragozic Acid A based on an
4505 Acetal [1,2] Wittig Rearrangement
Katsuhiko Tomooka, Makoto Kikuchi, Kazunobu Igawa, Masaki Suzuki, PingHuai Keong, Takeshi Nakai
4505- Subtle Variations in the Long-Range Transmission of
4508 Stereochemical Information: Matched and Mismatched Aldol
Reactions
Zhicai Wu, Fei Zhang, Samuel J. Danishefsky
4509- The Synthesis of CP-263,114 and CP-225,917: Striking Long-Range
4511 Stereocontrol in the Fashioning of C7
Qiang Tan, Samuel J. Danishefsky
4512- Synthesis and Reactions of Palladium and Platinum Complexes
4513 Bearing Diphosphinidenecyclobutene Ligands: A Thermally Stable
Catalyst for Ethylene Polymerization
Shintaro Ikeda, Fumie Ohhata, Masaki Miyoshi, Rika Tanaka, Tatsuya Minami,
Fumiyuki Ozawa, Masaaki Yoshifuji
4513- Highly Selective Ring-Opening/Cross-Metathesis Reactions of
4515 Norbornene Derivatives Using Selenocarbene Complexes as
Catalysts
Hiroyuki Katayama, Hideto Urushima, Tsuneo Nishioka, Chikaya Wada,
Masato Nagao, Fumiyuki Ozawa
4516- Crystal Structure of [(Ph(Me)C:N:C(H)Ph)K (tBuOK)2 (thf)2] : A
4518 Unimetallic Mixed Anion Model for a Superbase ?
Philip C. Andrews, Gary D. Fallon, Melissa Maguire, Anna C. Peatt
4518- Catalytic Asymmetric Aziridination with Arylborate Catalysts
4521 Derived from VAPOL and VANOL Ligands
Jon C. Antilla, William D. Wulff
4521- Stereoselective Synthesis of RP- and SP-Dithymidine
4524 Phosphorothioates via Chiral Indolooxazaphosphorine
Intermediates Derived from Tryptophan
Yixin Lu, George Just
4524- Early Transition Metal -Diazoalkane Complexes
4528 Victorio Cadierno, Maria Zablocka, Bruno Donnadieu, Alain Igau, Jean-Pierre
Majoral
4528- Hybrid Coordination Polymers - Metal Oxide Compounds with
4531 Chiral Structures
Li-Min Zheng, Tabatha Whitfield, Xiqu Wang, Allan J. Jacobson
4531- [HC{(CMe)(NAr)}2]Al[(NSiMe3)2N2] (Ar=2,6-iPr2C6H3): The First Five4533 Membered AlN4 Ring System
Chunming Cui, Herbert W. Roesky, Hans-Georg Schmidt, Mathias Noltemeyer
4533- Synthesis of Stable Organo(bis-silanetriols): X-Ray Powder
4537 Structure of 1,4-Bis(trihydroxysilyl)benzene
Geneviève Cerveau, Robert J. P. Corriu, Bertrand Dabiens, Jean Le Bideau
4537- The Essential Role of a ZnII Ion in the Disproportionation of
4539 Semiquinone Radical Anion by an Imidazolate-Bridged CuII-ZnII
Model of Superoxide Dismutase
Hideki Ohtsu, Shunichi Fukuzumi
4539- New Family of Cyclopropanating Reagents: Synthesis, Reactivity,
4542 and Stability Studies of Iodomethylzinc Phenoxides
André B. Charette, Sébastien Francoeur, Jonathan Martel, Nicole Wilb
