SAFETY DATA SHEET SECTION 1- PRODUCT AND COMPANY IDENTIFICATION

SAFETY DATA SHEET SECTION 1- PRODUCT AND COMPANY IDENTIFICATION
SAFETY DATA SHEET
LOW PRESSURE POLYURETHANE FOAM SEALANT (134a)
SECTION 1- PRODUCT AND COMPANY IDENTIFICATION
1.1 Product Identifier
Handi-Foam® 40 Series and Handi-Seal® Window & Door Polyurethane Foam Sealants
A16355
No data available
Product Name:
SDS ID Number
REACH Registration:
1.2 Relevant identified uses of the substance or mixture and uses advised against
General Use
Uses advised against
One Component Polyurethane Foam Sealants
1.3 Details of the supplier and of the safety data sheet
Manufacturer
Fomo Products Inc.
2775 Barber Road
Norton, Ohio 44203
In Ohio: 330-753-4585; 1-800-321-5585 (Monday-Friday 8:00am-5:00pm EST)
1.4 Emergency telephone numbers
In the U.S.A
International Emergency
CHEMTREC (24 hours) 1-800-424-9300
CHEMTREC (24 hours) 1-703-527-3887
SECTION 2- HAZARDS IDENTIFICATION
2.1 Classification of substance or mixture
Product definition:
Classification:
Mixture
Gases Under Pressure- Compressed Gas
Acute Toxicity Inhalation- Category 4
Skin Irritation- Category 2
Serious Eye Irritation- Category 2A
Respiratory Sensitizing- Category 1
Skin Sensitization – Category 1
Specific Target Organ Toxicity SE 3
Reproductive toxicity- Effects on or via lactation
Specific Target Organ Toxicity RE 2
Aquatic Chronic- Category 4
2.2 Label elements
Hazard Symbols:
Signal Word:
Hazard Statements:
WARNING
H280- Contains gas under pressure; may explode if heated
H315- Causes Skin Irritation
H317- May cause an allergic skin reaction
H319- Causes Serious Eye Irritation
H332- Harmful if inhaled
H334- May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335- May cause respiratory irritation
H362- May cause harm to breastfed children
H373- May cause damage to organs through prolonged or repeated exposure
H413- May cause long lasting harmful effects to aquatic life
Prevention:
P102- Keep Out of Reach of Children
P202- Do not handle until all safety precautions have been read and understood
P251- Pressurized Container: Do not pierce or burn, even after use
P261- Avoid breathing vapors or fumes
P262- Do not get in eyes, on skin, or on clothing
P264- Wash hands and other skin areas exposed to material thoroughly after handling
P271- Use only outdoors or in a well-ventilated area
P273- Avoid release to the environment
P280- Wear protective gloves, protective clothing and eye protection
LP PU FOAM SEALANTS 134A
Response:
ISSUE DATE: October 2010
LAST REV: April 2015
PAGE 2 OF 7
P285- In case of inadequate ventilation wear respiratory protection
P302+P352+P333+P313 IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get
medical attention
P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position
comfortable for breathing
P305+P351+P338- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P314- Get medical advice if you feel unwell
P342+P311- If experiencing respiratory symptoms: Call a POISON CENTER or doctor
P381- Eliminate all ignition sources if safe to do so
Storage:
P403+P405- Store in a well-ventilated place. Store locked up.
P410- Protect from sunlight
P412- Do not expose to temperatures exceeding 50◦C/122◦F.
Disposal:
P501 Dispose of contents/container in accordance with applicable local/regional/national/international
regulations.
SECTION 3- COMPOSITION/INFORMATION ON INGREDIENTS
% by
Weight
Ingredient
CAS No.
