SAFETY DATA SHEET SPOTMASTER PRO XP

SAFETY DATA SHEET SPOTMASTER PRO XP
SAFETY DATA SHEET
SPOTMASTER PRO XP
SECTION 1- PRODUCT IDENTIFICATION
PRODUCT NAME
SYNONYMS
PRODUCT USE
SUPPLIER
SUPPLIER’S ADDRESS
:
:
:
:
:
EMERGENCY RESPONSE PHONE
:
SPOTMASTER PRO XP
Product is a mixture: No synonyms are available.
Moderately Alkaline Material
HYDRAMASTER CORP.
11015 47TH AVE W, MUKILTEO, WA 98275
(425) 776-7272
PERS: 1-800-633-8253
SECTION 2 – HAZARD IDENTIFICATION
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE
GHS U.S. – CLASSIFICATION
: H302
Harmful if swallowed.
: H315
Causes skin irritation
: H319
Causes serious eye irritation
LABEL ELEMENTS
:
HAZARD PICTOGRAMS
:
SIGNAL WORD
HAZARD STATEMENTS
(GHS-US)
:
:
WARNING
:
:
:
H302
H315
H319
Harmful if swallowed.
Causes skin irritation.
Causes serious eye irritation.
:
P101
If medical advice is needed, have product container or label at hand.
:
:
:
:
:
P102
P103
P264
P270
P280
:
:
:
:
P301+
P312
P302+P352
P305+351+
P338
P332+P313
P337+P313
P501
Keep out of reach of children.
Read label before use.
Wash skin and contaminated clothing thoroughly after handling.
Do not eat, drink or smoke when using this product.
Wear suitable protective gloves/protective clothing/eye
protection/face protection.
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel
unwell.
: IF ON SKIN: Wash with plenty of soap and water.
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Dispose of contents/container in accordance with
local/regional/national/international regulations
:
:
:
NFPA/HMIS Definitions: 0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme.
Health = 2, Fire = 0, Reactivity = 0
Health = 2, Fire = 0, Reactivity = 0
PRECAUTIONARY STATEMENTS
(GHS-US)
:
:
CLASSIFICATION SYSTEM
NFPA RATINGS (SCALE 0-4)
HMIS RATINGS (SCALE 0-5)
GHS – US HAZARD PICTOGRAMS
The product is classified and labeled according
to the Globally Harmonized System (GHS).
Not established
PAGE 1 of 8
SAFETY DATA SHEET
SPOTMASTER PRO XP
SECTION 3 – COMPOSITON/INFORMATION ON INGREDIENTS
CHEMICAL CHARACTERISTIC
DESCRIPTION
:
:
Mixtures
Mixture of the substances listed below with nonhazardous additions.
COMPONENT
Diethylene Glycol Monobutyl Ether
Isopropanol (Isopropyl alcohol)
PERCENT
1-5
1-5
CAS #
112-34-5
67-63-0
EINECS #
203-961-6
200-661-7
GHS CLASSIFICATION
Eye Irrit Cat 2B
Eye Irrit Cat 2, Flam Liq Cat 2
STOT SE Cat 3
Triethanolamine
1-5
102-71-6
203-049-8
Skin Irrit Cat 2, Eye Dam Cat 1,
STOT-RE Cat 2 (Oral)
Sodium Octane Sulfonate
1-5
5324-84-5
226-195-4
Skin Irrit Cat 2, Eye Irrit Cat 2A
STOT SE Cat 3
Sodium Lauryl Sulfate
0.1-1
151-21-3
205-788-1
Skin Irrit Cat 2, Eye Irrit Cat 2A,
Acute Tox Oral Cat 4, Aquatic Tox Cat 2
Propanediol
1-5
2163-42-0
412-350-5
Not Classified under GHS
Sodium Thiosulfate
1-5
7772-98-7
231-867-5
Not Classified under GHS
Irrit. = Irritation, Corr. = Corrosion, Cat. = Category, Dam = Damage, Tox = Toxic, STOT RE = Single Target Organ Toxicity
Repeated exposure.
SECTION 4 – FIRST AID MEASURES
DESCRIPTION OF FIRST AID MEASURES
GENERAL
: Never give anything by mouth to an unconscious person. If you feel unwell, seek
medical advice. Show the label where possible.
EYE CONTACT
: Immediately flush eyes with water for at least 15 minutes. Hold eyelids open to
ensure adequate flushing. Get immediate medical attention.
SKIN CONTACT
: Remove contaminated clothing and shoes. Wash affected skin area with soap and
water. Delayed skin damage is possible if product is not completely washed off. Get
immediate medical attention.
