MATERIAL SAFETY DATA SHEET AEROSOL LUBRICANTS & PENETRANTS 10/12/05 PRODUCTS COVERED: AB-S, AC-G, AG-R, AG-W, AR-4, AR-B, AR-T, AS-H, AT-L SECTION I MANUFACTURER Crest Industries, Inc., 1337 King Road, Trenton, MI 48183 Phone: (734) 479-4141 FAX: (734) 479-4040 24 HOUR EMERGENCY TELEPHONE (CHEMTEL): (800) 255-3924 INTERNATIONAL CALLS: (813) 248-0585 Stock Number AB-S AC-G AG-R AG-W AR-4 AR-B AR-T SECTION II PRODUCTS Numbers of Ingredients HMIS RATING Product Name on Label in Products H F R Red Battery Terminal Protector 1, 11, 18, 20, 34, 36 3* 3 0 Clear Cheetah Grease 1, 9, 11, 18, 27, 28, 30 3* 4 0 Red Lube 1, 2, 5, 25, 37 3* 1 0 White Lithium Grease 8, 14, 17, 31, 37, 38 3* 3 0 Rustek Plus 4 12, 13, 16, 32, 36 3 3 0 Rustek Penetrant Lubricant 4, 7, 31, 35 2 4 0 RusTerminator Cyberlube Penetrant 5, 19, 21, 22, 23, 24 3 2 0 AS-H Hi-Viscosity Silicone Spray 1, 10, 29, 31 2 4 0 AT-L Dry Lubricant 3, 10, 26, 30, 31, 33 2 4 0 *Chronic health effects may occur from ingredients 11, 37. See NOTES in SECTION VI. SECTION III HAZARDOUS INGREDIENTS Ingredients 1. Acetone 2. Antimony Metal Salt 3. Butane (or n-Butane) 4. Calcium Dinonylnaphthalene Sulfonate 5. Carbon Dioxide 6. Cyclohexane 7. Heavy Aliphatic Naphtha 8. Heavy Naphthenic Petroleum Oil 9. Heavy Paraffinic Petroleum Distillate 10. Heptane (or n-Heptane) 11. Hexane (or n-Hexane)** 12. Hydrotreated Kerosene 13. Hydrotreated, Severe, Lt. Naphthenic Distillate 14. Isobutane 15. Isohexane Isomers 16. Kerosene 17. Light Petroleum Distillate 18. Liquid (or Liquefied) Petroleum Gas 19. Medium Aromatic Hydrocarbons 20. Metalworking Fluid Additive 21. 2-Methoxymethylethoxypropanol 22. Methyl Acetate 23. Mineral Spirits 140-Flash 24. Naphthalene 25. Paraffin Oil 26. Pentane 27. Petrolatum 28. Petroleum Oil 29. Polydimethylsiloxane 30. Polytetrafluoroethylene (PTFE) 31. Propane 32. Propane/Isobutane/ n-Butane 33. 2-Propanol 34. Severely Hydrotreated Mineral Oil 35. Solvent-Dewaxed Heavy Paraffinic Petroleum Distillate Mineral Oil 36. Stoddard Solvent 37. Tetrachloroethylene** 38. Zinc Oxide CAS Number 67-64-1 Unknown 106-97-8 Exposure Limits* in ppm (parts per million) 750 A, O 0.5 mg/m3 A, O 1000 A, 800 N 57855-77-3 NE 124-38-9 5000 A,10000 O 110-82-7 300 A, O 68551-20-2 5 mg/m3 A mist 64742-52-5 5 mg/m3 A mist Flash Vapor PresPoint sure (mm Hg °F °C at 20°C) -4 -20 185 -NANA <-40 >1500 >200 >93 <0.01 None >45000 -7 -22 95 >200 >93 <0.01 Appearance and Odor Red liquid, strong solvent Clear liquid, strong solvent Red liquid, strong solvent White paste, mild solvent Amber liquid, mild solvent Gray liquid, mild solvent Solubility % in Water 10 24 20 <1 <1 <1 Volatile Volume% 60 to 70 75 to 85 50 to 60 50 to 60 40 to 50 15 to 25 Yellow liquid, strong solvent Clear liquid, strong solvent Cloudy liquid, mild solvent 30 35 <3 65 to 70 95 to 98 95 to 99 Evap. Rate (n-Butyl Acetate=1) 7.7 NA 114 Boiling Point °F °C 132 56 -NA31 -1 Flammable Limits in % Lower Upper 2.6 12.8 -NA1.8 8.4 Autoignition Pt. °F °C 869 465 -NA860 460 <0.01 NA 6.1 <0.1 1120 605 -108 -78 177 81 Unknown Unknown -NA1.3 8.3 Unknown Unknown None 473 245 Unknown >200 >93 <0.01 <0.1 Unknown Unknown Unknown 5 mg/m A mist 400 A, 500 O 50 A, 500 O** 100 mg/m3 N >200 >93 25 4 -7 -22 148 64 <0.01 45 140 0.4 <0.1 4.5 8.1 Unknown Unknown 201 94 156 69 350 177 Unknown 1.2 6.7 1.2 7.4 1.0 8.0 Unknown 433 223 437 225 Unknown 64742-52-5 5 mg/m3 A mist 75-28-5 1000 A, 800 N 107-83-5 500 A, O 8008-20-6 100 mg/m3 N 64742-89-8 400 E >200 >93 <-40 -32 -36 148 64 <20 <-7 <0.01 >1500 <200 0.4 60 <0.1 >114 16.2 Unknown 3.9 Unknown 11 -12 140 60 350 177 206 97 Unknown 1.8 8.4 1.0 7.0 1.0 8.0 1.2 6.8 Unknown 860 460 507 264 Unknown 536 280 >164 -45 2.1 9.5 842 450 64742-65-0 142-82-5 110-54-3 64742-47-8 3 68476-86-8 1000 