SAFETY DATA SHEET

Section 1. Identification

Product identifier :

SAKRETE STUCCO COLOR PACKS

Chemical family

Identified uses

Supplier/Manufacturer

: Inorganic Metal oxide.

: Inorganic pigment

: SAKRETE OF NORTH AMERICA

625 Griffith Rd., Ste100

Charlotte, NC 282 17

USA

In case of emergency

For information: 866-725-7383

: C HEMTREC

1-800-424-9300 [USA] /

+1 703-527-3887 [CAN]

Section 2. Hazards identification

HAZCOM Standard Status

Physical state

Color

Classification of the substance or mixture

Hazard pictograms :

:

: This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

: Powder.

: Light tan.

SKIN CORROSION/IRRITATION - Category 2

SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A

CARCINOGENICITY - Category 1A

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3

Signal word

Hazard statements

Hazard Not Otherwise

Classified (HNOC)

Precautionary statements

Prevention

: Danger

: Causes serious eye irritation. Causes skin irritation. May cause cancer. May cause respiratory irritation.

: None known.

Response

Storage

Sakrete Stucco Color Packs

: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Wear protective gloves and eye/face protection. Use only in a well-ventilated area. Avoid breathing dust. Wash hands thoroughly after handling.

: Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention.

IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

: Store locked up.

Version 1 1/9

Section 2. Hazards identification

Disposal

Supplemental label elements

: Dispose of contents and container in accordance with all local, regional, national and international regulations.

: Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials and food and drink.

Section 3. Composition/information on ingredients

Substance/mixture

Ingredient name

: Mixture

% CAS number calcium carbonate

Crystalline Quartz Silica

56 - 62%

0.1 - 1%

1317-65-3

14808-60-7

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of first aid measures

Eye contact :

Inhalation

Skin contact

Ingestion

:

:

:

Check for and remove any contact lenses. Get medical attention. In case of contact, flush eyes with plenty of water for at least 20 minutes. Use fingers to ensure that eyelids are separated and that the eye is being irrigated.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. If not breathing, if breathing is irregulor or respiratory arrest occurs, provide artifical respiration, or oxygen by a trained professional, using a pocket type respirator.

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes.

Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. In case of contact, flush skin with plenty of water for at least 20 minutes.

Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Potential acute health effects

Eye contact :

Skin contact

Causes serious eye irritation.

Inhalation : May cause respiratory irritation. Exposure to Silica, Quartz can cause a very serious lung disease called Silicosis with cough, shortness of breath, and changes in chest xray.

: Causes skin irritation.

Skin contact

Ingestion : No known significant effects or critical hazards.

Over-exposure signs/symptoms

Eye contact

Inhalation

:

: Causes irritation with symptoms of reddening, tearing, stinging, and swelling.

: The symptoms of silicosis may include: Shortness of breath, coughing, wheezing, fatigue, chest pain, loss of appetite and fever.

May cause respiratory tract irritation with symptoms of coughing, sore throat and runny nose.

Causes irritation with symptoms of reddening, itching, and swelling.

Sakrete Stucco Color Packs Version 1 2/9

Section 4. First aid measures

Ingestion :

Potential chronic health effects

No specific data.

Long-term exposure to high concentrations of dust containing iron oxide can cause a benign condition termed

“pulmonary siderosis”. This condition is not associated with any physical impairment of lung function. Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation. Excessive exposure to airborne crystalline silica can cause fibrotic lung damage, with scarring of the lungs with cough and shortness of breath. This is called "Silicosis". This is generally a slowly developing fibrotic disease as symptoms are usually delayed for 10 years or more. Symptoms are dyspnea, chest pain, breathlessness, and cough. The chronic lung scarring developed from the silica dust causes a progressive massive fibrosis. This may lead to increased susceptibility to tuberculosis. Suspected of causing cancer.

Notes to physician

Protection of first-aiders :

: Treat symptomatically. No specific treatment.

