MATERIAL SAFETY DATA SHEET
Lithium Polymer Rechargeable Battery
Model:
643463AP-1500mAh-2S
Prepared by
Approved by
Jianyong Li
Wangmei Zhang
Date: Dec.
07 ,2012
Date:
Dec. 07,2012
Page 1 of 9
The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation.
SPRINGPOWER TECHOLOGY SHENZHEN CO.,LTD. makes no warranty, expressed or implied, with respect to this information and
disclaims all liabilities from reliance on it
--- File No./Rev.: SP-MSDS-036/E00
Material Safety Data Sheet
Section 1-SCeh
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Product Identification
SP Lithium-Ion Polymer battery
Norminal Voltage
:3.7 V
Norminal Capacity
:3000mAh
Equivalent Lithium content :11.1Wh
Testing Period
: Dec. 03,2012
To
Dec. 06,2012
Manufacturer
SPRINGPOWER TECHOLOGY SHENZHEN CO.,LTD
Chaoshun Industrial Zone, Renmin Road, Fumin, Guanlan, Baoan, Shenzhen, Guangdong, China
Postcode
:518110
Telephone
:+86-755- 61862699-818
Fax
:+86-755-29522241
E-mail
:jyli@highpowertech.com
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Chemical Composition
Lithium Cobalt Oxide
Graphite powder
Electrolyte
Molecular Formula Weight%
35~38%
LiCoO2
C
LiPF6 C3H4O3
C4H6O3 C3H10O3
CAS No
OSHA(PEL)
ACGIH(TLV)
12190-79-3
N/A
N/A
23~25%
7782-42-5
N/A
N/A
12~15%
21324-40-3
N/A
N/A
Polyethylene
(C2H4)n
0.5~1%
9002-88-4
N/A
N/A
Cu
Cu
5~10%
7440-50-8
N/A
N/A
Nickel
Nickel
2~3%
7440-02-0
N/A
N/A
Polyvinylidene fluoride
(CH2CF2)n
0.5~2%
24937-79-9
N/A
N/A
Polypropylene
(C3H6)n
2~5%
9003-07-0
N/A
N/A
Aluminum foil
Al
7~10%
7429-90-5
N/A
N/A
Silicon
Si
1~2%
7440-21-3
N/A
N/A
Epoxy Resin
EP
1.5~2%
38891-59-7
N/A
N/A
1.5~2%
65997-17-3
N/A
N/A
Fibre glass
PVC
(C2H3Cl)x
0.2~0.5%
9002-86-2
N/A
N/A
Gold
Au
0.2~0.5%
7440-57-5
N/A
N/A
Sn
Sn
0.05~0.1%
7440-31-5
N/A
N/A
Page 2 of 9
The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation.
SPRINGPOWER TECHOLOGY SHENZHEN CO.,LTD. makes no warranty, expressed or implied, with respect to this information and
disclaims all liabilities from reliance on it
--- File No./Rev.: SP-MSDS-036/E00
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Preparation
hazards and
classification
Not dangerous with normal use. Do not dismantle, open or shred Li-ion Battery.
Exposure to the ingredients contained within or their ingredients products could be harmful.
Appearance,
Color, and
Odor
Solid object with no odor, no color.
Primary
Route(s) of
Exposure
These chemicals are contained in a sealed stainless steel enclosure. Risk of exposure occurs
only if the cell is mechanically, thermally or electrically abused to the point of
compromising the enclosure. If this occurs, exposure to the electrolyte solution contained
within can occur by Inhalation, Ingestion, Eye contact and Skin contact.
Potential
Health
Effects:
ACUTE (short term): see Section 8 for exposure controls In the event that this battery has
been ruptured, the electrolyte solution contained within the battery would be corrosive and
can cause burns.
Inhalation: Inhalation of materials from a sealed battery is not an expected route of
exposure. Vapors or mists from a ruptured battery may cause respiratory irritation.