A, O 3 <-40 64742-94-5 (Mixture) 5 mg/m A mist 100 A, O >200 >93 >200 >93 34590-94-8 79-20-9 64742-88-7 91-20-3 8012-95-1 109-66-0 8009-03-8 64742-52-5 63148-62-9 100 (Skin) A, O 200 A, O 100 A, O 10 A, O 5 mg/m3 A mist 600 A, 1000 O 5 mg/m3 A mist 5 mg/m3 A mist 5 mg/m3 A mist >200 4 140 189 >200 -57 >200 >200 >200 >93 -15 60 87 >93 -49 >93 >93 >93 >760 -43 0.12 <0.01 <0.1 <0.01 Unknown Unknown Unknown Unknown Unknown Unknown 0.4 180 0.5 <1 <0.01 425 <0.01 <0.01 <1 <0.1 6.2 <0.01 <1 <0.01 >10 <0.1 <0.1 <0.1 Unknown 132 56 355 179 424 218 Unknown 97 36 Unknown Unknown Unknown Unknown 3.1 16.0 1.4 6.8 0.9 5.9 Unknown 1.4 7.8 Unknown Unknown Unknown Unknown 934 501 Unknown 979 526 Unknown 496 258 Unknown Unknown Unknown NA >114 -NA-44 -42 -NA2.1 9.5 -NA919 493 >164 1.7 -45 180 -43 82 2.1 9.5 2.0 12.0 842 450 750 399 9002-84-0 NE 74-98-6 1000 A, O -NA<-40 NA >1500 68476-86-8 1000 A, O 67-63-0 400 A, O <-40 53 12 >760 31 5 mg/m3 A mist >200 >93 <0.01 <0.1 Unknown Unknown Unknown 64742-65-0 5 mg/m3 A mist 8052-41-3 100 A, 500 O 127-18-4 50 A, 25 O** 1314-13-2 10 mg/m3 A, 10 (5 Respirable Dust Fraction) O >200 >93 104 40 None -NA- <0.01 3 13 NA <0.1 0.2 2.1 NA Unknown 318 159 250 121 -NA- Unknown 0.7 6.0 None -NA- Unknown >394 >201 None -NA- 64742-52-5 *A means ACGIH TLV, N means NIOSH, O means OSHA PEL. Other abbreviations: > means greater than, < means less than, Lt. Means Light, NA means Not Applicable, NE means Not Established. **See NOTES in SECTION VI. Aerosol Lubricants & Penetrants MSDS 10/12/05 page 2 SECTION IV PHYSICAL DATA Pressure of Can Contents: Maximum pressure less than 140 PSI GAUGE @ 130°F (54°C). Evaporation Rate: See SECTIONS II, III. Vapor Density: Heavier than air. Solubility in Water (Wt%): See SECTION II. Volatile Volume %: See SECTION II. Approximate Boiling Point: See SECTIONS II, III. Product Density (water=1): Less than 1 (AGR and AGW are greater than 1). Ingredients (except 2, 37, 38): Less than 1. Appearance and Odor: See SECTION II. SECTION V FIRE AND EXPLOSION DATA Flash Point (Tag Closed Cup Method): See SECTIONS II, III. Approximate Flammable Limits: See SECTIONS II, III. Autoignition Temperature: See SECTIONS II, III. Extinguishing Media: Foam, carbon dioxide, dry chemical. Special Fire Fighting Procedures: Full protective equipment, including self-contained breathing apparatus, is recommended because highly toxic gasses may be generated by combustion or thermal decomposition. Water from fog nozzles may be used to cool closed containers to prevent pressure build up (containers may leak or burst when heated). Unusual Fire and Explosion Hazards: Vapors are heavier than air and may travel along the ground or be moved by ventilation and ignited by pilot lights, other flames, sparks, heaters, electric motors, smoking or other ignition sources at locations far from material handling point. At elevated temperatures [130°F (54°C) or over] containers may vent, rupture or burst. SECTION VI HEALTH HAZARD DATA PRIMARY ROUTES OF EXPOSURE: Inhalation, Skin contact, Eye contact. SIGNS AND SYMPTOMS OF EXPOSURE: INHALATION: Acute Exposure: Solvent vapors at concentrations above the TLV can irritate the respiratory tract (nose, throat, lungs) causing a burning sensation, runny nose, sore throat, coughing, chest discomfort (tightness). May cause central nervous system depression with the following progressive symptoms: headache, dizziness, nausea, staggering gait, confusion, unconsciousness, cessation of breathing and death. NOTE: Do not smoke while using Dry Lube (AT-L). Wash hands thoroughly before smoking. Heating particles of 30. Polytetrafluoroethylene (PTFE) (contained in AT-L) in burning tobacco will result in fumes which, when inhaled with the tobacco smoke, can cause a temporary