4542- A Near-Infrared Luminescent Label Based on YbIII Ions and Its
4544 Application in a Fluoroimmunoassay
Martinus H. V. Werts, Richard H. Woudenberg, Peter G. Emmerink, Rob van
Gassel, Johannes W. Hofstraat, Jan W. Verhoeven
4545- Removal of Benzyl Protecting Groups from Solid-Supported
4547 Compounds by Hydrogenolysis Using Palladium Nanoparticles
Osamu Kanie, Gijsbert Grotenbreg, Chi-Huey Wong
4547- Tuning the Semiconducting Properties of Sexithiophene by , 4551 Substitution - , -Diperfluorohexylsexithiophene: The First n-Type
Sexithiophene for Thin-Film Transistors
Antonio Facchetti, Yvonne Deng, Anchuan Wang, Yoshihiro Koide, Henning
Sirringhaus, Tobin J. Marks, Richard H. Friend
4552- Crystallization of a Large-Pore Three-Dimensional Gallium
4555 Fluorophosphate under Mild Conditions
Richard I. Walton, Franck Millange, Thierry Loiseau, Dermot O'Hare, Gérard
Férey
4555- A One-Dimensional Metallocyclophane with Columnar Aromatic
4557 Stacking: The Silver(i) 2-Coordination Complex of 1,2Benztriphenylene
Megumu Munakata, Gui Ling Ning, Yusaku Suenaga, Takayoshi KurodaSowa, Masahiko Maekawa, Tetsuhiro Ohta
4558- Supramolecular Assembly of Hexagonal Mesostructured
4562 Germanium Sulfide and Selenide Nanocomposites Incorporating
the Biologically Relevant Fe4S4 Cluster
Pantelis N. Trikalitis, Thomas Bakas, Vasilios Papaefthymiou, Mercouri G.
Kanatzidis
4562- Benzene-Centered Tri- and Tetrametallacarborane Sandwich
4564 Complexes
Martin Bluhm, Hans Pritzkow, Walter Siebert, Russell N. Grimes
4565- Ground-State Reversal by Matrix Interaction: Electronic States and
4567 Vibrational Frequencies of CUO in Solid Argon and Neon
Lester Andrews, Binyong Liang, Jun Li, Bruce E. Bursten
4567- Visualization of Single Multivalent Receptor-Ligand Complexes by
4570 Transmission Electron Microscopy
Jason E. Gestwicki, Laura E. Strong, Laura L. Kiessling
4570- A Remarkable, Stable Radical-Molecule Complex: HO2 CF3C(O)OH
4571 Joseph S. Francisco
4573- Stochastic Resonance in a Bistable Chemical System: The
4576 Oxidation of Ascorbic Acid by Oxygen Catalyzed by Copper(ii) Ions
Peter E. Strizhak, Igor Demjanchyk, Frank Fecher, Friedemann W. Schneider,
Arno F. Münster
4576- Enantioselective Ribozyme Catalysis of a Bimolecular
4579 Cycloaddition Reaction
Burckhard Seelig, Sonja Keiper, Friedrich Stuhlmann, Andres Jäschke
4580- (Ph4P)S6 - A Compound Containing the Cyclic Radical Anion S6.4582 Bernhard Neumüller, Fritjof Schmock, Reinhard Kirmse, Andreas Voigt, Axel
