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Spies Hecker Material Safety Data Sheet
1. Identification of the substance/mixture and of the company/undertaking
Product name
R Hi-TEC Base Coat 480 Diamond White
Permahyd
Product code
WT 377
Intended use
Coating for professional use
Formula Date: 2015-03-05
Spies-Hecker
50 Applied Card Way, Suite 300
US Glen Mills, PA 19342
Telephone
Product information
Medical emergency
Transportation emergency
(888) 371-3313
(855) 274-5698
(800) 424-9300
2. Hazards identification
This preparation is hazardous per the following GHS criteria
GHS-Classification
Serious eye damage/eye irritation
Category 1
Endpoints which are “not classified”, “cannot classified” and “not applicable” are not shown.
GHS-Labelling
Hazard symbols
Signal word
Danger
Hazard statements
Causes serious eye damage.
Precautionary statements
Wear eye protection/ face protection.
Immediately call a POISON CENTER or doctor/ physician.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
Other hazards which do not result in classification
Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
The following percentage of the mixture consists of ingredient(s) with unknown acute toxicity:
9.9 %
3. Composition/information on ingredients
Mixture of synthetic resins, pigments, and solvents as well as water
Components
CAS-No.
71-41-0
Chemical Name
N-pentanol
Concentration
1 - 4%
B12206249
Axalta and Axalta Coating Systems are trademarks or registered trademarks of Axalta Coating Systems, LLC and all affilR Permahyd,
R Permasolid,
R Permacron,
R Priomat
R , Permafleet,
R Permaloid,
R Permafast
R
iates. Spies Hecker,
R are registered trademarks of Axalta Coating Systems, LLC and all affiliates. All rights reserved.
and Raderal
1-9
2016-01-27
Spies Hecker Material Safety Data Sheet
CAS-No.
Chemical Name
Concentration
71-23-8
N-propanol
1 - 4%
107-98-2
Propylene glycol methyl ether
1 - 4%
13463-67-7
Titanium dioxide
1.9%
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Non-regulated ingredients 80 - 90%
OSHA Hazardous: Yes
* Assigned CAS No. - An official CAS No. does not exist. The CAS No. shown is for a similar chemical.
4. First aid measures
Eye contact
Remove contact lenses. Irrigate copiously with clean, fresh water for at least 15 minutes, holding the eyelids apart. Seek medical
advice.
Skin contact
Do NOT use solvents or thinners. Take off all contaminated clothing immediately. Wash skin thoroughly with soap and water or use
recognized skin cleanser. If skin irritation persists, call a physician.
Inhalation
Avoid inhalation of vapour or mist. Move to fresh air in case of accidental inhalation of vapours. If breathing is irregular or stopped,
administer artificial respiration. If unconscious place in recovery position and seek medical advice. If symptoms persist, call a
physician.
Ingestion
If swallowed, seek medical advice immediately and show this container or label. Do NOT induce vomiting. Keep at rest.
Most Important Symptoms/effects, acute and delayed
Inhalation
May cause nose and throat irritation. If this product mixed with an isocyanate activator/hardener (see MSDS for the activator), the
following health effects may apply: Exposure to isocyanates may cause respiratory sensitization. This effect may be permanent.
Symptoms include an asthma-like reaction with shortness of breath, wheezing, cough or permanent lung sensitization. This effect
may be delayed for several hours after exposure. Repeated overexposure to isocyanates may cause a decrease in lung function,
which may be permanent. Individuals with lung or breathing problems or prior reactions to isocyanates must not be exposed to
vapors or spray mist of this product.
Ingestion
May result in gastrointestinal distress.
Skin or eye contact
May cause irritation or burning of the eyes. Repeated or prolonged liquid contact may cause skin irritation with discomfort and
dermatitis.
If this product is mixed with an isocyanate, skin contact may cause sensitization.
Indication of Immediate medical attention and special treatment needed if necessary
No data available on the product. See section 3 and 11 for hazardous ingredients found in the product.
