MATERIAL SAFETY DATA SHEET Total Solutions P.O. Box 240014 Milwaukee, WI 53224 GENERAL INFORMATION NUMBER: (414) 354-6417 CHEMTREC: (800) 424-9300 DATE OF REVISION: January 16, 2006 DATE OF ISSUE: January 16, 2006 I - Product Identification Orange Drain Cleaner PRODUCT CODE: 0379 CHEMICAL FORMULATION: Solvent based drain maintainer. NFPA HAZARD IDENTIFICATION SYSTEM: HEALTH: 1 HAZARD RATING: 4 - Extreme; 3 - High; FLAMMABILITY: 2 2 - Moderate; 1 - Slight; REACTIVITY: 0 0 - Insignificant II - Hazardous Ingredients SUBSTANCE Mineral Spirits d-Limonene Poly (oxyethylene) nonylphenol Ethoxylated octyl phenol Key: APPROX % 40.0-50.0 45.0-55.0 1.00-5.00 1.00-5.00 Values reported as TWA unless noted. OSHA ACGIH EPA 40 CFR: PEL TLV 302 355 372 N/E N/E N N N N/E N/E Y N N N/E N/E N N N N/E N/E N N N CAS # 8052-41-3 5989-27-5 9016-45-9 9036-19-5 PEL: Permissible Exposure Limit TLV: Threshold Limit Value C: Ceiling level STEL: Short Term Exposure Limit N/A: Not Applicable N/D: Not Determined N/E: Not Established Y: Yes N: No 302: CERCLA List of Hazardous Substances and Reportable Quantities (40 CFR 302.4). 355: SARA TITLE III / List of Extremely Hazardous Substances for Emergency Planning and Notification (40 CFR 355). 372: SARA TITLE III / List of Toxic Chemicals subject to Release Reporting (Community Right to Know) (40 CFR 372). III - Physical Data BOILING POINT (°F): N/D VAPOR PRESSURE (mm Hg): N/D VAPOR DENSITY (AIR = 1): N/D SOLUBILITY IN WATER: Emulsifiable APPEARANCE AND ODOR: Clear, orange liquid; citrus scent. SPECIFIC GRAVITY (WATER = 1): 0.812 VOC CONTENT (% by weight): > 90.0 EVAPORATION RATE (WATER = 1): > 1.0 pH: N/A IV - Fire and Explosion Hazard Data FLASH POINT (°F): 121 (TEST METHOD): Closed cup FLAMMABLE LIMITS IN AIR (VOLUME %) UPPER: N/E LOWER: N/E EXTINGUISHING MEDIA: Foam, carbon dioxide, dry chemical. SPECIAL FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water fog. Firefighters should be equipped with full protective gear including self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARD: None PRODUCT NAME: Orange Drain Cleaner PRODUCT NUMBER: 0379 V - Reactivity Data STABILITY: Stable INCOMPATIBILITY: Strong oxidizers CONDITIONS TO AVOID: Excess heat and open flame. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may produce oxides of carbon. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: None VI - Health Hazard Data ROUTES OF ENTRY INHALATION: EYE CONTACT: X SKIN CONTACT: X INGESTION: X INGREDIENTS THAT ARE CONSIDERED BY OSHA, NTP, IARC TO BE SUSPECTED HUMAN CARCINOGENS: None EFFECTS OF OVEREXPOSURE IF IN EYES: Moderate to severe irritation, redness and possible tearing. IF ON SKIN: Irritation, chapping and dermatitis, with prolonged or repeated exposure. Contains a possible sensitizer. IF SWALLOWED: Nausea, cramps, diarrhea. Small amounts of this product aspirated into the respiratory system during ingestion or vomiting may cause mild to severe pulmonary injury, possibly progressing to death. IF INHALED: Irritation of the respiratory tract, coughing and headache. EMERGENCY AND FIRST AID PROCEDURES IF IN EYES: Flush eyes and under eyelids with plenty of cool water for at least 15 minutes. If irritation persists, obtain medical attention. IF ON SKIN: Remove contaminated clothing and launder separately before re-use. Wash with soap and water. If irritation persists, obtain medical attention. IF SWALLOWED: Call a physician or poison control center immediately. Do not induce vomiting. Rinse mouth with water, then drink one glass of water. Never give anything by mouth to an unconscious person. IF INHALED: Remove person to fresh air. If irritation persists, obtain medical attention. VII - Spill or Leak Protection STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Ventilate area and extinguish all sources of ignition. Contain spill. Soak up spilled material with inert absorbent material and place in properly labeled closed container for disposal. WASTE DISPOSAL METHOD: Consult local environmental authorities. VIII - Special Protection Information RESPIRATORY PROTECTION: Use with adequate ventilation. VENTILATION LOCAL: Recommended MECHANICAL: Not required PROTECTIVE GLOVES: Chemical resistant. EYE PROTECTION: Safety glasses or chemical goggles. OTHER PROTECTIVE EQUIPMENT: Protective clothing, eyewash station. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in a cool, dry place away from heat or open flame. Keep container tightly closed when not in use. OTHER PRECAUTIONS: Keep out of reach of children. IX - Transportation Information (ground transportation only) DOT PROPER SHIPPING NAME: None DOT CLASS: None DOT ID NUMBER: None DOT PACKING GROUP: None The shipping information listed above applies only to non-bulk (< 119 gallons) containers of this product. This product may have more than one proper shipping name depending on packaging, product properties, & mode of shipment. If any alteration of packaging, product, or mode of transportation is further intended, different shipping names and labeling may apply. DATE OF REVISION: January 16, 2006 Prepared by: Technical Dept. DATE OF ISSUE: January 16, 2006 This information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Total Solutions assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material such vendees or users assume all risks associated with the use of this material.