MSDS Sheets
Product:
FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Effective Date: 03/16/10
NOTICE
The Material Safety Data Sheet information for the two component FROTH-PAK(TM) Sealant
200HFC Kit CDN is contained in two separate datasheets; one for the isocyanate and one for the
polyol. When printing or filing, please be sure to include both documents.
®(™)*Trademark of The Dow Chemical Company
1 of 30
Material Safety Data Sheet
The Dow Chemical Company
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Effective Date: 03/16/10
The Dow Chemical Company encourages and expects you to read and understand the entire
(M)SDS, as there is important information throughout the document. We expect you to follow the
precautions identified in this document unless your use conditions would necessitate other
appropriate methods or actions.
1.
Product and Company Identification
Product Name
Polyurethane System - Isocyanate
COMPANY IDENTIFICATION
The Dow Chemical Company
2030 Willard H. Dow Center
Midland, MI 48674
USA
For MSDS updates and Product Information:
Prepared By:
Revision
Print Date:
800-258-2436
Prepared for use in Canada by EH&S, Hazard Communications.
2010.02.25
7/13/2011
Customer Information Number:
800-258-2436
EMERGENCY TELEPHONE NUMBER
24-Hour Emergency Contact:
Local Emergency Contact:
989-636-4400
989-636-4400
2.
Hazards Identification
Emergency Overview
Color: Brown
Physical State: Liquid.
Odor: Musty
®(™)*Trademark of The Dow Chemical Company
2 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Effective Date: 03/16/10
Hazards of product:
WARNING! May cause eye irritation. May cause skin irritation. May cause allergic
skin reaction. May cause allergic respiratory reaction. Vapor reduces oxygen
available for breathing. May cause central nervous system effects. Keep upwind of
spill. May cause anesthetic effects. May cause respiratory tract irritation. May cause
lung injury. May react with water. Stay out of low areas. Material reacts slowly with
water, releasing carbon dioxide which can cause pressure buildup and rupture of
closed containers. Elevated temperatures accelerate this reaction. Toxic fumes may
be released in fire situations. Contents under pressure.
Potential Health Effects
Eye Contact: May cause moderate eye irritation. May cause slight temporary corneal injury.
Skin Contact: Prolonged contact may cause skin irritation with local redness. May stain skin.
Skin Absorption: Prolonged skin contact is unlikely to result in absorption of harmful amounts.
Skin Sensitization: Skin contact may cause an allergic skin reaction. Animal studies have
shown that skin contact with isocyanates may play a role in respiratory sensitization.
Inhalation: In confined or poorly ventilated areas, vapor can easily accumulate and can cause
unconsciousness and death due to displacement of oxygen. Excessive exposure may cause
irritation to upper respiratory tract (nose and throat) and lungs. May cause pulmonary edema
(fluid in the lungs.) Effects may be delayed. Decreased lung function has been associated with
overexposure to isocyanates. Excessive exposure may increase sensitivity to epinephrine and
increase myocardial irritability (irregular heartbeats). May cause central nervous system effects.
Symptoms of excessive exposure may be anesthetic or narcotic effects; dizziness and
drowsiness may be observed.
Respiratory Sensitization: May cause allergic respiratory response. MDI concentrations below
the exposure guidelines may cause allergic respiratory reactions in individuals already sensitized.
Asthma-like symptoms may include coughing, difficult breathing and a feeling of tightness in the
chest. Occasionally, breathing difficulties may be life threatening.
Ingestion: Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal
handling operations are not likely to cause injury; however, swallowing larger amounts may cause
injury. Observations in animals include: Gastrointestinal irritation.
Aspiration hazard: Based on available information, aspiration hazard could not be determined.
Effects of Repeated Exposure: Tissue injury in the upper respiratory tract and lungs has been
observed in laboratory animals after repeated excessive exposures to MDI/polymeric MDI
aerosols.
Cancer Information: Lung tumors have been observed in laboratory animals exposed to
respirable aerosol droplets of MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred
concurrently with respiratory irritation and lung injury. Current exposure guidelines are expected
to protect against these effects reported for MDI.
Birth Defects/Developmental Effects: In laboratory animals, MDI/polymeric MDI did not cause
birth defects; other fetal effects occurred only at high doses which were toxic to the mother.
Based on information for component(s): 1,1,1,2-Tetrafluoroethane. Has been toxic to the fetus in
laboratory animals at doses toxic to the mother.
®(™)*Trademark of The Dow Chemical Company
3 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
3.
Composition/information on ingredients
Component
CAS #
Diphenylmethane Diisocyanate, isomers and
9016-87-9
homologues
4,4' -Methylenediphenyl diisocyanate
101-68-8
1,1,1,2-Tetrafluoroethane
811-97-2
Amounts are presented as percentages by weight.
Note: CAS 101-68-8 is an MDI isomer that is part of CAS 9016-87-9.
4.
Effective Date: 03/16/10
Amount
W/W
>= 60.0 - <= 100.0 %
>= 30.0 - <= 60.0 %
>= 5.0 - <= 10.0 %
First-aid measures
Eye Contact: Immediately flush eyes with water; remove contact lenses, if present, after the first
5 minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without
delay, preferably from an ophthalmologist. Eye wash fountain should be located in immediate
work area.
Skin Contact: Remove material from skin immediately by washing with soap and plenty of water.
Remove contaminated clothing and shoes while washing. Seek medical attention if irritation
persists. Wash clothing before reuse. An MDI skin decontamination study demonstrated that
cleaning very soon after exposure is important, and that a polyglycol-based skin cleanser or corn
oil may be more effective than soap and water. Discard items which cannot be decontaminated,
including leather articles such as shoes, belts and watchbands.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to
mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be
administered by qualified personnel. Call a physician or transport to a medical facility.
Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so
by medical personnel.
Notes to Physician: Maintain adequate ventilation and oxygenation of the patient. May cause
respiratory sensitization or asthma-like symptoms. Bronchodilators, expectorants and
antitussives may be of help. Treat bronchospasm with inhaled beta2 agonist and oral or
parenteral corticosteroids. Respiratory symptoms, including pulmonary edema, may be delayed.
Persons receiving significant exposure should be observed 24-48 hours for signs of respiratory
distress. If you are sensitized to diisocyanates, consult your physician regarding working with
other respiratory irritants or sensitizers. Exposure may increase "myocardial irritability". Do not
administer sympathomimetic drugs such as epinephrine unless absolutely necessary. Treatment
of exposure should be directed at the control of symptoms and the clinical condition of the patient.
®(™)*Trademark of The Dow Chemical Company
4 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Effective Date: 03/16/10
Medical Conditions Aggravated by Exposure: Excessive exposure may aggravate preexisting
asthma and other respiratory disorders (e.g. emphysema, bronchitis, reactive airways dysfunction
syndrome).
Emergency Personnel Protection: First Aid responders should pay attention to self-protection
and use the recommended protective clothing (chemical resistant gloves, splash protection). If
potential for exposure exists refer to Section 8 for specific personal protective equipment.
5.
Fire Fighting Measures
Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide
fire extinguishers. Foam. Do not use direct water stream. May spread fire. Alcohol resistant
foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein
foams may function, but will be less effective.
Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay
upwind. Keep out of low areas where gases (fumes) can accumulate. Water is not
recommended, but may be applied in large quantities as a fine spray when other extinguishing
agents are not available. Do not use direct water stream. May spread fire. Fight fire from
protected location or safe distance. Consider the use of unmanned hose holders or monitor
nozzles. Immediately withdraw all personnel from the area in case of rising sound from venting
safety device or discoloration of the container. Move container from fire area if this is possible
without hazard. Use water spray to cool fire-exposed containers and fire-affected zone until fire is
out. Contain fire water run-off if possible. Fire water run-off, if not contained, may cause
environmental damage. Review the "Accidental Release Measures" and the "Ecological
Information" sections of this (M)SDS.
Special Protective Equipment for Firefighters: Wear positive-pressure self-contained
breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet,
coat, trousers, boots, and gloves). Avoid contact with this material during fire fighting operations.
If contact is likely, change to full chemical resistant fire fighting clothing with self-contained
breathing apparatus. If this is not available, wear full chemical resistant clothing with selfcontained breathing apparatus and fight fire from a remote location. For protective equipment in
post-fire or non-fire clean-up situations, refer to the relevant sections.
Unusual Fire and Explosion Hazards: Some components of this product will burn in a fire
situation. Product reacts with water. Reaction may produce heat and/or gases. This reaction
may be violent. Container may rupture from gas generation in a fire situation. Blowing agent
vaporizes quickly at room temperature. Violent steam generation or eruption may occur upon
application of direct water stream to hot liquids. Dense smoke is produced when product burns.
Hazardous Combustion Products: During a fire, smoke may contain the original material in
addition to combustion products of varying composition which may be toxic and/or irritating.
Combustion products may include and are not limited to: Nitrogen oxides. Isocyanates.
Hydrogen cyanide. Carbon monoxide. Carbon dioxide. Hydrogen halides. Halogenated
hydrocarbons.
See Section 9 for related Physical Properties
®(™)*Trademark of The Dow Chemical Company
5 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
6.
Effective Date: 03/16/10
Accidental Release Measures
Steps to be Taken if Material is Released or Spilled: Contain spilled material if possible.
Absorb with materials such as: Vermiculite. Dirt. Sand. Clay. Do NOT use absorbent materials
such as: Cement powder (Note: may generate heat). Collect in suitable and properly labeled
open containers. Do not place in sealed containers. Suitable containers include: Metal drums.
Plastic drums. Polylined fiber pacs. Wash the spill site with large quantities of water. Attempt to
neutralize by adding suitable decontaminant solution: Formulation 1: sodium carbonate 5 - 10%;
liquid detergent 0.2 - 2%; water to make up to 100%, OR Formulation 2: concentrated ammonia
solution 3 - 8%; liquid detergent 0.2 - 2%; water to make up to 100%. If ammonia is used, use
good ventilation to prevent vapor exposure. Contact Dow for clean-up assistance. See Section
13, Disposal Considerations, for additional information.
Personal Precautions: Isolate area. Ventilate area of leak or spill. Keep personnel out of low
areas. Keep upwind of spill. Keep unnecessary and unprotected personnel from entering the
area. If available, use foam to smother or suppress. Refer to Section 7, Handling, for additional
precautionary measures. See Section 10 for more specific information. Use appropriate safety
equipment. For additional information, refer to Section 8, Exposure Controls and Personal
Protection.
Environmental Precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information.
7.
Handling and Storage
Handling
General Handling: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid
prolonged or repeated contact with skin. Use with adequate ventilation. Wash thoroughly after
handling. Keep container tightly closed. Contents under pressure. Do not puncture or incinerate
container. Containers, even those that have been emptied, can contain vapors. Do not cut, drill,
grind, weld, or perform similar operations on or near empty containers. Do not enter confined
spaces unless adequately ventilated. See Section 8, EXPOSURE CONTROLS AND PERSONAL
PROTECTION.
Storage
Store under cover in a dry, clean, cool, well ventilated place away from sunlight. Do not store
product contaminated with water to prevent potential hazardous reaction.
Storage Period:
Storage temperature:
15 Months
24 °C
8.
Exposure Controls / Personal Protection
Exposure Limits
®(™)*Trademark of The Dow Chemical Company
6 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Component
|
4,4' -Methylenediphenyl
diisocyanate
|
Diphenylmethane
Diisocyanate, isomers and
homologues
|
1,1,1,2-Tetrafluoroethane
Effective Date: 03/16/10
List
Type
Value
ACGIH
TWA
0.005 ppm
CAD AB OEL
CAD BC OEL
TWA
TWA
0.051 mg/m3 0.005 ppm
0.005 ppm SKIN
CAD BC OEL
CAD ON OEL
CAD ON OEL
OEL (QUE)
CEILING
TWAEV
CEV
TWA
0.01 ppm SKIN
0.005 ppm
0.02 ppm
0.051 mg/m3 0.005 ppm SEN
Exposure must be minimized.
CAD AB OEL
TWA
0.07 mg/m3 0.005 ppm
CAD BC OEL
CAD BC OEL
TWA
CEILING
0.005 ppm
0.01 ppm
AIHA WEEL
TWA
4,240 mg/m3 1,000 ppm
Consult local authorities for recommended exposure limits.
A "skin" notation following the inhalation exposure guideline refers to the potential for dermal
absorption of the material including mucous membranes and the eyes either by contact with
vapors or by direct skin contact.
It is intended to alert the reader that inhalation may not be the only route of exposure and that
measures to minimize dermal exposures should be considered.
A "SEN" notation following the exposure guideline refers to the potential to produce sensitization,
as confirmed by human or animal data.
Personal Protection
Eye/Face Protection: Use chemical goggles. Eye wash fountain should be located in immediate
work area.
Skin Protection: Use protective clothing chemically resistant to this material. Selection of
specific items such as face shield, boots, apron, or full body suit will depend on the task. Remove
contaminated clothing immediately, wash skin area with soap and water, and launder clothing
before reuse or dispose of properly. Items which cannot be decontaminated, such as shoes,
belts and watchbands, should be removed and disposed of properly.
Hand protection: Use gloves chemically resistant to this material. Examples of
preferred glove barrier materials include: Butyl rubber. Polyethylene. Chlorinated
polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Examples of acceptable glove
barrier materials include: Viton. Neoprene. Polyvinyl chloride ("PVC" or "vinyl").
Nitrile/butadiene rubber ("nitrile" or "NBR"). NOTICE: The selection of a specific glove for
a particular application and duration of use in a workplace should also take into account
all relevant workplace factors such as, but not limited to: Other chemicals which may be
handled, physical requirements (cut/puncture protection, dexterity, thermal protection),
®(™)*Trademark of The Dow Chemical Company
7 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Effective Date: 03/16/10
potential body reactions to glove materials, as well as the instructions/specifications
provided by the glove supplier.
Respiratory Protection: Atmospheric levels should be maintained below the exposure guideline.