EC Number
Annex Number
EC Classification
615-005-00-9
Car. Cat 3, R40; Xn R20,
R48/20; Xi R36/37/37,
R42/43
602-095-00-X
R53; R64
Urethane Pre-Polymer Blend (NonHazardous Polyol Blend)
Proprietary
1,1,1,2 Tetrafluoroethane
4,4’ Diphenylmethane diisocyanate
(MDI)
811-97-2
101-68-8
217-377-0
202-966-0
9016-87-9
500-079-6
3-7
Polymethylene polyphenyl isocyanate
(PMDI)
Alkanes, C14-C17, Chloro
85535-85-9
287-477-0
3-7
Tris (1-chloro-2-propyl) phosphate
13674-84-5
237-158-7
40-70
10-30
3-7
3-7
There are not additional ingredients present which, within the current knowledge of the supplier and in the concentration applicable, are classified as
hazardous to the health or environment and hence require reporting in this section.
SECTION 4- FIRST AID MEASURES
4.1 Description of first aid measures
Eye:
Skin:
Inhalation:
Ingestion:
Immediately flush eyes with large amounts of water for at least 15 minutes, holding the eyes open with fingers and
occasionally lifting the upper and lower lids. Use lukewarm water if possible. If present and easy to do so, remove contact
lenses, If irritation persists, get medical attention.
In case of contact, immediately flush skin with plenty of soap and water. Foam will stick to skin, gently wipe product from skin
with a damp cloth and wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash clothing before
reuse. Call a physician if irritation persists.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Obtain medical
attention.
If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Get medical advice/attention.
4.2 Most important symptoms and effects, both acute and delayed
Eye:
Skin:
Inhalation
Ingestion:
Chronic:
May cause eye irritation.
May cause skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. May cause an
allergic reaction. Prolonged skin exposure is unlikely to result in absorption of harmful amounts
May be harmful if inhaled. May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if
inhaled. Inhalation of propellant may cause headache, lightheadedness and lethargy.
May be harmful if swallowed. May cause gastrointestinal irritation: stomach distress, nausea, or vomiting.
Chlorinated paraffin (C14-C17) may cause harm to breastfed children. Refer to section 12.2
4.3 Notes to the physician
Symptoms may not appear immediately. If case of an accident or if you feel unwell, seek medical advice immediately (show label or SDS if
possible).
LP PU FOAM SEALANTS 134A
ISSUE DATE: October 2010
LAST REV: April 2015
PAGE 3 OF 7
SECTION 5- FIRE FIGHTING MEASURES
5.1 Extinguishing media
Suitable methods of extinction: Use dry chemical, carbon dioxide, foam, Halon 1211 and water spray or fog.
Unsuitable methods of extinction: Do not use water jets and high pressure water as these may spread the fire
5.2 Special hazards arising from the substance or mixture
Contains compressed gas. Eliminate all ignition sources. Closed containers may explode due to buildup of pressure when exposed to
extreme heat. Aerosol cans exposed to fire or high temperature can rupture and rocket. Cured foam will burn in the presence of heat,
oxygen and an ignition source.
5.3 Advice to firefighters
Products of combustion: May include and are not limited to: oxides of carbon, oxides of nitrogen, hydrogen fluoride, and traces of
hydrogen cyanide.
Keep upwind of fire. Wear full fire-fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Use water spray to keep fireexposed containers cool. Containers may explode if heated.
SECTION 6- ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected
personnel. Eliminate sources of ignition.
6.2 Environmental precautions
Do not allow to enter sewers, drains, or waterways
6.3 Methods and materials for containment and cleaning up
Method for containment: Uncured product is very sticky; carefully remove the bulk of the foam by scraping it up and then immediately
remove the residue with a rag and solvent such as Handi-Cleaner, mineral spirits, acetone (nail polish remover), paint thinner, etc. Once
the product is cured it can only be removed mechanically by scraping, buffing, etc. Use appropriate PPE.
