Super Iron Out LI0616PN 16 fl. oz. Spray Specification

MATERIAL SAFETY DATA SHEET

space

Product Name space

CAS # space

Product use space

Manufacturer space

LEGEND

HMIS/NFPA

Severe

Serious

Moderate

Slight

Minimal

2

1

4

3

0

1. Product and Company Identification

Super Iron Out Spray

Mixture

Rust Stain Remover

Iron Out dba Summit Brands

7201 Engle Road

Fort Wayne, IN 46804-5875 US

Phone: 260-483-2519

Emergency Phone: 1-800-424-9300 (CHEMTREC)

Health / 3

Flammability

Physical Hazard

0

0

0

3 0

Personal Protection

X

2. Hazards Identification

space

Emergency overview DANGER -- CORROSIVE

CAUSES EYE BURNS. CAUSES SKIN BURNS.

space

Potential short term health effects

Routes of exposure space

Eyes space

Skin space

Inhalation space

Ingestion space

Target organs space

Chronic effects space

Signs and symptoms space

OSHA Regulatory Status space

Potential environmental effects

Eye, Skin contact, Skin absorption, Inhalation, Ingestion.

Causes chemical burns. May cause blindness.

Causes chemical burns.

Harmful if inhaled. May cause respiratory tract irritation or chemical burns.

Harmful if swallowed. May cause chemical burns to mouth, throat and stomach.

Eyes. Kidney. Respiratory system. Skin.

Prolonged or repeated exposure to dilutions can cause drying, defatting and dermatitis.

The product causes burns of eyes, skin and mucous membranes.

This product is a "Hazardous Chemical" as defined by the OSHA Hazard

Communication Standard, 29 CFR 1910.1200.

See section 12.

3. Composition / Information on Ingredients

space

Ingredient(s)

Oxalic acid

1,2-Propylene glycol

CAS #

144-62-7

57-55-6

Percent

5 - 10

1 - 5

4. First Aid Measures

space

First aid procedures

Eye contact space space space

Skin contact

Inhalation

Ingestion space

Notes to physician

Immediately flush with cool water. Remove contact lenses, if applicable, and continue flushing for 15 minutes. Obtain medical attention immediately.

Immediately flush with cool water for 15 minutes while removing contaminated clothing and shoes. Discard or wash well before reuse. Obtain medical advice immediately.

If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention.

Do not induce vomiting. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention.

Symptoms may be delayed.

#21770 Page 1 of 6 Issue date 30-Jan-2012

space

General advice If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of children.

5. Fire Fighting Measures

space

Flammable properties space

Extinguishing media space

Not flammable by WHMIS/OSHA criteria.

Suitable extinguishing media Dry chemical. Water spray. Alcohol foam. Carbon dioxide.

space

Unsuitable extinguishing media Not available space

Protection of firefighters

Specific hazards arising from the chemical space

Protective equipment for firefighters space

Hazardous combustion products

Not available

Firefighters should wear full protective clothing including self contained breathing apparatus.

May include and are not limited to: Oxides of carbon. Oxides of nitrogen. Hydrogen fluoride.

space

Explosion data

Sensitivity to mechanical impact

Not available

Sensitivity to static discharge Not available

6. Accidental Release Measures

space

Personal precautions space

Environmental precautions space

Methods for containment space

Methods for cleaning up

Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak.

Prevent entry into waterways, sewers, basements or confined areas.

Stop leak if you can do so without risk.

Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills to original containers for re-use.

space

Handling space

Storage

7. Handling and Storage

DANGER -- CORROSIVE

Use good industrial hygiene practices in handling this material.

Do not get in eyes, on skin or on clothing.

Avoid breathing vapors or mists of this product.

Use only with adequate ventilation.

Wash thoroughly after handling.

Keep out of the reach of children. Store in a closed container away from incompatible materials.

8. Exposure Controls / Personal Protection

space

Exposure limits

Ingredient(s)

1,2-Propylene glycol

Exposure Limits

ACGIH-TLV

Not established

OSHA-PEL

Not established

Oxalic acid ACGIH-TLV

TWA: 1 mg/m3

STEL: 2 mg/m3

OSHA-PEL

TWA: 1 mg/m3

#21770 Page 2 of 6 Issue date 30-Jan-2012

space

Engineering controls space

Personal protective equipment

Eye / face protection space

Hand protection space

Skin and body protection space space

Use only under good ventilation conditions or with respiratory protection.

