FOSROC NITOFLOR FC130 BASE SDS (NZ)

FOSROC NITOFLOR FC130 BASE SDS (NZ)
Safety Data Sheet
CS: 1.9.6
Page:
Infosafe No™
LQ36M
Issue Date : April 2014
1 of
7
ISSUED by PARCHEMN
Product Name :FOSROC NITOFLOR FC130 BASE
Classified as hazardous
1. Identification
GHS Product
Identifier
Company Name
FOSROC NITOFLOR FC130 BASE
Address
7 Lucca Road Wyong
NSW 2259 Australia
Tel: 02 4350 5000
Fax: 02 4351 2024
0800 154 666 (available 24/7)
Telephone/Fax
Number
Emergency phone
number
Recommended use of
the chemical and
restrictions on use
Other Information
Parchem Construction Supplies Pty Ltd (ABN 80 069 961 968)
Base component of water based epoxy flooring system.
Distributed in New Zealand by:
Concrete Plus
23 Watts Road
Sockburn
New Zealand
Tel: (03) 343 0090
Fax: (03) 343 0202
This SDS summarises at the date of issue our best knowledge of the health
and
safety hazard information of the product, and in particular how to safely
handle and use the product in the workplace. Since Parchem Construction
Supplies Pty Ltd cannot anticipate or control the conditions under which the
product may be used, each user must, prior to usage, review this MSDS in the
context of how the user intends to handle and use the product in the
workplace.
If clarification or further information is needed to ensure that an
appropriate assessment can be made, the user should contact this company.
Our responsibility for product as sold is subject to our standard terms and
conditions, a copy of which is sent to our customers and is also available
upon request.
www.parchem.co.nz
2. Hazard Identification
Classification of the
substance or mixture
Signal Word (s)
Hazard Statement
(s)
General
Precautionary
Statement (s)
Pictogram (s)
Print Date: 11/04/2014
Classified as Hazardous according to the Hazardous Substances (Minimum
Degrees of Hazard) Regulations 2001, New Zealand.
Classified as Dangerous Goods for transport according to the New Zealand
Standard NZS 5433:2012 Transport of Dangerous Goods on Land.
HSNO Classification:
6.3B - Substance that is mildly irritating to the skin
6.4A - Substance that is irritating to the eyes
6.5B - Substance that is a contact sensitiser
6.9B - Substance that is harmful to human target organs or systems (Repeated
exposure)
9.1B - Substance that is ecotoxic in the aquatic environment
Warning
H316 Causes mild skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H373 May cause damage to organs through prolonged or repeated exposure by
skin contact.
H411 Toxic to aquatic life with long lasting effects.
P103 Read label before use.
Health hazard, Exclamation mark, Environment
CS: 1.9.6
Safety Data Sheet
CS: 1.9.6
Page:
Infosafe No™
LQ36M
Issue Date : April 2014
2 of
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ISSUED by PARCHEMN
Product Name :FOSROC NITOFLOR FC130 BASE
Classified as hazardous
Precautionary
statement –
Prevention
Precautionary
statement –
Response
Precautionary
statement – Disposal
P260 Do not breathe dust/fume/mist/vapours.
P264 Wash contaminated skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face
protection.
GENERAL:
P314 Get medical advice/attention if you feel unwell.
P391 Collect spillage.
EYES:
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
SKIN:
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P363 Wash contaminated clothing before reuse.
P501 In the case of a substance that is in compliance with a HSNO approval
other than a Part 6A (Group Standards) approval, a label must provide a
description of one or more appropriate and achievable methods for the
disposal of a substance in accordance with the Hazardous Substances
(Disposal) Regulations 2001. This may also include any method of disposal
that must be avoided. See Section 13 for disposal details.
3. Composition/information on ingredients
Ingredients
Name
CAS
Proportion
Bisphenol A epichlorohydrin
C12-C14 Alkyl glycidyl
ether
Bisphenol F-epoxy
resin
Ingredients determined
not to be hazardous
25068-38-6
>60 %
68609-97-2
10-<30 %
9003-36-5
10-<30 %
Balance
4. First-aid measures
Inhalation
First Aid Facilities
If inhaled, remove affected person from contaminated area. Keep at rest
until recovered. If symptoms persist seek medical attention.
Do not induce vomiting. Wash out mouth thoroughly with water. Seek medical
attention.
Wash affected area thoroughly with soap and water. Remove contaminated
clothing and wash before reuse or discard. Seek medical attention.
If in eyes, hold eyelids apart and flush the eyes continuously with running
water. Continue flushing for several minutes until all contaminants are
washed out completely. Seek medical attention.
Eye wash, safety shower and normal washroom facilities.