Diefenbach, F. Matthias Bickelhaupt, Kurt Dehnicke
4582- Conical Intersections in Charge-Transfer Induced Quenching
4586 Adalgisa Sinicropi, Uwe Pischel, Riccardo Basosi, Werner M. Nau, Massimo
Olivucci
4586- From a Racemate to a Pure Enantiomer by Laser Pulses: Quantum
4588 Model Simulations for H2POSH
Yuichi Fujimura, Leticia González, Kunihito Hoki, Dominik Kröner, Jörn
Manz, Yukiyoshi Ohtsuki
4588- Bis(pentafluorophenyl)xenon, Xe(C6F5)2: A Homoleptic
4591 Diorganoxenon Derivative
Nicola Maggiarosa, Dieter Naumann, Wieland Tyrra
4591- C6F5XeF, A Key Substrate in Xenon-Carbon Chemistry: Synthesis of
4593 Symmetric and Asymmetric Pentafluorophenylxenon(ii) Derivatives
Hermann-Josef Frohn, Michael Theißen
4593- An Enantiospecific Synthesis of the Potent Immunosuppressant
4596 FR901483
Goetz Scheffler, Hirofumi Seike, Erik J. Sorensen
4596- Total Synthesis of (-)-Spirotryprostatin B and Three Stereoisomers
4599 Larry E. Overman, Mark D. Rosen
4599- Reconstitution of Channel Proteins in (Polymerized) ABA Triblock
4602 Copolymer Membranes
Wolfgang Meier, Corinne Nardin, Mathias Winterhalter
4602- Direct Observation of the Lower Critical Solution Temperature of
4604 Surface-Attached Thermo-Responsive Hydrogels by Surface
Plasmon Resonance
Erik Wischerhoff, Thomas Zacher, André Laschewsky, El Djouhar Rekaï
4605- Asymmetric Synthesis of -Substituted -Nitrophosphonic Acids
4607 by Phospha-Analogous Michael Addition to Aromatic Nitroalkenes
Dieter Enders, Livio Tedeschi, Jan Willem Bats
4607- Breakdown of Bond Length-Bond Strength Correlation: A Case
4609 Study
Martin Kaupp, Bernhard Metz, Hermann Stoll L
4610- Transition Metal Catalyzed Preparation of Grignard Compounds
4612 Borislav Bogdanovi , Manfred Schwickardi
4612- Total Synthesis of Lankacyclinol
4615 David R. Williams, Guillermo S. Cortez, Stéphane L. Bogen, Christian M.
Rojas
4615- Phenylaziridine as a Masked 1,3 Dipole in Reactions with
4617 Nonactivated Alkenes
Ioana Ungureanu, Philippe Klotz, André Mann
ANGEWANDTE
CHEMIE
2001
Volume 40, Issue 1, 2001
1
Cover Picture
Dieter Seebach, Albert K. Beck, Alexander Heckel
Review
4073
Asymmetric Catalysis by Architectural and Functional Molecular
Engineering: Practical Chemo- and Stereoselective Hydrogenation of
Ketones
Ryoji Noyori, Takeshi Ohkuma
7491
Dendritic Encapsulation of Function: Applying Nature's Site Isolation
Principle from Biomimetics to Materials Science
Stefan Hecht, Jean M. J. Fréchet
92138
TADDOLs, Their Derivatives, and TADDOL Analogues: Versatile
Chiral Auxiliaries
Dieter Seebach, Albert K. Beck, Alexander Heckel
Essay
139- Angewandte Chemie in Light of the Science Citation Index
143 Werner Marx
Highlight
145- Metal-Assisted Cleavage of a C-C Double Bond: Simple and
147 Reversible
Helmut Werner, Elke Bleuel
147- NMR Quantum Computing
149 Steffen J. Glaser
Communication
151- Synthesis, Structure, and Preliminary Magnetic Studies of a Ni24
154 Wheel
Angela L. Dearden, Simon Parsons, Richard E. P. Winpenny
154- Off-the-Shelf Colorimetric Anion Sensors
157 Hidekazu Miyaji, Jonathan L. Sessler
157- Resolution and Kinetic Stability of a Chiral Supramolecular
160 Assembly Made of Labile Components
Andreas J. Terpin, Marco Ziegler, Darren W. Johnson, Kenneth N. Raymond
160- Catalytic Asymmetric Friedel-Crafts Alkylation of , -Unsaturated -
163
Ketoesters: Enantioselective Addition of Aromatic C-H Bonds to
Alkenes
Kim B. Jensen, Jacob Thorhauge, Rita G. Hazell, Karl Anker Jørgensen
165- Nonpeptidic v 3 Integrin Antagonist Libraries: On-Bead Screening
