SAFETY DATA SHEET MANUAL BAR GLASS SANITIZER Section 1. Chemical product and company identification Product name Recommended use and restrictions : MANUAL BAR GLASS SANITIZER : Sanitizer. Use only for the purpose on the product label. Product dilution information : Up to 1 packet/3gals of water Supplier's information Code Date of issue EPA Registration No. : Ecolab Inc. Institutional Division 370 N. Wabasha Street St. Paul, MN 55102 1-800-352-5326 : 912065-01 : 28 Mar 2013 : 65169-1-1677 EMERGENCY HEALTH INFORMATION: 1-800-328-0026 Outside United States and Canada CALL 1-651-222-5352 (in USA) Section 2. Hazards identification GHS Classification Product AS SOLD : ACUTE TOXICITY: ORAL - Category 4 ACUTE TOXICITY: INHALATION - Category 4 SKIN CORROSION/IRRITATION - Category 1 SERIOUS EYE DAMAGE/ EYE IRRITATION Category 1 Product AT USE DILUTION Not classified. : Danger : No signal word. GHS label elements Signal word Symbol Hazard statements : Harmful if swallowed or if inhaled. Causes severe skin burns and eye damage. Precautionary statements Prevention Response : Wear protective gloves. Wear eye or face protection. Wear protective clothing. Use only outdoors or in a well-ventilated area. Avoid breathing dust. Do not breathe dust or mist. Mixing this product with acid or ammonia releases chlorine gas. Do not mix with bleach or other chlorinated products - will cause chlorine gas. Wash hands thoroughly after handling. : No known significant effects or critical hazards. Wash thoroughly after handling. Page: 1/8 MANUAL BAR GLASS SANITIZER 28 Mar 2013 Section 2. Hazards identification IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or physician. IF SWALLOWED: Immediately call a POISON CENTER or physician. Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER or physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician. : No other specific measures identified. : See section 13 for waste disposal information. Storage Disposal Other hazards : Handling and/or processing of this material may generate a dust which can cause mechanical irritation of the eyes, skin, nose and throat. Get medical attention if symptoms appear. No other specific measures identified. See section 13 for waste disposal information. None known. Section 3. Composition/information on ingredients Substance/mixture Product AS SOLD : Mixture Hazardous ingredients Concentration Range (%) CITRIC ACID Trichloromelamine benzenesulfonic acid, mono-c10-16-alkyl derivs., sodium salts 20 - 50 18.7 5 - 20 CAS number 77-92-9 7673-09-8 68081-81-2 Product AT USE DILUTION Within the present knowledge of the supplier, this product does not contain any hazardous ingredients in quantities requiring reporting, in accordance with local regulations. Section 4. First aid measures Eye contact : Skin contact : Inhalation : Ingestion : Protection of firstaiders : Product AS SOLD Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. Take off immediately all contaminated clothing. Rinse skin with water or shower. Get medical attention immediately. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention immediately. Get medical attention immediately. Rinse mouth. Do not induce vomiting. Product AT USE DILUTION No known effect after eye contact. Rinse with water for a few minutes. No known effect after skin contact. Rinse with water for a few minutes. No special measures required. Treat symptomatically. Get medical attention if symptoms occur. Page: 2/8 MANUAL BAR GLASS SANITIZER 28 Mar 2013 Section 4. First aid measures No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If ventilation is inadequate, use respirator that will protect against dust/mist. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. See toxicological information (section 11) Section 5. Fire-fighting measures Product AS SOLD Suitable fire extinguishing media Specific hazards arising from the chemical Hazardous thermal decomposition products Specific fire-fighting methods Special protective equipment for fire-fighters : Use dry chemical powder. : No specific fire or explosion hazard. : Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides phosphorus oxides halogenated compounds metal oxide/oxides : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions Environmental precautions Methods for cleaning up Product AS SOLD : Initiate company's spill response procedures immediately. Keep