MATERIAL SAFETY DATA SHEET

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

CHAMPION® MSDS 100 SERIES LUBRICANTS

Synonyms:

4030 CHAMPION® SUPER GRADE SAE 10W 40

4033 CHAMPION® SUPER GRADE HD SAE 30

4036 CHAMPION® PREMIUM HD SAE 10

4037 CHAMPION® PREMIUM HD SAE 20W 20

4038 CHAMPION® PREMIUM HD SAE 30

4039 CHAMPION® PREMIUM HD SAE 40

4040 CHAMPION® PREMIUM HD SAE 50

4160 CHAMPION® ALL FLEET T TBN 11 SAE 10W 30

4166 CHAMPION® HTSYNTHETIC FLEET SAE 15W 40

4173 CHAMPION® HTSYNTHETIC FLEET SAE 5W 40

4198 CHAMPION® ALL FLEET T TBN 13.2 SAE 30

4222 CHAMPION® SYNTHETIC BLEND SAE 5W30

4223 CHAMPION® MULT-VISC HEAT TRANSFER FLUID

4228 CHAMPION® SYNTHETIC BLEND SAE 10W30

4229 CHAMPION® SYNTHETIC BLEND SAE 5W20 4092 CHAMPION® 4 CYCLE LAWNMOWER SAE 30

4110 CHAMPION® 4-CYC MOTORCYCLE SAE 20W 50 4230 CHAMPION® SYNCLEAN 7500 SAE 5W20

4111 CHAMPION® RACING XP SAE 20W 50

4152 CHAMPION® PREMIUM HD SAE 15W 40

4158 CHAMPION® ALL FLEET T TBN 11 SAE 15W 40

4231 CHAMPION® SYNCLEAN 7500 SAE 5W30

4232 CHAMPION® SYNCLEAN 7500 SAE 10W30

4287 CHAMPION® SUPER GRADE TORQUE FLUID

Company Identification

Champion Brands, L.L.C., 1001 Golden Drive, Clinton, MO 64735

PHONE: 800-821-5693 WEBSITE: www.championbrands.com

CAS Registry Number Not Applicable

Synonyms

Generic/Chemical Name

Product Type

Preparation Date

None

Mixture

Petroleum Based Lubricating Oil

June 11, 2007

Transportation Emergency Response

CHEMTREC: (800) 424-9300

Product Information

Product Information and MSDS Requests: (800) 821-5693 and www.championbrands.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

COMPONENTS

Highly refined BASE OIL (C15 - C50)

Zinc dialkyldithiophosphate

ADDITIVES

CAS

NUMBER

Mixture

AMOUNT

85.85 – 99.95 %weight

68649-42-3 0.05 – 0.17 %weight

Mixture 0.00 – 14.00 %weight

The BASE OIL may be a mixture of any of the following: CAS 64741884, CAS 64741895, CAS 64741964, CAS 64741975, CAS

64742014, CAS 64742525, CAS 64742536, CAS 64742547, CAS 64742558, CAS 64742570, CAS 64742627

The ADDITIVES are a mixture of confidential ingredients permitted by 29 CFR 1910.1200 and various State Right to Know Laws. In the event of medical emergency, specific chemical information will be disclosed to a treating physician or nurse.

3. HAZARD IDENTIFICATION

IMMEDIATE HEALTH EFFECTS

Eye: Not expected to cause prolonged or significant eye irritation.

Skin: Contact with the skin is not expected to cause prolonged or significant irritation. Not expected to be harmful to internal organs if absorbed through the skin.

Ingestion: Not expected to be harmful if swallowed.

Inhalation: Not expected to be harmful if inhaled. Contains a petroleum-based mineral oil. May cause respiratory

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irritation or other pulmonary effects following prolonged or repeated inhalation of oil mist at airborne levels above the recommended mineral oil mist exposure limit. Symptoms of respiratory irritation may include coughing and difficulty breathing.

4. FIRST AID MEASURES

Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and flush eyes with water.

Skin: No specific first aid measures are required. As a precaution, remove clothing and shoes if contaminated. To remove the material from skin, use soap and water. Discard contaminated clothing and shoes or thoroughly clean before reuse.