Ingestion: Swallowing of materials from a sealed battery is not an expected route of
exposure. Swallowing the contents of an open battery can cause serious chemical burns of
mouth, esophagus, and gastrointestinal tract.
Skin: Contact between the battery and skin will not cause any harm. Skin contact with
contents of an open battery can cause severe irritation or burns to the skin.
Eye: Contact between the battery and the eye will not cause any harm. Eye contact with
contents of an open battery can cause severe irritation or burns to the eye.
CHRONIC (long term): see Section 11 for additional toxicological data
Medical
Conditions
Aggravated
by
Exposure
Not applicable
Reported as
carcinogen
Not applicable
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Meeaassuurreess
Inhalation
If contents of an opened battery are inhaled, remove source of contamination or move victim
to fresh air. Obtain medical advice.
Skin contact
If skin contact with contents of an open battery occurs, as quickly as possible remove
contaminated clothing, shoes and leather goods. Immediately flush with lukewarm, gently
flowing water for at least 30 minutes. If irritation or pain persists, seek medical attention.
Page 3 of 9
The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation.
SPRINGPOWER TECHOLOGY SHENZHEN CO.,LTD. makes no warranty, expressed or implied, with respect to this information and
disclaims all liabilities from reliance on it
--- File No./Rev.: SP-MSDS-036/E00
Completely decontaminate clothing, shoes and leather goods before reuse or discard.
Eye contact
If eye contact with contents of an open battery occurs, immediately flush the contaminated
eye(s) with lukewarm, gently flowing water for at least 30 minutes while holding the eyelids
open. Neutral saline solution may be used as soon as it is available. If necessary, continue
flushing during transport to emergency care facility. Take care not to rinse contaminated
water into the unaffected eye or onto face. Quickly transport victim to an emergency care
facility.
Ingestion
If ingestion of contents of an open battery occurs, never give anything by mouth if victim is
rapidly losing consciousness, or is unconscious or convulsing. Have victim rinse mouth
thoroughly with water. DO NOT INDUCE VOMITING. Have victim drink 60 to 240 mL
(2-8 oz.) of water. If vomiting occurs naturally, have victim lean forward to reduce risk of
aspiration. Have victim rinse mouth with water again. Quickly transport victim to an
emergency care facility.
Section 5-Fire Fighting Measures
Flammable
Properties
In the event that this battery has been ruptured, the electrolyte solution contain within the
battery would be flammable. Like any sealed container, battery cells may rupture when
exposed to excessive heat; this could result in the release of flammable or corrosive
materials.
Suitable
extinguishing
Media
Use extinguishing media suitable for the materials that are burning.
Unsuitable
extinguishing
Media
Not available
Explosion
Data
Sensitivity to Mechanical Impact: This may result in rupture in extreme cases
Sensitivity to Static Discharge: Not Applicable
Specific
Hazards
arising from
the chemical
Fires involving Li-ion Battery can be controlled with water. When water is used, however,
hydrogen gas may evolve. In a confined space, hydrogen gas can form an explosive mixture.
In this situation, smothering agents are recommended to extinguish the fire
Protective
Equipment
and
precautions
for firefighters
As for any fire, evacuate the area and fight the fire from a safe distance. Wear a
pressure-demand, self-contained breathing apparatus and full protective gear.
Fight fire from a protected location or a safe distance. Use NIOSH/MSHA approved
full-face self-contained breathing apparatus(SCBA) with full protective gear.
NFPA
Health: 0 Flammability: 0 Instability: 0
Page 4 of 9
The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation.
SPRINGPOWER TECHOLOGY SHENZHEN CO.,LTD. makes no warranty, expressed or implied, with respect to this information and
disclaims all liabilities from reliance on it
--- File No./Rev.: SP-MSDS-036/E00
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Personal Precautions, protective equipment, and
emergency procedures
Restrict access to area until completion of
clean-up. Do not touch t
he spilled material. Wear
adequate personal protective equipment as
indicated in Section 8.
Environmental Precautions
Prevent material from contaminating soil and
from entering sewers or waterways.
