Olive

Olive
 MSDS
OLIVE
TERRON REPAIR KITS
PART NUMBER S65-117BN
&
TERRON JOINT KITS
PART NUMBER S65-169BN
CONSISTS OF:
CATALYST EP4920 POLYESTER |
EAGER PLASTICS ISSUED 01/21/2011 PAGES 5
ENVIREZ ASHLAND ISSUED 01/14/2011 PAGES 13
FILLER R J MARSHALL ISSUED 08/04/2009 PAGES 4
PIGMENT H K RESEARCH ISSUED 10/26/2011 PAGES 5
259-007BN
REV B EN 11-11-025
P.O. Box 309, Menomonee Falls, WI 53052-0309
Phone: 1-800-BRADLEY Fax: (262) 251-5817
www.bradleycorp.com
MSDS for MEK-P Methyl Ethyl Ketone Peroxide Catalyst / Hardener for Polyester Resin Page 1 of 5
- MATERIAL SAFETY DATA MSDS
S H E ET Polyester Catalyst
Print Date
01/21/11
| EP4920
Back to our homepage at: www.eagerplastics.com
SECTION 1 - IDENTIFICATION OF THE PRODUCT AND THE COMPANY
PRODUCT NAME EP4920 Polyester Catalyst TELEPHONE 773-927-3484
FROM Eager Polymers EMERGENCY (24hr) 815-545-8789
ADDRESS 3350 W. 48 Place, Chicago, IL 60632 CAS NO. See Section II
CHEMICAL NAME Methyl Ethyl Ketone Peroxide | CHEMICAL FORMULA Mixture of
(MEKP) many.
CHEMICAL FAMILY Organic Peroxide
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
COMPONENTS CAS NO. %
Methyl Ethyl Ketone Peroxide 1338-23-4 34
Dimethyl Phthalate 131-11-3 43
2,2,4-Trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 20
Hydrogen Peroxide 7722-84-1 01
Methyl Ethyl Ketone 78-93-3 02
Water 7732-18-5 01
SECTION 3 - HAZARD IDENTIFICATION OF THE PREPARATION
PHYSICAL HAZARDS Organic Peroxide. Decomposition
HEALTH HAZARDS Severe Irritant
EXPOSURE LIMITS The ACGIH Ceiling STEL is 1.5 mg/m? (0.2 ppm) for Methyl Ethyl Ketone
Peroxide.
ROUTES OF EXPOSURE
Skin Absorption Severe skin irritant, causes redness, blistering, and edema.
Eye Contact Eye contact causes severe corrosion and may cause blindness.
Ingestion Human systemic effects by ingestion: changes in structure or function of
esophagus, nausea, or vomiting, and other gastrointestinal effects.
Inhalation Moderately toxic by inhalation.
EFFECTS OF OVER- Prolonged inhalation of vapors may cause mucous membrane irritation and
EXPOSURE - vertigo. There are no known medical conditions, which are recognized as being
aggravated by exposure.
SECTION 4 - FIRST-AID MEASURES
Skin Immediately remove any contaminated clothing. Wash contaminated area thoroughly with
soap and copious amounts of water for at least 15 minutes. If irritation or adverse
symptoms develop seek medical attention.
Eyes Remove any contact lenses at once. Flush eyes with water for at least 15 minutes. Ensure
adequate flushing by separating the eyelids with fingers. If irritation or adverse symptoms
develop seek medical attention.
Ingestion | Contact a physician, hospital or Poison Control Center at once. DO NOT INDUCE
VOMITING.
Inhalation Remove to fresh air, if coughing, breathing becomes labored, irritation develops or other
symptoms develop, seek medical attention at once, even if symptoms develop several
hours after the exposure.
SECTION 5 - FIRE-FIGHTING MEASURES
FLASH POINT: (C.0.C)>200°F FLAMMABLE LIMITS: Unknown
FIRE EXTINGUISHER MEDIA Water from a safe distance — preferably with a fog nozzle. In case of very small
fires, other means such as carbon dioxide, foam or dry chemical extinguishers
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MSDS for MEK-P Methyl Ethyl Ketone Peroxide Catalyst / Hardener for Polyester Resin ~~ Page 2 of 5
SPECIAL FIRE FIGHTING
PROCEDURES
UNUSUAL FIRE AND
EXPLOSION HAZARDS
may be effective. Dry chemical combined with MEKP formulations may re-
ignite. Light water additives may be particularly effective at extinguishing
MEKP fires.
Firemen should be equipped with protective clothing and SCBA’s. In case of fire
near storage area, cool the containers with water spray. If dry chemical is used to
extinguish an MEKP fire, the extinguished area must be thoroughly wetted down
with water to prevent re-ignition.
The heat of decomposition of the peroxides adds to the heat of the fire. Dry
chemical fire extinguishing agent may catalyze the decomposition.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN
EVENT OF SPILL OR
RELEASE
Dike to prevent runoff from entering drains, sewers, streams, etc. and transfer into
containers. Spilled material should be swept up with an inert, moist diluent such
as perlite, vermiculite, or sand, and placed in a clean polyethylene drum or a
polyethylene pail. Wet drum or pail with water prior to sealing containers.
SECTION 7 - HANDLING AND STORAGE
HANDLING AND STORING
OTHER PRECAUTIONS
Keep containers closed to prevent contamination. Rotate stock using the oldest
material first. The activity and stability of MEKP is directly related to the
shipping and storage temperature history. Cool storage at 80°F or below is
recommended for longer shelf life and stability. Prolonged storage at elevated
temperatures of 100°F and higher will cause product degradation, gassing and
potential container rupture which can result in a fire and/or explosion.
MEKP should never be added to hot solvents or monomers as a violent
decomposition and/or reaction may result. When using spray equipment, never
spray raw MEKP onto curing or into raw resin or flues. Keep MEKP in its
original container. DO NOT STORE WITH FOOD OR DRINK. DO NOT USE
NEAR FOOD OR DRINK.
Unmixed, uncontaminated material, remaining at the end of the day, shall be
LI
returned to a proper organic peroxide storage area. [2] nder no circumstances
hna lA mantamian 1 La eandara nd + tha Anita] arta ia ne
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MSDS for MEK-P Methyl Ethyl Ketone Peroxide Catalyst / Hardener for Polyester Resin ~~ Page 3 of 5
| SECTION 8 - EXPOSURE CONTROL/PERSONAL PROTECTION
RESPIRATORY PROTECTION If airborne concentrations are expected to exceed acceptable levels wear a
NIOSH/MSHA approved air-purifying respirator with an organic vapor cartridge
or canister. When using respirators refer to OSHA’s 29CFR 1910.134.
VENTILATION Mechanical, general.
EYE PROTECTION Safety goggles recommended. Permanent eyewash is highly recommended.