5. Firefighting measures
B12206249
Axalta and Axalta Coating Systems are trademarks or registered trademarks of Axalta Coating Systems, LLC and all affilR Permahyd,
R Permasolid,
R Permacron,
R Priomat
R , Permafleet,
R Permaloid,
R Permafast
R
iates. Spies Hecker,
R are registered trademarks of Axalta Coating Systems, LLC and all affiliates. All rights reserved.
and Raderal
2-9
2016-01-27
Spies Hecker Material Safety Data Sheet
Suitable extinguishing media
Water spray, Dry chemical, Foam.
Extinguishing media which shall not be used for safety reasons
High volume water jet
Hazardous combustion products
CO, CO2, smoke, and oxides of any heavy metals that are reported in “Composition, Information on Ingredients” section.
Fire and Explosion Hazards
Avoid heating above flash point.
Special Protective Equipment and Fire Fighting Procedures
Full protective flameproof clothing should be worn as appropriate. Wear self contained breathing apparatus for fire fighting if
necessary. In the event of fire, cool tanks with water spray. Do not allow run-off from fire fighting to enter public sewer systems or
public waterways.
6. Accidental release measures
Procedures for cleaning up spills or leaks
Ventilate area. If heated above the flashpoint, remove sources of ignition. Prevent skin and eye contact and breathing of vapor. If the
material contains, or is mixed with an isocyanate activator/hardener: Wear a positive-pressure, supplied-air respirator (NIOSH
approved TC-19C), eye protection, gloves and protective clothing. Pour liquid decontamination solution over the spill and allow to sit
at least 10 minutes. Typical decontamination solutions for isocyanate containing materials are: 20% Surfactant (Tergitol TMN 10) and
80% Water OR 0 -10% Ammonia, 2-5% Detergent and Water (balance) Pressure can be generated. Do not seal waste containers for
48 hours to allow C02 to vent. After 48 hours, material may be sealed and disposed of properly. If material does not contain or is not
mixed with an isocyanate activator/hardener: Wear a properly fitted air-purifying respirator with organic vapor cartridges (NIOSH
approved TC-23C), eye protection, gloves and protective clothing. Confine, remove with inert absorbent, and dispose of properly.
Environmental precautions
Do not let product enter drains. Notify the respective authorities in accordance with local law in the case of contamination of rivers,
lakes or waste water systems.
7. Handling and storage
Precautions for safe handling
Observe label precautions. Keep away from heat, flame and other sources of ignition. When heated above its flash point, this must
be handled as if it were a flammable liquid. Close container after each use. Do not transfer contents to bottles or unlabeled
containers. Wash thoroughly after handling and before eating or smoking.
If material is a coating: do not sand, flame cut, braze or weld dry coating without a NIOSH approved air purifying respirator with
particulate filters or appropriate ventilation, and gloves. Combustible dust clouds may be created where operations produce fine
material (dust). Avoid formation of significant deposits of material as they may become airborne and form combustible dust clouds.
Build up of fine material should be cleaned using gentle sweeping or vacuuming in accordance with best practices. Cleaning methods
(e.g. compressed air) which can generate potentially combustible dust clouds should not be used.
Advice on protection against fire and explosion
Solvent vapours are heavier than air and may spread along floors. Vapors may form explosive mixtures with air and will burn when an
ignition source is present. Always keep in containers of same material as the original one. Never use pressure to empty container:
container is not a pressure vessel. The accumulation of contaminated rags may result in spontaneous combustion. Good
housekeeping standards and regular safe removal of waste materials will minimize the risks of spontaneous combustion and other
fire hazards.
Storage
Requirements for storage areas and containers
Observe label precautions. Storage temperature: +5 to +35o C. No smoking. Prevent unauthorized access. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
B12206249
Axalta and Axalta Coating Systems are trademarks or registered trademarks of Axalta Coating Systems, LLC and all affilR Permahyd,
R Permasolid,
R Permacron,
R Priomat
R , Permafleet,
R Permaloid,
R Permafast
R
iates. Spies Hecker,
R are registered trademarks of Axalta Coating Systems, LLC and all affiliates. All rights reserved.
and Raderal
3-9
2016-01-27
Spies Hecker Material Safety Data Sheet
Advice on common storage
Store separately from oxidizing agents and strongly alkaline and strongly acidic materials.