No special measures required.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media

Suitable extinguishing media

Unsuitable extinguishing media

:

:

Use an extinguishing agent suitable for the surrounding fire. In case of fire, use water spray (fog), foam or dry chemical.

None known.

Specific hazards arising from the chemical

Hazardous thermal decomposition products

: No specific fire or explosion hazard.

: Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides

Special protective actions for fire-fighters

Special protective equipment for fire-fighters

:

:

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

Environmental precautions

Methods and materials for containment and cleaning up

:

: No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing dust. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

: Move containers from spill area. Approach release from upwind. Avoid dust generation.

Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Avoid creating dusty conditions and prevent wind dispersal. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Prevent entry into sewers, water courses, basements or confined areas.

Sakrete Stucco Color Packs Version 1 3/9

Section 7. Handling and storage

Precautions for safe handling

Protective measures :

Conditions for safe storage :

Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing.

Do not ingest. Avoid breathing dust. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Remove contaminated clothing and protective equipment before entering eating areas. Workers should wash hands and face before eating, drinking and smoking.

Put on appropriate personal protection equipment. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed.

Do not store near sources of heat (furnaces, kilns, boilers, etc.). Exposure to excessive heat may cause this product to become unstable (slowly auto-oxidize) which generates additional heat. Under certain circumstances this heat generation may be sufficient to cause combustible materials to ignite. Do not store near strong oxidizers, sources of heat, or near flammable or combustible materials. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Empty containers retain product residue and can be hazardous. Do not reuse container.

Section 8. Exposure controls/personal protection

Occupational exposure limits

Ingredient name calcium carbonate

Crystalline Quartz Silica

Exposure limits

OSHA PEL (United States, 2/2013).

TWA: 5 mg/m³ 8 hours. Form: Respirable fraction

TWA: 15 mg/m³ 8 hours. Form: Total dust

OSHA PEL Z3 (United States, 2/2013).

TWA: 250 MPPCF / (%SiO2+5) 8 hours.

Form: Respirable

TWA: 10 MG/M3 / (%SiO2+2) 8 hours. Form:

Respirable

ACGIH TLV (United States, 4/2014).

TWA: 0.025 mg/m³ 8 hours. Form:

Respirable fraction

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.

Appropriate engineering controls

: Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Personal protection

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Sakrete Stucco Color Packs Version 1 4/9

Section 8. Exposure controls/personal protection

Respiratory protection

Skin protection

Eye/face protection

Medical Surveillance

: The following respirator is recommended if airborne concentrations exceed the appropriate standard/guideline. NIOSH approved, air-purifying particulate respirator with

N-95 filters.

: Permeation resistant clothing and foot protection. Permeation resistant gloves.

: safety glasses with side-shields

: Not available.

Section 9. Physical and chemical properties

Physical state

Color

Odor

Odor threshold pH

Boiling point

Melting point

Flash point

: Solid. [Powder.]

:

:

Light tan.

Odorless.

: Not available.

:

:

: Not available.

: Not available.

Not available.

Not available.

Evaporation rate

Explosion limits

Vapor pressure

Specific gravity (Relative density)

Solubility

Partition coefficient: noctanol/water

Vapor density

Viscosity

:

:

:

:

:

:

:

Not available.

: Not available.

Not available.

Not available.

Insoluble in the following materials: cold water

Not available.

Not available.

Not available.

Auto-ignition temperature : Not available.

Decomposition temperature : Not available.

Section 10. Stability and reactivity

Reactivity

Chemical stability

Possibility of hazardous reactions

Conditions to avoid

:

: No specific test data related to reactivity available for this product or its ingredients.

The product is stable.

: Under normal conditions of storage and use, hazardous reactions will not occur.

Incompatible materials

Hazardous decomposition products

:

:

:

Excessive temperatures. At temperatures greater than 176 F (80 C), this product may become unstable and slowly auto-oxidize into Fe2O3 which generates additional heat.

