Polyurethane Foam Sealant

Polyurethane Foam Sealant
Material Safety Data Sheet
NFPA
HMIS
Issuing Date 27-Feb-2007
PPE
Revision Date 24-Sept-2009
Transport Symbol
Revision Number 1
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name
Touch 'n Foam Professional Quick Cure Polyurethane Insulating Sealant
Touch 'n Seal Quick Cure Polyurethane Foam Sealant RX (cylinder)
Touch 'n Seal Quick Cure Polyurethane Foam Sealant HY (cylinder)
Recommended Use
Sealant, Insulation
Supplier Address
Convenience Products, Division of Clayton Corp.
866 Horan Drive
Fenton, MO 63026-2416 USA
TEL: (636) 349-5333
Emergency Telephone Number
Chemtrec 1-800-424-9300
(703) 527-3887 outside US
2. HAZARDS IDENTIFICATION
WARNING!
Emergency Overview
Contents under pressure. Avoid temperatures above (120°F)
May be harmful if swallowed or inhaled.
May cause allergic skin reaction.
May cause allergic respiratory reaction.
Vapors may be irritating to eyes, nose, throat, and lungs.
May cause drowsiness and dizziness.
Keep upwind of spill. Stay out of low areas
Appearance Pale Amber
Potential Health Effects
Principle Routes of Exposure
Physical State Liquid Aerosol
Odor Faint hydrocarbon
Inhalation, Skin contact, Eye contact.
Acute Toxicity
Eyes
Irritating to eyes. May cause slight temporary corneal injury due to adhesive character.
Skin
Prolonged or repeated exposure may cause slight skin irritation. Material will stick to skin
causing irritation upon removal. Animal studies have shown that skin contact with isocyanates
may play a role in causing respiratory sensitization. Repeated or prolonged skin contact may
cause allergic reactions with susceptible persons.
Skin Absorption
A single prolonged exposure is unlikely to result in the material being absorbed in harmful
amounts.
Page 1 / 8 MSDS Part # 4004517165
Touch 'n Foam
 Professional Quick Cure Polyurethane Insulating Sealant
Touch 'n Seal
 Quick Cure Polyurethane Foam Sealant RX (cylinder)
Touch 'n Seal Quick Cure Polyurethane Foam Sealant HY (cylinder)
Revision Date
24-Sept-2009
Inhalation
Maintain local exhaust ventilation system during use. If large concentrations of vapors build up
they could cause upper respiratory tract and lung irritation. May cause allergic respiratory
reaction. Inhalation of vapors in high concentration may cause shortness of breath (lung
edema).
Ingestion
May be harmful if swallowed. May cause additional affects as listed under "Inhalation".
Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Product may
cure in the gastrointestinal tract and form an obstruction. May cause adverse cardiac effects,
blood disturbances, and metabolic acidosis.
Chronic Effects
Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals
after repeated excessive exposures to MDI / Polymeric MDI aerosols. Intentional misuse by
deliberately concentrating and inhaling contents may be harmful or fatal. Repeated or
prolonged contact causes sensitization, asthma and eczemas.
Birth / Developmental Effects:
In laboratory animals, MDI/Polymeric MDI did not cause birth defects; other fetal effects
occurred only at high doses that were toxic to the mother.
Aggravated Medical Conditions
Allergies. Skin disorders. Respiratory disorders. Central nervous system. Preexisting eye
disorders. Kidney disorders. Liver disorders.
Interactions with Other Chemicals
Irritants. Sensitizers. Epoxies. Use of alcoholic beverages may enhance toxic effects.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
1,1,1,2 – Tetrafluoroethane (HFC-134a,
Fluorocarbon)
Flame Retardant
Flame Retardant
Polymethylene polyphenylene isocyanate
Methylene bisphenyl isocyanate (MDI)
Polyol blend
Methylenediphenyl diisocyanate
CAS-No
811-97-2
Weight %
10-30
Proprietary
Proprietary
9016-87-9
101-68-8
Proprietary
26447-40-5
5-20
5-20
10-30
10-30
10-30
1-5
4. FIRST AID MEASURES
General Advice
If emergency warrants call 911 or emergency medical service. Show this safety data sheet to
the doctor in attendance. Remove and wash soiled clothing before reuse.
