B C Page : 1 MATERIAL SAFETY DATA SHEET Revised edition no : 5 Date : 8 / 11 / 2012 Supersedes : 24 / 10 / 2012 Nitric oxide Danger AL187 ÁM M œM »M « SECTION 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name SDS Nr Chemical formula : Nitric oxide : AL187 : NO 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use : Industrial and professional. Perform risk assessment prior to use. Test gas / Calibration gas. Laboratory use Contact supplier for more uses information : Chemical reagent. 1.3. Details of the supplier of the safety data sheet Company identification : Air Liquide Australia Limited Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia Tel: + 61 3 9697 9888 Fax: + 61 3 9690 7107 [email protected] 1.4. Emergency telephone number Emergency telephone number : 1800 812 588 SECTION 2. Hazards identification 2.1. Classification of the substance or mixture Hazard Class and Category Code Regulation EC 1272/2008 (CLP) R Phrase(s) • Health hazards • Physical hazards : R8 : Contact with combustible material may cause fire. - R26 : Very toxic by inhalation. R34 : Causes burns. : Acute toxicity, Inhalation - Category 1 - Danger - (CLP : Acute Tox. 1) - H330 Skin corrosion - Category 1B - Danger - (CLP : Skin Corr. 1B) - H314 : Oxidizing gases - Category 1 - Danger - (CLP : Ox. Gas 1) - H270 Gases under pressure - Compressed gas - Warning - (CLP : Press. Gas) - H280 Classification EC 67/548 or EC 1999/45 : O; R8 T+; R26 C; R34 2.2. Label elements Labelling Regulation EC 1272/2008 (CLP) • Hazard pictograms • Hazard pictograms code • Signal word • Hazard statements Á M M œ M » M « : GHS06 - GHS03 - GHS05 - GHS04 : Danger : H270 - May cause or intensify fire; oxidizer. H280 - Contains gas under pressure; may explode if heated. H330 - Fatal if inhaled. H314 - Causes severe skin burns and eye damage. Air Liquide Australia Limited Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia Tel: + 61 3 9697 9888 Fax: + 61 3 9690 7107 [email protected] In case of emergency : 1800 812 588 B C Page : 2 MATERIAL SAFETY DATA SHEET Revised edition no : 5 Date : 8 / 11 / 2012 Supersedes : 24 / 10 / 2012 Nitric oxide AL187 SECTION 2. Hazards identification (continued) • Precautionary statements - Prevention : P260 - Do not breathe gas, vapours. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P244 - Keep valves and fittings free from oil and grease P220 - Keep away from combustible materials. : P304+P340+P315 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get immediate medical advice / attention. P305+P351+P338+P315 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice / attention. P303+P361+P353+P315 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Get immediate medical advice / attention. P370+P376 - In case of fire : Stop leak if safe to do so. : P403 - Store in a well-ventilated place. P405 - Store locked up. - Response - Storage 2.3. Other hazards : None. SECTION 3. Composition/information on ingredients 3.1. Substance / 3.2. Mixture Substance. Substance name Nitric oxide : Contents 100 % CAS No 10102-43-9 EC No 233-271-0 Annex No ----- Classification *2 O; R8 T+; R26 C; R34 ---------------------------------Acute Tox. 1 (H330) Ox. Gas 1 (H270) Skin Corr. 1B (H314) EUH071 Press. Gas (H280) Contains no other components or impurities which will influence the classification of the product. * 1: Listed in Annex IV / V REACH, exempted from registration. * 2: Registration deadline not expired. * 3: Registration not required: Substance manufactured or imported < 1t/y Full text of R-phrases see chapter 16. Full text of H-statements see chapter 16 SECTION 4. First aid measures 4.1. Description of first aid measures First aid measures - Inhalation - Skin/eye contact - Skin contact - Eye contact - Ingestion : Fatal if inhaled. Delayed adverse effects possible. Prolonged exposure to small concentrations may result in pulmonary oedema. Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep victim warm and rested. Call a doctor. Apply artificial respiration if breathing stopped. : May cause chemical burns to skin and cornea (with temporary disturbance to vision). Immediately flush eyes thoroughly with water for at least 15 minutes. Remove contaminated clothing. Drench affected area with water for at least 15 minutes. Obtain medical assistance. : Adverse effects not expected from this product. : Adverse effects not expected from this product. : Ingestion is not considered a potential route of exposure. 