SWALLOWING (INGESTION)
: If ingested, dilute swallowed material by drinking water. DO NOT INDUCE VOMITING.
If vomiting occurs spontaneously, keep airway clear. Give more water when vomiting
stops. Never give anything by mouth to an unconscious person. Get immediate
medical attention.
INHALATION
: Remove to fresh air. Get immediate medical attention.
OTHER INSTRUCTIONS
: Rescue personnel must wear appropriate protective equipment during removal of
victims from contaminated areas. Treat symptomatically and supportively.
SECTION 5 – FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
SPECIAL PROTECTIVE
EQUIPMENT AND
PRECAUTIONS FOR FIRE
FIGHTERS
UNUSUAL FIRE AND
EXPLOSION HAZARDS
:
:
Dry chemical, foam, water or carbon dioxide.
In the event of a fire, wear a NIOSH (USA) or CEN (EU) approved, positive pressure,
self-contained breathing apparatus (SCUBA) and full protective clothing. Evacuate all
non-essential personnel from the danger area.
:
No further relevant information is available.
SECTION 6 – ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS,
PROTECTIVE EQUIPMENT &
EMERGENCY PROCEDURES
:
Restrict access to keep out unauthorized or unprotected personnel. Wear protective
equipment. Avoid inhalation and direct contact.
PAGE 2 of 8
SAFETY DATA SHEET
SPOTMASTER PRO XP
ENVIRONMENTAL PROCEDURES
METHODS AND MATERIALS
FOR CONTAINMENT AND
CLEAN-UP
:
:
Keep spilled material away from sewage/drainage systems and waterways.
All clean-up personnel must be properly trained. Confine the spill and remove
incompatible materials and ignition sources. Ensure adequate ventilation. Secure the
source of the leak if conditions are safe. Neutralize spill and collect using an
appropriate absorbent material such as clay or vermiculite. Place waste in an
appropriate container for disposal. Use care during clean-up to avoid exposure to
the material and injury from broken containers.
SECTION 7 – HANDLING AND STORAGE
PRECAUTIONS FOR SAFE
HANDLING
:
CONDITIONS FOR SAFE
STORAGE
:
Use with adequate ventilation. Wear proper protective equipment. Do not mix with
water or acids without proper dilution and agitation to prevent a potentially violent
reaction.
Store in closed, properly labeled containers. Protect containers from heat, physical
damage, ignition sources and incompatible materials. Have emergency equipment
for fires and spills readily available.
SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION
TLV (THRESHOLD LIMIT VALUE)
:
COMPONENT
Diethylene Glycol Monobutyl Ether
Isopropanol (Isopropyl alcohol)
Triethanolamine
Sodium Octane Sulfonate
Sodium Lauryl Sulfate
Propanediol
Sodium Thiosulfate
The TLV in section in section III is the ACGIH/TLV-TWA (threshold limit value/time
weighted average concentration for an eight hour work day). The STEL is the short
term exposure limit and the (Ceil) is the ceiling limit.
OSHA PEL – TWA
Not Established
400 ppm
Not Established
Not Established
Not Established
Not Established
Not Established
EYE PROTECTION
SKIN PROTECTION
:
:
RESPIRATORY PROTECTION
:
VENTILATION
ADDITIONAL MEASURES
:
:
REQUIRED WORK/HYGIENE
:
ACGIH – TLV
Not Established
200 ppm
Not Established
Not Established
Not Established
Not Established
Not Established
Wear chemical splash goggles or face shield.
Minimize contact with product. Wear chemical resistant coveralls, boots, gloves,
apron and/or suitable long-sleeved clothing.
In case of brief exposure use respiratory filter device. In case of intensive or longer
exposure, use respiratory protective device that is independent of circulating air.
Ensure adequate ventilation.
Emergency eyewash and safety shower facilities should be available in the
immediate work area.
Wash hands thoroughly after handling. Keep away from all food stuffs, beverages
and feed. Do not eat, drink or smoke in work area.
SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
ODOR
ODOR THRESHOLD
PH
:
:
:
:
ACGIH – STEL
Not Established
400 ppm
Not Established
Not Established
Not Established
Not Established
Not Established
Clear light amber liquid with mild odor
Not available
10.5 + 0.5 AS IS
PAGE 3 of 8
SAFETY DATA SHEET
SPOTMASTER PRO XP
MELTING POINT/FREEZING
POINT
BOILING POINT
FLASH POINT
EVAPORATION RATE
FLAMMABILITY
LOWER FLAMMABILITY LIMIT
UPPER FLAMMABILITY LIMIT
VAPOR PRESSURE
VAPOR DENSITY (AIR=1)
RELATIVE DESNITY
SOLUBILITY IN WATER
PARTITION COEFFICIENT nOCTANOL/WATER
AUTOIGNITION TEMPERATURE
DECOMPOSITION
TEMPERATURE
:
Not available
:
:
:
:
:
:
:
:
:
:
:
Not available.
