sheet metal MSDS safety

sheet metal MSDS safety
Sheet Metal
MSDS
Commercial Sheet Metal MSDS
Trade Name
3M Silicone Lubricant
440 Tape Alum/Grey
55-010 Breeze Eggshell Latex-White
ABC Super 90 Dry Chemical
All Season Windshield Washer Fluid
Argon
Black Spray Paint
Can Dry Absorbent
Cantesco Premium Anti-Spatter Concentrate
Carbon and Alloy Steels
Duro Dyne Solvent Based Adhesive
Emery Cloth Medium Grit
Fantastik Original All Purpose Cleaner
Hardcast Foil Grip 1403-181BFX
Hardcast Duct Seal 321
Industrial Hydraulic Oil
Linacoustic RC Duct Liner
Lubriplate Wheel Bearing Grease
Microlite XG
Mineral Wool Insulation
Oil Based Floor Sweep
Powdered Chalk
Propane
PROtack Water Based Duct Liner Adhesive
SPRAYON Zinc Rich Cold Galvanizing Compound
Unfaced Fiber Glass Insulation
United Duct Sealer Water Based
Used Oil
UVEX Clear Lens Cleaner
Vulkem 801 Gray-5 Gal
Xirtec 5 GRY Low Voc Cement for PVC Pipe
Xylene
Manufacturer
3M
Tremco
General Paint
Strike First Corporation
Recochem
Airgas Inc.
The Fastners Group
Absorbent Products
Cantesco
Various Manufacturers
Duro Dyne
3M
S.C. Johnson
Carlisle
Carlisle
Boss Lubricants
Johns Manville
Lubriplate Lubricants
Johns Manville
Roxul
Floor Sweep
Starrett
Superior Propane
Ductmate Industries
The Sherwin-Williams Company
Johns Manville
McGill AirSeal
Various Manufacturers
Uvex
Tremco
IPS Corporation
Imperial Oil
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MATERIAL SAFETY DATA SHEET 3M(TM) Silicone Lubricant
07/12/13
Material Safety Data Sheet
Copyright, 2013, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Silicone Lubricant
MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 07/12/13
Supercedes Date: 08/04/10
Document Group: 05-6937-6
Product Use:
Limitations on Use:
Intended Use:
Sale and use severely restricted due to high VOC in CT, DE, ME,
MD, NH, NJ, NY, PA, RI, VA, DC, in CA per R-1168.
Industrial use
SECTION 2: INGREDIENTS
Ingredient
C.A.S. No.
% by Wt
ISOBUTANE
HEPTANE
POLY(DIMETHYLSILOXANE)
75-28-5
142-82-5
63148-62-9
70 - 80
15 - 25
3- 7
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Odor, Color, Grade: in aerosol, transparent, very slight odor
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and
explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and
flash back.
May cause target organ effects. May cause frostbite.
3.2 POTENTIAL HEALTH EFFECTS
_________________________________________________________________________________________________
Page 1 of 8
MATERIAL SAFETY DATA SHEET 3M(TM) Silicone Lubricant
07/12/13
Eye Contact:
Frostbite: Signs/symptoms may include intense pain, clouding of the cornea, redness, swelling, and blindness.
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:
Frostbite: Signs/symptoms may include intense pain, discoloration of skin, and tissue destruction.
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
Inhalation:
Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Intentional concentration and inhalation may be harmful or fatal.
May be absorbed following inhalation and cause target organ effects.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.
Target Organ Effects:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed:
Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious
person. Get immediate medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature
Flash Point
Flammable Limits(LEL)
Flammable Limits(UEL)
No Data Available
-50 ºF [Test Method: Tagliabue Closed Cup] [Details:
CONDITIONS: Propellant]
Approximately 1.5 % volume
Approximately 8 % volume
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
_________________________________________________________________________________________________
Page 2 of 8
MATERIAL SAFETY DATA SHEET 3M(TM) Silicone Lubricant
07/12/13
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed
containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained
breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely
flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if
necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available.
Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all
ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with
fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with
good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill
area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard.
6.2. Environmental precautions
For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Collect the resulting residue
containing solution. Place in a metal container approved for transportation by appropriate authorities. Dispose of collected material
as soon as possible.
Clean-up methods
Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill.
Contain spill. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam (AFFF) is recommended. Working
from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material.
Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools. Clean up
residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow
safety precautions on the solvent label and MSDS. Seal the container.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat,
sparks, open flame, pilot lights and other sources of ignition. Ground containers securely when transferring contents. Wear low static
or properly grounded shoes. Do not pierce or burn container, even after use. No smoking while handling this material. Do not spray
near flames or sources of ignition. Avoid breathing of vapors, mists or spray. Avoid static discharge. Avoid eye contact with vapors,
mists, or spray. Keep out of the reach of children. Avoid contact with oxidizing agents.
7.2 STORAGE
Store away from acids. Store away from heat. Store out of direct sunlight. Keep container tightly closed. Store away from oxidizing
_________________________________________________________________________________________________
Page 3 of 8
MATERIAL SAFETY DATA SHEET 3M(TM) Silicone Lubricant
07/12/13
agents.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use with appropriate local exhaust ventilation. Use with functioning spray booth or local exhaust. Do not use in a confined area or
areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to
below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection
equipment. Do not use in a confined area or areas with little or no air movement. If exhaust ventilation is not adequate, use
appropriate respiratory protection. Provide ventilation adequate to control vapor concentrations below recommended exposure limits
and/or control spray or mist.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Safety Glasses with side shields
.
8.2.2 Skin Protection
Not applicable. Wear insulated gloves to protect against frostbite.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Nitrile Rubber
.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray.
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full
respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce
inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors
For questions about suitability for a specific application, consult with your respirator manufacturer.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Not applicable.
8.3 EXPOSURE GUIDELINES
Ingredient
HEPTANE
HEPTANE
HEPTANE
ISOBUTANE
Authority
Type
Limit
ACGIH
ACGIH
OSHA
ACGIH
TWA
STEL
TWA
STEL
400 ppm
500 ppm
2000 mg/m3
1000 ppm
Additional Information
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
_________________________________________________________________________________________________
Page 4 of 8
MATERIAL SAFETY DATA SHEET 3M(TM) Silicone Lubricant
07/12/13
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Flammable Limits(LEL)
Flammable Limits(UEL)
Boiling Point
Density
Vapor Density
in aerosol, transparent, very slight odor
Liquid
No Data Available
-50 ºF [Test Method: Tagliabue Closed Cup] [Details:
CONDITIONS: Propellant]
Approximately 1.5 % volume
Approximately 8 % volume
No Data Available
0.64 g/ml
2.97 [Ref Std: AIR=1]
Specific Gravity
pH
Melting point
0.640 [Ref Std: WATER=1]
Not Applicable
No Data Available
Solubility in Water
Evaporation rate
Hazardous Air Pollutants
Volatile Organic Compounds
Nil
1.90 [Ref Std: WATER=1]
0 % weight [Test Method: Calculated]
Approximately 565 g/l [Test Method: calculated SCAQMD rule
443.1] [Details: low solids less exempts]
<=5.06 lb/gal [Test Method: calculated SCAQMD rule 443.1]
[Details: low solids less exempts]
No Data Available
Approximately 95 % weight
<=94.7 % [Test Method: calculated per CARB title 2]
Not Applicable
0%
Odor, Color, Grade:
General Physical Form:
Autoignition temperature
Flash Point
Volatile Organic Compounds
Kow - Oct/Water partition coef
Percent volatile
VOC Less H2O & Exempt Solvents
Viscosity
Solids Content
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid:
10.1 Conditions to avoid
Heat
10.2 Materials to avoid
Strong oxidizing agents
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance
Condition
Carbon monoxide
Carbon dioxide
During Combustion
During Combustion
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Page 5 of 8
MATERIAL SAFETY DATA SHEET 3M(TM) Silicone Lubricant
07/12/13
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. Facility must be capable of handling aerosol cans.
As a disposal alternative, dispose of waste product in a permitted hazardous waste facility.
Dispose of empty product containers in a sanitary landfill.
RECYCLE EMPTY AEROSOL CONTAINERS WHERE AVAILABLE.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
62-4678-0930-7, 62-4678-0931-5, 62-4678-4930-3, 62-4678-4935-2, 78-8033-2219-3
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - Yes
Reactivity Hazard - No
Immediate Hazard - Yes
Delayed Hazard - No
STATE REGULATIONS
Contact 3M for more information.
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
_________________________________________________________________________________________________
Page 6 of 8
MATERIAL SAFETY DATA SHEET 3M(TM) Silicone Lubricant
07/12/13
INTERNATIONAL REGULATIONS
Contact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 4 Reactivity: 0
Aerosol Storage Code: 3
Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
Revision Changes:
Section 1: Product use information was modified.
Section 16: Disclaimer (second paragraph) was modified.
Section 10: Hazardous decomposition or by-products table was modified.
Section 8: Respiratory protection - recommended respirators information was modified.
Section 8: Respiratory protection - recommended respirators was modified.
Section 14: Transportation legal text was modified.
Section 15: Inventories information was modified.
Section 9: Density information was modified.
Section 9: Vapor density value was modified.
Section 9: Boiling point information was modified.
Section 5: Flammable limits (UE) information was modified.
Section 5: Flammable limits (LEL) information was modified.
Section 5: Autoignition temperature information was modified.
Section 5: Flash point information was modified.
Section 9: Property description for required properties was modified.
Section 9: Property description for optional properties was modified.
Section 9: Specific gravity information was modified.
Section 9: pH information was modified.
Section 9: Melting point information was modified.
Section 9: Solubility in water text was modified.
Section 8: Respiratory protection - recommended respirators guide was modified.
Section 9: Flash point information was modified.
Section 9: Flammable limits (LEL) information was modified.
Section 9: Flammable limits (UEL) information was modified.
Section 9: Autoignition temperature information was modified.
Section 2: Ingredient table was modified.
Section 8: Exposure guidelines ingredient information was modified.
Section 6: 6.2. Environmental precautions heading was modified.
Section 6: 6.1. Personal precautions, protective equipment and emergency procedures heading was modified.
Section 16: Web address was added.
Section 1: Address was added.
Copyright was added.
Company logo was added.
Telephone header was added.
Company Telephone was added.
Section 1: Emergency phone information was added.
_________________________________________________________________________________________________
Page 7 of 8
MATERIAL SAFETY DATA SHEET 3M(TM) Silicone Lubricant
07/12/13
Section 1: Emergency phone information was deleted.
Company Logo was deleted.
Copyright was deleted.
Section 16: Web address heading was deleted.
Section 1: Address line 1 was deleted.
Section 1: Address line 2 was deleted.
Section 8: Respiratory protection - recommended respirators punctuation was deleted.
Section 15: TSCA section 12[b] text was deleted.
Section 15: TSCA section 12[b] information was deleted.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M
3M USA MSDSs are available at www.3M.com
_________________________________________________________________________________________________
Page 8 of 8
SECTI ON 1 - PROD UCT I N FORM ATI ON
Pr odu ct I de n t ifie r :
55- 010 BREEZE EGGSHELL LATEX- WHI TE
Pr odu ct Use : Prot ect ive Coat ing
M a n u fa ct u r e r 's N a m e : General Paint Corp.
Su pplie r 's N a m e : General Paint Corp.
St r e e t Addr e ss: 950 Ray m ur Ave
St r e e t Addr e ss: 950 Ray m ur Ave
Cit y: Vancouver
Pr ovin ce : BC
Cit y: Vancouver
Pr ovin ce : BC
Post a l Code :
V6A 3L5
Em e r ge n cy Ph on e :
( 604) 253- 4022
Post a l Code :
V6A 3L5
Em e r ge n cy
Ph on e :
( 604) 253- 4022
SECTI ON 2 - H AZARD OUS I N GRED I EN TS
H a za r dou s
I n gr e die n t s( Spe cific)
%
CAS
N u m be r
LD 5 0 of
I n gr e die n t ( Spe cify
spe cie s,r out e )
LC 5 0 of
I n gr e die n t ( Spe cify
spe cie s)
TI TANI UM DI OXI DE
14 - 16
13463- 67- 7
NOT AVAI LABLE
NOT AVAI LABLE
PROPYLENE GLYCOL
2.29 - 2.31
57- 55- 6
20000 MG/ KG( ORAL,
RAT)
NOT AVAI LABLE
SECTI ON 3 - PH YSI CAL D ATA
Coa t in g VOC( gm / l) :
128
Odou r
Th r e sh old( ppm ) :
Not Available
Ph ysica l St a t e :
Liquid
Odou r a n d
Appe a r a n ce :
liquid wit h a slight
am m onia sm ell
Spe cific Gr a vit y:
1.31
Va por D e n sit y( a ir = 1 ) : Va por
Not Available
Pr e ssur e ( m m H g) :
Not Available
Eva por a t ion Ra t e :
Not Available
Boilin g Poin t ( º C ) :
Great er t han 100° C
Fr e e z in g Poin t ( º C ) :
Less t han 0° C
Coe fficie n t of
W a t e r / Oil
D ist r ibu t ion :
Not Available
pH :
8.5- 9.5
SECTI ON 4 - FI RE AN D EXPLOSI ON D ATA
Fla m m a bilit y:No
I f ye s, Un de r w h ich Con dit ion s?Not Applicable
M e a n s of Ex t in ct ion : Alcohol foam , Carbon dioxide, Dry chem ical powder, Polym er foam
Fla sh poin t a n d M e t h od:
" Not Applicable
Uppe r Fla m m a ble Lt ( % by
Volu m e ) :Not Applicable
Low e r Fla m m a ble Lt ( % by
Volu m e ) :Not Applicable
Au t oign it ion Te m pe r a t u r e :
Not Applicable
Ex plosion D a t a - Se n sit ivit y t o Ex plosion D a t a - Se n sit ivit y t o
I m pa ct : No
St a t ic disch a r ge s: No
H a za r dou s Com bu st ion Pdt s:carbon m onoxide, carbon dioxide, acrid, irrit ant fum es ( com ponent s not
specified) , calcium oxide, aldehydes, nit rogen oxides, sulfur oxides, m agnesium oxide, am m onium
nit rat e, nit rogen, nit rogen dioxide
SECTI ON 5 - REACTI VI TY D ATA
Ch e m ica l St a bilit y:St able
I f Ye s, Un de r w h ich Con dit ion s?Not Applicable
I n com pa t ibilit y w it h ot h e r
su bst a n ce s:Yes
I f ye s, w h ich on e s?
St rong Acids
St rong Oxidizing agent s
St rong Bases
Re a ct ivit y, a n d u n de r w h a t con dit ion s?heat , ignit ion sources, nit ric acid, dichlorohydrant ion, heat ,
sparks, or ot her ignit ion sources, generat ion of dust , t em perat ur es above 320° c
H a za r dou s D e com posit ion Pr odu ct s:oxides of nit rogen, acet aldehyde, acet ic acid, am m onia, carbon
dioxide, aldehydes, hydrogen
SECTI ON 6 - TOXI COLOGI CAL PROPERTI ES
Rou t e of
Ent r y
Sk in Con t a ct : Yes
Absor pt ion :
Yes
Eye Cont a ct :
Yes
I n h a la t ion : Yes I n ge st ion :
Yes
Effe ct s t o Acu t e e x posu r e t o Pr odu ct :
I nsufficient Dat a
Effe ct s t o Ch r on ic e x posu r e t o Pr odu ct :
PROPYLENE GLYCOL has been known t o cause LACTI C ACI DOSI S.
Ex posu r e Lim it s ( Va lu e ,Un it s,By)
TI TANI UM DI OXI DE: 10 m g/ m 3 ACGI H
PROPYLENE GLYCOL: 10 m g/ m 3 AI HA
I r r it a n cy ( if ye s, e x pla in )
Se n sit iz a t ion ( if ye s, e x pla in )
Ca r cin oge n icit y ( if ye s, e x pla in )
TI TANI UM DI OXI DE is possibly carcinogenic t o
hum ans( 2B) by I ARC.
Re pr odu ct ive Tox icit y ( if ye s, e x pla in )
Te r a t oge n icit y ( if ye s, e x pla in )
M u t a ge n icit y ( if ye s, e x pla in )
Syn e r gist ic Pr odu ct s ( if ye s, e x pla in )
SECTI ON 7 - PREVEN TI VE M EASURES
Pe r son a l Pr ot e ct ive Glove s: No Re spir a t or :
Equ ipm e n t
Yes
Eye : No
Foot w e a r :
No
Clot h in g:
No
Ot h e r : No
I f ch e ck e d, spe cify t ype : Respirat or: NI OSH APPROVED
En gin e e r in g con t r ols ( spe cify su ch a s ve nt ila t ion, e n close d pr oce ss) : Use m echanical vent ilat ion
t o reduce ex posure, ground all equipm ent and avoid exposure t o open flam es or sparks.
Le a k a n d Spill Pr oce du r e : Wear adequat e prot ect ive equipm ent and elim inat e all ignit ion sources.
Cont ain spill wit h absorbant m at erial and place in a suit able covered and labeled cont ainer for disposal.
W a st e D isposa l:
Check wit h Federal, Provincial and local governm ent regulat ions and requirem ent s for disposal.
H a n dlin g Pr oce du r e s a n d Equ ipm e n t :
Use in a well vent ilat ed area. Do not use wit h incom pat ible subst ances and keep away from heat and all
ignit ion sources. Use grounded and non- sparking equipm ent only.
St or a ge Re qu ir e m e n t s:
St ore in a cool, well vent ilat ed area out of direct sunlight . St ore away from heat and all ignit ion sources.
St orage facilit y should be m anufact ured out of fire resist ant m at erials.
Spe cia l Sh ippin g I n for m a t ion :
None Required
SECTI ON 8 - FI RST AI D M EASURES
I n h a la t ion : Rem ove t o fresh air. Get m edical help if t here is any breat hing difficult y.
I n ge st ion : Do not induce vom it ing unless direct ed by a physician. I f conscious and alert , give t wo
glasses of wat er. Seek m edical at t ent ion im m ediat ely.
Sk in Con t a ct : Rem ove Cont am inat ed clot hing ( including shoes) and wash before reuse. Flush wit h
large am ount s of soap and wat er. I f irrit at ion persist s, seek m edical at t ent ion.
Eye Cont a ct : Flush eyes wit h large am ount s of lukewarm wat er for 20 m inut es, while holding eyelids
open or unt il irrit at ion subsides. I f irrit at ion persist , get m edical at t ent ion.
SECTI ON 9 - PREPARATI ON I N FORM ATI ON
Pr e pa r e d by:
General Paint Technical Dept
Ph on e :
( 604) 253- 3131
Pr e pa r a t ion D a t e :
Jul 03, 2012
MATERIAL SAFETY DATA SHEET
SECTION: 1
PAGE 1 OF 4
DATE PREPARED:
REVISED:
MANUFACTURER:
PRODUCT IDENTIFICATION
Strike First Corporation
c/o Steel Fire Equipment
150 Superior Blvd.
Mississuaga, ON
L5T 2L2
Phone: 1-905-564-1500
ABC SUPER 90 DRY CHEMICAL
Multi-Purpose Dry Chemical
Fire Extinguisher
JUNE 01/06
April 2/2012
EMERGENCY PHONE:
Canutec: 1-613-996-6666
SECTION: 2
HAZARDOUS INGREDIENTS
%
*ACGIH
*OSHA
CHEMICAL NAME
CAS #
mg/m3
W/W TLV
mg/m3
STEL PEL STEL
IDLH
Mono Ammonium Phosphate
Mica
Attaclay
Silicone Oil
Calcium Carbonate
Silica
Yellow Pigment
7722-76-1
12001-26-2
8031-18-3
63148-57-2
471-34-1
112926-00-8
5468-75-7
95*
<3
<3
<1
<1
<1
<1
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
3
NE
NE
NE
2
NE
3
NE
NE
NE
6
NE
NE
NE
NE
NE
NE
NE
OTHER
NE
NE
NE
NE
NE
NE
*ACGIH TLV for particulars, not otherwise classified = 10; OSHA PEL for particulars not otherwise
regulated, Total dust =15 Respirable fraction 5.
NE = Not established
SECTION :3
PHYSICAL DATA
BOILING POINT
VAPOR PRESSURE
VAPOR DENSITY
SOLUBILITY IN WATER
SPECIFIC GRAVITY
PERCENT VOLATILE BY
VOLUME
EVAPORATION RATE
pH: (10% solution)
APPEARANCE &
COLOR
Not applicable
Not applicable
Not applicable
Not soluble. Water repellent coating.
Approximately 0.88
Not applicable
Not applicable
Approximately 9-10
This material is a finely divided yellow
powder.
MATERIAL SAFETY DATA SHEET
PAGE 2 OF 4
MANUFACTURER: Strike First Corporation
PRODUCT IDENTIFICATION: ABC DRY CHEMICAL FIRE EXTINGUISHER
SECTION: 4
FIRE AND EXPLOSION DATA
FLASH POINT
FLAMMABLE LIMITS
EXTINGUISHING MEDIA
SPECIAL FIREFIGHTING
PROCEDURES
SECTION: 5
Not applicable
Lower (LEL) Not applicable
Upper (LEL) Not applicable
None This product is a fire extinguishing
agent.
Incipient fire responders should wear eye
protection. Structural fire fighters must
wear Self-Contained Breathing Apparatus
and full protective equipment.
HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE
OSHA PEL
*ACGIH TLV for particulars, Not otherwise
classified = 10
For particulars not otherwise regulated;
Total Dust =15, Respirable Fraction 5.
EFFECTS OF OVEREXPOSURE
Acute
This extinguishing material presents only
a slight risk of causing acute health
effects. If such effects occur, they will be in
the form of mild irritation of the skin, nose, or
throat and moderate irritation of the eyes.
If ingested, this product may cause an
upset stomach.
Chronic
This product is not known to cause
chronic illnesses or diseases.
EMERGENCY FIRST-AID PROCEDURES
SKIN EXPOSURE
If spilled on skin, immediately begin
decontamination with running water.
Remove exposed or contaminated clothing,
taking care not to contaminate eyes. If
reddening or irritation occurs, victim and
rescuers must seek immediate medical
attention.
EYE EXPOSURE
If chemical is splashed in eyes, open
victim's eyes while under gentle running
water. Use sufficient force to open eyelids.
Have victim "roll" eyes. Minimum flushing
is for 15 minutes.
MATERIAL SAFETY DATA SHEET
PAGE 3 OF 4
MANUFACTURER: Strike First Corporation
PRODUCT IDENTIFICATION: ABC DRY CHEMICAL FIRE EXTINGUISHER
SECTION: 5
EMERGENCY FIRST-AID PROCEDURES
INHALATION
SECTION: 6
If chemical is inhaled, remove victim to
fresh air. If necessary, use artificial
respiration to support vital functions. If
reddening or irritation occurs, victim and
rescuers must seek immediate medical
attention.
REACTIVITY DATA
STABILITY
INCOMPATIBILITY
Stable
Strong acids. Reacts violently with lithium.
HAZARDOUS
Carbon monoxide and carbon dioxide
DECOMPOSITION PRODUCT
HAZARDOUS
POLYMERIZATION
SECTION: 7
Will not occur
SPILL OR LEAK PROCEDURES
SMALL SPILLS
Sweep up the spilled solid and place all
spill residue in a double plastic bag and
seal.
LARGE SPILLS
If it is determined that exposure guidelines
for nuisance particulates - 10 mg/m3
(total particulates) or 5 mg/m3 (respirable
particulates) is exceeded use Level C:
triple gloves (rubber gloves with nitrile gloves,
over latex gloves), chemically resistant
suit and boots, hard hat, and air purifying
respirator with a HEPA filter.
Sweep or vacuum.
Dispose of in accordance with Federal,
Provincial and local hazardous waste
disposal regulations.
MATERIAL SAFETY DATA SHEET
PAGE 4 OF 4
MANUFACTURER: Strike First Corporation
PRODUCT IDENTIFICATION: ABC DRY CHEMICAL FIRE EXTINGUISHER
SECTION: 8
SPECIAL PROTECTION INFORMATION
RESPIRATORY
PROTECTION
VENTILATION
PROTECTIVE GLOVES
EYE PROTECTION
OTHER PROTECTIVE
EQUIPMENT:
SECTION: 9
Respiratory protection is not expected to
be needed. Maintain airborne contaminant
concentrations below guidelines for
nuisance particulates: (see Section 5)
Use with adequate ventilation. Use a
mechanical fan or vent area to outside.
Wear rubber gloves for routine industrial
use.
Safety glasses.
Use body protection appropriate for task.
SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
All employees who handle this material should be trained to handle it
safety. Avoid breathing dusts generated by this product.
Avoid getting chemicals ON YOU or IN YOU.
OTHER PRECAUTIONS:
None
SECTION: 10
TRANSPORTATION
Hazard Class or Division:
Fire Extinguisher,
Class 2.2
UN 1044
For additional information contact Strike First Corporation
No harm to the environment is expected from this preparation
Fire extinguishers are designed and produced for the specific purpose of providing a safe and efficient
safety tool to be used only in the fighting of fires. Improper or careless use may cause severe bodily
injury and/or property damage.
Contents are under pressure which is necessary to deliver the contained extinguishing agent to the fire
source.
- Contents under pressure. Do not puncture, incinerate or discharge into another person's face.
- Do not store at high temperatures above 120 degrees Farenheit or 49 degrees Celcius.
- Keep away from children.
- Avoid inhaling the extinguishing agent. Avoid inhaling smoke and fumes - all fires release toxic
substances that are hamful. DO NOT remain in a closed area after use: evacuate the area
immediately and ventilate thoroughly before re-entering.
- Although extinguishing agents are non toxic when used properly, contact with them may cause
irritation to eyes, nose, throat and other allergic symptoms.
Material Safety Data Sheet
WHMIS (Pictograms)
WHMIS (Classification)
Personal protective equipment
Class B-2: Flammable liquid
Class D-1B: Material causing immediate and serious toxic effects (Toxic).
Class D-2A: Material causing other toxic effects (Very toxic).
Class D-2B: Material causing other toxic effects (Toxic).
Section 1. Product and Company Identification
Product
name /
Trade name
Windshield Washer -45°C PC purple
All Season Windshield Washer
Associated
Product’s Item
Code
WIP-35404PC
15-408H52
Synonym
Not available.
CAS #
Mixture.
Chemical family
Not available.
Validation date
04/05/2011.
Apr. 05 2011
Chemical formula
Not available.
Print date
04/05/2011.
Apr. 05 2011
Manufacturer/Supplier Recochem Inc.
850 Montee de Liesse
Montreal, Quebec
514-341-3550
Material uses
In case of
emergency
Recochem Inc.
Communications and Regulatory
Affairs Department
(905) 878-5544
Consumer products: Windshield de-icing fluid.
Section 2. Hazards identification
Emergency Overview
WARNING!
NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHEN THE RECOMMENDED
INSTRUCTIONS FOR USE ARE FOLLOWED.
No known significant effects or critical hazards. Avoid prolonged contact with eyes, skin and clothing.
Potential Acute Health
Effects
See section 11 for more detailed information on health effects and symptoms.
Extremely hazardous by the following route of exposure: of ingestion. Hazardous by the following route of exposure: of
inhalation. Slightly hazardous by the following route of exposure: of skin contact (irritant, permeator), of eye contact
(irritant). Non-sensitizer to skin. Severe over-exposure can result in death.
Note to Physician
Acute exposure to methanol, either through ingestion or breathing high airborne concentrations can result in
symptoms appearing between 40 minutes and 72 hours after exposure. Symptoms and signs are usually limited to
CNS, eyes and gastrointestinal tract. Because of the initial CNS’s effects of headache, vertigo, lethargy and
confusion, there may be an impression of ethanol intoxication. Blurred vision, decreased acuity and photophobia are
common complaints. Treatment with ipecac or lavage is indicated in any patient presenting within two hours of
ingestion. A profound metabolic acidosis occurs in severe poisoning and serum bicarbonate levels are a more
accurate measure of severity than serum methanol levels. Treatment protocols are available from most major
hospitals and early collaboration with appropriate hospitals is recommended.
Section 3. Composition, information on ingredients
Canada
Name
Methanol
CAS number
67-56-1
Conc. (% w/w)
40 - 50
There are no ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Continued on next page
Apr. 05 2011
Validated on 04/05/2011.
Windshield Washer -45°C PC
All Season Windshield Washer
purple
Page: 2/8
Section 4. First aid measures
Eye contact
Immediately flush eyes with plenty of water for at least 20 minutes, occasionally lifting the upper and lower eyelids.
Check for and remove any contact lenses. Get medical attention if irritation occurs.
Skin contact
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if
symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Inhalation
Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Get medical attention if
symptoms occur. If unconscious, place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Ingestion
Wash out mouth with water. Remove dentures if any. Move exposed person to fresh air. Keep person warm and at
rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink.
Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so
by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get
medical attention if symptoms occur. Never give anything by mouth to an unconscious person. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a
collar, tie, belt or waistband.
See section 2
Contact poison treatment specialist immediately if large quantities have been ingested or
inhaled.
Notes to physician
Section 5. Fire-fighting measures
Products of combustion
No specific data.
Fire-fighting media and
instructions
Use an extinguishing agent suitable for the surrounding fire.
Fire Hazards
Explosive in the form of vapor when exposed to heat or flame. Vapor may travel considerable distance to source of
ignition and flash back. When heated to decomposition, it emits acrid smoke and irritating fumes.
Explosion Hazards
Highly flammable liquid and vapor.
Section 6. Accidental release measures
Small spill and leak
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal
container. Dispose of via a licensed waste disposal contractor.
Large spill and leak
Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or
confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage
with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container
for disposal according to local regulations (see section 13). Dispose of via a licensed waste disposal contractor.
Note: see section 1 for emergency contact information and section 13 for waste disposal.
Continued on next page
Apr. 05 2011
Validated on 04/05/2011.
Windshield Washer -45°C PC
All Season Windshield Washer
purple
Page: 3/8
Section 7. Handling and Storage
Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited
in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking.
Handling
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and
well-ventilated area, away from incompatible materials (see section 10) and food and drink. Keep container tightly
closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright
to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental
contamination.
