STANDOX MATERIAL SAFETY DATA SHEET ... 05/05/2013 ****** SECTION 1 - Product and Company Identification ******

STANDOX MATERIAL SAFETY DATA SHEET     ... 05/05/2013  ****** SECTION  1 - Product and Company Identification ******
STANDOX MATERIAL SAFETY DATA SHEET
****** SECTION
PAGE:
1
05/05/2013
1 - Product and Company Identification ******
Supplier:
Axalta Coating Systems Canada Company
408 Fairall Street
Ajax, ON, L1S 1R6
Manufacturer:
Standox
47802 W. Anchor Ct.
Plymouth, MI, 48170
Telephone:
Product Information:
Medical Emergency (24 hours):
Transportation Emergency (24 hours):
(800) 551-9296
(855) 274-5698
(613) 996-6666(CANUTEC)
PRODUCT IDENTIFIER: PE Spray Filler
PRODUCT CODE:
16177
Prepared by:
120725
Regulatory Affairs
Chemical Family:
Not Available
Copyright (c) 2013 Axalta Coating Systems Canada Company.
reserved.
Copies may be made only for those using
Standox products.
All rights
****** SECTION 2 - Composition, Information on Ingredients ******
CAS #
Ingredient
(%)
Exposure Limits**
------------ ---------------------------------------------Not Avail Polyesters, unsaturated
3- 7
A
None
O
None
Not Avail
POLYESTER RESIN
57472-68-1
Methacrylic monomers
67-56-1
METHYL ALCOHOL
15- 40
3-
0.1-
A
O
None
None
7
A
O
None
None
1.0
A
250.0 ppm
15 min STEL
Skin
200.0 ppm
Skin
200.0 ppm
200.0 ppm
8 & 12 hour TWA
Skin
A
O
D
141-78-6
ETHYL ACETATE
1-
5
A
O
400.0 ppm
400.0 ppm
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****** SECTION
100-42-5
PAGE:
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2 - Composition, Information on Ingredients ******
Cont'd
STYRENE
15- 40
A
A
O
O
O
D
D
112945-52-5
FUMED SILICA
0.5-
1.5
A
O
D
13463-67-7
TITANIUM DIOXIDE
3-
7
O
D
D
A
14807-96-6
HYDROUS MAGNESIUM SILICAT
15- 40
A
MAGNESITE (MG(CO3)), CALCINED
7- 13
2.0 mg/m3
Respirable Dust
6.0 mg/m3
1.0 mg/m3
Respirable Dust
15.0 mg/m3
Total Dust
10.0 mg/m3
8 & 12 hour TWA
Total Dust
5.0 mg/m3
8 & 12 hour TWA
Respirable Dust
None
O
2.0 mg/m3
Respirable Dust
0.5 mg/m3
8 & 12 hour TWA
Respirable Dust
None
A
O
None
None
D
83897-85-2
40.0 ppm
15 min STEL
20.0 ppm
200.0 ppm
CEIL
600.0 ppm
5 min STEL
100.0 ppm
40.0 ppm
15 min TWA
20.0 ppm
8 & 12 hour TWA
** A = ACGIH, O = OSHA, D = Dupont, TWAEV = Ontario, S = Supplier
D=Dupont Results obtained from E.I. duPont de Nemours and Company
(For additional definition of terms, see section 16)
Limits are 8-hour TWA unless otherwise specified.
****** SECTION
3 - Hazards Information ******
Emergency Overview:
WARNING! FLAMMABLE LIQUID AND VAPOR. VAPORS AND SPRAY MIST HARMFUL IF
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3 - Hazards Information ******
Cont'd
INHALED.
MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS SUCH AS DIZZINESS,
HEADACHE, OR NAUSEA. MAY CAUSE NOSE, THROAT, EYE AND SKIN
IRRITATION. CAN BE ABSORBED THROUGH THE SKIN.
Potential Health Effects:
Inhalation:
May cause nose and throat irritation.
May cause nervous system
depression characterized by the following progressive steps: headache,
dizziness, nausea, staggering gait, confusion, unconsciousness.
Reports have associated repeated and prolonged overexposure to
solvents with permanent brain and nervous system damage.
Ingestion:
May result in gastrointestinal distress.
Skin or eye contact:
May cause irritation or burning of the eyes. Repeated or prolonged
liquid contact may cause skin irritation with discomfort and
dermatitis.
Other Potential Health Effects in addition to those listed above:
METHYL ALCOHOL
Increased susceptibility to the effects of this material may be
observed in people with preexisting disease of any of the following:
eyes
kidneys
liver
skin
Excessive human exposure to methanol may lead to: fatigue, headache,
anaesthetic, neurologic effects, and visual difficulties including
blindness or death.
