SAFETY DATA SHEET Section 1. Chemical product and company identification

SAFETY DATA SHEET Section 1. Chemical product and company identification
SAFETY DATA SHEET
MANUAL BAR GLASS SANITIZER
Section 1. Chemical product and company identification
Product name
Recommended use and
restrictions
: MANUAL BAR GLASS SANITIZER
: Sanitizer.
Use only for the purpose on the product label.
Product dilution information : Up to 1 packet/3gals of water
Supplier's information
Code
Date of issue
EPA Registration No.
: Ecolab Inc. Institutional Division
370 N. Wabasha Street
St. Paul, MN 55102
1-800-352-5326
: 912065-01
: 28 Mar 2013
: 65169-1-1677
EMERGENCY HEALTH INFORMATION: 1-800-328-0026
Outside United States and Canada CALL 1-651-222-5352 (in USA)
Section 2. Hazards identification
GHS Classification
Product AS SOLD
: ACUTE TOXICITY: ORAL - Category 4
ACUTE TOXICITY: INHALATION - Category 4
SKIN CORROSION/IRRITATION - Category 1
SERIOUS EYE DAMAGE/ EYE IRRITATION Category 1
Product AT USE DILUTION
Not classified.
: Danger
:
No signal word.
GHS label elements
Signal word
Symbol
Hazard statements
: Harmful if swallowed or if inhaled.
Causes severe skin burns and eye damage.
Precautionary statements
Prevention
Response
: Wear protective gloves. Wear eye or face
protection. Wear protective clothing. Use only
outdoors or in a well-ventilated area. Avoid
breathing dust. Do not breathe dust or mist.
Mixing this product with acid or ammonia
releases chlorine gas. Do not mix with bleach
or other chlorinated products - will cause
chlorine gas. Wash hands thoroughly after
handling.
:
No known significant effects or critical
hazards.
Wash thoroughly after handling.
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28 Mar 2013
Section 2. Hazards identification
IF INHALED: Remove victim to fresh air and
keep at rest in a position comfortable for
breathing. Immediately call a POISON
CENTER or physician. IF SWALLOWED:
Immediately call a POISON CENTER or
physician. Rinse mouth. Do NOT induce
vomiting. IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse
skin with water or shower. Wash contaminated
clothing before reuse. Immediately call a
POISON CENTER or physician. IF IN EYES:
Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to
do. Continue rinsing. Immediately call a
POISON CENTER or physician.
: No other specific measures identified.
: See section 13 for waste disposal information.
Storage
Disposal
Other hazards
: Handling and/or processing of this material
may generate a dust which can cause
mechanical irritation of the eyes, skin, nose and
throat.
Get medical attention if symptoms appear.
No other specific measures identified.
See section 13 for waste disposal
information.
None known.
Section 3. Composition/information on ingredients
Substance/mixture
Product AS SOLD
: Mixture
Hazardous ingredients
Concentration Range (%)
CITRIC ACID
Trichloromelamine
benzenesulfonic acid, mono-c10-16-alkyl derivs., sodium
salts
20 - 50
18.7
5 - 20
CAS number
77-92-9
7673-09-8
68081-81-2
Product AT USE DILUTION
Within the present knowledge of the supplier, this product does not contain any hazardous ingredients in
quantities requiring reporting, in accordance with local regulations.
Section 4. First aid measures
Eye contact
:
Skin contact
:
Inhalation
:
Ingestion
:
Protection of firstaiders
:
Product AS SOLD
Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do.
Continue rinsing. Get medical attention
immediately.
Take off immediately all contaminated clothing.
Rinse skin with water or shower. Get medical
attention immediately. Wash clothing before
reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a
position comfortable for breathing. Get medical
attention immediately.
Get medical attention immediately. Rinse mouth.
Do not induce vomiting.
Product AT USE DILUTION
No known effect after eye contact. Rinse with
water for a few minutes.
No known effect after skin contact. Rinse
with water for a few minutes.
No special measures required. Treat
symptomatically.
Get medical attention if symptoms occur.
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28 Mar 2013
Section 4. First aid measures
No action shall be taken involving any personal risk or without suitable training. It may be
dangerous to the person providing aid to give mouth-to-mouth resuscitation. If ventilation is
inadequate, use respirator that will protect against dust/mist. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The
exposed person may need to be kept under medical surveillance for 48 hours.
See toxicological information (section 11)
Section 5. Fire-fighting measures
Product AS SOLD
Suitable fire extinguishing
media
Specific hazards arising
from the chemical
Hazardous thermal
decomposition products
Specific fire-fighting
methods
Special protective
equipment for fire-fighters
: Use dry chemical powder.
: No specific fire or explosion hazard.
: Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
phosphorus oxides
halogenated compounds
metal oxide/oxides
: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without
suitable training.
: Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Section 6. Accidental release measures
Personal
precautions
Environmental
precautions
Methods for
cleaning up
Product AS SOLD
: Initiate company's spill response procedures
immediately. Keep people out of area. Put on
appropriate personal protective equipment (see
section 8). Do not touch or walk through spilled
material.
: Avoid contact of spilled material and runoff with
soil and surface waterways.
: If emergency personnel are not present, contain
and collect small spillages with non-combustible
absorbent material, e.g. sand, earth or other
suitable material and place in a suitable container
for disposal. Use a water rinse for final clean-up.
Product AT USE DILUTION
Use personal protective equipment as
required.
Avoid contact of large amounts of spilled
material and runoff with soil and surface
waterways.
Use a water rinse for final clean-up.
Section 7. Handling and storage
Handling
Product AS SOLD
: Do not ingest. Do not get in eyes or on skin or
clothing. Do not breathe dust. Use only with
adequate ventilation. Mixing this product with
acid or ammonia releases chlorine gas. Do not
mix with bleach or other chlorinated products will cause chlorine gas. Wash thoroughly after
handling.
Product AT USE DILUTION
Wash thoroughly after handling.
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Section 7. Handling and storage
Storage
: Keep out of reach of children. Keep container
tightly closed.
Keep out of reach of children.
Store between the following temperatures: 0 and
30°C
Section 8. Exposure controls/personal protection
Control parameters
Ingredient name
Exposure limits
chlorine
ACGIH TLV (United States, 3/2012).
STEL: 2.9 mg/m³ 15 minutes.
STEL: 1 ppm 15 minutes.
TWA: 1.5 mg/m³ 8 hours.
TWA: 0.5 ppm 8 hours.
OSHA PEL (United States, 6/2010).
CEIL: 3 mg/m³
CEIL: 1 ppm
NIOSH REL (United States, 6/2009).
CEIL: 0.5 ppm 15 minutes.
CEIL: 1.45 mg/m³ 15 minutes.
Product AS SOLD
Appropriate
: Use only with adequate ventilation. If user
operations generate dust, fumes, gas, vapor or
engineering controls
mist, use process enclosures, local exhaust
ventilation or other engineering controls to keep
worker exposure to airborne contaminants below
any recommended or statutory limits. Provide
suitable facilities for quick drenching or flushing
of the eyes and body in case of contact or splash
hazard.
Personal protection
Eye protection
: Use chemical splash goggles. For continued or
severe exposure wear a face shield over the
goggles.
Hand protection
: Use chemical-resistant, impervious gloves.
Skin protection
Respiratory
protection
Hygiene measures
: Use synthetic apron, other protective equipment
as necessary to prevent skin contact.
: Wear appropriate respirator when ventilation is
inadequate and occupational exposure limits are
exceeded.
Product AT USE DILUTION
Good general ventilation should be sufficient
to control worker exposure to airborne
contaminants.
No protective equipment is needed under
normal use conditions.
No protective equipment is needed under
normal use conditions.
No protective equipment is needed under
normal use conditions.
A respirator is not needed under normal and
intended conditions of product use.
: Wash hands, forearms and face thoroughly after handling chemical products, before eating,
smoking and using the lavatory and at the end of the working period. Appropriate techniques
should be used to remove potentially contaminated clothing. Wash contaminated clothing
before reusing.
Section 9. Physical and chemical properties
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28 Mar 2013
Section 9. Physical and chemical properties
Physical state
Product AS SOLD
: Powder
Product AT USE DILUTION
Liquid.
Color
: White to yellowish
Colorless
Odor
pH
Flash point
: Faint odor
: 3.5 to 4.5 (1%)
: > 100°C
Faint odor
3.26 to 3.26
> 100°C
Explosion limits
Flammability (solid,
gas)
Melting point
Boiling point
Evaporation rate
(butyl acetate = 1)
Vapor pressure
: Not available.
: Not available.
Vapor density
: Not available.
: 0 (Water = 1)
Relative density
: Not available.
: >100°C (>212°F)
: Not available.
: Not available.
Solubility
: Easily soluble in the following materials: cold
water and hot water.
Partition coefficient: : Not available.
n-octanol/water
Auto-ignition
: Not available.
temperature
Decomposition
: 105°C (221°F)
temperature
Odor threshold
: Not available.
Viscosity
: Not available.
Section 10. Stability and reactivity
Product AS SOLD
Stability
Possibility of hazardous
reactions
Conditions to avoid
Materials to avoid
Hazardous decomposition
products
: The product is stable.
: Under normal conditions of storage and use, hazardous reactions will not occur.
: No specific data.
: Slightly reactive or incompatible with the following materials: alkalis. Mixing this
product with acid or ammonia releases chlorine gas. Do not mix with bleach or other
chlorinated products - will cause chlorine gas.
: Under normal conditions of storage and use, hazardous decomposition products
should not be produced.