Wear chemical goggles.

Rubber gloves. Confirm with a reputable supplier first.

As required by employer code. Rubber apron recommended.

Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator.

General hygiene considerations Use good industrial hygiene practices in handling this material. When using do not eat or drink. Wash hands before breaks and immediately after handling the product.

9. Physical and Chemical Properties

space

Appearance space

Color space

Form space

Odor space

Odor threshold space

Physical state space pH space

Melting point space

Freezing point space

Boiling point space

Pour point space

Evaporation rate space

Flash point space

Auto-ignition temperature space

Flammability limits in air, lower, % by volume space

Flammability limits in air, upper, % by volume space

Vapor pressure space

Vapor density space

Specific gravity space

Octanol/water coefficient space

Percent volatile

Clear

Colorless

Liquid

Lime.

Not available

Liquid

< 1

Not available

Not available

Not available

Not available

Not available

Not available

Not available

Not available

Not available

Not available

Not available

Not available

Not available

Not available

10. Stability and Reactivity

space

Reactivity space

Conditions to avoid space

Reacts violently with alkaline material. This product may react with reducing agents.

Possibility of hazardous reactions Hazardous polymerization does not occur.

space

Chemical stability space

Stable under recommended storage conditions.

Do not mix with other chemicals.

Incompatible materials space

Acids. Oxidizers. Caustics. Reducing agents.

Hazardous decomposition products May include and are not limited to: Oxides of carbon. Oxides of nitrogen. Hydrogen fluoride.

11. Toxicological Information

space

Component analysis - LC50

Ingredient(s)

1,2-Propylene glycol

Oxalic acid

LC50

Not available

Not available

#21770 Page 3 of 6 Issue date 30-Jan-2012

space

Component analysis - Oral LD50

Ingredient(s) LD50

1,2-Propylene glycol

Oxalic acid space

Effects of acute exposure

Eye space

Skin space

Inhalation space

Ingestion space

Sensitization space

Chronic effects space

Carcinogenicity space

Mutagenicity space

Reproductive effects space

Teratogenicity space

Name of Toxicologically Synergistic

Products

14800 mg/kg rabbit; 20000 mg/kg rat

375 mg/kg rat

Causes chemical burns. May cause blindness.

Causes chemical burns.

Harmful if inhaled. May cause respiratory tract irritation or chemical burns.

Harmful if swallowed. May cause chemical burns to mouth, throat and stomach.

Non-hazardous by WHMIS/OSHA criteria.

Non-hazardous by WHMIS/OSHA criteria.

Not classified or listed by IARC, NTP, OSHA and ACGIH.

Non-hazardous by WHMIS/OSHA criteria.

Non-hazardous by WHMIS/OSHA criteria.

Non-hazardous by WHMIS/OSHA criteria.

Not available

12. Ecological Information

space

Ecotoxicity Because of the low pH of this product, it would be expected to produce significant ecotoxicity upon exposure to aquatic organisms and aquatic systems.

Ecotoxicity - Freshwater Algae - Acute Toxicity Data

1,2-Propylene glycol 57-55-6

Ecotoxicity - Freshwater Fish - Acute Toxicity Data

1,2-Propylene glycol 57-55-6

96 Hr EC50 Pseudokirchneriella subcapitata: 19000 mg/L

Oxalic acid space

Persistence / degradability space

Bioaccumulation / accumulation space

Mobility in environmental media space

Environmental effects space

Aquatic toxicity space

Partition coefficient space

Chemical fate information space

Other adverse effects

Not available

Not available

Not available

Not available

Not available

Not available

Not available

96 Hr LC50 Oncorhynchus mykiss: 51600 mg/L [static]; 96 Hr LC50 Oncorhynchus mykiss: 41 - 47 mL/L [static]; 96 Hr LC50 Pimephales promelas: 51400 mg/L [static]; 96

Hr LC50 Pimephales promelas: 710 mg/L

24 Hr LC50 Lepomis macrochirus: 4000 mg/L [static] Oxalic acid 144-62-7

Ecotoxicity - Water Flea - Acute Toxicity Data

1,2-Propylene glycol 57-55-6

144-62-7

Not available

24 Hr EC50 Daphnia magna: >10000 mg/L; 48 Hr EC50 Daphnia magna: >1000 mg/L

[Static]

48 Hr EC50 Daphnia magna: 125 - 150 mg/L [Static]

13. Disposal Considerations

space

Disposal instructions space

Waste from residues / unused products space

Contaminated packaging

Review federal, state/provincial, and local government requirements prior to disposal.