HAND PROTECTION Protective gloves recommended, solvent resistant, such as butyl rubber, nitrile or
neoprene.
OTHER A safety shower and eyewash is recommended when the risk of a significant
exposure exits.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT °F Unknown SPECIFIC GRAVITY (Water=1) 1.1
VAPOR PRESSURE mm Hg. Unknown % VOLATILE BY Unknown
VOLUME
VAPOR DENSITY (Air=1) > 1
SOLUBILITY IN WATER Slight EVAPORATION RATE Unknown
APPEARANCE AND ODOR Water white liquid with a slight odor.
SECTION 10 - STABILITY AND REACTIVITY
INCOMPATIBILITY Dimethylaniline, cobalt napthenate and other promoters, promoted resins,
(Materials to avoid) accelerators, reducing agents, strong acids, bases, metals, metal alloys and salts,
sulfur compounds, amines or any hot material.
STABILITY Stable when kept in original, closed container, out of direct sunlight at
temperatures below 80°F.
HAZARDOUS Decomposition products are flammable. Acrid smoke and irritating fumes.
DECOMPOSITION PRODUCTS
HAZARDOUS Will not occur.
POLYMERIZATION
SECTION 11 - TOXICOLOGICAL INFORMATION
Methyl Ethyl Ketone Peroxide
Hazard Data:
Inhalation: Rat--LC,,: 200 ppm/4 hr, lung, thorax, respiration, or dyspnea; Mouse--L.C,: 170 ppm/4 hr, lung,
thorax, respiration, or dyspnea.
Intraperitoneal: Rat--LD.,: 65 mg/kg, behavioral, muscle weakness behavioral, ataxia.
Oral: Rat--LD.,: 484 mg/kg; Mouse--LD,: 470 mg/kg; Human--TD, : 480 mg/kg, changes in structure or
fimctinn
of esophagus gastrointestinal, nausea or vomiting gastrointestinal.
| Skin: Rabbit--LD,,: 500 mg.
Dimethyl Phthalate
Hazard Data:
Inhalation: Cat--LC; . 9300 mg/m>/6.5 hr.
Intraperitoneal: Mouse--LD;,: 1380 mg/kg.
Oral: Rat & Mouse--LD,,: 6800 mg/kg, somnolence behavioral, withdrawal nutritional and gross metabolic,
weight loss or decreased weight gain; Dog--LD: >1400 mg/kg; Rabbit--LD,: 4400 uL/kg.
Subcutaneous: Mouse--LD, ,: 6500 mg/kg, dyspnea lung, thorax, respiration, or cyanosis.
2,2,4-Trimethyl-1,3-pentanediol diisobutyrate
Hazard Data:
Oral: Rat--LD.,: >3200 mg/kg
Hydrogen Peroxide
Hazard Data:
Inhalation: Mouse--LC, y 227 ppm; Rat
Intraperitoneal: Mouse--LD.,: 880 mg/kg.
Intravenous: Rabbit--LD.,: 15 gm/kg, behavioral, convulsions or effect on seizure threshold.
Oral: Rat--LD.: 376 mg/kg, gastrointestinal, peritonitis blood, pigmented or nucleated red blood cells;
Mouse--LD,: 2 mg/kg.
Subcutaneous: Rat--LD.: 620 mg/kg; Mouse--LD.,: 1072 mg/kg.
Skin: Rat--LD: 4060 mg/kg, lung, thorax, respiration, or pulmonary emboli; Rabbit--LD; : 500 mg/kg,
TC, 5: 67 ppm/6hr/óW-1, dermatitis, irritative of the skin.
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MSDS for MEK-P Methyl Ethyl Ketone Peroxide Catalyst / Hardener for Polyester Resin Page 4 of 5
behavioral, convulsions or effect on seizure threshold.
Methyl Ethyl Ketone
Hazard Data:
Eye: Human: 350 ppm.
Inhalation: Rat--LC,,: 23500 mg/m°/8hr.
Intraperitoneal: Rat--LD.,: 607 mg/kg; Mouse--LD,: 616 mg/kg.
Oral: Rat--LD,: 2737 mg/kg; Mouse--LD;¿¡: 4050 mg/kg.
Skin: Rabbit--LD,: 6480 mg/kg.
Severely irritating to the skin, may cause redness, blistering, and edema. May be harmful if absorbed through the skin.
Irritating to the eyes may cause severe corrosion and blindness. Harmful if swallowed. May be harmful if inhaled.
Prolonged inhalation of vapors may cause mucous membrane irritation and vertigo.
SECTION 12 - ECOLOGICAL INFORMATION
Ecotoxicity: Methyl ethyl ketone peroxide: EC, (Guppy), 44.2 mg/L/96 hr; EC, (alga), 42,700 ug/L/96 hr.
Environmental Fate: Methyl ethyl ketone peroxide (MEKP) was evaluated for biodegradability in a closed bottle system anc
was reported to be readily biodegradable. An EC, of 16mg MEKP/L activated sludge was reported in an activated sludge
respiration inhibition test.
SECTION 13 - DISPOSAL CONSIDERATIONS
Prevent material from entering drains, sewers, streams, etc.
Immediately dispose of waste material at a RCRA approved hazardous waste management facility in accordance with federal,
state and local regulations.
SECTION 14 - TRANSPORT INFORMATION
DOT Shipping Name: ORGANIC PEROXIDE TYPE D, LIQUID
(METHYL ETHYL KETONE PEROXIDE, <45%)
DOT Hazard Class: 5.2
UN/NA ID No.: | UN3105
DOT Packing Group: PG II
DOT RQ RQ
2000 ERG GUIDE NO.: 145
SECTION 15 - REGULATORY INFORMATION
The following chemicals are subject to the reporting requirements of Section 313 of Title IIT of the Superfund Amendments
and Reauthorization Act of 1986 and 40 CFR Part 372.
Chemical Name CAS Number Percent
Dimethyl Phthalate 131-11-3 43
Methyl Ethyl Ketone 78-93-3 02
Reportable Quantity
2-Butanone Peroxide (MEKP): 10 Ibs (4.54 kg)
TSCA Status
The ingredients in this product are listed in the US Toxic Substances Control Act (TSCA) Inventory.
Canadian Domestic Substances List (DSL)
The ingredients in this product are listed in the Canadian DSL Inventory.
European Inventory of Existing Commercial Chemical Substances (EINECS)
The ingredients in this product are listed in the European EINECS Inventory.
Australian Inventory of Chemical Substances (AICS)
The ingredients in this product are listed in the Australian AICS Inventory.
Status of Carcinogicity
Not recognized as a carcinogen by the IARC, NTP or OSHA.