Methods for cleaning up: Scoop up material and place in a disposal container. Dispose of as plastic waste in accordance with all
applicable guidelines and regulations. Vapors can accumulate in low areas. Provide ventilation
6.4 Reference to other sections
For indications about waste treatment, see Section 13
SECTION 7- HANDLING AND STORAGE
7.1 Precautions for safe handling
Pressurized container: do not pierce or burn, even after use. Container may explode if heated. Avoid contact with skin and eyes. Do not
breathe dust/fume/gas/mist/vapors/spray. Do not swallow. Use only in a well-ventilated area or outdoors. Avoid welding or other “hot
work” in the vicinity of exposed cured foam. When using do not eat, drink or smoke. (See section 8)
General hygiene advice: Launder contaminated clothing before reuse. Wash hands before eating, drinking or smoking.
7.2 Conditions for safe storage including any incompatibilities
Store in a dry place. Ideal use temperature is 65F to 80F (18C to 27C). Do not expose aerosol cans to open flame or store at
temperatures above 122F (50C). Excessive heat can cause premature aging of components resulting in a shorter shelf life. Storage
below 55F (12.7C) may affect foam quality if chemicals are not warmed to room temperature before using. Protect containers from
physical abuse. Keep containers upright. KEEP AWAY FROM CHILDREN.
SECTION 8- EXPOSURE CONTROLS/ PERSONAL PROTECTION
8.1 Control Parameters
CAS No.
Ingredient
101-68-8
4,4’ Diphenylmethane
diisocyanate
811-97-2
1,1,1,2 Tetrafluoroethane
OSHA-PEL TWA
ACGIH-TLV
NIOSH/ Other
0.02 PPM; 0.2 mg/m3
Ceiling
0.005 ppm; 0.051 mg/ m3 (8
hours) TWA
0.005 ppm; 0.050 mg/m3 TWA
0.02 ppm; 0.2 mg/m3 CEIL
WEEL 1,000 ppm
8.2 Exposure Controls:
Engineering measures: Use ventilation adequate to keep exposures below recommended exposure limits.
Eye/face Protection: Wear protective safety glasses with side shields or goggles.
Hand Protection: Use chemically resistant gloves (i.e. Nitrile gloves). Nitrile/butadiene rubber, butyl rubber, polyethylene, PVC (vinyl), or
neoprene gloves are also effective. Glove selection should take into account potential body reactions to certain materials and
manufacturer’s instructions for use. Break through time of selected gloves must be greater than the intended use period.
Other Protective Equipment: Use clothing that protects against dermal exposure. Appropriate protective clothing varies depending on the
potential for exposure. To ensure proper skin protection, wear PPE in such a manner that no skin is exposed.
LP PU FOAM SEALANTS 134A
ISSUE DATE: October 2010
LAST REV: April 2015
PAGE 4 OF 7
Respiratory Protection: If atmospheric levels are expected to exceed the exposure levels, use a NIOSH approved air purifying respirator
equipped with an organic vapor cartridge and particulate filter. If atmospheric levels exceed 10 times the TLV or PEL level for which an airpurifying respirator is effective, use a powered air purifying respirator (PAPR). The type of respiratory protection selected must comply with
the requirements set forth in OSHA’s Respiratory Protection Standard (29 CFR 1910.134).
Hygiene Measures: An eye wash station or portable eye wash station should be in the area. Wash hands thoroughly after use, before
eating, drinking or using the lavatory. Employees/Users should be educated and trained in the safe use and handling of this product.
SECTION 9- Physical and chemical properties
9.1 Information on basic physical and chemical properties
General Physical Form
Color
Odor
Odor Threshold:
Physical State:
pH:
Melting Point/Freezing Point
Initial Boiling Point and Boiling Range
Flash Point:
Evaporation Rate:
Flammability:
Lower Flammability/Explosive Limit:
Upper Flammability/Explosive Limit:
Vapor Pressure
Vapor Density:
Relative Density/Specific Gravity:
Solubility:
Partition coefficient: n-octanol/water:
Auto-ignition Temperature:
Decomposition Temperature;
Viscosity:
Oxidizing Properties:
VOC Content (calculated minus exempt
compounds and water)
Viscous liquid which forms off-white to yellowish foam upon release.