Storage
Section 8. Exposure controls/personal protection
Engineering controls
No special ventilation requirements. Good general ventilation should be sufficient to
control worker exposure to airborne contaminants. If this product contains ingredients
with exposure limits, use process enclosures, local exhaust ventilation or other
engineering controls to keep worker exposure below any recommended or statutory
limits.
Personal protection
Eyes Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts. Recommended: splash goggles
Body Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling
this product.
Respiratory Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Hands Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. >8 hours (breakthrough time): nitrile rubber
United States
Product name
Methanol
Continued on next page
Exposure limits
ACGIH TLV (United States, 1/2008). Absorbed through skin.
TWA: 200 ppm 8 hour(s).
TWA: 262 mg/m³ 8 hour(s).
STEL: 250 ppm 15 minute(s).
STEL: 328 mg/m³ 15 minute(s).
OSHA PEL 1989 (United States, 3/1989). Absorbed through skin.
TWA: 200 ppm 8 hour(s).
TWA: 260 mg/m³ 8 hour(s).
STEL: 250 ppm 15 minute(s).
STEL: 325 mg/m³ 15 minute(s).
NIOSH REL (United States, 6/2008). Absorbed through skin.
TWA: 200 ppm 10 hour(s).
TWA: 260 mg/m³ 10 hour(s).
Apr. 05 2011
Validated on 04/05/2011.
Page: 4/8
Windshield Washer -45°C PC
All Season Windshield Washer
purple
STEL: 250 ppm 15 minute(s).
STEL: 325 mg/m³ 15 minute(s).
OSHA PEL (United States, 11/2006).
TWA: 200 ppm 8 hour(s).
TWA: 260 mg/m³ 8 hour(s).
OSHA (United States, 2003).
TWA: 200 ppm 8 hour(s).
TWA: 260 mg/m³ 8 hour(s).
Canada
Occupational exposure limits
TWA (8 hours)
STEL (15 mins)
Ceiling
Ingredient
List name
ppm mg/m³ Other
ppm mg/m³ Other
ppm mg/m³ Other
Notations
Methanol
US ACGIH 1/2008
AB 6/2008
BC 6/2008
ON 6/2008
QC 6/2008
200
200
200
200
200
250
250
250
250
250
-
[1]
[1]
[1]
[1]
[1]
262
262
260
262
-
328
328
325
328
-
-
-
[1]Absorbed through skin.
Section 9. Physical and chemical properties
Physical State and
Appearance
Liquid.
Odour
Alcohol. [Slight]
Molecular weight
Not available.
Taste
Not available.
pH
8 to 11
Colour
Purple.
Boiling/condensation
point
Not available.
Volatility
Not available.
Melting/freezing point
Not available.
Evaporation
rate
2.1 compared to Butyl acetate.
Relative density
0.9 to 0.97
Odour
Threshold
Not available.
Vapor pressure
<12.8 kPa (<96 mm Hg)
Viscosity
Not available.
Vapour Density
<1.11 [Air = 1]
Solubility
Soluble in water.
VOC content
Not available.
Other
Properties
Not available.
The product is:
May be combustible at high temperature.
Auto-ignition temperature
385°C (725°F)
Flash point
Closed cup: 28°C (82.4°F) [Tagliabue.]
Flammable limits
Lower: 6%
Upper: 36%
Fire hazards in the
presence of various
substances
Slightly flammable in the presence of the following materials or conditions: open flames, sparks and static discharge
and heat.
Non-flammable in the presence of the following materials or conditions: shocks and mechanical impacts.
Explosive in the form of vapor when exposed to heat or flame. Vapor may travel considerable distance to source of
ignition and flash back. When heated to decomposition, it emits acrid smoke and irritating fumes.
Continued on next page
Apr. 05 2011
Validated on 04/05/2011.
Page: 5/8
Windshield Washer -45°C PC
All Season Windshield Washer
purple
Section 10. Stability and reactivity
Stability
The product is stable. Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions of instability
Not available.
Slightly reactive or incompatible with the following materials: oxidizing materials, acids and alkalis.
Incompatibility with
various substances
Hazardous decomposition Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
products
Section 11. Toxicological Information
Canada
Acute toxicity
Product/ingredient name
Methanol
Conclusion/Summary
Chronic toxicity
Conclusion/Summary
Carcinogenicity
Conclusion/Summary
Classification
Product/ingredient name
Methanol
Mutagenicity
Conclusion/Summary
Teratogenicity
Conclusion/Summary
Reproductive Toxicity
Conclusion/Summary
Continued on next page
Result
LC50 Inhalation Gas.
LD50 Dermal
LD50 Dermal
LD50 Oral
LD50 Oral
Not available.
Species
Rat
Rabbit
Rabbit
Rat
Rat
Dose
64000 ppm
15800 mg/kg
15840 mg/kg
5600 mg/kg
5600 mg/kg
Exposure
4 hours
-
Not available.
May be fatal or cause blindness if swallowed.
ACGIH
A5
: Not available.
: Not available.
: Not available.
IARC
4
EPA
-
NIOSH
-
NTP
-
OSHA
None.
Apr. 05 2011
Validated on 04/05/2011.
Windshield Washer -45°C PC
All Season Windshield Washer
purple
Page: 6/8
Section 12. Ecological information
For accidental discharges into the environment, see Section 6:"Accidental Release Measures" for suggested
instructions.
Ecotoxicity
Canada
Aquatic ecotoxicity
Product/ingredient name
Methanol
Conclusion/Summary
Biodegradability
Conclusion/Summary
: No known significant effects or critical hazards.
Result
Species
Acute LC50 2500000 ug/L Marine water Crustaceans - Crangon crangon Adult
Acute LC50 3289 to 4395 mg/L Fresh
Daphnia - Daphnia magna water
Neonate - <24 hours
Acute LC50 >100000 ug/L Fresh water
Fish - Pimephales promelas Juvenile (Fledgling, Hatchling,
Weanling) - 0.2 to 0.5 g
: Not available.
Exposure
48 hours
48 hours
96 hours
: Not available.
Section 13. Disposal considerations
Waste information
The generation of waste should be avoided or minimized wherever possible. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all
times comply with the requirements of environmental protection and waste disposal legislation and any regional local
authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Section 14. Transport information
Canada TDG Classification
No placard (handling and hazard label) required.
Class
Subsidiary class
Not applicable.
Proper Shipping Name
(Canada) TDG
UN number
Packing Group
Windshield washer antifreeze, Alcohol exempt.
Special provisions
In containers of 450L or less, this product meets the requirements
for exemption under TDG regulation special provisions, part 1,
section 1.36b: Class 3, Flammable liquids: Alcohol Exemption.
Not applicable.
Not applicable.
Not applicable.
Continued on next page
Apr. 05 2011
Validated on 04/05/2011.
Page: 7/8
Windshield Washer -45°C PC
All Season Windshield Washer
purple
IMDG Classification
Class
Subsidiary class
Class 3: Flammable liquid.
Proper Shipping Name
IMDG
UN number
Packing Group
Alcohols, n.o.s. (Methanol)
Marine pollutant
Special provisions
Not a pollutant.
-
UN 1987
III
No placard (handling and hazard label) required.
Emergency schedules (EmS)
3-06
Remarks
In a means of containment of 5 L capacity or less this product is
classified as a "Limited Quantity".
United States DOT (Classification)
Class
Class 3: Flammable liquid.
Subsidiary class
-
Proper Shipping Name
(United States) DOT
UN number
Packing Group
Alcohols, n.o.s. (Methanol)
Special provisions
In containers of 5 L (5Kg) capacity or less this product is classified
as a "Consumer Commodity" under DOT regulations.
International Air
Transport Association
(IATA)
For air shipment classification and associated regulations, please refer to the latest edition of
IATA Dangerous Goods Regulations.
UN 1987
III
Section 15. Regulatory information
WHMIS Classification
(Canada)
Canada Domestic
Substances List (DSL)
Status
Class B-2: Flammable liquid
Class D-1B: Material causing immediate and serious toxic effects
(Toxic).
Class D-2A: Material causing other toxic effects (Very toxic).
Class D-2B: Material causing other toxic effects (Toxic).
This product and/ or all of its components are on the DSL.
HCS Classification
(U.S.A.)
Not regulated.
U.S.A. Regulatory Lists
This product and/ or all of its components are on the TSCA inventory list.
Continued on next page
Apr. 05 2011
Validated on 04/05/2011.
Hazardous Material
Information System
(U.S.A.)
Health
Flammability
Reactivity
Personal protection
Windshield Washer -45°C PC
All Season Windshield Washer
purple
2
National Fire
Protection
3
Health
Association
0
(U.S.A.)
B
Page: 8/8
Flammability
3
2 0
Reactivity
Specific hazard
Section 16. Other information
Printed 04/05/2011.
Apr. 05 2011
Apr. 05 2011
Validated and verified by Compliance and Technical Information Manager on 04/05/2011
ph.# 905-878-5544.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for
the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain
hazards are described herein, we cannot guarantee that these are the only hazards that exist.
MSDS are available at www.recochem.com
Material Safety Data Sheet
Argon
Section 1. Chemical product and company identification
Product name
Supplier
: Argon
: AIRGAS INC., on behalf of its subsidiaries
259 North Radnor-Chester Road
Suite 100
Radnor, PA 19087-5283
1-610-687-5253
Product use
Synonym
MSDS #
Date of
Preparation/Revision
In case of emergency
:
:
:
:
Synthetic/Analytical chemistry.
argon, compressed; Cryogenic Liquid Argon, Liquid Argon
001004
5/6/2013.
: 1-866-734-3438
Section 2. Hazards identification
Physical state
Emergency overview
: Gas. [COLORLESS, ODORLESS INERT GAS OR LIQUID]
: WARNING!
GAS:
CONTENTS UNDER PRESURE.
Do not puncture or incinerate container.
Can cause rapid suffocation.
May cause severe frostbite.
LIQUID:
Extremely cold liquid and gas under pressure.
Can cause rapid suffocation.
May cause severe frostbite.
Do not puncture or incinerate container.
Contact with rapidly expanding gases or liquids can cause frostbite.
: Inhalation
Routes of entry
Potential acute health effects
Eyes
: Contact with rapidly expanding gas may cause burns or frostbite. Contact with cryogenic
liquid can cause frostbite and cryogenic burns.
Skin
: Contact with rapidly expanding gas may cause burns or frostbite. Contact with cryogenic
liquid can cause frostbite and cryogenic burns.
Inhalation
: Acts as a simple asphyxiant.
Ingestion
Medical conditions
aggravated by overexposure
: Ingestion is not a normal route of exposure for gases. Contact with cryogenic liquid can
cause frostbite and cryogenic burns.
: Acute or chronic respiratory conditions may be aggravated by overexposure to this gas.
See toxicological information (Section 11)
Section 3. Composition, Information on Ingredients
Name
Argon
Build 1.1
CAS number
7440-37-1
% Volume
100
Exposure limits
Oxygen Depletion [Asphyxiant]
Page: 1/6
Argon
Section 4. First aid measures
No action shall be taken involving any personal risk or without suitable training.If it is suspected that fumes are still present,
the rescuer should wear an appropriate mask or self-contained breathing apparatus.It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation.
Eye contact
: Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
attention immediately.
Skin contact
: None expected.
Frostbite
: Try to warm up the frozen tissues and seek medical attention.
Inhalation
: Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.
Ingestion
: As this product is a gas, refer to the inhalation section.
Section 5. Fire-fighting measures
Flammability of the product
Products of combustion
Fire-fighting media and
instructions
Special protective
equipment for fire-fighters
: Non-flammable.
: No specific data.
: Use an extinguishing agent suitable for the surrounding fire.
Apply water from a safe distance to cool container and protect surrounding area. If
involved in fire, shut off flow immediately if it can be done without risk.
Contains gas under pressure. In a fire or if heated, a pressure increase will occur and
the container may burst or explode.
: Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Section 6. Accidental release measures
Personal precautions
: Immediately contact emergency personnel. Keep unnecessary personnel away. Use
suitable protective equipment (section 8). Shut off gas supply if this can be done safely.
Isolate area until gas has dispersed.
Environmental precautions
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
: Immediately contact emergency personnel. Stop leak if without risk. Note: see section 1
for emergency contact information and section 13 for waste disposal.
Methods for cleaning up
Section 7. Handling and storage
Handling
: High pressure gas. Do not puncture or incinerate container. Use equipment rated for
cylinder pressure. Close valve after each use and when empty. Protect cylinders from
physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder
movement.
Never allow any unprotected part of the body to touch uninsulated pipes or vessels that
contain cryogenic liquids. Prevent entrapment of liquid in closed systems or piping
without pressure relief devices. Some materials may become brittle at low temperatures
and will easily fracture.
Storage
: Cylinders should be stored upright, with valve protection cap in place, and firmly secured
to prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C
(125 °F).
For additional information concerning storage and handling refer to Compressed Gas
Association pamphlets P-1 Safe Handling of Compressed Gases in Containers and P12 Safe Handling of Cryogenic Liquids available from the Compressed Gas Association,
Inc.
Build 1.1
Page: 2/6
Argon
Section 8. Exposure controls/personal protection
Engineering controls
Personal protection
Eyes
Skin
Respiratory
Hands
Personal protection in case
of a large spill
Product name
argon
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits.
: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts.
When working with cryogenic liquids, wear a full face shield.
: Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling
this product.
: Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
The applicable standards are (US) 29 CFR 1910.134 and (Canada) Z94.4-93
: Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary.
Insulated gloves suitable for low temperatures
: Self-contained breathing apparatus (SCBA) should be used to avoid inhalation of the
product.
Oxygen Depletion [Asphyxiant]
Consult local authorities for acceptable exposure limits.
Section 9. Physical and chemical properties
Molecular weight
Molecular formula
Boiling/condensation point
Melting/freezing point
Critical temperature
Vapor density
Specific Volume (ft 3/lb)
Gas Density (lb/ft 3)
:
:
:
:
:
:
:
:
39.95 g/mole
Ar
-185.7°C (-302.3°F)
-189.2°C (-308.6°F)
-122.4°C (-188.3°F)
1.38 (Air = 1). Liquid [email protected]: 87 lb/ft3 (1393 kg/m3)
9.70874
0.103
Section 10. Stability and reactivity
Stability and reactivity
Hazardous decomposition
products
: The product is stable.
: Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
Hazardous polymerization
: Under normal conditions of storage and use, hazardous polymerization will not occur.
Section 11. Toxicological information
Toxicity data
Other toxic effects on
humans
: No specific information is available in our database regarding the other toxic effects of
this material to humans.
Specific effects
Carcinogenic effects
Mutagenic effects
Reproduction toxicity
: No known significant effects or critical hazards.
: No known significant effects or critical hazards.
: No known significant effects or critical hazards.
Build 1.1
Page: 3/6
Argon
Section 12. Ecological information
Aquatic ecotoxicity
Not available.
Environmental fate
Environmental hazards
Toxicity to the environment
: Not available.
: No known significant effects or critical hazards.
: Not available.
Section 13. Disposal considerations
Product removed from the cylinder must be disposed of in accordance with appropriate Federal, State, local
regulation.Return cylinders with residual product to Airgas, Inc.Do not dispose of locally.
Section 14. Transport information
Regulatory
information
UN number
Proper shipping
name
Class
Packing group
DOT Classification
UN1006
ARGON,
COMPRESSED
2.2
Not applicable (gas).
UN1951
Argon, refrigerated
liquid
Label
Additional
information
Limited
quantity
Yes.
Packaging
instruction
Passenger
aircraft
Quantity
limitation:
75 kg
Cargo aircraft
Quantity
limitation:
150 kg
TDG Classification
UN1006
ARGON,
COMPRESSED
UN1951
Argon, refrigerated
liquid
2.2
Not applicable (gas).
Explosive
Limit and
Limited
Quantity
Index
0.125
Passenger
Carrying
Road or Rail
Index
75
Special
provisions
42
Mexico
Classification
UN1006
ARGON,
COMPRESSED
UN1951
Argon, refrigerated
liquid
2.2
Not applicable (gas).
-
“Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the
product.”
Build 1.1
Page: 4/6
Argon
Section 15. Regulatory information
United States
U.S. Federal regulations
: TSCA 8(a) IUR: argon
United States inventory (TSCA 8b): This material is listed or exempted.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: argon
SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
argon: Sudden release of pressure
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
State regulations
Canada
WHMIS (Canada)
Clean Air Act (CAA) 112 regulated flammable substances: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
: Connecticut Carcinogen Reporting: This material is not listed.
Connecticut Hazardous Material Survey: This material is not listed.
Florida substances: This material is not listed.
Illinois Chemical Safety Act: This material is not listed.
Illinois Toxic Substances Disclosure to Employee Act: This material is not listed.
Louisiana Reporting: This material is not listed.
Louisiana Spill: This material is not listed.
Massachusetts Spill: This material is not listed.
Massachusetts Substances: This material is listed.
Michigan Critical Material: This material is not listed.
Minnesota Hazardous Substances: This material is not listed.
New Jersey Hazardous Substances: This material is listed.
New Jersey Spill: This material is not listed.
New Jersey Toxic Catastrophe Prevention Act: This material is not listed.
New York Acutely Hazardous Substances: This material is not listed.
New York Toxic Chemical Release Reporting: This material is not listed.
Pennsylvania RTK Hazardous Substances: This material is listed.
Rhode Island Hazardous Substances: This material is not listed.
: Class A: Compressed gas.
CEPA Toxic substances: This material is not listed.
Canadian ARET: This material is not listed.
Canadian NPRI: This material is not listed.
Alberta Designated Substances: This material is not listed.
Ontario Designated Substances: This material is not listed.
Quebec Designated Substances: This material is not listed.
Section 16. Other information
United States
Label requirements
Canada
Label requirements
Build 1.1
: GAS:
CONTENTS UNDER PRESURE.
Do not puncture or incinerate container.
Can cause rapid suffocation.
May cause severe frostbite.
LIQUID:
Extremely cold liquid and gas under pressure.
Can cause rapid suffocation.
May cause severe frostbite.
: Class A: Compressed gas.
Page: 5/6
Argon
Hazardous Material
Information System (U.S.A.)
: Health
0
Flammability
0
Physical hazards
0
liquid:
National Fire Protection
Association (U.S.A.)
Health
3
Fire hazard
0
Reactivity
0
Personal protection
C
:
Health
0
0
SA
Flammability
0
Instability
Special
liquid:
Flammability
0
Health
3
SA
0
Instability
Special
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Build 1.1
Page: 6/6
MATERIAL SAFETY DATA SHEET
E119
02 00
DATE OF PREPARATION
Feb 3, 2012
SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
E119
PRODUCT NAME
Spray Paint, Flat Black
MANUFACTURER'S NAME
Mfd. for: J2 PRODUCTS
54 Audia Court, Unit 2A
Concord, ON L4K 3N4
Telephone Numbers and Websites
Product Information (905) 699-9410
Regulatory Information (216) 566-2902
Medical Emergency (216) 566-2917
Transportation Emergency* (800) 424-9300
*for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident)
SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS
% by Weight
14
13
16
36
3
7
1
0.4
CAS Number
74-98-6
106-97-8
108-88-3
67-64-1
763-69-9
14807-96-6
471-34-1
1333-86-4
Ingredient
Units
Propane
ACGIH TLV
2500
OSHA PEL
1000
Butane
ACGIH TLV
800
OSHA PEL
800
Toluene
ACGIH TLV
20
OSHA PEL
100
OSHA PEL
150
Acetone
ACGIH TLV
500
ACGIH TLV
750
OSHA PEL
1000
Ethyl 3-Ethoxypropionate
ACGIH TLV
OSHA PEL
Talc
ACGIH TLV
2
OSHA PEL
2
Calcium Carbonate
ACGIH TLV
10
OSHA PEL
15
OSHA PEL
5
Carbon Black
ACGIH TLV
3.5
OSHA PEL
3.5
Vapor Pressure
PPM
PPM
760 mm
PPM
PPM
760 mm
PPM
ppm (Skin)
ppm (Skin) STEL
22 mm
PPM
PPM STEL
PPM
180 mm
Not Available
Not Available
1.11 mm
mg/m3 as Resp. Dust
mg/m3 as Resp. Dust
mg/m3 as Dust
mg/m3 Total Dust
mg/m3 Respirable Fraction
MG/M3
MG/M3
SECTION 3 — HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
HMIS Codes
Health 2*
Flammability 3
Reactivity 0
page 1 of 5
E119
May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death.
Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems:
the liver
the urinary system
the cardiovascular system
the reproductive system
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
SECTION 4 — FIRST AID MEASURES
EYES:
SKIN:
INHALATION:
INGESTION:
Flush eyes with large amounts of water for 15 minutes. Get medical attention.
Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
If affected, remove from exposure. Restore breathing. Keep warm and quiet.
Do not induce vomiting. Get medical attention immediately.
SECTION 5 — FIRE FIGHTING MEASURES
FLASH POINT
LEL
UEL
EXTINGUISHING MEDIA
Propellant < 0 °F
1.0
12.8
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately
apparent. Obtain medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus should be used.
Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure
build-up and possible autoignition or explosion when exposed to extreme heat.
SECTION 6 — ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
SECTION 7 — HANDLING AND STORAGE
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off
stoves, electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children.
SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are
ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction).
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
page 2 of 5
E119
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this
product, underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal.
SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES
768 g/l
PRODUCT WEIGHT 6.41 lb/gal
SPECIFIC GRAVITY 0.77
<-18 - 172 °C
BOILING POINT <0 - 342 °F
MELTING POINT Not Available
VOLATILE VOLUME 92%
EVAPORATION RATE Faster than ether
VAPOR DENSITY Heavier than air
SOLUBILITY IN WATER N.A.
pH 7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
Volatile Weight 47.26%
Less Water and Federally Exempt Solvents
SECTION 10 — STABILITY AND REACTIVITY
STABILITY — Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
SECTION 11 — TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage.
Carbon Black is classified by IARC as possibly carcinogenic to humans (group 2B) based on experimental animal data, however, there is
insufficient evidence in humans for its carcinogenicity.
page 3 of 5
E119
TOXICOLOGY DATA
CAS No.
74-98-6
106-97-8
108-88-3
67-64-1
763-69-9
14807-96-6
471-34-1
1333-86-4
Ingredient Name
Propane
LC50 RAT
LD50 RAT
4HR
Not Available
Not Available
LC50 RAT
LD50 RAT
4HR
Not Available
Not Available
LC50 RAT
LD50 RAT
4HR
4000 ppm
5000 mg/kg
RAT
RAT
4HR
Not Available
5800 mg/kg
RAT
RAT
4HR
Not Available
5000 mg/kg
RAT
RAT
4HR
Not Available
Not Available
RAT
RAT
4HR
Not Available
Not Available
RAT
RAT
4HR
Not Available
Not Available
Butane
Toluene
Acetone
LC50
LD50
Ethyl 3-Ethoxypropionate
LC50
LD50
Talc
LC50
LD50
Calcium Carbonate
LC50
LD50
Carbon Black
LC50
LD50
SECTION 12 — ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.
SECTION 13 — DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution.
SECTION 14 — TRANSPORT INFORMATION
Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping
description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of
transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport.
US Ground (DOT)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)
Canada (TDG)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)
IMO
May be shipped as Limited Quantity
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U, ADR (D)
IATA/ICAO
UN1950, AEROSOLS, FLAMMABLE, 2.1, LIMITED QUANTITY
SECTION 15 — REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
108-88-3
Toluene
16
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory.
% Element
page 4 of 5
E119
SECTION 16 — OTHER INFORMATION
This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the
MSDS contains all of the information required by the CPR.
The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other
additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no
warranties, express or implied, and assume no liability in connection with any use of this information.
page 5 of 5
MATERIAL SAFETY DATA SHEET
1 Of 3
Abbreviations used on this Material Safety Data Sheet:
N/av. = Not available, N/ap. = Not applicable, ppm = parts per million, TLV = Threshold Limit Value.
NFPA Hazard Rating: 4-Extreme, 3-High, 2-Moderate, 1-Slight, 0-None, X-Blank
SECTION I - PRODUCT IDENTIFICATION AND USE
PRODUCT IDENTIFIER
CAN DRY SUPREME ABSORBENT
MANUFACTURER'S NAME
Absorbent Products Ltd
STREET ADDRESS
724 East Sarcee St.
CITY/PROVINCE
Kamloops, BC
POSTAL CODE
V2H 1E7
4 - extreme
0
1
EMERGENCY TELEPHONE NUMBER:
3 - high
1
2 - moderate
.
1-800-667-0336
1 - slight
CHEMICAL NAME:
Diatomaceous Earth
TRADE NAME:
CAN DRY ABSORBENT
NFPA HAZARD RATING:
0 - insignificant
CHEMICAL FAMILY:
Silica
Health - 1, Flammability - 0, Reactivity - 1
MATERIAL USE:
Industrial Absorbent
SECTION II - HAZARDOUS INGREDIENTS OF MATERIAL
HAZARDOUS INGREDIENTS
%
CAS NUMBER OR
OSHA PEL
LD50/ /LC 50
UN NUMBER OR
(ACGIH TLV)
SPECIES AND ROUTE
NA NUMBER
Naturally Occuring Diatomaceous
Earth
100%
61790-53-2
see below
N/av.
<1%
14808-60-7
see below
N/av.
(Typical Analysis = 67% Silicon
Dioxide)
Free Crystalline Silica
or Silica, quartz
For sampling silica dusts refer to NIOSH Analytical Method 7500 or OSHA method ID 142
SECTION III - PHYSICAL DATA FOR MATERIAL
PHYSICAL STATE
solid
ODOR AND APPEARANCE
No odor, Buff / grey granules
VAPOR PRESSURE (mm Hg)
N/ap.
DENSITY (20 degrees Celcius)
35lb\cu. ft. +/- 5
VAPOR DENSITY (Air = 1)
N/ap.
SOLUBILITY IN WATER
Insoluble, forms
SPECIFIC GRAVITY (Water=1)
2.0
FREEZING POINT
N/ap.
BOILING POINT
N/ap.
colloidal suspension
pH
5.5 - 6.5
slightly acidic in water
SECTION IV - FIRE AND EXPLOSION DATA
FLAMMABILITY (IF YES, UNDER WHICH CONDITIONS?)
YES
NO
X
MEANS OF EXTINCTION
N/ap.
SPECIAL PROCEDURES
N/ap.
FLASHPOINT AND METHOD
N/ap.
UPPER FLAMMABILITY LIMIT (% BY VOLUME)
N/ap.
AUTOIGNITION TEMPERATURE
N/ap.
LOWER FLAMMABILITY LIMIT (% BY VOLUME)
N/ap.
HAZARDOUS COMBUSTION PRODUCTS
N/ap.
SENSITIVITY TO STATIC DISCHARGE
No
EXPLOSION DATA:
SENSITIVITY IMPACT
No
MATERIAL SAFETY DATA SHEET
2 Of 3
MATERIAL IDENTIFIER:
CAN DRY SUPREME ABSORBENT
SECTION V - HEALTH HAZARDS
Routes of Exposure and Effects:
Inhalation: Acute (short term) exposure to dust levels exceeding the PEL may cause irritation of respiratory tract resulting in a dry cough. Chronic (long term) exposure to
crystalline free silica contained by airborne diatomaceous earth dust where levels are higher than TLV's may lead to the development of silicosis or other respiratory problems.
Persistent dry cough, throat irritation and labored breathing on exertion are symptomatic. exposure may aggravate existing upper respiratory tract diseases such as asthma,
bronchitis or emphysema.
Eyes: Irritant.
Skin: Possible drying results in dermatitis.
Ingestion: No adverse effects.
Permissible Exposure Limits:
OSHA PEL
ACGIH
OHS
(for airborne, nuisance dusts)
8 hr TWA
TLV
8 hr TWA
OHS STEL
Total dust
15 mg/m3
Not detected
4 mg/m3
Respirable dust
5 mg/m
Not detected
1.5 mg/m
n/a
Crystalline quartz (respirable)
0.1 mg/m3
0.1 mg/m3
0.025mg/m3
n/a
Diatomaceous earth
3
n/a
3
EFFECTS OF CHRONIC EXPOSURE TO PRODUCT
Exposure to quantities of crystalline silica dust, in the forms of quartz, cristobalite or tridymite, may be present in airborne dust. If the concentration levels are in excess of th
OSHA Permissible Limit (PEL-TWA 8hrs) of 0.05mg/m3 or the ACGIH Threshold Limit Value (TLV) of 0.05mg/m3, the crystalline silica is a known cause of silicosis, a
progressive, sometimes fatal, lung disease. From the International Agency for Research on Cancer (IARC), a 1997 review of "Crystalline Silica Inhaled in the Form of Quart
or Cristobalite" coded Monograph 68 concluded that Amorphous Silica is not classifiable to its carcinogenicity to humans (Group 3)
SECTION VI - REACTIVITY DATA
CHEMICAL STABILITY (IF NO,
YES
UNDER WHICH CONDITIONS)
NO
INCOMPATIBILITY WITH OTHER SUBSTANCES
YES
(IF YES, WHICH ONES)
NO
X
X
REACTIVITY, AND UNDER WHAT CONDITIONS
N/ap.
HAZARDOUS DECOMPOSITION PRODUCTS
N/ap.
Hydrofluoric acid - silica may react violently
SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE
PERSONAL PROTECTIVE EQUIPMENT
Bureau of Mines or NIOSH approved respirators for protection against pneumoconiosis producing dusts recommended when dust is present. If the dust concentration is less
than ten (10) times the Permissible Exposure Limit (PEL) use quarter or half mask respirator with replacement dust filter or single use dust respirator with valve. If dust
concentration is greater than ten (10) times and less than one hundred (100) times the PEL use full faceplate respirator with replaceable dust filter; if greater than one hundred
(100) and less than two hundred (200) times the PEL use power air purifying (positive pressure) respirator with replaceable filter; if greater than two hundred (200) times the
PEL use type C, automatic-air respirator, continuous flow type (positive pressure), with full facepiece, head or helmet.
GLOVES (SPECIFY)
Not needed under normal conditions of use.
RESPIRATOR (SPECIFY)
Avoid breathing dust. Use respirators approved NIOSH/OSHA for silica bearing dust.
EYE (SPECIFY)
Use protective goggles in high dust conditions.
FOOTWEAR (SPECIFY)
As required on jobsite.