Eye Contact
Immediately flush with plenty of water. After initial flushing, remove any contact lenses and
continue flushing for at least 15 minutes. Keep eye wide open while rinsing. Obtain medical
attention, preferably from an ophthalmologist.
Skin Contact
Remove contaminated clothing; wash before reuse. Foam will stick to skin; studies
demonstrate that cleaning very soon after exposure with corn oil or nail polish remover is most
effective. If foam dries on skin, apply generous amounts of petroleum jelly or lanolin, put on
plastic gloves and wait 1 hour. With a clean cloth, firmly wipe off petroleum jelly and repeat
process if necessary. Do not attempt to remove dried foam with solvents.
Inhalation
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen
if breathing is difficult. If breathing is difficult, oxygen should be administered by qualified
personnel. Call a physician or transport to a medical facility.
Ingestion
Call a physician or Poison Control Center immediately. May produce an allergic reaction. Do
not induce vomiting unless directed to do so by medical personnel. Drink plenty of water.
Never give anything by mouth to an unconscious person.
Page 2 / 8 MSDS Part # 4004517165
Touch 'n Foam
 Professional Quick Cure Polyurethane Insulating Sealant
Touch 'n Seal
 Quick Cure Polyurethane Foam Sealant RX (cylinder)
Touch 'n Seal Quick Cure Polyurethane Foam Sealant HY (cylinder)
Revision Date
24-Sept-2009
Notes to Physician
Maintain adequate ventilation and oxygenation of the patient. May cause asthma-like (reactive
airways) symptoms. May cause respiratory sensitization or asthma-like symptoms.
Respiratory symptoms, including pulmonary edema, may be delayed. Exposure may increase
“myocardial irritability”. If you are sensitized to diisocyanates, consult your physician regarding
working with other respiratory irritants or sensitizers. No specific antidote. Treatment of
exposure should be directed at the control of symptoms and the clinical condition of the
patient.
Protection of First-aiders
Remove all sources of ignition. Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves.
5. FIRE-FIGHTING MEASURES
Flammable Properties
Aerosol cans exposed to fire can rupture.
Flash Point
Suitable Extinguishing Media
None
Isolate fire and deny unnecessary entry. Use an extinguishing
agent suitable for type of surrounding fire. Dry chemical, CO2,
water spray, fog or regular foam. Stay upwind. Keep out of low
areas where gases fume s can accumulate. Move containers from
fire area if you can do it without risk. Damaged cylinders should be
handled only by specialists.
Explosion Data
Sensitivity to mechanical impact
Sensitivity to static discharge
None
None
Specific Hazards Arising from the Chemical
Ruptured cylinders may rocket.
Protective Equipment and Precautions for Firefighters
Wear self-contained breathing apparatus and protective suit.
NFPA
Health Hazard 2
Flammability 1
Stability 1
Physical and Chemical
Hazards -
HMIS
Health Hazard 2*
Flammability 1
Stability 1
Personal Precautions -B
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
Do not touch or walk through spilled material. Use appropriate safety equipment. Evacuate
area. Keep personnel out of low areas, confined or poorly ventilated areas. Keep upwind of
spill. Ensure adequate ventilation. No smoking in area. Only trained and properly protected
personnel must be involved in clean-up operations.
Methods for Containment
If possible, turn leaking containers so that gas escapes rather than liquid. Allow substance to
evaporate. Contain spilled materials if possible without risk. Absorb with materials such as
Sawdust. Dirt Vermiculite. Collect in suitable and properly labeled open containers. Do not
place in sealed containers. Wash what is left of the spill site with large quantities water.
Methods for Cleaning Up
Soak up with inert absorbent material. Sweep up and shovel into suitable containers for
disposal. Do not direct water at spill or source of leak.
Other Information
Ventilate the area. Curing foam gives off HFC-134a. Do not put curing foam in a sealed drum.
7. HANDLING AND STORAGE
Page 3 / 8 MSDS Part # 4004517165
Touch 'n Foam
 Professional Quick Cure Polyurethane Insulating Sealant
Touch 'n Seal
 Quick Cure Polyurethane Foam Sealant RX (cylinder)
Touch 'n Seal Quick Cure Polyurethane Foam Sealant HY (cylinder)
Revision Date
24-Sept-2009
7. HANDLING AND STORAGE
Handling
Avoid contact with skin, eyes and clothing. Wear personal protective equipment. Remove and
wash contaminated clothing before re-use. Do not breathe vapors or spray mist. Do not eat,
drink or smoke when using this product. Use only in area provided with appropriate exhaust
ventilation. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or
incinerate cans. Container, even those that have been emptied, can contain vapors. Do not
stick pin or any other sharp object into opening on top of can.
