SAFETY DATA SHEET 1. Identification

SAFETY DATA SHEET 1. Identification
SAFETY DATA SHEET
1. Identification
Product number
1000002536
Product identifier
40 CT GRAFFITI-WIPE 6PK
Company information
WALTER E NELSON CO
5937 N CUTTER CIRCLE
PORTLAND, OR 97217 United States
1-866-836-8855
Emergency telephone US
Emergency telephone outside
US
1-952-852-4646
Version #
01
Recommended use
Not available.
Recommended restrictions
None known.
2. Hazard(s) identification
Physical hazards
Not classified.
Health hazards
Acute toxicity, inhalation
Category 4
Serious eye damage/eye irritation
Category 1
Specific target organ toxicity, single exposure Category 3 respiratory tract irritation
Environmental hazards
Not classified.
OSHA defined hazards
Not classified.
Label elements
Signal word
Danger
Hazard statement
Causes serious eye damage. Harmful if inhaled. May cause respiratory irritation.
Precautionary statement
Prevention
Avoid breathing mist or vapor. Use only outdoors or in a well-ventilated area. Wear eye/face
protection.
Response
If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Immediately call a poison center/doctor.
Storage
Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal
Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information
None.
3. Composition/information on ingredients
Mixtures
Chemical name
Common name and synonyms
CAS number
%
1119-40-0
20 - 40
Ethyl lactate
97-64-3
20 - 40
Dimethyl Succinate
106-65-0
10 - 20
Dimethyl adipate
627-93-0
2.5 - 10
Dimethyl Glutarate
Other components below reportable levels
20 - 40
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
Product name: 40 CT GRAFFITI-WIPE 6PK
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4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or
artificial respiration if needed. Call a POISON CENTER or doctor/physician if you feel unwell.
Wash off with soap and water. Get medical attention if irritation develops and persists.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention immediately.
Rinse mouth. Get medical attention if symptoms occur.
Most important
symptoms/effects, acute and
delayed
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
vision. Permanent eye damage including blindness could result. May cause respiratory irritation.
Indication of immediate
medical attention and special
treatment needed
Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim
under observation. Symptoms may be delayed.
General information
If you feel unwell, seek medical advice (show the label where possible). Ensure that medical
personnel are aware of the material(s) involved, and take precautions to protect themselves.
5. Fire-fighting measures
Suitable extinguishing media
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing
media
Do not use water jet as an extinguisher, as this will spread the fire.
Specific hazards arising from
the chemical
During fire, gases hazardous to health may be formed.
Special protective equipment
and precautions for firefighters
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Fire-fighting
equipment/instructions
Move containers from fire area if you can do so without risk.
Specific methods
Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards
No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation
of vapors and spray mists. Do not touch damaged containers or spilled material unless wearing
appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if
significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth
and place into containers. Prevent entry into waterways, sewer, basements or confined areas.
Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Environmental precautions
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Do not get this material in contact with eyes. Avoid inhalation of vapors and spray mists. Use only
outdoors or in a well-ventilated area. Wear appropriate personal protective equipment. Observe
good industrial hygiene practices.
Store locked up. Store in original tightly closed container. Store in a well-ventilated place. Store
away from incompatible materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
No exposure limits noted for ingredient(s).
Biological limit values
No biological exposure limits noted for the ingredient(s).
Product name: 40 CT GRAFFITI-WIPE 6PK
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Appropriate engineering
controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Provide
eyewash station.
Individual protection measures, such as personal protective equipment
Chemical respirator with organic vapor cartridge and full facepiece.
Eye/face protection
Hand protection
Wear appropriate chemical resistant gloves.
Skin protection
Other
Wear suitable protective clothing.
Respiratory protection
Chemical respirator with organic vapor cartridge and full facepiece.
Thermal hazards
Wear appropriate thermal protective clothing, when necessary.
General hygiene
considerations
Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Physical state
Liquid.
Form
Premoistened towel
Color
Not available.
Odor
Not available.
Odor threshold
Not available.
pH
Not available.
Melting point/freezing point
Not available.
Initial boiling point and boiling
range
337.62 °F (169.79 °C) estimated
Flash point
163.0 °F (72.8 °C) Closed Cup SUPPLIER estimated
Evaporation rate
Not available.
Flammability (solid, gas)
Not available.
Upper/lower flammability or explosive limits
Not available.
Flammability limit - lower
(%)
Flammability limit - upper
(%)
Not available.
Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure
2.23 psig @70F estimated
Vapor density
Not available.
Relative density
Not available.
Solubility(ies)
Solubility (water)
Not available.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature
Not available.
Decomposition temperature
Not available.
Viscosity
Not available.
Other information
Specific gravity
1.03 SUPPLIER estimated
10. Stability and reactivity
Reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability
Material is stable under normal conditions.
Product name: 40 CT GRAFFITI-WIPE 6PK
Product #: 1000002536 Version #: 01 Issue date: 02-17-2015
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Possibility of hazardous
reactions
Hazardous polymerization does not occur.
Conditions to avoid
Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Incompatible materials
Strong oxidizing agents.
Hazardous decomposition
products
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Expected to be a low ingestion hazard.
Ingestion
Inhalation
Harmful if inhaled.