people out of area. Put on appropriate personal protective equipment (see section 8). Do not touch or walk through spilled material. : Avoid contact of spilled material and runoff with soil and surface waterways. : If emergency personnel are not present, contain and collect small spillages with non-combustible absorbent material, e.g. sand, earth or other suitable material and place in a suitable container for disposal. Use a water rinse for final clean-up. Product AT USE DILUTION Use personal protective equipment as required. Avoid contact of large amounts of spilled material and runoff with soil and surface waterways. Use a water rinse for final clean-up. Section 7. Handling and storage Handling Product AS SOLD : Do not ingest. Do not get in eyes or on skin or clothing. Do not breathe dust. Use only with adequate ventilation. Mixing this product with acid or ammonia releases chlorine gas. Do not mix with bleach or other chlorinated products will cause chlorine gas. Wash thoroughly after handling. Product AT USE DILUTION Wash thoroughly after handling. Page: 3/8 MANUAL BAR GLASS SANITIZER 28 Mar 2013 Section 7. Handling and storage Storage : Keep out of reach of children. Keep container tightly closed. Keep out of reach of children. Store between the following temperatures: 0 and 30°C Section 8. Exposure controls/personal protection Control parameters Ingredient name Exposure limits chlorine ACGIH TLV (United States, 3/2012). STEL: 2.9 mg/m³ 15 minutes. STEL: 1 ppm 15 minutes. TWA: 1.5 mg/m³ 8 hours. TWA: 0.5 ppm 8 hours. OSHA PEL (United States, 6/2010). CEIL: 3 mg/m³ CEIL: 1 ppm NIOSH REL (United States, 6/2009). CEIL: 0.5 ppm 15 minutes. CEIL: 1.45 mg/m³ 15 minutes. Product AS SOLD Appropriate : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or engineering controls mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard. Personal protection Eye protection : Use chemical splash goggles. For continued or severe exposure wear a face shield over the goggles. Hand protection : Use chemical-resistant, impervious gloves. Skin protection Respiratory protection Hygiene measures : Use synthetic apron, other protective equipment as necessary to prevent skin contact. : Wear appropriate respirator when ventilation is inadequate and occupational exposure limits are exceeded. Product AT USE DILUTION Good general ventilation should be sufficient to control worker exposure to airborne contaminants. No protective equipment is needed under normal use conditions. No protective equipment is needed under normal use conditions. No protective equipment is needed under normal use conditions. A respirator is not needed under normal and intended conditions of product use. : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Section 9. Physical and chemical properties Page: 4/8 MANUAL BAR GLASS SANITIZER 28 Mar 2013 Section 9. Physical and chemical properties Physical state Product AS SOLD : Powder Product AT USE DILUTION Liquid. Color : White to yellowish Colorless Odor pH Flash point : Faint odor : 3.5 to 4.5 (1%) : > 100°C Faint odor 3.26 to 3.26 > 100°C Explosion limits Flammability (solid, gas) Melting point Boiling point Evaporation rate (butyl acetate = 1) Vapor pressure : Not available. : Not available. Vapor density : Not available. : 0 (Water = 1) Relative density : Not available. : >100°C (>212°F) : Not available. : Not available. Solubility : Easily soluble in the following materials: cold water and hot water. Partition coefficient: : Not available. n-octanol/water Auto-ignition : Not available. temperature Decomposition : 105°C (221°F) temperature Odor threshold : Not available. Viscosity : Not available. Section 10. Stability and reactivity Product AS SOLD Stability Possibility of hazardous reactions Conditions to avoid Materials to avoid Hazardous decomposition products : The product is stable. : Under normal conditions of storage and use, hazardous reactions will not occur. : No specific data. : Slightly reactive or incompatible with the following materials: alkalis. Mixing this product with acid or ammonia releases chlorine gas. Do not mix with bleach or other chlorinated products - will cause chlorine gas. : Under normal conditions of storage and use, hazardous decomposition products should not be produced. Section 11. Toxicological information Route of exposure : Skin contact, Eye contact, Ingestion