When atmospheric levels may exceed the exposure guideline, use an approved air-purifying
respirator equipped with an organic vapor sorbent and a particle filter. For situations where the
atmospheric levels may exceed the level for which an air-purifying respirator is effective, use a
positive-pressure air-supplying respirator (air line or self-contained breathing apparatus). For
emergency response or for situations where the atmospheric level is unknown, use an approved
positive-pressure self-contained breathing apparatus or positive-pressure air line with auxiliary
self-contained air supply. In confined or poorly ventilated areas, use an approved self-contained
breathing apparatus or positive pressure air line with auxiliary self-contained air supply. The
following should be effective types of air-purifying respirators: Organic vapor cartridge with a
particulate pre-filter.
Ingestion: Use good personal hygiene. Do not consume or store food in the work area. Wash
hands before smoking or eating.
Engineering Controls
Ventilation: Use only with adequate ventilation. Local exhaust ventilation may be necessary for
some operations. Provide general and/or local exhaust ventilation to control airborne levels
below the exposure guidelines. Exhaust systems should be designed to move the air away from
the source of vapor/aerosol generation and people working at this point. The odor and irritancy of
this material are inadequate to warn of excessive exposure. Lethal concentrations may exist in
areas with poor ventilation.
9.
Physical and Chemical Properties
Physical State
Color
Odor
Odor Threshold
Flash Point - Closed Cup
Flammability (solid, gas)
Flammable Limits In Air
Autoignition Temperature
Vapor Pressure
Boiling Point (760 mmHg)
Vapor Density (air = 1)
Specific Gravity (H2O = 1)
Freezing Point
Melting Point
Solubility in water (by
weight)
pH
Liquid.
Brown
Musty
No test data available
Not applicable
Not applicable to liquids
Lower: No test data available
Upper: No test data available
No test data available
240 psi @ 23 °C Estimated. Container is under pressure.
No test data available.
No test data available
1.24 Estimated.
No test data available
No test data available
insoluble, reacts, evolution of CO2
Not applicable
®(™)*Trademark of The Dow Chemical Company
8 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Decomposition
Temperature
Partition coefficient, noctanol/water (log Pow)
Evaporation Rate (Butyl
Acetate = 1)
Kinematic Viscosity
10.
Effective Date: 03/16/10
No test data available
No data available for this product. See Section 12 for individual
component data.
No test data available
No test data available
Stability and Reactivity
Stability/Instability
Stable under recommended storage conditions. See Storage, Section 7.
Conditions to Avoid: Exposure to elevated temperatures can cause product to decompose.
Elevated temperatures can cause pressure buildup in closed containers due to the release of
blowing agents. Generation of gas during decomposition can cause pressure in closed systems.
Pressure build-up can be rapid. Avoid moisture. Material reacts slowly with water, releasing
carbon dioxide which can cause pressure buildup and rupture of closed containers. Elevated
temperatures accelerate this reaction.
Incompatible Materials: Avoid contact with: Acids. Alcohols. Amines. Water. Ammonia.
Bases. Metal compounds. Moist air. Strong oxidizers. Diisocyanates react with many materials
and the rate of reaction increases with temperature as well as increased contact; these reactions
can become violent. Contact is increased by stirring or if the other material mixes with the
diisocyanate. Diisocyanates are not soluble in water and sink to the bottom, but react slowly at
the interface. The reaction forms carbon dioxide gas and a layer of solid polyurea. Reaction with
water will generate carbon dioxide and heat. Avoid contact with metals such as: Aluminum.
Zinc. Brass. Tin. Copper. Galvanized metals. Avoid contact with absorbent materials such as:
Moist organic absorbents. Avoid unintended contact with polyols. The reaction of polyols and
isocyanates generate heat.
Hazardous Polymerization
Can occur. Elevated temperatures can cause hazardous polymerization. Polymerization can be
catalyzed by: Strong bases. Water.
Thermal Decomposition
Decomposition products depend upon temperature, air supply and the presence of other
materials. Gases are released during decomposition.
11.
Toxicological Information
®(™)*Trademark of The Dow Chemical Company
9 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Effective Date: 03/16/10
Acute Toxicity
Ingestion
Single dose oral LD50 has not been determined. Estimated. LD50, Rat > 10,000 mg/kg
Dermal
The dermal LD50 has not been determined. Estimated. LD50, Rabbit > 2,000 mg/kg
Inhalation
The LC50 has not been determined. Estimated. LC50, Aerosol, Rat > 490 mg/m3
Serious eye damage/eye irritation
May cause moderate eye irritation. May cause slight temporary corneal injury.
Skin corrosion/irritation
Prolonged contact may cause skin irritation with local redness. May stain skin.
Sensitization
Skin
Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact
with isocyanates may play a role in respiratory sensitization.
Respiratory
May cause allergic respiratory response. MDI concentrations below the exposure guidelines may
cause allergic respiratory reactions in individuals already sensitized. Asthma-like symptoms may
include coughing, difficult breathing and a feeling of tightness in the chest. Occasionally,
breathing difficulties may be life threatening.
Repeated Dose Toxicity
Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals
after repeated excessive exposures to MDI/polymeric MDI aerosols.
Chronic Toxicity and Carcinogenicity
Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of
MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory
irritation and lung injury. Current exposure guidelines are expected to protect against these
effects reported for MDI.
Developmental Toxicity
In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred
only at high doses which were toxic to the mother. Based on information for component(s):
1,1,1,2-Tetrafluoroethane. Has been toxic to the fetus in laboratory animals at doses toxic to the
mother. Did not cause birth defects in laboratory animals.
Reproductive Toxicity
No relevant information found.
Genetic Toxicology
Genetic toxicity data on MDI are inconclusive. MDI was weakly positive in some in vitro studies;
other in vitro studies were negative. Animal mutagenicity studies were predominantly negative.
12.
Ecological Information
®(™)*Trademark of The Dow Chemical Company
10 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Effective Date: 03/16/10
ENVIRONMENTAL FATE
Data for Component: Diphenylmethane Diisocyanate, isomers and homologues
Movement & Partitioning
In the aquatic and terrestrial environment, movement is expected to be limited by its
reaction with water forming predominantly insoluble polyureas.
Persistence and Degradability
In the aquatic and terrestrial environment, material reacts with water forming
predominantly insoluble polyureas which appear to be stable. In the atmospheric
environment, material is expected to have a short tropospheric half-life, based on
calculations and by analogy with related diisocyanates.
Data for Component: 4,4' -Methylenediphenyl diisocyanate
Movement & Partitioning
In the aquatic and terrestrial environment, movement is expected to be limited by its
reaction with water forming predominantly insoluble polyureas.
Persistence and Degradability
In the aquatic and terrestrial environment, material reacts with water forming
predominantly insoluble polyureas which appear to be stable. In the atmospheric
environment, material is expected to have a short tropospheric half-life, based on
calculations and by analogy with related diisocyanates.
Data for Component: 1,1,1,2-Tetrafluoroethane
Movement & Partitioning
Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential
for mobility in soil is high (Koc between 50 and 150).
Henry's Law Constant (H): 5.00E-02 atm*m3/mole; 25 °C Measured
Partition coefficient, n-octanol/water (log Pow): 1.68 Estimated.
Partition coefficient, soil organic carbon/water (Koc): 97 Estimated.