Skin contact
No adverse effects due to skin contact are expected.
Eye contact
Causes serious eye damage.
Symptoms related to the
physical, chemical and
toxicological characteristics
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
vision. Permanent eye damage including blindness could result. May cause respiratory irritation.
Information on toxicological effects
Acute toxicity
Harmful if inhaled. May cause respiratory irritation.
Components
Species
Test Results
Rabbit
> 1000 mg/kg, 24 Hours
Rat
> 2000 mg/kg, 24 Hours
Rat
> 11 mg/l, 4 Hours
Acute
Dermal
LD50
Rat
> 2000 mg/kg, 24 Hours
Inhalation
LC50
Rat
> 11 mg/l, 4 Hours
Acute
Dermal
LD50
Rat
> 2000 mg/kg, 24 Hours
Oral
LD50
Rat
6892 mg/kg
Dimethyl adipate (CAS 627-93-0)
Acute
Dermal
LD50
Inhalation
LC50
Dimethyl Glutarate (CAS 1119-40-0)
Dimethyl Succinate (CAS 106-65-0)
* Estimates for product may be based on additional component data not shown.
Prolonged skin contact may cause temporary irritation.
Skin corrosion/irritation
Serious eye damage/eye
irritation
Causes serious eye damage.
Respiratory or skin sensitization
Not available.
Respiratory sensitization
Skin sensitization
This product is not expected to cause skin sensitization.
Germ cell mutagenicity
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
This product is not expected to cause reproductive or developmental effects.
Reproductive toxicity
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Product #: 1000002536 Version #: 01 Issue date: 02-17-2015
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Specific target organ toxicity single exposure
May cause respiratory irritation.
Specific target organ toxicity repeated exposure
Not classified.
Aspiration hazard
Not available.
12. Ecological information
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Ecotoxicity
Components
Species
Test Results
EC50
Daphnia
142.8 mg/L, 48 Hours
Aquatic
Crustacea
EC50
Water flea (Daphnia magna)
560 - 763 mg/l, 48 hours
Fish
LC50
Zebra danio (Danio rerio)
305 - 417 mg/l, 96 hours
Dimethyl Glutarate (CAS 1119-40-0)
Aquatic
Crustacea
Ethyl lactate (CAS 97-64-3)
* Estimates for product may be based on additional component data not shown.
No data is available on the degradability of this product.
Persistence and degradability
Bioaccumulative potential
No data available.
Partition coefficient n-octanol / water (log Kow)
Dimethyl adipate
Dimethyl Succinate
No data available.
Mobility in soil
Other adverse effects
1.03
0.35
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions
Local disposal regulations
Hazardous waste code
Waste from residues / unused
products
Contaminated packaging
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
14. Transport information
DOT
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Special precautions for user
Special provisions
Packaging exceptions
Packaging non bulk
Packaging bulk
IATA
UN number
UN proper shipping name
UN1192
Ethyl lactate, solution (Ethyl lactate)
3
3
III
Read safety instructions, SDS and emergency procedures before handling.
B1, IB3, T2, TP1
150
203
242
UN1192
Ethyl lactate solution (Ethyl lactate)
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Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Environmental hazards
ERG Code
Special precautions for user
Other information
Passenger and cargo
aircraft
Cargo aircraft only
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Environmental hazards
Marine pollutant
EmS
Special precautions for user
Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
3
3
III
No.
3L
Read safety instructions, SDS and emergency procedures before handling.
Allowed.
Allowed.
UN1192
ETHYL LACTATE SOLUTION (Ethyl lactate)
3
3
III
No.
F-E, S-D
Read safety instructions, SDS and emergency procedures before handling.
This substance/mixture is not intended to be transported in bulk.
DOT
IATA; IMDG
15. Regulatory information
US federal regulations
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
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OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - Yes
Hazard categories
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
No
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Not regulated.
Safe Drinking Water Act
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Ethyl lactate (CAS 97-64-3)
US. New Jersey Worker and Community Right-to-Know Act
Ethyl lactate (CAS 97-64-3)
US. Pennsylvania Worker and Community Right-to-Know Law
Ethyl lactate (CAS 97-64-3)
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region
Australia
Inventory name
Australian Inventory of Chemical Substances (AICS)
On inventory (yes/no)*
Yes
Canada
Domestic Substances List (DSL)
Canada
Non-Domestic Substances List (NDSL)
China
Inventory of Existing Chemical Substances in China (IECSC)
Yes
Europe
European Inventory of Existing Commercial Chemical
Substances (EINECS)
Yes
Europe
European List of Notified Chemical Substances (ELINCS)
No
Japan
Inventory of Existing and New Chemical Substances (ENCS)
No
Yes
No
Korea
Existing Chemicals List (ECL)
Yes
New Zealand
New Zealand Inventory
Yes
Philippines
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
United States & Puerto Rico
Toxic Substances Control Act (TSCA) Inventory
No
Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date
02-17-2015
Version #
01
Product name: 40 CT GRAFFITI-WIPE 6PK
Product #: 1000002536 Version #: 01 Issue date: 02-17-2015
SDS US
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Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Product name: 40 CT GRAFFITI-WIPE 6PK
Product #: 1000002536 Version #: 01 Issue date: 02-17-2015
SDS US
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