Material Safety Data Sheet Section 1. Product and Company Identification

Material Safety Data Sheet Section 1. Product and Company Identification
Material Safety Data Sheet
TITISTAR ® Hydrochloric Acid 6N
Section 1. Product and Company Identification
Product name
Product code
Synonym
Material uses
Manufacturer
Validation date
Print date
In case of emergency
:
:
:
:
:
TITISTAR ® Hydrochloric Acid 6N
HX0603M
None.
Other non-specified industry: Laboratory Reagent
EMD Chemicals Inc.
P.O. Box 70
480 Democrat Road
Gibbstown, NJ 08027
856-423-6300 Technical Service
Monday - Friday: 8:00 - 5:00 PM
: 8/14/2007.
: 8/14/2007.
: 800-424-9300 CHEMTREC (USA)
613-996-6666 CANUTEC (Canada)
24 Hours/Day: 7 Days/Week
Section 2. Hazards Identification
Physical state
Odor
OSHA/HCS status
Emergency overview
: Liquid. (Liquid.)
: Pungent.
: This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
: DANGER!
POISON!
MAY BE FATAL IF SWALLOWED.
CAUSES EYE AND SKIN BURNS.
HARMFUL IF INHALED.
CAUSES RESPIRATORY TRACT IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION.
MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS: LUNGS, RESPIRATORY
TRACT, SKIN, EYES, EYE, LENS OR CORNEA.
Do not ingest. Do not get in eyes or on skin or clothing. Avoid breathing vapor or mist.
Keep container closed. Use only with adequate ventilation. Wash thoroughly after
handling.
: Dermal contact. Inhalation. Ingestion.
Routes of entry
Potential acute health effects
Eyes
:
Skin
:
Inhalation
:
:
Ingestion
Carcinogenic effects
:
Mutagenic effects
:
Teratogenicity /
:
Reproductive toxicity
:
Medical conditions
aggravated by overexposure
Corrosive to eyes.
Corrosive to the skin. May cause sensitization by skin contact.
Toxic by inhalation. Irritating to respiratory system.
Very toxic if swallowed. May cause burns to mouth, throat and stomach.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Repeated skin exposure can produce local skin destruction or dermatitis. Repeated or
prolonged exposure to the substance can produce lung damage. Repeated or
prolonged contact with spray or mist may produce chronic eye irritation and severe skin
irritation. Repeated or prolonged exposure to the substance can produce target organs
damage.
See toxicological information (section 11)
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TITISTAR ® Hydrochloric Acid 6N
HX0603M
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Section 3. Composition/Information on Ingredients
United States
Name
Hydrochloric Acid
Water
CAS number
7647-01-0
7732-18-5
% by Weight
18.5
81.5
Section 4. First Aid Measures
Eye contact
Skin contact
Inhalation
Ingestion
Protection of first-aiders
: Get medical attention immediately. Immediately flush eyes with plenty of water for at
least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove
any contact lenses. Chemical burns must be treated promptly by a physician.
: Get medical attention immediately. Flush contaminated skin with plenty of water.
Continue to rinse for at least 10 minutes. Remove contaminated clothing and shoes.
Wash contaminated clothing thoroughly with water before removing or wear gloves.
Chemical burns must be treated promptly by a physician. Wash clothing before reuse.
Clean shoes thoroughly before reuse.
: Get medical attention immediately. Move exposed person to fresh air. If it is suspected
that fumes are still present, the rescuer should wear an appropriate mask or selfcontained breathing apparatus. Keep person warm and at rest. If not breathing, if
breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen
by trained personnel. It may be dangerous to the person providing aid to give mouthto-mouth resuscitation. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.
: Get medical attention immediately. Wash out mouth with water. Remove dentures if
any. Move exposed person to fresh air. Keep person warm and at rest. If material has
been swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the
head should be kept low so that vomit does not enter the lungs. Chemical burns must
be treated promptly by a physician. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or
waistband.
: No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing or wear gloves.
Section 5. Fire Fighting Measures
Flammability of the product : Combustible when exposed to heat or flame.
Products of combustion
: These products are carbon oxides (CO, CO 2), halogenated compounds, hydrogen
chloride.
Extinguishing media
Suitable
: Use an extinguishing agent suitable for the surrounding fire.
Not suitable
: None known.
Special exposure hazards
: Not available.
: Fire-fighters should wear appropriate protective equipment and self-contained breathing
Special protective
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
equipment for fire-fighters
Flammable
hydrogen gas may be produced on prolonged contact with metals such as
:
Special remarks on fire
aluminum,
tin,
lead and zinc. (Hydrochloric Acid )
hazards
: Development of hazardous combustion gases or vapors possible in the event of fire.
Special remarks on
explosion hazards
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TITISTAR ® Hydrochloric Acid 6N
HX0603M
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Section 6. Accidental Release Measures
Personal precautions
: Immediately contact emergency personnel. Keep unnecessary personnel away. Use
suitable protective equipment.