Persistence and Degradability
1,1,1,2-Tetrafluoroethane (HFC-134a) has a stratospheric ozone depletion potential
(ODP) of zero, relative to CFC 12 (ODP=1). Material is expected to biodegrade only very
slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability.
Indirect Photodegradation with OH Radicals
Rate Constant
Atmospheric Half-life
Method
6.20E-15 cm3/s
1,700 d
Estimated.
OECD Biodegradation Tests:
Biodegradation
Exposure Time
Method
4%
28 d
OECD 301D Test
Theoretical Oxygen Demand: 0.47 mg/mg
®(™)*Trademark of The Dow Chemical Company
11 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Effective Date: 03/16/10
ECOTOXICITY
Data for Component: Diphenylmethane Diisocyanate, isomers and homologues
The measured ecotoxicity is that of the hydrolyzed product, generally under conditions
maximizing production of soluble species. Material is practically non-toxic to aquatic
organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive
species tested).
Toxicity to Soil Dwelling Organisms
LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg
Data for Component: 4,4' -Methylenediphenyl diisocyanate
The measured ecotoxicity is that of the hydrolyzed product, generally under conditions
maximizing production of soluble species. Material is practically non-toxic to aquatic
organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive
species tested).
Toxicity to Soil Dwelling Organisms
LC50, Earthworm Eisenia foetida, adult, 14 d: > 1,000 mg/kg
Data for Component: 1,1,1,2-Tetrafluoroethane
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Fish Acute & Prolonged Toxicity
LC50, rainbow trout (Oncorhynchus mykiss), static, 96 h: 450 mg/l
Aquatic Invertebrate Acute Toxicity
EC50, water flea Daphnia magna, 48 h, immobilization: 980 mg/l
13.
Disposal Considerations
DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER.
All disposal practices must be in compliance with all Federal, State/Provincial and local laws and
regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN
ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information.
FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a
licensed, permitted: Incinerator or other thermal destruction device.
®(™)*Trademark of The Dow Chemical Company
12 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
14.
Effective Date: 03/16/10
Transport Information
TDG Small container
Proper Shipping Name: COMPRESSED GAS, N.O.S.
Technical Name: Fluorinated Hydrocarbons, Nitrogen
Hazard Class: 2.2 ID Number: UN1956
TDG Large container
Proper Shipping Name: COMPRESSED GASES, N.O.S.
Technical Name: Fluorinated Hydrocarbons, Nitrogen
Hazard Class: 2.2 ID Number: UN1956
IMDG
Proper Shipping Name: COMPRESSED GASES, N.O.S.
Technical Name: Fluorinated Hydrocarbons, Nitrogen
Hazard Class: 2.2 ID Number: UN1956
EMS Number: F-C,S-V
ICAO/IATA
Proper Shipping Name: COMPRESSED GAS, N.O.S.
Technical Name: Fluorinated Hydrocarbons, Nitrogen
Hazard Class: 2.2 ID Number: UN1956Cargo Packing Instruction: 200
Passenger Packing Instruction: 200
15.
Regulatory Information
US. Toxic Substances Control Act
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory
requirements under 40 CFR 720.30
CEPA - Domestic Substances List (DSL)
All substances contained in this product are listed on the Canadian Domestic Substances List
(DSL) or are not required to be listed.
Hazardous Products Act Information: CPR Compliance
This product has been classified in accordance with the hazard criteria of the Canadian
Controlled Products Regulations (CPR) and the MSDS contains all the information required by
the CPR.
Hazardous Products Act Information: WHMIS Classification
A
Compressed Gas
D2A
Respiratory Tract Sensitizer
D2B
Eye or Skin Irritant
D2B
Skin Sensitizer
®(™)*Trademark of The Dow Chemical Company
13 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Effective Date: 03/16/10
Hazardous Products Act Information: Hazardous Ingredients
This product contains the following ingredients which are Controlled Products and/or are on the
Ingredient Disclosure List (Canadian HPA Section 13 and 14).
Component
CAS #
Amount
W/W
4,4' -Methylenediphenyl diisocyanate
101-68-8
>= 30.0 - <= 60.0 %
16.
Other Information
Recommended Uses and Restrictions
Component(s) for the manufacture of urethane polymers.
Revision
Identification Number: 1041164 / 1001 / Issue Date 2010.02.25 / Version: 2.1
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Legend
N/A
W/W
OEL
STEL
TWA
ACGIH
DOW IHG
WEEL
HAZ_DES
VOL/VOL
Not available
Weight/Weight
Occupational Exposure Limit
Short Term Exposure Limit
Time Weighted Average
American Conference of Governmental Industrial Hygienists, Inc.
Dow Industrial Hygiene Guideline
Workplace Environmental Exposure Level
Hazard Designation
Volume/Volume
The Dow Chemical Company urges each customer or recipient of this (M)SDS to study it
carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date
shown above. However, no warranty, express or implied, is given. Regulatory requirements are
subject to change and may differ between various locations. It is the buyer's/user's responsibility
to ensure that his activities comply with all federal, state, provincial or local laws. The information
presented here pertains only to the product as shipped. Since conditions for use of the product
are not under the control of the manufacturer, it is the buyer's/user's duty to determine the
conditions necessary for the safe use of this product. Due to the proliferation of sources for
®(™)*Trademark of The Dow Chemical Company
14 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Effective Date: 03/16/10
information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for
(M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from
another source or if you are not sure that the (M)SDS you have is current, please contact us for
the most current version.
®(™)*Trademark of The Dow Chemical Company
15 of 30
Material Safety Data Sheet
The Dow Chemical Company
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Effective Date: 03/16/10
The Dow Chemical Company encourages and expects you to read and understand the entire
(M)SDS, as there is important information throughout the document. We expect you to follow the
precautions identified in this document unless your use conditions would necessitate other
appropriate methods or actions.
1.
Product and Company Identification
Product Name
Polyurethane System - Polyol
COMPANY IDENTIFICATION
The Dow Chemical Company
2030 Willard H. Dow Center
Midland, MI 48674
USA
For MSDS updates and Product Information:
Prepared By:
Revision
Print Date:
800-258-2436
Prepared for use in Canada by EH&S, Hazard Communications.
2010.03.09
7/13/2011
Customer Information Number:
800-258-2436
EMERGENCY TELEPHONE NUMBER
24-Hour Emergency Contact:
Local Emergency Contact:
989-636-4400
989-636-4400
2.
Hazards Identification
Emergency Overview
Color: Yellow
Physical State: Liquid.
Odor: Characteristic
®(™)*Trademark of The Dow Chemical Company
16 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Effective Date: 03/16/10
Hazards of product:
CAUTION! May cause eye irritation. May be harmful if inhaled. Vapor reduces
oxygen available for breathing. May cause anesthetic effects. May cause central
nervous system effects; may cause respiratory tract irritation. Isolate area. Keep
upwind of spill. Contents under pressure.
Potential Health Effects
Eye Contact: May cause slight eye irritation. May cause slight temporary corneal injury.
Skin Contact: Prolonged contact may cause slight skin irritation with local redness.
Skin Absorption: Prolonged skin contact is unlikely to result in absorption of harmful amounts.