Not available.
Not available
Non flammable-Non combustible
Not available
Not available
Not available
Not available
1.01
Soluble in water
Not available
:
:
Not available
Not available
SECTION 10 – STABILITY AND REACTIVITY
STABILITY
HAZARDOUS CONDITONS TO
AVOID
INCOMPATIBLE MATERIALS
HAZARDOUS DECOMPOSITION
PRODUCTS
:
:
Stable under recommended storage conditions.
No decomposition if used according to specifications
:
:
Keep away from strong acids.
No dangerous decomposition products known.
SECTION 11 – TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
CHRONIC EFFECTS
SENSITISATION
CARCINOGENICITY
: Diethylene Glycol Monobutyl Ether
: Oral LD50 Oral (rat): 5560 mg/kg. LC50 dermal and inhalation: Not listed.
: Prolonged absorption causes liver and kidney damage, and red cell haemolysis
(blood in urine) in laboratory animals; no such effects have been seen in humans
: Not a sensitizer.
No component of this product present at levels greater than or equal to 0.1% is
identified as probable or confirmed human carcinogen by IARC, ACGIH, NTP, and
OSHA.
TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
:
:
OTHER INFORMATION EYES
:
OTHER INFORMATION
INGESTION
:
OTHER INFORMATION
INHALATION
:
OTHER INFORMATION SKIN
:
STOT SINGLE EXPSOSURE
:
Isopropanol (Isopropyl Alcohol)
LD50 Oral (rat): 5045 mg/kg. LD50 Dermal (rabbit): 12,800 mg/kg. LC50 Inhalation
(rat) 8hr: 16,000 mg/kg.
Produces irritation, characterized by a burning sensation, redness, tearing,
inflammation, and possible corneal injury. May cause transient corneal injury
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause
kidney damage. May cause central nervous system depression, characterized by
excitement, followed by headache, dizziness, drowsiness, and nausea.
Inhalation of high concentrations may cause central nervous system effects
characterized by nausea, headache, dizziness, unconsciousness and coma. May
cause narcotic effects in high concentration. Causes upper respiratory tract
irritation. Inhalation of vapors may cause drowsiness and dizziness.
May cause irritation with pain and stinging, especially if the skin is abraded.
Isopropanol has a low potential to cause allergic skin reactions; however, rare cases
of allergic contact dermatitis have been reported.
Inhalation - May cause drowsiness or dizziness. - Central Nervous System.
PAGE 4 of 8
SAFETY DATA SHEET
SPOTMASTER PRO XP
CARCINOGENICITY
:
IARC: Group 3: Not classifiable as to its carcinogenicity to humans. No component of
this product, present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by ACGIH, NTP or OSHA.
TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
:
:
CHRONIC EFFECTS ON HUMANS
:
OTHER TOXIC EFFECDTS ON
HUYMANS
SPECIAL REMARKS ON TOXICITY
TO ANIMALS
SPECIAL REMARKS ON CHRONIC
EFFECTS ON HUMANS
:
Triethanolamine
ORAL (LD50): Acute: 2200 mg/kg [Guinea pig]. 5846 mg/kg [Mouse]. 2200 mg/kg
[Rabbit].
CARCINOGENIC EFFECTS: 3 (Not classifiable for human.) by IARC. MUTAGENIC
EFFECTS: Mutagenic for mammalian somatic cells. May cause damage to the
following organs: kidneys, liver, skin.
Hazardous in case of skin contact (permeator), of ingestion, of inhalation. Slightly
hazardous in case of skin contact (irritant)
LD50 [Rat] - Route: Oral; Dose: 4920 ul/kg LD50 [Rabbit] - Route: Skin; Dose:
>20ml/kg
May cause cancer (tumorigenic) based on animal data. May affect genetic material
(mutagen): cytogenic analysis (human lymphocyte) = 100 umol/L; sister chromatid
exchange (human lymphocyte) = 1mmol/L.