Storage
Keep containers tightly closed in a cool, well-ventilated place. Keep in properly labeled
containers. Keep in an area equipped with sprinklers. Keep out of the reach of children. Ideal
storage temperature is 16-32 °C / 60 – 90 °F. Stor age above 32 °C / 90 °F will reduce its
shelf-life. Never keep at temperatures above 48.8 °C / 120 °F.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Chemical Name
Methylene bisphenyl isocyanate
(MDI)
ACGIH TLV
TWA: 0.005 ppm
OSHA PEL
Ceiling: 0.02 ppm
Ceiling: 0.2 mg/m3
NIOSH IDLH
75 mg/m3
NIOSH IDLH: Immediately Dangerous to Life or Health
Engineering Measures
Personal Protective Equipment
Eye/Face Protection
Showers
Eyewash stations
Ventilation systems
Tightly fitting safety glasses with side-shields.
Skin and Body protection
Lightweight protective clothing. Impervious gloves.
Respiratory Protection
Atmospheric levels of PMDI should be maintained below the exposure guidelines. If exposure
limits are exceeded or irritation is experienced, use a NIOSH/MSHA approved air-purifying
respirator equipped with an organic vapor absorbent and a particle filter. For situations where
the atmospheric levels exceed the level for which an air-purifying respirator is effective, use a
positive-pressure air-supplied respirator. Respiratory protection must be provided in
accordance with current local regulations.
Hygiene Measures
When using, do not eat, drink or smoke. Maintain regular cleaning of equipment, work area
and clothing.
Page 4 / 8 MSDS Part # 4004517165
Touch 'n Foam
 Professional Quick Cure Polyurethane Insulating Sealant
Touch 'n Seal
 Quick Cure Polyurethane Foam Sealant RX (cylinder)
Touch 'n Seal Quick Cure Polyurethane Foam Sealant HY (cylinder)
Revision Date
24-Sept-2009
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Pale Amber
Odor
Faint hydrocarbon
Odor Threshold
No information available
Physical State
Liquid Aerosol
pH
No information available
Flash Point
None
Autoignition Temperature
Not applicable
Decomposition temperature
No data available
Boiling Point/Range
-41°C / -42°F
Melting Point/Range
No data available
Flammability Limits in Air
No data available
Explosion Limits
No data available
Specific Gravity
1.2
Water Solubility
Not Compatible
Solubility
Compatible.
Evaporation Rate
No data available
Vapor Pressure
No data available
Vapor Density
No data available
VOC Content
Not applicable
EPA VOC (g/l)
0
10. STABILITY AND REACTIVITY
Stability
Stable under recommended storage conditions
Conditions to Avoid
Keep away from open flames, hot surfaces and sources of ignition.
Temperatures above 48.8 °C / 120 °F.
Incompatible Products
Water. Alcohols. Strong bases. Strong oxidizing agents. Finely
powdered metals.
Hazardous Decomposition Products
Carbon monoxide (CO), Carbon dioxide (CO2), Nitrogen oxides
(NOx), Hydrogen cyanide.
Hazardous Polymerization
Hazardous polymerization does not occur.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Sensitization - Skin
Sensitization – Respiratory
Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact
with isocyanates may play a role in respiratory sensitization.
May cause allergic respiratory response. MDI concentrations below the exposure guidelines
may cause allergic respiratory reactions in individuals already sensitized. Asthma-like
symptoms may include coughing, difficult breathing and a feeling of tightness in the chest.
Occasionally, breathing difficulties may be life threatening.