Inhalation: Prolonged excessive exposure may cause adverse effects. In confined or poorly
ventilated areas, vapor can easily accumulate and can cause unconsciousness and death due to
displacement of oxygen. May cause respiratory irritation and central nervous system depression.
Excessive exposure may increase sensitivity to epinephrine and increase myocardial irritability
(irregular heartbeats). Symptoms of excessive exposure may be anesthetic or narcotic effects;
dizziness and drowsiness may be observed.
Ingestion: Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal
handling operations are not likely to cause injury; however, swallowing larger amounts may cause
injury. Signs and symptoms of excessive exposure may include: May cause lacrimation (tears).
Salivation. Convulsions. Tremors. Increased activity (hyperactivity).
Aspiration hazard: Based on physical properties, not likely to be an aspiration hazard.
Effects of Repeated Exposure: Contains a component which is reported to be a weak
organophosphate-type cholinesterase inhibitor. Excessive exposure may produce
organophosphate type cholinesterase inhibition. Signs and symptoms of excessive exposure
may be headache, dizziness, incoordination, muscle twitching, tremors, nausea, abdominal
cramps, diarrhea, sweating, pinpoint pupils, blurred vision, salivation, tearing, tightness in chest,
excessive urination, convulsions. Contains component(s) which have been reported to cause
effects on the following organs in animals: Heart.
Birth Defects/Developmental Effects: Contains component(s) which, in laboratory animals,
have been toxic to the fetus at doses nontoxic to the mother. Contains component(s) which, in
laboratory animals, have been toxic to the fetus only at doses toxic to the mother. Based on
animal studies, ingestion of very large amounts of ethylene glycol appears to be the major and
possibly only route of exposure to produce birth defects. Exposures by inhalation or skin contact,
the primary routes of occupational exposure, had minimal effect on the fetus, in animal studies.
Reproductive Effects: In animal studies on component(s), effects on reproduction were seen
only at doses that produced significant toxicity to the parent animals.
3.
Composition/information on ingredients
®(™)*Trademark of The Dow Chemical Company
17 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Component
CAS #
1,1,1,2-Tetrafluoroethane
Glycerol propylene oxide polymer
Polyester polyol, aromatic
Sucrose , propylene oxide polymer
Tris(1-chloro-2-propyl) phosphate
1,1,1,3,3 - Pentafluoropropane
Triethyl phosphate
811-97-2
25791-96-2
Not available
9049-71-2
13674-84-5
460-73-1
78-40-0
Ethylene glycol
107-21-1
Amounts are presented as percentages by weight.
4.
Effective Date: 03/16/10
Amount
W/W
>= 10.0 - <= 30.0 %
>= 10.0 - <= 30.0 %
>= 10.0 - <= 30.0 %
>= 10.0 - <= 30.0 %
>= 10.0 - <= 30.0 %
>= 1.0 - <= 10.0 %
>= 1.0 - <= 5.0 %
> 0.1 - < 1.0 %
First-aid measures
Eye Contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after
the initial 1-2 minutes and continue flushing for several additional minutes. If effects occur,
consult a physician, preferably an ophthalmologist.
Skin Contact: Wash skin with plenty of water.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to
mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be
administered by qualified personnel. Call a physician or transport to a medical facility.
Ingestion: Do not induce vomiting. Call a physician and/or transport to emergency facility
immediately.
Notes to Physician: Maintain adequate ventilation and oxygenation of the patient. This material
is a cholinesterase inhibitor. Treat symptomatically. In case of severe acute poisoning, use
antidote immediately after establishing an open airway and respiration. Atropine, only by
injection, is the preferable antidote. Oximes, such as 2-PAM/protopam, may be therapeutic if
used early; however, use only in conjunction with atropine. Attempt seizure control with
diazepam 5-10 mg (adults) intravenous over 2-3 minutes. Repeat every 5-10 minutes as needed.
Monitor for hypotension, respiratory depression, and need for intubation. Consider second agent
if seizures persist after 30 mg. If seizures persist or recur administer phenobarbital 600-1200 mg
(adults) intravenous diluted in 60 ml 0.9% saline given at 25-50 mg/minute. Evaluate for hypoxia,
dysrhythmia, electrolyte disturbance, hypoglycemia (treat adults with dextrose 100 mg
intravenous). If exposed, plasma and red blood cell cholinesterase tests may indicate
significance of exposure (baseline data are useful). Exposure may increase "myocardial
irritability". Do not administer sympathomimetic drugs such as epinephrine unless absolutely
necessary. Treatment of exposure should be directed at the control of symptoms and the clinical
condition of the patient.
Emergency Personnel Protection: First Aid responders should pay attention to self-protection
and use the recommended protective clothing (chemical resistant gloves, splash protection). If
potential for exposure exists refer to Section 8 for specific personal protective equipment.
®(™)*Trademark of The Dow Chemical Company
18 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
5.
Effective Date: 03/16/10
Fire Fighting Measures
Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide
fire extinguishers. Foam. Do not use direct water stream. May spread fire. Alcohol resistant
foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein
foams may function, but will be less effective.
Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Use
water spray to cool fire exposed containers and fire affected zone until fire is out and danger of
reignition has passed. Fight fire from protected location or safe distance. Consider the use of
unmanned hose holders or monitor nozzles. Immediately withdraw all personnel from the area in
case of rising sound from venting safety device or discoloration of the container. Do not use
direct water stream. May spread fire. Move container from fire area if this is possible without
hazard. Burning liquids may be moved by flushing with water to protect personnel and minimize
property damage. Contain fire water run-off if possible. Fire water run-off, if not contained, may
cause environmental damage. Review the "Accidental Release Measures" and the "Ecological
Information" sections of this (M)SDS.
Special Protective Equipment for Firefighters: Wear positive-pressure self-contained
breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet,
coat, trousers, boots, and gloves). Avoid contact with this material during fire fighting operations.
If contact is likely, change to full chemical resistant fire fighting clothing with self-contained
breathing apparatus. If this is not available, wear full chemical resistant clothing with selfcontained breathing apparatus and fight fire from a remote location. For protective equipment in
post-fire or non-fire clean-up situations, refer to the relevant sections.
Unusual Fire and Explosion Hazards: Container may rupture from gas generation in a fire
situation. Blowing agent vaporizes quickly at room temperature. Violent steam generation or
eruption may occur upon application of direct water stream to hot liquids.
Hazardous Combustion Products: During a fire, smoke may contain the original material in
addition to combustion products of varying composition which may be toxic and/or irritating.
Combustion products may include and are not limited to: Carbon monoxide. Carbon dioxide.
Hydrogen halides.
See Section 9 for related Physical Properties
6.
Accidental Release Measures
Steps to be Taken if Material is Released or Spilled: Contain spilled material if possible.
Absorb with materials such as: Dirt. Sand. Sawdust. Collect in suitable and properly labeled
containers. Wash the spill site with water. See Section 13, Disposal Considerations, for
additional information.
Personal Precautions: Isolate area. Keep unnecessary and unprotected personnel from
entering the area. Spilled material may cause a slipping hazard. Refer to Section 7, Handling,
for additional precautionary measures. Use appropriate safety equipment. For additional
information, refer to Section 8, Exposure Controls and Personal Protection.