Section 11. Toxicological information
Route of exposure
: Skin contact, Eye contact, Ingestion
Product AS SOLD
Symptoms
Eye contact
Skin contact
: Adverse symptoms may include the following:
pain
watering
redness
:
Product AT USE DILUTION
No specific data.
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28 Mar 2013
Section 11. Toxicological information
Inhalation
Ingestion
Acute toxicity
Eye contact
Skin contact
Inhalation
Ingestion
Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
: Adverse symptoms may include the following:
respiratory tract irritation
coughing
Respiratory tract irritation
: Adverse symptoms may include the following:
stomach pains
No specific data.
No specific data.
No specific data.
: Causes serious eye damage.
No known significant effects or critical
hazards.
: Causes severe burns.
No known significant effects or critical
hazards.
: Harmful if inhaled. May cause respiratory
No known significant effects or critical
irritation.
hazards.
: Harmful if swallowed. May cause burns to mouth, No known significant effects or critical
throat and stomach.
hazards.
Toxicity data
Product/ingredient name
citric acid
Result
Species
LD50 Dermal
Rat
LD50 Oral
Rat
1,3,5-triazine, n,n',n''-trichloro-2,4,6-triamino- LC50 Inhalation Dusts
Rat
and mists
LD50 Dermal
Rabbit
LD50 Oral
Rat
benzenesulfonic acid, mono-c10-16-alkyl
LD50 Dermal
Rat
derivs., sodium salts
LD50 Oral
Rat
Chronic toxicity
Carcinogenicity
: No known significant effects or critical hazards.
Mutagenicity
: No known significant effects or critical hazards.
Teratogenicity
: No known significant effects or critical hazards.
Developmental effects
Fertility effects
: No known significant effects or critical hazards.
: No known significant effects or critical hazards.
Dose
>2000 mg/kg
11700 mg/kg
0.59 mg/l
>2000 mg/kg
398 mg/kg
>2000 mg/kg
1090 mg/kg
Section 12. Ecological information
Product AS SOLD
Ecotoxicity
: This material is toxic to aquatic life.
Aquatic and terrestrial toxicity
Product/ingredient name
Result
citric acid
Acute LC50 >100 mg/l
1,3,5-triazine, n,n',n''-trichloro-2,4,6-triaminoAcute EC10 0.8 mg/l
Acute EC50 1.2 mg/l
Acute LC50 2 mg/l
benzenesulfonic acid, mono-c10-16-alkyl derivs. Acute LC50 3.2 mg/l
, sodium salts
Other adverse effects
: No known significant effects or critical hazards.
Species
Fish
Daphnia
Daphnia
Fish
Fish
Exposure
96 hours
48 hours
48 hours
96 hours
96 hours
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28 Mar 2013
Section 13. Disposal considerations
Disposal methods
Product AS SOLD
: Avoid disposal. Attempt to use product
completely in accordance with intended use.
Disposal should be in accordance with applicable
regional, national and local laws and regulations.
Product AT USE DILUTION
Diluted product can be flushed to sanitary
sewer. Discard empty container in trash.
Section 14. Transport information
Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification
provided may not reflect those exceptions and may not apply to all shipping modes or package sizes.
DOT
DOT Classification
UN3261
DOT Proper shipping name
Corrosive solid, acidic, organic, n.o.s. (Trichloromelamine)
Class
8
Packing group
III
IMO/IMDG
IMO/IMDG Classification
UN3261
IMO/IMDG Proper shipping name
CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (TRICHLOROMELAMINE)
Class
8
Packing group
III
For transport in bulk, see shipping documents for specific transportation information.
Product AT USE DILUTION
Not intended for transport.
Section 15. Regulatory information
Product AS SOLD
U.S. Federal regulations
TSCA 8(b) inventory
EPA Registration No.
: All components are listed or exempted.
: 65169-1-1677
SARA 302/304/311/312 extremely hazardous substances: No listed substance
SARA 302/304 emergency planning and notification: No listed substance
SARA 313
Form R - Reporting
requirements
California Prop. 65
Product name
CAS number
Concentration
: No listed substance
: No listed substance
Section 16. Other information
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28 Mar 2013
Section 16. Other information
Product AS SOLD
Hazardous Material
Information System (U.S.A.)
Product AT USE DILUTION
:
Health
3
Health
Flammability
0
Flammability
0
Physical hazards
0
Physical hazards
0
Flammability
0
Health
0
Instability/Reactivity
Special
Date of issue
Prepared by
0
:
National Fire Protection
Association (U.S.A.)
3
Data not
available Refer to
Product AS
SOLD
Flammability
0
Health
0
0
Instability/Reactivity
Special
: 28 Mar 2013
: Regulatory Affairs
1-800-352-5326
Notice to reader
The above information is believed to be correct with respect to the formula used to manufacture the product in
the country of origin. As data, standards, and regulations change, and conditions of use and handling are
beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR
CONTINUING ACCURACY OF THIS INFORMATION.
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