Advice to Doctor
Treat symptomatically.
Other Information
For advice in an emergency, contact a Poisons Information Centre (Phone New
Zealand 0800 POISON / 0800 764 766) or a doctor at once.
Ingestion
Skin
Eye contact
5. Fire-fighting measures
Suitable
extinguishing media
Unsuitable
Extinguishing Media
Print Date: 11/04/2014
Use carbon dioxide, dry chemical or foam. Alcohol resistant foam is
preferred. If not available normal foam can be used.
Do not use water jet.
CS: 1.9.6
Safety Data Sheet
CS: 1.9.6
Page:
Infosafe No™
LQ36M
Issue Date : April 2014
3 of
7
ISSUED by PARCHEMN
Product Name :FOSROC NITOFLOR FC130 BASE
Classified as hazardous
Hazards from
Combustion
Products
Specific hazards
arising from the
chemical
Hazchem Code
Under fire conditions this product may emit toxic and/or irritating fumes
and gases including carbon dioxide, carbon monoxide and halogenated
compounds.
Decomposition
Temp.
Precautions in
connection with Fire
Not available
Combustible. This product will readily burn under fire conditions.
•3Z
Fire fighters should wear Self-Contained Breathing Apparatus (SCBA) operated
in positive pressure mode and full protective clothing to prevent exposure
to vapours or fumes. Water spray may be used to cool down heat-exposed
containers. Fight fire from safe location. This product should be prevented
from entering drains and watercourses.
6. Accidental release measures
Personal
precautions,
protective
equipment and
emergency
procedures
Wear appropriate personal protective equipment and clothing to prevent
exposure. Extinguish or remove all sources of ignition and stop leak if safe
to do so. Increase ventilation. Evacuate all unprotected personnel. If
possible contain the spill. Place inert absorbent, non-combustible material
onto spillage. Use clean non-sparking tools to collect the material and
place into suitable labelled containers for subsequent recycling or
disposal. Dispose of waste according to the applicable local and national
regulations. If contamination of sewers or waterways occurs inform the local
water and waste management authorities in accordance with local regulations.
7. Handling and storage
Precautions for Safe
Handling
Conditions for safe
storage, including
any
incompatabilities
Storage
Temperatures
Use only in a well ventilated area. Keep containers sealed when not in use.
Prevent the build up of mists or vapours in the work atmosphere. Avoid
inhalation of vapours and mists, and skin or eye contact. Do not use near
ignition sources. Do not pressurise, cut, heat or weld containers as they
may contain hazardous residues. Maintain high standards of personal hygiene
i.e. Washing hands prior to eating, drinking, smoking or using toilet
facilities.
Store in a cool, dry well-ventilated area away from heat, sources of
ignition, oxidising agents, foodstuffs, and clothing and out of direct
sunlight. Keep containers closed when not in use and securely sealed and
protected against physical damage. Inspect regularly for deficiencies such
as damage or leaks. Do NOT pressurise, cut, heat or weld containers as they
may contain hazardous residues. For information on the design of the
storeroom, reference should be made to Australian Standard AS1940 - The
storage and handling of flammable and combustible liquids. Reference should
also be made to all State and Federal regulations.
2-40°C
8. Exposure controls/personal protection
Occupational
exposure limit values
Biological Limit
Values
Appropriate
engineering controls
Respiratory
Protection
Eye Protection
Print Date: 11/04/2014
No exposure standards have been established for the mixture. However,
over-exposure to some chemicals may result in enhancement of pre-existing
adverse medical conditions and/or allergic reactions and should be kept to
the least possible levels.
No biological limits allocated.
Use with good general ventilation. If mists or vapours are produced local
exhaust ventilation should be used.
If engineering controls are not effective in controlling airborne exposure
then an approved respirator with a replaceable organic vapour filter should
be used. Reference should be made to Australian/New Zealand Standards
AS/NZS 1715, Selection, Use and Maintenance of Respiratory Protective
Devices; and AS/NZS 1716, Respiratory Protective Devices, in order to make
any necessary changes for individual circumstances.
Safety glasses with side shields or chemical goggles should be worn. Final
CS: 1.9.6
Safety Data Sheet
CS: 1.9.6
Page:
Infosafe No™
LQ36M
Issue Date : April 2014
4 of
7
ISSUED by PARCHEMN
Product Name :FOSROC NITOFLOR FC130 BASE
Classified as hazardous
Hand Protection
Body Protection
choice of appropriate eye/face protection will vary according to individual
circumstances. Eye protection devices should conform with Australian/New
Zealand Standard AS/NZS 1337 - Eye Protectors for Industrial Applications.