®(™)*Trademark of The Dow Chemical Company
19 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Effective Date: 03/16/10
Environmental Precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information.
7.
Handling and Storage
Handling
General Handling: Avoid contact with eyes. Avoid breathing vapor. Wash thoroughly after
handling. Keep container closed. Use only with adequate ventilation. This material is
hygroscopic in nature. Contents under pressure. Do not puncture or incinerate container. Do
not enter confined spaces unless adequately ventilated. See Section 8, EXPOSURE
CONTROLS AND PERSONAL PROTECTION.
Other Precautions: Spills of these organic materials on hot fibrous insulations may lead to
lowering of the autoignition temperatures possibly resulting in spontaneous combustion.
Storage
Store under cover in a dry, clean, cool, well ventilated place away from sunlight.
Storage Period:
Storage temperature:
15 Months
24 °C
8.
Exposure Controls / Personal Protection
Exposure Limits
Component
|
1,1,1,2-Tetrafluoroethane
|
1,1,1,3,3 - Pentafluoropropane
||
Ethylene glycol
List
Type
Value
AIHA WEEL
TWA
4,240 mg/m3 1,000 ppm
AIHA WEEL
TWA
1,644 mg/m3 300 ppm
CAD ON OEL
ACGIH
CEV
Ceiling
Aerosol.
TWA
Particulate.
CEILING
Vapor.
CEILING
Aerosol.
STEL
Particulate.
CEILING
Vapor and
mist.
100 mg/m3
100 mg/m3
CAD BC OEL
CAD BC OEL
CAD BC OEL
CAD BC OEL
OEL (QUE)
®(™)*Trademark of The Dow Chemical Company
10 mg/m3
50 ppm
100 mg/m3
20 mg/m3
127 mg/m3 50 ppm
20 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
OEL (QUE)
OEL (QUE)
OEL (QUE)
CAD AB OEL
Vapor and
mist.
CEILING
Vapor and
mist.
Vapor and
mist.
CEILING
Effective Date: 03/16/10
Recirculation prohibited
127 mg/m3 50 ppm
Recirculation prohibited
100 mg/m3
Consult local authorities for recommended exposure limits.
Personal Protection
Eye/Face Protection: Use safety glasses (with side shields).
Skin Protection: Wear clean, body-covering clothing.
Hand protection: Use gloves chemically resistant to this material when prolonged or
frequently repeated contact could occur. Examples of preferred glove barrier materials
include: Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate ("EVAL").
Polyvinyl alcohol ("PVA"). Styrene/butadiene rubber. Viton. Examples of acceptable
glove barrier materials include: Butyl rubber. Natural rubber ("latex"). Polyvinyl chloride
("PVC" or "vinyl"). NOTICE: The selection of a specific glove for a particular application
and duration of use in a workplace should also take into account all relevant workplace
factors such as, but not limited to: Other chemicals which may be handled, physical
requirements (cut/puncture protection, dexterity, thermal protection), potential body
reactions to glove materials, as well as the instructions/specifications provided by the
glove supplier.
Respiratory Protection: Respiratory protection should be worn when there is a potential to
exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit
requirements or guidelines, use an approved respirator. When respiratory protection is required,
use an approved positive-pressure self-contained breathing apparatus or positive-pressure airline
with auxiliary self-contained air supply. For emergency conditions, use an approved positivepressure self-contained breathing apparatus. In confined or poorly ventilated areas, use an
approved self-contained breathing apparatus or positive pressure air line with auxiliary selfcontained air supply.
Ingestion: Use good personal hygiene. Do not consume or store food in the work area. Wash
hands before smoking or eating.
Engineering Controls
Ventilation: Use engineering controls to maintain airborne level below exposure limit
requirements or guidelines. If there are no applicable exposure limit requirements or guidelines,
use only in enclosed systems or with local exhaust ventilation. Exhaust systems should be
designed to move the air away from the source of vapor/aerosol generation and people working
at this point. Lethal concentrations may exist in areas with poor ventilation.
9.
Physical and Chemical Properties
®(™)*Trademark of The Dow Chemical Company
21 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Physical State
Color
Odor
Odor Threshold
Flash Point - Closed Cup
Flammability (solid, gas)
Flammable Limits In Air
Autoignition Temperature
Vapor Pressure
Boiling Point (760 mmHg)
Vapor Density (air = 1)
Specific Gravity (H2O = 1)
Freezing Point
Melting Point
Solubility in water (by
weight)
pH
Decomposition
Temperature
Partition coefficient, noctanol/water (log Pow)
Evaporation Rate (Butyl
Acetate = 1)
Kinematic Viscosity
10.
Effective Date: 03/16/10
Liquid.
Yellow
Characteristic
No test data available
> 100 °C Estimated.
Not applicable to liquids
Lower: No test data available
Upper: No test data available
No test data available
Not applicable
No test data available.
No test data available
1.18 Calculated
No test data available
No test data available
No test data available
Not applicable
No test data available
No data available for this product. See Section 12 for individual
component data.
No test data available
2,240 cSt ASTM D4878
Stability and Reactivity
Stability/Instability
Stable under recommended storage conditions. See Storage, Section 7.
Conditions to Avoid: Product can oxidize at elevated temperatures. Elevated temperatures can
cause pressure buildup in closed containers due to the release of blowing agents. Generation of
gas during decomposition can cause pressure in closed systems.
Incompatible Materials: Avoid contact with oxidizing materials. Avoid contact with: Strong
acids. Strong bases. Avoid unintended contact with isocyanates. The reaction of polyols and
isocyanates generates heat.
Hazardous Polymerization
Will not occur by itself.
Thermal Decomposition
®(™)*Trademark of The Dow Chemical Company
22 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Effective Date: 03/16/10
Decomposition products depend upon temperature, air supply and the presence of other
materials. Decomposition products can include and are not limited to: Carbon dioxide. Alcohols.
Ethers. Hydrocarbons. Hydrogen halides. Ketones. Polymer fragments.
11.
Toxicological Information
Acute Toxicity
Ingestion
As product. Single dose oral LD50 has not been determined. Estimated. LD50, Rat > 2,000
mg/kg
Dermal
As product. The dermal LD50 has not been determined. Estimated. LD50, Rabbit > 2,000
mg/kg
Inhalation
As product. The LC50 has not been determined.
Serious eye damage/eye irritation
May cause slight eye irritation. May cause slight temporary corneal injury.
Skin corrosion/irritation
Prolonged contact may cause slight skin irritation with local redness.
Sensitization
Skin
No relevant information found.
Respiratory
No relevant information found.
Repeated Dose Toxicity
Contains a component which is reported to be a weak organophosphate-type cholinesterase
inhibitor. Excessive exposure may produce organophosphate type cholinesterase inhibition.
Signs and symptoms of excessive exposure may be headache, dizziness, incoordination, muscle
twitching, tremors, nausea, abdominal cramps, diarrhea, sweating, pinpoint pupils, blurred vision,
salivation, tearing, tightness in chest, excessive urination, convulsions. Contains component(s)
which have been reported to cause effects on the following organs in animals: Heart.
