IPC-7530A Draft Document for Industry Consensus Only August 2016
While all the primary fluids can be classed as perfluorocarbons, the basic structure (amine, cyclic or ether) will determine the key properties of in-use stability, solder paste chemicals solubility and overall process economics.
The choice of a fluid is normally based on the melting point of the solder alloy to be reflowed.
For the range cited, the lower temperatures are suitable for the typical tin-lead or tin-lead-silver alloys used for standard attachment processes. The upper end of the range will permit reflow of high-lead alloys, which are used to attach pins to pin grid array (PGA) packages. Users faced with reflow of a specialty alloy have been successful in mixing two primary fluids to tailor a vapor-phase system for a specific stable boiling point. Higher temperatures will permit shorter times, which may be advantageous with some solder pastes.
The primary vapor phase should be inert and not introduce contaminants that must be removed later. Solder paste chemicals that dissolve in the fluid are carried in the high-boiling vapor then deposited onto the surface of the boards. Such residues tend to be difficult to remove. Minimizing solder paste residue in the primary fluid will maximize the lifetime of the fluid, prevent boiling point elevation due to dissolved paste ingredients and simplify cleaning.
The secondary vapor blanket was originally CFC-113, a lower-boiling fluorinated material, which formed a low-cost sacrificial “lid” over the costlier primary fluid. The constant exposure to the high-boiling primary fluid at the interface of the two fluids would cause the secondary fluid to undergo thermal decomposition at the interface, generating HCl (hydrochloric) and HF (hydrofluoric) acid vapors. These corrosive vapors often attacked the soldering equipment over time. While in theory the vapors could be absorbed in flux residues and cause problems for high-reliability products, this was rare in comparison to the attack on the equipment. With the phase-out of
CFC-113, a low-boiling perfluorocarbon was introduced to replace it. This second-generation secondary blanket fluid was more stable than CFC-113 for prolonged exposure to the high-boiling vapor-phase fluids.
As surface mount technology grew, most users converted to the higher throughput in-line machines, which used the single-fluid approach. Defluxing after vapor-phase reflow should be done with either a polar solvent formulation or include an aqueous cleaning formulation that can ensure removal of all solder paste residues, with the choice of cleaning process based on the composition of the solder paste. Secondary factors influencing the decision would be compatibility and the component-to-PWB surface spacing. In addition, most companies gave serious thought to considering the potential chemical loss from using this type of equipment since many perfluorinated compounds are very long-lived global warming compounds.
5 WAVE SOLDERING PROFILING
By definition, mass wave soldering implies creating many solder connections simultaneously in a semiautomated or automated process. Equipment designed for this task generally has four basic characteristics:
• Product conveyance
• Fluxing capability
• Preheating capability
• Molten pot of solder with a nozzle
The key feature of the wave soldering machine is the type of wave nozzle that is used, this will determine the quality of solder for both through-hole and surface-mount components. Solder waves commonly used are singlewave, or dual-wave where the first wave is turbulent either rough and also or oscillating-wave. The other key feature of a solder wave is whether the solder falls in one direction or in both directions back into the solder pot.
In general, the number of defects (e.g., icicles or bridging) are much lower in waves where the solder falls only in one direction – backward.
27
IPC-7530A Draft Document for Industry Consensus Only August 2016
The differences between manufacturers are in the application of these basic concepts and the equipment controls.
Each machine has unique characteristics that need to be taken into account when developing a thermal profile.
Traditional wave soldering machines are used for mass soldering of through-hole and some surface-mount components (typically chip resistors and capacitors). When bottom-side surface-mount components are soldered, they are secured in place with a cured adhesive prior to soldering.
The wave soldering system automatically performs the soldering process, which is flux application, heating of the area to be soldered, application of molten solder and solidification, as all of these characteristics act together to ensure proper soldering. A solder recipe is developed by recording the optimum process parameters selected for conveyor speed, flux application, preheaters and solder temperature.
When profiling assemblies for wave soldering, the following areas should be monitored. See Figure 5-1 for an example of a dual wave soldering profile.
Preheat: The rate of temperature increase is controlled to ensure the PWB, components and flux have sufficient time to reach soldering temperatures without degradation.
Thermal shock/peak temperature: Thermal shock and peak temperature is measured to ensure components are not exposed to excessive shock and/or temperature that can result in damage.
Dwell time: Dwell time is measured to ensure excessive time in the solder does not occur, which could result in damage to components.
Peak topside temperature: Maximum topside temperature is monitored to ensure solder joints formed by reflow do not revert to a liquid state.
FIRST
WAVE
SECOND
WAVE
200
180
160
150
140
130
280
270
260
250
240
230
220
210
120
110
100
90
80
60
50
40
TOO RAPID
HEATING RATE
15 30 45 60 75 90 105 120 135 150 165 180 195
TIME (SECONDS)
Figure 5-1 Dual-Wave Solder Profile
28