MATERIAL SAFETY DATA SHEET
3 Of 3
MATERIAL IDENTIFIER:
CAN DRY SUPREME ABSORBENT
SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE CONTINUED
CLOTHING (SPECIFY)
Wear coveralls in high dust conditions.
ENGINEERING CONTROLS (SPECIFY, E.G. VENTILATION, ENCLOSED PROCESS)
Local - control within recommended TLV/PEL, mechanical filtration to minimize dust. Refer to ACGIH publication "Industrial
Ventilation" or similar publications for design of ventilation systems.
LEAK AND SPILL PROCEDURE
Vacuum clean spillage, wet sweep or wash away. Avoid creating dust.
WASTE DISPOSAL
Dispose of in accordance with local, state and federal regulations.
HANDLING PROCEDURES
Avoid creating dust. Repair or properly dispose of broken bags. Use wet process or enclosed handling.
STORAGE REQUIREMENTS
Store in a dry place to maintain product quality. Keep containers closed and in good condition. Repair damaged containers.
SPECIAL SHIPPING INFORMATION
None
SECTION VIII - FIRST AID MEASURES
SPECIFIC MEASURES
Inhalation: Remove victim to fresh air. If breathing has stopped, a trained person should perform artificial respiration.
Acute inhalation can cause dryness of the nasal passage and congestion of the upper respiratory tract.
Ingestion: Do not induce vomiting. Short-term exposure not considered harmful. Drink generous amounts of water to
reduce bulk and drying effects.
Eye: Wash with generous quantities of water. Consult physician if irritation persists. May cause irritation or inflammation.
Skin contact: Remove contaminated clothing. Wash with soap and water until clean. Use moisture renewing lotions
if dryness occurs. Not absorbed by the skin. May cause dryness.
SECTION IX - DEPARTMENT OF TRANSPORTATION
HAZARDOUS MATERIALS DESCRIPTION:
None
IDENTIFICATION NUMBER:
None
TECHNICAL NAME:
None
LABEL(S) REQUIRED:
None
HAZARDOUS CLASS:
None
SECTION X - ENVIRONMENTAL DATA
EMERGENCY PLANNING AND COMMUNITY RIGHT TO KNOW INFORMATION
This product contains no toxic chemicals subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40
CFR Part 372 (SARA 313 - Toxic Chemical Release Reporting).
EPA SARA 311/312 Hazard Classification: This product is considered hazardous under OSHA and SARA Title III, Section 301. Category: Chronic Health.
CERCLA Section 103: This product is not subject to CERCLA reporting requirements as it is sold. Refer to CERCLA regulations to determine if used product mixed with
other chemicals or materials may be reportable. Many states have more stringent release reporting requirements. Reports spills required under federal, state and local
regulations.
EPZ Toxic Substance Control Act (TSCA): All of the ingredients are listed on the TSCA Chemical Substances Inventory.
DOT Marine Pollutants: This product does not contain Marine Pollutants as defined in 49 CFR 171.8.
SECTION XI - PREPARATION DATE OF MSDS
PREPARED BY:
PHONE NUMBER
DATE
Quality Control Staff, Absorbent Products Ltd.
1-800-667-0336
May, 2013
All information presented herein is believed to be accurate; however, it is the user's responsibility to determine in advance of need that the information is current and suitable for their circumstances. No warranty or guarantee, expressed
or implied is made by Absorbent Products Ltd., as to the information, or as to the safety, toxicity or the effect of this product.
36.0.12
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Safety Data Sheet
acc. to OSHA HCS
Printing date 10/07/2013
Reviewed on 10/07/2013
1 Identification of the substance/mixture and of the company/undertaking
· Trade name: CANTESCO ® PREMIUM ANTI-SPATTER- CONCENTRATE
· Article number: ENVIROSPAT, ES-16-P, ES-16-T, ES-1G, ES-5G, ES-DR, ES-4L, ES-20L
· MSDS Number: 00104-CA-EN
· UPC bar code(s):
699913-10250, 699913-10255, 699913-10260,
699913-10265, 699913-10270
· Relevant identified uses of the substance:
PREVENTS SPATTER BUILD UP
IN WELDING APPLICATIONS
· Manufacturer/Supplier:
WWW.CANTESCO.COM
USA ADDRESS :
KEMPER SYSTEM AMERICA, INC
1200 NORTH AMERICA DR,
WEST SENECA, NY 14224
PH (716) 693-8206
FAX (716) 558-2969
CANADIAN ADDRESS :
KEMPER SYSTEM CANADA
13 - 5200 DIXIE ROAD
MISSISSAUGA, ON L4W 1E4
PH (905) 624-5463
FAX (905) 624-2840
· Information department:
Tel: (716) 558-2971 ext. 228
www.cantesco.com
· Emergency telephone number:
ChemTrec (800) 424-9300
Canada only: CANUTEC (Call collect) (613) 996-6666
2 Hazards identification
· Classification of the substance or mixture:
The product is not classified according to the Globally Harmonized System (GHS).
· Information concerning particular hazards for human and environment:
The product does not have to be labelled due to the calculation procedure of international guidelines.
· Classification system:
The classification was made according to the latest editions of international substances lists, and expanded upon
from company and literature data.
· NFPA ratings (scale 0 - 4):
0
0
0
Health = 0
Fire = 0
Reactivity = 0
CA
(Contd. on page 2)
36.0.12
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Safety Data Sheet
acc. to OSHA HCS
Printing date 10/07/2013
Reviewed on 10/07/2013
Trade name: CANTESCO ® PREMIUM ANTI-SPATTER- CONCENTRATE
(Contd. of page 1)
3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of the substances listed below with nonhazardous additions.
· Dangerous components:
68412-54-4 Polyoxyethylene (9) nonylphenylether, branched
Acute Tox. 3, H301;
Skin Irrit. 2, H315; Eye Irrit. 2A, H319
112-80-1 oleic acid, pure
Skin Irrit. 2, H315; Eye Irrit. 2A, H319; STOT SE 3, H335
· Additional information: Exact concentrations are being withheld as trade secrets.
1-<3%
≤1%
4 First aid measures
· General information: No special measures required.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: If symptoms persist consult doctor.
· Most important symptoms and effects, both acute and delayed: No further relevant information available.
· Indication of any immediate medical attention and special treatment needed:
No further relevant information available.
5 Firefighting measures
· Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· Special hazards arising from the substance or mixture: No further relevant information available.
· Protective equipment: No special measures required.
6 Accidental release measures
· Personal precautions, protective equipment and emergency procedures: Not required.
· Environmental precautions: Dilute with plenty of water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
· Reference to other sections:
No dangerous substances are released.
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
· Handling
· Precautions for safe handling: No special measures required.
· Information about protection against explosions and fires: No special measures required.
· Storage
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
(Contd. on page 3)
CA
36.0.12
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Safety Data Sheet
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Printing date 10/07/2013
Reviewed on 10/07/2013
Trade name: CANTESCO ® PREMIUM ANTI-SPATTER- CONCENTRATE
(Contd. of page 2)
· Further information about storage conditions: None.
· Specific end use(s): No further relevant information available.
8 Exposure controls/personal protection
· Additional information about design of technical systems: No further data; see item 7.
· Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
· Additional information: The lists that were valid during the creation were used as basis.
· Personal protective equipment
· General protective and hygienic measures:
The usual precautionary measures for handling chemicals should be followed.
· Breathing equipment: Not required.
· Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves:
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
· Eye protection: Goggles recommended during refilling.
9 Physical and chemical properties
· Form:
· Color:
· Odor:
· Odour threshold:
Liquid
Light beige
Mild
Not determined.
· pH-value at 20 °C:
7
· Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
0 °C
100 °C
· Flash point:
Not applicable.
· Flammability (solid, gaseous):
Not applicable.
· Ignition temperature:
Decomposition temperature:
Not determined.
· Auto igniting:
Product is not selfigniting.
· Danger of explosion:
Product does not present an explosion hazard.
· Explosion limits
Lower:
Upper:
Not determined.
Not determined.
· Vapor pressure at 20 °C:
23 hPa
· Density at 20 °C:
· Relative density:
1 g/cm³
Not determined.
(Contd. on page 4)
CA
36.0.12
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Safety Data Sheet
acc. to OSHA HCS
Printing date 10/07/2013
Reviewed on 10/07/2013
Trade name: CANTESCO ® PREMIUM ANTI-SPATTER- CONCENTRATE
(Contd. of page 3)
· Vapour density at 20 °C:
· Evaporation rate at 20 °C:
.610 (AIR=1)
1 (BA=1)
· Solubility in / Miscibility with
Water:
Fully miscible.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic:
Kinematic:
Not determined.
Not determined.
· Solvent content:
Organic solvents:
0.0 %
Solids content:
· Other information
22.0 %
No further relevant information available.
10 Stability and reactivity
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions: No dangerous reactions known.
· Conditions to avoid: No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.
11 Toxicological information
· Information on toxicological effects:
· Acute toxicity
· Primary irritant effect
· on the skin: No irritant effect.
· on the eye: No irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
The product is not subject to classification according to internally approved calculation methods for preparations:
When used and handled according to specifications, the product does not have any harmful effects according to
our experience and the information provided to us.
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
102-71-6 2,2',2''-nitrilotriethanol
3
· NTP (National Toxicology Program)
None of the ingredients is listed.
12 Ecological information
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability: No further relevant information available.
· Behavior in environmental systems
· Bioaccumulative potential: No further relevant information available.
· Mobility in soil: No further relevant information available.
(Contd. on page 5)
CA
36.0.12
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Safety Data Sheet
acc. to OSHA HCS
Printing date 10/07/2013
Reviewed on 10/07/2013
Trade name: CANTESCO ® PREMIUM ANTI-SPATTER- CONCENTRATE
(Contd. of page 4)
· Other adverse effects: No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation: Smaller quantities can be disposed of with household waste.
· Uncleaned packagings
· Recommendation:
Place in a sealed container and label as waste. Place in a safe area, and comply with all federal, state, provincial
and local regulations for disposal.
· Recommended cleansing agent: Water, if necessary with cleansing agents.
14 Transport information
· UN-Number
· DOT, TDG, ADN, IMDG, IATA
Not Available
· UN proper shipping name
· DOT, TDG, ADN, IMDG, IATA
Not Available
· Transport hazard class(es)
· DOT, TDG, ADN, IMDG, IATA
· Class
Not Available
· Packing group
· DOT, TDG, IMDG, IATA
Not Available
· Environmental hazards:
· Marine pollutant:
No
· Special precautions for user:
Not applicable.
· Transport in bulk according to Annex II of
Not applicable.
MARPOL73/78 and the IBC Code:
· UN "Model Regulation":
-
15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Sara
· Section 355 (extremely hazardous substances):
None of the ingredients is listed.
· Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
· TSCA (Toxic Substances Control Act):
All ingredients are listed.
· Proposition 65
· Chemicals known to cause cancer:
None of the ingredients is listed.
(Contd. on page 6)
CA
36.0.12
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Safety Data Sheet
acc. to OSHA HCS
Printing date 10/07/2013
Reviewed on 10/07/2013
Trade name: CANTESCO ® PREMIUM ANTI-SPATTER- CONCENTRATE
(Contd. of page 5)
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
· Carcinogenic categories
· EPA (Environmental Protection Agency):
None of the ingredients is listed.
· TLV (Threshold Limit Value established by ACGIH):
None of the ingredients is listed.
· NIOSH-Ca (National Institute for Occupational Safety and Health):
None of the ingredients is listed.
· OSHA-Ca (Occupational Safety & Health Administration):
None of the ingredients is listed.
· Canadian substance listings
· Canadian Domestic Substances List (DSL):
All ingredients are listed.
· Canadian Ingredient Disclosure list (limit 0.1%):
None of the ingredients is listed.
· Canadian Ingredient Disclosure list (limit 1%):
112-80-1 oleic acid, pure
16 Other information
This MSDS format meets ANSI Z400.1-1998, OSHA 1910.1200 and WHMIS requirements. Kemper System
America, Inc. provides the information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary
handling of the material by a properly trained person using this product. Product use and conditions of use are
beyond the control of Kemper System America, Inc. Warranty of materials is limited to test results of product
performance as detailed in certificates of compliance. Interpretation of test results is the responsibility of end-user.
No other warranties, expressed or implied, are made. Kemper System America, Inc is an ISO 9001:2008
registered company.
· Department issuing MSDS: Product safety department
· Contact: Stephen Nowicki
· Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
NFPA: National Fire Protection Association (USA)
CA
MATERIAL SAFETY DATA SHEET
Contractors Steel Company
P.O. Box 3364
Livonia, Michigan 48150
(734) 464 4000 / Fax (734) 452 3939
(This product may contain chemicals subject to reporting requirements of section 313, Emergency Planning and Community Right To Know Act of 1986 and of 40CFR72)
Revision: March 12, 2013
Section 1 - Product Identification
Manufacturers Name: VARIOUS
Product Name / Trade Name Carbon
and Alloy Steels ( Bar ( Hot rolled- Round, Square, Strip, Flat )( Cold Finished - Round, Square, Flat )
( Angle - Bar size, Structural )( Channel - Bar, Structural, Junior )( Beam - Standard I, Wide Flange & H, Junior )( Sheet - Hot rolled )
( Plate - Floor, Abrasion Resisting )( Pipe )( Tubing - Square, Rectangular )( Expanded Metal - Standard, Flattened ) ( Bar size Tees)
(Grating - Standard, Bar, Stair tread, Catwalk, Grip strut ) ( Molded Cover Bar ) ( Re rod )( Threaded Rod )( Rail) ( Structural Tees ))
Galvanized ( Sheet, Round, Angle, Channel )
Section 2 - Ingredients
Components
Base Metal Iron (Fe)
Alloying Elements
Aluminum (Al)
CAS#
7439-89-6
balance
7429-90-5
0-.15
Antimony (Sb)
Arsenic As)
Beryllium (Be)
Boron (B)
Cadmium (Cd)
7440-36-0
7440-38-2
7440-41-7
7440-42-8
7440-43-9
<1
<1
<1
<1
<1
Calcium (Ca)
Carbon (C)
Chromium (Cr)
Cobalt (Co)
Copper (Cu)
1305-78-8
7440-4-0
7440-47-3
7440-48-4
7440-50-8
0-1
.003-.1.1
.01-1
<1
.04-1
Lead Pb)
Magnesium (Mg)
Manganese (Mn)
Molybdenum (Mo)
Niobium (Nb)
Nickel (Ni)
Nitrogen (N)
Phosphorus (P)
Selenium (Se)
Silicon (Si)
Sulfur (S)
7439-92-1
7439-95-4
7439-96-5
7439-98-7
7440-03-1
7440-02-0
7727-37-9
7723-14-0
7782-49-2
7440-21-3
7446-09-5
0.-0.9
0-1
0.2-2
0.01-0.8
0-1
0.01-1
<1
0-1
<1
0-3
0-1
Tin (Sn)
Titanium (Ti)
Tungsten (W)
7723-14-0
7440-32-6
7440-33-7
0-1
0-1
0-1
Vanadium (V)
7440-62-2
0-1
Zinc (Zn)
7440-66-6
0.-.05
% Weight (1)
ACGIH TLV (mg/m3) (Threshold limit value) (2)
5
Oxide dust/fume
OSHA PEL (mg/m3) (Permissible exposure limit)
10
Oxide dust/fume
10
5
.5
.01
.002
10
.01
.002
2
15
5
.5
.01
.002
15
.005
.0025
5
.5
.02
1
.2
.05
0.2
10
1.5
0.1
0.2
10
5.2
13
2
5
10
0.05
Dust
Fume
As Antimony
as Arsenic (A1 Carcinogen)
as Beryllium (A1 Carcinogen)
Oxide dust
as Cadmium (A2 Carcinogen)
Respirable fraction
Oxide dust
not established
Metal
as Cobalt (A3 Carcinogen)
Dust
Fume
Dust / Fume (A3 Carcinogen)
Not established
Elemental Mn and Inorg compounds
Insoluble compounds
Not established
Metal
simple Asphyxiant
Phosphorus
Selenium
Dust
Sulfur dioxide
Sulfur dioxide (STEL)
Metal, oxide and organic compounds
Not established
Insoluble compounds as W
Insoluble compounds as W (STEL)
Oxide Dust/Fume
1
.1
1
.1
.05
5
15
1
0.1
0.2
15
13
Dust
Respirable fraction
As Antimony
as Arsenic
as Beryllium
Oxide dust
as Cadmium
as Cadmium (action level)
Oxide dust
not established
Metal
Metal/Dust/Fume
Dust
Fume
Dust / Fume
Not established
Fume (ceiling)
Insoluble compounds
Metal and insoluble compounds
simple Asphyxiant
Phosphorus
Selenium
Dust
Sulfur dioxide
2
Inorganic compounds
Not established
not Established
0.5
0.1
5
10
Oxide dust (ceiling)
Oxide Fume (ceiling)
Oxide fume
Oxide dust
10
Oxide dust
5
Oxide fume
10
Oxide fume (STEL)
(1) % of alloying material varies with grade of material. (2) ACGIH Threshold Limit Value. (NOTE: No OSHA PEL’s or ACGIH TLV’s exist for steel. Various grades of steel
will contain different combinations of these elements and/or trace elements..
Section 3 - Physical Data
Material is (at normal conditions)
Solid
Boiling Point (Galvanized) 908o C
Appearance and Odor (Carbon) Gray-Black metallic,
Odorless (Galvanized) Silver or Bluish white
Vapor pressure (mm Hg.)Galvanized 1 mmHg
pH
N/A
Section 4 - Fire and Explosion Data
487o C
Solubility in water(% by weight) N/A
Melting Point (Base Metal)>2500o F
Specific Gravity
420o C (Galvanized)
approximately 7
Vapor Density (Air = 1)
No information Found (NIF)
Percent Volatile by Volume (%)
Evaporation Rate
NIF
N/A
Extinguishing Media ( Base Metal) N/A (Galvanized) CO2 Dry Powder extinguisher - Do not use water
Special Fire Fighting Procedures Steel products in the solid state present no fire or explosion hazard
Unusual Fire and Explosion Hazards Zinc oxide fume Flash Point (method used) Auto ignition (solid zinc in oxygen) 908o C
Special fire fighting procedures Self
Section 5 - Reactivity Data
- contained breathing apparatus
Incompatibility (Materials to Avoid) Reacts with strong acids to produce Hydrogen gas
Stability Stable
(Galvanized)Avoid contact with acids and Alkalis
Conditions to avoid N/A
Hazardous Decomposition Products Zinc forms zinc oxide fumes at boiling point
Metallic dust or fumes may be produced during welding, burning, grinding and machining
6-2hri3.doc
Revision 03/12/13
Section 6 - Health Hazard Data
Note: Steel products in their natural state do not present an inhalation, ingestion or contact hazard. However, operations such as Burning, Welding, Sawing, Brazing, Grinding
and Machining may release fumes and/or dusts which may present health hazards if TLV’s are exceeded. The major exposure hazard is inhalation. Effects of overexposure to
fumes and dust are as follows:
ACUTE: Excessive inhalation of metallic fumes and dust may result in irritation of eyes, nose, and throat. High concentrations of fumes and dust of ironoxide, manganese, and zinc may result in metal fume fever. Typical symptoms last from 12 to 48 hours and consist of a metallic taste in the mouth, dryness
and irritation of the throat, chills and fever
CHRONIC: Chronic health effects (including cancer) have been associated with the fumes and dusts of individual component metals, and welding fumes as
a general category have been listed by IARC as a carcinogen. See conditions listed opposite the element:
Iron (Fe)
siderosis, a benign pneumoconiosis, symptoms may include chronic bronchitis, emphysema, and shortness of breath, breathing fumes may result in metal
fume fever. Penetration of iron particles into the skin or eye may cause an exogenous or ocular siderosis. Ingestion overexposures may affect the
gastrointestinal, nervous, hematopoietic system and the liver
Aluminum (Al)
breathing fumes may result in metal fume fever
Antimony (Sb)
breathing fumes may result in metal fume fever
Arsenic As)
breathing fumes may result in metal fume fever
Beryllium (Be)
breathing fumes may result in metal fume fever
No chronic debilitating symptoms indicated
Bismuth
no information available
Boron (B)
breathing fumes may result in metal fume fever, Primary target organs are the lung and kidney. Because of its cumulative nature, chronic cadmium
poisoning can cause serious disease which takes many years to develop and may continue to progress despite cessation of exposure. Progression of the
disease may not reflect current exposure conditions. It is also capable of causing a painful osteomalacia called “Itai-Itai” in postmenopausal women, and
has caused developmental effects and/or reproductive effects in male / female animals. Cadmium is a listed carcinogen.
Cadmium (Cd)
No information available
Calcium (Ca)
No chronic debilitating symptoms indicated
Carbon (C)
breathing fumes may result in metal fume fever. Prolonged and repeated overexposure to dust or fumes may cause skin ulcers, nasal irritation and
ulceration, kidney damage and cancer of the respiratory system. Is listed as a carcinogen
Chromium (Cr)
breathing fumes may result in metal fume fever
Cobalt (Co)
Dust and fume can irritate the eyes, nose and throat causing coughing, wheezing, nosebleeds, ulcers and metal fume fever. Other effects from repeated
inhalation include a metallic or sweet taste, discoloration of skin, teeth or hair, and allergic skin reaction.
Copper (Cu)
breathing fumes may result in metal fume fever, Lead can accumulate in the body. Consequently, exposure to fumes or dust may produce signs of
polyneuritis, diminished vision and peripheral neuropathy, such as tingling and loss of feeling in fingers, arms and legs. Lead is a known reproductive
and developmental toxin. It is also associated with central nervous system disorders, anemia, kidney disfunction and neurobehavioral abnormalities. The
brain is a major target organ. Lead is a listed carcinogen
Lead Pb)
breathing fumes may result in metal fume fever
Magnesium (Mg)
breathing fumes may result in metal fume fever, Bronchitis,and pneumonitis. A variety of neurological symptoms including muscle spasms, gait
disturbances, tremors, and psychoses.
Manganese (Mn)
No information available
Molybdenum Mo) No chronic debilitating symptoms indicated
Niobium (Nb) breathing fumes may result in metal fume fever, Prolonged and repeated contact may cause sensitization dermatitis. Inhalation has caused lung damage
as well as sinus, nasal and lung cancer in lab animals. Nickel is a listed carcinogen.
Nickel (Ni)
No information available
Nitrogen (N)
Necrosis of the mandible
Phosphorus (P)
breathing fumes may result in metal fume fever
Selenium (Se)
No chronic debilitating symptoms indicated
Silicon (Si)
(as sulfur dioxide) Edema of the lungs
Sulfur (S)
breathing fumes may result in metal fume fever
Tin (Sn)
No information available
Titanium (Ti)
No information available
Tungsten (W)
The major target for vanadium pentoxide toxicity is the respiratory tract. Fumes or dust can cause severe eye and respiratory irritation and systemic
effects. Emphysema, pneumonia, Chronic bronchitis, green tongue, conjunctivitis, pharyngitis, rhinitis, rales, chronic productive cough, tightness of the
chest, and allergic reactions have been reported following overexposure.
Vanadium (V)
breathing fumes may result in metal fume fever, as vanadium pentoxide - Emphysema, pneumonia
Zinc (Zn)
Gastrointestinal inflammation reported in animal studies
Carcinogen(N.T.P.) N/A Carcinogen(I.A.R.C.) N/A Medical conditions aggravated by exposure: Individuals with chronic respiratory disorders may be adversely
affected by any fume or airborne particulate matter exposure
Emergency Medical Procedures: Inhalation: Remove to fresh air, if condition continues, consult a physician. Eye Contact: Flush thoroughly with running
water to remove particulate, obtain medical attention. Skin Contact: Remove particles by washing thoroughly with soap and water. Seek medical attention
if condition persists. Ingestion: If significant amounts of metal are ingested, consult a physician
HMIS RATING - Health 0 Flammability 0 Reactivity 0 HMIS HAZARD INDEX - Minimal 0 Slight 1 Moderate 2 Serious 3 Severe 4
Section 7 - Environmental Protection
Spill or Leak procedures: Fine turnings and small chips should be swept or vacuumed. Scrap metal can be reclaimed for reuse. Waste Disposal Method:
Used or unused product should be disposed of in accordance with Federal, State and Local disposal or discharge laws.
Section 8 - Special Protection Information
Respiratory Protection: An appropriate dust/mist/fume respirator should be used to avoid excessive inhalation of particulate. If exposure limits are reached
or exceeded, use NIOSH approved equipment. Hands, Arms, and Body: Protective gloves should be worn as required for welding burning or handling
operations. Eyes and Face: Face shields or goggles should be worn when grinding or cutting. Face shields should be worn when welding or cutting. Other
Clothing and Equipment: As required depending on operations and safety codes
In welding, precautions should be taken for airborne contaminants which may originate from components of the welding rod.
Arc or Spark generated when welding or burning could be a source of ignition for combustible and flammable materials
DISCLAIMER
The information in this MSDS was obtained from sources which we believe are reliable, however, the information is provided without any representation or warranty,
express or implied, regarding the accuracy or correctness.
The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we
do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use, or disposal of
the product.
6-2hri3.doc
Revision 03/12/13
HEALTH
2
FLAMMABILITY 3
REACTIVITY
0
SAFETY DATA SHEET
Prepared by Duro Dyne December 27, 2013
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Trade name:
Product Identifier:
Item #:
Supplier Details:
Information
Phone No:
Emergency
Phone No:
DURO DYNE SOLVENT BASED ADHESIVE
RPG-1, RPG-5, RPG-55
5047, 5048, 5049
DURO DYNE CORPORATION
81 Spence Street
Bay Shore, NY 11706
800-899-3876
800-424-9300 (CHEMTREC)
2. HAZARD IDENTIFICATION
Permissible Exposure Level:
Threshold Limit Value:
Effects of Acute Overexposure:
Eyes:
Skin:
Breathing:
Swallowing:
Effects of Chronic Overexposure:
50 ppm
50 ppm
Can cause severe irritation, redness, tearing, blurred
vision.
Prolonged or repeated contact can cause moderate
irritation, defatting, dermatitis.
Excessive inhalation or vapors can cause nasal and
respiratory irritation, central nervous system effects
including dizziness, weakness, fatigue, nausea, headache
and possible unconsciousness, and even death.
Can cause gastrointestinal irritation, nausea, vomiting and
diarrhea. Aspiration of material into the lungs can cause
chemical pneumonitis, which can be fatal.
Prolonged or repeated exposure to N-Hexane may damage
peripheral nerve tissue (that of the arms and legs) and
result in muscular weakness and loss of sensation in the
extremities (Peripheral Neuropathy). Methyl Ethyl Ketone
may potentate (shorten time of onset) peripheral
neuropathy caused by N-Hexane. Prolonged and repeated
inhalation of high levels of mixed isomers of Hexane
resulted kidney damage in male rats. The effects observed
are the same of those seen in male rats exposed to other
hydrocarbons. The mechanism by which these chemicals
cause the characteristics kidney toxicity is unique to the
male rat and the kidney effects are not expected to occur
in man. Overexposure to this material (or its components)
has been suggested as a cause of the following effects in
Page 1 of 4
2. HAZARD IDENTIFICATION continued
humans and may aggravate pre-existing disorders of these
organs, central nervous system, and visual impairment.
3. COMPOSITION/INFORMATION ON INGREDIENTS
PRINCIPAL HAZARDOUS
COMPONENTS
Toluene
Hexane
% BY
WEIGHT
12.5%
55.5%
CAS#
108-88-3
110-54-3
THRESHOLD LIMIT
VALUE
100 ppm
50 ppm
These chemicals are subject to the reporting requirements of Section 313 of Sara Title III. OSHA, NTP
or IARC does not class the ingredients in this product as carcinogens. All ingredients in this product are
on the TSCA Inventory.
4. FIRST AID MEASURES
Skin:
Eyes:
Ingested:
Inhalation:
Primary Routes of Entry:
Effects of Chronic Overexposure:
Thoroughly wash exposed area with soap and water.
Remove contaminated clothing. Launder contaminated
clothing before re-use.
Flush with large amounts of water. Lifting upper and
lower lids occasionally, Get medical attention.
Do not induce vomiting. Keep person warm, quiet and get
medical attention. Aspiration of material into the lungs
due to vomiting can cause chemical pneumonits, which
can be fatal.
If affected remove individual to fresh air. If breathing is
difficult, administer oxygen. If breathing has stopped give
artificial respiration. Keep person warm, quiet and get
medical attention.
Inhalation, skin contact.
Prolonged or repeated exposure to N-Hexane may
Damage peripheral nerve tissue(that of the arms and
legs) and result in muscular weakness and loss of
sensation in the extremities (Peripheral Nauropathy).
Methyl Ethyl Ketone may potentate (shorten the time of
onset) peripheral neuropathy caused by N-Hexane.
Prolonged and repeated inhalation of high levels of
mixed isomers of Hexane resulted kidney damage in
male rats. The effects observed are the same of those
seen in male rats exposed to other hydrocarbons. The
mechanism by which these chemicals cause the
characteristic kidney toxicity is unique to the male rat
and the kidney effects are not expected to occur in man.
Overexposure to this material (or its components) has
been suggested as a cause of the following effects in
humans and may aggravate pre-existing disorders of
these organs, central nervous system, and visual
impairment.
Page 2 of 4
5. FIRE-FIGHTING MEASURES
Tag closed cup. <0°F
LEL: 1.2%
UEL: 6.9%
Foam, dry chemical CO2, water fog or spray.
Use air supplied breathing equipment for enclosed areas.
Avoid breathing of vapor or fumes.
Heat may build up pressure in closed containers. Cool
with water spray.
Flash Point (Test Method):
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire & Explosion Hazards:
6. ACCIDENTAL RELEASE MEASURES
Remove all ignition sources. Keep people away. Recover
liquid. Add absorbent sawdust, etc. Ventilate, wipe up.
Place in sealed containers.
Spill Response:
7. HANDLING AND STORAGE
Hygienic Practices in
Handling & Storage:
Flammable mixture. Do not store near heat, sparks or
open flame. Use with adequate ventilation. Avoid
prolonged or repeated breathing of vapor or contact with
skin. Do not take internally, in an emergency call a
physician. Keep out of reach of children.
Do not store with strong oxidants like liquid chlorine or
concentrated oxygen.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye Protection:
Skin Protection:
Respiratory Protection (Specific Type):
Ventilation Recommended:
Other Protection:
Splash goggles or safety glasses.