Chronic Toxicity and Carcinogenicity
No relevant information found.
Developmental Toxicity
Contains component(s) which, in laboratory animals, have been toxic to the fetus at doses
nontoxic to the mother. Contains component(s) which, in laboratory animals, have been toxic to
the fetus only at doses toxic to the mother. Based on animal studies, ingestion of very large
amounts of ethylene glycol appears to be the major and possibly only route of exposure to
produce birth defects. Exposures by inhalation or skin contact, the primary routes of occupational
exposure, had minimal effect on the fetus, in animal studies.
Reproductive Toxicity
In animal studies on component(s), effects on reproduction were seen only at doses that
produced significant toxicity to the parent animals.
®(™)*Trademark of The Dow Chemical Company
23 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Effective Date: 03/16/10
Genetic Toxicology
Genetic toxicity studies on tested components were predominantly negative. Contains
component(s) which were negative in some animal genetic toxicity studies and positive in others.
Component Toxicology - 1,1,1,2-Tetrafluoroethane
Inhalation
LC50, 4 h, Rat > 500,000 ppm
Component Toxicology - Tris(1-chloro-2-propyl) phosphate
Inhalation
LC50, 4 h, Aerosol, Rat > 4.6 mg/l
Component Toxicology - Triethyl phosphate
Inhalation
LC50, 6 h, Aerosol, Rat > 2.05 mg/l
Component Toxicology - Ethylene glycol
Inhalation
LC50, 7 h, Aerosol, Rat > 3.95 mg/l
12.
Ecological Information
ENVIRONMENTAL FATE
Data for Component: 1,1,1,2-Tetrafluoroethane
Movement & Partitioning
Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential
for mobility in soil is high (Koc between 50 and 150).
Henry's Law Constant (H): 5.00E-02 atm*m3/mole; 25 °C Measured
Partition coefficient, n-octanol/water (log Pow): 1.68 Estimated.
Partition coefficient, soil organic carbon/water (Koc): 97 Estimated.
Persistence and Degradability
1,1,1,2-Tetrafluoroethane (HFC-134a) has a stratospheric ozone depletion potential
(ODP) of zero, relative to CFC 12 (ODP=1). Material is expected to biodegrade only very
slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability.
Indirect Photodegradation with OH Radicals
Rate Constant
Atmospheric Half-life
Method
6.20E-15 cm3/s
1,700 d
Estimated.
OECD Biodegradation Tests:
Exposure Time
Method
Biodegradation
4%
28 d
OECD 301D Test
Theoretical Oxygen Demand: 0.47 mg/mg
®(™)*Trademark of The Dow Chemical Company
24 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Effective Date: 03/16/10
Data for Component: Glycerol propylene oxide polymer
Movement & Partitioning
Based on information for a similar material: Bioconcentration potential is low (BCF less
than 100 or log Pow less than 3).
Persistence and Degradability
For this family of materials: Based on stringent OECD test guidelines, this material
cannot be considered as readily biodegradable; however, these results do not necessarily
mean that the material is not biodegradable under environmental conditions.
Data for Component: Sucrose , propylene oxide polymer
Movement & Partitioning
No bioconcentration is expected because of the relatively high water solubility.
Persistence and Degradability
Based on information for a similar material: Material is inherently biodegradable (reaches
> 20% biodegradation in OECD test(s) for inherent biodegradability).
Data for Component: Tris(1-chloro-2-propyl) phosphate
Movement & Partitioning
Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Potential for mobility in
soil is low (Koc between 500 and 2000).
Henry's Law Constant (H): < 1.35E-05 atm*m3/mole; 25 °C Estimated.
Partition coefficient, n-octanol/water (log Pow): 2.59 Measured
Partition coefficient, soil organic carbon/water (Koc): 1,300 Estimated.
Bioconcentration Factor (BCF): 0.8 - 4.6; common carp (Cyprinus carpio); Measured
Persistence and Degradability
Material is expected to biodegrade only very slowly (in the environment). Fails to pass
OECD/EEC tests for ready biodegradability.
Indirect Photodegradation with OH Radicals
Rate Constant
Atmospheric Half-life
Method
4.47E-11 cm3/s
0.24 d
Estimated.
OECD Biodegradation Tests:
Biodegradation
Exposure Time
Method
14 %
28 d
OECD 301E Test
Theoretical Oxygen Demand: 1.17 mg/mg
Data for Component: 1,1,1,3,3 - Pentafluoropropane
Movement & Partitioning
Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential
for mobility in soil is medium (Koc between 150 and 500).
Henry's Law Constant (H): 6.89E-02 atm*m3/mole; 25 °C Estimated.
Partition coefficient, n-octanol/water (log Pow): 1.35 Measured
Partition coefficient, soil organic carbon/water (Koc): 280 Estimated.
®(™)*Trademark of The Dow Chemical Company
25 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Effective Date: 03/16/10
Persistence and Degradability
Material is expected to biodegrade only very slowly (in the environment). Fails to pass
OECD/EEC tests for ready biodegradability.
Indirect Photodegradation with OH Radicals
Rate Constant
Atmospheric Half-life
Method
2.97E-14 cm3/s
360 d
Estimated.
OECD Biodegradation Tests:
Biodegradation
Exposure Time
Method
8%
28 d
OECD 301D Test
Theoretical Oxygen Demand: 0.60 mg/mg
Data for Component: Triethyl phosphate
Movement & Partitioning
Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Potential for mobility in
soil is very high (Koc between 0 and 50). Given its very low Henry's constant,
volatilization from natural bodies of water or moist soil is not expected to be an important
fate process.
Henry's Law Constant (H): 3.60E-08 atm*m3/mole; 25 °C Measured
Partition coefficient, n-octanol/water (log Pow): 0.80 Measured
Partition coefficient, soil organic carbon/water (Koc): 48 Estimated.
Persistence and Degradability
Biodegradation under aerobic laboratory conditions is below detectable limits (BOD20 or
BOD28/ThOD < 2.5%).
Indirect Photodegradation with OH Radicals
Rate Constant
Atmospheric Half-life
Method
5.794E-11 cm3/s
0.18 d
Estimated.
Biological oxygen demand (BOD):
BOD 5
BOD 10
BOD 20
BOD 28
0%
Theoretical Oxygen Demand: 1.58 mg/mg
Data for Component: Ethylene glycol
Movement & Partitioning
Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Potential for mobility in
soil is very high (Koc between 0 and 50). Given its very low Henry's constant,
volatilization from natural bodies of water or moist soil is not expected to be an important
fate process.
Henry's Law Constant (H): 8.05E-09 atm*m3/mole; 25 °C Estimated.
Partition coefficient, n-octanol/water (log Pow): -1.36 Measured
Partition coefficient, soil organic carbon/water (Koc): 1 Estimated.
Distribution in Environment: Mackay Level 1 Fugacity Model:
Air
Water.
Biota
Soil
Sediment
2.1 %
98 %
< 0.01 %
< 0.01 %
< 0.01 %
®(™)*Trademark of The Dow Chemical Company
26 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Effective Date: 03/16/10
Persistence and Degradability
Material is readily biodegradable. Passes OECD test(s) for ready biodegradability.
