PPG PRL91 - Green Powder Pearl (English)

PPG PRL91 - Green Powder Pearl (English)
SAFETY DATA SHEET
Date of issue/Date of revision
27 August 2015
Version 3.01
Section 1. Identification
Product name
: GREEN PEARL
Product code
: PRL91
Other means of
identification
: Not available.
Product type
: Powder.
Relevant identified uses of the substance or mixture and uses advised against
Product use
: Industrial applications.
Use of the substance/
mixture
: Coating. Paints. Painting-related materials.
Uses advised against
: Not applicable.
Supplier
Emergency telephone
number
Technical Phone Number
: PPG Industries, Inc.
One PPG Place,
Pittsburgh, PA 15272
: (412) 434-4515 (U.S.)
(514) 645-1320 (Canada)
01-800-00-21-400 (Mexico)
: 1-800-647-6050
Section 2. Hazards identification
OSHA/HCS status
Classification of the
substance or mixture
: This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
: COMBUSTIBLE DUSTS
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 99.1%
GHS label elements
Hazard pictograms
:
Signal word
: Warning
Hazard statements
: May form combustible dust concentrations in air.
May cause respiratory irritation.
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Section 2. Hazards identification
Precautionary statements
Prevention
: Use only outdoors or in a well-ventilated area. Avoid breathing dust.
Response
: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a
POISON CENTER or physician if you feel unwell.
: Store locked up.
Storage
Disposal
Supplemental label
elements
Hazards not otherwise
classified
: Dispose of contents and container in accordance with all local, regional, national and
international regulations.
: Keep container tightly closed. Keep away from heat, sparks, open flames and hot
surfaces. - No smoking. Prevent dust accumulation. Avoid contact with skin and clothing.
Wash thoroughly after handling. Emits toxic fumes when heated.
: Fine dust clouds may form explosive mixtures with air. Handling and/or processing of
this material may generate a dust which can cause mechanical irritation of the eyes,
skin, nose and throat. Prolonged or repeated contact may dry skin and cause irritation.
Section 3. Composition/information on ingredients
Substance/mixture
: Mixture
Product name
: GREEN PEARL
Ingredient name
Mica-group minerals
Naphtha (petroleum), heavy alkylate
%
≥25 - <50
≥5 - <10
CAS number
12001-26-2
64741-65-7
SUB codes represent substances without registered CAS Numbers.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First aid measures
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Description of necessary first aid measures
Eye contact
Inhalation
Skin contact
Ingestion
: Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids
apart for at least 10 minutes and seek immediate medical advice.
: Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
: If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.
Most important symptoms/effects, acute and delayed
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Section 4. First aid measures
Potential acute health effects
Eye contact
Inhalation
: Exposure to airborne concentrations above statutory or recommended exposure limits
may cause irritation of the eyes.
: May cause respiratory irritation.
Skin contact
: Defatting to the skin. May cause skin dryness and irritation.
Ingestion
: No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact
Inhalation
Skin contact
Ingestion
: Adverse symptoms may include the following:
irritation
redness
: Adverse symptoms may include the following:
respiratory tract irritation
coughing
: Adverse symptoms may include the following:
irritation
dryness
cracking
: No specific data.
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician
: Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments
: No specific treatment.
Protection of first-aiders
: No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Extinguishing media
Suitable extinguishing
media
: Use dry chemical powder.
Unsuitable extinguishing
media
: Do not use water jet.
Specific hazards arising
from the chemical
Hazardous thermal
decomposition products
: Fine dust clouds may form explosive mixtures with air.
: Decomposition products may include the following materials:
metal oxide/oxides
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Section 5. Fire-fighting measures
Special protective actions
for fire-fighters
Special protective
equipment for fire-fighters
: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
: Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency
personnel
: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing dust. Provide adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Put on
appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Environmental precautions
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
Small spill
Large spill
: Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Avoid dust generation. Using a vacuum with HEPA filter will reduce dust dispersal.
Place spilled material in a designated, labeled waste container. Dispose of via a
licensed waste disposal contractor.
: Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Approach release from upwind. Prevent entry into sewers, water courses, basements
or confined areas. Avoid dust generation. Do not dry sweep. Vacuum dust with
equipment fitted with a HEPA filter and place in a closed, labeled waste container.
Avoid creating dusty conditions and prevent wind dispersal. Dispose of via a licensed
waste disposal contractor. Note: see Section 1 for emergency contact information and
Section 13 for waste disposal.