Ingestion: No specific first aid measures are required. Do not induce vomiting. As a precaution, get medical advice.

Inhalation: No specific first aid measures are required. If exposed to excessive levels of material in the air, move the exposed person to fresh air. Get medical attention if coughing or respiratory discomfort occurs.

5. FIRE FIGHTING MEASURES

FIRE CLASSIFICATION:

OSHA Classification (29 CFR 1910.1200): Not classified by OSHA as flammable or combustible.

NFPA RATINGS: Health: 1 Flammability: 1 Reactivity: 0

FLAMMABLE PROPERTIES:

Flashpoint: 204 °C (399 °F) (Min)

Autoignition: NDA

Flammability (Explosive) Limits (% by volume in air): Lower: NA Upper: NA

EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.

PROTECTION OF FIRE FIGHTERS:

Fire Fighting Instructions: This material will burn although it is not easily ignited. For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment, including self-contained breathing apparatus.

Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds will be evolved when this material undergoes combustion. Combustion may form oxides of: Calcium, Sulfur, Phosphorus, Boron, Molybdenum,

Nitrogen, Zinc .

6. ACCIDENTAL RELEASE INFORMATION

Protective Measures: Eliminate all sources of ignition in vicinity of spilled material.

Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent further contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing precautions in

Exposure Controls/Personal Protection. Use appropriate techniques such as applying non-combustible absorbent materials or pumping. Where feasible and appropriate, remove contaminated soil. Place contaminated materials in disposable containers and dispose of in a manner consistent with applicable regulations.

Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at (800) 424-

8802 as appropriate or required.

7. HANDLING AND STORAGE

Precautionary Measures: Keep out of the reach of children.

General Handling Information: Avoid contaminating soil or releasing this material into sewage and drainage systems and bodies of water.

Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this material.

To minimize this hazard, bonding and grounding may be necessary but may not, by themselves, be sufficient. Review all operations which have the potential of generating an accumulation of electrostatic charge and/or a flammable atmosphere (including tank and container filling, splash filling, tank cleaning, sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and use appropriate mitigating procedures. For more information, refer to OSHA Standard 29 CFR 1910.106, 'Flammable and Combustible Liquids', National Fire

Protection Association (NFPA 77, 'Recommended Practice on Static Electricity', and/or the American Petroleum

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Institute (API) Recommended Practice 2003, 'Protection Against Ignitions Arising Out of Static, Lightning, and Stray

Currents'.

Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid, and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode and cause injury or death. Empty containers should be completely drained, properly closed, and promptly returned to a drum reconditioner or disposed of properly.

8. EXPOSURE CONTROL/PERSONAL PROTECTIVE EQUIPMENT

GENERAL CONSIDERATIONS:

Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user should read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances.

Special note: Do not use in breathing air apparatus or medical equipment.

ENGINEERING CONTROLS:

Use in a well-ventilated area.

PERSONAL PROTECTIVE EQUIPMENT

Eye/Face Protection: No special eye protection is normally required. Where splashing is possible, wear safety glasses with side shields as a good safety practice.

Skin Protection: No special protective clothing is normally required. Where splashing is possible, select protective clothing depending on operations conducted, physical requirements and other substances in the workplace.

Suggested materials for protective gloves include: 4H (PE/EVAL), Nitrile Rubber, Silver Shield, Viton.

Respiratory Protection: No respiratory protection is normally required.

If user operations generate an oil mist, determine if airborne concentrations are below the occupational exposure limit for mineral oil mist. If not, wear an approved respirator that provides adequate protection from the measured concentrations of this material. For air-purifying respirators use a particulate cartridge.

Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not provide adequate protection.

Occupational Exposure Limits:

Component ACGIH OSHA NIOSH Other: Percent (%) wt

Highly refined mineral oil (C15 - C50)

5mg/m3 TWA

10 mg/m3 STEL

5 mg/m3

TWA

2500 mg/m3

IDLH as Oil Mist, if Generated

5 mg/m3 NOHSC TWA

85.85 – 99.95

Zinc dialkyldithiophosphate

5 mg/m3

TWA

5 mg/m3

TWA

- - 0.05 – 0.15

NE NE NE 0.00 – 14.00 Additives PROPRIETARY NE

1%=10,000 PPM.