Material is ultimately biodegradable (reaches > 70% mineralization in OECD test(s) for
inherent biodegradability).
Indirect Photodegradation with OH Radicals
Rate Constant
Atmospheric Half-life
Method
8.32E-12 cm3/s
15 h
Estimated.
OECD Biodegradation Tests:
Biodegradation
Exposure Time
Method
> 94 %
28 d
OECD 301F Test
90 %
1d
OECD 302B Test
Theoretical Oxygen Demand: 1.29 mg/mg
ECOTOXICITY
Data for Component: 1,1,1,2-Tetrafluoroethane
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Fish Acute & Prolonged Toxicity
LC50, rainbow trout (Oncorhynchus mykiss), static, 96 h: 450 mg/l
Aquatic Invertebrate Acute Toxicity
EC50, water flea Daphnia magna, 48 h, immobilization: 980 mg/l
Data for Component: Glycerol propylene oxide polymer
For this family of materials: Material is practically non-toxic to aquatic organisms on an
acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Data for Component: Sucrose , propylene oxide polymer
Based on information for a similar material: Material is practically non-toxic to aquatic
organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive
species tested).
Data for Component: Tris(1-chloro-2-propyl) phosphate
Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10
and 100 mg/L in the most sensitive species tested).
Fish Acute & Prolonged Toxicity
LC50, bluegill (Lepomis macrochirus), 96 h: 84 mg/l
Aquatic Invertebrate Acute Toxicity
EC50, water flea Daphnia magna, 48 h, immobilization: 63 mg/l
Aquatic Plant Toxicity
EC50, green alga Pseudokirchneriella subcapitata (formerly known as Selenastrum
capricornutum), biomass growth inhibition, 96 h: 47 mg/l
EC50, alga Scenedesmus sp., biomass growth inhibition, 72 h: 45 mg/l
Toxicity to Micro-organisms
EC50, OECD 209 Test; activated sludge, respiration inhibition, 3 h: 784 mg/l
®(™)*Trademark of The Dow Chemical Company
27 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
Effective Date: 03/16/10
Data for Component: 1,1,1,3,3 - Pentafluoropropane
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Fish Acute & Prolonged Toxicity
LC50, rainbow trout (Oncorhynchus mykiss), static renewal, 96 h: > 100 mg/l
Aquatic Invertebrate Acute Toxicity
EC50, water flea Daphnia magna, static, 48 h, immobilization: > 100 mg/l
Data for Component: Triethyl phosphate
Material is practically non-toxic to fish on an acute basis (LC50 > 100 mg/L).
Fish Acute & Prolonged Toxicity
LC50, Japanese medaka (Oryzias latipes), static, 48 h: > 500 mg/l
Data for Component: Ethylene glycol
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Fish Acute & Prolonged Toxicity
LC50, rainbow trout (Oncorhynchus mykiss), static, 96 h: 18,000 - 46,000 mg/l
Aquatic Invertebrate Acute Toxicity
LC50, water flea Daphnia magna, static, 48 h: 46,300 - 51,100 mg/l
Aquatic Plant Toxicity
EC50, green alga Pseudokirchneriella subcapitata (formerly known as Selenastrum
capricornutum), biomass growth inhibition, 96 h: 9,500 - 13,000 mg/l
Toxicity to Micro-organisms
EC50, OECD 209 Test; activated sludge, respiration inhibition, 30 min: 225 mg/l
13.
Disposal Considerations
DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER.
All disposal practices must be in compliance with all Federal, State/Provincial and local laws and
regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN
ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information.
FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a
licensed, permitted: Recycler. Reclaimer. Incinerator or other thermal destruction device. For
additional information, refer to: Handling & Storage Information, MSDS Section 7 Stability &
Reactivity Information, MSDS Section 10 Regulatory Information, MSDS Section 15
®(™)*Trademark of The Dow Chemical Company
28 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
14.
Effective Date: 03/16/10
Transport Information
TDG Small container
Proper Shipping Name: COMPRESSED GAS, N.O.S.
Technical Name: Fluorinated Hydrocarbons, Nitrogen
Hazard Class: 2.2 ID Number: UN1956
TDG Large container
Proper Shipping Name: COMPRESSED GASES, N.O.S.
Technical Name: Fluorinated Hydrocarbons, Nitrogen
Hazard Class: 2.2 ID Number: UN1956
IMDG
Proper Shipping Name: COMPRESSED GASES, N.O.S.
Technical Name: Fluorinated Hydrocarbons, Nitrogen
Hazard Class: 2.2 ID Number: UN1956
EMS Number: F-C,S-V
ICAO/IATA
Proper Shipping Name: COMPRESSED GAS, N.O.S.
Technical Name: Fluorinated Hydrocarbons, Nitrogen
Hazard Class: 2.2 ID Number: UN1956Cargo Packing Instruction: 200
Passenger Packing Instruction: 200
15.
Regulatory Information
US. Toxic Substances Control Act
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory
requirements under 40 CFR 720.30
CEPA - Domestic Substances List (DSL)
All substances contained in this product are listed on the Canadian Domestic Substances List
(DSL) or are not required to be listed.
Hazardous Products Act Information: CPR Compliance
This product has been classified in accordance with the hazard criteria of the Canadian
Controlled Products Regulations (CPR) and the MSDS contains all the information required by
the CPR.
Hazardous Products Act Information: WHMIS Classification
This product is not a "Controlled Product" under WHMIS.
®(™)*Trademark of The Dow Chemical Company
29 of 30
Product: FROTH-PAK(TM) Sealant 200HFC Kit CDN
Issue Date: 03/16/10
Isocyanate SDS pages 2-14
Polyol SDS pages 15-29
16.
Effective Date: 03/16/10
Other Information
Revision
Identification Number: 1042556 / 1001 / Issue Date 2010.03.09 / Version: 1.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Legend
N/A
W/W
OEL
STEL
TWA
ACGIH
DOW IHG
WEEL
HAZ_DES
VOL/VOL
Not available
Weight/Weight
Occupational Exposure Limit
Short Term Exposure Limit
Time Weighted Average
American Conference of Governmental Industrial Hygienists, Inc.
Dow Industrial Hygiene Guideline
Workplace Environmental Exposure Level
Hazard Designation
Volume/Volume
The Dow Chemical Company urges each customer or recipient of this (M)SDS to study it
carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date
shown above. However, no warranty, express or implied, is given. Regulatory requirements are
subject to change and may differ between various locations. It is the buyer's/user's responsibility
to ensure that his activities comply with all federal, state, provincial or local laws. The information
presented here pertains only to the product as shipped. Since conditions for use of the product
are not under the control of the manufacturer, it is the buyer's/user's duty to determine the
conditions necessary for the safe use of this product. Due to the proliferation of sources for
information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for
(M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from
another source or if you are not sure that the (M)SDS you have is current, please contact us for
the most current version.
®(™)*Trademark of The Dow Chemical Company
30 of 30
Was this manual useful for you? yes no
Thank you for your participation!

* Your assessment is very important for improving the work of artificial intelligence, which forms the content of this project

Download PDF

advertisement