169 and Mass Spectrometric Identification without Tagging
Christoph Gibson, Gábor A. G. Sulyok, Diane Hahn, Simon L. Goodman, Günter
Hölzemann, Horst Kessler
169- The First Synthetic Application of a Monooxygenase Employing
171 Indirect Electrochemical NADH Regeneration
Frank Hollmann, Andreas Schmid, Eberhard Steckhan
172- Patterning Solid-Supported Lipid Bilayer Membranes by
174 Lithographic Polymerization of a Diacetylene Lipid
Kenichi Morigaki, Tobias Baumgart, Andreas Offenhäusser, Wolfgang Knoll
174- Synthesis of 1,4-Diazidobuta-1,3-dienes by Electrocyclic Ring
177 Opening: Precursors for Bi-2H-azirin-2-yls and Their Valence
Isomerization to Diazabenzenes
Klaus Banert, Frank Köhler
177- Highly Enantioselective Isomerization of 4,7-Dihydro-1,3-dioxepins
179 Catalyzed by Me-DuPHOS-Modified Dihalogenonickel Complexes
and Determination of the Absolute Configuration of the
Isomerization Products
Herbert Frauenrath, Dirk Brethauer, Stefan Reim, Martin Maurer, Gerhard Raabe
180- Tetracyclopropylmethane: A Unique Hydrocarbon with S4 Symmetry
183 Sergei I. Kozhushkov, Rafael R. Kostikov, Alexander P. Molchanov, Roland
Boese, Jordi Benet-Buchholz, Peter R. Schreiner, Christopher Rinderspacher, Ion
Ghiviriga, Armin de Meijere
183- Cyclopentadienyl-Free Calcium Alkyls with Heteroelement186 Substituted Anionic Phosphane Ligands: Synthesis and Structure of
a Trialkyl Calcate(ii) and of an Organocalcium Heterocubane
Volker Knapp, Gerhard Müller
186- The Unusual Photochemistry of Dendrimers with an Anthracene
188 Core
Derong Cao, Herbert Meier
189- A Silyl Substituent Can Dictate a Concerted Electrocyclic Pathway:
190 Inward Torquoselectivity in the Ring Opening of 3-Silyl-1cyclobutene
Masahiro Murakami, Yasufumi Miyamoto, Yoshihiko Ito
191- The Spongistatins: Architecturally Complex Natural Products - Part
195 One: A Formal Synthesis of (+)-Spongistatin 1 by Construction of an
Advanced ABCD Fragment
Amos B. Smith III, Victoria A. Doughty, Qiyan Lin, Linghang Zhuang, Mark D.
McBriar, Armen M. Boldi, William H. Moser, Noriaki Murase, Kiyoshi
Nakayama, Masao Sobukawa
196- The Spongistatins: Architecturally Complex Natural Products - Part
199 Two: Synthesis of the C(29-51) Subunit, Fragment Assembly, and
Final Elaboration to (+)-Spongistatin 2
Amos B. Smith III, Qiyan Lin, Victoria A. Doughty, Linghang Zhuang, Mark D.
McBriar, Jeffrey K. Kerns, Christopher S. Brook, Noriaki Murase, Kiyoshi
Nakayama
199- A Chemical Model of Homeostasis
202 Helmut H. Zepik, Eveline Blöchliger, Pier Luigi Luisi
202- Mechanistic Studies of Periodinane-Mediated Reactions of Anilides
206 and Related Systems
K. C. Nicolaou, Phil S. Baran, Remo Kranich, Yong-Li Zhong, Kazuyuki Sugita,
Ning Zou
207- New Synthetic Technology for the Construction of N-Containing
210 Quinones and Derivatives Thereof: Total Synthesis of
Epoxyquinomycin B
K. C. Nicolaou, Kazuyuki Sugita, Phil S. Baran, Yong-Li Zhong
210- Structure and Base Catalysis of Supercritical Water in the
213 Noncatalytic Benzaldehyde Disproportionation Using Water at High
Temperatures and Pressures
Yutaka Ikushima, Kiyotaka Hatakeda, Osamu Sato, Toshirou Yokoyama,
Masahiko Arai
213- Isolation of Dinuclear ( -Silylene)(silyl)nickel Complexes and Si-Si
216 Bond Formation on a Dinuclear Nickel Framework
Shigeru Shimada, Maddali L. N. Rao, Teruyuki Hayashi, Masato Tanaka
216- A Mass Spectrometric Labeling Strategy for High-Throughput
219 Reaction Evaluation and Optimization: Exploring C-H Activation
Jason W. Szewczyk, Rebecca L. Zuckerman, Robert G. Bergman, Jonathan A.