Product AS SOLD Symptoms Eye contact Skin contact : Adverse symptoms may include the following: pain watering redness : Product AT USE DILUTION No specific data. Page: 5/8 MANUAL BAR GLASS SANITIZER 28 Mar 2013 Section 11. Toxicological information Inhalation Ingestion Acute toxicity Eye contact Skin contact Inhalation Ingestion Adverse symptoms may include the following: pain or irritation redness blistering may occur : Adverse symptoms may include the following: respiratory tract irritation coughing Respiratory tract irritation : Adverse symptoms may include the following: stomach pains No specific data. No specific data. No specific data. : Causes serious eye damage. No known significant effects or critical hazards. : Causes severe burns. No known significant effects or critical hazards. : Harmful if inhaled. May cause respiratory No known significant effects or critical irritation. hazards. : Harmful if swallowed. May cause burns to mouth, No known significant effects or critical throat and stomach. hazards. Toxicity data Product/ingredient name citric acid Result Species LD50 Dermal Rat LD50 Oral Rat 1,3,5-triazine, n,n',n''-trichloro-2,4,6-triamino- LC50 Inhalation Dusts Rat and mists LD50 Dermal Rabbit LD50 Oral Rat benzenesulfonic acid, mono-c10-16-alkyl LD50 Dermal Rat derivs., sodium salts LD50 Oral Rat Chronic toxicity Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects Fertility effects : No known significant effects or critical hazards. : No known significant effects or critical hazards. Dose >2000 mg/kg 11700 mg/kg 0.59 mg/l >2000 mg/kg 398 mg/kg >2000 mg/kg 1090 mg/kg Section 12. Ecological information Product AS SOLD Ecotoxicity : This material is toxic to aquatic life. Aquatic and terrestrial toxicity Product/ingredient name Result citric acid Acute LC50 >100 mg/l 1,3,5-triazine, n,n',n''-trichloro-2,4,6-triaminoAcute EC10 0.8 mg/l Acute EC50 1.2 mg/l Acute LC50 2 mg/l benzenesulfonic acid, mono-c10-16-alkyl derivs. Acute LC50 3.2 mg/l , sodium salts Other adverse effects : No known significant effects or critical hazards. Species Fish Daphnia Daphnia Fish Fish Exposure 96 hours 48 hours 48 hours 96 hours 96 hours Page: 6/8 MANUAL BAR GLASS SANITIZER 28 Mar 2013 Section 13. Disposal considerations Disposal methods Product AS SOLD : Avoid disposal. Attempt to use product completely in accordance with intended use. Disposal should be in accordance with applicable regional, national and local laws and regulations. Product AT USE DILUTION Diluted product can be flushed to sanitary sewer. Discard empty container in trash. Section 14. Transport information Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. DOT DOT Classification UN3261 DOT Proper shipping name Corrosive solid, acidic, organic, n.o.s. (Trichloromelamine) Class 8 Packing group III IMO/IMDG IMO/IMDG Classification UN3261 IMO/IMDG Proper shipping name CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (TRICHLOROMELAMINE) Class 8 Packing group III For transport in bulk, see shipping documents for specific transportation information. Product AT USE DILUTION Not intended for transport. Section 15. Regulatory information Product AS SOLD U.S. Federal regulations TSCA 8(b) inventory EPA Registration No. : All components are listed or exempted. : 65169-1-1677 SARA 302/304/311/312 extremely hazardous substances: No listed substance SARA 302/304 emergency planning and notification: No listed substance SARA 313 Form R - Reporting requirements California Prop. 65 Product name CAS number Concentration : No listed substance : No listed substance Section 16. Other information Page: 7/8 MANUAL BAR GLASS SANITIZER 28 Mar 2013 Section 16. Other information Product AS SOLD Hazardous Material Information System (U.S.A.) Product AT USE DILUTION : Health 3 Health Flammability 0 Flammability 0 Physical hazards 0 Physical hazards 0 Flammability 0 Health 0 Instability/Reactivity Special Date of issue Prepared by 0 : National Fire Protection Association (U.S.A.) 3 Data not available Refer to Product AS SOLD Flammability 0 Health 0 0 Instability/Reactivity Special : 28 Mar 2013 : Regulatory Affairs 1-800-352-5326 Notice to reader The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION. Page: 8/8
* Your assessment is very important for improving the work of artificial intelligence, which forms the content of this project
advertisement
© 2021