Product Information
Chemical Name
Flame Retardant
Flame Retardant
LD50 Oral
1,250 mg/kg ( Rat )
>2,000 mg/kg (Rat)
Polymethylene polyphenylene
isocyanate
Methylene bisphenyl isocyanate
(MDI)
Polyol blend
49 g/kg ( Rat )
LD50 Dermal
>5,000 mg/kg (Rabbit)*
>23,700 mg/kg ( Rabbit )
>2000 mg/kg ( Rat )
9400 mg/kg ( Rabbit )
9200 mg/kg ( Rat )
64 mL/kg ( Rat )
20 mL/kg ( Rabbit )
Page 5 / 8 MSDS Part # 4004517165
LC50 Inhalation
>4.6 mg/l ( Rat ) 4-hr
>5.22 mg/l ( Rat ) 4-h
490 mg/m3 ( Rat ) 4 h
Touch 'n Foam
 Professional Quick Cure Polyurethane Insulating Sealant
Touch 'n Seal
 Quick Cure Polyurethane Foam Sealant RX (cylinder)
Touch 'n Seal Quick Cure Polyurethane Foam Sealant HY (cylinder)
Chemical Name
Methylenediphenyl diisocyanate
LD50 Oral
Revision Date
24-Sept-2009
LD50 Dermal
6200 mg/kg ( Rabbit )
LC50 Inhalation
0.369 mg/L ( Rat ) 4 h
Chronic Toxicity
Repeated or prolonged exposure may cause central nervous system damage. Tissue injury in
the upper respiratory tract and lungs has been observed in laboratory animals after repeated
excessive exposures to MDI/polymeric MDI aerosols. Repeated or prolonged contact causes
sensitization, asthma and eczemas. Repeated or prolonged contact may causes sensitization,
asthma and eczemas.
Carcinogenicity
There are no known carcinogenic chemicals in this product.
Mutagenicity
Contains no known mutagenetic chemicals
Reproductive Toxicity
This product does not contain any known or suspected reproductive hazards
Target Organ Effects
Contains component(s) that have been reported to cause effects on the following organs in
animals: Kidney, Liver, Bone marrow.
Endocrine Disruptor Information
This product does not contain any known or suspected endocrine disruptors
12. ECOLOGICAL INFORMATION
Ecotoxicity effects.
Chemical Name
Flame Retardant
Methylenediphenyl
diisocyanate
Toxicity to Algae
EC50 > 10 mg/L 72 h
EC50 = 3230 mg/L 96 h
Toxicity to Fish
Microtox
Daphnia Magna (Water Flea)
EC50 3.9 - 5.5 mg/L 48 h
EC50 > 1000 mg/L 24 h
13. DISPOSAL CONSIDERATIONS
Waste Disposal Method
This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261).
Should not be released into the environment. Dispose of in accordance with local regulations. Allow
foam to cure before disposal.
Contaminated Packaging
Dispose of in accordance with local regulations.
14. TRANSPORT INFORMATION
DOT
Proper Shipping Name
Hazard Class
Description
TDG
UN-No
Proper Shipping Name
Hazard Class
Description
MEX
UN-No
Proper Shipping Name
Hazard Class
Description
ICAO
UN-No
Proper Shipping Name
Hazard Class
Description
IATA
UN-No
Proper Shipping Name
Hazard Class
ERG Code
Description
IMDG/IMO UN-No
Proper Shipping Name
Hazard Class
Consumer commodity
ORM-D
Consumer commodity, ORM-D
UN1950
Aerosols
2.2
UN1950, Aerosols, 2.2
UN1950
Aerosols
2.2
UN1950, Aerosols, 2.2
UN1950
Aerosols
2.2
UN1950, Aerosols
UN1950
Aerosols, non-flammable
2.2
2L
UN1950, Aerosols, non-flammable, 2.2
UN1950
Aerosols
2.2
Page 6 / 8 MSDS Part # 4004517165
Touch 'n Foam
 Professional Quick Cure Polyurethane Insulating Sealant
Touch 'n Seal
 Quick Cure Polyurethane Foam Sealant RX (cylinder)
Touch 'n Seal Quick Cure Polyurethane Foam Sealant HY (cylinder)
Revision Date
24-Sept-2009
14. TRANSPORT INFORMATION
RID
ADR
ADN
Description
UN-No
Proper Shipping Name
Hazard Class
Classification Code
Description
ADR/RID-Labels
UN-No
Proper Shipping Name
Hazard Class
Classification Code
ADR/RID-Labels
UN-No
Proper Shipping Name
Hazard Class
Classification Code
Special Provisions
Description
Hazard Labels
Limited Quantity
UN1950, Aerosols, 2.2