influenza-like condition called polymer fume fever. Chronic Exposure: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Symptoms include: loss of memory, loss of intellectual ability and loss of coordination. NOTE: Prolonged and/or repeated overexposure to 11. Hexane (n-Hexane) that is contained in AB-S and AC-G may cause Peripheral Neuropathy (damage to nerve tissue of the arms or legs) resulting in muscular weakness and loss of sensation in some or all of the following: fingers, hands, arms, toes, feet or legs. NOTE: INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING ANY SOLVENT VAPORS MAY BE HARMFUL OR FATAL. SKIN CONTACT: Acute Exposure: Repeated or prolonged skin contact with solvents can result in dry, defatted and cracked skin causing increased susceptibility to infection. Skin irritation may develop into contact dermatitis. Chronic Exposure: Exposure to small amounts of solvent over long periods of time may cause some or all of the symptoms as in acute exposure to solvents. EYE CONTACT: Acute Exposure: Irritation of the eyes with itching, burning, redness and even permanent tissue damage if sprayed directly into the eyes and not flushed out immediately. Chronic Exposure: Irritation of the eyes with itching, burning, redness. INGESTION: Acute Exposure: (Not likely unless deliberately sprayed into mouth.) Irritation to the mouth, and if swallowed, to the esophagus, stomach tissue and digestive tract. If swallowed, vomiting may cause breathing of liquid solvent resulting in chemical pneumonia. Chronic Exposure: Unknown. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: (See NOTES) None specifically known to Crest Industries, Inc. but it is possible that eye, respiratory tract, skin, liver, kidney, blood cell formation, nervous system and brain diseases may be aggravated by overexposure to the products on this MSDS. CARCINOGENICITY: Products not listed by NTP, IARC or OSHA. NOTE: 37. Tetrachloroethylene (contained in AG-R and AG-W) has been designated a carcinogen by OSHA. Risk to health depends on level and duration of exposure. Be especially careful to minimize breathing the solvent vapors from AG-R and AG-W. Use products outdoors, if possible. If you must use indoors, open all windows and doors or use other means to assure fresh air movement during application and drying. If properly used, a respirator (NIOSH/MSHA TC23C or equivalent) may offer additional protection. Get professional advice for respirator use. A dust mask does not provide protection against vapors! Clean up rags and other waste immediately and allow solvent vapors to evaporate outdoors. DO NOT use in basement or other unventilated area! SECTION VII EMERGENCY AND FIRST AID PROCEDURES INHALATION: Move to an area free from risk of further exposure. Administer oxygen or artificial respiration as needed. Obtain medical attention. SKIN CONTACT: Remove contaminated clothing immediately. Wash affected areas thoroughly with soap and water. Wash contaminated clothing thoroughly before reuse. Seek medical attention if irritation develops or persists. EYE CONTACT: Flush with clean, lukewarm water (low pressure) for at least 15 minutes while lifting eyelids. Refer person to physician for immediate attention. INGESTION: DO NOT INDUCE VOMITING! Consult physician, hospital emergency room or poison control center immediately. Have list of ingredients available. NOTES TO PHYSICIAN: Inhalation: Treat as for solvent vapor inhalation. Bronchodilators, expectorants and antitussives may help. Skin: Treat as any contact dermatitis. Eyes: May cause conjunctivitis. Stain for evidence of corneal injury. Ingestion: Treat as for solvent ingestion. Inducing vomiting is contraindicated because of the possibility of chemical pneumonia caused by