Not available

Not available

#21770 Page 4 of 6 Issue date 30-Jan-2012

.

14. Transport Information

space

U.S. Department of Transportation (DOT)

Basic shipping requirements:

Proper shipping name Corrosive liquids, n.o.s. (OXALIC ACID)

Hazard class

UN number

8

UN1760

Packing group

Additional information:

II

Special provisions B2, IB2, T11, TP2, TP27

Packaging exceptions 154

ERG number 154 space

Transportation of Dangerous Goods (TDG - Canada)

Basic shipping requirements:

Proper shipping name CORROSIVE LIQUID, N.O.S. (OXALIC ACID)

Hazard class

UN number

8

UN1760

Packing group

Additional information:

II

Special provisions 16

15. Regulatory Information

space

Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled

Products Regulations and the MSDS contains all the information required by the

Controlled Products Regulations.

Canada - WHMIS - Ingredient Disclosure List

1,2-Propylene glycol

Oxalic acid space

WHMIS status space

WHMIS classification space

WHMIS labeling

57-55-6

144-62-7

Controlled

1 %

0.1 %

Class E - Corrosive Material space

Occupational Safety and Health Administration (OSHA)

29 CFR 1910.1200 hazardous chemical

Yes space

US Federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard

Communication Standard, 29 CFR 1910.1200.

space

CERCLA (Superfund) reportable quantity

None space

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate Hazard - Yes

Delayed Hazard - No

Fire Hazard - No

Pressure Hazard - No

Reactivity Hazard - No

#21770 Page 5 of 6 Issue date 30-Jan-2012

space space

Section 302 extremely hazardous substance

No

Section 311 hazardous chemical Yes space

Clean Air Act (CAA) space

Not available

Clean Water Act (CWA) space

Hazardous substance

State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm.

U.S. - California - 8 CCR Section 339 - Director's List of Hazardous Substances

Oxalic acid 144-62-7

U.S. - Massachusetts - Right To Know List

Present

Oxalic acid 144-62-7

U.S. - Minnesota - Hazardous Substance List

1,2-Propylene glycol

Oxalic acid

57-55-6

144-62-7

U.S. - Pennsylvania - RTK (Right to Know) List

Present

1,2-Propylene glycol 57-55-6 Present

Oxalic acid 144-62-7 Present

U.S. - New Jersey - Right to Know Hazardous Substance List sn 3595 sn 1445

Present

Present

1,2-Propylene glycol 57-55-6

Oxalic acid 144-62-7

U.S. - Rhode Island - Hazardous Substance List

1,2-Propylene glycol

Oxalic acid space

Inventory name

57-55-6

144-62-7

Flammable

Toxic; Flammable

Country(s) or region

Canada

Canada

United States & Puerto Rico

Inventory name

Domestic Substances List (DSL)

Non-Domestic Substances List (NDSL)

Toxic Substances Control Act (TSCA) Inventory

On inventory (yes/no)*

Yes

No

Yes

A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

16. Other Information

space

Disclaimer space

Issue date space

Effective date space

Expiry date space

Prepared by space

Other information

The data contained in this material safety data sheet was obtained from sources that were technically accurate, reliable, and state of the art when this document was prepared. If data was unavailable to complete certain sections, the absence of that data is identified in this document. Because the supplier cannot know the exact circumstances during actual use of this product, other hazards, exposure scenarios, disposal considerations, and regulations may apply and it is the responsibility of the user to read and understand the product label and this document before use. Do not use the product for purposes other than those stated in Section 1.

30-Jan-2012

15-Jan-2012

15-Jan-2015

Dell Tech Laboratories Ltd. (519) 858-5021

For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document.

#21770 Page 6 of 6 Issue date 30-Jan-2012