Chemical resistant gloves.
NIOSH approved dual cartridge respirator with cartridges
suitable for organic solvent vapor.
Adequate = to outdoors.
Eye wash, safety shower.
9. PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point:
Specific Gravity (Water = 1):
Vapor Pressure (mmHg):
Percent Volatile:
Vapor Density (Air = 1):
Evaporation Rate (N-Butyl Aceate = 1):
Solubility in Water:
Appearance & Odor:
Volatile Organic Content:
150°F
.77
180
68% by weight
3
8
Not Soluble.
Amber colored syrup, mild odor.
4.43 lbs/gal or 531 grams/liter
Page 3 of 4
10. STABILITY AND REACTIVITY
Stability:
Conditions to Avoid:
Incompatibility/Materials to Avoid:
Hazardous Polymerization:
Conditions to Avoid:
Hazardous Decomposition of Products:
Stable
None
Strong oxidants like liquid chlorine.
Will not occur.
None
If burned, fumes could contain oxides of carbon and
nitrogen.
11. TOXICOLOGICAL INFORMATION
No information available.
12. ECOLOGICAL INFORMATION
No information available.
13. DISPOSAL METHOD
Waste Disposal Method:
Approved site. Obey local, state and federal regulations.
14. TRANSPORT INFORMATION
Proper DOT Shipping Name:
Adhesive Containing Flammable Liquid,3, PG II.
15. REGULATORY INFORMATION
Chemical Family:
DOT Hazard Classification:
Solvent Based Adhesive
UN 133
16. OTHER INFORMATION
Warning:
This product contains chemicals known to the State of
California to cause cancer.
Do not store with strong oxidants like liquid chlorine or
concentrated oxygen.
Hazard Rating:
Health: 2
Flammability: 3
Reactivity: 0
April 3, 2012
Date SDS Prepared:
THE INFORMATION AND RECOMMENDATIONS SET FORTH HEREIN ARE BELIEVED TO BE ACCURATE. BECAUSE SOME
OF THE INFORMATION IS DERIVED FROM INFORMATION PROVIDED TO DURO DYNE CORPORATION FROM ITS
SUPPLIERS, DURO DYNE CORPORATION MAKES NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY
OF THE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. SINCE THE USE OF THIS INFORMATION AND
THE CONDITIONS AND USE OF THIS PRODUCT ARE CONTROLLED BY THE USER, IT IS THE USER'S OBLIGATION TO
DETERMINE THE CONDITIONS OF SAFE USE OF THE PRODUCT. THE INFORMATION IS SUPPLIED FOR YOUR
INFORMATION AND CONSIDERATION AND DURO DYNE CORPORATION ASSUMES NO RESPONSIBILITY FOR USE OR
RELIANCE THEREON. IT IS THE RESPONSIBILITY OF THE USER OF DURO DYNE CORPORATION PRODUCTS TO COMPLY
WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL LAWS AND REGULATIONS.
Page 4 of 4
3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse
03/11/14
Safety Data Sheet
Copyright,2014,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:
Issue Date:
25-0157-5
03/11/14
Version Number:
Supercedes Date:
1.06
03/22/13
SECTION 1: Identification
1.1. Product identifier
3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse
1.2. Recommended use and restrictions on use
Recommended use
Abrasive Product
1.3. Supplier’s details
MANUFACTURER:
DIVISION:
ADDRESS:
Telephone:
3M
Abrasive Systems Division
3M Center, St. Paul, MN 55144-1000, USA
1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification
Not classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200.
2.2. Label elements
Signal word
Not applicable.
Symbols
Not applicable.
Pictograms
Not applicable.
Notes to Physician:
Not applicable
2.3. Hazards not otherwise classified
None.
__________________________________________________________________________________________
Page 1 of 11
3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse
03/11/14
48% of the mixture consists of ingredients of unknown acute oral toxicity.
SECTION 3: Composition/information on ingredients
Ingredient
Aluminum Oxide Mineral (non-fibrous)
Iron Oxide Mineral
Limestone
Silica
Titanium Dioxide
Quartz Silica
Cured Resin
Cloth Backing
C.A.S. No.
1344-28-1
1309-37-1
1317-65-3
7631-86-9
13463-67-7
14808-60-7
Mixture
Mixture
% by Wt
15 - 30
5 - 15
5 - 15
1- 2
0.5 - 1.5
0.001 - 0.25
2 - 15
15 - 40
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance
Carbon monoxide
Carbon dioxide
Condition
During Combustion
During Combustion
5.3. Special protective actions for fire-fighters
No unusual fire or explosion hazards are anticipated.
__________________________________________________________________________________________
Page 2 of 11
3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse
03/11/14
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Observe precautions from other sections.
6.2. Environmental precautions
Not applicable.
6.3. Methods and material for containment and cleaning up
Not applicable.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
For industrial or professional use only. Avoid breathing of dust created by sanding, grinding or machining. Do not eat, drink
or smoke when using this product. Wash thoroughly after handling. Combustible dust may form by action of this product on
another material (substrate). Dust generated from the substrate during use of this product may be explosive if in sufficient
concentration with an ignition source. Dust deposits should not be allowed to accumulate on surfaces because of the potential
for secondary explosions.
7.2. Conditions for safe storage including any incompatibilities
No special storage requirements.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
Ingredient
Iron Oxide Mineral
C.A.S. No.
1309-37-1
Iron Oxide Mineral
1309-37-1
ROUGE
1309-37-1
Limestone
1317-65-3
US Dept of
Labor - OSHA
Aluminum Oxide Mineral (nonfibrous)
1344-28-1
Aluminum Oxide Mineral (nonfibrous)
1344-28-1
Chemical
Manufacturer
Rec Guid
US Dept of
Labor - OSHA
Aluminum, insoluble compounds 1344-28-1
Titanium Dioxide
Agency
Amer Conf of
Gov. Indust.
Hyg.
US Dept of
Labor - OSHA
US Dept of
Labor - OSHA
Amer Conf of
Gov. Indust.
Hyg.
13463-67-7 Amer Conf of
Gov. Indust.
Hyg.
Limit type
TWA(respirable fraction):5
mg/m3
Additional Comments
TWA(as fume):10 mg/m3
TWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
TWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
TWA:1 fiber/cc
TWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
TWA(respirable fraction):1
mg/m3
TWA:10 mg/m3
__________________________________________________________________________________________
Page 3 of 11
3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse
Titanium Dioxide
Titanium Dioxide
Quartz Silica
Quartz Silica
13463-67-7 Chemical
Manufacturer
Rec Guid
13463-67-7 US Dept of
Labor - OSHA
14808-60-7 Amer Conf of
Gov. Indust.
Hyg.
14808-60-7 US Dept of
Labor - OSHA
Silica
7631-86-9
SILICA, AMORPHOUS
7631-86-9
Chemical
Manufacturer
Rec Guid
US Dept of
Labor - OSHA
03/11/14
TWA(as respirable dust):5
mg/m3
TWA(as total dust):15 mg/m3
TWA(respirable
fraction):0.025 mg/m3
TWA concentration(as total
dust):0.3 mg/m3;TWA
concentration(respirable):0.1
mg/m3(2.4 millions of
particles/cu. ft.)
TWA(as respirable dust):3
mg/m3
TWA concentration:0.8
mg/m3;TWA:20 millions of
particles/cu. ft.
Amer Conf of Gov. Indust. Hyg. : American Conference of Governmental Industrial Hygienists
American Indust. Hygiene Assoc : American Industrial Hygiene Association
Chemical Manufacturer Rec Guid : Chemical Manufacturer's Recommended Guidelines
US Dept of Labor - OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Provide appropriate local exhaust ventilation for sanding, grinding or machining. Use general dilution ventilation and/or
local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control
dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Provide local exhaust at
process emission sources to control exposure near the source and to prevent the escape of dust into the work area. Ensure that
dust-handling systems (such as exhaust ducts, dust collectors, vessels, and processing equipment) are designed in a manner to
prevent the escape of dust into the work area (i.e., there is no leakage from the equipment).
8.2.2. Personal protective equipment (PPE)
Eye/face protection
To minimize the risk of injury to face and eyes, always wear eye and face protection when working at sanding or grinding
operations or when near such operations. Select and use eye/face protection to prevent contact based on the results of an
exposure assessment. The following eye/face protection(s) are recommended:
Safety Glasses with side shields
Skin/hand protection
Wear appropriate gloves to minimize risk of injury to skin from contact with dust or physical abrasion from grinding or
sanding.
Respiratory protection
Assess exposure concentrations of all materials involved in the work process. Consider material being abraded when
determining the appropriate respiratory protection. Select and use appropriate respirators to prevent inhalation overexposure.
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
__________________________________________________________________________________________
Page 4 of 11
3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse
03/11/14
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Solid
General Physical Form:
Odor, Color, Grade:
Odor threshold
pH
Melting point
Boiling Point
Flash Point
Evaporation rate
Flammability (solid, gas)
Flammable Limits(LEL)
Flammable Limits(UEL)
Vapor Pressure
Solid Abrasive Product
Not Applicable
Not Applicable
Not Applicable
Not Applicable
Not Applicable
Not Applicable
Not Classified
Not Applicable
Not Applicable
Not Applicable
Vapor Density
Not Applicable
Specific Gravity
Solubility In Water
Not Applicable
Not Applicable
Solubility- non-water
Not Applicable
Partition coefficient: n-octanol/ water
Autoignition temperature
Decomposition temperature
Viscosity
Not Applicable
Not Applicable
Not Applicable
Not Applicable
SECTION 10: Stability and reactivity
10.1. Reactivity
This material is considered to be non reactive under normal use conditions.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
None known.
10.5. Incompatible materials
None known.
__________________________________________________________________________________________
Page 5 of 11
3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse
10.6. Hazardous decomposition products
Substance
None known.
03/11/14
Condition
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Dust from grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough,
sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Skin Contact:
Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching.
Eye Contact:
Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion.
Dust created by grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling,
pain, tearing, and blurred or hazy vision.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Carcinogenicity:
Ingredient
Quartz Silica
SILICA, CRYS AIRRESP
Titanium Dioxide
C.A.S. No.
14808-60-7
14808-60-7
13463-67-7
Class Description
Grp. 1: Carcinogenic to humans
Known human carcinogen
Grp. 2B: Possible human carc.
Regulation
International Agency for Research on Cancer
National Toxicology Program Carcinogens
International Agency for Research on Cancer
Additional Information:
This document covers only the 3M product. For complete assessment, when determining the degree of hazard, the material
being abraded must also be considered.
This product contains titanium dioxide and quartz (crystalline) silica. Cancer of the lungs has been associated with inhalation
of high levels of titanium dioxide in animal studies, and occupational exposure to inhaled quartz silica has been associated
with silicosis and lung cancer. No exposure to titanium dioxide or quartz silica is expected during the normal handling and
use of this product. Titanium dioxide and quartz silica were not detected when air sampling was conducted during simulated
use of similar products containing these substances. Therefore, the health effects associated with titanium dioxide and quartz
(crystalline) silica are not expected during the normal use of this product.
Toxicological Data
__________________________________________________________________________________________
Page 6 of 11
3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse
03/11/14
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name
Overall product
Aluminum Oxide Mineral (non-fibrous)
Aluminum Oxide Mineral (non-fibrous)
Limestone
Iron Oxide Mineral
Route
Ingestion
Dermal
InhalationDust/Mist
(4 hours)
Ingestion
Dermal
InhalationDust/Mist
(4 hours)
Ingestion
Dermal
Rat
Value
No data available; calculated ATE > 5,000 mg/kg
LD50 estimated to be > 5,000 mg/kg
LC50 > 2.3 mg/l
Rat
Rat
Rat
LD50 > 5,000 mg/kg
LD50 > 2,000 mg/kg
LC50 3.0 mg/l
Rat
Not
available
Not
available
Rabbit
Rat
LD50 6,450 mg/kg
LD50 3,100 mg/kg
Iron Oxide Mineral
Ingestion
Silica
Silica
Dermal
InhalationDust/Mist
(4 hours)
Ingestion
Dermal
InhalationDust/Mist
(4 hours)
Ingestion
Dermal
Ingestion
Rat
Rabbit
Rat
LD50 > 5,110 mg/kg
LD50 > 10,000 mg/kg
LC50 > 6.82 mg/l
Rat
LD50 > 10,000 mg/kg
LD50 estimated to be > 5,000 mg/kg
LD50 estimated to be > 5,000 mg/kg
Species
Rabbit
Rabbit
Rabbit
Rabbit
Rabbit
Value
No significant irritation
No significant irritation
No significant irritation
No significant irritation
No significant irritation
No significant irritation
Species
Rabbit
Rabbit
Rabbit
Rabbit
Rabbit
Value
No significant irritation
No significant irritation
No significant irritation
No significant irritation
No significant irritation
Name
Iron Oxide Mineral
Species
Human
Silica
Human
and
animal
Human
and
animal
Value
Some positive data exist, but the data are not
sufficient for classification
Not sensitizing
Aluminum Oxide Mineral (non-fibrous)
Limestone
Limestone
Silica
Titanium Dioxide
Titanium Dioxide
Titanium Dioxide
Quartz Silica
Quartz Silica
Species
LD50 3,700 mg/kg
LD50 > 5,000 mg/kg
LC50 > 0.691 mg/l
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name
Aluminum Oxide Mineral (non-fibrous)
Limestone
Iron Oxide Mineral
Silica
Titanium Dioxide
Quartz Silica
Serious Eye Damage/Irritation
Name
Aluminum Oxide Mineral (non-fibrous)
Limestone
Iron Oxide Mineral
Silica
Titanium Dioxide
Skin Sensitization
Titanium Dioxide
Not sensitizing
Respiratory Sensitization
Name
Species
Value
__________________________________________________________________________________________
Page 7 of 11
3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse
03/11/14
Germ Cell Mutagenicity
Name
Aluminum Oxide Mineral (non-fibrous)
Iron Oxide Mineral
Silica
Titanium Dioxide
Titanium Dioxide
Quartz Silica
Route
In Vitro
In Vitro
In Vitro
In Vitro
In vivo
In Vitro
Quartz Silica
In vivo
Value
Not mutagenic
Not mutagenic
Not mutagenic
Not mutagenic
Not mutagenic
Some positive data exist, but the data are not
sufficient for classification
Some positive data exist, but the data are not
sufficient for classification
Carcinogenicity
Name
Aluminum Oxide Mineral (non-fibrous)
Iron Oxide Mineral
Route
Inhalation
Inhalation
Species
Rat
Human
Silica
Mouse
Titanium Dioxide
Not
Specified
Ingestion
Titanium Dioxide
Quartz Silica
Inhalation
Inhalation
Multiple
animal
species
Rat
Human
and
animal
Value
Not carcinogenic
Some positive data exist, but the data are not
sufficient for classification
Some positive data exist, but the data are not
sufficient for classification
Not carcinogenic
Carcinogenic
Carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name
Route
Value
Species
Test Result
Limestone
Ingestion
Not toxic to development
Rat
NOAEL 625
mg/kg/day
Silica
Ingestion
Not toxic to female reproduction
Rat
Silica
Ingestion
Not toxic to male reproduction
Rat
Silica
Ingestion
Not toxic to development
Rat
NOAEL 509
mg/kg/day
NOAEL 497
mg/kg/day
NOAEL
1,350
mg/kg/day
Exposure
Duration
premating &
during
gestation
1 generation
1 generation
during
organogenesi
s
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name
Route
Target Organ(s)
Value
Species
Test Result
Limestone
Inhalation
respiratory system
All data are negative
Rat
NOAEL
0.812 mg/l
Exposure
Duration
90 minutes
Specific Target Organ Toxicity - repeated exposure
Name
Route
Target Organ(s)
Value
Species
Test Result
Aluminum Oxide Mineral
(non-fibrous)
Inhalation
pneumoconiosis |
pulmonary fibrosis
Human
NOAEL Not
available
Limestone
Inhalation
respiratory system
Human
NOAEL Not
available
occupational
exposure
Iron Oxide Mineral
Inhalation
pulmonary fibrosis |
pneumoconiosis
Some positive data exist, but the
data are not sufficient for
classification
Some positive data exist, but the
data are not sufficient for
classification
Some positive data exist, but the
data are not sufficient for
Exposure
Duration
occupational
exposure
Human
NOAEL Not
available
occupational
exposure
__________________________________________________________________________________________
Page 8 of 11
3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse
Silica
Inhalation
Titanium Dioxide
Inhalation
respiratory system |
silicosis
respiratory system
Titanium Dioxide
Inhalation
pulmonary fibrosis
Quartz Silica
Inhalation
silicosis
03/11/14
classification
All data are negative
Human
Some positive data exist, but the
data are not sufficient for
classification
All data are negative
Rat
Causes damage to organs
through prolonged or repeated
exposure
Human
Human
NOAEL Not
available
LOAEL
0.010 mg/l
occupational
exposure
2 years
NOAEL Not
available
NOAEL Not
available
occupational
exposure
occupational
exposure
Aspiration Hazard
Name
Value
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Prior to disposal, consult all applicable authorities and regulations to insure proper classification. The substrate that was
abraded must be considered as a factor in the disposal method for this product. Dispose of waste product in a permitted
industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction
may require the use of additional fuel during incineration processes. If no other disposal options are available, waste product
may be placed in a landfill properly designed for industrial waste.
EPA Hazardous Waste Number (RCRA): Not regulated
SECTION 14: Transport Information
Not regulated per U.S. DOT, IATA or IMO.
These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for
complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M
transportation classifications are based on product formulation, packaging, 3M policies and 3M understanding of
applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information
applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3M
package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet
applicable regulatory requirements.
SECTION 15: Regulatory information
__________________________________________________________________________________________
Page 9 of 11
3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse
03/11/14
15.1. US Federal Regulations
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
Immediate Hazard - No
Delayed Hazard - No
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 0 Flammability: 1 Instability: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
HMIS Hazard Classification
Health: 0 Flammability: 1 Physical Hazard: 0 Personal Protection: X - See PPE section.
Hazardous Material Identification System (HMIS® III) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use
and are not intended for use in emergency situations. HMIS® III ratings are to be used with a fully implemented HMIS® III
program. HMIS® is a registered mark of the American Coatings Association (ACA).
Document Group:
Issue Date:
25-0157-5
03/11/14
Version Number:
Supercedes Date:
1.06
03/22/13
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
__________________________________________________________________________________________
Page 10 of 11
3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse
03/11/14
directly from 3M
3M USA SDSs are available at www.3M.com
__________________________________________________________________________________________
Page 11 of 11
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
FANTASTIK® ORIGINAL DISINFECTANT ALL PURPOSE CLEANER
Version 3.0
Print Date 03/15/2013
Revision Date 02/25/2013
MSDS Number 350000004769
1. PRODUCT AND COMPANY IDENTIFICATION
Product information
Trade name
:
FANTASTIK® ORIGINAL DISINFECTANT ALL PURPOSE
CLEANER
Use of the
Substance/Mixture
Company
:
Hard Surface Cleaner
:
S.C. Johnson and Son, Limited
1 Webster Street
Brantford ON N3T 5R1
Emergency telephone
number
:
24 Hour Transport & Medical Emergency Phone (866) 2315406
24 Hour International Emergency Phone (952) 852-4647
24 Hour Canadian Transport Emergency Phone (CANUTEC)
(613) 996-6666
Emergency Overview
Appearance / Odor
:
yellow / liquid / pleasant
Immediate Concerns
:
Caution
CAUSES EYE IRRITATION.
Avoid contact with skin, eyes and clothing.
Potential Health Effects
Exposure routes
:
Eye, Skin, Inhalation, Ingestion.
Eyes
:
Causes:
Moderate eye irritation
Skin
:
Causes skin irritation.
Inhalation
:
No adverse effects expected when used as directed.
Ingestion
:
May cause irritation to mouth, throat and stomach.
May cause abdominal discomfort.
Aggravated Medical
Condition
:
Persons with pre-existing skin disorders may be more
susceptible to irritating effects.
2. HAZARDS IDENTIFICATION
1/8
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
FANTASTIK® ORIGINAL DISINFECTANT ALL PURPOSE CLEANER
Version 3.0
Print Date 03/15/2013
Revision Date 02/25/2013
MSDS Number 350000004769
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or
the Canadian Controlled Products Regulations are listed in this table:
Chemical Name
Propylene glycol monobutyl
ether
Alkyl dimethyl benzyl
ammonium chloride
Alkyl dimethyl ethyl benzyl
ammonium chloride (C1214)
CAS-No.
5131-66-8
Weight percent
1.00 - 5.00
68391-01-5
0.10 - 1.00
68956-79-6
0.10 - 1.00
For additional information on product ingredients, see www.whatsinsidescjohnson.com.
4. FIRST AID MEASURES
Eye contact
:
Remove contact lenses. Flush immediately with plenty of water
for at least 15 to 20 minutes. Get medical attention if irritation
develops and persists.
Skin contact
:
Wash off immediately with plenty of water. Remove
contaminated clothing and shoes. Get medical attention if
irritation develops and persists. Wash clothing before reuse.
Thoroughly clean shoes before reuse.
Inhalation
:
No special requirements
Ingestion
:
If swallowed, DO NOT induce vomiting unless directed to do so
by medical personnel. Never give anything by mouth to an
unconscious person. Get medical attention immediately.
Suitable extinguishing
media
:
Use water spray, alcohol-resistant foam, dry chemical or
carbon dioxide.
Specific hazards during
firefighting
:
Container may melt and leak in heat of fire.
Further information
:
Fight fire with normal precautions from a reasonable distance.
Standard procedure for chemical fires. Wear full protective
clothing and positive pressure self-contained breathing
apparatus.
5. FIREFIGHTING MEASURES
2/8
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
FANTASTIK® ORIGINAL DISINFECTANT ALL PURPOSE CLEANER
Version 3.0
Print Date 03/15/2013
Revision Date 02/25/2013
MSDS Number 350000004769
Flash point
:
Note: no data available
Lower explosion limit
:
Note: no data available
Upper explosion limit
:
Note: no data available
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
:
No special precautions required.
Environmental precautions
:
Outside of normal use, avoid release to the environment.
Methods for cleaning up
:
Soak up with inert absorbent material.
Sweep up and shovel into suitable containers for disposal.
Dike large spills.
Clean residue from spill site.
Advice on safe handling
:
Avoid contact with skin, eyes and clothing.
For personal protection see section 8.
Use only as directed.
KEEP OUT OF REACH OF CHILDREN AND PETS.
Advice on protection
against fire and explosion
:
Normal measures for preventive fire protection.
:
Keep container closed when not in use.
Keep in a dry, cool and well-ventilated place.
7. HANDLING AND STORAGE
Handling
Storage
Requirements for storage
areas and containers
3/8
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
FANTASTIK® ORIGINAL DISINFECTANT ALL PURPOSE CLEANER
Version 3.0
Print Date 03/15/2013
Revision Date 02/25/2013
MSDS Number 350000004769
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
ACGIH or OSHA exposure limits have not been established for this product or reportable
ingredients unless noted in the table above.
Occupational Exposure Limits
Components
Ethyl alcohol
CAS-No.
mg/m3
ppm
64-17-5
-
1,000 ppm
Nonstandard
units
-
Basis
ACGIH
STEL
Occupational Exposure Limits
Personal protective equipment
No personal respiratory protective equipment normally
required.
Respiratory protection
Hand protection
:
If prolonged or repeated contact is possible:
Wear suitable gloves.
Safety glasses with side-shields
Eye protection
Skin and body protection
:
No special requirements.
Hygiene measures
:
Handle in accordance with good industrial hygiene and safety
practice. Wash thoroughly after handling.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form
:
liquid
Color
:
yellow
Odor
:
pleasant
pH
:
11.8 - 12.4
Melting point
:
no data available
Boiling point
:
no data available
Freezing point
:
no data available
4/8
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
FANTASTIK® ORIGINAL DISINFECTANT ALL PURPOSE CLEANER
Version 3.0
Print Date 03/15/2013
Revision Date 02/25/2013
MSDS Number 350000004769
Flash point
:
no data available
Evapouration rate
:
no data available
Auto-ignition temperature
:
no data available
Lower explosion limit
:
no data available
Upper explosion limit
:
no data available
Vapour pressure
:
17.5 mmHg
Density
:
1.01 g/cm3
similar to water
Water solubility
:
completely soluble
Partition coefficient: noctanol/water
:
Viscosity, dynamic
:
no data available
Relative vapour density
:
no data available
Volatile Organic Compounds
Total VOC (wt. %)*
:
3%
- additional exemptions may apply
*as defined by US Federal and State Consumer Product
Regulations
Conditions to avoid
:
Direct sources of heat.
Materials to avoid
:
Strong acids
Hazardous decomposition
products
:
Thermal decomposition can lead to release of irritating gases
and vapours.
Thermal decomposition
:
Note: no data available
Hazardous reactions
:
Stable under recommended storage conditions.
no data available
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute oral toxicity
:
LD50
Measured
> 5,000 mg/kg
5/8
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
FANTASTIK® ORIGINAL DISINFECTANT ALL PURPOSE CLEANER
Version 3.0
Print Date 03/15/2013
Revision Date 02/25/2013
MSDS Number 350000004769
Acute inhalation toxicity
:
no data available
Acute dermal toxicity
:
LD50
Measured
> 5,000 mg/kg
Chronic effects
Carcinogenicity
:
no data available
Mutagenicity
:
None Anticipated
Reproductive effects
:
no data available
Teratogenicity
:
no data available
Sensitisation
:
no data available
:
no data available
12. ECOLOGICAL INFORMATION
Ecotoxicity effects
13. DISPOSAL CONSIDERATIONS
Observe all applicable Federal, Provincial and State
regulations and Local/Municipal ordinances regarding
disposal.
Consumer may discard empty container in trash, or recycle
where facilities exist.
14. TRANSPORT INFORMATION
Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.
Land transport
 U.S. DOT and Canadian TDG Surface Transportation:
Proper shipping name
not regulated
Class:
None.
UN/ID No.:
None.
Packaging group
None.
Sea transport
 IMDG:
Proper shipping name
not regulated
6/8
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
FANTASTIK® ORIGINAL DISINFECTANT ALL PURPOSE CLEANER
Version 3.0
Print Date 03/15/2013
Revision Date 02/25/2013
MSDS Number 350000004769
Class:
UN/ID No.:
Packaging group
None.
None.
None.
Air transport
 ICAO/IATA:
Proper shipping name
Class:
UN/ID No.:
Packaging group
not regulated
None.
None.
None.
15. REGULATORY INFORMATION
California Prop. 65
:
Canada Regulations
:
This product is not subject to the reporting requirements under
California's Proposition 65.
This product has been classified in accordance with hazard
criteria of the Controlled Products Regulations and the MSDS
contains all the information required by the Controlled Products
Regulations.
16. OTHER INFORMATION
HMIS Ratings
Health
2
Flammability
0
Reactivity
0
NFPA Ratings
Health
2
Fire
0
Reactivity
0
Special
-
This information is being provided in accordance with Occupational Safety and Health
Administration (OSHA) and Canada’s Workplace Hazard Material Information System (WHMIS)
regulations. The information supplied is designed for workplaces where product use and
frequency of exposure exceeds that established for the labeled consumer use.
Further information
7/8
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
FANTASTIK® ORIGINAL DISINFECTANT ALL PURPOSE CLEANER
Version 3.0
Print Date 03/15/2013
Revision Date 02/25/2013
MSDS Number 350000004769
This document has been prepared using data from sources considered to be technically reliable.
It does not constitute a warranty, expressed or implied, as to the accuracy of the information
contained herein. Actual conditions of use are beyond the seller's control. User is responsible to
evaluate all available information when using product for any particular use and to comply with all
Federal, State, Provincial and Local laws and regulations.
Prepared by:
SC Johnson Global Safety Assessment &
Regulatory Affairs (GSARA)
8/8
MATERIAL SAFETY DATA SHEET
______________________________________________________________________________________
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name: DuctSeal 321
Synonyms: Water-Based Mastic
Manufacturer/Supplier
Carlisle HVAC Products
900 Hensley Lane
Wylie, TX 75098
Internet Address: http://www.carlisleHVAC.com
Fax Number: (972) 442-0076
Phone Numbers
Medical Emergency:
CHEMTREC (USA): (800) 424-9300
CHEMTREC (International):
MSDS Assistance: (972) 442-6545
Fax On Demand: NA
Technical Assistance: (888) 229-2199
Customer Service: (888) 229-0199
______________________________________________________________________________________
2. COMPONENT INFORMATION
Component
CAS No.
Percent Range
Hazardous in Blend
Methanol
67-56-1
0.5 – 3.45
This product is not hazardous according OSHA 29 CFR 1910.1200.
Hazards:
Flammable/Combustible
No Acute
No
Chronic
No Carcinogen No
Toxin
Toxin
Pressure No Reactive
No Exposure Limit
Target Organ
Other
2A. OTHER INGREDIENTS Greater than 3%
Component
CAS No.
Latex Co-polymer
24937-78-8
Calcium Carbonate
1317-65-3
Clay
1332-58-7
Chlorinated Paraffin
63449-39-8
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Emergency and Hazards Overview:
May cause moderate irritation to eyes. May be harmful if swallowed. Read and understand all health and
safety information on the product label and Material Safety Data Sheet before use.
Ratings
Health
1
Flammability
0
Reactivity
0
Primary Route of Exposure: Skin x Inhalation x Eye x Ingestion x
Health Effect Information
Eye Contact: May cause eye irritation if wiped or rubbed into eyes.
Skin Contact: May cause mild skin irritation on prolonged or repeated contact.
Inhalation: Breathing high concentrations of vapors may cause nausea & irritation of nose, throat, &
respiratory tract. Respiratory symptoms associated with pre-existing lung disorders may be
aggravated by exposure to this material.
Ingestion: Ingestion of large quantity may cause initial central nervous system stimulation, followed by
depression.
DuctSeal 321
Issued: 1 February 2014
Supersedes: 1 March 2011
Page 1 of 6
Medical Conditions Aggravated by Exposure: Prolonged exposure to vapors could aggravate
pre-existing disorders in lungs, kidney and liver.
4. FIRST AID INFORMATION
Eye Contact: Flush with water for 15 minutes. Get medical attention immediately.