OSHA/NFPA Storage Classification: II
8. Exposure controls/personal protection
Engineering controls and work practices
Provide adequate ventilation. This should be achieved by a good general extraction and -if practically feasible- by the use of a local
exhaust ventilation. If these are not sufficient to maintain concentrations of particulates and solvent vapour below the OEL, suitable
respiratory protection must be worn.
National occupational exposure limits
CAS-No.
71-23-8
107-98-2
13463-67-7
Chemical Name
N-propanol
Propylene glycol methyl ether
Titanium dioxide
Time
Type
Value
Source
ACGIH
Note
8 hr
TWA
100 ppm
OSHA
15 min
STEL
250 ppm
8 hr
TWA
200 ppm
Dupont
8 hr
TWA
200 ppm
ACGIH
15 min
STEL
150 ppm
8 hr
TWA
100 ppm
OSHA
8 hr
TWA
15 mg/m3
Total Dust
Dupont
8 & 12
hour
TWA
10 mg/m3
Total Dust
8 & 12
hour
TWA
5 mg/m3
Respirable
Dust
Skin
** TWA = Time-weighted average.
STEL = Short term exposure limit.
Protective equipment
Personal protective equipment should be worn to prevent contact with eyes, skin or clothing.
Respiratory protection
Do not breathe vapors or mists. When this product is used with an isocyanate activator/hardener, wear a positive-pressure,
supplied-air respirator (NIOSH approved TC-19C) while mixing activator/hardener with paint, during application and until all vapors
and spray mist are exhausted. If product is used without isocyanate activator/hardener, a properly fitted air-purifying respirator with
organic vapor cartridges (NIOSH TC-23C) and particulate filter (NIOSH TC-84A) may be used. Follow respirator manufacturer’s
directions for respirator use. Do not permit anyone without protection in the painting area. Refer to the hardener/activator label
instructions and MSDS for further information. Individuals with history of lung or breathing problems or prior reaction to isocyanates
should not use or be exposed to this product if mixed with isocyanate activators/hardeners.
Eye protection
Desirable in all industrial situations. Goggles are preferred to prevent eye irritation. If safety glasses are substituted, include splash
guard or side shields.
Skin and body protection
Neoprene gloves and coveralls are recommended.
B12206249
Axalta and Axalta Coating Systems are trademarks or registered trademarks of Axalta Coating Systems, LLC and all affilR Permahyd,
R Permasolid,
R Permacron,
R Priomat
R , Permafleet,
R Permaloid,
R Permafast
R
iates. Spies Hecker,
R are registered trademarks of Axalta Coating Systems, LLC and all affiliates. All rights reserved.
and Raderal
4-9
2016-01-27
Spies Hecker Material Safety Data Sheet
Hygiene measures
Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners.
Environmental exposure controls
Do not let product enter drains. For ecological information, refer to Ecological Information Section 12.
9. Physical and chemical properties
Appearance
Form: liquid
Colour: silver
Flash point
Lower Explosive Limit
Upper Explosive Limit
Evapouration rate
Vapor pressure of principal solvent
Water solubility
Vapor density of principal solvent (Air = 1)
Approx. Boiling Range
Approx. Freezing Range
Gallon Weight (lbs/gal)
Specific Gravity
Percent Volatile By Volume
Percent Volatile By Weight
Percent Solids By Volume
Percent Solids By Weight
pH (waterborne systems only)
Partition coefficient: n-octanol/water
Ignition temperature
Decomposition temperature
Viscosity (23 ◦ C)
VOC* less exempt (lbs/gal)
VOC* as packaged (lbs/gal)
105 ◦ F
Not applicable.
Not applicable.
Slower than Ether
3.6 hPa
appreciable
0.6
100 ◦ C
Not applicable.
8.84
1.06
80.20%
73.53%
19.80%
26.47%
7.5 – 7.8
no data available
270 ◦ C
Not applicable.
24 s
3.1
1.1
DIN 51794
ISO 2431-1993 6 mm
Does not sustain combustion.
* VOC less exempt (theoretical) and VOC as packaged (theoretical) are based upon the VOC of the packaged material at the point of
manufacture.
10. Stability and reactivity
Stability
Stable
Conditions to avoid
Stable under recommended storage conditions.
Materials to avoid
None reasonably foreseeable.