Ellman
220- Reversible S-S Bond Breaking and Bond Formation in Disulfide222 Containing Dinuclear Complexes of MnI
Javier Ruiz, Mario Ceroni, Oscar V. Quinzani, Víctor Riera, Oscar E. Piro
222- Efficient Catalytic Alkane Nitration with NO2 under Air Assisted by N224 Hydroxyphthalimide
Satoshi Sakaguchi, Yoshiki Nishiwaki, Takaaki Kitamura, Yasutaka Ishii
224- Immobilization of Redox-Active Ligands on an Electrode: The
227 Dendrimer Route
Franck Le Derf, Eric Levillain, Gaëlle Trippé, Alain Gorgues, Marc Sallé, Rosa-
María Sebastían, Anne-Marie Caminade, Jean-Pierre Majoral
228- A Rare Phosphane Coordination Mode: A Symmetrically 2-Bridging
231 Phosphole in a Dinuclear Palladium(i) Complex
Mathieu Sauthier, Boris Le Guennic, Valérie Deborde, Loïc Toupet, JeanFrançois Halet, Régis Réau
231- Asymmetric Total Synthesis of Rhizoxin D
234 Gary E. Keck, Carrie A. Wager, Travis T. Wager, Kenneth A. Savin, Jonathan A.
Covel, Mark D. McLaws, Dhileep Krishnamurthy, Victor J. Cee
234- Kinetic Resolution of Amines by a Nonenzymatic Acylation Catalyst
236 Shigeru Arai, Stéphane Bellemin-Laponnaz, Gregory C. Fu
236- High-Nuclearity Chromium-Nickel-Cyanide Clusters: An Open
239 Cr8Ni5(CN)24 Cage and a C3-Symmetric Cr10Ni9(CN)42 Cluster
Incorporating Three Forms of Cyanonickelate
Jennifer J. Sokol, Matthew P. Shores, Jeffrey R. Long
239- Chelate Formation around a Hexarhenium Cluster Core by the
242 Diphosphane Ligand Ph2P(CH2)6PPh2
Zhong-Ning Chen, Takashi Yoshimura, Masaaki Abe, Yoichi Sasaki, Shoji
Ishizaka, Haeng-Boo Kim, Noboru Kitamura
242- Coordinatively Unsaturated Metal Centers as Building Blocks for
244 High Coordination Number Metallomesogens
Koen Binnemans, Katleen Lodewyckx
244- Singly and Doubly Oxidized Phthalocyanine (pc) Rings:
246 [Cu(pc)(ReO4)] and [Cu(pc)(ReO4)2]
Anna S. Gardberg, Peter E. Doan, Brian M. Hoffman, James A. Ibers
247- Highly Active Metathesis Catalysts Generated In Situ from
249 Inexpensive and Air-Stable Precursors
Janis Louie, Robert H. Grubbs
249- Highly Enantioselective Palladium-Catalyzed Ene-Type Cyclization of
253 a 1,6-Enyne
Manabu Hatano, Masahiro Terada, Koichi Mikami
Volume 40, Issue 2, 2001
265
Cover Picture
Chun-Ru Wang, Tsutomu Kai, Testuo Tomiyama, Takuya Yoshida, Yuji
Kobayashi, Eiji Nishibori, Masaki Takata, Makoto Sakata, Hisanori Shinohara
Review
284- Combinatorial and Evolution-Based Methods in the Creation of
310 Enantioselective Catalysts
Manfred T. Reetz
312- Combinatorial Heterogeneous Catalysis - A New Path in an Old Field
329 Selim Senkan
Essay
331- Wilhelm Schlenk: The Man Behind the Flask
337 Thomas T. Tidwell
Highlight
339- Diversity-Based Organic Synthesis in the Era of Genomics and
346 Proteomics
Prabhat Arya, Doug T. H. Chou, Myung-Gi Baek
346- Chemically Modified Amino Acids in Copper Proteins That Bind or
349 Activate Dioxygen
Malcolm A. Halcrow
Communication
351- The Key to Solving the Protein-Folding Problem Lies in an Accurate
355 Description of the Denatured State