Crème. Some products contain a dye or colorant.
Slight fluorocarbon odor during curing stage
No data available
Gas/Pressurized Liquid/Semi-Solid
No data available
No data available
HFC-134A boils at -26◦C (-15◦F). Other components boil at 93.3◦C (200◦F)
Use of non-flammable propellant
No data available
Flammable
No data available
No data available
Aerosol product > 50 psig/ 345 kPa
Final product (sprayed): Very low (not determined)
Not available
~ 1.1 (Water = 1)
Insoluble; reacts slowly with water during cure, liberating traces of CO2
No data available
No data available
No data available
No data available
No data available
0 g/l minus exempted compounds
SECTION 10- STABILITY AND REACTIVITY
10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical Stability
Stable under normal storage conditions. Contents under pressure. Container may explode if heated. Do not pierce or burn, even after use.
Avoid temperatures below 40F (4C). For longest shelf life, avoid storage above 100F (38C).
10.3 Possibility of Hazardous Reactions
Elevated temperatures can cause product to decompose, releasing carbon dioxide. Flammable propellant. Contents are under pressure
and exposure to high temperature can cause containers to rupture or explode.
10.4 Conditions To Avoid
Heat. Incompatible materials. Sources of ignition. Avoid temperatures below 40°F (4°C) or temperatures above 100°F (38°C).
10.5 Incompatible Materials
Alcohols, strong bases, amines, metal compounds, ammonia, and strong oxidizers.
10.6 Hazardous Decomposition Products
May include, and are not limited to: oxides of carbon, oxides of nitrogen, hydrogen fluoride and traces of hydrogen cyanide.
SECTION 11- TOXICOLOGICAL INFORMATION
11.1 Information on Toxicological effects:
Acute Oral Toxicity
Expected to have low acute oral toxicity
Acute inhalation toxicity
Expected to have low acute inhalation toxicity
Acute dermal toxicity
Expected to have low acute dermal toxicity
LP PU FOAM SEALANTS 134A
ISSUE DATE: October 2010
LAST REV: April 2015
PAGE 5 OF 7
Skin irritation
Causes skin irritation
Eye irritation
Causes serious eye irritation
Sensitization
May cause skin and respiratory sensitization
Genotoxicity
Genetic toxicity data for MDI is inconclusive. Some in-vitro studies yielded positive results, while other test data was negative
Mutagenicity
Test data using laboratory animals was predominately negative
Specific organ toxicity- single exposure
May cause respiratory irritation
Specific organ toxicity- repeated exposure
May cause damage to the lungs, central nervous system and skin
Aspiration hazard
No data available
11.2 Delayed, Immediate, and Chronic Effects of Short and Long Term Exposure
MDI and PMDI: IARC Group 3 carcinogen- Not classifiable as to its carcinogenicity to humans. Not listed as a carcinogen by ACGIH,
OSHA or NTP. MDI/PMDI did not cause birth defects in laboratory animals; fetal effects occurred only at high doses which were toxic to the
mother. Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of MDI/PMDI (6mg/m3) for their
lifetime. Tumors occurred concurrently with respiratory irritation and lung injury. Current exposure guidelines are expected to protect
against these effects. Chlorinated paraffins (C14-C16) may accumulate in body tissues and fluids rich in lipid content; therefore, this
material may cause harm to breastfed children.
SECTION 12- ECOLOGICAL INFORMATION
12.1 Ecotoxicity
The aquatic toxicity of this product has not been experimentally determined. However, it is expected to have low acute aquatic toxicity
based on the acute aquatic toxicity of the individual components and their concentration in this mixture.
12.2 Persistence and degradability
Product is not readily biodegradable. In aquatic and terrestrial environments, this material reacts with water, which forms predominately
insoluble polyureas.