Recurrent overexposure may result in liver and kidney injury.
Ingestion may cause any of the following: blindness
Eye contact may cause: Conjunctivitis mild irritation corneal
opacity
Studies in laboratory animals have shown embryotoxic and
developmental effects.
WARNING: This chemical is known to the State of California to cause
birth defects or other reproductive harm.
ETHYL ACETATE
Increased susceptibility to the effects of this material may be
observed in people with preexisting disease of any of the following:
eyes
respiratory system
skin
Tests in laboratory animals have shown effects on any of the
following organs/systems: blood
kidneys
liver
STYRENE
Is an IARC, NTP or OSHA carcinogen.
Prolonged or repeated exposure may cause any of the followin
color discrimination
Tests in laboratory animals have shown effects on any of the
following organs/systems: lungs
loss of
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3 - Hazards Information ******
Cont'd
Ingestion may cause any of the following: nausea
Causes stupor
(central nervous system depression). gastrointestinal irritation
aspiration leading to lung damage.
Ingestion may be: harmful or fatal
Repeated or prolonged eye contact may cause: Conjunctivitis burns
TITANIUM DIOXIDE
Is an IARC, NTP or OSHA carcinogen.
In a lifetime inhalation test, lung cancers were found in some rats
exposed to 250 mg/m3 respirable titanium dust. Analysis of the
titanium dioxide concentrations in the rat's lungs showed that the
lung clearance mechanism was overwhelmed and that the results at the
massive 250 mg/m3 level are not relevant to the workplace.`Results of
a DuPont epidemiology study showed that employees who had been
exposed to Titanium Dioxide were at no greater risk of developing
lung cancer than were employees who had not been exposed to Titanium
dioxide. No pulmonary fibrosis was found in any of the employees and
no association was observed between Titanium dioxide exposure and
chronic respiratory disease or x-ray abnormalities. Based on the
results of this study DuPont concludes that titanium dioxide will not
cause lung cancer or chronic respiratory disease in humans at
concentrations experienced in the workplace.`
****** SECTION
4 - First Aid Measures ******
First Aid Procedures:
Inhalation:
If affected by inhalation of vapor or spray mist, move to fresh air.
If not breathing, give artificial respiration, preferably
mouth-to-mouth. If breathing difficulty persists, or occurs later,
consult a physician.
Ingestion:
In the unlikely event of ingestion, DO NOT induce vomiting.
Call a
physician immediately and have names of ingredients available.
Skin or eye:
In case of contact, immediately flush with plenty of water for at
least 15 minutes; call a physician. In case of skin contact, wash
thoroughly with soap and water. If irritation occurs, contact a
physician.
****** SECTION
5 - Firefighting Measures ******
Flash Point (Method)
Between 24 to 38 deg C
Closed Cup
Approx. flammable limits
LFL
1.1 % UFL
6.1 %
Auto ignition temperature
490.0
Deg C
Hazardous Combustion Products:
CO, C02, smoke, and oxides of any heavy metals that are reported in
"Composition, Information on Ingredients" section.
Extinguishing media:
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STANDOX MATERIAL SAFETY DATA SHEET
****** SECTION
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5 - Firefighting Measures ******
Cont'd
Universal aqueous film-forming foam, carbon dioxide, dry chemical.
Special fire fighting procedures:
Full protective equipment, including self-contained breathing
apparatus, is recommended. Water from fog nozzles may be used to
prevent pressure build-up.
Fire & explosion hazards:
Flammable liquid. Vapor/air mixture will burn when an ignition
source is present.
****** SECTION
6 - Accidental Release Measures ******
Procedures for cleaning up spills or leaks:
Ventilate area. Remove sources of ignition. Prevent skin and eye
contact and breathing of vapor.
Wear a properly fitted air-purifying respirator with organic vapor
cartridges (NIOSH approved TC-23C), eye protection, gloves and
protective clothing. Confine, remove with inert absorbent, and
dispose of properly.
****** SECTION
7 - Handling and Storage ******
Precautions to be taken in handling and storing:
Observe label precautions. Keep away from heat, sparks, flame, static
discharge and other sources of ignition. VAPORS MAY CAUSE FLASH FIRE.
Close container after each use. Ground containers when pouring.
Do not transfer contents to bottles or unlabeled containers. Wash
thoroughly after handling and before eating or smoking. Do not store
above 120 deg F.
OSHA/NFPA Storage Classification:
IC
Other precautions:
If material is a coating: do not sand, flame cut, braze or weld dry
coating without a NIOSH approved air purifying respirator with
particulate filters or appropriate ventilation , and gloves.