TOXICOLOGICAL INFORMATION
ACUTE TOXICITY IRRITATION
INHALATION
CARCINOGENICITY
:
:
TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
:
:
MUTAGENICITY
IRRITATION
CARCINOGENICITY
:
:
:
TOXICOLOGICAL INFORMATION
ROUTES OF ENTRY
TOXICITY TO ANIMALS
CHRONIC EFFECTS ON HUMANS
OTHER TOXIC EFFECTS ON
HUMANS
SPECIAL REMARKS ON TOXICITY
TO ANIMNALS
SPECIAL REMARKS ON CHRONIC
EFFECTS ON HUMANS
SPECIAL REMARKS ON OTHER
TOXIC EFFECTS ON HUMANS
:
:
:
:
:
TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
CARCINOGENICITY
MUTAGENICITY
SENSITISATION
:
:
:
Sodium Octane Sulfonate
Inhalation may cause pain in respiratory system, sneezing coughing and difficulty in
breathing.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP or OSHA.
Sodium Lauryl Sulfate
LD50 Oral (rat): 1280 mg/kg, LD50 Dermal (rabbit): 580 mg/kg, LC50 Inhalation (rat)
1h: 3900 mg/m3.
Mutagenic for bacteria and/or yeast.
May cause respiratory irritation.
No components of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC, ACGIH,
NTP and OSHA.
:
Propanediol
Eye contact
LD50: Not available. LC50: Not available.
Not available.
Hazardous in case of skin contact (irritant). Slightly hazardous in case of skin contact
(sensitizer, permeator).
Not available.
:
Not available.
:
Not available.
:
:
:
:
:
Sodium Thiosulfate
LD50: Not available. May cause irritation to Eyes, skin and Respiratory tract.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP or OSHA.
No data available.
Not a sensitizer.
SECTION 12 – ECOLOGICAL INFORMATION
PAGE 5 of 8
SAFETY DATA SHEET
SPOTMASTER PRO XP
ECOLOGICAL INFORMATION
ECOTOXICITY
PERSISTENCE AND
DEGRADABILITY
: Diethylene Glycol Monobutyl Ether
: This product cannot accumulate in living tissue; diluted, this product is readily and
rapidly in a wastewater treatment facility; in BOD test, 88% degraded in 28 says;
half-life in air estimated as 10 hours.
: No data available.
ECOLOGICAL INFORMATION
ACUTE FISH TOXICITY
TOXICITY TO DAPHNIA
TOXICITY TO PLANTS
MOBILITY
:
:
:
:
:
PERSISTENCE AND
DEGRADABILITY
BIOACCUMULATIVE POTENTIAL
:
Isopropanol
LC50 / 96 hr: Pimephales promelas: 9,640 mg/L.
EC50 / 24 h / Water Flea - 5,102 mg/L.
EC50 / 72 hours Desmodesmus subspicatus > 2,000 mg/L.
This material is expected to have very high mobility in soil. It does not absorb to
most soil types.
No data available.
:
No data available.
ECOLOGICAL INFORMATION
ECOTOXICITY
BOD5 AND COD
PRODUCTS OF
BIODEGRADATION
TOXICITY OF THE PRODUCTS OF
BIODEGRADATION
:
:
:
:
Triethanolamine
Not available.
Not available.
Possibly hazardous short term degradation products are not likely. However, long
term degradation products may arise.
The product itself and its products of degradation are not toxic.
:
ECOLOGICAL INFORMATION
ACUTE TOXICITY FISH,
DAPHNIA, BACTERIA
Sodium Octane Sulfonate
No ecological data available for this material.
ECOLOGICAL INFORMATION
ECOTOXICITY AQUATIC
VERTEBRATE
:
:
ECOTOXICITY AQUATIC
INVERTEBRATE
PERSISTENCE AND
DEGRADABILITY
OTHER TOXIC EFFECTS
:
Sodium Lauryl Sulfate
mortality NOEC-Oncorhynchus mykiss (rainbow trout) -19.5 mg/l -96 h
mortality LOEC-Pimephales promelas (fathead minnow)-4.6 mg/l -8d
LC50 -Oncorhynchus mykiss (rainbow trout)-3.6 g/l -96 h
Not available.
:
Result: 90% readily biodegradable.
:
Toxic to aquatic life.
ECOLOGICAL INFORMATION
ECOTOXICITY
BOD5 AND COD
PRODUCTS OF
BIODEGRADATION
TOXICITY OF THE PRODUCTS OF
BIODEGRADATION
SPECIAL REMARKS ON THE
PRODUCTS OF
BIODEGRADATION
:
:
:
:
:
Propanediol
Not available.
Not available.
Possibly hazardous short term degradation products are not likely. However, long
term degradation products may arise.
The products of degradation are more toxic.
:
Not available.
ECOLOGICAL INFORMATION
ECOTOXICITY
PERSISTENCE AND
DEGRADABILITY
:
:
:
Sodium Thiosulfate
No data available.
No data available.