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MSDS for MEK-P Methyl Ethyl Ketone Peroxide Catalyst / Hardener for Polyester Resin Page 5 of 5
SECTION 16 - OTHER INFORMATION
VOC Information
Using ASTM Test Method D-2369-87, but at 40°C (since MEKP decomposes rapidly above 100°C and is not a VOC),
MEKP-9 contains 2.4% VOC, by weight, or 27 grams per liter. For more information call Norac.
NFPA 432 Organic Peroxide Classification
Class III
NFPA 704 Rating HMIS Rating
Health Flammability Reactivity Health Flammability Reactivity
3 2 2 3 2 2
DISCLAIMER OF LIABILITY
The information in this MSDS was obtained from sources, which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding
its correctness.
The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not
assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use, or disposal of the
product.
This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
Ш See CCR Title 8 Section 5461, NFPA 432, and UFC (91) Sec. 80.307.
[21 See NFPA 14-3
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SAFETY DATA SHEET Revision Date: 01/14/2011
| Print Date: 7/18/2011
MSDS Number: 000000042826
Envirez™ 70301 RESIN a Version: 1.6
T™ Trademark, Ashland or its subsidiaries,
registered in various countries596638
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
Ashland Regulatory Information Number 1-800-325-3751
P.O. Box 2219 Telephone 614-790-3333
Columbus, OH 43216 Emergency telephone number 1-800-ASHLAND (1-800-274-
5263)
Product name Envirez™ 70301 RESIN |
™ Trademark, Ashland or its subsidiaries, registered in various
countries
Product code 596638
Product Use Description No data
| 2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance: liquid
WARNING! FLAMMABLE LIQUID AND VAPOR. MAY AFFECT THE CENTRAL NERVOUS
SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. MAY BE HARMFUL IF INHALED.
ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE.
MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. PROLONGED OR
REPEATED CONTACT MAY DRY SKIN, CAUSE IRRITATION AND BURNS.
Potential Health Effects
Exposure routes
Inhalation, Skin absorption, Skin contact, Eye Contact, Ingestion
Eye contact
Can cause eye irritation. Symptoms include stinging, tearing, redness, and swelling of eyes.
ANLER LTUIILéeaN ©
Can cause skin irritation. Prolonged or repeated contact may dry the skin. Symptoms may
include redness, burning, and drying and cracking of skin, burns and other skin damage. Passage of this
Page 1/13
FAN LE à 5 Page: 2
SAFETY DATA SHEET Revision Date: 01/14/2011
Print Date: 7/18/2011
| MSDS Number: 000000042826
Envirez™ 70301 RESIN Version: 1.6
T™ Trademark, Ashland or its subsidiaries,
registered in various countries596638
material into the body through the skin is possible, but it is unlikely that this would result in harmful
effects during safe handling and use.
Ingestion
Swallowing small amounts of this material during normal handling is not likely to cause harmful
effects. Swallowing large amounts may be harmful. This material can get into the lungs during
swallowing or vomiting. This results in lung inflammation and other lung injury.
Inhalation |
Breathing aerosol and/or mist is possible when material is sprayed. Aerosol and mist may
present a greater risk of injury because more material may be present in the air than from vapor alone.
Breathing small amounts of this material during normal handling is not likely to cause harmful effects.
Breathing large amounts may be harmful. Symptoms are not expected at air concentrations below the
recommended exposure limits, if applicable (see Section 8.).
Aggravated Medical Condition
| Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure
to this material:, respiratory tract, skin, lung (for example, asthma-like conditions), liver, central nervous
system, male reproductive system, auditory system
Symptoms
Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage
of the material through the skin may include:, metallic taste, stomach or intestinal upset (nausea,
vomiting, diarrhea), irritation (nose, throat, airways), central nervous system depression (dizziness,
drowsiness, weakness, fatigue, nausea, headache, unconsciousness) and other central nervous system
~
, loss of coordination, confusion, liver damage
Target Organs
Overexposure to this material (or its components) has been suggested as a cause of the following
effects in laboratory animals:, mild, reversible kidney effects, effects on hearing, respiratory tract
damage (nose, throat, and airways), testis damage, liver damage, Overexposure to this material (or its
components) has been suggested as a cause of the following effects in humans:, mild effects on color
vision, effects on hearing, respiratory tract damage (nose, throat, and airways), central nervous system
effects
Carcinogenicity
There was no increase in cancer in rats expo ; 1.
increase in lung cancer in styrene-exposed mice. The relevance of the mouse lung cancer to humans is
uncertain. Styrene did not cause cancer in mice in studies in which the chemical was placed in the
stomachs through a feeding tube, or in a study in which styrene was given by Injection. Epidemiological
- ; ; +1 "ZA TT ral жи
to styrene by mhalation. However, there was an
Page 2 / 13
SAFETY DATA SHEET | Revision Date: 01/14/2011
Print Date: 7/18/2011
MSDS Number: 000000042826
Envirez™ 70301 RESIN | | Version: 1.6
TM Trademark, Ashland or its subsidiaries, | | |
registered in various countries596638
studies do not provide a basis for concluding that styrene causes cancer. Styrene is listed as a possible
human carcinogen by the International A gency for Research on Cancer (IARC).
Reproductive hazard |
This material (or a component) has been shown to cause harm to the fetus in laboratory animal
studies. Harm to the fetus occurs only at exposure levels that harm the pregnant animal. The relevance
of these findings to humans is uncertain.
Other information
Styrene readily reacts with low concentrations of halogens (for example, fluorine, chlorine,
bromine, or iodine) to form a tear-producing substance.
| | 3. COMPOSITION/INFORMATION ON INGREDIENTS |
Hazardous Components CAS-No. Concentration
STYRENE 100-42-5 >=20-<30%
| 4. FIRST AID MEASURES |
Eyes
If symptoms develop, immediately move individual away from exposure and into fresh air.
Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical
attention.
Skin | |
Remove contaminated clothing. Flush exposed area with large amounts of water. If skin is
damaged, seek immediate medical attention. If skin is not damaged and symptoms persist, seek
medical attention. Launder clothing before reuse.
Ingestion
Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth;
place individual on the left side with the head down. Contact a physician, medical facility, or poison
control center for advice about whether to induce vomiting. If possible, do not leave individual
unattended.
Page 3 / 13
As WALD Page: 4
SAFETY DATA SHEET Revision Date: 01/14/2011
Print Date: 7/18/2011
| MSDS Number: 000000042826
Envirez™ 70301 RESIN | Version: 1.6
™ Trademark, Ashland or its subsidiaries,
registered in various countries596638
Inhalation
If symptoms develop, move individual away from exposure and into fresh air. If symptoms
persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and
quiet; seek immediate medical attention.
Notes to physician
Hazards: This material is an aspiration hazard. Potential danger from aspiration must be
weighed against possible oral toxicity (See Section 2 - Swallowing) when deciding whether to induce
vomiting.