UN1950
Aerosols
2
5A
UN1950, Aerosols, 2, RID
2
UN1950
Aerosols
2
5A
2
UN1950
Aerosols
2
5A
63, 190, 191, 277, 913
UN1950, Aerosols, 2
2
See SP277
International Inventories
TSCA
DSL
EINECS/ELINCS
ENCS
Complies
Complies
Complies
Complies
CHINA
KECL
PICCS
AICS
Complies
Complies
Complies
Complies
15. REGULATORY INFORMATION
U.S. Federal Regulations :SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
Chemical Name
Polymethylene polyphenylene isocyanate
Methylene bisphenyl isocyanate (MDI)
Methylenediphenyl diisocyanate
SARA 311/312 Hazard Categories
Acute Health Hazard
Chronic Health Hazard
Clean Water Act
CERCLA
Chemical Name
Methylene bisphenyl isocyanate (MDI)
CAS-No
9016-87-9
101-68-8
26447-40-5
Yes
Yes
Weight %
10-30
10-30
1-5
Fire Hazard
Reactive Hazard
SARA 313 - Threshold Values
1.0
1.0
1.0
No
No
This product does not contain any substances regulated as pollutants pursuant to the Clean
Water Act (40 CFR 122.21 and 40 CFR 122.42).
This material, as supplied, contains one or more substances regulated as a hazardous
substance under the Comprehensive Environmental Response Compensation and Liability Act
(CERCLA) (40 CFR 302).
Hazardous Substances RQs
5000 lb
Extremely Hazardous Substances RQs
U.S. State Regulations
California Proposition 65
Warning! This product contains chemical known to the State of California to cause cancer. (concentration <0.1%)
Page 7 / 8 MSDS Part # 4004517165
Touch 'n Foam
 Professional Quick Cure Polyurethane Insulating Sealant
Touch 'n Seal
 Quick Cure Polyurethane Foam Sealant RX (cylinder)
Touch 'n Seal Quick Cure Polyurethane Foam Sealant HY (cylinder)
Revision Date
24-Sept-2009
U.S. State Right-to-Know Regulations
Chemical Name
Methylene bisphenyl
isocyanate (MDI)
Massachusetts
X
New Jersey
X
Pennsylvania
X
Illinois
X
Rhode Island
X
X
1,1,1,2 –
Tetrafluoroethane (HFC134a, Fluorocarbon)
X
International Regulations
Mexico - Grade
The exposure limits values for 101-68-8 are listed under two synonyms:
3
Diphenylmethane diisocyanate - 0.02 ppm TWA; 0.2 mg/m TWA
3
Methylene bisphenyl isocyanate - 0.005 ppm TWA; 0.051 mg/m TWA
Chemical Name
Methylene bisphenyl isocyanate (MDI)
Carcinogen Status
Diphenylmethane diisocyanate
Exposure Limits
Mexico: TWA= 0.2 mg/m3
Mexico: TWA= 0.02 ppm
Mexico: TWA= 0.005 ppm
Mexico: TWA= 0.051 mg/m3
Canada: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR)
and the MSDS contains all the information required by the CPR.
WHMIS Hazard Class, A Compressed gases, D2B Toxic Materials
Chemical Name
Methylene bisphenyl isocyanate (MDI)
NPRI
X
Legend
NPRI - National Pollutant Release Inventory
WHMIS – Workplace Hazardous Materials Information System
TSCA – Toxic Substance Control Act
DSL – Domestic Substance List
EINECS – European Inventory of Existing Commercial Chemical
Substances
ENCS – Japan, Existing and New Chemical Substances
KECL- Korean Existing Chemical List
PICS – Philippine Inventory of Chemicals and Chemical
Substances
AICS – Australian Inventory of Chemical Substances
TDG – Transportation of Dangerous Goods Act
ICAO – International Civil Aviation Organization
IATA – International Maritime Dangerous Goods Code
IMDG – International Maritime Dangerous Goods Code
16. OTHER INFORMATION
Issuing Date
22-Feb-2007
Revision Date
24-Sept-2009
Revision Note
Revised by Clayton Corporation EHS Department
Disclaimer
The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any other material or in any
process, unless specified in the text.
End of MSDS
Page 8 / 8 MSDS Part # 4004517165
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