Skin Contact: Wipe off and wash skin with soap and water. Promptly remove contaminated clothing and
wash before reuse.
Inhalation: Remove to fresh air. If breathing has stopped, start artificial respiration. Oxygen may be
administered. Consult physician immediately
Ingestion: Do not induce vomiting unless directed to do so by a physician. Consult a physician
immediately.
Notes to Physician: This product contains ethylene glycol, Hexahydro-1, 3,5-triethyl-s-triazine (not in a
reportable amount).
5. FIRES AND EXPLOSION INFORMATION
Flammable Properties
Flash Point: No flash to boiling
Flame extension: NA
Flammable Limits in Air
Upper Percent: NA
Lower Percent: NA
Auto ignition Temperature: NA
Test Method: Closed cup
Test Method: NA
Test Method: NA
NFPA Classification: H 1 F 0 R 0
Extinguishing Media: CO2, foam, dry chemical or water spray.
Fire Fighting Measures
Special Fire Fighting Procedures and Equipment: Firemen must wear full-face air-supplied masks and
full protective clothing.
Unusual Fire and Explosion Conditions: This product is not sensitive to physical shock or static
discharge. Exposure of closed container to temperatures above the boiling point could cause
pressure buildup and container rupture.
Hazardous Combustion By-Products: CO, CO2, unburned hydrocarbons, or nitrous oxides.
DuctSeal 321
Issued: 1 February 2014
Supersedes: 1 March 2011
Page 2 of 6
______________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Personnel Safeguards: Evacuate non-essential personnel to safe areas. Clean-up responders should wear
proper protective clothing and gloves before entering the affected area.
Regulatory Notifications: Certain component of this product is defined as hazardous according to U.S.
EPA. Spill reporting requirements and reportable quantities vary by region.
Consult all applicable state and local regulations. For Canada, observe all
precautions noted above.
Containment and Clean up: Prevent product from entering drinking water supplies or streams. Observe
above precautions, collect liquid with inert, noncombustible material and
remove for disposal.
7. HANDLING AND STORAGE INFORMATION
Handling: Normal use condition doesn’t produce respirable Silica. However, sanding, grinding, and
burning might release respirable Silica. Keep out of reach of children. Launder contaminated
clothing. Wash hands with soap and water after use, especially before eating or drinking.
Storage: Store in a dry, well ventilated environment away from heat, above 35 deg F and below 110 deg F.
Keep containers closed when not in use. Do not pressurize, cut weld or grind containers.
Empty Container Warnings
Drums: Drums may be reused after wash.
Plastic: Plastic containers may be reused after wash.
______________________________________________________________________________________
8. EXPOSURE CONTROLS / PERSONAL PROTECTION INFORMATION
Exposure Limits and Guidelines
Component
Methanol
CAS No.
67-56-1
Exposure Limit
200 ppm OSHA PEL
200 ppm ACGIH TWA, 250 ppm STEL
Personal Protective Equipment
Eye/Face Protection: Wear safety goggles or face shield. Contact lenses should not be worn.
Skin Protection: Use protective rubber gloves (Hycron, neoprene, or nitrile).
Respiratory Protection: Provide adequate ventilation to maintain vapors below PEL/TWA. If vapor
levels are exceeded, use NIOSH approved respirator, both during and
immediately after application, until vapor levels are below limits.
Personal Hygiene: Avoid rubbing eyes during handling. Use good personal hygiene practices to avoid
incidental ingestion.
Engineering Controls / Work Practices
Ventilation: Provide local exhaust or area ventilation to maintain concentration of vapors below
PEL/TWA.
Other: Source of clean water should be available in the work area for flushing eyes and skin. Wash
thoroughly with soap and water after use and before eating.
DuctSeal 321
Issued: 1 February 2014
Supersedes: 1 March 2011
Page 3 of 6
______________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES??
Appearance: Gray Mastic
Odor: Typical latex with slight ammonia odor
Physical state: Mastic
pH: 8.4 – 9.5
DOT Corrosivity: NA
Boiling Point: 212ºF
Melting Point: NA
Specific Gravity: 1.34-1.41
Pour Point: NA
Solubility in Water: Miscible with water
Octanol / Water Coefficient: Log Kow = NA
Vapor Pressure: 17 mm Hg @ 20ºC
Vapor Density (air=1): <air
Percent Volatile by Weight: 28-32
Volatile Organic Content: 93 g/l (according
to SCAQMD calculation)
Molecular Weight: NA
Average Carbon Number: NA
Viscosity @ 77 F: >300 K cps
______________________________________________________________________________________
10. STABILITY AND REACTIVITY INFORMATION
Chemical Stability: Stable
Conditions to Avoid: Avoid extreme heat, fire and temperature.
Incompatible Materials to Avoid: Avoid strong acids, strong oxidizers.
______________________________________________________________________________________
11. TOXICOLOGICAL INFORMATION (will only print available data)
Primary Eye Irritation: Irritating
Primary Skin Irritation: NA
Acute Dermal Toxicity: Product toxicity has not been determined.
Subacute Dermal Toxicity: NA
Dermal Sensitization: NA
Inhalation Toxicity: Product toxicity has not been determined.
Inhalation Sensitization: NA
Oral Toxicity: Product toxicity has not been determined.
Mutagenicity: NA
Carcinogenicity: NA
Reproductive Toxicity: Product toxicity has not been determined.
Teratogenicity: NA
Immunotoxicity: NA
Neurotoxicity: NA
No other toxicological information available
______________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Aquatic Toxicity: Not known
Terrestrial Toxicity: Not known
Chemical Fate and Transport: Not known
No other ecological information available
______________________________________________________________________________________
13. DISPOSAL INFORMATION
Regulatory Information: Consult all regulations (federal, state, provincial, local etc.) or a qualified waste
disposal firm when characterizing waste for disposal.
DuctSeal 321
Issued: 1 February 2014
Supersedes: 1 March 2011
Page 4 of 6
Waste Disposal Methods: Recover free liquid. Absorb residue and dispose of according to local, state and
Federal EPA regulation. Empty container: may contain explosive vapors. Do
Not cut, puncture or weld on or nearby.
______________________________________________________________________________________
14. TRANSPORTATION INFORMATION
U.S. Department of Transportation (DOT)
Highway / Rail: Not regulated by DOT
International Highway (Transportation of Dangerous Goods-TDG):
Not regulated
International Ocean (International Maritime Dangerous Goods – IMDG): Not regulated
International Air (International Air Transportation Authority – IATA):
Not regulated
The DOT description is provided to assist in the proper shipping classification of this product and
may not be suitable for all shipping descriptions.
Other: No other information available
______________________________________________________________________________
15. REGULATORY INFORMATION
Regulatory Lists
U.S. TSCA Inventory: All components of this material are on the US TSCA Inventory or exempt from
listing on the TSCA Inventory.
Sara Section 313: This product contains the following Sara, Title III, Section 313 Chemicals:
Chemical
CAS Number
Percent in Product
Methanol
67-56-1
0.5 – 3.45
IARC Group: NA
Regulatory Lists Searched
This product contains a mixture of one or more components found on the following State List at or above
OSHA de minimis quantities
Health & Safety: NA
Environmental: NA
International: NA
State: FL, MA, MN, PA, NJ, WA
National Inventories: NA
SARA 311 / 312 Categories (For the chemicals above)
Yes
Yes
Acute:
Chronic: Yes Fire:
Pressure:
Regulated: No
No
Reactive:
No
California Proposition 65 Information: Warning! None in the list
Canadian WHMIS Classification
Methanol
DuctSeal 321
Issued: 1 February 2014
Supersedes: 1 March 2011
Page 5 of 6
Class: Class B2 and D2B
This product has been classified in accordance with hazard criteria of the Controlled Products
Regulations (CPR). This MSDS contains all the information required by the CPR.
Canadian Environmental Protection Act (CEPA)
All reportable chemical substance is listed on the Domestic Substances List (DSL) or otherwise complies
with CEPA new substance notification requirements.
National Pollution Release Inventory (NPRI)
This product contains the following chemical subject to the reporting requirements of the CEPA
subsection 16(1), NPRI.
Chemical
CAS Number
Percent in Product
Methanol
67-56-1
0.5 – 3.45
Other Regulations: No other information available.
______________________________________________________________________________________
16. OTHER INFORMATION
Health and Environmental Label Language
All ingredients contained in this product are included on the US EPA Toxic Substances Control Act
(TSCA) inventory or exempt from listing on the TSCA inventory. All ingredients contained in this
product comply with the requirements of the Canadian Environmental Protection Act (CEPA) and are
listed on the Domestic Substance List (DSL) or Non-Domestic Substance List (NDSL)
MSDS Revisions
Previous Version Date: 1 March 2011
Section
Old Information:
New Information:
Prepared By: R&D Department
Date: 1 February 2014
Disclaimer of Warranty: The information contained herein is based upon data and information available
to us, and reflects our best professional judgment. This product may be formulated in part with
components purchased from other companies. In many instances, especially when proprietary or trade
secret materials are used, CCWI Company must rely upon the hazard evaluation of such components
submitted by that product’s manufacturer or importer. No warranty of merchantability, fitness for any use,
or any other warranty is expressed or implied regarding the accuracy of such data or information. The
results to be obtained from the use thereof, or that any such use does not infringe any patent, since the
information contained herein may be applied under conditions of use beyond our control and with which
we may be unfamiliar, we do not assume responsibility for the results of such application. This information
is furnished upon the condition that the person receiving it shall make his own determination of the
suitability of the material for his particular use.
DuctSeal 321
Issued: 1 February 2014
Supersedes: 1 March 2011
Page 6 of 6
Boss Lubricants: Material Safety Data Sheet
Issue Date: January 1, 2012
Product Information
Product Trade Name: Boss Industrial Hydraulic Oils
Transportation:
Emergency Phone Number
(CHEMTREC): (800) 424-9300
Chemical Name:
Petroleum Oil Blend
NFPA Code:
Health: 0 Fire: 1 Reactivity: 0
HMIS System:
Health: 0 Flamability: 1 Reactivity:
0
1. HAZARDOUS INGREDIENTS
This material is not known to contain any chemical listed as a
carcinogen or suspected carcinogen by OSHA, IARC or the
National Toxiology Program (NIP) at a concentration greater than
0.1%.
Contains refined petroleum oil and selected additives.
This material is non-carcinogenic as defined by OSHA, IARC,
or NIP
Ventilation Procedure:
Glove protection:
Eye protection:
Other Protection:
5. PHYSICAL DATA
Vapour Pressure: >1mm Hg
Specific Gravity: <1.00 @ 15.5 C
Water Solubility: Slight
Percent Volatile: Not determined
Vapour Density: Not determined
Evaporation Rate: Not determined
Odor:
Mild hydrocarbon odor
Appearance: Amber liquid.
6. STABILITY
Stability:
Stable
Incompatibility:
Oxidizing agents
Polymerization:
Will not occur
Thermal Decomposition: Oxides of carbon, nitrogen,
phosphorus, and hydrogen
sulfide.
2. FIRE AND EXPLOSION HAZARDS
216- 246
Not determined
Not determined
CO2 dry chemical: foam: water
spray: water fog
Special Firefighting Procedures: Cool containers with H2O and
remove from fire exposure
Unusual fire & Explosion Hazards: Empty containers could contain
flammable vapours
Flash point, C:
Upper Flammable Limit:
Lower Flammable Limit:
Extinguishing Media:
3. HEALTH HAZARD DATA
Normal shop ventilation adequate
Oil impervious gloves recommended
Not usually required, but goggles
recommended
None required
7.
SPILL OR LEAK PROCEDURES
Spill Procedures: Wear chemical splash goggles
Wear rubber boots
Prevent entry into sewers and waterways. Pickup free
liquid for recycle/disposal
Absorb small amounts of inert material for disposal
Waste Disposal: Disposal should be in compliance with federal, provincial
and local laws
Oral Toxicity:
Minimal hazard. Oral toxicity greater than 5,000
mg/kg
Eye Irritation: May be an eye irritant
Skin Irritation: Possible redness may result from prolonged exposure.
Other:
Unknown
TLV:
5 mg/m3 as oil mist
8. SPECIAL PRECAUTIONS
Special Precautions: Launder contaminated clothing before reuse.
Wash skin thoroughly after handling. Avoid
prolonged contact
Emergency First Aid Procedures:
Skin:
Eye:
Inhalation:
Oral:
Additional:
Wash with soap
Flush with large amounts of water. If irritation
persists, get medical attention
Remove to fresh air. See physician if irritation
persists
Call physician. Do not induce vomiting
None
4. SPECIAL PROTECTION INFORMATION
9. TRANSPORTATION AND LABELING
DOT Proper Shipping Name: Not applicable
DOT Hazard Class:
Not applicable
10. OTHER REGULATORY INFORMATION
BOSS INDUSTRIAL HYDRAULIC OILS
Boss Lubricants: Material Safety Data Sheet
SARA
SEC
313
SUPPLIER
NOTIFICATIONS
This product contains the following toxic chemical, subject to the reporting requirements of sec 313 of the energy planning and community
right-to-know act of 1986 and of 40CFR372.
CAS# CHEMICAL NAME %WEIGHT
Available
This information must be included in all MSDS’s that are copied and distributed for this material.
The information presented herein has been compiled from sources considered to be dependable, and is accurate to the best of BOSS
LUBRICANT’S knowledge; however, BOSS makes no warranty whatsoever, expressed or implied, of merchantability or fitness for the
particular purpose, regarding the accuracy of such date or the results to be obtained from the use thereof. BOSS LUBRICANTS assumes no
responsibility for injury to recipient or to third persons or for any damage to any property and recipient assumes all such risks.
11. January 1, 2011
Prepared by: Technical Services
Boss Lubricants Ltd.
112, 6303 30th street S.E.
Calgary, Alberta
T2C 1R4
(800) 844-9457
BOSS INDUSTRIAL HYDRAULIC OILS
Material Name: Fiberglass Wool Commercial and Industrial
Insulation, Antimony-free
Safety Data Sheet
ID: 1077
Section 1 - Product and Company Identification
Hazard Label WARNING label
Company Information
Johns Manville
Insulation Systems
P.O. Box 5108
Denver, CO 80127 USA
Telephone: 303-978-2000 8:00AM-5:00PM M-F
Internet Address: http://www.jm.com
Emergency: 800-424-9300 (Chemtrec, In English)
Trade Names:
800 Series Spin Glas® Board, unfaced
1000 Series Spin Glas® Board
Duct Liner PM
Blended Blowing Wool
Fabrication Board
Hullboard (Incombustible)
Hullinsul® Fiber Glass Board
Incombustible Microlite®
Insul-SHIELD® Coated Black
Linacoustic® RC
Micromat Rx™
Permacote® Linacoustic® (Types:Standard, HP and R-300)
Precipitator Spin Glas®
Spin Glas® HTB 26 & 23
R Series Microlite® (Plain)
Spin Glas® HTB 26 & 23
Use: Lining sheet metal ducts in AC, heating and ventilation systems
Section 2 - Hazards Identification
Emergency Overview
Inhalation of excessive amounts of dust from the product may cause temporary upper respiratory irritation and/or congestion-remove individual to fresh air.
In high temperature applications, treatment, curing, or in geographic areas of high heat and humidity, this product may release
gases irritating to the eyes, nose and throat.
Inhalation
Temporary mechanical irritation may occur upon exposure to dust or fibers released from cutting this product.
Irritation of the upper respiratory tract, coughing, and congestion may occur in extreme exposures. Severe irritation of the
mouth, nose, and throat, as well as signs of central nervous system depression (drowsiness, dizziness, headache), may occur
upon inhalation of vapors or gases.
Skin
Temporary irritation (itching) or redness may occur.
Ingestion
This product is not intended to be ingested (eaten). If ingested, it may cause temporary irritation to the gastrointestinal
(digestive) tract.
Eyes
Temporary irritation (itching) or redness may occur.
Ears
Temporary irritation (itching) or redness may occur.
Primary Routes of Entry (Exposure)
Eyes, skin, inhalation (breathing dust and fibers) and ingestion.
Target Organs
Nose (nasal passages), throat, lungs, skin, eyes
Medical Conditions Aggravated by Exposure
Pre-existing chronic respiratory, skin, or eye diseases or conditions.
Section 3 - Composition/Information on Ingredients
CAS #
Not Applicable
Not Applicable
Not Available
NA
1333-86-4
Component
Continuous Filament Glass Fiber
Fiber Glass Wool
Urea extended phenol-formaldehyde binder (cured)
Acrylic Coating
Carbon black, bound (present in black products only)
____________________________________________________________
Page 1 of 7
Issue Date: 01/11/2013
Revision: 1.0002
Percent
0-12
65-85
10-18
0-10
<1
Material Name: Fiberglass Wool Commercial and Industrial Insulation, Antimony-free
50-00-0
Safety Data Sheet
ID: 1077
Formaldehyde
<1
Component Information
Formaldehyde may be released by partial hydrolysis of the urea formaldehyde polymer.
General Product Description
Fibrous glass blankets or boards with glass mat facing or coating.
Section 4 - First Aid Measures
First Aid: Inhalation
If dust is inhaled in excess of exposure limits referenced in section 8 of this safety data sheet, remove individual to fresh air.
Drink water to clear throat, and blow nose to remove dust. A saline spray in the nose may help clear any fibers.
First Aid: Skin
Wash gently with soap and water to remove dust and fibers. Alternatively, fibers can be removed from the skin by use of
ordinary masking or wrapping tape. Should irritation persist, seek medical attention.
First Aid: Ingestion
Rinse mouth with water to remove dust and fibers and drink plenty of water to help reduce irritation. If irritation persists, seek
medical attention.
First Aid: Eyes
Do not rub or scratch eyes. Dust particles may cause the eye to be scratched. Flush eyes with large amounts of water until
irritation subsides. If irritation persists, seek medical attention.
First Aid: Ears
Wash exposed skin with soap and water. If irritation develops in the inner ear, seek medical attention.
First Aid: Notes to Physician
Dust from the product may cause mechanical irritation of the eyes, skin, and upper respiratory tract. Treat symptomatically.
Irritating gases may be released under conditions of high heat or humidity. At high levels, these could cause severe upper
respiratory and eye irritation. Formaldehyde gas is a skin and respiratory sensitizer. Treatment should be directed toward
removing the source of irritation with symptomatic treatment as necessary.
Section 5 - Fire Fighting Measures
Flash Point: Not applicable
Upper Flammable Limit (UFL): Not applicable
Auto Ignition: Not determined
Rate of Burning: Not determined
Method Used: Not applicable
Lower Flammable Limit (LFL): Not applicable
Flammability Classification: Not determined
General Fire Hazards
There is no potential for spontaneous fire or explosion. Inorganic glass fibers are naturally non-combustible and nonflammable.
Extinguishing Media
Carbon dioxide (CO2), water, water fog, dry chemical.
Fire Fighting Equipment/Instructions
No special procedures are expected to be necessary for this product. Normal fire fighting procedures should be followed to
avoid inhalation of smoke and gases.
Section 6 - Accidental Release Measures
Clean-Up Procedures
Pick up large pieces. Vacuum dusts. If sweeping is necessary, use a dust suppressant such as water. Do not dry sweep dust
accumulation. These procedures will help to minimize potential exposures.
Section 7 - Handling and Storage
Handling Procedures
Use protective equipment as described in Section 8 of this safety data sheet when handling uncontained material. Handle in
accordance with good industrial hygiene and safety practices.
Storage Procedures
Warehouse storage should be in accordance with package directions, if any. Material should be kept clean, dry, and in original
packaging.
____________________________________________________________
Page 2 of 7
Issue Date: 01/11/2013 Revision: 1.0002
Material Name: Fiberglass Wool Commercial and Industrial Insulation, Antimony-free
Safety Data Sheet
ID: 1077
Section 8 - Exposure Controls / Personal Protection
The Occupational Safety and Health Administration (OSHA) has not adopted specific occupational exposure standards for
fiber glass. Fiber glass is treated as a nuisance dust and is regulated by OSHA as a particulate not otherwise regulated (total
dust) shown in CFR 1910.1000 Table Z-3.
Respirable fraction 5 mg/m3
Total dust 15 mg/m3
JM has adopted the fiber glass industry voluntary Product Stewardship Program (PSP), formerly the NAIMA-OSHA Health and
Safety Partnership Program (HSPP). Under the PSP, JM recommends that exposures be limited to the voluntary concentration
of 1 f/cc TWA for fibers longer than 5 microns with a diameter less than 3 microns. This will help minimize potential irritation
effects. The PSP also includes the PPE recommendations described below.
Formaldehyde (50-00-0)
OSHA: 0.75 ppm TWA
0.5 ppm Action Level; 0.75 ppm TWA; 2 ppm STEL (Irritant and potential cancer hazard - see 29
CFR 1910.1048)
3 ppm TWA (unless specified in 1910.1048)
ACGIH: 0.3 ppm Ceiling
Carbon black, bound (present in black products only) (1333-86-4)
OSHA: 3.5 mg/m3 TWA
3.5 mg/m3 TWA
ACGIH: 3.5 mg/m3 TWA
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Safety glasses with side shields are recommended to keep dust out of the eyes.
Personal Protective Equipment: Ears
Use ear protection (earplugs, hood, or earmuffs) to prevent airborne dust or fibers from entering the ear, if necessary.
Personal Protective Equipment: Skin
Leather or cotton gloves should be worn to protect against mechanical abrasion. See also Personal Protective Equipment:
General, below.
Personal Protective Equipment: Respiratory
A NIOSH-approved respirator should be used if ventilation is unavailable, or is inadequate for keeping levels below the
applicable exposure limits referenced in Section 8 of this SDS.
Ventilation
In fixed manufacturing settings, local exhaust ventilation should be provided at areas of cutting, milling or other processing to
remove airborne dust and fibers.
Personal Protective Equipment: General
Wear a cap, a loose-fitting, long-sleeved shirt and long pants to protect skin from irritation. Exposed skin areas should be
washed with soap and water after handling or working with fiber glass. Clothing should be washed separately from other
clothes, and the washer should be rinsed thoroughly (run empty for a complete wash cycle). This will reduce the chances of
fiber glass being transferred to other clothing.
Section 9 - Physical & Chemical Properties
Appearance:
Physical State:
Vapor Pressure:
Boiling Point:
Solubility (H2O):
VOC:
Fibrous glass blankets or
boards with glass mat facing or
coating with glass mat facing.
Solid
Not applicable
Not applicable
Nil
Not determined
Odor:
Mild resin odor
pH:
Vapor Density:
Melting Point:
Specific Gravity:
Not applicable
Not applicable
>704ºC/1300ºF
Variable
____________________________________________________________
Page 3 of 7
Issue Date: 01/11/2013 Revision: 1.0002
Material Name: Fiberglass Wool Commercial and Industrial Insulation, Antimony-free
Safety Data Sheet
ID: 1077
Section 10 - Stability & Reactivity Information
Stability
These products are not reactive.
Hazardous Decomposition
May form carbon dioxide and carbon monoxide.
Hazardous Polymerization
Will not occur.
Section 11 - Toxicological Information
Acute Toxicity
A: General Product Information
If dust evolves from this product during use it may cause temporary mechanical irritation or scratchiness of the throat and/or
itching of the eyes and skin.
Exposure to formaldehyde may cause eye and upper respiratory irritation, and possible respiratory or skin sensitization
(allergy). If sensitization occurs, subsequent exposures to formaldehyde may worsen asthma or other respiratory problems,
and cause allergic-type reactions.
B: Component Analysis - LD50/LC50
Formaldehyde (50-00-0)
Inhalation LC50 Rat: 0.578 mg/L/4H; Oral LD50 Rat:500 mg/kg
Carbon black, bound (present in black products only) (1333-86-4)
Oral LD50 Rat: >15400 mg/kg; Dermal LD50 Rabbit:>3 g/kg
Carcinogenicity
A: General Product Information
Exposure to formaldehyde has been associated with the development of nasopharyngeal cancer in laboratory animals and
humans. Formaldehyde has been classified as a known human carcinogen, Group 1, by the International Agency for Research
on Cancer (IARC). OSHA specifically regulates formaldehyde under 29 CFR 1910.1048.
B: Component Carcinogenicity
Fiber glass wool
NTP: Not listed.
IARC: Group 3 - Not Classifiable (IARC Monograph 81 [2002] (listed under Man-made mineral fibres),
Monograph 43 [1988])
Formaldehyde (50-00-0)
ACGIH: A2 - Suspected Human Carcinogen
OSHA: 0.5 ppm Action Level; 0.75 ppm TWA; 2 ppm STEL (Irritant and potential cancer hazard - see 29
CFR 1910.1048)
NTP: Known to Cause Cancer
IARC: Group 1 - Known Human Carcinogen
Carbon black, bound (present in black products only) (1333-86-4)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 93 [in preparation], Monograph
65 [1996])
Chronic Toxicity
Continuous Filament Glass Fiber: No chronic health effects are known to be associated with exposure to continuous filament
fiber glass. Results from epidemiologic studies have not shown any increases in respiratory disease or cancer. The
International Agency for Research on Cancer (IARC) has classified continuous filament fiber glass as a Group 3 substance,
not classifiable as to its carcinogenicity to humans. Because of the large diameter of continuous filament fibers, these products
are not considered respirable.
____________________________________________________________
Page 4 of 7
Issue Date: 01/11/2013 Revision: 1.0002
Material Name: Fiberglass Wool Commercial and Industrial Insulation, Antimony-free
Safety Data Sheet
ID: 1077
Fiber Glass Wool (non-durable glass fibers):
In October 2001, IARC classified fiber glass wool as Group 3, "not classifiable as to its carcinogenicity to humans." The 2001
decision was based on current human and animal research that shows no association between inhalation exposure to dust
from fiber glass wool and the development of respiratory disease
In 2011, the National Toxicology Program (NTP, a component of the United States Department of Health and Human
Services) issued its 12th Report on Carcinogens (Report). The Report makes clear that any glass fibers that have been
successfully assessed in an animal study and shown no cancer hazard are NOT among those “certain” fibers and NOT listed
in the Report.
The glass fibers comprising the products on this MSDS have either been successfully assessed by appropriate animal
protocols and / or have modeled Kdis values such that they are considered non-durable and the current human and animal
research that shows no association between inhalation exposure to dust from fiber glass wool and the development of
respiratory disease is applicable to these fibers.
Section 12 - Ecological Information
Ecotoxicity
A: General Product Information
No data available for this product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Formaldehyde (50-00-0)
96 Hr LC50 Pimephales promelas: 24.1 mg/L [flow-through]; 96 Hr LC50 Lepomis macrochirus: 0.10 mg/L [flow-through]; 96
Hr LC50 Brachydanio rerio: 41 mg/L [static]
5 min EC50 Photobacterium phosphoreum: 9.0 mg/L; 15 min EC50 Photobacterium phosphoreum: 7.26 mg/L; 25 min EC50
Photobacterium phosphoreum: 6.81 mg/L; 30 min EC50 Photobacterium phosphoreum: 16.5 mg/L; 1 Hr EC50 Vibrio harveyi:
1.2 mg/L; 5 Hr EC50 Vibrio harveyi: 3.7 mg/L; 72 Hr EC50 Colpoda aspera: 5.39 mg/L
96 Hr EC50 water flea: 20 mg/L; 48 Hr EC50 Daphnia magna: 2 mg/L
Carbon black, bound (present in black products only) (1333-86-4)
24 Hr EC50 Daphnia magna: >5600 mg/L
Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
General Product Information
This product is not expected to be a hazardous waste when it is disposed of according to the U.S. Environmental Protection
Agency (EPA) under Resource Conservation and Recovery Act (RCRA) regulations. Product characterization after use is
recommended to ensure proper disposal under federal and/or state requirements.
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
Section 14 - Transport Information
International Transport Regulations
These products are not classified as dangerous goods according to international transport regulations.
Section 15 - Regulatory Information
US Federal Regulations
A: General Product Information
SARA 311/312: This product is not classified as hazardous under SARA 311/312.
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Formaldehyde (50-00-0)
SARA 302: 500 lb TPQ
SARA 313: 0.1 % de minimis concentration
CERCLA: 100 lb final RQ; 45.4 kg final RQ
____________________________________________________________
Page 5 of 7
Issue Date: 01/11/2013 Revision: 1.0002
Material Name: Fiberglass Wool Commercial and Industrial Insulation, Antimony-free
Safety Data Sheet
ID: 1077
State Regulations
A: General Product Information
The glass fibers in this product are not known to be regulated.
Other state regulations may apply. Check individual state requirements.
WARNING: This product contains a substance known to the state of California to cause cancer: Methyl Carbamate (trace)
598-55-0 present in mat facer
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component
CAS #
CA
FL
MA
Fiber Glass Wool (¹related to Glass, fibrous or
Not
Yes¹
No
Yes²
dust) (²related to Fibrous glass)
Applicable
Fiber Glass Wool (¹related to Mineral wool fiber)
Not
Yes¹
No
Yes¹
(²related to Fibrous glass)
Applicable
Formaldehyde
50-00-0
Yes
No
Yes
Carbon black, bound (present in black products
1333-86-4
Yes
No
Yes
only)
MN
No
NJ
Yes²
PA
Yes²
Yes
Yes²
Yes¹
Yes
Yes
Yes
Yes
Yes
Yes
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
A: TSCA Status
This product and its components are listed on the TSCA 8(b) inventory.
B: Component Analysis - Inventory
Component
Fiber Glass Wool
Fiber Glass Wool
Formaldehyde
Carbon black, bound (present in black products only)
CAS #
Not Applicable
Not Applicable
50-00-0
1333-86-4
TSCA
No
Yes
Yes
Yes
DSL
No
Yes
Yes
Yes
EINECS
No
Yes
Yes
Yes
International Regulations
A: General Product Information
These products are considered articles under both U.S. and international product regulations and as such, these products do
not require registration or notification on the various country-specific inventories.
B: Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component
CAS #
Minimum Concentration
Fiber Glass Wool
Not Applicable
1 % (related to Fibrous glass)
Formaldehyde
50-00-0
0.1 %
WHMIS Classification
Controlled Product Classification: D2A
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations. This SDS
contains all the information required by the Controlled Products Regulations.