Treatment: No information available.
| 5. FIRE-FIGHTING MEASURES —
Suitable extinguishing media
Dry chemical, Foam, Water spray, Carbon dioxide (CO2)
Hazardous combustion products
May form:, carbon dioxide and carbon monoxide, toxic fumes, various hydrocarbons
Precautions for fire-fighting
Material is volatile and readily gives off vapors which may travel along the ground or be moved
by ventilation and ignited by pilot lights, flames, sparks, heaters, smoking, electric motors, static
discharge or other ignition sources at locations near the material handling point. Never use welding or
cutting torch on or near drum (even empty) because product (even just residue) can ignite explosively.
During a fire, irritating or toxic decomposition products may be generated. Wear full firefighting turn-out
gear (full Bunker gear), and respiratory protection (SCBA). Polymerization will take place under fire
conditions. If polymerization occurs in a closed container, there is a possibility it will rupture violently.
Cool storage container with water, if exposed to fire.
NFPA Flammable and Combustible Liquids Classification
Flammable Liquid Class IC
| 6. ACCIDENTAL RELEASE MEASURES |
Personal precautions
For personal protection see section 8. Eliminate all ignition sources (flares, flames including
pilot lights, electrical sparks). Persons not wearing protective equipment should be excluded from area
Page 4 / 13
FA WAL DD Page: 5
SAFETY DATA SHEET Revision Date: 01/14/2011
| Print Date: 7/18/2011
MSDS Number: 000000042826
Envirez™ 70301 RESIN Version: 1.6
™ Trademark, Ashland or its subsidiaries,
registered in various countries596638
of spill until clean-up has been completed. Stop spill at source. Prevent from entering drains, sewers,
streams or other bodies of water. Prevent from spreading. If runoff occurs, notify authorities as
required. Pump or vacuum transfer spilled product to clean containers for recovery. Absorb
unrecoverable product. Transfer contaminated absorbent, soil and other materials to containers for
disposal.
Environmental precautions
Prevent run-off to sewers, streams or other bodies of water. If run-off occurs, notify proper
authorities as required, that a spill has occurred.
Methods for cleaning up
Persons not wearing protective equipment should be excluded from area of spill until clean-up
has been completed. Stop spill at source, dike area of spill to prevent spreading, pump liquid to salvage
tank. Remaining liquid may be taken up on sand, clay, earth, floor absorbent, or other absorbent material
and shoveled into containers.
| 7. HANDLING AND STORAGE |
Handling
Containers of this material may be hazardous when emptied. Since emptied containers retain
product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be
observed. Avoid prolonged or frequently repeated skin contact with-this material. Skin contact can be
minimized by wearing impervious protective gloves. As with all products of this nature, good personal
hygiene is essential. Hands and other exposed areas should be washed thoroughly with soap and water
after contact, especially before eating and/or smoking. Regular laundering of contaminated clothing 1s
essential to reduce indirect skin contact with this material. Static ignition hazard can result from
handling and use. Electrically bond and ground all containers, personnel and equipment before transfer
or use of material. Special precautions may be necessary to dissipate static electricity for non-
conductive containers. Use proper bonding and grounding during product transfer as described in
National Fire Protection Association document NFPA 77. Warning. Sudden release of hot organic
chemical vapors or mists from process equipment operating at elevated temperature and pressure, or
sudden ingress of air into vacuum equipment, may result in ignitions without the presence of obvious
ignition sources. Published "autoignition" or "ignition" temperature values cannot be treated as safe
operating temperatures in chemical processes without analysis of the actual process conditions. Any use
of this product in elevated temperature processes should be thoroughly evaluated to establish and
maintain safe operating conditions.
Storage
Store in closed containers in a dry, well-ventilated area. Do not store near extreme heat, open
flame, or sources of ignition.
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Page: 6
Revision Date: 01/14/2011
Print Date: 7/18/2011
MSDS Number: 000000042826
Version: 1.6
SAFETY DATA SHEET
Envirez™ 7030] RESIN
™ Trademark, Ashland or its subsidiaries,
registered in various countries596638
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
Exposure Guidelines
STYRENE 100-42-5
ACGIH time weighted average 20 ppm
ACGIH Short term exposure limit 40 ppm
NIOSH Recommended exposure 50 ppm
limit (REL):
NIOSH Recommended exposure 215 mg/m3
limit (REL):
NIOSH Short term exposure limit 100 ppm
NIOSH Short term exposure limit 425 mg/m3
OSHA Z2 time weighted average 100 ppm
OSHA Z2 - Ceiling Limit Value: 200 ppm
OSHA 72 Maximum concentration: 600 ppm
General advice
These recommendations provide general guidance for handlin g this product. Personal protective
equipment should be selected for individual applications and should consider factors which affect
exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately
the responsibility of the employer to follow regulatory guidelines established by local authorities.
Exposure controls
Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure
below TLV(s). OSHA has formally endorsed a styrene industry proposal for a voluntary 50 ppm
workplace limit on styrene. Members of the Styrene Information and Research Council (SIRO),
Composites Institute (CI), Composite Fabricators Association (CFA), International Cast Polymers
Association (ICPA) and National Marine Manufacturers Association (NMMA) have agreed to use either
engineering controls, work practices or respiratory protection to achieve this voluntary limit for styrene.
Eye protection |
Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA
regulations also permit other type safety glasses. Consult your safety representative.
Skin and body protection
Wear resistant gloves (consult your safety equipment supplier)
Page 6 / 13
HEET
SAFETY DATA S
Envirez™ 70301 RESIN
™ Trademark, Ashland or its subsidiaries,
registered 1n various countries596638
Respiratory protection
Page: 7
Revision Date: 01/14/2011
Print Date: 7/18/2011
MSDS Number: 000000042826
1.6
Version:
If workplace exposure limit(s) of product or any component is exceeded (see exposure
guidelines), a NIOSH-approved air supplied respirator is advised in absence of proper environmental
control. OSHA regulations also permit other NIOSH respirators (negative pressure type) under
specified conditions (see your industrial hygienist). Engineering or administrative controls should be
implemented to reduce exposure.
| 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state
Form
Colour
Odour
Boiling point/boiling range
Melting point/range
Sublimation point
pH
Flash point
Ignition temperature
Evaporation rate
Lower explosion limit/Upper explosion limit
Particle size
Vapour pressure
Relative vapour density
Density
Bulk density
Water solubility
Solubility(ies)
Partition coefficient: n-octanol/water
log Pow
Autoignition temperature
Viscosity, dynamic
Viscosity, kinematic
Solids in Solution
Decomposition temperature
Burning number
Dust explosion constant
Minimum ignition energy
Page 7/13
liquid
no data available
no data available
no data available
293 °F / 145 °C
no data available
no data available
no data available
34.9 °F / 29.4 °C Seta closed cup
no data available
no data available
1.1 %(V) /6.1 %(V)
no data available
8.532 hPa (@ 77 °F / 25 °C Calculated Vapor
Pressure
no data available
1.078 g/lem3 @ 77 °F / 25 °C
No data
insoluble
no data available
no data available
no data available
no data available
no data available
no data available
no data available
no data available
no data available
no data available
no data available
в. Page: 8
HEET Revision Date: 01/14/2011
Print Date: 7/18/2011
MSDS Number: 000000042826
Envirez™ 70301 RESIN Version: 1.6
™ Trademark, Ashland or its subsidiaries,
registered in various countries596638
SAFETY DATA S
| 10. STABILITY AND REACTIVITY
Stability
Stable.