4.2. Most important symptoms and effects, both acute and delayed : Refer to section 11. Air Liquide Australia Limited Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia Tel: + 61 3 9697 9888 Fax: + 61 3 9690 7107 [email protected] In case of emergency : 1800 812 588 B C Page : 3 MATERIAL SAFETY DATA SHEET Revised edition no : 5 Date : 8 / 11 / 2012 Supersedes : 24 / 10 / 2012 Nitric oxide AL187 SECTION 4. First aid measures (continued) 4.3. Indication of any immediate medical attention and special treatment needed : None. SECTION 5. Fire-fighting measures 5.1. Extinguishing media Extinguishing media - Suitable extinguishing media : All known extinguishants can be used. 5.2. Special hazards arising from the substance or mixture Specific hazards Hazardous combustion products : Supports combustion. Exposure to fire may cause containers to rupture/explode. : None that are more toxic than the product itself. 5.3. Advice for fire-fighters Specific methods Special protective equipment for fire fighters : If possible, stop flow of product. Coordinate fire measure to the surrounding fire. Cool endangered containers with water spray jet from a protected position. Do not empty contaminated fire water into drains. Move away from the container and cool with water from a protected position. : Use self-contained breathing apparatus and chemically protective clothing. SECTION 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions : Evacuate area. Ensure adequate air ventilation. Use self-contained breathing apparatus and chemically protective clothing. 6.2. Environmental precautions : None. : Try to stop release. Reduce vapour with fog or fine water spray. Prevent from entering sewers, basements and workpits, or any place where its accumulation can be dangerous. 6.3. Methods and material for containment and cleaning up Clean up methods : None. : Ventilate area. Wash contaminated equipment or sites of leaks with copious quantities of water. Hose down area with water. 6.4. Reference to other sections : See also sections 8 and 13. SECTION 7. Handling and storage 7.1. Precautions for safe handling Safe use of the product : Use only properly specified equipment which is suitable for this product, its supply pressure and temperature. Contact your gas supplier if in doubt. Only experienced and properly instructed persons should handle gases under pressure. The product must be handled in accordance with good industrial hygiene and safety procedures. Do not smoke while handling product. Ensure the complete gas system was (or is regularily) checked for leaks before use. Air Liquide Australia Limited Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia Tel: + 61 3 9697 9888 Fax: + 61 3 9690 7107 [email protected] In case of emergency : 1800 812 588 B C Page : 4 MATERIAL SAFETY DATA SHEET Revised edition no : 5 Date : 8 / 11 / 2012 Supersedes : 24 / 10 / 2012 Nitric oxide AL187 SECTION 7. Handling and storage (continued) Safe handling of the gas receptacle Handling : Refer to supplier's container handling instructions. Do not allow backfeed into the container. Protect cylinders from physical damage; do not drag, roll, slide or drop. When moving cylinders, even for short distances, use a cart (trolley, hand truck, etc.) designed to transport cylinders. Leave valve protection caps in place until the container has been secured against either a wall or bench or placed in a container stand and is ready for use. If user experiences any difficulty operating cylinder valve discontinue use and contact supplier. Never attempt to repair or modify container valves or safety relief devices. Damaged valves should be reported immediately to the supplier. Keep container valve outlets clean and free from contaminates particularly oil and water. Replace valve outlet caps or plugs and container caps where supplied as soon as container is disconnected from equipment. Close container valve after each use and when empty, even if still connected to equipment. Never attempt to transfer gases from one cylinder/container to another. Never use direct flame or electrical heating devices to raise the pressure of a container. Do not remove or deface labels provided by the supplier for the identification of the cylinder contents. : Use only properly specified equipment which is suitable for this product, its supply pressure and temperature. Contact your gas supplier if in doubt. Open valve slowly to avoid pressure shock. Refer to supplier's container handling instructions. Use no oil or grease. Do not allow backfeed into the container. Suck back of water into the container must be prevented. 