Hazardous decomposition products
When exposed to high temperatures may produce hazardous decomposition products such as carbon monoxide and dioxide, smoke,
oxides of nitrogen.
B12206249
Axalta and Axalta Coating Systems are trademarks or registered trademarks of Axalta Coating Systems, LLC and all affilR Permahyd,
R Permasolid,
R Permacron,
R Priomat
R , Permafleet,
R Permaloid,
R Permafast
R
iates. Spies Hecker,
R are registered trademarks of Axalta Coating Systems, LLC and all affiliates. All rights reserved.
and Raderal
5-9
2016-01-27
Spies Hecker Material Safety Data Sheet
Hazardous Polymerization
Will not occur.
Sensitivity to Static Discharge
If heated above the flash point, solvent vapors in air may explode if static grounding and bonding is not used during transfer of this
product.
Sensitivity to Mechanical Impact
None known.
11. Toxicological information
Information on likely routes of exposure
Inhalation
May cause nose and throat irritation. If this product mixed with an isocyanate activator/hardener (see MSDS for the activator), the
following health effects may apply: Exposure to isocyanates may cause respiratory sensitization. This effect may be permanent.
Symptoms include an asthma-like reaction with shortness of breath, wheezing, cough or permanent lung sensitization. This effect
may be delayed for several hours after exposure. Repeated overexposure to isocyanates may cause a decrease in lung function,
which may be permanent. Individuals with lung or breathing problems or prior reactions to isocyanates must not be exposed to
vapors or spray mist of this product.
Ingestion
May result in gastrointestinal distress.
Skin or eye contact
May cause irritation or burning of the eyes. Repeated or prolonged liquid contact may cause skin irritation with discomfort and
dermatitis.
Delayed and immediate effects and also chronic effects from short and long term exposure:
Acute oral toxicity
not hazardous
Acute dermal toxicity
not hazardous
Acute inhalation toxicity
not hazardous
% of unknown composition 9.9 %
Skin corrosion/irritation
Not classified according to GHS criteria
Serious eye damage/eye irritation
N-pentanol
N-propanol
Category 2A
Category 1
Respiratory sensitisation
Not classified according to GHS criteria
B12206249
Axalta and Axalta Coating Systems are trademarks or registered trademarks of Axalta Coating Systems, LLC and all affilR Permahyd,
R Permasolid,
R Permacron,
R Priomat
R , Permafleet,
R Permaloid,
R Permafast
R
iates. Spies Hecker,
R are registered trademarks of Axalta Coating Systems, LLC and all affiliates. All rights reserved.
and Raderal
6-9
2016-01-27
Spies Hecker Material Safety Data Sheet
Skin sensitisation
Not classified according to GHS criteria
Germ cell mutagenicity
Not classified according to GHS criteria
Carcinogenicity
Not classified according to GHS criteria
Toxicity for reproduction
Not classified according to GHS criteria
Target Organ Systemic Toxicant - Single exposure
Not classified according to GHS criteria
Target Organ Systemic Toxicant - Repeated exposure
Not classified according to GHS criteria
Aspiration toxicity
Not classified according to GHS criteria
Numerical measures of toxicity (acute toxicity estimation (ATE),etc. )
No information available.
Symptoms related to the physical, chemical and toxicological characteristics
Exposure to component solvents vapours concentration in excess of the stated occupational exposure limit may result in adverse
health effect such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous
system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of
consciousness. Through skin resorbtion, solvents can cause some of the effects described here. Repeated or prolonged contact with
the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the
skin. The liquid splashed in the eyes may cause irritation and reversible damage.
Whether the hazardous chemical is listed by NTP, IARC or OSHA
Titanium dioxide
IARC 2B
12. Ecological information
There are no data available on the product itself. The product should not be allowed to enter drains or watercourses.
13. Disposal considerations
Waste Disposal Method
Do not allow material to contaminate ground water systems. Incinerate or otherwise dispose of waste material in accordance with
Federal, State, Provincial, and local requirements. Do not incinerate in closed containers.
14. Transport information
Not classified as dangerous in the meaning of transport regulations.
Not classified as supporting combustion according to the transport regulations.