Wilfred F. van Gunsteren, Roland Bürgi, Christine Peter, Xavier Daura
355- Electronic Insight into an Antithrombotic Agent by High-Resolution
359 X-Ray Crystallography
Ralf Flaig, Tibor Koritsánszky, Rainer Soyka, Ludger Häming, Peter Luger
359- Polyol-Mediated Preparation of Nanoscale Oxide Particles
362 Claus Feldmann, Hans-Otto Jungk
362- Counter-Rotating Ring Currents in Coronene and Corannulene
366 Erich Steiner, Patrick W. Fowler, Leonardus W. Jenneskens
366- Towards the Development of Antitumor Vaccines: A Synthetic
369 Conjugate of a Tumor-Associated MUC1 Glycopeptide Antigen and a
Tetanus Toxin Epitope
Stefanie Keil, Christine Claus, Wolfgang Dippold, Horst Kunz
369- Synthesis and Membrane-Binding Properties of a Characteristic
373 Lipopeptide from the Membrane-Anchoring Domain of Influenza
Virus A Hemagglutinin
Frank Eisele, Jürgen Kuhlmann, Herbert Waldmann
373- First Use of a Mineral Liquid Crystal for Measurement of Residual
376 Dipolar Couplings of a Nonlabeled Biomolecule
Hervé Desvaux, Jean-Christophe P. Gabriel, Patrick Berthault, Franck Camerel
376- Novel Approach to Mixed Group 15/16 Element Ligands - Formation
378 of Unusual Trichalcogenophosphonato Ligands in Mixed Fe/Cr
Clusters
Manfred Scheer, Shubhangi B. Umbarkar, Saurav Chatterjee, Rajiv Trivedi,
Pradeep Mathur
378- About the Chemistry of Phosphorus Suboxides
381 Bernd Engels, Anna R. Soares Valentim, Sigrid D. Peyerimhoff
381- Alkylating Polymers: Resin-Released Carbenium Ions as Versatile
385 Reactive Intermediates in Polymer-Assisted Solution-Phase
Synthesis
Jörg Rademann, Joachim Smerdka, Günther Jung, Philipp Grosche, Dietmar
Schmid
385- Molecular Switching in the Near Infrared (NIR) with a Functionalized
387 Boron-Dipyrromethene Dye
Knut Rurack, Matthias Kollmannsberger, Jörg Daub
387- An Efficient Cobalt(i) Catalyst System for the Selective 1,4389 Hydrovinylation of 1,3-Dienes
Gerhard Hilt, François-Xavier du Mesnil, Steffen Lüers
389- Subnanomolar Inhibitors from Computer Screening: A Model Study
393 Using Human Carbonic Anhydrase II
Sven Grüneberg, Bernd Wendt, Gerhard Klebe
393- Thioformaldehyde S-sulfide (Thiosulfine)
396 Grzegorz Mlosto , Jaroslaw Roma ski, Hans Peter Reisenauer, Günther Maier
397- A Scandium Carbide Endohedral Metallofullerene: (Sc2C2)@C84
399 Chun-Ru Wang, Tsutomu Kai, Testuo Tomiyama, Takuya Yoshida, Yuji
Kobayashi, Eiji Nishibori, Masaki Takata, Makoto Sakata, Hisanori Shinohara
399- A Two-Dimensional Polyrotaxane with Large Cavities and Channels:
402 A Novel Approach to Metal-Organic Open-Frameworks by Using
Supramolecular Building Blocks
Eunsung Lee, Jaheon Kim, Jungseok Heo, Dongmok Whang, Kimoon Kim
402- Design of a Molecular Beacon DNA Probe with Two Fluorophores
405 Peng Zhang, Terry Beck, Weihong Tan
405- An Exceptionally Stable Ti Superoxide Radical Ion: A Novel
408 Heterogeneous Catalyst for the Direct Conversion of Aromatic
Primary Amines to Nitro Compounds
Gajanan K. Dewkar, Milind D. Nikalje, Iliyas Sayyed Ali, Abhimanyu S.