12.3 Bioaccumulative potential
Bioaccumulation potential is low
12.4 Mobility in soil
Expected to have low mobility based on product’s reactivity with water
12.5 Results of PBT and vPvB assessment
No data available
12.6 Other Adverse Effects
No data available
SECTION 13- DISPOSAL CONSIDERATIONS
13.1 Waste Treatment Methods
Methods of disposal
Before disposing of containers, relieve container of any remaining foam and pressure. Allow dispensed product to fully cure before
disposing. Never discard in a liquid state. This material must be disposed of in accordance with all local, regional, national, international
regulations.
Other disposal recommendations:
Do not puncture or incinerate containers. Use appropriate Personal Protective Equipment.
LP PU FOAM SEALANTS 134A
ISSUE DATE: October 2010
LAST REV: April 2015
PAGE 6 OF 7
SECTION 14- TRANSPORTATION
Shipping Information
Containers 1000 cu. cm. (1 liter) or less:
Due to changes in December 2020: See shipping papers for
exact 49 CFR descriptions.
Ground
Consumer Commodity ORM-D
Limited Quantity
Air
UN1950 Aerosols, Non-Flammable 2.2 (NonFlammable Gas Label)
LIMITED QUANTITY
Packing Instructions (Cargo & Passenger) 203
UN1950 Aerosols, Non-Flammable 2.2 (Non-Flammable Gas
Label)
LIMITED QUANTITY
Packing Instructions (Cargo & Passenger) 203
Water
UN1950 Aerosols, Non-Flammable 2.2 (NonFlammable Gas Label)
LIMITED QUANTITY
UN1950 Aerosols, Non-Flammable 2.2 (Non-Flammable Gas
Label)
LIMITED QUANTITY
SECTION 15- REGULATORY
15.1 Safety, health, and environmental regulations/ legislations specific for the substance or mixture
U.S. Federal Regulations
OSHA Hazard Communication Standard: This material is classified as a hazardous in accordance with OSHA 29 CFR 1910-1200
TSCA Status: All components of this product are listed on the Toxic Substance Control Act (TSCA) Inventory. This product is not subject
to TSCA 12(b) Export Notification.
Superfund Amendments and Reauthorization Act (SARA)
SARA Section 311/312 Hazard Categories: Acute Health Hazard, Chronic Health Hazard, Reactive Hazard, Sudden Release of
Pressure Hazard
SARA 313 Information: MDI and PMDI are subject to reporting levels established by Section 313 of the Emergency Planning and
Community Right-to-Know Act of 1986.
SARA 302/304 Extremely Hazardous Substance: No components of the product exceed the threshold (de minimis) reporting levels
established by these sections of the Title III of SARA.
SARA 302/304 Emergency Planning & Notification: No components of the product exceed the threshold (de minimis) report levels
established by these sections of the Title III of SARA.
Comprehensive Response Compensation and Liability Act (CERCLA): This product contains the following CERCLA reportable
substances: 4,4’- Diphenylmethane diisocyanate (CAS #101-68-8), RQ- 2,268 kg (5,000 lbs).
Clean Air Act (CAA) - 4,4’- Diphenylmethane diisocyanate (CAS #101-68-8) is listed as a Hazardous Air Pollutant (HAP) designated in
CAA Section 112 (b). This product does not contain any Class 1 or Class 2 Ozone depletors.
Clean Water Act (CWA) - 4,4’- Diphenylmethane diisocyanate (CAS #101-68-8) is listed as a Hazardous Substance under the CWA.
None of the chemicals in these products are listed as Priority Pollutants under the CWA. None of the chemicals listed in these products
are listed as Toxic Pollutants under the CWA.
U.S. State Regulations:
California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986: This product contains trace amount of substances
known to the State of California to cause cancer or other reproductive harm.