7.2. Conditions for safe storage, including any incompatibilities Storage : Keep away from combustible materials. Keep container below 50°C in a well ventilated plac e. Observe all regulations and local requirements regarding storage of containers. Containers should not be stored in conditions likely to encourage corrosion. Containers should be stored in the vertical position and properly secured to prevent toppling. Stored containers should be periodically checked for general condition and leakage. Container valve guards or caps should be in place. Store containers in location free from fire risk and away from sources of heat and ignition. : Segregate from flammable gases and other flammable materials in store. Keep container below 50°C in a well ventilated plac e. 7.3. Specific end use(s) : None. SECTION 8. Exposure controls/personal protection 8.1. Control parameters Occupational Exposure Limits Nitric oxide : : : : : : : : : : : : TLV© -TWA [ppm] : 25 LTEL - UK [ppm] : 25 STEL - UK [ppm] : 35 VME - France [mg/m³] : 30 VME - France [ppm] : 25 MAK (AU) Tagesmittelwert (ml/m³) : 25 MAK (AU) Tagesmittelwert (mg/m³) : 30 VLA-ED - Spain [ppm] : 25 VLA-ED - Spain [mg/m3] : 31 NGV - [ppm] : 25 NGV - [mg/m³] : 30 KTV - [ppm] : 50 Air Liquide Australia Limited Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia Tel: + 61 3 9697 9888 Fax: + 61 3 9690 7107 [email protected] In case of emergency : 1800 812 588 B C Page : 5 MATERIAL SAFETY DATA SHEET Revised edition no : 5 Date : 8 / 11 / 2012 Supersedes : 24 / 10 / 2012 Nitric oxide AL187 SECTION 8. Exposure controls/personal protection (continued) DNEL: Derived no effect level PNEC: Predicted no effect concentration : : : : : : : : : : : : : : : KTV - [mg/m³] : 50 Grænserværdier (DK) (ppm) : 0.25 Grænserværdier (DK) (ppm) : 25 HTP-värden (FI) - 8 H - [ppm] : 3 HTP-värden (FI) - 8 H - [mg/m³] : 5.7 HTP-värden - 15min - [ppm] : 6 Grænserværdier (DK) : 30 HTP-värden - 15min - [mg/m³] : 11 GV Value Limit (Norway) [ppm] : 25 GV Value Limit (Norway) [mg/m³] : 30 8-Hour TWA (PL) (NDS) (mg/m³) : 3.5 15-Minute STEL (PL)(NDSCh) (mg/m³) : 7 TLV-TWA (Belgium) (ppm) : 25 None available. None available. 8.2. Exposure controls : Systems under pressure shoud be regularily checked for leakages. Provide adequate general and local exhaust ventilation. Consider work permit system e.g. for maintenance activities. 8.2.2. Individual protection measures, : A risk assessment should be conducted and documented in each work area to assess the risks related to the use of the product and to select the PPE that matches the relevant risk. e.g. personal protective equipment The following recommendations should be considered. Wear safety glasses with side shields Wear leather safety gloves and safety shoes when handling cylinders. : Keep suitable chemically resistant protective clothing readily available for emergency use. Personal protection Keep self contained breathing apparatus readily available for emergency use. Do not smoke while handling product. Ensure adequate ventilation. : Refer to local regulations for restriction of emissions to the atmosphere. See section 13 for 8.2.3. Environmental exposure specific methods for waste gas treatment. controls 8.2.1. Appropriate engineering controls SECTION 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance - Physical state at 20°C / 101.3kPa - Colour Odour Odour threshold pH value Molar mass [g/mol] Melting point [°C] Boiling point [°C] Critical temperature [°C] Flash point [°C] Evaporation rate (ether=1) Flammability range [vol% in air] Vapour pressure [20°C] Relative density, gas (air=1) : : : : : : : : : : : : : Gas. Colourless gas. Poor warning properties at low concentrations. Odour threshold is subjective and inadequate to warn for overexposure. Not applicable for gas-mixtures. Not applicable for gases and gas-mixtures. -164 -152 -93 Not applicable for gas-mixtures. Not applicable for gas-mixtures. Oxidiser. Not applicable. Not applicable. : 1 Air Liquide Australia Limited Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia Tel: + 61 3 9697 9888 Fax: + 61 3 9690 7107 [email protected] In case of emergency : 1800 812 588 B C Page : 6 MATERIAL SAFETY DATA SHEET Revised edition no : 5 Date : 8 / 11 / 2012 Supersedes : 24 / 10 / 2012 Nitric oxide AL187 SECTION 9. Physical and chemical properties (continued) Relative density, liquid (water=1) Solubility in water [mg/l] Partition coefficient n-octanol/water Auto-ignition temperature [°C] Viscosity at 20°C [mPa.s] Explosive Properties : : : : : : 1.3 67 Not applicable for gas-mixtures. Not applicable. Not applicable. Not applicable. 