Conditions to avoid
Avoid heat, open flame, and prolonged storage at elevated temperatures., Avoid contact with:,
excessive heat
Incompatible products |
Avoid contact with:, acids, aluminum chloride, halogens, iron chloride, metal salts, peroxides,
strong alkalis, strong oxidizing agents
Hazardous decomposition products
May form:, carbon dioxide and carbon monoxide, toxic fumes, various hydrocarbons
Hazardous reactions
Product can undergo hazardous polymerization, Avoid exposure to excessive heat, peroxides
and polymerization catalysts.
Thermal decomposition
No data
| 11. TOXICOLOGICAL INFORMATION |
Acute oral toxicity
STYRENE : LD 50 Rat: 2,650 mg/kg
Acute inhalation toxicity |
STYRENE ; LC 50 Rat: 2800 ppm; 4 h
Acute dermal toxicity
STYRENE : no data available
Page 8 / 13
FA £n 0 5 | | Page: 9
SAFETY DATA SHEET Revision Date: 01/14/2011
Print Date: 7/18/2011
MSDS Number: 000000042826
Envirez™ 70301 RESIN | Version: 1.6
™ Trademark, Ashland or its subsidiaries,
registered in various countries596638
[12. ECOLOGICAL INFORMATION
Biodegradability
STYRENE : no data available
Bioaccumulation
STYRENE : no data available
Toxicity to fish
STYRENE : no data available
Toxicity to daphnia and other aquatic invertebrates.
STYRENE : no data available
Toxicity to algae
STYRENE | : no data available
Toxicity to bacteria
STYRENE : no data available
Biochemical Oxygen Demand (BOD)
STYRENE : no data available
Chemical Oxygen Demand (COD)
STYRENE : no data available
Additional ecological information
STYRENE : no data available
Page 9 / 13
SS
Jo
SAFETY DATA S
H
Envirez™ 70301 RESIN
™ Trademark,
Ashland or its subsidiaries,
registered in various countries596638
Page: 10
Revision Date: 01/14/2011
Print Date: 7/18/2011
MSDS Number: 000000042826
Version: 1.6
“| 13. DISPOSAL CONSIDERATIONS
Waste disposal methods
Contaminated absorbent may be deposited in a landfill in accordance with local, state and federal
regulations. Destroy by liquid incineration in accordance with applicable regulations. Dispose of in
accordance with all applicable local, state and federal regulations. Do not discharge effluent containing
this product into lakes, streams, ponds or estuaries, oceans, or other waters unless in accordance with
the requirements of a National Pollutant Discharge Elimination System (NPDES) permit, and the
permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing
this product to sewer systems without previously notifying the local sewage treatment plant authority.
For guidance, contact your State Water Board or Regional Office of the EPA. For assistance with your
waste management needs - including disposal, recycling and waste stream reduction, contact Ashland
Distribution's Environmental Services Group at 800-637-7922.
=
| 14. TRANSPORT INFORMATION
REGULATION |
ID PROPER SHIPPING NAME ‘| *HAZARD | SUBSIDIARY | PACKING | MARINE
NUMBER CLASS HAZARDS GROUP | POLLUTANT
| / LTD. QTY.
MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND
WASTES
[UN 1866 RESINA, SOLUCIONES DE 3 I |
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER
[UN 1866 Resin solution 3 Ш |
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO
¡UN 1866 Resin solution 3 Ш |
INTERNATIONAL MARITIME DANGEROUS GOODS
|UN 1866 RESIN SOLUTION 3 Ш ||
TRANSPORT CANADA - INLAND WATERWAYS
[UN 1866 RESIN SOLUTION 3 Ш |
TRANSPORT CANADA - RAIL
[UN 1866 RESIN SOLUTION 3 Ш
Page 10 / 13
SAFETY D
Bs
+
ATA SHEET
Envirez™ 70301 RESIN
™ Trademark, Ashland or its subsidiaries,
registered in various countries596638
TRANSPORT CANADA - ROAD
Page: 11
Revision Date: 01/14/2011
Print Date: 7/18/2011
MSDS Number: 000000042826
Version: 1.6
[UN 1866 RESIN SOLUTION 3 Ш |
U.S. DOT - INLAND WATERWAYS
[UN 1866 Resin solution 3 Ш |
U.S. DOT - RAIL
[UN 1866 Resin solution 3 Ш |
U.S. DOT - ROAD |
[UN 1866 Resin solution 3 Ш |
*ORM = ORM-D, CBL = COMBUSTIBLE LIQUID
Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific
exceptions that can be applied. Consult shipping documents for descriptions that are specific to the
shipment.
| 15. REGULATORY INFORMATION
California Prop. 65
—~ .
NENE A a. A
of California to cause cancer.
WARNING! This product contains a chemical known to the State
BENZENE
WARNING! This product contains a chemical known to the State
of California to cause birth defects or other reproductive harm.
BENZENE
SARA Hazard Classification
Fire Hazard
Acute Health Hazard
Chronic Health Hazard
Reactivity Hazard
SARA 313 Component(s)
STYRENE
Page 11 / 13
29.98 %
HEET
SAFETY DATA S
EnvirezTM 70301 RESIN
TM Trademark, Ashland or its subsidiaries,
registered in various countries596638
New Jersey RTK Label Information
POLYMER (8)
STYRENE
Pennsylvania RTK Label Information
POLYMER (8)
STYRENE
Notification status
US. Toxic Substances Control Act
Canada. Canadian Environmental Protection Act (CEPA).
Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133)
Australia. Industrial Chemical (Notification and Assessment)
Act |
New Zealand. Inventory of Chemicals (NZIoC), as published
by ERMA New Zealand
Japan. Kashin-Hou Law List |
Korea. Toxic Chemical Control Law (TCCL) List
Philippines. The Toxic Substances and Hazardous and Nuclear
Waste Control Act
China. Inventory of Existing Chemical Substances
Reportable quantity - Product
US. EPA CERCLA Hazardous Substances (40 CFR 302)
Reportable quantity-Components
STYRENE 100-42-5
Health
Flammabili
Physical hazards
Instabili
Specific Hazard
| Page: 12
Revision Date: 01/14/2011
Print Date: 7/18/2011
MSDS Number: 000000042826
Version: 1.6
300986-5634P
100-42-5
300986-5634P
100-42-5
y (positive listing)
y (positive listing)
n (Negative listing)
- n (Negative listing)
n (Negative listing)
n (Negative listing)
y (positive listing)
n (Negative listing)
3335 Ibs
1000 165
NFPA
2
3
| 16. OTHER INFORMATION
Page 12/13
FAY mw WALD) Page: 13
SAFETY DATA SHEET Revision Date: 01/14/2011
| Print Date: 7/18/2011
MSDS Number: 000000042826
Envirez™ 70301 RESIN Version: 1.6
™ Trademark, Ashland or its subsidiaries,
registered in various countries596638
The information accumulated herein is believed to be accurate but is not warranted to be whether
originating with the company or not. Recipients are advised to confirm in advance of need that the
information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by
Ashland's Environmental Health and Safety Department (1-800-325-3751).
Page 13 / 13
Material Safety Data Sheet
Densified Granite Effect Series & Luxury Series Granite MSDS No. 9623.18
Date of Preparation: 7/16/96 Revision: 8/4/09
Section 1 - Chemical Product and Company Identification
Product/Chemical Name: Densified Granite Effect, all colors
General Use: Used in solid surface applications
Manufacturer: The R. J. Marshall Company Emergency Phone: (800) 424-9300
26776 W. 12 Mile Road Date Revised: 8/4/09
Southfield, MI 48034-7807 Prepared By: Stephanie Nichols
(248) 353-4100
Section 2 - Composition / Information on Ingredients
Ingredient Name | CAS Number |
Alumina Trihydrate 21645-51-2
Filled Polyester | eee
Trace Impurities:
| OSHA | PEL ACGIH | TL
Ingredient TWA STEL TWA STEL
Alumina Trihydrate none estab. none estab. None estab. none estab.
Filled Polyester — |none estab. none estab. None estab. none estab.
Section 3 - Hazards Identification
HMIS
TT Emergency Overview XA H |
F 0
. IR O
Potential Health Effects PPETE
Primary Entry Routes: Inhalation, Eye, and Ingestion Sec. 8
Acute Effects
Inhalation: Inhalation of high concentrations of this inert particulate can result in mild irritation of the respiratory tract.
Eye: May cause irritation through mechanical abrasion.
Skin: May cause irritation through mechanical abrasion.
Ingestion: Unlikely.
Carcinogenicity: IARC, OSHA, and NTP do not list this product or any of its components as a carcinogen.
Chronic Effects: n/a
Section 4 - First Aid Measures
Inhalation: If overcome by high dust concentrations, remove to a ventilated area. Seek medical attention for any symptoms that
may develop.
Eye Contact: Flush eyes thoroughly for 15 minutes taking care to rinse under eyelids. Do not scrub. Abrasion may cause
irritation. If discomfort continues, continue to wash with water. If irritation persists, consult a physician.
Skin Contact: Wash skin thoroughly with soap and water for at least 15 minutes. Consult a physician if irritation persists.
Ingestion: Consult a physician,
After first aid, get appropriate in-plant, paramedic, or community medical support.
Note to Physicians: n/a
Special Precautions/Procedures: n/a
Section 5 - Fire-Fighting Measures
Flash Point: n/a
Flash Point Method: n/a
Burning Rate: not determined.
Autoignition Temperature: not determined
Flammability Classification: Non-flammable.
Extinguishing Media: Water spray, carbon dioxide or other dry chemical.
Unusual Fire or Explosion Hazards: None known.
Hazardous Combustion Products: May include carbon monoxide, carbon dioxide, smoke, oxides of nitrogen, and styrene.
Revision date 8/4/09 Densified Granite Effect & Luxury Series Granites MSDS No. 9623.18
Fire-Fighting Instructions: Do not release runoff from fire control methods to sewers or waterways.
Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products, wear a self-contained breathing
apparatus (SCBA) with a full facepiece operated in pressure-demand or positive-pressure mode.
Section 6 - Accidental Release Measures
Spill /Leak Procedures: Collect solids. Recycle if possible.
Regulatory Requirements: Follow applicable OSHA regulations (29 CFR 1910.120).
Section 7 - Handling and Storage
Handling Precautions: Avoid generating dust during handling.
Storage Requirements: Keep material dry.
Section 8 - Exposure Controls / Personal Protection
Engineering Controls:
Ventilation: Provide general or local exhaust ventilation systems to maintain airborne concentrations below OSHA PELs
(Sec. 2). Local exhaust ventilation is preferred because it prevents contaminant dispersion into the work area by controlling it at
its source.
Administrative Controls:
Respiratory Protection: Seek professional advice prior to respirator selection and use. Follow OSHA respirator regulations
(29 CFR 1910.134) and, if necessary, wear an MSHA/NIOSH-approved respirator. Select respirator based on its suitability to
provide adequate worker protection for given working conditions, level of airborne contamination, and presence of sufficient
oxygen.
Protective Clothing/Equipment: Wear protective eyeglasses or chemical safety goggles, per OSHA eye- and face-protection
regulations (29 CFR 1910.133). Contact lenses are not eye protective devices. Appropriate eye protection must be worn instead
of, or in conjunction with contact lenses.
Contaminated Equipment: Separate contaminated work clothes from street clothes. Launder before reuse. Remove this
material from your shoes and clean personal protective equipment.
Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before
eating, drinking, smoking, using the toilet, or applying cosmetics.
co Section 9 - Physical and Chemical Properties
Physical State: Powder Water Solubility: Slight.
Appearance and Odor: odorless, color varies. Other Solubilities: n/a
Odor Threshold: n/e Boiling Point: n/a
Vapor Pressure: n/a Freezing/Melting Point:n/a
Vapor Density (Air=1):n/a Viscosity: n/a
Formula Weight: n/a Refractive Index: n/a
Density: n/e Surface Tension: n/a
Specific Gravity (H),O=1, at 4 *C):2.2-2.3 % Volatile: n/a
pH: n/e Evaporation Rate: n/e
Section 10 - Stability and Reactivity
Stability: DGE is stable at room temperature in closed containers under normal storage and handling conditions.
Polymerization: Hazardous polymerization cannot occur.
Chemical Incompatibilities: Strong alkaline may destroy surface appearance.
Conditions to Avoid: None known.
Hazardous Decomposition Products: Thermal oxidative decomposition of DGE may produce carbon monoxide, carbon
dioxide, smoke, oxides of nitrogen, and styrene.