Paraskar, H. S. Jagtap, A. Sudalai
408- Parallel Synthesis of ZSM-5 Zeolite Films from Clear Organic-Free
411 Solutions
Re Lai, Beom Seok Kang, George R. Gavalas
411- Bowl-Shaped Tris(2,6-diphenylbenzyl)tin Hydride: A Unique
414 Reducing Agent for Radical and Ionic Chemistry
Kouji Sasaki, Yuichiro Kondo, Keiji Maruoka
414- Chemoselective Iterative Dehydrative Glycosylation
417 Hien M. Nguyen, Jennifer L. Poole, David Y. Gin
417- -Mannosynthase: Synthesis of -Mannosides with a Mutant 420 Mannosidase
Oyekanmi Nashiru, David L. Zechel, Dominik Stoll, Taraneh Mohammadzadeh,
R. Antony J. Warren, Stephen G. Withers
420- 6-Aminofulvene-1-aldimine: A Model Molecule for the Study of
423 Intramolecular Hydrogen Bonds
Rosa María Claramunt, Dionísia Sanz, Sergio Hugo Alarcón, Marta Pérez
Torralba, José Elguero, Concepción Foces-Foces, Mariusz Pietrzak, Uwe Langer,
Hans-Heinrich Limbach
423- Identification and Isolation of a Receptor for N-Methyl
428 Alkylammonium Salts: Molecular Amplification in a Pseudo-peptide
Dynamic Combinatorial Library
Graham R. L. Cousins, Ricardo L. E. Furlan, Yiu-Fai Ng, James E. Redman,
Jeremy K. M. Sanders
428- Synthesis of a Conjugated Macromolecular Initiator for Nitroxide430 Mediated Free Radical Polymerization
Ulf Stalmach, Bert de Boer, Alice D. Post, Paul F. van Hutten, Georges
Hadziioannou
431- X-Ray Photoelectron Spectroscopy of Porphycenes: Charge
434 Asymmetry Across Low-Barrier Hydrogen Bonds
Abhik Ghosh, John Moulder, Martin Bröring, Emanuel Vogel
434- Cyano-Bridged 4f-3d Coordination Polymers with a Unique Two437 Dimensional Topological Architecture and Unusual Magnetic
Behavior
Bao-Qing Ma, Song Gao, Gang Su, Guang-Xian Xu
437- Immobilization of Homogeneous Palladium(ii) Complex Catalysts on
440 Novel Polysiloxanes with Controllable Solubility: Important
Implications for the Study of Heterogeneous Catalysis on Silica
Surfaces
Yaw-Shyan Fu, Shuchun J. Yu
440- Catalytic Enantioselective Protonation of Lithium Ester Enolates
442 Generated by Conjugate Addition of Arylthiolate to Enoates
Katsumi Nishimura, Masashi Ono, Yasuo Nagaoka, Kiyoshi Tomioka
442- Synthesis of Nanophase Iron Oxide in Lumazine Synthase Capsids
445 Wayne Shenton, Stephen Mann, Helmut Cölfen, Adelbert Bacher, Markus
Fischer
446- -Cyclodextrin-Assisted Intervalence Charge Transfer in Mixed448 Valent [2]Rotaxane Complexes Having Metal Centers Linked by an
Interrupted -Electron System
Atindra D. Shukla, H. C. Bajaj, Amitava Das
448- Synthesis and Self-Assembly of Monodisperse Indium Nanoparticles
451 Prepared from the Organometallic Precursor [In( 5-C5H5)]
Katerina Soulantica, André Maisonnat, Marie-Claire Fromen, Marie-José
Casanove, Pierre Lecante, Bruno Chaudret
451- Induction of a Preferred Twist in a Biphenyl Core by Stereogenic
454 Centers: A Novel Approach to the Absolute Configuration of 1,2- and
1,3-Diols
Stefano Superchi, Daniele Casarini, Alessandro Laurita, Alfonso Bavoso, Carlo
Rosini
455- Fullerene Anions: Unusual Charge Distribution in C706457 Tamar Sternfeld, Roy E. Hoffman, Ivan Aprahamian, Mordecai Rabinovitz
457- An Artificial Ion Channel Formed by a Macrocyclic Resorcin[4]arene
459 with Amphiphilic Cholic Acid Ether Groups
Naomi Yoshino, Akiharu Satake, Yoshiaki Kobuke