aspiration of solvent liquid. SECTION VIII EMPLOYEE RECOMMENDATIONS VENTILATION AND RESPIRATORY PROTECTION: If exhaust ventilation sufficient to keep the airborne concentrations of solvents and propellants below their respective TLV's is not possible, an OSHA/MSHA approved TC23C Paint Spray Respirator with Particulate Prefilter or TC19C Air Supplied Respirator must be used. Observe OSHA regulations (29 CFR 1910.134) for respirator use. NOTE: THERE MUST ALWAYS BE ENOUGH VENTILATION TO KEEP VAPOR CONCENTRATION BELOW THE LOWER FLAMMABLE LIMIT! SKIN PROTECTION: Cover as much of the skin as possible with appropriate clothing. Wear solvent resistant gloves. EYE PROTECTION: Desirable during use of aerosol products. Wear safety glasses, splash goggles or face shield. Contact lenses should not be worn. OTHER PROTECTIVE MEASURES: Eyewash stations should be available. Educate and train employees in safe use of products. Follow all label instructions. SECTION IX REACTIVITY DATA STABILITY: Stable under normal room conditions. HAZARDOUS POLYMERIZATION: Will not occur. INCOMPATIBILITY (Materials to Avoid): Strong oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS: By high heat and fire: carbon dioxide, carbon monoxide, hydrocarbon fumes, smoke. AG-R and AG-W will also give off hydrogen chloride, chlorine, phosgene and chlorinated hydrocarbon vapors. SECTION X SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Put on protective equipment including respiratory protection. Prevent further spillage. Evacuate nonessential personnel. Remove all sources of ignition and ventilate the area. Keep spill from reaching sewers and waterways. Cover the spill with sawdust, vermiculite, Fuller's Earth or other absorbent material. Collect material with non-sparking tools and put in a tightly sealed container. Remove container to a safe place. WASTE DISPOSAL METHOD: Follow all federal, state and local environmental control regulations. Incineration is the preferred method. DO NOT PUT AEROSOL CONTAINERS IN A HOME TRASH COMPACTOR! DO NOT INCINERATE (OR BURN) AEROSOL CONTAINERS EVEN WHEN EMPTY! Containers may become pressurized and burst even if they will not spray. Containers must be handled with care due to toxic and/or flammable and pressure producing residue. RCRA STATUS: Since these products are ignitable and toxic they are hazardous when discarded. SECTION XI SPECIAL PRECAUTIONS & STORAGE DATA STORAGE TEMPERATURE MINIMUM / MAXIMUM: 50°F (10°C) / 120°F (49°C) RECOMMENDED SHELF LIFE: One year Aerosol Lubricants & Penetrants MSDS 10/12/05 page 3 PRECAUTIONS TO BE TAKEN IN HANDLING, STORAGE AND USE: Keep away from heat, sparks and open flame. Do not store in temperatures above 120°F (49°C) or in direct sunlight. Do not inhale vapors or spray mist. Avoid contact with skin and eyes. Wash hands after use and before eating, drinking, smoking or using the toilet. Employee education and training in the safe use and handling of these materials are required under the OSHA Hazard Communication Standard (29 CFR 1910.1200). KEEP OUT OF THE REACH OF CHILDREN SECTION XII ENVIRONMENTAL PROTECTION AGENCY (EPA) REGULATORY INFORMATION The following percentage table is to be used to meet Environmental Protection Agency (EPA) Regulations: 1. 40 CFR Part 370 Emergency and Hazardous Chemical Inventory Forms and Community Right-to-Know Reporting Requirements. 