Page 2 of 4
Revision date 8/4/09 Densified Granite Effect & Luxury Series Granites MSDS No. 9623.18
Section 11- Toxicological Information
Toxicity Data:*
Eye Effects: Nuisance dust. May cause Acute Inhalation Effects: Overexposure to dust may cause irritation
irritation through mechanical abrasion. Flush to the respiratory tract. Should this occur, remove affected individual
with water for at least 15 minutes. Consult to fresh air. If symptoms persist, consult a physician.
physician if irritation is persistent.
Skin Effects: Nuisance dust. May cause Acute Oral Effects: None known.
irritation through mechanical abrasion. Wash Chronic Effects: None known.
skin thoroughly with soap and water. Carcinogenicity: Neither this product nor any of its components are
listed as carcinogens by IARC, NTP, OSHA, or ACGIH.
Section 12 - Ecological Information
No information available.
“Section 13 - Disposal Considerations
Disposal: Contact your supplier or a licensed contractor for detailed recommendations. Follow applicable Federal, state, and
local regulations.
Section 14 - Transport Information
DOT Transportation Data (49 CFR 172.101): This product is not classified as dangerous under the transport
regulation for road, rail, sea, or air transport.
Section 15 - Regulatory Information
EPA Regulations:
RCRA Hazardous Waste Number: Not listed (40 CFR 261.33)
RCRA Hazardous Waste Classification: Not classified
CERCLA Hazardous Substance (40 CFR 302.4) not listed
SARA Toxic Chemical (40 CFR 372.65): Not listed
SARA EHS (Extremely Hazardous Substance) (40 CFR 355): Not listed
OSHA Regulations:
Air Contaminant (29 CFR 1910.1000, Table Z-1, Z-1-A): Not listed
TSCA
This substance or all of its components are on the Chemical Substances Inventory of the Toxic Substance Control Act (TSCA
Inventory [USA]). Please note that this product is not subject to any legal reporting requirements under these acts
INTERNATIONAL REGULATIONS
Canadian Domestic Substances List: Components of this product are listed on the Canadian DSL.
European Community: Components of this product are listed on ECOIN, the European Core Inventory (EC) market.
Page 3 of 4
Revision date 8/4/09
Densified Granite Effect & Luxury Series Granites
Section 16 - Other Information
MSDS No. 9623.18
Prepared By: Stephanie Nichols
Revision Notes: Updated product codes
Product Grades Available from the R. J. Marshall Company (this list may be incomplete):
DGE 200 DGE 622 LXS 355 LXX 629 DGE 330B SPR 570
DGE 205 DGE 625 LXS 365 LXX 855 DGE 390B SPR 670
DGE 209 DGE 725 LXS 370 LXX 903 DGE 622B
DGE 210 DGE 750 LXS 450 LXX 904 LXX 202B
DGE 300 DGE 800 LXS 630 LXX 905 |
DGE 305 DGE 805 LXS 720 LXX 910 SPC 213
DGE 307 LXS 850 LXX 911 SPC 214
DGE 310 LXS 203 LXX 912 SPC 260
DGE 320 LXS 206 LXX 202 LXX 204SE SPC 324
DGE 321 LXS 212 LXX 204 LXX 260SE SPC 626
DGE 330 LXS 230 LXX 260 LXX 302SE SPC 807
DGE 335 LXS 235 LXX 302 LXX 327SE SPR 204
DGE 340 LXS 315 LXX 32 XX 357SE SPR 250
DGE 390 LXS 319 LXX 336 LXX 430SE SPR 312
DGE 400 LXS 320 LXX 357 LXX 435SE SPR 331
DGE 420 LXS 322 LXX 430 LXX 629SE SPR 352
DGE 620 LXS 345 LXX 435 LXX 855SE SPR 430
Note: This includes all EXP DGE blends and all DGE SB, DGE F, LXSSB, and GRN special blends.
Disclaimer: Information contained herein is presented in good faith and is based on data believed to be accurate. However no
warranty is expressed or implied regarding this information or the results obtained from the use of this Material Safety Data
Sheet, whether it originates with The R. J. Marshall Company or others. This Material Safety Data Sheet relates only to the
specific material designated herein. It does not relate to use with other material or processes. This information is supplied with
the condition that the use will make appropriate determination as to its suitability for their purpose prior to using it.
Page 4 of 4
= MATERIAL SAFETY DATA SHEET
REVISION DATE: OCTOBER 26 2011
Research
CORPORATION
HK RESEARCH CORPORATION
PO Box 1809 EMERGENCY TELEPHONE
908 Lenoir Road
Hickory, NC 28603 828-328-1721
(828) 328-1721
kkkkxkkkkkkk* PRODUCT IDENTIFICATION + sd ax
TRADE NAME: POLYESTER PIGMENT DISPERSION
CAS NUMBER: MIXTURE PRODUCT CODE: HGY-9396
PRODUCT DESCRIPTION: OLIVE D-COLOR PASTE
CHEMICAL FAMILY: NA DOT CLASS: PIGMENT, NOI LIQUID OR PASTE
MOLECULAR FORMULA: NA DOT SHIP NAME: Item 149980 Sub 2
MOLECULAR WEIGHT: NA
de de de dx dx XXX * PRODUCT HAZARD SUMMARY + % e de dr % do dolor
HMIS <CODE>
HEALTH: <2>
CAUTION!
MAY BE HARMFUL IF SWALLOWED OR INHALED
* *
* MAY BE IRRITATING TO THE SKIN EYES AND RESPIRATORY TRACT
* MAY CAUSE ALLERGIC SKIN REACTION
* HEATED MATERIAL MAY CAUSE THERMAL BURNS
FLAMMABILITY : <1>
* WARNING! KEEP AWAY FROM OPEN FLAME!
REACTIVITY: <1>
* CAUTION! UNSTABLE AT HIGH TEMPERATURES
SPECIFIC HAZARD: <--->
de dd IMPORTANT COMPONENTS **kkkkkkkkkkk
INGREDIENT CAS # % OSHA PEL ACGIH-TLV
UNSATURATED POLYESTER RESIN MIXTURE 41 - 51 NO DATA NO DATA
TITANIA 013463-67-7 38 - 48 10 mg/m’ 15 mg/m’
INORGANIC METAL OXIDE N/A 1 - 10 15 mg/m’ 10 mg/m?