Wear gloves of impervious material such as butyl rubber or Ethyl Vinyl
Alcohol Laminate (EVAL) (> 8 hours breakthrough time). Final choice of
appropriate gloves will vary according to individual circumstances i.e.
methods of handling or according to risk assessments undertaken. Reference
should be made to AS/NZS 2161.1: Occupational protective gloves - Selection,
use and maintenance.
Suitable protective work wear, e.g. cotton overalls buttoned at neck and
wrist is recommended. Chemical resistant apron is recommended where large
quantities are handled.
9. Physical and chemical properties
Appearance
Clear liquid.
Colour
Light yellow
Odour
Characterisitc epoxy odour
Decomposition
Temperature
Melting Point
Not available
Boiling Point
>200°C
Solubility in Water
Insoluble (20°C)
Specific Gravity
1.12 (23°C)
pH
7 (approximate) (1:1 in water)
Vapour Pressure
0.00001 kPa (0.000075 mmHg) (room temperature)
Vapour Density
(Air=1)
Evaporation Rate
Not available
Odour Threshold
Not available
Viscosity
600-900 mPa.s (25°C)
Partition
Coefficient:
n-octanol/water
Flash Point
Not available
Flammability
Combustible Paste
Auto-Ignition
Temperature
Flammable Limits Lower
Flammable Limits Upper
Not available
Not available
Not available
>155°C (Pensky Martens Closed Cup) (DIN 51758)
Not available
Not available
10. Stability and reactivity
Reactivity
Reacts with incompatibles.
Chemical Stability
Stable under normal conditions of storage and handling.
Conditions to Avoid
Heat, flames and other ignition sources.
Incompatible
Materials
Hazardous
Decomposition
Products
Strong acids, bases and oxidising agents.
Print Date: 11/04/2014
Thermal decomposition may result in the release of toxic and/or irritating
fumes and gases including carbon dioxide, carbon monoxide and halogenated
compounds.
CS: 1.9.6
Safety Data Sheet
CS: 1.9.6
Page:
Infosafe No™
LQ36M
Issue Date : April 2014
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ISSUED by PARCHEMN
Product Name :FOSROC NITOFLOR FC130 BASE
Classified as hazardous
Hazardous
Polymerization
Under normal conditions of storage and use, hazardous reactions will not
occur.
11. Toxicological Information
Toxicology
Information
Acute Toxicity Oral
Acute Toxicity Dermal
Ingestion
Inhalation
Skin
Eye
Respiratory
sensitisation
Skin Sensitisation
No toxicity data are available for this specific product. The available data
for the ingredients are as follows:
Bisphenol A - epichlorohydrin:
LD50 (Rat): >2,000 mg/kg
Bisphenol A - epichlorohydrin:
LD50 (Rabbit): >2,000 mg/kg
Ingestion of this product may irritate the gastric tract causing nausea and
vomiting.
Inhalation of product vapours may cause irritation of the nose, throat and
respiratory system.
Causes mild skin irritation. Skin contact will cause redness, itching and
swelling. Repeated exposure may cause skin dryness and cracking and may lead
to dermatitis. May cause an allergic skin reaction.
Causes serious eye irritation. On eye contact this product will cause
tearing, stinging, blurred vision, and redness.
Not expected to be a respiratory sensitiser.
May cause an allergic skin reaction.
Germ cell
mutagenicity
Carcinogenicity
Not considered to be a mutagenic hazard.
Reproductive
Toxicity
STOT-single
exposure
STOT-repeated
exposure
Aspiration Hazard
Not considered to be toxic to reproduction.
Not considered to be a carcinogenic hazard.
Not expected to cause damage to organs.
May cause damage to organs through prolonged or repeated exposure by skin
contact.
Not expected to be an aspiration hazard.
12. Ecological information
Ecotoxicity
Toxic to aquatic life with long lasting effects.
Persistence and
degradability
Mobility
Not available
Bioaccumulative
Potential
Other Adverse
Effects
Environmental
Protection
Acute Toxicity - Fish
Not available
Acute Toxicity Daphnia
LC50 (Daphnia magna straus 1820): 3.6 mg/L/24h
Not available
Not available
Do not discharge this material into waterways, drains and sewers.
LC50(Rainbow trout): 2.4 mg/L/96h
13. Disposal considerations
Disposal
Considerations
Print Date: 11/04/2014
Product Disposal:
Product wastes are controlled wastes and should be disposed of in accordance
with all applicable local and national regulations. This product can be
disposed through a licensed commercial waste collection service. It can be
disposed by burning in an approved high temperature incineration facility;
or alternatively, it can be reacted with the base component to enable it to
cure to an inert solid that can be disposed in a licensed landfill facility.