****** SECTION
8 - Exposure Controls or Personal Protection ******
Engineering controls and work practices:
Ventilation:
Provide sufficient ventilation in volume and pattern to keep
contaminants below applicable exposure limits.
Personal Protective Equipment:
Recommended PPE:
Respiratory:
Do not breathe vapours or mists. Wear an appropriate, properly
fitted NIOSH approved respirator during application and until all
vapours and spray mists are exhausted unless air monitoring
demonstrates vapour/mist levels are below applicable limits. If
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STANDOX MATERIAL SAFETY DATA SHEET
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8 - Exposure Controls or Personal Protection ******
Cont'd
respirators are required, use a properly fitted air-purifying
respirator with organic vapour cartridges (NIOSH approved TC-23C) and
particulate filter (NIOSH TC-84A).
In confined spaces, or in
situations where continuous spray operations are typical, or if
proper air-purifying respirator fit is not possible, wear a positive
pressure, supplied-air respirator (NIOSH TC-19C). In all cases,
follow respirator manufacturer's directions for respirator use.
Protective clothing:
Neoprene gloves and coveralls are recommended.
Eye protection:
Desirable in all industrial situations. Goggles are preferred to
prevent eye irritation.
If safety glasses are substituted, include
splash guard or side shields.
****** SECTION
9 - Physical and Chemical Properties ******
Evaporation Rate
Vapor Pressure of principal solvent
Solubility of solvent in water
Vapour density (principal solvent)
Approx. Boiling range (deg C)
Approx. Freezing range (deg C)
Gallon weight (lbs/US gal)
Specific gravity
Percent volatile by volume
Percent volatile by weight
Percent solids by volume
Percent solids by weight
Physical state
pH (waterborne systems only)
VOC* less exempt (g/l)
VOC* as packaged (g/l)
Slower than Ether
6.00 hPa @ 20 Deg C
NIL
3.60
145 - 145 DEG (C)
-31
DEG (C)
11.90
1.43
43.99
28.74
56.01
71.26
Liquid
Not Applicable
409.9
409.9
* VOC less exempt (theoretical) and VOC as packaged (theoretical)
are based upon the VOC of the packaged material at the point of
manufacture.
****** SECTION 10 - Stability and Reactivity ******
Stability:
Stable
Incompatibility (materials to avoid):
None reasonably foreseeable
Hazardous decomposition products:
CO, C02, smoke, and oxides of any heavy metals that are reported in
"Composition, Information on Ingredients" section.
Hazardous polymerization:
Will not occur.
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****** SECTION 10 - Stability and Reactivity ******
Cont'd
Sensitivity to static discharge:
Solvent vapors in air may explode if static grounding and bonding is
not used during transfer of this product.
Sensitivity to mechanical impact:
None Known
****** SECTION 11 - Toxicological Information ******
METHYL ALCOHOL
Oral LD50
Dermal LD50
Inhalation LC50
5628 mg/kg
15800 mg/kg
64000 ppm
ETHYL ACETATE
Oral LD50
Dermal LD50
Inhalation LC50
5600 mg/kg
20 ml/kg
29 mg/l
STYRENE
Oral LD50
Dermal LD50
Inhalation LC50
2650 mg/kg
20 mg/kg
2770 ppm
FUMED SILICA
Oral LD50
Dermal LD50
TITANIUM DIOXIDE
Oral LD50
Dermal LD50
Inhalation ALC
4 h
Rat
Rabbit
Rat
SUPPLIER MSDS
RTECS
RTECS
4 h
Rat
Rabbit
Rat
SUPPLIER MSDS
SUPPLIER MSDS
SUPPLIER MSDS
4 h
Rat
Rabbit
Rat
RTECS
SUPPLIER MSDS
RTECS
5000 mg/kg
2000 mg/kg
Rat
Rabbit
SUPPLIER MSDS
SUPPLIER MSDS
24000 mg/m3
10000 mg/m3
6820 mg/m3
Rat
Rabbit
Rat
SUPPLIER MSDS
SUPPLIER MSDS
SUPPLIER MSDS
4 h
For all other ingredients, no information is available.