Section 7. Handling and storage
Precautions for safe handling
Protective measures
: Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid
contact with eyes, skin and clothing. Avoid breathing dust. Avoid the creation of dust
when handling and avoid all possible sources of ignition (spark or flame). Prevent dust
accumulation. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Keep in the original container or an approved alternative
made from a compatible material, kept tightly closed when not in use. Electrical
equipment and lighting should be protected to appropriate standards to prevent dust
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Product code PRL91
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Product name GREEN PEARL
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
coming into contact with hot surfaces, sparks or other ignition sources. Take
precautionary measures against electrostatic discharges. To avoid fire or explosion,
dissipate static electricity during transfer by grounding and bonding containers and
equipment before transferring material. Empty containers retain product residue and
can be hazardous. Do not reuse container.
: Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
: Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.
Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
Ingredient name
Exposure limits
Mica-group minerals
ACGIH TLV (United States, 4/2014).
TWA: 3 mg/m³ 8 hours. Form: Respirable
fraction
OSHA PEL Z3 (United States, 2/2013).
TWA: 20 mppcf 8 hours.
None.
Naphtha (petroleum), heavy alkylate
A
ACGIH
C
F
IPEL
OSHA
R
Z
=
=
=
=
=
=
=
=
Key to abbreviations
Acceptable Maximum Peak
American Conference of Governmental Industrial Hygienists.
Ceiling Limit
Fume
Internal Permissible Exposure Limit
Occupational Safety and Health Administration.
Respirable
OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances
S
SR
SS
STEL
TD
TLV
TWA
=
=
=
=
=
=
=
Potential skin absorption
Respiratory sensitization
Skin sensitization
Short term Exposure limit values
Total dust
Threshold Limit Value
Time Weighted Average
Consult local authorities for acceptable exposure limits.
Recommended monitoring
procedures
: If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
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Product code PRL91
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Product name GREEN PEARL
Section 8. Exposure controls/personal protection
Appropriate engineering
controls
Environmental exposure
controls
: Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor
or mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits. The engineering controls also need to keep gas, vapor or dust concentrations
below any lower explosive limits. Use explosion-proof ventilation equipment.
: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Individual protection measures
Hygiene measures
Eye/face protection
Skin protection
Hand protection
Body protection
Other skin protection
Respiratory protection
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
: Safety glasses with side shields.
: Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
: Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
: Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
: Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.
Section 9. Physical and chemical properties
Appearance
Physical state
: Solid.
Color
: Not available.
Odor
Melting point
: Not available.
: Not available.
: Not available.
: Not available.
Boiling point
: Not available.
Flash point
: Closed cup: Not applicable.
Odor threshold
pH
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Product code PRL91
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Section 9. Physical and chemical properties
Material supports
combustion.
Auto-ignition temperature
: Yes.
Decomposition temperature
Flammability (solid, gas)
: Not available.
: Not available.
Lower and upper explosive
(flammable) limits
Evaporation rate
: Lower: 1%
Vapor pressure
: 0.13 kPa (1 mm Hg) [room temperature]
Vapor density
Relative density
: Not available.
: 2.52
Density ( lbs / gal )
: 21.03
Solubility
: Insoluble in the following materials: cold water.
Partition coefficient: noctanol/water
: Not available.
Viscosity
: Kinematic (40°C (104°F)): Not applicable.
Volatility
: 33% (v/v), 10% (w/w)
% Solid. (w/w)
: 90
: Not available.
: 0.1 (butyl acetate = 1)
Section 10. Stability and reactivity
Reactivity
: No specific test data related to reactivity available for this product or its ingredients.
Chemical stability
: The product is stable.
Possibility of hazardous
reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid
: When exposed to high temperatures may produce hazardous decomposition products.
Refer to protective measures listed in sections 7 and 8.
Incompatible materials
: Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.
Hazardous decomposition
products
: Decomposition products may include the following materials: carbon monoxide, carbon
dioxide, smoke, oxides of nitrogen.
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Product code PRL91
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Product name GREEN PEARL
Section 11. Toxicological information
Information on toxicological effects
Acute toxicity
Conclusion/Summary
: There are no data available on the mixture itself.
Irritation/Corrosion
Conclusion/Summary
Skin
Eyes
Respiratory
Sensitization
: There are no data available on the mixture itself.
: There are no data available on the mixture itself.
: There are no data available on the mixture itself.
Conclusion/Summary
Skin
: There are no data available on the mixture itself.
Respiratory
: There are no data available on the mixture itself.
Mutagenicity
Conclusion/Summary
: There are no data available on the mixture itself.
Carcinogenicity
Conclusion/Summary
: There are no data available on the mixture itself.
Reproductive toxicity
Conclusion/Summary
: There are no data available on the mixture itself.
