3M Specialty Adhesive Remover Template

3M MATERIAL SAFETY DATA SHEET 3M(TM) Adhesive Remover, Citrus Base, Bulk or 3M(TM) Scotch(TM) Adhesive Remover, Citrus Base, Pen 6042 / 6043 04/09/2003

Material Safety Data Sheet

Copyright, 2003, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: MANUFACTURER: DIVISION:

3M(TM) Adhesive Remover, Citrus Base, Bulk or 3M(TM) Scotch(TM) Adhesive Remover, Citrus Base, Pen 6042 / 6043 3M Industrial Adhesives and Tapes

ADDRESS:

3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)

Issue Date: Supercedes Date:

04/09/2003 11/16/2001

Document Group:

16-2070-7

Product Use:

Specific Use: citrus base adhesive remover

SECTION 2: INGREDIENTS

Ingredient

CITRUS EXTRACT

C.A.S. No.

8028-48-6

% by Wt

95 - 100

SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW

Odor, Color, Grade:

colorless to light yellow, citrus odor

General Physical Form:

Liquid

Immediate health, physical, and environmental hazards:

Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Combustible liquid and vapor.

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3.2 POTENTIAL HEALTH EFFECTS

Eye Contact:

Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.

Skin Contact:

Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.

Inhalation:

Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

Ingestion:

Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.

SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES

The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed.

Eye Contact:

Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.

Skin Contact:

Wash affected area with soap and water. If signs/symptoms develop, get medical attention.

Inhalation:

Remove person to fresh air. If signs/symptoms develop, get medical attention.

If Swallowed:

Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person.

Get immediate medical attention.

SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES

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3M MATERIAL SAFETY DATA SHEET 3M(TM) Adhesive Remover, Citrus Base, Bulk or 3M(TM) Scotch(TM) Adhesive Remover, Citrus Base, Pen 6042 / 6043 04/09/2003 Autoignition temperature Flash Point Flammable Limits - LEL Flammable Limits - UEL

No Data Available

117 ºF [

Test Method:

Pensky-Martens Closed Cup] .7 % [

Details:

CONDITIONS: @150 C] Approximately 6.1 % [

Details:

CONDITIONS: @262 C]

5.2 EXTINGUISHING MEDIA

Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).

5.3 PROTECTION OF FIRE FIGHTERS

Special Fire Fighting Procedures:

Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head.

Unusual Fire and Explosion Hazards:

Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Not applicable. Combustible liquid and vapor.

Use normal precautions suitable for oily rags.

Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information.

SECTION 6: ACCIDENTAL RELEASE MEASURES

Accidental Release Measures:

Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Cover or dilute with water. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with detergent and water. Place in a metal container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible.

In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations.

SECTION 7: HANDLING AND STORAGE 7.1 HANDLING

Avoid eye contact with vapors, mists, or spray. Avoid breathing of vapors, mists or spray. Avoid prolonged or repeated skin contact.

Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. No smoking while handling this material. Avoid contact with oxidizing agents. Keep out of the reach of children.

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7.2 STORAGE

Store away from acids. Store away from heat. Store out of direct sunlight. Store away from oxidizing agents. Keep container in well-ventilated area.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS

Use with appropriate local exhaust ventilation. Provide appropriate local exhaust ventilation on open containers.

8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)

8.2.1 Eye/Face Protection

Avoid eye contact with vapors, mists, or spray. Avoid eye contact.

The following eye protection(s) are recommended: Safety Glasses with side shields.

8.2.2 Skin Protection

Avoid prolonged or repeated skin contact. Gloves not normally required.

Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.

Gloves made from the following material(s) are recommended: Butyl Rubber, Neoprene, Nitrile Rubber.

8.2.3 Respiratory Protection

Avoid breathing of vapors, mists or spray.

Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.

8.2.4 Prevention of Swallowing

Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.

8.3 EXPOSURE GUIDELINES

None Established

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Odor, Color, Grade: General Physical Form: Autoignition temperature Flash Point Flammable Limits - LEL Flammable Limits - UEL Boiling point Vapor Density Vapor Pressure Specific Gravity

colorless to light yellow, citrus odor Liquid

No Data Available

117 ºF [

Test Method:

Pensky-Martens Closed Cup] .7 % [

Details:

CONDITIONS: @150 C] Approximately 6.1 % [

Details:

CONDITIONS: @262 C] 340 - 372 ºF >=1 [

Ref Std:

<=2 mmHg AIR=1] Approximately 0.84 Units not avail. or not appl. [

Ref Std:

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3M MATERIAL SAFETY DATA SHEET 3M(TM) Adhesive Remover, Citrus Base, Bulk or 3M(TM) Scotch(TM) Adhesive Remover, Citrus Base, Pen 6042 / 6043 04/09/2003 pH Melting point Solubility in Water Evaporation rate Hazardous Air Pollutants Volatile Organic Compounds Percent volatile VOC Less H2O & Exempt Solvents Viscosity

WATER=1] 7 [

Details:

CONDITIONS: 5% solution in water]

Not Applicable

Nil <=1 [

Ref Std:

BUOAC=1] 0 % weight [

Test Method:

Calculated] 100 % weight [

Test Method:

calculated per EPA method 24] 100 % weight 840 g/l [

Test Method:

calculated per EPA method 24] Approximately 0.8 centipoise

SECTION 10: STABILITY AND REACTIVITY

Stability:

Stable.

Materials and Conditions to Avoid:

Strong bases; Temperatures above the boiling point

Hazardous Polymerization:

Hazardous polymerization will not occur.

Substance

Hydrocarbons Carbon monoxide Carbon dioxide Irritant Vapors or Gases

Hazardous Decomposition or By-Products

Condition

Oxidation, heat or reaction Oxidation, heat or reaction Oxidation, heat or reaction Oxidation, heat or reaction

SECTION 11: TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components.

SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION

Not determined.

CHEMICAL FATE INFORMATION

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Not determined.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste Disposal Method:

Reclaim if feasible. Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility.

EPA Hazardous Waste Number (RCRA):

D001 (Ignitable)

Since regulations vary, consult applicable regulations or authorities before disposal.

SECTION 14:TRANSPORT INFORMATION

ID Number(s):

62-4453-7530-6, 62-4453-7535-5, 62-4453-8530-5, 62-4453-8535-4, 62-4453-9530-4, 62-4453-9535-3, 62-4453-9930-6, 62 4453-9931-4, 62-4453-9932-2

Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material.

SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS

Contact 3M for more information.

311/312 Hazard Categories:

Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No

FDA Reference

FDA - Other

Status

Meets

Citation

21CFR 180.20

STATE REGULATIONS


CHEMICAL INVENTORIES

All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),

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or are exempt polymers whose monomers are listed on EINECS.

The components of this product are in compliance with the chemical notification requirements of TSCA.


INTERNATIONAL REGULATIONS


This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: OTHER INFORMATION

NFPA Hazard Classification Health:

1

Flammability:

2

Reactivity:

0

Special Hazards:

None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

No revision information is available.

DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.

In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.

3M MSDSs are available at www.3M.com

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