9.2. Other information Other data Molecular weight : Gas/vapour heavier than air. May accumulate in confined spaces, particularly at or below ground level. : 30 SECTION 10. Stability and reactivity 10.1. Reactivity Stability and reactivity : No reactivity hazard other than the effects described in sub-sections below. : Violently oxidises organic material. Decomposes at room temperature to other nitrogen oxides and nitrogen. Oxidises in air to form nitrogen dioxide which is extremely reactive. May react violently with reducing agents. May react violently with combustible materials. 10.2. Chemical stability : Stable under normal conditions. 10.3. Possibility of hazardous reactions : None. 10.4. Conditions to avoid : Decomposes at room temperature to other nitrogen oxides and nitrogen. Oxidises in air to form nitrogen dioxide which is extremely reactive. 10.5. Incompatible materials : May react violently with reducing agents. Keep away from clothing and other combustible materials. Violently oxidises organic material. 10.6. Hazardous decomposition products : Decomposes at room temperature to other nitrogen oxides and nitrogen. Oxidises in air to form nitrogen dioxide which is extremely reactive. SECTION 11. Toxicological information 11.1. Information on toxicological effects Toxicity information Acute toxicity Rat inhalation LC50 [ppm/4h] LC50 [ppm/1h] Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Carcinogenicity Germ cell mutagenicity : Delayed fatal pulmonary oedema possible. Severe corrosion to skin, eyes and respiratory tract at high concentrations. : No known toxicological effects from this product. : • Nitric oxide : 57.5 : 115 : No known effects from this product. : No known effects from this product. : No known effects from this product. : No known effects from this product. : No known effects from this product. Air Liquide Australia Limited Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia Tel: + 61 3 9697 9888 Fax: + 61 3 9690 7107 [email protected] In case of emergency : 1800 812 588 B C Page : 7 MATERIAL SAFETY DATA SHEET Revised edition no : 5 Date : 8 / 11 / 2012 Supersedes : 24 / 10 / 2012 Nitric oxide AL187 SECTION 11. Toxicological information (continued) Toxic for reproduction : Fertility Toxic for reproduction : unborn child STOT-single exposure STOT-repeated exposure Aspiration hazard : : : : : No known effects from this product. No known effects from this product. No known effects from this product. No known effects from this product. Not applicable for gases and gas-mixtures. SECTION 12. Ecological information 12.1. Toxicity : No data available. 12.2. Persistence - degradability : No data available. 12.3. Bioaccumulative potential : No data available. 12.4. Mobility in soil : No data available. 12.5. Results of PBT and vPvB assessment : No data available. 12.6. Other adverse effects Ecological effects information : May cause pH changes in aqueous ecological systems. SECTION 13. Disposal considerations 13.1. Waste treatment methods General : May be vented to atmosphere in a well ventilated place. Do not discharge into any place where its accumulation could be dangerous. Refer to the code of practice of EIGA (Doc. 30/10 “Disposal of Gases, downloadable at http:// www.eiga.org) for more guidance on suitable disposal methods Contact supplier if guidance is required. : Avoid discharge to atmosphere. Gas may be scrubbed in alkaline solution under controlled conditions to avoid violent reaction. Do not discharge into any place where its accumulation could be dangerous. Contact supplier if guidance is required. 13.2. Additional information : None. SECTION 14. Transport information UN number Labelling ADR, IMDG, IATA : 1660 o ó J Ñ { : 2.3 : Toxic gas. 5.1 : Oxidizing substances. 8 : Corrosive substance. Land transport (ADR/RID) Air Liquide Australia Limited Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia Tel: + 61 3 9697 9888 Fax: + 61 3 9690 7107 [email protected] In case of emergency : 1800 812 588 B C Page : 8 MATERIAL SAFETY DATA SHEET Revised edition no : 5 Date : 8 / 11 / 2012 Supersedes : 24 / 10 / 2012 Nitric oxide AL187 SECTION 14. Transport information (continued) H.I. nr UN proper shipping name Transport hazard class(es) Classification code Packing Instruction(s) HAZCHEM - Emergency Action Code : : : : : : : -NITRIC OXIDE, COMPRESSED 2 1 TOC P200 2PE 2 = Fine water spray. P = Risk of violent reaction or explosion. Recommended personal protective equipment : Liquid-tight chemical protective clothing and breathing apparatus. Appropriate measures : dilute. E = There may be a public safety hazard outside the immediate area of the incident, and that the following actions should be considered : 1. People should be warned to stay indoors with all doors and windows closed, preferably in rooms upstairs and facing away from the incident. Ignition sources should be eliminated and any ventilation stopped. 