Under certain conditions this heat may be sufficient to cause combustible materials to ignite.

Contact with water/moisture causes formation of corrosive reaction products.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Section 11. Toxicological information

Information on the likely routes of exposure

Potential acute health effects

Eye contact

Inhalation

Skin contact

: Dermal contact. Eye contact. Inhalation. Ingestion.

: Causes serious eye irritation.

: May cause respiratory irritation. Exposure to Silica, Quartz can cause a very serious lung disease called Silicosis with cough, shortness of breath, and changes in chest xray.

: Causes skin irritation.

Sakrete Stucco Color Packs Version 1 5/9

Section 11. Toxicological information

Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact

Inhalation

Skin contact :

: Causes irritation with symptoms of reddening, tearing, stinging, and swelling.

: The symptoms of silicosis may include: Shortness of breath, coughing, wheezing, fatigue, chest pain, loss of appetite and fever.

May cause respiratory tract irritation with symptoms of coughing, sore throat and runny nose.

Causes irritation with symptoms of reddening, itching, and swelling.

Ingestion :

Potential chronic health effects

Short term exposure

Potential immediate effects

:

No specific data.

Not available.

Long term exposure

Potential delayed effects : Not available.

General

Carcinogenicity :

: Long-term exposure to high concentrations of dust containing iron oxide can cause a benign condition termed “pulmonary siderosis”. This condition is not associated with any physical impairment of lung function. Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation. Excessive exposure to airborne crystalline silica can cause fibrotic lung damage, with scarring of the lungs with cough and shortness of breath. This is called "Silicosis". This is generally a slowly developing fibrotic disease as symptoms are usually delayed for 10 years or more. Symptoms are dyspnea, chest pain, breathlessness, and cough. The chronic lung scarring developed from the silica dust causes a progressive massive fibrosis. This may lead to increased susceptibility to tuberculosis. Suspected of causing cancer.

May cause cancer. Risk of cancer depends on duration and level of exposure.

Mutagenicity

Teratogenicity

Developmental effects

Fertility effects

:

:

:

:

No known significant effects or critical hazards.

No known significant effects or critical hazards.

No known significant effects or critical hazards.

No known significant effects or critical hazards.

Information on toxicological effects

Acute toxicity

Product/ingredient name Result Species Dose Exposure Test calcium carbonate LD50 Oral Rat 6450 mg/kg -

Irritation/Corrosion

Conclusion/Summary

Skin : calcium carbonate:Moderate irritant

: calcium carbonate:Severe irritant Eyes

Mutagenicity

Product/ingredient name

Crystalline Quartz Silica

Conclusion/Summary

Carcinogenicity

Test

Sister chromatid exchange assay

Experiment

Experiment: In vivo

Subject: Mammalian-Animal

Cell: Somatic

: Crystalline Quartz Silica:No mutagenic effect.

Result

Negative

Sakrete Stucco Color Packs Version 1 6/9

Section 11. Toxicological information

CAS # Product/ingredient name calcium carbonate

Crystalline Quartz Silica

1317-65-3

14808-60-7

IARC

Not classified.

1 Carcinogenic to humans

Specific target organ toxicity (single exposure)

Name Category

NTP

Not classified.

Proven.

OSHA

Not classified.

Not classified.

calcium carbonate

Crystalline Quartz Silica

Category 3

Category 3

Route of exposure

Not applicable.

Not applicable.

Target organs

Respiratory tract irritation

Respiratory tract irritation

Acute toxicity estimates

Route

Not available.

ATE value (Acute Toxicity Estimates)

Section 12. Ecological information

Toxicity

Product/ingredient name Test Result Species Exposure calcium carbonate

-

-

-

-

Acute EC50 >200 mg/l

Acute EC50 >1000 mg/l

Acute LC50 >10000 mg/l

Acute LC50 56000 mg/l

Algae

Daphnia

Fish

Fish - Gambusia affinis

72 hours

48 hours

96 hours

48 hours

Conclusion/Summary

Persistence and degradability

: Not available.