PAGE 6 of 8
SAFETY DATA SHEET
SPOTMASTER PRO XP
MOBILITY
:
No data available.
SECTION 13 – DISPOSAL CONSIDERATIONS
WASTE DISPOSAL
:
This product must be disposed of in accordance with Federal, state and local
environmental regulations. Discarded materials may be considered hazardous waste
due to pH/corrosivity. It is the responsibility of the product user to determine at the
time of disposal whether a material containing, or derived from this product, should
be classified as a hazardous waste.
SECTION 14 – TRANSPORTATION INFORMATION
DOT/IMDG/ IATA PROPER
SHIPPING NAME
HAZARD CLASS AND LABEL
UN NUMBER
PACKAGING GROUP
EPA REPORTABLE QUANTITY
(RQ)
MARINE POLLUTANT
EMERGENCY RESPONSE GUIDE
:
Not Hazardous
:
:
:
:
Not Applicable.
Not Applicable.
Not Applicable.
Not Applicable.
:
:
Not listed.
Not Applicable.
SECTION 15 – REGULATORY INFORMATION
U.N. GHS CLASSIFICATION & LABELING INFORMATION: See Section 2 for GHS Hazard Information
U.S. FEDERAL REGULATORY INFORMATION:
LISTED CARCINOGEN
: Not listed.
TSCA STATUS
: The ingredients of this product are listed in TSCA inventory (40CFR 710.)
SARA SECTION 302
: No chemicals in this material are subject to the reporting requirements of SARA Title
III, Section 302.
SARA SECTION 312
: Not applicable.
SARA SECTION 313
: This material does not contain any chemical components with known CAS numbers
that exceed the threshold (De Minimis) reporting levels established by SARA Title III,
Section 313.
NFPA HEALTH
: 2
NFPA FLAMMABILITY
: 0
NFPA REACTIVITY
: 0
EUROPEAN UNION REGULATORY INFORMATION:
EC CLASSIFICATION
: Xi: Irritant
DSD/DPD RISK (R) PHRASES
: R22: Harmful is swallowed.
R36/38: Irritating to eyes and skin.
DSD/DPD SAFETY (S) PHRASES
: S1/2: Keep locked up and out of reach of children.
S24/25: Avoid contact with eyes and skin.
S26: In case of contact with eyes, rinse immediately with
PAGE 7 of 8
SAFETY DATA SHEET
SPOTMASTER PRO XP
DSD/DPD HAZARD SYMBOL
:
plenty of water and seek medical advice.
S36/S37/39: Wear suitable protective clothing, gloves and
eye/face protection.
S45: In case of accidents or if you feel unwell, seek
medical advice immediately. Show label where possible.
S61: Avoid release to the environment.
S62: If swallowed, do not induce vomiting.
S64: If swallowed, rinse mouth with water if victim is
conscious.
Xi: Irritant
CANADIAN REGULATORY INFORMATION:
WHMIS CATEGORY
: D2B: Materials that cause other toxic effects (TOXIC).
DOMESTIC SUBSTANCES LIST
: Listed
(DSL)
INGREDIENT DISCLOSURE LIST
: Listed
SECTION 16 – OTHER INFORMATION
DISCLAIMER
:
The information contained herein has been compiled from sources believed to be
realiable and accurate to the best of our knowledge at this date. It is provided
without warranty, expressed or implied, as to the results of use of this information
or to the product to which it relates. Hydramaster Corp. assumes no responsibility
for injury to any person or property resulting from any use of the material. Each user
assumes the risk in their use of this product and should review the data and
recommendations in the specific context of their intended use.
CERCLA
EINECS
IMDG
IARC
IATA
ACGIH
NFPA
NTP
SARA
TSCA
HMIS
WHMIS
LC50
LD50
STOT
DATE PREPARED
DATE REVISED
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Comprehensive Environmental Response, Compensation, and Liability Act.
European Inventory of Existing Commercial Chemical Substances
International Maritime Code for Dangerous Goods
International Agency for Research on Cancer
International Air Transportation Association
American Conference of Governmental Industrial Hygienists
National Fire Protection Association (USA)
National Toxicology Program
Superfund Amendments and Reauthorization Act
Toxic Substances Control Act
Hazardous Materials Identification System (USA)
Workplace Hazardous Materials Information System
Lethal concentration, 50 percent
Lethal dose, 50 percent
Systemic Target Organ Toxicity
JAN 2, 2013
JAN 2, 2015
PAGE 8 of 8
Was this manual useful for you? yes no
Thank you for your participation!

* Your assessment is very important for improving the work of artificial intelligence, which forms the content of this project

Download PDF

advertisement