2. Effects may spread beyond the immediate vicinity. all non-essential personnel should be instructed to move at least 250 metres away from the incident. 3. Police and fire brigade incident commanders should consult each other and with a product expert, or with a source of product expertise. 4. The possible need for subsequent evacuation should be considered, but it should be remembered that in most cases it will be safer to remain in a building than to evacuate. : : : : : NITRIC OXIDE, COMPRESSED 2.3 F-C S-W P200 : : : : NITRIC OXIDE, COMPRESSED 2.3 DO NOT LOAD IN PASSENGER AIRCRAFT. FORBIDDEN. Sea transport (IMDG) Proper shipping name Class Emergency Schedule (EmS) - Fire Emergency Schedule (EmS) - Spillage Packing instruction Air transport (ICAO-TI / IATA-DGR) Proper shipping name (IATA) Class Passenger and Cargo Aircraft Cargo Aircraft only Special precautions for user Labelling ADR Other transport information : Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before transporting product containers : - Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure cylinder valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided) is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted. : 2.3 : Toxic gas. 5.1 : Oxidizing substances. 8 : Corrosive substance. : Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before transporting product containers : - Ensure that containers are firmly secured. - Ensure cylinder valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided) is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted. - Ensure there is adequate ventilation. - Compliance with applicable regulations. Air Liquide Australia Limited Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia Tel: + 61 3 9697 9888 Fax: + 61 3 9690 7107 [email protected] In case of emergency : 1800 812 588 B C Page : 9 MATERIAL SAFETY DATA SHEET Revised edition no : 5 Date : 8 / 11 / 2012 Supersedes : 24 / 10 / 2012 Nitric oxide AL187 SECTION 14. Transport information (continued) SECTION 15. Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture EU legislation Seveso directive 96/82/EC : Not covered. National legislation : Ensure all national/local regulations are observed. 15.2. Chemical Safety Assessment : A CSA does not need to be carried out for this product. SECTION 16. Other information : Revised safety data sheet in accordance with commisssion regulation (EU) No 453/2010 : Receptacle under pressure. Ensure all national/local regulations are observed. Ensure operators understand the toxicity hazard. Users of breathing apparatus must be trained. List of full text of R-phrases in section : R8 : Contact with combustible material may cause fire. R26 : Very toxic by inhalation. 3. R34 : Causes burns. : EUH071 - Corrosive to respiratory tract. List of full text of H-statements in H270 - May cause or intensify fire; oxidizer. section 3. H280 - Contains gas under pressure; may explode if heated. H314 - Causes severe skin burns and eye damage. H330 - Fatal if inhaled. : Classification in accordance with calculation methods of regulation (EC) 1272/2008 CLP / ( Further information EC) 1999/45 DPD. This Safety Data Sheet has been established in accordance with the applicable European Union legislation. : This Safety Data Sheet has been established in accordance with the applicable European Note Union legislation. : Before using this product in any new process or experiment, a thorough material compatibility DISCLAIMER OF LIABILITY and safety study should be carried out. Details given in this document are believed to be correct at the time of going to press. Whilst proper care has been taken in the preparation of this document, no liability for injury or damage resulting from its use can be accepted. Indication of changes Training advice The contents and format of this SDS are in accordance with EC Commission Directive 2001/58/EC. DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. End of document Air Liquide Australia Limited Level 9 / 380 St. Kilda Road Melbourne VIC 3004 Australia Tel: + 61 3 9697 9888 Fax: + 61 3 9690 7107 [email protected] In case of emergency : 1800 812 588
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