Key:
RTECHS CCOHS
Patty's -
Registry of Toxic Effects of Chemical Substances
Canadian Center for Occupational Health and Safety
Patty's Industrial Hygiene and Toxicology, 3rd Edition
****** SECTION 12 - Ecological Information ******
METHYL ALCOHOL
28100 mg/l
4 days
Fathead Minnow
FISH
ETHYL ACETATE
425 mg/l
230 mg/l
230 mg/l
270 mg/l
4
4
2
2
Rainbow Trout
Fathead Minnow
Daphnia
Golden Orfe
FISH
FISH
AQUATIC PLANTS
FISH
days
days
days
days
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****** SECTION 12 - Ecological Information ******
Cont'd
STYRENE
9
41
10
47
1
mg/l
mg/l
mg/l
mg/l
mg/l
FUMED SILICA
10000 mg/l
10000 mg/l
TITANIUM DIOXIDE
1000 mg/l
96
4
4
2
4
h
days
days
days
days
24 h
96 h
4 days
Sheephead minnow
Rainbow Trout
Fathead Minnow
Daphnia
Algae
FISH
FISH
FISH
INVERTEBRATES
AQUATIC PLANTS
Daphnia
zebra fish
FISH
FISH
Fathead Minnow
FISH
****** SECTION 13 - Disposal Considerations ******
Provincial Waste Classification:
Check appropriate provincial and local waste disposal regulations
for proper classifications.
Waste disposal method:
Do not allow material to contaminate ground water systems. Incinerate
or otherwise dispose of waste material in accordance with Federal,
State, Provincial, and local requirements. Use only approved waste
management contractors. Do not incinerate in closed containers.
****** SECTION 14 - Transportation Information ******
TDG Shipping Name:
PAINT
Hazard Class:
UN/NA#
Packing Group:
3
1263
III
****** SECTION 15 - Regulatory Information ******
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS contains
all the information required by the Controlled Products Regulations.
TSCA Status:
In compliance with TSCA Inventory requirements for commercial
purposes.
DSL Status:
All components of the mixture are listed on the DSL.
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****** SECTION 15 - Regulatory Information Con’t ******
OCI:
One or more components of the
Inventory.
WHMIS Classification:
Class
Class
Class
Class
Class
WHMIS symbols:
Flame
Toxic "T"
Photochemical Reactivity:
mixture are not listed on the Ontario
B
D
D
D
D
Division
Division
Division
Division
Division
2
2
2
2
2
Subdivision
Subdivision
Subdivision
Subdivision
A
A
B
B
53
54
60
61
Photochemically reactive
Other Regulatory Information:
CAS #
Ingredient
------------ ------------------------26590-75-0
Polyesters, unsaturated
25214-38-4
POLYESTER RESIN
57472-68-1
Methacrylic monomers
67-56-1
METHYL ALCOHOL
141-78-6
ETHYL ACETATE
100-42-5
STYRENE
112945-52-5
FUMED SILICA
13463-67-7
TITANIUM DIOXIDE
14807-96-6
HYDROUS MAGNESIUM SILICAT
83897-85-2
MAGNESITE (MG(CO3)), CALCINED
302
--N
N
N
N
N
N
N
N
N
N
EPCRA
CERCLA
TPQ/RQ 311/312 313 RQ(lbs) HAP
------ ------- --- ------- --NR
NA
N
NR
N
NR
NA
N
NR
N
NR
NA
N
NA
N
NR
A,C,F
Y
5000
Y
NR
C,F
N
NR
N
NR
A,C,F,R
Y
1000
Y
NR
N
N
NR
N
NR
A
N
NR
N
NR
C
N
NR
N
NR
NA
N
NA
N
Key:
EPCRA: Emergency Planning and Community Right-to-Know Act
(aka Title III, SARA)
302: Extremely hazardous substances
311/312 Categories:
F = Fire Hazard
A = Acute Hazard
R = Reactivity Hazard
C = Chronic Hazard
P = Pressure Related Hazard
313 Information: Section 313 Supplier Notification - The chemicals
listed above with a 'Y' in the 313 column are
subject to reporting requirements of Section 313
of the Emergency Planning and Community
Right-to-Know act of 1986 and of 40 CFR 372.
CERCLA: Comprehensive Emergency Response, Compensation and
Liability Act of 1980.
HAP = Listed as a Clean Air Act Hazardous Air Pollutant
TPQ = Threshold planning quantity
RQ = Reportable quantity
NA = not available
NR = not regulated
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****** SECTION 16 - Additional Information ******
HMIS Rating:
Glossary
ACGIH
IARC
NTP
OSHA
STEL
TWA
PNOR
PNOC
of
-
H: 2
F: 3
R: 2
Terms:
American Conference of Governmental Industrial Hygienists
International Agency for Research on Cancer
National Toxicology Program
Occupational Safety and Health Administration
Short term exposure limit
Time-weighted average
Particles not otherwise regulated
Particles not otherwise classified
Notice from Axalta Coating Systems
The information on this Material Safety Data Sheet relates only to the
specific material designated herein and does not relate to use in
combination with any other material or in any process.
Approved by:
Technical Manager
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