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Methods for cleaning up
: If emergency personnel are unavailable, contain spilled material. For small spills, add
absorbent (soil may be used in the absence of other suitable materials), scoop up
material and place in a sealable, liquid-proof container for disposal. For large spills, dike
spilled material or otherwise contain material to ensure runoff does not reach a
waterway. Place spilled material in an appropriate container for disposal.
Section 7. Handling and Storage
Handling
Storage
: Do not ingest. Do not get in eyes or on skin or clothing. Keep container closed. Use
only with adequate ventilation. Avoid breathing vapor or mist. Wash thoroughly after
handling.
: Keep container tightly closed. Keep container in a cool, well-ventilated area.
Section 8. Exposure Controls/Personal Protection
Product name
United States
Hydrochloric Acid
Exposure limits
ACGIH TLV (United States, 2003).
CEIL: 2 ppm
NIOSH REL (United States, 12/2001).
CEIL: 7 mg/m 3 Form: All forms
CEIL: 5 ppm Form: All forms
OSHA PEL (United States, 8/1997).
CEIL: 7 mg/m 3 Form: All forms
CEIL: 5 ppm Form: All forms
OSHA PEL 1989 (United States, 3/1989).
CEIL: 7 mg/m 3 Form: All forms
CEIL: 5 ppm Form: All forms
ACGIH TLV (United States, 1/2005). Notes: Refers to Appendix A -Carcinogens. ACGIH 2003 Adoption
CEIL: 2 ppm Form: All forms
Consult local authorities for acceptable exposure limits.
Engineering measures
: Use only with adequate ventilation. If user operations generate dust, fumes, vapor or
mist, use process enclosures, local exhaust ventilation or other engineering controls to
keep worker exposure to airborne contaminants below any recommended or statutory
limits.
Personal protection
Eyes
: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts.
Recommended: face shield
Skin
: Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling
this product.
Body: Recommended: Full suit. and gloves
Feet: Recommended: Boots.
Respiratory
: Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Recommended: Vapor respirator. Be sure to use an approved/certified respirator or
equivalent. Vapor respirator or self-contained breathing apparatus (SCBA).
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TITISTAR ® Hydrochloric Acid 6N
HX0603M
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Section 8. Exposure Controls/Personal Protection
Hands
Hygiene measures
: Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary.
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety showers
are close to the workstation location.
Section 9. Physical and Chemical Properties
Physical state
Color
Odor
Molecular formula
Boiling/condensation point
:
:
:
:
:
Melting/freezing point
:
Critical temperature
Relative density
Vapor pressure
Vapor density
Evaporation rate
:
:
:
:
:
Liquid. (Liquid.)
Clear.Colorless to slight yellow
Pungent.
HCL in Aqueous solution
The lowest known value is 99.9°C (211.8°F) (Water). Weighted average: 101.77°C
(215.2°F)
May start to solidify at -0.1°C (31.8°F) based on data for: Water. Weighted average:
-13.77°C (7.2°F)
The lowest known value is 51.5°C (124.7°F) (Hydrochloric Acid ).
The only known value is 1.2 (Water = 1) (Hydrochloric Acid ).
The highest known value is 21.3 kPa (160 mm Hg) (at 20°C) (Hydrochloric Acid ).
The highest known value is >1 (Air = 1) (Hydrochloric Acid ).
0.36 (Water) compared with(n-Butyl Acetate =1)
Section 10. Stability and Reactivity
Stability and reactivity
Incompatibility with various
substances
Hazardous decomposition
products
Hazardous polymerization
Conditions of reactivity
: The product is stable.
: Reactive or incompatible with the following materials: oxidizing materials, combustible
materials, organic materials, metals, acids and alkalis.
: These products are halogenated compounds, . Hydrogen chloride (HCl).
: Will not occur.
: Explosive in the presence of the following materials or conditions: metals.
Development of hazardous combustion gases or vapors possible in the event of fire.
Section 11. Toxicological Information
Toxicity data
United States
Product/ingredient name
Hydrochloric Acid
Result
Route
Species
900 mg/kg
Oral
Rabbit
1108 ppm (1
Inhalation
Mouse
hour/hours)
Chronic effects on humans : CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) by
ACGIH, 3 (Not classifiable for humans.) by IARC [Hydrochloric Acid ].
May cause damage to the following organs: lungs, upper respiratory tract, skin, eyes,
eye, lens or cornea.
Other toxic effects on
humans
Specific effects
Carcinogenic effects
Mutagenic effects
Test
LD50
LC50
: Extremely hazardous in case of eye contact (corrosive), of ingestion, .
Very hazardous in case of skin contact (corrosive), of inhalation (lung irritant).
Slightly hazardous in case of inhalation (lung sensitizer, lung corrosive).
: No known significant effects or critical hazards.
: No known significant effects or critical hazards.
Continued on Next Page
TITISTAR ® Hydrochloric Acid 6N
HX0603M
Page: 5/7
Section 11. Toxicological Information
Teratogenicity /
Reproductive toxicity
Sensitization
Ingestion
Inhalation
Eyes
Skin
: No known significant effects or critical hazards.