Section 16 - Other Information
Other Information
Prepared for:
Johns Manville
Insulation Systems
P. O. Box 5108
Denver, CO USA 80217-5108
Prepared by:
____________________________________________________________
Page 6 of 7
Issue Date: 01/11/2013 Revision: 1.0002
Material Name: Fiberglass Wool Commercial and Industrial Insulation, Antimony-free
Safety Data Sheet
ID: 1077
Johns Manville Technical Center
P.O. Box 625005
Littleton, CO USA 80162-5005
The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no
warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or
provincial, and local laws.
Date
09/30/08
09/3/2011
01/11/2013
MSDS #
1077-1.0000
1077-1.0001
1077-1.0002
Reason
New SDS for new product.
Regulatory update.
Trade name and toxicological update in section 11.
End of Sheet 1077
____________________________________________________________
Page 7 of 7
Issue Date: 01/11/2013 Revision: 1.0002
Material Safety Data Sheet
Material Name: Mineral Wool Insulation
1.
Identification:
1.1
Product Generic Name:
Mineral Wool Insulation
1.2
Product Use:
Commercial, Industrial, Residential, and Marine Insulation
1.3
Products:
AFB®, CAVITYROCK®, COMFORTBATT®, COMFORTBOARDTM, CONROCK, CURTAINROCK®, DRAINBOARD®,
ENERWRAP®, FABROCKTM, FIREWALL®, MONOBOARD®, RHM®, RHT®, ROCKBOARD®, ROCKFILLTM, ROXUL
Plus, SAFE®, SAFE’n’SOUND®1, STURDIROCK®, TECHTON 1200®, TECHTON 1200® MARINE, TOPROCK®
1.4
Company Address:
ROXUL Inc.
420 Bronte St. S.
Suite 105
Milton, Ontario
Canada
L9T 0H9
1.5
Web Site:
www.roxul.com
1.6
If further information is required, please call or fax ROXUL Inc.
Telephone: 1-800-265-6878 or 905-878-8474 Fax: 905-878-8077
1. SAFE’n’SOUND® is a registered Trademark used under license by ROXUL Inc.
2.
Information on Ingredients:
Ingredient Name
CAS Number
%
Mineral Fiber
RN 65997-17-3
94-99
Cured Urea Extended Phenolic
Formaldehyde Binder
25104-55-6
1-6
3.
Hazards Identification:
3.1
Appearance and Odor:
Grey, green, brown fibrous batt, blanket, preformed pipe or board.
3.2
Emergency Overview:
Acrid smoke may be generated during a fire.
Exposure to dust may be irritating to the eyes, nose and throat.
3.3
Potential Health Effects:
3.3.1
Inhalation: Temporary mechanical irritation of the upper respiratory tract (scratchy throat, coughing,
congestion) may result from exposures to dusts and fibers in excess of applicable exposure limits.
3.3.2
Skin Contact: Dusts and fibers may cause temporary mechanical irritation (itching) or redness to the
skin.
3.3.3
Eye Contact: Dusts and fibers may cause temporary mechanical irritation (itching) or redness to the
eyes.
3.3.4
Ingestion: Ingestion of this product is unlikely and not intended under normal conditions of use.
Ingestion of this product may cause gastrointestinal irritation.
3.3.5
Existing Medical Conditions: Pre-existing chronic eye, skin and respiratory conditions may temporarily
worsen due to exposure to dusts and fibers.
Page 1 of 7
Issue Date: September 20th, 2013
Replaces Issue: November 16, 2010
Material Safety Data Sheet
Material Name: Mineral Wool Insulation
4.
First-Aid Measures:
4.1
Inhalation: If irritation occurs, remove the affected person to fresh air. Drink water, and blow nose, to clear
dusts and fibers from throat and nose. If irritation persists, consult a physician.
4.2
Skin: If irritation occurs, do not rub or scratch. Rinse under running water prior to washing with mild soap
and water. Use a washcloth to help remove fibers. If irritation persists, consult a physician.
4.3
Eyes: If irritation occurs, flush eyes with plenty of water for at least 15 minutes. Do not rub the eyes. Consult a
physician if irritation persists.
4.4
Ingestion: Ingestion of this product is unlikely and not intended under normal conditions of use. If it does
occur, rinse mouth with plenty of water to help remove dust and fibers, and drink plenty of water to help reduce
potential gastrointestinal irritation. Do not induce vomiting unless directed to do so by a physician.
5.
Fire-Fighting Measures:
The products are non-combustible and do not pose a fire hazard. However, packaging material may burn.
5.1.
Suitable extinguishing media:
Water, foam, carbon dioxide or dry powder
5.2
Extinguishing media which
must not be used for safety reasons:
None
5.3
Combustion products:
Carbon dioxide, carbon monoxide and trace gases
5.4
Special protective equipment
for fire-fighters:
Observe normal fire fighting procedures
Flash point:
Flash Point Method Used:
5.5
None
Not Applicable
Upper Flammable
Limit (UFL): Not Applicable
Lower Flammable
Limit:
Autoignition: Not Applicable
Explosive Properties: Not Applicable
Not Applicable
6.
Accidental Release Measures:
6.1
Containment Procedures: Pick up large pieces and scoop up dusts and fibers after they have settled out of air.
These materials will disperse and settle along the bottom of waterways and ponds. It cannot easily be removed
once it is waterborne, but is considered non-hazardous in water.
6.2
Cleanup Procedures: Use OSHA-recommended work practices and protective equipment as described in
Section 8 of this Material Safety Data Sheet. Avoid generating airborne dusts and fibers during cleanup. Do
not use compressed air. Vacuum dusts and fibers. Place material in an appropriate container for disposal as
non-hazardous waste.
6.3
Response Procedures: Isolate area. Keep unnecessary personnel away. If dry methods or compressed air are
used to collect dusts and fibers, all personnel in the area should wear OSHA-approved protective equipment
(see Section 8 of this Material Safety Data Sheet).
Page 2 of 7
Issue Date: September 20th, 2013
Replaces Issue: November 16, 2010
Material Safety Data Sheet
Material Name: Mineral Wool Insulation
7.
Handling and Storage:
7.1
General Precautions:
-
7.2
7.3
Utilize OSHA-recommended work practices and protective equipment when using the products (see Section
8 of this Material Safety Data Sheet).
Handling:
-
Unpack material at application site to avoid unnecessary handling of product.
-
Keep work areas clean. Avoid unnecessary handling of scrap material and debris by placing such materials
in suitable containers, which should be kept as close to the work area as possible.
-
Ensure good ventilation. Local exhaust ventilation may be required if the method of use produces dust
levels which exceed applicable exposure limits (see Section 8 of this Material Safety Data Sheet).
-
Avoid excessive eye and skin contact with dusts and fibers.
-
Use recommended cleanup procedures to avoid buildup of dusts and fibers in the work area.
Storage:
-
Keep material in original packaging until it is to be used.
-
Store material to protect against adverse conditions including precipitation.
8.
Exposure Controls/Personal Protection:
8.1
Exposure Guidelines:
8.1.1
General Product Information: Follow all applicable exposure limits. Local regulations may apply. Roxul
recommends that users of the products adhere to the OSHA-recommended PEL of 1 f/cc TWA (fibers
longer than 5 m with diameters less than 3 m). This recommended PEL, together with recommended
work practices and personal protective equipment, were adopted in a Health and Safety Partnership
Program (HSPP) agreement in 1999 between OSHA and the North American Insulation Manufacturers
Association (NAIMA), of which Roxul is a member. Adherence to the OSHA-recommended PEL, work
practices and protective equipment in the HSPP is expected to provide appropriate protection against all
inhalation-related health risks that may be associated with exposures to mineral wool fibers (ACGIH
1997; NAIMA 1999; OSHA 1999; National Research Council 2000, IARC 2001), and to minimize eye and
skin irritation.
8.1.2
Component Exposure Limits:
Page 3 of 7
Source
Legal or Recommended Exposure Limit
Exposure
OSHA
1 f/cc TWA (recommended)
Synthetic Vitreous Fibers, > 5 m
length, < 3 m diameter
ACGIH
1 f/cc TWA (threshold limit value – TLV)
Synthetic Vitreous Fibers, > 5 m
length, < 3 m diameter
OSHA
15 mg/m3 TWA-PEL (total particulate)
5 mg/m3 TWA-PEL (respirable particulate)
Inert dust and particulates not
otherwise regulated
ACGIH
10 mg/m3 TWA-TLV (inhalable particulate)
3 mg/m3 TWA-TLV (respirable particulate)
Particulates not otherwise
classified, containing no asbestos
and <1% crystalline silica
Issue Date: September 20th, 2013
Replaces Issue: November 16, 2010
Material Safety Data Sheet
Material Name: Mineral Wool Insulation
8.2
8.3
Equipment and Work Practices: Follow OSHA-recommended equipment and work practices. A complete
copy of these practices can be obtained from Roxul Inc. (see Section 1 of this Material Safety Data Sheet), and
is available on the OSHA website (http://www.osha.gov/SLTC/syntheticmineralfibers).
8.2.1
Follow OSHA-recommended safe handling practices listed in Section 7.2 above.
8.2.2
Where feasible, general dilution ventilation or local exhaust ventilation should be used as necessary to
maintain exposures below applicable exposure limits. Dust collection systems should be used in cutting
or machining operations and may be needed when using power tools.
8.2.3
Follow OSHA-recommended work practices when fabricating, installing or removing product.
Personal Protective Equipment::
8.3.1
Respiratory:
8.3.1.1 General:
In poorly ventilated areas when dusty conditions exist and/or dust levels exceed applicable exposure
limits, wear a NIOSH certified dust respirator with an efficiency rating of N95 or higher. Use disposable
face masks complying with NIOSH respirator standards, such as a 3M Model 8210 (or 8710) (3M Model
9900 in high humidity environments) or equivalent. For exposures up to five times the established
exposure limits use a quarter-mask respirator, rated N95 or higher; and for exposures up to ten times
the established exposure limits use a half-mask respirator (e.g. MSA’s DM-11, Racal’s Delta N95, 3M’s
8210), rated N95 or higher. For exposures up to 50 times the established exposure limits use a full-face
respirator, rated N99 or higher.
8.3.1.2 Specific Operations:
In poorly ventilated areas when dusty conditions exist and/or dust levels exceed applicable exposure
limits, wear a NIOSH certified dust respirator with an efficiency rating of N95 or higher, such as a 3M
Model 8210 (or 8710) (3M Model 9900 in high humidity environments) or equivalent, when fabricating,
installing or removing product.
8.3.2
Skin:
Wear loose fitting, long sleeved and long-legged clothing to prevent irritation. A head cover is also
recommended, especially when working with material overhead. The use of suitable gloves is also
recommended. Skin irritation cannot occur if there is no contact with the skin. Do not tape sleeves or
pants at wrists or ankles. Remove fibers from the work clothes, before leaving work to reduce potential
skin irritation. If working in a very dusty environment it is advisable to shower and change clothes
8.3.3
Eyes/Face:
Wear safety goggles or safety glasses with side shields.
9.
Physical and Chemical Properties:
9.1
Appearance:
9.2
State:
Solid
9.3
Odor:
May have slight resin odour
9.4
Boiling point::
n.a.
9.5
Melting point:
Approximately 2150 F (1177 C)
9.6
Vapour pressure:
n.a.
9.7
Vapour Density:
n.a.
9.8
Specific Gravity:
n.a.
9.9
Evaporation Rate:
n.a.
9.10
Freezing Point:
n.a.
9.11
Viscosity:
n.a.
9.12
Solubility:
Insoluble (H2O)
9.13
Partition coefficient:
n.a.
Grey, green fibrous batt or board
n.a. = not applicable
Page 4 of 7
Issue Date: September 20th, 2013
Replaces Issue: November 16, 2010
Material Safety Data Sheet
Material Name: Mineral Wool Insulation
10.
Stability and Reactivity:
10.1
Stability:
Stable
10.2
Reactivity:
Not reactive
10.3
Thermal decomposition products:
Primary combustion products of the cured urea extended phenolic formaldehyde binder, when heated above
390 F (200 C), are carbon monoxide, carbon dioxide, ammonia, water and trace amounts of formaldehyde.
Other undetermined compounds could be released in trace quantities. Emission usually only occurs during the
first heating. The released gases may be irritating to the eyes, nose and throat during initial heat-up. Use
appropriate respirators (air supplied) particularly in tightly confined or poorly ventilated areas during initial
heat-up.
10.4
Hazardous Polymerization:
Will not occur
10.5
Incompatible Materials:
This product reacts with hydrofluoric acid.
11.
Toxicological Information:
11.1
Acute Toxicity:
Coarse fibers and dust from mineral wool products can cause temporary mechanical irritation (itching, redness)
of the skin, and of the mucous membranes in the eyes and in the upper respiratory tract (nose and throat). The
itching and possible inflammation are a mechanical reaction to dust and coarse fibers (of more than about 5 µm
in diameter), and are not damaging in the way chemical irritants may be. They generally abate within a short
time after the end of exposure. When products are handled continually, the skin itching generally diminishes.
11.2
Chronic Toxicity:
11.2.1
Summary: In October 2001, IARC completed a re-evaluation of respirable mineral wool fibers and
classified them in Group 3 (not classifiable as to their carcinogenicity to humans). A summary of the
most important scientific studies appears below:
11.2.2
Human Data:
11.2.2.1 The possible carcinogenic effects of exposure to mineral wool fibers has been evaluated in a number of
epidemiological (human) studies. Most of this research, including large long-tem studies of mineral
wool production workers in the U.S. and Europe, has been sponsored or supported by the North
American and International thermal insulation industries, including Roxul Inc. Published reports of
the early results of these studies identified significantly elevated rates of respiratory cancer in several
subcohorts of the worker populations under evaluation (e.g., Simonato et al. 1987; Enterline et al.
1987). However, the studies had several methodological limitations, including failure to control for
confounding exposures to other possible causes of the elevated cancer risk, including tobacco use
and occupational exposures to recognized carcinogens such as asbestos. For these reasons, the
authors of these reports did not interpret the results as establishing an association between exposure
to mineral wool fibers and an increased risk of cancer. Several of these earlier reports formed part of
the basis for IARC’s previous classification of mineral wool fibers in Group 2B (possibly carcinogenic
to humans) (IARC 1987).
11.2.2.2 Follow-up studies, including case-control studies designed to exclude the contribution of confounding
exposures to the cancer experience of the study populations, found no evidence that mineral wool
fibers are associated with an increased cancer risk (Marsh et al. 1996; Wong, et al. 1991; Kjaerheim
et al. 2001). In announcing the new Group 3 classification for mineral wool fibers, IARC stated:
“Epidemiologic studies published during the 15 years since the previous IARC Monographs review of
these fibers in 1988 provide no evidence of increased risks of lung cancer or of mesothelioma (cancer
of the lining of the body cavities) from occupational exposures during manufacture of these materials”
(IARC 2001).
11.2.3
Animal Data:
11.2.3.1 Several studies of intraperitoneal injection of high doses of mineral wool fibers have produced
significant increases in the incidence of mesothelioma (IARC 2002). The intraperitoneal injection
studies formed part of the basis for IARC’s previous (IARC 1987) Group 2B classification for mineral
wool fibers. Leading scientists agree that intraperitoneal injection studies (i.e., surgical implantation
or injection into the chest or abdomen) are the least relevant type of animal study for evaluating
Page 5 of 7
Issue Date: September 20th, 2013
Replaces Issue: November 16, 2010
Material Safety Data Sheet
Material Name: Mineral Wool Insulation
potential human risk for fiber exposures, because such studies bypass the animals’ natural defense
mechanisms and involve a type and pattern of exposure (implantation of a high dose early in life) that
does not mimic human patterns of exposure (inhalation of much lower doses over a lifetime) (National
Research Council 2000).
11.2.3.2 A well-designed long-term inhalation study in rats exposed to mineral wool fibers found no significant
increase in lung tumor incidence, and no mesotheliomas (IARC 2002). Likewise, in two intratracheal
instillation studies of mineral wool fibers, no significant increase in the incidence of lung tumors or
mesotheliomas was found (IARC 2002). Inhalation studies are regarded as the most relevant type of
animal data for evaluating potential human risk, and intratracheal instillation studies, while less
relevant, are considered valuable for the initial screening of fibrous compounds (National Research
Council 2000). Thus, evaluating all the available animal studies in conjunction with the human data,
IARC’s most recent review finds “inadequate evidence overall for any cancer risk” from mineral wool
fibers (IARC 2001).
11.3
Evaluations of Potential Carcinogenicity:
Source
Classification
Description
IARC
Group 3
Not Classifiable as a Human Carcinogen
ACGIH
Group A3
Confirmed Animal Carcinogen with Unknown Relevance to Humans
12.
Ecological Information:
12.1
Ecotoxicity: No data available for the products. The products are stable, are not expected to cause harm to
animals, plants or fish, and have no other known adverse environmental effects.
12.2
Environmental Fate: No data available for the products.
13.
Disposal Considerations:
13.1
US EPA Waste Number & Descriptions:
13.1.1 General Product Information: The products, as supplied, are not expected to be a characteristic
hazardous waste under RCRA if discarded.
13.1.2 EPA Waste Numbers: No EPA Waste Numbers are applicable for this product's components.
13.2
Disposal Instructions: Product is not considered a hazardous waste. Dispose of waste material according to
Federal, State, Provincial, and Local environmental regulations.
14.
Transport Information:
14.1
General: No special precautions.
14.2
US DOT Information: This product is not classified as a hazardous material for transport.
15.
Regulatory Information:
15.1
U.S. Regulations:
15.1.1 Toxic Substances Control Act (TSCA): All components in this product are listed, as required, on the US
EPA TSCA inventory, or are not required to be listed
15.1.2 CERCLA: Includes mineral fiber emissions from facilities manufacturing or processing glass rock or slag
fibers (or other mineral derived fibers) of average diameter 1 micrometer or less; Statutory RQ = 1 pound (.454
kg); no final RQ is being assigned to the generic or broad class (related to Fine mineral fibers).
Page 6 of 7
Issue Date: September 20th, 2013
Replaces Issue: November 16, 2010
Material Safety Data Sheet
Material Name: Mineral Wool Insulation
15.1.3 Clean Air Act: Mineral wool fiber appears on the Clean Air Act-1990 Hazardous Air Pollutants List.
15.2
State and Local Regulations: State, Provincial, and Local regulations not identified in this Material Safety Data
Sheet may apply.
15.3
WHMIS: The products have been classified in accordance with the hazard criteria of the Controlled Product
Regulations and this Material Safety Data Sheet contains all the information required by the Controlled Product
Regulations
15.3.1:
WHMIS IDL:
No components are listed on the IDL
15.3.2:
WHMIS Classification:
No components are classified as controlled products.
16.
Further Information:
16.1
Potential Health Effects:
IARC Monograph Man-made Vitreous Fibres, press release October 2001
Safety in the Use of Mineral and Synthetic Fibers, Occupational Safety and Health Series. International
Labor Office (ILO).
Information about “Health and Safety Research on Rock- and Slag-wool” can be obtained from the North
American Insulation Manufacturers Association (NAIMA), 44 Canal Center Plaza, Suite 310, Alexandria, VA
22314, USA). Home-page: http://www.naima.org
16.2
Key/Legend:
ACGIH = American Conference of Governmental Industrial Hygienists; CAA = Clean Air Act; CAS = Chemical
Abstracts Service; CERCLA = Comprehensive Environmental Response, Compensation and Liability Act; DOT =
Department of Transportation; EPA = Environmental Protection Agency; HMIS = Hazardous Material
Identification System; HSPP = Health and Safety Partnership Program; IARC = International Agency for
Research on Cancer; MSDS = Material Safety Data Sheet; NAIMA = North American Insulation Manufacturers
Association; NFPA = National Fire Protection Association; NIOSH = National Institute for Occupational Safety
and Health; OSHA = Occupational Safety and Health Administration; PEL = Permissible Exposure Limit; RCRA
= Resource Conservation and Recovery Act; RQ = Reportable Quantity; SVF = synthetic vitreous fibers; TSCA =
Toxic Substances Control Act; TWA = time-weighted average; WHMIS = Workplace Hazardous Materials
Information System.
16.3
References: Complete citations, or copies, of all references cited in this Material Safety Data Sheet can be
obtained from Roxul Inc. (see Section 1).
16.4
Accuracy: The information contained herein is based upon data considered to be accurate. However, no
warranty is expressed or implied regarding the accuracy of these data, the results to be obtained from the use
thereof, or that any such use will not infringe upon any patent. This information is furnished as a guide only
and upon the condition that the person receiving it shall make tests to determine the accuracy and suitability
for his or her own purpose.
Page 7 of 7
Issue Date: September 20th, 2013
Replaces Issue: November 16, 2010
(Effective Date January 1, 2014)
MATERIAL SAFETY DATA SHEET
Manufacturer’s Data:
Floor Sweep, Inc.
4239 Joe Street
Charlotte, N.C. 28206
Telephone : 704-596-4570
Fax : 704-596-5588
Contact: Robin D. Garner
I. Product Identification
Oil Base :Sweeping compound (Intended use on concrete or non-waxed surfaces)
Wax Base : Sweeping compound (Intended use on resilient tile,linoleum,terazzo)
Ingredients : Trade Secret, Info withheld per OSHA (CFR 1910.1200)
II. Hazardous Components
No known hazardous components per 29 CFR 1910.1200
NFPA Codes: Health code: 1, Flammability: 1, Reactivity: 0, Personal protection: N/A
III. Physical and Chemical Characteristics
Volatility and Solubility : Nil
Appearance : Oil Base - Green with Pine Scent
Wax Base - Red with Pine Scent
IV. Fire and Explosion Data
Flashpoint : Greater than 350 degrees F
The compounds should be stored away from fire sources. If ignited by
exposure to high temperatures, treat as sawdust fire and extinguish with
CO2 or Foam. Considered Stable: Will not flash spontaneously.
V. Health Hazard Data
First Aid Procedures : The products require no respiratory or other forms of
protective equipment as there is little or no effects form overexposure. If
irritation occurs, wash irritated area with soap and water.
VI. Environmental Protection
Sweep up and dispose utilizing permitted industrial waste disposal site. Not considered
EPA hazardous waste.
VII. Other Data : Instructions for use, and Shelf Life Data
Products should be applied to floor surface and swept up immediately as surface
could become slippery if applied for extended periods of time.
Shelf Life : Products should be used within 6 months from date of purchase.
MATERIAL SAFETY DATA SHEET
SECTION 1 – PRODUCT INFORMATION
Product Name: Propane
Trade Name:
Supplier:
Superior Propane
A Division of Superior Plus LP
1111 - 49th Avenue N.E.
Calgary, AB T2E 8V2
Business: (403) 730-7500
LPG (Liquefied Petroleum Gas), LP-Gas
Chemical Formula:
C3H8
WHMIS Classification
Class A – Compressed Gas
Class B, Division 1 – Flammable G
24-Hour
Emergency Contact:
Canutec (613) 996-6666
Application and Use:
Propane is commonly used as a fuel for heating, cooking, automobiles, forklift trucks, crop drying and welding
and cutting operations. Propane is used in industry as a refrigerant, solvent and as a chemical feedstock.
SECTION 2 – HAZARDOUS INGREDIENTS
COMPONENTS
Propane
LD 50 (RAT, ORAL)
% VOLUME (v/v)
CAS No
74-98-6
90% -99%
Not Applicable
Propylene
115-07-1
0% - 5%
Not Applicable
E thane
74-84-0
0% - 5%
Not Applicable
Butane and heavier hydro carbons
106-97-8
0% - 2.5%
Not Applicable
Occupational Exposure Limit:
Based upon animal test data, the acute toxicity of this product is expected to be inhalation: 4 hour LC50 = 280,000 ppm (Rat)
Note: Composition is typical for HD-5 Propane per The Canadian General Standard Board CGSB 3.14 National Standard of Canada.
Exact composition will vary from shipment to shipment.
SECTION 3 – CHEMICAL AND PHYSICAL DATA
Form:
Liquid and vapour while
stored under pressure
Boiling Point:
-42°C @ 1 atm
Freezing Point:
-188°C
Evaporation Rate:
Rapid (Gas at normal ambient conditions)
Vapour Pressure:
1435 kPa (maximum) @ 37.8°C
Vapour Density:
1.52 (Air = 1)
pH:
Not available
Solubility in Water:
Slight, 6.1% by volume @ 17.8°C
Specific Gravity:
0.51 (water = 1)
Appearance/Odour:
Colourless liquid and vapour while stored
under pressure. Colourless and odourless
gas in natural state at any concentration.
Commercial propane has an odourant
added, ethyl mercaptan, which has an
odour similar to boiling cabbage.
Coefficient of Water/Oil Distribution: Not available
Odour Threshold:
4800 ppm
With proper handling, transportation and storage, adding a chemical odourant such as ethyl mercaptan has proven to be a very
effective warning device, but all odourants have certain limitations. The effectiveness of the odourant may be diminished by a person’s
sense of smell, by competing odours and by oxidation which may cause a potentially dangerous situation.
SECTION 4 – FIRE OR EXPLOSION HAZARD
Flash Point:
-103.4°C
Method: Closed cup
Flammable Limits:
Lower 2.4%, Upper 9.5%
Auto Ignition Temperature:
432 °C
Hazardous Combustion Products: Carbon monoxide can be
produced when primary air and secondary air are
while
combustion is taking place.
Fire and Explosive Hazards: Explosive air - vapour allowed to
leak to atmosphere.
Sensitivity to Impact:
No
Sensitivity to Static Discharge:
Fire Extinguishing Precautions: Use water spray to cool exposed
cylinders or tanks. Do not extinguish fire unless the source of the
escaping gas that is fueling the fire can be turned off.
Fire can be extinguished with carbon dioxide and/or dry chemical
(BC). Container metal shells require cooling with water to prevent
impingement and the weakening of metal.
If sufficient water is not available to protect the container shell from
weakening, the area will be required to be evacuated.
If gas has not ignited, liquid or vapour may be dispersed by water
spray or flooding.
Special Fire Fighting Equipment: Protective clothing, hose monitors,
fog nozzles, self-contained breathing apparatus material, drains and
openings to building
Yes
SECTION 5 – REACTIVITY DATA
Conditions to Avoid: Keep separate from oxidizing agents.
Gas explodes spontaneously when mixed with chloride dioxide.
Incompatibility: Remove sources of ignition and observe distance
requirements for storage tanks from combustible
MSDS-Propane-32003-2
(01/14)
Hazardous Decomposition Products: Deficient primary and
secondary air can produce carbon monoxide.
Hazardous Polymerization:
Will not occur.
Side 1 of 2
SECTION 6 – TOXICOLOGICAL PROPERTIES OF MATERIAL
Routes of Entry:
Skin Contact, Eye Contact, Inhalation
Acute Exposure: Contact with Liquefied Petroleum Gas may cause
frostbite or cold burns. Propane acts as a simple asphyxiant as oxygen
content in air is displaced by the propane. At increasing
concentration levels, propane may cause dizziness, headaches, loss of
coordination, fatigue, unconsciousness and death.
Inhalation: Simple asphyxiant. No effect at concentrations of
10,000 ppm (peak exposures). Higher concentrations may cause
central nervous system disorder and/or damage. Lack of oxygen
may cause dizziness, loss of coordination, weakness, fatigue,
euphoria, mental confusion, blurred vision, convulsions, breathing
failure, coma and death. Breathing high vapour concentrations
(saturated vapours) for a few minutes may be fatal. Saturated
vapours may be encountered in confined spaces and/or under
conditions of poor ventilation. Avoid breathing vapours or mist.
Chronic Exposure:
exposure.
No reported effects from long term low level
Sensitization to Product:
Not known to be a sensitizer.
Occupational Exposure Limits: American Conference of
Governmental Industrial Hygienists (ACGIH) lists as a simple
asphyxiant.
Skin and Eye Contact: Exposure to vapourizing liquid may cause
frostbite (cold burns) and permanent eye damage.
ACGIH TLV: 1000 ppm
Carcinogenicity, Reproductive Toxicity, Teratogenicity,
Mutagenicity: No effects reported.
Ingestion: Not considered to be a hazard.
Other Toxicological Effects:
None
SECTION 7 – PREVENTATIVE MEASURES
Eyes:
Safety glasses or chemical goggles are recommended when transferring product.
Skin:
Insulated gloves required if contact with liquid or liquid cooled equipment is expected. Wear gloves and long
sleeves when transferring product.
Inhalation:
Where concentration in air would reduce the oxygen level below 18% air or exceed occupational exposure limits
in section 6, self-contained breathing apparatus is required.
Ventilation:
Use in well-ventilated areas. Use with explosion proof mechanical ventilation in confined spaces or poorly
ventilated areas.
SECTION 8 – EMERGENCY AND FIRST AID PROCEDURES
Eyes:
Should eye contact with liquid occur, flush eyes with lukewarm water for 15 minutes. Obtain immediate
medical care.
Skin:
In case of Cold Burn from contact with liquid, immediately place affected area in lukewarm water and keep at this
temperature until circulation returns. If fingers or hands are frostbitten, have the victim hold his hand next to his body such
as under the armpit. Obtain immediate medical care.
Ingestion:
None considered necessary.
Inhalation:
Remove person to fresh air. If breathing is difficult or has stopped, administer artificial respiration. Obtain immediate
medical care.
Spill or Leak:
Eliminate leak if possible. Eliminate source of ignition. Ensure cylinder is upright. Disperse vapours with hose streams
using fog nozzles. Monitor low areas as propane is heavier than air and can settle into low areas. Remain upwind of leak.
Keep people away. Prevent vapour and/or liquid from entering into sewers, basements or confined areas.
SECTION 9 – TRANSPORTATION, HANDLING AND STORAGE
•
•
Transport and store cylinders and tanks secured in an
upright position in a ventilated space away from ignition
sources (so the pressure relief valve is in contact with
the vapour space of the cylinder or tank).
Cylinders that are not in use must have the valves in the
closed position and be equipped with a protective cap or guard.
Transportation of Dangerous Goods (TDG)
TDG Classification:
Flammable Gas 2.1
•
Do not store with oxidizing agents, oxygen, or chlorine
cylinders.
•
Empty cylinders and tanks may contain product residue.
Do not pressurize, cut, heat or weld empty containers.
•
Transport, handle and store according to applicable federal
and provincial codes and regulations.