Conclusion/Summary

Bioaccumulative potential

Not available.

: Not available.

Mobility in soil

Soil/water partition coefficient (K

OC

)

Other adverse effects

: Not available.

: No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods

RCRA classification

: The generation of waste should be avoided or minimized wherever possible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal should be in accordance with existing federal state, provincial and or local environmental controls laws.

: : If discarded in its purchased form, this product would not be a hazardous waste either by listing or by characteristic. However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste. (40

CFR 261.20-24)

Sakrete Stucco Color Packs Version 1 7/9

Section 13. Disposal considerations

RCRA classification : If discarded in its purchased form, this product would not be a hazardous waste either by listing or by characteristic. However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste. (40

CFR 261.20-24)

Section 14. Transport information

Classes PG* Label Regulatory information

DOT Classification -

UN number Proper shipping name

-

Additional information

Not regulated.

IMDG Class Not regulated.

Not regulated.

IATA-DGR Class -

PG* : Packing group

RQ : 0 lbs

Section 15. Regulatory information

SARA 311/312

SARA Title III Section 302

Extremely Hazardous

Substances

:

:

Immediate (acute) health hazard

Delayed (chronic) health hazard

None

SARA Title III Section 313

Toxic Chemicals

: None

US EPA CERCLA

Hazardous Subtances (40

CFR 302)

: None

State regulations

The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections on the SDS may also be applicable for state requirements. For details on your regulatory requirements you should contact the appropraite agency in your state.

Ingredient name CAS number State Code Concentration

(%) calcium carbonate

Iron (III) Oxide

Crystalline Quartz Silica

C.I. Pigment Black 11

C.I. Pigment Yellow 42

1317-65-3

1309-37-1

14808-60-7

1317-61-9

51274-00-1

MA - S, NJ - HS, PA - RTK HS

MA - S, NJ - HS, PA - RTK HS

NJ - HS, PA - RTK HS

56 - 62%

3 - 5%

0.1 - 1%

16 - 22%

13 - 19%

Massachusetts Substances: MA - S

Massachusetts Extraordinary Hazardous Substances: MA - Extra HS

New Jersey Hazardous Substances: NJ - HS

Pennsylvania RTK Hazardous Substances: PA - RTK HS

Pennsylvania Special Hazardous Substances: PA - Special HS

California Prop. 65

WARNING: This product contains a chemical known to the State of California to cause cancer.

Potential exposure to some or all of the California Proposition 65 chemicals in this product have been determined to be below the No Significant Risk Level (NSRL)

Ingredient name

Crystalline Quartz Silica

CAS #

14808-60-7

Concentration (%)

0.1 - 1%

Cancer

Yes

Reproductive

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Section 15. Regulatory information

U.S. Toxic Substances

Control Act

: Listed on the TSCA Inventory.

Section 16. Other information

Hazardous Material

Information System

:

Health

Flammability

Physical hazards

* 2

0

1

0=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme

*=Chronic

The customer is responsible for determining the PPE code for this material. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association

(NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.

No

National Fire Protection

Association (U.S.A.)

:

Health

2

0

1

Flammability

Instability/Reactivity

Special

0= Minimal 1=Slight 2=Moderate 3=Serious 4=Severe

Sakrete of North America's method of hazard communication is comprised of Product Labels and Safety Data

Sheets. HMIS and NFPA ratings are provided by Sakrete of North America as a customer service.

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency

Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.

No

Date of issue

Date of previous issue :

:

0 2-25-2016

05-26-2015

Version : 1

Product Safety and Regulatory Affairs

Indicates information that has changed from previously issued version.

No

Notice to reader

This information is furnished without warranty, express or implied. This information is believed to be accurate to the best knowledge of Sakrete of North America . The information in this SDS relates only to the specific material designated herein. Sakrete of North America assumes no legal responsibility for use of or reliance upon the information in this SDS.