Personal protective clothing and equipment as specified in Section 8 of this
SDS must be worn during handling and disposal of this product. The
CS: 1.9.6
Safety Data Sheet
CS: 1.9.6
Page:
Infosafe No™
LQ36M
Issue Date : April 2014
6 of
7
ISSUED by PARCHEMN
Product Name :FOSROC NITOFLOR FC130 BASE
Classified as hazardous
ventilation requirements as specified in the same section must also be
followed, and the precautions given in Section 7 of this SDS regarding
handling must also be followed.
Do not dispose into the sewerage system. Do not discharge into drains or
watercourses or dispose where ground or surface waters may be affected.
In New Zealand, the disposal agency or contractor must comply with the New
Zealand Hazardous Substances (Disposal) Regulations 2001. Further details
regarding disposal can be obtained on the ERMA New Zealand website under
specific group standards.
Container Disposal:
The container or packaging must be cleaned and rendered incapable of holding
any substance. It can then be disposed of in a manner consistent with that
of the substance it contained. In this instance the packaging can be
disposed through a commercial waste collection service.
Alternatively, the container or packaging can be recycled if the hazardous
residues have been thoroughly cleaned or rendered non-hazardous.
In New Zealand, the packaging (that may or may not hold any residual
substance) that is lawfully disposed of by householders or other consumers
through a public or commercial waste collection service is a means of
compliance with regulations.
14. Transport information
Transport
Information
Road and Rail Transport:
This material is classified as a Class 9 - Miscellaneous Substances
according to NZS 5433:2012 Transport of Dangerous Goods on Land.
Must not be loaded in the same freight container or on the same vehicle
with:
- Class 1, Explosives
Class 9 dangerous goods that contain organic matter must not be loaded in
the same bulk container or tankwagon with dangerous goods of Division 5.1
unless the Class 9 and Division 5.1 dangerous goods are in separate
compartments of a bulk container or tankwagon.
Goods of packing group II or III may be loaded in the same freight container
or on the same vehicle if transported in segregation devices. Segregation
devices may be used to segregate Dangerous goods of Class 9 when the nature
of those dangerous goods requires them to be segregated from dangerous goods
of Class 3, 4, 5, 6 or 8 or from food items.
Marine Transport (IMO/IMDG):
Classified as Dangerous Goods by the criteria of the International Maritime
Dangerous Goods Code (IMDG Code) for transport by sea.
UN No.: 3082
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Contains Bisphenol A Epichlorohydrin)
DG Class: 9
Packaging Group: III
EMS No.: F-A, S-F
Special provisions: 274, 335
U.N. Number
Print Date: 11/04/2014
Air Transport (ICAO/IATA):
Classified as Dangerous Goods by the criteria of the International Air
Transport Association (IATA) Dangerous Goods Regulations for transport by
air.
UN No: 3082
Proper Shipping Name: : Environmentally hazardous substance, liquid, n.o.s.
(Contains Bisphenol A Epichlorohydrin)
Class: 9
Packing Group: III
Label: Miscellaneous
Packing Instruction: 964 (For passenger and cargo aircraft)
Packing Instruction: 964 (For cargo aircraft only)
Special provisions: A97, A158
3082
CS: 1.9.6
Safety Data Sheet
CS: 1.9.6
Page:
Infosafe No™
LQ36M
Issue Date : April 2014
7 of
7
ISSUED by PARCHEMN
Product Name :FOSROC NITOFLOR FC130 BASE
Classified as hazardous
UN proper shipping
name
Transport hazard
class(es)
Hazchem Code
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. - (Contains Bisphenol A
Epichlorohydrin)
9
Packing Group
III
EPG Number
9C1
IERG Number
47
IMDG Marine
pollutant
Yes
•3Z
15. Regulatory information
Regulatory
Information
HSNO Approval
Number
Classified as Hazardous according to the New Zealand Hazardous Substances
(Minimum Degrees of Hazard) Regulations 2001.
Group Standard:
Construction Products (Subsidiary Hazard) Group Standard 2006
HSR002544
16. Other Information
Date of preparation
or last revision of
SDS
Literature
References
Contact
Person/Point
SDS Created: April 2014
Workplace Exposure Standards and Biological Exposure Indices , Department of
Labour, Health & Safety.
Transport of Dangerous goods on land NZS 5433.
Preparation of Safety Data Sheets - Approved Code of Practice Under the HSNO
Act 1996 (HSNO CoP 8-1 09-06).
Assigning a hazardous substance to a group standard.
American Conference of Industrial Hygienists (ACGIH).
Technical Support: 1800 812 864
...End Of MSDS...
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Print Date: 11/04/2014
CS: 1.9.6
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