Methods and materials for Containment
Stop the leak if safe to do so. Contain the spilled
liquid with dry sand or earth. Clean up spills
immediately.
Methods and materials for cleaning up
Absorb spilled material with an inert absorbent (dry
sand or earth). Scoop contaminated absorbent into an
acceptable waste container.
Collect all contaminated absorbent and dispose of
according to directions in Section 13. Scrub the area
with detergent and water; collect all contaminated
wash water for proper disposal.
Section 7-Handling and Storage
Handling
Don’t handling Li-ion Battery with metalwork. Do not
open, dissemble, crush or burn battery.
Ensure good ventilation/ exhaustion at the workplace.
Prevent formation of dust. Information about
protection against explosions and fires: Keep ignition
sources away- Do not smoke.
Storage
If the Li-ion Battery are subject to storage for such a
long term as more than 3 months, it is recommended
to recharge the Li-ion Battery periodically.
3 months: -10 ℃ ~+40 ℃ , 45 to 85%RH And
recommended at 0℃~+35℃ for long period storage.
The capacity recovery rate in the delivery state (50%
capacity of fully charged) after storage is assumed to
be 80% or more. The voltage for a long time storage
shall be 3.7V~4.2V range.
Page 5 of 9
The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation.
SPRINGPOWER TECHOLOGY SHENZHEN CO.,LTD. makes no warranty, expressed or implied, with respect to this information and
disclaims all liabilities from reliance on it
--- File No./Rev.: SP-MSDS-036/E00
Do not storage Li-ion Battery haphazardly in a box or
drawer where they may short-circuit each other or be
short-circuited by other metal objects.
Keep out of reach of children.
Do not expose Li-ion Battery to heat or fire.
Avoid storage in direct sunlight.
Do not store together with oxidizing and acidic
materials.
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Engineering Controls
Use local exhaust ventilation or other engineering
controls to control sources of dust, mist, fumes and
vapor. Keep away from heat and open flame. Store in
a cool, dry place.
Personal Protective Equipment
Respiratory Protection: Not necessary under
normal conditions.
Skin and body Protection: Not necessary under
normal conditions, Wear neoprene or nitrile rubber
gloves if handling an open or leaking battery.
Hand protection: Wear neoprene or natural rubber
material gloves if handling an open or leaking
battery.
Eye Protection: Not necessary under normal
conditions, Wear safety glasses if handling an open or
leaking battery.
Other Protective Equipment
Have a safety shower and eye wash fountain readily
available in the immediate work area.
Hygiene Measures
Do not eat, drink, or smoke in work area.
Maintain good housekeeping.
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Physical
State
Form: Solid
Color: White
Odour: Monotony
Change in condition:
Page 6 of 9
The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation.
SPRINGPOWER TECHOLOGY SHENZHEN CO.,LTD. makes no warranty, expressed or implied, with respect to this information and
disclaims all liabilities from reliance on it
--- File No./Rev.: SP-MSDS-036/E00
pH, with indication of the concentration
Not applicable
Melting point/freezing point
Not available.
Boiling Point, initial boiling point and Boiling
range:
Not available.
Flash Point
Not available.
Upper/lower flammability or explosive limits
Not available.
Vapor Pressure:
Not applicable
Vapor Density: (Air = 1)
Not applicable
Density/relative desity
Not available.
Solubility in Water:
Insoluble
n-octanol/water partition coefficient
Not available.
Auto-ignition temperature
130℃
Decomposition temperature
Not available.
Odout threshold
Not available.
Evaporation rate
Not available.
Flammability (soil, gas)
Not available.
Viscosity
Not applicable
SSeeccttioionn1100--SSttaabbiliiltityyaannddRReeaaccttivivitityy
Stability
The product is stable under normal conditions.
Conditions to Avoid (e.g. static discharge, shockor
vibration)
Do not subject Li-ion Batteryto mechanical shock.
