MSDS Canada - YSI 2726 Methanol Standard Kit (10-08-14)

MSDS Canada - YSI 2726 Methanol Standard Kit (10-08-14)
MATERIAL SAFETY DATA SHEET
1. Product and Company Identification
Product identifier
YSI 2726 Methanol Standard Kit
Version #
01
Issue date
08-October-2014
Revision date
-
Supersedes date
-
CAS #
Mixture
Product code
2726
Product use
Analysis Standard/Reagent
Manufacturer information
YSI, a Xylem brand
1700/1725 Brannum Lane
Yellow Springs, Ohio 45387
Yellow Springs, Ohio 45387
MSDSinfo@ysi.com
(937) 767-7241
CHEMTREC (US/Canada)
CHEMTREC (International)
(Collect calls accepted)
(800) 424-9300
011 703-527-3887
2. Hazards Identification
Emergency overview
May cause skin and eye irritation. Swallowing methyl alcohol may cause blindness.
Potential health effects
Routes of exposure
Eyes. Skin. Ingestion.
Eyes
Contact with eyes may cause irritation.
Skin
Contact may cause skin irritation.
Inhalation
May cause irritation of nose, throat and mucous membranes.
Ingestion
Ingestion may cause irritation and malaise.
Signs and symptoms
May cause temporary irritation on skin or eye contact.
Potential environmental effects
Ecological injuries are not known or expected under normal use.
3. Composition / Information on Ingredients
Components
CAS #
Percent
Water
7732-18-5
>97
EDTA
25102-12-9
<1
Methanol
67-56-1
<1
Sodium Benzoate
532-32-1
<1
4. First Aid Measures
First aid procedures
Inhalation
Skin contact
If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
Call a physician if symptoms develop or persist.
Rinse skin with water/shower. Get medical attention if irritation develops and persists.
Eye contact
Rinse with water. Get medical attention if irritation develops and persists.
Ingestion
Rinse mouth. If ingestion of a large amount does occur, call a poison control center immediately.
General advice
If you feel unwell, seek medical advice (show the label where possible). Show this safety data
sheet to the doctor in attendance.
5. Fire Fighting Measures
Flammable properties
Not flammable by WHMIS criteria.
YSI 2726 Methanol Standard Kit
923090 Version #: 01 Revision date: -
Issue date: 08-October-2014
MSDS Canada
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Extinguishing media
Suitable extinguishing
media
Unsuitable extinguishing
media
Protection of firefighters
Specific hazards arising
from the chemical
Protective equipment for
firefighters
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.
During fire, gases hazardous to health may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Fire fighting
equipment/instructions
Move containers from fire area if you can do so without risk.
Specific methods
Use standard firefighting procedures and consider the hazards of other involved materials.
Explosion data
Sensitivity to static
discharge
Not sensitive.
Sensitivity to mechanical
impact
Hazardous combustion
products
Not sensitive.
None known.
6. Accidental Release Measures
Personal precautions
Keep unnecessary personnel away. For personal protection, see section 8 of the MSDS.
Environmental precautions
Do not contaminate water.
Methods for containment
Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible.
Methods for cleaning up
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth
and place into containers. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the
MSDS.
7. Handling and Storage
Handling
Storage
Use care in handling/storage. Handle and open container with care. Observe good industrial
hygiene practices.
Store in original tightly closed container. Store away from incompatible materials (see Section 10
of the MSDS).
8. Exposure Controls / Personal Protection
Occupational exposure limits
ACGIH Biological Exposure Indices
Components
Type
Value
Methanol (CAS 67-56-1)
US. ACGIH Threshold Limit Values
BEI
15 mg/l
Components
Type
Value
Methanol (CAS 67-56-1)
STEL
TWA
250 ppm
200 ppm
Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)
Components
Type
Value
Methanol (CAS 67-56-1)
STEL
328 mg/m3
250 ppm
262 mg/m3
200 ppm
TWA
YSI 2726 Methanol Standard Kit
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Issue date: 08-October-2014
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Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and
Safety Regulation 296/97, as amended)
Components
Type
Methanol (CAS 67-56-1)
STEL
TWA
Value
250 ppm
200 ppm
Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act)
Components
Type
Value
Methanol (CAS 67-56-1)
STEL
TWA
250 ppm
200 ppm
Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)
Components
Type
Value
Methanol (CAS 67-56-1)
STEL
TWA
250 ppm
200 ppm
Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)
Components
Type
Value
Methanol (CAS 67-56-1)
STEL
328 mg/m3
250 ppm
262 mg/m3
200 ppm
TWA
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
Type
Value
Methanol (CAS 67-56-1)
PEL
260 mg/m3
200 ppm
Exposure guidelines
Canada - Alberta OELs: Skin designation
Methanol (CAS 67-56-1)
Can be absorbed through the skin.
Canada - British Columbia OELs: Skin designation
Methanol (CAS 67-56-1)
Can be absorbed through the skin.
Canada - Manitoba OELs: Skin designation
Methanol (CAS 67-56-1)
Can be absorbed through the skin.
Canada - Ontario OELs: Skin designation
Methanol (CAS 67-56-1)
Can be absorbed through the skin.
Canada - Quebec OELs: Skin designation
Methanol (CAS 67-56-1)
Can be absorbed through the skin.
Canada - Saskatchewan OELs: Skin designation
Methanol (CAS 67-56-1)
Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
Methanol (CAS 67-56-1)
Can be absorbed through the skin.
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
Engineering controls
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Personal protective equipment
Eye / face protection
If contact is likely, safety glasses with side shields are recommended.