NE=Not Established

All components are listed on the TSCA inventory.

9. PHYSICAL AND CHEMICAL PROPERTIES

Attention: the data below are typical values and do not constitute a specification.

Color: Brown

Physical State: Liquid

Odor: Petroleum odor

pH: NA

Vapor Pressure: <0.01 mmHg @ 37.8°C (100°F)

Vapor Density (Air = 1): >1

Boiling Point: >315.6°C (600°F)

Solubility: Soluble in hydrocarbons; insoluble in water

Freezing Point: NA

Melting Point: NA

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Specific Gravity: 0.87 - 0.9 @ 15.6°C (60.1°F) / 15.6°C (60.1°F)

Viscosity: 6.6 cSt - 18.6 cSt @ 100°C (212°F) (Min)

10. STABILITY AND REACTIVITY

Chemical Stability: This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.

Incompatibility With Other Materials: May react with strong oxidizing agents, such as chlorates, nitrates, peroxides, etc.

Hazardous Decomposition Products: Hydrogen Sulfide (Temperatures >149 °F (65 °C))

Hazardous Polymerization: Hazardous polymerization will not occur.

11. TOXILOGICAL INFORMATION

IMMEDIATE HEALTH EFFECTS

Eye Irritation: The eye irritation hazard is based on evaluation of data for similar materials or product components.

Skin Irritation: The skin irritation hazard is based on evaluation of data for similar materials or product components.

Skin Sensitization: No product toxicology data available.

Acute Toxicity:

Lubricant Base Oil (Petroleum) - CAS: VARIOUS

Dermal LD50 = >2 g/kg

Oral

LC50 = No information available

LD50 = >5 g/kg

Zinc Compound(s) - CAS: 68649-42-3

Dermal LD50 = No information available

LC50 = No information available

Oral LD50 = No information available

Additives - CAS: PROPRIETARY

Dermal LD50 = No information available

LC50 = No information available

LD50 = No information available Oral

ADDITIONAL TOXICOLOGY INFORMATION:

Carcinogenicity: The petroleum base oils contained in this product have been highly refined by a variety of processes including solvent extraction, hydrotreating, and dewaxing to remove aromatics and improve performance characteristics. All of the oils meet the IP-346 criteria of less than 3 percent PAH's and therefore none are listed as a carcinogen by NTP, IARC, or OSHA.

12. ECOLOGICAL INFORMATION

ECOTOXICITY

The toxicity of this material to aquatic organisms has not been evaluated. Consequently, this material should be kept out of sewage and drainage systems and all bodies of water.

ENVIRONMENTAL FATE

This material is not expected to be readily biodegradable.

13. DISPOSAL INFORMATION

Oil collection services are available for used oil recycling or disposal. Place contaminated materials in containers and dispose of in a manner consistent with applicable regulations. Contact your sales representative or local environmental or health authorities for approved disposal or recycling methods. (See B.C. Reg. GY/92 Waste

Management Act; R.R.O. 1990, Reg. 347 General-Waste Management; C.C.SM.c. W40 The Waste Reduction and

Prevention Act; N.S. Reg. 51/95 and N.S. Reg. 179/96 for examples of Provincial legislation.)

14. TRANSPORTATION INFORMATION

The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods

Regulations, for additional description requirements (e.g., technical name) and mode-specific or quantity-specific shipping requirements.

DOT Shipping Name: NOT REGULATED AS A HAZARDOUS MATERIAL FOR TRANSPORTATION UNDER 49 CFR

DOT Hazard Class: NOT APPLICABLE

DOT Identification Number: NOT APPLICABLE

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DOT Packing Group: NOT APPLICABLE

Additional Information: NOT HAZARDOUS BY U.S. DOT. ADR/RID HAZARD CLASS NOT APPLICABLE.