Vibration encoutered during transportation does not
cause leakage, fire or explosion.
Do not disassemble, crush, short or install with
incorrect polarity. Avoid mechanical or electrical
abuse.
Incompatible Materials
Not Available
Hazardous Decomposition Products
This material may release toxic fumes if burned
or exposed to fire
Possibility of Hazardous Reaction
Not Available
Page 7 of 9
The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation.
SPRINGPOWER TECHOLOGY SHENZHEN CO.,LTD. makes no warranty, expressed or implied, with respect to this information and
disclaims all liabilities from reliance on it
--- File No./Rev.: SP-MSDS-036/E00
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Irritation
Risk of irritation occurs only if the cell is
mechanically, thermally or electrically abused to the
point of compromising the enclosure. If this occurs,
irritation to the skin, eyes and respiratory tract may
occur.
Sensitization
Not Available
Neurological Effects
Not Available
Teratoaenicitv
Not Available
Reproductive Toxicity
Not Available
Mutagenicity (Genetic Effects)
Not Available
Toxicologically Synergistic Materials
Not Available
Section 12-Ecological Information
General note:
Water hazard class 1(Self-assessment): slightly
hazardous for water.
Do not allow undiluted product or large quantities
of it to reach ground water, water course or
sewage system.
Anticipated behavior of a chemical product in
environment/possible environmental
impace/ecotoxicity
Not Available
Mobility in soil
Not Available
Persistence and Degradability
Not Available
Bioaccumulation potential
Not Available
Other Adverse Effects
Not Available
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Product disposal recommendation: Observe local, state and federal laws and regulations. Packaging disposal
recommendation: Be aware discarded batteries may cause fire, tape the battery terminals to insulate them. Don’t
disassembly the battery. Completely discharge containers(no tear drops, no powder rest, scraped arefully). Containers
may be recycled or re-used. Observe local, state and federal laws and regulations.
Page 8 of 9
The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation.
SPRINGPOWER TECHOLOGY SHENZHEN CO.,LTD. makes no warranty, expressed or implied, with respect to this information and
disclaims all liabilities from reliance on it
--- File No./Rev.: SP-MSDS-036/E00
SeSceticotn
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The battery models listed have aggregate equivalent lithium content is not more than 100Wh. And shipment contains
no item listed under IATA DGR Special Provision A154 and meets all requirements under UN Manual of Tests and
Criteria Part III, subsection 38.3.
No
ITEMS
RESULT
1
Altitude simulation
Pass
2
Thermal test
Pass
3
Vibration
Pass
4
Shock
Pass
5
External short circuit
Pass
6
Impact
Pass
7
Overcharge
Pass
REMARKS
Test 1 to 5 must be conducted in sequence on the same
cell or battery
Only battery do need this test item
The product is not classified as dangerous Goods according to the current edition of IATA Dangerous Goods
Regulations. And not regulated by IATA DGR. This product fully conforms to IATA Shipping PI 965, section Ⅱ. Do
not damage or mishandle this package. If package is damaged, batteries must be quarantined, inspected, and repacked.
For emergency information, call: +86-755-61862699.
The Li-ion Battery according to NEW PACKING INSTRUCTION 965~967 of IATA DGR 53 rd Edition for
transportation.
Section 15-Regulatory Information
Section 15-Regulatory Information
OSHA hazard communication standard (29 CFR 1910.1200)
Hazardous
V
Non-hazardous
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This information is not effective to all the batteries manufactured by SPRINGPOWER. This information comes
from reliable sources, but no warranty is made to the completeness and accuracy of information contained.
SPRINGPOWER doesn’t assume responsibility for any damage or loss because of misuse of batteries. Users should
grasp the correct use method and be responsible for the use of batteries.
Page 9 of 9
The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation.
SPRINGPOWER TECHOLOGY SHENZHEN CO.,LTD. makes no warranty, expressed or implied, with respect to this information and
disclaims all liabilities from reliance on it
--- File No./Rev.: SP-MSDS-036/E00