Skin protection
Wear suitable protective clothing. Wear protective gloves.
Respiratory protection
In case of insufficient ventilation, wear suitable respiratory equipment. When workers are facing
concentrations above the exposure limit they must use appropriate certified respirators.
9. Physical & Chemical Properties
Appearance
Physical state
Liquid.
Form
Not available.
Color
Clear, colorless.
YSI 2726 Methanol Standard Kit
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Issue date: 08-October-2014
MSDS Canada
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Odor
Not available.
Odor threshold
Not available.
pH
6.5 - 7.5
Vapor pressure
Equivalent to water
Vapor density
Equal to water vapor
Boiling point
212 °F (100 °C)
Melting point/Freezing point
Not available.
Solubility (water)
Infinitely soluble in water
Specific gravity
Not available.
Flash point
None
Flammability limits in air,
upper, % by volume
Not available.
Flammability limits in air,
lower, % by volume
Not available.
Auto-ignition temperature
Not available.
Evaporation rate
Not available.
Partition coefficient
(n-octanol/water)
Not available.
10. Chemical Stability & Reactivity Information
Reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability
Material is stable under normal conditions.
Conditions to avoid
Contact with incompatible materials.
Incompatible materials
Strong oxidizing agents.
Hazardous decomposition
products
No hazardous decomposition products are known.
Possibility of hazardous
reactions
No dangerous reaction known under conditions of normal use.
11. Toxicological Information
Toxicological data
Components
Species
Test Results
-
3700 mg/kg
Rat
2800 mg/kg
Acute
Dermal
LD50
Rabbit
15800 mg/kg
Inhalation
LC50
Rat
64000 mg/l, 4 Hours
Oral
LD50
Rat
5628 mg/kg
Rat
2100 mg/kg
EDTA (CAS 25102-12-9)
Acute
Oral
LD50
Methanol (CAS 67-56-1)
Sodium Benzoate (CAS 532-32-1)
Acute
Oral
LD50
Acute effects
Not expected to be acutely toxic.
Sensitization
Not a skin or respiratory sensitizer.
Chronic effects
Prolonged inhalation may be harmful. Swallowing methyl alcohol may cause blindness.
YSI 2726 Methanol Standard Kit
923090 Version #: 01 Revision date: -
Issue date: 08-October-2014
MSDS Canada
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Carcinogenicity
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Skin corrosion/irritation
Prolonged skin contact may cause temporary irritation.
Serious eye damage/irritation
Direct contact with eyes may cause temporary irritation.
Mutagenicity
Reproductive effects
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
This product is not expected to cause reproductive or developmental effects.
Teratogenicity
No data available.
Symptoms and target organs
May cause temporary irritation on skin or eye contact.
Synergistic materials
No data available.
12. Ecological Information
Ecotoxicological data
Components
Species
Test Results
> 10000 mg/l, 48 hours
Methanol (CAS 67-56-1)
Aquatic
Crustacea
EC50
Water flea (Daphnia magna)
Fish
LC50
Fathead minnow (Pimephales promelas) > 100 mg/l, 96 hours
LC50
Fathead minnow (Pimephales promelas) > 100 mg/l, 96 hours
Sodium Benzoate (CAS 532-32-1)
Aquatic
Fish
Environmental effects
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Not available.
Aquatic toxicity
Not classified.
Persistence and degradability
No data is available on the degradability of this product.
Ecotoxicity
Partition coefficient
Methanol (CAS 67-56-1)
Mobility in environmental
media
-0.77
The product is soluble in water.
13. Disposal Considerations
Disposal instructions
Collect and reclaim or dispose in sealed containers at licensed waste disposal site.
Waste from residues / unused
products
Empty containers or liners may retain some product residues. This material and its container must
be disposed of in a safe manner (see: Disposal instructions). Dispose of in accordance with local
regulations.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
Contaminated packaging
14. Transport Information
TDG
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
15. Regulatory Information
WHMIS status
Controlled
WHMIS classification
D2A - Other Toxic Effects-VERY TOXIC
WHMIS labeling
YSI 2726 Methanol Standard Kit
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Issue date: 08-October-2014
MSDS Canada
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International Inventories
Country(s) or region
Australia
Inventory name
Australian Inventory of Chemical Substances (AICS)
On inventory (yes/no)*
Yes
Canada
Domestic Substances List (DSL)
Canada
Non-Domestic Substances List (NDSL)
China
Inventory of Existing Chemical Substances in China (IECSC)
Europe
European Inventory of Existing Commercial Chemical
Substances (EINECS)
No
Europe
European List of Notified Chemical Substances (ELINCS)
No
Japan
Inventory of Existing and New Chemical Substances (ENCS)
No
Korea
Existing Chemicals List (ECL)
No
New Zealand
New Zealand Inventory
Yes
Philippines
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
Yes
United States & Puerto Rico
Toxic Substances Control Act (TSCA) Inventory
Yes
No
Yes
No
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other Information
HMIS® ratings
NFPA ratings
Disclaimer
Prepared by
Health: 1
Flammability: 0
Physical hazard: 0
Health: 1
Flammability: 0
Instability: 0
YSI, a Xylem brand cannot anticipate all conditions under which this information and its product, or
the products of other manufacturers in combination with its product, may be used. It is the user’s
responsibility to ensure safe conditions for handling, storage and disposal of the product, and to
assume liability for loss, injury, damage or expense due to improper use.
Not available.
YSI 2726 Methanol Standard Kit
923090 Version #: 01 Revision date: -
Issue date: 08-October-2014
MSDS Canada
6/6
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