2. Title III Section 313 Toxic Chemical Release Reporting Requirements. Note: All the chemicals listed must be considered for 1. above. Only the ones marked with an asterisk (*) fall under 2. The numbers in the following tables are good for all shipments until further notice.Note: This page is legally required to be sent with the previous two pages of this MSDS. HAZARDOUS INGREDIENTS IN AEROSOL LUBRICANTS & PENETRANTS APPROXIMATE PERCENTAGES BY WEIGHT Ingredients CAS Number ABS ACG AGR AGW AR4 ARB ART ASH ATL 1. Acetone 67-64-1 10 24 20 35 *2. Antimony Metal Salt Unknown 01 3. Butane (or n-Butane) 106-97-8 31 4. Calcium Dinonylnaphthalene Sulfonate 57855-77-3 01 5. Carbon Dioxide 124-38-9 02 03 *6. Cyclohexane 110-82-7 7. Heavy Aliphatic Naphtha 68551-20-2 75 8. Heavy Naphthenic Petroleum Oil 64742-52-5 26 9. Heavy Paraffinic Petroleum Distillate 64742-65-0 13 10. Heptane (or n-Heptane) 142-82-5 45 16 *11. Hexane (or n-Hexane)** 110-54-3 30 23 12. Hydrotreated Kerosene 64742-47-8 20 13. Hydrotreated, Severe, Lt. Naphthenic Distillate 64742-52-5 20 14. Isobutane (Methylpropane) 75-28-5 07 15. Isohexane Isomers 107-83-5 16. Kerosene 8008-20-6 25 17. Light Petroleum Distillate 64742-89-8 06 18. Liquid (or Liquefied) Petroleum Gas 68476-86-8 15 24 19. Medium Aromatic Hydrocarbons 64742-94-5 46 20. Metalworking Fluid Additive (Mixture) 05 21. 2-Methoxymethylethoxypropanol 34590-94-8 06 22. Methyl Acetate 79-20-9 24 23. Mineral Spirits 140-Flash 64742-88-7 17 *24. Naphthalene 91-20-3 04 25. Paraffin Oil 8012-95-1 28 26. Pentane 109-66-0 34 27. Petrolatum 8009-03-8 07 28. Petroleum Oil 64742-52-5 03 29. Poly (dimethylsilioxane) 63148-62-9 05 30. Polytetrafluoroethylene (PTFE) 9002-84-0 01 03 31. Propane 74-98-6 08 10 15 14 32. Propane/Isobutane/n-Butane 68476-86-8 20 33. 2-Propanol 67-63-0 02 34. Severely Hydrotreated Mineral Oil 64742-52-5 40 35. Solvent-Dewaxed Heavy Paraffinic Petroleum Distillate Mineral Oil 64742-65-0 12 36. Stoddard Solvent 8052-41-3 05 15 *37. Tetrachloroethylene (Perchloroethylene) 127-18-4 49 48 38. Zinc Oxide 1314-13-2 02 Physical Hazard-Fire 60 71 20 21 80 10 24 95 97 Physical Hazard-Pressure Release 15 24 02 15 20 10 03 15 45 Health Hazard-Acute 100 100 100 100 100 100 100 100 100 Health Hazard-Chronic 30 23 49 48 Physical Hazard-Reactivity NONE OF THE AEROSOL LUBRICANTS HAVE THIS HAZARD. Aerosol Level 3 3 1 2 3 3 3 3 3 Ingredients CAS Number ABS ACG AGR AGW AR4 ARB ART ASH ATL SECTION XIII VOLATILE ORGANIC COMPOUND (V.O.C.) CONTENT OF AEROSOL LUBRICANTS ACCORDING TO THE FEDERAL EPA Stock Number ABS ACG AGR AGW AR4 ARB ART ASH ATL Percent by Weight 49.3 48.0 0 22.0 48.8 85.3 50.0 60.0 98.7 Pounds per Gallon 3.00 2.82 0 1.81 3.12 5.52 3.61 3.49 5.01 Grams per Liter 359 338 0 216 373 661 4.33 418 600 Pounds per Can 0.362 0.39 0 0.179 0.374 0.667 0.375 0.384 0.62 SECTION XIV CALIFORNIA PROPOSITION 65 WARNINGS According to the California Safe Drinking Water and Toxic Enforcement Act (PROPOSITION 65) "No person in the course of doing business shall knowingly and intentionally expose any individual to a chemical known to the State of California to cause cancer, birth defects or reproductive toxicity without first giving clear and reasonable warning to such individuals of such an exposure". The following warnings apply: Tetrachloroethylene containing products (AG-R and AG-W): WARNING: This product contains a chemical known to the State of California to cause cancer. SECTION XV OZONE DEPLETION IN THE UPPER ATMOSPHERE None of the products on this MSDS contain Upper Atmosphere ozone depleting substances. DISCLAIMER: The information contained in this MSDS is believed to be accurate and reliable as of the date indicated. Crest Industries, Inc. assumes no legal responsibility and makes no representation, warranty or guarantee, expressed or implied, as to the completeness or accuracy of the information. It is offered solely for your consideration, investigation and verification. The user is ultimately responsible for the safe use of the material in accordance with applicable federal, state, provincial and local laws and regulations.
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