IMO/IMDG Shipping Name: NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORTATION UNDER THE IMDG CODE

IMO/IMDG Hazard Class: NOT APPLICABLE

IMO/IMDG Identification Number: NOT APPLICABLE

IMO/IMDG Packing Group: NOT APPLICABLE

15. REGULATORY INFORMATION

EPCRA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: NO

2. Delayed (Chronic) Health Effects: NO

3. Fire Hazard: NO

4. Sudden Release of Pressure Hazard: NO

5. Reactivity Hazard: NO

SARA - Section 313 and 40 CFR 372:

This material contains the following chemicals subject to the reporting requirements of SARA 313 and 40 CFR 372:

Zinc Compound(s)................PROPRIETARY................0.5-1.5%

EPA (CERCLA) Reportable Quantity (in pounds):

--None Known--

CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs (in pounds):

This material contains the following chemicals subject to the reporting requirements of SARA 302 and 40 CFR 372:

-- None Known --

California Proposition 65:

Warning: This material contains the following chemicals which are known to the State of California to cause cancer, birth defects or other reproductive harm, and are subject to the requirements of California Proposition 65 (CA Health &

Safety Code Section 25249.5): Used engine oils, while not a component of this material, is on the Proposition 65 list of chemicals known to the State of

California to cause cancer.

Carcinogen Identification:

This material has not been identified as a carcinogen by NTP, IARC, or OSHA. See Section 11 for carcinogenicity information of individual components, if any. Used motor oil has been identified as a possible skin carcinogen by IARC.

TSCA:

All components are listed on the TSCA inventory.

International Regulations:

Canadian Regulations:

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations

(CPR) and the MSDS contains all the information required by the CPR.

Domestic Substances List: Listed

WHMIS Classification: Not regulated

CHEMICAL INVENTORIES:

AUSTRALIA: All the components of this material are listed on the Australian Inventory of Chemical Substances

(AICS).

CANADA: One or more components of this product are not on the Domestic Substances List (DSL). Volume tracking or notification by the Canadian Importer of Record may be required. Please contact Champion LLC Global Lubricants.

EUROPEAN UNION: All the components of this material are in compliance with the EU Seventh Amendment

Directive 92/32/EEC.

JAPAN: This material contains components that require notification before sale or importation into Japan.

KOREA: All the components of this product are on the Existing Chemicals List (ECL) in Korea.

PHILIPPINES: This material contains components that require notification before sale or importation into the

Philippines.

UNITED STATES: All of the components of this material are on the Toxic Substances Control Act (TSCA) Chemical

Inventory.

NEW JERSEY RTK CLASSIFICATION:

Under the New Jersey Right-to-Know Act L. 1983 Chapter 315 N.J.S.A. 34:5A-1 et. seq., the product is to be identified as follows: PETROLEUM OIL (Motor oil)

WHMIS CLASSIFICATION:

This product is not considered a controlled product according to the criteria of the Canadian Controlled Products

Regulations.

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16. DISCLAIMER

NFPA RATINGS:

HMIS RATINGS:

Health: 1 Flammability: 1 Reactivity: 0

Health: 1 Flammability: 1 Reactivity: 0

(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index recommendation, *-

Chronic Effect Indicator). These values are obtained using the guidelines or published evaluations prepared by the

National Fire Protection Association (NFPA) or the National Paint and Coating Association (for HMIS ratings).

REVISION STATEMENT: Revision updates many sections and the MSDS should be read in its entirety.

ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:

TLV Threshold Limit Value

STEL Short-term Exposure Limit

CHA - Champion LLC

TWA

PEL

CAS

-

-

-

Time Weighted Average

Permissible Exposure Limit

Chemical Abstract Service Number

NDA No Data Available

<= Less Than or Equal To

NA

>=

-

-

Not Applicable

Greater Than or Equal To

Prepared according to the OSHA Hazard Communication Standard (29 CFR 1910.1200) and the ANSI MSDS

Standard (Z400.1) by Champion LLC, 1001 Golden Drive, Clinton, Missouri 64735.

The information presented herein has been compiled from sources considered to be dependable and is accurate to the best knowledge of

Champion Brands, L.L.C. Champion Brands, L.L.C., makes no warranty whatsoever expressed or implied of merchantability or fitness for the particular purpose, regarding the accuracy of such data or the results to be obtained from the use thereof. Champion Brands, L.L.C., assumes no legal responsibility for use or reliance upon this data. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose.

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