TDG Shipping Name: Liquefied Petroleum Gas (Propane)
PIN Number:
UN1075
SECTION 10 – PREPARATION INFORMATION
Prepared by:
Superior Propane
Health Safety and Environment Team
Telephone: (403) 730-7500
Revision: January 17, 2014
Supersedes: January 17, 2011
The information contained herein is believed to be accurate. It is provided independently of any sale of the product. It is not intended to
constitute performance information concerning the product. No express warranty, implied warranty of merchantability or fitness for a particular
purpose is made with respect to the product information contained herein.
MSDS-Propane-32003-2
(01/14)
Side 2 of 2
MATERIAL SAFETY DATA SHEET
ISSUE DATE: 5/4/98
REVISED DATE: 6/22/12
Supersedes: Any Previous M.S.D.S. On This Product
EMERGENCY PHONE NUMBER: CHEM-TEL, INC. 1-800-255-3924
I. IDENTIFICATION
PROtack/PROtack HV
PRODUCT NAME:
PRODUCT CLASS: Water Based Duct Liner Adhesive
DUCTMATE INDUSTRIES, INC.
210 5th St.
Charleroi, PA 15022
II. HAZARDOUS INGREDIENTS
REPORTING REQUIREMENTS:
OSHA Hazard Communication Standard (29CFR1910.1200) hazard class………………….….None
EPA SARA Title III Section 312 (40CFR370) hazard class……………………………………..None
EPA SARA Title III Section 313 (40CFR372) toxic chemicals above “de minimis” level are….None
CALIFORNIA PROP 65 substances listed by the State of California under the “Safe Drinking Water and Toxic Enforcement Act of 1986”.
No such substances are present in reportable amounts for occupational exposure as per OSHA’s approval of the California Hazard
Communication Standard, Federal Register, page 31159 ff, 6 June 1997.
III. PHYSICAL DATA
APPEARANCE: Grey Liquid
SOLUBILITY IN WATER: Dilutable
BOILING POINT: 100 C / 212 F
WEIGHT PER GALLON: 9.5 .2 lbs./gallon
VOLATILE BY WEIGHT: 60% 2% (Water)
VAPOR DENSITY: Heavier than Air.
EVAPORATION RATE: Slower than Ether.
ODOR: Mild
PHYSICAL STATE: Liquid
Ph: 8 to 9.5
VOC CONTENT: 40 g/L EPA Method 24
IV. HEALTH AND FIRST AID
CAUTION: May cause discomfort in eyes. Prolonged or repeated contact with skin may cause dryness.
IN EYES: Flush with water for 15 minutes.
ON SKIN: Wash with soap and water.
INGESTED: Seek medical attention.
INHALATION: No effects expected. If difficulty breathing occurs remove to fresh air and consult physician.
V. FIRE AND EXPLOSION HAZARD DATA
FLAMMABILITY CLASS (OSHA/NFPA): None.
FLASH POINT: >212 F PM Closed Cup
EXTINGUISHING MEDIA: Water or dry type extinguisher.
UNUSUAL FIRE HAZARD: Containers may burst when exposed to extreme heat.
FIRE FIGHTING PROCEDURES: Firemen should wear equipment to protect against noxious fumes.
apparatus may be needed.
PRODUCT OF COMBUSTION: May yield Carbon Monoxide and/or Carbon Dioxide.
Self contained breathing
VI. SPILL OR LEAK PROCEDURES
Dike area to prevent spill from spreading. Collect spilled material in salvage container. Small amounts may be absorbed into appropriate
absorbents. Prevent spill from entering sewers, drains, and waterways.
Dispose of product in accordance with applicable local, state, and federal regulations.
VII. SPECIAL PROTECTION
VENTILATION: Provide sufficient ventilation to maintain constant fresh air in workplace.
EYE PROTECTION: Use safety goggles when splash potential exists.
HAND PROTECTION: Protective impervious gloves are recommended.
OTHER: A clean source of water should be available for washing eyes and skin.
VIII. TRANSPORTATION INFORMATION
Non-flammable, as a Latex compound
U.S.A.: Regulation by the following: DOT, IMO, ICAD/IATA: None
Canada: Regulation by the following: DSL, WHMIS: None
European: EEC SYMBOL: None
EEC Classification, Packaging and Labeling of Dangerous Substances: None
TSCA 12(b) Export Notification Requirement: TSCA 12(b) Export Notification Requirement: All components of this product are either
listed on the U.S. Toxic Substances Control Act (TSCA) inventory of chemicals or are otherwise compliant with TSCA regulations.
Acrylic Acid residual monomer CAS# 79-10-7
IX. REACTIVITY DATA
STABILITY: Stable under normal conditions of handling and use.
INCOMPATIBILITY: Products may react violently with products that react with water.
HAZARDOUS DECOMPOSITION: Fumes produced when heated to decomposition may include: oxides of carbon, nitrogen, and sulfur
along with hydrocarbon residues.
HAZARDOUS POLYMERIZATION: Will not occur.
X. SPECIAL PRECAUTIONS
HANDLING AND STORAGE: Store in tightly closed containers, at temperatures 45 F to 90 F. Guard against inhalation of excess
vapors, ingestion, and contact with skin and eyes. Change soiled workclothes frequently. Clean hands after handling. Precautions also
apply to emptied containers. Keep containers away from extreme heat and cold. Prevent from freezing, but if product is allowed to freeze,
thaw completely before use.
This information is taken from sources or based upon data believed to be reliable; however, DUCTMATE INDUSTRIES, INC. makes no
warranty as to the absolute correctness or sufficiency of any of the foregoing or that additional or other measures may not be required under
particular conditions. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist, as all
materials may present unknown health hazards.
199/6-12
USED OIL
MATERIAL SAFETY DATA SHEET
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME:
USED OIL
SYNONYMS:
Waste oil; Used lubricating oil; Oil and water mixture
PRODUCT PART
NUMBER(S):
Not applicable.
PRODUCT USE:
Oil or water mixture for re-refining or reprocessing.
If this product is used in combination with other products, refer to the
Material Safety Data Sheets for those products.
These numbers are for
emergency use only. If
you desire non-emergency
product information,
please call a phone
number listed below.
24-HOUR EMERGENCY PHONE NUMBERS
MEDICAL AND TRANSPORTATION (SPILL):
1-800-468-1760
MANUFACTURER/ SUPPLIER: Safety-Kleen Systems, Inc.
2600 North Central Expressway
Suite 400
Richardson, Texas 75080
USA
1-800-669-5740
www.safety-kleen.com
TECHNICAL INFORMATION: 1-800-669-5740 Press 1 then 1 then Extension 7500
MSDS FORM NUMBER: 81451
ISSUE: September 15, 2013
ORIGINAL ISSUE: January 15, 1990
SUPERSEDES: September 15, 2010
PREPARED BY: Product MSDS Coordinator
APPROVED BY: MSDS Task Force
Revision 9/13; MSDS Form No. 81451 - Page 1 of 10
USED OIL
MATERIAL SAFETY DATA SHEET
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
WT%
NAME
SYNONYM
CAS NO.
TWA
OSHA PEL
STEL
ACGIH TLV®
TWA
STEL
80 to 100
Lubricating oils, used
Used oil
70514-12-4
N. Av.
N. Av.
N. Av.
N. Av.
LDa
N. Av.
LCb
N. Av.
0 to 20*
Water/solids
N. Av.
N. Av.
N. Av.
N. Av.
N. Av.
N. Av.
N. Av.
N. Av.
0 to 10*
Hydrocarbon solvents.
May include gasoline,
diesel fuel, jet fuel,
mineral spirits, etc.
N. Av.
N. Av.
N. Av.
N. Av.
N. Av.
N. Av.
N. Av.
N. Av.
0 to 1.5*
Metals.
May include lead, iron,
zinc, copper, chromium,
arsenic, nickel, and
others: each below 1.0
WT%.
N. Av.
N. Av.
N. Av.
N. Av.
N. Av.
N. Av.
N. Av.
N. Av.
0 to 1.0*
Polynuclear aromatics.
May include naphthalene,
fluoranthene,
phenanthrene, pyrene,
and others: each below
0.3 WT%.
N. Av.
N. Av.
N. Av.
N. Av.
N. Av.
N. Av.
N. Av.
N. Av.
0 to 0.5*
Chlorinated solvents.
N. Av.
N. Av.
N. Av.
N. Av.
N. Av.
N. Av.
N. Av.
N. Av.
N.Av. = Not Available
*Even though the concentration range does not fall under the ranges prescribed aOral-Rat LD (mg/kg)
50
by WHMIS, this is the actual range which varies with each batch of the product.
bInhalation-Rat LC
50
SECTION 3: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
APPEARANCE
Liquid, black and viscous (thick), petroleum odor.
WARNING!
PHYSICAL HAZARDS
Combustible liquid.
HEALTH HAZARDS
May be harmful if inhaled.
May be harmful if absorbed through skin.
May be harmful or fatal if swallowed.
May irritate the respiratory tract (nose, throat, and lungs), eyes, and skin.
Suspect cancer hazard. Contains material which can cause cancer. Risk of cancer depends
on duration and level of exposure.
Contains material which can cause birth defects.
Contains material which can cause central nervous system damage.
ENVIRONMENTAL HAZARDS
Product may be toxic to fish, plants, wildlife, and/or domestic animals.
Revision 9/13; MSDS Form No. 81451 - Page 2 of 10
USED OIL
MATERIAL SAFETY DATA SHEET
POTENTIAL HEALTH EFFECTS
Effects may vary depending on material composition. Typical effects may include:
INHALATION High concentrations of vapor or mist may be harmful if inhaled. High
(BREATHING): concentrations of vapor or mist may irritate the respiratory tract (nose, throat,
and lungs). High concentrations of vapor or mist may cause nausea, vomiting,
headaches, dizziness, loss of coordination, numbness, and other central
nervous system effects. Massive acute overexposure may cause rapid central
nervous system depression, sudden collapse, coma, and/or death.
EYES:
May cause irritation.
SKIN:
May cause irritation. Product may be absorbed through the skin and cause
harm as noted under INHALATION (BREATHING).
INGESTION
May be harmful or fatal if swallowed. May cause throat irritation,
(SWALLOWING): nausea, vomiting, and central nervous system effects as noted under
INHALATION (BREATHING). Breathing product into the lungs during
ingestion or vomiting may cause lung injury and possible death.
MEDICAL CONDITIONS Individuals with pre-existing cardiovascular, liver, kidney,
AGGRAVATED BY
respiratory tract (nose, throat, and lungs), central nervous
EXPOSURE:
system, eye, and/or skin disorders may have increased
susceptibility to the effects of exposure.
CHRONIC:
CANCER
INFORMATION:
Prolonged or repeated inhalation may cause oil pneumonia, lung tissue
inflammation, fibrous tissue formation, and/or toxic effects as noted under
INHALATION (BREATHING). Prolonged or repeated eye contact may cause
inflammation of the membrane lining the eyelids and covering the eyeball
(conjunctivitis). Prolonged or repeated skin contact may cause drying,
cracking, redness, itching, and/or swelling (dermatitis).
This product contains mineral oils, untreated or mildly treated, which can
cause cancer. This product may contain hydrocarbon and chlorinated
solvents; metals, and polynuclear aromatics which can cause cancer. Risk
of cancer depends on duration and level of exposure. For more
information, see SECTION 11: CARCINOGENICITY.
POTENTIAL ENVIRONMENTAL EFFECTS
Product may be toxic to fish, plants, wildlife, and/or domestic animals.
Also see SECTION 12: ECOLOGICAL INFORMATION.
Revision 9/13; MSDS Form No. 81451 - Page 3 of 10
USED OIL
MATERIAL SAFETY DATA SHEET
SECTION 4: FIRST AID MEASURES
INHALATION:
(BREATHING)
Remove to fresh air. If not breathing, give artificial respiration. If breathing
is difficult, give oxygen. Oxygen should only be administered by qualified
personnel. Someone should stay with victim. Get medical attention if
breathing difficulty persists.
EYES:
If irritation or redness from exposure to vapor develops, move away from
exposure into fresh air. Upon contact, immediately flush eyes with plenty of
lukewarm water, holding eyelids apart, for 15 minutes. Get medical
attention.
SKIN:
Remove affected clothing and shoes. Wash skin thoroughly with soap and
water. Get medical attention if irritation or pain develops or persists.
INGESTION:
(SWALLOWING)
Do NOT induce vomiting. Immediately get medical attention. Call
1-800-468-1760 for additional information. If spontaneous vomiting occurs,
keep head below hips to avoid breathing the product into the lungs. Never
give anything to an unconscious person by mouth.
NOTE TO
PHYSICIANS:
Treat symptomatically and supportively. Treatment may vary with condition
of victim and specifics of incident. Call 1-800-468-1760 for additional
information.
SECTION 5: FIRE FIGHTING MEASURES
FLASH POINT:
>200°F (93°C) (minimum) Pensky-Martens Closed Cup
FLAMMABLE LIMITS IN AIR:
Not available.
AUTOIGNITION
TEMPERATURE:
Not available.
HAZARDOUS COMBUSTION
PRODUCTS:
CONDITIONS OF
FLAMMABILITY:
Decomposition and combustion materials may be toxic.
Burning may produce phosgene gas, nitrogen oxides, carbon
monoxide, and unidentified organic compounds.
Heat, sparks, or flame. Product may burn but does not ignite
readily.
EXTINGUISHING MEDIA:
Use carbon dioxide, regular foam, dry chemical, water spray,
or water fog.
Revision 9/13; MSDS Form No. 81451 - Page 4 of 10
USED OIL
MATERIAL SAFETY DATA SHEET
NFPA 704
HAZARD
IDENTIFICATION:
This information is intended solely for the use by individuals
trained in this system.
FIRE HAZARD
(RED)
HEALTH HAZARD
(BLUE)
1
SPECIFIC
HAZARD
(WHITE)
1
0
0
REACTIVITY
(YELLOW)
FIRE FIGHTING
INSTRUCTIONS:
Keep storage containers cool with water spray.
A positive-pressure, self-contained breathing apparatus
(SCBA) and full-body protective equipment are required for
fire emergencies.
FIRE AND
EXPLOSION HAZARDS:
Heated containers may rupture. “Empty” containers may
retain residue and can be dangerous. Product is not sensitive
to mechanical impact. Product may be sensitive to static
discharge, which could result in fire or explosion.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Remove all ignition sources. Do not touch or walk through spilled product. Stop leak if you can
do it without risk. Wear protective equipment and provide engineering controls as specified in
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION. Isolate hazard area.
Keep unnecessary and unprotected personnel from entering. Ventilate area and avoid
breathing vapor or mist. A vapor suppressing foam may be used to reduce vapors. Contain
spill away from surface waters and sewers. Contain spill as a liquid for possible recovery, or
sorb with compatible sorbent material and shovel with a clean, sparkproof tool into a sealable
container for disposal.
Additionally, for large spills: Water spray may reduce vapor, but may not prevent ignition in
closed spaces. Dike far ahead of liquid spill for collection and later disposal.
There may be specific federal regulatory reporting requirements associated with spills, leaks, or
releases of this product. Also see SECTION 15: REGULATORY INFORMATION.
Revision 9/13; MSDS Form No. 81451 - Page 5 of 10
USED OIL
MATERIAL SAFETY DATA SHEET
SECTION 7: HANDLING AND STORAGE
HANDLING:
Keep away from heat, sparks, or flame. Where flammable mixtures may be
present, equipment safe for such locations should be used. Use clean,
sparkproof tools and explosion-proof equipment. When transferring
product, storage tanks, tanker trucks, and rail tank cars should be grounded
and bonded. Do not breathe vapor or mist. Use in a well ventilated area.
Avoid contact with eyes, skin, clothing, and shoes. Do not smoke while
using this product.
SHIPPING AND
STORING:
Keep container tightly closed when not in use and during transport. Do not
pressurize, cut, weld, braze, solder, drill, or grind containers. Keep
containers away from heat, flame, sparks, static electricity, or other sources
of ignition. Empty product containers may retain product residue and can
be dangerous. See SECTION 14: TRANSPORT INFORMATION for
Packing Group information.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING
CONTROLS:
Use general ventilation, process enclosures, local exhaust ventilation, or
other engineering controls to control air-borne levels. Where explosive
mixtures may be present, equipment safe for such locations should be
used.
PERSONAL PROTECTIVE EQUIPMENT
RESPIRATORY
A respiratory protection program which meets USA’s OSHA General
PROTECTION:
Industry Standard 29 CFR 1910.134 or Canada’s CSA Standard
Z94.4-M1982 requirements must be followed whenever workplace
conditions warrant a respirator’s use. Consult a qualified Industrial
Hygienist or Safety Professional for respirator selection guidance.
EYE
PROTECTION:
Wearing chemical goggles is recommended.
Contact lens may be worn with eye protection.
SKIN
PROTECTION:
Where prolonged or repeated skin contact is likely, wear neoprene,
nitrile (4 mil minimum), PVC (polyvinyl chloride), or equivalent protective
gloves; wearing natural rubber or equivalent gloves is not recommended.
When product is heated and skin contact is likely, wear
heat-insulating gloves, boots, and other protective clothing.
To avoid prolonged or repeated contact with product where spills and
splashes are likely, wear appropriate chemical-resistant faceshield, boots,
apron, whole body suits, or other protective clothing.
Revision 9/13; MSDS Form No. 81451 - Page 6 of 10
USED OIL
MATERIAL SAFETY DATA SHEET
PERSONAL
HYGIENE:
Wash thoroughly with soap and water after handling product and before
eating, drinking, or using tobacco products. Clean affected clothing, shoes,
and protective equipment before reuse. Discard affected clothing, shoes,
and/or protective equipment if they cannot be thoroughly cleaned. Discard
leather articles, such as shoes, saturated with the product.
OTHER
PROTECTIVE
EQUIPMENT:
Where spills and splashes are likely, facilities storing or using this product
should be equipped with an emergency eyewash and shower, both
equipped with clean water, in the immediate work area.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE,
APPEARANCE, AND ODOR:
Liquid, black and viscous (thick), petroleum odor.
ODOR THRESHOLD:
Not available.
MOLECULAR WEIGHT:
Not applicable.
SPECIFIC GRAVITY:
0.8 to 1.0 at 60°F (15.6°C) (water = 1)
DENSITY:
6.7 to 8.3 LB/US gal (800 to 1000 g/l) (approximately)
VAPOR DENSITY:
greater than 1 (air = 1) (based on kerosene)
VAPOR PRESSURE:
Not available.
BOILING POINT:
Not available.
FREEZING/MELTING POINT:
Not available.
pH:
Not applicable.
EVAPORATION RATE:
less than 1 (butyl acetate = 1)
SOLUBILITY IN WATER:
Slight.
FLASH POINT:
>200°F (93°C) (minimum) Pensky-Martens Closed Cup
FLAMMABLE LIMITS IN AIR:
Not available.
AUTOIGNITION
TEMPERATURE:
Not available.
Revision 9/13; MSDS Form No. 81451 - Page 7 of 10
USED OIL
MATERIAL SAFETY DATA SHEET
SECTION 10: STABILITY AND REACTIVITY
STABILITY:
Stable under normal temperatures and pressures. Avoid heat, sparks, or
flame.
INCOMPATIBILITY:
Avoid acids, alkalies, oxidizing agents, reducing agents, reactive
halogens, or reactive metals.
REACTIVITY:
Polymerization is not known to occur under normal temperatures and
pressures. Not reactive with water.
HAZARDOUS
DECOMPOSITION
PRODUCTS:
None under normal temperatures and pressures. Also see
SECTION 5: HAZARDOUS COMBUSTION PRODUCTS.
SECTION 11: TOXICOLOGICAL INFORMATION
SENSITIZATION:
Based on best current information, there may be known human
sensitization associated with this product.
MUTAGENICITY:
Based on best current information, there may be mutagenicity
associated with this product.
CARCINOGENICITY: Mineral oils, untreated or mildly treated are listed by IARC as a known
carcinogen. Mineral oils, untreated or mildly treated are classified by
NTP as having limited evidence of carcinogenicity in humans or
sufficient evidence of carcinogenicity in experimental animals.
There may be hydrocarbon and chlorinated solvents; metals, and
polynuclear aromatics present in this product which are listed by OSHA
as known carcinogens. There may be hydrocarbon and chlorinated
solvents; metals, and polynuclear aromatics present in this product
which are listed by IARC as known, probable, or possible carcinogens.
There may be hydrocarbon and chlorinated solvents; metals, and
polynuclear aromatics present in this product which are classified by
NTP as known carcinogens or as having limited evidence of
carcinogenicity in humans or sufficient evidence of carcinogenicity in
experimental animals. There may be hydrocarbon and chlorinated
solvents; metals, and polynuclear aromatics present in this product
which are recognized by ACGIH as confirmed or suspected human
carcinogens.
Also see SECTION 3: CANCER INFORMATION.
Revision 9/13; MSDS Form No. 81451 - Page 8 of 10
USED OIL
MATERIAL SAFETY DATA SHEET
REPRODUCTIVE
TOXICITY:
Based on best current information, there may be reproductive
toxicity associated with this product.
TERATOGENICITY:
Based on best current information, there may be teratogenicity
associated with this product.
TOXICOLOGICALLY
SYNERGISTIC
Based on best current information, there may be toxicologically
PRODUCT(S):
synergistic products associated with this product.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICITY:
Not available.
OCTANOL/WATER
PARTITION COEFFICIENT:
Not available.
VOLATILE ORGANIC
COMPOUNDS:
Not available.
As per 40 CFR Part 51.100(s).
SECTION 13: DISPOSAL CONSIDERATIONS
Dispose in accordance with federal, state, provincial, and local regulations. Regulations may
also apply to empty containers. The responsibility for proper waste disposal lies with the owner
of the waste. Contact Safety-Kleen regarding proper recycling or disposal.
SECTION 14: TRANSPORT INFORMATION
DOT:
Not regulated.
TDG:
Not regulated.
EMERGENCY RESPONSE Not applicable.
GUIDE NUMBER:
Reference North American Emergency Response Guidebook
SECTION 15: REGULATORY INFORMATION
USA REGULATIONS Based on the ingredient(s) listed in SECTION 2, this product does not
SARA SECTIONS
contain any "extremely hazardous substances" listed pursuant to Title III
302 AND 304:
of the Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 302 or Section 304 as identified in 40 CFR Part 355, Appendix
A and B.
Revision 9/13; MSDS Form No. 81451 - Page 9 of 10
USED OIL
MATERIAL SAFETY DATA SHEET
SARA SECTIONS
311 AND 312:
This product poses the following physical and health hazards as
defined in 40 CFR Part 370 and is subject to the requirements of
sections 311 and 312 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 (SARA):
Immediate (Acute) Health Hazard
Delayed (Chronic) Health Hazard
SARA SECTION
313:
This product may contain "toxic" chemicals subject to the requirements
of section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 (SARA) and 40 CFR Part 372.
CERCLA:
This product may contain “hazardous substances” listed pursuant to
Comprehensive Environmental Response, Compensation and Liability
Act of 1980 (CERCLA) in 40 CFR Part 302, Table 302.4.
TSCA:
Not available.
CALIFORNIA:
This product is not for sale or use in the State of California.
CANADIAN REGULATIONS
WHMIS:
Not regulated
CANADIAN
ENVIRONMENTAL
PROTECTION ACT
(CEPA):
Not available.
SECTION 16: OTHER INFORMATION
REVISION INFORMATION:
Regulatory review. Update to Section 1.
LABEL/OTHER INFORMATION:
Not available.
User assumes all risks incident to the use of this product. To the best of our knowledge, the information contained herein is accurate.
However, Safety-Kleen assumes no liability whatsoever for the accuracy or completeness of the information contained herein. No
representations or warranties, either express or implied, of merchantability, fitness for a particular purpose or of any other nature are made
hereunder with respect to information or the product to which information refers. The data contained on this sheet apply to the product as
supplied to the user.
Revision 9/13; MSDS Form No. 81451 - Page 10 of 10
MATERIAL SAFETY DATA SHEET
HMIS RATINGS: HEALTH:1, FLAMMABITY:0, REACTIVITY:0
Identity: Uvex Clear Lens Cleaner - # S461, S463, S464, S467
Section I
Manufacturer: Uvex Safety, Inc.
Address:
900 Douglas Pike
Smithfield, RI 02917
Emergency Telephone: 401-232-1200
Information Telephone: 800-343-3411
Date Prepared: 04/23/12
Section II - Hazardous Ingredients/Identity Information
Hazardous Components
(Specific Chemical Identity; Common Name(s))
Ethylene Glycol Mono Butyl Ether #111-76-2
OSHA PEL
1
ACGIH TLV
1
25 PPM
TWA (SKIN)
25 PPM TWA
(SKIN)
Other limits % (optional)
recommended
N/A
<6%
Section III - Physical/Chemical Characteristics
Boiling Point: 212° F (100° C)
Specific Gravity (H2O=1): 0.98 at 77° F (25° C)
Melting Point: N/A
Vapor Pressure (mm Hg.): 22 mm Hg at 70° F (20° C)
Vapor Density (Air = 1) : NOT DETERMINED
Evaporation Rate (Butyl Acetate = 1): < 1
Solubility in Water: 100%
Appearance and Odor: CLEAR TINTED LIQUID WITH A SLIGHT ODOR.
Section IV - Fire and Explosion Hazard Data
LEL: N/A
UEL: N/A
Flammable Limits: NOT
FLAMMABLE UNDER NORMAL
CONDITIONS OF STORAGE & USE.
Extinguishing Media: 1. WATER FOG OR SPRAY, 2. CARBON DIOXIDE (CO2), 3. DRY CHEMICAL, 4. CLASS B EXTINGUISHERS
Special Fire Fighting Procedures: KEEP FIRE EXPOSED CONTAINERS COOL. WEAR SELF-CONTAINED BREATHING APPARATUS (SCBA)
AND FULL PROTECTIVE EQUIPMENT.
Unusual Fire and Explosion Hazards: N/A
Flash Point (Method Used): >212°F
Section V - Reactivity Data
Stability
Unstable: NO
Conditions to Avoid: DO NOT FREEZE, STORE IN COOL AREA.
AVOID IGNITION SOURCES.
Stable: YES
Incompatibility (Materials to Avoid): STRONG ACIDS, ALKALIES, AND OXIDIZERS.
Hazardous Decomposition or Byproducts: NONE
Hazardous
May Occur: NO
Conditions to Avoid: NONE
Polymerization
Will Not Occur: YES
Section VI - Health Hazard Data
Route(s) of Entry: Inhalation? YES Skin? NO
Ingestion? YES
Health Hazards (Acute and Chronic):
.
EYE CONTACT: IN SOME CASES EYE IRRITATION MAY OCCUR. IMMEDIATELY FLUSH WITH A
WATER OR EYEWASH SOLUTION AND CONSULT A PHYSICIAN. IN SOME CASES SKIN CONTACT MAY CAUSE IRRITATION, IMMEDIATELY
FLUSH WITH SOAP AND WATER, REMOVE CONTAMINATED CLOTHING AND CONSULT A PHYSICIAN. INGESTION: GASTRIC IRRITATION
AND VOMITING. DO NOT INDUCE VOMITING, GIVE PLENTY OF WATER AND CONSULT A PHYSICIAN. PREVENT ASPIRATION OF VOMITED
MATERIAL INDUCED BY INGESTION OF PRODUCT.
Carcinogenicity: NTP? NO
IARC Monographs? NO
OSHA Regulated? NO
Signs and Symptoms of Exposure: EYE, SKIN OR GASTRIC IRRITATION, NAUSEA, DIZZINESS, HEADACHE.
Medical Conditions Generally Aggravated by Exposure: NONE KNOWN
Emergency First Aid Procedures: SEEK MEDICAL ATTENTION IF LARGE QUANTITIES ARE SWALLOWED. WASH EXPOSED SKIN
THOROUGHLY WITH SOAP & WATER. FLUSH EXPOSED EYES WITH WATER OR EYEWASH SOLUTION FOR AT LEAST 15 MINUTES. SEEK
MEDICAL ATTENTION IN ALL CASES.
Section VII - Precautions for Safe Handling and Use
Steps to Be Taken in Case Material is Released or Spilled: IN CASE OF LARGE SPILLS WEAR PROTECTIVE CLOTHING, NEOPRENE
GLOVES AND CHEMICAL SPLASH GOGGLES.
Waste Disposal Method: ABSORB WITH SAND OR INERT MATERIAL. THEN REMOVE AND A DISPOSE OF ABSORBED MATERIAL IN AN
APPROPRIATE MANNER.
Precautions to Be Taken in Handling and Storing: AVOID SKIN & EYE CONTACT. AVOID INHALATION AND INGESTION. WEAR
PROTECTIVE CLOTHING, GLOVES AND SAFETY GLASSES WHEN A LARGE SPILL OR SPLASH HAZARD EXISTS. HANDLE AND STORE IN A
WELL-VENTILATED AND COOL AREA.
Other Precautions: DO NOT FREEZE. STORE IN A COOL, WELL-VENTILATED AREA.
Section VIII - Control Measures
Ventilation
Local Exhaust: GENERAL AIR CIRCULATION SUFFICIENT FOR NORMAL PRODUCT USE.
Special: N/A
Mechanical: ADEQUATE VENTILATION
Other: N/A
Protective Gloves: NONE REQUIRED FOR NORMAL PRODUCT USE.
Eye Protection: NONE REQUIRED FOR NORMAL PRODUCT USE.
Other Protective Clothing: NONE REQUIRED FOR NORMAL PRODUCT USE.
Work Hygienic Practices: ALWAYS FOLLOW SAFE WORK PRACTICES.
Part #32-003108 Rev G
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GHS SAFETY DATA SHEET
IPEX
Date Revised: JUN 2013
XIRTEC 5 GRY Low VOC Cement for PVC Plastic Pipe
Supersedes:
JAN 2012
SECTION I - PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME:
XIRTEC 5 GRY Low VOC Cement for PVC Plastic Pipe
PRODUCT USE:
Low VOC Solvent Cement for PVC Plastic Pipe
SUPPLIER:
IPEX Inc.