Teratogenicity
Conclusion/Summary
: There are no data available on the mixture itself.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Target organs
: Contains material which causes damage to the following organs: brain, central nervous
system (CNS).
Contains material which may cause damage to the following organs: lungs, upper
respiratory tract.
Aspiration hazard
Name
Result
Naphtha (petroleum), heavy alkylate
ASPIRATION HAZARD - Category 1
Information on the likely routes of exposure
Potential acute health effects
Eye contact
: Exposure to airborne concentrations above statutory or recommended exposure limits
may cause irritation of the eyes.
Inhalation
: May cause respiratory irritation.
Skin contact
: Defatting to the skin. May cause skin dryness and irritation.
Ingestion
: No known significant effects or critical hazards.
Over-exposure signs/symptoms
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Product name GREEN PEARL
Section 11. Toxicological information
Eye contact
: Adverse symptoms may include the following:
irritation
redness
Inhalation
: Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact
: Adverse symptoms may include the following:
irritation
dryness
cracking
Ingestion
: No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure
Conclusion/Summary
: There are no data available on the mixture itself. Exposure to component solvent vapor
concentrations in excess of the stated occupational exposure limit may result in adverse
health effects such as mucous membrane and respiratory system irritation and adverse
effects on the kidneys, liver and central nervous system. Symptoms and signs include
headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases,
loss of consciousness. Solvents may cause some of the above effects by absorption
through the skin. There is some evidence that repeated exposure to organic solvent
vapors in combination with constant loud noise can cause greater hearing loss than
expected from exposure to noise alone. Repeated exposure of the eyes to a low level
of dust can produce eye irritation. Repeated or prolonged inhalation of dust may lead to
chronic respiratory irritation. Ingestion may cause nausea, diarrhea and vomiting. This
takes into account, where known, delayed and immediate effects and also chronic
effects of components from short-term and long-term exposure by oral, inhalation and
dermal routes of exposure and eye contact.
Short term exposure
Potential immediate
: There are no data available on the mixture itself.
effects
Potential delayed effects : There are no data available on the mixture itself.
Long term exposure
Potential immediate
: There are no data available on the mixture itself.
effects
Potential delayed effects : There are no data available on the mixture itself.
Potential chronic health effects
General
: Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation.
Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or
dermatitis.
Carcinogenicity
: No known significant effects or critical hazards.
Mutagenicity
: No known significant effects or critical hazards.
Teratogenicity
: No known significant effects or critical hazards.
Developmental effects
: No known significant effects or critical hazards.
Fertility effects
: No known significant effects or critical hazards.
Numerical measures of toxicity
Acute toxicity estimates
Not available.
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Product name GREEN PEARL
Section 12. Ecological information
Toxicity
Not available.
Persistence and degradability
Not available.
Bioaccumulative potential
Not available.
Mobility in soil
Soil/water partition
coefficient (KOC)
: Not available.
Section 13. Disposal considerations
Disposal methods
: The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
14. Transport information
DOT
IMDG
IATA
UN number
Not regulated.
Not regulated.
Not regulated.
UN proper shipping
name
-
-
-
Transport hazard class (es)
-
-
Packing group
-
-
Environmental hazards No.
No.
No.
Marine pollutant
substances
Not applicable.
Not applicable.
Not applicable.
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Product code PRL91
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Product name GREEN PEARL
14. Transport information
Additional information
DOT
: None identified.
IMDG
IATA
: None identified.
: None identified.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
Section 15. Regulatory information
United States
United States inventory (TSCA 8b) : All components are listed or exempted.
U.S. Federal regulations
SARA 302/304
SARA 304 RQ
:
: Not applicable.
Composition/information on ingredients
No products were found.
SARA 311/312
Classification
: Fire hazard
Immediate (acute) health hazard
Composition/information on ingredients
Name
Fire
Sudden
hazard release of
pressure
Reactive
Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Naphtha (petroleum), heavy alkylate
Yes.
No.
Yes.
No.
No.
-
Additional environmental information is contained on the Environmental Data Sheet for this product, which
can be obtained from your PPG representative.
Section 16. Other information
Hazardous Material Information System (U.S.A.)
Health
:
2
Flammability :
0
Physical hazards :
0
( * ) - Chronic effects
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are
to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS®
materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
National Fire Protection Association (U.S.A.)
Health
:
2
Flammability :
0
Instability
:
0
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Product code PRL91
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Product name GREEN PEARL
Section 16. Other information
Date of previous issue
: 8/21/2015
Organization that prepared
the MSDS
: EHS
Key to abbreviations
: ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Indicates information that has changed from previously issued version.
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.
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