:
:
:
:
May cause burns to mouth, throat and stomach.
Irritating to respiratory system.
Corrosive to eyes.
Corrosive to the skin. May cause sensitization by skin contact.
Section 12. Ecological Information
Environmental precautions : No known significant effects or critical hazards.
Products of degradation
: These products are carbon oxides (CO, CO 2) and water, halogenated compounds.
Toxicity of the products of : The products of degradation are as toxic as the product itself.
biodegradation
Section 13. Disposal Considerations
: The generation of waste should be avoided or minimized wherever possible. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers. Disposal of this product, solutions and any by-products should at all times
comply with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements.
: Code: (C) (T)
Waste disposal
RCRA classification
Disposal should be in accordance with applicable regional, national and local laws and regulations. Local
regulations may be more stringent than regional or national requirements.
The information presented below only applies to the material as supplied. The identification based on
characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the
responsibility of the waste generator to determine the toxicity and physical properties of the material generated to
determine the proper waste identification and disposal methods in compliance with applicable regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.
Section 14. Transport Information
Regulatory
information
UN number
Proper shipping
name
Class
DOT Classification
UN1789
Hydrochloric Acid Soluton 8
PG* Label
Additional
information
II
Reportable quantity
5000 lbs. (2268 kg)
CORROSIVE
8
PG* : Packing group
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TITISTAR ® Hydrochloric Acid 6N
HX0603M
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Section 15. Regulatory Information
United States
HCS Classification
U.S. Federal regulations
: Highly toxic material
Corrosive material
Sensitizing material
Target organ effects
: TSCA 8(b) inventory: Listed
SARA 302/304/311/312 extremely hazardous substances: Hydrochloric Acid
SARA 302/304 emergency planning and notification: Hydrochloric Acid
SARA 302/304/311/312 hazardous chemicals: Hydrochloric Acid
SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
Hydrochloric Acid : Sudden release of pressure, Immediate (acute) health hazard,
Delayed (chronic) health hazard
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: Hydrochloric Acid
Clean Air Act (CAA) 112 accidental release prevention: Hydrochloric Acid
Clean Air Act (CAA) 112 regulated flammable substances: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: Hydrochloric Acid
SARA 313
Form R - Reporting
requirements
Supplier notification
Product name
: Hydrochloric Acid
CAS number
7647-01-0
Concentration
18.5
: Hydrochloric Acid
7647-01-0
18.5
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall
include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
: Pennsylvania RTK: Hydrochloric Acid : (environmental hazard, generic environmental
State regulations
hazard)
Massachusetts RTK: Hydrochloric Acid
New Jersey: Hydrochloric Acid 6N
Canada
: Class D-1A: Material causing immediate and serious toxic effects (Very toxic).
WHMIS (Canada)
Class D-2B: Material causing other toxic effects (Toxic).
Class E: Corrosive material
CEPA DSL/CEPA NDSL
: CEPA DSL: Hydrochloric Acid ; Water
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all the
information required by the CPR.
EU regulations
Hazard symbol/symbols
Risk phrases
Safety phrases
International regulations
International lists
:
: R36/37/38- Irritating to eyes, respiratory system and skin.
: S2- Keep out of the reach of children.
S46- If swallowed, seek medical advice immediately and show this container or label.
: Australia (NICNAS): Hydrochloric Acid ; Water
China: Hydrochloric Acid
Germany water class: Hydrochloric Acid
Japan (METI): Hydrochloric Acid ; Water
Korea (TCCL): Hydrochloric Acid ; Water
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TITISTAR ® Hydrochloric Acid 6N
HX0603M
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Section 15. Regulatory Information
Philippines (RA6969): Hydrochloric Acid ; Water
Section 16. Other Information
Label requirements
National Fire Protection
Association (U.S.A.)
: DANGER!
POISON!
MAY BE FATAL IF SWALLOWED.
CAUSES EYE AND SKIN BURNS.
HARMFUL IF INHALED.
CAUSES RESPIRATORY TRACT IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION.
MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS: LUNGS, RESPIRATORY
TRACT, SKIN, EYES, EYE, LENS OR CORNEA.
:
Flammability
0
0
Health 2
Instability
Special
Notice to reader
The statements contained herein are based upon technical data that EMD Chemicals Inc. believes to be reliable,
are offered for information purposes only and as a guide to the appropriate precautionary and emergency handling
of the material by a properly trained person having the necessary technical skills. Users should consider these
data only as a supplement to other information gathered by them and must make independent determinations of
suitability and completeness of information from all sources to assure proper use, storage and disposal of these
materials and the safety and health of employees and customers and the protection of the environment. EMD
CHEMICALS INC. MAKES NO REPRESENTATION OR WARRANTY OF ANY KIND, EXPRESS OR IMPLIED,
INCLUDING MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE, WITH RESPECT TO THE INFORMATION
HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS.
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