807 Pharmacy Avenue
Scarborough, Ontario M1L 3K2, CAN
MANUFACTURER:
EMERGENCY: Transportation: CHEMTEL Tel. 800.255-3924, 813-248-0585 (International)
IPS Corporation
17109 South Main Street, Gardena, CA 90248-3127
P.O. Box 379, Gardena, CA 90247-0379
Tel. 1-310-898-3300
Medical: CHEMTEL Tel. 800.255-3924, 813-248-0585 (International)
SECTION 2 - HAZARDS IDENTIFICATION
GHS CLASSIFICATION:
Health
Acute Toxicity:
Category 4
Skin Irritation:
Category 3
Skin Sensitization:
NO
Eye:
Category 2B
Acute Toxicity:
Chronic Toxicity:
Environmental
None Known
None Known
GHS LABEL:
Physical
Flammable Liquid
Signal Word:
Danger
OR
WHMIS CLASSIFICATION:
Hazard Statements
Category 2
CLASS B, DIVISION 2
Precautionary Statements
H225: Highly flammable liquid and vapor
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking
H319: Causes serious eye irritation
P261: Avoid breathing dust/fume/gas/mist/vapors/spray
H332: Harmful if inhaled
P280: Wear protective gloves/protective clothing/eye protection/face protection
H335: May cause respiratory irritation
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
H336: May cause drowsiness or dizziness
P403+P233: Store in a well ventilated place. Keep container tightly closed
EUH019: May form explosive peroxides
P501: Dispose of contents/container in accordance with local regulation
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
CAS#
Tetrahydrofuran (THF)
Methyl Ethyl Ketone (MEK)
Cyclohexanone
EINECS #
109-99-9
78-93-3
108-94-1
203-726-8
201-159-0
203-631-1
REACH
Pre-registration Number
CONCENTRATION
% by Weight
05-2116297729-22-0000
05-2116297728-24-0000
05-2116297718-25-0000
25 - 50
5 - 36
15 - 30
All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances maintained by the US EPA, or are exempt from that listing.
* Indicates this chemical is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 (40CFR372).
# indicates that this chemical is found on Proposition 65’s List of chemicals known to the State of California to cause cancer or reproductive toxicity.
SECTION 4 - FIRST AID MEASURES
Contact with eyes:
Skin contact:
Inhalation:
Ingestion:
Flush eyes immediately with plenty of water for 15 minutes and seek medical advice immediately.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water. If irritation develops, seek medical advice.
Remove to fresh air. If breathing is stopped, give artificial respiration. If breathing is difficult, give oxygen. Seek medical advice.
Rinse mouth with water. Give 1 or 2 glasses of water or milk to dilute. Do not induce vomiting. Seek medical advice immediately.
SECTION 5 - FIREFIGHTING MEASURES
Suitable Extinguishing Media:
Unsuitable Extinguishing Media:
Exposure Hazards:
Combustion Products:
Protection for Firefighters:
Dry chemical powder, carbon dioxide gas, foam, Halon, water fog.
Water spray or stream.
Inhalation and dermal contact
Oxides of carbon, hydrogen chloride and smoke
Health
Flammability
Reactivity
PPE
Self-contained breathing apparatus or full-face positive pressure airline masks.
HMIS
2
3
0
B
NFPA
2
3
0
0-Minimal
1-Slight
2-Moderate
3-Serious
4-Severe
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Personal precautions:
Keep away from heat, sparks and open flame.
Provide sufficient ventilation, use explosion-proof exhaust ventilation equipment or wear suitable respiratory protective equipment.
Prevent contact with skin or eyes (see section 8).
Environmental Precautions:
Prevent product or liquids contaminated with product from entering sewers, drains, soil or open water course.
Methods for Cleaning up:
Clean up with sand or other inert absorbent material. Transfer to a closable steel vessel.
Materials not to be used for clean up:
Aluminum or plastic containers
SECTION 7 - HANDLING AND STORAGE
Handling: Avoid breathing of vapor, avoid contact with eyes, skin and clothing.
Keep away from ignition sources, use only electrically grounded handling equipment and ensure adequate ventilation/fume exhaust hoods.
Do not eat, drink or smoke while handling.
Storage: Store in ventilated room or shade below 44°C (110°F) and away from direct sunlight.
Keep away from ignition sources and incompatible materials: caustics, ammonia, inorganic acids, chlorinated compounds, strong oxidizers and isocyanates.
Follow all precautionary information on container label, product bulletins and solvent cementing literature.
SECTION 8 - PRECAUTIONS TO CONTROL EXPOSURE / PERSONAL PROTECTION
EXPOSURE LIMITS:
Component
Tetrahydrofuran (THF)
Methyl Ethyl Ketone (MEK)
Cyclohexanone
ACGIH TLV
ACGIH STEL
OSHA PEL
50 ppm
200 ppm
20 ppm
100 ppm
300 ppm
50 ppm
200 ppm
200 ppm
50 ppm
OSHA STEL:
Engineering Controls: Use local exhaust as needed.
Monitoring:
Maintain breathing zone airborne concentrations below exposure limits.
Personal Protective Equipment (PPE):
Eye Protection:
Avoid contact with eyes, wear splash-proof chemical goggles, face shield, safety glasses (spectacles) with brow guards and side shields,
etc. as may be appropriate for the exposure.
Skin Protection:
Prevent contact with the skin as much as possible. Butyl rubber gloves should be used for frequent immersion.
Use of solvent-resistant gloves or solvent-resistant barrier cream should provide adequate protection when normal adhesive application
practices and procedures are used for making structural bonds.
Respiratory Protection: Prevent inhalation of the solvents. Use in a well-ventilated room. Open doors and/or windows to ensure airflow and air changes. Use local
exhaust ventilation to remove airborne contaminants from employee breathing zone and to keep contaminants below levels listed above.
With normal use, the Exposure Limit Value will not usually be reached. When limits approached, use respiratory protection equipment.
Filename: XIRTEC 5 GRY_LoVoc 6-13.xls
Page 1 of 2
6/12/2013 9:34 AM
GHS SAFETY DATA SHEET
IPEX
Date Revised: JUN 2013
XIRTEC 5 GRY Low VOC Cement for PVC Plastic Pipe
Supersedes:
JAN 2012
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Gray, medium syrupy liquid
Odor:
Ketone
Odor Threshold:
0.88 ppm (Cyclohexanone)
pH:
Not Applicable
Melting/Freezing Point:
-108.5°C (-163.3°F) Based on first melting component: THF
Boiling Range:
66°C (151°F) to 156°C (313°F)
Boiling Point:
66°C (151°F) Based on first boiling component: THF
Evaporation Rate:
> 1.0 (BUAC = 1)
Flash Point:
-20°C (-4°F) TCC based on THF
Flammability:
Category 2
LEL: 1.1% based on Cyclohexanone
Specific Gravity:
0.9611 @23°C ( 73°F)
Flammability Limits:
UEL: 11.8% based on THF
Solubility:
Solvent portion soluble in water. Resin portion separates out.
Partition Coefficient n-octanol/water:
Not Available
Vapor Pressure:
129 mm Hg @ 20°C (68°F)based on THF
Auto-ignition Temperature:
321°C (610°F) based on THF
Vapor Density:
>2 (Air = 1)
Decomposition Temperature:
Not Applicable
Other Data: Viscosity:
Medium bodied
When applied as directed, per SCAQMD Rule 1168, Test Method 316A,VOC content is: < 510 g/l.
VOC Content:
SECTION 10 - STABILITY AND REACTIVITY
Stability:
Hazardous decomposition products:
Conditions to avoid:
Incompatible Materials:
Stable
None in normal use. When forced to burn, this product gives off oxides of carbon, hydrogen chloride and smoke.
Keep away from heat, sparks, open flame and other ignition sources.
Oxidizers, strong acids and bases, amines, ammonia
SECTION 11 - TOXICOLOGICAL INFORMATION
Likely Routes of Exposure:
Inhalation, Eye and Skin Contact
Acute symptoms and effects:
Inhalation:
Severe overexposure may result in nausea, dizziness, headache. Can cause drowsiness, irritation of eyes and nasal passages.
Eye Contact:
Vapors slightly uncomfortable. Overexposure may result in severe eye injury with corneal or conjunctival inflammation on contact with the liquid.
Skin Contact:
Liquid contact may remove natural skin oils resulting in skin irritation. Dermatitis may occur with prolonged contact.
Ingestion:
May cause nausea, vomiting, diarrhea and mental sluggishness.
Chronic (long-term) effects:
None known to humans
LD50
LC50
Toxicity:
Inhalation 3 hrs. 21,000 mg/m3 (rat)
Tetrahydrofuran (THF)
Oral: 2842 mg/kg (rat)
Inhalation 8 hrs. 23,500 mg/m3 (rat)
Methyl Ethyl Ketone (MEK)
Oral: 2737 mg/kg (rat), Dermal: 6480 mg/kg (rabbit)
Cyclohexanone
Oral: 1535 mg/kg (rat), Dermal: 948 mg/kg (rabbit)
Inhalation 4 hrs. 8,000 PPM (rat)
Reproductive Effects
Not Established
Teratogenicity
Not Established
Mutagenicity
Not Established
Embryotoxicity
Not Established
Sensitization to Product
Not Established
Synergistic Products
Not Established
SECTION 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Mobility:
Degradability:
Bioaccumulation:
None Known
In normal use, emission of volatile organic compounds (VOC's) to the air takes place, typically at a rate of < 510 g/l.
Biodegradable
Minimal to none.
SECTION 13 - WASTE DISPOSAL CONSIDERATIONS
Follow local and national regulations. Consult disposal expert.
SECTION 14 - TRANSPORT INFORMATION
Proper Shipping Name:
Hazard Class:
Secondary Risk:
Identification Number:
Packing Group:
Label Required:
Marine Pollutant:
Adhesives
3
EXCEPTION for Ground Shipping
DOT Limited Quantity: Up to 5L per inner packaging, 30 kg gross weight per package.
None
Consumer Commodity: Depending on packaging, these quantities may qualify under DOT as "ORM-D" .
UN 1133
PG II
Class 3 Flammable Liquid
TDG INFORMATION
NO
TDG CLASS:
FLAMMABLE LIQUID 3
SHIPPING NAME:
ADHESIVES
UN NUMBER/PACKING GROUP:
UN 1133, PG II
SECTION 15 - REGULATORY INFORMATION
Precautionary Label Information: Highly Flammable, Irritant
Symbols:
F, Xi
Risk Phrases:
R11: Highly flammable.
Ingredient Listings: USA TSCA, Europe EINECS, Canada DSL, Australia
AICS, Korea ECL/TCCL, Japan MITI (ENCS)
R20: Harmful by inhalation.
R36/37: Irritating to eyes and respiratory system.
Safety Phrases:
S9: Keep container in a well-ventilated place.
S16: Keep away from sources of ignition - No smoking.
S25: Avoid contact with eyes.
R66: Repeated exposure may cause skin dryness or cracking
R67: Vapors may cause drowsiness and dizziness
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S33: Take precautionary measures against static discharges.
S46: If swallowed, seek medical advise immediately and show this container or label.
SECTION 16 - OTHER INFORMATION
Specification Information:
Department issuing data sheet:
Safety Health & Environmental Affairs
Training necessary:
Reissue date / reason for reissue:
Intended Use of Product:
Yes, training in practices and procedures contained in product literature.
6/12/2013 / Updated GHS Standard Format
Solvent Cement for PVC Plastic Pipe
All ingredients are compliant with the requirements of the European
Directive on RoHS (Restriction of Hazardous Substances).
This product is intended for use by skilled individuals at their own risk. The information contained herein is based on data considered accurate based on current state of
knowledge and experience. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof.
Filename: XIRTEC 5 GRY_LoVoc 6-13.xls
Page 2 of 2
6/12/2013 9:34 AM
Product Name: XYLENE
Revision Date: 26 Feb 2013
Page 1 of 11
______________________________________________________________________________________________________________________
MATERIAL SAFETY DATA SHEET
SECTION 1
PRODUCT AND COMPANY IDENTIFICATION
PRODUCT
Product Name: XYLENE
Product Description: Aromatic Hydrocarbon
MSDS Number: 4562
Intended Use:
Chemical feedstock, Solvent
COMPANY IDENTIFICATION
Supplier:
IMPERIAL OIL CHEMICALS DIVISION
240 4th Avenue S.W.
CALGARY, ALBERTA. T2P 3M9 Canada
24 Hour Environmental / Health Emergency
1-866-232-9563
Telephone
Transportation Emergency Phone Number
1-866-232-9563
Product Technical Information
1-800-663-4109
SECTION 2
COMPOSITION / INFORMATION ON INGREDIENTS
Reportable Hazardous Substance(s) or Complex Substance(s)
Name
CAS#
Mixed Xylenes
1330-20-7
Hazardous Constituent(s) Contained in Complex Substance(s)
Name
CAS#
ETHYL BENZENE
100-41-4
Concentration*
100 %
Concentration*
10 - 20%
Acute Toxicity
Oral Lethality: LD50 > 5000
mg/kg (Rat)
Acute Toxicity
Inhalation Lethality: LC50
17.8 mg/l (Rat); Oral
Lethality: LD50 3.5 g/kg (Rat)
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
SECTION 3
HAZARDS IDENTIFICATION
This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15).
PHYSICAL/CHEMICAL EFFECTS
FLAMMABLE. In use, may form flammable/explosive vapour-air mixture. Material can release vapours that
readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited. Material can
accumulate static charges which may cause an ignition.
HEALTH EFFECTS
Irritating to skin. May cause cancer. May cause harm to the unborn child. If swallowed, may be aspirated and
cause lung damage. May be irritating to the eyes, nose, throat, and lungs.
Target Organs: Skin |
Product Name: XYLENE
Revision Date: 26 Feb 2013
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NFPA Hazard ID:
HMIS Hazard ID:
Health:
Health:
2
2*
Flammability: 3
Flammability: 3
Reactivity: 0
Reactivity: 0
NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert
advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary
from person to person.
SECTION 4
FIRST AID MEASURES
INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use
adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use
mouth-to-mouth resuscitation.
SKIN CONTACT
Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing
before reuse.
EYE CONTACT
Flush thoroughly with water for at least 15 minutes. Get medical assistance.
INGESTION
Seek immediate medical attention. Do not induce vomiting.
NOTE TO PHYSICIAN
If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately.
This light hydrocarbon material, or a component, may be associated with cardiac sensitisation following very
high exposures (well above occupational exposure limits) or with concurrent exposure to high stress levels or
heart-stimulating substances like epinephrine. Administration of such substances should be avoided.
SECTION 5
FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.
Inappropriate Extinguishing Media: Straight streams of water
FIRE FIGHTING
Fire Fighting Instructions: FLAMMABLE. Evacuate area. If a leak or spill has not ignited, use water spray to
disperse the vapours and to protect personnel attempting to stop a leak. Prevent run-off from fire control or
dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective
equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire
exposed surfaces and to protect personnel.
Unusual Fire Hazards: Hazardous material. Firefighters should consider protective equipment indicated in
Section 8.
Product Name: XYLENE
Revision Date: 26 Feb 2013
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Hazardous Combustion Products: Smoke, Fume, Incomplete combustion products, Oxides of carbon
FLAMMABILITY PROPERTIES
Flash Point [Method]: >23°C (73°F) [ASTM D-56]
Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0
Autoignition Temperature: 432°C (810°F) - 528°C (982°F) [Technical literature]
SECTION 6
ACCIDENTAL RELEASE MEASURES
NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations.
PROTECTIVE MEASURES
Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if
required, due to toxicity or flammability of the material. See Section 5 for fire fighting information. See the
Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for
advice on the minimum requirements for personal protective equipment. Additional protective measures may be
necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders.
SPILL MANAGEMENT
Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if
you can do so without risk. All equipment used when handling the product must be grounded. Do not touch or
walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapoursuppressing foam may be used to reduce vapour. Use clean non-sparking tools to collect absorbed material.
Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large Spills:
Water spray may reduce vapour, but may not prevent ignition in enclosed spaces. Recover by pumping or with
suitable absorbent.
Water Spill: Stop leak if you can do so without risk. Eliminate sources of ignition. Warn other shipping. If the
Flash Point exceeds the Ambient Temperature by 10 deg C or more, use containment booms and remove from
the surface by skimming or with suitable absorbents when conditions permit. If the Flash Point does not exceed
the Ambient Air Temperature by at least 10C, use booms as a barrier to protect shorelines and allow material to
evaporate. Seek the advice of a specialist before using dispersants.
Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways,
sewers, basements or confined areas.
SECTION 7
HANDLING AND STORAGE
HANDLING
Avoid contact with skin. Avoid contact with eyes. Prevent exposure to ignition sources, for example use non-
Product Name: XYLENE
Revision Date: 26 Feb 2013
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______________________________________________________________________________________________________________________
sparking tools and explosion-proof equipment. Prevent small spills and leakage to avoid slip hazard. Material
can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding
and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static
accumulation. Consult local applicable standards for guidance. Additional references include American
Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or
National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404
(Electrostatics - Code of practice for the avoidance of hazards due to static electricity).
Loading/Unloading Temperature:
[Ambient]
Transport Temperature: [Ambient]
Transport Pressure: [Ambient]
Static Accumulator: This material is a static accumulator. A liquid is typically considered a nonconductive,
static accumulator if its conductivity is below 100 pS/m (100x10E-12 Siemens per meter) and is considered a
semiconductive, static accumulator if its conductivity is below 10,000 pS/m. Whether a liquid is nonconductive
or semiconductive, the precautions are the same. A number of factors, for example liquid temperature,
presence of contaminants, anti-static additives and filtration can greatly influence the conductivity of a liquid.
STORAGE
Ample fire water supply should be available. A fixed sprinkler/deluge system is recommended. The container
choice, for example storage vessel, may effect static accumulation and dissipation. Keep container closed.
Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, wellventilated area. Outside or detached storage preferred. Storage containers should be earthed and bonded.
Fixed storage containers, transfer containers and associated equipment should be grounded and bonded to
prevent accumulation of static charge.
Storage Temperature:
[Ambient]
Storage Pressure: [Ambient]
Suitable Containers/Packing: Tankers; Drums; Tank Trucks; Barges; Tank Cars
Suitable Materials and Coatings (Chemical Compatibility): Carbon Steel; Polyester; Stainless Steel; Teflon
Unsuitable Materials and Coatings: Natural Rubber; Butyl Rubber; Ethylene-proplyene-diene monomer
(EPDM); Polystyrene; Polyethylene; Polypropylene; PVC; Polyvinyl Alcohol; Polyacrylonitrile; Compatibility with
plastics will vary
SECTION 8
Substance Name
ETHYL BENZENE
Mixed Xylenes
Mixed Xylenes
Mixed Xylenes
EXPOSURE CONTROLS / PERSONAL PROTECTION
Form
Vapour.
Limit/Standard
TWA
20 ppm
RCP 434 mg/m3 100 ppm
TWA
STEL
TWA
150 ppm
100 ppm
NOTE: Limits/standards shown for guidance only. Follow applicable regulations.
ENGINEERING CONTROLS
Note
Total
Hydrocarbon
s
Source
ACGIH
Supplier
ACGIH
ACGIH
Product Name: XYLENE
Revision Date: 26 Feb 2013
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______________________________________________________________________________________________________________________
The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
Adequate ventilation should be provided so that exposure limits are not exceeded. Use explosionproof ventilation equipment.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a
level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
Half-face filter respirator
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.
Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use
conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material
include:
Chemical resistant gloves are recommended.
Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
Chemical/oil resistant clothing is recommended.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practise good housekeeping.
ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water and
soil. Protect the environment by applying appropriate control measures to prevent or limit
emissions.
SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
Note: Physical and chemical properties are provided for safety, health and environmental considerations only
and may not fully represent product specifications. Contact the Supplier for additional information.
GENERAL INFORMATION
Physical State: Liquid
Form: Clear
Product Name: XYLENE
Revision Date: 26 Feb 2013
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Colour: Colourless
Odour: Aromatic
Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15 °C): 0.869 [Technical literature]
Density (at 15 ºC): 870 kg/m³ (7.26 lbs/gal, 0.87 kg/dm³) [ISO 12185]
Flash Point [Method]: >23°C (73°F) [ASTM D-56]
Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0
Autoignition Temperature: 432°C (810°F) - 528°C (982°F) [Technical literature]
Boiling Point / Range: 136°C (277°F) - 145°C (292°F) [Technical literature]
Vapour Density (Air = 1): < 1 at 101 kPa [Technical literature]
Vapour Pressure: 0.8 kPa (6 mm Hg) at 20ºC [Calculated]
Evaporation Rate (n-butyl acetate = 1): 0.85 [In-house method]
pH: N/D
Log Pow (n-Octanol/Water Partition Coefficient): 3.12 - 3.16 [Technical literature]
Solubility in Water: Negligible
Viscosity: [N/D at 40 °C] | 0.79 cSt (0.79 mm2/sec) at 20°C [ASTM D7042]
Oxidizing Properties: See Hazards Identification Section.
OTHER INFORMATION
Freezing Point: -54°C (-65°F) [Technical literature]
Melting Point: -39°C (-39°F) [Technical literature]
Pour Point: -95°C (-139°F) - 13°C (56°F) [Technical literature]
Molecular Weight: 106 G/MOLE [Calculated]
Hygroscopic: No
Coefficient of Thermal Expansion: 0.00105 V/V/DEG C [Calculated] [In-house method]
Decomposition Temperature: N/D
SECTION 10
STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions.
CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources.
MATERIALS TO AVOID: Strong oxidizers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.
HAZARDOUS POLYMERIZATION: Will not occur.
SECTION 11
ACUTE TOXICITY
Route of Exposure
Inhalation
Toxicity (Rat): LC50 > 20 mg/l
Irritation: No end point data for material.
Ingestion
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for the material.
Elevated temperatures or mechanical action may form vapours,
mist, or fumes which may be irritating to the eyes, nose, throat, or
lungs.
Product Name: XYLENE
Revision Date: 26 Feb 2013
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Toxicity (Rat): LD50 > 3523 mg/kg
Minimally Toxic. Based on test data for the material.
Skin
Toxicity (Rabbit): LD50 > 4200 mg/kg
Irritation: Data available.
Minimally Toxic. Based on test data for the material.
Irritating to the skin. Based on test data for the material.
Eye
Irritation: Data available.
Moderately irritating to the eyes. Based on test data for structurally
similar materials.
CHRONIC/OTHER EFFECTS
For the product itself:
Vapour concentrations above recommended exposure levels are irritating to the eyes and the respiratory tract,
may cause headaches and dizziness, are anaesthetic and may have other central nervous system effects.
Small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical
pneumonitis or pulmonary edema. Very high exposure (confined spaces / abuse) to light hydrocarbons may
result in abnormal heart rhythm (arrhythmias). Concurrent high stress levels and/or co-exposure to high levels
of hydrocarbons (above occupational exposure limits), and to heart-stimulating substances like epinephrine,
nasal decongestants, asthma drugs, or cardiovascular drugs may initiate arrhythmias.
Contains:
ETHYLBENZENE: Caused cancer in laboratory animal studies. The relevance of these findings to humans is
uncertain.
XYLENES: High exposures to xylenes in some animal studies have been reported to cause health effects on
the developing embryo/fetus. These effects were often at levels toxic to the mother. The significance of these
findings to humans has not been determined.
CMR Status:
Chemical Name
ETHYL BENZENE
Mixed Xylenes
1 = IARC 1
2 = IARC 2A
CAS Number
100-41-4
1330-20-7
List Citations
3, 4
4
--REGULATORY LISTS SEARCHED-3 = IARC 2B
5 = ACGIH A1
4 = ACGIH ALL
6 = ACGIH A2
SECTION 12
ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials.
ECOTOXICITY
Material -- Expected to be toxic to aquatic organisms.
Material -- Not expected to demonstrate chronic toxicity to aquatic organisms.
MOBILITY
Material -- Highly volatile, will partition rapidly to air. Not expected to partition to sediment and wastewater
solids.
PERSISTENCE AND DEGRADABILITY
Biodegradation:
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Revision Date: 26 Feb 2013
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______________________________________________________________________________________________________________________
Material -- Expected to be readily biodegradable.
Hydrolysis:
Material -- Transformation due to hydrolysis not expected to be significant.
Photolysis:
Material -- Transformation due to photolysis not expected to be significant.
Atmospheric Oxidation:
Material -- Expected to degrade rapidly in air
BIOACCUMULATION POTENTIAL
Material -- Potential to bioaccumulate is low.
OTHER ECOLOGICAL INFORMATION
VOC (EPA Method 24): 7.252 lbs/gal
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.
DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of undesirable combustion products.
REGULATORY DISPOSAL INFORMATION
Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain
residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty
drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty
containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor
and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER,
DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR
OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14
TRANSPORT INFORMATION
LAND (TDG)
Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S. (Xylenes, Ethylbenzene)
Hazard Class & Division: 3
UN Number: 1993
Packing Group: III
Special Provisions: 16
LAND (DOT)
Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S. (Xylenes, Ethylbenzene )
Hazard Class & Division: 3
ID Number: 1993
Packing Group: III
Product RQ: 100 LBS - Mixed Xylenes
ERG Number: 128
Product Name: XYLENE
Revision Date: 26 Feb 2013
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______________________________________________________________________________________________________________________
Label(s): 3
Transport Document Name:
UN1993, FLAMMABLE LIQUIDS, N.O.S. (Xylenes, Ethylbenzene), 3, PG III
SEA (IMDG)
Proper Shipping Name: XYLENES
Hazard Class & Division: 3
EMS Number: F-E, S-D
UN Number: 1307
Packing Group: III
Label(s): 3
Transport Document Name:
UN1307, XYLENES, 3, PG III, (>23°C c.c.)
AIR (IATA)
Proper Shipping Name: XYLENES
Hazard Class & Division: 3
UN Number: 1307
Packing Group: III
Label(s) / Mark(s): 3
Transport Document Name: UN1307, XYLENES, 3, PG III
SECTION 15
REGULATORY INFORMATION
WHMIS Classification: Class B, Division 2: Flammable Liquids Class D, Division 2, Subdivision A: Very Toxic
Material Class D, Division 2, Subdivision B: Toxic Material
This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the
(M)SDS contains all the information required by the Controlled Products Regulations.
CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have
been notified under CEPA.
Complies with the following national/regional chemical inventory requirements: AICS, DSL, ENCS, IECSC,
KECI, PICCS, TSCA
The Following Ingredients are Cited on the Lists Below:
Chemical Name
ETHYL BENZENE
Mixed Xylenes
CAS Number
100-41-4
1330-20-7
1 = TSCA 4
2 = TSCA 5a2
--REGULATORY LISTS SEARCHED-3 = TSCA 5e
5 = TSCA 12b
4 = TSCA 6
6 = NPRI
SECTION 16
OTHER INFORMATION
N/D = Not determined, N/A = Not applicable
List Citations
6
6
Product Name: XYLENE
Revision Date: 26 Feb 2013
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THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:
Revision Changes:
Section 06: Protective Measures was modified.
Section 09: Boiling Point C(F) was modified.
Section 09: Pour Point C(F) was modified.
Section 09: Density - Header was modified.
Section 09: Density kg/m3(lbs/gal) was modified.
Section 08: Comply with applicable regulations phrase was modified.
Section 09: Vapour Pressure was modified.
Section 11: Inhalation Irritation Test Data was modified.
Section 09: Relative Density - Header was modified.
Section 09: Flash Point C(F) was modified.
Section 09: Autoignition Temperature was modified.
Section 09 Viscosity was modified.
Section 09 Viscosity was modified.
Section 14: Transport Document Name was modified.
Section 15: National Chemical Inventory Listing was modified.
Section 11: Additional Health Information was modified.
Section 16: MSN,MAT ID was modified.
Section 09: Freezing Point ºC(ºF) was modified.
Section 09: Melting Point C(F) was modified.
Composition: Component table was modified.
Composition: Component table was modified.
Section 08: Exposure Limits Table was modified.
Section 15: Canadian List Citations Table was modified.
Section 01: Company Contact Methods Sorted by Priority was modified.
Section 11: Tox List Cited Table was modified.
Section 16: CA Contains was added.
Section 16: CA Contains - Header was added.
------------------------------------------------------------------------------------------------------------------- ---------------------------------PRECAUTIONARY LABEL TEXT:
Contains: Mixed Xylenes
WHMIS Classification: Class B, Division 2: Flammable Liquids Class D, Division 2, Subdivision A: Very Toxic Material
Class D, Division 2, Subdivision B: Toxic Material
HEALTH HAZARDS
Irritating to skin. May cause cancer. May cause harm to the unborn child. If swallowed, may be aspirated and cause
lung damage.
Target Organs: Skin |
PHYSICAL HAZARDS
In use, may form flammable/explosive vapour-air mixture. Material can accumulate static charges which may cause an
ignition. FLAMMABLE.
PRECAUTIONS
Avoid contact with skin. Avoid contact with eyes. Prevent exposure to ignition sources, for example use non-sparking
tools and explosion-proof equipment. Use proper bonding and/or earthing procedures.However, bonding and earthing
may not eliminate the hazard from static accumulation.
Product Name: XYLENE
Revision Date: 26 Feb 2013
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______________________________________________________________________________________________________________________
FIRST AID
Eye: Flush thoroughly with water for at least 15 minutes. Get medical assistance.
Oral: Seek immediate medical attention. Do not induce vomiting.
Skin: Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing
before reuse.
FIRE FIGHTING MEDIA
Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.
SPILL/LEAK
Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you
can do so without risk. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam
may be used to reduce vapour. Absorb or cover with dry earth, sand or other non-combustible material and transfer to
containers.
Water Spill: Stop leak if you can do so without risk. Eliminate sources of ignition. Warn other shipping. Report spills
as required to appropriate authorities. If the Flash Point exceeds the Ambient Temperature by 10 deg C or more, use
containment booms and remove from the surface by skimming or with suitable absorbents when conditions permit. If
the Flash Point does not exceed the Ambient Air Temperature by at least 10C, use booms as a barrier to protect
shorelines and allow material to evaporate. Seek the advice of a specialist before using dispersants.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate
and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the
document is the most current available from an official Imperial Oil distribution system. The information and
recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy
itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be
consulted to insure proper health, safety and other necessary information is included on the container. Appropriate
warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly
prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is
not permitted.
----------------------------------------------------------------------------------------------------------------------------- -----------------------DGN: 5004671 (1020902)
----------------------------------------------------------------------------------------------------------------------------------------------------Copyright 2002 Imperial Oil Limited, All rights reserved
Prepared by: Imperial Oil Limited, Solvents
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