CARBON BLACK 001333-86-4 1 - 6 3.5mg/m° 3.5mg/m°
REMAINING COMPONENTS NOT DETERMINED TO BE HAZARDOUS AND/OR HAZARDOUS
COMPONENTS PRESENT AT LESS THAN 1.0% (0.1% FOR CARCINOGENS)
page 1 of 5
dx PHYSICAL DATA ddr
BOILING POINT, °C (°F): Non Volatile
VAPOR PRESSURE, mm Hg: <5 @ 20°C (68°F)
VAPOR DENSITY (AIR=1): NA
SOLUBILITY IN WATER: NEGLIGIBLE
SPECIFIC GRAVITY (H20=1) : 1.74 +/- 5% @ 25°C
PERCENT VOLATILE: <1
EVAPORATION RATE (n-Bu AC=1: <l
APPEARANCE /ODOR: GRAY LIQUID WITH SLIGHT ODOR
********* FIRE AND EXPLOSION HAZARD DATA * kkk kkk *
FLASH POINT °C (°F): GREATER THAN 93°C (200 °F)
FLAMMABILITY CLASSIFICATION: PLASTIC LIQUID OR PASTE - NOT REGULATED
AUTOIGNITION TEMPERATURE, °C (°F): 490 (914)
FLAMMABILITY LIMITS IN AIR (% by volume): NA UPPER: NA
BASIC FIREFIGHTING PROCEDURES:
Use dry chemical, all-purpose or polar AFFF foam or water spray to
extinguish fire. Water or foam may cause frothing, with further application
leading to boilover. Foam may have limited effectiveness on three
dimensional fires. Use water spray to cool fire-exposed containers,
structures and to protect personnel. Use water to flush spills away from
source of ignition. Do not flush down public sewers.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Fire may produce poisonous or irritating gas, fumes or vapor. Containers may
explode in heat of fire. Exposed firefighters should wear MSHA/NIOSH
approved self-contained breathing apparatus, with full face mask and full
protective equipment.
AAA PRODUCT HEALTH HAZARD INFORMATION *XxxXXXXXXXX%
ROUTE OF EXPOSURE
INGESTION:
Moderately Toxic. May cause gastrointestinal disturbances. Symptoms may
include irritation, nausea, vomiting and diarrhea. Seek immediate
medical attention if ingested.
SKIN: |
Moderately Irritating. Repeated or prolonged skin contact may cause
reddening, inflammation or blistering. May cause allergic reactions in some
individuals. Contact with heated material may cause thermal burns.
EYE:
Moderately Irritating. Direct contact may cause temporary corneal lesions.
Contact with heated material may cause thermal burns.
page 2 of 5
INHALATION:
NOT APPLICABLE /MEANINGFUL FOR COLOR PASTE DISPERSIONS.
******* EMERGENCY AND FIRST AID *****k*****
INGESTION:
DO NOT INDUCE VOMITING BECAUSE OF DANGER OF ASPIRATING LIQUID INTO LUNGS
AND/OR BURNING (IRRITATING) ESOPHAGUS AGAIN. If spontaneous vomiting
occurs, monitor for breathing difficulty. Keep affected person warm and at
rest. Get immediate medical attention.
SKIN CONTACT:
Wash area of contact thoroughly with soap and water. Remove contaminated
clothing immediately. Place contaminated clothing in closed container for
storage until laundered or discarded. If clothing is to be laundered,
inform person performing operation of contaminant's hazardous properties.
Get medical attention if irritation persists.
EYE CONTACT:
Flush immediately with large amounts of water. Eye lids should be held away
from the eyeball to insure thorough rinsing. Get medical attention if
irritation persists.
INHATATION:
Remove affected person from source of exposure. If breathing is difficult,
give oxygen. Keep affected person warm and at rest. Get immediate medical
attention.
kkkkkkkkk* REACTIVITY DATA dde dada
STABILITY/INCOMPATIBILITY:
Stable under normal conditions of use. Avoid contact with strong oxidizers.
Mixtures with uninhibited monomers may result in auto-polymerization.
HAZARDOUS REACTIONS/DECOMPOSITION PRODUCTS:
Thermal decomposition products may be hazardous. Reacts vigorously with
oxidizing agents.
********* SPILL OR LEAK PROCEDURES **%%kk%%kkx%
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
No flares, smoking, flames, sparks & other sources of ignition in hazardous
area. Stop leak if you can do it without risk. Use water spray to reduce
vapors.
--SMALL SPILLS--Take up with sand or other noncombustible absorbent material
or other sorbent known to be compatible, then flush area with water.
--LARGE SPILLS--Dike far ahead of spill for later disposal.
WASTE DISPOSAL METHOD:
Incinerate in an approved incinerator or dispose of in a chemical dump in
accordance with local, state and federal regulations.
page 3 of 5
******** PERSONAL PROTECTION INFORMATION *******x
EYE PROTECTION:
Wear safety glasses or chemical goggles to prevent eye contact. Do not wear
contact lenses when working with this substance. Have eye baths readily
available where eye contact can occur.
SKIN PROTECTION:
Wear impervious gloves and protective clothing to prevent skin contact.
Suggested protective materials are: Polyvinyl alcohol, Polyethylene and
Viton. Provide safety showers at any location where skin contact can occur.
RESPIRATORY PROTECTION:
Use NIOSH or MSHA approved equipment when airborne exposure limits are
exceeded. NIOSH/MSHA approved breathing equipment may be required for
non-routine and emergency use. Ventilation may be used to control or reduce
airborne concentrations.
******** SPECIAL PRECAUTIONS ***k*kkkkkkkk
HANDLING/STORAGE :
Store in tightly closed containers in cool, dry, isolated, well-ventilated
area away from heat, sources of ignition and incompatibles.
"Empty" containers may contain toxic, flammable/combustible or explosive
residue or vapors. Do not cut, grind, drill, weld or reuse containers
unless adequate precautions are taken against these hazards.
Information contained herein is presented in good faith and is based on
data believed to be accurate. However, no warranty is expressed or
implied regarding this information or the results obtained from the use of
this Material Safety Data Sheet whether it originated with HK Research
Corporation or not. This Material Safety Data Sheet relates only to the
specific material designated herein and does not relate to use with any
other material or process. This information is supplied with the
condition that the user will make the appropriate determination as to its
suitability for their purposes prior to use. HK Research Corporation
assumes no legal responsibility for use or reliance upon this information.
page 4 of 5
MATERIAL SAFETY DATA SHEET ADDENDUM
California Proposition 65 Statement
California Proposition 65 involving warnings of the presence of certain
listed chemicals is now in effect.
HK Research Corporation believes the law requires us to inform you that
detectable amounts of any of the listed chemicals might be present in HK
Research products. Based on a review of the list, HK Research products,
like all synthetic and naturally occurring chemical substances,
may conceivably contain trace contaminants of some of the listed substances.
While not necessarily added to HK Research Corporation products as
ingredients, some of the listed chemicals may be present in the raw
materials as received from suppliers over which we have no control.
In order to comply with the California Law, even though some of the listed
substances may not t represent a significant risk as defined by the
E = las >
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"Warning: HK Research Corporation products may contain
trace amounts of some chemicals considered by the State
of California to be carcinogens or reproductive Toxicants."
page 5 of 5
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