Other U.S. State Inventories:
4, 4’- Diphenylmethane diisocyanate (CAS #101-68-8) is listed on the following State Hazardous Substance Inventories, Right-to-Know
lists and/or Air Quality/air Pollutants lists: CA, DE, ID, IL, ME, MA, MN, NJ, PA, WA, WI
Polymeric MDI (CAS #9016-87-9) is listed on the following State Hazardous Substance Inventories, Right-to-Know lists and/or Air
Quality/Air Pollutants lists: DE, NJ, MN
1,1,1,2 Tetrafluoroethane (CAS #811-97-2) is listed on the following State Hazardous Substance Inventories, Right-to-Know lists and/or Air
Quality/Air Pollutants lists: ME, WI
Canada
WHMIS Hazard Symbol and Classification:
A- Compressed Gas
D2A- Very toxic material causing other toxic effects (Respiratory Sensitizer)
D2B- Toxic Material causing other toxic effects (Skin Sensitizer) (Skin/Eye Irritant)
LP PU FOAM SEALANTS 134A
ISSUE DATE: October 2010
LAST REV: April 2015
PAGE 7 OF 7
Canada Controlled Product Regulations (CPR): This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulation, and the SDS contains all the information required by the Controlled Products Regulations.
Canadian Ingredient Disclosure List (IDL): 4,4’- Diphenylmethane diisocyanate (CAS #101-68-8) is listed on the IDL.
Canadian National Pollutant Release Inventory (NPRI): MDI and PMDI are listed on the NPRI
European Economic Community
Labeling (67/548/EEC or 1999/45/EC)
Xn- Harmful
Risk Phrases:
R20- Harmful by inhalation
R36/37/38- Irritating to eyes, respiratory system and skin
R40- Limited evidence of carcinogenic effect
R42/43- May cause sensitization by inhalation and skin contact
R48/20- Harmful: danger or serious damage to health by prolonged exposure through inhalation.
R64- May cause harm to breastfed babies
R53- May cause long-term adverse effects in the aquatic environment
Safety
S1/2- Keep locked up and out of reach of children
Phrases:
S23- Do not breathe fumes, vapor, or mist
S36/37- Wear suitable protective clothing and gloves
S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label or this SDS where
possible.
WGK, Germany (Water danger/protection): 1
Global Chemical Inventory Lists:
United States: Toxic Substance Control Act (TSCA)- Yes
Canada: Domestic Substances List (DSL)- Yes
Canada: Non-Domestic Substances List (NDSL)- No
Europe: Inventory of New and Existing Chemicals- (EINECS)- Yes
Australia: Australian Inventory of Chemical Substances (AICS)- Yes
New Zealand: New Zealand Inventory of Chemicals (NZLoC)- Yes
China: Inventory of Existing Chemical Substances in China (IECSC)- Yes
Japan: Inventory of Existing and New Chemical Substances (ENCS)- Yes
Korea: Existing Chemicals List (ECL)- Yes
15.2 Chemical safety assessment: For this product a chemical safety assessment was not carried out
SECTION 16- OTHER
NFPA: Health Hazard 2; Flammability 1; Reactivity 1
HMIS: Health Hazard 2; Flammability 1; Physical Hazard 1
Hazard Rating: 0=minimal, 1= slight, 2=moderate, 3=severe, 4= extreme
The information and recommendations set forth herein are presented in good faith and believed to be correct as of the date hereof. The
manufacturer makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the
persons receiving it will make their own determination as to its suitability for their purposes prior to use. In no event will the manufacturer
be responsible for damages of any nature whatsoever resulting from the use of or reliance upon information. No representations or
warranties, either expressed or implied, of merchantability or fitness for a particular use are made hereunder with respect to this information
or the product to which information refers.
Information contained herein is deemed to be reliable, conservative and accurate. Fomo Products, Inc. reserves the right to change the
design, specifications or any other features at any time and without notice, while otherwise maintaining regulatory compliance.
Revision-April 13, 2015 Version 2.0 (Replaces Version 1.7- June 25, 2012)
Was this manual useful for you? yes no
Thank you for your participation!

* Your assessment is very important for improving the work of artificial intelligence, which forms the content of this project

Download PDF

advertisement