B12206249
Axalta and Axalta Coating Systems are trademarks or registered trademarks of Axalta Coating Systems, LLC and all affilR Permahyd,
R Permasolid,
R Permacron,
R Priomat
R , Permafleet,
R Permaloid,
R Permafast
R
iates. Spies Hecker,
R are registered trademarks of Axalta Coating Systems, LLC and all affiliates. All rights reserved.
and Raderal
7-9
2016-01-27
Spies Hecker Material Safety Data Sheet
Matters needing attention for transportation
Confirm that there is no breakage, corrosion, or leakage from the container before shipping. Be sure to prevent damage to cargo by
loading so as to avoid falling, dropping, or collapse. Ship in appropriate containers with denotation of the content in accordance with
the relevant statutes and rules.
15. Regulatory information
TSCA Status
In compliance with TSCA Inventory requirements for commercial purposes.
DSL Status
Product is not DSL listed because one or more ingredients are not on the DSL inventory.
Photochemical Reactivity
Non-photochemically reactive
Regulatory information
CAS #
71-41-0
71-23-8
107-98-2
13463-67-7
Ingredient
N-pentanol
N-propanol
Propylene glycol
ether
Titanium dioxide
—————— EPCRA —————–
302
TPQ
RQ
311/312
313
N
NR
NR
NA
N
N
NR
NR
C,F
N
N
NR
NR
C,F
N
methyl
N
NR
NR
A
CERCLA
RQ(lbs)
NR
NR
NR
N
NR
CAA
HAP
N
N
N
N
Key:
EPCRA
Emergency Planning and Community Right-to-know Act (aka Title III, SARA)
302
Extremely hazardous substances
311/312 Categories
F = Fire Hazard
R = Reactivity Hazard
P = Pressure Related Hazard
313 Information
Section 313 Supplier Notification - The chemicals listed above with
a ’Y’ in the 313 column are subject to reporting requirements of
Section 313 of the Emergency Planning and Community
Right-to-Know act of 1986 and of 40 CFR 372.
CERCLA
HAP
TPQ
RQ
NA
NR
Comprehensive Emergency Response, Compensation and Liability Act of 1980.
Listed as a Clean Air Act Hazardous Air Pollutant.
Threshold Planning Quantity.
Reportable Quantity
not available
not regulated
A = Acute Hazard
C = Chronic Hazard
16. Other information
HMIS rating
H: 1 F: 2 R: 0
Glossary of Terms:
ACGIH
IARC
NTP
OEL
American Conference of Governmental Industrial Hygienists.
International Agency for Research on Cancer.
National Toxicology Program.
Occupational Exposure Limit
B12206249
Axalta and Axalta Coating Systems are trademarks or registered trademarks of Axalta Coating Systems, LLC and all affilR Permahyd,
R Permasolid,
R Permacron,
R Priomat
R , Permafleet,
R Permaloid,
R Permafast
R
iates. Spies Hecker,
R are registered trademarks of Axalta Coating Systems, LLC and all affiliates. All rights reserved.
and Raderal
8-9
2016-01-27
Spies Hecker Material Safety Data Sheet
OSHA
STEL
TWA
PNOR
PNOC
Occupational Safety and Health Administration.
Short term exposure limit.
Time-weighted average.
Particles not otherwise regulated.
Particles not otherwise classified.
NOTE: The list (above) of glossary terms may be modified.
Notice from
The document reflects information provided to Spies Hecker by its suppliers. Information is accurate to the best of our knowledge and
is subject to change as new data is received by Spies Hecker. Persons receiving this information should make their own
determination as to its suitability for their purposes prior to use. The information on this Safety Data Sheet relates only to the specific
material designated herein and does not relate to use in combination with any other material or in any process.
SDS prepared by:
Spies Hecker Regulatory Affairs Consultant
(888) 371-3313
spieshecker.us
axalta.us
B12206249
Axalta and Axalta Coating Systems are trademarks or registered trademarks of Axalta Coating Systems, LLC and all affilR Permahyd,
R Permasolid,
R Permacron,
R Priomat
R , Permafleet,
R Permaloid,
R Permafast
R
iates. Spies Hecker,
R are registered trademarks of Axalta Coating Systems, LLC and all affiliates. All rights reserved.
and Raderal
9-9
2016-01-27
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